TW201704743A - Magnetic electrode for monitoring degradation of coating of steel sheet and system of the same - Google Patents

Abstract

The present invention provides a magnetic electrode for monitoring degradation of a coating of a steel sheet. The magnetic electrode includes a metal element, at least one magnet, a first wire, and an embedding material. The metal element has a first portion with a hole and a second portion with an outer surface and an inner surface, in which the first portion is interconnected to the second portion. The first wire passes through the hole, and an angle between the first portion and the inner surface of the second portion is greater than 45 degree to less than 180 degree. The magnet is disposed on the inner surface of the second portion. The embedding material covers the first portion of the metal element, the magnet and a part of the first wire, while at least the outer surface of the second portion is exposed.

Description

Magnetic electrode and system for monitoring deterioration of steel coating

The present invention provides a magnetic electrode and, in particular, a magnetic electrode for monitoring deterioration of a steel sheet coating.

Steel structures such as offshore wind turbines or oil rigs that are located in marine environments (such as intertidal zones) are prone to corrosion and failure of the above structures due to the strong corrosive nature of seawater. In order to avoid the occurrence of corrosion, the coating is often applied to the surface of the above structure as a protection. The coating separates the steel structure from the corrosive medium in the seawater, such as water, ions or oxygen. Although the coating can alleviate the corrosion condition, the coating will still be degraded, foamed or peeled off due to the influence of sea water or ultraviolet rays, and the original protective performance of the coating will be lost, thereby making the foregoing The steel structure is corroded and fails.

Therefore, the state of corrosion or deterioration of the coating is monitored, and the deteriorated coating is treated early, thereby avoiding the occurrence of failure of the steel structure. When the coating is degraded or corroded, its conductivity to isolate ions or electrons decreases, so the measured conductivity will rise (or the impedance value will decrease), so it is generally A chemical method monitors the condition of coating degradation. Common electrochemical methods include electrochemical impedance spectroscopy (EIS), local electrochemical impedance spectroscopy (LEIS), scanning Kelvin probe (SKP) or electrochemical noise (EN), among which electrochemical impedance spectroscopy (EIS) is the most widely used.

Electrochemical AC impedance spectroscopy (EIS) applies an AC voltage with a small amplitude (typically 5mV to 20mV) on the system to be tested. By measuring the response, the coating, solution resistance, capacitance and interface double layer are obtained. Capacitors and other information about coating properties and failure processes.

The coating is a good barrier layer in the initial use, has a very high resistance value, and also delays the corrosion of the steel structure. However, after the action of seawater and ultraviolet rays, the coating resistance value is gradually reduced. In general, a good and complete coating has an impedance value of up to 10 ⁸ Ω. When the coating resistance value is reduced to 10 ⁶ Ω, the coating is considered to be degraded (eg, corrosion), and the lower the impedance value, the coating The more serious the deterioration.

When measuring the impedance using an electrochemical impedance spectroscopy, measurements can be made using a three-pole (working electrode, counter and reference electrode) or two-pole (working and counter) impedance analyzers. The working electrode is electrically connected to the substrate to be tested, and the counter electrode can be connected to any conductor to form a path for current circulation, and the working electrode and the counter electrode should be immersed in the aqueous solution to conduct electricity.

The conventional steel plate coating degradation monitoring system uses a sticky conductive metal tape to adhere a metal foil as an electrode to the surface of a substrate to be tested (for example, the aforementioned coated steel structure), and then electrochemically The impedance analyzer measures the impedance of the coating. The material of the metal foil used may be aluminum foil or copper foil. However, the above method is easy due to intertidal zone or droplets. With a long-term wet environment, the adhesive conductive metal tape is detached, which makes the monitoring system fail, and the metal foil is easily corroded in the marine environment.

Another steel sheet coating degradation monitoring system is applied directly to the surface of the substrate to be tested using conductive metal powder or a coating or ink as an electrode for measuring the impedance value. However, the surface of the substrate to be tested must be thoroughly cleaned before the coating is applied, and the coating can be performed after it is dried, which is complicated and time consuming. In addition, when the surface of the substrate to be tested is cleaned, the solvent used may cause damage to the substrate itself to be tested. Furthermore, coatings or inks containing metal powder are not resistant to corrosion by seawater and it is not easy to change the monitoring position.

In view of the above disadvantages, there is an urgent need to develop an electrode for monitoring deterioration of a steel sheet coating, and a steel sheet coating deterioration monitoring system using the same to improve the aforementioned drawbacks.

Therefore, an aspect of the present invention provides a magnetic electrode for monitoring degradation of a steel sheet coating, which comprises an L-shaped metal member of a specific material and provided with a magnet, which is resistant to seawater corrosion and provides a magnetic arrangement. .

Another aspect of the present invention provides a steel sheet coating deterioration monitoring system which is magnetically fixed to a substrate to be tested using the above-described magnetic electrode and monitors deterioration of the steel sheet coating.

According to the above aspect of the invention, a magnetic electrode for monitoring deterioration of a steel sheet coating is proposed. In an embodiment, the magnetic electrode comprises an L-shaped metal component, at least one magnet, a first wire, and a cladding material. The L-shaped metal member has a first portion and a second portion connected to each other, the first portion having The second portion has an inner surface and an outer surface opposite the inner surface, and the first portion forms an included angle with the inner surface of the second portion that is greater than 45 degrees to less than 180 degrees. At least one magnet is disposed on an inner surface of the second portion. The first wire is threaded through the hole, and the first wire is electrically connected to the L-shaped metal component. The cladding material described above covers the first portion of the L-shaped metal member, the magnet and a portion of the first wire, and at least exposes the outer surface of the second portion.

According to an embodiment of the present invention, the L-shaped metal member may comprise a titanium alloy, a nickel-based alloy or a stainless steel material.

According to an embodiment of the invention, the magnet may be a permanent magnet.

According to an embodiment of the invention, the cladding material may comprise a polyurea ester, a polyurethane or a fluororesin.

According to an embodiment of the invention, the magnet and the second portion further comprise an adhesive layer to fix the magnet on the second portion.

According to another aspect of the present invention, a steel sheet coating degradation monitoring system is provided. In one embodiment, the steel sheet coating degradation monitoring system described above includes a substrate to be tested, a magnetic electrode, an impedance analyzer, and a second wire. Wherein, the substrate to be tested comprises a substrate layer and a coating layer covering a part of the substrate layer, and the substrate layer may be a magnetic metal plate. The magnetic electrode is magnetically disposed on the coating of the substrate to be tested, and the magnetic electrode comprises an L-shaped metal member, at least one magnet, a first wire, and a cladding material. The L-shaped metal member has a first portion and a second portion that are interconnected, the first portion having a hole, the second portion having an inner surface and an outer surface opposite the inner surface, and the first portion and the inner surface of the second portion forming greater than 45 degrees to Less than 180 degrees. At least one magnet is disposed on an inner surface of the second portion. The first wire is threaded through the hole and is first The wire is electrically connected to the L-shaped metal component. The cladding material described above covers the first portion of the L-shaped metal member, the magnet and a portion of the first wire, and at least exposes the outer surface of the second portion. In the steel sheet coating degradation monitoring system, the first wire is electrically connected to the magnetic electrode and the impedance analyzer, and the second wire is electrically connected to the substrate layer and the impedance analyzer of the remaining portion not covered by the coating.

According to an embodiment of the invention, the steel sheet coating degradation monitoring system further comprises a third wire electrically connected to the magnetic electrode and the impedance analyzer. In the steel sheet coating degradation monitoring system, the first wire is connected to the opposite electrode end of the impedance analyzer, the second wire is connected to the working electrode end of the impedance analyzer, and the third wire is connected to the reference electrode of the impedance analyzer. extreme.

According to an embodiment of the invention, the outer surface of the magnetic electrode is magnetically disposed on the coating of the substrate to be tested.

According to an embodiment of the invention, the impedance analyzer is an AC impedance analyzer or a coating monitor.

The magnetic electrode and the steel plate coating degradation monitoring system for monitoring the deterioration of the steel plate coating of the present invention can effectively overcome the conventional adhesive electrode, which is caused by corrosion of the electrode due to immersion in seawater for a long time, or an adhesive layer. Falling off, so that the shortcomings of coating defects cannot be known in time. In addition, the magnetic electrode can be a portable electrode to facilitate changing the monitoring position.

100‧‧‧Magnetic electrode

110‧‧‧L type metal parts

111‧‧‧Part 1

113‧‧‧Part II

113a‧‧‧ inner surface

113b‧‧‧ outer surface

115‧‧‧ holes

120‧‧‧ Magnet

130‧‧‧First wire

140‧‧‧Covering material

150‧‧‧Adhesive layer

200‧‧‧Steel coating degradation monitoring system

210‧‧‧Substrate to be tested

211‧‧‧ substrate layer

213‧‧‧Coating

220‧‧‧Magnetic electrode

221‧‧‧First wire

223‧‧‧ Third wire

230‧‧‧ Impedance Analyzer

231‧‧‧electrode end

233‧‧‧Working electrode end

235‧‧‧ reference electrode end

240‧‧‧second wire

301, 305‧‧‧ the logarithm of the impedance value

303, 307‧‧‧ phase angle

T‧‧‧ thickness

W‧‧‧Width

L ₁ ‧‧‧First length

L ₂ ‧‧‧second length

Θ‧‧‧ angle

The above and other objects, features, advantages and embodiments of the present invention will become more apparent and understood. 1 is a schematic view showing a magnetic electrode for monitoring deterioration of a steel sheet coating according to an embodiment of the present invention; [FIG. 2] showing a steel sheet according to an embodiment of the present invention. A schematic diagram of a coating degradation monitoring system; [Fig. 3A] shows a Bode Plot of impedance values according to an embodiment of the present invention; [Fig. 3B] shows an impedance according to a comparative example of the present invention. The value of the Bode Plot.

Many different embodiments or examples are provided below to implement various features of the invention. Specific examples of the components and arrangements described below are used to simplify the invention. Of course, these are only examples and are not intended to be limiting. For example, in the description, the first feature is formed on or over the second feature, and may include an embodiment in which the first feature and the second feature are formed in direct contact, and may also include additional features that may be formed in the first feature. With the embodiment between the second feature, such first feature and second feature may not be in direct contact. Furthermore, the invention may repeat the component symbols and/or letters in the various examples. Such repetitions are based on the simplification and clarity of the invention and are not intended to define the relationship between the various embodiments and/or configurations discussed.

The term "deterioration of the steel sheet coating" as used herein means a coating of a coated steel sheet (or a substrate), which is externally immersed in a highly corrosive seawater or other solution, irradiated by ultraviolet rays or the like. Factor, the coating of the coated steel sheet is damaged or deteriorated.

First, please refer to Figure 1 first. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a diagram showing a magnetic electrode for monitoring deterioration of a steel sheet coating according to an embodiment of the present invention. The magnetic electrode 100 includes an L-shaped metal member 110, a magnet 120, a first wire 130, and a covering member 140. The L-shaped metal member 110 has a first portion 111 and a second portion 113 connected to each other, the first portion 111 has a hole 115, the second portion 113 has an inner surface 113a and an outer surface 113b with respect to the inner surface 113a, and the first portion 111 and the first portion The inner surface 113a of the two portions 113 forms an included angle θ of more than 45 degrees to less than 180 degrees. In an embodiment, the included angle θ may be, for example, 90 degrees. The L-shaped metal member 110 may be integrally formed from a metal foil or welded by two parts. When the L-shaped metal member 110 is integrally molded from a metal foil, a portion of the metal foil may be bent to form the first portion 111, and the unbent portion of the metal foil is the second portion 113.

As shown in FIG. 1, the magnet 120 is disposed on the inner surface 113a of the second portion 113. The first wire 130 is inserted through the hole 115 and electrically connected to the L-shaped metal member 110. In an embodiment, the first wire 130 may be bolted to the hole 115. The cladding material 140 covers the first portion 111 of the L-shaped metal member 110, the magnet 120 and a portion of the first wire 130, and at least exposes the outer surface 113b of the second portion 113.

In one embodiment, the magnet 120 can be secured to the second portion 113 of the L-shaped metal component 110 using a cladding material 140. In another embodiment, an adhesive layer 150 may be included between the magnet 120 and the second portion 113 to adhere the magnet 120 to the second portion 113. The adhesive layer 150 may be an instant adhesive or any conventional adhesive, and is not particularly limited herein.

In the embodiment shown in Figure 1, only two magnets are used. 120. The number of magnets 120 may be adjusted according to the size of the L-shaped metal member 110, and may be, for example, one, three, four or more.

In an embodiment, the magnetic electrode 100 is a portable electrode. If the L-shaped metal member 110 is flattened (meaning that even if the angle θ between the first portion 111 and the second portion 113 is 180 degrees), the L-shaped metal member 110 may have a thickness T of 0.2 mm to 2 mm and 2 cm to 10 cm. The width W. Whereas the first portion 111 may have a first length L _{1 of} 1 cm to 2 cm, and the second portion 113 may have a second length L _{2 of} 10 cm to 20 cm, and the sum of the first length L ₁ and the second length L ₂ That is, the length of the long side of the flattened L-shaped metal member 110. However, the size of the L-shaped metal component 110 can be adjusted to the design requirements, and the values disclosed herein are illustrative only and are not intended to limit the scope of the invention.

The material of the L-shaped metal member 110 may include a titanium alloy, a nickel-based alloy, or a stainless steel material. Specific examples of the above stainless steel material may be AL-6XN, 254SMO, 654SMO or the like. The L-shaped metal member 110 obtained by using the above material can have better corrosion resistance, so that the magnetic electrode obtained is not easily damaged by long-term immersion in seawater.

The magnet 120 may be a permanent magnet, and specifically, for example, a rare earth element magnet such as a neodymium iron boron magnet or a samarium cobalt magnet, a ferrite magnet, or an alnico magnet, etc., and a neodymium iron boron magnet is preferable.

The material of the covering material may comprise polyurea ester, polyurethane or fluorine resin. Specific examples of the fluorine-containing resin may, for example, be Teflon, polychlorotrifluoroethylene (PCTFE), polyvinylidene fluoride (PVDF), ethylene-tetrafluoroethylene copolymer (ETFE), and ethylene-chlorotrifluoroethylene copolymer ( ECTFE), polyvinyl fluoride (PVF), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (or fusible polymer) Tetrafluoroethylene; PFA), tetrafluoroethylene-hexafluoropropylene copolymer (or fluoroplastic 46; FEP), tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer, and the like.

Next, please refer to Figure 2. 2 is a diagram showing a steel sheet coating degradation monitoring system according to an embodiment of the present invention. The steel sheet coating degradation monitoring system 200 includes a substrate to be tested 210, a magnetic electrode 220, an impedance analyzer 230, and a second wire 240. The substrate to be tested 210 includes a substrate layer 211 and a coating layer 213 covering the substrate layer 211, wherein the substrate layer 211 is partially covered by the coating layer 213. The magnetic electrode 220 is magnetically disposed on the substrate 210 to be tested. In the steel plate coating degradation monitoring system 200, the first wire 221 is electrically connected to the magnetic electrode 220 and the impedance analyzer 230, and the second wire 240 is electrically connected to the uncoated 213 package of the substrate 210 to be tested. The substrate layer 211 and the impedance analyzer 230 are covered.

It is to be noted that the magnetic electrode 220 shown in FIG. 2 has the same structure as the magnetic electrode 100 shown in FIG. 1, wherein the first wire 130 of the magnetic electrode 100 can be combined with the magnetic electrode. The first wire 221 of 220 corresponds to each other, so it will not be described here.

The magnetic attraction electrode 220 disposed on the substrate 210 to be tested may be magnetically coated on the outer surface of the L-shaped metal member (the outer surface 113b as shown in FIG. 1) or the cladding material (coated as shown in FIG. 1). One side of the material 140) is contacted and magnetically placed on the substrate 210 to be tested. In this embodiment, the outer surface of the L-shaped metal member is magnetically placed on the substrate to be tested 210.

The base material layer 211 and the coating layer 213 of the substrate 210 to be tested are not particularly limited, and any substrate and corrosion-resistant coating for marine steel structures can be used. However, it is specifically stated that in order to make the magnetic electrode 220 of the present invention The magnetic attraction mode is set on the substrate 210 to be tested, and the material of the substrate to be tested 210 must be magnetic.

In an embodiment, the steel sheet coating degradation monitoring system 200 may further include a third wire 223 electrically connected to the magnetic electrode 220 and the impedance analyzer 230. Further, in the steel sheet coating degradation monitoring system 200, the first wire 221 is connected to the counter electrode end 231 of the impedance analyzer 230, the second wire 240 is connected to the working electrode terminal 233 of the impedance analyzer 230, and the third wire is connected. The 223 is connected to the reference electrode terminal 235 of the impedance analyzer 230.

The impedance analyzer 230 can be an AC impedance analyzer or a coating monitor. Therefore, the steel sheet coating deterioration monitoring system of the present invention can be performed by Electrochemical Impedance Spectrum (EIS). The principle and the manner of carrying out the electrochemical impedance method should be well known to those of ordinary skill in the art, and therefore will not be further described herein.

In an embodiment, the foregoing AC impedance analyzer can be a three-pole type (ie, including a working electrode, a counter electrode, and a reference electrode), and can detect an impedance value of a scanning frequency range (for example, 1 mHz to 10 kHz) and Bode Plot, the results obtained are more accurate but cannot be easily installed on site (such as in the marine environment). In addition, the AC impedance analyzer referred to here is more sensitive, so it is also possible to monitor the impedance value in a solution with low conductivity (such as tap water or rain water).

In another embodiment, the foregoing coating monitor can be any commercially available coating monitor, which can be a two-pole type (only working electrode and counter electrode), and is convenient to be installed on site due to its small size. Only specific frequencies can be detected (eg 0.2Hz, 0.5Hz or 0.9Hz). Therefore, when the impedance analyzer When 230 is a coating monitor, the reference electrode end 235 and the third wire 223 (not shown) may not be included.

In addition, the steel plate coating degradation monitoring system of the present invention uses a magnetic electrode as a counter electrode and a reference electrode, which is directly magnetically placed on the substrate to be tested, and uses a surrounding solution (for example, seawater) as an electrolyte. Therefore, the solution tank is not additionally provided to carry the electrolytic solution and the electrode, and therefore no component for sealing the solution tank is provided.

The following examples are used to illustrate the application of the present invention, and are not intended to limit the present invention. Those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. .

Set steel plate coating degradation monitoring system

Example

In the embodiment of the present invention, the steel plate having a length of 22 cm, a width of 16 cm and a thickness of 4 mm is sandblasted to the Sa2 ^{1/2 of the} Swedish Standards Association SIS-05-5900. Next, a spray coating step was applied to all six sides of the surface blasted steel sheet to coat the six sides of the steel sheet with an epoxy resin coating having a thickness of about 84 μm. Curing is then carried out to produce the desired substrate to be tested.

Next, the coating of one corner of the substrate to be tested was abraded to expose the steel sheet, and the exposed steel sheet was electrically connected to the working electrode end of a coating monitor (Coating Health Monitor, manufactured by ElectraWatch Co., Ltd.) using a wire. Then, the magnetic electrode of the present invention is magnetically placed on the The surface of the substrate is measured, and the magnetic electrode is electrically connected to the opposite electrode end of the coating monitor by another wire. After that, the substrate to be tested, the magnetic electrode and a part of the wire are obliquely placed in a 3 liter glass tank, and a 3.5% by weight sodium chloride solution is added to a half height of the substrate to be tested to soak the magnetic electrode. In sodium chloride solution.

The steel sheet coating deterioration monitoring system described above was evaluated in the following evaluation manner.

Comparative example

The steel sheet coating deterioration monitoring system of the comparative example uses the same arrangement as the embodiment, except that the comparative example replaces the magnetic electrode with a commercially available conductive aluminum foil (manufactured by 3M Company) and pastes it. The conductive aluminum foil is disposed on the substrate to be tested.

Evaluation method 1. Impedance value of the substrate to be tested

The impedance value of the substrate to be tested referred to in the present invention is first set by the coating monitors of the above embodiments and comparative examples to perform measurement once a day. After continuous measurement for 7 days, the coating was cut by a blade from the bottom of the substrate to be tested about 10 cm away from the magnetic electrode or the conductive aluminum foil, and monitoring was continued. If the impedance value of the substrate to be tested after cutting is smaller than the impedance value of the substrate to be tested before cutting, it means that the magnetic electrode or the conductive aluminum foil can effectively monitor the damage of the coating. The evaluation results of the impedance values of the substrates to be tested are shown in Table 1.

2. Electrode appearance

The appearance of the electrode referred to in the present invention is a condition in which the magnetic electrode or the conductive aluminum foil immersed in the sodium chloride solution for a long time is corroded or damaged, and the appearance of the electrode is evaluated in the following manner:

○: no corrosion and no peeling off from the substrate to be tested

×: corroded and partially peeled off from the substrate to be tested

The evaluation results of the appearance of the electrodes are shown in Table 1.

3. Low-frequency zone impedance value of the substrate to be tested

The coating monitor of the steel sheet coating degradation monitoring system of the examples of the foregoing impedance evaluation and the comparative example was replaced with an AC impedance analyzer (BioLogic; VSP) to monitor the low frequency region impedance value of the substrate to be tested. The substrate to be tested is electrically connected to the working electrode end of the AC impedance analyzer, and the magnetic electrode or the conductive aluminum foil is electrically connected to the opposite electrode end of the AC impedance analyzer and the reference electrode. Extremely, and use tap water as an electrolyte solution. The voltage applied by the AC impedance analyzer is 10 mV, the scanning current frequency is 1 mHz to 10 kHz, and the change of the impedance value in the low frequency region is observed, wherein the low frequency region is below 1 Hz. When the logarithm of the impedance value of the low frequency region is less than 6, it indicates that the coating is damaged. The evaluation results are shown in Fig. 3A and Fig. 3B.

First, please refer to Table 1. Coil coating deterioration monitoring system according to examples and comparative examples of the present invention is not to be measured in the base of the cut to the measured impedance values are all 5 × 10 ⁸ Ω, and the amount of cut in the substrate to be tested The measured impedance values were 3 × 10 ³ Ω to 5 × 10 ³ Ω and 2 × 10 ³ Ω to 4 × 10 ³ Ω, respectively. The steel sheet coating deterioration monitoring system of the embodiment of the present invention and the comparative example of the present invention can effectively monitor the deterioration state of the coating. However, after the electrode of the example was immersed in the sodium chloride solution for a long time, the appearance remained intact and was not corroded, nor dropped from the substrate to be tested. However, the appearance of the conductive aluminum foil of the comparative example was corroded and partially peeled off from the substrate to be tested.

According to the results of Table 1, the magnetic electrode to which the embodiment of the present invention is applied can effectively monitor the condition of the coating breakage and maintain a good appearance state in the sodium chloride solution.

Next, please refer to FIG. 3A. 3A is a diagram showing a Bode diagram obtained by monitoring a steel sheet coating degradation monitoring system according to an embodiment of the present invention, wherein the substrate to be tested used is a damaged substrate to be tested after being cut. In Fig. 3A, line segment 301 represents the logarithmic value of the impedance value, and line segment 303 represents the phase angle. Generally, when monitoring the degree of deterioration of the coating, the impedance value in the low frequency region (below 1 Hz) is mainly evaluated, usually 10 ⁶ Ω as the standard, and when it is lower than 10 ⁶ Ω (the logarithm is 6), the coating is degraded. , damaged or corroded. According to Fig. 3A, the logarithmic value of the impedance value measured by the steel sheet coating deterioration monitoring system using the embodiment of the present invention is 4.4 to 4.6, and the state of deterioration of the coating can be effectively observed.

On the other hand, please refer to FIG. 3B. FIG. 3B is a diagram showing the Bode diagram obtained by monitoring the steel sheet coating degradation monitoring system of the comparative example of the present invention, wherein the substrate to be tested used is a damaged substrate to be tested after cutting. In Figure 3B, line segment 305 represents the logarithmic value of the impedance value and line segment 307 represents the phase angle. The resistance value of the conductive aluminum foil is 4.1 to 4.3, and the coating can be effectively observed. Deteriorating condition.

In summary, the embodiments of the present invention can have the same efficacy as commercially available electrodes, but the magnetic electrode of the present invention can be immersed in seawater for a long time without being corroded, and the magnetic arrangement makes the electrode difficult to be tested. The substrate is detached. In addition, another advantage of the magnetic electrode is that the monitoring position can be easily changed, that is, the magnetic electrode produced is a portable electrode.

While the invention has been described above in terms of several embodiments, it is not intended to limit the scope of the invention, and the invention may be practiced in various embodiments without departing from the spirit and scope of the invention. The scope of protection of the present invention is defined by the scope of the appended claims.

100‧‧‧Magnetic electrode

110‧‧‧L type metal parts

111‧‧‧Part 1

113‧‧‧Part II

113a‧‧‧ inner surface

113b‧‧‧ outer surface

115‧‧‧ holes

120‧‧‧ Magnet

130‧‧‧First wire

140‧‧‧Covering material

150‧‧‧Adhesive layer

T‧‧‧ thickness

W‧‧‧Width

L ₁ ‧‧‧First length

L ₂ ‧‧‧second length

Θ‧‧‧ angle

Claims (9)

A magnetic electrode for monitoring degradation of a steel sheet coating, comprising: an L-shaped metal member, wherein the L-shaped metal member has a first portion and a second portion interconnected, the first portion having a hole, the first portion The two portions have an inner surface and an outer surface opposite to the inner surface, and the first portion forms an angle with the inner surface of the second portion that is greater than 45 degrees to less than 180 degrees; at least one magnet is disposed on the first portion a first wire disposed in the hole, wherein the first wire is electrically connected to the L-shaped metal member; and a cladding material covering the L-shaped metal member The first portion, the magnet and the portion of the first wire, and at least the outer surface of the second portion. The magnetic electrode for monitoring degradation of a steel sheet coating according to the first aspect of the invention, wherein the material of the L-shaped metal member comprises a titanium alloy, a nickel-based alloy or a stainless steel. A magnetic electrode for monitoring deterioration of a steel sheet coating as described in claim 1, wherein the magnet is a permanent magnet. The magnetic electrode for monitoring degradation of a steel sheet coating according to the first aspect of the invention, wherein the material of the cladding material comprises polyurea ester, polyurethane or fluorine-containing resin. The magnetic electrode for monitoring degradation of a steel sheet coating according to claim 1, wherein the magnet further includes an adhesive layer between the magnet and the second portion to fix the at least one magnet to the second portion. A steel plate coating degradation monitoring system comprises: a substrate to be tested, comprising a substrate layer and a coating layer covering a portion of the substrate layer, wherein the substrate layer is magnetic one metal plate; A magnetic electrode comprising: an L-shaped metal member, wherein the L-shaped metal member has a first portion and a second portion interconnected, the first portion having a hole, the second portion having an inner surface and opposite An outer surface of the inner surface, and the first portion and the inner surface of the second portion form an angle of more than 45 degrees to less than 180 degrees; at least one magnet is disposed on the inner surface of the second portion; a first wire disposed in the hole, wherein the first wire is electrically connected to the L-shaped metal member; and a cladding material covering the first portion of the L-shaped metal member, the magnet and the portion The first wire, and at least the outer surface of the second portion is exposed, wherein the magnetic electrode is magnetically disposed on the coating of the substrate to be tested; an impedance analyzer; and a second a wire, wherein the first wire is electrically connected The magnetic electrode and the impedance analysis And the second wire is electrically connected to the substrate layer of the remaining portion not covered by the coating and the impedance analyzer. The steel plate coating degradation monitoring system of claim 6, further comprising a third wire electrically connected to the magnetic electrode and the impedance analyzer, wherein the first wire is connected to the impedance analyzer One of the pair of electrode ends is connected to one of the working electrode terminals of the impedance analyzer, and the third wire is connected to one of the reference electrode terminals of the impedance analyzer. The steel sheet coating deterioration monitoring system according to claim 6, wherein the outer surface of the magnetic electrode is magnetically disposed on the coating of the substrate to be tested. The steel sheet coating degradation monitoring system according to claim 6, wherein the impedance analyzer is an AC impedance analyzer or a coating monitor.