TW201601628A - Poison bait for pests - Google Patents

Poison bait for pests Download PDF

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Publication number
TW201601628A
TW201601628A TW103141493A TW103141493A TW201601628A TW 201601628 A TW201601628 A TW 201601628A TW 103141493 A TW103141493 A TW 103141493A TW 103141493 A TW103141493 A TW 103141493A TW 201601628 A TW201601628 A TW 201601628A
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Taiwan
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bait
poison
poison bait
component
pests
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TW103141493A
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Chinese (zh)
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Rino YASUDAI
Yuya Suzuki
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Earth Chemical Co
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Agronomy & Crop Science (AREA)
  • Food Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Insects & Arthropods (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)

Abstract

The purpose of the present invention is to provide a poison pest bait that pests find appetizing. This poison bait for pests is suitable to centipede control, and contains an insecticidal component and an attractant component. Over time, this solid poison bait absorbs moisture from the atmosphere and the attractant component deliquesces such that the surface of the solid bait becomes covered with the liquefied attractant.

Description

害蟲用毒餌劑 Pest bait

本發明係關於一種害蟲用毒餌劑,更詳細而言,尤其是關於一種適於防治蜈蚣之害蟲用毒餌劑。 The present invention relates to a bait for pests, and more particularly to a bait for pests suitable for controlling cockroaches.

先前,為防治蜈蚣、蟑螂、螞蟻等害蟲,有將害蟲之嗜好性較高且含有殺蟲成分之毒餌劑設置於害蟲之發生場所,讓害蟲食用而防治之方法。 In the past, in order to control pests such as cockroaches, cockroaches, and ants, there is a method in which pests with high pests and insecticidal components are placed in a place where pests occur, and pests are eaten and prevented.

例如,蜈蚣生活於草叢、石垣之間、土壤中等,以小型之昆蟲、蜘蛛、蚯蚓等為食物,有時會尋求食物而侵入房屋內或潛入傢俱或鞋中,此時會帶來咬人而引起過敏反應之傷害,故而成為防治之對象。 For example, cockroaches live in grass, sarcophagus, and soil. They use small insects, spiders, crickets, etc. as food. Sometimes they seek food to invade the house or sneak into furniture or shoes. It causes damage to allergic reactions and is therefore the object of prevention and treatment.

於防治蜈蚣時使用毒餌劑之情形時,引誘蜈蚣使其充分食用毒餌劑變得重要。為解決該課題,例如下述專利文獻1中揭示有含有烏賊之乾燥粉末、魚白子之乾燥粉末、螃蟹殼之粉末中至少1種之蜈蚣用引誘劑、及含有該引誘劑與殺蟲成分之蜈蚣用毒餌劑。 In the case of using a bait for controlling cockroaches, it is important to induce cockroaches to fully consume the bait. In order to solve this problem, for example, the following Patent Document 1 discloses an attractant containing at least one of a dry powder containing squid, a dry powder of fish white, and a powder of crab shell, and an attractant and an insecticidal component. Use bait.

先前技術文獻 Prior technical literature 專利文獻 Patent literature

專利文獻1:日本專利特開2005-35922號公報 Patent Document 1: Japanese Patent Laid-Open Publication No. 2005-35922

然而,即便向毒餌劑中添加引誘劑,亦有由於毒餌劑之硬度或 柔軟度、大小、表面狀態等而使害蟲之食用受到影響之情況。 However, even if an attractant is added to the bait, it is due to the hardness of the bait or Softness, size, surface condition, etc., which affect the eating of pests.

尤其是,如蜈蚣之捕食性害蟲係捕食小型昆蟲等會動者,故而僅放置含有引誘劑之毒餌劑並不能使捕食性害蟲將其認作食物,難以讓捕食性害蟲充分食用。 In particular, if predatory pests such as cockroaches prey on small insects, it is not possible to place predatory pests as food, and it is difficult for predatory pests to fully consume them.

因此,本發明之目的在於提供一種害蟲用毒餌劑,其係尤其適於防治蜈蚣之毒餌劑,且具有較高之食用性。 Accordingly, it is an object of the present invention to provide a bait for pests which is particularly suitable for controlling baits of cockroaches and which has high applicability.

本發明者等人進行努力研究,結果發現,為讓如蜈蚣之捕食性害蟲充分食用毒餌劑,使該毒餌劑中所含之引誘成分潮解,並以經潮解之引誘成分覆蓋毒餌劑之表面,藉此可解決上述課題,從而可完成本發明。 As a result of intensive studies, the present inventors have found that in order to allow the predatory pests of Rugao to fully consume the poison bait, the attracting components contained in the bait agent are deliquescent, and the surface of the poison bait is covered with the deliquescent attracting component. Thereby, the above problems can be solved, and the present invention can be completed.

即,本發明係藉由以下之(1)~(2)而達成者。 That is, the present invention is achieved by the following (1) to (2).

(1)一種固體形狀之害蟲用毒餌劑,其係適於防治蜈蚣之毒餌劑,且含有殺蟲成分與引誘成分,經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之上述引誘成分覆蓋之狀態。 (1) A solid-shaped poison bait for pest control, which is suitable for controlling a bait agent of cockroaches, and containing an insecticidal component and an attracting component, and absorbing the moisture in the atmosphere over time to cause deliquescence of the attracting component, thereby forming a surface-forming liquid The state in which the above-mentioned attracting component is covered.

(2)如上述(1)之害蟲用毒餌劑,其中毒餌劑之自表面至重心之最短距離為10mm以下。 (2) The poison bait for pests according to (1) above, wherein the shortest distance from the surface to the center of gravity of the poison bait is 10 mm or less.

本發明之害蟲用毒餌劑係使其中所含之引誘成分潮解,並以成為液狀之引誘成分覆蓋毒餌劑之表面,故而與毒餌劑接觸之害蟲容易將其認作餌食,食用性提高,因此可提高防治效果。尤其是對蜈蚣具有較高之食用性,可使其充分食用殺蟲成分,故而對防治蜈蚣極其有效。 The pest bait agent of the present invention causes the attracting component contained therein to deliquesce and covers the surface of the poison bait with a liquid attracting component. Therefore, the pest in contact with the poison bait is easily regarded as a bait, and the eating property is improved. Can improve the control effect. In particular, it has a high edible property for cockroaches, and it can fully consume insecticidal ingredients, so it is extremely effective for controlling cockroaches.

1A、1B‧‧‧毒餌劑 1A, 1B‧‧‧ poison bait

m‧‧‧圓盤狀之毒餌劑之軸方向之自表面至重心之最短距離 m‧‧‧The shortest distance from the surface to the center of gravity in the axial direction of the disc-shaped bait

n‧‧‧圓柱狀之毒餌劑之軸方向之自表面至重心之最短距離 n‧‧‧The shortest distance from the surface to the center of gravity in the axial direction of the cylindrical bait

圖1(a)及圖1(b)係表示檢體1及2之害蟲用毒餌劑於加濕環境下保存前之狀態之照片圖式,圖1(a)係檢體1之害蟲用毒餌劑,圖1(b)係檢 體2之害蟲用毒餌劑。 Fig. 1 (a) and Fig. 1 (b) are photographs showing the state of the pests of the specimens 1 and 2 before being stored in a humidified environment, and Fig. 1 (a) is a pest bait for the specimen 1 Agent, Figure 1 (b) check The pest of the body 2 uses a poison bait.

圖2(a)及圖2(b)係表示檢體1及2之害蟲用毒餌劑於加濕環境下保存後之狀態之照片圖式,圖2(a)係檢體1之害蟲用毒餌劑,圖2(b)係檢體2之害蟲用毒餌劑。 Fig. 2 (a) and Fig. 2 (b) are photographs showing the state of the pests of the specimens 1 and 2 after being stored in a humidified environment, and Fig. 2 (a) is a pest bait for the specimen 1 The agent (Fig. 2(b) is a poison bait for the pest of the sample 2.

圖3(a)係表示於加濕環境下保存後之檢體1之害蟲用毒餌劑上載置有拭布之狀態之照片圖式及其模式圖,圖3(b)係表示經回收之拭布之狀態之照片圖式及其模式圖。 Fig. 3(a) is a photograph showing a state in which a pest of a sample 1 stored in a humidified environment is placed on a poison bait, and a schematic view thereof, and Fig. 3(b) shows a recovered wipe. Photograph of the state of the cloth and its pattern diagram.

圖4(a)係表示於加濕環境下保存後之檢體2之害蟲用毒餌劑上載置有拭布之狀態之照片圖式及其模式圖,圖4(b)係表示經回收之拭布之狀態之照片圖式及其模式圖。 Fig. 4(a) is a photograph showing a state in which a pest of a sample 2 stored in a humidified environment is placed on a poison bait, and a schematic view thereof, and Fig. 4(b) shows a recovered wipe. Photograph of the state of the cloth and its pattern diagram.

圖5(a)及圖5(b)係表示本發明之害蟲用毒餌劑之形態之概略圖。 Fig. 5 (a) and Fig. 5 (b) are schematic views showing the form of the poison bait for pests of the present invention.

以下,對本發明之實施形態進而進行詳細說明。此處,以作為較佳對象之蜈蚣為例進行詳細說明,但並不排除應用於蝗蟲、球潮蟲、馬陸、蚰蜒、螞蟻等其他害蟲。 Hereinafter, embodiments of the present invention will be described in detail. Here, the description will be made in detail as an example of a preferred object, but it is not excluded to be applied to other pests such as aphids, ball worms, horses, pelicans, ants, and the like.

本發明之害蟲用毒餌劑(以下簡稱為「毒餌劑」)之特徵在於,含有殺蟲成分與引誘成分,經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之上述引誘成分覆蓋之狀態。由於毒餌劑之表面經液狀物覆蓋,形成如濕潤之狀態,故而害蟲容易食用。其中,蜈蚣等捕食性害蟲只要其口觸碰含有水分之引誘成分(液狀物),則將毒餌劑認作食物,採取食用之行為,故而尤其對蜈蚣可較佳地使用,而起到有效防治。 The poison bait for pests of the present invention (hereinafter referred to as "toxic bait") is characterized in that it contains an insecticidal component and an attracting component, and absorbs moisture in the atmosphere over time to cause deliquescence of the attracting component, thereby forming a surface which becomes liquid. The state of the lure component. Since the surface of the bait agent is covered with a liquid to form a wet state, the pest is easy to eat. Among them, as long as the predatory pests such as cockroaches touch the moisture-containing attracting component (liquid substance), the poison bait is recognized as food and the eating behavior is adopted, so that it is particularly effective for use, and is effective. Prevention and treatment.

再者,所謂「潮解」,係物質吸取大氣中之水分而成為水溶液之現象,於本發明中,毒餌劑中之引誘成分具有潮解性之性質。 Further, the "tidal solution" is a phenomenon in which a substance absorbs moisture in the atmosphere and becomes an aqueous solution. In the present invention, the attracting component in the poison bait has a deliquescent property.

作為本發明中使用之殺蟲成分,只要為對害蟲具有殺蟲效果者,則並無特別限制,例如可列舉:撲滅松、大利松、馬拉松、噠淨松、 普硫松、辛硫磷、陶斯松等有機磷系化合物;加保利(Carbaryl)、安丹(Propoxur)、納乃得、硫敵克等胺基甲酸酯系化合物;亞列寧、列滅寧、炔呋菊酯(Furamethrin)、胺菊酯(Phthalthrin)、百滅甯、酚丁滅虱(Phenothrin)、賽滅寧、賽酚寧、普亞列寧(Prallethrin)、右旋烯炔菊酯(Empenthrin)、四氟苯菊酯(Transfluthrin)、美特寧(Metofluthrin)、丙氟菊酯(Profluthrin)等擬除蟲菊酯系化合物;蟲酮(Metoxadiazone)等二唑系化合物;芬普尼等苯基吡唑系化合物;硼酸、硼砂、愛美松(Hydramethylnon)、呋蟲胺、依普寧等。該等殺蟲成分可單獨使用1種,亦可混合2種以上而使用。 The insecticidal component to be used in the present invention is not particularly limited as long as it has an insecticidal effect on pests, and examples thereof include, for example, chlorpyrifos, dansone, marathon, strontium pine, phenylpyrazine, phoxim, Organophosphorus compounds such as Taosson; urethane-based compounds such as Carbaryl, Propoxur, Nanet, and Sulfuric acid; Yalene, Lenin, Furamethrin, Phthalthrin, fentanin, Phenothrin, cyprodin, pirfenin, Prallethrin, empenthrin, tetrafluthrin Pyrethroid-based compounds such as Transfluthrin), Metofluthrin, and Profluthrin; Metoxadiazone, etc. a bisazole compound; a phenylpyrazole compound such as fenpini; boric acid, borax, Hydramethylnon, dinotefuran, epredamine, and the like. These insecticidal components may be used singly or in combination of two or more.

殺蟲成分之調配量只要不妨礙藉由引誘成分之潮解而將毒餌劑表面以液狀物包圍,則可考慮力價適當設定。具體而言,較佳為於毒餌劑中含有0.1重量%以上,更佳為0.5重量%以上。又,上限較佳為未達30重量%。 The amount of the insecticidal component can be appropriately set in consideration of the force price as long as it does not prevent the surface of the poison bait from being surrounded by the liquid by deliquescent of the attracting component. Specifically, it is preferably contained in the bait agent in an amount of 0.1% by weight or more, more preferably 0.5% by weight or more. Further, the upper limit is preferably less than 30% by weight.

本發明中使用之引誘成分可選擇害蟲嗜好之成分,且如上述般具有經時地吸收大氣中之水分而潮解之性質。例如可列舉:葡萄糖、果糖、半乳糖、麥芽糖、蔗糖、糊精、晶粒砂糖(granulated sugar)、黑糖等糖類;丙胺酸、甘胺酸、纈胺酸、天冬胺酸、麩胺酸等胺基酸等。該等引誘成分可單獨使用1種,亦可混合2種以上而使用。 The attracting component used in the present invention can select a component which is pest-loving, and has the property of absorbing moisture in the atmosphere and deliquescent as described above. For example, glucose, fructose, galactose, maltose, sucrose, dextrin, granulated sugar, brown sugar, and the like; alanine, glycine, lysine, aspartic acid, glutamic acid, etc. Amino acid and the like. These attracting components may be used alone or in combination of two or more.

該等引誘成分只要含有於毒餌劑設置於屋內或屋外之所需場所後吸收空氣中之水分而成為液狀,並滲出至毒餌劑之表面之量即可,且只要根據毒餌劑之形狀、大小等適當設定即可。 The attracting component may be contained in a liquid in the air after being placed in a desired place in the house or outside the house, and may be oozing to the surface of the poison bait, and only according to the shape of the bait agent, The size can be set appropriately.

本發明中,為使經潮解之引誘成分滲出至毒餌劑之表面,與毒餌劑之自表面至重心之最短距離有關。再者,所謂毒餌劑之重心,不僅為位於毒餌劑之軸心上之重量中心,亦可為軸心上之幾何學中心。 In the present invention, in order to allow the deliquescent attracting component to exude to the surface of the poison bait, it is related to the shortest distance from the surface to the center of gravity of the poison bait. Furthermore, the center of gravity of the poison bait is not only the center of weight on the axis of the bait, but also the geometric center on the axis.

本發明中,較佳為以毒餌劑之自表面至重心之最短距離成為10mm以下之方式成形毒餌劑。藉由將毒餌劑之自表面至重心之最短距 離設為10mm以下,不僅僅是毒餌劑中之接近表面部分之引誘成分,內部之引誘成分亦吸附空氣中之水分而液狀化,從而容易滲出至毒餌劑之表面。 In the present invention, it is preferred to form the poison bait so that the shortest distance from the surface to the center of gravity of the poison bait is 10 mm or less. By the shortest distance from the surface to the center of gravity of the bait When the distance is 10 mm or less, it is not only an attracting component close to the surface portion of the bait agent, but the internal attracting component also adsorbs moisture in the air to be liquidified, and thus easily exudes to the surface of the poison bait.

再者,毒餌劑之自表面至重心之最短距離越短,則引誘成分越容易滲出至毒餌劑之表面,故而若為粒徑較小之毒餌劑則可減少引誘成分之含量。因此,可根據毒餌劑之自表面至重心之最短距離調整毒餌劑中之引誘成分之含量。 Furthermore, the shorter the shortest distance from the surface to the center of gravity of the bait agent, the more easily the attracting component oozes out to the surface of the poison bait, so that if it is a poison bait having a small particle size, the content of the attracting component can be reduced. Therefore, the content of the attracting component in the poison bait can be adjusted according to the shortest distance from the surface to the center of gravity of the bait agent.

具體而言,於毒餌劑之自表面至重心之最短距離未達2mm之情形時,較佳為以潮解前之重量為基準,於毒餌劑中含有引誘成分40重量%以上,於最短距離為2mm以上且未達2.5mm之情形時,較佳為含有引誘成分60重量%以上,於最短距離為2.5mm以上且未達6mm之情形時,較佳為含有引誘成分70重量%以上,於最短距離為6mm以上之情形時,較佳為含有引誘成分80重量%以上。又,為充分發揮本發明之效果,較佳為將最短距離設為10mm以下。 Specifically, when the shortest distance from the surface to the center of gravity of the poison bait is less than 2 mm, it is preferable to contain 40% by weight or more of the attracting component in the poison bait based on the weight before deliquescence, and the shortest distance is 2 mm. When it is less than 2.5 mm, it is preferable to contain 60% by weight or more of the attracting component, and when the shortest distance is 2.5 mm or more and less than 6 mm, it is preferable to contain the attracting component by 70% by weight or more at the shortest distance. When it is 6 mm or more, it is preferable to contain 80% by weight or more of the attracting component. Moreover, in order to fully exert the effect of the present invention, it is preferable to set the shortest distance to 10 mm or less.

作為毒餌劑之形態,只要為固體形狀,則並無特別限定,只要適當設定即可。例如可列舉顆粒狀、粉狀、圓柱狀、圓盤狀、段狀(block shape)、塊狀、膏狀等。如圖5(a)所示,於毒餌劑1A為圓盤狀之製劑時,只要將毒餌劑之軸方向X之自表面至重心之長度設為最短距離m,適當調整引誘成分之調配量即可,如圖5(b)所示,於毒餌劑1B為長軸之圓柱狀之製劑時,只要將毒餌劑之與軸方向Y正交之方向之自表面至重心之長度(相對於軸方向Y之切斷面之半徑長度)設為最短距離n,適當調整引誘成分之調配量即可。 The form of the poison bait is not particularly limited as long as it is a solid shape, and may be appropriately set. For example, a pellet shape, a powder shape, a column shape, a disk shape, a block shape, a block shape, a paste form, etc. are mentioned. As shown in Fig. 5 (a), when the bait 1A is a disk-shaped preparation, the length of the poisoning bait from the surface to the center of gravity in the axial direction X is set to the shortest distance m, and the amount of the attracting component is appropriately adjusted. As shown in FIG. 5(b), when the poison bait 1B is a long-axis cylindrical preparation, the length from the surface to the center of gravity of the direction in which the poison bait is orthogonal to the axial direction Y (relative to the axial direction) The radius length of the cut surface of Y is set to the shortest distance n, and the amount of the attracting component can be appropriately adjusted.

如上所述,藉由根據毒餌劑之自表面至重心之最短距離調整引誘成分之含量,可藉由潮解作用使引誘成分充分成為液狀,以害蟲將毒餌劑認作食物之程度將毒餌劑之表面以液狀物覆蓋。於引誘成分之含量不充分之情形時,無法將毒餌劑表面以液狀物充分覆蓋,不足以 使害蟲將其認作食物,故而欠佳。 As described above, by adjusting the content of the attracting component according to the shortest distance from the surface to the center of gravity of the poison bait, the attracting component can be sufficiently made liquid by deliquescence, and the poison bait can be recognized as a pest by the pest. The surface is covered with a liquid. When the content of the attractant component is insufficient, the surface of the poison bait cannot be sufficiently covered with the liquid material, which is insufficient It is not good for the pest to recognize it as food.

本發明之毒餌劑中,引誘成分吸收空氣中之水分而潮解,故而可根據自然環境之濕度等之變化,將毒餌劑之表面保持為濕潤狀態。又,藉由如上述般根據毒餌劑之自表面至重心之最短距離含有特定量以上之引誘成分,亦可於夜間或冬季等低濕度環境下將毒餌劑表面以液狀物覆蓋。 In the poisoning bait of the present invention, the attracting component absorbs moisture in the air and deliquesces, so that the surface of the poisoning bait can be kept in a wet state according to changes in humidity of the natural environment or the like. Further, by including a specific amount or more of the attracting component from the surface to the center of gravity of the poison bait as described above, the surface of the poison bait can be covered with a liquid material in a low-humidity environment such as nighttime or winter.

再者,於對象害蟲為蜈蚣之情形時,由於蜈蚣為夜行性,故而較佳為以可將潮解狀態保持一晚(例如,12~16小時)左右之方式調整引誘成分之調配量。 Further, in the case where the target pest is a cockroach, since the cockroach is a nocturnal property, it is preferable to adjust the blending amount of the attracting component so that the deliquescent state can be maintained for one night (for example, 12 to 16 hours).

本發明之毒餌劑中,除上述潮解性之引誘成分、殺蟲成分以外,可視需要調配公知之各種成分。作為其他成分,例如可列舉賦形劑、抗氧化劑、防腐劑、防誤食劑、溶劑等。 In the bait agent of the present invention, in addition to the above-described deliquescent attracting component and insecticidal component, various known components may be blended as needed. Examples of other components include an excipient, an antioxidant, a preservative, an anti-feeding agent, a solvent, and the like.

作為賦形劑,例如可列舉:白碳、矽藻土、結晶纖維素、黏土、高嶺土、滑石、膨潤土、二氧化矽、羧甲基纖維素、石蠟、聚乙二醇、苯乙烯樹脂、聚矽氧樹脂等。 Examples of the excipient include white carbon, diatomaceous earth, crystalline cellulose, clay, kaolin, talc, bentonite, cerium oxide, carboxymethyl cellulose, paraffin, polyethylene glycol, styrene resin, and poly Oxygen resin, etc.

作為抗氧化劑,例如可列舉:異抗壞血酸、異抗壞血酸鈉、二丁基羥基甲苯、dl-α-生育酚、丁基羥基苯甲醚、沒食子酸丙酯等。 Examples of the antioxidant include erythorbic acid, sodium erythorbate, dibutylhydroxytoluene, dl-α-tocopherol, butyl hydroxyanisole, and propyl gallate.

作為防腐劑,例如可列舉:苯甲酸、苯甲酸鈉、苯甲酸苄酯、水楊酸苄酯、水楊酸、山梨酸、山梨酸鉀、去氫乙酸、去氫乙酸鈉、對羥基苯甲酸酯、丙酸鈣、丙酸鈉、氯化鯨蠟基吡啶鎓等。 Examples of the preservative include benzoic acid, sodium benzoate, benzyl benzoate, benzyl salicylate, salicylic acid, sorbic acid, potassium sorbate, dehydroacetic acid, sodium dehydroacetate, and p-hydroxybenzoic acid. Ester, calcium propionate, sodium propionate, cetylpyridinium chloride, and the like.

作為防誤食劑,例如可列舉:苯甲地那銨(Denatonium Benzoate)、辣椒末等。 Examples of the anti-ingestion agent include: denatonium Benzoate, capsicum, and the like.

作為溶劑,例如可列舉:水;異丙醇、乙醇、甘油等醇類;丙二醇、乙二醇等二醇類;及石蠟類等。 Examples of the solvent include water; alcohols such as isopropyl alcohol, ethanol, and glycerin; glycols such as propylene glycol and ethylene glycol; and paraffin waxes.

此外,亦可視需要使用香料、著色劑、pH值調整劑等。 In addition, perfumes, colorants, pH adjusters, and the like may also be used as needed.

進而,於本發明中,亦可於不損及發明效果之範圍內使用不具 有潮解性之性質之其他引誘成分,例如:蟲蛹粉、玉米澱粉、蜂幼蟲、牛肉、蛋、磷蝦、明蝦(prawn)、乳酪、畜肉、魚肉、澱粉、小麥粉、麥麩、豆、米糠、種子、棉籽、椰子油、橄欖油、肉油、魚油、芝麻油等。 Further, in the present invention, it is also possible to use it within a range that does not impair the effects of the invention. Other deceptive ingredients of deliquescent nature, such as: worm powder, corn starch, bee larvae, beef, eggs, krill, prawn, cheese, meat, fish, starch, wheat flour, wheat bran, beans Rice bran, seeds, cottonseed, coconut oil, olive oil, meat oil, fish oil, sesame oil, etc.

作為本發明之毒餌劑之製備方法,可採用公知之手法,例如可列舉將原料成分混合、打錠之方法、及造粒方法等。 As a preparation method of the poisoning bait of the present invention, a known method can be employed, and examples thereof include a method of mixing a raw material component, a method of tableting, a granulation method, and the like.

本發明之毒餌劑較佳為以其表面於非使用時為乾燥狀態,於使用時成為潮解狀態之方式包裝、保存。藉由將非使用時設為乾燥狀態,可提高流通時或保管時之操作性。為於非使用時將本發明之毒餌劑保持為乾燥狀態,例如較佳為於使用毒餌劑之前,於具有氣密性之容器、袋等之內部與矽膠等乾燥劑一併保存等,保持濕度極低之狀態。 The bait agent of the present invention is preferably packaged and stored in such a manner that its surface is in a dry state when it is not in use and is in a deliquescent state at the time of use. By setting the non-use state to a dry state, the operability at the time of circulation or storage can be improved. In order to keep the poisoning bait of the present invention in a dry state when it is not in use, for example, it is preferable to store the inside of the container, the bag, etc., which is airtight, together with a desiccant such as silicone, before using the bait, and to maintain the humidity. Very low state.

本發明中,使用時引誘成分潮解,毒餌劑之表面經液狀物覆蓋之潮解狀態可以目視確認。又,亦可藉由使紙漿製拭布(例如,Nippon Paper Crecia股份有限公司製之「Kimwipe S-200」)於不施加荷重之情況下與其接觸約5秒時,成為液狀之引誘成分附著於紙漿製拭布表面之現象而確認。 In the present invention, the inducing component is deliquescent when used, and the deliquescent state of the surface of the poison bait covered by the liquid can be visually confirmed. In addition, a pulp wiping cloth (for example, "Kimwipe S-200" manufactured by Nippon Paper Crecia Co., Ltd.) can be brought into contact with the attractant component in a liquid state for about 5 seconds without applying a load. Confirmed by the phenomenon of the surface of the pulp wiping cloth.

實施例 Example

以下,藉由以下之試驗例進而說明本發明,但本發明並不限定於下述例。 Hereinafter, the present invention will be further illustrated by the following test examples, but the present invention is not limited to the following examples.

<毒餌劑之經時試驗> <Time test of poison bait>

相對於表1記載之毒餌劑基劑100重量份,添加水4.5重量份、乙醇3重量份進行混練,成形為如圖5(b)所示之直徑約5mm、長度約10mm之圓柱狀,獲得毒餌劑(檢體1、2)。繼而,將所得之各毒餌劑約1g於20~23℃、濕度100%之條件下保存72小時。 With respect to 100 parts by weight of the bait base shown in Table 1, 4.5 parts by weight of water and 3 parts by weight of ethanol were added and kneaded, and formed into a columnar shape having a diameter of about 5 mm and a length of about 10 mm as shown in Fig. 5 (b). Poison bait (sample 1, 2). Then, about 1 g of each of the obtained poison baits was stored under the conditions of 20 to 23 ° C and a humidity of 100% for 72 hours.

將剛成形後之毒餌劑之狀態示於圖1(a)及圖1(b),將保存後之毒 餌劑之狀態示於圖2(a)及圖2(b)。圖1(a)及圖2(a)表示檢體1之毒餌劑,圖1(b)及圖2(b)表示檢體2之毒餌劑。 The state of the newly formed poison bait is shown in Fig. 1 (a) and Fig. 1 (b), and the poison after storage The state of the bait is shown in Fig. 2 (a) and Fig. 2 (b). Fig. 1 (a) and Fig. 2 (a) show the poisoning bait of the specimen 1, and Fig. 1 (b) and Fig. 2 (b) show the bait of the specimen 2.

根據圖2(a)及圖2(b)之結果可知,檢體1之毒餌劑於保存中經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之上述引誘成分覆蓋之狀態。相對於此,檢體2之毒餌劑不會使引誘成分潮解,保存前後幾乎未見形狀之變化。 2(a) and 2(b), it can be seen that the poisoning bait of the sample 1 absorbs the moisture in the atmosphere over time during storage to cause the attracting component to deliquesce, and the surface is formed to be covered by the above-mentioned attracting component which becomes liquid. State. On the other hand, the poisoning bait of the sample 2 did not cause deliquescence of the attracting component, and almost no change in shape was observed before and after storage.

<毒餌劑之吸濕確認> <Humidity confirmation of poison bait>

藉由以下之式,對檢體1及2之毒餌劑約1g求出於20~23℃、濕度100%之條件下保存72小時後之重量增加倍率。試驗係各檢體各進行2次,求出其平均值。將結果示於表2。 According to the following formula, about 1 g of the poisoning baits of the specimens 1 and 2 were obtained and the weight-increasing magnification was stored for 72 hours under the conditions of 20 to 23 ° C and a humidity of 100%. Each test piece was tested twice for each sample, and the average value was obtained. The results are shown in Table 2.

由吸濕引起之重量增加倍率=保存後之毒餌劑之重量/保存前之毒餌劑之重量 Weight gain due to moisture absorption = weight of bait after storage / weight of bait before storage

根據表2之結果可知,檢體1及檢體2之毒餌劑之保存後之由吸濕引起之重量增加倍率為相同程度,並無較大差異。如圖2(a)及圖2(b) 所示,檢體1之毒餌劑於保存後成為表面經液狀物覆蓋之狀態,相對於此,檢體2之毒餌劑幾乎無變化,由此可認為,檢體1經時地吸收大氣中之水分,引誘成分發生潮解而滲出至毒餌劑之表面,相對於此,檢體2係毒餌劑整體吸收水分,將水分吸取至毒餌劑內者。 According to the results of Table 2, the weight gain ratios due to moisture absorption after storage of the poisons of the sample 1 and the sample 2 were not the same, and there was no significant difference. Figure 2 (a) and Figure 2 (b) As shown in the figure, the poison bait of the sample 1 is in a state in which the surface is covered with the liquid material after storage, whereas the poisonous bait of the sample 2 has almost no change, and it can be considered that the sample 1 absorbs the atmosphere over time. The moisture of the attractant component is deliquescent and oozes out to the surface of the poison bait. In contrast, the sample 2 is a poison bait which absorbs moisture as a whole and absorbs moisture into the poison bait.

<毒餌劑之表面狀態確認試驗> <Surface test confirmation test of poison bait>

針對上述保存後之檢體1及2之毒餌劑,將切斷為1cm寬之短條狀之拭布(Nippon Paper Crecia股份有限公司製之「Kimwipe S-200」)於不施加荷重之情況下靜置於毒餌劑上,放置5秒。其後,回收拭布,以目視確認拭布之表面狀態。將檢體1之結果示於圖3(a)及圖3(b),將檢體2之結果示於圖4(a)及圖4(b)。 The smear of the specimens 1 and 2 after the above-mentioned storage was cut into a short strip-shaped cloth ("Kimwipe S-200" manufactured by Nippon Paper Crecia Co., Ltd.) of 1 cm width without applying a load. Place on the bait and place for 5 seconds. Thereafter, the wipe was recovered to visually confirm the surface state of the wipe. The results of the sample 1 are shown in Fig. 3 (a) and Fig. 3 (b), and the results of the sample 2 are shown in Fig. 4 (a) and Fig. 4 (b).

保存後之檢體1之毒餌劑如圖3(a)所示,剛與拭布接觸後,覆蓋毒餌劑之表面之成為液狀之引誘成分即被拭布吸收,如圖3(b)所示,於5秒後回收之拭布之表面,與成為液狀之引誘成分一併亦附著有毒餌劑之一部分。另一方面,關於檢體2之毒餌劑,如圖4(a)及圖4(b)所示,拭布表面未附著任何物質。 The toxic bait of the sample 1 after storage is as shown in Fig. 3(a), and immediately after contact with the cloth, the surface of the toxic bait is covered with a liquid-like attracting component, that is, absorbed by the cloth, as shown in Fig. 3(b). It is shown that the surface of the cloth which is recovered after 5 seconds is also attached to a part of the poison bait together with the attracting component which becomes liquid. On the other hand, regarding the poison bait of the sample 2, as shown in Figs. 4(a) and 4(b), no substance adhered to the surface of the wipe.

由此亦可知,檢體1之毒餌劑之表面狀態經時地變化。 From this, it is also known that the surface state of the poisoning bait of the specimen 1 changes with time.

<食用試驗1> <edible test 1>

使用保存後之檢體1及2之毒餌劑評價蜈蚣之食用性。 The edible properties of the cockroaches were evaluated using the toxic baits of the samples 1 and 2 after storage.

於放置有檢體1及2之保存後之毒餌劑約1g之籠(縱30cm、橫50cm、深度40cm)內放入1隻體長約20cm之少棘蜈蚣(Scolopendra subspinipes mutilans),調查蜈蚣首次接觸毒餌劑時是否食用毒餌劑。試驗重複進行5次。 For the first time, a small squid (Scolopendra subspinipes mutilans) with a body length of about 20 cm was placed in a cage of about 1 g (30 cm in length, 50 cm in width, and 40 cm in depth) after the storage of the specimens 1 and 2. Whether to use poison bait when contacting bait. The test was repeated 5 times.

試驗之結果為,於使用檢體1之毒餌劑之情形時,經確認所有蜈蚣均食用了毒餌劑,於使用檢體2之毒餌劑之情形時,雖有所有蜈蚣均接近毒餌劑之情況,但並未食用毒餌劑。 As a result of the test, in the case of using the poison bait of the sample 1, it was confirmed that all the cockroaches were eaten with the poison bait, and in the case of using the poison bait of the sample 2, although all the cockroaches were close to the toxic bait, But did not eat poison bait.

<食用試驗2> <edible test 2>

相對於表3記載之毒餌劑基劑100重量份,添加水4.5重量份、乙醇3重量份進行混練,成形為如圖5(b)所示之直徑約5mm、長度約10mm之圓柱狀,獲得毒餌劑(檢體3~5)。繼而,將所得之各毒餌劑約1g於20~23℃、濕度100%之條件下保存72小時。 With respect to 100 parts by weight of the bait base of Table 3, 4.5 parts by weight of water and 3 parts by weight of ethanol were added and kneaded, and formed into a columnar shape having a diameter of about 5 mm and a length of about 10 mm as shown in Fig. 5 (b). Poison bait (sample 3~5). Then, about 1 g of each of the obtained poison baits was stored under the conditions of 20 to 23 ° C and a humidity of 100% for 72 hours.

以目視觀察保存後之各檢體,將成為潮解狀態,毒餌劑之表面經液狀物覆蓋者評價為「○」,將無法確認到潮解狀態者評價為「×」。 Each of the specimens after storage was visually observed to be in a deliquescent state, and the surface of the poison bait was evaluated as "○" by the liquid material covering, and the "X" was evaluated when the deliquescent state could not be confirmed.

檢體3~5之毒餌劑經確認經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之引誘成分覆蓋之狀態。將結果示於表3。 The poisoning bait of the specimens 3 to 5 is confirmed to absorb the moisture in the atmosphere over time to cause the attracting component to deliquesce, and the surface is covered with the attracting component which becomes liquid. The results are shown in Table 3.

繼而,針對檢體3~5,使用保存前與保存後之毒餌劑評價蜈蚣之食用性。 Then, for the samples 3 to 5, the edible properties of the cockroaches were evaluated before and after storage.

於分別放置有檢體3~5之保存前與保存後之毒餌劑約1g之籠(縱30cm、橫50cm、深度40cm)內放入1隻體長約20cm之少棘蜈蚣,調查蜈蚣首次接觸毒餌劑時是否食用毒餌劑。將蜈蚣食用者評價為「○」,將蜈蚣未食用者評價為「×」。試驗重複進行5次。又,亦求出各檢體之蜈蚣之致死率。將結果示於表4。 Place one body of about 1g of cage (length 30cm, width 50cm, depth 40cm) before storage and 3~5 of specimens, and place one less than 20cm of thorns in the body for the first time. Whether the bait is used when the bait is used. The person who has eaten is evaluated as "○", and the person who has not eaten is evaluated as "x". The test was repeated 5 times. Moreover, the lethality rate of each sample was also determined. The results are shown in Table 4.

根據表4之結果可知,自表面至重心之最短距離為2.5mm之毒餌劑中,若為保存前之毒餌劑,則檢體3~5均未確認到蜈蚣之食用。然而,於保存後之狀態下,檢體3~5之毒餌劑為60%以上之食用率,食用過之蜈蚣全部致死。尤其是保存後之檢體3,經確認所有蜈蚣均食用毒餌劑而致死。 According to the results of Table 4, in the poison bait which has a minimum distance of 2.5 mm from the surface to the center of gravity, if it is a poison bait before storage, the samples 3 to 5 have not confirmed the consumption of the cockroach. However, in the state after the preservation, the poisoning bait of the sample 3 to 5 is an edible rate of 60% or more, and all of them are killed after eating. In particular, the specimen 3 after storage was confirmed to have died by eating all the cockroaches.

<食用試驗3> <edible test 3>

相對於表5記載之毒餌劑基劑100重量份,添加水4.5重量份、乙醇3重量份進行混練,成形為如圖5(b)所示之直徑約2mm、長度約5mm之圓柱狀,獲得毒餌劑(檢體6~10)。繼而,將所得之各毒餌劑約0.5g於20~23℃、濕度100%之條件下保存48小時。 With respect to 100 parts by weight of the bait base of Table 5, 4.5 parts by weight of water and 3 parts by weight of ethanol were added and kneaded, and formed into a columnar shape having a diameter of about 2 mm and a length of about 5 mm as shown in Fig. 5 (b). Poison bait (sample 6~10). Then, about 0.5 g of each of the obtained poison baits was stored at 20 to 23 ° C and a humidity of 100% for 48 hours.

以目視確認保存後之各檢體,與上述<食用試驗2>同樣地觀察毒餌劑之表面狀態。 Each specimen after storage was visually confirmed, and the surface state of the poison bait was observed in the same manner as in <Edible Test 2> described above.

檢體6~8之毒餌劑經確認經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之引誘成分覆蓋之狀態,但檢體9、10之毒餌劑未確認到保存後之潮解現象。 The poison bait of the specimens 6 to 8 is confirmed to absorb the moisture in the atmosphere over time to cause the attracting component to deliquesce, and the surface is covered with the attracting component which becomes liquid, but the poison bait of the specimens 9 and 10 is not confirmed after storage. The phenomenon of deliquescence.

又,藉由上述式求出毒餌劑之由吸濕引起之重量增加倍率。將結果匯總示於表6。 Further, the weight increase ratio due to moisture absorption of the poison bait was determined by the above formula. The results are summarized in Table 6.

繼而,針對檢體6~10,與上述<食用試驗2>同樣地評價蜈蚣之食用性,求出致死率。再者,毒餌劑使用約0.5g。將結果示於表7。 Then, with respect to the samples 6 to 10, the edible properties of the cockroaches were evaluated in the same manner as in the above-mentioned <edible test 2>, and the lethality was determined. Further, the bait agent is used in an amount of about 0.5 g. The results are shown in Table 7.

根據表7之結果可知,自表面至重心之最短距離為1mm之毒餌劑中,檢體6~8之毒餌劑於保存前均未確認到蜈蚣之食用,但於保存後之狀態下為100%之食用率,食用過之蜈蚣全部致死。另一方面,檢體9、10之毒餌劑於保存後之狀態下幾乎未被食用,可認為蜈蚣未將其認作餌食。 According to the results of Table 7, it can be seen that in the bait agent with the shortest distance from the surface to the center of gravity of 1 mm, the poisonous baits of the samples 6 to 8 were not confirmed to be eaten before storage, but were 100% in the state after storage. The rate of consumption, after eating, all died. On the other hand, the poison baits of the specimens 9 and 10 were hardly eaten in the state after storage, and it was considered that they were not regarded as bait.

<食用試驗4> <Food Test 4>

相對於表8記載之毒餌劑基劑100重量份,添加水4.5重量份、乙醇3重量份進行混練,打錠為如圖5(a)所示之直徑約20mm、厚度約20mm之圓盤狀,獲得毒餌劑(檢體11~13)。繼而,將所得之各毒餌劑之約5~8g於20~23℃、濕度100%之條件下保存48小時。 With respect to 100 parts by weight of the bait base described in Table 8, 4.5 parts by weight of water and 3 parts by weight of ethanol were added and kneaded, and the ingot was in the form of a disk having a diameter of about 20 mm and a thickness of about 20 mm as shown in Fig. 5 (a). , get bait (samples 11~13). Then, about 5 to 8 g of each of the obtained poison baits was stored at 20 to 23 ° C and a humidity of 100% for 48 hours.

以目視觀察保存後之各檢體,與上述<食用試驗2>同樣地觀察毒餌劑之表面狀態。 Each of the specimens after storage was visually observed, and the surface state of the poison bait was observed in the same manner as in the above-mentioned <Edible Test 2>.

檢體11、12之毒餌劑經確認經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之引誘成分覆蓋之狀態,但檢體13之毒餌劑未確認到保存後之潮解現象。 The poisoning bait of the specimens 11 and 12 is confirmed to absorb the moisture in the atmosphere over time to cause the attracting component to deliquesce, and the surface is covered with the attracting component which becomes liquid, but the poison bait of the specimen 13 is not confirmed to be deliquescent after storage. phenomenon.

又,藉由上述式求出毒餌劑之由吸濕引起之重量增加倍率。將結果匯總示於表9。 Further, the weight increase ratio due to moisture absorption of the poison bait was determined by the above formula. The results are summarized in Table 9.

繼而,針對檢體11~13,與上述<食用試驗2>同樣地評價蜈蚣之食用性,求出致死率。再者,毒餌劑使用約5~8g,試驗重複進行6次。將結果示於表10。 Then, with respect to the samples 11 to 13, the edible properties of the cockroaches were evaluated in the same manner as in the above-mentioned <edible test 2>, and the lethality was determined. Furthermore, the bait was used in an amount of about 5 to 8 g, and the test was repeated 6 times. The results are shown in Table 10.

根據表10之結果可知,自表面至重心之最短距離為10mm之毒餌劑中,含有引誘成分80重量%以上之檢體11、12成為潮解狀態,保存後之毒餌劑可提高蜈蚣之食用性。 According to the results of Table 10, in the bait agent having a shortest distance from the surface to the center of gravity of 10 mm, the samples 11 and 12 containing 80% by weight or more of the attracting component were in a deliquescent state, and the stored bait agent improved the edible properties of the cockroach.

以上,詳細地且參照特定之實施態樣對本發明進行了說明,但業者清楚可於不偏離本發明之精神與範圍之情況下施以各種變更或修正。本申請案係基於2013年12月6日提出申請之日本專利申請案(日本專利特願2013-253645)者,其內容被作為參照引入此處。 The present invention has been described in detail above with reference to the specific embodiments thereof. It is understood that various changes and modifications may be made without departing from the spirit and scope of the invention. The present application is based on Japanese Patent Application No. 2013-253645, filed on Dec.

Claims (2)

一種固體形狀之害蟲用毒餌劑,其係適於防治蜈蚣之毒餌劑,且含有殺蟲成分與引誘成分,經時地吸收大氣中之水分使引誘成分潮解,而形成表面經成為液狀之上述引誘成分覆蓋之狀態。 The utility model relates to a poison bait for a solid shape, which is suitable for controlling a bait agent for cockroaches, and contains an insecticidal component and an attracting component, and absorbs moisture in the atmosphere over time to deliquesce the attracting component, thereby forming a surface which becomes liquid. The state of the lure component. 如請求項1之害蟲用毒餌劑,其中毒餌劑之自表面至重心之最短距離為10mm以下。 The pest of claim 1 is a poison bait, wherein the shortest distance from the surface to the center of gravity of the poison bait is 10 mm or less.
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