TW201840291A - Sensor system, clothing and clothing system - Google Patents

Sensor system, clothing and clothing system Download PDF

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Publication number
TW201840291A
TW201840291A TW107100914A TW107100914A TW201840291A TW 201840291 A TW201840291 A TW 201840291A TW 107100914 A TW107100914 A TW 107100914A TW 107100914 A TW107100914 A TW 107100914A TW 201840291 A TW201840291 A TW 201840291A
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Taiwan
Prior art keywords
piezoelectric element
clothing
piezoelectric
fiber
linear
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TW107100914A
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Chinese (zh)
Inventor
田實佳郎
小野雄平
兼松俊介
山本智義
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日商帝人股份有限公司
學校法人關西大學
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Publication of TW201840291A publication Critical patent/TW201840291A/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K15/00Devices for taming animals, e.g. nose-rings or hobbles; Devices for overturning animals in general; Training or exercising equipment; Covering boxes
    • A01K15/02Training or exercising equipment, e.g. mazes or labyrinths for animals ; Electric shock devices ; Toys specially adapted for animals
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00Measuring for diagnostic purposes; Identification of persons
    • A61B5/103Detecting, measuring or recording devices for testing the shape, pattern, colour, size or movement of the body or parts thereof, for diagnostic purposes
    • A61B5/11Measuring movement of the entire body or parts thereof, e.g. head or hand tremor, mobility of a limb
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L5/00Apparatus for, or methods of, measuring force, work, mechanical power, or torque, specially adapted for specific purposes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/30Piezoelectric or electrostrictive devices with mechanical input and electrical output, e.g. functioning as generators or sensors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • H10N30/85Piezoelectric or electrostrictive active materials
    • H10N30/857Macromolecular compositions
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B71/00Games or sports accessories not covered in groups A63B1/00 - A63B69/00
    • A63B71/06Indicating or scoring devices for games or players, or for other sports activities

Abstract

This sensor system 1000 is provided with: a linear piezoelectric element 101 which is arranged in clothing worn on a body being measured and generates an electric signal in response to applied stress, and which includes polylactic acid as the main component; a signal detection unit 102 which detects an electric signal generated by the linear piezoelectric element 101; and a calculation processing unit 103 which determines the deformation state of the clothing on the basis of the electric signal detected by the signal detection unit 102.

Description

感測系統、衣物及衣物系統Sensing system, clothing and clothing system

本發明係關於判斷被測定體穿著的衣物的變形態樣之感測系統、衣物及衣物系統。The present invention relates to a sensing system, clothing, and a clothing system for judging the deformation of clothing worn by a subject.

藉由被組裝進入衣物的感測系統,檢測穿著該衣物的人或動物等的生體之種種動態的用途近年來逐漸增加。With a sensing system assembled into clothing, the use of detecting various dynamics of the living bodies of people or animals wearing the clothing has gradually increased in recent years.

例如,具備可彈性變形的基材、被固定於此基材的表面及內部之至少一部分的含有導電性高分子與結合劑樹脂的混合物所構成的電阻體、與被導電連接於此電阻體的導電面的端部之1對端子之伸長感測器,此電阻體被組裝入衣物者係屬已知(例如參照專利文獻1)。For example, there is an elastically deformable substrate, a resistor composed of a mixture containing a conductive polymer and a binder resin fixed to at least a part of the surface and inside of the substrate, and a resistor electrically connected to the resistor It is known that a pair of terminal extension sensors at the end of the conductive surface are assembled into clothes by this resistor (for example, refer to Patent Document 1).

例如,一種已知的衣料品,其特徵係具備:被構成穿著在使用者的身體之衣服構件,在第1場所被接續在前述衣服構件之感測器,且由依第1分散密度使導電性粒子材料分散的聚合物材料形成、被構成在穿著中會因應前述使用者的動態而讓前述衣服構件變形之感測器,被構成與電子模組通訊之埠,且在遠離前述第1場所的第2場所被接續在前述衣服構件之埠,與被接續在前述第1衣服構件之導電性導線,且被接續在前述感測器與前述埠之間並於前述感測器與前述埠之間沿著前述衣服構件延伸之導線;前述感測器被構成在承受壓力而變形時電阻會增加(例如,參照專利文獻2)。For example, a known clothing item is characterized by having a clothing member configured to be worn on the body of a user, a sensor connected to the clothing member at the first place, and being electrically conductive according to the first dispersion density The sensor is formed by a polymer material dispersed with a particulate material, and is configured to deform the clothing member in response to the user's dynamics during wearing, is configured as a communication port with the electronic module, and is located away from the first location The second location is connected to the port of the clothing member, and the conductive wire connected to the first clothing member, and is connected between the sensor and the port and between the sensor and the port A wire extending along the clothing member; the sensor is configured to increase resistance when deformed under pressure (for example, refer to Patent Document 2).

例如,一種已知的健身監控系統,其特徵係具備供監視從事身體的活動之被驗者的生理學的參數用之健身監控系統、且具備第1感測器及第2感測器之感測器次系統(sensor subsystem);前述第1感測器,係具備有利用印刷電路基板形成的導電性圓形線圈之多層印刷電路;各層係相互串聯接續;前述第1及第2感測器係可以回應參數的變化;前述感測器次系統被構成生成表示前述參數的訊號且送訊(例如,參照專利文獻3)。 [先前技術文獻] [專利文獻]For example, a known fitness monitoring system is characterized by having a fitness monitoring system for monitoring physiological parameters of a subject engaged in physical activities, and having a sense of a first sensor and a second sensor Sensor subsystem; the aforementioned first sensor is a multilayer printed circuit provided with a conductive circular coil formed by a printed circuit board; each layer is connected in series with each other; the aforementioned first and second sensors It can respond to changes in parameters; the aforementioned sensor sub-system is configured to generate and send signals representing the aforementioned parameters (for example, refer to Patent Document 3). [Prior Technical Literature] [Patent Literature]

[專利文獻1] 日本特開2014-228507號公報   [專利文獻2] 日本特表2016-509635號公報   [專利文獻3] 日本特開2015-62675號公報[Patent Document 1] Japanese Patent Application Publication No. 2014-228507 [Patent Document 2] Japanese Patent Application Publication No. 2016-509635 [Patent Document 3] Japanese Patent Application Publication No. 2015-62675

[發明所欲解決之課題][Problems to be solved by the invention]

在被組裝進入衣物的感測系統,謀求在不損及穿著衣物的生物的穿著舒適而可以正確地檢知生物的動態。此外,衣物,人類穿著之物或動物穿著之物等種類真的很多,而謀求開發出對於任何衣物都可以無差別地、容易組裝進入之感測系統。特別是針對人類穿著的衣物多被要求設計性。再者,伴隨種種的事物透過網際網路進行相互交換資訊之IOT(Internet of Things)技術急速的進展,不限於人類或動物等生物,也得以假設在機器人或玩具等之類的機械,也穿著感測系統被組裝進入的衣物之機會。因而,期待開發出可以不損及穿戴感而正確地檢知生物的動態,尚且,可以容易組裝進入衣物之泛用性高的感測系統、衣物及衣物系統。 [供解決課題之手段]In the sensing system assembled into the clothes, it is possible to accurately detect the dynamics of the creature without impairing the comfort of the creature wearing the clothes. In addition, there are really many types of clothing, things worn by humans or animals, and we are seeking to develop a sensing system that can be easily assembled into any clothing. Especially clothing designed for humans is often required to be designed. Furthermore, with the rapid progress of IOT (Internet of Things) technology that exchanges information with various things through the Internet, it is not limited to living things such as humans or animals, but it can also be assumed that it is also worn on machinery such as robots or toys. The chance of sensing the clothing that the system is assembled into. Therefore, it is expected to develop a highly versatile sensing system, clothes, and clothes system that can accurately detect the dynamics of living things without impairing the sense of wearing, and that can be easily incorporated into clothes. [Means for solving the problem]

本發明人等發現,可以在被穿著在被測定體的衣物配置線狀壓電元件,根據於各線狀壓電元件產生的電性訊號辨別衣物變形之樣態,得出本發明。The present inventors have found that linear piezoelectric elements can be arranged on clothing worn on an object to be measured, and the deformation of the clothing can be identified based on the electrical signals generated by the linear piezoelectric elements, and the present invention can be obtained.

亦即,本發明包含以下的發明。   1.一種感測系統,其特徵為具備:被配置於穿著在被測定體的衣物,因應被施加的應力而產生電性訊號的線狀壓電元件,且係主成分含有聚乳酸之線狀壓電元件,檢測出在前述線狀壓電元件產生的電性訊號之訊號檢測部,與根據前述訊號檢測部檢測出的電性訊號,判斷前述衣物的變形的態樣之演算處理部。   2.如前述1記載之感測系統,其中前述線狀壓電元件,被配置在對應於穿著前述衣物的被測定體的可變部位之前述衣物上的位置附近。   3.如前述1或2記載之感測系統,其中進而具備被配置於配置在前述衣物的前述線狀壓電元件的附近之前述衣物的一部分,藉由與穿著前述衣物的被測定體之間的相互作用產生電性訊號的導電性纖維;前述演算處理部,根據前述訊號檢測部檢測出的電性訊號,與由前述導電性纖維產生的電性訊號,辨別前述衣物的變形的態樣。   4.如前述1~3之任一項記載之感測系統,其中前述線狀壓電元件係利用伸長變形輸出電性訊號。   5.如前述1~4之任一項記載之感測系統,其中前述線狀壓電元件,係具有以導電性纖維形成的芯部、與以包覆前述芯部的方式以穗帶狀的壓電性纖維形成的鞘部之穗帶狀壓電元件。   6.如前述5記載之感測系統,其中前述壓電性纖維,是包含使配向軸區分3軸時之壓電常數d14的絕對值具有數值0.1pC/N以上1000pC/N以下之結晶性高分子為主成分之壓電性高分子;前述壓電性高分子相對於利用該壓電性高分子包覆的前述芯部的中心軸方向之配向角度為15°以上75°以下;前述壓電性高分子,包含含有以壓電常數d14之數值為正的結晶性高分子為主成分的P體,與含有負的結晶性高分子為主成分的N體;針對前述中心軸具有1cm長的部分,在將配向軸朝Z搓捻方向螺旋捲繞配置的該P體的質量設為ZP,將配向軸朝S搓捻方向螺旋捲繞配置的該P體的質量設為SP,將配向軸朝Z搓捻方向螺旋捲繞配置的該N體的質量設為ZN,將配向軸朝S搓捻方向螺旋捲繞配置的該N體的質量設為SN,將(ZP+SN)與(SP+ZN)之中較小者設為T1,較大者設為T2時,T1/T2之數值為0以上0.8以下。   7.一種衣物,其特徵係具備:前述1~6之任一項記載之感測系統。   8.一種衣物系統,其特徵係具備前述1~6之任一項記載之感測系統,前述線狀壓電元件及前述訊號檢測部,被配置於穿著在被測定體的衣物,前述演算處理部,設於與前述衣物不同個體之計算裝置內。 [發明之效果]That is, the present invention includes the following inventions. 1. A sensing system characterized by a linear piezoelectric element which is arranged in clothing worn on a body to be measured and generates an electrical signal in response to applied stress, and is a linear component whose main component contains polylactic acid The piezoelectric element detects the electrical signal generated by the linear piezoelectric element, and the calculation processing portion that determines the deformation of the clothing based on the electrical signal detected by the signal detection section. 2. The sensing system according to item 1, wherein the linear piezoelectric element is disposed near a position on the clothing corresponding to a variable portion of the body to be measured wearing the clothing. 3. The sensing system according to 1 or 2 above, further comprising a part of the clothing disposed near the linear piezoelectric element of the clothing, and between the object to be measured wearing the clothing Conductive fibers that generate electrical signals by the interaction of each other; the calculation processing unit recognizes the deformation of the clothes based on the electrical signals detected by the signal detection unit and the electrical signals generated by the conductive fibers. 4. The sensing system according to any one of the above 1 to 3, wherein the linear piezoelectric element outputs electrical signals by extensional deformation. 5. The sensing system according to any one of 1 to 4 above, wherein the linear piezoelectric element has a core formed of conductive fibers, and a tape-like shape to cover the core A ribbon-shaped piezoelectric element of a sheath portion formed of piezoelectric fibers. 6. The sensing system according to the above 5, wherein the piezoelectric fiber includes an absolute value of the piezoelectric constant d14 when the alignment axis is divided into three axes, and the absolute value of the value is 0.1 pC / N or more and 1000 pC / N or less. A piezoelectric polymer whose main component is a molecule; the alignment angle of the piezoelectric polymer with respect to the central axis direction of the core covered with the piezoelectric polymer is 15 ° or more and 75 ° or less; the piezoelectric Polymer, including P body containing crystalline polymer with a positive piezoelectric constant d14 as the main component, and N body containing negative crystalline polymer as the main component; In part, the mass of the P body spirally wound with the alignment axis in the Z twisting direction is ZP, the mass of the P body spirally wound with the alignment axis in the S twisting direction is SP, and the alignment axis The mass of the N body spirally wound in the Z twisting direction is set to ZN, the mass of the N body spirally wound in the S twisting direction is set to SN, and (ZP + SN) and (SP + ZN) When the smaller one is T1 and the larger one is T2, the value of T1 / T2 is 0 or more and 0.8 or less. 7. A piece of clothing characterized by comprising the sensing system described in any one of 1 to 6 above. 8. A clothing system, characterized by comprising the sensing system described in any one of the above 1 to 6, the linear piezoelectric element and the signal detection unit, which are arranged in clothing worn on the object to be measured, and the calculation processing The unit is located in a computing device of a different individual from the aforementioned clothing. [Effect of invention]

根據本揭示之一態樣,可以不損及穿戴感而正確地檢知生物的動態,尚且,可以實現能容易組裝進入衣物之泛用性高的感測系統、衣物及衣物系統。本態樣之感測系統,不需要特殊的製程且可在簡單的製程製造,生產性佳。According to one aspect of the present disclosure, it is possible to accurately detect the dynamics of living beings without impairing the sense of wearing, and furthermore, it is possible to realize a highly versatile sensing system, clothes, and clothes system that can be easily assembled into clothes. The sensing system of this aspect does not require a special process and can be manufactured in a simple process with good productivity.

此外,由於構成感測系統的感測部分之線狀壓電元件富於柔軟性,所以容易配合衣物的形狀配置。藉由在作成位於人類或動物等之生物及機器人或人型模特兒、人偶、填充玩具之類的玩具等機器這種被測定體的可動部分的附近之衣物的部位配置線狀壓電元件,可以正確地檢知穿著衣物之被測定體的動態。此外,由於線狀壓電元件係富於柔軟性,所以並不妨礙被測定體的動態,而不損及穿著感。由於線狀壓電元件細且富於柔軟性,所以即使將線狀壓電元件組裝進入衣物也不會損害設計性。例如,可以在人類穿著的運動服將本發明之感測系統組裝進入。此外,由於線狀壓電元件不受水氣影響,所以使在與線狀壓電元件一起被組裝進入衣物的線狀壓電元件檢測出產生的電性訊號之訊號檢測部具有防水功能的話,就可以與通常的衣物同樣地清洗。In addition, since the linear piezoelectric element constituting the sensing portion of the sensing system is rich in flexibility, it is easy to arrange according to the shape of the clothes. By arranging linear piezoelectric elements in the vicinity of the movable part of the object to be measured, such as creatures such as humans and animals, robots, human models, dolls, stuffed toys, and other machines , You can accurately detect the dynamics of the subject wearing clothing. In addition, since the linear piezoelectric element is rich in flexibility, it does not hinder the dynamics of the object to be measured without impairing the feeling of wearing. Since the linear piezoelectric element is thin and rich in flexibility, even if the linear piezoelectric element is assembled into clothing, the designability will not be impaired. For example, the sensing system of the present invention can be assembled into sportswear worn by humans. In addition, since the linear piezoelectric element is not affected by moisture, if the signal detection portion that detects the electrical signal generated by the linear piezoelectric element assembled into the clothing together with the linear piezoelectric element has a waterproof function, It can be washed in the same way as normal clothes.

依照本態樣之感測系統,係可以組裝進入被穿著在種種被測定體的衣物。作為可以將依照本態樣的感測系統組裝進入之衣物之例,係有上衣、褲子、護具、手套、緊身衣褲、襪子、日式短布襪、厚毛圍巾、圍脖、圍巾、帽子、髮帶、絲質大手帕、腕套或者面罩等。更具體而言,依照本態樣之感測系統,係可以組裝進入運動服。作為被適用的運動,例如,係有高爾夫球、網球、棒球、足球、英式橄欖球、美式橄欖球、桌球、羽球、板球、門球、田徑賽、體操、舞蹈、游泳(泳裝)、柔道、劍道、空手道等。此外,衣物以外,在床單、毛巾、套子、袋子等雜貨,也可以將依照本態樣之感測系統組裝進入。According to this aspect of the sensing system, it can be assembled into clothing that is worn on various subjects. As an example of clothing that can be incorporated into the sensing system according to this aspect, there are tops, pants, protective gear, gloves, bodysuits, socks, Japanese socks, thick hair scarves, bibs, scarves, hats, Hair bands, silk bandanas, cuffs or face masks. More specifically, the sensing system according to this aspect can be assembled into sportswear. Examples of applicable sports include golf, tennis, baseball, soccer, rugby, American football, billiards, badminton, cricket, gateball, track and field competitions, gymnastics, dance, swimming (swimsuit), judo, and kendo , Karate, etc. In addition to clothing, other groceries such as bed sheets, towels, covers, bags, etc., can also be assembled with the sensing system according to this aspect.

以下,參照圖式、並說明感測系統及衣物。在各圖式,在同樣的構件附上同樣的參照圖號。此外,在不同的圖式被附上相同參照圖號,係意味具有相同功能之構成要素。又,為了容易理解,這些圖示酌情變更比例尺。Hereinafter, the sensing system and the clothes will be described with reference to the drawings. In each drawing, the same reference numeral is attached to the same member. In addition, the same reference figure number is attached to different drawings, which means that the components have the same function. In addition, for ease of understanding, the scale of these figures is changed as appropriate.

(感測器系統之基本構成)   圖1係顯示關於一實施形態之感測系統的基本構成之模式圖。在此,作為感測系統1000被組裝進入的衣物,於圖1顯示上衣500-1及褲子500-2作為一例,但圖1並非意味作為衣物該經常具備上衣500-1及褲子500-2兩者,而到底是個例示而已。作為上衣500-1及褲子500-2以外之衣物,例如,有護具、手套、緊身衣褲、襪子、日式短布襪、厚毛圍巾、圍脖、圍巾、帽子、髮帶、絲質大手帕、腕套或者面罩等。此外,衣物以外,在床單、毛巾、套子、袋子等雜貨,也可以將依照本態樣之感測系統組裝進入。(Basic configuration of sensor system) FIG. 1 is a schematic diagram showing the basic configuration of a sensor system according to an embodiment. Here, as the clothes into which the sensing system 1000 is assembled, FIG. 1 shows the top 500-1 and the pants 500-2 as an example, but FIG. 1 does not mean that the clothes 500-1 and the pants 500-2 are often provided as clothes. In the end, it is just an example. As clothing other than top 500-1 and pants 500-2, for example, there are protective gear, gloves, bodysuits, socks, Japanese socks, thick wool scarf, scarf, scarf, hat, hair band, silk Handkerchiefs, wristbands, masks, etc. In addition to clothing, other groceries such as bed sheets, towels, covers, bags, etc., can also be assembled with the sensing system according to this aspect.

穿著感測系統1000被組裝進入的衣物且利用該感測系統1000將其動態被檢知的對象、於本說明書稱作「被測定體」。作為被測定體之例,有人類及動物等生物,以及機器人及玩具(人偶、填充玩具等)等之類的機械。In this specification, a subject who wears the clothes into which the sensing system 1000 is assembled and uses the sensing system 1000 to be dynamically detected is referred to as a "subject to be measured" in this specification. Examples of the subject include creatures such as humans and animals, and machines such as robots and toys (dolls, stuffed toys, etc.).

感測系統1000,係具備線狀壓電元件101、訊號檢測部102、與演算處理部103。此外,作為選項,感測系統1000,係具備被配置於配置在衣物的線狀壓電元件101的附近,藉由與穿著衣物的被測定體之間的相互作用產生電性訊號的導電性纖維104。The sensing system 1000 includes a linear piezoelectric element 101, a signal detection unit 102, and an arithmetic processing unit 103. In addition, as an option, the sensing system 1000 includes conductive fibers that are disposed near the linear piezoelectric element 101 disposed on the clothing and generate an electrical signal by interacting with the subject wearing the clothing 104.

線狀壓電元件101,係因應被施加的應力產生電性訊號之元件。作為線狀壓電元件101,最好是利用伸長變形產生電性訊號,但也可以採用對於伸長以外的應力產生訊號之線狀壓電元件。以下敘述構成線狀壓電元件101之素材之具體例。當被測定體活動時(也包含應力直接被施加到線狀壓電元件101之場合),在線狀壓電元件101產生因伸長造成的變形。利用該伸長變形,在線狀壓電元件101產生電性訊號。線狀壓電元件101,係配置在被穿著在被測定體的衣物(於圖1所示之例為上衣500-1及褲子500-2)。線狀壓電元件101,雖在衣物上怎樣配置皆可,但其配置大致依存於穿著衣物的被測定體的、欲檢知的動態內容。又,於本說明書,「線狀壓電元件101被配置在衣物上(或單單「衣類」)」之表現,係包含「線狀壓電元件101被配置在衣物質地的表面上或背面上」及「線狀壓電元件101被埋入衣物質地中」之各概念。The linear piezoelectric element 101 is an element that generates an electrical signal in response to applied stress. As the linear piezoelectric element 101, an electrical signal is preferably generated by extensional deformation, but a linear piezoelectric element that generates a signal for stress other than elongation may be used. A specific example of materials constituting the linear piezoelectric element 101 will be described below. When the body to be measured moves (including when the stress is directly applied to the linear piezoelectric element 101), the linear piezoelectric element 101 deforms due to elongation. By this elongation deformation, the linear piezoelectric element 101 generates an electrical signal. The linear piezoelectric element 101 is placed on clothing worn on the body to be measured (in the example shown in FIG. 1, the top 500-1 and the pants 500-2). The linear piezoelectric element 101 may be arranged in any manner on clothing, but its arrangement generally depends on the dynamic content of the subject to be detected wearing the clothing to be detected. In addition, in this specification, the expression "the linear piezoelectric element 101 is arranged on clothing (or just" clothing ")" includes the expression that "the linear piezoelectric element 101 is arranged on the surface or back of the clothing texture And the concepts of "the linear piezoelectric element 101 is buried in the texture of clothing".

作為將線狀壓電元件101配置在衣物上之方法,只要可以藉由在被測定體活動時該被測定體穿著的衣物變形且利用被施加的應力而在線狀壓電元件產生變形則並未特別限定。例如,有往衣物質地的縫入或刺繡、往衣物質地的表面上或背面上中介著接著劑的黏貼、上鎖邊等。此外,還有也可以作成將線狀壓電元件組裝進入的織物或編物,將此定制到衣物。此外,亦可以設計成容易產生變形或將質地部分地薄化或上折線等。任何場合下,線狀壓電元件101的長度都可酌情決定。As a method of arranging the linear piezoelectric element 101 on the clothing, as long as the clothing worn by the measurement subject can be deformed while the measurement subject is in motion and the applied piezoelectric stress deforms the linear piezoelectric element, there is no need Specially limited. For example, there are sewing or embroidering to the texture of the clothing, adhesion to the surface or back surface of the clothing with an adhesive, and locking. In addition, there may be fabrics or knitted fabrics into which linear piezoelectric elements are assembled, which can be customized to clothing. In addition, it can also be designed so as to easily deform or partially thin the texture or fold the line. In any case, the length of the linear piezoelectric element 101 can be determined as appropriate.

例如,在對應於穿著衣物的被測定體的可變部位之衣物上的位置附近,配置線狀壓電元件101。於本說明書,衣物上的位置附近,係意味在被測定體活動時,會根據被測定體的動作而變形之衣物的範圍。以下,於本說明書,為了特定對應於穿著衣物的被測定體的可變部位之衣物上的位置,而有單單使用被測定體的部位之名稱。例如,在「上衣的肘部」係意味「被測定體(人類等)穿著上衣時,會是位置相當於肘部的部分之上衣上的位置」,「手套的手背」係意味「被測定體(人類等)穿戴手套時,會是位置相當於手背的部分之手套上的位置」。衣物上其他位置的名稱也是同樣的。作為被測定體的可變部位之例,係有在人類或動物等生物之、例如肩、肘、手腕、腳踝、膝、髖關節、手指、頭部、口、眼瞼、臉頰、額頭、鼻、耳、腹部、胸部、大腿、小腿、上臂、背部、臀部、手掌、手背、足弓、腳背等。在機器人或玩具等機械之可動部位,也可舉作被測定體的可變部位之例。或者,雖不是在對應於穿著衣物的被測定體的可變部位之衣物上的位置附近(亦即離開可變部位),也是在會伴隨可變部位的活動而使穿著的衣物變形之類的位置,配置線狀壓電元件101。例如,在穿著衣物時,被配置於位置於頭與肩之間、肩與肘之間、肘與手腕之間、手指的各關節之間、頭與胸部之間、胸部與腹部之間、腹部與髖關節之間、髖關節與臀部之間、頭與背部之間、背部與臀部之間、臀部與髖關節之間、髖關節與膝之間,或者,膝與腳踝之間等之衣物上的位置。以下敘述線狀壓電元件101之配置之具體例。由於構成感測系統的感測部分之線狀壓電元件101富於柔軟性,所以容易配合被測定體的形狀設置。For example, the linear piezoelectric element 101 is arranged near the position on the clothing corresponding to the variable portion of the body to be measured wearing the clothing. In this specification, the vicinity of the position on the clothing means the range of clothing that will be deformed according to the movement of the measured body when the measured body moves. Hereinafter, in this specification, in order to specify the position on the clothing corresponding to the variable portion of the object to be measured wearing clothing, the name of the portion of the object to be measured is used alone. For example, in the "elbow of the coat" means "when the subject (human, etc.) wears the top, it will be the position on the upper part of the part that corresponds to the elbow", "back of the hand of the glove" means "the subject (Humans, etc.) When wearing gloves, it is the position on the glove that corresponds to the back of the hand. " The names of other places on the clothes are the same. Examples of the variable parts of the subject include humans and animals, such as shoulders, elbows, wrists, ankles, knees, hip joints, fingers, head, mouth, eyelids, cheeks, forehead, nose, Ear, abdomen, chest, thigh, calf, upper arm, back, buttocks, palm, back of hand, arch of foot, instep, etc. The movable part of a machine such as a robot or a toy can also be cited as an example of a variable part of a body to be measured. Or, although not in the vicinity of the position on the clothing corresponding to the variable part of the subject wearing the clothing (that is, away from the variable part), it is also the case that the clothing worn is deformed with the movement of the variable part Position, the linear piezoelectric element 101 is arranged. For example, when wearing clothing, it is placed between the head and shoulders, between the shoulders and elbows, between the elbows and wrists, between the joints of the fingers, between the head and chest, between the chest and the abdomen, the abdomen Between the hip, hip and hip, head and back, back and hip, hip and hip, hip and knee, or between knee and ankle s position. A specific example of the arrangement of the linear piezoelectric element 101 will be described below. Since the linear piezoelectric element 101 constituting the sensing portion of the sensing system is rich in flexibility, it can be easily arranged in accordance with the shape of the object to be measured.

在此,針對於依照本實施型態之感測系統被使用之、利用伸長產生電性訊號之線性壓電元件101之電性的特性,參照圖2及圖3加以說明。圖2係於本實施形態採用之線狀壓電元件的變形速度之說明圖。於本實施形態,作為線狀壓電元件101,使用不論其長度或伸長發生的位置,因伸長的變形速度都是固定者。如圖2所示,準備長短2根於本實施形態被使用之線狀壓電元件101,針對各個,以夾頭抓持固定距離,中介著連接器121接續到訊號檢測部102,進行施加被測定體在線方向伸長並測定這時產生的訊號強度(電流值)之實驗。圖3係顯示依照圖2所示之線狀壓電元件的伸長所形成之變形與訊號強度之關係圖,圖3(A)係顯示變形速度與訊號強度(電流值)之關係,圖3(B)係顯示變形部分的位置與訊號強度(電流值)之關係。於本實施形態被使用之線狀壓電元件101,如圖3(A)所示線狀壓電元件101的伸長變形速度與訊號強度(電流值)係成正比,如圖3(B)所示不論伸長變形發生的位置(以自連接器21起的距離來表示)而訊號強度(電流值)大致固定。如此,於本實施形態,作為線狀壓電元件101,最好是使用不論其長度或伸長發生的位置,訊號強度對伸長導致的變形速度都是固定者。又,將線狀壓電元件101、以訊號強度對於因伸長的變形速度並非固定者來實現亦可,該場合,係將預先測定針對該線狀壓電元件的伸長所對應的變形速度與訊號強度之關係,且根據該測定結果將各位置的伸長程度所對應之變形速度換算成固定之訊號強度並輸出之事前補正演算部、設置在演算處理部103的前段即可。Here, the electrical characteristics of the linear piezoelectric element 101 used to generate an electrical signal by elongation used in the sensing system according to this embodiment will be described with reference to FIGS. 2 and 3. FIG. 2 is an explanatory diagram of the deformation speed of the linear piezoelectric element used in this embodiment. In the present embodiment, as the linear piezoelectric element 101, regardless of its length or the position where the extension occurs, the deformation rate due to the extension is fixed. As shown in FIG. 2, two linear piezoelectric elements 101 used in this embodiment are prepared. For each, a fixed distance is gripped by a chuck, and the signal detection unit 102 is connected via a connector 121 to be applied. An experiment for measuring the extension of the body in the line direction and measuring the signal strength (current value) generated at this time. FIG. 3 is a graph showing the relationship between the deformation and signal strength formed by the extension of the linear piezoelectric element shown in FIG. 2, and FIG. 3 (A) is a graph showing the relationship between the deformation speed and the signal strength (current value). B) shows the relationship between the position of the deformed part and the signal strength (current value). In the linear piezoelectric element 101 used in this embodiment, as shown in FIG. 3 (A), the elongation deformation speed of the linear piezoelectric element 101 is proportional to the signal strength (current value), as shown in FIG. 3 (B). It shows that the signal strength (current value) is almost fixed regardless of the position where the extensional deformation occurs (indicated by the distance from the connector 21). In this way, in the present embodiment, it is preferable to use the linear piezoelectric element 101 regardless of its length or the location where elongation occurs, and the signal strength and the deformation rate due to elongation are all fixed. In addition, the linear piezoelectric element 101 may be implemented with a signal strength for those whose deformation rate due to elongation is not fixed. In this case, the deformation rate and signal corresponding to the elongation of the linear piezoelectric element will be measured in advance According to the measurement results, the deformation speed corresponding to the elongation of each position is converted into a fixed signal strength and output beforehand, and the pre-correction calculation unit may be provided at the front stage of the calculation processing unit 103.

回到圖1之說明,訊號檢測部102係檢測於各線狀壓電元件101產生之電性訊號。於圖1,為了簡明化說明,將訊號檢測部102記載在遠離上衣500-1及褲子500-2之位置,但最好是在每件衣物(於圖1所示之例,在每件上衣500-1及褲子500-2)、在該衣物上的任意位置設置。線狀壓電元件101與訊號檢測部102可以是直接地接續,亦可中介著放大訊號強度的放大器或過濾器等(未圖示)而接續。又,作為線狀壓電元件101,如以後述之方式使用具有電磁波屏蔽的穗帶狀壓電元件,則可以省略供去除雜訊用之濾波器。如作為訊號檢測部102使用具有防水功能者,則線狀壓電元件101及訊號檢測部102被組裝進入的衣物是可以清洗的。Returning to the description of FIG. 1, the signal detection unit 102 detects the electrical signals generated by the linear piezoelectric elements 101. In FIG. 1, in order to simplify the description, the signal detection unit 102 is described at a position away from the top 500-1 and the pants 500-2, but preferably on each piece of clothing (in the example shown in FIG. 1, on each top 500-1 and pants 500-2), set anywhere on the clothing. The linear piezoelectric element 101 and the signal detection unit 102 may be directly connected, or may be connected via an amplifier or a filter (not shown) that amplifies the signal strength. In addition, as the linear piezoelectric element 101, a spike-shaped piezoelectric element having electromagnetic wave shielding is used as described later, and a filter for removing noise can be omitted. If a waterproof function is used as the signal detection unit 102, the clothes into which the linear piezoelectric element 101 and the signal detection unit 102 are assembled can be washed.

訊號檢測部102,係包含:接續從線狀壓電元件101被拉出的導線之連接器(未圖示)、將於線狀壓電元件101產生的類比電性訊號轉換成數位電性訊號之AD轉換部(未圖示)、與將從AD轉換部被輸出的數位電性訊號往次階段的演算處理部103送訊之送訊部(未圖示)。訊號檢測部102(之送訊部)與演算處理部103之間之通訊可以是無線亦或有線。將訊號檢測部102與演算處理部103之間利用無線通訊實現之場合,訊號檢測部102之送訊部,係在從AD轉換部被輸出之數位電性訊號、附加對應之線狀壓電元件101的識別資訊後,往演算處理部103無線送訊。無線送訊之方法本身並不以本發明為限,採用公知的方法即可。將訊號檢測部102與演算處理部103之間利用有線通訊實現之場合,係將每一根對應的線狀壓電元件101之訊號線、接續到演算處理部103的各輸入端子。The signal detection unit 102 includes a connector (not shown) that connects a wire pulled from the linear piezoelectric element 101, and converts the analog electrical signal generated by the linear piezoelectric element 101 into a digital electrical signal The AD conversion unit (not shown) and the transmission unit (not shown) that transmits the digital electrical signal output from the AD conversion unit to the calculation processing unit 103 of the next stage. The communication between the signal detection part 102 (the sending part) and the calculation processing part 103 may be wireless or wired. When the signal detection unit 102 and the calculation processing unit 103 are realized by wireless communication, the transmission unit of the signal detection unit 102 is a digital electrical signal output from the AD conversion unit and a corresponding linear piezoelectric element is added After the identification information of 101, it sends a wireless message to the calculation processing section 103. The wireless transmission method itself is not limited to the present invention, and a well-known method may be used. When the signal detection unit 102 and the calculation processing unit 103 are implemented by wired communication, the signal line of each corresponding linear piezoelectric element 101 is connected to each input terminal of the calculation processing unit 103.

訊號檢測部102,係作為在各線狀壓電元件產生的電性訊號的大小,檢測出例如電流值或電壓值等。此外,例如,作為在各線狀壓電元件產生的電性訊號的大小,替代電流值或電壓值等之類的訊號強度本身,也可以使用該等數值的微分值或其他演算值。例如若是微分值,則可以精確度良好地取得急遽的電性訊號變動,抑或如果是積分值則可以基於變形大小來解析。The signal detection unit 102 detects, for example, the current value or the voltage value as the magnitude of the electrical signal generated in each linear piezoelectric element. In addition, for example, as the magnitude of the electrical signal generated in each linear piezoelectric element, instead of the signal strength itself such as a current value or a voltage value, a differential value or other calculation value of these values may be used. For example, if it is a differential value, a sharp electrical signal change can be obtained with good accuracy, or if it is an integrated value, it can be analyzed based on the magnitude of the deformation.

演算處理部103,係基於訊號檢測部102檢測出的電性訊號,辨別衣物501-1及500-2之變形樣態。當藉由穿著衣物的被測定體活動使衣物變形時在線狀壓電元件101會產生電性訊號,藉由利用演算處理部103解析該電性訊號來辨別衣物的變形樣態,而查明穿著該衣物的被測定體的活動內容。The calculation processing unit 103 recognizes the deformation of the clothes 501-1 and 500-2 based on the electrical signal detected by the signal detection unit 102. The linear piezoelectric element 101 generates an electrical signal when the clothing is deformed by the movement of the body to be measured wearing clothing, and by analyzing the electrical signal using the calculation processing section 103 to identify the deformation of the clothing, the wear is identified Activity content of the subject of the clothing.

演算處理部103,例如,在離開衣物的電腦等計算裝置被實現。該場合,線狀壓電元件101及訊號檢測部102係配置在被穿著在被測定體的衣物,演算處理部103係設置在與該衣物不同個體的計算裝置內,但訊號檢測部102與演算處理部103之間最好是利用無線通訊被接續。此外或者,演算處理部103,例如,在配置於衣物上的任意位置之積體電路(IC)晶片被實現。該場合,線狀壓電元件101、訊號檢測部102及演算處理部103,係配置在被穿著於被測定體的衣物,而訊號檢測部102及演算處理部103之間是可以無線通訊亦或有線通訊,此外,為了將感測系統1000被組裝進入的衣物作成可以清洗,針對演算處理部103也最好具有防水功能。The calculation processing unit 103 is realized, for example, in a computing device such as a computer leaving clothes. In this case, the linear piezoelectric element 101 and the signal detection unit 102 are arranged in clothing worn on the body to be measured, and the calculation processing unit 103 is provided in a computing device different from the clothing, but the signal detection unit 102 and the calculation The processing units 103 are preferably connected by wireless communication. In addition, or alternatively, the calculation processing unit 103 is realized, for example, in an integrated circuit (IC) wafer arranged at an arbitrary position on the clothing. In this case, the linear piezoelectric element 101, the signal detection unit 102, and the calculation processing unit 103 are arranged in clothing worn on the subject, and the signal detection unit 102 and the calculation processing unit 103 can communicate wirelessly or For wired communication, in addition, in order to make the clothes into which the sensing system 1000 is assembled to be washable, it is preferable that the arithmetic processing unit 103 also has a waterproof function.

利用演算處理部103作成的衣物變形樣態之辨別結果,係可以利用於種種的用途。以下,列舉數個具體例。The discrimination result of the deformation pattern of the clothes created by the calculation processing unit 103 can be used for various purposes. Several specific examples are listed below.

例如,在演算處理部103,藉由接續個人電腦、移動終端、或者觸控面板等之顯示裝置(未圖示),當然可將被測定體的活動內容僅以數值或圖表表示,亦可用電腦繪圖或動畫顯示在顯示裝置。例如,高爾夫球員或網球球員如穿著感測系統1000被組裝進入的運動服,則可以將自身的打球內容在顯示裝置確認。例如,能實現以使業餘與專家之各球員穿著感測系統1000被組裝進入的運動服,可以比較每個打球內容之方式於顯示裝置顯示這樣的練習態樣。特別是,在複數部位設置感測器之場合,可以顯示基於非測定體的活動順序或定時之解析結果。例如,也可以作成將穿著感測系統1000被組裝進入的衣物之演員表演的演技、轉換成電腦繪圖或動畫之動態擷取裝置來利用。For example, in the calculation processing unit 103, by connecting a display device (not shown) such as a personal computer, a mobile terminal, or a touch panel, of course, the activity content of the object to be measured can be represented only by numerical values or graphs, or a computer Drawings or animations are displayed on the display device. For example, if a golfer or a tennis player wears a sportswear into which the sensing system 1000 is assembled, he can confirm his playing content on the display device. For example, it can be realized that each player of the amateur and the expert wears the sportswear in which the sensing system 1000 is assembled, and such a practice form can be displayed on the display device in a manner of comparing the contents of each game. In particular, when a sensor is provided at a plurality of locations, the analysis result based on the movement sequence or timing of the non-measured body can be displayed. For example, it can also be used as a dynamic capture device that converts acting performed by actors wearing clothing into which the sensing system 1000 is assembled into computer graphics or animation.

例如,如果將轉換被輸入的電性訊號成振動之振動產生裝置(未圖示)或使微小的電擊產生之電性產生裝置(未圖示)、進而組裝進入感測系統1000被組裝進入的衣物,且在該等振動產生裝置或電性產生裝置接續演算處理部103,則可以將被測定體的活動內容、對於穿著衣物的人類或動物以振動或電擊之形式反饋。例如,高爾夫球員或網球球員如穿著感測系統1000及振動產生裝置或電性產生裝置被組裝進入的運動服,則可以將自身的打球內容以振動或電擊之形式感知。例如,可以使專業球員穿著該運動服,將利用演算處理部103得到的辨別結果預先保持在記憶裝置,其次,使業餘球員穿著該運動服,打球內容與專業球員不同之場合,實現以振動或電擊反饋給穿著運動服的業餘球員這樣的練習態樣。例如,將感測系統1000及振動產生裝置或電性產生裝置被組裝進入之衣物、使寵物或家畜穿著,以振動或電擊進行訓練這樣的用途亦可。For example, if a vibration generating device (not shown) that converts an input electrical signal into vibration or an electrical generating device (not shown) that generates a tiny electric shock, and then assembled into the sensing system 1000 is assembled into Clothing, and the vibration generation device or the electrical generation device connected to the calculation processing unit 103 can feed back the activity content of the subject and the human or animal wearing the clothing in the form of vibration or electric shock. For example, if a golfer or a tennis player wears a sportswear into which the sensing system 1000 and the vibration generating device or the electrical generating device are assembled, they can perceive their playing contents in the form of vibration or electric shock. For example, a professional player may wear the sportswear, and the discrimination result obtained by the calculation processing unit 103 may be kept in a memory device in advance. Secondly, an amateur player may wear the sportswear and the playing content is different from that of the professional player. The electric shock feedback was given to amateur players wearing sportswear. For example, the clothes into which the sensing system 1000 and the vibration generating device or the electrical generating device are assembled, wearing pets or domestic animals, and training with vibration or electric shock may also be used.

例如,可以實現在演算處理部103,藉由接續發出喇叭、蜂音器、鐘(chime)等之類的聲音之音響機器,而因應被測定體的活動而發出警報音這樣的安全系統。例如,可以實現這樣的安全系統,使建設作業員或工廠勞動者穿著感測系統1000被組裝進入之衣物,在利用演算處理部103得到的識別結果顯示預先登錄之危險動作之場合,發出警報音。例如,可以實現這樣的安全系統,使汽車駕駛或鐵路駕駛穿著感測系統1000被組裝進入之衣物,在顯示利用演算處理部103得到的識別結果顯示打瞌睡特有的動作之場合,發出警報音。For example, the calculation processing unit 103 may implement a safety system such as an alarm sound in response to the movement of the body to be measured by an audio device that continuously emits sounds such as a horn, a buzzer, and a chime. For example, it is possible to realize a safety system that allows construction workers or factory workers to wear clothes into which the sensing system 1000 is assembled, and when the recognition result obtained by the calculation processing unit 103 shows a dangerous action registered in advance, an alarm sound . For example, it is possible to realize a safety system that causes a car driver or a railroad driver to wear clothes that the sensor system 1000 is assembled into, and displays an alarm sound when the recognition result obtained by the calculation processing unit 103 shows a unique action for dozing.

此外,例如,可以也實現提供這樣的玩具,使人偶、填充玩具等穿著感測系統1000被組裝進入之衣物,發出因應利用演算處理部103得到的識別結果之聲音。In addition, for example, it is also possible to provide such a toy that makes clothes such as dolls, stuffed toys, etc. that are assembled in the wear-sensing system 1000 utter a sound in response to the recognition result obtained by the arithmetic processing unit 103.

例如,也可以藉由在演算處理部103接續機器人控制裝置而使用感測系統1000作為對機器人的介面。例如,也可以在演算處理部103接續機器人控制裝置,使穿著感測系統1000被組裝進入的衣物之人類的動作再現於機器人。如該機器人為玩具,就成為再現人類動作的機器人玩具。或者,也可以使感測系統1000被組裝進入的衣物穿著在機器人,使該機器人的動作再現於別的機器人。如該機器人為產業用機器人,則可以減低對產業用機器人之教示作業負擔。For example, the sensor system 1000 may be used as an interface to the robot by connecting the robot control device to the calculation processing unit 103. For example, the calculation processing unit 103 may be connected to the robot control device to reproduce the actions of the human wearing the clothes into which the sensing system 1000 is assembled into the robot. If the robot is a toy, it becomes a robot toy that reproduces human movements. Alternatively, the clothes into which the sensing system 1000 is assembled can be worn on the robot, and the movement of the robot can be reproduced on another robot. If the robot is an industrial robot, the teaching burden on the industrial robot can be reduced.

回到圖1之說明,作為選項而被設置之導電性纖維104,係配置在被配置於衣物(於圖1所示之例為上衣500-1及褲子500-2)的線狀壓電元件101的附近之前述衣物的部分。導電性纖維104,最好是配置在對應於該導電性纖維104的線狀壓電元件101的附近。導電性纖維104,雖是該導電性纖維104與所對應的線狀壓電元件101組合起來設置,但沒有必要對全部的線狀壓電元件101設置導電性纖維104。導電性纖維104,係利用與穿著衣物的被測定體之間之相互作用產生電性訊號。利用被測定體、導電性纖維104、與位置於被測定體及導電性纖維104之間的衣物及空氣等之介電體形成電容器。亦即,當藉由穿著衣物的被測定體活動使衣物變形時,設置在該衣物的導電性纖維104與被測定體之間之距離會改變,因而改變導電性纖維104與被測定體之間之靜電電容。利用這靜電電容的變化而在導電性纖維104產生微弱的電性訊號。導電性纖維104與訊號檢測部102係電性地接續著,於導電性纖維104產生的微弱的電性訊號,係利用作為電極功能的訊號檢測部102被檢測出。導電性纖維104產生電性訊號之機制,係與靜電電容型感測器同樣。訊號檢測部102,係包含:接續從導電性纖維104被拉出的導線之連接器(未圖示)、將於導電性纖維104產生的類比電性訊號轉換成數位電性訊號之AD轉換部(未圖示)、與將從AD轉換部被輸出的數位電性訊號往次階段的演算處理部103送訊之送訊部(未圖示)。此外,因為於導電性纖維104產生之電性訊號微弱,所以訊號檢測部102係具有將之放大的放大器(未圖示)。放大器,可以是類比放大器亦或數位放大器,但由類比放大器構成之場合係設在AD轉換部的前段,而由數位放大器構成之場合則設在AD轉換部的後段。將導電性纖維104與線狀壓電元件101組合設置之場合,演算處理部103,基於訊號檢測部102檢測出的於線狀壓電元件101產生的電性訊號與由導電性纖維104產生之電性訊號,可以更正確地辨別衣物的變形樣態。亦即,當藉由穿著衣物的被測定體活動使衣物變形時,在線狀壓電元件101及導電性纖維104雙方會產生電性訊號,而藉由利用演算處理部103解析電性訊號來辨別衣物的變形樣態,知道穿著該衣物的被測定體的活動。線狀壓電元件101係檢知因被測定體活動使衣物變形,但並非檢知衣物的變形狀態。例如,線狀壓電元件101係檢知被測定體的關節是彎曲或伸展,但並沒有檢知到被測定體的關節變形程度。於是,在感測系統1000,基於從導電性纖維104被輸出的電性訊號,檢知導電性纖維104與被測定體之間之靜電電容,並檢知被測定體的關節變形程度。由前述之觀點而言,導電性纖維104,最好是配置在線狀壓電元件101被配置之衣物的部分變形時,與該衣物的部分一起變形之衣物的部分。於本說明書,導電性纖維104配置在對應於該導電性纖維104的線狀壓電元件101的附近,係意味導電性纖維104配置在線狀壓電元件101被配置之衣物的部分變形時,與該衣物的部分一起變形之衣物的部分。此外,在複數線狀壓電元件被配置於衣物之場合,導電性纖維104,最好是配置在比其他線狀壓電元件、更靠近對應於該導電性纖維104的線狀壓電元件101的位置。例如,導電性纖維104,最好是被配置在對於所對應的線狀壓電元件101、30mm~100mm之範圍。Returning to the description of FIG. 1, the conductive fiber 104 provided as an option is arranged in a linear piezoelectric element disposed on clothing (in the example shown in FIG. 1 is a top 500-1 and a trouser 500-2) The portion of the aforementioned clothing in the vicinity of 101. The conductive fiber 104 is preferably arranged in the vicinity of the linear piezoelectric element 101 corresponding to the conductive fiber 104. Although the conductive fiber 104 is provided in combination with the corresponding linear piezoelectric element 101, it is not necessary to provide the conductive fiber 104 for all the linear piezoelectric elements 101. The conductive fiber 104 uses the interaction with the subject to be dressed to generate electrical signals. The capacitor is formed by the object to be measured, the conductive fiber 104, and a dielectric body such as clothing and air positioned between the object to be measured and the conductive fiber 104. That is, when the clothing is deformed by the movement of the body to be measured wearing clothing, the distance between the conductive fiber 104 provided in the clothing and the body to be measured changes, thus changing between the conductive fiber 104 and the body to be measured Of electrostatic capacitance. This change in electrostatic capacitance generates a weak electrical signal in the conductive fiber 104. The conductive fiber 104 and the signal detection unit 102 are electrically connected, and the weak electrical signal generated by the conductive fiber 104 is detected by the signal detection unit 102 functioning as an electrode. The mechanism by which the conductive fiber 104 generates electrical signals is the same as the electrostatic capacitance type sensor. The signal detection unit 102 includes: a connector (not shown) that connects a wire drawn from the conductive fiber 104, and an AD conversion unit that converts the analog electrical signal generated by the conductive fiber 104 into a digital electrical signal (Not shown), and a transmission unit (not shown) that transmits the digital electrical signal output from the AD conversion unit to the calculation processing unit 103 of the next stage. In addition, since the electrical signal generated by the conductive fiber 104 is weak, the signal detection unit 102 has an amplifier (not shown) that amplifies it. The amplifier may be an analog amplifier or a digital amplifier, but when it is constituted by an analog amplifier, it is provided in the front stage of the AD conversion unit, and when it is constituted by a digital amplifier, it is provided in the rear stage of the AD conversion unit. When the conductive fiber 104 and the linear piezoelectric element 101 are provided in combination, the calculation processing section 103 is based on the electrical signal generated by the linear piezoelectric element 101 detected by the signal detection section 102 and the electrical signal generated by the conductive fiber 104 Electrical signals can more accurately identify the deformation of clothing. That is, when the clothing is deformed by the movement of the body to be measured wearing clothing, both the linear piezoelectric element 101 and the conductive fiber 104 generate electrical signals, which are identified by analyzing the electrical signals by the calculation processing section 103 The deformed appearance of the clothing knows the activity of the subject wearing the clothing. The linear piezoelectric element 101 detects that the clothes are deformed due to the movement of the subject, but it does not detect the deformed state of the clothes. For example, the linear piezoelectric element 101 detects that the joint of the subject is bent or stretched, but does not detect the degree of deformation of the joint of the subject. Therefore, in the sensing system 1000, based on the electrical signal output from the conductive fiber 104, the electrostatic capacitance between the conductive fiber 104 and the subject is detected, and the degree of joint deformation of the subject is detected. From the foregoing point of view, it is preferable that the conductive fiber 104 is a portion of the clothing that is deformed together with the portion of the clothing when the portion of the clothing where the linear piezoelectric element 101 is disposed is deformed. In this specification, the conductive fiber 104 is arranged in the vicinity of the linear piezoelectric element 101 corresponding to the conductive fiber 104, which means that when the conductive fiber 104 is deformed in the part of the clothing on which the linear piezoelectric element 101 is arranged, the The part of the garment that deforms together. In addition, when a plurality of linear piezoelectric elements are arranged on clothing, the conductive fiber 104 is preferably arranged closer to the linear piezoelectric element 101 corresponding to the conductive fiber 104 than other linear piezoelectric elements s position. For example, the conductive fiber 104 is preferably arranged in the range of 30 mm to 100 mm for the corresponding linear piezoelectric element 101.

接著,例示線狀壓電元件101之配置例。Next, an example of the arrangement of the linear piezoelectric element 101 will be described.

圖4係顯示將依照一實施形態的感測系統組裝進入之上衣及褲子的前面(正面)之模式圖,圖5係顯示圖4的上衣及褲子的背面之模式圖。例如,線狀壓電元件101,係如圖4所示設置在位置於人類的髖關節附近及膝附近之褲子500-2上的前面,如圖5所示設置在位置於人類的肩附近及肘附近之上衣500-1上的背面,如圖5所示設置在位置於人類的臀部附近之褲子500-2上的前面。例如,導電性纖維104,係如圖5所示設置在被設在位置於人類的肩附近及肘附近之上衣500-1上的背面之線狀壓電元件101附近。圖6係圖示將依照一實施形態的感測系統組裝進入之上衣的背面之實際照片,對應於圖5模式地顯示之線狀壓電元件101及導電性纖維104之配置。FIG. 4 is a schematic diagram showing the assembly of the sensing system according to an embodiment into the front (front) of the top and pants, and FIG. 5 is a schematic diagram showing the back of the top and pants of FIG. 4. For example, the linear piezoelectric element 101 is arranged in front of the trousers 500-2 located near the hip joints and knees of the human as shown in FIG. 4, and is located near the shoulders of the human as shown in FIG. 5 The back of the top 500-1 near the elbow is placed on the front of the pants 500-2 located near the human hips as shown in FIG. For example, as shown in FIG. 5, the conductive fiber 104 is provided near the linear piezoelectric element 101 provided on the back of the top 500-1 positioned near the shoulder and the elbow of a human. FIG. 6 is an actual photograph of the sensor system according to an embodiment assembled into the back of the top, corresponding to the arrangement of the linear piezoelectric element 101 and the conductive fiber 104 schematically shown in FIG. 5.

接著,在本實施形態,針對穿著感測系統被組裝進入的衣物之人類實際活動之場合之實驗結果,參照圖7~圖11並加以說明。又,在圖8~圖11被顯示之實驗結果,電性訊號的正負極性的取法為一例,依接地(0電位)的設定情況而改變對於熟悉該項技藝者(業者)係周知之事項。Next, in this embodiment, the experimental results of the case where the human wearing the clothes into which the sensing system is assembled are actually moving will be described with reference to FIGS. 7 to 11. In addition, in the experimental results shown in FIGS. 8 to 11, the method of taking the positive and negative polarities of the electrical signal is an example, and it is a matter that is well known to those skilled in the art (industry) according to the setting of the ground (0 potential).

圖7係圖示在上衣的肩及肘的附近配置線狀壓電元件之實際照片。如圖7所示,將線狀壓電元件101分別設在上衣500-1的肘、前臂部、及上臂部。FIG. 7 is a photograph showing the actual arrangement of linear piezoelectric elements near the shoulders and elbows of the jacket. As shown in FIG. 7, the linear piezoelectric elements 101 are provided on the elbow, forearm, and upper arm of the jacket 500-1, respectively.

圖8係圖示在穿著圖7所示之上衣後彎曲肘之場合所產生之電性訊號,圖8(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,圖8(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。圖9係圖示在從穿著圖7所示之上衣後彎曲肘之狀態(圖8)回復到原來之場合所產生之電性訊號,圖9(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,圖9(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。Fig. 8 illustrates the electrical signal generated when the elbow is bent after wearing the top shown in Fig. 7, and Fig. 8 (A) shows the electrical property generated by the linear piezoelectric element provided on the elbow of the top The signal, FIG. 8 (B) shows the electrical signal generated by the linear piezoelectric elements provided on the forearm and upper arm of the jacket. Fig. 9 illustrates the electrical signal generated when the elbow is bent after wearing the top shown in Fig. 7 (Fig. 8) and returned to the original occasion. Fig. 9 (A) shows the elbow provided in the top The electrical signal generated by the linear piezoelectric element, FIG. 9 (B) shows the electrical signal generated by the linear piezoelectric element provided on the forearm and upper arm of the jacket.

由圖8(A)與圖9(A)之比較可知,針對於設在上衣500-1的肘之線狀壓電元件101產生的電性訊號,肘彎曲時與將肘從彎曲狀態回復到原來時出現電性訊號的變化。亦即,將肘彎曲時,設在上衣500-1的肘之線狀壓電元件101,產生負極性的電性訊號(參照圖8(A))。另一方面,將肘從彎曲的狀態回復到原來時,設在上衣500-1的肘之線狀壓電元件101,產生正極性的電性訊號(參照圖9(A))。如此,針對於設在上衣500-1的肘之線狀壓電元件101產生的電性訊號,於肘彎曲與回復之前後電性訊號的極性會反轉。From the comparison between FIG. 8 (A) and FIG. 9 (A), it can be seen that for the electrical signal generated by the linear piezoelectric element 101 provided on the elbow of the jacket 500-1, the elbow is bent and the elbow is restored from the bent state to There was a change in electrical signals. That is, when the elbow is bent, the linear piezoelectric element 101 provided on the elbow of the jacket 500-1 generates a negative electrical signal (see FIG. 8 (A)). On the other hand, when the elbow is restored from the bent state, the linear piezoelectric element 101 provided on the elbow of the jacket 500-1 generates a positive electrical signal (see FIG. 9 (A)). In this way, for the electrical signal generated by the linear piezoelectric element 101 provided at the elbow of the jacket 500-1, the polarity of the electrical signal is reversed before and after the elbow is bent and restored.

此外,由圖8(B)與圖9(B)之比較可知,針對於設在上衣500-1的上臂部之線狀壓電元件101產生的電性訊號,肘彎曲時與將肘從彎曲狀態回復到原來時出現電性訊號的變化。亦即,將肘彎曲時,設在上衣500-1的上臂部之線狀壓電元件101,產生正極性的電性訊號(參照圖8(B))。一方面,將肘從彎曲的狀態回復到原來時,設在上衣500-1的上臂部之線狀壓電元件101,產生負極性的電性訊號(參照圖9(B))。如此,針對於設在上衣500-1的上臂部之線狀壓電元件101產生的電性訊號,於肘彎曲與回復之前後電性訊號的極性會反轉。In addition, as can be seen from the comparison between FIG. 8 (B) and FIG. 9 (B), for the electrical signal generated by the linear piezoelectric element 101 provided on the upper arm of the jacket 500-1, the elbow is bent and the elbow is bent from The electrical signal changes when the status returns to the original. That is, when the elbow is bent, the linear piezoelectric element 101 provided on the upper arm portion of the jacket 500-1 generates a positive electrical signal (see FIG. 8 (B)). On the one hand, when the elbow is restored from the bent state, the linear piezoelectric element 101 provided on the upper arm of the jacket 500-1 generates a negative electrical signal (see FIG. 9 (B)). In this way, for the electrical signal generated by the linear piezoelectric element 101 provided on the upper arm of the jacket 500-1, the polarity of the electrical signal is reversed before and after the elbow is bent and restored.

另一方面,由圖8(B)與圖9(B)之比較可知,針對於設在上衣500-1的前臂部之線狀壓電元件101產生的電性訊號,肘彎曲時與將肘從彎曲狀態回復到原來時出現電性訊號的變化,但特徵是其變化的程度小且不明確。On the other hand, as can be seen from the comparison between FIG. 8 (B) and FIG. 9 (B), for the electrical signal generated by the linear piezoelectric element 101 provided on the forearm of the top 500-1, the elbow is bent and the elbow is bent. When returning from the bent state to the original, the electrical signal changes, but the characteristic is that the degree of change is small and unclear.

因而可知,有關肘彎曲與回復(伸長),係能依據是否「於設在上衣500-1的肘及/或上臂部的線狀壓電元件101產生的電性訊號的極性上有明確的反轉、還是於設在前臂部的線狀壓電元件101產生的電性訊號的極性的反轉不明確」而予以辨別。例如,演算處理部103,係觀測設在上衣500-1的肘、前臂部、及上臂部的各線狀壓電元件101產生的電性訊號的極性,設在上衣500-1的肘及/或上臂部的線狀壓電元件101產生的電性訊號的極性上有前述之類的明確的反轉,還是於設在上衣500-1的前臂部的線狀壓電元件101產生的電性訊號的極性的反轉不明確之場合,進行辨別「肘被彎曲」或者「肘的彎曲被回復到原來」。Therefore, it can be seen that the elbow flexion and recovery (elongation) can be clearly determined by whether there is a “polarity in the polarity of the electrical signal generated by the linear piezoelectric element 101 provided on the elbow and / or upper arm of the jacket 500-1. It is unclear whether the rotation or the inversion of the polarity of the electrical signal generated by the linear piezoelectric element 101 provided in the forearm is determined ". For example, the calculation processing unit 103 observes the polarities of the electrical signals generated by the linear piezoelectric elements 101 provided on the elbow, forearm, and upper arm of the jacket 500-1, and the elbow and / or the jacket 500-1. The polarity of the electrical signal generated by the linear piezoelectric element 101 in the upper arm portion is clearly reversed as described above, or is the electrical signal generated by the linear piezoelectric element 101 provided in the forearm portion of the jacket 500-1 When the polarity inversion is not clear, distinguish between "elbow is bent" or "elbow bending is restored to the original."

圖10係圖示在穿著圖7所示之上衣後扭轉肘之場合所產生之電性訊號,圖10(A)係顯示於設在上衣的肘之線狀壓電元件所產生之電性訊號,圖10(B)係顯示於設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。圖11係圖示在從穿著圖7所示之上衣後扭轉肘之狀態(圖10)回復到原來之場合所產生之電性訊號,圖11(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,圖11(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。Fig. 10 is a diagram illustrating electrical signals generated when the elbow is twisted after wearing the top shown in Fig. 7, and Fig. 10 (A) is a diagram showing electrical signals generated by a linear piezoelectric element provided on the elbow of the top 10 (B) shows the electrical signals generated by the linear piezoelectric elements provided on the forearm and upper arm of the jacket. Fig. 11 shows the electrical signal generated when the elbow is twisted after wearing the top shown in Fig. 7 (Fig. 10) to return to the original situation, and Fig. 11 (A) is shown on the elbow provided in the top The electrical signal generated by the linear piezoelectric element is shown in FIG. 11 (B) on the electrical signal generated by the linear piezoelectric element provided on the forearm and upper arm of the jacket.

由圖10(A)與圖11(A)之比較可知,針對於設在上衣500-1的肘之線狀壓電元件101產生的電性訊號,扭轉肘時與將肘的扭轉回復到原來時出現電性訊號的變化,但其變化的程度小且不明確。From the comparison between FIG. 10 (A) and FIG. 11 (A), it can be seen that for the electrical signal generated by the linear piezoelectric element 101 provided on the elbow of the jacket 500-1, when the elbow is twisted, the torsion of the elbow is restored to the original There is a change in electrical signals, but the degree of change is small and unclear.

此外,由圖10(B)與圖11(B)之比較可知,針對於設在上衣500-1的上臂部之線狀壓電元件101產生的電性訊號,扭轉肘時與將肘的扭轉回復到原來時出現電性訊號的變化,但其變化的程度小且不明確。In addition, as can be seen from the comparison between FIG. 10 (B) and FIG. 11 (B), for the electrical signal generated by the linear piezoelectric element 101 provided on the upper arm of the jacket 500-1, the elbow is twisted and the elbow is twisted. When you revert to the original, the electrical signal changes, but the degree of change is small and unclear.

另一方面,由圖10(B)與圖11(B)之比較可知,針對於設在上衣500-1的前臂部之線狀壓電元件101產生的電性訊號,扭轉肘時與將肘的扭轉回復到原來時明確地出現電性訊號的變化。亦即,將肘扭轉時,設在上衣500-1的前臂部之線狀壓電元件101,產生正極性的電性訊號(參照圖10(B))。另一方面,將肘的扭轉回復到原來時,設在上衣500-1的前臂部之線狀壓電元件101,產生負極性的電性訊號(參照圖11(B))。如此,針對於設在上衣500-1的前臂部之線狀壓電元件101產生的電性訊號,於扭轉肘時與將肘的扭轉回復到原來時電性訊號的極性明確地反轉。On the other hand, as can be seen from the comparison between FIG. 10 (B) and FIG. 11 (B), for the electrical signal generated by the linear piezoelectric element 101 provided on the forearm of the jacket 500-1, when turning the elbow and turning the elbow The reversal of the signal clearly changes when the electrical signal is restored. That is, when the elbow is twisted, the linear piezoelectric element 101 provided on the forearm of the jacket 500-1 generates a positive electrical signal (see FIG. 10 (B)). On the other hand, when the torsion of the elbow is restored, the linear piezoelectric element 101 provided in the forearm of the jacket 500-1 generates a negative electrical signal (see FIG. 11 (B)). In this way, the electrical signal generated by the linear piezoelectric element 101 provided on the forearm of the jacket 500-1 is clearly reversed when the elbow is twisted and when the elbow is returned to its original state.

因而可知,有關扭轉與回復(伸長)肘,係能依據是否「於設在上衣500-1的肘及/或上臂部的線狀壓電元件101產生的電性訊號的極性反轉不明確、還是於設在前臂部的線狀壓電元件101產生的電性訊號的極性為明確地反轉」而予以辨別。例如,演算處理部103,係觀測設在上衣500-1的上臂部的各線狀壓電元件101產生的電性訊號的極性,設在肘及/或上臂部的線狀壓電元件101產生的電性訊號的極性反轉不明確,還是於設在前臂部的線狀壓電元件101產生的電性訊號的極性上有前述之類的明確的反轉之場合,進行辨別「肘扭轉」或者「肘的扭轉被回復到原來」。Therefore, it can be seen that the torsion and recovery (elongation) of the elbow can be determined based on whether the polarity of the electrical signal generated by the linear piezoelectric element 101 provided on the elbow and / or upper arm of the jacket 500-1 is not clear. It is distinguished whether the polarity of the electrical signal generated by the linear piezoelectric element 101 provided in the forearm is clearly reversed. For example, the calculation processing unit 103 observes the polarities of the electrical signals generated by the linear piezoelectric elements 101 provided on the upper arm of the jacket 500-1, and the linear piezoelectric elements 101 provided on the elbow and / or upper arm. It is not clear whether the polarity of the electrical signal is reversed, or if the polarity of the electrical signal generated by the linear piezoelectric element 101 provided on the forearm is clearly reversed as described above, distinguish "elbow twist" or "The torsion of the elbow was restored to the original."

此外,比較圖8及圖9所示之實驗結果與圖10及圖11所示之實驗結果可知,如果觀察設在上衣500-1的肘、前臂部、及上臂部之線狀壓電元件101中,是設在哪個部分的線狀壓電元件101之電性訊號的極性為明確地反轉及是設在哪個部分的線狀壓電元件101之電性訊號的極性反轉不明確,就可以辨別腕彎曲或扭轉。In addition, comparing the experimental results shown in FIGS. 8 and 9 with the experimental results shown in FIGS. 10 and 11, it can be seen that if the linear piezoelectric elements 101 provided on the elbow, forearm, and upper arm of the top 500-1 are observed , It is unclear which part of the linear piezoelectric element 101 is provided with the polarity of the electrical signal of the linear piezoelectric element 101 is clearly reversed and which part of the linear piezoelectric element 101 is provided with the polarity of the electrical signal Can distinguish the wrist bending or twisting.

如以上說明,根據本實施形態,可以於利用伸長產生電性訊號之線狀壓電元件101,辨別「肘被彎曲」、「肘的彎曲被回復到原來」、「肘被扭轉」及「肘的扭轉被回復到原來」之各動作。又,於前述以人類的肘的活動為例加以說明,而針對在人類或動物等生物之、例如肩、手腕、腳踝、膝、髖關節、手指、頭部、口、眼瞼、臉頰、額頭、鼻、耳、腹部、胸部、大腿、小腿、上臂、背部、臀部、手掌、手背、足弓、腳背這樣的可動部位、及在機器人或玩具等機械之可動部位,也可以適用同樣的設計思想。又,為了提高被測定體可動部活動的檢知正確性,也可以作成將感測系統1000被組裝進入的衣物穿著在被測定體並實際地活動被測定體後觀測於線狀壓電元件101及導電性纖維產生的電性訊號的波形,將觀測結果對照被測定體的活動取得電性訊號的波形與被測定體的活動之關係性之圖表,使該圖表記憶於演算處理部103,並使演算處理部103實行被測定體的活動的辨別。As described above, according to the present embodiment, the linear piezoelectric element 101 that generates electrical signals by elongation can distinguish between "elbow is bent", "elbow bending is restored", "elbow is twisted", and "elbow The torsion was restored to the original "actions. In addition, in the foregoing, the activity of the human elbow is taken as an example, and it is aimed at human or animal organisms such as shoulders, wrists, ankles, knees, hips, fingers, head, mouth, eyelids, cheeks, forehead, Nose, ear, abdomen, chest, thigh, calf, upper arm, back, buttocks, palm, back of hand, arch of foot, instep of the foot, and mechanical parts such as robots or toys can apply the same design ideas. In addition, in order to improve the accuracy of detecting the movement of the movable part of the object to be measured, the clothes into which the sensing system 1000 is assembled can be worn on the object to be measured, and the object can be actually moved to observe the linear piezoelectric element 101 And the waveform of the electrical signal generated by the conductive fiber, the observation result is compared with the activity of the measured body to obtain a graph of the relationship between the waveform of the electrical signal and the activity of the measured body, and the graph is stored in the calculation processing unit 103, and The calculation processing unit 103 is made to discriminate the movement of the subject.

圖12係圖示將依照一實施形態的感測系統組裝進入之手套之實際照片,圖12(A)係顯示穿戴手套之手背,圖12(B)係顯示穿戴手套之手掌,圖12(C)係顯示穿戴手套之手的一側面。圖12係顯示將依照本實施形態的感測系統1000組裝進入手套500-3之場合之、線狀壓電元件101之配置例。12 is a diagram showing actual photos of gloves assembled according to an embodiment of the sensing system, FIG. 12 (A) shows the back of the glove, FIG. 12 (B) shows the palm of the glove, and FIG. 12 (C ) Shows the side of the hand wearing the glove. FIG. 12 shows an arrangement example of the linear piezoelectric element 101 when the sensing system 1000 according to this embodiment is assembled into the glove 500-3.

圖13係顯示關於接續機器人控制裝置之一實施形態之感測系統的基本構成之模式圖。例如,也可以在演算處理部103接續機器人控制裝置201,使穿著感測系統1000被組裝進入的衣物之人類的動作再現於機器人202。FIG. 13 is a schematic diagram showing the basic configuration of a sensing system related to an embodiment of a connection robot control device. For example, the calculation processing unit 103 may be connected to the robot control device 201 to reproduce the actions of the human wearing the clothes into which the sensing system 1000 is assembled into the robot 202.

具有以上說明之配置在被穿著在被測定體之衣物,且因應被施加的應力產生電性訊號之線狀壓電元件之依照本實施形態之感測系統1000,也可以與檢測被測定體活動的其他手法組合起來。The sensing system 1000 according to the present embodiment having the linear piezoelectric element configured in the clothing worn on the body to be measured and generating an electrical signal in response to the applied stress can also move with the detection body The other methods are combined.

例如,也可以將依照本實施形態之感測系統1000與供檢知重心移動用之感測器(例如感壓感測器)並用來構築系統。該態樣之場合,例如,可以設置演算處理部,基於在線狀壓電元件101產生的電性訊號與來自檢知重心移動的感測器之訊號,同時地進行辨別被穿著在被測定體的衣物的變形樣態與被測定體自身的活動(重心移動)。根據組合該感測系統1000與檢知重心移動的感測器之態樣,例如,可以同時地實現依照感測系統1000的被測定體(在此係人體)之上半身的活動的檢知與依照別的感測器(例如感壓感測器)之體重移動的檢知,故而可以更加詳細地把握例如高爾夫的揮桿、網球的揮拍等動作。又,作為供檢知被測定體重心移動用之感測器可以使用任一種公知的感測器,但如果將在例如聚乳酸薄膜等面方向發現壓電性之壓電性高分子薄膜層(例如聚-L-乳酸及聚-D-乳酸)、層積複數層的壓電層積體用於壓電層積體元件,使用將壓電層積體捲繞成圓筒狀、在圓角長、方形等的一部分具有曲線部的形狀之感測器,由於荷重依存性的電壓會產生、衰減,如果持續地荷重施加,電壓就會持續一定時間而輸出也會被進行,所以能進行更加詳細的測定。For example, the sensor system 1000 according to this embodiment and a sensor (for example, a pressure sensor) for detecting the movement of the center of gravity may be used to construct the system. In this aspect, for example, an arithmetic processing unit may be provided to simultaneously discriminate between the electrical signal generated by the linear piezoelectric element 101 and the signal from the sensor that detects the movement of the center of gravity while being worn on the body to be measured The deformation of clothes and the movement of the subject itself (the center of gravity moves). According to the combination of the sensing system 1000 and the sensor for detecting the movement of the center of gravity, for example, the detection and compliance of the activity of the upper body of the object to be measured (here, the human body) according to the sensing system 1000 can be simultaneously realized The detection of the movement of the weight of another sensor (for example, a pressure-sensitive sensor) makes it possible to grasp movements such as golf swings and tennis swings in more detail. In addition, as a sensor for detecting the movement of the center of gravity to be measured, any known sensor can be used. However, if a piezoelectric polymer film layer of piezoelectricity is found in the plane direction of, for example, a polylactic acid film ( (E.g. poly-L-lactic acid and poly-D-lactic acid), a piezoelectric laminate in which a plurality of layers are laminated is used for the piezoelectric laminate element, and the piezoelectric laminate is wound into a cylindrical shape and rounded Some sensors with a curved shape such as a long and square shape will generate and decay due to the load-dependent voltage. If the load is continuously applied, the voltage will continue for a certain period of time and the output will be carried out. Detailed measurement.

(線狀壓電元件)   作為本發明之線狀壓電元件,係可以使用因應被施加的應力產生電性訊號的所有公知的元件。例如,作為線狀壓電元件,可以使用具有以導電性纖維作為芯紗並在其周圍配置壓電性纖維的芯鞘構造之壓電元件。更具體而言,作為線狀壓電元件,可以使用在導電性纖維的周圍單單纏繞壓電性薄膜或壓電性纖維之壓電元件、或者在導電性纖維的周圍將壓電性纖維纏繞成穗帶狀之穗帶狀壓電元件。其中,作為本發明之線狀壓電元件,最好是對於伸長變形可輸出較大的電性訊號之壓電元件,由此類之觀點而言,穗帶狀壓電元件是更好的。於是,在以下詳細地說明穗帶狀壓電元件。(Linear piezoelectric element) As the linear piezoelectric element of the present invention, all known elements that generate electrical signals in response to applied stress can be used. For example, as the linear piezoelectric element, a piezoelectric element having a core-sheath structure with conductive fibers as core yarns and piezoelectric fibers arranged around them can be used. More specifically, as the linear piezoelectric element, a piezoelectric element in which a piezoelectric film or piezoelectric fiber is simply wound around the conductive fiber, or a piezoelectric fiber wound around the conductive fiber into Spike ribbon-shaped piezoelectric element. Among them, the linear piezoelectric element of the present invention is preferably a piezoelectric element capable of outputting a large electrical signal by elongation deformation. From such viewpoints, a spike-shaped piezoelectric element is better. Therefore, the spike-shaped piezoelectric element will be described in detail below.

(穗帶狀壓電元件)   圖14係顯示關於實施形態之穗帶狀壓電元件的構成例之模式圖。   穗帶狀壓電元件1,係具備由導電性纖維B形成的芯部3、與以包覆芯部3之方式由穗帶狀的壓電性纖維A形成之鞘部2。(Tape-shaped piezoelectric element) FIG. 14 is a schematic diagram showing a configuration example of the tassel-shaped piezoelectric element according to the embodiment. The ribbon-shaped piezoelectric element 1 includes a core portion 3 formed of conductive fibers B, and a sheath portion 2 formed of piezoelectric fibers A formed in the shape of spikes so as to cover the core portion 3.

於穗帶狀壓電元件1,多數的壓電性纖維A緻密地捲繞至少一根導電性纖維B的外周面。當在穗帶狀壓電元件1發生變形時,因多數的壓電性纖維A分別變形致使應力產生,藉此在多數的壓電性纖維A分別產生電場(壓電效果),結果,使捲繞導電性纖維B的多數壓電性纖維A的電場重疊之電壓變化就在導電性纖維B發生。亦即,比起壓電性纖維A不用穗帶狀鞘部2之場合,來自導電性纖維B的電性訊號會增大。藉此,於穗帶狀壓電元件1,即使利用由比較小的變形所產生的應力,也可以取出較大的電性訊號。又,導電性纖維B也可以是複數根。In the spike-shaped piezoelectric element 1, many piezoelectric fibers A are densely wound on the outer peripheral surface of at least one conductive fiber B. When the spike-shaped piezoelectric element 1 is deformed, a stress is generated due to the deformation of each of the piezoelectric fibers A, thereby generating an electric field (piezoelectric effect) in each of the piezoelectric fibers A. As a result, the coil The voltage change of the electric field overlap of most piezoelectric fibers A around the conductive fiber B occurs at the conductive fiber B. That is, the electrical signal from the conductive fiber B increases compared to the case where the spike-shaped sheath portion 2 is not used for the piezoelectric fiber A. In this way, even if the stress generated by the relatively small deformation is used in the spike-shaped piezoelectric element 1, a large electrical signal can be extracted. Moreover, the conductive fiber B may be plural.

穗帶狀壓電元件1,最好是對於往其中心軸(圖14中的CL)方向的伸長變形選擇性地輸出大的電性訊號。It is preferable that the spike-shaped piezoelectric element 1 selectively outputs a large electrical signal with respect to elongation deformation in the direction of its central axis (CL in FIG. 14).

(對於伸長變形選擇性地輸出大的電性訊號之穗帶狀壓電元件)   作為對於往中心軸方向的伸長變形選擇性地輸出大的電性訊號之穗帶狀壓電元件1,例如,作為壓電性纖維A,可以是一軸配向之高分子的成型體,使用壓電性高分子,包含主成分在使配向軸區分3軸時的壓電常數d14的絕對值具有0.1pC/N以上1000pC/N以下的數值之結晶性高分子。在本發明的「包含主成分」,係指占構成成分的50質量%以上。此外,在本發明之結晶性高分子,係由1質量%以上的結晶部、與結晶部以外的非晶部構成之高分子,結晶性高分子的質量係將結晶部與非晶部合計之質量。又,d14的數值係顯示隨不同的成型條件或純度及測定氛圍而異之數值,但在本發明,係測定實際上被使用之壓電性高分子中的結晶性高分子的結晶化度及結晶配向度,用該結晶性高分子作成具有與這同等的結晶化度及結晶配向度之1軸延伸薄膜,該薄膜的d14的絕對值,在實際上被使用溫度顯示0.1pC/N以上1000pC/N以下的數值即可,且作為本實施形態的壓電性高分子所含的結晶性高分子,並不以後述之類的特定的結晶性高分子為限。薄膜樣本的d14測定可以採取公知的種種方法,例如可以藉由把在薄膜樣本的雙面蒸鍍金屬做成電極之樣本、切出從延伸方向朝45度傾斜方向具有4邊的長方形,在對該長條方向施加拉伸荷重時測定在雙面的電極發生的電荷,而測定d14的數值。(Spike ribbon piezoelectric element that selectively outputs a large electrical signal for elongation deformation) As a spike ribbon piezoelectric element 1 that selectively outputs a large electrical signal for elongation deformation in the direction of the central axis, for example, As the piezoelectric fiber A, a uniaxially oriented polymer molded body may be used. The piezoelectric polymer is used, and the absolute value of the piezoelectric constant d14 including the main component when the alignment axis is divided into three axes is 0.1 pC / N or more. A crystalline polymer with a value of 1000 pC / N or less. In the present invention, "including the main component" means 50% by mass or more of the constituent components. In addition, the crystalline polymer of the present invention is a polymer composed of 1% by mass or more of a crystalline portion and an amorphous portion other than the crystalline portion, and the quality of the crystalline polymer is the total of the crystalline portion and the amorphous portion quality. In addition, the value of d14 is a value that varies with different molding conditions or purity and measurement atmosphere, but in the present invention, it is a measurement of the crystallinity and crystallization of the crystalline polymer in the piezoelectric polymer actually used The degree of crystal alignment, using this crystalline polymer to make a uniaxially stretched film with the same degree of crystallinity and crystal alignment, the absolute value of d14 of this film, in actual use temperature shows 0.1pC / N or more 1000pC The value of / N or less may be sufficient, and the crystalline polymer contained in the piezoelectric polymer of the present embodiment is not limited to a specific crystalline polymer such as described later. The d14 of the thin film sample can be measured by various well-known methods. For example, by evaporating metal on both sides of the thin film sample as an electrode sample, a rectangle with four sides inclined from the extending direction to the 45-degree inclined direction can be cut out. When a tensile load is applied in the longitudinal direction, the electric charge generated on the double-sided electrode is measured, and the value of d14 is measured.

此外,在對於往中心軸方向的伸長變形選擇性地輸出大的電性訊號之穗帶狀壓電元件1,最好是中心軸的方向與壓電性高分子的配向方向所形成之角度(配向角度θ)為15°以上75°以下。滿足這條件時,藉由對穗帶狀壓電元件1給與中心軸方向的伸長變形(拉伸應力及壓縮應力),可以有效率地利用壓電性高分子包含的結晶性高分子的壓電常數d14所對應之壓電效果,在穗帶狀壓電元件1的中心軸側與外側有效地產生逆極性(逆符號)的電荷。從這樣的觀點而言,配向角度θ為25°以上65°以下佳,35°以上55°以下更佳,40°以上50°以下再更佳。以這方式配置壓電性高分子時,壓電性高分子的配向方向就描繪出螺旋狀。In addition, in the spike-shaped piezoelectric element 1 that selectively outputs a large electrical signal for elongation in the direction of the central axis, it is preferable that the angle formed by the direction of the central axis and the alignment direction of the piezoelectric polymer ( The alignment angle θ) is 15 ° or more and 75 ° or less. When this condition is satisfied, by giving elongational deformation (tensile stress and compressive stress) in the direction of the central axis to the spike-shaped piezoelectric element 1, the pressure of the crystalline polymer contained in the piezoelectric polymer can be used efficiently The piezoelectric effect corresponding to the electric constant d14 effectively generates charges of reverse polarity (reverse sign) on the central axis side and the outside of the spike-shaped piezoelectric element 1. From such a viewpoint, the alignment angle θ is preferably 25 ° or more and 65 ° or less, more preferably 35 ° or more and 55 ° or less, and even more preferably 40 ° or more and 50 ° or less. When the piezoelectric polymer is arranged in this way, the alignment direction of the piezoelectric polymer is drawn in a spiral shape.

此外,藉由以這方式配置壓電性高分子,可以對於擦過穗帶狀壓電元件1的表面之類的剪切變形、或彎曲中心軸之類的彎曲變形、或以中心軸當作軸之扭轉變形而形成在穗帶狀壓電元件1的中心軸側與外側不產生大的電荷,亦即作成對於中心軸方向的伸長選擇性地產生大的電荷之穗帶狀壓電元件1。In addition, by arranging the piezoelectric polymer in this way, it is possible to apply shear deformation such as rubbing across the surface of the spike-shaped piezoelectric element 1 or bending deformation such as a bending central axis, or use the central axis as an axis The torsional deformation is formed so that the spike-shaped piezoelectric element 1 does not generate a large electric charge on the central axis side and the outer side of the spike-shaped piezoelectric element 1, that is, the spike-shaped piezoelectric element 1 that selectively generates a large electric charge with respect to elongation in the direction of the central axis.

配向角度θ,盡可能以下述之方法予以測定。拍攝穗帶狀壓電元件1的側面照片,測定壓電性高分子A’的螺旋間距HP。螺旋間距HP係如圖15,主要是1根壓電性高分子A’從表面起轉過背面再來到表面為止之,中心軸方向的直線距離。此外,在因應必要而用接著劑固定構造後,在穗帶狀壓電元件1的中心軸切出垂直的剖面並拍攝照片,測定鞘部2所占的部分的外側半徑Ro及內側半徑Ri。剖面的外緣及內緣為橢圓形或扁平的圓形之場合,將長徑與短徑的平均值設為Ro及Ri。由下述數式計算出壓電性高分子對中心軸的方向之配向角度θ。   θ = arctan(2πRm/HP) (0°≦θ≦90°)   但是,Rm=2(Ro3 -Ri3 )/3(Ro2 -Ri2 ),亦即是以剖面積加重平均之穗帶狀壓電元件1的半徑。The alignment angle θ should be measured by the following method as much as possible. A side photograph of the spike-shaped piezoelectric element 1 was taken, and the helical pitch HP of the piezoelectric polymer A ′ was measured. The spiral pitch HP is shown in Fig. 15, which is mainly a linear distance from the surface of the piezoelectric polymer A 'from the surface to the back and then to the surface. In addition, after fixing the structure with an adhesive as necessary, a vertical cross section is cut out on the central axis of the spike-shaped piezoelectric element 1 and a photograph is taken, and the outer radius Ro and the inner radius Ri of the portion occupied by the sheath 2 are measured. When the outer and inner edges of the cross section are elliptical or flat round, the average value of the long and short diameters is Ro and Ri. The orientation angle θ of the piezoelectric polymer to the direction of the central axis is calculated from the following formula. θ = arctan (2πRm / HP) (0 ° ≦ θ ≦ 90 °) However, Rm = 2 (Ro 3 -Ri 3 ) / 3 (Ro 2 -Ri 2 ), that is, the average spike zone is increased by the cross-sectional area The radius of the piezoelectric element 1.

在穗帶狀壓電元件1的側面照片,壓電性高分子具有均一的表面,在無法辨別壓電性高分子的螺旋間距之場合,將用接著劑等固定之穗帶狀壓電元件1於通過中心軸的平面予以割斷,在垂直於割斷面的方向,於十分狹窄的範圍通過中心軸透過X光進行廣角X光繞射分析,決定配向方向取得與中心軸之角度,設為θ。In the side photo of the spike-shaped piezoelectric element 1, the piezoelectric polymer has a uniform surface, and when the spiral pitch of the piezoelectric polymer cannot be recognized, the spike-shaped piezoelectric element 1 fixed with an adhesive or the like It is cut in a plane passing through the central axis, and in a direction perpendicular to the cutting plane, a wide-angle X-ray diffraction analysis is performed through X-rays through the central axis in a very narrow range to determine the alignment direction to obtain the angle from the central axis, which is set to θ.

在關於本發明之穗帶狀壓電元件1,針對沿著壓電性高分子的配向方向描繪的螺旋狀,又同時存在將螺旋方向(S搓捻方向或者Z搓捻方向)或螺旋間距作成不同的2個以上螺旋狀之場合,針對各個螺旋方向及螺旋間距的壓電性高分子分別進行前述測定,且任一螺旋方向及螺旋間距的壓電性高分子滿足前述條件是必要的。In the spike-shaped piezoelectric element 1 of the present invention, for the spiral shape drawn along the alignment direction of the piezoelectric polymer, the spiral direction (S-twisting direction or Z-twisting direction) or the spiral pitch is also present. In the case of two or more different spiral shapes, the above-mentioned measurement is performed for each piezoelectric polymer of each spiral direction and spiral pitch, and it is necessary for any piezoelectric polymer of any spiral direction and spiral pitch to satisfy the foregoing conditions.

對於中心軸方向的伸長變形而在中心軸側與外側發生的電荷的極性,在將壓電性高分子的配向方向沿著S搓捻的螺旋狀配置之場合、與將相同壓電性高分子的配向方向沿著Z搓捻的螺旋狀配置之場合,成為互逆的極性。因此,將壓電性高分子的配向方向沿著S搓捻的螺旋狀配置、同時沿著Z搓捻的螺旋狀配置之場合,由於對伸長變形的發生電荷會在S搓捻方向與Z搓捻方向相互打消而無法有效率地利用,所以並不佳。從而,前述的壓電性高分子係包含含以壓電常數d14的數值為正的結晶性高分子作為主成分的P體、與含以負的結晶性高分子作為主成分的N體;針對穗帶狀壓電元件1的中心軸有1cm長度的部分,將配向軸朝Z搓捻方向螺旋纏繞被配置的該P體的質量設為ZP、將配向軸朝S搓捻方向螺旋纏繞被配置的該P體的質量設為SP、將配向軸朝Z搓捻方向螺旋纏繞被配置的該N體的質量設為ZN、將配向軸朝S搓捻方向螺旋纏繞被配置的該N體的質量設為SN;在將(ZP+SN)與(SP+ZN)中的較小者設為T1、將較大者設為T2時,T1/T2的數值為0以上0.8以下佳,0以上0.5以下更佳。When the polarities of the charges generated on the central axis side and the outside are elongated and deformed in the direction of the central axis, when the alignment direction of the piezoelectric polymer is spirally arranged along S, the same piezoelectric polymer is used. When the alignment direction of is along the spiral shape of Z twisting, it becomes the reversible polarity. Therefore, when the alignment direction of the piezoelectric polymer is arranged along the spiral shape of S twisting and at the same time along the spiral shape of Z twisting, the charge generated due to the elongation deformation will rub with Z in the S twisting direction The twist directions cancel each other and cannot be used efficiently, so it is not good. Therefore, the aforementioned piezoelectric polymer system includes a P body containing a crystalline polymer having a positive piezoelectric constant d14 as a main component and an N body containing a negative crystalline polymer as a main component; The central axis of the spike-shaped piezoelectric element 1 has a length of 1 cm, and the mass of the P body arranged with the alignment axis spirally wound in the Z twisting direction is set to ZP, and the alignment axis is spirally wound in the direction S The mass of the P body is set to SP, the mass of the N body configured by spirally winding the alignment axis in the Z twisting direction is ZN, and the mass of the N body configured by spirally winding the alignment axis in the S twisting direction Set to SN; when the smaller of (ZP + SN) and (SP + ZN) is set to T1 and the larger to T2, the value of T1 / T2 is preferably 0 or more and 0.8 or less, and 0 or more and 0.5 The following is better.

作為本發明之壓電性纖維使用含主成分之聚乳酸之纖維之場合,聚乳酸中的乳酸單元為90莫耳%以上佳,95莫耳%以上更佳,98莫耳%以上再更佳。When a fiber containing polylactic acid as a main component is used as the piezoelectric fiber of the present invention, the lactic acid unit in polylactic acid is preferably 90 mol% or more, more preferably 95 mol% or more, and even more preferably 98 mol% or more .

又,於穗帶狀壓電元件1,只要達成本發明之目的,可以於鞘部2組合壓電性纖維A以外的其他纖維而進行混纖等,抑或於芯部3組合導電性纖維B以外的其他纖維而進行混纖等。Furthermore, as long as the ribbon-shaped piezoelectric element 1 achieves the purpose of the present invention, it is possible to combine other fibers other than the piezoelectric fiber A in the sheath portion 2 to mix fibers, or to combine the core portion 3 with other than the conductive fiber B And other fibers.

由導電性纖維B的芯部3與穗帶狀壓電性纖維A的鞘部2構成的穗帶狀壓電元件的長度並無特別限定,因應被測定體上的測定領域大小或形狀等酌情決定即可。例如,穗帶狀壓電元件可以在製造上被連續地製造,之後切斷成必要的長度來利用。穗帶狀壓電元件之長度為1mm~20m,以1cm~10m為佳,10cm~5m更佳。長度太短時,會有與從前之點感測器比較後之本發明之前述效果,亦即可以減少每單位面積的感測器的配置個數、能以個數少的感測器特定出應力被施加的位置這樣的效果無法充分達成之場合,此外,長度過長時則有必要考慮導電性纖維B的電阻值。但是,例如,針對電阻值,有並無必要藉由計測電流值來考慮電阻值之場合,針對雜訊則有可藉放大訊號來抑制(或去除)雜訊之場合,以使用電流放大行的放大器特佳。The length of the spike-shaped piezoelectric element composed of the core portion 3 of the conductive fiber B and the sheath portion 2 of the spike-shaped piezoelectric fiber A is not particularly limited, depending on the size or shape of the measurement area on the body to be measured Just make a decision. For example, a spike-shaped piezoelectric element can be manufactured continuously in manufacturing, and then cut to a necessary length and used. The length of the spike-shaped piezoelectric element is 1 mm to 20 m, preferably 1 cm to 10 m, and more preferably 10 cm to 5 m. When the length is too short, there will be the aforementioned effect of the present invention compared with the previous point sensor, that is, the number of sensors per unit area can be reduced, and the number of sensors can be specified When the effect such as the position where the stress is applied cannot be sufficiently achieved, in addition, when the length is too long, it is necessary to consider the resistance value of the conductive fiber B. However, for example, for the resistance value, it is not necessary to consider the resistance value by measuring the current value, and for the noise, the current amplification line can be used to suppress (or remove) the noise by amplifying the signal. Very good amplifier.

以下,詳細說明各構成。Hereinafter, each structure will be described in detail.

(導電性纖維)   作為導電性纖維B,只要顯示導電性者即可,一切公知的都可以使用。作為導電性纖維B,例如,可列舉金屬纖維、由導電性高分子構成之纖維、碳纖維、由分散纖維狀或粒狀的導電性填充物的高分子構成之纖維、或在纖維狀物的表面設置有導電性的層之纖維。作為在纖維狀物的表面設有導電性的層之方法,可列舉金屬塗布、導電性高分子塗布、纏捲導電性纖維等。其中尤以金屬塗布從導電性、耐久性、柔軟性等的觀點而言是最佳。作為塗布金屬的具體性方法,可列舉蒸鍍、濺鍍、電解電鍍、無電解電鍍等,而從生產性等觀點而言則最好是電鍍。被電鍍此類的金屬之纖維係可以稱作金屬電鍍纖維。(Conductive fiber) As the conductive fiber B, any one that shows conductivity can be used, and any known ones can be used. Examples of the conductive fiber B include metal fibers, fibers composed of conductive polymers, carbon fibers, fibers composed of polymers dispersed in a fibrous or granular conductive filler, or on the surface of fibrous materials Fibers provided with conductive layers. Examples of the method for providing a conductive layer on the surface of the fibrous material include metal coating, conductive polymer coating, and winding conductive fibers. Among them, metal coating is particularly preferred from the viewpoint of conductivity, durability, flexibility, and the like. As a specific method of coating the metal, vapor deposition, sputtering, electrolytic plating, electroless plating, etc. may be mentioned, but from the viewpoint of productivity, electroplating is preferable. The fiber system of the metal that is electroplated can be called metal electroplating fiber.

作為基層被塗布金屬的纖維,可以使用有或沒有導電性的公知的纖維,例如,聚酯纖維、尼龍纖維、丙烯酸纖維、聚乙烯纖維、聚丙烯纖維、氯乙烯纖維、芳香族聚醯胺纖維、聚碸纖維、聚醚纖維、聚氨基甲酸酯纖維等合成纖維之外,可以使用棉、麻、絲綢等天然纖維、乙酸酯等半合成纖維、嫘縈、銅銨嫘縈(cupro)等再生纖維。基層的纖維並不以這些纖維為限,可以任意使用公知的纖維,也可以組合這些纖維使用。As the fibers coated with metal on the base layer, known fibers with or without conductivity can be used, for example, polyester fibers, nylon fibers, acrylic fibers, polyethylene fibers, polypropylene fibers, vinyl chloride fibers, aromatic polyamide fibers In addition to synthetic fibers such as polyester fiber, polyether fiber, polyurethane fiber, natural fibers such as cotton, hemp, silk, and semi-synthetic fibers such as acetate, rayon, copper ammonium cupro (cupro) And other recycled fibers. The fibers of the base layer are not limited to these fibers, and any known fibers may be used arbitrarily or in combination.

在基層的纖維被塗布之金屬係顯示導電性,任何金屬只要發揮本發明之效果就可以使用。例如,可以使用金、銀、鉑、銅、鎳、錫、鋅、鈀、氧化銦錫、硫化銅等、及這些的混合物或合金等。The metal to which the fibers of the base layer are coated exhibits electrical conductivity, and any metal can be used as long as the effect of the present invention is exerted. For example, gold, silver, platinum, copper, nickel, tin, zinc, palladium, indium tin oxide, copper sulfide, etc., and mixtures or alloys of these can be used.

使用在導電性纖維B塗布具有耐彎曲性的金屬之有機纖維時,導電性纖維折斷之情形非常少,且在作為使用壓電元件的感測器之耐久性或安全性上優良。When an organic fiber coated with a metal having bending resistance is applied to the conductive fiber B, the conductive fiber is rarely broken, and is excellent in durability and safety as a sensor using a piezoelectric element.

導電性纖維B係可以使用捆束複數根單絲之複絲,抑或,可以使用由一根單絲構成的單體纖維。複絲方面在電性特性的長條安定性的觀點上是較佳。單體纖維(含細紗)之場合,其單絲徑長係1μm~5000μm,以2μm~100μm較佳。以3μm~50μm更佳。複絲之場合,作為單絲數以1根~100000根佳,5根~500根較佳、以10根~100根更佳。但是,導電性纖維B的纖度・根數,係製作穗帶時所使用的芯部3的纖度・根數,由複數根單絲(單體纖維)形成的複絲亦可算作一根導電性纖維B。在此,芯部3,即使是使用導電性纖維以外的纖維之場合,也當作是包含此的全體的量。For the conductive fiber B system, a multifilament bundled with a plurality of monofilaments may be used, or a single fiber composed of a single filament may be used. The multifilament aspect is preferable from the viewpoint of long-term stability of electrical characteristics. In the case of a single fiber (including spun yarn), the monofilament diameter length is 1 μm to 5000 μm, preferably 2 μm to 100 μm. It is more preferably 3 μm to 50 μm. In the case of multifilament, the number of single filaments is preferably 1 to 100,000, preferably 5 to 500, and more preferably 10 to 100. However, the fineness and number of the conductive fiber B are the fineness and number of the core 3 used in making the tape, and the multifilament formed by a plurality of monofilaments (single fiber) can also be counted as one conductive Sex fiber B. Here, even when a fiber other than conductive fibers is used, the core portion 3 is considered to include the entire amount.

纖維的直徑小的話強度降低且操作變得困難,此外,直徑大的場合下則會犧牲可撓性。作為導電性纖維B的剖面形狀為圓形或橢圓形,在壓電元件的設計及製造之觀點上很好,但並不以此為限。If the diameter of the fiber is small, the strength decreases and the operation becomes difficult. In addition, when the diameter is large, flexibility is sacrificed. The cross-sectional shape of the conductive fiber B is circular or elliptical, which is good from the viewpoint of the design and manufacture of the piezoelectric element, but it is not limited to this.

此外,為了有效率地取出來自壓電性高分子的電性輸出,電性電阻最好是低,且作成體積電阻率為10-1 Ω・cm以下佳、10-2 Ω・cm以下較佳、為10-3 Ω・cm以下更佳。但是,只要於電性訊號的檢測出可得到充分的強度,則導電性纖維B的電阻率並不以此為限。In addition, in order to efficiently extract the electrical output from the piezoelectric polymer, the electrical resistance is preferably low, and the volume resistivity is preferably 10 -1 Ω · cm or less, preferably 10 -2 Ω · cm or less It is better to be 10 -3 Ω · cm or less. However, as long as sufficient strength can be obtained from the detection of the electrical signal, the resistivity of the conductive fiber B is not limited to this.

導電性纖維B,從本發明之用途而言,對於所謂的反覆的彎曲或扭轉之活動必須有耐性。作為其指標,結節強度最好是較大者。結節強度係可以依照JIS L1013 8.6之方法測定。對於本發明作為適當的結節強度之程度,為0.5cN/dtex以上佳,1.0cN/dtex以上較佳,1.5cN/dtex以上更佳,2.0cN/dtex以上最佳。此外,作為別的指標,彎曲剛性是較小者。彎曲剛性,一般上是用Kato Tech(股)公司製KES―FB2純彎曲試驗機等之測定裝置來測定。對於本發明作為適當的彎曲剛性之程度,最好是比Toho Tenax(股)公司製的碳纖維“Tenax”(登錄商標)HTS40-3K還小者。具體而言,導電性纖維之彎曲剛性為0.05×10-4 N・m2 /m以下佳,0.02×10-4 N・m2 /m以下較佳,為0.01×10-4 N・m2 /m以下更佳。For the purpose of the present invention, the conductive fiber B must be resistant to so-called repeated bending or twisting. As its index, the nodule strength is preferably the greater. The nodule strength can be measured in accordance with JIS L1013 8.6. For the present invention, the degree of suitable nodule strength is preferably 0.5 cN / dtex or more, preferably 1.0 cN / dtex or more, more preferably 1.5 cN / dtex or more, and most preferably 2.0 cN / dtex or more. In addition, as another index, the bending rigidity is the smaller. The bending rigidity is generally measured with a measuring device such as a KES-FB2 pure bending tester made by Kato Tech Co., Ltd. The degree of appropriate bending rigidity of the present invention is preferably smaller than carbon fiber "Tenax" (registered trademark) HTS40-3K manufactured by Toho Tenax Corporation. Specifically, the flexural rigidity of the conductive fiber is 0.05 × 10 -4 N · m 2 / m or less good, 0.02 × 10 -4 N · m 2 / m or less preferably, of 0.01 × 10 -4 N · m 2 Below / m is better.

(壓電性纖維)   作為壓電性纖維A之材料即壓電性高分子係可以利用聚偏二氟乙烯或聚乳酸之類的顯示壓電性之高分子,而在本實施形態,如前述,壓電性纖維A作為主成分最好是將配向軸作成3軸時的壓電常數d14的絕對值高之結晶性高分子,特別是包含聚乳酸。聚乳酸,例如在熔融紡紗後因延伸而容易配向並顯示壓電性,在不需要用聚偏二氟乙烯等必須的電場配向處理之點上於生產性優良。但是這情況,並非意圖排除在實施本發明時使用聚偏二氟乙烯之外的壓電性材料。(Piezoelectric fiber) As a material of piezoelectric fiber A, that is, a piezoelectric polymer system, a polymer exhibiting piezoelectricity such as polyvinylidene fluoride or polylactic acid can be used. In this embodiment, as described above It is preferable that the piezoelectric fiber A as the main component is a crystalline polymer having a high absolute value of the piezoelectric constant d14 when the alignment axis is formed into three axes, and particularly contains polylactic acid. Polylactic acid, for example, is easy to align due to elongation after melt spinning and exhibits piezoelectricity, and is excellent in productivity in that it does not require necessary electric field alignment treatment with polyvinylidene fluoride or the like. However, this situation is not intended to exclude the use of piezoelectric materials other than polyvinylidene fluoride in the practice of the present invention.

作為聚乳酸,依其結晶構造之不同,有L-乳酸、聚合L-Lactide而成的聚-L-乳酸、D-乳酸、聚合D-Lactide而成的聚-D-乳酸,再者,由這些混合構造構成的STEREO COMPLEX POLYLACTIC ACID(SC-PLA)等,但只要顯示壓電性者則任一種皆可以利用。就壓電率高低之觀點而言最好是聚-L-乳酸、聚-D-乳酸。聚-L-乳酸、聚-D-乳酸,各自對於相同應力會逆轉分極,故而也可以因應目的而組合這些來使用。As polylactic acid, depending on its crystal structure, there are L-lactic acid, poly-L-lactic acid obtained by polymerizing L-Lactide, D-lactic acid, and poly-D-lactic acid obtained by polymerizing D-Lactide. Furthermore, STEREO COMPLEX POLYLACTIC ACID (SC-PLA), etc. composed of these hybrid structures can be used as long as they exhibit piezoelectricity. From the viewpoint of the piezoelectricity, poly-L-lactic acid and poly-D-lactic acid are preferred. Poly-L-lactic acid and poly-D-lactic acid each reverse their polarization to the same stress, so they can be used in combination according to the purpose.

聚乳酸的光學純度為99%以上佳,99.3%以上更佳,99.5%以上再更佳。光學純度未滿99%時有壓電率顯著降低之場合,有因壓電性纖維A的形狀變化導致難以得到充分的電性訊號之場合。特別是,壓電性纖維A,包含主成分之聚-L-乳酸或者聚-D-乳酸,這些的光學純度最好是99%以上。The optical purity of polylactic acid is preferably 99% or more, more preferably 99.3% or more, and even more preferably 99.5% or more. When the optical purity is less than 99%, there is a case where the piezoelectric ratio is significantly reduced, and there are cases where it is difficult to obtain a sufficient electrical signal due to the shape change of the piezoelectric fiber A. In particular, the piezoelectric fiber A contains the main component poly-L-lactic acid or poly-D-lactic acid, and the optical purity of these is preferably 99% or more.

以聚乳酸作為主成分之壓電性纖維A,係於製造時被延伸,並在其纖維軸方向一軸配向。再者,壓電性纖維A,最好是不僅在其纖維軸方向一軸配向,也包含聚乳酸的結晶之纖維,更好是包含一軸配向之聚乳酸的結晶之纖維。這是因為聚乳酸藉由其結晶性高及一軸配向而顯示更大的壓電性,增加d14的絕對值的緣故。The piezoelectric fiber A with polylactic acid as the main component is stretched at the time of manufacture, and is aligned one axis in the fiber axis direction. Furthermore, the piezoelectric fiber A is preferably not only uniaxially aligned in the fiber axis direction but also includes crystalline fibers of polylactic acid, and more preferably crystalline fibers including uniaxially aligned polylactic acid. This is because polylactic acid shows greater piezoelectricity due to its high crystallinity and uniaxial alignment and increases the absolute value of d14.

結晶性及一軸配向性係依照homo PLA結晶化度Xhomo (%)及結晶配向度Ao(%)而求出。作為本發明之壓電性纖維A,homo PLA結晶化度Xhomo (%)及結晶配向度Ao(%)最好是滿足以下數式(1)。未滿足前述數式(1)之場合,結晶性及/或一軸配向性並不充分,而或有電性訊號對動作之輸出值降低,或有對特定方向的動作之訊號感度降低之疑慮。前述數式(1)左邊的數值,為0.28以上較佳,0.3以上更佳。在此,各個數值係依照下述而求出。The crystallinity and uniaxial alignment are determined based on the homo PLA crystallinity X homo (%) and the crystal orientation Ao (%). As the piezoelectric fiber A of the present invention, the homo PLA crystallinity degree X homo (%) and the crystal orientation degree Ao (%) preferably satisfy the following formula (1). When the foregoing formula (1) is not satisfied, the crystallinity and / or uniaxial alignment is insufficient, and there may be a decrease in the output value of the electrical signal to the action, or a decrease in the signal sensitivity to the action in a specific direction. The numerical value on the left side of the foregoing formula (1) is preferably 0.28 or more, and more preferably 0.3 or more. Here, each numerical value is calculated as follows.

Homo聚乳酸結晶化度Xhomo :   針對Homo聚乳酸結晶化度Xhomo ,可以由利用廣角X光繞射分析(WAXD)之結晶構造解析求出。於廣角X光繞射分析(WAXD),係使用Rigaku(股)公司製ultrax18型X光繞射裝置利用透過法,依照以下條件將樣本的X光繞射圖形記錄在影像板(imaging plate)。   X光源:Cu-Kα光(共焦反射鏡:confocal mirror)   輸出:45kV×60mA   狹縫:1st:1mmΦ,2nd:0.8mmΦ   攝影機長度:120mm   積算時間:10分鐘   樣本:將35mg的聚乳酸纖維拉齊做成3cm的纖維束。   在得到的X光繞射圖形跨方位角求出全散射強度Itotal,於此求出由出現在2θ=16.5°, 18.5°, 24.3°附近的Homo聚乳酸結晶而來的各繞射峰值的積分強度的總和ΣIHMi 。由這些數值依照以下數式(2),求出Homo聚乳酸結晶化度Xhomo又,ΣIHMi ,係藉由在全散射強度減去因背景(background)或非晶造成的漫散射而算出。Homo polylactic acid crystallinity degree X homo : The Homo polylactic acid crystallinity degree X homo can be calculated from the crystal structure analysis using wide-angle X-ray diffraction analysis (WAXD). For wide-angle X-ray diffraction analysis (WAXD), an ultrax18 X-ray diffraction device manufactured by Rigaku Co., Ltd. was used to record the X-ray diffraction pattern of the sample on an imaging plate using the transmission method according to the following conditions. X light source: Cu-Kα light (confocal mirror: confocal mirror) Output: 45kV × 60mA Slit: 1st: 1mmΦ, 2nd: 0.8mmΦ Camera length: 120mm Total time: 10 minutes Sample: Pull 35mg of polylactic acid fiber Make 3cm fiber bundle together. Obtain the total scattering intensity Itotal from the obtained X-ray diffraction pattern across the azimuth angle, here we obtain the integral of each diffraction peak from the crystal of Homo polylactic acid appearing near 2θ = 16.5 °, 18.5 °, 24.3 ° The sum of the intensity ΣI HMi . From these numerical values, the Homo polylactic acid crystallinity X homo was determined according to the following formula (2). In addition, ΣI HMi is calculated by subtracting the diffuse scattering caused by the background or amorphous from the total scattering intensity.

(2)結晶配向度Ao:   針對結晶配向度Ao,在利用前述的廣角X光繞射分析(WAXD)得到的X光繞射圖形,針對出現在動徑方向的2θ=16.5°附近的由Homo聚乳酸結晶而來的繞射峰值,取得對方位角(°)之強度分布,由得到的分布分析圖表的半值幅的總計ΣWi (°)依照以下數式(3)算出來。 (2) Crystal alignment degree Ao: For the crystal alignment degree Ao, the X-ray diffraction pattern obtained by the aforementioned wide-angle X-ray diffraction analysis (WAXD) is for Homo, which appears near 2θ = 16.5 ° in the dynamic diameter direction. The diffraction peak derived from the crystallization of polylactic acid obtains the intensity distribution with respect to the azimuth (°), and the total ΣW i (°) of the half-value amplitude from the obtained distribution analysis chart is calculated according to the following equation (3).

又,由於聚乳酸係加水分解比較快速的聚酯,所以,在耐濕熱性會成為問題之場合,也可以添加公知的異氰酸酯化合物、氧唑啉化合物、環氧化合物、碳二亞胺化合物等加水分解防止劑。此外,因應必要也可以添加磷酸系化合物等氧化防止劑、可塑劑、光劣化防止劑等予以物性改良。In addition, since the polylactic acid-based polyester is relatively rapidly decomposed by water, when a damp heat resistance becomes a problem, a well-known isocyanate compound, oxazoline compound, epoxy compound, carbodiimide compound, etc. may be added to add water Decomposition inhibitor. In addition, if necessary, an oxidation inhibitor such as a phosphoric acid compound, a plasticizer, an optical deterioration inhibitor, etc. may be added to improve the physical properties.

壓電性纖維A係可以使用捆束複數根單絲之複絲,抑或,可以使用由一根單絲構成的單體纖維。單體纖維(含細紗)之場合,其單絲徑長係1μm~5mm,以5μm~2mm為佳,更好是10μm~1mm。複絲之場合,其單絲徑長係0.1μm~5mm,以2μm~100μm為佳,更好是3μm~50μm。作為複絲的單絲數量,以1根~100000根佳,50根~50000根較佳、以100根~20000根更佳。但是,針對壓電性纖維A的纖度或根數,係製作穗帶時每1個載體的纖度、根數,由複數根單絲(單體纖維)形成的複絲亦可算作一根壓電性纖維A。在此,在1個載體中,即使是使用壓電性纖維以外的纖維之場合,也當作是包含此的全體的量。For the piezoelectric fiber A series, a multifilament bundled with a plurality of monofilaments may be used, or a single fiber composed of a single filament may be used. In the case of a single fiber (including spun yarn), the monofilament diameter length is 1 μm to 5 mm, preferably 5 μm to 2 mm, more preferably 10 μm to 1 mm. In the case of multifilament, the diameter of the monofilament is 0.1 μm to 5 mm, preferably 2 μm to 100 μm, more preferably 3 μm to 50 μm. The number of monofilaments of the multifilament is preferably 1 to 100,000, preferably 50 to 50,000, and more preferably 100 to 20,000. However, regarding the fineness or the number of piezoelectric fibers A, the fineness and number of each carrier when making the tape, the multifilament formed from a plurality of monofilaments (single fiber) can also be counted as a single Electrical fiber A. Here, even if a fiber other than piezoelectric fibers is used in one carrier, it is regarded as an amount including the entirety.

為了將這類的壓電性高分子做成壓電性纖維A,只要發揮本發明的效果就可以採用任何用以從高分子予以纖維化的公知的手法。例如,可以採用將壓電性高分子擠出成型後纖維化之手法、將壓電性高分子熔紡後纖維化之手法、將壓電性高分子利用乾式或濕式紡紗而纖維化之手法、將壓電性高分子利用靜電紡紗而纖維化之手法、在形成薄膜後切細之手法等等。這些的紡紗條件,因應所採用的壓電性高分子而適用不同的公知的手法即可,通常而言採用工業上容易生產的熔紡法即可。再者,在形成纖維後將被形成的纖維予以延伸。藉此,形成一軸延伸配向且含結晶的顯示大壓電性的壓電性纖維A。In order to make such a piezoelectric polymer into a piezoelectric fiber A, as long as the effect of the present invention is exerted, any known technique for fibrillating from a polymer can be adopted. For example, a method of extruding piezoelectric polymers after fibrillation, a method of melt-spinning piezoelectric polymers after fibrillation, and piezoelectric fibers using dry or wet spinning and fiberization Techniques, methods of spinning piezoelectric polymers by electrospinning to fibrillate them, methods of cutting thin films after forming films, etc. For these spinning conditions, different well-known methods may be applied depending on the piezoelectric polymer used, and generally, a melt spinning method that is easy to produce in industry may be used. Furthermore, after forming the fiber, the formed fiber is extended. Thereby, a piezoelectric fiber A exhibiting large piezoelectricity and having uniaxial extension alignment and containing crystals is formed.

此外,壓電性纖維A,可以在將前述方式製作出之物做成穗帶之前,進行染色、撚紗、併紗、熱處理等之處理。In addition, the piezoelectric fiber A may be subjected to dyeing, twisting, doubling, heat treatment, etc., before the object produced in the above-described manner is made into a tape.

再者,壓電性纖維A,由於在形成穗帶時或有纖維彼此摩擦而斷線,或有毛羽跑出來之場合,所以其強度與耐磨耗性高者佳,強度為1.5cN/dtex以上佳,2.0cN/dtex以上較佳,2.5cN/dtex以上更佳,為3.0cN/dtex以上最佳。耐磨耗性係可以依照JIS L1095 9.10.2 B法等予以評價,摩擦回數為100回以上佳,1000回以上較佳,5000回以上更佳,為10000回以上最佳。用以提升耐磨耗性之方法並未特別限定,可以採用公知的所有方法,例如,可以或是提高結晶化度、或是添加微粒子、或是予以表面加工。此外,也可以在對穗帶加工時,在纖維塗布潤滑劑以減低摩擦。In addition, the piezoelectric fiber A has a strong strength and abrasion resistance of 1.5 cN / dtex because the fibers are broken due to friction between the fibers when forming the ear belt, or when hairiness runs out. The above is preferable, preferably 2.0 cN / dtex or more, more preferably 2.5 cN / dtex or more, and most preferably 3.0 cN / dtex or more. The wear resistance can be evaluated according to JIS L1095 9.10.2 B method, etc. The number of friction cycles is preferably 100 cycles or more, preferably 1000 cycles or more, more preferably 5000 cycles or more, and most preferably 10,000 cycles or more. The method for improving the abrasion resistance is not particularly limited, and all known methods can be used, for example, either to increase the crystallinity, to add fine particles, or to perform surface processing. In addition, it is also possible to apply a lubricant to the fibers during processing of the ear tape to reduce friction.

此外,壓電性纖維的收縮率,最好是與前述的導電性纖維的收縮率的差異小。收縮率差異大時,由於穗帶製作後的後處理製程或實際使用時加熱時或經時變化會有導致穗帶彎曲等等,造成壓電訊號減弱之場合。將收縮率依後述的沸水收縮率而定量化之場合,最好是壓電性纖維的沸水收縮率S(p)及導電性纖維的沸水收縮率S(c)滿足下述數式(4)。前述數式(4)的左邊為5以下較佳,3以下更佳。In addition, the shrinkage rate of the piezoelectric fiber is preferably smaller than the shrinkage rate of the aforementioned conductive fiber. When the difference in shrinkage ratio is large, the post-processing process after the production of the ear belt or the actual use will cause the ear belt to bend when heated or changed over time, which will cause the piezoelectric signal to weaken. When the shrinkage rate is quantified according to the boiling water shrinkage rate described later, it is preferable that the boiling water shrinkage rate S (p) of the piezoelectric fiber and the boiling water shrinkage rate S (c) of the conductive fiber satisfy the following formula (4) . The left side of the aforementioned equation (4) is preferably 5 or less, more preferably 3 or less.

此外,壓電性纖維的收縮率,最好是與導電性纖維以外的纖維、例如絕緣性纖維的收縮率的差異也小。收縮率差異大時,由於穗帶製作後的後處理製程或實際使用時加熱時或經時變化會有導致穗帶彎曲等等,造成壓電訊號減弱之場合。將收縮率依沸水收縮率而定量化之場合,最好是壓電性纖維的沸水收縮率S(p)及絕緣性纖維的沸水收縮率S(i)滿足下述數式(5)。前述數式(5)的左邊為5以下較佳,3以下更佳。In addition, the shrinkage rate of the piezoelectric fiber is preferably smaller than the shrinkage rate of fibers other than conductive fibers, for example, insulating fibers. When the difference in shrinkage ratio is large, the post-processing process after the production of the ear belt or the actual use will cause the ear belt to bend when heated or changed over time, which will cause the piezoelectric signal to weaken. When the shrinkage ratio is quantified according to the boiling water shrinkage ratio, it is preferable that the boiling water shrinkage ratio S (p) of the piezoelectric fiber and the boiling water shrinkage ratio S (i) of the insulating fiber satisfy the following formula (5). The left side of the aforementioned equation (5) is preferably 5 or less, more preferably 3 or less.

此外,壓電性纖維的收縮率,小者較佳。在例如將收縮率依沸水收縮率而定量化之場合,壓電性纖維的收縮率為15%以下佳,10%以下較佳、5%以下更佳、為3%以下最佳。作為降低收縮率之手段,可以適用公知的所有方法,例如,可以利用熱處理使非晶部的配向緩和或藉由提高結晶化度以減低收縮率,實施熱處理之時間並未特別限定,可以列舉延伸後、撚紗後、或穗帶化後等。又,前述的沸水收縮率係依照以下的方法來測定。用框周1.125m的量測機(measuring machine)作出捲數20回的線團,施加0.022cN/dtex的荷重,懸掛在刻度板並測定初期的線團長L0。其後,在將該線團於100℃的沸騰水浴中處理30分鐘後,放冷再施加前述荷重後懸掛在刻度板測定收縮後的線團長L。使用被測定出的L0及L並利用以下數式(6)來計算沸水收縮率。 In addition, the shrinkage rate of the piezoelectric fiber is preferably smaller. For example, when the shrinkage rate is quantified according to the boiling water shrinkage rate, the shrinkage rate of the piezoelectric fiber is preferably 15% or less, preferably 10% or less, more preferably 5% or less, and most preferably 3% or less. As a means for reducing the shrinkage rate, all known methods can be applied. For example, heat treatment can be used to ease the alignment of the amorphous portion or to reduce the shrinkage rate by increasing the degree of crystallization. After, after twisting the yarn, or after the ears are tapered, etc. In addition, the aforementioned boiling water shrinkage rate is measured according to the following method. Using a measuring machine with a circumference of 1.125 m, a coil of 20 turns was made, a load of 0.022 cN / dtex was applied, the suspension was hung on the scale plate, and the initial coil length L0 was measured. Thereafter, after the coil was treated in a boiling water bath at 100 ° C. for 30 minutes, the coil was left to cool and the aforementioned load was applied, and then hung on a scale plate to measure the length L of the coil after shrinkage. Using the measured L0 and L, the boiling water shrinkage ratio was calculated using the following equation (6).

(包覆)   導電性纖維B,亦即芯部3,係由壓電性纖維A、亦即穗帶狀鞘部2包覆表面。包覆導電性纖維B的鞘部2之厚度為1μm~10mm佳,5μm~5mm較佳,10μm~3mm更佳,為20μm~1mm最佳。太薄的話在強度之點有成為問題之場合,此外,過厚的話則有穗帶狀壓電元件1變硬且變形困難之場合。又,在此所稱的鞘部2係指鄰接在芯部3之層。(Coating) The conductive fiber B, that is, the core portion 3, is coated with a surface of the piezoelectric fiber A, that is, the spike-shaped sheath portion 2. The thickness of the sheath portion 2 covering the conductive fiber B is preferably 1 μm to 10 mm, preferably 5 μm to 5 mm, more preferably 10 μm to 3 mm, and most preferably 20 μm to 1 mm. If it is too thin, it may be a problem in terms of strength. In addition, if it is too thick, the spike-shaped piezoelectric element 1 may become hard and difficult to deform. In addition, the sheath portion 2 referred to herein refers to the layer adjacent to the core portion 3.

在穗帶狀壓電元件1,鞘部2的壓電性纖維A的總纖度,係芯部3的導電性纖維B的總纖度的1/2倍以上、20倍以下佳,1倍以上、15倍以下較佳,為2倍以上、10倍以下更佳。壓電性纖維A的總纖度相對於導電性纖維B的總纖度過小時,包圍導電性纖維B的壓電性纖維A會過少而使導電性纖維B無法輸出足夠的電性訊號,再者會有導電性纖維B接觸到所接近的其他導電性纖維之疑慮。壓電性纖維A的總纖度相對於導電性纖維B的總纖度過大時,包圍導電性纖維B的壓電性纖維A會過多而使穗帶狀壓電元件1變硬且變形困難。亦即,在任一場合下穗帶狀壓電元件1都不能充分發揮作為感測器之功能。   在此,總纖度,係構成鞘部2的壓電性纖維A全部的纖度加總,例如,在一般的8打穗帶之場合,為8根纖維纖度的加總。In the spike-shaped piezoelectric element 1, the total fineness of the piezoelectric fibers A of the sheath portion 2 is preferably 1/2 or more, 20 or less, and 1 or more of the total fineness of the conductive fibers B of the core portion 3 It is preferably 15 times or less, more preferably 2 times or more, and more preferably 10 times or less. If the total fineness of the piezoelectric fiber A is too small relative to the total fineness of the conductive fiber B, the piezoelectric fiber A surrounding the conductive fiber B will be too small, so that the conductive fiber B cannot output enough electrical signals, and There is a concern that the conductive fiber B is in contact with other conductive fibers in proximity. When the total fineness of the piezoelectric fiber A is too large relative to the total fineness of the conductive fiber B, the piezoelectric fiber A surrounding the conductive fiber B is too much, making the spike-shaped piezoelectric element 1 hard and difficult to deform. That is, in any case, the spike-shaped piezoelectric element 1 cannot fully function as a sensor. Here, the total fineness is the total fineness of all the piezoelectric fibers A constituting the sheath portion 2, for example, in the case of a general 8-tapping tape, the total fineness of 8 fibers is added.

此外,在穗帶狀壓電元件1,鞘部2的壓電性纖維A的每一根纖度係導電性纖維B的總纖度的1/20倍以上、2倍以下佳,1/15倍以上、1.5倍以下較佳,為1/10倍以上、1倍以下更佳。壓電性纖維A每一根的纖度相對於導電性纖維B的總纖度過小時,壓電性纖維A過少而使導電性纖維B無法輸出足夠的電性訊號,再者會有切斷壓電性纖維A之疑慮。壓電性纖維A每一根的纖度相對於導電性纖維B的總纖度過大時,壓電性纖維A太粗而使穗帶狀壓電元件1變硬且變形困難。亦即,在任一場合下穗帶狀壓電元件1都不能充分發揮作為感測器之功能。In addition, in the tape-shaped piezoelectric element 1, each denier of the piezoelectric fiber A of the sheath portion 2 is 1/20 times or more, preferably 2 times or less, and 1/15 times or more of the total fineness of the conductive fiber B. It is preferably 1.5 times or less, more preferably 1/10 times or more, more preferably 1 times or less. The fineness of each of the piezoelectric fibers A is too small relative to the total fineness of the conductive fibers B. Too few piezoelectric fibers A prevents the conductive fibers B from outputting sufficient electrical signals. Sex fiber A doubts. When the fineness of each of the piezoelectric fibers A is too large relative to the total fineness of the conductive fibers B, the piezoelectric fibers A are too thick, making the spike-shaped piezoelectric element 1 hard and difficult to deform. That is, in any case, the spike-shaped piezoelectric element 1 cannot fully function as a sensor.

又,在導電性纖維B使用金屬纖維之場合,或將金屬纖維混纖到導電性纖維B或壓電性纖維A之場合,纖度的比率則不以前述為限。在本發明,前述比率,在接觸面積或包覆率、亦即面積及體積之觀點上是重要的緣故。例如,在纖維各自的比重超過2之類的場合,最好是纖維的平均剖面積的比率為前述纖度的比率。In addition, when metal fibers are used as the conductive fibers B, or when the metal fibers are mixed with the conductive fibers B or the piezoelectric fibers A, the ratio of fineness is not limited to the above. In the present invention, the aforementioned ratio is important from the viewpoint of contact area or coverage, that is, area and volume. For example, when the specific gravity of each fiber exceeds 2, it is preferable that the ratio of the average cross-sectional area of the fiber be the ratio of the fineness.

壓電性纖維A與導電性纖維B最好是盡可能地密貼著,而為了改良密貼性,也可以在導電性纖維B與壓電性纖維A之間設置錨層或黏接層等。The piezoelectric fiber A and the conductive fiber B are preferably adhered as closely as possible, and in order to improve the adhesion, an anchor layer or an adhesive layer may be provided between the conductive fiber B and the piezoelectric fiber A .

包覆之方法可採取以導電性纖維B作為芯紗,並在其周圍纏繞壓電性纖維A為穗帶狀之方法。另一方面,壓電性纖維A之穗帶形狀,只要可以對於由被施加的荷重產生的應力輸出電性訊號則無特別限定,但最好是具有芯部3的8打穗帶或16打穗帶。For the coating method, the conductive fiber B is used as the core yarn, and the piezoelectric fiber A is wound around it in the shape of a spike. On the other hand, the shape of the spike tape of the piezoelectric fiber A is not particularly limited as long as it can output electrical signals for the stress generated by the applied load, but it is preferably 8 spike tapes or 16 dozen with the core 3 Spike band.

作為導電性纖維B與壓電性纖維A之形狀並無特別限定,但最好是盡可能接近同心圓狀。又,作為導電性纖維B而使用複絲之場合,壓電性纖維A,包覆成接觸導電性纖維B的複絲表面(纖維周面)的至少一部分即可,在構成複絲的全部的單絲表面(纖維周面)可以有抑或沒有壓電性纖維A包覆。壓電性纖維A之往構成導電性纖維B複絲的內部的各單絲之包覆狀態,考慮作為壓電性元件之性能、操作性等而斟酌設定即可。The shapes of the conductive fiber B and the piezoelectric fiber A are not particularly limited, but they are preferably as close to concentric circles as possible. In addition, when a multifilament is used as the conductive fiber B, the piezoelectric fiber A may be coated so as to contact at least a part of the multifilament surface (fiber peripheral surface) of the conductive fiber B. The surface of the monofilament (the peripheral surface of the fiber) may or may not be covered with piezoelectric fiber A. The coating state of each monofilament of the piezoelectric fiber A to the inside of the multifilament constituting the conductive fiber B may be set as appropriate considering the performance and operability of the piezoelectric element.

在本發明之穗帶狀壓電元件1,由於並無使其表面存在電極之必要,所以沒有必要進而包覆穗帶狀壓電元件1本身,還有不易誤動作之優點。In the spike-shaped piezoelectric element 1 of the present invention, since there is no need to have an electrode on its surface, there is no need to further coat the spike-shaped piezoelectric element 1 itself, and there is an advantage that it is less likely to malfunction.

(絕緣性纖維)   更具體而言,於穗帶狀壓電元件1,鞘部2可以僅利用壓電性纖維A而形成,或者也可以利用壓電性纖維A與絕緣性纖維之組合而形成。(Insulating fiber) More specifically, in the spike-shaped piezoelectric element 1, the sheath portion 2 may be formed using only the piezoelectric fiber A, or may be formed using a combination of the piezoelectric fiber A and the insulating fiber .

作為這類的絕緣性纖維,例如,聚酯纖維、尼龍纖維、丙烯酸纖維、聚乙烯纖維、聚丙烯纖維、氯乙烯纖維、芳香族聚醯胺纖維、聚碸纖維、聚醚纖維、聚氨基甲酸酯纖維等合成纖維之外,可以使用棉、麻、絲綢等天然纖維、乙酸酯等半合成纖維、嫘縈、銅銨嫘縈(cupro)等再生纖維。並不以這些為限,可以任意使用公知的絕緣性纖維。再者,也可以組合使用這些絕緣性纖維,抑或與不具絕緣性的纖維組合,做成全體上具有絕緣性的纖維亦可。   此外,也可以使用公知的所有剖面形狀的纖維。As this type of insulating fiber, for example, polyester fiber, nylon fiber, acrylic fiber, polyethylene fiber, polypropylene fiber, vinyl chloride fiber, aromatic polyamide fiber, polyphenol fiber, polyether fiber, polyurethane In addition to synthetic fibers such as ester fibers, natural fibers such as cotton, hemp, and silk, semi-synthetic fibers such as acetate, regenerated fibers such as rayon, cupro, etc. can be used. It is not limited to these, and a well-known insulating fiber can be used arbitrarily. In addition, these insulating fibers may be used in combination, or they may be combined with fibers without insulation to form fibers having insulation properties as a whole. In addition, all known cross-sectional shapes of fibers can also be used.

(製造方法)   在本發明之穗帶狀壓電元件1係將至少1根導電性纖維B的表面以穗帶狀壓電性纖維A包覆,而作為其製造方法可列舉例如以下之方法。亦即,將導電性纖維B與壓電性纖維A於各別的製程製作,在導電性纖維B將壓電性纖維A纏繞成穗帶狀而包覆之方法。在該場合,最好是包覆成盡可能地接近同心圓狀。(Manufacturing method) In the spike-shaped piezoelectric element 1 of the present invention, the surface of at least one conductive fiber B is covered with spike-shaped piezoelectric fibers A, and examples of the manufacturing method include the following methods. That is to say, the conductive fiber B and the piezoelectric fiber A are produced in separate processes, and the conductive fiber B is wound around the piezoelectric fiber A in a ribbon shape and covered. In this case, it is preferable to coat as close to concentric circles as possible.

該場合,在使用聚乳酸作為形成壓電性纖維A的壓電性高分子之場合下最好的紡絲、延伸條件,熔融紡絲溫度最好是150~250℃,延伸溫度最好是40~150℃,延伸倍率從1.1倍到5.0倍佳,結晶化溫度最好是80~170℃。In this case, when polylactic acid is used as the piezoelectric polymer forming the piezoelectric fiber A, the best spinning and drawing conditions are as follows. The melt spinning temperature is preferably 150 to 250 ° C, and the drawing temperature is preferably 40 ~ 150 ° C, the stretch ratio is preferably from 1.1 to 5.0 times, and the crystallization temperature is preferably 80 to 170 ° C.

作為纏繞在導電性纖維B的壓電性纖維A,可以使用捆束複數單絲之複絲,此外,也可以使用單體纖維(包含細紗)。此外,作為被纏繞壓電性纖維A之導電性纖維B,可以使用捆束複數單絲之複絲,抑或,可以使用單體纖維(包含細紗)。As the piezoelectric fiber A wound around the conductive fiber B, a multifilament bundled with a plurality of monofilaments may be used, or a single fiber (including spun yarn) may be used. In addition, as the conductive fiber B to which the piezoelectric fiber A is wound, a multifilament bundled with a plurality of monofilaments may be used, or a single fiber (including spun yarn) may be used.

作為包覆的最佳形態,可以藉由將導電性纖維B作為芯紗,在其周圍將壓電性纖維A紐製成穗帶狀,並製作管狀編織物(Tubular Braid),而予以包覆。更具體而言,可列舉具有芯部3之8打穗帶或16打穗帶。但是,例如,可以藉由將壓電性纖維A做成像編織管之類的形態,將導電性纖維B當作芯並插入該編織管而包覆。As the best form of coating, the conductive fiber B is used as the core yarn, the piezoelectric fiber A button is formed into a ribbon shape around the circumference, and a tubular braid (Tubular Braid) is produced and coated . More specifically, there may be an 8-heading belt or a 16-heading belt having a core 3. However, for example, the piezoelectric fiber A may be used as an image braided tube or the like, and the conductive fiber B may be used as a core and inserted into the braided tube to be coated.

利用如以上之類的製造方法,可以得到將導電性纖維B的表面以穗帶狀壓電性纖維A包覆之穗帶狀壓電元件1。According to the manufacturing method as described above, a spike-shaped piezoelectric element 1 in which the surface of the conductive fiber B is coated with spike-shaped piezoelectric fibers A can be obtained.

在本發明之穗帶狀壓電元件1,由於沒有必要作成在表面形成供檢測電性訊號用之電極,所以能比較簡單地進行製造。In the spike-shaped piezoelectric element 1 of the present invention, since it is not necessary to form electrodes for detecting electrical signals on the surface, it can be manufactured relatively easily.

(保護層)   也可以在本發明之穗帶狀壓電元件1的最表面設置保護層。該保護層最好是絕緣性,從可撓性等的觀點而言更好是由高分子所構成。在保護層具有絕緣性之場合,當然,在該場合下或有連同保護層變形,或有摩擦保護層上之情形,但只要這些外力到達壓電性纖維A為止,可以誘發其分極則並無特別限定。作為保護層,並不以利用高分子等的塗布而被形成者為限,可以是纏繞薄膜、布帛、纖維等,或者,也可以是組合這些之物。(Protective layer) A protective layer may be provided on the outermost surface of the spike-shaped piezoelectric element 1 of the present invention. The protective layer is preferably insulating, and is preferably composed of a polymer from the viewpoint of flexibility and the like. In the case where the protective layer is insulating, of course, there may be deformation with the protective layer or friction on the protective layer, but as long as these external forces reach the piezoelectric fiber A, the polarization can be induced. Specially limited. The protective layer is not limited to those formed by coating with a polymer or the like, and may be wound film, fabric, fiber, or the like, or may be a combination of these.

作為保護層的厚度係盡量愈薄愈容易將剪切應力傳達到壓電性纖維A,但太薄時容易發生保護層本身被破壞等問題,因而以10nm~200μm為佳,50nm~50μm較佳,70nm~30μm更佳,為100nm~10μm最佳。也可以依照這保護層形成壓電元件的形狀。As the thickness of the protective layer is as thin as possible, the shear stress can be easily transmitted to the piezoelectric fiber A, but when it is too thin, problems such as damage to the protective layer itself are likely to occur, so 10 nm to 200 μm is preferable, and 50 nm to 50 μm is preferable , 70nm ~ 30μm is better, 100nm ~ 10μm is the best. The shape of the piezoelectric element may be formed according to this protective layer.

此外,以減低雜訊為目的也可以將電磁波遮蔽層納入穗帶構造。電磁波遮蔽層並未特別限定,可以是塗布導電性的物質,也可以是纏繞具有導電性的薄膜、布帛、纖維等。作為電磁波遮蔽層的體積電阻率以10-1 Ω・cm以下佳,為10-2 Ω・cm以下較佳,為10-3 Ω・cm以下更佳。但是,只要可以得到電磁波遮蔽層的效果,則電阻率並不以此為限。該電磁波遮蔽層,可以設置在鞘的壓電性纖維A的表面,也可以設置在前述的保護層的外側。當然,電磁波遮蔽層與保護層可以被層積複數層,其順序也可因應目的之不同而酌情決定。In addition, for the purpose of reducing noise, the electromagnetic wave shielding layer can also be incorporated into the ear belt structure. The electromagnetic wave shielding layer is not particularly limited, and may be a material coated with conductivity, or may be wound with a conductive film, cloth, fiber, or the like. The volume resistivity of the electromagnetic wave shielding layer is preferably 10 -1 Ω · cm or less, preferably 10 -2 Ω · cm or less, and more preferably 10 -3 Ω · cm or less. However, as long as the effect of the electromagnetic wave shielding layer can be obtained, the resistivity is not limited to this. The electromagnetic wave shielding layer may be provided on the surface of the piezoelectric fiber A of the sheath, or may be provided outside the aforementioned protective layer. Of course, the electromagnetic wave shielding layer and the protective layer can be laminated in multiple layers, and the order can also be determined according to different purposes.

再者,也可以又設置複數層由壓電性纖維構成的層,又設置複數層供取出訊號用的由導電性纖維構成的層。當然,該等保護層、電磁波遮蔽層、由壓電性纖維構成的層、由導電性纖維構成的層,可因應其目的之不同,而酌情決定其順序及層數。又,作為纏繞之方法,可列舉或在鞘部2的更外層形成穗帶構造,或予以覆蓋之方法。Furthermore, a plurality of layers composed of piezoelectric fibers may be further provided, and a plurality of layers composed of conductive fibers for taking out signals may be further provided. Of course, the protective layer, the electromagnetic wave shielding layer, the layer composed of piezoelectric fibers, and the layer composed of conductive fibers can determine the order and number of layers according to their different purposes. In addition, as a method of winding, a method of forming a tape structure on the outer layer of the sheath 2 or covering it may be mentioned.

當在穗帶狀壓電元件1發生變形時,壓電性纖維A變形並產生分極。受到因壓電性纖維A的分極產生的正負各電荷的配列之影響,在來自形成穗帶狀壓電元件1的芯部3之導電性纖維B的輸出端子之拉出線上會產生電荷移動。在來自導電性纖維B的拉出線上之電荷移動係顯現成微小的電性訊號(亦即電流或電位差)。換言之,因應於給穗帶狀壓電元件1帶來變形時產生的電荷,電性訊號是從輸出端子被輸出。從而,穗帶狀壓電元件1,係可以在關於本發明之感測系統有效地發揮功能。When the spike-shaped piezoelectric element 1 is deformed, the piezoelectric fiber A is deformed and polarized. Affected by the arrangement of the positive and negative charges due to the polarization of the piezoelectric fiber A, charge movement occurs on the pull-out line from the output terminal of the conductive fiber B forming the core portion 3 of the spike-shaped piezoelectric element 1. The movement of charge on the pull-out line from the conductive fiber B appears as a tiny electrical signal (ie, current or potential difference). In other words, the electrical signal is output from the output terminal in accordance with the charge generated when the spike-shaped piezoelectric element 1 is deformed. Therefore, the spike-shaped piezoelectric element 1 can effectively function in the sensing system of the present invention.

又,於以上說明之圖9~11所示的實驗,作為關於本發明之感測系統之線狀壓電元件,使用在以下說明的穗帶狀壓電元件1-2,這是依以下的方法製造。In addition, in the experiments shown in FIGS. 9 to 11 described above, as the linear piezoelectric element of the sensing system of the present invention, the spike-shaped piezoelectric element 1-2 described below is used, which is as follows Method manufacturing.

在穗帶狀壓電元件被使用的壓電性纖維之特性,係依照以下的方法來決定。   (1)聚-L-乳酸結晶化度Xhomo :   針對聚-L-乳酸結晶化度Xhomo ,由依據廣角X光繞射分析(WAXD)之結晶構造解析而求出。於廣角X光繞射分析(WAXD),係使用Rigaku(股)公司製ultrax18型X光繞射裝置利用透過法,依照以下條件將樣本的X光繞射圖形記錄在影像板。   X光源:Cu-Kα光(共焦反射鏡:confocal mirror)   輸出:45kV×60mA   狹縫:1st:1mmΦ,2nd:0.8mmΦ   攝影機長度:120mm   積算時間:10分鐘   樣本:將35mg的聚乳酸纖維拉齊做成3cm的纖維束。   在得到的X光繞射圖形跨方位角求出全散射強度Itotal ,於此求出由出現在2θ=16.5°,18.5°,24.3°附近的聚-L-乳酸結晶而來的各繞射峰值的積分強度的總和ΣIHMi 。由這些數值依照以下數式(7),求出聚-L-乳酸結晶化度Xhomo又,ΣIHMi ,係藉由在全散射強度減去因背景或非晶造成的漫散射而算出。The characteristics of the piezoelectric fiber used in the spike-shaped piezoelectric element are determined according to the following method. (1) Poly-L-lactic acid crystallinity degree X homo : The poly-L-lactic acid crystallinity degree X homo is obtained from crystal structure analysis based on wide-angle X-ray diffraction analysis (WAXD). For wide-angle X-ray diffraction analysis (WAXD), an ultrax18 X-ray diffraction device manufactured by Rigaku Co., Ltd. was used to record the X-ray diffraction pattern of the sample on the image board according to the following conditions using the transmission method. X light source: Cu-Kα light (confocal mirror: confocal mirror) Output: 45kV × 60mA Slit: 1st: 1mmΦ, 2nd: 0.8mmΦ Camera length: 120mm Total time: 10 minutes Sample: Pull 35mg of polylactic acid fiber Make 3cm fiber bundle together. Obtain the total scattering intensity I total from the obtained X-ray diffraction pattern across the azimuth angle. Here, each diffraction from poly-L-lactic acid crystals appearing near 2θ = 16.5 °, 18.5 °, and 24.3 ° is obtained. The sum of the integrated intensity of the peak value ΣI HMi . From these numerical values, the degree of poly-L-lactic acid crystallinity X homo was determined according to the following equation (7). In addition, ΣI HMi is calculated by subtracting the diffuse scattering caused by background or amorphous from the total scattering intensity.

(2)聚-L-乳酸結晶配向度A:   針對聚-L-乳酸結晶配向度A,在利用前述的廣角X光繞射分析(WAXD)得到的X光繞射圖形,針對出現在動徑方向的2θ=16.5°附近的聚-L-乳酸結晶而來的繞射峰值,取得對方位角(°)之強度分布,由得到的分布分析圖表的半值幅的總計ΣWi (°)依照以下數式(8)算出來。 (2) Poly-L-lactic acid crystal orientation degree A: For the poly-L-lactic acid crystal orientation degree A, the X-ray diffraction pattern obtained by the aforementioned wide-angle X-ray diffraction analysis (WAXD) is aimed at the occurrence of The diffraction peak from the poly-L-lactic acid crystal near 2θ = 16.5 ° in the direction obtains the intensity distribution for the azimuth (°). The total half-value amplitude ΣW i (°) from the obtained distribution analysis chart is in accordance with Calculate the following formula (8).

(3)聚乳酸的光學純度:   採取構成穗帶狀壓電元件之1根(複絲之場合為1束)聚乳酸纖維0.1g,添加5莫耳/公升濃度的氫氧化鈉水溶液1.0mL與甲醇1.0mL,放到設定在65℃的水浴振動器、直到聚乳酸成為均一溶液為止進行30分鐘左右加水分解,再者,在加水分解結束的溶液添加0.25莫耳/公升的硫酸且中和直到pH7為止,採取0.1mL該分解溶液後利用高效能液相層析法(HPLC)移動相溶液3mL而稀釋,利用膜過濾器(0.45μm)過濾。進行該調整溶液的HPLC測定,將L-乳酸單體與D-乳酸單體之比率予以定量。1根聚乳酸纖維不滿0.1g之場合,配合可以採取的量調整其它溶液的使用量,把供給HPLC測定之樣本溶液的聚乳酸濃度作成從與前述同等成為100分之1的範圍。 <HPLC測定條件>   Column:日本SCAS(股)公司製「SUMICHIRAL(登錄商標)」OA-5000(4.6mmφ×150mm)、   移動相:1.0毫莫耳/公升的硫酸銅水溶液   移動相流量:1.0毫升/分   檢測器:UV檢測器(波長254nm)   注入量:100微升   將由L乳酸單體而來的峰值面積設為SLLA ,將由D-乳酸單體而來的峰值面積設為SDLA 時,SLLA 及SDLA 係分別與L-乳酸單體的莫耳濃度MLLA 及D-乳酸單體的莫耳濃度MDLA 成正比,故而,將SLLA 與SDLA 中較大者的數值設為SMLA ,光學純度係依以下數式(9)計算出來。 (3) Optical purity of polylactic acid: Take 0.1 g of polylactic acid fiber (one bundle in the case of multifilament) that constitutes a spike-shaped piezoelectric element, add 1.0 mL of 5 mol / liter sodium hydroxide aqueous solution and Methanol 1.0mL, placed in a water bath shaker set at 65 ℃, until the polylactic acid becomes a homogeneous solution for about 30 minutes of hydrolysis, and then, add 0.25 mol / liter of sulfuric acid to the solution after the hydrolysis is completed and neutralize until Up to pH7, 0.1 mL of this decomposition solution was taken, diluted with 3 mL of mobile phase solution by high performance liquid chromatography (HPLC), and filtered with a membrane filter (0.45 μm). HPLC measurement of this adjusted solution was performed, and the ratio of L-lactic acid monomer and D-lactic acid monomer was quantified. When one polylactic acid fiber is less than 0.1 g, the usage amount of other solutions is adjusted according to the amount that can be taken, and the polylactic acid concentration of the sample solution supplied to the HPLC measurement is made into a range of 1/100 from the same as described above. <HPLC measurement conditions> Column: "SUMICHIRAL (registered trademark)" OA-5000 (4.6mmφ × 150mm) manufactured by SCAS (Japan), mobile phase: 1.0 millimolar / liter of copper sulfate aqueous solution Mobile phase flow rate: 1.0 ml / Min detector: UV detector (wavelength 254nm) Injection volume: 100 microliters When the peak area from L lactic acid monomer is S LLA and the peak area from D-lactic acid monomer is S DLA , S LLA and S DLA are respectively proportional to the molar concentration of L-lactic acid monomer M LLA and the molar concentration of D-lactic acid monomer M DLA , therefore, the larger of S LLA and S DLA is set as S MLA , the optical purity is calculated according to the following formula (9).

(聚乳酸之製造)   聚乳酸係依照以下之方法製造。   對L-Lactide(日本武藏野化學研究所(股)公司製,光學純度100%)100質量部,添加0.005質量部tin octylate,氮氛圍下,在帶攪拌葉片的反應機以180℃使之反應2小時,添加對tin octylate的1.2倍當量的磷酸之後,將在13.3Pa殘留的交酯(lactide)減壓去除,晶片化,得到聚-L-乳酸(PLLA1)。得到的PLLA1的質量平均分子量為15.2萬,玻璃轉移點(Tg)為55℃、熔點為175℃。(Manufacture of polylactic acid) polylactic acid is manufactured according to the following method. To L-Lactide (manufactured by Japan Musashino Chemical Research Institute Co., Ltd., 100% optical purity) 100 parts, add 0.005 parts of tin octylate, under a nitrogen atmosphere, react at 180 ℃ in a reactor with a stirring blade After 2 hours of addition of 1.2 times the equivalent of phosphoric acid to tin octylate, the lactide remaining at 13.3 Pa was removed under reduced pressure and wafered to obtain poly-L-lactic acid (PLLA1). The obtained PLLA1 had a mass average molecular weight of 152,000, a glass transition point (Tg) of 55 ° C, and a melting point of 175 ° C.

(壓電性纖維)   將在240℃熔融的PLLA1從24孔的蓋子以20g/min吐出,以887m/min取回。藉由將該未延伸複絲紗以80℃、延伸成2.3倍,以100℃熱固定處理而得到84dTex/24單絲的複絲一軸延伸紗PF1。將在240℃熔融的PLLA1從12孔的蓋子以8g/min吐出,以1050m/min取回。藉由將該未延伸複絲紗以80℃、延伸成2.3倍,以150℃熱固定處理,得到33dTex/12單絲的複絲一軸延伸紗PF2。將這些壓電性纖維PF1及PF2用作壓電性高分子。PF1及PF2之聚-L-乳酸結晶化度、聚-L-乳酸結晶配向度及光學純度係依照前述方法予以測定,如表1。(Piezoelectric fiber) The PLLA1 melted at 240 ° C was discharged from the 24-hole lid at 20 g / min and retrieved at 887 m / min. By stretching this undrawn multifilament yarn at 80 ° C, 2.3 times, and heat-fixed at 100 ° C, 84dTex / 24 monofilament multifilament uniaxially stretched yarn PF1 was obtained. The PLLA1 melted at 240 ° C was discharged from the 12-hole lid at 8 g / min and retrieved at 1050 m / min. By stretching this undrawn multifilament yarn at 80 ° C, 2.3 times, and heat-fixed at 150 ° C, a 33dTex / 12 monofilament multifilament uniaxially stretched yarn PF2 was obtained. These piezoelectric fibers PF1 and PF2 are used as piezoelectric polymers. The poly-L-lactic acid crystallinity, poly-L-lactic acid crystal orientation and optical purity of PF1 and PF2 were measured according to the aforementioned method, as shown in Table 1.

(導電性纖維)   使用日本Mitsufuji(股)公司製的鍍銀尼龍、商品名『AGposs』100d34f(CF1)作為導電性纖維B。CF1之電阻率係250Ω/m。   此外,使用日本Mitsufuji(股)公司製的鍍銀尼龍、商品名『AGposs』30d10f(CF2)作為導電性纖維B。CF2之導電性係950Ω/m。(Conductive fiber) As the conductive fiber B, silver-plated nylon manufactured by Japan Mitsufuji Co., Ltd., trade name "AGposs" 100d34f (CF1) was used. The resistivity of CF1 is 250Ω / m. In addition, as the conductive fiber B, silver-plated nylon manufactured by Japan Mitsufuji Co., Ltd., trade name "AGposs" 30d10f (CF2) was used. The conductivity of CF2 is 950Ω / m.

(絕緣性纖維)   分別將藉由在熔紡後將聚對苯二甲酸乙二醇酯延伸而製造出的84dTex/24單絲的延伸紗IF1、及33dTex/12單絲的延伸紗IF2作成絕緣性纖維。(Insulating fiber) Insulation of 84dTex / 24 monofilament extension yarn IF1 and 33dTex / 12 monofilament extension yarn IF2 produced by extending polyethylene terephthalate after melt spinning Sex fiber.

(穗帶狀壓電元件)   如圖14所示,藉由以導電性纖維CF1作為芯紗,8打圓穗帶製紐機之8根載體中,在朝Z搓捻方向編織的4根載體裝上前述的壓電性纖維PF1,在朝S搓捻方向編織的4根載體裝上前述的絕緣性纖維IF1並編織,而製作出在芯紗周圍朝Z搓捻方向把壓電性纖維PF1捲繞成螺旋狀之穗帶狀壓電元件1-1。在此,壓電性纖維對導電性纖維纖維軸CL之纏繞角度(配向角度θ)係形成45°。再者,藉由以穗帶狀壓電元件1-1作為芯紗,製紐機之8根載體中,在朝Z搓捻方向編織的4根載體及朝S搓捻方向編織的4根載體全部裝上前述的導電性纖維CF2並編織,而製作出以導電性纖維覆蓋穗帶狀壓電元件1-1的周圍之物,作成穗帶狀壓電元件1-2。將該穗帶狀壓電元件1-2,如前述,使用在圖11~18所示之實驗。(Spike-shaped piezoelectric element) As shown in Fig. 14, by using conductive fiber CF1 as the core yarn, among the 8 carriers of the 8-round round-tape machine, four carriers are woven in the Z twist direction The aforementioned piezoelectric fiber PF1 is installed, and the aforementioned insulating fiber IF1 is installed on the four carriers woven in the S twisting direction and woven to produce the piezoelectric fiber PF1 around the core yarn in the Z twisting direction Spiral ribbon piezoelectric element 1-1 wound into a spiral shape. Here, the winding angle (alignment angle θ) of the piezoelectric fiber to the conductive fiber fiber axis CL is 45 °. Furthermore, by using the spike-shaped piezoelectric element 1-1 as the core yarn, of the eight carriers of the button making machine, four carriers woven in the Z twist direction and four carriers woven in the S twist direction All the aforementioned conductive fibers CF2 were installed and woven, and the surroundings of the spike-shaped piezoelectric element 1-1 were covered with conductive fibers to make the spike-shaped piezoelectric element 1-2. The spike-shaped piezoelectric element 1-2 was used in the experiments shown in FIGS. 11 to 18 as described above.

其次,有關在本發明之感測系統被使用之壓電元件,調查壓電性高分子的配向角度θ及T1/T2之數值會帶給電性訊號對伸長變形之影響。Secondly, regarding the piezoelectric element used in the sensing system of the present invention, the value of the orientation angle θ and T1 / T2 of the piezoelectric polymer will be investigated to bring the influence of the electrical signal on the elongation deformation.

壓電元件之特性,係依照以下的方法來決定。   (1)壓電性高分子對中心軸的方向之配向角度θ   壓電性高分子對中心軸的方向之配向角度θ係從以下數式計算出來。   θ = arctan(2πRm/HP) (0°≦θ≦90°)   但是,Rm=2(Ro3 -Ri3 )/3(Ro2 -Ri2 ),亦即是以剖面積加重平均之穗帶狀壓電元件(或其他構造體)的半徑。螺旋間距HP、穗帶狀壓電元件(或其他構造體)所佔部分的外側半徑Ro及內側半徑Ri係如以下進行測定。   (1-1)穗帶狀壓電元件之場合,(作成穗帶狀壓電元件利用壓電性高分子以外的包覆之場合係因應必要而作成去除包覆並可以從側面觀察壓電性高分子的狀態的緣故)拍攝側面照片,於任意5處如圖15方式測定壓電性高分子的螺旋間距HP(μm),取平均值。此外,在穗帶狀壓電元件染入低黏性的瞬間接著劑「Aron Alpha EXTRA2000」(日本東亞合成(股)公司製)並使之固化後,在穗帶的長軸切出垂直的剖面並拍攝剖面照片,針對1張剖面照片如後述測定穗帶狀壓電元件所佔的部分之外側半徑Ro(μm)及內側半徑Ri(μm),針對別的任意5處剖面進行測定,取平均值。同時編織壓電性高分子與絕緣性高分子之場合,例如使用壓電性纖維與絕緣性纖維併絲之物之場合,或8打穗帶之4根纖維為壓電性高分子、餘下的4根纖維為絕緣性高分子之場合,在種種位置取剖面時,壓電性高分子存在之領域與絕緣性高分子存在之領域會互相替換,故而將壓電性高分子存在之領域與絕緣性高分子存在之領域加起來看作穗帶狀壓電元件所佔之部分。但是,針對絕緣性高分子並未與壓電性高分子同時編織之部分,則並不視為穗帶狀壓電元件之一部分。   針對外側半徑Ro與內側半徑Ri,如以下方式測定。如圖16(a)之剖面照片,定義壓電性構造體(由壓電性纖維A形成的鞘部2)所占之領域(以下記載為PSA),與位在PSA的中央部且並非PSA之領域(以下記載為CA)。將位於PSA的外側、不重疊在PSA的最小真圓的直徑,與不通過PSA的外側的(可以通過CA)最大真圓的直徑之平均值設為Ro(圖16(b))。此外,將位於CA的外側、不重疊在CA的最小真圓的直徑,與不通過CA的外側的最大真圓的直徑之平均值設為Ri(圖16(c))。   (1-2)包覆絲狀壓電元件之場合,係在覆蓋壓電性高分子時的捲繞速度為T回/m(每一包覆絲的長度之壓電性高分子的旋轉數)時,設定螺旋間距HP(μm)=1000000/T。此外,在包覆絲狀壓電元件染入低黏性的瞬間接著劑「Aron Alpha EXTRA2000」(日本東亞合成(股)公司製)並使之固化後,在穗帶的長軸切出垂直的剖面並拍攝剖面照片,針對1張剖面照片與穗帶狀壓電元件之場合同樣地測定包覆絲狀壓電元件所佔的部分之外側半徑Ro(μm)及內側半徑Ri(μm),針對別的任意5處剖面進行同樣的測定,取平均值。同時編織壓電性高分子與絕緣性高分子之場合,例如將壓電性纖維與絕緣性纖維併絲之物覆蓋之場合,或以壓電性纖維與絕緣性纖維不重疊之方式同時地覆蓋之場合,在種種位置取剖面時,壓電性高分子存在之領域與絕緣性高分子存在之領域會互相替換,故而將壓電性高分子存在之領域與絕緣性高分子存在之領域加起來視為包覆絲狀壓電元件所佔之部分。但是,針對絕緣性高分子並未與壓電性高分子同時覆蓋,亦即取哪個剖面而絕緣性高分子都經常是在壓電性高分子的內側或外側之部分,則並不視為包覆絲狀壓電元件之一部分。The characteristics of the piezoelectric element are determined according to the following method. (1) The orientation angle θ of the piezoelectric polymer to the direction of the central axis The orientation angle θ of the piezoelectric polymer to the direction of the central axis is calculated from the following equation. θ = arctan (2πRm / HP) (0 ° ≦ θ ≦ 90 °) However, Rm = 2 (Ro 3 -Ri 3 ) / 3 (Ro 2 -Ri 2 ), which means that the average spike zone is the cross-sectional area The radius of the piezoelectric element (or other structure). The spiral pitch HP, the outer radius Ro and the inner radius Ri of the portion occupied by the spike-shaped piezoelectric element (or other structure) are measured as follows. (1-1) In the case of a spike-shaped piezoelectric element, (when the spike-shaped piezoelectric element is coated with a coating other than piezoelectric polymers, the coating is removed as necessary and the piezoelectricity can be viewed from the side Because of the state of the polymer) side photographs were taken, and the helical pitch HP (μm) of the piezoelectric polymer was measured at any five locations as shown in FIG. 15 and the average value was taken. In addition, after the spike-shaped piezoelectric element was dyed with a low-viscosity instant adhesive "Aron Alpha EXTRA2000" (manufactured by Japan East Asia Synthetic Co., Ltd.) and cured, a vertical section was cut along the long axis of the spike Take a cross-sectional photo, measure the outer radius Ro (μm) and inner radius Ri (μm) of the portion occupied by the spike-shaped piezoelectric element for one cross-section photo as described later, and measure for any other 5 cross-sections, and take the average value. When the piezoelectric polymer and the insulating polymer are braided at the same time, for example, when the piezoelectric fiber and the insulating fiber are combined, or the 4 fibers of the 8 tacking tape are piezoelectric polymer, the remaining When the four fibers are insulating polymers, when the cross-sections are taken at various positions, the area where the piezoelectric polymer exists and the area where the insulating polymer exists are replaced with each other, so the area where the piezoelectric polymer exists is insulated from The area where the sexual polymer exists is taken together as the portion occupied by the spike-shaped piezoelectric element. However, the portion of the insulating polymer that is not woven with the piezoelectric polymer at the same time is not regarded as a part of the spike-shaped piezoelectric element. The outer radius Ro and the inner radius Ri are measured as follows. As shown in the cross-sectional photograph of FIG. 16 (a), the area occupied by the piezoelectric structure (the sheath portion 2 formed of the piezoelectric fiber A) (hereinafter referred to as PSA) is defined, and is located at the center of the PSA and is not the PSA Field (hereinafter referred to as CA). The average value of the diameter of the smallest true circle on the outside of the PSA that does not overlap the PSA and the diameter of the largest true circle that does not pass through the outside of the PSA (can pass CA) is set to Ro (FIG. 16 (b)). In addition, let the average value of the diameter of the smallest true circle outside the CA that does not overlap the CA and the diameter of the largest true circle that does not pass through the CA be Ri (FIG. 16 (c)). (1-2) When the filament-shaped piezoelectric element is coated, the winding speed when covering the piezoelectric polymer is T / m (the number of rotations of the piezoelectric polymer per length of the coated filament ), Set the spiral pitch HP (μm) = 1000000 / T. In addition, after coating the filament-shaped piezoelectric element with a low viscosity instant adhesive "Aron Alpha EXTRA2000" (manufactured by Japan East Asia Synthetic Co., Ltd.) and curing it, the vertical axis of the ear tape is cut out vertically Take a profile and take a profile photo. For one profile photo, measure the outer radius Ro (μm) and the inner radius Ri (μm) of the portion of the covered filament piezoelectric element in the same way as in the case of a spike-shaped piezoelectric element. Perform the same measurement on any other 5 cross sections and take the average value. When the piezoelectric polymer and the insulating polymer are braided at the same time, for example, when the piezoelectric fiber and the insulating fiber are laid together, or when the piezoelectric fiber and the insulating fiber are not overlapped In this case, when cross-sections are taken at various positions, the area where the piezoelectric polymer exists and the area where the insulating polymer exists are replaced with each other, so the area where the piezoelectric polymer exists and the area where the insulating polymer exists are added together It is regarded as the part covered by the wire-shaped piezoelectric element. However, if the insulating polymer is not covered with the piezoelectric polymer at the same time, that is, which cross section is taken and the insulating polymer is often inside or outside the piezoelectric polymer, it is not regarded as a package. Part of the wire-shaped piezoelectric element.

(2)電性訊號測定   在將電表(Keysight Technologies Inc.製 B2987A)中介著同軸電纜(芯:Hi極、屏蔽:Lo極)而接續在壓電元件的導電體之狀態下,對壓電元件邊進行以下2-1~5之任一之動作試驗邊以50m秒的間隔計測電流值。 (2-1)拉伸試驗   採用日本ORIENTEC(股)公司製萬能材料試驗機「Tensilon RTC-1225A」,在壓電元件的長條方向空出12cm間隔並將壓電元件用夾頭(chuck)抓住,將元件鬆弛之狀態設為0.0N,將在直到張力0.5N為止拉伸的狀態下的移位設為0mm,將以動作速度100mm/min拉伸直到1.2mm為止後、以0mm為止-100mm/min動作速度回復之動作反覆進行10回。 (2-2)扭曲試験   採用被設計成抓住壓電元件的2處夾頭中,一方的夾頭不進行扭曲動作而在壓電元件的長軸方向可自由移動之類的軌道上被設置並形成對壓電元件經常施加張力0.5N之狀態,另一方的夾頭則不朝壓電元件的長軸方向移動而進行扭曲動作之扭曲試驗裝置,在壓電元件的長條方向空出72mm間隔並將壓電元件用這些夾頭抓住,將以從元件的中央來看夾頭並朝順時針旋轉扭曲之方式以速度100°/s從0°起到45°為止旋轉之後,以速度-100°/s從45°起到0°為止旋轉之往復扭曲動作反覆進行10回。 (2-3)彎曲試驗   使用具備上部與下部之2個夾頭,下部夾頭被固定、上部夾頭位置於下部夾頭的上方72mm,上部夾頭移動過以連結2個夾頭的線段作為直徑之假想圓周上之試驗裝置,將壓電元件抓持在夾頭並固定,將在該圓周上形成上部夾頭在12時的位置、下部夾頭在6時的位置時,在形成使壓電元件朝9時方向凸出稍微撓曲之狀態後,使上部夾頭從12時的位置起經由該圓周上的1時、2時的位置到3時的位置以固定速度移動0.9秒後,直到12時的位置為止移動0.9秒之往復彎曲動作反覆進行10回。 (2-4)剪切試驗   利用將用第50號棉紗編織的平織布黏貼在表面之2枚剛直的金屬板,將壓電元件的中央部64mm的長度部分從上下水平地挾著(下部的金屬板被固定在台子),由上施加3.2N的垂直荷重,直接在形成金屬板表面的棉布與壓電元件之間不滑動之狀態,將上金屬板從0N起到1N荷重為止1秒朝壓電元件的長條方向拉伸之後,拉伸荷重1秒回復到0N為止之剪切動作反覆進行10回。 (2-5)推壓試驗   採用日本ORIENTEC(股)公司製萬能材料試驗機「Tensilon RTC-1225A」,將以水平靜置於剛直的金屬台上之壓電元件的中央部64mm的長度部分,利用被設置在上部的十字頭(crosshead)之剛直的金屬板水平地挾著壓電元件,從壓電元件往上部的金屬板之反力從0.01N起到20N為止施加0.6秒後將上部的十字頭降下並推壓,反力直到成為0.01N為止施加0.6秒後除壓之動作反覆進行10回。(2) Measurement of electrical signals When the electric meter (B2987A manufactured by Keysight Technologies Inc.) is connected to the electrical conductor of the piezoelectric element through a coaxial cable (core: Hi pole, shield: Lo pole), the piezoelectric element The current value was measured at intervals of 50 m seconds while performing any of the following operation tests 2-1 to 5. (2-1) Tensile test uses the universal material testing machine "Tensilon RTC-1225A" manufactured by Japan Orientec Co., Ltd., with a gap of 12 cm in the longitudinal direction of the piezoelectric element, and the piezoelectric element chuck (chuck) Grab, set the element to a slack state of 0.0N, set the displacement when stretched to a tension of 0.5N to 0mm, and stretch at an operating speed of 100mm / min to 1.2mm, then to 0mm The action of -100mm / min action speed recovery is repeated 10 times. (2-2) The twist test is made of two chucks designed to hold the piezoelectric element, and one of the chucks is installed on a track such as the piezoelectric element that can move freely in the long axis direction without twisting. It also forms a state where a tension of 0.5N is often applied to the piezoelectric element, and the other chuck does not move in the direction of the long axis of the piezoelectric element and twists. Hold the piezoelectric element with these chucks at intervals, and rotate it at a speed of 100 ° / s from 0 ° to 45 ° in a manner that the chuck is viewed from the center of the element and rotates and twists clockwise. The reciprocating twisting action of -100 ° / s rotating from 45 ° to 0 ° is repeated 10 times. (2-3) The bending test uses two chucks with an upper part and a lower part, the lower chuck is fixed, the upper chuck is positioned 72 mm above the lower chuck, and the upper chuck is moved through the line segment connecting the two chucks as The test device on the imaginary circumference of the diameter holds the piezoelectric element on the chuck and fixes it. When the upper chuck is at 12 o'clock and the lower chuck is at 6 o'clock, the pressure After the electrical component protrudes slightly in the direction of 9 o'clock, the upper chuck moves from the 1 o'clock position through the 1 o'clock, 2 o'clock position to 3 o'clock position on the circumference at a fixed speed for 0.9 seconds. The reciprocating bending motion that moves 0.9 seconds up to the 12 o'clock position is repeated 10 times. (2-4) For the shear test, two straight metal plates with plain woven cloth woven with No. 50 cotton yarn stuck to the surface are used to hold the central portion of the piezoelectric element at a length of 64 mm horizontally from above and below (the lower part The metal plate is fixed on the table), applying a vertical load of 3.2N from the top, directly sliding between the cotton cloth forming the surface of the metal plate and the piezoelectric element, the upper metal plate is loaded from 0N to 1N for 1 second After stretching in the longitudinal direction of the piezoelectric element, the shearing action until the tensile load returns to 0 N for 1 second is repeated 10 times. (2-5) For the pushing test, the universal material testing machine "Tensilon RTC-1225A" made by Japan Orientec Co., Ltd. was used, and the length of the central part of the piezoelectric element that was placed horizontally on a rigid metal table was 64mm. The rigid metal plate placed on the upper part of the crosshead (crosshead) is used to hold the piezoelectric element horizontally. The reaction force from the piezoelectric element to the upper metal plate is applied from 0.01N to 20N for 0.6 seconds. The crosshead is lowered and pressed, and the reaction force is applied for 0.6 seconds until it becomes 0.01 N. The pressure-removing operation is repeated 10 times.

(例A)   作為例A之試料,如圖14所示,藉由以導電性纖維CF1作為芯紗,8打圓穗帶製紐機之8根載體中,在朝Z搓捻方向編織的4根載體裝上前述的壓電性纖維PF1,在朝S搓捻方向編織的4根載體裝上前述的絕緣性纖維IF1並編織,而作成在芯紗周圍朝Z搓捻方向把壓電性纖維PF1捲繞成螺旋狀之穗帶狀壓電元件1-A。(Example A) As the sample of Example A, as shown in FIG. 14, by using the conductive fiber CF1 as the core yarn, 8 carriers of the 8-round round-belt binding machine were knitted in the direction of Z twist The root carrier is equipped with the aforementioned piezoelectric fiber PF1, and the four carriers braided in the S twisting direction are fitted with the aforementioned insulating fiber IF1 and woven, so that the piezoelectric fiber is twisted in the Z twisting direction around the core yarn PF1 is wound into a spiral spike-shaped piezoelectric element 1-A.

(例B)   藉由以穗帶狀壓電元件1-A作為芯紗,製紐機之8根載體中,在朝Z搓捻方向編織的4根載體及朝S搓捻方向編織的4根載體全部裝上前述的導電性纖維CF2並編織,而製作出以導電性纖維覆蓋穗帶狀壓電元件1-A的周圍之物,作成穗帶狀壓電元件1-B。(Example B) By using the ribbon-shaped piezoelectric element 1-A as the core yarn, of the eight carriers of the button making machine, four carriers woven in the Z twist direction and four woven in the S twist direction All the carriers were loaded with the aforementioned conductive fibers CF2 and woven, and the surroundings of the spike-shaped piezoelectric elements 1-A were covered with conductive fibers to make the spike-shaped piezoelectric elements 1-B.

(例C、D)   除了變更PF1的纏繞速度以外,係與穗帶狀壓電元件1-A同樣作法,作成2根穗帶狀壓電元件,以這些穗帶狀壓電元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀壓電元件1-C及1-D。(Examples C and D) Except that the winding speed of PF1 was changed, two spike-shaped piezoelectric elements were prepared in the same manner as the spike-shaped piezoelectric elements 1-A, and these spike-shaped piezoelectric elements were used as core yarns. In the same manner as the spike-shaped piezoelectric element 1-B, an object covered with conductive fibers was fabricated to make spike-shaped piezoelectric elements 1-C and 1-D.

(例E~H)   藉由在製紐機之8根載體中,如表2,在朝Z搓捻方向及S搓捻方向編織的載體分別將PF1或IF1裝上並編織,在芯紗的周圍作成朝Z搓捻方向及S搓捻方向分別以指定比例把壓電性纖維PF1螺旋狀地捲繞之穗帶狀壓電元件,以這些穗帶狀壓電元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀壓電元件1-E~1-H。(Examples E to H) Put PF1 or IF1 on the eight carriers of the button making machine, as shown in Table 2, in the Z-twisting direction and S-twisting direction, and weave them separately. The surroundings are made into spike ribbon-shaped piezoelectric elements in which the piezoelectric fiber PF1 is spirally wound in the Z twisting direction and the S twisting direction at a specified ratio, and these spike ribbon-shaped piezoelectric elements are used as core yarns and the spike ribbons The piezoelectric element 1-B is similarly produced by covering it with conductive fibers, and made into spike-shaped piezoelectric elements 1-E to 1-H.

(例I)   除了取代PF1而使用PF2、取代IF1而使用IF2、調整纏繞速度以外,係與穗帶狀壓電元件1-A同樣作法作成穗帶狀壓電元件,以這穗帶狀壓電元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀壓電元件1-I。(Example I) Except for using PF2 instead of PF1, using IF2 instead of IF1, and adjusting the winding speed, the ribbon-shaped piezoelectric element was made in the same way as the spike-shaped piezoelectric element 1-A. The element was used as a core yarn, and similarly to the spike-shaped piezoelectric element 1-B, an object covered with conductive fibers was produced to make the spike-shaped piezoelectric element 1-I.

(例J)   除了取代PF2而使用IF2、取代IF2而使用PF2以外,係與穗帶狀壓電元件1-A同樣作法作成穗帶狀壓電元件,以這穗帶狀壓電元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀壓電元件1-J。(Example J) Except that PF2 is used instead of PF2, and PF2 is used instead of IF2, a spiked piezoelectric element is made in the same way as the spiked piezoelectric element 1-A, and this spiked piezoelectric element is used as the core yarn In the same manner as the spike-shaped piezoelectric element 1-B, an object covered with conductive fibers was produced to make the spike-shaped piezoelectric element 1-J.

(例K)   作成以CF1作為芯紗,在芯紗的周圍將PF1朝S搓捻方向以3000回/m之覆蓋回數纏繞,再在其外側將IF1朝Z搓捻方向以3000回/m之覆蓋回數纏繞,再在其外側將CF2朝S搓捻方向以3000回/m之覆蓋回數纏繞,進而在其外側將CF2朝Z搓捻方向以3000回/m之覆蓋回數纏繞,在芯紗的周圍朝S搓捻方向將壓電性纖維PF1螺旋狀地捲繞,再將外側用導電性纖維覆蓋之包覆紗狀壓電元件1-K。(Example K) Made CF1 as the core yarn, wrap PF1 around the core yarn in the direction of S twisting with a covering number of 3000 times / m, and then wrap IF1 on the outside in the direction of Z twisting with 3000 times / m Wrap the CF2 back, and then wrap CF2 in the S twisting direction with a wrap count of 3000 rounds / m on the outside, and then wrap CF2 in the Z twist direction with a wrap count of 3000 rounds / m on the outside, The piezoelectric fiber PF1 is spirally wound in the S twisting direction around the core yarn, and the outer side is coated with the conductive fiber to cover the yarn-shaped piezoelectric element 1-K.

(例L)   除了取代PF1而使用IF1以外,係與穗帶狀壓電元件1-A同樣作法作成穗帶狀壓電元件,以這穗帶狀元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀元件1-L。(Example L) Except for using IF1 instead of PF1, a spike-shaped piezoelectric element was made in the same way as the spike-shaped piezoelectric element 1-A, using this spike-shaped element as a core yarn, and a spike-shaped piezoelectric element 1-B Similarly, an object covered with conductive fibers was prepared to make a spike-shaped element 1-L.

(例M)   除了取代PF1而使用IF1以外,係與包覆絲狀壓電元件1-K同樣作法,作成包覆絲狀元件,作成包覆絲狀元件1-M。(Example M) Except for using IF1 instead of PF1, the coated wire-shaped element was prepared in the same manner as the coated wire-shaped piezoelectric element 1-K, and the coated wire-shaped element 1-M.

(例N)   除了取代IF1而使用PF1以外,係與穗帶狀壓電元件1-B同樣作法,作成穗帶狀壓電元件1-N。(Example N) Except that PF1 was used instead of IF1, the spike-shaped piezoelectric element 1-N was prepared in the same manner as the spike-shaped piezoelectric element 1-B.

(例O)   除了取代IF2而使用PF2以外,係與穗帶狀壓電元件1-I同樣作法,作成穗帶狀壓電元件1-O。(Example O) Except for using PF2 instead of IF2, the same method was used as the spike-shaped piezoelectric element 1-I, and the spike-shaped piezoelectric element 1-O was prepared.

(例P)   藉由以導電性纖維CF1作為芯紗,16打圓穗帶製紐機之16根載體中,在朝Z搓捻方向編織的8根載體裝上前述的壓電性纖維PF1、在朝S搓捻方向編織的8根載體裝上前述的絕緣性纖維IF1並編織,在芯紗的周圍作成朝Z搓捻方向把壓電性纖維PF1螺旋狀地捲繞之穗帶狀壓電元件,以這穗帶狀壓電元件作為芯紗,與穗帶狀壓電元件1-B同樣地製作出以導電性纖維覆蓋之物,作成穗帶狀壓電元件1-P。(Example P) With the conductive fiber CF1 as the core yarn, the above-mentioned piezoelectric fibers PF1 were mounted on the eight carriers woven in the Z twisting direction among the 16 carriers of the 16-round tape-making machine. The eight insulating carriers woven in the direction of S twisting are loaded with the aforementioned insulating fiber IF1 and woven, and a piezoelectric ribbon PF1 is spirally wound around the core yarn in the direction of Z twisting. For the element, using this spike-shaped piezoelectric element as a core yarn, an object covered with conductive fibers was produced in the same manner as the spike-shaped piezoelectric element 1-B, to make a spike-shaped piezoelectric element 1-P.

(例Q)   作成以CF1作為芯紗,在芯紗的周圍將PF1朝S搓捻方向以6000回/m之覆蓋回數纏繞,再在其外側將IF1朝Z搓捻方向以6000回/m之覆蓋回數纏繞,再在其外側將CF2朝S搓捻方向以3000回/m之覆蓋回數纏繞,進而在其外側將CF2朝Z搓捻方向以3000回/m之覆蓋回數纏繞,在芯紗的周圍朝S搓捻方向將壓電性纖維PF1螺旋狀地捲繞,再將外側用導電性纖維覆蓋之包覆紗狀壓電元件1-Q。(Example Q) Make CF1 as the core yarn, wrap PF1 around the core yarn in the direction of S twisting with a covering number of 6000 cycles / m, and then wrap IF1 on the outside in the direction of Z twisting with 6000 cycles / m Wrap the CF2 back, and then wrap CF2 in the S twisting direction with a wrap count of 3000 rounds / m on the outside, and then wrap CF2 in the Z twist direction with a wrap count of 3000 rounds / m on the outside, The piezoelectric fiber PF1 is spirally wound in the S twisting direction around the core yarn, and the outer side is coated with the conductive fiber to cover the yarn-shaped piezoelectric element 1-Q.

測定各壓電元件的Ri、Ro、HP,將計算出來的壓電性高分子對中心軸的方向之配向角度θ數值、及T1/T2數值顯示於表2。針對穗帶狀壓電元件,Ri及Ro,係在剖面將壓電性纖維與絕緣性纖維存在之領域合併而測定作為壓電元件所占之領域。針對包覆絲狀壓電元件,Ri及Ro,係在剖面將壓電性纖維與絕緣性纖維存在之領域合併而測定作為壓電元件所占之領域。此外,將各壓電元件切斷成15cm的長度,以芯的導電性纖維作為Hi極,以屏蔽周邊的金網或鞘的導電性纖維作為Lo極並接續在電表(Keysight Technologies Inc.製 B2987A),監控電流值。將拉伸試驗、扭曲試驗、彎曲試驗、剪切試驗及推壓試驗時的電流值顯示於表2。又,由於例L、M不含壓電性高分子,所以無法測定θ及T1/T2之數值。The Ri, Ro, and HP of each piezoelectric element were measured, and the calculated value of the orientation angle θ of the piezoelectric polymer to the direction of the central axis and the value of T1 / T2 are shown in Table 2. For spike-shaped piezoelectric elements, Ri and Ro, the areas where piezoelectric fibers and insulating fibers exist are combined in a cross section to measure the areas occupied by piezoelectric elements. For the covered wire-shaped piezoelectric element, Ri and Ro, the areas where the piezoelectric fiber and the insulating fiber exist are merged in the cross section to measure the area occupied by the piezoelectric element. In addition, each piezoelectric element was cut to a length of 15 cm, and the conductive fiber of the core was used as the Hi pole, and the conductive fiber shielding the surrounding gold mesh or sheath was used as the Lo pole and connected to an electric meter (B2987A manufactured by Keysight Technologies Inc.) To monitor the current value. The current values at the time of tensile test, torsion test, bending test, shear test and pushing test are shown in Table 2. In addition, since Examples L and M do not contain piezoelectric polymers, the values of θ and T1 / T2 cannot be measured.

由表2的結果,當壓電性高分子對中心軸的方向之配向角度θ為15°以上75°以下,T1/T2數值為0以上0.8以下時,對於拉伸動作(伸長變形)會發生大的訊號,對拉伸以外的動作則不會發生大的訊號,可知是會對拉伸動作選擇性地回應之元件。此外,例I跟J相比時,朝Z搓捻方向捲繞較多壓電性纖維之場合、與朝S方向捲繞較多壓電性纖維之場合相比時,拉伸試驗時的訊號的極性變成相反,捲繞方向會對應於訊號的極性。From the results in Table 2, when the orientation angle θ of the piezoelectric polymer to the direction of the central axis is 15 ° or more and 75 ° or less, and the T1 / T2 value is 0 or more and 0.8 or less, the stretching action (elongation deformation) occurs A large signal does not generate a large signal for actions other than stretching. It can be seen that it is an element that selectively responds to stretching actions. In addition, when Example I is compared with J, when more piezoelectric fibers are wound in the Z twisting direction, compared with when more piezoelectric fibers are wound in the S direction, the signal during the tensile test The polarity becomes reversed, and the winding direction will correspond to the polarity of the signal.

再者,表並未顯示出,在給例A~K之元件施予拉伸荷重時之訊號、與將拉伸荷重解除時之訊號相比時,由於會發生極性互逆且絕對值大致相同之訊號,所以可知這些元件適於拉伸荷重或位移之定量。另一方面,在給例N及O之元件施予拉伸荷重時之訊號、與將拉伸荷重解除時之訊號相比時,由於極性有發生互逆之場合也有相同之場合,所以可知這些元件並不適於拉伸荷重或位移之定量。此外,表並未顯示出,但可知例B之拉伸試驗時之雜訊水準係較低於例A之拉伸試驗時之雜訊水準,且在穗帶狀壓電元件的外側配置導電性纖維作為屏蔽之元件係可以減低雜訊。Furthermore, the table does not show that the signal when the tensile load is applied to the elements of Examples A to K is compared with the signal when the tensile load is released, because the polarity reversal occurs and the absolute values are approximately the same Signal, it can be seen that these components are suitable for quantifying tensile load or displacement. On the other hand, when the tensile load is applied to the elements of Examples N and O, compared with the signal when the tensile load is released, there are also cases where the polarity is reversed, so these are known. The element is not suitable for the quantification of tensile load or displacement. In addition, the table does not show, but it can be seen that the noise level during the tensile test of Example B is lower than that during the tensile test of Example A, and the conductivity is arranged outside the spike-shaped piezoelectric element Fiber as a shielding element can reduce noise.

1‧‧‧穗帶狀壓電元件1‧‧‧ Spike piezoelectric element

2‧‧‧鞘部2‧‧‧Sheath

3‧‧‧芯部3‧‧‧Core

5‧‧‧布帛狀壓電元件5‧‧‧Fabric piezoelectric element

6‧‧‧布帛6‧‧‧ cloth

6a‧‧‧布帛中央面6a‧‧‧Fabric central surface

7‧‧‧絕緣性纖維7‧‧‧Insulating fiber

8‧‧‧導電性纖維8‧‧‧ conductive fiber

10‧‧‧裝置10‧‧‧ installation

11‧‧‧壓電元件11‧‧‧ Piezoelectric element

12‧‧‧放大手段12‧‧‧Amplification

13‧‧‧輸出手段13‧‧‧Output means

14‧‧‧送訊手段14‧‧‧Communication

15‧‧‧比較演算手段15‧‧‧Comparative calculation method

101‧‧‧線狀壓電元件101‧‧‧Linear piezoelectric element

102‧‧‧訊號檢測部102‧‧‧Signal Detection Department

103‧‧‧演算處理部103‧‧‧Calculation Processing Department

104‧‧‧導電性纖維104‧‧‧ conductive fiber

201‧‧‧機械臂控制器201‧‧‧manipulator controller

202‧‧‧機械臂202‧‧‧Robot

500-1‧‧‧上衣500-1‧‧‧Top

500-2‧‧‧褲子500-2‧‧‧ pants

500-3‧‧‧手套500-3‧‧‧ gloves

1000‧‧‧感測系統1000‧‧‧sensing system

A‧‧‧壓電性纖維A‧‧‧Piezoelectric fiber

A’‧‧‧壓電性高分子A’‧‧‧ Piezoelectric polymer

B‧‧‧導電性纖維B‧‧‧conductive fiber

CL‧‧‧纖維軸CL‧‧‧ fiber shaft

α‧‧‧纏繞角度α‧‧‧Winding angle

圖1係顯示關於一實施形態之感測系統的基本構成之模式圖。 圖2係於本實施形態採用之線狀壓電元件的變形速度之說明圖。   圖3係顯示依照圖2所示之線狀壓電元件的伸長所形成之變形與訊號強度之關係圖,(A)係顯示變形速度與訊號強度(電流值)之關係,(B)係顯示變形部分的位置與訊號強度(電流值)之關係。   圖4係顯示將依照一實施形態的感測系統組裝進入之上衣及褲子的前面(正面)之模式圖。   圖5係顯示圖4之上衣及褲子的背面之模式圖。   圖6係圖示將依照一實施形態的感測系統組裝進入之上衣的背面之實際照片。   圖7係圖示在上衣的肩及肘的附近配置線狀壓電元件之實際照片。   圖8係圖示在穿著圖7所示之上衣後彎曲肘之場合所產生之電性訊號,(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。   圖9係圖示在從穿著圖7所示之上衣後彎曲肘之狀態(圖8)回復到原來之場合所產生之電性訊號,(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。   圖10係圖示在穿著圖7所示之上衣後扭轉肘之場合所產生之電性訊號,(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。   圖11係圖示在從穿著圖7所示之上衣後扭轉肘之狀態(圖10)回復到原來之場合所產生之電性訊號,(A)係顯示於被設在上衣的肘之線狀壓電元件所產生之電性訊號,(B)係顯示於被設在上衣的前臂部及上臂部之線狀壓電元件所產生之電性訊號。   圖12係圖示將依照一實施形態的感測系統組裝進入之手套之實際照片,(A)係顯示穿戴手套之手背,(B)係顯示穿戴手套之手掌,(C)係顯示穿戴手套之手的一側面。   圖13係顯示關於接續機器人控制裝置之一實施形態之感測系統的基本構成之模式圖。   圖14係顯示關於實施形態之穗帶狀壓電元件的構成例之模式圖。   圖15係說明配向角度θ的計算方法之模式圖。   圖16(A)~(C)係關於實施形態之穗帶狀壓電元件之剖面照片。FIG. 1 is a schematic diagram showing the basic configuration of a sensing system according to an embodiment. FIG. 2 is an explanatory diagram of the deformation speed of the linear piezoelectric element used in this embodiment. FIG. 3 is a graph showing the relationship between the deformation and the signal strength formed by the extension of the linear piezoelectric element shown in FIG. 2, (A) shows the relationship between the deformation speed and the signal strength (current value), and (B) shows The relationship between the position of the deformed part and the signal strength (current value). FIG. 4 is a schematic diagram showing the assembly of the sensing system according to an embodiment into the front (front) of the top and trousers. FIG. 5 is a schematic diagram showing the back of the top and pants of FIG. 4. FIG. 6 is an actual photo showing the assembly of the sensing system according to an embodiment into the back of the top. FIG. 7 is a photo showing the actual arrangement of the linear piezoelectric elements near the shoulders and elbows of the jacket. 8 is a diagram showing electrical signals generated when the elbow is bent after wearing the top shown in FIG. 7, (A) is an electrical signal generated by a linear piezoelectric element provided on the elbow of the top, (B) is an electrical signal generated by linear piezoelectric elements provided on the forearm and upper arm of the jacket. 9 is a diagram showing the electrical signal generated when the elbow is bent after wearing the top shown in FIG. 7 (FIG. 8) to the original situation, (A) is shown in the line shape of the elbow provided in the top The electrical signal generated by the piezoelectric element, (B), is displayed on the electrical signal generated by the linear piezoelectric elements provided on the forearm and upper arm of the jacket. 10 is a diagram showing the electrical signal generated when the elbow is twisted after wearing the top shown in FIG. 7, (A) is an electrical signal generated by a linear piezoelectric element provided on the elbow of the top, (B) is an electrical signal generated by linear piezoelectric elements provided on the forearm and upper arm of the jacket. Fig. 11 shows the electrical signal generated when the elbow is twisted after wearing the top shown in Fig. 7 (Fig. 10) and returned to the original occasion, (A) is shown in the line shape of the elbow provided in the top The electrical signal generated by the piezoelectric element, (B), is displayed on the electrical signal generated by the linear piezoelectric elements provided on the forearm and upper arm of the jacket. 12 is a diagram showing actual photos of gloves assembled according to an embodiment of the sensing system, (A) shows the back of the glove, (B) shows the palm of the glove, (C) shows the glove One side of the hand. FIG. 13 is a schematic diagram showing the basic configuration of a sensing system related to an embodiment of a connection robot control device. FIG. 14 is a schematic diagram showing a configuration example of the spike-shaped piezoelectric element according to the embodiment. FIG. 15 is a schematic diagram illustrating the calculation method of the alignment angle θ. FIG. 16 (A) to (C) are cross-sectional photographs of spike-shaped piezoelectric elements according to the embodiment.

Claims (8)

一種感測系統,其特徵為具備:   被配置於穿著在被測定體的衣物,因應於被施加的應力而產生電氣訊號的線狀壓電元件,且係主成分含有聚乳酸之線狀壓電元件、   檢測出在前述線狀壓電元件產生的電氣訊號之訊號檢測部、以及   根據前述訊號檢測部檢測出的電氣訊號,判斷前述衣物的變形的態樣之演算處理部。A sensing system characterized by: is a linear piezoelectric element that is arranged in clothing worn on the object to be measured, generates an electrical signal in response to applied stress, and is a linear piezoelectric element whose main component contains polylactic acid An element, a signal detection unit that detects the electrical signal generated by the linear piezoelectric element, and an arithmetic processing unit that determines the deformation of the clothing based on the electrical signal detected by the signal detection unit. 如申請專利範圍第1項之感測系統,其中   前述線狀壓電元件,被配置在對應於穿著前述衣物的被測定體的可變部位之前述衣物上的位置附近。A sensing system as claimed in item 1 of the patent application, wherein the linear piezoelectric element is arranged near a position on the clothing corresponding to a variable portion of the body to be measured wearing the clothing. 如申請專利範圍第1或2項之感測系統,其中   進而具備被配置於配置在前述衣物的前述線狀壓電元件的附近之前述衣物的一部分,藉由與穿著前述衣物的被測定體之間的相互作用產生電氣訊號的導電性纖維;   前述演算處理部,根據前述訊號檢測部檢測出的電氣訊號,與由前述導電性纖維產生的電氣訊號,判斷前述衣物的變形的態樣。A sensing system as claimed in item 1 or 2 of the patent application, which further includes a part of the clothing disposed near the linear piezoelectric element of the clothing, and the measurement object wearing the clothing Conductive fibers that generate electrical signals through interaction between them; The calculation processing section determines the deformation of the clothes based on the electrical signals detected by the signal detection section and the electrical signals generated by the conductive fibers. 如申請專利範圍第1~3項中任一項之感測系統,其中   前述線狀壓電元件藉由伸長變形輸出電氣訊號。The sensing system according to any one of the items 1 to 3 of the patent application scope, wherein the linear piezoelectric element outputs an electrical signal by extension and deformation. 如申請專利範圍第1~4項中任一項之感測系統,其中   前述線狀壓電元件,為具有以導電性纖維形成的芯部,及以包覆前述芯部的方式以穗帶狀的壓電性纖維形成的鞘部之穗帶狀壓電元件。The sensing system according to any one of the items 1 to 4 of the patent application range, wherein the linear piezoelectric element has a core formed of conductive fibers, and is formed in the shape of a spike tape so as to cover the core The piezoelectric fiber is formed of a ribbon-shaped piezoelectric element in the sheath of the spike. 如申請專利範圍第5項之感測系統,其中   前述壓電性纖維,是包含使配向軸區分3軸時之壓電常數d14的絕對值具有0.1pC/N以上1000pC/N以下之值的結晶性高分子為主成分的壓電性高分子,前述壓電性高分子相對於藉由該壓電性高分子包覆的前述芯部的中心軸方向之配向角度為15°以上75°以下,前述壓電性高分子,包含含有以壓電常數d14之值為正的結晶性高分子為主成分的P體,與含有負的結晶性高分子為主成分的N體;針對前述中心軸具有1cm長的部分,在配向軸在Z撚線方向拉伸捲曲配置的該P體的質量為ZP,在配向軸在S撚線方向拉伸捲曲配置的該P體的質量為SP,在配向軸在Z撚線方向拉伸捲曲配置的該N體的質量為ZN,在配向軸在S撚線方向拉伸捲曲配置的該N體的質量為SN,而(ZP+SN)與(SP+ZN)之中較小者為T1,較大者為T2時,T1/T2之值為0以上0.8以下。A sensing system as claimed in item 5 of the patent application, wherein the piezoelectric fiber includes crystals in which the absolute value of the piezoelectric constant d14 when the alignment axis is divided into three axes has a value of 0.1 pC / N or more and 1000 pC / N or less The piezoelectric polymer is a piezoelectric polymer whose main component is, the alignment angle of the piezoelectric polymer with respect to the central axis direction of the core portion coated with the piezoelectric polymer is 15 ° or more and 75 ° or less, The piezoelectric polymer includes a P body containing a crystalline polymer having a positive piezoelectric constant d14 as a main component, and an N body containing a negative crystalline polymer as a main component; 1cm long part, the mass of the P body stretched and curled in the Z twist direction on the alignment axis is ZP, and the mass of the P body stretched and curled in the S twist direction on the alignment axis is SP, in the alignment axis The mass of the N body stretched and crimped in the Z twisting direction is ZN, the mass of the N body stretched and crimped in the S twisting direction on the alignment axis is SN, and (ZP + SN) and (SP + ZN ) The smaller of T1 and the larger of T2, the value of T1 / T2 is 0 or more and 0.8 or less. 一種衣物,其特徵為   具備:申請專利範圍第1~6項中任一項之感測系統。A piece of clothing characterized by having a sensing system according to any of items 1 to 6 of the patent application. 一種衣物系統,其特徵為   具備申請專利範圍第1~6項中任一項之感測系統,   前述線狀壓電元件及前述訊號檢測部,被配置於穿著在被測定體的衣物,前述演算處理部,設於與前述衣物不同個體之計算裝置內。A clothing system characterized by having a sensing system according to any one of claims 1 to 6, the linear piezoelectric element and the signal detection unit are arranged in clothing worn on the body to be measured, and the calculation The processing unit is provided in a computing device of an individual different from the aforementioned clothes.
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