TW201722397A - Hair cosmetic - Google Patents

Hair cosmetic Download PDF

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TW201722397A
TW201722397A TW105142797A TW105142797A TW201722397A TW 201722397 A TW201722397 A TW 201722397A TW 105142797 A TW105142797 A TW 105142797A TW 105142797 A TW105142797 A TW 105142797A TW 201722397 A TW201722397 A TW 201722397A
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hair
mass
component
hair cosmetic
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TWI775736B (en
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Tomoyuki Suzawa
Tetsuya Kawai
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Kao Corp
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

A hair cosmetic containing the following components (A)-(C) in which the mass ratio (A)/(B) is 0.8-99 inclusive, and the water content is less than 5%. (A): A C1-4 monohydric alcohol; (B): a lipophilic solvent selected from C9-21 liquid oils represented by formula (1) [R1-R8 are H or CH3. X is -CH2-, -COO-, or -CH2COO-. n is 1-7, m and l are 0-2, and n+m+l is 1-7. When both m and l are 1 or higher, one of R4-R7 is CH3.] and silicones having a number-average molecular weight of 100-1500 inclusive; and (C): a C14-24 branched saturated or linear unsaturated aliphatic alcohol or ether thereof.

Description

毛髮化妝品Hair cosmetics

本發明係關於一種毛髮化妝品。The present invention relates to a hair cosmetic.

近年來,消費者期望之髮型正在發生變化。因此,對整髮劑所要求之性能亦自如先前之藉由黏著性聚合物或覆膜形成聚合物而固定頭髮者,變化為維持自然之整齊感,並且打理後之頭髮之觸感亦較為柔軟且自然者。 針對此種要求,有非水系之毛髮化妝品、尤其是一般被稱為護髮油之製品。然而,尤其是最近之女性謀求如下整髮劑:不存在以毛髮之乾澀感或油膩感為代表之不舒適之存在感,為如未經修飾之頭髮之手觸感,無髮束感且為自然之外觀,並且梳理性較佳且整齊。因此,期望如下問題之改善之呼聲變大:因護髮油中所包含之油,而導致於塗佈時使其浸潤於頭髮整體時及塗佈後,油之表面膩滑感亦暫時持續;不自然之髮束感殘留;頭髮之外觀或手觸感較厚重,黏膩性殘留等。 為了消除護髮油中之上述問題,例如於專利文獻1中揭示有一種併用特定結構之聚醚改性聚矽氧、揮發性油分及乙醇之護髮油。於該文獻中揭示有剛塗佈該護髮油後之油膩感得以消除,頭髮浸潤性較佳,經時之乾枯感得到改善。 又,於專利文獻2中揭示有一種含有特定之異烷烴系烴及特定之烴之速乾性護髮油。於該文獻中揭示有藉由將該速乾性護髮油應用於濕潤之頭髮,可縮短使毛髮乾燥之時間,給乾燥之毛髮帶來潤髮效果。 於專利文獻3中揭示有一種大量含有包含異烷烴、礦物油、揮發性聚矽氧化合物及該等之混合物之基礎油,以固定比率含有泛醇等親水性材料及特定之液體醇之非水系毛髮護理組合物。於該文獻中揭示有該組合物可降低油膩之觸感,並且使親水性材料溶解於基礎油中,維持透明之外觀。 (專利文獻1)日本專利特開2011-195471號公報 (專利文獻2)日本專利特開2015-003886號公報 (專利文獻3)日本專利特表2014-527507號公報In recent years, the hairstyles consumers expect are changing. Therefore, the performance required for the hair styling agent can be changed from the previous formation of the polymer by the adhesive polymer or the film to change the hair to maintain the natural tidyness, and the sense of the hair after the care is also relatively good. Soft and natural. In response to such requirements, there are non-aqueous hair cosmetics, especially those generally referred to as hair oils. However, especially recently, women have sought the following hair styling agents: there is no feeling of discomfort represented by the dryness or greasy feeling of hair, and the feeling of the hand such as unmodified hair has no hair sensation and is Natural appearance, and combing is better and neat. Therefore, it is expected that the improvement of the following problems becomes louder: due to the oil contained in the hair oil, the surface of the oil is temporarily moisturized when it is applied to the hair as a whole and after application; The unnatural hair has a residual sensation; the appearance of the hair or the touch of the hand is thick, and the stickyness remains. In order to eliminate the above problems in the hair oil, for example, Patent Document 1 discloses a hair care oil which is modified with a polyether of a specific structure, a polyoxymethylene, a volatile oil and an ethanol. It is disclosed in the literature that the greasy feeling immediately after application of the hair oil is eliminated, the hair wettability is better, and the dry feeling over time is improved. Further, Patent Document 2 discloses a quick-drying hair oil containing a specific isoparaffinic hydrocarbon and a specific hydrocarbon. It is disclosed in the literature that by applying the quick-drying hair oil to moist hair, the time for drying the hair can be shortened, and the dry hair can be moisturized. Patent Document 3 discloses a base oil containing a large amount of a base oil containing an isoparaffin, a mineral oil, a volatile polyoxo compound, and the like, and a hydrophilic material such as panthenol and a specific liquid alcohol in a fixed ratio. Hair care composition. It is disclosed in this document that the composition reduces the greasy feel and dissolves the hydrophilic material in the base oil to maintain a transparent appearance. (Patent Document 1) Japanese Patent Laid-Open Publication No. JP-A No. Hei. No. Hei. No. Hei. No. Hei.

本發明提供一種毛髮化妝品,其含有以下之成分(A)~(C),成分(A)與成分(B)之質量比(A)/(B)為0.8以上且99以下,水之含量未達5質量%。 (A):碳數1~4之一元醇 (B):選自由通式(1)所表示之碳數9~21之液狀油及數量平均分子量100以上且1500以下之聚矽氧所組成之群中的親油性溶劑 [化1][式中,R1 ~R8 分別獨立地表示氫原子或甲基。X表示-CH2 -、-COO-或-CH2 COO-。n表示1~7,m表示0~2,l表示0~2,n+m+l為1~7。其中,於m及l均為1以上時,R4 ~R7 中之任一者為甲基] (C):碳數14~24之支鏈狀飽和或直鏈狀不飽和之脂肪族醇或該等之醚The present invention provides a hair cosmetic comprising the following components (A) to (C), wherein the mass ratio (A)/(B) of the component (A) to the component (B) is 0.8 or more and 99 or less, and the water content is not Up to 5 mass%. (A): one or more carbon atoms (B): a liquid oil having a carbon number of 9 to 21 represented by the formula (1) and a polyoxanium having a number average molecular weight of 100 or more and 1,500 or less. Lipophilic solvent in the group [Chemical 1] [wherein, R 1 to R 8 each independently represent a hydrogen atom or a methyl group. X represents -CH 2 -, -COO- or -CH 2 COO-. n represents 1 to 7, m represents 0 to 2, l represents 0 to 2, and n + m + l is 1 to 7. In the case where both m and l are 1 or more, any of R 4 to R 7 is a methyl group] (C): a branched or saturated unsaturated alcohol having a carbon number of 14 to 24 Or such ethers

關於專利文獻1~3之護髮油,於塗佈於洗髮後之濕潤頭髮之情形時,可賦予乾燥後之整齊感或潤髮效果,但於塗佈於乾燥頭髮之情形時,潤濕擴散性不充分,故而存在乾燥後之整齊度或梳理性之良好程度不充分之問題。又,若以可均勻地塗佈於毛髮整體之方式塗佈充分之量,則亦有於乾燥後厚重感或髮束感殘留之問題。又,於專利文獻1中,關於因揮發性油而產生之不自然之髮束感或厚重感,仍然殘留問題,於專利文獻2及3中,即便可加快洗髮後之濕潤之毛髮之水的蒸發速度,於塗佈於乾燥頭髮後至乾燥為止之期間,因揮發性油分所引起之不自然之手觸感亦較強,有改善之餘地。 本發明者等人認為上述非水系毛髮化妝品之問題主要在於塗佈後揮發性油揮發需要時間之方面,並進行研究,結果發現若將特定之親油性溶劑及低級醇設為特定比率,則毛髮化妝品中所包含之聚合物或其他成分極為快速地較薄且均勻地潤濕擴散,其結果為,不會給毛髮帶來不自然之髮束感或厚重感,於剛塗佈後、乾燥後均具有良好之觸感。 但是,於該毛髮化妝品於使用中或保管中吸收大氣中之水蒸氣之情形時,有產生發生分離或白濁之問題之情形。 因此,本發明係關於一種毛髮化妝品,其係於塗佈於乾燥頭髮時,於塗佈後立即乾燥,不會帶來乾澀感或油膩感,於乾燥後可不打造髮束而使毛髮自然地整齊,進而,即便於在使用中或保存中混入水之情形時,亦不易產生外觀之劣化。 本發明者等人發現:若使以特定比率含有特定之親油性溶劑及低級醇之非水系毛髮化妝品中含有支鏈飽和或直鏈狀不飽和之脂肪族醇或其醚,則即便於在使用中或保存中混入水之情形時,亦不易產生外觀之劣化,進而塗佈後之觸感亦變得良好,從而完成發明。 本發明之毛髮化妝品由於極為快速地較薄且均勻地潤濕擴散,故而於塗佈毛髮化妝品後快速地乾燥,不存在乾澀感或黏膩感,亦不會感覺到油膩感。又,於乾燥後可帶來自然之整齊感,而不會給毛髮帶來不自然之髮束感或厚重感。進而,不易產生因於使用中及保存中混入水分之情形所引起之毛髮化妝品之外觀劣化。 [成分(A):碳數1~4之一元醇] 成分(A)係藉由與成分(B)之組合而控制毛髮化妝品之潤濕擴散性及毛髮上之乾燥速度的成分。作為成分(A)之碳數1~4之一元醇,可使用飽和或不飽和之脂肪族醇。該等一元醇可單獨使用1種,或者組合2種以上而使用。作為醇,較佳為乙醇、丙醇、異丙醇、第三丁醇,更佳為乙醇、異丙醇,進而較佳為乙醇。 就乾燥之速度、不存在髮束感之觀點而言,本發明之毛髮化妝品中之成分(A)之含量較佳為45質量%以上,更佳為55質量%以上,進而較佳為60質量%以上,又,就塗佈後不存在乾澀感之觀點而言,較佳為98質量%以下,更佳為90質量%以下,進而較佳為80質量%以下,進而較佳為75質量%以下。 [成分(B):特定之親油性溶劑] 成分(B)係選自由(B1)通式(1)所表示之碳數9~21之液狀油、及(B2)數量平均分子量100以上且1500以下之聚矽氧所組成之群中的親油性溶劑。成分(B)係藉由與成分(A)之組合而控制毛髮化妝品之潤濕擴散性之成分。又,藉由與成分(A)之組合,於塗佈於毛髮後不會帶來不舒適之存在感,帶來清爽之自然之觸感。 ・(B1)通式(1)所表示之碳數9~21之液狀油 成分(B1)之液狀油係由以下之通式(1)表示。 [化2][式中,R1 ~R8 分別獨立地表示氫原子或甲基。X表示-CH2 -、-COO-或-CH2 COO-。n表示1~7,m表示0~2,l表示0~2,n+m+l為1~7。其中,於m及l均為1以上時,R4 ~R7 中之任一者為甲基] 作為此種成分(B1),較佳為異十二烷、氫化聚異丁烯、異壬酸異壬酯、異硬脂酸異丙酯,更佳為異十二烷、氫化聚異丁烯、異壬酸異壬酯,進而較佳為異十二烷、氫化聚異丁烯。 作為較佳之液狀油,可列舉X為-CH2 -、m為0、l為0、n為1~3之異十二烷及氫化聚異丁烯。作為此種異十二烷,可列舉於通式(1)中R1 、R2 及R8 為甲基、R3 為氫原子、n=1之異十二烷(Marukasol R,丸善石油化學股份有限公司)。又,於為氫化聚異丁烯之情形時,通式(1)中之n表示括號內之異丁烯之平均聚合度,更佳為1~2,進而較佳為1。作為此種化合物,可列舉:於通式(1)中R1 、R2 及R3 為甲基、R8 為氫原子、n=1之氫化聚異丁烯(Parleam 3,日油股份有限公司);R1 、R2 及R3 為甲基、R8 為氫原子、n=2之氫化聚異丁烯(Parleam 4,日油股份有限公司)。成分(B1)可單獨使用任一者或者組合2種以上而使用。 ・(B2)數量平均分子量100以上且1500以下之聚矽氧 成分(B2)係數量平均分子量100以上且1500以下之聚矽氧。就塗佈後之潤滑性、梳理性較佳之觀點而言,數量平均分子量較佳為150以上,更佳為200以上。又,就乾燥後不存在髮束感、輕盈感之觀點而言,較佳為1000以下,更佳為700以下,更佳為500以下。 又,就乾燥後之輕盈感之觀點、及乾燥後不會帶來毛髮化妝品之不舒適之存在感之觀點而言,成分(B2)較佳為揮發性聚矽氧。揮發性聚矽氧係WHO(World Health Organization,世界衛生組織)規定之高揮發性有機化合物、揮發性有機化合物,為沸點為260℃以下之聚矽氧。又,作為揮發性聚矽氧,較佳為沸點為50℃以上者。 作為此種聚矽氧,例如可列舉:八甲基環四矽氧烷、十甲基環五矽氧烷、十二甲基環六矽氧烷、甲基環聚矽氧烷等環狀聚矽氧;八甲基三矽氧烷、十四甲基六矽氧烷、甲基三甲聚矽氧烷、25℃下之動黏度例如為0.5 mm2 /s以上且10 mm2 /s以下之甲基聚矽氧烷等鏈狀聚矽氧等。其中,較佳為十甲基環五矽氧烷、甲基三甲聚矽氧烷、25℃下之動黏度為0.5 mm2 /s以上且未達6 mm2 /s之甲基聚矽氧烷等鏈狀聚矽氧,更佳為十甲基環五矽氧烷、甲基三甲聚矽氧烷。成分(B2)可單獨使用任一者或者組合2種以上而使用。 ・含量、質量比 作為成分(B),可僅使用成分(B1)、成分(B2)中之任一者,亦可組合成分(B1)及成分(B2)而使用。就塗佈後之潤滑性、梳理性較佳之觀點而言,本發明之毛髮化妝品中之成分(B)之含量較佳為1質量%以上,更佳為10質量%以上,進而較佳為20質量%以上,進而較佳為25質量%以上,又,就乾燥後不存在髮束感、輕盈感之觀點而言,較佳為52質量%以下,更佳為45質量%以下,進而較佳為40質量%以下,進而較佳為35質量%以下。 進而,本發明之毛髮化妝品中之成分(A)與成分(B)之質量比(A)/(B)為0.8以上且99以下。於使用成分(B1)作為成分(B)之情形時,於該範圍內,不論本發明之毛髮化妝品為親水表面或疏水表面,均表現出快速地於表面進行潤濕擴散之特異之性質。因此,推測獲得不論為健康頭髮或損傷之毛髮,均於將毛髮化妝品應用於毛髮表面之瞬間自發且快速地於毛髮表面進行潤濕擴散,並且毛髮化妝品於毛髮表面快速地乾燥之毛髮化妝品。另一方面,於作為成分(B),使用成分(B2)之情形時、併用(B1)及(B2)之情形時,於該範圍內,本發明之毛髮化妝品不論為親水表面或疏水表面、即不論為健康頭髮或損傷之毛髮,若應用於毛髮,則均表現出毛髮化妝品橫向擴散,並且自上往下於毛髮表面自發地移動之性質。因此,推測獲得毛髮化妝品自發且快速地於毛髮表面進行潤濕擴散,並且毛髮化妝品於毛髮表面快速地乾燥之毛髮化妝品。 因此,於使用成分(B1)、成分(B2)中之任一者之情形時,均於塗佈後快速地進行潤濕擴散,故而不易形成髮束,又,毛髮化妝品之不舒適之存在感快速地消失,為於乾燥後未沾上任何東西之如未經修飾之頭髮之手觸感,並且帶來自然之整齊感。進而,於塗佈時不存在表面膩滑感或黏滑感,亦不會感覺到油膩感。就進一步提昇該效果之觀點而言,成分(A)與成分(B)之質量比(A)/(B)較佳為1以上,更佳為1.2以上,進而較佳為1.5以上,進而較佳為2以上,且較佳為50以下,更佳為30以下,進而較佳為10以下,進而較佳為5以下。 [成分(C):碳數14~24之支鏈狀飽和或直鏈狀不飽和之脂肪族醇或該等之醚] 成分(C)係抑制因混入至毛髮化妝品中之水分所引起之外觀劣化之成分,為碳數14~24之支鏈狀飽和或直鏈狀不飽和之脂肪族醇或該等之醚。其中,作為支鏈狀飽和之脂肪族醇,可列舉:己基癸醇、16-甲基十七烷醇、辛基癸醇、癸基辛醇等異硬脂醇、2-辛基十二烷醇、2-癸基十四烷醇等,作為直鏈狀不飽和之脂肪族醇,可列舉油醇等。又,作為醚,可列舉異硬脂基甘油醚。於該等中,較佳為異硬脂醇、異硬脂基甘油醚,更佳為異硬脂醇。 就於使用中及保存中不會產生毛髮化妝品之外觀劣化之觀點而言,本發明之毛髮化妝品中之成分(C)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,進而較佳為1質量%以上,進而較佳為2質量%以上,又,就乾燥後不存在不舒適之存在感之觀點而言,較佳為10質量%以下,更佳為8質量%以下,進而較佳為6質量%以下。 [成分(D):於水或乙醇中具有溶解性或分散性之毛髮化妝品用聚合物] 本發明之毛髮化妝品可進而含有於水或乙醇中具有溶解性或分散性之毛髮化妝品用聚合物作為成分(D)。作為成分(D),就可穩定地存在於如成分(A)之具有極性之溶劑中之觀點而言,較佳為即便不使用界面活性劑,亦溶解或穩定地分散於水或乙醇中者。該成分(D)係藉由本發明之構成而均勻地塗佈於毛髮表面上,藉此可於乾燥後給毛髮帶來自然之整齊感或自然之觸感,而不會感覺到來自聚合物之不舒適之存在感之成分。作為此種於水或乙醇中具有溶解性或分散性之毛髮化妝品用聚合物,較佳為覆膜形成聚合物或聚醚改性聚矽氧。 就進一步加強乾燥後之整齊感之觀點而言,較佳為使用覆膜形成聚合物作為成分(D)。作為可用於成分(D)之皮膜形成聚合物,只要為於水或乙醇中具有溶解性或分散性者則並無特別限定,可使用自整髮劑中一般使用之定型力較高者至定型力相對較低者之任一者。 作為此種覆膜形成聚合物,可列舉:聚矽氧系接枝聚合物、胺基甲酸酯系高分子化合物、聚乙烯吡咯啶酮系高分子化合物、陰離子性乙烯醚系高分子化合物、陰離子性聚乙酸乙烯酯系高分子化合物、陰離子性(甲基)丙烯酸系高分子化合物、兩性(甲基)丙烯酸系高分子化合物、非離子性(甲基)丙烯酸系高分子化合物、陽離子性(甲基)丙烯酸系高分子化合物、順丁烯二醯亞胺系高分子化合物等。 作為聚矽氧系接枝聚合物,可列舉:聚(N-甲醯基伸乙基亞胺)有機聚矽氧烷、聚(N-乙醯基伸乙基亞胺)有機聚矽氧烷、聚(N-丙醯基伸乙基亞胺)有機聚矽氧烷等多聚矽氧-9;多聚矽氧-28等國際公開第2014/002707號記載之有機聚矽氧烷接枝聚合物;KP-545(信越化學工業公司)等丙烯酸烷基酯共聚物甲基聚矽氧烷酯;Silsoft Spread TT(邁圖公司)等多聚矽氧-17;Luviflex Silk(BASF公司)等丙烯酸烷基酯-甲基丙烯酸-聚矽氧共聚物等。於該等中,就定型性、乾燥時不存在黏膩性、塗佈後之柔軟性、塗佈後之梳理性之觀點而言,更佳為聚(N-甲醯基伸乙基亞胺)有機聚矽氧烷、聚(N-乙醯基伸乙基亞胺)有機聚矽氧烷、聚(N-丙醯基伸乙基亞胺)有機聚矽氧烷等多聚矽氧-9;多聚矽氧-28等國際公開第2014/002707號記載之有機聚矽氧烷接枝聚合物、KP-545(信越化學工業公司)等丙烯酸烷基酯共聚物甲基聚矽氧烷酯。 作為胺基甲酸酯系高分子化合物,可列舉:Luviset P.U.R.(BASF Japan公司)等聚胺基甲酸酯;Dynam X(AkzoNobel公司)等聚胺基甲酸酯-14-AMP(adenosine monophosphate,單磷酸腺苷)-丙烯酸酯共聚物。 作為聚乙烯吡咯啶酮系高分子化合物,可列舉:Luviskol K12、Luviskol K17、Luviskol K30、Luviskol L60、Luviskol K80、Luviskol K90(BASF公司);PVP K15、PVP K17、PVP K30、PVP K60、PVP K90、PVP K120(以上為Ashland公司)等聚乙烯吡咯啶酮;Luviskol VA28、Luviskol VA37、Luviskol VA55、Luviskol VA64P、Luviskol VA73(以上為BASF公司);Luviskol Plus(BASF公司)等聚乙烯基己內醯胺;PVP/VA E-735、PVP/VA E-635、PVP/VA E-535、PVP/VA E-335、PVP/VA S-630、PVP/VA W-735(以上為Ashland公司)等(乙烯吡咯啶酮/乙酸乙烯酯)共聚物;Luviskol VAP343(BASF公司)等聚乙烯吡咯啶酮/乙酸乙烯酯/丙酸乙烯酯三元共聚物;Luviflex(BASF公司);Copolymer 845、Copolymer 937、Copolymer 958(以上為Ashland公司)等聚乙烯吡咯啶酮/二甲基胺基甲基/丙烯酸共聚物;Copolymer VC-713(Ashland公司)等聚乙烯吡咯啶酮/甲基丙烯酸二甲基胺基乙酯/乙烯基己內醯胺共聚物;Luviset Clear(BASF公司)等(VP(vinylpyrrolidone,乙烯吡咯啶酮)/甲基丙烯醯胺/乙烯基咪唑)共聚物;Luviquat HM552(BASF公司)等偏氯化乙烯基咪唑鎓/乙烯吡咯啶酮共聚物等。於該等中,就剛塗佈後之順滑性、定型性、乾燥時不存在黏膩性、塗佈後之柔軟性之觀點而言,更佳為(乙烯吡咯啶酮/乙酸乙烯酯)共聚物、聚乙烯吡咯啶酮。 作為陰離子性乙烯醚系高分子化合物,可列舉:Gantrez ES-225(Ashland公司)等(乙烯基甲醚/順丁烯二酸乙酯)共聚物;Gantrez ES-425(Ashland公司)等(乙烯基甲醚/順丁烯二酸丁酯)共聚物等。於該等中,就定型性、乾燥時不存在黏膩性、塗佈後之柔軟性之觀點而言,較佳為(乙烯基甲醚/順丁烯二酸丁酯)共聚物。 作為陰離子性聚乙酸乙烯酯系高分子化合物,可列舉:Resin 28-1310(AkzoNobel公司)、Luviset CA66(BASF公司)等乙酸乙烯酯/丁烯酸共聚物;Resin 28-2930(AkzoNobel公司)等(乙酸乙烯酯/丁烯酸/新癸酸乙烯酯)共聚物;Luviset CAP(BASF公司)等乙酸乙烯酯/丁烯酸/丙酸乙烯酯共聚物等。 作為陰離子性(甲基)丙烯酸系高分子化合物,可列舉:Plas-size L-53P、Plas-size L-9540B(以上為互應化學工業公司)等丙烯酸系樹脂烷醇胺溶液;Diahold(三菱化學公司)等丙烯酸/丙烯酸酯共聚物;Ultrahold 8、Ultrahold strong(以上為BASF公司)、或Amphomer V-42、Dermacryl 79(以上為AkzoNobel公司)等丙烯酸/丙烯醯胺/丙烯酸乙酯共聚物;Aniset NF-1000、Aniset HS-3000(以上為大阪有機化學工業公司)等丙烯酸烷基酯共聚物等。 作為兩性(甲基)丙烯酸系高分子化合物,可列舉:Yukaformer M-75、Yukaformer R205、Yukaformer 301、Yukaformer SM(以上為三菱化學公司)、RAM Resin(大阪有機化學公司)等(甲基丙烯醯氧基乙基羧基甜菜鹼/甲基丙烯酸烷基酯)共聚物;Amphomer 28-4910、Amphomer LV-71(以上為AkzoNobel公司)等(辛基丙烯醯胺/丙烯酸羥基丙酯/甲基丙烯酸丁基胺基乙酯)共聚物;Amphomer HC(AkzoNobel公司)等(丙烯酸烷基酯/辛基丙烯醯胺)共聚物;Diaformer Z-651(三菱化學公司)等(丙烯酸酯/丙烯酸月桂酯/丙烯酸硬脂酯/甲基丙烯酸乙基胺氧化物)共聚物等。於該等中,就定型性、乾燥時不存在黏膩性、塗佈後之柔軟性之觀點而言,較佳為(甲基丙烯醯氧基乙基羧基甜菜鹼/甲基丙烯酸烷基酯)共聚物。 作為非離子性(甲基)丙烯酸系高分子化合物,可列舉:Plas-size L-2700、Plas-size L-2714(以上為互應化學工業公司)等(二甲基丙烯醯胺/丙烯酸羥基乙酯/丙烯酸甲氧基乙酯)共聚物等。 作為陽離子性(甲基)丙烯酸系高分子化合物,可列舉:日本專利特開平2-180911號公報中記載之烷基丙烯醯胺/丙烯酸酯/烷基胺基烷基丙烯醯胺/聚乙二醇甲基丙烯酸酯共聚物;日本專利特開平8-291206號公報中記載之烷基丙烯醯胺/烷基胺基烷基丙烯醯胺/聚乙二醇甲基丙烯酸酯共聚物;Plas-size L-515(互應化學工業公司)等聚四級銨鹽-99;Aquaflex SF-40(Ashland公司)等(PVP(polyvinyl pyrrolidone,聚乙烯吡咯啶酮)/乙烯基己內醯胺/丙烯酸DMAPA(dimethyl amino propyl amine,二甲基胺基丙胺))共聚物;Styleze CC-10(Ashland公司)等(乙烯吡咯啶酮/丙烯酸DMAPA)共聚物;Luviquat PQ11(BASF公司)、Gafquat 734、Gafquat 755(以上為Ashland公司)等乙烯吡咯啶酮/甲基丙烯酸二甲基胺酯共聚物之四級化物(聚四級銨鹽-11)。其中,較佳為日本專利特開平2-180911號公報中記載之烷基丙烯醯胺/丙烯酸酯/烷基胺基烷基丙烯醯胺/聚乙二醇甲基丙烯酸酯共聚物、日本專利特開平8-291206號公報中記載之烷基丙烯醯胺/烷基胺基烷基丙烯醯胺/聚乙二醇甲基丙烯酸酯共聚物、聚四級銨鹽-11。 作為順丁烯二醯亞胺系高分子化合物,可列舉:Aquaflex FX-64(ISP Japan公司)等(異丁烯/乙基順丁烯二醯亞胺/羥基乙基順丁烯二醯亞胺)共聚物。 於該等覆膜形成聚合物中,就定型性、乾燥時不存在黏膩性、塗佈後之柔軟性之觀點而言,更佳為聚矽氧系接枝聚合物、聚乙烯吡咯啶酮系高分子化合物、陰離子性聚乙酸乙烯酯系高分子化合物、兩性(甲基)丙烯酸系高分子化合物、非離子性(甲基)丙烯酸系高分子、陽離子性(甲基)丙烯酸系化合物。 另一方面,就剛塗佈後不存在乾澀感、進一步提昇乾燥後之整齊度之觀點而言,較佳為使用聚醚改性聚矽氧作為成分(D)。作為可用於成分(D)之聚醚改性聚矽氧,只要為具有於水或乙醇中之溶解性或分散性者則並無特別限定,可列舉:聚氧乙烯改性聚矽氧、聚丙烯改性聚矽氧、聚氧乙烯/聚氧丙烯改性聚矽氧、聚甘油改性聚矽氧等,作為改性之形式,可列舉側鏈型(側鏈改性型)及直鏈共聚合型等。 作為此種聚醚改性聚矽氧,較佳為具有有機矽氧烷鏈與聚伸烷基鏈之嵌段鏈之共聚物,可列舉:Silsoft A+(邁圖公司)等(PEG(polyethylene glycol,聚乙二醇)-40/PPG(polypropylene glycol,聚丙二醇)-8甲基胺基丙基/羥基丙基二甲聚矽氧烷)共聚物;FZ-2222、FZ-2233、CB2250(東麗道康寧公司)等多聚矽氧-13;Silwet L-8600(邁圖公司)等PEG-12二甲聚矽氧烷、Silsoft 900(邁圖公司)等PPG-12二甲聚矽氧烷;Silsoft 860(邁圖公司)等PEG-10二甲聚矽氧烷;Silstyle 104(東麗道康寧公司)等(雙異丁基PEG-14/胺基二甲聚矽氧烷)共聚物;Silstyle 401(東麗道康寧公司)等(雙異丁基PEG/PPG-20/35/胺基二甲聚矽氧烷)共聚物;CE-8411 Smooth Plus Emulsion(東麗道康寧公司)等雙-異丙醇胺基-PG-丙基二甲聚矽氧烷/雙-異丁基PEG-14共聚物;DOW CORNING TORAY SS-3588(東麗道康寧公司)等(雙異丁基PEG-15/胺基二甲聚矽氧烷)共聚物等。其中,較佳為具有胺基改性有機聚矽氧烷鏈與聚氧伸烷基鏈之嵌段鏈之共聚物,更佳為(雙異丁基PEG-14/胺基二甲聚矽氧烷)共聚物、(雙異丁基PEG/PPG-20/35/胺基二甲聚矽氧烷)共聚物、雙-異丙醇胺基-PG-丙基二甲聚矽氧烷/雙-異丁基PEG-14共聚物、(雙異丁基PEG-15/胺基二甲聚矽氧烷)共聚物之類之直鏈共聚合型胺基-聚醚改性聚矽氧,進而較佳為(雙異丁基PEG-15/胺基二甲聚矽氧烷)共聚物。 該等覆膜形成聚合物及聚醚改性聚矽氧可單獨使用任一者或者組合2種以上而使用,就進一步提昇乾燥後之自然之整齊感及自然之觸感兩者的觀點而言,較佳為併用覆膜形成聚合物及聚醚改性聚矽氧作為成分(D)。 又,就於乾燥時不會產生黏膩性而較薄地均勻地殘留於毛髮上,進一步帶來乾燥後之自然之觸感及整齊度之觀點而言,成分(D)較佳為兩親媒性之覆膜形成聚合物或聚醚改性聚矽氧。兩親媒性之覆膜形成聚合物係以質量比計包含10%以上且98%以下之疏水部之定型聚合物,作為此種兩親媒性之覆膜形成聚合物,可列舉:多聚矽氧-9、多聚矽氧-28,尤佳為多聚矽氧-9。 就賦予乾燥後之毛髮之整齊性之觀點而言,本發明之毛髮化妝品中之成分(D)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,進而較佳為1質量%以上。又,就於乾燥後不會給毛髮帶來厚重感或髮束感,帶來自然之觸感及整齊感之觀點而言,較佳為10質量%以下,更佳為7質量%以下,進而較佳為5質量%以下。 [成分(E):高溫穩定劑] 就即便於高溫下保存,毛髮化妝品亦可不分離而穩定地保存之觀點而言,本發明之毛髮化妝品較佳為進而含有選自多元醇、脲、有機酸、聚氧伸烷基烷基葡糖苷及聚氧伸烷基甘油醚中之1種或2種以上作為成分(E)。作為較佳之多元醇,可列舉:1,3-丁二醇、甘油、聚甘油等。又,作為較佳之有機酸,可列舉:乳酸、蘋果酸、檸檬酸等。又,作為較佳之聚氧伸烷基烷基葡糖苷,可列舉:PPG-10甲基葡萄糖、PPG-20甲基葡萄糖、甲基葡萄糖10環氧乙烷、甲基葡萄糖20環氧乙烷等。又,作為較佳之聚氧伸烷基甘油醚,可列舉PEG/PPG/聚丁二醇-8/5/3甘油等。其中,就高溫保存穩定性之觀點而言,較佳為脲、乳酸、甘油,更佳為脲。 就確保高溫穩定性之觀點而言,本發明之毛髮化妝品中之成分(E)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,又,就同時實現高溫穩定性及自然之觸感之觀點而言,較佳為3質量%以下,更佳為2質量%以下。 [水] 本發明之毛髮化妝品較佳為不含有水。但是,亦有不可避免地混入微量~少量(例如0.0001質量%以上)之水之情況,於此種情形時,亦較佳為水分量較少。具體而言,水分之含量較佳為未達5質量%,更佳為未達3質量%,進而較佳為未達0.5質量%。 [任意成分] 於本發明之毛髮化妝品中,除以上所述之成分以外,亦可於不會妨礙本發明之效果之範圍內,含有成分(B)及(D)以外之化妝品用油劑。毛髮化妝品中之成分(B)及(D)以外之化妝品用油劑之含量較佳為0.1質量%以上且10質量%以下。作為此種化妝品用油劑,可列舉:蓖麻油、可可油、貂油、萼梨油、橄欖油等甘油酯類;蜂蠟、鯨蠟、羊毛脂、巴西棕櫚蠟等蠟類;肉豆蔻酸異丙酯、月桂酸己酯、乳酸鯨蠟酯、丙二醇單硬脂酸酯、油酸油酯、2-乙基己酸十六烷基酯、肉豆蔻酸辛基十二烷基酸之酯類;二甲基聚矽氧烷、甲基苯基聚矽氧烷、環氧改性聚矽氧油、胺基改性聚矽氧油、烷基改性聚矽氧油等除成分(B)及(D)中所包含者以外之聚矽氧衍生物等。 進而,於本發明之毛髮化妝品中,為了提高商品價值,可含有香料或色素,為了防止毛髮化妝品之經日變質,可含有防腐劑或抗氧化劑,又,亦可進而視需要含有界面活性劑、硬化劑、防靜電劑、消泡劑、分散劑、增黏劑、紫外線吸收劑、抗氧化劑、防腐劑、有色染料、染料固定劑、噴射劑等。 [劑型] 作為本發明之毛髮化妝品之劑型,並無特別限制,可為透明液狀、乳狀、乳液狀、霧狀(髮妝水噴霧、造型噴霧)、泡狀(慕絲)等,其中,較佳為採用以霧狀之形態進行塗佈之劑型,更佳為非氣溶膠型之劑型。再者,於採用非氣溶膠毛髮化妝品之情形時,就於成分(A)及成分(B)兩者中之分散性或溶解性優異之觀點而言,成分(D)較佳為兩親媒性之覆膜形成聚合物或聚醚改性聚矽氧。 再者,於以包含氣溶膠原液及噴射劑之氣溶膠式毛髮化妝品之形式使用本發明之毛髮化妝品之情形時,各成分之含量係指不包含噴射劑之氣溶膠原液之總組成中的含量。 本發明之毛髮化妝品可根據劑型填充於任意之容器而使用。本發明之毛髮化妝品即便於混入水之情形時,亦不易產生外觀劣化,故而容器之材質只要為毛髮化妝品之領域中一般使用者,則可為任一種,即便為具有透濕性之材質之容器、例如塑膠製容器,亦可較佳地使用,就該方面而言優異。 [整髮方法] 本發明之毛髮化妝品可較佳地用作整髮劑。作為整髮劑之使用方法、即整髮方法,只要為將本發明之毛髮化妝品應用於毛髮,整理髮型之方法,則亦可採用任一種方法。本發明之毛髮化妝品可應用於濕潤頭髮,亦可應用於乾燥頭髮,較佳為應用於乾燥頭髮。 例如較佳為霧狀地直接塗佈毛髮化妝品,一面藉由手指梳理或藉由梳子、刷子等進行梳理一面整理毛髮之形狀。 關於以上所述之實施形態,以下,進而揭示本發明之較佳之態樣。 <1> 一種毛髮化妝品,其含有以下之成分(A)~(C),成分(A)與成分(B)之質量比(A)/(B)為0.8以上且99以下,水之含量未達5質量%, (A):碳數1~4之一元醇 (B):選自由通式(1)所表示之碳數9~21之液狀油及數量平均分子量為100以上且1500以下之聚矽氧所組成之群中的親油性溶劑 [化3][式中,R1 ~R8 分別獨立地表示氫原子或甲基;X表示-CH2 -、-COO-或-CH2 COO-;n表示1~7,m表示0~2,l表示0~2,n+m+l為1~7;其中,於m及l均為1以上時,R4 ~R7 中之任一者為甲基] (C):碳數14~24之支鏈狀飽和或直鏈狀不飽和之脂肪族醇或該等之醚。 <2> 如<1>記載之毛髮化妝品,其中較佳為成分(A)為乙醇、丙醇、異丙醇、第三丁醇,更佳為乙醇、異丙醇,進而較佳為乙醇。 <3> 如<1>或<2>記載之毛髮化妝品,其中成分(A)之含量較佳為45質量%以上,更佳為55質量%以上,進而較佳為60質量%以上,且較佳為98質量%以下,更佳為90質量%以下,進而較佳為80質量%以下,進而較佳為75質量%以下。 <4> 如<1>至<3>中任一項記載之毛髮化妝品,其中成分(B)之通式(1)所表示之碳數9~21之液狀油較佳為異十二烷、氫化聚異丁烯、異壬酸異壬酯、異硬脂酸異丙酯,較佳為異十二烷、氫化聚異丁烯、異壬酸異壬酯,更佳為異十二烷、氫化聚異丁烯。 <5> 如<1>至<4>中任一項記載之毛髮化妝品,其中成分(B)之通式(1)所表示之碳數9~21之液狀油較佳為R1 、R2 及R3 為甲基、R8 為氫原子、n=1之氫化聚異丁烯,或R1 、R2 及R3 為甲基、R8 為氫原子、n=2之氫化聚異丁烯。 <6> 如<1>至<5>中任一項記載之毛髮化妝品,其中成分(B)之聚矽氧之數量平均分子量較佳為150以上,更佳為200以上,且較佳為1000以下,更佳為700以下,更佳為500以下。 <7> 如<1>至<6>中任一項記載之毛髮化妝品,其中成分(B)之聚矽氧較佳為揮發性聚矽氧。 <8> 如<1>至<7>中任一項記載之毛髮化妝品,其中成分(B)之含量較佳為1質量%以上,更佳為10質量%以上,進而較佳為20質量%以上,進而較佳為25質量%以上,且較佳為52質量%以下,更佳為45質量%以下,進而較佳為40質量%以下,進而較佳為35質量%以下。 <9> 如<1>至<8>中任一項記載之毛髮化妝品,其中成分(A)與成分(B)之質量比(A)/(B)較佳為1以上,更佳為1.2以上,進而較佳為1.5以上,進而較佳為2以上,且較佳為50以下,更佳為10以下,進而較佳為5以下。 <10> 如<1>至<9>中任一項記載之毛髮化妝品,其中成分(C)較佳為異硬脂醇、2-辛基十二烷醇、2-癸基十四烷醇、油醇、異硬脂基甘油醚,更佳為異硬脂醇、異硬脂基甘油醚,進而較佳為異硬脂醇。 <11> 如<1>至<10>中任一項記載之毛髮化妝品,其中成分(C)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,進而較佳為1質量%以上,進而較佳為2質量%以上,且較佳為10質量%以下,更佳為8質量%以下,進而較佳為6質量%以下。 <12> 如<1>至<11>中任一項記載之毛髮化妝品,其中較佳為進而含有於水或乙醇中具有溶解性或分散性之毛髮化妝品用聚合物作為成分(D)。 <13> 如<12>記載之毛髮化妝品,其中成分(D)較佳為覆膜形成聚合物或聚醚改性聚矽氧。 <14> 如<12>或<13>記載之毛髮化妝品,其中成分(D)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,進而較佳為1質量%以上,且較佳為10質量%以下,更佳為7質量%以下,進而較佳為5質量%以下。 <15> 如<1>至<14>中任一項記載之毛髮化妝品,其中較佳為進而含有選自多元醇、脲、有機酸、聚氧伸烷基烷基葡糖苷及聚氧伸烷基甘油醚中之1種或2種以上作為成分(E)。 <16> 如<15>記載之毛髮化妝品,其中成分(E)之含量較佳為0.1質量%以上,更佳為0.5質量%以上,且較佳為3質量%以下,更佳為2質量%以下。 <17> 如<1>至<16>記載之毛髮化妝品,其中水分之含量較佳為未達5質量%,更佳為未達3質量%,進而較佳為未達0.5質量%,進而較佳為不含有水。 <18> 如<1>至<17>中任一項記載之毛髮化妝品,其係填充於較佳為具有透濕性之材質之容器、更佳為塑膠製容器而使用。 [實施例] 以下,藉由實施例更具體地說明本發明。本發明並不限定於該等實施例。 [實施例1~12及比較例1~4] 藉由常規方法製備表1中記載之毛髮化妝品,按照以下之方法及基準進行耐水性及高溫穩定性之評價。 「耐水性評價」 作為混入水時之模型,於表1中記載之毛髮化妝品中添加水,調查不會產生白濁或分離之最大之水添加量。 1.量取表1中記載之毛髮化妝品10 g置於No.6螺旋管(Maruemu公司製造)中。 2.一面藉由攪拌器進行攪拌,一面藉由微量吸管(Research Plus V 3120,Eppendorf公司製造)滴加離子交換水每次25 μL。 3.每1次滴加即攪拌1分鐘,水均勻地溶解後,加入下一25 μL。 4.反覆進行2及3次,若水無法完全溶解而發生白濁,或者溶液發生分離則結束,將即將分離之前之合計之水添加量(μL)設為毛髮化妝品每10 g之最大之耐水性量。 「高溫穩定性評價」 於50 mL玻璃瓶(廣口標準瓶 PS-No.6;三商股份有限公司)中量取表3之毛髮化妝品40 mL,蓋上蓋子進行密封。將其靜置於50℃之恆溫槽中2小時。其後,自恆溫槽中取出,目測觀察玻璃瓶中之毛髮化妝品之情況。評價係藉由以下之基準而進行。 A:未分離 B:發生白濁,但若恢復至室溫則恢復至均勻溶液 C:發生白濁或分離,於恢復至室溫後,即便進行振盪亦不會恢復至均勻溶液 又,將耐水性試驗良好之表1中記載之毛髮化妝品填充於吉野製作所公司製造之泵壓噴霧容器(使用噴霧實施例、比較例之毛髮化妝品之情形時之平均粒徑成為60 μm的噴霧器)中,按照以下之方法及基準進行性能評價。 (評價用髮束) 藉由無化學處理歷程之日本人之較脆弱之不規則毛髮而製作長度30 cm、重量8 g之髮束。藉由40℃自來水將髮束濕潤30秒後塗佈3 g花王公司製造之Success藥用洗髮水h,使之起泡30秒後進行清洗,藉由40℃之自來水沖洗30秒。反覆進行2次該洗髮操作。繼而,塗佈下述配方所示之模型洗液3 g,使之浸潤15秒後,藉由40℃之自來水沖洗30秒。繼而,用毛巾擦乾後,於實驗室條件下自然乾燥6小時,使用所得者作為評價用髮束。 (模型洗液之組成) (評價方法) 「剛塗佈後之乾澀感之有無」 對評價用髮束整體噴霧填充於泵壓噴霧器中之各毛髮化妝品0.2 g。於噴霧後,對評價用髮束手指梳理30次。針對反覆進行1~10次手指梳理期間之乾澀感之有無,藉由以下之基準進行評價。 評價係使7名官能檢查員擇一性地選擇於藉由上述操作使用各組合物進行處理時為「不存在乾澀感」/「難以判斷屬於何者」/「存在乾澀感」中之哪一者。依序表示回答為不存在乾澀感/難以判斷屬於何者/存在乾澀感之官能檢查員之人數。 「乾燥後之髮束感之有無」 藉由與「剛塗佈後之乾澀感之有無」相同之方法進行處理,完成手指梳理後,放置3分鐘。其後,針對髮束感之有無,藉由以下之基準進行評價。 評價係使7名官能檢查員擇一性地選擇於藉由上述操作使用各組合物進行處理時為「不存在髮束感」/「稍微存在髮束感」/「存在髮束感」中之哪一者。依序表示回答為不存在髮束感/稍微存在髮束感/存在髮束感之官能檢查員之人數。 「乾燥後之整齊度」 藉由與「剛塗佈後之乾澀感之有無」相同之方法進行處理,完成手指梳理後,放置3分鐘。其後,針對整齊度,藉由以下之基準進行評價。 評價係使7名官能檢查員擇一性地選擇於藉由上述操作使用各組合物進行處理時為「整齊」/「稍微整齊」/「不整齊」中之哪一者。依序表示回答為整齊/稍微整齊/不整齊之官能檢查員之人數。 「乾燥後之整髮劑之存在感之有無」 藉由與「剛塗佈後之乾澀感之有無」相同之方法進行處理,完成手指梳理後,放置3分鐘。其後,針對因評價用髮束上之整髮劑、尤其是聚合物或油劑所引起之不舒適之存在感,藉由以下之基準進行評價。 評價係使7名官能檢查員擇一性地選擇於藉由上述操作使用各組合物進行處理時為「無存在感」/「難以判斷屬於何者」/「有存在感」中之哪一者。依序表示回答為無存在感/難以判斷屬於何者/有存在感之官能檢查員之人數。 「乾燥後之梳理性之良好程度」 藉由與「剛塗佈後之乾澀感之有無」相同之方法進行處理,完成手指梳理後,放置3分鐘。其後,針對評價用髮束之梳理性,藉由以下之基準進行評價。 評價係使7名官能檢查員擇一性地選擇於藉由上述操作使用各組合物進行處理時為「梳理性較佳」/「難以判斷屬於何者」/「梳理性較差」中之哪一者。依序表示回答為梳理性較佳/難以判斷屬於何者/梳理性較差之官能檢查員之人數。 [表1] *1:Parleam 3(日油公司製造) *2:KF-96L-5cs(信越化學工業公司製造) *3:Risonol 16SP(高級醇工業公司製造) *4:異硬脂醇EX(高級醇工業公司製造) *5:Risonol 18SP(高級醇工業公司製造) *6:Risonol 20SP(高級醇工業公司製造) *7:Risonol 24SP(高級醇工業公司製造) *8:Penetol GE-IS(花王公司製造) *9:日本專利特開2013-40162號公報之合成例1中記載之有機聚矽氧烷AThe hair oils of Patent Documents 1 to 3 can impart a feeling of tidyness or moisturization after drying when applied to wet hair after shampooing, but are wetted when applied to dry hair. The diffusibility is insufficient, so there is a problem that the degree of uniformity after drying or the degree of combability is insufficient. Further, if a sufficient amount is applied so as to be uniformly applied to the entire hair, there is a problem that a heavy feeling or a hair feel is left after drying. Further, in Patent Document 1, there is still a problem of unnatural hair sensation or heavy feeling due to volatile oil, and in Patent Documents 2 and 3, even water of moist hair after shampooing can be accelerated. The evaporation rate, during the application to dry hair until dry, is also due to the unnatural hand touch caused by volatile oil, and there is room for improvement. The inventors of the present invention considered that the problem of the above-mentioned non-aqueous hair cosmetic mainly lies in the time required for the volatile oil to volatilize after application, and studies have been conducted. As a result, it has been found that when a specific lipophilic solvent and a lower alcohol are set to a specific ratio, the hair is found. The polymer or other component contained in the cosmetic is extremely thin and evenly wetted and spread, and as a result, does not give the hair an unnatural hair sensation or a heavy feeling, just after application and after drying. Both have a good touch. However, in the case where the hair cosmetic absorbs water vapor in the atmosphere during use or storage, there is a problem that separation or white turbidity occurs. Therefore, the present invention relates to a hair cosmetic which is applied to a dry hair and dried immediately after application without causing a dry feeling or a greasy feeling. After drying, the hair can be naturally arranged without drying the hair bundle. Further, even in the case where water is mixed during use or storage, deterioration of appearance is less likely to occur. The present inventors have found that a non-aqueous hair cosmetic containing a specific lipophilic solvent and a lower alcohol in a specific ratio contains a branched or linear unsaturated aliphatic alcohol or an ether thereof, even if it is used. In the case where water is mixed in the middle or during storage, the appearance is not easily deteriorated, and the touch after application is also good, thereby completing the invention. Since the hair cosmetic of the present invention is extremely thin and uniformly wetted and spread, it is quickly dried after application of the hair cosmetic, and there is no dry feeling or sticky feeling, and no greasy feeling is felt. Moreover, after drying, it can bring a natural sense of neatness without giving the hair an unnatural hairiness or a heavy feeling. Further, it is less likely to cause deterioration in appearance of the hair cosmetic caused by the incorporation of moisture during use and during storage. [Component (A): Monohydric alcohol having 1 to 4 carbon atoms] The component (A) is a component which controls the wettability of the hair cosmetic and the drying speed on the hair by the combination with the component (B). As the monohydric alcohol having 1 to 4 carbon atoms of the component (A), a saturated or unsaturated aliphatic alcohol can be used. These monohydric alcohols may be used alone or in combination of two or more. The alcohol is preferably ethanol, propanol, isopropanol or tert-butanol, more preferably ethanol or isopropanol, and still more preferably ethanol. The content of the component (A) in the hair cosmetic of the present invention is preferably 45 mass% or more, more preferably 55 mass% or more, and still more preferably 60 mass, from the viewpoint of the speed of drying and the absence of hair sensation. In addition, it is preferably 98% by mass or less, more preferably 90% by mass or less, further preferably 80% by mass or less, and further preferably 75% by mass, from the viewpoint of having no dry feeling after application. the following. [Component (B): specific lipophilic solvent] The component (B) is selected from the group consisting of a liquid oil having a carbon number of 9 to 21 represented by the formula (1) (B1), and (B2) a number average molecular weight of 100 or more. a lipophilic solvent in a group consisting of polyfluorenes of 1500 or less. The component (B) is a component which controls the wettability of the hair cosmetic by the combination with the component (A). Moreover, the combination with the component (A) does not cause an uncomfortable feeling after application to the hair, and brings a refreshing natural touch. (B1) The liquid oil of the liquid oil component (B1) having a carbon number of 9 to 21 represented by the formula (1) is represented by the following general formula (1). [Chemical 2] [where, R 1 ~R 8 Each represents a hydrogen atom or a methyl group independently. X means -CH 2 -, -COO- or -CH 2 COO-. n represents 1 to 7, m represents 0 to 2, l represents 0 to 2, and n + m + l is 1 to 7. Wherein, when both m and l are 1 or more, R 4 ~R 7 Any one of them is methyl] as such a component (B1), preferably isododecane, hydrogenated polyisobutylene, isodecyl isononanoate, isopropyl isostearate, and more preferably isodecyl The alkane, hydrogenated polyisobutylene, isodecyl isononanoate, and more preferably isododecane or hydrogenated polyisobutylene. As a preferred liquid oil, X is -CH 2 -, m is 0, l is 0, n is 1 to 3 isodecane and hydrogenated polyisobutylene. As such isododecane, R in the general formula (1) can be cited. 1 , R 2 And R 8 Methyl, R 3 It is a hydrogen atom, n=1 of dodecane (Marukasol R, Maruzen Petrochemical Co., Ltd.). Further, in the case of hydrogenating polyisobutylene, n in the formula (1) represents an average degree of polymerization of isobutylene in the parentheses, more preferably 1 to 2, still more preferably 1. As such a compound, R in the general formula (1) can be mentioned. 1 , R 2 And R 3 Methyl, R 8 Hydrogenated polyisobutylene (hydrogen atom, n=1) (Parleam 3, Nippon Oil Co., Ltd.); R 1 , R 2 And R 3 Methyl, R 8 Hydrogenated polyisobutylene (Parleam 4, Nippon Oil Co., Ltd.) which is a hydrogen atom and n=2. The component (B1) may be used alone or in combination of two or more. (B2) Polyoxane component having a number average molecular weight of 100 or more and 1,500 or less and a polyoxonium component (B2) coefficient of an average molecular weight of 100 or more and 1,500 or less. The number average molecular weight is preferably 150 or more, and more preferably 200 or more from the viewpoint of better lubricity after coating and combability. Moreover, from the viewpoint of no hair sensation and lightness after drying, it is preferably 1,000 or less, more preferably 700 or less, still more preferably 500 or less. Further, the component (B2) is preferably a volatile polyfluorene from the viewpoint of the lightness after drying and the feeling of discomfort of the hair cosmetic after drying. A highly volatile organic compound or a volatile organic compound specified by the World Health Organization (WHO) is a polyfluorene having a boiling point of 260 ° C or less. Further, as the volatile polyfluorene oxide, those having a boiling point of 50 ° C or higher are preferred. Examples of such polyfluorene oxide include cyclic polycondensation such as octamethylcyclotetraoxane, decamethylcyclopentaoxane, dodecamethylcyclohexaoxane, and methylcyclopolysiloxane. Oxygen; octamethyltrioxane, tetradecyl hexaoxane, methyltrimethylpolyoxane, dynamic viscosity at 25 ° C, for example, 0.5 mm 2 /s above and 10 mm 2 Chain polyphosphonium such as methyl polyoxyalkylene below /s. Among them, decamethylcyclopentaoxane and methyltrimethylpolyoxyalkylene are preferred, and the dynamic viscosity at 25 ° C is 0.5 mm. 2 /s or more and less than 6 mm 2 The chain polyphosphoric acid such as methyl polysiloxane of /s is more preferably decamethylcyclopentaoxane or methyltrimethylpolyoxyalkylene. The component (B2) may be used alone or in combination of two or more.・Content and mass ratio As the component (B), only one of the component (B1) and the component (B2) may be used, and the component (B1) and the component (B2) may be used in combination. The content of the component (B) in the hair cosmetic of the present invention is preferably 1% by mass or more, more preferably 10% by mass or more, and still more preferably 20, from the viewpoint of the lubricity after the application and the combability. The mass% or more is more preferably 25% by mass or more, and is preferably 52% by mass or less, more preferably 45% by mass or less, and further preferably from the viewpoint of no hair sensation and lightness after drying. It is 40% by mass or less, and more preferably 35% by mass or less. Further, the mass ratio (A)/(B) of the component (A) to the component (B) in the hair cosmetic of the present invention is 0.8 or more and 99 or less. In the case where the component (B1) is used as the component (B), within this range, regardless of whether the hair cosmetic of the present invention is a hydrophilic surface or a hydrophobic surface, it exhibits a specific property of rapidly spreading and spreading on the surface. Therefore, it is presumed that hair which is healthy hair or damaged is obtained from the hair cosmetic which spontaneously and rapidly spreads on the surface of the hair at the moment when the hair cosmetic is applied to the surface of the hair, and the hair cosmetic is quickly dried on the surface of the hair. On the other hand, when the component (B2) is used as the component (B), and (B1) and (B2) are used in combination, the hair cosmetic of the present invention is a hydrophilic surface or a hydrophobic surface, That is, whether it is healthy hair or damaged hair, if applied to hair, it exhibits a lateral spread of the hair cosmetic and spontaneously moves from the top to the bottom of the hair surface. Therefore, it is presumed that a hair cosmetic which spontaneously and rapidly spreads the hair cosmetic on the surface of the hair and which is quickly dried on the surface of the hair is obtained. Therefore, when either of the component (B1) or the component (B2) is used, the wet diffusion is quickly performed after the coating, so that the hair bundle is not easily formed, and the hair cosmetic is uncomfortable. Quickly disappears, for the untouched hair of the hand after drying without any touch, and brings a natural sense of neatness. Further, there is no surface slipperiness or stickiness at the time of coating, and no greasy feeling is felt. From the viewpoint of further enhancing the effect, the mass ratio (A)/(B) of the component (A) to the component (B) is preferably 1 or more, more preferably 1.2 or more, still more preferably 1.5 or more, and further It is preferably 2 or more, and is preferably 50 or less, more preferably 30 or less, still more preferably 10 or less, still more preferably 5 or less. [Component (C): a branched or saturated unsaturated alcohol having a carbon number of 14 to 24 or such an ether] The component (C) suppresses the appearance due to moisture incorporated into the hair cosmetic. The deteriorated component is a branched or saturated unsaturated alcohol having a carbon number of 14 to 24 or such an ether. Here, examples of the branched saturated aliphatic alcohol include isostearyl alcohol such as hexyl decyl alcohol, 16-methyl heptadecyl alcohol, octyl decyl alcohol, and decyl octyl alcohol, and 2-octyldodecane. Examples of the linear unsaturated unsaturated alcohol include an alcohol, 2-mercaptotetradecyl alcohol and the like. Further, examples of the ether include isostearyl glyceryl ether. Among these, isostearyl alcohol and isostearyl glyceryl ether are preferred, and isostearyl alcohol is more preferred. The content of the component (C) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, from the viewpoint that the appearance of the hair cosmetic is not deteriorated during use and during storage. It is preferably 1% by mass or more, more preferably 2% by mass or more, and is preferably 10% by mass or less, more preferably 8% by mass or less, from the viewpoint of no uncomfortable feeling after drying. Further, it is preferably 6% by mass or less. [Component (D): a polymer for hair cosmetics having solubility or dispersibility in water or ethanol] The hair cosmetic of the present invention may further contain a polymer for hair cosmetics having solubility or dispersibility in water or ethanol. Ingredient (D). As the component (D), it can be stably present in a solvent having polarity as the component (A), and is preferably dissolved or stably dispersed in water or ethanol even without using a surfactant. . The component (D) is uniformly applied to the surface of the hair by the constitution of the present invention, whereby the hair can be brought to a natural tidy or natural touch after drying without feeling from the polymer. An ingredient that is uncomfortable. As such a hair cosmetic polymer having solubility or dispersibility in water or ethanol, a film-forming polymer or a polyether-modified polyfluorene is preferred. From the viewpoint of further enhancing the feeling of uniformity after drying, it is preferred to use a film forming polymer as the component (D). The film forming polymer which can be used for the component (D) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and a higher fixing force generally used in the hair dressing agent can be used. Any one of the relatively low forces. Examples of such a film-forming polymer include a polyoxymethylene-based graft polymer, a urethane-based polymer compound, a polyvinylpyrrolidone-based polymer compound, and an anionic vinyl ether-based polymer compound. An anionic polyvinyl acetate polymer compound, an anionic (meth)acrylic polymer compound, an amphoteric (meth)acrylic polymer compound, a nonionic (meth)acrylic polymer compound, and a cationic ( A methyl)acrylic polymer compound or a maleimide-based polymer compound. Examples of the polyoxygen-based graft polymer include poly(N-methyl fluorenylethylenimine) organopolyoxyalkylene, poly(N-ethyl fluorenylethylenimine) organopolyoxyalkylene, and poly (N-propionyl extended ethyl imine) polyorganooxy-9 such as organopolyoxyalkylene; organopolyoxyalkylene graft polymer described in International Publication No. 2014/002707; KP-545 (Shin-Etsu Chemical Industry Co., Ltd.) and other alkyl acrylate copolymers, methyl polyoxyalkylene esters; Silsoft Spread TT (Mitto Corporation) and other polyoxyl-17; Luviflex Silk (BASF) and other alkyl acrylates Ester-methacrylic acid-polyfluorene copolymer and the like. Among these, poly(N-methyl decylethylidene) is more preferable in terms of setting property, no stickiness at the time of drying, flexibility after coating, and combability after coating. Organopolyoxyalkylene, poly(N-ethinylethylidene) organopolyoxyalkylene, poly(N-propionylethylidene) organopolyoxyalkylene, and the like An alkyl polyoxyalkylene acrylate copolymer such as an organopolyoxane graft polymer described in International Publication No. 2014/002707, and KP-545 (Shin-Etsu Chemical Industries, Ltd.). Examples of the urethane-based polymer compound include polyurethanes such as Luviset PUR (BASF Japan Co., Ltd.) and polyaluminate-14-AMP (adenosine monophosphate) such as Dynam X (AkzoNobel Co., Ltd.). Adenosine monophosphate)-acrylate copolymer. Examples of the polyvinylpyrrolidone-based polymer compound include Luviskol K12, Luviskol K17, Luviskol K30, Luviskol L60, Luviskol K80, Luviskol K90 (BASF); PVP K15, PVP K17, PVP K30, PVP K60, PVP K90 , PVP K120 (above Ashland) and other polyvinylpyrrolidone; Luviskol VA28, Luviskol VA37, Luviskol VA55, Luviskol VA64P, Luviskol VA73 (above BASF); Luviskol Plus (BASF) and other polyvinyl caprolactone Amine; PVP/VA E-735, PVP/VA E-635, PVP/VA E-535, PVP/VA E-335, PVP/VA S-630, PVP/VA W-735 (above Ashland) (vinylpyrrolidone/vinyl acetate) copolymer; polyvinylpyrrolidone/vinyl acetate/vinyl propionate terpolymer such as Luviskol VAP343 (BASF); Luviflex (BASF); Copolymer 845, Copolymer 937 Polyvinylpyrrolidone/dimethylaminomethyl/acrylic acid copolymer such as Copolymer 958 (above Ashland); polyvinylpyrrolidone/methacrylic acid dimethylamine such as Copolymer VC-713 (Ashland) Ethyl ethyl ester/vinyl caprolactam copolymer; Luviset Clear (BASF Division) and the like (VP (vinylpyrrolidone, vinyl pyrrolidone) / methyl acrylamide / vinyl imidazole) copolymer; Luviquat HM552 (BASF, Inc.) vinylidene chloride, vinylimidazolium / vinyl pyrrolidone copolymer. Among these, it is more preferably (vinylpyrrolidone/vinyl acetate) from the viewpoints of smoothness after coating, setting property, no stickiness at the time of drying, and flexibility after coating. Copolymer, polyvinylpyrrolidone. Examples of the anionic vinyl ether-based polymer compound include a (vinyl vinyl ether/maleic acid ethyl ester) copolymer such as Gantrez ES-225 (Ashland Corporation), and Gantrez ES-425 (Ashland Corporation) (ethylene). Methyl ether / butyl maleate copolymer, and the like. Among these, a (vinyl methyl ether / maleic acid butyl ester) copolymer is preferred from the viewpoints of setting property, no stickiness during drying, and flexibility after coating. Examples of the anionic polyvinyl acetate-based polymer compound include vinyl acetate/butenoic acid copolymers such as Resin 28-1310 (AkzoNobel Co., Ltd.) and Luviset CA66 (BASF Co., Ltd.); and Resin 28-2930 (Akzo Nobel Co., Ltd.). (vinyl acetate/crotonic acid/vinyl neodecanoate) copolymer; vinyl acetate/butenoic acid/vinyl propionate copolymer such as Luviset CAP (BASF). Examples of the anionic (meth)acrylic polymer compound include an acrylic resin alkanolamine solution such as Plas-size L-53P or Plas-size L-9540B (above, Mutual Chemical Industry Co., Ltd.); Diahold (Mitsubishi) Acrylic/acrylic acid ester copolymer, etc.; acrylic/acrylamide/ethyl acrylate copolymer such as Ultrahold 8, Ultrahold strong (above BASF), or Amphomer V-42, Dermacryl 79 (above AkzoNobel); Aniset NF-1000, Aniset HS-3000 (above, Osaka Organic Chemical Industry Co., Ltd.) and other alkyl acrylate copolymers. Examples of the amphoteric (meth)acrylic polymer compound include Yukaformer M-75, Yukaformer R205, Yukaformer 301, Yukaformer SM (above, Mitsubishi Chemical Corporation), and RAM Resin (Osaka Organic Chemical Co., Ltd.). Oxyethylcarboxybetaine/alkyl methacrylate copolymer; Amphomer 28-4910, Amphomer LV-71 (above AkzoNobel), etc. (octyl acrylamide/hydroxypropyl acrylate/methacrylic acid butyl Aminomer ethyl ester) copolymer; Amphomer HC (AkzoNobel), etc. (alkyl acrylate/octyl acrylamide) copolymer; Diaformer Z-651 (Mitsubishi Chemical Co., Ltd.), etc. (acrylate/lauryl acrylate/acrylic acid) Stearyl ester / ethyl methacrylate oxide copolymer). Among these, (methacryloxyethyl carboxybetaine/alkyl methacrylate) is preferred from the viewpoints of stereotype, absence of stickiness upon drying, and flexibility after coating. ) Copolymer. Examples of the nonionic (meth)acrylic polymer compound include Plas-size L-2700 and Plas-size L-2714 (above, Mutual Chemical Industry Co., Ltd.) (dimethacrylamide/acrylic acid hydroxyl group). Ethyl ester / methoxyethyl acrylate copolymer and the like. Examples of the cationic (meth)acrylic polymer compound include an alkyl acrylamide/acrylate/alkylaminoalkyl acrylamide/polyethylene group described in JP-A-2-180911. Alcohol methacrylate copolymer; alkyl acrylamide/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer described in Japanese Patent Laid-Open Publication No. Hei 8-291206; Plas-size L-515 (Mujia Chemical Industry Co., Ltd.) and other polyquaternary ammonium salt-99; Aquaflex SF-40 (Ashland), etc. (PVP (polyvinyl pyrrolidone) / vinyl caprolactam / acrylic acid DMAPA (dimethyl amino propyl amine, dimethylaminopropylamine) copolymer; Styleze CC-10 (Ashland) and other (vinyl pyrrolidone / acrylic acid DMAPA) copolymer; Luviquat PQ11 (BASF), Gafquat 734, Gafquat 755 (The above is Ashland), etc., a tetracyclide (polytetra-ammonium salt-11) of a vinylpyrrolidone/dimethylammonium methacrylate copolymer. Among them, an alkyl acrylamide/acrylate/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer described in Japanese Patent Laid-Open Publication No. Hei No. 2-108911, Japanese Patent No. An alkyl acrylamide/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer or a polytetra-ammonium salt-11 described in JP-A-H09-291206. Examples of the maleimide-based polymer compound include Aquaflex FX-64 (ISP Japan), etc. (isobutylene/ethyl maleimide/hydroxyethyl maleimide) Copolymer. Among these film-forming polymers, a polyfluorene-based graft polymer or a polyvinylpyrrolidone is preferred in terms of setting property, no stickiness during drying, and flexibility after coating. A polymer compound, an anionic polyvinyl acetate polymer compound, an amphoteric (meth)acrylic polymer compound, a nonionic (meth)acrylic polymer, and a cationic (meth)acrylic compound. On the other hand, from the viewpoint of not having a dry feeling immediately after application and further improving the uniformity after drying, it is preferred to use polyether-modified polyfluorene as the component (D). The polyether-modified polyfluorene which can be used for the component (D) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and examples thereof include polyoxyethylene-modified polysiloxane and polycondensation. Propylene modified polyfluorene oxide, polyoxyethylene/polyoxypropylene modified polyfluorene oxide, polyglycerin modified polyfluorene, etc., as a modified form, side chain type (side chain modified type) and linear chain Copolymerization type, etc. As such a polyether-modified polyfluorene oxide, a copolymer having a block chain of an organic siloxane chain and a polyalkylene chain is preferred, and examples thereof include: Silsoft A+ (Moto Corporation), etc. (PEG (polyethylene glycol) , polyethylene glycol) -40/PPG (polypropylene glycol) - 8 - methylaminopropyl / hydroxypropyl dimethyl polyoxyalkylene) copolymer; FZ-2222, FZ-2233, CB2250 (east Lido Corning Company), such as polyoxyl-13; PEG-12 dimethylpolysiloxane, such as Silwet L-8600 (Moto Company), Silsoft 900 (Moto Company), etc. PPG-12 dimethyl polyoxy siloxane; Silsoft 860 (Mituto) and other PEG-10 dimercaptosiloxane; Silstyle 104 (Dolly Dow Corning) and other (bisisobutyl PEG-14 / amino dimethyl polyoxyalkylene) copolymer; Silstyle 401 (Dongli Dao Kangning Company) and other (bisisobutyl PEG/PPG-20/35/amino dimethylpolysiloxane) copolymer; CE-8411 Smooth Plus Emulsion (Dolly Dow Corning) and other double-isopropyl alcohol Amino-PG-propyl dimethyl polyoxy siloxane / bis-isobutyl PEG-14 copolymer; DOW CORNING TORAY SS-3588 (Dongli Dao Kangning company), etc. (bisisobutyl PEG-15 / amine base II A polyoxyalkylene copolymer) or the like. Among them, a copolymer having an amine-modified organopolyoxyalkylene chain and a block chain of a polyoxyalkylene chain is preferred, and more preferably (bisisobutyl PEG-14/amino dimethylpolyoxyl) Copolymer, (bisisobutyl PEG/PPG-20/35/amino dimethylpolyoxyalkylene) copolymer, bis-isopropanolamine-PG-propyl dimethylpolyoxane/double a linear copolymerized amine-polyether modified polyoxane such as an isobutyl PEG-14 copolymer or a (bisisobutyl PEG-15/aminodimethylpolysiloxane) copolymer, and further Preferred is a (bisisobutyl PEG-15/aminodimethylpolyoxane) copolymer. The film-forming polymer and the polyether-modified polyfluorene oxide may be used singly or in combination of two or more, in order to further enhance the natural sensation after drying and the natural touch. Preferably, a film-forming polymer and a polyether-modified polyfluorene oxide are used in combination as the component (D). Further, the component (D) is preferably an amphiphilic agent from the viewpoint of not being sticky at the time of drying and remaining evenly on the hair evenly, and further bringing about the natural touch and uniformity after drying. The film is formed into a polymer or polyether modified polyfluorene. The amphiphilic film-forming polymer is a styling polymer containing 10% or more and 98% or less of a hydrophobic portion in a mass ratio, and examples of such an amphiphilic film-forming polymer include polyaddition. Oxygen-9, polyoxo-28, especially polyoxy-9. The content of the component (D) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and still more preferably 1% by mass, from the viewpoint of imparting uniformity to the hair after drying. the above. Moreover, it is preferably 10% by mass or less, more preferably 7% by mass or less, from the viewpoint of imparting a feeling of naturalness and a feeling of hairiness to the hair after drying, and more preferably 7% by mass or less. It is preferably 5% by mass or less. [Component (E): High-temperature stabilizer] The hair cosmetic of the present invention preferably further contains a selected from the group consisting of a polyol, a urea, and an organic acid, from the viewpoint of being stored at a high temperature and the hair cosmetic product can be stably stored without separation. One or two or more kinds of polyoxyalkylene alkyl glucoside and polyoxyalkylene glyceryl ether are used as the component (E). Preferred examples of the polyhydric alcohol include 1,3-butylene glycol, glycerin, and polyglycerin. Moreover, as a preferable organic acid, lactic acid, malic acid, citric acid, etc. are mentioned. Further, preferred examples of the polyoxyalkylalkyl glucoside include PPG-10 methyl glucose, PPG-20 methyl glucose, methyl glucose 10 ethylene oxide, methyl glucose 20 ethylene oxide, and the like. . Further, preferred examples of the polyoxyalkylene glycol glyceryl ether include PEG/PPG/polybutylene glycol-8/5/3 glycerin. Among them, from the viewpoint of high-temperature storage stability, urea, lactic acid, glycerin, and more preferably urea are preferred. From the viewpoint of ensuring high-temperature stability, the content of the component (E) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and at the same time, high-temperature stability and naturalness are simultaneously achieved. From the viewpoint of the touch, it is preferably 3% by mass or less, and more preferably 2% by mass or less. [Water] The hair cosmetic of the present invention preferably does not contain water. However, it is also inevitable to mix a small amount to a small amount (for example, 0.0001% by mass or more) of water, and in this case, it is preferable that the amount of water is small. Specifically, the content of moisture is preferably less than 5% by mass, more preferably less than 3% by mass, still more preferably less than 0.5% by mass. [Individual component] In the hair cosmetic of the present invention, in addition to the components described above, an oil composition for cosmetics other than the components (B) and (D) may be contained within a range that does not impair the effects of the present invention. The content of the cosmetic oil agent other than the components (B) and (D) in the hair cosmetic is preferably 0.1% by mass or more and 10% by mass or less. Examples of such cosmetic oil agents include glycerides such as castor oil, cocoa butter, eucalyptus oil, avocado oil, and olive oil; waxes such as beeswax, cetyl wax, lanolin, and carnauba wax; and myristic acid. Propyl ester, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleic acid ester, cetyl 2-ethylhexanoate, ester of octyl dodecanoic acid myristate; Dimethylpolysiloxane, methylphenyl polyoxyalkylene, epoxy modified polyoxyxide oil, amine modified polyoxyxide oil, alkyl modified polyoxyl oil, etc. A polyoxyl derivative other than those contained in (D). Further, in the hair cosmetic of the present invention, in order to improve the commercial value, a fragrance or a coloring matter may be contained, and in order to prevent deterioration of the hair cosmetic, a preservative or an antioxidant may be contained, or a surfactant may be optionally contained. Hardener, antistatic agent, antifoaming agent, dispersing agent, tackifier, ultraviolet absorber, antioxidant, preservative, colored dye, dye fixing agent, propellant, etc. [Formulation] The dosage form of the hair cosmetic of the present invention is not particularly limited, and may be a transparent liquid, a milk, an emulsion, a mist (a makeup spray, a styling spray), a foam (mousse), or the like. Preferably, it is a dosage form which is applied in the form of a mist, and more preferably a non-aerosol type. Further, in the case of using a non-aerosol hair cosmetic, the component (D) is preferably an amphiphilic agent from the viewpoint of excellent dispersibility or solubility in both the component (A) and the component (B). The film is formed into a polymer or polyether modified polyfluorene. Further, in the case of using the hair cosmetic of the present invention in the form of an aerosol hair cosmetic comprising an aerosol stock solution and a propellant, the content of each component means the content in the total composition of the aerosol stock solution not containing the propellant. . The hair cosmetic of the present invention can be used by filling it in a container according to a dosage form. The hair cosmetic of the present invention is less likely to cause deterioration in appearance even when it is mixed with water. Therefore, the material of the container may be any one of the general users in the field of hair cosmetics, even if it is a container having a moisture permeability material. For example, a plastic container can also be preferably used, which is excellent in this respect. [Whole Hair Method] The hair cosmetic of the present invention can be preferably used as a hair styling agent. As a method of using the hair styling agent, that is, the hair styling method, any method may be employed as long as the hair cosmetic of the present invention is applied to the hair and the hair styling method is used. The hair cosmetic of the present invention can be applied to wet hair, and can also be applied to dry hair, preferably for drying hair. For example, it is preferable to directly apply the hair cosmetic in a mist form, and to arrange the shape of the hair by combing with a finger or combing with a comb, a brush or the like. With regard to the above-described embodiments, the preferred aspects of the present invention are further disclosed below. <1> A hair cosmetic comprising the following components (A) to (C), wherein the mass ratio (A)/(B) of the component (A) to the component (B) is 0.8 or more and 99 or less, and the water content is not 5% by mass, (A): a carbon number of 1 to 4, a monohydric alcohol (B): a liquid oil selected from the group consisting of the carbon number of 9 to 21 represented by the formula (1), and a number average molecular weight of 100 or more and 1,500 or less a lipophilic solvent in a group consisting of polyoxyl [where, R 1 ~R 8 Respectively represent a hydrogen atom or a methyl group; X represents -CH 2 -, -COO- or -CH 2 COO-;n represents 1 to 7, m represents 0 to 2, l represents 0 to 2, and n+m+l is 1 to 7; wherein, when m and l are both 1 or more, R 4 ~R 7 Any of them is a methyl group (C): a branched or saturated unsaturated alcohol having a carbon number of 14 to 24 or an ether of the same. <2> The hair cosmetic according to <1>, wherein the component (A) is preferably ethanol, propanol, isopropanol or tert-butanol, more preferably ethanol or isopropanol, and still more preferably ethanol. <3> The hair cosmetic according to <1> or <2>, wherein the content of the component (A) is preferably 45% by mass or more, more preferably 55% by mass or more, still more preferably 60% by mass or more, and more preferably It is preferably 98% by mass or less, more preferably 90% by mass or less, further preferably 80% by mass or less, and further preferably 75% by mass or less. <4> The hair cosmetic according to any one of <1> to <3>, wherein the liquid oil having a carbon number of 9 to 21 represented by the formula (1) of the component (B) is preferably isododecane. , hydrogenated polyisobutylene, isodecyl isononanoate, isopropyl isostearate, preferably isododecane, hydrogenated polyisobutylene, isodecyl isononanoate, more preferably isododecane, hydrogenated polyisobutylene . <5> The hair cosmetic according to any one of <1> to <4> wherein the liquid oil having a carbon number of 9 to 21 represented by the formula (1) of the component (B) is preferably R. 1 , R 2 And R 3 Methyl, R 8 Is a hydrogen atom, hydrogenated polyisobutylene of n=1, or R 1 , R 2 And R 3 Methyl, R 8 It is a hydrogen atom, hydrogenated polyisobutylene of n=2. <6> The hair cosmetic according to any one of <1> to <5> wherein the number average molecular weight of the polyoxane of the component (B) is preferably 150 or more, more preferably 200 or more, and preferably 1,000. Hereinafter, it is more preferably 700 or less, and still more preferably 500 or less. <7> The hair cosmetic according to any one of <1> to <6> wherein the polyfluorene oxide of the component (B) is preferably a volatile polyoxygen. The hair cosmetic according to any one of the above aspects, wherein the content of the component (B) is preferably 1% by mass or more, more preferably 10% by mass or more, and still more preferably 20% by mass. The above is more preferably 25% by mass or more, and is preferably 52% by mass or less, more preferably 45% by mass or less, still more preferably 40% by mass or less, and still more preferably 35% by mass or less. The hair cosmetic according to any one of the above aspects, wherein the mass ratio (A)/(B) of the component (A) to the component (B) is preferably 1 or more, more preferably 1.2. The above is more preferably 1.5 or more, still more preferably 2 or more, and is preferably 50 or less, more preferably 10 or less, still more preferably 5 or less. <10> The hair cosmetic according to any one of <1> to <9> wherein the component (C) is preferably isostearyl alcohol, 2-octyldodecanol or 2-decyltetradecyl alcohol. Further, oleyl alcohol or isostearyl glyceryl ether is more preferably isostearyl alcohol or isostearyl glyceryl ether, and further preferably isostearyl alcohol. The hair cosmetic according to any one of the above aspects, wherein the content of the component (C) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and still more preferably 1% by mass. The above is more preferably 2% by mass or more, and is preferably 10% by mass or less, more preferably 8% by mass or less, and still more preferably 6% by mass or less. <12> The hair cosmetic according to any one of the above aspects, wherein the hair cosmetic further contains a polymer for hair cosmetic having solubility or dispersibility in water or ethanol as the component (D). <13> The hair cosmetic according to <12>, wherein the component (D) is preferably a film-forming polymer or a polyether-modified polyfluorene. <14> The hair cosmetic according to <12> or <13>, wherein the content of the component (D) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and more preferably It is preferably 10% by mass or less, more preferably 7% by mass or less, and still more preferably 5% by mass or less. <15> The hair cosmetic according to any one of <1> to <14> which preferably further comprises a polyhydric alcohol, a urea, an organic acid, a polyoxyalkylalkyl glucoside, and a polyoxyalkylene One or two or more kinds of the glyceryl ethers are used as the component (E). <16> The hair cosmetic according to <15>, wherein the content of the component (E) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and preferably 3% by mass or less, more preferably 2% by mass. the following. <17> The hair cosmetic according to <1> to <16>, wherein the moisture content is preferably less than 5% by mass, more preferably less than 3% by mass, still more preferably less than 0.5% by mass, and further less than Jiawei does not contain water. <18> The hair cosmetic according to any one of <1> to <17>, which is filled in a container which is preferably a material having moisture permeability, and more preferably used as a plastic container. [Examples] Hereinafter, the present invention will be more specifically described by way of examples. The invention is not limited to the embodiments. [Examples 1 to 12 and Comparative Examples 1 to 4] The hair cosmetics described in Table 1 were prepared by a conventional method, and evaluation of water resistance and high-temperature stability was carried out in accordance with the following methods and standards. "Water resistance evaluation" As a model when water was mixed, water was added to the hair cosmetic described in Table 1, and the maximum amount of water added without white turbidity or separation was examined. 1. 10 g of the hair cosmetic described in Table 1 was placed in a No. 6 spiral tube (manufactured by Maruemu Co., Ltd.). 2. While stirring with a stirrer, ion-exchanged water was added dropwise by 25 μL each time by a micropipette (Research Plus V 3120, manufactured by Eppendorf). 3. Stir for 1 minute every 1 drop, dissolve the water evenly, and add the next 25 μL. 4. Repeat 2 and 3 times, if the water is not completely dissolved and it becomes cloudy, or the solution is separated, the total amount of water added before the separation (μL) is set as the maximum water resistance per 10 g of the hair cosmetic. . "High Temperature Stability Evaluation" 40 mL of the hair cosmetic of Table 3 was taken in a 50 mL glass bottle (Guangkou Standard Bottle PS-No. 6; Sanshang Co., Ltd.), and the lid was sealed for sealing. It was allowed to stand in a thermostat at 50 ° C for 2 hours. Thereafter, it was taken out from the constant temperature bath, and the condition of the hair cosmetic in the glass bottle was visually observed. The evaluation was carried out by the following criteria. A: Not separated B: White turbidity occurs, but if it returns to room temperature, it returns to a homogeneous solution C: white turbidity or separation occurs. After returning to room temperature, even if it is shaken, it will not return to a homogeneous solution. The hair cosmetic product described in Table 1 was filled in a pump spray container manufactured by Yoshino Seisakusho Co., Ltd. (a sprayer having an average particle diameter of 60 μm when sprayed with the hair cosmetic of the comparative example or the comparative example), and the following method was used. And benchmarks for performance evaluation. (Evaluation hair bundle) A hair bundle having a length of 30 cm and a weight of 8 g was produced by the irregular hair of the Japanese who had no chemical treatment. The hair bundle was wetted by tap water at 40 ° C for 30 seconds, and then coated with 3 g of the medicinal shampoo h manufactured by Kao Corporation, which was foamed for 30 seconds, washed, and rinsed with tap water at 40 ° C for 30 seconds. This shampooing operation was repeated twice. Then, 3 g of the model lotion shown in the following formulation was applied, and after soaking for 15 seconds, it was rinsed with tap water of 40 ° C for 30 seconds. Then, after drying with a towel, it was naturally dried under laboratory conditions for 6 hours, and the obtained one was used as an evaluation hair bundle. (composition of model lotion) (Evaluation method) "The presence or absence of dryness immediately after application" 0.2 g of each hair cosmetic filled in the pump sprayer for the evaluation hair bundle as a whole. After the spraying, the hairpins for evaluation were combed 30 times. The presence or absence of the dry feeling during the finger combing period of 1 to 10 times was evaluated by the following criteria. The evaluation system allows seven functional inspectors to selectively select which one of the "no dry feeling" / "difficult to judge which belongs" / "existing dry feeling" when using the respective compositions for the above operation. . The number of functional inspectors who responded in order to the absence of a dry feeling/difficult to judge who belonged/have a sense of cognac. "The presence or absence of the hair sensation after drying" was treated by the same method as "the presence or absence of dryness after application", and the fingers were combed and left for 3 minutes. Thereafter, the presence or absence of the hair bundle feeling was evaluated by the following criteria. In the evaluation, seven functional inspectors were selectively selected to use the respective compositions for the above-mentioned operation, and the treatment was performed as "no hair sensation" / "slightly hair sensation" / "existing hair sensation". Which one. The number of the functional inspectors who did not have a hair sensation/slightly a hair sensation/a hair sensation was sequentially indicated. "The degree of uniformity after drying" was treated by the same method as "the presence or absence of dryness after application", and the fingers were combed and left for 3 minutes. Thereafter, the evaluation was performed on the basis of the following criteria for the uniformity. The evaluation system selected seven functional inspectors to selectively select which one of "tidy" / "slightly neat" / "not neat" when using the respective compositions for processing by the above operation. The number of functional inspectors who are tidy/slightly neat/untidy are indicated in order. "The presence or absence of the feeling of the hair styling after drying" was treated by the same method as "the presence or absence of the dry sensation immediately after application", and the fingers were combed and left for 3 minutes. Thereafter, the feeling of discomfort caused by the hair styling agent on the hair bundle for evaluation, in particular, a polymer or an oil agent, was evaluated based on the following criteria. The evaluation system selected seven functional inspectors to selectively select which one of "no sense of presence" / "difficult to determine which belongs" / "have a sense of presence" when using the respective compositions by the above operation. The number of functional inspectors who have no sense of presence/difficult to judge who is/have a sense of presence are indicated in order. "The degree of good combability after drying" was treated by the same method as "the presence or absence of dryness after application", and the fingers were combed and left for 3 minutes. Thereafter, the combability of the hair bundle for evaluation was evaluated by the following criteria. The evaluation department selected seven functional inspectors to selectively select which one of the "comfort better" / "difficult to judge which belongs" / "poor comb" when using the respective compositions by the above operation. . In order, the answer is that the number of the inspectors who are combed better/hard to judge who is/compared to the comb. [Table 1] *1: Parleam 3 (manufactured by Nippon Oil Co., Ltd.) *2: KF-96L-5cs (manufactured by Shin-Etsu Chemical Co., Ltd.) *3: Risonol 16SP (manufactured by Advanced Alcohol Industries, Inc.) *4: Isostearyl alcohol EX (Advanced Alcohol Industry) Manufactured by the company *5: Risonol 18SP (manufactured by Advanced Alcohol Industries, Inc.) *6: Risonol 20SP (manufactured by Advanced Alcohol Industries, Inc.) *7: Risonol 24SP (manufactured by Advanced Alcohol Industries, Inc.) *8: Penetol GE-IS (manufactured by Kao Corporation) *9: The organopolyoxane A described in Synthesis Example 1 of JP-A-2013-40162

no

Claims (8)

一種毛髮化妝品,其含有以下之成分(A)~(C),成分(A)與成分(B)之質量比(A)/(B)為0.8以上且99以下,水之含量未達5質量%, (A):碳數1~4之一元醇 (B):選自由通式(1)所表示之碳數9~21之液狀油及數量平均分子量為100以上且1500以下之聚矽氧所組成之群中的親油性溶劑 [化1][式中,R1 ~R8 分別獨立地表示氫原子或甲基;X表示-CH2 -、-COO-或-CH2 COO-;n表示1~7,m表示0~2,l表示0~2,n+m+l為1~7;其中,於m及l均為1以上時,R4 ~R7 中之任一者為甲基] (C):碳數14~24之支鏈狀飽和或直鏈狀不飽和之脂肪族醇或該等之醚。A hair cosmetic comprising the following components (A) to (C), wherein the mass ratio (A)/(B) of the component (A) to the component (B) is 0.8 or more and 99 or less, and the water content is less than 5 mass. (A): a one-carbon alcohol having a carbon number of 1 to 4 (B): a liquid oil selected from the group consisting of carbon number 9 to 21 represented by the general formula (1) and a polyfluorene having a number average molecular weight of 100 or more and 1,500 or less a lipophilic solvent in a group consisting of oxygen [Chemical 1] Wherein R 1 to R 8 each independently represent a hydrogen atom or a methyl group; X represents -CH 2 -, -COO- or -CH 2 COO-; n represents 1 to 7, m represents 0 to 2, and l represents 0 to 2, n+m+l is 1 to 7; wherein, when both m and l are 1 or more, any one of R 4 to R 7 is a methyl group] (C): a branched chain of 14 to 24 carbon atoms Or a linear, unsaturated fatty alcohol or such ether. 如請求項1之毛髮化妝品,其中成分(A)之含量為45質量%以上且98質量%以下。The hair cosmetic of claim 1, wherein the content of the component (A) is 45 mass% or more and 98 mass% or less. 如請求項1或2之毛髮化妝品,其中成分(B)之含量為1質量%以上且52質量%以下。The hair cosmetic of claim 1 or 2, wherein the content of the component (B) is 1% by mass or more and 52% by mass or less. 如請求項1或2之毛髮化妝品,其中成分(C)之含量為0.1質量%以上且10質量%以下。The hair cosmetic of claim 1 or 2, wherein the content of the component (C) is 0.1% by mass or more and 10% by mass or less. 如請求項1或2之毛髮化妝品,其進而含有於水或乙醇中具有溶解性或分散性之毛髮化妝品用聚合物作為成分(D)。The hair cosmetic of claim 1 or 2, which further contains a polymer for hair cosmetic having solubility or dispersibility in water or ethanol as component (D). 如請求項1或2之毛髮化妝品,其中成分(A)為乙醇。The hair cosmetic of claim 1 or 2, wherein component (A) is ethanol. 如請求項1或2之毛髮化妝品,其進而含有選自多元醇、脲、有機酸、聚氧伸烷基烷基葡糖苷及聚氧伸烷基甘油醚中之1種或2種以上作為成分(E)。The hair cosmetic of claim 1 or 2, which further comprises one or more selected from the group consisting of a polyhydric alcohol, a urea, an organic acid, a polyoxyalkylalkyl glucoside, and a polyoxyalkylene glyceryl ether. (E). 如請求項1或2之毛髮化妝品,其係以非氣溶膠型使用。The hair cosmetic of claim 1 or 2, which is used in a non-aerosol type.
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