TW201532791A - Three-dimensional print forming method using metallic material or ceramic material - Google Patents

Three-dimensional print forming method using metallic material or ceramic material Download PDF

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TW201532791A
TW201532791A TW103105571A TW103105571A TW201532791A TW 201532791 A TW201532791 A TW 201532791A TW 103105571 A TW103105571 A TW 103105571A TW 103105571 A TW103105571 A TW 103105571A TW 201532791 A TW201532791 A TW 201532791A
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dimensional
finished product
printing method
mixed material
ceramic
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TWI537123B (en
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Jin-Zi You
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Jin-Zi You
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Abstract

The present invention relates to a three-dimensional print forming method using metallic material or ceramic material, comprising the following steps: (S01) providing metal or ceramic powder in 100 parts by weight and adding binder in 3-25 parts by weight for mixing to form a mixed material; (S03) heating and compounding the mixed material to make it have rheological property; (S05) extrusion forming and cooling the mixed material having rheological property to make it in strip shape; (S07) using a three-dimensional printing machine to print the strip-shaped mixed material to form a three-dimensional crude product; (S09) degreasing the three-dimensional crude product to remove the binder; (S11) sintering the degreased three-dimensional crude product; and (S13) forming the final three-dimensional product. Accordingly, this invention can use metal or ceramic material for printing to form a higher-strength three-dimensional product.

Description

使用金屬材料或陶瓷材料的三維列印成型方法Three-dimensional printing method using metal material or ceramic material

本發明係有關於一種三維列印成型方法,尤指一種使用金屬材料或陶瓷材料進行列印的三維列印成型方法。The invention relates to a three-dimensional printing method, in particular to a three-dimensional printing method using a metal material or a ceramic material for printing.

習知的三維列印成型方法係使用丙烯-丁二烯-苯乙烯(Acrylonitrile Butadiene Styrene, ABS)或聚乳酸(Polylactic Acid, PLA)等塑膠材料進行列印,藉由上述的塑膠材料所列印出來的三維成品有機械強度不足或不耐磨耗…等的問題,故僅能用於打樣、開模…等時機。The conventional three-dimensional printing method uses a plastic material such as Acrylonitrile Butadiene Styrene (ABS) or Polylactic Acid (PLA) for printing, and the above-mentioned plastic material is printed. The three-dimensional finished product has problems such as insufficient mechanical strength or wear resistance, etc., so it can only be used for timing of proofing, mold opening, etc.

若使用金屬射出成型方法或陶瓷射出成型方法來製作強度較高的成品,則會有耗時且模具成本高昂的問題。When a metal injection molding method or a ceramic injection molding method is used to produce a finished product having high strength, there is a problem that it takes time and the mold cost is high.

因此,如何發明出一種三維列印成型方法,使用金屬材料或陶瓷材料進行列印,以形成強度較高的三維成品,將是本發明所欲積極揭露之處。Therefore, how to invent a three-dimensional printing method, using metal materials or ceramic materials for printing to form a three-dimensional finished product with high strength, will be actively disclosed in the present invention.

為解決上述問題,本發明之一目的在於提供一種使用金屬材料或陶瓷材料的三維列印成型方法,使用金屬材料或陶瓷材料進行列印,以形成強度較高的三維成品。In order to solve the above problems, it is an object of the present invention to provide a three-dimensional printing method using a metal material or a ceramic material, which is printed using a metal material or a ceramic material to form a three-dimensional finished product having high strength.

為達上述目的及其他目的,本發明提供一種使用金屬材料或陶瓷材料的三維列印成型方法包含以下七個步驟。To achieve the above and other objects, the present invention provides a three-dimensional printing method using a metal material or a ceramic material comprising the following seven steps.

步驟(S01)提供100重量份的金屬粉末或陶瓷粉末,並將3-25重量份的熱塑性高分子材料作為黏結劑混合至該金屬粉末或該陶瓷粉末,以形成一混合材料;步驟(S03)將該混合材料進行加熱混練處理,以使該混合材料具有流變性質;步驟(S05)將具有流變性質的該混合材料進行擠出成型及冷卻處理,以使具有流變性質的該混合材料成型為條狀的該混合材料;步驟(S07)以三維列印機將條狀的該混合材料進行列印處理,以形成一粗製三維成品;步驟(S09)將該粗製三維成品進行脫脂處理,以去除該黏結劑;步驟(S11)將經脫脂處理的該粗製三維成品進行燒結處理;及步驟(S13)形成一最終三維成品。Step (S01) providing 100 parts by weight of a metal powder or ceramic powder, and mixing 3-25 parts by weight of a thermoplastic polymer material as a binder to the metal powder or the ceramic powder to form a mixed material; Step (S03) The mixed material is subjected to a heat kneading process to impart rheological properties to the mixed material; and the step (S05) is to extrude and cool the mixed material having rheological properties to make the mixed material having rheological properties. Forming the mixed material into strips; step (S07) printing the strip of the mixed material by a three-dimensional printing machine to form a rough three-dimensional finished product; and step (S09) degreasing the crude three-dimensional finished product, To remove the binder; the step (S11) to subject the degreased rough three-dimensional finished product to sintering; and the step (S13) to form a final three-dimensional finished product.

於上述之三維列印成型方法,於步驟(S09)中,該脫脂處理為熱脫脂或溶劑脫脂。In the above three-dimensional printing method, in the step (S09), the degreasing treatment is thermal degreasing or solvent degreasing.

於上述之三維列印成型方法,於步驟(S09)與步驟(S11)之間,更包含以下步驟:(S10)將經脫脂處理的該粗製三維成品進行精度加工處理。In the above three-dimensional printing method, between the step (S09) and the step (S11), the method further comprises the following steps: (S10) performing the precision processing of the degreased three-dimensional finished product.

於上述之三維列印成型方法,於步驟 (S11)之後,更包含以下步驟:(S12)將經燒結處理的該粗製三維成品進行精度加工處理。In the above three-dimensional printing method, after the step (S11), the method further comprises the step of: (S12) subjecting the sintered three-dimensional finished product to precision processing.

於上述之三維列印成型方法,於步驟(S01)中,更將1-10重量份的塑化劑或潤滑劑混合至該金屬粉末或該陶瓷粉末;且於步驟(S09)中,該脫脂處理去除該塑化劑或潤滑劑。In the above three-dimensional printing method, in step (S01), 1-10 parts by weight of a plasticizer or lubricant is further mixed to the metal powder or the ceramic powder; and in the step (S09), the degreasing The treatment removes the plasticizer or lubricant.

於上述之三維列印成型方法,於步驟(S11)中,該燒結處理的溫度為800℃以上。In the above three-dimensional printing method, in the step (S11), the temperature of the sintering treatment is 800 ° C or higher.

於上述之三維列印成型方法,於步驟(S01)中,該黏結劑為7-15重量份。In the above three-dimensional printing method, in the step (S01), the binder is 7-15 parts by weight.

綜上所述,本發明使用金屬材料或陶瓷材料的三維列印成型方法,藉由上述步驟,能針對金屬材料或陶瓷材料進行列印,以形成強度較高的三維成品。In summary, the present invention uses a three-dimensional printing method of a metal material or a ceramic material, and by the above steps, printing can be performed on a metal material or a ceramic material to form a three-dimensional finished product having high strength.

為充分瞭解本發明之目的、特徵及功效,茲藉由下述具體之實施例,並配合所附之圖式,對本發明做一詳細說明,說明如後:In order to fully understand the objects, features and advantages of the present invention, the present invention will be described in detail by the following specific embodiments and the accompanying drawings.

請參照第1圖,其係為本發明使用金屬材料或陶瓷材料的三維列印成型方法之第一具體實施例的流程圖,共包含七個步驟。Please refer to FIG. 1 , which is a flow chart of a first embodiment of a three-dimensional printing method using a metal material or a ceramic material, which comprises seven steps.

首先,於步驟S101,提供100重量份的金屬粉末或陶瓷粉末,並將3-25重量份的黏結劑混合至該金屬粉末或該陶瓷粉末,以形成一混合材料,該黏結劑較佳為7-15重量份。舉例來說,當要製作金屬的三維成品時,將100g的金屬粉與10g的黏結劑進行混合,以形成該混合材料。其中,該金屬粉末為鐵、不鏽鋼或合金…等粉末,該陶瓷粉末為氧化鋁、氧化鋯、氧化鐵、磷酸鋰鐵、碳化矽或氮化矽…等粉末,該黏結劑為熱塑性高分子化合物(例如,樹脂、塑膠或蠟…等),且該黏結劑於常溫下較佳為固態。First, in step S101, 100 parts by weight of metal powder or ceramic powder is provided, and 3-25 parts by weight of a binder is mixed to the metal powder or the ceramic powder to form a mixed material, and the binder is preferably 7 -15 parts by weight. For example, when a three-dimensional finished product of metal is to be produced, 100 g of metal powder is mixed with 10 g of a binder to form the mixed material. Wherein, the metal powder is a powder such as iron, stainless steel or alloy, and the ceramic powder is a powder such as alumina, zirconia, iron oxide, lithium iron phosphate, tantalum carbide or tantalum nitride, etc., and the binder is a thermoplastic polymer compound. (for example, resin, plastic or wax, etc.), and the binder is preferably solid at normal temperature.

接著,於步驟S103,將該混合材料進行加熱混練處理,以使該混合材料具有流變性質,其中,該混合材料中的該金屬粉末與該黏結劑係均勻分佈。Next, in step S103, the mixed material is subjected to a heat kneading process to impart rheological properties to the mixed material, wherein the metal powder in the mixed material is uniformly distributed with the binder.

接著,於步驟S105,將具有流變性質的該混合材料進行擠出成型處理及冷卻處理,以使具有流變性質的該混合材料成型為條狀的該混合材料;其中,該條狀的該混合材料為固態。藉此,利於使用者將條狀的該混合材料進行收納與搬移。Next, in step S105, the mixed material having rheological properties is subjected to an extrusion molding treatment and a cooling treatment to form the mixed material having rheological properties into a strip-shaped mixed material; wherein the strip-shaped material The mixed material is solid. Thereby, it is advantageous for the user to store and move the strip-shaped mixed material.

接著,於步驟S107,將條狀的該混合材料輸送至一三維列印機中,以進行列印處理,從而形成一粗製三維成品。舉例來說,當使用金屬粉末時,該粗製三維成品為螺絲、螺帽、金屬盒、金屬蓋、傳動齒輪、金屬連桿或軸承…等;當使用陶瓷粉末時,該粗製三維成品為花瓶、瓷碗、杯子、義齒、人工骨骼或關節、耐酸鹼凡而、工程陶瓷導架或導輪、電池芯或耐火材…等。上述的粗製三維成品僅為舉例,並不限於此。Next, in step S107, the strip-shaped mixed material is conveyed to a three-dimensional printing machine for printing processing to form a rough three-dimensional finished product. For example, when metal powder is used, the rough three-dimensional finished product is a screw, a nut, a metal box, a metal cover, a transmission gear, a metal connecting rod or a bearing, etc.; when a ceramic powder is used, the crude three-dimensional finished product is a vase, Porcelain bowls, cups, dentures, artificial bones or joints, acid and alkali resistant, engineering ceramic guides or guide wheels, battery cells or refractory materials...etc. The above-mentioned rough three-dimensional finished product is merely an example and is not limited thereto.

接著,於步驟S109,將該粗製三維成品進行脫脂處理,以去除該黏結劑,從而使該粗製三維成品的成分僅包含金屬或陶瓷。此外,依照黏結劑的成分不同,選擇進行熱脫脂或溶劑脫脂;再者,脫脂溫度約為200-800℃,較佳為400-500℃。Next, in step S109, the crude three-dimensional finished product is degreased to remove the binder, so that the component of the crude three-dimensional finished product contains only metal or ceramic. Further, depending on the composition of the binder, thermal degreasing or solvent degreasing is selected; further, the degreasing temperature is about 200-800 ° C, preferably 400-500 ° C.

接著,於步驟S111,將經脫脂處理的該粗製三維成品進行燒結處理,若該粗製三維成品中包含金屬粉末,燒結溫度較佳約為800℃以上;若該粗製三維成品中包含陶瓷粉末,則燒結溫度較佳為1200℃以上。Next, in step S111, the degreased crude three-dimensional finished product is subjected to sintering treatment. If the crude three-dimensional finished product contains metal powder, the sintering temperature is preferably about 800 ° C or higher; if the crude three-dimensional finished product contains ceramic powder, The sintering temperature is preferably 1200 ° C or higher.

最後,於步驟S113,經燒結處理的該粗製三維成品會形成一最終三維成品。Finally, in step S113, the sintered three-dimensional finished product forms a final three-dimensional finished product.

綜上所述,本發明使用金屬材料或陶瓷材料的三維列印成型方法,藉由上述步驟,能針對金屬材料或陶瓷材料進行列印,以形成強度較高的三維成品,以應用於各個領域。In summary, the present invention uses a three-dimensional printing method of a metal material or a ceramic material, and by the above steps, can print on a metal material or a ceramic material to form a three-dimensional finished product having high strength, and is applied to various fields. .

接著,請參照第2圖,其係為本發明使用金屬材料或陶瓷材料的三維列印成型方法之第二具體實施例的流程圖。該三維列印成型方法之第二具體實施例除了包含第一具體實施例中的七個步驟之外,更包含另外兩個步驟,總共為九個步驟。Next, please refer to FIG. 2, which is a flow chart of a second embodiment of a three-dimensional printing method using a metal material or a ceramic material according to the present invention. The second embodiment of the three-dimensional printing method includes two steps in addition to the seven steps in the first embodiment, for a total of nine steps.

於步驟S109與步驟S111之間,更包含步驟S110,將經脫脂處理的該粗製三維成品進行精度加工處理,以將該粗製三維成品的毛邊修除,並整平該粗製三維成品的表面。其中,該精度加工處理可藉由切削、拋光或研磨…等方式來進行。Between step S109 and step S111, step S110 is further included, and the rough three-dimensional finished product is subjected to precision processing to trim the rough three-dimensional finished product and level the surface of the rough three-dimensional finished product. Wherein, the precision processing can be performed by cutting, polishing or grinding.

於步驟S111之後,更包含步驟S112,將經燒結處理的該粗製三維成品進行精度加工處理,以提高其精度。其中,該精度加工處理可藉由切削、拋光或研磨…等方式來進行。After step S111, step S112 is further included, and the sintered three-dimensional finished product is subjected to precision processing to improve the precision thereof. Wherein, the precision processing can be performed by cutting, polishing or grinding.

應了解到,步驟S110與步驟S112係依該粗製三維成品的狀況來決定是否實施,因此,步驟S110與步驟S112可被省略。It should be understood that step S110 and step S112 determine whether or not to implement according to the condition of the rough three-dimensional finished product, and therefore, step S110 and step S112 may be omitted.

另外,雖然圖未示,應了解到,於步驟S101,使用者依情況額外將1-10重量份的塑化劑或潤滑劑混合至該金屬粉末或該陶瓷粉末,其中,該塑化劑或該潤滑劑為固態;並且,於步驟S109時,藉由該脫脂處理,來去除該塑化劑或潤滑劑。藉此,來提高該最終三維成品的製作品質。In addition, although not shown, it should be understood that, in step S101, the user additionally adds 1-10 parts by weight of a plasticizer or lubricant to the metal powder or the ceramic powder, wherein the plasticizer or The lubricant is in a solid state; and, in step S109, the plasticizer or lubricant is removed by the degreasing treatment. Thereby, the production quality of the final three-dimensional finished product is improved.

綜上所述,本發明使用金屬材料或陶瓷材料的三維列印成型方法,藉由上述步驟,能針對金屬材料或陶瓷材料進行列印,以形成強度較高的三維成品。In summary, the present invention uses a three-dimensional printing method of a metal material or a ceramic material, and by the above steps, printing can be performed on a metal material or a ceramic material to form a three-dimensional finished product having high strength.

本發明在上文中已以較佳實施例揭露,然熟習本項技術者應理解的是,該實施例僅用於描繪本發明,而不應解讀為限制本發明之範圍。應注意的是,舉凡與該實施例等效之變化與置換,均應設為涵蓋於本發明之範疇內。因此,本發明之保護範圍當以申請專利範圍所界定者為準。The invention has been described above in terms of the preferred embodiments, and it should be understood by those skilled in the art that the present invention is not intended to limit the scope of the invention. It should be noted that variations and permutations equivalent to those of the embodiments are intended to be included within the scope of the present invention. Therefore, the scope of protection of the present invention is defined by the scope of the patent application.

S101-113‧‧‧步驟S101-113‧‧‧Steps

第1圖係為本發明使用金屬材料或陶瓷材料的三維列印成型方法之第一具體實施例的流程圖。 第2圖係為本發明使用金屬材料或陶瓷材料的三維列印成型方法之第二具體實施例的流程圖。Fig. 1 is a flow chart showing a first embodiment of a three-dimensional printing method using a metal material or a ceramic material according to the present invention. Fig. 2 is a flow chart showing a second embodiment of a three-dimensional printing method using a metal material or a ceramic material according to the present invention.

S101-S113‧‧‧步驟 S101-S113‧‧‧Steps

Claims (9)

一種使用金屬材料或陶瓷材料的三維列印成型方法,包含以下步驟: (S01)提供100重量份的金屬粉末或陶瓷粉末,並將3-25重量份的黏結劑混合至該金屬粉末或該陶瓷粉末,以形成一混合材料; (S03)將該混合材料進行加熱混練處理,以使該混合材料具有流變性質; (S05)將具有流變性質的該混合材料進行擠出成型及冷卻處理,以使具有流變性質的該混合材料成型為條狀的該混合材料; (S07)以三維列印機將條狀的該混合材料進行列印處理,以形成一粗製三維成品; (S09)將該粗製三維成品進行脫脂處理,以去除該黏結劑; (S11)將經脫脂處理的該粗製三維成品進行燒結處理;及 (S13)形成一最終三維成品。A three-dimensional printing method using a metal material or a ceramic material, comprising the steps of: (S01) providing 100 parts by weight of a metal powder or a ceramic powder, and mixing 3-25 parts by weight of a binder to the metal powder or the ceramic a powder to form a mixed material; (S03) heating and kneading the mixed material to impart rheological properties to the mixed material; (S05) extruding and cooling the mixed material having rheological properties, The mixed material having rheological properties is formed into strips of the mixed material; (S07) the strip of the mixed material is printed by a three-dimensional printer to form a rough three-dimensional finished product; (S09) The crude three-dimensional finished product is subjected to degreasing treatment to remove the bonding agent; (S11) the degreased processed three-dimensional finished product is subjected to sintering treatment; and (S13) to form a final three-dimensional finished product. 如請求項1所述之三維列印成型方法,於步驟(S09)中,該脫脂處理為熱脫脂或溶劑脫脂。The three-dimensional printing method according to claim 1, wherein in the step (S09), the degreasing treatment is thermal degreasing or solvent degreasing. 如請求項2所述之三維列印成型方法,於步驟(S09)與步驟(S11)之間,更包含以下步驟:(S10)將經脫脂處理的該粗製三維成品進行精度加工處理。The three-dimensional printing method according to claim 2, further comprising the step of: (S10) performing the precision processing of the degreased three-dimensional finished product between the step (S09) and the step (S11). 如請求項1所述之三維列印成型方法,於步驟(S09)與步驟(S11)之間,更包含以下步驟:(S10)將經脫脂處理的該粗製三維成品進行精度加工處理。The three-dimensional printing method according to claim 1, further comprising the step of: (S10) performing the precision processing of the degreased three-dimensional finished product between the step (S09) and the step (S11). 如請求項1-4中任一項所述之三維列印成型方法,於步驟 (S11)之後,更包含以下步驟:(S12)將經燒結處理的該粗製三維成品進行精度加工處理。The three-dimensional printing method according to any one of claims 1 to 4, after the step (S11), further comprising the step of: (S12) subjecting the sintered three-dimensional finished product to precision processing. 如請求項5所述之三維列印成型方法,於步驟(S01)中,更將1-10重量份的塑化劑或潤滑劑混合至該金屬粉末或該陶瓷粉末;且於步驟(S09)中,該脫脂處理去除該塑化劑或潤滑劑。The three-dimensional printing method according to claim 5, wherein in step (S01), 1-10 parts by weight of a plasticizer or lubricant is further mixed to the metal powder or the ceramic powder; and in step (S09) The degreasing treatment removes the plasticizer or lubricant. 如請求項1-4中任一項所述之三維列印成型方法,於步驟(S01)中,更將1-10重量份的塑化劑或潤滑劑混合至該金屬粉末或該陶瓷粉末;且於步驟(S09)中,該脫脂處理去除該塑化劑或潤滑劑。The three-dimensional printing method according to any one of claims 1 to 4, wherein in step (S01), 1-10 parts by weight of a plasticizer or lubricant is further mixed to the metal powder or the ceramic powder; And in the step (S09), the degreasing treatment removes the plasticizer or the lubricant. 如請求項1-4中任一項所述之三維列印成型方法,於步驟(S11)中,該燒結處理的溫度為800℃以上。The three-dimensional printing method according to any one of claims 1 to 4, wherein in the step (S11), the temperature of the sintering treatment is 800 ° C or higher. 如請求項1-4中任一項所述之三維列印成型方法,於步驟(S01)中,該黏結劑為7-15重量份。The three-dimensional printing method according to any one of claims 1 to 4, wherein in the step (S01), the binder is 7 to 15 parts by weight.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105921751A (en) * 2016-02-19 2016-09-07 珠海天威飞马打印耗材有限公司 Three-dimensional printer and printing method thereof
CN107129285A (en) * 2016-02-26 2017-09-05 加我科技股份有限公司 Ceramic powders with high intensity and the method that biscuit is made using it
TWI655982B (en) * 2018-04-18 2019-04-11 大陸商昆山卡德姆新材料科技有限公司 3D printing material, preparation method and application thereof
US11110519B2 (en) 2016-02-19 2021-09-07 Print-Rite ⋅ Unicorn Image Products Co., Ltd. Of Zhuhai Metal three-dimensional printer

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105921751A (en) * 2016-02-19 2016-09-07 珠海天威飞马打印耗材有限公司 Three-dimensional printer and printing method thereof
US11110519B2 (en) 2016-02-19 2021-09-07 Print-Rite ⋅ Unicorn Image Products Co., Ltd. Of Zhuhai Metal three-dimensional printer
CN107129285A (en) * 2016-02-26 2017-09-05 加我科技股份有限公司 Ceramic powders with high intensity and the method that biscuit is made using it
TWI655982B (en) * 2018-04-18 2019-04-11 大陸商昆山卡德姆新材料科技有限公司 3D printing material, preparation method and application thereof

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