TW201604937A - Apparatus and method for deposition of material on a substrate - Google Patents

Apparatus and method for deposition of material on a substrate Download PDF

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TW201604937A
TW201604937A TW104111913A TW104111913A TW201604937A TW 201604937 A TW201604937 A TW 201604937A TW 104111913 A TW104111913 A TW 104111913A TW 104111913 A TW104111913 A TW 104111913A TW 201604937 A TW201604937 A TW 201604937A
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deposition
deposition assembly
assembly
edge portion
outer deposition
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TW104111913A
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艾芙琳 史屈
麥卡司 班德
法畢歐 皮瑞里西
丹尼爾 瑟維琳
雷波 林登博克
海瑞德 蓋特能
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應用材料股份有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3464Operating strategies
    • H01J37/347Thickness uniformity of coated layers or desired profile of target erosion
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • C23C14/352Sputtering by application of a magnetic field, e.g. magnetron sputtering using more than one target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/542Controlling the film thickness or evaporation rate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • C23C14/568Transferring the substrates through a series of coating stations
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32366Localised processing
    • H01J37/32385Treating the edge of the workpieces
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/3244Gas supply means
    • H01J37/32449Gas control, e.g. control of the gas flow
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3402Gas-filled discharge tubes operating with cathodic sputtering using supplementary magnetic fields
    • H01J37/3405Magnetron sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/3414Targets
    • H01J37/3417Arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3464Operating strategies

Abstract

An apparatus for deposition of material on a substrate is described. The apparatus includes a deposition array (222) having three or more cathodes (122), wherein the deposition array comprises: a first outer deposition assembly (301) comprising at least a first cathode of the three or more cathodes; a second outer deposition assembly (302) opposing the first outer deposition assembly comprising at least a second cathode of the three or more cathodes; and an inner deposition assembly (303) comprising at least one inner cathode located between the first outer deposition assembly and the second outer deposition assembly. At least one of the first outer deposition assembly (301) and the second outer deposition assembly (302) is configured for depositing the material at a higher rate than the inner deposition assembly (303) on the same substrate during the same time.

Description

於物理氣相沈積陣列塗佈機中散熱均勻改良 Uniform heat dissipation in physical vapor deposition array coater

本發明的實施例是關於藉由從靶材的濺射的層沉積。本發明的實施例特別是關於在大面積基板上的濺射,更特別是用於靜態沉積製程。實施例具體是關於用於在基板上沉積材料層的設備和方法。 Embodiments of the invention relate to layer deposition by sputtering from a target. Embodiments of the invention are particularly directed to sputtering on large area substrates, and more particularly for static deposition processes. Embodiments are particularly directed to apparatus and methods for depositing a layer of material on a substrate.

在許多應用中,渴望沉積薄層在基板(例如玻璃基板)上。依照慣例,基板係在一塗佈設備的不同腔室中塗佈。對於一些應用而言,基板係在真空中,使用氣相沉積技術塗佈。 In many applications, it is desirable to deposit a thin layer on a substrate, such as a glass substrate. Conventionally, the substrates are coated in different chambers of a coating apparatus. For some applications, the substrate is in a vacuum and coated using a vapor deposition technique.

已知數種方法,用於在基板上沉積材料。舉例來說,基板可以藉由物理氣相沉積(physical vapor deposition,PVD)製程、化學氣相沉積(chemical vapor deposition,CVD)製程、或電漿輔助化學氣相沉積(plasma enhanced chemical vapor deposition,PECVD)製程等等來塗佈。通常,製程係在待塗佈的基板所位在的處理設備或處理室中進行。對於PVD製程而言,沉積材料能夠以固相存在於靶材中。藉由以高能粒子撞擊靶材,靶材材料(亦即待沉積的材料)的原子係從靶材發射。靶材材料的原子係沉積在待塗佈的基板上。在PVD製程中,濺射的材料,亦即待沉積在基板 上的材料,可以以不同的方式配置。舉例來說,靶材可以由待沉積的材料製成,或者可以具有待沉積的材料固定於其上的背元件。包含待沉積的材料的靶材係支撐或固定在沉積室內的預定位置中。 Several methods are known for depositing materials on a substrate. For example, the substrate may be subjected to a physical vapor deposition (PVD) process, a chemical vapor deposition (CVD) process, or a plasma enhanced chemical vapor deposition (PECVD). ) Process and so on to coat. Typically, the process is carried out in a processing apparatus or processing chamber in which the substrate to be coated is located. For PVD processes, the deposited material can be present in the target in a solid phase. The atomic system of the target material (ie, the material to be deposited) is emitted from the target by impacting the target with high energy particles. The atomic system of the target material is deposited on the substrate to be coated. In the PVD process, the sputtered material, that is, the substrate to be deposited The material on it can be configured in different ways. For example, the target may be made of a material to be deposited, or may have a backing member to which the material to be deposited is affixed. The target containing the material to be deposited is supported or fixed in a predetermined location within the deposition chamber.

典型地,濺射能夠以磁控濺射的方式進行,其中為了改善濺射條件,磁鐵組件係用以限制電漿。電漿分佈、電漿特性和其他沉積參數需要被控制,以在基板上得到想要的層沉積。 舉例而言,係渴望帶有想要的層性質的均勻層。這對於大面積沉積而言,例如對於在大面積基板上製造顯示器而言,特別是有利的。另外,對於其中基板並非連續性地移動通過沉積區域的靜態沉積製程而言,均勻性和製程穩定性會是特別難達成的。據此,考慮到對於在大尺度上製造光電裝置和其他裝置的需求增加,製程均勻性和/或穩定性需要被進一步地改善。 Typically, sputtering can be performed in a magnetron sputtering manner in which a magnet assembly is used to limit the plasma in order to improve sputtering conditions. The plasma distribution, plasma characteristics, and other deposition parameters need to be controlled to achieve the desired layer deposition on the substrate. For example, a uniform layer with the desired layer properties is desired. This is particularly advantageous for large area deposition, for example for the manufacture of displays on large area substrates. In addition, uniformity and process stability can be particularly difficult to achieve for static deposition processes in which the substrate does not move continuously through the deposition zone. Accordingly, in view of the increased demand for manufacturing optoelectronic devices and other devices on a large scale, process uniformity and/or stability needs to be further improved.

在常規的大面積多靶材靜態PVD陣列塗佈器中,使用數個濺射靶材,以覆蓋整個基板面積。從一個靶材所濺射的材料的分佈,通常遍布一個寬闊的範圍,並且也對於在接下來的二或多個鄰近的靶材的區域中的塗佈沉積有所貢獻。在基板的邊緣,沒有這個來自鄰近的靶材的貢獻,其導致在基板邊緣的塗層厚度降低。 In conventional large area multi-target static PVD array applicators, several sputtering targets are used to cover the entire substrate area. The distribution of material sputtered from a target typically spreads over a wide range and also contributes to coating deposition in the area of the next two or more adjacent targets. At the edge of the substrate, there is no contribution from this adjacent target, which results in a reduced coating thickness at the edge of the substrate.

據此,存在著對於改善PVD沉積的渴望,特別是改善在大面積基板的邊緣的沉積的渴望。 Accordingly, there is a desire to improve PVD deposition, particularly to improve deposition at the edges of large area substrates.

鑑於上述情況,提供根據獨立項的用於在基板上沉 積材料層的設備和方法。另外的方面、優點和特徵,係由附屬項、說明書及所附圖式闡明。 In view of the above, it is provided for sinking on the substrate according to the independent item. Apparatus and method for accumulating material layers. Further aspects, advantages and features are set forth in the dependent claims, the description and the drawings.

根據一實施例,提供一種用於材料在一基板上之沉積的設備。該設備包含一沉積陣列,該沉積陣列具有三或多個可旋轉陰極。沉積陣列包含:一第一外側沉積組件,該第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極;一第二外側沉積組件,相對於第一外側沉積組件,該第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極;以及一內側沉積組件,該內側沉積組件包括至少一內側可旋轉陰極,該內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件和第二外側沉積組件中的至少一者,係配置成用於在相同的時間之中於相同的基板上以高於內側沉積組件的速率沉積材料。 According to an embodiment, an apparatus for depositing a material on a substrate is provided. The apparatus includes a deposition array having three or more rotatable cathodes. The deposition array includes: a first outer deposition assembly including at least one first rotatable cathode of the three or more rotatable cathodes; and a second outer deposition assembly opposite the first outer deposition assembly The second outer deposition assembly includes at least one second rotatable cathode of the three or more rotatable cathodes; and an inner deposition assembly including at least one inner rotatable cathode, the inner deposition assembly being located Between the first outer deposition assembly and the second outer deposition assembly. At least one of the first outer deposition assembly and the second outer deposition assembly is configured to deposit material at a higher rate than the inner deposition assembly over the same substrate over the same time.

根據一實施例,提供一種用於材料在一基板上之沉積的設備。該設備包含一沉積陣列,該沉積陣列具有三或多個陰極。沉積陣列包含:一第一外側沉積組件,該第一外側沉積組件包括該三或多個陰極中的至少一第一陰極;一第二外側沉積組件,相對於第一外側沉積組件,該第二外側沉積組件包括該三或多個陰極中的至少一第二陰極;以及一內側沉積組件,該內側沉積組件包括至少一內側陰極,該內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件和第二外側沉積組件中的至少一者,係配置成用於在相同的時間之中於相同的基板上以高於內側沉積組件的速率沉積材料。根據又另外的實施例,如此處所揭露的細節、特徵和方面,特別是如附屬項中所揭 露者,可以結合這個實施例,以產生又另外的實施例。 According to an embodiment, an apparatus for depositing a material on a substrate is provided. The apparatus includes a deposition array having three or more cathodes. The deposition array includes: a first outer deposition assembly including at least one first cathode of the three or more cathodes; a second outer deposition assembly, the second outer deposition assembly, the second The outer deposition assembly includes at least one second cathode of the three or more cathodes; and an inner deposition assembly including at least one inner cathode disposed on the first outer deposition assembly and the second outer deposition Between components. At least one of the first outer deposition assembly and the second outer deposition assembly is configured to deposit material at a higher rate than the inner deposition assembly over the same substrate over the same time. According to still further embodiments, the details, features, and aspects as disclosed herein, particularly as disclosed in the accompanying items This embodiment can be combined with other embodiments to create yet another embodiment.

根據一第二實施例,提供一種用於材料在一基板上之沉積的設備。該設備包含一沉積陣列,該沉積陣列具有三或多個可旋轉陰極。沉積陣列包含:一第一外側沉積組件,該第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極;一第二外側沉積組件,相對於第一外側沉積組件,該第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極;以及一內側沉積組件,該內側沉積組件包括至少一內側可旋轉陰極,該內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件在基板傳送方向中定義一第一邊緣部分,第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分,其中沉積陣列更包含一第三邊緣部分和一第四邊緣部分,第三邊緣部分包含內側沉積組件的該至少一內側陰極的第一端,第四邊緣部分包含陰極陣列的該內側沉積組件的該些陰極之相對的第二端。氣體分佈系統係配置成用於提供第一處理氣體條件到第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分,用於以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。 According to a second embodiment, an apparatus for depositing material on a substrate is provided. The apparatus includes a deposition array having three or more rotatable cathodes. The deposition array includes: a first outer deposition assembly including at least one first rotatable cathode of the three or more rotatable cathodes; and a second outer deposition assembly opposite the first outer deposition assembly The second outer deposition assembly includes at least one second rotatable cathode of the three or more rotatable cathodes; and an inner deposition assembly including at least one inner rotatable cathode, the inner deposition assembly being located Between the first outer deposition assembly and the second outer deposition assembly. The first outer deposition assembly defines a first edge portion in the substrate transfer direction, and the second outer deposition assembly defines a second edge portion relative to the first edge portion in the substrate transfer direction, wherein the deposition array further includes a third edge And a fourth edge portion, the third edge portion comprising a first end of the at least one inner cathode of the inner deposition assembly, the fourth edge portion comprising opposite second ends of the cathodes of the inner deposition assembly of the cathode array. a gas distribution system configured to provide first process gas conditions to the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion for uppering the first edge portion, the second edge The rate of deposition of the remaining portion of the portion, the third edge portion, and the fourth edge portion.

根據一第二實施例,提供一種用於材料在一基板上之沉積的設備。該設備包含一沉積陣列,該沉積陣列具有三或多個陰極。沉積陣列包含:一第一外側沉積組件,該第一外側沉積組件包括該三或多個陰極中的至少一第一陰極;一第二外側沉積組件,相對於第一外側沉積組件,該第二外側沉積組件包括該三 或多個陰極中的至少一第二陰極;以及一內側沉積組件,該內側沉積組件包括至少一內側陰極,該內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件在基板傳送方向中定義一第一邊緣部分,第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分,其中沉積陣列更包含一第三邊緣部分和一第四邊緣部分,第三邊緣部分包含內側沉積組件的該至少一內側陰極的第一端,第四邊緣部分包含陰極陣列的該內側沉積組件的該些陰極之相對的第二端。氣體分佈系統係配置成用於提供第一處理氣體條件到第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分,用於以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。根據又另外的實施例,如此處所揭露的細節、特徵和方面,特別是如附屬項中所揭露者,可以結合這個實施例,以產生又另外的實施例。 According to a second embodiment, an apparatus for depositing material on a substrate is provided. The apparatus includes a deposition array having three or more cathodes. The deposition array includes: a first outer deposition assembly including at least one first cathode of the three or more cathodes; a second outer deposition assembly, the second outer deposition assembly, the second The outer deposition assembly includes the three Or at least one second cathode of the plurality of cathodes; and an inner deposition assembly including at least one inner cathode disposed between the first outer deposition assembly and the second outer deposition assembly. The first outer deposition assembly defines a first edge portion in the substrate transfer direction, and the second outer deposition assembly defines a second edge portion relative to the first edge portion in the substrate transfer direction, wherein the deposition array further includes a third edge And a fourth edge portion, the third edge portion comprising a first end of the at least one inner cathode of the inner deposition assembly, the fourth edge portion comprising opposite second ends of the cathodes of the inner deposition assembly of the cathode array. a gas distribution system configured to provide first process gas conditions to the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion for uppering the first edge portion, the second edge The rate of deposition of the remaining portion of the portion, the third edge portion, and the fourth edge portion. In accordance with still further embodiments, the details, features, and aspects disclosed herein, particularly as disclosed in the accompanying claims, may be combined with the embodiments to produce additional embodiments.

根據另一實施例,提供一種用於材料在一基板上之沉積的方法。該方法包含:提供一沉積陣列,該沉積陣列具有三或多個可旋轉陰極,其中沉積陣列包含一第一外側沉積組件、一第二外側沉積組件、和一內側沉積組件,第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極,第二外側沉積組件相對於第一外側沉積組件,第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極,內側沉積組件包括至少一內側可旋轉陰極,內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間;以及以藉由第一外側沉積組件和第二外側沉積組件中的至少一者高於藉由內側沉積組件的速率,在基板 上沉積材料。 According to another embodiment, a method for depositing a material on a substrate is provided. The method includes providing a deposition array having three or more rotatable cathodes, wherein the deposition array includes a first outer deposition assembly, a second outer deposition assembly, and an inner deposition assembly, the first outer deposition assembly Including at least one first rotatable cathode of the three or more rotatable cathodes, a second outer deposition assembly relative to the first outer deposition assembly, and a second outer deposition assembly including at least one of the three or more rotatable cathodes a second rotatable cathode, the inner deposition assembly including at least one inner rotatable cathode, the inner deposition assembly positioned between the first outer deposition assembly and the second outer deposition assembly; and the first outer deposition assembly and the second outer deposition At least one of the components is higher than the rate of deposition of the component by the inner side, on the substrate Deposited material.

根據另一實施例,提供一種用於材料在一基板上之沉積的方法。該方法包含:提供一沉積陣列,該沉積陣列具有三或多個陰極,其中沉積陣列包含一第一外側沉積組件、一第二外側沉積組件、和一內側沉積組件,第一外側沉積組件包括該三或多個陰極中的至少一第一陰極,第二外側沉積組件相對於第一外側沉積組件,第二外側沉積組件包括該三或多個陰極中的至少一第二陰極,內側沉積組件包括至少一內側陰極,內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間;以及以藉由第一外側沉積組件和第二外側沉積組件中的至少一者高於藉由內側沉積組件的速率,在基板上沉積材料。根據又另外的實施例,如此處所揭露的細節、特徵和方面,特別是如附屬項中所揭露者,可以結合這個實施例,以產生又另外的實施例。 According to another embodiment, a method for depositing a material on a substrate is provided. The method includes providing a deposition array having three or more cathodes, wherein the deposition array includes a first outer deposition assembly, a second outer deposition assembly, and an inner deposition assembly, the first outer deposition assembly including the At least one first cathode of the three or more cathodes, a second outer deposition assembly relative to the first outer deposition assembly, a second outer deposition assembly including at least one second cathode of the three or more cathodes, the inner deposition assembly including At least one inner cathode, the inner deposition component being positioned between the first outer deposition component and the second outer deposition component; and being deposited by the inner side by at least one of the first outer deposition component and the second outer deposition component The rate of the component, depositing material on the substrate. In accordance with still further embodiments, the details, features, and aspects disclosed herein, particularly as disclosed in the accompanying claims, may be combined with the embodiments to produce additional embodiments.

根據又另一實施例,提供一種用於材料在一基板上之沉積的方法。該方法包含提供一沉積陣列,該沉積陣列具有三或多個可旋轉陰極,其中沉積陣列包含一第一外側沉積組件、一第二外側沉積組件、和一內側沉積組件,第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極,第二外側沉積組件相對於第一外側沉積組件,第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極,內側沉積組件包括至少一內側可旋轉陰極,內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件在基板傳送方向中定義一第一邊緣部分,第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分,其中沉積陣列更包括一第 三邊緣部分和一第四邊緣部分,第三邊緣部分包含內側沉積組件的該至少一內側陰極的第一端,第四邊緣部分包含陰極陣列的該內側沉積組件的該些陰極之相對的第二端,其中在基板上沉積材料更包含在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分,以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。 According to yet another embodiment, a method for depositing a material on a substrate is provided. The method includes providing a deposition array having three or more rotatable cathodes, wherein the deposition array includes a first outer deposition assembly, a second outer deposition assembly, and an inner deposition assembly, the first outer deposition assembly including At least one first rotatable cathode of the three or more rotatable cathodes, a second outer deposition assembly relative to the first outer deposition assembly, and a second outer deposition assembly including at least one of the three or more rotatable cathodes A rotatable cathode, the inner deposition assembly including at least one inner rotatable cathode, the inner deposition assembly being positioned between the first outer deposition assembly and the second outer deposition assembly. The first outer deposition assembly defines a first edge portion in the substrate transfer direction, and the second outer deposition assembly defines a second edge portion relative to the first edge portion in the substrate transfer direction, wherein the deposition array further includes a first a third edge portion and a fourth edge portion, the third edge portion comprising a first end of the at least one inner cathode of the inner deposition assembly, the fourth edge portion comprising an opposite second of the cathodes of the inner deposition assembly of the cathode array An end, wherein the deposition material on the substrate is further included in the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion to be higher than the first edge portion, the second edge portion, and the third edge portion The material is deposited at a rate that is the remainder of the portion between the fourth edge portion.

根據又另一實施例,提供一種用於材料在一基板上之沉積的方法。該方法包含提供一沉積陣列,該沉積陣列具有三或多個陰極,其中沉積陣列包含一第一外側沉積組件、一第二外側沉積組件、和一內側沉積組件,第一外側沉積組件包括該三或多個陰極中的至少一第一陰極,第二外側沉積組件相對於第一外側沉積組件,第二外側沉積組件包括該三或多個陰極中的至少一第二陰極,內側沉積組件包括至少一內側陰極,內側沉積組件位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件在基板傳送方向中定義一第一邊緣部分,第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分,其中沉積陣列更包括一第三邊緣部分和一第四邊緣部分,第三邊緣部分包含內側沉積組件的該至少一內側陰極的第一端,第四邊緣部分包含陰極陣列的該內側沉積組件的該些陰極之相對的第二端,其中在基板上沉積材料更包含在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分,以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。根據又另外的實施例,如此處所揭露的細節、特徵和方面,特別是如附屬項中所揭露者,可以結合這個實施例, 以產生又另外的實施例。 According to yet another embodiment, a method for depositing a material on a substrate is provided. The method includes providing a deposition array having three or more cathodes, wherein the deposition array includes a first outer deposition assembly, a second outer deposition assembly, and an inner deposition assembly, the first outer deposition assembly including the three Or at least one first cathode of the plurality of cathodes, the second outer deposition assembly relative to the first outer deposition assembly, the second outer deposition assembly including at least one second cathode of the three or more cathodes, the inner deposition assembly including at least An inner cathode, the inner deposition assembly is positioned between the first outer deposition assembly and the second outer deposition assembly. The first outer deposition assembly defines a first edge portion in the substrate transfer direction, and the second outer deposition assembly defines a second edge portion relative to the first edge portion in the substrate transfer direction, wherein the deposition array further includes a third edge a portion and a fourth edge portion, the third edge portion comprising a first end of the at least one inner cathode of the inner deposition assembly, the fourth edge portion comprising an opposite second end of the cathodes of the inner deposition assembly of the cathode array, Wherein the deposition material on the substrate is further included in the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion to be higher than the first edge portion, the second edge portion, the third edge portion, and the first portion The rate of deposition of the remaining portion of the four edge portions is deposited. According to still further embodiments, the details, features, and aspects as disclosed herein, particularly as disclosed in the accompanying items, may be combined with this embodiment. To create yet another embodiment.

1‧‧‧箭頭 1‧‧‧ arrow

14‧‧‧基板 14‧‧‧Substrate

100‧‧‧設備 100‧‧‧ Equipment

102‧‧‧腔室 102‧‧‧ chamber

103‧‧‧腔室 103‧‧‧ chamber

104‧‧‧閥殼 104‧‧‧ valve housing

105‧‧‧閥單元 105‧‧‧Valve unit

111‧‧‧箭頭 111‧‧‧ arrow

114‧‧‧載具 114‧‧‧ Vehicles

115‧‧‧陽極 115‧‧‧Anode

116‧‧‧氣體管線 116‧‧‧ gas pipeline

121‧‧‧磁鐵組件 121‧‧‧ Magnet assembly

122‧‧‧陰極 122‧‧‧ cathode

123a‧‧‧電源 123a‧‧‧Power supply

123b‧‧‧電源 123b‧‧‧Power supply

123c‧‧‧電源 123c‧‧‧Power supply

130‧‧‧遮蓋屏蔽物 130‧‧‧ Covering shield

133‧‧‧氣體導管或氣體管道 133‧‧‧ gas duct or gas pipeline

134‧‧‧流量控制器 134‧‧‧Flow Controller

135‧‧‧流量控制器 135‧‧‧Flow Controller

136‧‧‧氣體槽 136‧‧‧ gas trough

138‧‧‧氣體進入點 138‧‧‧ gas entry point

141‧‧‧第一組槽 141‧‧‧First set of slots

142‧‧‧第二組槽 142‧‧‧Second group slot

143‧‧‧第三組槽 143‧‧‧ third set of slots

222‧‧‧沉積陣列 222‧‧‧Deposition array

233‧‧‧氣體導管或氣體管道 233‧‧‧ gas ducts or gas pipelines

234‧‧‧流量控制器 234‧‧‧Flow Controller

301‧‧‧外側沉積組件 301‧‧‧External sedimentary components

302‧‧‧外側沉積組件 302‧‧‧Outside deposition components

303‧‧‧內側沉積組件 303‧‧‧Inside deposition assembly

333‧‧‧氣體導管或氣體管道 333‧‧‧ gas duct or gas pipeline

334‧‧‧流量控制器 334‧‧‧Flow controller

410‧‧‧偏心配置 410‧‧‧Eccentric configuration

500‧‧‧控制器 500‧‧‧ controller

501‧‧‧部分 Section 501‧‧‧

502‧‧‧部分 Section 502‧‧‧

503‧‧‧部分 Section 503‧‧‧

504‧‧‧部分 Section 504‧‧‧

505‧‧‧部分 Section 505‧‧‧

600‧‧‧方法 600‧‧‧ method

601‧‧‧步驟 601‧‧ steps

602‧‧‧步驟 602‧‧ steps

D‧‧‧距離 D‧‧‧Distance

為了能夠理解本發明上述特徵的細節,可以參照實施例,得到對於簡單總括於上之本發明更詳細的敘述。所附之圖式是關於本發明的實施例,並敘述如下:第1圖示出根據此處所述的實施例的設備的示意圖,該設備用於材料在一基板上的沉積。 In order to be able to understand the details of the above-described features of the present invention, a more detailed description of the present invention will be made by referring to the embodiments. The accompanying drawings are in relation to embodiments of the invention and are described as follows: Figure 1 shows a schematic view of an apparatus according to embodiments described herein for deposition of material on a substrate.

第2圖示出根據此處所述的實施例的設備的示意圖,該設備用於材料在一基板上的沉積。 Figure 2 shows a schematic of an apparatus according to embodiments described herein for deposition of material on a substrate.

第3A圖示出一設備的剖面示意圖,該設備具有根據此處所述的實施例的一旋轉陰極陣列配置型態,其中該陣列係由交流電源所供應,且其中提供用於控制至少一項製程參數的一控制器。 3A is a cross-sectional view of a device having a rotating cathode array configuration in accordance with embodiments described herein, wherein the array is supplied by an alternating current source and wherein is provided for controlling at least one item A controller for process parameters.

第3B圖示出一設備的剖面示意圖,該設備具有根據此處所述的實施例的一旋轉陰極陣列配置型態,其中該陣列係由直流電源所供應,且其中提供用於控制至少一項製程參數的一控制器。 3B is a cross-sectional view of a device having a rotating cathode array configuration in accordance with embodiments described herein, wherein the array is supplied by a DC power source and wherein is provided for controlling at least one item A controller for process parameters.

第4A圖示出根據此處所述的實施例的一旋轉陰極的剖面示意圖,其中配置成用於變化磁性組件相對於陰極的位置的一偏心配置(eccentric arrangement)係示出在第一位置。 4A is a cross-sectional view of a rotating cathode in accordance with embodiments described herein, wherein an eccentric arrangement configured to vary the position of the magnetic component relative to the cathode is shown in a first position.

第4B圖示出根據此處所述的實施例的一旋轉陰極的剖面示意圖,其中配置成用於變化磁性組件相對於陰極的位置的一偏心配置係示出在第二位置。 4B illustrates a cross-sectional view of a rotating cathode in accordance with embodiments described herein, wherein an eccentric configuration configured to vary the position of the magnetic component relative to the cathode is shown in the second position.

第5圖示出根據此處所述的實施例的設備的示意圖,該設備用於材料在一基板上的沉積。 Figure 5 shows a schematic of an apparatus according to embodiments described herein for deposition of material on a substrate.

第6圖示出根據此處所述的實施例的一流程圖,繪示用於材料在一基板上的沉積的方法。 Figure 6 illustrates a flow diagram for deposition of a material on a substrate in accordance with an embodiment described herein.

現在將對於本發明的各種實施例進行詳細說明,本發明的一或多個示例係繪示於圖中。在以下對於圖式的敘述中,相同的元件符號意指相同的元件。在以下內容中,只會對於個別實施例的不同處進行敘述。各個示例是以解釋本發明的方式來提供,而非意味著作為本發明的限制。另外,作為一個實施例的一部分而被繪示或敘述的特徵,能夠被用於或結合其他實施例,以產生另外的一實施例。所述內容意欲包含這樣的修改和變化。 Various embodiments of the invention will now be described in detail, and one or more examples of the invention are illustrated in the drawings. In the following description of the drawings, the same element symbols mean the same elements. In the following, only the differences of the individual embodiments will be described. The various examples are provided by way of explanation of the invention, and are not intended to limit the invention. In addition, features illustrated or described as part of one embodiment can be used or combined with other embodiments to create a further embodiment. The content is intended to encompass such modifications and variations.

根據此處所述的實施例,並示例性地參照第1圖,提供一設備100,設備100用於材料在一基板上的沉積,設備100包含一沉積陣列222,沉積陣列222具有三或多個陰極。沉積陣列222包含一第一外側沉積組件301、一第二外側沉積組件302、和一內側沉積組件303,第一外側沉積組件301包括該三或多個陰極中的至少一第一陰極,第二外側沉積組件302相對於第一外側沉積組件,第二外側沉積組件302包括該三或多個陰極中的至少一第二陰極,內側沉積組件303包括至少一內側陰極,內側沉積組件303位在第一外側沉積組件和第二外側沉積組件之間。第一外側沉積組件和第二外側沉積組件中的至少一者,係配置成用於在相同的時間之中於相同的基板上以高於內側沉積組件的速率沉積材料,如第1圖底部的圖所示例性地示出的,在該圖中,繪製第一外側沉積組件301和第二外側沉積組件302之間整段距離的沉積速率DR。如第1圖底部的圖所繪示的,在第1圖的示 例性實施例中,第一外側沉積組件301和第二外側沉積組件302二者皆配置成用於以高於內側沉積組件的速率沉積材料。 In accordance with an embodiment described herein, and by way of example with reference to FIG. 1, an apparatus 100 is provided for deposition of material on a substrate, apparatus 100 includes a deposition array 222 having three or more deposition arrays 222 Cathode. The deposition array 222 includes a first outer deposition assembly 301, a second outer deposition assembly 302, and an inner deposition assembly 303. The first outer deposition assembly 301 includes at least one of the three or more cathodes, and a second The outer deposition assembly 302 is opposite to the first outer deposition assembly, the second outer deposition assembly 302 includes at least one second cathode of the three or more cathodes, the inner deposition assembly 303 includes at least one inner cathode, and the inner deposition assembly 303 is at the An outer deposition assembly and a second outer deposition assembly. At least one of the first outer deposition assembly and the second outer deposition assembly is configured to deposit material at a rate higher than the inner deposition assembly on the same substrate over the same time, as at the bottom of FIG. Illustratively shown in the figure, in this figure, the deposition rate DR of the entire distance between the first outer deposition assembly 301 and the second outer deposition assembly 302 is plotted. As shown in the figure at the bottom of Figure 1, the illustration in Figure 1 In an exemplary embodiment, both the first outer deposition assembly 301 and the second outer deposition assembly 302 are configured to deposit material at a higher rate than the inner deposition assembly.

因此,藉由提供具有配置成用於以高於內側沉積組件的速率沉積材料的外側沉積組件的設備,能夠實質上避免在傳送方向中於基板邊緣處的厚度降低。由此,此處所述的設備允許均勻塗層在基板上的沉積,特別是在靜態沉積製程期間於大面積基板上的沉積。 Thus, by providing an apparatus having an outer deposition assembly configured to deposit material at a higher rate than the inner deposition assembly, thickness reduction at the edge of the substrate in the transport direction can be substantially avoided. Thus, the apparatus described herein allows for the deposition of a uniform coating on a substrate, particularly on a large area substrate during a static deposition process.

在本揭露書中,且不受限於任何此處所述的特定實施例,用詞「沉積速率」或「沉積的速率」可以被理解成塗佈材料在每單位時間內沉積於基板上的量。 In the present disclosure, and without being limited to any of the specific embodiments described herein, the terms "deposition rate" or "deposition rate" may be understood to mean that the coating material is deposited on the substrate per unit time. the amount.

在本揭露書中,且不受限於任何此處所述的特定實施例,一沉積陣列包含多個沉積組件,特別是至少三個沉積組件。該些沉積組件可以被配置成彼此相鄰。特別是,該些沉積組件可以被配置成彼此平行,例如以鄰近的沉積組件之間等距的方式平行。 In the present disclosure, and without being limited to any of the specific embodiments described herein, a deposition array includes a plurality of deposition assemblies, particularly at least three deposition assemblies. The deposition assemblies can be configured to be adjacent to each other. In particular, the deposition assemblies can be configured to be parallel to each other, such as in an equidistant manner between adjacent deposition assemblies.

在本揭露書中,且不受限於任何此處所述的特定實施例,沉積組件可以包含至少一沉積源,其用於材料在一基板上的沉積,例如是一靶材。沉積組件可以包含選自由下列選項組成之群組的至少一者:氣體分佈系統、陰極(特別是旋轉陰極)、電源、磁鐵組件、和用於控制至少一項處理參數的手段。該用於控制至少一項處理參數的手段,能例如包含用於控制一沉積組件的電源的一控制器、和/或用於控制到一沉積組件的處理氣體量的一流量控制器、和/或用於控制一磁鐵組件的磁場的一元件例如一偏 心配置。偏心配置可以被配置成用於變化磁性組件相對於陰極的位置。 In the present disclosure, and without being limited to any of the specific embodiments described herein, the deposition assembly can include at least one deposition source for deposition of the material on a substrate, such as a target. The deposition assembly can include at least one selected from the group consisting of a gas distribution system, a cathode (particularly a rotating cathode), a power source, a magnet assembly, and means for controlling at least one processing parameter. The means for controlling at least one processing parameter can, for example, comprise a controller for controlling the power supply of a deposition assembly, and/or a flow controller for controlling the amount of process gas to a deposition assembly, and / Or a component for controlling the magnetic field of a magnet assembly, such as a bias Heart configuration. The eccentric configuration can be configured to vary the position of the magnetic component relative to the cathode.

根據能夠和此處所述其他實施例結合的不同實施例,濺射能夠以直流(direct current,DC)濺射、中頻(middle frequency,MF)濺射、射頻濺射、或脈衝濺射的方式進行。如此處所述,一些沉積製程可能有利地應用中頻、直流、或脈衝濺射。 然而,也能夠應用其他濺射方法。根據此處的實施例,中頻是在0.5kHz至350kHz的範圍之中的頻率,例如是在10kHz至50kHz的範圍之中的頻率。 According to different embodiments that can be combined with other embodiments described herein, sputtering can be by direct current (DC) sputtering, middle frequency (MF) sputtering, radio frequency sputtering, or pulsed sputtering. Way to proceed. As described herein, some deposition processes may advantageously employ intermediate frequency, direct current, or pulsed sputtering. However, other sputtering methods can also be applied. According to embodiments herein, the intermediate frequency is a frequency in the range of 0.5 kHz to 350 kHz, such as a frequency in the range of 10 kHz to 50 kHz.

根據一些能夠和此處所述其他實施例結合的實施例,根據所述實施例的濺射能夠以三或多個陰極進行。然而,特別是對於大面積沉積的應用而言,陰極的一陣列具有六或多個陰極,例如十或多個陰極。舉例而言,能夠提供三或多個陰極或陰極對,例如四個、五個、六個、或甚至更多個陰極或陰極對。該陣列能夠提供在一個真空腔室中。另外,陣列典型地能夠被定義成使得相鄰的陰極或陰極對彼此影響,例如是藉由具有互相作用的電漿限制。根據典型的實施方案,濺射能夠藉由一旋轉陰極陣列來進行,例如但不限於譬如應用材料公司之PiVot的系統。 According to some embodiments that can be combined with other embodiments described herein, sputtering according to the embodiments can be performed with three or more cathodes. However, especially for large area deposition applications, an array of cathodes has six or more cathodes, such as ten or more cathodes. For example, three or more cathode or cathode pairs can be provided, such as four, five, six, or even more cathode or cathode pairs. The array can be provided in a vacuum chamber. Additionally, arrays can typically be defined such that adjacent cathodes or cathodes affect each other, for example by plasma interaction with interaction. According to a typical embodiment, sputtering can be performed by a rotating cathode array such as, but not limited to, a system such as Applied Materials' PiVot.

根據又另外的能夠和此處所述其他實施例結合的典型實施例,材料在基板上的靜態沉積係藉由反應性濺射製程來完成。那意味著,膜的化學計量比係藉由使用非反應性氣體和反應性氣體的混合物濺射或者金屬靶材、或者半金屬靶材、或者化合物靶材而得到。典型地,此處所述的實施例也可以適用於只使用非反應性氣體作為處理氣體的金屬層或半導電層的靜態沉積。在 這個案例中,本發明實施例的設備和方法可以允許沿著水平方向具有不同的局部製程壓力,特別是在基板邊緣和基板的內側區域相比具有不同的製程壓力。 According to yet another exemplary embodiment that can be combined with other embodiments described herein, static deposition of material on the substrate is accomplished by a reactive sputtering process. That means that the stoichiometric ratio of the film is obtained by sputtering or a metal target, or a semi-metal target, or a compound target using a mixture of a non-reactive gas and a reactive gas. Typically, the embodiments described herein are also applicable to the static deposition of metal or semiconducting layers using only non-reactive gases as process gases. in In this case, the apparatus and method of the embodiments of the present invention may allow for different local process pressures along the horizontal direction, particularly with different process pressures at the edge of the substrate and the inner region of the substrate.

據此,此處所述的一些實施例是關於在基板上沉積材料層的設備和方法。特別是對於反應性濺射製程而言,均勻性和/或電漿穩定性是要被考慮的關鍵性參數。反應性濺射製程,例如在其進行期間,材料係在氧氣氣氛或另一反應性氣氛之下濺射,以沉積一含有被濺射的材料的氧化物或類似物的層的沉積製程,這樣的反應性濺射製程需要在電漿穩定性的方面被控制。典型地,反應性沉積製程具有一遲滯曲線。反應性沉積製程能夠例如是氧化鋁(Al2O3)、或氧化矽(SiO2)、或銦鎵鋅氧化物(IGZO)的沉積,其中鋁、矽、銦、鎵、或鋅是從陰極濺射,而氧氣係提供在電漿中。舉例而言,氧化鋁、氧化矽、或銦鎵鋅氧化物能夠被沉積在基板上。遲滯曲線典型地是沉積參數的函數,例如提供至濺射陰極的電壓與處理氣體(例如氧氣)的流動相關。 Accordingly, some embodiments described herein are directed to apparatus and methods for depositing a layer of material on a substrate. Especially for reactive sputtering processes, uniformity and/or plasma stability are key parameters to be considered. A reactive sputtering process, for example, during which the material is sputtered under an oxygen atmosphere or another reactive atmosphere to deposit a deposition process comprising a layer of oxide or the like of the sputtered material, such that The reactive sputtering process needs to be controlled in terms of plasma stability. Typically, the reactive deposition process has a hysteresis curve. The reactive deposition process can be, for example, deposition of aluminum oxide (Al 2 O 3 ), or yttrium oxide (SiO 2 ), or indium gallium zinc oxide (IGZO), wherein aluminum, germanium, indium, gallium, or zinc is from the cathode. Sputtering, while oxygen is provided in the plasma. For example, aluminum oxide, cerium oxide, or indium gallium zinc oxide can be deposited on a substrate. The hysteresis curve is typically a function of the deposition parameters, such as the voltage supplied to the sputtering cathode is related to the flow of the process gas (e.g., oxygen).

此處所述的實施例,在靜態反應性濺射製程期間在沿著基板傳送方向(以下稱為水平方向)的不同位置處存在著不同電漿密度、或不同的反應性氣體消耗的情況中,允許改善均勻性。這些不同也造成基板上的不均勻沉積。此處所述的實施例允許補償在水平方向(亦即基板傳送方向或垂直於旋轉陰極的旋轉軸的方向)中的膜性質的變化。由此,此處所述的實施例特別是配置成用於在整個基板上,亦即包含在基板的傳送方向中的基板邊緣,提供均勻的塗層。 The embodiments described herein have different plasma densities, or different reactive gas consumptions, at different locations along the substrate transport direction (hereinafter referred to as the horizontal direction) during the static reactive sputtering process. Allows for improved uniformity. These differences also cause uneven deposition on the substrate. The embodiments described herein allow for compensating for variations in film properties in the horizontal direction (i.e., the substrate transfer direction or the direction perpendicular to the axis of rotation of the rotating cathode). Thus, the embodiments described herein are specifically configured to provide a uniform coating over the entire substrate, i.e., the edge of the substrate contained in the direction of transport of the substrate.

根據能夠和此處所述其他實施例結合的實施例,處 理氣體中至少一種的分壓係沿著水平方向(亦即沿著基板傳送方向)在第一外側沉積組件和/或第二外側沉積組件處有所不同。舉例而言,係改變反應性氣體(例如氧氣)的分壓。還可能額外地改變一第二處理氣體的壓力,該第二處理氣體例如是一非反應性或惰性氣體。據此,總壓力能夠實質上維持不變。 According to an embodiment that can be combined with other embodiments described herein, The partial pressure system of at least one of the gas is different in the horizontal direction (i.e., along the substrate transport direction) at the first outer deposition component and/or the second outer deposition component. For example, the partial pressure of a reactive gas such as oxygen is changed. It is also possible to additionally change the pressure of a second process gas, such as a non-reactive or inert gas. Accordingly, the total pressure can be substantially maintained.

根據典型的實施例,處理氣體能夠包含非反應性氣體和/或反應性氣體,非反應性氣體例如是氬氣(Ar),反應性氣體例如是氧氣(O2)、氮氣(N2)、氫氣(H2)、水(H2O)、氨(NH3)、臭氧(O3)、活化氣體、或類似氣體。 According to a typical embodiment, the process gas can comprise a non-reactive gas such as argon (Ar), and a reactive gas such as oxygen (O 2 ), nitrogen (N 2 ), Hydrogen (H 2 ), water (H 2 O), ammonia (NH 3 ), ozone (O 3 ), an activating gas, or the like.

已經發現到,對於靜態沉積製程而言,膜性質可以以多種方式變化,該些方式導致不均勻性。以上述的設計和製程,不可能補償膜性質在水平方向中的任何變化,特別是在待塗佈的基板的邊緣的變化。為了能對於靜態沉積補償在水平方向中,特別是在基板的邊緣的膜性質的局部不同,本發明的實施例提供設備和方法,以其能夠達成越過整個基板、包含基板邊緣的均勻膜厚度。因此,根據能夠和此處其他實施例結合的實施例,如第2圖示例性地示出的,提供一氣體分佈系統,其係配置成用於供應不同的處理氣體條件到第一外側沉積組件和/或第二外側沉積組件。 It has been found that for static deposition processes, film properties can be varied in a number of ways that result in non-uniformities. With the above design and process, it is not possible to compensate for any change in film properties in the horizontal direction, particularly at the edges of the substrate to be coated. In order to be able to compensate for local differences in film properties in the horizontal direction, particularly at the edges of the substrate, for static deposition, embodiments of the present invention provide apparatus and methods that enable uniform film thickness across the entire substrate, including the edge of the substrate. Thus, in accordance with an embodiment that can be combined with other embodiments herein, as exemplarily shown in FIG. 2, a gas distribution system is provided that is configured to supply different process gas conditions to a first outer deposition A component and/or a second outer deposition component.

請參照第2圖,係示出一用於材料在一基板上的沉積的設備,該設備具有一沉積陣列222,沉積陣列222包含一第一外側沉積組件301和一第二外側沉積組件302,第一外側沉積組件301伴隨著至少一第一陰極122,第二外側沉積組件302相對於第一外側沉積組件101,第二外側沉積組件302伴隨著至少 一第二陰極122。另外,根據此處所述的實施例,提供一內側沉積組件303,內側沉積組件303包含至少一內側陰極122,內側沉積組件303位在第一外側沉積組件301和第二外側沉積組件302之間。在如第2圖所示例性示出的實施例中,第一外側沉積組件301和第二外側沉積組件302各包含一個陰極,其中內側沉積組件301包含十個陰極。 Referring to FIG. 2, there is shown an apparatus for depositing a material on a substrate, the apparatus having a deposition array 222 comprising a first outer deposition assembly 301 and a second outer deposition assembly 302. The first outer deposition assembly 301 is accompanied by at least one first cathode 122, the second outer deposition assembly 302 is opposite the first outer deposition assembly 101, and the second outer deposition assembly 302 is accompanied by at least A second cathode 122. Additionally, in accordance with embodiments described herein, an inner deposition assembly 303 is provided that includes at least one inner cathode 122 that is positioned between the first outer deposition assembly 301 and the second outer deposition assembly 302 . In the embodiment exemplarily shown in Fig. 2, the first outer deposition assembly 301 and the second outer deposition assembly 302 each comprise a cathode, wherein the inner deposition assembly 301 comprises ten cathodes.

根據此處所述的實施例,設備包含一處理氣體分佈系統,其配置成用於提供一處理氣體到沉積陣列222。特別是,如第2圖示例性地示出的,氣體分佈系統可以被配置成用於對於外側沉積組件301、302和內側沉積組件303獨立地控制處理氣體的流動速率。因此,在待塗佈的基板的邊緣處的製程參數,例如氣體分壓和/或供應的處理氣體量,能夠獨立於在待塗佈的基板的內側區域處的製程參數而被修改和調整,如此而可以達成均勻的塗層厚度。據此,能夠實質上避免在傳送方向中於基板邊緣處的厚度降低。在第2圖中,基板傳送方向係由箭頭111指示。這特別是有利於其中基板是為了靜態沉積製程而被放置的沉積製程。根據一些能夠和此處所述其他實施例結合的實施例,至少一種處理氣體的流動速率能夠對於第一外側沉積組件和第二外側沉積組件中的至少一者而言獨立地變化,例如藉由第2圖示例性地示出的流量控制器。 In accordance with embodiments described herein, the apparatus includes a process gas distribution system configured to provide a process gas to the deposition array 222. In particular, as exemplarily shown in FIG. 2, the gas distribution system can be configured to independently control the flow rate of the process gas for the outer deposition assemblies 301, 302 and the inner deposition assembly 303. Thus, process parameters at the edges of the substrate to be coated, such as gas partial pressure and/or amount of process gas supplied, can be modified and adjusted independently of process parameters at the inner region of the substrate to be coated, This achieves a uniform coating thickness. According to this, it is possible to substantially avoid the thickness reduction at the edge of the substrate in the conveying direction. In FIG. 2, the substrate transfer direction is indicated by an arrow 111. This is particularly advantageous for deposition processes in which the substrate is placed for a static deposition process. According to some embodiments, which can be combined with other embodiments described herein, the flow rate of the at least one process gas can vary independently for at least one of the first outer deposition component and the second outer deposition component, for example by The flow controller is exemplarily shown in Fig. 2.

根據此處所述的實施例,處理氣體分佈系統係配置成用於提供一第一處理氣體條件到第一外側沉積組件301和第二外側沉積組件302,並用於提供一第二處理氣體條件到內側沉積組件303。示例性地參照第2圖,根據此處所述的實施例,設備 包含一氣體分佈系統,其配置成用於以三重水平分段提供一處理氣體,其中第一區段包含第一外側沉積組件301,第二區段包含第二外側沉積組件302,第三區段包含內側沉積組件303。氣體分佈系統可以包含位在多條氣體管線116之中的多個氣體進入點138。該多條氣體管線116,例如其中具有開口的導管,能夠被放置在沉積陣列222的成對陰極122之間,沿著水平方向,平行於它們的長軸。 According to embodiments described herein, the process gas distribution system is configured to provide a first process gas condition to the first outer deposition assembly 301 and the second outer deposition assembly 302 and to provide a second process gas condition to The inner deposition assembly 303. By way of example with reference to Figure 2, in accordance with embodiments described herein, a device A gas distribution system is included that is configured to provide a process gas in a triple horizontal section, wherein the first section includes a first outer deposition assembly 301 and the second section includes a second outer deposition assembly 302, a third section An inner deposition assembly 303 is included. The gas distribution system can include a plurality of gas entry points 138 located in the plurality of gas lines 116. The plurality of gas lines 116, such as conduits having openings therein, can be placed between the pair of cathodes 122 of the deposition array 222, along the horizontal direction, parallel to their long axes.

根據此處所述的實施例,氣體分佈系統可以包含一第一流量控制器234和一第二流量控制器134,第一流量控制器234係配置成用於控制到第一外側沉積組件301和第二外側沉積組件302的處理氣體量,第二流量控制器134係配置成用於控制到內側沉積組件303的處理氣體量。在第2圖的示例性實施例中,示出三個流量控制器:一個第二流量控制器134用於控制到內側沉積組件303的處理氣體量,二個第一流量控制器234分別用於控制到第一外側沉積組件301的處理氣體量和到第二外側沉積組件302的處理氣體量。根據實施例,用於控制到第一外側沉積組件301和第二外側沉積組件302的處理氣體量的二個第一流量控制器234可以是同等的。或者,用於控制到第一外側沉積組件301和第二外側沉積組件302的處理氣體量的該二個第一流量控制器234可以不同地配置。 According to embodiments described herein, the gas distribution system can include a first flow controller 234 and a second flow controller 134 configured to control to the first outer deposition assembly 301 and The amount of process gas of the second outer deposition assembly 302, the second flow controller 134 is configured to control the amount of process gas to the inner deposition assembly 303. In the exemplary embodiment of Fig. 2, three flow controllers are shown: one second flow controller 134 for controlling the amount of process gas to the inner deposition assembly 303, and two first flow controllers 234 for respectively The amount of process gas to the first outer deposition assembly 301 and the amount of process gas to the second outer deposition assembly 302 are controlled. According to an embodiment, the two first flow controllers 234 for controlling the amount of process gas to the first outer deposition assembly 301 and the second outer deposition assembly 302 may be equivalent. Alternatively, the two first flow controllers 234 for controlling the amount of process gas to the first outer deposition assembly 301 and the second outer deposition assembly 302 can be configured differently.

如第2圖示例性地示出的,處理氣體分佈系統可以具有二個含有處理氣體的氣體槽136。存在於處理氣體中的非反應性氣體和/或反應性氣體的流動速率和/或量,可以藉由流量控制器135控制。處理氣體分別經由流量控制器134和234通過氣 體導管或氣體管道133和233饋入至位在多條氣體管線116之中的多個氣體進入點138。根據又另外的能夠和此處所述其他實施例結合的實施例,處理氣體中的一或多種的流動速率,亦即處理氣體中的一或多種的量,也能夠藉由另一流動速率控制元件來控制,例如針閥。據此,流量控制器、針閥、和/或其他流動速率控制元件,能夠被用以對於氣體分佈系統的複數個區段獨立地控制一或多種處理氣體的流動速率,或對於氣體分佈系統的複數個區段獨立地控制一或多種處理氣體的量。 As exemplarily shown in Fig. 2, the process gas distribution system can have two gas tanks 136 containing process gases. The flow rate and/or amount of non-reactive gas and/or reactive gas present in the process gas can be controlled by flow controller 135. The process gas passes through the flow controllers 134 and 234, respectively. Body conduits or gas conduits 133 and 233 are fed into a plurality of gas entry points 138 located in a plurality of gas lines 116. According to still further embodiments which can be combined with other embodiments described herein, the flow rate of one or more of the process gases, i.e., the amount of one or more of the process gases, can also be controlled by another flow rate. Components to control, such as needle valves. Accordingly, flow controllers, needle valves, and/or other flow rate control elements can be used to independently control the flow rate of one or more process gases for a plurality of sections of the gas distribution system, or for gas distribution systems The plurality of segments independently control the amount of one or more process gases.

根據能夠和此處所述其他實施例結合的實施例,氣體分佈系統可以被配置成用於提供和內側沉積組件相比不同的處理氣體混合物到第一外側沉積組件301和第二外側沉積組件302,尤其是伴隨著反應性氣體的變化。因此,示例性地參照第3A圖,第一外側沉積組件301可以被連接至用於提供第一組成之反應性氣體的第一組槽141,第二外側沉積組件302可以被連接至用於提供第二組成之反應性氣體的第二組槽142,內側沉積組件可以被連接至用於提供第三組成之反應性氣體到內側沉積組件的第三組槽143。根據實施例,供應到第一外側沉積組件301的第一組成之反應性氣體,可以對應至供應到第二外側沉積組件302的第二組成之反應性氣體。因此,設備的實施例,如第3A圖示例性地示出的,係配置成用於對於第一外側沉積組件301、第二外側沉積組件302和內側沉積組件303獨立地提供不同的處理氣體流動速率、和/或不同的處理氣體量、和/或不同的處理氣體混合物,尤其是伴隨著反應性氣體的變化。 According to embodiments that can be combined with other embodiments described herein, the gas distribution system can be configured to provide a different process gas mixture to the first outer deposition assembly 301 and the second outer deposition assembly 302 than the inner deposition assembly. Especially with the change of reactive gases. Thus, by way of example with reference to FIG. 3A, a first outer deposition assembly 301 can be coupled to a first set of slots 141 for providing a first composition of reactive gas, and a second outer deposition assembly 302 can be coupled for providing A second set of channels 142 of the second composition of reactive gases, the inner deposition assembly can be coupled to a third set of channels 143 for providing a third composition of reactive gas to the inner deposition assembly. According to an embodiment, the reactive gas supplied to the first composition of the first outer deposition assembly 301 may correspond to the reactive gas supplied to the second composition of the second outer deposition assembly 302. Accordingly, an embodiment of the apparatus, as exemplarily shown in FIG. 3A, is configured to independently provide different process gases for the first outer deposition assembly 301, the second outer deposition assembly 302, and the inner deposition assembly 303. The flow rate, and/or the amount of different process gases, and/or different process gas mixtures, especially with changes in reactive gases.

第3A圖示出根據此處所述的實施例的一沉積設備 100的剖面示意圖。示例性地,示出一個真空的腔室102,用於其中的層沉積。如第3A圖指出的,能夠提供另外的腔室103,相鄰於腔室102。真空腔室102能夠藉由一閥而從相鄰的腔室分開,該閥具有一閥殼104和一閥單元105。在其上帶有基板14的載具114如箭頭1所指示地被加入至真空腔室102中之後,能夠關閉閥單元105。據此,真空腔室102和103中的氣氛能夠藉由例如以連接至腔室102和103的真空幫浦產生技術上的真空(technical vacuum),和/或藉由將處理氣體添加到腔室內的沉積區中,而獨立地被控制。如上所述,對於大面積處裡應用而言,大面積基板係由載具所支撐。然而,此處所述的實施例並不受限於此,而可以使用其他用於傳送基板通過處理設備或處理系統的傳送元件。 3A shows a deposition apparatus in accordance with embodiments described herein A schematic view of the section of 100. Illustratively, a vacuum chamber 102 is shown for layer deposition therein. As indicated in Figure 3A, an additional chamber 103 can be provided adjacent to the chamber 102. The vacuum chamber 102 can be separated from adjacent chambers by a valve having a valve housing 104 and a valve unit 105. After the carrier 114 with the substrate 14 thereon is added to the vacuum chamber 102 as indicated by the arrow 1, the valve unit 105 can be closed. Accordingly, the atmosphere in the vacuum chambers 102 and 103 can be created by, for example, a vacuum vacuum connected to the chambers 102 and 103, and/or by adding a process gas to the chamber. In the sedimentary zone, it is independently controlled. As noted above, for large area applications, large area substrates are supported by the carrier. However, the embodiments described herein are not limited thereto, and other transfer elements for transporting the substrate through the processing device or processing system may be used.

在腔室102之中,提供一傳送系統,以將其上具有基板14的載具114傳送進入至腔室102中或離開腔室102。如此處所使用的用詞「基板」,應囊括非可撓性基板,例如玻璃基板、晶圓、透明結晶如藍寶石或類似物的薄片、或玻璃板。 Within the chamber 102, a delivery system is provided to transport the carrier 114 having the substrate 14 thereon into or out of the chamber 102. The term "substrate" as used herein shall encompass a non-flexible substrate such as a glass substrate, a wafer, a sheet of transparent crystal such as sapphire or the like, or a glass plate.

如第3A圖所繪示的,在腔室102之中,提供沉積源122。沉積源能夠例如是可旋轉陰極,其具有待沉積在基板上的材料的靶材。根據能夠和此處所述其他實施例結合的實施例,陰極能夠是可旋轉陰極,伴隨著磁鐵組件121於其中。能夠進行磁控濺射,用於層的沉積。如第3A圖示例性地示出的,各對鄰近的陰極能夠被連接至一電源123。取決於在靶材陣列之範圍內的沉積製程的本質,或者各對鄰近的陰極能夠被連接至一交流電源,或者各對鄰近的陰極能夠被連接至一直流電源。根據一些能夠和此處所述其他實施例結合的實施例,陰極122係連接至交流 電源,使得陰極能夠以交替的方式被偏壓。交流電源123,例如中頻電源,能夠被提供以例如沉積氧化鋁(Al2O3)層。在這樣的案例中,由於藉由成對陰極122提供包含陰極和陽極的完整電路,陰極不需要額外的陽極,陽極能夠例如被移除。 As depicted in FIG. 3A, a deposition source 122 is provided in the chamber 102. The deposition source can for example be a rotatable cathode having a target of material to be deposited on the substrate. According to an embodiment that can be combined with other embodiments described herein, the cathode can be a rotatable cathode with the magnet assembly 121 therein. Magnetron sputtering can be performed for layer deposition. As exemplarily shown in FIG. 3A, each pair of adjacent cathodes can be connected to a power source 123. Depending on the nature of the deposition process within the range of the target array, or each pair of adjacent cathodes can be connected to an alternating current source, or each pair of adjacent cathodes can be connected to a direct current source. According to some embodiments that can be combined with other embodiments described herein, the cathode 122 is connected to an alternating current source such that the cathode can be biased in an alternating manner. An alternating current source 123, such as an intermediate frequency power source, can be provided, for example, to deposit an aluminum oxide (Al 2 O 3 ) layer. In such a case, since a complete circuit comprising a cathode and an anode is provided by the pair of cathodes 122, the cathode does not require an additional anode and the anode can be removed, for example.

示例性地參照第3B圖,根據其他實施例,設備可以包含陰極122和陽極115,其可以電性連接至直流電源。根據另外的能夠和此處所述其他實施例結合的實施例,沉積設備能夠包括沿著水平方向延伸的一個陽極、或如第3B圖示例性地示出的沿著水平方向間隔開來的至少三個陽極。 Illustratively with reference to FIG. 3B, according to other embodiments, the apparatus can include a cathode 122 and an anode 115 that can be electrically coupled to a DC power source. According to further embodiments, which can be combined with other embodiments described herein, the deposition apparatus can comprise an anode extending in a horizontal direction, or spaced apart in a horizontal direction as exemplarily shown in FIG. 3B At least three anodes.

從靶材的濺射,例如是用於透明導電氧化物膜的從靶材的濺射,典型地是以直流濺射的方式進行。陰極可以偕同陽極一起連接至直流電源,以在濺射期間收集電子。根據一些能夠和此處所述其他實施例結合的實施例,氣體管線116能夠提供在陽極115或一屏蔽物的一側,而陰極能夠提供在該陽極或屏蔽物的另一側(例如見第3A圖)。氣體能夠通過陽極或屏蔽物中的開口(未示出)提供在沉積區中。根據一替代性的實施方案,氣體管線或導管和陰極也可以提供在陽極或屏蔽物的同一側。 Sputtering from the target, for example, sputtering from a target for a transparent conductive oxide film, is typically performed by direct current sputtering. The cathode can be connected to the DC power source along with the anode to collect electrons during sputtering. According to some embodiments that can be combined with other embodiments described herein, the gas line 116 can be provided on one side of the anode 115 or a shield, and the cathode can be provided on the other side of the anode or shield (see, for example, 3A)). Gas can be provided in the deposition zone through an opening in the anode or shield (not shown). According to an alternative embodiment, a gas line or conduit and cathode may also be provided on the same side of the anode or shield.

根據又另外的能夠和此處所述其他實施例結合的實施例,陰極中的一或多個能夠分別具有它們對應的獨立電壓供應。舉例而言,對於至少一個、一些、或全部的陰極,能夠對每個陰極提供一個電源。據此,至少一個第一陰極能夠被連接至一第一電源,而一第二陰極能夠被連接至一第二電源。根據又另外的能夠和此處所述其他實施例結合的實施例,舉例而言,像是銦錫氧化物(ITO)、銦鋅氧化物(IZO)、銦鎵鋅氧化物(IGZO)、或氮 化鉬(MoN)的材料,可以以直流濺射沉積製程來沉積。 According to still further embodiments which can be combined with other embodiments described herein, one or more of the cathodes can each have their respective independent voltage supply. For example, for at least one, some, or all of the cathodes, one power source can be provided for each cathode. Accordingly, at least one first cathode can be connected to a first power source and a second cathode can be connected to a second power source. According to still further embodiments which can be combined with other embodiments described herein, for example, indium tin oxide (ITO), indium zinc oxide (IZO), indium gallium zinc oxide (IGZO), or nitrogen Molybdenum (MoN) materials can be deposited by a DC sputtering process.

如第3B圖所進一步繪示的,在腔室102之中,也提供多條氣體管線116和遮蓋屏蔽物130。如第3A和3B圖示例性地示出的,設備100的氣體分佈系統可以包含六個含有處理氣體的氣體槽136。存在於處理氣體中的非反應性氣體和/或反應性氣體的流動速率,能夠藉由流量控制器135控制。處理氣體可以分別經由流量控制器134、234和334通過氣體導管或氣體管道133、233和333饋入至位在多條氣體管線126之中的多個氣體進入點138(未示出)。據此,此處所述的設備的實施例,允許獨立地提供不同的處理氣體流動速率和/或不同的處理氣體混合物到第一外側沉積組件301、第二外側沉積組件302和內側沉積組件303。據此,係提供用於在一基板上沉積材料的一設備,以其能夠實質上避免在傳送方向中於基板邊緣處的厚度降低。 As further illustrated in FIG. 3B, a plurality of gas lines 116 and a cover shield 130 are also provided in the chamber 102. As exemplarily shown in Figures 3A and 3B, the gas distribution system of apparatus 100 can include six gas tanks 136 containing process gases. The flow rate of the non-reactive gas and/or the reactive gas present in the process gas can be controlled by the flow controller 135. The process gas may be fed to a plurality of gas entry points 138 (not shown) located in the plurality of gas lines 126 via gas conduits or gas conduits 133, 233, and 333 via flow controllers 134, 234, and 334, respectively. Accordingly, embodiments of the apparatus described herein allow for differently provided different process gas flow rates and/or different process gas mixtures to the first outer deposition assembly 301, the second outer deposition assembly 302, and the inner deposition assembly 303, respectively. . Accordingly, an apparatus for depositing material on a substrate is provided that is capable of substantially avoiding a reduction in thickness at the edge of the substrate in the transport direction.

如第3A和3B圖所示,此處所述的實施例能夠提供用於靜態沉積製程,例如閥單元105係在沉積期間關閉,並伴隨著多個旋轉陰極,例如三或多個旋轉陰極。當關上沉積製程時,基板14係移動至沉積區內用於沉積的位置中。能夠穩定製程壓力。一旦製程被穩定下來,陰極磁鐵組件121能夠朝前旋轉,以沉積待沉積材料的正確化學計量比至靜態的基板上,直到沉積結束為止。 As shown in Figures 3A and 3B, the embodiments described herein can be provided for a static deposition process, such as valve unit 105 being closed during deposition, with a plurality of rotating cathodes, such as three or more rotating cathodes. When the deposition process is closed, the substrate 14 is moved into a position in the deposition zone for deposition. Ability to stabilize process pressure. Once the process is stabilized, the cathode magnet assembly 121 can be rotated forward to deposit the correct stoichiometric ratio of material to be deposited onto the static substrate until the end of deposition.

示例性地參照第3A和3B圖,根據此處所述的實施例的設備可以包含一控制器500,其係配置成用於控制第一外側沉積組件和第二外側沉積組件的至少一項製程參數。另外,控制器500可以被配置成用於控制內側沉積組件的至少一項製程參 數。根據此處所述的實施例,一沉積組件(例如第一外側沉積組件、第二外側沉積組件、和內側沉積組件)可以包含至少一陰極(特別是一旋轉陰極)、一氣體分佈系統或氣體分佈系統的一區段、和一磁性組件。因此,根據此處所述的實施例,該至少一項處理參數能夠藉由控制器500所控制。根據此處所述的實施例,該至少一項處理參數係選自由下列選項組成之群組的至少一者:供應到第一外側沉積組件和第二外側沉積組件的電力、供應到第一外側沉積組件和第二外側沉積組件的處理氣體量、以及在第一外側沉積組件和第二外側沉積組件的磁場。據此,係提供一用於材料在一基板上的沉積的設備,其係配置成以其而使得材料能夠在相同的時間之中於相同的基板上,在第一外側沉積組件301和/或第二外側沉積組件(302)以高於在內側沉積組件303的速率沉積。據此,係提供一用於材料在一基板上的沉積的設備,以其能夠實質上避免在傳送方向中於基板邊緣處的厚度降低。 Illustratively with reference to Figures 3A and 3B, the apparatus according to embodiments described herein can include a controller 500 configured to control at least one of the first outer deposition assembly and the second outer deposition assembly parameter. Additionally, the controller 500 can be configured to control at least one process parameter of the inner deposition assembly number. According to embodiments described herein, a deposition assembly (eg, a first outer deposition assembly, a second outer deposition assembly, and an inner deposition assembly) can include at least one cathode (particularly a rotating cathode), a gas distribution system, or a gas A section of the distribution system, and a magnetic component. Thus, in accordance with embodiments described herein, the at least one processing parameter can be controlled by controller 500. According to embodiments described herein, the at least one processing parameter is selected from at least one of the group consisting of: power supplied to the first outer deposition component and the second outer deposition component, supplied to the first outer side The amount of process gas of the deposition assembly and the second outer deposition assembly, and the magnetic fields of the first outer deposition assembly and the second outer deposition assembly. Accordingly, an apparatus for depositing material on a substrate is provided that is configured to enable the material to deposit component 301 and/or on the first outer side over the same substrate at the same time. The second outer deposition assembly (302) is deposited at a higher rate than the deposition assembly 303 on the inner side. Accordingly, an apparatus for depositing material on a substrate is provided to substantially avoid thickness reduction at the edge of the substrate in the transport direction.

根據能夠和此處所述其他實施例結合的實施例,控制器500係配置成用於控制一第一電源,該第一電源用於供應第一電力到第一外側沉積組件和第二外側沉積組件。控制器也能夠被配置成用於控制一第二電源,該第二電源用於供應第二電力到內側沉積組件。參照第3A和3B圖的示例性實施例,用於供應第一電力到第一外側沉積組件和第二外側沉積組件的第一電源,能夠包含二個個別的電源123a、123c,用於供應第一電力到第一外側沉積組件和第二外側沉積組件。 According to an embodiment that can be combined with other embodiments described herein, the controller 500 is configured to control a first power source for supplying the first power to the first outer deposition assembly and the second outer deposition Component. The controller can also be configured to control a second power source for supplying the second power to the inner deposition assembly. Referring to the exemplary embodiments of FIGS. 3A and 3B, the first power source for supplying the first power to the first outer deposition component and the second outer deposition component can include two individual power sources 123a, 123c for supplying the first A power is applied to the first outer deposition assembly and the second outer deposition assembly.

如第3A和3B圖所繪示的,在腔室102之中,提供沉積源122。沉積源能夠例如是可旋轉陰極,其具有待沉積在基 板上的材料的靶材。典型地,陰極能夠是可旋轉陰極,伴隨著磁鐵組件121於其中。據此,能夠進行磁控濺射,以在基板上沉積材料。如第3A和3B圖示例性地示出的,沉積製程能夠以旋轉陰極和旋轉磁鐵組件(亦即其中的旋轉磁軛)來進行。 As depicted in Figures 3A and 3B, a deposition source 122 is provided in the chamber 102. The deposition source can be, for example, a rotatable cathode having a base to be deposited The target of the material on the board. Typically, the cathode can be a rotatable cathode with the magnet assembly 121 therein. According to this, magnetron sputtering can be performed to deposit a material on the substrate. As exemplarily shown in Figures 3A and 3B, the deposition process can be performed with a rotating cathode and a rotating magnet assembly (i.e., a rotating yoke therein).

如此處所使用的,「磁控濺射」意指使用磁控管進行的濺射,磁控管即磁鐵組件,就是說能夠產生磁場的單元。典型地,這樣的磁鐵組件由一或多個永久磁鐵所組成。這些永久磁鐵,典型地以使得自由電子被捕捉在所產生之產生在可旋轉靶材的表面下的磁場之中的方式,配置在可旋轉靶材之中,或耦接至平面靶材。這樣的磁鐵組件也可以被配置成耦接至平面陰極(planar cathode)。根據典型的實施方案,磁控濺射能夠以雙磁控管陰極(亦即陰極122)實現,例如但不限於TwinMagTM陰極組件。特別是,對於從靶材的MF濺射(中頻濺射)而言,能夠應用包含雙陰極的靶材組件。根據典型的實施例,在沉積室中的陰極可以是能夠被更換的。據此,在要被濺射的材料已被消耗掉之後更換靶材。 As used herein, "magnetron sputtering" means sputtering using a magnetron, that is, a magnet assembly, that is, a unit capable of generating a magnetic field. Typically, such a magnet assembly is comprised of one or more permanent magnets. These permanent magnets are typically disposed in the rotatable target or coupled to the planar target in such a manner that free electrons are captured in the resulting magnetic field generated beneath the surface of the rotatable target. Such a magnet assembly can also be configured to be coupled to a planar cathode. According to a typical embodiment, magnetron sputtering can be implemented with a dual magnetron cathode (i.e., cathode 122) such as, but not limited to, a TwinMagTM cathode assembly. In particular, for MF sputtering (intermediate frequency sputtering) from a target, a target assembly including a double cathode can be applied. According to typical embodiments, the cathode in the deposition chamber can be replaceable. According to this, the target is replaced after the material to be sputtered has been consumed.

根據能夠和此處所述其他實施例結合的不同實施例,濺射能夠以直流濺射、MF(中頻)濺射、射頻濺射、或脈衝濺射的方式進行。如此處所述,一些沉積製程可能有利地應用中頻、直流、或脈衝濺射。然而,也能夠應用其他濺射方法。 According to different embodiments that can be combined with other embodiments described herein, sputtering can be performed by direct current sputtering, MF (intermediate frequency) sputtering, radio frequency sputtering, or pulsed sputtering. As described herein, some deposition processes may advantageously employ intermediate frequency, direct current, or pulsed sputtering. However, other sputtering methods can also be applied.

在第3A和3B圖中,示出多個陰極122,伴隨著提供在陰極中的磁鐵組件121或磁控管。根據一些能夠和此處所述其他實施例結合的實施例,根據所述實施例的濺射能夠以三或多個陰極進行。然而,特別是對於大面積沉積的應用而言,能夠提 供陰極或陰極對的一陣列。舉例而言,能夠提供三或多個陰極或陰極對,例如三個、四個、五個、六個、或甚至更多個陰極或陰極對。該陣列能夠提供在一個真空腔室中。另外,陣列典型地能夠被定義成使得相鄰的陰極或陰極對彼此影響,例如是藉由具有互相作用的電漿限制。 In Figures 3A and 3B, a plurality of cathodes 122 are shown, along with a magnet assembly 121 or a magnetron provided in the cathode. According to some embodiments that can be combined with other embodiments described herein, sputtering according to the embodiments can be performed with three or more cathodes. However, especially for large-area deposition applications, An array of cathode or cathode pairs. For example, three or more cathode or cathode pairs can be provided, such as three, four, five, six, or even more cathode or cathode pairs. The array can be provided in a vacuum chamber. Additionally, arrays can typically be defined such that adjacent cathodes or cathodes affect each other, for example by plasma interaction with interaction.

對於可旋轉陰極而言,磁鐵組件能夠提供在背管之中,或伴隨著靶材材料管而提供。第3A圖示出三對陰極,分別提供一沉積源。陰極對可以具有交流電源,用於例如中頻濺射、射頻濺射、或類似者。特別是對於大面積沉積製程而言和對於工業尺度的沉積製程而言,能夠進行中頻濺射,以提供想要的沉積速率。根據實施例,如第3A和3B圖示例性地示出的,真空腔室102中之陰極的磁鐵組件,能夠具有實質上相同的旋轉位置,或至少能夠全部被導向朝著基板14或一對應的沉積區。典型地,沉積區是伴隨著一沉積系統的範圍或區域,該沉積系統係為了材料在基板上的沉積(預期的沉積)而被提供和/或配置。 For a rotatable cathode, the magnet assembly can be provided in the back tube or along with the target material tube. Figure 3A shows three pairs of cathodes, each providing a deposition source. The cathode pair can have an alternating current source for, for example, medium frequency sputtering, radio frequency sputtering, or the like. Especially for large-area deposition processes and for industrial-scale deposition processes, medium frequency sputtering can be performed to provide the desired deposition rate. According to an embodiment, as exemplarily shown in FIGS. 3A and 3B, the magnet assemblies of the cathodes in the vacuum chamber 102 can have substantially the same rotational position, or at least can be all directed toward the substrate 14 or Corresponding deposition area. Typically, the deposition zone is a range or region that is accompanied by a deposition system that is provided and/or configured for deposition of the material on the substrate (expected deposition).

不過,根據能夠和此處所述其他實施例結合的不同實施例,在一個腔室中的電漿源,在層在基板上沉積的期間,能夠具有變化的電漿位置(對於旋轉陰極而言是旋轉位置)。舉例而言,磁鐵組件或磁控管能夠相對於彼此和/或相對於基板進行移動,例如是以振盪或前後往返的方式進行移動,以增加待沉積的層的均勻性。舉例而言,第一外側沉積組件和第二外側沉積組件的磁鐵組件,可以和內側沉積組件的磁鐵組件相比有不同的移動,以實現第一外側沉積組件和第二外側沉積組件和內側沉積組件相比較高的材料沉積速率。 However, according to different embodiments that can be combined with other embodiments described herein, the plasma source in one chamber can have varying plasma positions during deposition of the layer on the substrate (for rotating cathodes) Is the rotation position). For example, the magnet assembly or magnetron can be moved relative to each other and/or relative to the substrate, for example in an oscillating or back-and-forward manner to increase the uniformity of the layer to be deposited. For example, the magnet assembly of the first outer deposition assembly and the second outer deposition assembly can be moved differently than the magnet assembly of the inner deposition assembly to achieve the first outer deposition assembly and the second outer deposition assembly and the inner deposition. Higher material deposition rates compared to components.

根據能夠和此處所述其他實施例結合的實施例,第一外側沉積組件301包含一第一磁鐵組件,該第一磁鐵組件用於產生一第一磁場,第二外側沉積組件302包含一第二磁鐵組件,該第二磁鐵組件用於產生該第一磁場,且內側沉積組件包含一第二磁鐵組件,該第二磁鐵組件用於產生一第二磁場。第一磁場能夠由於選自由下列選項組成之群組的至少一種手段而不同於第二磁場:磁性材料的選擇、磁性組件之幾何形狀的選擇、可控制的一電磁鐵、一用於控制第一磁場和/或第二磁場的元件。該用於控制第一磁場和/或第二磁場的元件能例如是一偏心配置410,偏心配置410係配置成用於變化磁性組件121相對於陰極的位置,如第4A和4B圖示例性地示出者。根據此處所述的實施例,在外側沉積組件301和302的磁場,如第3A和3B圖所示例性地示出者,可以被控制和調整,以實現在外側沉積組件301和302處較高的沉積速率,如此而能夠實質上避免在沉積在基板上的層的邊緣處的厚度降低。 According to an embodiment that can be combined with other embodiments described herein, the first outer deposition assembly 301 includes a first magnet assembly for generating a first magnetic field, and the second outer deposition assembly 302 includes a first a second magnet assembly for generating the first magnetic field, and the inner deposition assembly includes a second magnet assembly for generating a second magnetic field. The first magnetic field can be different from the second magnetic field by at least one means selected from the group consisting of: selection of magnetic material, selection of geometry of the magnetic component, controllable electromagnet, and control of the first A component of a magnetic field and/or a second magnetic field. The element for controlling the first magnetic field and/or the second magnetic field can be, for example, an eccentric configuration 410 configured to vary the position of the magnetic assembly 121 relative to the cathode, as exemplified by FIGS. 4A and 4B. Show the person. In accordance with the embodiments described herein, the magnetic fields of the outer deposition assemblies 301 and 302, as exemplarily shown in Figures 3A and 3B, can be controlled and adjusted to achieve comparison at the outer deposition assemblies 301 and 302. A high deposition rate, as such, can substantially avoid a reduction in thickness at the edges of the layer deposited on the substrate.

在第4A圖中,示出根據此處所述的實施例的一旋轉陰極122的剖面示意圖,其中偏心配置410是位在其中磁性組件121和陰極122之間的距離D係最小值的位置。第4B圖示出根據此處所述的實施例的一旋轉陰極122的剖面示意圖,其中偏心配置410是位在其中磁性組件121和陰極122之間的距離D係最大值的位置。 In FIG. 4A, a cross-sectional view of a rotating cathode 122 in accordance with embodiments described herein is illustrated, wherein the eccentric configuration 410 is at a location where the distance D between the magnetic assembly 121 and the cathode 122 is the minimum. 4B illustrates a cross-sectional view of a rotating cathode 122 in accordance with embodiments described herein, wherein the eccentric configuration 410 is at a location where the distance D between the magnetic assembly 121 and the cathode 122 is the maximum.

根據一些能夠和此處所述其他實施例結合的實施例,此處所述的實施例能夠被用於顯示器PVD,亦即在用於顯示器市場的大面積基板上所作的濺射沉積。根據一些實施例,大面 積基板或各自的載具,其中所述載具具有複數個基板,可以具有至少0.67平方公尺的尺寸。典型地,該尺寸能夠是約0.67平方公尺(0.73公尺×0.92公尺,第4.5代)至約8平方公尺,更典型地約2平方公尺至約9平方公尺或甚至高達12平方公尺。典型地,根據此處所述的實施例的結構、設備(例如陰極組件)和方法為其提供的所謂基板或載具,係如此處所述之大面積基板。舉例來說,大面積基板或載具能夠是對應至約0.67平方公尺之基板(0.73公尺×0.92公尺)的第4.5代、對應至約1.4平方公尺之基板(1.1公尺×1.3公尺)的第5代、對應至約4.29平方公尺之基板(1.95公尺×2.2公尺)的第7.5代、對應至約5.7平方公尺之基板(2.2公尺×2.5公尺)的第8.5代、或甚至對應至約8.7平方公尺之基板(2.85公尺×3.05公尺)的第10代。更大的世代如第11代和第12代及對應的基板面積,能夠以類似的方式實施。 In accordance with some embodiments that can be combined with other embodiments described herein, the embodiments described herein can be used for display PVD, i.e., sputter deposition on large area substrates for the display market. According to some embodiments, the large face The substrate or the respective carrier, wherein the carrier has a plurality of substrates and may have a size of at least 0.67 square meters. Typically, the size can be from about 0.67 square meters (0.73 meters x 0.92 meters, 4.5th generation) to about 8 square meters, more typically from about 2 square meters to about 9 square meters or even up to 12 Square meters. Typically, the so-called substrate or carrier provided in accordance with the structures, devices (e.g., cathode assemblies) and methods of the embodiments described herein are large area substrates as described herein. For example, a large area substrate or carrier can be a 4.5th generation corresponding to a substrate of approximately 0.67 square meters (0.73 meters by 0.92 meters), corresponding to a substrate of approximately 1.4 square meters (1.1 meters x 1.3) The fifth generation of the meter, the 7.5th generation corresponding to the substrate of about 4.29 square meters (1.95 meters x 2.2 meters), and the substrate corresponding to about 5.7 square meters (2.2 meters x 2.5 meters) The 10th generation of the 8.5th generation, or even the substrate (2.85 meters x 3.05 meters) corresponding to approximately 8.7 square meters. Larger generations such as the 11th and 12th generations and corresponding substrate areas can be implemented in a similar manner.

根據又另外的能夠和此處所述其他實施例結合的實施例,靶材材料能夠選自由下列選項組成之群組:鋁、矽、鉭、鉬、鈮、鈦、銦、鎵、鋅、錫、銀、和銅。特別是,靶材材料能夠選自由下列選項組成之群組:銦、鎵、和鋅。反應性濺射製程典型地提供這些靶材材料的沉積氧化物。然而,也可以沉積氮化物或氮氧化物。 According to still further embodiments capable of being combined with other embodiments described herein, the target material can be selected from the group consisting of aluminum, tantalum, niobium, molybdenum, niobium, titanium, indium, gallium, zinc, tin. , silver, and copper. In particular, the target material can be selected from the group consisting of indium, gallium, and zinc. Reactive sputtering processes typically provide deposited oxides of these target materials. However, it is also possible to deposit a nitride or an oxynitride.

根據此處所述的實施例,所述方法提供用於基板是為了靜態沉積製程而定位的濺射沉積。典型地,特別是對於大面積基板處理,例如處於垂直方向的大面積基板的處理而言,能夠區別靜態沉積和動態沉積。根據一些能夠和此處所述其他實施例結合的實施例,此處所述的基板和/或載具、和用於使用此處所述 的氣體分佈系統的設備,能夠被配置成用於垂直的基板處理。垂直的基板處理的用詞,係理解成和水平的基板處理有所區別。就是說,垂直的基板處理是關於載具和基板在基板處理期間實質上垂直的方向,其中從精準的垂直方向有幾度偏差(例如高達10°或甚至高達15°)仍然被視為垂直的基板處理。帶有小幅傾斜的垂直基板方向,能夠例如帶來更穩定的基板運送(handling),或減少顆粒汙染沉積層的風險。或者,根據此處所述的實施例的氣體分佈系統也可以被用於實質上垂直以外的基板方向,例如水平的基板方向。對於水平的基板方向而言,陰極陣列將例如也是實質上水平的。 According to embodiments described herein, the method provides for sputter deposition where the substrate is positioned for a static deposition process. Typically, static deposition and dynamic deposition can be distinguished, particularly for large area substrate processing, such as processing of large area substrates in the vertical direction. The substrates and/or carriers described herein, and for use herein, in accordance with some embodiments that can be combined with other embodiments described herein The device of the gas distribution system can be configured for vertical substrate processing. The term "vertical substrate processing" is understood to be distinguished from horizontal substrate processing. That is, vertical substrate processing is about the direction in which the carrier and substrate are substantially perpendicular during substrate processing, with a few degrees of deviation from the precise vertical direction (eg, up to 10° or even up to 15°) still considered a vertical substrate. deal with. With a slightly tilted vertical substrate orientation, for example, a more stable substrate handling can be brought about, or the risk of particles contaminating the deposited layer can be reduced. Alternatively, the gas distribution system according to embodiments described herein can also be used for substrate orientations other than substantially perpendicular, such as horizontal substrate orientation. For a horizontal substrate orientation, the cathode array will, for example, also be substantially horizontal.

動態濺射,亦即其中基板係連續性或準連續性地相鄰於沉積源移動的直線型(inline)製程,由於製程能夠在基板移動到沉積區中之前被穩定下來,並接著在基板通過沉積源時維持不變的事實,將會是較容易的。不過,動態沉積會具有其他缺點,例如顆粒產生。這特別是對於薄膜電晶體底板沉積而言會是如此。根據此處所述的實施例,靜態的濺射能夠提供予例如薄膜電晶體的處理,其中電漿能夠於在原始基板上沉積之前被穩定下來。應注意的是,和動態沉積製程相比有所不同的靜態沉積製程的用詞,並未排除基板任何將被具有通常知識者所領會的移動。 靜態沉積製程能夠包含例如在沉積期間靜態的基板位置、在沉積期間振盪的基板位置、在沉積期間實質上不變的平均基板位置、在沉積期間顫動的基板位置、在沉積期間晃動的基板位置、陰極為了其而提供在一個腔室中的沉積製程(亦即預先決定的陰極組為了其而提供在該腔室中的沉積製程)、其中沉積室在層沉積期間 具有相對於鄰近的腔室密封的氣氛(例如是藉由關閉將腔室從相鄰腔室分開的閥單元)的基板位置、或其組合。 Dynamic sputtering, that is, an inline process in which the substrate is continuously or quasi-continuously moved adjacent to the deposition source, since the process can be stabilized before the substrate moves into the deposition zone, and then passes through the substrate It will be easier to maintain the same source of deposition. However, dynamic deposition can have other disadvantages such as particle generation. This is especially true for thin film transistor backplane deposition. According to embodiments described herein, static sputtering can provide for processing, for example, a thin film transistor in which the plasma can be stabilized prior to deposition on the original substrate. It should be noted that the terms of the static deposition process that differ from the dynamic deposition process do not preclude any movement of the substrate that would be appreciated by those of ordinary skill. The static deposition process can include, for example, a static substrate position during deposition, a substrate position that oscillates during deposition, an average substrate position that is substantially constant during deposition, a substrate position that trembles during deposition, a substrate position that sways during deposition, The cathode provides a deposition process in one chamber for it (ie, a predetermined deposition process for which the cathode group is provided), wherein the deposition chamber is during layer deposition An atmosphere having a seal relative to an adjacent chamber (eg, by closing a valve unit that separates the chamber from an adjacent chamber), or a combination thereof.

據此,靜態沉積製程能夠被理解成伴隨著靜態的基板位置的沉積製程、伴隨著實質上靜態的基板位置的沉積製程、或伴隨著部分靜態的基板位置的沉積製程。靜態沉積製程,如此處所述,能夠清楚地從動態沉積製程區別開來,而不需要對於靜態沉積製程而言基板位置在沉積期間完全沒有任何移動。根據又另外的能夠和此處所述其他實施例結合的實施例,仍被具有通常知識者視為靜態沉積的從完全靜態之基板位置的偏差,例如振盪、晃動、或如上所述以其他方式移動基板,能夠額外地或替代性地藉由陰極或陰極陣列的移動來提供,所述陰極或陰極陣列的移動例如是晃動、振盪、或類似方式。基板和陰極(或陰極陣列)能夠相對於彼此進行移動,這例如是在基板傳送方向、在實質上垂直於基板傳送方向的橫向方向、或二者中。 Accordingly, the static deposition process can be understood as a deposition process accompanied by a static substrate position, a deposition process accompanied by a substantially static substrate position, or a deposition process accompanied by a partially static substrate position. The static deposition process, as described herein, can be clearly distinguished from the dynamic deposition process without the need for the substrate to be completely free of any movement during deposition during the static deposition process. According to still further embodiments which can be combined with other embodiments described herein, deviations from completely static substrate positions, such as oscillations, shaking, or otherwise, as still static deposition, are still considered by those of ordinary skill. Moving the substrate can additionally or alternatively be provided by movement of a cathode or cathode array, such as shaking, oscillating, or the like. The substrate and cathode (or cathode array) are movable relative to one another, such as in the substrate transport direction, in a lateral direction substantially perpendicular to the substrate transport direction, or both.

根據如此處所述的能夠和此處所述其他實施例結合的實施例,設備100,如第5圖示例性地示出的,包含一沉積陣列,該沉積陣列具有三或多個陰極,一第一外側沉積組件在基板傳送方向中定義一第一邊緣部分501,而一第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分502。另外,沉積陣列包含一第三邊緣部分503和一第四邊緣部分504,第三邊緣部分503包含內側沉積組件的至少一內側陰極的第一端,第四邊緣部分504包含陰極陣列的剩餘部分505的陰極之相對的第二端。第三邊緣部分503和/或第四邊緣部分在陰極的軸方向上的延伸,可以分別對應至陰極總長度的至少5%,特 別是陰極總長度的至少10%,特別是陰極總長度的至少15%。據此,係提供一用於在一基板上沉積材料的設備,以其能夠實質上避免在傳送方向中於基板邊緣處、以及在垂直於傳送方向的基板邊緣處的厚度降低。 In accordance with an embodiment as described herein in combination with other embodiments described herein, apparatus 100, as exemplarily shown in FIG. 5, includes a deposition array having three or more cathodes, A first outer deposition assembly defines a first edge portion 501 in the substrate transfer direction, and a second outer deposition assembly defines a second edge portion 502 relative to the first edge portion in the substrate transfer direction. Additionally, the deposition array includes a third edge portion 503 comprising a first end of at least one inner cathode of the inner deposition assembly and a fourth edge portion 504 comprising a remaining portion 505 of the cathode array The opposite second end of the cathode. The extension of the third edge portion 503 and/or the fourth edge portion in the axial direction of the cathode may correspond to at least 5% of the total length of the cathode, respectively. It is at least 10% of the total length of the cathode, especially at least 15% of the total length of the cathode. Accordingly, an apparatus for depositing material on a substrate is provided which is capable of substantially avoiding a reduction in thickness at the edge of the substrate in the transport direction and at the edge of the substrate perpendicular to the transport direction.

如第5圖所示,此處所述之設備的另外的實施例提供一處理氣體分佈系統,該處理氣體分佈系統具有位在沉積陣列222的第一邊緣部分501、第二邊緣部分502、第三邊緣部分503、第四邊緣部分504、和剩餘部分505的區段。如第5圖示例性地示出的,可以提供位在多條氣體管線116之中的多個氣體進入點138。舉例而言,每條氣體管線能夠具有三或多個開口,例如六或多個開口,例如六至二十個開口。該多條氣體管線116,能夠被放置在成陰極122之間,例如是沿著水平方向平行於它們的長軸。如第5圖示例性地示出的,處理氣體能夠藉由五個流量控制器134來供應,分別提供一個流量控制器給各個部分。據此,供應到各個個別部分的處理氣體量可以被獨立地控制。據此,提供到個別部分的處理氣體的分壓可以被獨立地調整。 As shown in FIG. 5, a further embodiment of the apparatus described herein provides a process gas distribution system having a first edge portion 501, a second edge portion 502, and a portion of the deposition array 222. A section of the three edge portion 503, the fourth edge portion 504, and the remaining portion 505. As exemplarily shown in FIG. 5, a plurality of gas entry points 138 located in the plurality of gas lines 116 may be provided. For example, each gas line can have three or more openings, such as six or more openings, such as six to twenty openings. The plurality of gas lines 116 can be placed between the cathodes 122, for example, parallel to their long axes along the horizontal direction. As exemplarily shown in Fig. 5, the process gas can be supplied by five flow controllers 134, each providing a flow controller to each of the sections. Accordingly, the amount of process gas supplied to each individual portion can be independently controlled. Accordingly, the partial pressure of the process gas supplied to the individual portions can be independently adjusted.

雖然並未詳盡地示於第5圖中,五個流量控制器134各者可以被連接至二個含有處理氣體的槽,類似於相關於第2、3A和3B圖所示之實施例所作的敘述。據此,存在於位在個別部分501、502、503、504和505中的處理氣體內的非反應性氣體和/或反應性氣體的流動速率和/或量,能夠藉由流量控制器135控制,如相關於第2圖所示之實施例所作的示例性的敘述。或者,連接至第一邊緣部分501、第二邊緣部分502、第三邊緣部分503和第四邊緣部分504的流量控制器134,能夠被連接至一個單一 的氣體槽、或一個包含分別用於各處理氣體的二個槽的單一的氣體槽群(gas tank battery)。連接至位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的流量控制器134,可以被連接至另一單一的氣體槽、或另一包含分別用於各處理氣體的二個槽的單一的氣體槽群。 Although not shown in detail in Figure 5, each of the five flow controllers 134 can be coupled to two tanks containing process gases, similar to the embodiments described in relation to Figures 2, 3A and 3B. Narrative. Accordingly, the flow rate and/or amount of non-reactive gas and/or reactive gas present in the process gases located in the individual portions 501, 502, 503, 504, and 505 can be controlled by the flow controller 135 An exemplary description made with respect to the embodiment shown in FIG. 2 is shown. Alternatively, the flow controllers 134 connected to the first edge portion 501, the second edge portion 502, the third edge portion 503, and the fourth edge portion 504 can be connected to a single unit A gas tank, or a single gas tank battery containing two tanks for each process gas. A flow controller 134 coupled to the remainder of the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion may be coupled to another single gas reservoir, or the other comprising a separate A single gas tank group for two tanks of each process gas.

根據實施例,提供一用於材料在一基板上的沉積的設備,該設備具有一氣體分佈系統,其配置成用於提供一第一處理氣體條件到第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分,用於以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。由此,根據此處所述的實施例,係提供一設備,以在整個基板上,亦即包含在基板的傳送方向中的基板邊緣和垂直於基板傳送方向的基板邊緣,提供均勻的塗層。 According to an embodiment, there is provided an apparatus for depositing a material on a substrate, the apparatus having a gas distribution system configured to provide a first process gas condition to the first edge portion, the second edge portion, The three edge portion and the fourth edge portion are for depositing material at a rate higher than the remaining portion between the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion. Thus, in accordance with embodiments described herein, an apparatus is provided to provide a uniform coating over the entire substrate, i.e., the edge of the substrate contained in the direction of transport of the substrate and the edge of the substrate perpendicular to the direction of substrate transfer. .

對應至第2、3A和3B圖的實施例示出氣體分佈系統,伴隨著每二個靶材一條的氣體管線。然而,根據此處所述的實施例的氣體分佈系統,能夠具有任何數目的氣體管線。舉例而言,氣體分佈系統能夠具有四條氣體管線至十三條氣體管線。類似地,每條氣體管線能夠具有二個至三十個氣體進入點。舉例而言,每條氣體管線能夠具有三個至二十個氣體進入點,譬如五個至十個,例如九個氣體進入點。 The embodiment corresponding to Figures 2, 3A and 3B shows a gas distribution system with a gas line for each of the two targets. However, the gas distribution system according to embodiments described herein can have any number of gas lines. For example, a gas distribution system can have four gas lines to thirteen gas lines. Similarly, each gas line can have two to thirty gas entry points. For example, each gas line can have three to twenty gas entry points, such as five to ten, such as nine gas entry points.

據此,此處所述的實施例允許在傳送方向中於外側沉積組件控制和調整處理氣體組成。另外,此處所述的實施例允許在如此處所述的陰極陣列的邊緣部分,特別是參照第5圖所示之實施例所述者,控制和調整處理氣體條件。此處所述的實施例 提供對於沉積遍及整個基板、包含其邊緣具有實質上為定值之厚度的層的精準控制。 Accordingly, the embodiments described herein allow the deposition assembly to control and adjust the process gas composition in the transfer direction. Additionally, the embodiments described herein allow control and adjustment of process gas conditions at the edge portions of the cathode array as described herein, particularly as described with respect to the embodiment illustrated in FIG. Embodiments described herein Provides precise control over the deposition of a layer having a substantially constant thickness throughout the substrate, including its edges.

根據典型的實施例,陰極陣列可以包括三或多個旋轉濺射靶材,陰極陣列特別是可以包括八個旋轉濺射靶材,陰極陣列更特別是可以包括十二個旋轉濺射靶材。典型地,陰極陣列的陰極係以使得它們的長軸彼此平行的方式彼此間隔開來,且其中該些長軸係與待處裡的基板等距離地配置。 According to typical embodiments, the cathode array may comprise three or more rotating sputtering targets, in particular the cathode array may comprise eight rotating sputtering targets, and more particularly the cathode array may comprise twelve rotating sputtering targets. Typically, the cathodes of the cathode array are spaced apart from each other such that their long axes are parallel to each other, and wherein the major axis systems are disposed equidistant from the substrate to be placed.

用於材料在一基板上的沉積的方法600的一實施例係示於第6圖。在步驟601中,提供一沉積陣列沉積陣列,該沉積陣列具有三或多個陰極,其中沉積陣列包含一第一外側沉積組件301、一第二外側沉積組件302、和一內側沉積組件303,第一外側沉積組件301包括該三或多個陰極中的至少一第一陰極,第二外側沉積組件302相對於第一外側沉積組件301,第二外側沉積組件302包含該三或多個陰極中的至少一第二陰極,內側沉積組件303包含至少一內側陰極,內側沉積組件303第一外側沉積組件301和第二外側沉積組件302之間。在步驟602中,在基板上的材料,藉由第一外側沉積組件301和第二外側沉積組件302中的至少一者,係以高於藉由內側沉積組件的速率沉積。據此,提供一用於材料在一基板上的沉積的方法,伴隨著在傳送方向中於基板邊緣處的厚度降低能夠實質上被避免掉。特別是,此處所述的方法允許均勻塗層在基板上的沉積,特別是在靜態沉積製程期間於大面積基板上的沉積。 An embodiment of a method 600 for depositing a material on a substrate is shown in FIG. In step 601, a deposition array deposition array is provided, the deposition array having three or more cathodes, wherein the deposition array includes a first outer deposition assembly 301, a second outer deposition assembly 302, and an inner deposition assembly 303, An outer deposition assembly 301 includes at least one first cathode of the three or more cathodes, a second outer deposition assembly 302 relative to the first outer deposition assembly 301, and a second outer deposition assembly 302 including the three or more cathodes At least one second cathode, the inner deposition assembly 303 includes at least one inner cathode, between the inner deposition assembly 303, the first outer deposition assembly 301, and the second outer deposition assembly 302. In step 602, the material on the substrate is deposited at a higher rate than the deposition of the component by the inner side by at least one of the first outer deposition assembly 301 and the second outer deposition assembly 302. Accordingly, a method for depositing a material on a substrate is provided, with the thickness reduction at the edge of the substrate in the transport direction being substantially avoided. In particular, the methods described herein allow for the deposition of a uniform coating on a substrate, particularly on a large area substrate during a static deposition process.

根據此處所述的方法的實施例,藉由第一外側沉積組件和第二外側沉積組件中的至少一者在基板上沉積材料,包含 控制至少一項處理參數,選自由下列選項組成之群組:控制供應到第一外側沉積組件和/或第二外側沉積組件的電力、控制供應到第一外側沉積組件和/或第二外側沉積組件的處理氣體量、控制在第一外側沉積組件和/或第二外側沉積組件的一第一磁場、以及控制在內側沉積組件的一第二磁場。據此,提供一用於在一基板上沉積材料的方法,以該方法,材料能夠在相同的時間之中於相同的基板上,在第一外側沉積組件301和/或第二外側沉積組件(302)以高於在內側沉積組件303的速率沉積。據此,所述的方法提供在基板上沉積材料,而使得在傳送方向中於基板邊緣處的厚度降低能夠實質上被避免掉。 According to an embodiment of the method described herein, the material is deposited on the substrate by at least one of the first outer deposition assembly and the second outer deposition assembly, including Controlling at least one processing parameter selected from the group consisting of controlling power supplied to the first outer deposition component and/or the second outer deposition component, controlling supply to the first outer deposition component, and/or the second outer deposition The amount of process gas of the assembly, a first magnetic field that controls the first outer deposition assembly and/or the second outer deposition assembly, and a second magnetic field that controls the deposition assembly on the inner side. Accordingly, a method is provided for depositing a material on a substrate in which the material can be deposited on the same substrate at the first outer deposition component 301 and/or the second outer deposition component (at the same time) 302) is deposited at a higher rate than the deposition of the component 303 on the inside. Accordingly, the method provides for depositing material on the substrate such that a reduction in thickness at the edge of the substrate in the transport direction can be substantially avoided.

根據能夠和此處所述其他實施例結合的實施例,控制第一磁場和/或第二磁場可以包含選自由下列選項組成之群組的至少一者:選擇一磁性材料、選擇一磁性配置的幾何形狀、控制一電磁鐵、以及使用一用於控制第一磁場和/或第二磁場的元件。舉例而言,該用於控制第一磁場和/或第二磁場的元件能夠為一偏心配置,其配置成用於變化磁性組件相對於陰極的位置,如以上相關於第4A和4B圖所作的示例性的敘述。 According to an embodiment capable of being combined with other embodiments described herein, controlling the first magnetic field and/or the second magnetic field may comprise at least one selected from the group consisting of: selecting a magnetic material, selecting a magnetic configuration Geometry, control of an electromagnet, and use of an element for controlling the first magnetic field and/or the second magnetic field. For example, the element for controlling the first magnetic field and/or the second magnetic field can be an eccentric configuration configured to vary the position of the magnetic component relative to the cathode, as described above in relation to Figures 4A and 4B. An exemplary narrative.

根據此處所述的用於材料在一基板上的沉積的方法的另外的實施例,步驟601可以包含提供一沉積陣列,在該沉積陣列中,第一外側沉積組件在基板傳送方向中定義一第一邊緣部分,第二外側沉積組件在基板傳送方向中定義相對於第一邊緣部分的一第二邊緣部分,其中沉積陣列更包含一第三邊緣部分和一第四邊緣部分,第三邊緣部分包含內側沉積組件的至少一內側陰極的第一端,第四邊緣部分包含陰極陣列的剩餘部分的陰極之相 對的第二端。據此,步驟602可以包含在基板上,在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分以高於位在第一邊緣部分、第二邊緣部分、第三邊緣部分和第四邊緣部分之間的剩餘部分的速率沉積材料。由此,根據此處所述的實施例,提供一方法,以在整個基板上,亦即包含在基板的傳送方向中的基板邊緣和垂直於基板傳送方向的基板邊緣,提供均勻的塗層。 According to further embodiments of the method for depositing a material on a substrate as described herein, step 601 can include providing a deposition array in which the first outer deposition assembly defines a direction in the substrate transfer direction a first edge portion, the second outer deposition assembly defines a second edge portion relative to the first edge portion in the substrate transfer direction, wherein the deposition array further includes a third edge portion and a fourth edge portion, the third edge portion a first end comprising at least one inner cathode of the inner deposition assembly, the fourth edge portion comprising a cathode phase of a remaining portion of the cathode array The second end of the pair. According to this, the step 602 may be included on the substrate, and the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion are higher than the first edge portion, the second edge portion, and the third edge portion. The material is deposited at a rate that is the remainder of the portion between the fourth edge portion. Thus, in accordance with embodiments described herein, a method is provided for providing a uniform coating over the entire substrate, i.e., the edge of the substrate contained in the direction of transport of the substrate and the edge of the substrate perpendicular to the direction of substrate transfer.

根據此處所述的實施例,材料係沉積在基板上,其中基板是為了靜態沉積製程而被放置。典型地,靶材的材料能夠以靶材材料之氧化物、氮化物、或氮氧化物的形式來被沉積,亦即是以反應性濺射製程沉積。 According to embodiments described herein, the material is deposited on a substrate where the substrate is placed for a static deposition process. Typically, the material of the target can be deposited in the form of an oxide, nitride, or oxynitride of the target material, that is, deposited in a reactive sputtering process.

雖然上述內容是關於本發明的實施例,但可在不背離本發明的基本範圍的情況下,設計出本發明其他和進一步的實施例,本發明的範圍係由以下的申請專利範圍決定。 While the foregoing is a description of the embodiments of the present invention, the subject matter of the invention, and the scope of the invention is defined by the scope of the following claims.

100‧‧‧設備 100‧‧‧ Equipment

122‧‧‧陰極 122‧‧‧ cathode

222‧‧‧沉積陣列 222‧‧‧Deposition array

301‧‧‧外側沉積組件 301‧‧‧External sedimentary components

302‧‧‧外側沉積組件 302‧‧‧Outside deposition components

303‧‧‧內側沉積組件 303‧‧‧Inside deposition assembly

Claims (20)

一種用於材料在一基板上之沉積的設備(100),包括:一沉積陣列(222),具有三或多個可旋轉陰極(122),其中該沉積陣列包括一第一外側沉積組件(301),該第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極;一第二外側沉積組件(302),相對於該第一外側沉積組件,該第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極;以及一內側沉積組件(303),該內側沉積組件包括至少一內側可旋轉陰極,該內側沉積組件位在該第一外側沉積組件和該第二外側沉積組件之間,其中該第一外側沉積組件(301)和該第二外側沉積組件(302)中的至少一者,係配置成用於在相同的時間之中於相同的該基板上以高於該內側沉積組件(303)的速率沉積材料。 An apparatus (100) for depositing a material on a substrate, comprising: a deposition array (222) having three or more rotatable cathodes (122), wherein the deposition array includes a first outer deposition assembly (301) The first outer deposition assembly includes at least one first rotatable cathode of the three or more rotatable cathodes; a second outer deposition assembly (302) opposite the first outer deposition assembly The deposition assembly includes at least one second rotatable cathode of the three or more rotatable cathodes; and an inner deposition assembly (303) including at least one inner rotatable cathode, the inner deposition assembly being located at the Between an outer deposition assembly and the second outer deposition assembly, wherein at least one of the first outer deposition assembly (301) and the second outer deposition assembly (302) are configured for use at the same time The material is deposited on the same substrate at a higher rate than the inner deposition assembly (303). 如請求項1之設備(100),其中該沉積陣列包括一氣體分佈系統,該氣體分佈系統係配置成用於提供一第一處理氣體條件到該第一外側沉積組件(301)和該第二外側沉積組件(302),以在相同的時間之中於相同的該基板上以高於該內側沉積組件(303)的速率沉積材料。 The apparatus (100) of claim 1, wherein the deposition array comprises a gas distribution system configured to provide a first process gas condition to the first outer deposition assembly (301) and the second The outer deposition assembly (302) deposits material at a higher rate than the inner deposition assembly (303) on the same substrate over the same time. 如請求項2之設備(100),其中該氣體分佈系統更包括一第一流量控制器(234)和一第二流量控制器(134),該第一流量控制器係配置成用於控制到該第一外側沉積組件(301)和該第二外側沉積 組件(302)的處理氣體量,該第二流量控制器係配置成用於控制用於該內側沉積組件(303)的處理氣體量。 The device (100) of claim 2, wherein the gas distribution system further comprises a first flow controller (234) and a second flow controller (134), the first flow controller configured to control The first outer deposition assembly (301) and the second outer deposition The amount of process gas of the assembly (302) is configured to control the amount of process gas for the inner deposition assembly (303). 如請求項1或2之設備(100),更包括一控制器(500),該控制器係配置成用於控制該第一外側沉積組件和該第二外側沉積組件的至少一項製程參數。 The apparatus (100) of claim 1 or 2, further comprising a controller (500) configured to control at least one process parameter of the first outer deposition component and the second outer deposition component. 如請求項4之設備(100),其中該至少一項處理參數係選自由下列選項組成之群組的至少一者:供應到該第一外側沉積組件和該第二外側沉積組件的電力、供應該第一外側沉積組件和該第二外側沉積組件的處理氣體量、以及在該第一外側沉積組件和該第二外側沉積組件的磁場。 The apparatus (100) of claim 4, wherein the at least one processing parameter is selected from at least one of the group consisting of: power supplied to the first outer deposition component and the second outer deposition component, The amount of process gas of the first outer deposition assembly and the second outer deposition assembly, and the magnetic fields at the first outer deposition assembly and the second outer deposition assembly. 如請求項4之設備(100),其中該控制器係配置成用於控制一第一電源,該第一電源用於供應一第一電力到該第一外側沉積組件和該第二外側沉積組件,該控制器並配置成用於控制一第二電源,該第二電源用於供應一第二電力到該內側沉積組件。 The device (100) of claim 4, wherein the controller is configured to control a first power source for supplying a first power to the first outer deposition component and the second outer deposition component The controller is further configured to control a second power source for supplying a second power to the inner deposition assembly. 如請求項1或2之設備(100),其中該第一外側沉積組件包括一第一磁鐵組件,該第一磁鐵組件用於產生一第一磁場,該第二外側沉積組件包括一第二磁鐵組件,該第二磁鐵組件用於產生該第一磁場,且其中該內側沉積組件包括一第二磁鐵組件,該第二磁鐵組件用於產生一第二磁場。 The apparatus (100) of claim 1 or 2, wherein the first outer deposition assembly comprises a first magnet assembly for generating a first magnetic field, the second outer deposition assembly comprising a second magnet And a second magnet assembly for generating the first magnetic field, and wherein the inner deposition assembly includes a second magnet assembly for generating a second magnetic field. 如請求項7之設備(100),其中該第一磁場係由於選自由下列選項組成之群組的至少一種手段而不同於該第二磁場:磁性材料的選擇、磁性組件之幾何形狀的選擇、可控制的一電磁鐵、一用於控制該第一磁場和/或該第二磁場的元件。 The apparatus (100) of claim 7, wherein the first magnetic field is different from the second magnetic field due to at least one means selected from the group consisting of: selection of magnetic material, selection of geometry of the magnetic component, An electromagnet that can be controlled, an element for controlling the first magnetic field and/or the second magnetic field. 如請求項8之設備(100),其中該用於控制該第一磁場和/或該第二磁場的元件係一偏心配置,該偏心配置係配置成用於變化磁性組件相對於該些陰極的位置。 The apparatus (100) of claim 8, wherein the means for controlling the first magnetic field and/or the second magnetic field is an eccentric configuration configured to vary a magnetic component relative to the cathodes position. 如請求項2之設備(100),其中該第一外側沉積組件在一基板傳送方向中定義一第一邊緣部分,該第二外側沉積組件在基板傳送方向中定義相對於該第一邊緣部分的一第二邊緣部分,其中該沉積陣列更包括一第三邊緣部分和一第四邊緣部分,該第三邊緣部分包含該內側沉積組件的該至少一內側陰極的第一端,該第四邊緣部分包含該陰極陣列的該內側沉積組件的該些陰極之相對的第二端,其中該氣體分佈系統係配置成用於提供該第一處理氣體條件到該第一邊緣部分、該第二邊緣部分、該第三邊緣部分和該第四邊緣部分,用於以高於位在該第一邊緣部分、該第二邊緣部分、該第三邊緣部分和該第四邊緣部分之間的剩餘部分的速率沉積材料。 The device (100) of claim 2, wherein the first outer deposition assembly defines a first edge portion in a substrate transfer direction, the second outer deposition assembly defining a first edge portion in the substrate transfer direction relative to the first edge portion a second edge portion, wherein the deposition array further includes a third edge portion and a fourth edge portion, the third edge portion including a first end of the at least one inner cathode of the inner deposition assembly, the fourth edge portion An opposite second end of the cathodes of the inner deposition assembly of the cathode array, wherein the gas distribution system is configured to provide the first process gas condition to the first edge portion, the second edge portion, The third edge portion and the fourth edge portion are configured to be deposited at a rate higher than a remaining portion of the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion material. 如請求項1或2之設備(100),其中該沉積陣列包括八或多個旋轉濺射靶材。 The apparatus (100) of claim 1 or 2, wherein the deposition array comprises eight or more rotating sputtering targets. 如請求項1或2之設備(100),其中該沉積陣列包括十二個旋轉濺射靶材。 The apparatus (100) of claim 1 or 2, wherein the deposition array comprises twelve rotating sputtering targets. 如請求項1或2之設備(100),其中該沉積陣列的該三或多個陰極係以使得它們的長軸彼此平行的方式彼此間隔開來,且其中該些長軸係與待處裡的該基板等距離地配置。 The apparatus (100) of claim 1 or 2, wherein the three or more cathodes of the deposition array are spaced apart from each other such that their long axes are parallel to each other, and wherein the long axis systems are in a waiting state The substrates are arranged equidistantly. 一種用於材料在一基板上之沉積的設備(100),該設備包括:一沉積陣列(222),具有三或多個可旋轉陰極(122),其中該沉積陣列包括一第一外側沉積組件(301),該第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極;一第二外側沉積組件(302),相對於該第一外側沉積組件,該第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極;以及一內側沉積組件(303),該內側沉積組件包括至少一內側可旋轉陰極,該內側沉積組件位在該第一外側沉積組件和該第二外側沉積組件之間,其中該第一外側沉積組件(301)和該第二外側沉積組件(302)中的至少一者,係配置成用於在相同的時間之中於相同的該基板上以高於該內側沉積組件(303)的速率沉積材料,其中該沉積陣列包括一氣體分佈系統,該氣體分佈系統係配置成用於提供一第一處理氣體條件到該第一外側沉積組件(301)和該第二外側沉積組件(302),以在相同的時間之中於相同的該基板上以高於該內側沉積組件(303)的速率沉積材料, 其中該設備更包括一控制器(500),該控制器係配置成用於控制該第一外側沉積組件和該第二外側沉積組件的至少一項製程參數,其中該至少一項處理參數係選自由下列選項組成之群組的至少一者:供應到該第一外側沉積組件和該第二外側沉積組件的電力、供應該第一外側沉積組件和該第二外側沉積組件的處理氣體量、以及在該第一外側沉積組件和該第二外側沉積組件的磁場。 An apparatus (100) for depositing a material on a substrate, the apparatus comprising: a deposition array (222) having three or more rotatable cathodes (122), wherein the deposition array includes a first outer deposition assembly (301), the first outer deposition assembly includes at least one first rotatable cathode of the three or more rotatable cathodes; and a second outer deposition assembly (302) opposite to the first outer deposition assembly a second outer deposition assembly comprising at least one second rotatable cathode of the three or more rotatable cathodes; and an inner deposition assembly (303) including at least one inner rotatable cathode, the inner deposition assembly being located Between the first outer deposition assembly and the second outer deposition assembly, wherein at least one of the first outer deposition assembly (301) and the second outer deposition assembly (302) are configured for use in the same Material is deposited on the same substrate at a higher rate than the inner deposition assembly (303), wherein the deposition array includes a gas distribution system configured to provide a first process Body conditions to the first outer deposition assembly (301) and the second outer deposition assembly (302) to deposit material at a higher rate than the inner deposition assembly (303) on the same substrate over the same time , Wherein the apparatus further includes a controller (500) configured to control at least one process parameter of the first outer deposition component and the second outer deposition component, wherein the at least one processing parameter is selected Freely at least one of the group consisting of: power supplied to the first outer deposition assembly and the second outer deposition assembly, an amount of process gas supplied to the first outer deposition assembly and the second outer deposition assembly, and A magnetic field is deposited on the first outer deposition component and the second outer deposition component. 一種用於材料在一基板上之沉積的方法(600),包括:提供一沉積陣列(601),該沉積陣列具有三或多個可旋轉陰極,其中該沉積陣列包括一第一外側沉積組件、一第二外側沉積組件、和一內側沉積組件,該第一外側沉積組件包括該三或多個可旋轉陰極中的至少一第一可旋轉陰極,該第二外側沉積組件相對於該第一外側沉積組件,該第二外側沉積組件包括該三或多個可旋轉陰極中的至少一第二可旋轉陰極,該內側沉積組件包括至少一內側可旋轉陰極,該內側沉積組件位在該第一外側沉積組件和該第二外側沉積組件之間,以及以藉由該第一外側沉積組件(301)和該第二外側沉積組件(302)中的至少一者高於藉由該內側沉積組件(303)的速率,在該基板上沉積材料(602)。 A method (600) for depositing a material on a substrate, comprising: providing a deposition array (601) having three or more rotatable cathodes, wherein the deposition array includes a first outer deposition component, a second outer deposition assembly, and an inner deposition assembly, the first outer deposition assembly including at least one first rotatable cathode of the three or more rotatable cathodes, the second outer deposition assembly being opposite the first outer portion a deposition assembly, the second outer deposition assembly including at least one second rotatable cathode of the three or more rotatable cathodes, the inner deposition assembly including at least one inner rotatable cathode, the inner deposition assembly being located on the first outer side Between the deposition assembly and the second outer deposition assembly, and by at least one of the first outer deposition assembly (301) and the second outer deposition assembly (302) being higher than the inner deposition assembly (303) At a rate, a material (602) is deposited on the substrate. 如請求項15之方法(600),其中該沉積陣列包括一氣體分佈系統,該氣體分佈系統係配置成用於提供一第一處理氣體條件到該第一外側沉積組件(301)和該第二外側沉積組件(302),以在相同的時間之中於相同的該基板上以高於該內側沉積組件(303)的速 率沉積材料。 The method of claim 15 (600), wherein the deposition array comprises a gas distribution system configured to provide a first process gas condition to the first outer deposition assembly (301) and the second The outer deposition assembly (302) is at a higher speed than the inner deposition assembly (303) on the same substrate at the same time Rate deposition material. 如請求項15之方法(600),其中藉由該第一外側沉積組件(301)和該第二外側沉積組件(302)中的該至少一者在該基板上沉積材料(602),包含控制至少一項處理參數,選自由下列選項組成之群組:控制供應到該第一外側沉積組件和/或該第二外側沉積組件的電力、控制供應到該第一外側沉積組件和/或該第二外側沉積組件的處理氣體量、控制在該第一外側沉積組件和/或該第二外側沉積組件的一第一磁場、以及控制在該內側沉積組件的一第二磁場。 The method (600) of claim 15, wherein the material (602) is deposited on the substrate by the at least one of the first outer deposition assembly (301) and the second outer deposition assembly (302), including control At least one processing parameter selected from the group consisting of: controlling power supplied to the first outer deposition assembly and/or the second outer deposition assembly, controlling supply to the first outer deposition assembly, and/or the The amount of process gas of the two outer deposition assemblies, a first magnetic field that controls the first outer deposition assembly and/or the second outer deposition assembly, and a second magnetic field that controls the inner deposition assembly. 如請求項17之方法(600),其中控制該第一磁場和/或該第二磁場包含選自由下列選項組成之群組的至少一者:選擇一磁性材料、選擇一磁性配置的幾何形狀、控制一電磁鐵、以及使用一用於控制該第一磁場和/或該第二磁場的元件。 The method of claim 17 (600), wherein controlling the first magnetic field and/or the second magnetic field comprises at least one selected from the group consisting of: selecting a magnetic material, selecting a geometry of a magnetic configuration, An electromagnet is controlled and an element for controlling the first magnetic field and/or the second magnetic field is used. 如請求項18之方法(600),其中該用於控制該第一磁場和/或該第二磁場的元件係一偏心配置,該偏心配置係配置成用於變化磁性組件相對於該些陰極的位置。 The method (600) of claim 18, wherein the means for controlling the first magnetic field and/or the second magnetic field is an eccentric configuration configured to vary a magnetic component relative to the cathodes position. 如請求項16之方法(600),其中該第一外側沉積組件在一基板傳送方向中定義一第一邊緣部分,該第二外側沉積組件在基板傳送方向中定義相對於該第一邊緣部分的一第二邊緣部分,其中該沉積陣列更包括一第三邊緣部分和一第四邊緣部分,該第三邊緣部分包含該內側沉積組件的該至少一內側陰極的第一端,該第 四邊緣部分包含該陰極陣列的該內側沉積組件的該些陰極之相對的第二端,其中在該基板上沉積材料(602)更包含在該第一邊緣部分、該第二邊緣部分、該第三邊緣部分和該第四邊緣部分,以高於位在該第一邊緣部分、該第二邊緣部分、該第三邊緣部分和該第四邊緣部分之間的剩餘部分的速率沉積材料。 The method (600) of claim 16, wherein the first outer deposition component defines a first edge portion in a substrate transfer direction, the second outer deposition component defining a first edge portion in the substrate transfer direction relative to the first edge portion a second edge portion, wherein the deposition array further includes a third edge portion and a fourth edge portion, the third edge portion including a first end of the at least one inner cathode of the inner deposition assembly, the first a fourth edge portion comprising opposite ends of the cathodes of the inner deposition assembly of the cathode array, wherein a deposition material (602) on the substrate is further included in the first edge portion, the second edge portion, the first The three edge portions and the fourth edge portion deposit material at a rate higher than a remaining portion of the first edge portion, the second edge portion, the third edge portion, and the fourth edge portion.
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