TW201827798A - Pressure sensors and manufacturing method thereof - Google Patents

Pressure sensors and manufacturing method thereof Download PDF

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TW201827798A
TW201827798A TW106102337A TW106102337A TW201827798A TW 201827798 A TW201827798 A TW 201827798A TW 106102337 A TW106102337 A TW 106102337A TW 106102337 A TW106102337 A TW 106102337A TW 201827798 A TW201827798 A TW 201827798A
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oxide
pressure sensor
sensitive layer
pressure
thin film
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TW106102337A
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TWI645173B (en
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何羽軒
蔡明志
謝明宏
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華邦電子股份有限公司
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Abstract

A pressure sensor and a manufacturing method thereof are provided. The pressure sensor includes a thin film transistor (TFT) array and a pressure-sensitive layer covering the TFT array. The pressure-sensitive layer includes a plurality of one dimensional materials arranged on the same plane or two dimensional materials, and a plurality of insulating layers. The insulating layers and the one or two dimensional materials are alternately stacked so as to effectively enhance the pressure resolution.

Description

壓力感測器及其製造方法Pressure sensor and method of manufacturing same

本發明是有關於一種壓力感測技術,且特別是有關於一種壓力感測器及其製造方法。The present invention relates to a pressure sensing technique, and more particularly to a pressure sensor and a method of manufacturing the same.

在現有技術中,壓力感測器中的感壓層大多是在樹脂中混合導電粒子的方式形成,其是藉由在受壓時,厚度變薄,輸出電阻降低,而可以作為感壓層使用。但由於導電粒子的導電特性沒有方向性,所以除了受壓的區域會產生電阻變化之外,未受壓的區域也容易受到影響,導致壓力解析度變差。因此,如何改善壓力感測器的前述問題,使其能提供優異解析度乃當前重要研發的課題。In the prior art, the pressure sensitive layer in the pressure sensor is mostly formed by mixing conductive particles in a resin, which can be used as a pressure sensitive layer by reducing the thickness and reducing the output resistance when pressed. . However, since the conductive property of the conductive particles has no directivity, in addition to the resistance change in the pressed region, the uncompressed region is also easily affected, resulting in deterioration of the pressure resolution. Therefore, how to improve the aforementioned problems of the pressure sensor to provide excellent resolution is a subject of current important research and development.

本發明提供一種壓力感測器,能夠有效提高壓力解析度。The invention provides a pressure sensor capable of effectively improving pressure resolution.

本發明另提供一種壓力感測器,也能夠有效提高壓力解析度。The invention further provides a pressure sensor, which can also effectively improve the pressure resolution.

本發明又提供一種壓力感測器的製造方法,能製作出壓力解析度高的壓力感測器。The invention further provides a method for manufacturing a pressure sensor, which can produce a pressure sensor with high pressure resolution.

本發明的一種壓力感測器包括一薄膜電晶體陣列以及覆蓋所述薄膜電晶體陣列的一感壓層。其中,所述感壓層包括於相同平面排列的數個一維材料以及數層絕緣層,所述一維材料和所述絕緣層交替堆疊。A pressure sensor of the present invention includes a thin film transistor array and a pressure sensitive layer covering the thin film transistor array. Wherein, the pressure sensitive layer comprises a plurality of one-dimensional materials arranged in the same plane and a plurality of insulating layers, and the one-dimensional material and the insulating layer are alternately stacked.

本發明的另一種壓力感測器包括一薄膜電晶體陣列以及覆蓋所述薄膜電晶體陣列的一感壓層。其中,所述感壓層包括數個二維材料以及數層絕緣層,所述二維材料和所述絕緣層交替堆疊。Another pressure sensor of the present invention includes a thin film transistor array and a pressure sensitive layer covering the thin film transistor array. Wherein, the pressure sensitive layer comprises a plurality of two-dimensional materials and a plurality of insulating layers, and the two-dimensional material and the insulating layer are alternately stacked.

在本發明的上述實施例中,所述感壓層可為感應電阻式。In the above embodiment of the invention, the pressure sensitive layer may be of a sense resistor type.

在本發明的一實施例中,所述一維材料的直徑可為5nm-100nm。In an embodiment of the invention, the one-dimensional material may have a diameter of 5 nm to 100 nm.

在本發明的一實施例中,所述一維材料的長徑比可大於100。In an embodiment of the invention, the one-dimensional material may have an aspect ratio greater than 100.

在本發明的一實施例中,所述一維材料可包括金屬奈米線、奈米碳管或金屬氧化物半導體。In an embodiment of the invention, the one-dimensional material may comprise a metal nanowire, a carbon nanotube or a metal oxide semiconductor.

在本發明的一實施例中,所述金屬奈米線的金屬可包括金、銀或銅。In an embodiment of the invention, the metal of the metal nanowire may comprise gold, silver or copper.

在本發明的一實施例中,所述金屬氧化物半導體可包括氧化鋅、氧化鈦、氧化鎢、氧化鉬、氧化釩、氧化銅、氧化鎳、氧化鈷、氧化鐵或氧化錫。In an embodiment of the invention, the metal oxide semiconductor may include zinc oxide, titanium oxide, tungsten oxide, molybdenum oxide, vanadium oxide, copper oxide, nickel oxide, cobalt oxide, iron oxide or tin oxide.

在本發明的另一實施例中,所述二維材料可包括石墨烯氧化物或二硫化鉬。In another embodiment of the invention, the two-dimensional material may comprise graphene oxide or molybdenum disulfide.

本發明的壓力感測器的製造方法,包括形成一薄膜電晶體陣列以及在所述薄膜電晶體陣列上利用3D列印形成一感壓層。所述感壓層包括交替堆疊的數層絕緣層以及於相同平面排列的數個一維材料或數個二維材料。A method of fabricating a pressure sensor of the present invention includes forming a thin film transistor array and forming a pressure sensitive layer on the thin film transistor array by 3D printing. The pressure sensitive layer includes a plurality of alternating layers of insulating layers and a plurality of one-dimensional materials or a plurality of two-dimensional materials arranged in the same plane.

基於上述,本發明的壓力感測器通過在感壓層中設置交替堆疊的絕緣層以及於相同平面排列的一維材料或二維材料,使得感壓層內的導電結構成為具有方向性的導電層,來提高壓力感測器的壓力解析度。Based on the above, the pressure sensor of the present invention makes the conductive structure in the pressure sensitive layer become directional conductive by providing alternately stacked insulating layers and one-dimensional materials or two-dimensional materials arranged in the same plane in the pressure sensitive layer. Layer to increase the pressure resolution of the pressure sensor.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the invention will be apparent from the following description.

圖1是依照本發明的一實施例的一種壓力感測器的立體示意圖。1 is a perspective view of a pressure sensor in accordance with an embodiment of the present invention.

請參照圖1。本實施例的一種壓力感測器100包括薄膜電晶體陣列102以及覆蓋所述薄膜電晶體陣列102的感壓層104。感壓層104例如是感應電阻式。Please refer to Figure 1. A pressure sensor 100 of the present embodiment includes a thin film transistor array 102 and a pressure sensitive layer 104 covering the thin film transistor array 102. The pressure sensitive layer 104 is, for example, a sense resistor type.

以下,配合圖2A和圖2B示例性地說明圖1的壓力感測器的詳細結構及其實施方式。Hereinafter, the detailed structure of the pressure sensor of FIG. 1 and its embodiment will be exemplarily described with reference to FIGS. 2A and 2B.

請先參照圖2A。本實施例之壓力感測器100包括薄膜電晶體陣列102以及覆蓋所述薄膜電晶體陣列102的感壓層104。所述感壓層104包括於相同平面排列的數個一維材料206以及數層絕緣層208,所述一維材料206和所述絕緣層208交替堆疊,使得層與層之間的一維材料206不會互相接觸。Please refer to Figure 2A first. The pressure sensor 100 of the present embodiment includes a thin film transistor array 102 and a pressure sensitive layer 104 covering the thin film transistor array 102. The pressure sensitive layer 104 includes a plurality of one-dimensional materials 206 and a plurality of insulating layers 208 arranged in the same plane, and the one-dimensional material 206 and the insulating layer 208 are alternately stacked such that the one-dimensional material between the layers 206 will not touch each other.

在本實施例中,所述一維材料的直徑通常為5nm-100nm,較佳為20nm-80nm,更佳為40nm-60nm。此外,就良好導電性質而言,只要所述一維材料的長徑比(aspect ratio)大於100,所述一維材料的長度沒有特別限制。舉例來說,所述一維材料可包括金屬奈米線、奈米碳管或金屬氧化物半導體。金屬奈米線的金屬可包括金、銀或銅,但不限於此。所述金屬氧化物半導體可包括氧化鋅、氧化鈦、氧化鎢、氧化鉬、氧化釩、氧化銅、氧化鎳、氧化鈷、氧化鐵或氧化錫,但不限於此。In this embodiment, the one-dimensional material has a diameter of usually 5 nm to 100 nm, preferably 20 nm to 80 nm, more preferably 40 nm to 60 nm. Further, in terms of good electrical conductivity, the length of the one-dimensional material is not particularly limited as long as the aspect ratio of the one-dimensional material is more than 100. For example, the one-dimensional material may comprise a metal nanowire, a carbon nanotube, or a metal oxide semiconductor. The metal of the metal nanowire may include gold, silver or copper, but is not limited thereto. The metal oxide semiconductor may include zinc oxide, titanium oxide, tungsten oxide, molybdenum oxide, vanadium oxide, copper oxide, nickel oxide, cobalt oxide, iron oxide or tin oxide, but is not limited thereto.

在圖2A和圖2B中,為方便說明僅繪示出相鄰的兩個薄膜電晶體元件(第一薄膜電晶體元件210、第二薄膜電晶體元件212),但應理解,薄膜電晶體陣列可包含更多的薄膜電晶體元件,而非僅限於圖2A或圖2B中所顯示的數量。In FIGS. 2A and 2B, only two adjacent thin film transistor elements (first thin film transistor element 210, second thin film transistor element 212) are illustrated for convenience of explanation, but it should be understood that the thin film transistor array More thin film transistor elements may be included, and are not limited to the numbers shown in Figure 2A or Figure 2B.

在未施加壓力時,如圖2A所示,第一薄膜電晶體元件210上的和第二薄膜電晶體元件212上的一維材料206之間因為有絕緣層208隔開,電流難以在其間傳遞,所以呈現高電阻的狀態。當在第一薄膜電晶體元件210的區域施加壓力214時,如圖2B所示,第一薄膜電晶體元件210上的感壓層104因受壓而形變,使得一維材料206之間的距離縮短,電流容易在一維材料206之間傳遞,感壓層104的電阻下降。而第二薄膜電晶體元件212上的感壓層104雖然也因為壓力214而產生形變,但因為不是直接位於施力點上,故即使產生形變,但是具有方向性的一維材料206之間並不容易接觸,所以在遠離施力點的區域216的感壓層104仍維持高電阻。因此,相較於以導電粒子形成感壓層的現有技術,本發明能提供較佳的壓力解析度,可應用於指紋辨識、足壓感測之類的壓力圖像感測技術範疇,但不限於此。舉凡需要應用壓力感測的場合,均可使用本發明。When no pressure is applied, as shown in FIG. 2A, between the first thin film transistor element 210 and the one-dimensional material 206 on the second thin film transistor element 212 is separated by an insulating layer 208, and current is difficult to pass between them. , so it presents a state of high resistance. When a pressure 214 is applied to a region of the first thin film transistor element 210, as shown in FIG. 2B, the pressure sensitive layer 104 on the first thin film transistor element 210 is deformed by being pressed, such that the distance between the one-dimensional materials 206 Shortening, current is easily transferred between the one-dimensional materials 206, and the resistance of the pressure-sensitive layer 104 is lowered. While the pressure-sensitive layer 104 on the second thin film transistor element 212 is also deformed by the pressure 214, since it is not directly at the point of application, even if deformation occurs, the one-dimensional material 206 having the directivity is It is not easy to contact, so the pressure sensitive layer 104 in the region 216 away from the point of application still maintains high resistance. Therefore, the present invention can provide a better pressure resolution than the prior art in which the pressure sensitive layer is formed by the conductive particles, and can be applied to the pressure image sensing technology such as fingerprint recognition and foot pressure sensing, but not Limited to this. The invention can be used wherever pressure sensing is desired.

此外,上述一維材料206也可改以二維材料(未繪示)取代,使二維材料和絕緣層208交替堆疊而成感應層。所述二維材料可列舉包括石墨烯氧化物(graphene oxide)或二硫化鉬(MoS2 )等,但不限於此。由於二維材料的結構也能藉由和絕緣層208交替堆疊,使得層與層之間的二維材料不會互相接觸,所以其實施方式與一維材料相似,故不再贅述。In addition, the one-dimensional material 206 may be replaced by a two-dimensional material (not shown), and the two-dimensional material and the insulating layer 208 are alternately stacked to form a sensing layer. The two-dimensional material may include, but is not limited to, graphene oxide or molybdenum disulfide (MoS 2 ). Since the structure of the two-dimensional material can also be alternately stacked with the insulating layer 208 so that the two-dimensional materials between the layers do not contact each other, the embodiment thereof is similar to the one-dimensional material, and therefore will not be described again.

以下,將說明依照本發明的另一實施例的壓力感測器的製造方法,請參照圖3。Hereinafter, a method of manufacturing a pressure sensor according to another embodiment of the present invention will be described. Please refer to FIG. 3.

首先,進行步驟300,形成一薄膜電晶體陣列(TFT array),且形成薄膜電晶體陣列的方式可採用任何已知的製造方法。First, step 300 is performed to form a thin film transistor array, and the manner of forming the thin film transistor array can be any known manufacturing method.

然後,進行步驟302,在所述薄膜電晶體陣列上利用3D列印形成一感壓層,所述感壓層包括交替堆疊的數層絕緣層以及於相同平面排列的一維材料或二維材料,且所述一維材料與所述二維材料可參照上述各實施例所記載,故不再贅述。在感壓層為一維材料的情況下,是在薄膜電晶體陣列上交替形成絕緣層與一維材料,所以層與層的一維材料之間均未受壓的情況下是不會接觸的,並於感壓層受到一定程度的壓力後,才能讓電流在一維材料之間傳遞,而改變(降低)壓力感測器的電阻。Then, step 302 is performed to form a pressure sensitive layer on the thin film transistor array by 3D printing, the pressure sensitive layer comprising a plurality of alternating layers of insulating layers and one-dimensional materials or two-dimensional materials arranged in the same plane. The one-dimensional material and the two-dimensional material can be referred to the above embodiments, and therefore will not be described again. In the case where the pressure sensitive layer is a one-dimensional material, the insulating layer and the one-dimensional material are alternately formed on the thin film transistor array, so that the one-dimensional material of the layer and the layer are not pressed without being contacted. And after the pressure layer is subjected to a certain degree of pressure, the current can be transferred between the one-dimensional materials, and the resistance of the pressure sensor is changed (reduced).

而在感壓層包括二維材料的情況下,同樣是在薄膜電晶體陣列上交替形成絕緣層與二維材料,其結果也與一維材料所構成的感壓層一樣。In the case where the pressure sensitive layer includes a two-dimensional material, the insulating layer and the two-dimensional material are alternately formed on the thin film transistor array, and the result is also the same as the pressure sensitive layer formed by the one-dimensional material.

另外,形成感壓層的方法除3D列印之外,亦可採用網版印刷、凹版(gravure)印刷等適用於捲對捲(roll to roll)的製造方法。Further, the method of forming the pressure-sensitive layer may be a roll-to-roll manufacturing method such as screen printing or gravure printing in addition to 3D printing.

綜上所述,本發明的壓力感測器通過在感壓層中將於相同平面排列的數個一維材料與絕緣層交替堆疊,或者將數個二維材料與絕緣層交替堆疊,能夠提高壓力感測器的壓力解析度。這是因為一維材料之間或二維材料之間的電流傳遞具有方向性,所以相較於以導電粒子形成感壓層的現有技術,本發明能提供較佳的壓力解析度。In summary, the pressure sensor of the present invention can be improved by alternately stacking a plurality of one-dimensional materials and insulating layers arranged in the same plane in the pressure sensitive layer or by alternately stacking a plurality of two-dimensional materials and an insulating layer. Pressure resolution of the pressure sensor. This is because the current transfer between the one-dimensional materials or between the two-dimensional materials is directional, so the present invention can provide a better pressure resolution than the prior art in which the pressure-sensitive layers are formed of conductive particles.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.

100‧‧‧壓力感測器100‧‧‧pressure sensor

102‧‧‧薄膜電晶體陣列102‧‧‧Thin-film array

104‧‧‧感壓層104‧‧‧Inductive layer

206‧‧‧一維材料206‧‧‧One-dimensional materials

208‧‧‧絕緣層208‧‧‧Insulation

210‧‧‧第一薄膜電晶體元件210‧‧‧First Thin Film Silicon Element

212‧‧‧第二薄膜電晶體元件212‧‧‧Second thin film transistor components

214‧‧‧壓力214‧‧‧ Pressure

216‧‧‧區域216‧‧‧ area

300、302‧‧‧步驟300, 302‧‧‧ steps

圖1是依照本發明的一實施例的一種壓力感測器的立體示意圖。 圖2A是圖1的壓力感測器,於未受壓情況下的剖面示意圖。 圖2B是圖2A的壓力感測器,於受壓情況下的剖面示意圖。 圖3是依照本發明的另一實施例的一種壓力感測器的製造流程步驟圖。1 is a perspective view of a pressure sensor in accordance with an embodiment of the present invention. 2A is a schematic cross-sectional view of the pressure sensor of FIG. 1 in an uncompressed condition. 2B is a schematic cross-sectional view of the pressure sensor of FIG. 2A under pressure. 3 is a flow chart showing the manufacturing process of a pressure sensor in accordance with another embodiment of the present invention.

Claims (15)

一種壓力感測器,包括: 一薄膜電晶體陣列;以及 一感壓層,覆蓋所述薄膜電晶體陣列,其中所述感壓層包括於相同平面排列的多數個一維材料以及多數層絕緣層,所述一維材料和所述絕緣層交替堆疊。A pressure sensor comprising: a thin film transistor array; and a pressure sensitive layer covering the thin film transistor array, wherein the pressure sensitive layer comprises a plurality of one-dimensional materials arranged in the same plane and a plurality of insulating layers The one-dimensional material and the insulating layer are alternately stacked. 如申請專利範圍第1項所述的壓力感測器,其中所述感壓層為感應電阻式。The pressure sensor of claim 1, wherein the pressure sensitive layer is of a sense resistor type. 如申請專利範圍第1項所述的壓力感測器,其中所述一維材料的直徑為5nm-100nm。The pressure sensor of claim 1, wherein the one-dimensional material has a diameter of 5 nm to 100 nm. 如申請專利範圍第1項所述的壓力感測器,其中所述一維材料的長徑比大於100。The pressure sensor of claim 1, wherein the one-dimensional material has an aspect ratio greater than 100. 如申請專利範圍第1項所述的壓力感測器,其中所述一維材料包括金屬奈米線、奈米碳管或金屬氧化物半導體。The pressure sensor of claim 1, wherein the one-dimensional material comprises a metal nanowire, a carbon nanotube or a metal oxide semiconductor. 如申請專利範圍第5項所述的壓力感測器,其中所述金屬奈米線的金屬包括金、銀或銅。The pressure sensor of claim 5, wherein the metal of the metal nanowire comprises gold, silver or copper. 如申請專利範圍第5項所述的壓力感測器,其中所述金屬氧化物半導體包括氧化鋅、氧化鈦、氧化鎢、氧化鉬、氧化釩、氧化銅、氧化鎳、氧化鈷、氧化鐵或氧化錫。The pressure sensor according to claim 5, wherein the metal oxide semiconductor comprises zinc oxide, titanium oxide, tungsten oxide, molybdenum oxide, vanadium oxide, copper oxide, nickel oxide, cobalt oxide, iron oxide or Tin oxide. 一種壓力感測器,包括: 一薄膜電晶體陣列;以及 一感壓層,覆蓋所述薄膜電晶體陣列,其中所述感壓層包括多數個二維材料以及多數層絕緣層,所述二維材料和所述絕緣層交替堆疊。A pressure sensor comprising: a thin film transistor array; and a pressure sensitive layer covering the thin film transistor array, wherein the pressure sensitive layer comprises a plurality of two-dimensional materials and a plurality of insulating layers, the two-dimensional The material and the insulating layer are alternately stacked. 如申請專利範圍第8項所述的壓力感測器,其中所述二維材料包括石墨烯氧化物或二硫化鉬。The pressure sensor of claim 8, wherein the two-dimensional material comprises graphene oxide or molybdenum disulfide. 如申請專利範圍第8項所述的壓力感測器,其中所述感壓層為感應電阻式。The pressure sensor of claim 8, wherein the pressure sensitive layer is of a sense resistor type. 一種壓力感測器的製造方法,包括: 形成一薄膜電晶體陣列;以及 在所述薄膜電晶體陣列上利用3D列印形成一感壓層,所述感壓層包括交替堆疊的多數層絕緣層以及於相同平面排列的多數個一維材料或多數個二維材料。A method of manufacturing a pressure sensor, comprising: forming a thin film transistor array; and forming a pressure sensitive layer on the thin film transistor array by 3D printing, the pressure sensitive layer comprising a plurality of insulating layers stacked alternately And a plurality of one-dimensional materials or a plurality of two-dimensional materials arranged in the same plane. 如申請專利範圍第11項所述的壓力感測器的製造方法,其中所述一維材料的直徑為5nm-100nm。The method of manufacturing a pressure sensor according to claim 11, wherein the one-dimensional material has a diameter of 5 nm to 100 nm. 如申請專利範圍第11項所述的壓力感測器的製造方法,其中所述一維材料的長徑比大於100。The method of manufacturing a pressure sensor according to claim 11, wherein the one-dimensional material has an aspect ratio of more than 100. 如申請專利範圍第11項所述的壓力感測器的製造方法,其中所述一維材料包括金屬奈米線、奈米碳管或金屬氧化物半導體,所述二維材料包括石墨烯氧化物或二硫化鉬。The method of manufacturing a pressure sensor according to claim 11, wherein the one-dimensional material comprises a metal nanowire, a carbon nanotube or a metal oxide semiconductor, and the two-dimensional material comprises a graphene oxide. Or molybdenum disulfide. 如申請專利範圍第14項所述的壓力感測器的製造方法,其中所述金屬奈米線的金屬包括金、銀或銅,所述金屬氧化物半導體包括氧化鋅、氧化鈦、氧化鎢、氧化鉬、氧化釩、氧化銅、氧化鎳、氧化鈷、氧化鐵或氧化錫。The method of manufacturing a pressure sensor according to claim 14, wherein the metal of the metal nanowire comprises gold, silver or copper, and the metal oxide semiconductor comprises zinc oxide, titanium oxide, tungsten oxide, Molybdenum oxide, vanadium oxide, copper oxide, nickel oxide, cobalt oxide, iron oxide or tin oxide.
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