TW201533285A - Abrasion resistant fabric - Google Patents

Abrasion resistant fabric Download PDF

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Publication number
TW201533285A
TW201533285A TW103139054A TW103139054A TW201533285A TW 201533285 A TW201533285 A TW 201533285A TW 103139054 A TW103139054 A TW 103139054A TW 103139054 A TW103139054 A TW 103139054A TW 201533285 A TW201533285 A TW 201533285A
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fabric
yarn
fibers
fiber
warp
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TW103139054A
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Chinese (zh)
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Giovanni Joseph Ida Henssen
Guelfo Valerio Bagordo
Flavio Berto
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Dsm Ip Assets Bv
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Abstract

The invention relates to a woven fabric comprising a weft yarn and at most two warp yarns A and B, wherein the weft yarn comprises a high performance fiber; the warp yarn A comprises at least 50 wt% of a natural fiber; the warp yarn B comprises a high performance fiber; and wherein the fabric has an outside layer comprising the warp yarn A and an inside layer comprising the warp yarn B and said outside and inside layers being at least partially interconnected by the weft yarn. The invention also relates to products comprising said woven fabric such as clothing, lining, sport apparel, gloves, curtains, upholstery fabric and floor covering.

Description

耐磨損的織物 Abrasion resistant fabric 發明領域 Field of invention

本發明係有關於包含高性能纖維及天然纖維之梭織物。本發明亦有關於該織物的使用及有關於包含該織物的物件諸如衣物、運動服裝、手套、窗簾、室內裝飾織物、地板覆蓋物及其他此種織物的應用。 The present invention relates to woven fabrics comprising high performance fibers and natural fibers. The invention also relates to the use of the fabric and to the use of articles comprising the fabric, such as clothing, sportswear, gloves, curtains, upholstery fabrics, floor coverings, and other such fabrics.

發明背景 Background of the invention

此種織物已知於US2007/0249250。US2007/0249250揭示一織物,其包含一由纖維素材料製造之緯紗及由一高性能纖維生產之經紗,其至少75%係由一包含天然纖維的覆蓋物所覆蓋。該織物在該織物的厚度中具有該經紗的一濃度梯度,由一主要為經紗之外部部分及主要為該緯紗之內部部分所組成。根據US2007/0249250之織物具有良好機械特性,特別是對火及對摩擦的抗性,但對於穿著而言亦為舒適的。US2010/0075557A1揭示一具有一第一表面及一第二表面的梭織物,該織物包含三個經線系統,其係以緯纖維交錯。該等第一經纖維可為美觀纖維(aesthetic fibers),例如,天然纖維、棉、羊毛、嫘縈、聚 醯胺纖維、高模數纖維;該等第二經紗可為性能纖維,例如,高分子量聚乙烯、醯胺纖維、碳纖維、纖維玻璃;該等第三纖維包括提供舒適性質者,例如,棉、嫘縈、羊毛、聚酯、尼龍。該等緯紗可為可拉伸纖維且包括Lycra®纖維、Spandex®纖維、Kevlar®纖維、高模數聚乙烯、羊毛、嫘縈、尼輪、改質聚丙烯腈(modeacrylic)纖維。 Such fabrics are known from US 2007/0249250. US 2007/0249250 discloses a fabric comprising a weft yarn made of a cellulosic material and a warp yarn produced from a high performance fiber, at least 75% of which is covered by a covering comprising natural fibers. The fabric has a concentration gradient of the warp yarns in the thickness of the fabric, consisting of an outer portion that is primarily warp yarns and an inner portion that is primarily the weft yarn. The fabric according to US 2007/0249250 has good mechanical properties, in particular resistance to fire and to friction, but is also comfortable for wearing. US 2010/0075557 A1 discloses a woven fabric having a first surface and a second surface, the fabric comprising three warp threads which are interlaced with weft fibers. The first warp fibers may be aesthetic fibers, for example, natural fibers, cotton, wool, enamel, poly Melamine fibers, high modulus fibers; the second warp yarns may be performance fibers, for example, high molecular weight polyethylene, guanamine fibers, carbon fibers, fiberglass; the third fibers include those that provide comfort properties, such as cotton,嫘萦, wool, polyester, nylon. The weft yarns may be stretchable fibers and include Lycra® fibers, Spandex® fibers, Kevlar® fibers, high modulus polyethylene, wool, enamel, nylon wheels, and modified modeacrylic fibers.

然而,先前技藝之織物在製造時係困難且昂貴的,由於該經紗包含一高性能纖維芯及一螺旋包裝(例如,棉)覆蓋該芯之表面的至少75%。此種經紗線的製造係勞力密集的且昂貴的方法。另外,此一經覆蓋的紗線在使用時較不穩健並顯示該螺旋包裝的位移或完整性損失,導致不均外觀的紗線及處理困難,造成生產的損失或降低該等織物的品質。 However, prior art fabrics are difficult and expensive to manufacture because the warp yarns comprise a high performance fiber core and a spiral wrap (e.g., cotton) covering at least 75% of the surface of the core. The manufacture of such warp yarns is a labor intensive and expensive process. In addition, the covered yarn is less robust in use and exhibits loss of displacement or integrity of the spiral package, resulting in uneven appearance of the yarn and handling difficulties, resulting in lost production or reduced quality of the fabric.

因此,本發明的一個目的可為提供一梭織物,其消除上面提及的缺點,且特別是較不易受製造損失或經降低之品質的影響,同時維持該織物的穿著舒適度。本發明之一另外的目的可為提供可由,由於較不勞力密集且具有降低的製造成本而更容易取得之紗線所製造的梭織物。本發明之一另外的目的可為提供一具有經改良的摩擦特性及穿著舒適性,或具有在摩擦特性及穿著舒適性之間最佳化平衡的織物,其中該織物係於經降低的花費及方法複雜度下製造。 Accordingly, it is an object of the present invention to provide a woven fabric that eliminates the above mentioned disadvantages and, in particular, is less susceptible to manufacturing loss or reduced quality while maintaining the wearing comfort of the fabric. It is a further object of the present invention to provide a woven fabric that can be manufactured from yarns that are more readily available due to less labor intensive and reduced manufacturing costs. It is a further object of the present invention to provide a fabric having improved friction characteristics and wearing comfort, or having an optimum balance between friction characteristics and wearing comfort, wherein the fabric is at a reduced cost and Manufacturing method complexity.

發明概要 Summary of invention

本發明提供一種包含一緯紗及至多二經紗A及B的梭織物,其中該緯紗包含高性能織物;該經紗A包含至少50wt%之天然纖維;該經紗B包含高性能纖維;且其中該織物具有包含該經紗A之一外部層及包含該經紗B之一內部層,且所述外部及內部層藉由該緯紗至少部分互連。 The present invention provides a woven fabric comprising a weft yarn and at most two warp yarns A and B, wherein the weft yarn comprises a high performance fabric; the warp yarn A comprises at least 50% by weight of natural fibers; the warp yarn B comprises high performance fibers; and wherein the fabric has An outer layer of the warp yarn A and an inner layer comprising the warp yarn B are included, and the outer and inner layers are at least partially interconnected by the weft yarn.

被觀察到的是本發明之該梭織物可通過一更穩健及/或便宜紗線而顯示經改良的製造效能。進一步觀察到的是本發明之該等織物在製造上係較不勞動密集的,同時其可具有一相等或改良的摩擦抗性且可具有相等或改良的穿著舒適性。 It has been observed that the woven fabric of the present invention exhibits improved manufacturing performance through a more robust and/or inexpensive yarn. It is further observed that the fabrics of the present invention are less labor intensive in manufacture, while they may have an equal or improved frictional resistance and may have equal or improved wearing comfort.

本發明之織物包含至多二經紗,A及B,因此提供充足的空間供織造可撓性以獲得經改良的摩擦抗性,同時保持低的製造複雜性以及表面密度及材料成本。 The fabric of the present invention comprises at most two warp yarns, A and B, thus providing sufficient space for weaving flexibility to achieve improved frictional resistance while maintaining low manufacturing complexity and surface density and material cost.

較佳實施例之詳細說明 Detailed description of the preferred embodiment

經紗此處被瞭解為具有相同組成物的大量紗線,且因此可被稱為經線系統(warp system)。各經紗實質上在該織物的機器方向縱向運行。本發明之織物具有至少二經紗,其等藉由於該織物中的相互位置而相區分。在該織物內的此種位置可藉由本領域熟知的方法達成。例如,該等複數經紗可以每個經軸一經紗而通過經軸被提供至該織造方法,但亦可經由具有不同經紗被彼此相鄰而組織的一單 一經軸提供。使用分開的經軸用於不同經紗可具有增加的可撓性及改良的織造控制之優點。將該等經紗設置於該織物內在此被瞭解為經紗A及經紗B的相對位置與該織物之厚度中的關聯。在此方面一織物可被認為是一三維物品其中一維(厚度)係遠小於該等另外兩個維度(長度或該經線方向及寬度或緯線方向)。一般而言,該長度方向僅受限於該等經紗的長度,而一織物的該寬度係主要受限於獨立經紗的數目及該使用之織造機器的寬度。該等二經紗的位置係根據其等在該織物之厚度之內的位置而界定,而該厚度係由一外部及一內部表面而定界。「外部」及「內部」在此被了解為該織物包含兩個可區別的表面。該術語「外部」及「內部」不應被理解為一限制特徵,而是該等兩個不同表面之間的區別。在該織物的許多應用中該外部表面可被定向朝向該外在環境,而該內部表面可被定向朝向將被保護免於,例如摩擦,的該主體。雖然此定向可為較偏好的,對於特定用途,該等表面亦可以面向相反方向,或該織物被折疊以形成一雙層織物,具有暴露於兩側的相同表面,而其他表面被向內朝向彼此。 Warp yarns are here understood to be a large number of yarns having the same composition, and thus may be referred to as a warp system. Each warp yarn runs substantially longitudinally in the machine direction of the fabric. The fabric of the present invention has at least two warp yarns which are distinguished by the mutual position in the fabric. Such location within the fabric can be achieved by methods well known in the art. For example, the plurality of warp yarns may be supplied to the weaving method through the warp beam per warp beam, but may also be organized via a warp yarn having different warp yarns adjacent to each other. Provided by a shaft. The use of separate warp beams for different warp yarns can have the advantages of increased flexibility and improved weaving control. The placement of the warp yarns in the fabric is here understood to be the association of the relative position of the warp yarns A and the warp yarns B with the thickness of the fabric. In this regard, a fabric can be considered a three-dimensional article in which one dimension (thickness) is much smaller than the other two dimensions (length or warp direction and width or weft direction). In general, the length direction is limited only by the length of the warp yarns, and the width of a fabric is primarily limited by the number of individual warp yarns and the width of the weaving machine used. The position of the two warp yarns is defined by their position within the thickness of the fabric, and the thickness is bounded by an outer and an inner surface. "External" and "internal" are understood herein to mean that the fabric contains two distinguishable surfaces. The terms "external" and "internal" are not to be understood as a limiting feature, but rather to distinguish between the two different surfaces. In many applications of the fabric, the outer surface can be oriented toward the outer environment, and the inner surface can be oriented toward the body to be protected from, for example, rubbing. While this orientation may be preferred, the surfaces may also face in opposite directions for a particular use, or the fabric may be folded to form a double layer fabric having the same surface exposed to both sides while the other surfaces are oriented inwardly. each other.

因此,一外部及內部層係通過該織物之厚度界定,其中該外部層包含該外部表面且該內部層包含該內部表面。層被界定為實質上平行至該等相對織物層而延伸且具有該織物之總厚度之50%或更少的厚度的體積。 Thus, an outer and inner layer is defined by the thickness of the fabric, wherein the outer layer comprises the outer surface and the inner layer comprises the inner surface. A layer is defined as a volume that extends substantially parallel to the opposing fabric layers and that has a thickness of 50% or less of the total thickness of the fabric.

在本申請案的內容中,包含該經紗A的該層可被認為是該外部層,而包含該經紗B的該層可被認為是該內部 層。 In the context of the present application, the layer comprising the warp yarn A can be considered as the outer layer, and the layer comprising the warp yarn B can be considered as the inner portion. Floor.

該緯紗通常表示於一交叉方向運行的紗,與該織物之該機器方向橫向。藉由該織物的一織造序列界定,各緯紗重複地通過兩個相鄰的經紗之間,在由該等相對經紗A或B所形成織該等平面的該等側之間轉換,並各自造成所述經紗之間以及包含所述經線層之內部層的交織或互連。形成於該等經紗及該緯紗之間的角度較佳係約90°。該織物可包含單一緯紗或具有不同組成物之複數個緯紗。根據本發明之織物中的該緯紗可為一單一緯紗或複數緯紗。在所述織物包含複數緯紗的案例中,此等紗線可具有相同或不同組成物。 The weft yarn is generally indicated as a yarn running in a cross direction transverse to the machine direction of the fabric. By a weaving sequence of the fabric, each weft yarn is repeatedly passed between two adjacent warp yarns, between the sides of the plane formed by the opposing warp yarns A or B, and each of which causes Interlacing or interconnecting between the warp yarns and the inner layer comprising the warp layers. The angle formed between the warp yarns and the weft yarn is preferably about 90°. The fabric may comprise a single weft yarn or a plurality of weft yarns having different compositions. The weft yarn in the fabric according to the invention may be a single weft yarn or a plurality of weft yarns. In the case where the fabric comprises a plurality of weft yarns, the yarns may have the same or different compositions.

由該等經紗及該等緯紗所形成的該織造結構可有複數類型,依據所使用之經紗及緯紗之數量以及在該織造方法期間用於該等經紗及該等緯紗之間的織造序列而定。此等不同序列對熟習此藝者是熟知的。通過該織造方法,該緯紗交織該等至多2經紗,A及B,藉此部分互連各自包含所述經紗A及B的該外部及內部層。此交織結構亦可被稱為單層織物,即使此單層可由如上所述之次層所組成。 The woven structure formed from the warp yarns and the weft yarns may be of a plurality of types depending on the number of warp and weft yarns used and the weaving sequence between the warp yarns and the weft yarns during the weaving process. . These different sequences are well known to those skilled in the art. By this weaving method, the weft yarns interlace the up to two warp yarns, A and B, thereby partially interconnecting the outer and inner layers each comprising the warp yarns A and B. This interwoven structure may also be referred to as a single layer fabric, even though the single layer may be composed of sublayers as described above.

考量到包含至多二經紗及一緯紗的織造結構可造成相當複雜的編織,一旦經由該緯紗的交織特徵被忽視,該獨立內部及外部層可存在用於諸如平紋、斜紋和緞紋之織物的典型編織,以及其他更為複雜的編織。藉此,本發明之織物的該織造結構之優點係該織物的兩個表面可具有可區分的或相同織造結構,其係獨立的選自於該另一表面 之織造結構,此對於由僅僅一經紗及一緯紗所組成之織物是不可能的。 Considering a woven structure comprising at most two warp yarns and a weft yarn can result in a rather complicated weave, which can be present for fabrics such as plain, twill and satin, once the interlacing characteristics through the weft yarn are neglected. Weaving, as well as other more complicated weaving. Thereby, the advantage of the woven structure of the fabric of the present invention is that the two surfaces of the fabric may have distinguishable or identical woven structures that are independently selected from the other surface. The woven structure is not possible for a fabric composed of only one warp yarn and one weft yarn.

一織造結構通常特徵在於一浮紋(float)、該浮紋的長度及浮紋比。該浮紋係緯紗的一部分,由兩個連續點定界,其處該緯紗交錯由該等相對經紗A或B所形成的虛擬平面。該浮紋的長度代表該浮紋通過所述兩個定界點之間的經紗數目。典型地浮紋長度可為1、2或3,表示藉由通過2相鄰經紗之間,該緯紗在與藉由該等經紗所形成的虛擬平面交叉之前通過1、2或3經紗。該浮紋比係該緯紗於藉由該等經紗所形成織平面兩側之該等浮紋織長度織間的比例。較佳地,該外部層的該織造結構具有3/1、2/1或1/1之浮紋比,最佳地該浮紋比係3/1,造成該外部層的一牛仔布(Jeans)外觀。對於該內部層的該織造結構可獨立地選自於該外部層且被最佳化以改良摩擦抗性或穿著舒適性。依據該經紗B及該緯紗的組成物,該內部層的該織造結構具有3/1、2/1或1/1的浮紋比,最佳地該浮紋比係1/1。 A woven structure is typically characterized by a float, the length of the embossment, and the ratio of embossing. A portion of the embossed weft yarn is delimited by two consecutive points at which the weft yarns are interlaced by the virtual plane formed by the opposing warp yarns A or B. The length of the float represents the number of warp yarns between the two delimiting points through the float. Typically, the length of the embossing can be 1, 2 or 3, meaning that by passing between two adjacent warp yarns, the weft yarn passes through 1, 2 or 3 warp yarns before intersecting with the virtual plane formed by the warp yarns. The embossing ratio is the ratio of the weft yarns to the lengths of the woven fabrics on both sides of the woven plane formed by the warp yarns. Preferably, the woven structure of the outer layer has a embossing ratio of 3/1, 2/1 or 1/1, and optimally the embossing ratio is 3/1, resulting in a denim of the outer layer (Jeans )Exterior. The woven structure for the inner layer can be independently selected from the outer layer and optimized to improve friction resistance or wearing comfort. Depending on the warp yarn B and the composition of the weft yarn, the woven structure of the inner layer has a embossing ratio of 3/1, 2/1 or 1/1, and the embossing ratio is preferably 1/1.

「至少部分互連」在此表示一緯紗通過藉由該經紗A所形成之虛擬平面的數目對於通過藉由該經紗B所形成之虛擬平面的數目之間的比例係至多4:1,較佳至多3:1,更佳至多2:1,且最佳至多1:1。「至少部分互連」在此亦可互換地代表「互連」。 "At least partially interconnected" means here that a weft yarn is preferably at most 4:1 by the ratio of the number of imaginary planes formed by the warp yarn A to the number of imaginary planes formed by the warp yarn B. Up to 3:1, better at most 2:1, and the best is at most 1:1. "At least partially interconnected" is also used interchangeably to mean "interconnect".

「纖維」此處被瞭解為具有長度、寬度及厚度的伸長體,其之該長度維度係遠大於其寬度及厚度的橫向維度。該用語纖維亦包括各種實施態樣,例如,絲狀物 (filament)、帶子(ribbon)、帶體(strip)、條帶(band)、帶狀物(tape)及具有規律或不規律橫截面的類似物。該等纖維可具有連續長度,於此領域中已知為長纖維(filaments),或不連續長度,於此領域中已知為短纖維(staple fiber)。天然纖維通常係短纖維但合成短纖維常見地由對應的合成纖維之長纖維切割或拉伸斷裂而獲得。該等纖維可具有各種橫截面,例如,具有圓形、豆形、橢圓形或矩形之規律或不規律橫截面。用於本發明之訴求的紗線係一包含複數纖維的伸長體。熟習此藝者可區辨連續長纖維紗或包含許多連續長纖維與短纖維紗或包含較短纖維之紡紗(亦稱為短纖維)。 "Fiber" is herein understood to be an elongate body having a length, a width and a thickness which is much larger than the transverse dimension of its width and thickness. The term fiber also includes various embodiments, such as a filament Filament, ribbon, strip, tape, tape, and the like having a regular or irregular cross section. The fibers may have a continuous length, known in the art as filaments, or discontinuous lengths, known in the art as staple fibers. Natural fibers are usually short fibers but synthetic short fibers are commonly obtained by cutting or tensile fracture of long fibers of corresponding synthetic fibers. The fibers can have various cross-sections, for example, having a regular or irregular cross-section of a circle, a bean, an ellipse or a rectangle. The yarn used in the present invention is an elongated body comprising a plurality of fibers. Those skilled in the art will be able to distinguish between continuous filament yarns or spun yarns (also known as staple fibers) comprising a plurality of continuous long fibers and staple fibers or comprising shorter fibers.

該至多二經紗(A及B)可進一步由其等紗線組成物區別。因此,該經紗A包含至少50wt%之天然纖維,較佳至少75wt%之天然纖維,更佳至少90wt%之天然纖維。最佳地,該經紗A實質上由天然纖維所組成。於本申請案的內容中,天然纖維被了解為自然存在於纖維諸如棉、羊毛、絲、黃麻、茯苓、亞麻及類似物。具有外觀質地及觸覺特性的織物可被獲得,其中根據本發明之織物中該經紗A之天然纖維係棉或羊毛。 The at most two warp yarns (A and B) can be further distinguished by their equal yarn composition. Accordingly, the warp yarn A comprises at least 50% by weight of natural fibers, preferably at least 75% by weight of natural fibers, more preferably at least 90% by weight of natural fibers. Most preferably, the warp yarn A consists essentially of natural fibers. Natural fiber is understood to be naturally present in fibers such as cotton, wool, silk, jute, alfalfa, flax, and the like in the context of this application. A fabric having an appearance texture and a tactile property can be obtained, wherein the natural fiber of the warp yarn A in the fabric according to the present invention is cotton or wool.

於本發明之內容中,該表示「實質上由...所組成」具有「可包含微量之其他物種」或換言之「包含多於98wt%之…」的含意,並因此允許至高2wt%之其他物種的存在。 In the context of the present invention, the expression "consisting essentially of" has the meaning of "may include a trace amount of other species" or in other words "containing more than 98% by weight of ..." and thus allows for up to 2% by weight of the other The existence of species.

該經紗A可進一步包含合成纖維,例如聚醯胺、聚酯、聚四氟乙烯、聚烯烴、聚乙烯醇及聚丙烯腈之合成 纖維;及/或高性能纖維;及/或其他棉、麻、羊毛、絲、黃麻、亞麻之外的天然纖維。 The warp yarn A may further comprise synthetic fibers, such as polyamine, polyester, polytetrafluoroethylene, polyolefin, polyvinyl alcohol and polyacrylonitrile. Fibers; and/or high performance fibers; and/or other natural fibers other than cotton, hemp, wool, silk, jute, and linen.

於本發明之內容中,高性能纖維被了解為包括包含或由一聚合物所組成的纖維,該聚合物係選自於由下列所組成之群組:聚烯烴、聚甲醛;聚(氯化亞乙烯);聚(甲基戊烷);聚(乙烯-三氟氯乙烯);聚醯胺及聚芳醯胺,例如,聚(對伸苯基對苯二甲醯胺)(已知為Kevlar®);聚芳酯;聚(四氟乙烯)(PTFE);聚{2,6-二咪唑-[4,5b-4’,5’e]吡啶基-1,4(2,5-二羥基)伸苯基}(已知為M5);聚(對伸苯基-2,6-苯雙噁唑)(PBO)(已知為Zylon®);聚(六亞甲基二醯己二胺)(已知為尼龍6,6);聚丁烯;聚酯,例如聚(乙烯對苯二甲酸乙二酯)、聚(丁烯對苯二甲酸乙二酯),及聚(1,4-亞環己基二亞甲基對苯二甲酸乙二酯);聚乙烯醇及熱致液晶聚合物(LCP)已知於例如US 4,384,016。較佳地,該等高性能纖維包含或由熱塑性聚合物所組成。較佳地,該等高性能纖維包含或由半結晶聚合物所組成。包含上述聚合物的纖維組合亦可被用於根據本發明之織物中。 In the context of the present invention, high performance fibers are understood to include fibers comprising or consisting of a polymer selected from the group consisting of polyolefins, polyoxymethylene, poly(chlorinated) (ethylene); poly(methylpentane); poly(ethylene-chlorotrifluoroethylene); polyamine and polyarylamine, for example, poly(p-phenylphenylphthalamide) (known as Kevlar®); polyarylate; poly(tetrafluoroethylene) (PTFE); poly{2,6-diimidazole-[4,5b-4',5'e]pyridinyl-1,4(2,5- Dihydroxy)phenylene} (known as M5); poly(p-phenylene-2,6-benzobisoxazole) (PBO) (known as Zylon®); poly(hexamethylene dioxime) Diamine) (known as nylon 6,6); polybutene; polyester, such as poly(ethylene terephthalate), poly(butylene terephthalate), and poly(1) , 4-cyclohexylene dimethylene terephthalate ethylene terephthalate); polyvinyl alcohol and thermotropic liquid crystal polymer (LCP) are known, for example, from US 4,384,016. Preferably, the high performance fibers comprise or consist of a thermoplastic polymer. Preferably, the high performance fibers comprise or consist of a semicrystalline polymer. Fiber combinations comprising the above polymers can also be used in the fabrics according to the invention.

另外,高性能纖維在此可被了解為包括纖維,較佳聚合性纖維,其具有至少1.2N/tex之韌性或抗拉強度,更佳至少2.5N/tex,最佳至少3.5N/tex,再最佳至少4N/tex。基於實務,該高性能纖維的韌性或抗拉強度可為最多10N/tex。該抗拉強度可藉由此處以下敘述於「實例」中之方法所量測。 Additionally, high performance fibers are understood herein to include fibers, preferably polymeric fibers, having a tenacity or tensile strength of at least 1.2 N/tex, more preferably at least 2.5 N/tex, and most preferably at least 3.5 N/tex. Again optimal at least 4N/tex. Based on practice, the high performance fiber can have a tenacity or tensile strength of up to 10 N/tex. The tensile strength can be measured by the method described herein below in the "Examples".

較佳地,根據本發明之織物包含聚烯烴纖維。更 佳地,該聚烯烴纖維包含丙烯及/或乙烯均聚物及/或以丙烯及/或乙烯為主之共聚物。甚至更佳地,該聚烯烴係一聚乙烯,更佳一中等、高或超高分子量聚乙烯且最佳地,一超高分子量聚乙烯(UHMWPE)。UHMWPE此處被瞭解為一聚乙烯,其具有至少4dl/g,更佳至少8dl/g,最佳至少12dl/g的固有黏度(IV)。較佳地所述IV係至多40dl/g,更佳至多30dl/g,更佳至多25dl/g。該IV可於135℃,在十氫萘中根據ASTM D1601(2004)量測,該溶解時間為16小時,具有2g/l溶液之量的BHT(丁基化羥基甲苯)作為抗氧化劑,藉由外推法在不同濃度至零濃度所測量的黏度而量測。較佳地,該UHMWPE纖維為凝膠紡纖維,即,以一凝膠-紡織方法所製造的纖維。用於製造UHMWPE纖維之凝膠紡織方法的實例係敘述於許多公開案中,包括EP 0205960 A、EP 0213208 A1、US 4413110、GB 2042414 A、GB-A-2051667、EP 0200547 B1、EP 0472114 B1、WO 01/73173 A1、EP 1,699,954及於“Advanced Fibre Spinning Technology”,Ed.T.Nakajima,Woodhead Publ.Ltd(1994),ISBN 185573 182 7中。 Preferably, the fabric according to the invention comprises polyolefin fibers. More preferably, the polyolefin fibers comprise propylene and/or ethylene homopolymers and/or copolymers based on propylene and/or ethylene. Even more preferably, the polyolefin is a polyethylene, more preferably a medium, high or ultra high molecular weight polyethylene and optimally, an ultra high molecular weight polyethylene (UHMWPE). UHMWPE is herein understood to be a polyethylene having an intrinsic viscosity (IV) of at least 4 dl/g, more preferably at least 8 dl/g, most preferably at least 12 dl/g. Preferably, the IV system is at most 40 dl/g, more preferably at most 30 dl/g, still more preferably at most 25 dl/g. The IV can be measured at 135 ° C in decalin according to ASTM D1601 (2004), the dissolution time is 16 hours, and the amount of 2 g / l solution of BHT (butylated hydroxytoluene) as an antioxidant, by The extrapolation method is measured at a viscosity measured from different concentrations to zero concentrations. Preferably, the UHMWPE fiber is a gel-spun fiber, that is, a fiber produced by a gel-weaving method. Examples of gel spinning processes for making UHMWPE fibers are described in a number of publications, including EP 0205960 A, EP 0213208 A1, US 4413110, GB 2042414 A, GB-A-2051667, EP 0200547 B1, EP 0472114 B1. WO 01/73173 A1, EP 1,699,954 and in " Advanced Fibre Spinning Technology ", Ed. T. Nakajima, Woodhead Publ. Ltd (1994), ISBN 185573 182 7.

較佳地,本發明之該高性能纖維為聚乙烯纖維,更佳地具有至少2N/tex,更佳至少3N/tex之韌性的UHMWPE纖維。 Preferably, the high performance fiber of the present invention is a polyethylene fiber, more preferably a UHMWPE fiber having a toughness of at least 2 N/tex, more preferably at least 3 N/tex.

較佳地,該經紗A包含0.5及50wt%之間之高性能纖維,更佳1至20wt%之間,甚至更佳2及10wt%之間之高性能纖維。於該經紗A中存在的一低量高性能纖維改良本發明之織物的摩擦抗性。 Preferably, the warp yarn A comprises between 0.5 and 50% by weight of high performance fibers, more preferably between 1 and 20% by weight, even more preferably between 2 and 10% by weight of high performance fibers. A low amount of high performance fibers present in the warp yarn A improves the frictional resistance of the fabric of the present invention.

於一進一步實施態樣中,存在於經紗A中的該高性能纖維係選自於聚芳醯胺纖維及聚烯烴之群組的高性能纖維,較佳聚乙烯且最佳UHMWPE纖維。被觀察到的是,當該編織之經紗A包含高性能纖維,特別是高性能芳族聚醯胺或聚烯烴纖維,更特別是聚(對伸苯基對苯二甲醯胺)或超高分子量聚乙烯纖維,該編織具有進一步改良的摩擦抗性。 In a further embodiment, the high performance fiber present in warp yarn A is selected from the group consisting of high performance fibers of polyarmine fiber and polyolefin, preferably polyethylene and the most preferred UHMWPE fiber. It has been observed that when the woven warp yarn A comprises high-performance fibers, in particular high-performance aromatic polyamide or polyolefin fibers, more particularly poly(p-phenylene terephthalamide) or super high Molecular weight polyethylene fibers, the weave has further improved friction resistance.

存在於本發明之織物之內部層中的該經紗B包含根據此處所定義之高性能纖維之定義的高性能纖維。較佳地,該經紗B包含至少1wt%之高性能纖維,較佳至少5wt%,更佳至少15wt%,更佳至少30wt%,再更佳至少50wt%,再更佳至少75wt%,且最佳至少90wt%之高性能纖維。被觀察到的是於該經紗B中高性能纖維之增加等級進一步改良該織物的摩擦抗性,同時該織物的穿著舒適性及外觀若有被影響,僅被輕微影響。 The warp yarn B present in the inner layer of the fabric of the present invention comprises high performance fibers according to the definition of high performance fibers as defined herein. Preferably, the warp yarn B comprises at least 1% by weight of high performance fibers, preferably at least 5% by weight, more preferably at least 15% by weight, more preferably at least 30% by weight, still more preferably at least 50% by weight, still more preferably at least 75% by weight, and most At least 90% by weight of high performance fiber. It has been observed that the increased grade of high performance fibers in the warp yarn B further improves the frictional resistance of the fabric, while the wearing comfort and appearance of the fabric are only slightly affected if it is affected.

雖然該織物之摩擦性質的進一步改良藉由使用較高量的高性能纖維於經紗B中而獲得,被觀察到的是根據本發明之織物的穿著舒適性藉由一包含至少一選自於下列群組之纖維的經紗B被進一步改良:棉、麻、羊毛、絲、黃麻、亞麻及聚醯胺、聚四氟乙烯、聚酯、聚烯烴、聚乙烯醇及聚丙烯腈之合成纖維。 Although a further improvement in the friction properties of the fabric is obtained by using a higher amount of high performance fibers in the warp yarn B, it is observed that the wearing comfort of the fabric according to the present invention comprises at least one selected from the following The warp yarns B of the group of fibers are further improved: synthetic fibers of cotton, hemp, wool, silk, jute, flax and polyamide, polytetrafluoroethylene, polyester, polyolefin, polyvinyl alcohol and polyacrylonitrile.

令人驚訝的,被觀察到的是,藉由令該經紗B為一紡紗,該織物的穿著舒適性及摩擦抗性被進一步改良,或其等之平衡被最佳化。被發現的是該經紗B的該紡織特徵 對於該摩擦抗性僅有一經限制的效應,而其更為天然的質地提供穿著者更自然的感覺。一進一步的優點係一紡紗的組成物可被輕易調整至任何所欲的比例,該比例允許摩擦及舒適性的進一步改良或最佳化。於一較佳實施態樣中,該紡紗實質上由高性能纖維所組成,更佳地由UHMWPE短纖維所組成。 Surprisingly, it has been observed that by making the warp yarn B a spun yarn, the fabric's wearing comfort and frictional resistance are further improved, or the balance thereof is optimized. What was found is the textile characteristics of the warp yarn B. There is only a limited effect on this frictional resistance, and its more natural texture provides a more natural feel to the wearer. A further advantage is that the composition of a spinning can be easily adjusted to any desired ratio which allows for further improvement or optimization of friction and comfort. In a preferred embodiment, the spinning consists essentially of high performance fibers, more preferably UHMWPE staple fibers.

該紡紗也藉由任何該領域中所熟知的技術製造,諸如環錠式精紡(ring spinning)方法或開放式精紡方法。施用該環錠式精紡方法的優點係該機械處理及方法溫度是更為適當的,若,例如,UHMWPE短纖維被紡織,而具有較高生產力的開放式精紡方法可被施用於僅具有少量UHMWPE存在於該摻合物中之高溫抗性短纖維紗的案例中。 The spinning is also produced by any technique well known in the art, such as a ring spinning process or an open spinning process. The advantage of applying the ring-type worsted method is that the mechanical treatment and method temperature are more suitable if, for example, UHMWPE staple fibers are woven, and the open-end worsted method with higher productivity can be applied to only A small amount of UHMWPE is present in the case of high temperature resistant staple fiber yarns in the blend.

本發明之織物包含的該緯紗包含根據此處之高性能纖維定義的高性能纖維。於一更佳實施態樣中,該緯紗包含至少10wt%之高性能纖維,更佳至少25wt%,再更佳至少50wt%,再更佳至少75wt%,再更佳至少90wt%,且最佳100wt%之高性能纖維。令人訝異的,被觀察到的是於該緯紗中高性能纖維的增加等及對於該織物的摩擦抗性是有益的,而該織物的穿著舒適性及外觀維持實際上未受影響。 The weft yarns comprised by the fabric of the present invention comprise high performance fibers as defined herein for high performance fibers. In a preferred embodiment, the weft yarn comprises at least 10% by weight of high performance fibers, more preferably at least 25% by weight, even more preferably at least 50% by weight, even more preferably at least 75% by weight, even more preferably at least 90% by weight, and most preferably 100% by weight of high performance fiber. Surprisingly, it has been observed that the increase in high performance fibers in the weft yarn and the like and the frictional resistance to the fabric are beneficial, while the fabric's wearing comfort and appearance maintenance are virtually unaffected.

被觀察到的是,當該編織之緯紗包含高性能纖維,更特別是高性能芳族聚醯胺或聚烯烴纖維,更特別是聚(對伸苯基對苯二甲醯胺)或超高分子量聚乙烯纖維,該織物可 具有進一步改良的摩擦抗性或可於高速下製造。因此,於一較佳實施態樣中,存在於該緯紗中的該高性能纖維係選自於由芳族聚醯胺纖維及UHMWPE纖維所組成之群組的高性能纖維。 It has been observed that when the woven weft yarn comprises high-performance fibers, more particularly high-performance aromatic polyamide or polyolefin fibers, more particularly poly(p-phenylene terephthalamide) or super high Molecular weight polyethylene fiber, the fabric can It has further improved friction resistance or can be manufactured at high speed. Therefore, in a preferred embodiment, the high performance fiber present in the weft yarn is selected from the group consisting of high performance fibers composed of a group of aromatic polyamide fibers and UHMWPE fibers.

雖然該織物之摩擦性質的進一步改良藉由使用較高量的高性能纖維於緯紗中而獲得,被觀察到的是根據本發明之織物的穿著舒適性藉由一包含至少一選自於下列之纖維的緯紗被進一步改良:棉、麻、羊毛、絲、黃麻、亞麻及聚醯胺、聚四氟乙烯、聚酯、聚烯烴、聚乙烯醇及聚丙烯腈之合成纖維。 Although a further improvement in the friction properties of the fabric is obtained by using a higher amount of high performance fibers in the weft yarn, it is observed that the wearing comfort of the fabric according to the present invention comprises at least one selected from the group consisting of The weft of the fiber is further improved: synthetic fibers of cotton, hemp, wool, silk, jute, flax and polyamide, polytetrafluoroethylene, polyester, polyolefin, polyvinyl alcohol and polyacrylonitrile.

令人驚訝的,被觀察到的是該織物的摩擦抗性藉由該緯紗為一連續長纖維紗而被進一步增加或最佳化。被發現的是,該緯紗B之連續長纖維特徵增強該摩擦抗性。於一較佳實施態樣中,該緯紗係UHMWPE長纖維、芳族聚醯胺長纖維或其等之組合之連續長纖維紗。 Surprisingly, it has been observed that the frictional resistance of the fabric is further increased or optimized by the weft yarn being a continuous filament yarn. It has been found that the continuous long fiber characteristics of the weft yarn B enhance the friction resistance. In a preferred embodiment, the weft yarn is a continuous filament yarn of UHMWPE long fiber, aromatic polyamine long fiber or the like.

進一步觀察到的是,存在於經紗B中之高性能纖維的特定種類甚至進一步改良該織物的摩擦抗性效能。因此,本發明之一較佳實施態樣係一織物,其中該緯紗及該經紗B之該高性能纖維係獨立地選自於由下列所組成之群組:芳族聚醯胺纖維、液晶聚合物纖維、聚苯并咪唑纖維、聚苯並噁唑纖維、聚芳酯纖維、高定向聚乙烯纖維及高定向聚丙烯纖維。 It has further been observed that the particular type of high performance fiber present in warp B even further improves the friction resistance effectiveness of the fabric. Accordingly, a preferred embodiment of the present invention is a fabric wherein the weft yarn and the high performance fiber of the warp yarn B are independently selected from the group consisting of aromatic polyamine fibers, liquid crystal polymerization. Fiber, polybenzimidazole fiber, polybenzoxazole fiber, polyarylate fiber, highly oriented polyethylene fiber and highly oriented polypropylene fiber.

雖然各該經紗B及該緯紗對該織物的機械性質提供獨立的益處,令人驚訝的,被發現的是於存在於該內 部層中之該等紗,即,該緯紗及該經紗B中的高性能纖維之總量,增加該織物的摩擦抗性。因此,於一較佳實施態樣中,於該緯紗及該經紗B中的高性能纖維之量係至少10wt%,較佳至少30wt%,更佳至少50wt%,甚至更佳至少70wt%且最佳至少80wt%,其中該wt%係被包含於該緯紗及經紗B中之高性能纖維的累積重量對該緯紗及該經紗B之累積重量的比例。 Although each of the warp yarns B and the weft yarns provide an independent benefit to the mechanical properties of the fabric, it is surprising that it is found to be present therein. The yarns in the layers, i.e., the total amount of high performance fibers in the weft yarns and the warp yarns, increase the frictional resistance of the fabric. Therefore, in a preferred embodiment, the amount of high performance fibers in the weft yarn and the warp yarn B is at least 10 wt%, preferably at least 30 wt%, more preferably at least 50 wt%, even more preferably at least 70 wt% and most Preferably, it is at least 80% by weight, wherein the wt% is the ratio of the cumulative weight of the high performance fibers contained in the weft yarn and the warp yarn B to the cumulative weight of the weft yarn and the warp yarn B.

於再較佳之實施態樣中,本發明之織物包含含有UHMWPE之經紗B及含有芳族聚醯胺纖維的緯紗。令人驚訝的發現在該獨立緯紗及經紗中之高性能纖維的此特定組合給予該織物之經改良或最佳化的穿著舒適性及其摩擦抗性之間的平衡。較佳的,於此實施態樣中,該經紗A實質上由天然纖維所組成,較佳由棉所組成。 In a further preferred embodiment, the fabric of the present invention comprises warp yarn B comprising UHMWPE and weft yarns comprising aromatic polyamide fibers. It has surprisingly been found that this particular combination of high performance fibers in the individual weft yarns and warp yarns gives a balance between improved or optimized wearing comfort and frictional resistance of the fabric. Preferably, in this embodiment, the warp yarn A consists essentially of natural fibers, preferably cotton.

根據本發明之該織物較佳包含實質上由棉所組成之該經紗A、為一紡紗且實質上由UHMWPE短纖維所組成之經紗B,及實質上由連續UHMWPE長纖維所組成之緯紗。此一組合產生根據本發明之該織物的穿著舒適性及摩擦抗性之間的最佳化平衡,或經改良之穿著舒適性及摩擦抗性。 The fabric according to the present invention preferably comprises the warp yarn A consisting essentially of cotton, a warp yarn B consisting of a spun yarn and consisting essentially of UHMWPE staple fibers, and a weft yarn consisting essentially of continuous UHMWPE long fibers. This combination produces an optimized balance between wearing comfort and frictional resistance of the fabric according to the present invention, or improved wearing comfort and friction resistance.

存在於該織物中之該等紗線可各自獨立地包含至少一選自於由下列所組成之群組的添加劑:顏料、染料、阻燃劑、抗氧化劑及/或其等之組合。作為該領域中常實行的,在上面記載的材料及科技選擇之外,此等添加劑可被用於克服該織造織物的缺陷。該等添加劑可被以,例如, 在該合成程序之不同階段之該等纖維、紗或織物的浸漬或塗覆而被施用至該織物,以及在其等之合成方法中添加至該(等)合成纖維。此等添加劑係於該領域中所熟知的。熟習此藝者可在未經過度實驗下輕易選擇任何合適的添加劑之組合及添加劑含量。添加劑的含量依其之類型及功能而定。通常,其等之含量將自0至20wt%,以該織物之總組成物為基準。 The yarns present in the fabric may each independently comprise at least one additive selected from the group consisting of pigments, dyes, flame retardants, antioxidants, and/or combinations thereof. As is often practiced in the art, in addition to the materials and technology options described above, such additives can be used to overcome the deficiencies of the woven fabric. Such additives can be used, for example, The impregnation or coating of the fibers, yarns or fabrics at different stages of the synthesis process is applied to the fabric, and to the synthetic fibers, etc., in the synthesis thereof. Such additives are well known in the art. Those skilled in the art can easily select any suitable combination of additives and additive levels without undue experimentation. The amount of the additive depends on its type and function. Typically, the content will be from 0 to 20% by weight based on the total composition of the fabric.

根據本發明之該織物的另一優點在於該等經使用之材料的異質性本質。例如,被包含於該織物中的該天然纖維以及一些合成纖維之親水特性對於吸收添加劑,諸如染料及顏料是有益的,而例如該聚烯烴纖維的疏水本質對於該織物對於,特別是抗氧化劑及阻燃劑的親和力是被希望的。 Another advantage of the fabric according to the present invention is the heterogeneous nature of the materials used. For example, the hydrophilic properties of the natural fibers and some synthetic fibers contained in the fabric are beneficial for absorbing additives such as dyes and pigments, for example, the hydrophobic nature of the polyolefin fibers for the fabric, especially antioxidants and The affinity of the flame retardant is desirable.

根據本發明之一織物對於衣物、內襯、運動服裝、手套、窗簾、室內裝飾織物及地板覆蓋物的製造是絕佳適合的。較佳地,根據本發明之該織物被用於工作服裝及休閒服裝的製造,其中對於舒適及輕便服裝,耐磨特性是需要的。因此,本發明之另外的實施態樣係本發明之該織物於服裝、內襯、運動服裝、手套、窗簾、室內裝飾織物及地板覆蓋物之製造的用途。本發明之另一實施態樣係包含根據本發明之該織物的產品,其中所述產品係選自於由服裝、內襯、運動服裝、手套、窗簾、室內裝飾織物及地板覆蓋物所組成之群組。 A fabric according to the present invention is an excellent fit for the manufacture of garments, linings, sportswear, gloves, curtains, upholstery fabrics, and floor coverings. Preferably, the fabric according to the present invention is used in the manufacture of work garments and casual garments where abrasion resistance properties are desirable for comfortable and lightweight garments. Accordingly, another embodiment of the present invention is the use of the fabric of the present invention in the manufacture of garments, linings, sportswear, gloves, curtains, upholstery fabrics, and floor coverings. Another embodiment of the invention is a product comprising the fabric according to the invention, wherein the product is selected from the group consisting of garments, linings, sportswear, gloves, curtains, upholstery fabrics and floor coverings. Group.

本發明亦有關包含一緯紗及至少二經紗A及B之 梭織物,其中該緯紗包含高性能纖維;該經紗A包含至少50wt%之天然纖維;該經紗B包含高性能纖維;且其中該織物具有包含該經紗A之外部層及包含該經紗B之內部層且所述外部及內部層係藉由該緯紗至少部分互聯。此種織物之該等組分、較佳實施態樣及特性等係如此處上述所界定。 The invention also relates to a weft yarn and at least two warp yarns A and B a woven fabric, wherein the weft yarn comprises high performance fibers; the warp yarn A comprises at least 50% by weight of natural fibers; the warp yarn B comprises high performance fibers; and wherein the fabric has an outer layer comprising the warp yarn A and an inner layer comprising the warp yarn B And the outer and inner layers are at least partially interconnected by the weft yarns. Such components, preferred embodiments and characteristics of such fabrics are as defined herein above.

注意到的是本發明係有關於記述於申請專利範圍中之特徵的所有可能的組合。敘述於說明書中的特徵可進一步被組合。 It is noted that the present invention is directed to all possible combinations of features recited in the scope of the claims. Features described in the specification can be further combined.

更被注意到的是該用語「包含」並未排除其他元件的存在。然而,被了解的是,包含某些組分的一產品之敘述亦揭示一由此等組分所組成之產品。相似地,亦被了解的是,包含某些步驟之方法的敘述亦揭示由此等步驟所組成之方法。 It is further noted that the term "comprising" does not exclude the existence of other elements. However, it is to be understood that the description of a product comprising certain components also reveals a product of such components. Similarly, it is also understood that the description of the method comprising certain steps also reveals the method consisting of the steps.

本發明將於以下借助數個實例被闡明,不被限制至此。 The invention will be elucidated below with the aid of several examples and is not limited thereto.

實例Instance 測試程序test program

該等織物的面密度藉由秤重一10 x 10cm2方形織物並將該記錄之以g為單位的重量乘以100而量測。 The areal density of such fabrics by weighing a 10 x 10cm 2 square of the fabric and recording the weight in g and multiplied by 100 measurements.

織物根據EN13595-2受到一磨擦抗性測試。 The fabric was subjected to a friction resistance test according to EN13595-2.

韌性係於一Zwick拉伸試驗機上根據ISO 2062-93(A)量測。 Toughness was measured on a Zwick tensile tester according to ISO 2062-93 (A).

纖維之拉伸性質,即,強度及模數於多絲紗上如 ASTM D885M規定者所量測,使用500mm之該纖維的標稱隔距長度、50%/min之夾頭速度(crosshead speed)及型號Fibre Grip D5618C之Instron 2714夾板。對於強度的計算,被量測之拉伸力被除以纖度(titre),如秤重10公尺之纖維所決定;以GPa為單位之值被計算,假設該聚合物之該本質密度,例如,對於UHMWPE係0.97g/cm3The tensile properties of the fibers, i.e., the strength and modulus, are measured on a multifilament yarn as specified by ASTM D885M, using a nominal gauge length of the fiber of 500 mm and a crosshead speed of 50%/min. And the Instron 2714 splint of the Fibre Grip D5618C model. For the calculation of the strength, the measured tensile force is divided by the titre, as determined by the fiber weighing 10 meters; the value in terms of GPa is calculated, assuming the essential density of the polymer, for example For UHMWPE series 0.97g/cm 3 .

實驗細節Experimental details 比較實驗A(Comp A)Comparative Experiment A (Comp A)

一平紋單層梭織物A自一單一經紗及一緯紗製造。該經紗I由下列所組成:一具有35cN/dtex之韌性的芯紗(商業上可得之纖維Dyneema® SK62(440dtex)),其係以每公尺3000圈由一Nm80/2來自棉的表紗螺旋形圍繞。該織物由29wt% Dyneema® SK62及71wt%之棉所組成,以該總紗組成物為基準。該緯紗係一紡棉紗II。該獲得之織物對應至揭示於US2007/0249250中的該等織物。 A plain weave woven fabric A is manufactured from a single warp yarn and a weft yarn. The warp yarn I consists of a core yarn having a toughness of 35 cN/dtex (commercially available fiber Dyneema® SK62 (440 dtex)), which is a watch of Nm 80/2 from cotton at 3,000 turns per meter. The yarn is spirally surrounded. The fabric consisted of 29 wt% Dyneema® SK62 and 71 wt% cotton based on the total yarn composition. The weft yarn is a spun cotton yarn II. The fabric obtained corresponds to the fabrics disclosed in US 2007/0249250.

該平紋組織已受到該摩擦測試(EN13595-2)。該織物A於不同方向(經方向、緯方向及45°)之摩擦測試結果可見於表1。 This plain weave has been subjected to this friction test (EN13595-2). The results of the friction test of the fabric A in different directions (transverse direction, weft direction and 45°) can be found in Table 1.

比較實驗B(Comp B)Comparative Experiment B (Comp B)

織物B之一代表性小塊自一商業上可取得之牛仔褲(來自HELD品牌)裁切。目測指示棉被用作單經紗且該 緯紗係由Kevlar®纖維所製造。該織物由60wt%棉及40wt% Kevlar®所組成,以該總紗線組成物為基準。該織物B於不同方向(經方向、緯方向及45°)之摩擦測試結果可見於表1。 A representative piece of fabric B is cut from a commercially available pair of jeans (from the HELD brand). Visually indicating that the quilt is used as a single warp yarn and The weft yarn is made of Kevlar® fiber. The fabric consisted of 60 wt% cotton and 40 wt% Kevlar® based on the total yarn composition. The results of the friction test of the fabric B in different directions (transverse direction, weft direction and 45°) can be found in Table 1.

實例1-5Example 1-5

材料:不同紗線已被使用作為單層織物中之經紗A、經紗B及緯紗: Material: Different yarns have been used as warp yarn A, warp yarn B and weft yarn in a single layer fabric:

紗線I:具有35cN/dtex之韌性的商業上可取得之纖維Dyneema® SK62(440dtex)之芯紗,由來自棉之一Nm80/2表紗(cover yarn)以每公尺3000圈螺旋形圍繞。該織物由60wt%棉及40wt% Kevlar®所組成,以該總紗組成物為基準。 Yarn I: A core yarn of commercially available fiber Dyneema® SK62 (440 dtex) with a toughness of 35 cN/dtex, surrounded by a Nm80/2 cover yarn from cotton, with a spiral of 3000 turns per meter. . The fabric consisted of 60 wt% cotton and 40 wt% Kevlar® based on the total yarn composition.

紗線II:100%紡棉紗(OENe6/1 Nm10/1) Yarn II: 100% spun cotton yarn (OENe6/1 Nm10/1)

紗線III:具有Nm17/l之支數的來自37wt% Dyneema® SK75短纖維及63wt%耐隆6短纖維之紡紗 Yarn III: Spinning from 37 wt% Dyneema® SK75 staple fiber and 63 wt% Nylon 6 staple fiber with a count of Nm17/l

紗線IV:來自100% Dyneema® SK75短纖維,支數Nm17/1之紡紗 Yarn IV: Spinning from 100% Dyneema® SK75 staple fiber, count Nm17/1

紗線V:紗II及紗IV的交替緯向插入 Yarn V: alternating weft insertion of yarn II and yarn IV

單層梭織物使用雙編織束技術製造,提供2經紗A及B及一緯紗於一1/3斜紋排列中。於該獲得之織物中的經紗A及B及緯紗之特定種類顯示於表1中實例1-5中。 The single layer woven fabric is manufactured using a double woven bundle technique that provides 2 warp yarns A and B and a weft yarn in a 1/3 twill arrangement. The specific types of warp yarns A and B and weft yarns in the obtained fabric are shown in Examples 1-5 in Table 1.

表1:根據EN13595-2之摩擦測試結果Table 1: Results of the friction test according to EN13595-2

表1顯示相較於由比較實驗(Comp A-D)所獲得之該等織物,包含一緯紗及二經紗A及B之根據本發明之該織物(Ex.1-5)顯示高摩擦抗性。另外,觀察到該製造損失很低且根據本發明之該織物的品質很高,同時維持高等級之穿著舒適性。此等優點在使用可輕易取得之材料用於製造該等紗線時可被獲得。 Table 1 shows that the fabric (Ex. 1-5) according to the present invention comprising a weft yarn and two warp yarns A and B exhibits high friction resistance as compared to the fabrics obtained by the comparative experiment (Comp A-D). In addition, it was observed that the manufacturing loss was low and the quality of the fabric according to the present invention was high while maintaining a high level of wearing comfort. These advantages are obtained when using readily available materials for the manufacture of such yarns.

Claims (15)

一種梭織物,其包含一緯紗及最多二經紗A及B,其中該緯紗包含高性能纖維;該經紗A包含至少50wt%之天然纖維;該經紗B包含高性能纖維;及其中該織物具有包含該經紗A之外部層及包含該經紗B之內部層,且所述外部及內部層藉由該緯紗至少部分互連。 a woven fabric comprising a weft yarn and a maximum of two warp yarns A and B, wherein the weft yarn comprises high performance fibers; the warp yarn A comprises at least 50% by weight of natural fibers; the warp yarn B comprises high performance fibers; and wherein the fabric has the inclusion The outer layer of warp yarn A and the inner layer comprising the warp yarn B, and the outer and inner layers are at least partially interconnected by the weft yarn. 如請求項1之織物,其中該天然纖維係棉或羊毛。 The fabric of claim 1 wherein the natural fiber is cotton or wool. 如請求項1至2之任一項之織物,其中該經紗B包含至少1wt%高性能纖維。 The fabric of any one of claims 1 to 2, wherein the warp yarn B comprises at least 1% by weight of high performance fibers. 如請求項1至3之任一項之織物,其中該緯紗包含至少10wt%高性能纖維。 The fabric of any one of claims 1 to 3, wherein the weft yarn comprises at least 10% by weight of high performance fibers. 如請求項1至4之任一項之織物,其中經紗A進一步包含聚醯胺、聚酯、聚四氟乙烯、聚烯烴、聚乙烯醇及聚丙烯腈之合成纖維;及/或高性能纖維;及/或棉、麻、羊毛、絲、黃麻、亞麻之外的天然纖維。 The fabric of any one of claims 1 to 4, wherein the warp yarn A further comprises a synthetic fiber of polyamine, polyester, polytetrafluoroethylene, polyolefin, polyvinyl alcohol and polyacrylonitrile; and/or high performance fiber And/or natural fibers other than cotton, hemp, wool, silk, jute, and linen. 如請求項1至5之任一項之織物,其中該緯紗及該經紗B之該高性能纖維係獨立地選自於由下列所組成之群組:芳香族聚醯胺纖維、液晶聚合物纖維、聚苯並咪唑纖維、聚苯並噁唑纖維、聚芳酯纖維、高定向聚乙烯纖維及高定向聚丙烯纖維。 The fabric of any one of claims 1 to 5, wherein the high-performance fiber of the weft yarn and the warp yarn B are independently selected from the group consisting of: aromatic polyamide fibers, liquid crystal polymer fibers Polybenzimidazole fiber, polybenzoxazole fiber, polyarylate fiber, highly oriented polyethylene fiber and highly oriented polypropylene fiber. 如請求項1至6之任一項之織物,其中於該緯紗及該經紗 B中之該高性能纖維的量係至少10wt%,較佳至少30wt%,更佳至少50wt%,再更佳至少70wt%且最佳至少80wt%,其中該wt%係被包含於該緯紗及經紗B中之高性能纖維的累積重量對該緯紗及該經紗B之累積重量的比例。 The fabric of any one of claims 1 to 6, wherein the weft yarn and the warp yarn The amount of the high performance fiber in B is at least 10% by weight, preferably at least 30% by weight, more preferably at least 50% by weight, still more preferably at least 70% by weight and most preferably at least 80% by weight, wherein the wt% is included in the weft yarn and The ratio of the cumulative weight of the high performance fibers in the warp yarn B to the cumulative weight of the weft yarn and the warp yarn B. 如請求項1至7之任一項之織物,其中該經紗B係紡紗(spun yarn)。 The fabric of any one of claims 1 to 7, wherein the warp yarn B is a spun yarn. 如請求項1至8之任一項之織物,其中該緯紗係連續長纖維紗(filament yarn)。 The fabric of any one of claims 1 to 8, wherein the weft yarn is a continuous filament yarn. 如請求項1至9之任一項之織物,其中該經紗B進一步包含至少一選自於下列所組成之群組的纖維:棉、麻、羊毛、絲、黃麻、亞麻以及聚醯胺、聚四氟乙烯、聚酯、聚烯烴、聚乙烯醇及聚丙烯腈的合成纖維。 The fabric of any one of claims 1 to 9, wherein the warp yarn B further comprises at least one fiber selected from the group consisting of cotton, hemp, wool, silk, jute, flax, and polyamine, Synthetic fibers of polytetrafluoroethylene, polyester, polyolefin, polyvinyl alcohol and polyacrylonitrile. 如請求項1至10之任一項之織物,其中該緯紗進一步包含至少一選自於下列所組成之群組的纖維:棉、麻、羊毛、絲、黃麻、亞麻以及聚醯胺、聚四氟乙烯、聚酯、聚烯烴、聚乙烯醇及聚丙烯腈的合成纖維。 The fabric of any one of claims 1 to 10, wherein the weft yarn further comprises at least one fiber selected from the group consisting of cotton, hemp, wool, silk, jute, flax, and polyamide, poly Synthetic fibers of tetrafluoroethylene, polyester, polyolefin, polyvinyl alcohol and polyacrylonitrile. 如請求項1至11之任一項之織物,其中該經紗B包含UHMWPE纖維且該緯紗包含芳香族聚醯胺纖維。 The fabric of any one of claims 1 to 11, wherein the warp yarn B comprises UHMWPE fibers and the weft yarns comprise aromatic polyamide fibers. 如請求項1至12之任一項之織物,其中該經紗A實質上由棉所組成,該經紗B係一實質上由UHMWPE短纖維(staple fibers)所組成之紡紗,且該緯紗係實質上由連續UHMWPE長纖維所組成。 The fabric of any one of claims 1 to 12, wherein the warp yarn A consists essentially of cotton, the warp yarn B being a spun yarn consisting essentially of UHMWPE staple fibers, and the weft yarn is substantially It consists of continuous UHMWPE long fibers. 一種如請求項1至13之任一項之織物的用途,用於製造 衣物、內襯、運動服裝、手套、窗簾、室內裝飾織物及地板覆蓋物。 Use of a fabric according to any one of claims 1 to 13 for manufacturing Clothing, lining, sportswear, gloves, curtains, upholstery fabrics and floor coverings. 一種包含如請求項1至13之任一項之織物的產品,其中所述產品係選自於由衣物、內襯、運動服裝、手套、窗簾、室內裝飾織物及地板覆蓋物所組成之群組。 A product comprising the fabric of any one of claims 1 to 13, wherein the product is selected from the group consisting of clothing, linings, sportswear, gloves, curtains, upholstery fabrics, and floor coverings. .
TW103139054A 2013-11-12 2014-11-11 Abrasion resistant fabric TW201533285A (en)

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