TW201740919A - Hair cleansing agent composition through which moist hair can be dried in a short period of time after shampooing the hair - Google Patents

Abstract

The present invention provides a hair cleansing composition, which can dry moist hair in a short period of time after shampooing the hair, and in addition, the hair does not tangle easily during a rinse, has a smooth feeling, is not sticky when being dried and tidy after being dried. A hair cleansing composition comprises component (A): a cationic hydroxypropyl cellulose having specific constituents, component (B): a cationic polymer other than the component (A), component (C): a sulfate surfactant, component (D): a carboxylate surfactant, and water. The mass ratio ((C)/(A)) of the content of the component (C) to the content of the component (A), and the mass ratio ((C)/(D)) of the content of the component (C) to the content of the component (D) are each in a specific range.

Description

Hair cleanser composition

The present invention is directed to a hair cleanser composition.

Hair may be damaged by heat treatment such as chemical treatment of hair dyes or perm agents, hair dryers or hair irons. In the damaged hair, the friction between the hairs becomes large, so that entanglement tends to occur, and the surface of the hair is physically damaged by entanglement, thereby causing further hair damage. In order to reduce the physical damage during such hair care behavior and to eliminate the trouble caused by the damage, there is a case where a cationic polymer or an oil agent such as polyoxymethylene is formulated in the hair cleansing agent. However, if the blending amount is excessively increased in order to enhance the blending effect, the hair after drying may be sticky or the feeling of use may be lowered. Therefore, it has been proposed to achieve a non-stickiness after drying and to balance the feeling of use by formulating a specific cationized hydroxypropylcellulose. For example, the combination of the cationized hydroxypropylcellulose and one or more selected from the group consisting of cationized guar gum and cationized hydroxyethylcellulose is described in Patent Document 1 (Japanese Laid-Open Patent Publication No. 2012-232945). The technique used for the compound discloses a hair cosmetic which is excellent in the finger fluency or softness of the hair during rinsing, the finger patency of the dried hair, the feeling of uniformity, the softness, and the strong feeling. Further, in Patent Document 2 (Japanese Laid-Open Patent Publication No. 2012-246288), there is described a technique relating to an aqueous hair cleansing agent comprising an anionic surfactant, a specific cationized hydroxypropylcellulose. a specific organic solvent and a specific organic carboxylic acid, and the pH is within a specific range. Further, according to the aqueous hair cleansing agent described in this document, even if the hair is damaged, it is possible to effectively suppress the entanglement of the hair after drying and the fluffiness of the hair, and impart a strong feeling to the hair. Further, in Patent Document 3 (International Publication No. 2011/059063), as a technique for applying a hair cosmetic which is not sticky after use and which imparts excellent finger fluency, wrap feeling, and tidyness to hair, A hair cosmetic comprising a surfactant and a specific cationized hydroxypropyl cellulose. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open Publication No. 2012-246945 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2012-246288 (Patent Document 3) International Publication No. 2011/059063

[Problems to be Solved by the Invention] It is said that hair which is hydrophilized by damage is difficult to dry after shampooing, and drying by a hair dryer or the like takes a long time and becomes a physical burden on the consumer. Moreover, the oil agent or polymer formulated for the purpose of damage care is a cause of stickiness in the drying of the hair dryer, and the wet damaged hair is easily entangled due to the stickiness, and the pulling occurred in the drying of the hair dryer further accumulates damage. And become the psychological burden of consumers. However, in the above Patent Documents 1 to 3, the drying speed of the wet hair after shampooing is not mentioned at all. Also, there is no mention of the presence or absence of stickiness of the hair when drying the wet hair. Further, according to the technique described in the above documents, the entanglement and uniformity of the hair after drying are improved, but there is still room for improvement in the entanglement of the hair during rinsing or the uniformity of the hair after drying. Accordingly, the present invention relates to a hair cleansing composition which can dry moist hair after shampooing in a short time, and which is not easily entangled during washing, has a smooth hand feeling, and is not sticky during drying. After drying, the hair can be neat. [Technical means for solving the problem] The present invention provides a hair cleansing composition comprising the following components (A), (B), (C), (D) and water, and the content of the above component (C) is relative to the above The mass ratio ((C)/(A)) of the content of the component (A) is 26 or more and 20,000 or less, and the mass ratio of the content of the above component (C) to the content of the above component (D) ((C)/ (D)) is 4 or more and 200 or less. (A) has a main chain derived from anhydroglucose represented by the following formula (1), and has a degree of substitution of 0.01 or more and 2.9 or less by cationized ethoxy group, and a degree of substitution of 0.1 by using propenyloxy group. Cationic hydroxypropylcellulose (B) above 4.0 and below, cationic polymer other than component (A) (C) sulfate type surfactant (D) carboxylate type surfactant [Chemical Formula 1] (In the above formula (1), R ¹ , R ² and R ³ each independently represent a substituent represented by the following formula (2) or (3), and n represents an average degree of polymerization of the above-described anhydroglucose, and It is 50 or more and 5000 or less) [Chemical 2] (In the above formulae (2) and (3), one of Y ¹ and Y ² represents a hydrogen atom, the other represents a cationic group represented by the following formula (4), and PO represents a propoxyl group. ;p represents the number of cationized ethoxy groups (-CH(Y ¹ )-CH(Y ² )-O-), and q represents the number of exopropoxy groups (-PO-), respectively 0 or a positive integer; Wherein, all of p and q in R ¹ , R ² and R ³ are not simultaneously 0; and, in the case where neither p nor q is 0, the above-mentioned cationized ethoxy group and the above-mentioned propoxy group The order of addition is arbitrary, and when neither p nor q is 0 and any of p and q or both are 2 or more, it may be any of block bonding and random bonding. 3] (In the above formula (4), R ⁴ , R ⁵ and R ⁶ each independently represent a linear or branched alkyl group having 1 or more and 3 or less carbon atoms, and X ^- represents an anionic group) Further, the present invention A method of cleaning a hair comprising applying the above-described hair cleansing composition of the present invention to hair and rinsing with water is provided. [Effects of the Invention] According to the present invention, a hair cleansing composition can be obtained which can dry moist hair after shampooing in a short time, and is not easily entangled during washing, has a smooth hand feeling, and is in a dry state. It is not sticky and can make hair tidy after drying.

Hereinafter, embodiments of the present invention will be described with reference to specific examples of the respective components. Further, each component may be used singly or in combination of two or more. The hair cleansing composition of the present embodiment contains the following components (A) to (D) and water. (Component (A)) The component (A) has a main chain derived from anhydroglucose represented by the formula (1), and the degree of substitution by the cationized ethoxy group is 0.01 or more and 2.9 or less. The cationized hydroxypropylcellulose (hereinafter also referred to as "C-HPC") having a degree of substitution of 0.1 or more and 4.0 or less. [Chemical 4](in the above formula (1), R¹ , R² And R³ Each of the substituents represented by the following formula (2) or (3) is independently represented, and n represents the average degree of polymerization of the above-described anhydroglucose, and is 50 or more and 5,000 or less).(In the above formulas (2) and (3), Y¹ And Y² One represents a hydrogen atom, the other represents a cationic group represented by the following formula (4), PO represents a propenoxy group, and p represents a cationized ethoxy group (-CH (Y)¹ )-CH(Y² The number of -O-), q represents the number of exopropoxy groups (-PO-), respectively 0 or a positive integer; where R¹ , R² And R³ All p and q in the middle are not 0 at the same time; in the case where neither p nor q is 0, the addition order of the above-mentioned cationized ethoxy group and the above-mentioned propenyloxy group is arbitrary, and further, in p and When q is not 0 and either or both of p and q are 2 or more, it may be either a block bond or a random bond.(In the above formula (4), R⁴ , R⁵ And R⁶ Each of which independently represents a linear or branched alkyl group having a carbon number of 1 or more and 3 or less, X^- (Anionic group) (The main chain derived from anhydroglucose represented by the formula (1)) As shown in the above formula (1), the component (A) has a main chain derived from anhydroglucose. In the general formula (1), R¹ , R² And R³ Substituents independently represented by the formula (2) or (3), R¹ , R² And R³ Can be the same or different. Also, n R¹ , n R² And n R³ They can be the same or different. Moreover, from the viewpoint of improving the quick-drying effect of the hair, suppressing the entanglement of the hair during rinsing, achieving the smooth hand feeling, suppressing the stickiness during drying, and improving the uniformity of the hair after drying, The average degree of polymerization n of the formula (1) is 50 or more, preferably 100 or more, more preferably 400 or more, still more preferably 700 or more, further preferably 5,000 or less, preferably 2,000 or less, more preferably 1300. the following. Here, the average degree of polymerization is a viscosity average degree of polymerization measured by a copper-ammonia method, and is specifically calculated by the method described in JP-A-2012-232942. (Substituent represented by the formula (2) or (3)) Component (A) is R in the formula (1)¹ , R² Or R³ It has a cationized ethoxy group and a propoxy group. R¹ , R² Or R³ Each is independently a substituent represented by the formula (2) or (3). In the general formulae (2) and (3), Y¹ And Y² One is a hydrogen atom, the other is a cationic group represented by the formula (4), and PO is a propionyloxy group. p represents a cationized ethoxy group (-CH(Y) contained in the formula (2) or (3)¹ )-CH(Y² The number of -O-) is 0 or a positive number. From the viewpoint of improving the ease of production of the component (A), p is preferably 0 or 1. q represents the number of exopropoxy groups (-PO-) contained in the formula (2) or (3), and is 0 or a positive number. From the viewpoint of improving the ease of production of the component (A), q is preferably 0 or more and 4 or less, more preferably 0 or more and 2 or less, still more preferably 0 or 1. In the case where a plurality of substituents represented by the formula (2) or (3) are present in the C-HPC molecule, the values of p and q may be different between the substituents. The total of p and q is preferably 1 or more and 5 or less, more preferably 1 or more and 4 or less, and still more preferably 1 or more and 3, from the viewpoint of improving the ease of production of the component (A). The following number is further preferably 1 or 2. In the general formula (2) or (3), when both p and q are not 0, the order of addition of the cationized ethoxy group and the propenyloxy group is arbitrary, but the production of the component (A) is improved. From the viewpoint of efficiency, the order described in the formula (3) is preferred. Further, when neither p nor q is 0 and either or both of p and q are 2 or more, the bonding of the cationized ethoxy group and the propenyloxy group may be block bonding and no Any of the bonding bonds is preferably a block bond from the viewpoint of improving the ease of production of the component (A). Also, R¹ , R² And R³ All p and q in the middle will not be 0 at the same time. That is, at n R¹ , n R² , n R³ In at least one of the formula (2) or (3), p is not 0, and at least one of the formula (2) or (3) is not 0. (Cation group represented by the formula (4)) Y in the formula (2) or (3)¹ , Y² The cationic group has a structure represented by the above formula (4). In the general formula (4), R⁴ , R⁵ And R⁶ Each of them is a linear or branched alkyl group having 1 or more and 3 or less carbon atoms, and specific examples thereof include a methyl group, an ethyl group, a n-propyl group, and an isopropyl group. Among these, from the viewpoint of improving the water solubility of C-HPC, a methyl group or an ethyl group is preferred, and a methyl group is more preferred. In the general formula (4), X^- An anionic group representing a counter ion as an ammonium group. X^- There is no limitation as long as it is an anionic group. As X^- Specific examples thereof include an alkyl sulfate ion, a sulfate ion, a phosphate ion, an alkyl carbonate ion, and a halide ion. Among these, from the viewpoint of facilitating the production of C-HPC, halide ions are preferred. Examples of the halide ion include a fluoride ion, a chloride ion, a bromide ion, and an iodide ion. From the viewpoint of improving the water solubility and chemical stability of the C-HPC, a chloride ion or a bromide ion is preferred. More preferably, it is a chloride ion. In the C-HPC represented by the formula (1), the viewpoint of improving the foaming property at the time of cleaning, the viewpoint of improving the quick-drying effect of the hair, and suppressing the entanglement of the hair during rinsing to achieve a smooth hand feeling, The degree of substitution of the cationized ethoxy group is 0.01 or more, preferably 0.1 or more, more preferably 0.18 or more, from the viewpoint of suppressing the stickiness during drying and improving the uniformity of the hair after drying. It is 2.9 or less, preferably 2.4 or less. Here, the degree of substitution of the cationized ethoxy group means the average number of moles of the cationized ethoxy group present in the C-HPC molecule per 1 mole of the anhydroglucose unit constituting the cellulose backbone. . The degree of substitution of the cationized ethoxy group is measured by the method described in JP-A-2012-232942. Further, in the C-HPC represented by the formula (1), the foaming property at the time of cleaning, the viewpoint of defoaming and defoaming at the time of washing, and the effect of improving the quick-drying effect of hair are provided. The degree of substitution of the propenyloxy group is 0.1 or more from the viewpoint of suppressing the entanglement of the hair during rinsing to achieve a smooth hand feeling, suppressing the stickiness in drying, and improving the uniformity of the hair after drying. It is preferably 0.2 or more, more preferably 1.1 or more, still more preferably 1.5 or more, still more preferably 2.0 or more, further preferably 4.0 or less, preferably 3.0 or less, more preferably 2.9 or less, still more preferably 2.6 or less. , especially good for 2.4 or less. Here, the degree of substitution of the propenyloxy group means the average number of moles of the propenyloxy group present in the C-HPC molecule per 1 mole of the anhydroglucose unit constituting the cellulose backbone. The degree of substitution of the propoxyl group is measured by the method described in JP-A-2012-232942. The C-HPC of the component (A) can be obtained, for example, by the following production methods (i) to (iii). (i) A method of mixing cellulose with a large amount of water and a large excess of an alkali metal hydroxide in a slurry state and reacting with a cationizing agent and propylene oxide. (ii) A method in which dimethyl acetamide containing lithium chloride is used as a solvent, and an amine or alkoxide catalyst is added to dissolve the cellulose and react with a cationizing agent and propylene oxide. (iii) A method of reacting a powder, granules or granules of cellulose with a cationizing agent and propylene oxide in the presence of a coexisting base, using an excess of water or a solvent as in the above (i) or (ii). In the production methods of the above (i) to (iii), either the reaction with the cationizing agent or the reaction with propylene oxide may be carried out at the same time. Among these production methods, the production method of the above (iii) is preferred from the viewpoint of improving the ease of production of the component (A). More specifically, C-HPC can be produced by the method described in Patent Document 2 described above. Hair from the viewpoint of improving the quick-drying effect of hair, suppressing the entanglement of hair during rinsing, achieving a smooth hand feeling, suppressing the stickiness in drying, and improving the uniformity of hair after drying The content of the component (A) in the detergent composition is preferably 0.001% by mass or more, more preferably 0.003% by mass or more, still more preferably 0.007% by mass or more, and still more preferably 0.01% based on the total amount of the hair cleansing composition. The mass% or more is particularly preferably 0.03% by mass or more. In the same manner, the content of the component (A) in the hair cleansing composition is preferably 1.5% by mass or less, more preferably 1.0% by mass or less, even more preferably 1.0% by mass or less, based on the total amount of the hair cleansing composition. It is 0.8% by mass or less, more preferably 0.6% by mass or less, particularly preferably 0.5% by mass or less, and particularly preferably 0.3% by mass or less. (Component (B)) The component (B) is a cationic polymer other than the above component (A). Specific examples of the component (B) include a cationized cellulose derivative other than the component (A) such as a cationized hydroxyethyl cellulose; a cationized starch; a cationized fenugreek gum, a cationized guar gum, and a cation. Cationic galactomannan and its derivatives such as tara gum and cationized locust bean gum; diallyl quaternary ammonium salt/acrylamide copolymer, vinyl imidazolium trichloride/vinyl pyrrolidine Ketone copolymer, hydroxyethyl cellulose/dimethyldiallylammonium chloride copolymer, vinyl pyrrolidone/quaternary dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone /alkylamino acrylate copolymer, polyvinylpyrrolidone / alkylamino acrylate / vinyl caprolactam copolymer, vinyl pyrrolidone / methacrylamide propyl chloride Alkyl ammonium copolymer, alkyl acrylamide/acrylate/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer, adipic acid/dimethylaminohydroxypropyl exoethyltriamine Copolymer (manufactured by Sandax, USA), copolymers, etc. Cationic polymers described in Publication No. 53-139734, the Japanese Patent Laid-Open Publication No. Sho 60-36407 cationic polymer as described in the. The cationized galactomannan is a water-soluble cationized product obtained by introducing a quaternary nitrogen-containing group into a galactomannan having a galactose as a main chain and a galactose unit as a side chain. polymer. The galactomannan is obtained, for example, from the endosperm of the seeds of legumes. The ratio of galactose to mannose is 1:1 for fenugreek gum, 1:2 for guar gum, 1:3 for tara gum, and 1:4 for locust bean gum. As a commercial product of the cationized galactomannan, Catinal CF-100 (manufactured by Toho Chemical Co., Ltd.) is exemplified as the cationized fenugreek gum. As a commercial product of the cationized guar gum, Jaguar series such as Jaguar C-13S, Jaguar C-14S, Jaguar C-14SK, Jaguar C-17, etc. (guar gum hydroxypropyl chloride galvanose manufactured by Solvay Co., Ltd.) can be cited. Base ammonium) and so on. Further, as a commercial product of the cationized tara gum, Catinal CTR-100 and Catinal CTR-200 (the above is Tara gum hydroxypropyltrimethylammonium chloride manufactured by Toho Chemical Industry Co., Ltd.) and the like are mentioned. Further, as a commercial product of the cationized locust bean gum, Catinal CLB-100 (a locust bean gum hydroxypropyltrimethylammonium chloride manufactured by Toho Chemical Industry Co., Ltd.) or the like can be mentioned. Further, specific examples of the commercial product of the component (B) include Merquat 100 (a copolymer of diallyldimethylammonium salt manufactured by Lubrizol Co., Ltd.; and INCI name poly-quaternary ammonium salt). -6), Merquat 550 (copolymer of acrylamide and diallyldimethylammonium salt manufactured by Lubrizol; INCI named polytetramine-7), Merquat 280 and Merquat 295 (manufactured by Lubrizol) Copolymer of acrylic acid with diallyldimethylammonium salt; INCI name poly-quaternary ammonium salt-22), Luviquat FC370 (1-vinyl-2-pyrrolidone and 1-vinyl-based by BASF) Copolymer of 3-methylimidazolium salt; INCI name poly-quaternary ammonium salt-16), Gafquat 755N (1-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate manufactured by ISP) Copolymer; INCI name poly quaternary ammonium salt-11), Ucare polymer JR and Ucare polymer LR series (salt of the reaction of trimethylammonium substituted epoxide and hydroxyethyl cellulose manufactured by Amerchol) ;INCI is called polytetra-ammonium salt-10), Poiz C-60H, Poiz C-80M, Poiz C-150L (the above is a trimethylammonium-substituted epoxide and hydroxy group manufactured by Kao Corporation) A salt thereof of the group of cellulose; the INCI name Poly quaternary ammonium salts -10), Sofcare KG-101E (manufactured by Kao Corporation; the INCI name -52 poly quaternary ammonium salt) and the like. In terms of improving the quick-drying effect of hair, suppressing the entanglement of hair during rinsing, achieving a smooth hand feeling, suppressing the stickiness in drying, and improving the uniformity of hair after drying, the composition (B) is preferably selected from the group consisting of cationized galactomannan, cationized hydroxyethyl cellulose (polytetramine ammonium-10), cationized starch, polytetramine-6, polytetramine -7, one or more of the group consisting of polytetra-ammonium salt-22 and polytetra-ammonium salt-52, more preferably selected from the group consisting of cationized galactomannan, cationized hydroxyethyl cellulose and cation One or more of the group consisting of starches is more preferably a cationized galactomannan. The content of the component (B) in the hair cleanser composition is relative to the hair cleanser combination from the viewpoint of suppressing the entanglement of the hair during rinsing to achieve a smooth hand feeling, and improving the uniformity of the hair after drying. The whole of the material is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, still more preferably 0.05% by mass or more. Further, the content of the component (B) in the hair cleansing composition is preferably 3 mass with respect to the entire hair cleansing composition from the viewpoint of improving the quick-drying effect of the hair and suppressing the stickiness during drying. % or less is more preferably 2% by mass or less, further preferably 1% by mass or less, further preferably 0.8% by mass or less, and particularly preferably 0.4% by mass or less. Further, the hair cleansing composition is improved from the viewpoint of improving the quick-drying effect of the hair, suppressing the entanglement of the hair during rinsing, suppressing the stickiness during drying, and improving the uniformity of the hair after drying. The mass ratio ((A)/(B)) of the content of the component (A) to the content of the component (B) is preferably 0.001 or more, more preferably 0.005 or more, still more preferably 0.01 or more, and still more preferably It is 0.03 or more, particularly preferably 0.07 or more, particularly preferably 0.12 or more, particularly preferably 0.16 or more, and particularly preferably 0.2 or more. Further, the mass ratio ((A)/(B)) is preferably 150 or less from the viewpoint of improving the quick-drying effect of the hair and suppressing the entanglement of the hair during rinsing to achieve a smooth hand feeling. It is preferably 100 or less, more preferably 50 or less, still more preferably 10 or less, particularly preferably 6 or less, particularly preferably 3 or less, and particularly preferably 2 or less. Next, the anionic surfactants of the components (C) and (D) will be described. (Component (C)) Component (C) is a sulfate type surfactant. Specific examples of the component (C) include alkyl sulfates, alkenyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene ether sulfates, and alkyl sulfosuccinates. Alkyl phenyl ether sulfate. The component (C) is preferably a polyoxyethylene alkyl ether sulfate represented by the following formula (5). R⁷ O(CH₂ CH₂ O)_a SO₃ ^- M⁺ (5) (In the above formula (5), R⁷ An alkyl group or an alkenyl group having a carbon number of 8 or more and 18 or less, M⁺ Indicates a cation derived from an alkali metal, an alkaline earth metal, an ammonium, an alkanolamine or a basic amino acid, and a is an average addition molar number of ethylene oxide, indicating a number of 0.5 or more and 5 or less) R in the general formula (5) from the viewpoint of foaming and good foam touch⁷ The carbon number is preferably 8 or more, more preferably 10 or more, further preferably 18 or less, more preferably 14 or less. From the same viewpoint, the average addition molar number a of the ethylene oxide in the formula (5) is preferably 0.5 or more, more preferably 0.6 or more, still more preferably 0.8 or more, and further preferably 5 or less, more preferably 4 or less, still more preferably 3.5 or less. Also, from the same point of view, as the counter ion M⁺ Preferred are cations derived from alkali metals such as sodium and potassium; cations derived from alkaline earth metals such as calcium and magnesium; cations derived from ammonium; cations derived from alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; a cation of a basic amino acid such as arginine or lysine; more preferably a cation derived from ammonium or sodium. In terms of the same point of view, component (C) is preferably M⁺ The polyoxyethylene alkyl ether sulfate which is a cation derived from ammonium or sodium is more preferably one or more selected from the group consisting of ammonium lauryl sulfate and sodium laureth sulfate. The viewpoint of further improving the foaming property, the viewpoint of improving the quick-drying effect of the hair, the viewpoint that the hair is not easily entangled during rinsing, giving a smooth hand feeling, suppressing the stickiness during drying, and improving the hair after drying From the viewpoint of the uniformity, the content of the component (C) in the hair cleansing composition is preferably 3% by mass or more, more preferably 5% by mass or more, and still more preferably 8% by mass based on the total amount of the hair cleansing composition. %the above. Further, from the viewpoint of improving the defoaming property and the fact that the hair is not easily entangled during rinsing and imparts a smooth hand feeling, the content of the component (C) in the hair cleansing composition is relatively higher than that of the hair cleansing composition. It is preferably 20% by mass or less, more preferably 18% by mass or less, and still more preferably 15% by mass or less. Moreover, from the viewpoint of improving the quick-drying effect of the hair, suppressing the entanglement of the hair during rinsing, achieving the smooth hand feeling, suppressing the stickiness during drying, and improving the uniformity of the hair after drying, The mass ratio ((C)/(A)) of the content of the component (C) to the content of the component (A) in the hair cleansing composition is 26 or more, preferably 30 or more, more preferably 50 or more. More preferably, it is 100 or more. Further, the above-mentioned mass ratio is obtained from the viewpoint of improving the quick-drying effect of the hair, suppressing the entanglement of the hair during rinsing, suppressing the stickiness of the hair during drying, and improving the uniformity of the hair after drying. ((C)/(A))) is 20,000 or less, preferably 10,000 or less, more preferably 5,000 or less, further preferably 3,000 or less, further preferably 2,000 or less, particularly preferably 1800 or less, and particularly preferably 1,500 or less. It is preferably 1000 or less, and particularly preferably 500 or less. (Component (D)) Component (D) is a carboxylate type surfactant. Specific examples of the carboxylate type surfactant include an ether carboxylate type anionic surfactant such as a polyoxyalkylene alkyl ether carboxylate, and an amino acid surfactant. The component (D) is preferably a polyoxyethylene alkyl ether carboxylate represented by the following formula (6). R⁸ O-(CH₂ -CH₂ O)_b -CH₂ COO^- Z⁺ (6) (In the above formula (6), R⁸ An alkyl group or an alkenyl group having a carbon number of 10 or more and 18 or less, Z⁺ It means a cation derived from an alkali metal, an alkaline earth metal, an ammonium, an alkanolamine or a basic amino acid, and b is a mass average, which is a number of 0.5 or more and 10 or less), and is sufficiently obtained to enrich the foaming during cleaning. By using the ingredients (A) to (C) together, the hair is not easily entangled during rinsing, the hand feels smooth, and it is not sticky during drying, and the effect of tidying the hair after drying is in the general formula. (6), R⁸ The carbon number is preferably 10 or more, more preferably 12 or more, still more preferably 18 or less, still more preferably 16 or less. In the general formula (6), b as an average addition mole number of ethylene oxide is preferably 0.5 or more, more preferably 1 or more, in terms of mass (weight), from the viewpoint of improving foaming property. Further, it is preferably 10 or less, more preferably 6 or less. Further, from the same viewpoint, in the general formula (6), Z as a counter ion⁺ Preferred are cations derived from alkali metals such as sodium and potassium; cations derived from alkaline earth metals such as calcium and magnesium; cations derived from ammonium; cations derived from alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; a cation of a basic amino acid such as arginine or lysine; more preferably a cation derived from ammonium or sodium. From the same point of view, the component (D) is preferably Z.⁺ The polyoxyethylene alkyl ether carboxylate which is a cation derived from ammonium or sodium is more preferably one or more selected from the group consisting of ammonium lauryl carboxylate and sodium laureth carboxylate. In terms of improving the quick-drying effect of hair, the viewpoint that the hair is not easily entangled during rinsing, giving a smooth hand feeling, and improving the uniformity of the hair after drying, the component (D) in the hair cleansing composition The content is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and still more preferably 0.5% by mass or more based on the total amount of the hair cleansing composition. Moreover, in view of the fact that the hair is not easily entangled at the time of rinsing, the viewpoint of smoothness is imparted, the viewpoint of the uniformity of the hair after drying, the viewpoint of suppressing the stickiness during drying, and the effect of improving the quick-drying effect of the hair are The content of the component (D) in the hair cleansing composition is preferably 10% by mass or less, more preferably 5% by mass or less, and still more preferably 2.5% by mass or less based on the total amount of the hair cleansing composition. In addition, from the viewpoint of achieving good foaming properties, the viewpoint that the hair is not easily entangled during rinsing, giving a smooth hand feeling, improving the uniformity of the hair after drying, suppressing the stickiness during drying, and improving hair From the viewpoint of the quick-drying effect, the mass ratio ((C)/(D)) of the content of the component (C) to the content of the component (D) in the hair cleanser composition is 4 or more, preferably 6 More preferably, it is 8 or more. Further, in terms of improving the quick-drying effect of hair, suppressing the entanglement of hair during rinsing, achieving a smooth hand feeling, and improving the uniformity of hair after drying, the above-mentioned mass ratio ((C)/ (D)) is 200 or less, preferably 150 or less, more preferably 100 or less, still more preferably 80 or less, still more preferably 50 or less, and particularly preferably 30 or less. Moreover, from the viewpoint of improving the quick-drying effect of the hair, suppressing the entanglement of the hair during rinsing, achieving the smooth hand feeling, suppressing the stickiness during drying, and improving the uniformity of the hair after drying, The mass ratio of the total content of the components (C) and (D) in the hair cleansing composition to the content of the component (A) (((C) + (D)) / (A))) is preferably 6.8. The above is more preferably 25 or more, further preferably 30 or more, further preferably 50 or more, and particularly preferably 80 or more. Further, in terms of suppressing the stickiness in drying, improving the quick-drying effect of the hair, and improving the uniformity of the hair after drying, the mass ratio (((C)+(D))/( A)) is preferably 25,000 or less, more preferably 5,000 or less, further preferably 3,000 or less, further preferably 2,000 or less, particularly preferably 1800 or less, particularly preferably 1,500 or less, particularly preferably 1200 or less, particularly preferably 1000 or less, particularly preferably 500 or less. (Water) The hair cleansing composition of the present embodiment contains water as a medium. As the water, ion-exchanged water or distilled water or the like can be used. The content of water is, for example, the remaining amount of the components (A) to (D) and other components in the hair cleansing composition. Further, in the present embodiment, the hair cleansing composition may contain components other than the above components. For example, the hair cleansing composition may further contain polyfluorene as the component (E). (Component (E)) Specific examples of the polyoxyl oxides as the component (E) include dimethyl polyoxyalkylene (hereinafter also referred to as quinone), cyclic polyfluorene oxide, and amine-based modified polymerization. Oxygen, dimethicone, polyether modified polyoxyl, polydehydroglycerin modified polyoxyl, methylphenyl polyoxyalkylene, fatty acid modified polyoxyl, alcohol modified poly Oxygen, alkoxy-modified polyfluorene oxide, epoxy-modified polyoxyl oxide, fluorine-modified polyoxyloxy, alkyl-modified polyoxyl, etc., in the application of the hair cleansing composition and the hair during rinsing From the viewpoint of the smoothness and the quick-drying performance of the appropriate hair, it is preferably one or more selected from the group consisting of dimethyl polysiloxane and an amine-modified polyfluorene. The content of the component (E) in the hair cleansing composition is from the viewpoint of suppressing the drying between the hair during drying, promoting the spreading to accelerate the drying time, and the fact that the hair is not easily entangled during rinsing to impart a smooth hand feeling. The total amount of the hair cleansing composition is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, and still more preferably 0.3% by mass or more. Moreover, the content of the component (E) in the hair cleansing composition is preferably 15% by mass or less, and more preferably 10% by mass or less based on the total amount of the hair cleansing composition, from the viewpoint of suppressing the stickiness during drying. Further, it is preferably 5% by mass or less, and more preferably 3% by mass or less. (Other optional components) The hair cleansing composition of the present embodiment may contain, in addition to the above components, components used in a usual hair cleansing composition as appropriate in accordance with a desired effect. Examples of such an optional component include antidandruff agents, vitamin agents, fungicides, glycyrrhizic acid such as dipotassium glycyrrhizinate and its salts, anti-inflammatory agents such as glycyrrhetinic acid and salts thereof, and preservatives such as benzoic acid and its salts. ; chelating agents such as EDTA-2Na (Ethylenediaminetetraacetic Acid Disodium Salt); humectants such as sorbitol and panthenol; surfactants other than components (C) and (D); dyes, pigments, etc. a coloring agent; a eucalyptus extract such as a polar solvent extract of eucalyptus, a shell hard protein or a hydrolyzate thereof, honey, royal jelly, a protein obtained from silk or a hydrolyzate thereof, a protein-containing extract obtained from a seed of a legume, Ginseng extract, rice germ extract, Fucus extract, aloe extract, lotus extract, pomegranate extract, wild rose extract, gerbera extract, licorice extract, moon leaf extract, green algae extract, etc. Extracts; pearlescent agents such as titanium oxide; perfume; ultraviolet absorber; antioxidant; shea butter; rose water; sunflower oil; sweet orange oil; eucalyptus oil. (pH value) The pH of the hair cleansing composition of the present embodiment is preferably 4.0 or more, more preferably 4.5 or more, and more preferably from the viewpoint that the hair is not easily entangled during rinsing and imparts a smooth hand. Further, 5.0 or more is preferably 8.0 or less, more preferably 7.5 or less, still more preferably 7.0 or less. In the present specification, the pH of the hair cleansing composition means a measured value at 25 ° C (glass electrode measurement method) when diluted with water to 20 times by mass. Next, a method of producing the hair cleansing composition of the present embodiment will be described. The hair cleansing composition of the present embodiment is produced, for example, by mixing or dispersing the components (A) to (D) and other appropriate components in a specific order to dissolve or disperse in water. Specifically, the components (C) and (D) are added to water and heated to about 80 ° C while stirring. An aqueous solution obtained by dissolving or uniformly dispersing the components (A) and (B) in water is added thereto, and the mixture is stirred and uniformly dissolved. The hair cleansing composition can be obtained by appropriately adding other components while stirring, stirring and uniformly dissolving, and cooling to room temperature (25 ° C, the same hereinafter). Moreover, the method of cleaning the hair using the hair cleansing composition of the present embodiment includes, for example, applying the hair cleansing composition to the hair, preferably to the hair, and sufficiently foaming and then rinsing. The hair cleansing composition of the present embodiment contains the components (A) to (D) and water, and the mass ratio ((C)/(A)) and the mass ratio ((C)/(D)) are respectively in a specific range. Therefore, the wet hair after shampooing can be dried in a short time. Further, by using the hair cleansing composition of the present embodiment, the hair is less likely to be entangled during rinsing, imparts a smooth hand feeling, suppresses stickiness during drying, and imparts regularity to the hair after drying. Moreover, according to the present embodiment, for example, the hair cleansing composition can be attached to the surface of the hair in a thin and uniform manner. Therefore, for example, entanglement of the hair after washing to dryness can be suppressed, and the uniformity of the hair after drying can be improved. Although the embodiments of the present invention have been described above, these are examples of the present invention, and various configurations other than the above may be employed. With regard to the embodiments described above, the preferred aspects of the invention are further disclosed below. <1> A hair cleansing composition comprising the following components (A), (B), (C), (D) and water, and a mass ratio of the content of the component (C) to the content of the component (A) ((C)/(A))) is 26 or more and 20,000 or less, and the mass ratio ((C) / (D)) of the content of the component (C) to the content of the component (D) is 4 or more and 200 or less. (A) has a main chain derived from anhydroglucose represented by the following formula (1), and has a degree of substitution of 0.01 or more and 2.9 or less by cationized ethoxy group, and a degree of substitution of 0.1 by using propenyloxy group. Cationic hydroxypropyl cellulose (B) above 4.0 and below, cationic polymer other than component (A) (C) sulfate type surfactant (D) carboxylate type surfactant [Chemical 7](in the above formula (1), R¹ , R² And R³ Each of the substituents represented by the following formula (2) or (3) is independently represented, and n represents the average degree of polymerization of the above-described anhydroglucose, and is 50 or more and 5,000 or less.(In the above formulas (2) and (3), Y¹ And Y² One represents a hydrogen atom, the other represents a cationic group represented by the following formula (4), PO represents a propenoxy group, and p represents a cationized ethoxy group (-CH (Y)¹ )-CH(Y² The number of -O-), q represents the number of exopropoxy groups (-PO-), respectively 0 or a positive integer; where R¹ , R² And R³ All p and q in the middle are not 0 at the same time; in the case where neither p nor q is 0, the addition order of the above-mentioned cationized ethoxy group and the above-mentioned propenyloxy group is arbitrary, and further, in p and When q is not 0 and either or both of p and q are 2 or more, it may be either a block bond or a random bond.(In the above formula (4), R⁴ , R⁵ And R⁶ Each of which independently represents a linear or branched alkyl group having a carbon number of 1 or more and 3 or less, X^- (2) The hair cleansing composition according to the above <1>, wherein the content of the component (A) in the hair cleansing composition is preferably 0.001% by mass or more based on the total amount of the hair cleansing composition. More preferably, it is 0.003 mass% or more, further preferably 0.007 mass% or more, further preferably 0.01 mass% or more, particularly preferably 0.03 mass% or more, further preferably 1.5 mass% or less, more preferably 1.0 mass%. % or less is more preferably 0.8% by mass or less, still more preferably 0.6% by mass or less, particularly preferably 0.5% by mass or less, and particularly preferably 0.3% by mass or less. The hair cleansing composition of the above-mentioned <1>, wherein the average degree of polymerization n of the formula (1) in the component (A) is 50 or more, preferably 100 or more, more preferably It is 400 or more, more preferably 700 or more, and further preferably 5,000 or less, preferably 2,000 or less, more preferably 1300 or less. The hair cleansing composition of any one of the above-mentioned <1>, wherein the degree of substitution of the cationized ethoxy group in the component (A) is 0.01 or more, preferably 0.1 or more. More preferably, it is 0.18 or more, and it is 2.9 or less, preferably 2.4 or less. The hair cleansing composition of any one of the above-mentioned <1>, wherein the degree of substitution of the propenoxy group in the component (A) is 0.1 or more, preferably 0.2 or more, more preferably It is preferably 1.1 or more, more preferably 1.5 or more, still more preferably 2.0 or more, further preferably 4.0 or less, preferably 3.0 or less, more preferably 2.9 or less, still more preferably 2.6 or less, and particularly preferably 2.4 or less. The hair cleansing composition of any one of the above-mentioned <1> to <5>, wherein the content of the component (B) in the hair cleansing composition is preferably 0.01 with respect to the entire hair cleansing composition. The mass% or more is more preferably 0.02% by mass or more, further preferably 0.05% by mass or more, more preferably 3% by mass or less, still more preferably 2% by mass or less, still more preferably 1% by mass or less, and further more preferably It is preferably 0.8% by mass or less, and particularly preferably 0.4% by mass or less. The hair cleansing composition of any one of the above-mentioned <1> to <6>, wherein the content of the component (C) in the hair cleansing composition is preferably 3 with respect to the entire hair cleansing composition. The mass% or more is more preferably 5% by mass or more, further preferably 8% by mass or more, more preferably 20% by mass or less, still more preferably 18% by mass or less, still more preferably 15% by mass or less. The hair cleansing composition of any one of the above-mentioned <1>, wherein the component (C) is preferably a polyoxyethylene alkyl ether sulfate represented by the following formula (5). More preferably, it is M in the following general formula (5)⁺ The polyoxyethylene alkyl ether sulfate which is ammonium or sodium is more preferably one or more selected from the group consisting of ammonium lauryl sulfate and sodium laureth sulfate. R⁷ O(CH₂ CH₂ O)_a SO₃ ^- M⁺ (5) (In the above formula (5), R⁷ An alkyl group or an alkenyl group having a carbon number of 8 or more and 18 or less, M⁺ Indicates a cation derived from an alkali metal, an alkaline earth metal, an ammonium, an alkanolamine or a basic amino acid, and a is an average addition molar number of ethylene oxide, which represents a number of 0.5 or more and 5 or less. <9> The hair cleansing composition according to any one of the above-mentioned items, wherein the content of the component (C) in the hair cleanser composition is compared with the content of the component (A) ((C)/ (A)) is 26 or more, preferably 30 or more, more preferably 50 or more, still more preferably 100 or more, further preferably 20,000 or less, preferably 10,000 or less, more preferably 5,000 or less, still more preferably 3,000. In the following, it is more preferably 2,000 or less, particularly preferably 1800 or less, particularly preferably 1,500 or less, particularly preferably 1,000 or less, and particularly preferably 500 or less. The hair cleansing composition of any one of the above-mentioned <1>, wherein the component (D) is preferably a polyoxyethylene alkyl ether carboxylic acid represented by the following formula (6). The salt is more preferably Z in the following general formula (6)⁺ The polyoxyethylene alkyl ether carboxylate which is ammonium or sodium is more preferably one or more selected from the group consisting of ammonium lauryl carboxylate and sodium laureth carboxylate. R⁸ O-(CH₂ -CH₂ O)_b -CH₂ COO^- Z⁺ (6) (In the above formula (6), R⁸ An alkyl group or an alkenyl group having a carbon number of 10 or more and 18 or less, Z⁺ Indicates a cation derived from an alkali metal, an alkaline earth metal, an ammonium, an alkanolamine or a basic amino acid, and b is a mass average, and represents a number of 0.5 or more and 10 or less. <11> as in the above <1> to <10> The hair cleansing composition according to any one of the present invention, wherein the content of the component (D) in the hair cleansing composition is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, based on the total amount of the hair cleansing composition. It is preferably 0.5% by mass or more, more preferably 10% by mass or less, still more preferably 5% by mass or less, still more preferably 2.5% by mass or less. The hair cleansing composition of any one of the above-mentioned <1> to <11>, wherein the mass ratio of the content of the component (C) in the detergent composition to the content of the component (D) (( C)/(D)) is 4 or more, preferably 6 or more, more preferably 8 or more, further preferably 200 or less, preferably 150 or less, more preferably 100 or less, still more preferably 80 or less, and furthermore The best is 50 or less, and the best is 30 or less. The hair cleansing composition of any one of the above-mentioned <1> to <12>, wherein the total content of the components (C) and (D) in the hair cleansing composition is relative to the component (A). The mass ratio (((C)+(D)))/(A))) is preferably 6.8 or more, more preferably 25 or more, still more preferably 30 or more, still more preferably 50 or more, and particularly preferably 80. The above is preferably 25,000 or less, more preferably 5,000 or less, further preferably 3,000 or less, further preferably 2,000 or less, particularly preferably 1800 or less, particularly preferably 1500 or less, and particularly preferably 1200 or less. It is 1000 or less, and particularly preferably 500 or less. The hair cleansing composition of any one of the above-mentioned <1> to <13>, wherein the mass ratio of the content of the component (A) in the hair cleaner composition to the content of the component (B) ( (A)/(B)) is preferably 0.001 or more, more preferably 0.005 or more, still more preferably 0.01 or more, still more preferably 0.03 or more, particularly preferably 0.07 or more, particularly preferably 0.12 or more, and particularly preferably 0.16. The above is particularly preferably 0.2 or more, more preferably 150 or less, still more preferably 100 or less, still more preferably 50 or less, still more preferably 10 or less, particularly preferably 6 or less, and particularly preferably 3 or less. It is 2 or less. The hair cleansing composition of any one of the above-mentioned <1> to <14> wherein the component (B) is preferably selected from the group consisting of a cationized galactomannan and a cationized hydroxyethylcellulose ( In the group consisting of polyquaternary ammonium salt-10), cationized starch, polyquaternary ammonium salt-6, polyquaternary ammonium salt-7, polyquaternary ammonium salt-22 and polyquaternary ammonium salt-52 One or more kinds are more preferably one or more selected from the group consisting of a cationized galactomannan, a cationized hydroxyethyl cellulose, and a cationized starch, and more preferably a cationized galactomannan. The hair cleansing composition of any one of the above-mentioned <1> to <15> further contains a polyfluorene as a component (E). The hair cleansing composition of any one of the above-mentioned <1> to <16> wherein the content of the component (E) in the hair cleansing composition is preferably 0.01 with respect to the entire hair cleansing composition. The mass% or more is more preferably 0.05% by mass or more, further preferably 0.1% by mass or more, more preferably 0.3% by mass or more, still more preferably 15% by mass or less, still more preferably 10% by mass or less, and further more preferably It is preferably 5% by mass or less, and more preferably 3% by mass or less. The hair cleansing composition of any one of the above-mentioned <1> to <17>, wherein the pH at 25 ° C when diluted with water to 20 times by mass is preferably 4.0 or more, more preferably 4.5. The above is further preferably 5.0 or more, more preferably 8.0 or less, still more preferably 7.5 or less, still more preferably 7.0 or less. The method for producing a hair cleansing composition according to any one of the above aspects of the present invention, which preferably comprises the components (A) to (D) and other appropriate components. a step of sequentially mixing and dissolving or dispersing in water; more preferably comprising: adding the components (C) and (D) to water, and heating to a first step of about 80 ° C while stirring; and obtaining the same in the first step A second step of uniformly dissolving the aqueous solution obtained by dissolving or uniformly dispersing the components (A) and (B) in water is added to the mixture; and the mixture obtained in the second step is cooled while being appropriately added. The ingredients were stirred to uniformly dissolve and cool to 25 ° C. <20> A method of cleaning a hair comprising applying the hair cleansing composition according to any one of the above <1> to <18> to hair and rinsing with water; preferably comprising <1 above The hair cleansing composition according to any one of <18> is applied to the hair and rinsed with water. [Examples] <Examples 1 to 11 and Comparative Examples 1 to 6> The shampoo compositions having the compositions shown in Tables 1 and 2 were prepared and evaluated according to the following methods and standards. [Preparation method of shampoo composition] The components (C) and (D) are added to water and heated to about 80 ° C while stirring, and the components (A) and (B) are dissolved or uniformly dispersed in water beforehand. The obtained aqueous solution was stirred and uniformly dissolved. Thereafter, the obtained mixture was cooled, and the component (E) was added thereto, stirred, uniformly dissolved, cooled to 25 ° C, and hydrochloric acid was appropriately added thereto to obtain a shampoo having a pH value in the parentheses of Tables 1 and 2. Fine composition. Further, the pH was measured by the method shown below. <Method for Measuring pH Value> The pH value is diluted with a purified water to a mass of 20 times and stirred and dissolved, and then a glass meter (Model HM-30R, manufactured by DKK-TOA Co., Ltd.) is used at 25 ° C. The measurement was carried out by an electrode measurement method. <Evaluation method> [The presence or absence of entanglement of the hair bundle during rinsing, the smoothness of the hair bundle during rinsing, the presence or absence of stickiness in the hair bundle during drying, and the drying time of the hair bundle] (Evaluation hair bundle) A hair bundle having a weight of 20 g, a length of 30 cm, and a width of 5.5 cm was produced using a Japanese straight hair using a hair dye at a frequency of four times a year. The hair bundle was wetted in running water at 40 ° C for 30 seconds, and then the formulation was shown in the following sample shampoo 1 g and foamed. Thereafter, the fingers were passed through the hair bundle while being rinsed with water at 40 ° C for 30 seconds. The subsequent hair bundle was used for evaluation. (Composition of sample shampoo) (Component) (% by mass) Polyoxyethylene (2.0) Sodium lauryl ether sulfate 15.5 Diethanolamine laurate 2.2 Disodium edetate 0.15 Sodium benzoate 0.18 Oxybenzone 0.03 Phosphoric acid 0.07 Sodium chloride 0.8 Fragrance 0.4 Remaining amount of purified water (total) 100 (Treatment method) Excess water was removed by hand straight hair bundle until the moisture content of the hair bundle for evaluation was 20 g. Next, 1 g of the shampoo composition shown in Tables 1 and 2 was applied to the hair bundle and foaming was carried out for 20 seconds. Then, while rinsing with tap water at a flow rate of 60 mL/s at 40 ° C for 20 seconds, the sensory evaluation was performed from the viewpoint of entanglement and smoothness. (The presence or absence of entanglement of the hair bundle during rinsing) Select whether or not there is a entanglement of the hair bundle during rinsing, and select one from "I don't feel the entanglement of hair" / "Nothing" / "I feel entangled in hair". Evaluation was performed by 7 functional inspectors. In Tables 1 and 2, the number of functional inspectors who answered "not feeling entangled in hair" / "all are not" / "feeling hair" is shown in order. (Smoothness of the hair bundle during rinsing) Regarding the smoothness of the hair bundle during rinsing, one of "Smooth" / "Never" or "No Smooth" is selected. Evaluation was performed by 7 functional inspectors. In Tables 1 and 2, the number of functional inspectors who answered "smooth" / "all" and "not smooth" were sequentially indicated. (When the drying time of the hair bundle is slow) After the entanglement at the time of the above-mentioned rinsing, the smoothness is evaluated, and the water is wiped by a towel so that the moisture content of the hair bundle becomes 10 g. The hair bundle is configured such that the distance from the air outlet of the hair dryer (manufactured by Can, SOL TYPE 315, set to high/very hot) to the center of the length direction of the hair bundle is about 20 cm. The blower is fixed in such a manner that the warm air is blown laterally. Dry the hair dryer while passing your fingers through the hair bundle. The measurement is made from the start of drying of the hair dryer to the time when the hairdresser is completely dry as judged by the researcher, and the drying time of the hair bundle is set to be fast. (The presence or absence of stickiness of the hair bundle during drying) The sensory evaluation of the tackiness of the hair bundle during drying in the same treatment as the above-mentioned "drying time of the hair bundle" was carried out. In the evaluation, one of the "not sticky in drying" / "all non-" or "feeling in dryness" was selected. Evaluation was performed by 7 functional inspectors. In Tables 1 and 2, the number of functional inspectors who answered "not sticky during drying" / "all are not" / "feeling sticky during drying" are indicated in order. [The uniformity of the hair bundle after drying] (Evaluation hair bundle) The non-chemically treated hair of Chinese with a length of 30 cm is made at about 200 pieces/cm.² The hair bundle obtained by the density and growth angle of 60° was planted to a range of 6 cm × 6 cm square. The hair bundle was wetted in running water at 40 ° C for 30 seconds, and then 1 g of the above sample shampoo was applied and foamed. Thereafter, the fingers were passed through the hair bundle while being rinsed with warm water of 40 ° C for 30 seconds. The subsequent hair bundle was used for evaluation. (Treatment method) After fully moisturizing the hair bundle with tap water of 40 ° C, 1 g of the shampoo composition shown in Tables 1 and 2 was applied and foaming was carried out for 20 seconds, and then 20 tap water was used for 20 hours. Flush in seconds. Thereafter, the towel was wiped with water so that the moisture content of the hair bundle became 3 g. Next, the hair bundle was placed so that the distance from the air outlet of the hair dryer to the center of the hair bundle in the longitudinal direction was about 20 cm, and the hair dryer was fixed by blowing the warm air from the lateral direction. The hair was shaken to the left and right at a speed of 2 times at a speed of 1 second, and the hair dryer was dried, and the comb (NEW DELRIN COMB manufactured by DELRIN Co., Ltd.) was spontaneously combed to the tip once every 30 seconds. The uniformity of the hair bundle after drying was evaluated. It was evaluated by seven functional inspectors, and one of them was selected from "no frizz, hair curl, neat to the tip of the hair" / "all non-" / "floating hair, more hair, and poor uniformity". In Tables 1 and 2, the functional inspectors who answered "no frizz, swell, until the hair is neat" / "all non-" / "floating hair, more hair, and poor uniformity" Number of people. [Table 1] [Table 2] In Tables 1 and 2, the following were used as the respective components. *1 PPG-2 hydroxypropyltrimethylammonium cellulose: (average degree of polymerization: 800, degree of substitution of cationized ethoxy group: 0.2, degree of substitution of propoxyl group: 2.2, X of formula (4)^- : Chloride ion) *2 Guar gum Hydroxypropyl chloride trimethylammonium: Jaguar C-14SK, manufactured by Solvay Company *3 Poly quaternary ammonium salt-10: Poiz C-150L, manufactured by Kao Corporation *4 Poly 4 Grade ammonium salt-52:Sofcare KG-101E, manufactured by Kao Corporation *5 Lauryl polyether (1) Ammonium sulfate: Emal 125A, manufactured by Kao Corporation *6 Mixture: average polymerization degree 50-300:1000-3000=42 : 18 According to Tables 1 and 2, the shampoo compositions of the respective examples contained the components (A) to (D) at a specific ratio, so that the quick-drying property and the entanglement during the rinsing were compared with those of the comparative examples. Excellent balance of smoothness, the presence or absence of stickiness during drying, and the effect of uniformity after drying. (Formulation Example 1) Hereinafter, a formulation example (display activity amount) of the hair cleansing composition is shown. C-HPC*1 0.05% by mass Polytetra-ammonium salt-7*7 0.1% by mass Lauryl polyether (1) Sodium ammonium sulfate*5 12.0% by mass Lauryl polyether (4) Sodium carboxylate 1.0% by mass Laurel Aminopropyl betaine*8 1.0% by mass 矽 混合物 mixture*6 1.0% by mass Total amount of purified water is 100% by mass In the above-mentioned formulation examples, the following components are used as the respective components except the above. *7 Polytetra-ammonium salt-7: Merquat 550, manufactured by Lubrizol Co., Ltd. *8 Laurolide propyl betaine: Amphitol 20AB, manufactured by Kao Corporation (Formulation Example 2) Hereinafter, a formulation example of a hair cleansing composition is shown (display Amount of activity). C-HPC*1 0.05% by mass guar hydroxypropyltrimethylammonium chloride*2 0.3% by mass Polytetracycline-10*3 0.1% by mass Polytetramine-52*4 0.1% by mass Laurel Alcohol polyether (1) sodium ammonium sulfate*5 12.0% by mass lauryl ether (4) sodium carboxylate 1.0% by mass 矽 spirit mixture *6 1.0% by mass Purified water balance total 100% by mass

no

Claims (11)

A hair cleansing composition comprising the following components (A), (B), (C), (D) and water, and a mass ratio of the content of the above component (C) to the content of the above component (A) ( (C)/(A)) is 26 or more and 20,000 or less, and the mass ratio ((C)/(D)) of the content of the said component (C) with respect to the content of the said component (D) is 4 or more and 200 or less. (A) has a main chain derived from anhydroglucose represented by the following formula (1), and has a degree of substitution of a cationized ethoxy group of 0.01 or more and 2.9 or less, and a degree of substitution with a propenoxy group is Cationic hydroxypropylcellulose (B) of 0.1 or more and 4.0 or less, cationic polymer other than component (A) (C) sulfate type surfactant (D) carboxylate type surfactant [Chemical Formula 1] (In the above formula (1), R ¹ , R ² and R ³ each independently represent a substituent represented by the following formula (2) or (3), and n represents an average degree of polymerization of the above-described anhydroglucose, and It is 50 or more and 5000 or less) [Chemical 2] (In the above formulae (2) and (3), one of Y ¹ and Y ² represents a hydrogen atom, the other represents a cationic group represented by the following formula (4), and PO represents a propoxyl group. ;p represents the number of cationized ethoxy groups (-CH(Y ¹ )-CH(Y ² )-O-), and q represents the number of exopropoxy groups (-PO-), respectively 0 or a positive integer; Wherein, all of p and q in R ¹ , R ² and R ³ are not simultaneously 0; and, in the case where neither p nor q is 0, the above-mentioned cationized ethoxy group and the above-mentioned propoxy group The order of addition is arbitrary, and when neither p nor q is 0 and any of p and q or both are 2 or more, it may be any of block bonding and random bonding. 3] (In the above formula (4), R ⁴ , R ⁵ and R ⁶ each independently represent a linear or branched alkyl group having 1 or more and 3 or less carbon atoms, and X ^- represents an anionic group). The hair cleansing composition of claim 1, wherein the content of the component (A) in the hair cleansing composition is 0.001% by mass or more and 1.5% by mass or less based on the total amount of the hair cleansing composition. The hair cleansing composition according to claim 1 or 2, wherein the content of the component (B) in the hair cleansing composition is 0.01% by mass or more and 3% by mass or less based on the total amount of the hair cleansing composition. The hair cleansing composition of claim 1 or 2, wherein the content of the component (C) in the hair cleansing composition is 3% by mass or more and 20% by mass or less based on the total amount of the hair cleansing composition. The hair cleansing composition according to claim 1 or 2, wherein the content of the component (D) in the hair cleansing composition is 0.1% by mass or more and 10% by mass or less based on the total amount of the hair cleansing composition. The hair cleansing composition according to claim 1 or 2, wherein a mass ratio of the content of the above component (A) to the content of the above component (B) in the hair cleansing composition ((A)/(B)) It is 0.001 or more and 150 or less. The hair cleansing composition according to claim 6, wherein the mass ratio ((A)/(B)) is 0.2 or more and 3 or less. The hair cleansing composition according to claim 1 or 2, wherein the mass ratio ((C)/(A)) is 100 or more and 500 or less. The hair cleansing composition according to claim 1 or 2, wherein the component (B) is selected from the group consisting of a cationized galactomannan, a cationized hydroxyethylcellulose (polytetraammonium salt-10), and a cationized starch. One or more of the group consisting of polytetra-ammonium salt-6, polytetra-ammonium salt-7, polyquaternary ammonium salt-22, and polytetra-ammonium salt-52. The hair cleansing composition according to claim 1 or 2, which further contains polyfluorene as the component (E). A method of cleaning a hair comprising applying a hair cleanser composition as claimed in claim 1 or 2 to hair and rinsing with water.