TW201622958A - Method for surface finishing to product made by additive manufacturing and such product with smooth surface - Google Patents
Method for surface finishing to product made by additive manufacturing and such product with smooth surface Download PDFInfo
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本發明係為一種應用於積層製造之製品的表面處理方法,尤指對積層製造而成的製品進行表面處理,以及一種具光滑表面之積層製造製品。The present invention relates to a surface treatment method for a product manufactured by lamination, in particular, a surface treatment of a product manufactured by lamination, and a laminate manufacturing product having a smooth surface.
隨著科技的演變,目前市面上大多的產品製造不再只是傳統的減材工藝(包含切削或鑽孔),而是演變至使用增材製造(Additive Manufacturing,AM),屬於快速成形技術的一種,它是一種數位模型檔案為基礎直接製造幾乎任意形狀三維實體的技術,一般會稱之為3D列印或者積層製造。3D列印運用粉末狀金屬或塑料等可粘合材料,透過逐層堆疊累積的方式來構造物體。With the evolution of technology, most of the products currently on the market are no longer just the traditional material reduction process (including cutting or drilling), but evolved to use Additive Manufacturing (AM), a kind of rapid prototyping technology. It is a digital model file based on the technology of directly manufacturing almost any shape of 3D solids, generally referred to as 3D printing or laminate manufacturing. 3D printing uses a bondable material such as powdered metal or plastic to construct an object by stacking it in layers.
目前大多的積層製造必須先透過電腦輔助設計(CAD)或電腦動畫建模軟體來進行模型的建立,緊接著將所建成的三維模型「分割」成逐層的截面,從而指導印表機逐層列印。At present, most of the laminate manufacturing must first establish a model through computer-aided design (CAD) or computer animation modeling software, and then "divide" the built 3D model into a layer-by-layer section to guide the printer layer by layer. Print.
請參閱第五圖所示,目前大部分積層製造所產出的製品(A)大多表面較為粗糙(解析度不佳),尤其是彎曲的表面,就向影像上的鋸齒一般,雖然對於大多數的應用已經足夠。但若是具有高藝術價值的製品往往不能有如此粗糙的表面,依照前面的作法,會在表面進行打磨處理,但相對所耗費的時間以及金錢成本都會提高,也不見得能獲得適當光滑度的表面。Please refer to the fifth figure. At present, most of the products produced by laminated manufacturing (A) are mostly rough (poor resolution), especially the curved surface, which is generally serrated on the image, although for most The application is enough. However, if the product with high artistic value often cannot have such a rough surface, according to the previous method, the surface will be polished, but the time and money cost will increase, and it is not necessary to obtain a surface with appropriate smoothness. .
為了解決上述積層製造所產出的製品大多表面較為粗糙之缺失,本發明人致力於研究一種應用於積層製造之製品的表面處理方法,包含以下之步驟:被覆步驟:將一混合溶液被覆在積層製造而成的一製品之表面,該混合溶液包含體積百分比1至60之一樹脂以及體積百分比40至99之一第一有機溶液。均勻處理:將經過被覆步驟後的該製品放置在由該第一有機溶液汽化後的蒸氣環境中,藉以催化該製品表面形成光滑。乾燥處理:將經過均勻處理步驟後的該製品施以乾燥處理。In order to solve the problem that most of the products produced by the above-mentioned laminated manufacturing are rough on the surface, the inventors of the present invention have been working on a surface treatment method for a product manufactured by lamination, comprising the following steps: a coating step: coating a mixed solution on a laminate The surface of a manufactured article comprising a first organic solution having a volume percentage of 1 to 60 of a resin and a volume percentage of 40 to 99. Uniform treatment: The article after the coating step is placed in a vapor environment after vaporization of the first organic solution, thereby catalyzing the smooth formation of the surface of the article. Drying treatment: The product after the uniform treatment step is subjected to a drying treatment.
其中,在均勻處理中該製品放置在由該第一有機溶液汽化後的蒸氣環境中一時間,該時間係與該蒸氣之濃度成反比。Wherein the article is placed in a vapor environment after vaporization of the first organic solution for a period of time in a uniform process, the time being inversely proportional to the concentration of the vapor.
其中該樹脂較佳之體積百分比為12至18,而該第一有機溶液較佳之體積百分比為82至88。Preferably, the resin has a volume percentage of from 12 to 18, and the first organic solution preferably has a volume percentage of from 82 to 88.
又或者,該第一有機溶液係包含下列任一者:丙酮、丁酮、甲異丁酮、乙酸乙酯、乙酸戊酯、甲苯、二甲苯、四氫呋喃、二氯乙烷、氯仿、二氯甲烷或三氯乙烷。Still alternatively, the first organic solution comprises any one of the following: acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, amyl acetate, toluene, xylene, tetrahydrofuran, dichloroethane, chloroform, dichloromethane Or trichloroethane.
進一步,更包含有一凝膠步驟在該被覆步驟之前,先將積層製造而成的製品與一第二有機溶液作用產生一凝膠反應。其中該第二有機溶液係包含下列任一種:熱苯、四氫呋喃、二氯甲烷或二噁烷。Further, a gel step is further included, in which the product manufactured by the laminate is reacted with a second organic solution to produce a gel reaction before the coating step. Wherein the second organic solution comprises any one of the following: hot benzene, tetrahydrofuran, dichloromethane or dioxane.
而較特別的是,該第二有機溶液係以下列任一者與積層製造之製品的表面產生該凝膠反應:塗抹、噴塗、浸入、蒸氣或沉積。More particularly, the second organic solution produces the gel reaction on the surface of the article manufactured by any of the following: smearing, spraying, dipping, vaporizing or depositing.
以及,所述混合溶液係以下列任一者方式被覆在積層製造之製品的表面:塗抹、噴塗、浸入、蒸氣或沉積。And, the mixed solution is coated on the surface of the product manufactured by the laminate in any of the following manners: painting, spraying, dipping, steaming or depositing.
本發明也是一種具光滑表面之積層製造製品,該積層製造製品係透過上述表面處理方法所製造而成。The present invention is also a laminate manufacturing article having a smooth surface, which is manufactured by the above surface treatment method.
本發明之應用於積層製造之製品的表面處理方法及具光滑表面之積層製造製品均具有以下之功效:The surface treatment method for the product manufactured by the laminate and the laminate manufacturing product having the smooth surface of the invention have the following effects:
1、一般以積層製造而成的製品表面較為粗糙,通常會先以機械研磨方式進行初步的表面處理,但製品的表面仍可透過肉眼看到製造紋路,透過上述表面處理方法所製造而成的製品表面不僅光滑,且製成簡單不須經過繁雜步驟則可處理完成。1. Generally, the surface of the product manufactured by lamination is rough, and the initial surface treatment is usually performed by mechanical grinding. However, the surface of the product can still be seen through the surface treatment by the naked eye. The surface of the product is not only smooth, but also simple to manufacture and can be processed without complicated steps.
2、進一步的可以透過在混合溶液中調入不同顏色的色料,藉此讓該製品的外觀有不同的顏色變化。2. Further, it is possible to change the color of the product by different colors in the mixed solution.
綜合上述技術特徵,本發明之應用於積層製造之製品的表面處理方法及具光滑表面之積層製造製品的主要功效將可於下述實施例清楚呈現。In combination with the above technical features, the main effects of the surface treatment method of the article for laminated production and the laminate manufacturing article having a smooth surface of the present invention will be clearly shown in the following examples.
首先,先說明本發明其一目的之應用於積層製造之製品的表面處理方法的第一實施例請先參閱第一圖所示,圖中係表示該方法的步驟流程圖,並同時搭配第二圖之流程架構圖說明,以下詳述之:First, a first embodiment of a surface treatment method for a product manufactured by lamination is first described with reference to the first figure. The figure shows a flow chart of the steps of the method, and is accompanied by a second The flow chart of the diagram illustrates the following:
在第一實施例中透過積層製造係以熔絲製造(Fused Filament Fabrication,FFF)方式進行,而所製造而成的製品以最常見的聚乳酸(PLA)作為材料說明。In the first embodiment, the laminated manufacturing system is carried out by a Fused Filament Fabrication (FFF) method, and the manufactured article is described by using the most common polylactic acid (PLA) as a material.
被覆步驟(S11):先取得經過積層製造而成的一製品,如同前一段說明,該製品係為一聚乳酸(PLA),再以一混合溶液被覆在該製品欲光滑處理的表面,其中該混合溶液包含體積百分比1至60之一樹脂以及體積百分比40至99之一第一有機溶液。該混合根據該製品的面積調配不同的總體積量。進一步,該樹脂較佳之體積百分比為12至18,而該第一有機溶液較佳之體積百分比為82至88。。然而該樹脂與該第一有機溶液最佳的體積百分比係為:體積百分比85之該樹脂與體積百分比15之第一有機溶液。需特別說明的是,該第一有機溶液係包含下列任一者:丙酮、丁酮、甲異丁酮、乙酸乙酯、乙酸戊酯、甲苯、二甲苯、四氫呋喃、二氯乙烷、氯仿、二氯甲烷或三氯乙烷任一者。在第一實施例中係以丙酮作為該第一有機溶液之說明,但不能做為任何限制條件。Coating step (S11): first obtaining a product manufactured by lamination, as described in the previous paragraph, the product is a polylactic acid (PLA), and then coated with a mixed solution on the surface of the product to be smoothed, wherein The mixed solution contains one resin in a volume percentage of 1 to 60 and a first organic solution in a volume percentage of 40 to 99. The mixing is formulated with different total volume amounts depending on the area of the article. Further, the resin preferably has a volume percentage of 12 to 18, and the first organic solution preferably has a volume percentage of 82 to 88. . However, the optimum volume percentage of the resin to the first organic solution is: a volume percentage of 85 of the resin and 15% by volume of the first organic solution. It should be particularly noted that the first organic solution comprises any one of the following: acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, amyl acetate, toluene, xylene, tetrahydrofuran, dichloroethane, chloroform, Either dichloromethane or trichloroethane. In the first embodiment, acetone is used as the description of the first organic solution, but it cannot be made as any limitation.
以及所述混合溶液係透過以下列任一方式被覆在積層製造之製品的表面:塗抹、噴塗、浸入、蒸氣或沉積。由於塗抹、噴塗、浸入、蒸氣或沉積均屬該領域通常知識,故不再贅述其內容。And the mixed solution is applied to the surface of the article manufactured by lamination in any of the following ways: smearing, spraying, dipping, vaporizing or depositing. Since smearing, spraying, immersion, vapor or deposition are common knowledge in the field, the contents thereof will not be described again.
藉由上述的被覆步驟(S11)能使該聚乳酸表面受到該有機溶液的影響而使凹凸不平的表面微溶解狀態,使其與該樹脂相結合,藉此提高表面的光滑度。By the coating step (S11) described above, the surface of the polylactic acid can be affected by the organic solution, and the uneven surface can be slightly dissolved to be combined with the resin, thereby improving the smoothness of the surface.
均勻處理(S21):緊接著再將經過被覆步驟(S11)後之該聚乳酸放置在相同於前述第一有機溶液所揮發之蒸氣中一特定時間。如同前述的說明係將該聚乳酸放置在一丙酮蒸氣中,並根據該丙酮蒸氣之濃度來決定該特定時間的長短,即是該特定時間與該蒸氣之濃度成反比。Uniform treatment (S21): The polylactic acid after the coating step (S11) is placed in the vapor volatilized in the same manner as the first organic solution for a specific period of time. As described above, the polylactic acid is placed in an acetone vapor, and the length of the specific time is determined according to the concentration of the acetone vapor, that is, the specific time is inversely proportional to the concentration of the vapor.
藉由上述的均勻處理(S21)能使該聚乳酸之表面所附著的樹脂更緊密的結合,避免輕易的被剝落。By the above uniform treatment (S21), the resin adhered to the surface of the polylactic acid can be more tightly bonded to avoid easy peeling.
乾燥處理(S31):將經過均勻處理(S21)的該聚乳酸自然乾燥。Drying treatment (S31): The polylactic acid subjected to uniform treatment (S21) is naturally dried.
藉由上述的表面處理方法能解決一般以積層製造而成的製品表面較為粗糙之缺失,透過上述表面處理方法所製造而成的製品表面不僅光滑,且製成簡單不須經過繁雜步驟則可處理完成,相當便捷。The above surface treatment method can solve the problem that the surface of the product which is generally manufactured by lamination is relatively rough, and the surface of the product manufactured by the above surface treatment method is not only smooth, but also can be processed without complicated steps. Completed, quite convenient.
請再參閱第三圖及第四圖所示,第三圖係表示本發明之應用於積層製造之製品的表面處理方法的第二實施例,特別是指第二實施例的步驟流程圖,並搭配第四圖之流程架構圖說明,第二實施例與第一實施例差異在於在該被覆步驟(S22)之前更包含有一凝膠步驟(S12),以下簡略說明:Referring to the third and fourth figures, the third figure shows a second embodiment of the surface treatment method of the article for laminated manufacturing of the present invention, in particular, the flow chart of the steps of the second embodiment, and The difference between the second embodiment and the first embodiment is that the gel step (S12) is further included before the covering step (S22), which is briefly described below:
凝膠步驟(S12):先將積層製造而成的之該聚乳酸與一第二有機溶液作用產生一凝膠反應,其中該第二有機溶液係包含下列任醫者:熱苯、四氫呋喃、二氯甲烷或二噁烷。需特別說明該第二有機溶液係透過以下列任一方式與積層製造之製品的表面產生該凝膠反應:塗抹、噴塗、浸入、蒸氣或沉積。Gel step (S12): firstly, the polylactic acid produced by lamination is reacted with a second organic solution to produce a gel reaction, wherein the second organic solution comprises the following doctors: hot benzene, tetrahydrofuran, two Methyl chloride or dioxane. It is specifically noted that the second organic solution is subjected to the gel reaction by coating the surface of the article produced by the laminate in any of the following ways: painting, spraying, dipping, vaporizing or depositing.
藉由上述的凝膠步驟(S12)能先在該聚乳酸的表面先形成較薄的外殼,讓原先較為凹凸不平的表面先進行第一的光滑處理,藉此提供後續的被覆步驟(S22)更為光滑的該聚乳酸的表面。再以該均勻處理(S32)以及該乾燥步驟(S42)完成具光滑表面的該聚乳酸。By the gel step (S12) described above, a thin outer shell can be formed on the surface of the polylactic acid first, so that the previously rough surface is first smoothed, thereby providing a subsequent coating step (S22). A smoother surface of the polylactic acid. The polylactic acid having a smooth surface is completed by the uniform treatment (S32) and the drying step (S42).
而本發明也是一種具光滑表面之積層製造製品,該具光滑表面之積層製造製品係透過上述表面處理方法所製造而成。然而製造過程與成品均相同於前述之說明,故不再贅述。The present invention is also a laminated product having a smooth surface, which is manufactured by the above surface treatment method. However, the manufacturing process and the finished product are the same as those described above, and therefore will not be described again.
惟以上所述實施例僅係為本發明之較佳實施例,當不能以此限定本發明實施之範圍,即依本發明申請專利範圍及發明說明內容所作簡單的等效變化與修飾,皆屬本發明涵蓋之範圍內。However, the above-mentioned embodiments are merely preferred embodiments of the present invention, and are not intended to limit the scope of the present invention, that is, simple equivalent changes and modifications according to the scope of the present invention and the description of the invention are It is within the scope of the invention.
(S11)‧‧‧第一實施例之被覆步驟(S11) ‧ ‧ the coating step of the first embodiment
(S21)‧‧‧第一實施例之均勻處理(S21) ‧‧ ‧ uniform processing of the first embodiment
(S31)‧‧‧第一實施例之乾燥處理(S31) ‧‧‧Drying treatment of the first embodiment
(S12)‧‧‧第二實施例之凝膠步驟(S12) ‧‧‧ gel step of the second embodiment
(S22)‧‧‧第二實施例之被覆步驟(S22) ‧‧ The coating step of the second embodiment
(S32)‧‧‧第二實施例之均勻處理(S32) ‧ ‧ uniform processing of the second embodiment
(S42)‧‧‧第二實施例之乾燥處理(S42) ‧‧‧Drying treatment of the second embodiment
(A)‧‧‧先前技術之積層製造的製品(A) ‧‧‧Products manufactured by laminates of prior art
[第一圖]本發明之應用於積層製造之製品的表面處理方法的第一實施例之步驟流程圖。[First Diagram] A flow chart of the steps of the first embodiment of the surface treatment method of the article for laminated manufacturing of the present invention.
[第二圖]本發明之應用於積層製造之製品的表面處理方法的第一實施例之流程架構圖。[Second Drawing] A flow chart of the first embodiment of the surface treatment method of the article for laminated manufacturing of the present invention.
[第三圖]本發明之應用於積層製造之製品的表面處理方法的第二實施例之步驟流程圖。[Third Diagram] A flow chart of the steps of the second embodiment of the surface treatment method of the article for laminated manufacturing of the present invention.
[第四圖]本發明之應用於積層製造之製品的表面處理方法的第二實施例之流程架構圖。[Fourth Diagram] A flow chart of the second embodiment of the surface treatment method of the article for laminated manufacturing of the present invention.
[第五圖]先前技術之積層製造的製品。[Fifth Figure] A product manufactured by a laminate of the prior art.
(S11)‧‧‧第一實施例之被覆步驟 (S11) ‧ ‧ the coating step of the first embodiment
(S21)‧‧‧第一實施例之均勻處理 (S21) ‧‧ ‧ uniform processing of the first embodiment
(S31)‧‧‧第一實施例之乾燥處理 (S31) ‧‧‧Drying treatment of the first embodiment
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