TW201523934A - Packaging material and of LED packaging structure containing the same - Google Patents

Packaging material and of LED packaging structure containing the same Download PDF

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TW201523934A
TW201523934A TW102145886A TW102145886A TW201523934A TW 201523934 A TW201523934 A TW 201523934A TW 102145886 A TW102145886 A TW 102145886A TW 102145886 A TW102145886 A TW 102145886A TW 201523934 A TW201523934 A TW 201523934A
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Taiwan
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wavelength converting
transparent insulating
conductive material
encapsulating material
encapsulating
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TW102145886A
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Chinese (zh)
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Min-Ya Chan
Chen-Chi Ma
Sheng-Tsung Hsiao
Wei-Hao Liao
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Lextar Electronics Corp
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Priority to TW102145886A priority Critical patent/TW201523934A/en
Priority to JP2014024118A priority patent/JP2015115597A/en
Publication of TW201523934A publication Critical patent/TW201523934A/en

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Abstract

A packaging material is provided including a transparent insulating material, a wavelength-converting material and a heat conduction material. The wavelength-converting material and the heat conduction material are mixed in the transparent insulating material. The heat conduction material is connected with part of the wavelength-converting material. An LED packaging structure containing the packaging material is also provided herein.

Description

封裝材料及包含其之發光二極體的封裝結構 Packaging material and package structure including the same

本發明係關於一種封裝材料及包含其之發光二極體的封裝結構,特別是關於一種具有導熱材料的封裝材料及包含其之發光二極體的封裝結構。 The present invention relates to a package material and a package structure including the same for the light emitting diode, and more particularly to a package material having a heat conductive material and a package structure including the light emitting diode thereof.

一般發光二極體(LED)的封裝材料會摻混螢光粉,用以做為波長轉換物質。其中,以短波長的LED(例如藍光LED)做為激發光源,且以摻混於封裝材料中的螢光粉產生波長轉換,製造不同顏色的LED。舉例來說,當利用藍光LED所發出的藍光照射到螢光粉時,螢光粉會吸收藍光的能量,且轉換成波長較長的其他色光(例如紅光、黃光或綠光),以製造能發光不同色光的LED。 Generally, a light-emitting diode (LED) encapsulating material is blended with a phosphor powder for use as a wavelength converting substance. Among them, a short-wavelength LED (for example, a blue LED) is used as an excitation light source, and a phosphor powder blended in a packaging material is used to generate wavelength conversion to manufacture LEDs of different colors. For example, when blue light emitted by a blue LED is used to illuminate the phosphor, the phosphor absorbs the energy of the blue light and converts it into other wavelengths of longer wavelength (such as red, yellow, or green) to Manufacture LEDs that emit different colors of light.

然而,在上述LED的波長轉換過程中,螢光粉所吸收的激發能量並非完全轉換成其他色光的能量,而有一部分係轉換為熱能。因為一般封裝材料中的透明絕緣材的導熱係數太小(K值約0.17W/m.K),以至於散熱不易,造成LED累積過多的熱能,致使LED溫度升高。此時高溫將 可能破壞LED的封裝結構,且降低LED的可靠度。 However, in the wavelength conversion process of the above LED, the excitation energy absorbed by the phosphor powder is not completely converted into energy of other color lights, and a part is converted into heat energy. Because the thermal conductivity of the transparent insulating material in the general packaging material is too small (K value is about 0.17 W/m.K), the heat dissipation is not easy, causing the LED to accumulate excessive thermal energy, causing the LED temperature to rise. High temperature will It may damage the package structure of the LED and reduce the reliability of the LED.

因此,目前亟需一種新的封裝材料及包含其的封裝結構,以解決傳統封裝材料及包含其的封裝結構所產生的缺失。 Therefore, there is a need for a new packaging material and a package structure including the same to solve the defects caused by the conventional packaging material and the package structure including the same.

本發明係提供一種封裝材料及包含其的封裝結構,用以解決傳統封裝材料及包含其的封裝結構的缺失。藉由提升封裝材料的導熱效率,以增進發光二極體的封裝結構的可靠度。 The present invention provides an encapsulating material and a package structure therewith for solving the lack of a conventional encapsulating material and a package structure including the same. The reliability of the package structure of the light-emitting diode is improved by improving the heat conduction efficiency of the package material.

本發明之一態樣在於提供一種封裝材料。此封裝材料包含透明絕緣材、波長轉換物質及導熱材料。波長轉換物質及導熱材料係摻混於透明絕緣材內。導熱材料係與部分波長轉換物質連結。 One aspect of the present invention is to provide an encapsulating material. The encapsulating material comprises a transparent insulating material, a wavelength converting substance and a heat conducting material. The wavelength converting substance and the heat conducting material are blended in the transparent insulating material. The thermally conductive material is coupled to a portion of the wavelength converting material.

根據本發明之一實施例,上述透明絕緣材包含一透明的熱塑性或熱固性樹脂。 According to an embodiment of the invention, the transparent insulating material comprises a transparent thermoplastic or thermosetting resin.

根據本發明之一實施例,上述波長轉換物質是選自由螢光粉、染料、色素及其組合所構成之族群。 According to an embodiment of the invention, the wavelength converting substance is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof.

根據本發明之一實施例,上述導熱材料的導熱係數為不小於1.5W/(m.K)。 According to an embodiment of the present invention, the heat conductive material has a thermal conductivity of not less than 1.5 W/(m.K).

根據本發明之一實施例,上述導熱材料係呈絲狀、片狀或其組合。 According to an embodiment of the invention, the thermally conductive material is in the form of a filament, a sheet or a combination thereof.

根據本發明之一實施例,上述導熱材料包含金屬、非金屬、陶瓷材料或其組合。 According to an embodiment of the invention, the thermally conductive material comprises a metal, a non-metal, a ceramic material or a combination thereof.

根據本發明之一實施例,上述金屬包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。 According to an embodiment of the invention, the metal comprises silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc (Zn), nickel (Ni), iron (Fe) , tin (Sn), lead (Pb), titanium (Ti) or a combination thereof.

根據本發明之一實施例,上述非金屬包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。 According to an embodiment of the invention, the non-metal comprises graphite, graphene, carbon nanotube, diamond.

根據本發明之一實施例,上述波長轉換物質與導熱材料之間,包含至少一交互作用力,令使部分波長轉換物質與導熱材料彼此連結。其中,交互作用力係為凡得瓦爾力(van der Waal force)、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 According to an embodiment of the invention, the wavelength conversion substance and the heat conductive material comprise at least one interaction force, so that a part of the wavelength conversion substance and the heat conductive material are connected to each other. The interaction force is van der Waal force, π-π force, polar force, metal coordination covalent bond or a combination thereof.

本發明之一態樣在於提供一種發光二極體的封裝結構。此發光二極體的封裝結構包含至少一發光二極體晶片及上述封裝材料。封裝材料係覆蓋於發光二極體晶片上。 One aspect of the present invention provides a package structure for a light emitting diode. The package structure of the light emitting diode comprises at least one light emitting diode chip and the above packaging material. The encapsulating material is overlaid on the LED substrate.

本發明之一態樣在於提供一種封裝材料。此封裝材料包含透明絕緣材、波長轉換物質、第一導熱材料及第二導熱材料。波長轉換物質、第一導熱材料及第二導熱材料係摻混於透明絕緣材內。第一導熱材料係與部分波長轉換物質連結。第二導熱材料係與部分波長轉換物質及部分第一導熱材料連結。 One aspect of the present invention is to provide an encapsulating material. The encapsulating material comprises a transparent insulating material, a wavelength converting substance, a first heat conducting material and a second heat conducting material. The wavelength converting substance, the first heat conductive material and the second heat conductive material are blended in the transparent insulating material. The first thermally conductive material is coupled to a portion of the wavelength converting material. The second thermally conductive material is coupled to a portion of the wavelength converting material and a portion of the first thermally conductive material.

根據本發明之一實施例,上述透明絕緣材包含一透明的熱塑性或熱固性樹脂。 According to an embodiment of the invention, the transparent insulating material comprises a transparent thermoplastic or thermosetting resin.

根據本發明之一實施例,上述波長轉換物質是選自螢光粉、染料、色素及其組合所構成之族群。 According to an embodiment of the invention, the wavelength converting substance is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof.

根據本發明之一實施例,上述第一、第二導熱材料的導熱係數為不小於1.5W/(m.K)。 According to an embodiment of the invention, the first and second heat conductive materials have a thermal conductivity of not less than 1.5 W/(m.K).

根據本發明之一實施例,上述第一、第二導熱材料係呈絲狀、片狀或其組合。 According to an embodiment of the invention, the first and second heat conducting materials are in the form of a filament, a sheet or a combination thereof.

根據本發明之一實施例,上述第一、第二導熱材料包含金屬、非金屬、陶瓷材料或其組合。 According to an embodiment of the invention, the first and second thermally conductive materials comprise a metal, a non-metal, a ceramic material or a combination thereof.

根據本發明之一實施例,上述金屬包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。 According to an embodiment of the invention, the metal comprises silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc (Zn), nickel (Ni), iron (Fe) , tin (Sn), lead (Pb), titanium (Ti) or a combination thereof.

根據本發明之一實施例,上述非金屬包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。 According to an embodiment of the invention, the non-metal comprises graphite, graphene, carbon nanotube, diamond.

根據本發明之一實施例,上述波長轉換物質與第一、第二導熱材料之間,以及第一導熱材料與第二導熱材料之間,分別包含至少一交互作用力,令使部分波長轉換物質與第一、第二導熱材料及第一導熱材料與第二導熱材料彼此連結。其中,交互作用力係為凡得瓦爾力(van der Waal force)、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 According to an embodiment of the invention, the wavelength conversion substance and the first and second heat conductive materials, and the first heat conductive material and the second heat conductive material respectively comprise at least one interaction force, so that a part of the wavelength conversion substance And the first and second heat conductive materials and the first heat conductive material and the second heat conductive material are coupled to each other. The interaction force is van der Waal force, π-π force, polar force, metal coordination covalent bond or a combination thereof.

本發明之一態樣在於提供一種發光二極體的封裝結構。此發光二極體的封裝結構包含至少一發光二極體晶片及上述封裝材料。封裝材料係覆蓋於發光二極體晶片上。 One aspect of the present invention provides a package structure for a light emitting diode. The package structure of the light emitting diode comprises at least one light emitting diode chip and the above packaging material. The encapsulating material is overlaid on the LED substrate.

100、200、300、420、520、620‧‧‧封裝材料 100, 200, 300, 420, 520, 620‧ ‧ encapsulation materials

110、210、310‧‧‧透明絕緣材 110, 210, 310‧‧‧ Transparent insulation

120、220、320‧‧‧波長轉換物質 120, 220, 320‧‧‧ wavelength conversion substances

130、230‧‧‧導熱材料 130, 230‧‧‧ Thermal materials

330a‧‧‧第一導熱材料 330a‧‧‧First thermal conductive material

330b‧‧‧第二導熱材料 330b‧‧‧Second thermal material

400、500、600‧‧‧封裝結構 400, 500, 600‧‧‧ package structure

410、510、610‧‧‧發光二極體晶片 410, 510, 610‧‧‧Light Emitting Diode Wafers

430、530、630‧‧‧膠杯 430, 530, 630‧‧ ‧ plastic cups

431、531、631‧‧‧固晶區 431, 531, 631‧‧‧ Gujing District

第1~3圖係根據本發明之一實施例所繪示的封裝材料示意圖;以及第4~6圖係根據本發明之一實施例所繪示的發光二極體的封裝結構示意圖。 1 to 3 are schematic views of a package material according to an embodiment of the present invention; and FIGS. 4 to 6 are schematic diagrams showing a package structure of a light emitting diode according to an embodiment of the present invention.

接著以實施例並配合圖式以詳細說明本發明,在圖式或描述中,相似或相同的部分係使用相同之符號或編號。在圖式中,實施例之形狀或厚度可能擴大,以簡化或方便標示,而圖式中元件之部分將以文字描述之。可瞭解的是,未繪示或未描述之元件可為熟習該項技藝者所知之各種樣式。 The invention will be described in detail by way of example and with reference to the accompanying drawings In the drawings, the shape or thickness of the embodiments may be expanded to simplify or facilitate the labeling, and the parts of the elements in the drawings will be described in the text. It will be appreciated that elements not shown or described may be in a variety of styles known to those skilled in the art.

本文所使用之術語僅是用於描述特定實施例之目的且不意欲限制本發明。如本文所使用,單數形式"一"(a、an)及"該"(the)意欲亦包括複數形式,除非本文另有清楚地指示。應進一步瞭解,當在本說明書中使用時,術語"包含"(comprises及/或comprising)指定存在所述之特徵、整數、步驟、運作、元件及/或組份,但並不排除存在或添加一或多個其它特徵、整數、步驟、運作、元件、組份及/或其群組。本文參照為本發明之理想化實施例(及中間結構)之示意性說明的橫截面說明來描述本發明之實施例。如此,吾人將預期偏離該等說明之形狀之由於(例如)製造技術及/或容差的改變。因此,不應將本發明之實施例理解為限於本文所說明之特定區域形狀,而將包括起因於(例如)製造之形狀 改變,且該等圖中所說明之區域本質上為示意性的,且其形狀不意欲說明設備之區域的實際形狀且不意欲限制本發明之範疇。 The terminology used herein is for the purpose of describing particular embodiments and is not intended to The singular forms "a", "the", "the" and "the" It is to be understood that the term "comprises" and / or "comprising" when used in the specification is intended to mean the presence of the described features, integers, steps, operations, components and/or components, but does not exclude the presence or addition. One or more other features, integers, steps, operations, components, components, and/or groups thereof. Embodiments of the present invention are described herein with reference to cross-section illustrations of the schematic illustration of the preferred embodiments (and intermediate structures) of the invention. As such, it is contemplated that the shapes of the descriptions may be varied, for example, from variations in manufacturing techniques and/or tolerances. Therefore, embodiments of the invention should not be construed as limited to the particular shapes of the embodiments described herein, but will include the The regions described in the figures are illustrative in nature and are not intended to limit the actual shape of the region of the device and are not intended to limit the scope of the invention.

第1圖係根據本發明之一實施例所繪示的封裝材料100示意圖。在第1圖中,封裝材料100包含透明絕緣材110、波長轉換物質120及導熱材料130。 1 is a schematic view of a package material 100 in accordance with an embodiment of the present invention. In FIG. 1 , the encapsulating material 100 includes a transparent insulating material 110 , a wavelength converting substance 120 , and a heat conductive material 130 .

波長轉換物質120係摻混於透明絕緣材110內,且透明絕緣材110包含透明的熱塑性或熱固性樹脂。根據本發明之一實施例,波長轉換物質120係選自由螢光粉、染料、色素及其組合所構成之群組。 The wavelength converting substance 120 is blended in the transparent insulating material 110, and the transparent insulating material 110 contains a transparent thermoplastic or thermosetting resin. In accordance with an embodiment of the invention, the wavelength converting material 120 is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof.

導熱材料130係摻混於透明絕緣材110內,且與部分波長轉換物質120連結。在此實施例中,導熱材料130係呈絲狀,且為一金屬絲。根據本發明之實施例,金屬包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。根據本發明之一實施例,導熱材料130的導熱係數為不小於1.5W/(m.K)。在此實施例中,導熱材料130係為奈米銀絲,其導熱係數為約430W/(m.K)。 The heat conductive material 130 is blended in the transparent insulating material 110 and is coupled to the partial wavelength converting substance 120. In this embodiment, the thermally conductive material 130 is filamentary and is a wire. According to an embodiment of the invention, the metal comprises silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc (Zn), nickel (Ni), iron (Fe), tin (Sn), lead (Pb), titanium (Ti) or a combination thereof. According to an embodiment of the invention, the thermal conductivity of the thermally conductive material 130 is not less than 1.5 W/(m.K). In this embodiment, the thermally conductive material 130 is a nanosilver wire having a thermal conductivity of about 430 W/(m.K).

在此實施例中,波長轉換物質120與導熱材料130之間具有至少一交互作用力,令使波長轉換物質120與導熱材料130彼此連結。其中,交互作用力係為凡得瓦爾力(van der Waal force)、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 In this embodiment, the wavelength converting substance 120 and the heat conductive material 130 have at least one interaction force to connect the wavelength converting substance 120 and the heat conductive material 130 to each other. The interaction force is van der Waal force, π-π force, polar force, metal coordination covalent bond or a combination thereof.

第2圖係根據本發明之一實施例所繪示的封裝材 料200示意圖。在第2圖中,封裝材料200包含透明絕緣材210、波長轉換物質220及導熱材料230。 2 is a package material according to an embodiment of the invention Schematic of material 200. In FIG. 2, the encapsulating material 200 includes a transparent insulating material 210, a wavelength converting substance 220, and a heat conductive material 230.

波長轉換物質220係摻混於透明絕緣材210內,且透明絕緣材210包含透明的熱塑性或熱固性樹脂。根據本發明之一實施例,波長轉換物質220係選自由螢光粉、染料、色素及其組合所構成之群組。 The wavelength converting substance 220 is blended in the transparent insulating material 210, and the transparent insulating material 210 contains a transparent thermoplastic or thermosetting resin. In accordance with an embodiment of the invention, the wavelength converting material 220 is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof.

導熱材料230係摻混於透明絕緣材210內,且與部分波長轉換物質220連結。在此實施例中,導熱材料230係呈片狀,且為一非金屬。根據本發明之實施例,非金屬包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。根據本發明之一實施例,導熱材料230的導熱係數為不小於1.5W/(m.K)。在此實施例中,導熱材料230係為石墨烯,其導熱係數為約5,300W/(m.K)。 The heat conductive material 230 is blended in the transparent insulating material 210 and is coupled to the partial wavelength converting material 220. In this embodiment, the thermally conductive material 230 is in the form of a sheet and is a non-metal. According to an embodiment of the invention, the non-metal comprises graphite, graphene, carbon nanotubes, diamonds. According to an embodiment of the invention, the thermal conductivity of the thermally conductive material 230 is not less than 1.5 W/(m.K). In this embodiment, the thermally conductive material 230 is graphene having a thermal conductivity of about 5,300 W/(m.K).

在此實施例中,波長轉換物質220與導熱材料230之間具有至少一交互作用力,令使波長轉換物質220與導熱材料230彼此連結。其中,交互作用力係為凡得瓦爾力、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 In this embodiment, the wavelength converting substance 220 and the heat conductive material 230 have at least one interaction force to connect the wavelength converting substance 220 and the heat conductive material 230 to each other. Among them, the interaction force is van der Waals force, π-π force, polar force, metal coordination covalent bond or a combination thereof.

第3圖係根據本發明之一實施例所繪示的封裝材料300示意圖。在第3圖中,封裝材料300包含透明絕緣材310、波長轉換物質320、第一導熱材料330a及第二導熱材料330b。 3 is a schematic view of a package material 300 in accordance with an embodiment of the present invention. In FIG. 3, the encapsulating material 300 includes a transparent insulating material 310, a wavelength converting substance 320, a first heat conductive material 330a, and a second heat conductive material 330b.

波長轉換物質320係摻混於透明絕緣材310內,且透明絕緣材310包含透明的熱塑性或熱固性樹脂。根據本 發明之一實施例,波長轉換物質320係選自由螢光粉、染料、色素及其組合所構成之群組。 The wavelength converting substance 320 is blended in the transparent insulating material 310, and the transparent insulating material 310 contains a transparent thermoplastic or thermosetting resin. According to this In one embodiment of the invention, the wavelength converting substance 320 is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof.

第一導熱材料330a及第二導熱材料330b係摻混於透明絕緣材310內,且第一導熱材料330a及第二導熱材料330b係與部分波長轉換物質320連結。其中,部份第一導熱材料330a及部份第二導熱材料330b係彼此互相連結。在此實施例中,第一導熱材料330a係呈絲狀,且為一金屬絲,包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。第二導熱材料330b係呈片狀,且為一非金屬,包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。根據本發明之一實施例,第一、第二導熱材料330a及330b的導熱係數為不小於1.5W/(m.K)。在此實施例中,第一導熱材料330a係為奈米銀絲,其導熱係數為約430W/(m.K),且第二導熱材料330b係為石墨烯,其導熱係數為約5,300W/(m.K)。在本發明之一實施例中,導熱材料亦可為導熱性良好的陶瓷材料。 The first heat conductive material 330a and the second heat conductive material 330b are blended in the transparent insulating material 310, and the first heat conductive material 330a and the second heat conductive material 330b are coupled to the partial wavelength converting material 320. The first heat conductive material 330a and the part of the second heat conductive material 330b are connected to each other. In this embodiment, the first heat conductive material 330a is filamentary and is a metal wire containing silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc ( Zn), nickel (Ni), iron (Fe), tin (Sn), lead (Pb), titanium (Ti) or a combination thereof. The second heat conductive material 330b is in the form of a sheet and is a non-metal, and includes graphite, graphene, carbon nanotubes, and diamonds. According to an embodiment of the invention, the first and second heat conductive materials 330a and 330b have a thermal conductivity of not less than 1.5 W/(m.K). In this embodiment, the first heat conductive material 330a is a nano silver wire having a thermal conductivity of about 430 W/(m.K), and the second heat conductive material 330b is graphene having a thermal conductivity of about 5,300 W/ (m.K). In an embodiment of the invention, the thermally conductive material may also be a ceramic material having good thermal conductivity.

在此實施例中,波長轉換物質320與第一、第二導熱材料330a及330b之間具有至少一交互作用力,令使波長轉換物質320與第一、第二導熱材料330a及330b彼此連結。其中,交互作用力係為凡得瓦爾力、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 In this embodiment, the wavelength converting substance 320 and the first and second heat conducting materials 330a and 330b have at least one interaction force to connect the wavelength converting substance 320 and the first and second heat conducting materials 330a and 330b to each other. Among them, the interaction force is van der Waals force, π-π force, polar force, metal coordination covalent bond or a combination thereof.

第4圖係根據本發明之一實施例所繪示的發光二極體的封裝結構400示意圖。在第4圖中,封裝結構400 包含至少一發光二極體晶片410及封裝材料420。 FIG. 4 is a schematic diagram of a package structure 400 of a light emitting diode according to an embodiment of the invention. In FIG. 4, the package structure 400 At least one light emitting diode wafer 410 and an encapsulating material 420 are included.

在此實施例中,封裝材料420係覆蓋於發光二極體晶片410上。封裝材料420包含透明絕緣材、波長轉換物質及導熱材料。 In this embodiment, the encapsulation material 420 is overlaid on the LED substrate 410. The encapsulation material 420 comprises a transparent insulating material, a wavelength converting substance, and a thermally conductive material.

波長轉換物質係摻混於透明絕緣材內。導熱材料係摻混於透明絕緣材內,且與部分波長轉換物質連結。在此實施例中,導熱材料係為奈米銀絲。波長轉換物質與導熱材料之間具有至少一交互作用力,令使波長轉換物質與導熱材料彼此連結。 The wavelength converting material is incorporated in a transparent insulating material. The thermally conductive material is incorporated into the transparent insulating material and is coupled to a portion of the wavelength converting material. In this embodiment, the thermally conductive material is a nanosilver. The at least one interaction between the wavelength converting substance and the thermally conductive material causes the wavelength converting substance and the thermally conductive material to be coupled to each other.

當發光二極體晶片410發出短波長的激發光時,此激發光會被波長轉換物質吸收且放出波長較長的放射光。在此同時,藉由連接於波長轉換物質的導熱材料可導出波長轉換物質所產生的熱能,以增加封裝材料420的導熱效率,且提升發光二極體的封裝結構400的可靠度。 When the light-emitting diode wafer 410 emits excitation light of a short wavelength, the excitation light is absorbed by the wavelength conversion substance and emits radiation of a longer wavelength. At the same time, the thermal energy generated by the wavelength converting substance can be derived by the thermally conductive material connected to the wavelength converting substance to increase the heat transfer efficiency of the encapsulating material 420 and improve the reliability of the package structure 400 of the light emitting diode.

在第4圖中,封裝結構400更包含一膠杯430,在膠杯430內具有一固晶區431。發光二極體晶片410係設置於固晶區431上,且封裝材料420係填充於膠杯430內並覆蓋發光二極體晶片410。 In FIG. 4, the package structure 400 further includes a glue cup 430 having a die bond region 431 therein. The LED wafer 410 is disposed on the die bonding region 431, and the encapsulation material 420 is filled in the plastic cup 430 and covers the LED wafer 410.

第5圖係根據本發明之一實施例所繪示的發光二極體的封裝結構500示意圖。在第5圖中,封裝結構500包含至少一發光二極體晶片510及封裝材料520。 FIG. 5 is a schematic diagram of a package structure 500 of a light emitting diode according to an embodiment of the invention. In FIG. 5, the package structure 500 includes at least one light emitting diode wafer 510 and an encapsulation material 520.

在此實施例中,封裝材料520係覆蓋於發光二極體晶片510上。封裝材料520包含透明絕緣材、波長轉換物質及導熱材料。 In this embodiment, the encapsulation material 520 is overlaid on the LED 510. The encapsulating material 520 includes a transparent insulating material, a wavelength converting substance, and a heat conductive material.

波長轉換物質係摻混於透明絕緣材內。導熱材料係摻混於透明絕緣材內,且與部分波長轉換物質連結。在此實施例中,導熱材料係為石墨烯。波長轉換物質與導熱材料之間具有至少一交互作用力,令使波長轉換物質與導熱材料彼此連結。 The wavelength converting material is incorporated in a transparent insulating material. The thermally conductive material is incorporated into the transparent insulating material and is coupled to a portion of the wavelength converting material. In this embodiment, the thermally conductive material is graphene. The at least one interaction between the wavelength converting substance and the thermally conductive material causes the wavelength converting substance and the thermally conductive material to be coupled to each other.

當發光二極體晶片510發出短波長的激發光時,此激發光會被波長轉換物質吸收且放出波長較長的放射光。在此同時,藉由連接於波長轉換物質的導熱材料可導出波長轉換物質所產生的熱能,以增加封裝材料520的導熱效率,且提升發光二極體的封裝結構500的可靠度。 When the light-emitting diode wafer 510 emits excitation light of a short wavelength, the excitation light is absorbed by the wavelength conversion substance and emits radiation of a longer wavelength. At the same time, the thermal energy generated by the wavelength converting substance can be derived by the thermally conductive material connected to the wavelength converting substance to increase the heat transfer efficiency of the encapsulating material 520 and improve the reliability of the package structure 500 of the light emitting diode.

在第5圖中,封裝結構500更包含一膠杯530,在膠杯530內具有一固晶區531。發光二極體晶片510係設置於固晶區531上,且封裝材料520係填充於膠杯530內並覆蓋發光二極體晶片510。 In FIG. 5, the package structure 500 further includes a plastic cup 530 having a die bond region 531 therein. The LED chip 510 is disposed on the die bonding region 531, and the encapsulation material 520 is filled in the plastic cup 530 and covers the LED chip 510.

第6圖係根據本發明之一實施例所繪示的發光二極體的封裝結構600示意圖。在第6圖中,封裝結構600包含至少一發光二極體晶片610及封裝材料620。 FIG. 6 is a schematic diagram of a package structure 600 of a light emitting diode according to an embodiment of the invention. In FIG. 6 , the package structure 600 includes at least one LED wafer 610 and an encapsulation material 620 .

在此實施例中,封裝材料620係覆蓋於發光二極體晶片610上。封裝材料620包含透明絕緣材、波長轉換物質、第一導熱材料及第二導熱材料。 In this embodiment, the encapsulation material 620 is overlaid on the LED substrate 610. The encapsulation material 620 includes a transparent insulating material, a wavelength converting substance, a first heat conductive material, and a second heat conductive material.

波長轉換物質係摻混於透明絕緣材內。第一、第二導熱材料係摻混於透明絕緣材內,且與部分波長轉換物質連結。在此實施例中,第一導熱材料係為奈米銀絲,而第二導熱物質係為石墨烯。波長轉換物質與第一、第二導熱 材料及之間具有至少一交互作用力,令使波長轉換物質與第一、第二導熱材料彼此連結。 The wavelength converting material is incorporated in a transparent insulating material. The first and second heat conductive materials are blended in the transparent insulating material and are coupled to a portion of the wavelength converting substance. In this embodiment, the first thermally conductive material is nanowire and the second thermally conductive material is graphene. Wavelength converting substance and first and second heat conduction The material and the at least one interaction force between the wavelength conversion material and the first and second heat conductive materials are coupled to each other.

當發光二極體晶片610發出短波長的激發光時,此激發光會被波長轉換物質吸收且放出波長較長的放射光。在此同時,藉由連接於波長轉換物質的第一、第二導熱材料可導出波長轉換物質所產生的熱能,以增加封裝材料620的導熱效率,且提升發光二極體的封裝結構600的可靠度。 When the light-emitting diode wafer 610 emits excitation light of a short wavelength, the excitation light is absorbed by the wavelength conversion substance and emits radiation of a longer wavelength. At the same time, the thermal energy generated by the wavelength converting substance can be derived by the first and second heat conducting materials connected to the wavelength converting substance to increase the heat conduction efficiency of the package material 620 and improve the reliability of the package structure 600 of the light emitting diode. degree.

在第6圖中,封裝結構600更包含一膠杯630,在膠杯630內具有一固晶區631。發光二極體晶片610係設置於固晶區631上,且封裝材料620係填充於膠杯630內並覆蓋發光二極體晶片610。 In FIG. 6, the package structure 600 further includes a plastic cup 630 having a die bonding region 631 therein. The LED chip 610 is disposed on the die bonding region 631, and the encapsulation material 620 is filled in the plastic cup 630 and covers the LED chip 610.

上述第3~6圖僅為表示本發明運用於PLCC(Plastic Leaded Chip Carrier)封裝型式而包含了膠杯,但本發明並不以此為限,於其他實施例中,本發明可運用於含有波長轉換物質及透明絕緣材的各種封裝型式,例如COB(Chip on board)或Emitter等。 The above 3rd to 6th drawings only show that the present invention is applied to a PLCC (Plastic Leaded Chip Carrier) package type and includes a rubber cup, but the present invention is not limited thereto. In other embodiments, the present invention can be applied to contain Various types of packages of wavelength converting materials and transparent insulating materials, such as COB (Chip on board) or Emitter.

雖然本發明之實施例已揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可做些許之更動與潤飾,因此本發明之保護範圍當以後附之申請專利範圍所界定為準。 Although the embodiments of the present invention have been disclosed as above, it is not intended to limit the present invention, and any person skilled in the art can make some modifications and retouchings without departing from the spirit and scope of the present invention. The scope is defined as defined in the scope of the patent application.

100‧‧‧封裝材料 100‧‧‧Packaging materials

110‧‧‧透明絕緣材 110‧‧‧Transparent insulation

120‧‧‧波長轉換物質 120‧‧‧ wavelength conversion substances

130‧‧‧導熱材料 130‧‧‧thermal materials

Claims (20)

一種封裝材料,包含:一透明絕緣材;一波長轉換物質,摻混於該透明絕緣材內;以及一導熱材料,摻混於該透明絕緣材內,且與部分該波長轉換物質連結。 An encapsulating material comprising: a transparent insulating material; a wavelength converting substance blended in the transparent insulating material; and a heat conductive material blended in the transparent insulating material and coupled to a portion of the wavelength converting substance. 如請求項1所述之封裝材料,其中該透明絕緣材包含一透明的熱塑性或熱固性樹脂。 The encapsulating material of claim 1, wherein the transparent insulating material comprises a transparent thermoplastic or thermosetting resin. 如請求項2所述之封裝材料,其中該波長轉換物質是選自由螢光粉、染料、色素及其組合所構成之族群。 The encapsulating material of claim 2, wherein the wavelength converting substance is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof. 如請求項3項所述之封裝材料,其中該導熱材料的導熱係數為不小於1.5W/(m.K)。 The encapsulating material according to claim 3, wherein the thermal conductive material has a thermal conductivity of not less than 1.5 W/(m.K). 如請求項4所述之封裝材料,其中該導熱材料係呈絲狀、片狀或其組合。 The encapsulating material of claim 4, wherein the thermally conductive material is in the form of a filament, a sheet, or a combination thereof. 如請求項5所述之封裝材料,其中該導熱材料包含金屬、非金屬、陶瓷材料或其組合。 The encapsulating material of claim 5, wherein the thermally conductive material comprises a metal, a non-metal, a ceramic material, or a combination thereof. 如請求項6所述之封裝材料,其中該金屬包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。 The encapsulating material according to claim 6, wherein the metal comprises silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc (Zn), nickel (Ni), iron (Fe), tin (Sn), lead (Pb), titanium (Ti) or a combination thereof. 如請求項6所述之封裝材料,其中該非金屬包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。 The encapsulating material of claim 6, wherein the non-metal comprises graphite, graphene, carbon nanotube, diamond. 如請求項1所述之封裝材料,其中該波長轉換物質與該導熱材料之間,包含至少一交互作用力,令使部分該波長轉換物質與該導熱材料彼此連結,且該交互作用力係為凡得瓦爾力(van der Waal force)、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 The encapsulating material according to claim 1, wherein the wavelength converting substance and the thermally conductive material comprise at least one interaction force, so that a part of the wavelength converting substance and the heat conducting material are connected to each other, and the interaction force is Van der Waal force, π-π force, polar force, metal coordination covalent bond, or a combination thereof. 一種發光二極體的封裝結構,包含:至少一發光二極體晶片;以及一如請求項1至9任一項所述之封裝材料,覆蓋於該發光二極體晶片上。 A package structure for a light-emitting diode, comprising: at least one light-emitting diode wafer; and a package material according to any one of claims 1 to 9, covering the light-emitting diode wafer. 一種封裝材料,包含:一透明絕緣材;一波長轉換物質,摻混於該透明絕緣材內;一第一導熱材料,摻混於該透明絕緣材內,且與部分該波長轉換物質連結;以及一第二導熱材料,摻混於該透明絕緣材內,且與部分該波長轉換物質及部分該第一導熱材料連結。 An encapsulating material comprising: a transparent insulating material; a wavelength converting substance blended in the transparent insulating material; a first heat conducting material blended in the transparent insulating material and coupled to a portion of the wavelength converting substance; A second heat conductive material is blended in the transparent insulating material and is coupled to a portion of the wavelength converting material and a portion of the first heat conducting material. 如請求項11所述之封裝材料,其中該透明絕緣材包含一透明的熱塑性或熱固性樹脂。 The encapsulating material of claim 11, wherein the transparent insulating material comprises a transparent thermoplastic or thermosetting resin. 如請求項12所述之封裝材料,其中該波長轉換物質是選自螢光粉、染料、色素及其組合所構成之族群。 The encapsulating material of claim 12, wherein the wavelength converting material is selected from the group consisting of phosphors, dyes, pigments, and combinations thereof. 如請求項13項所述之封裝材料,其中該第一、第二導熱材料的導熱係數為不小於1.5W/(m.K)。 The encapsulating material according to claim 13 , wherein the first and second thermally conductive materials have a thermal conductivity of not less than 1.5 W/(m.K). 如請求項14所述之封裝材料,其中該第一、第二導熱材料係呈絲狀、片狀或其組合。 The encapsulating material of claim 14, wherein the first and second thermally conductive materials are in the form of a filament, a sheet, or a combination thereof. 如請求項15所述之封裝材料,其中該第一、第二導熱材料包含金屬、非金屬、陶瓷材料或其組合。 The encapsulating material of claim 15, wherein the first and second thermally conductive materials comprise a metal, a non-metal, a ceramic material, or a combination thereof. 如請求項16所述之封裝材料,其中該金屬包含銀(Ag)、銅(Cu)、鋁(Al)、鎢(W)、鎂(Mg)、鋅(Zn)、鎳(Ni)、鐵(Fe)、錫(Sn)、鉛(Pb)、鈦(Ti)或其組合。 The encapsulating material according to claim 16, wherein the metal comprises silver (Ag), copper (Cu), aluminum (Al), tungsten (W), magnesium (Mg), zinc (Zn), nickel (Ni), iron (Fe), tin (Sn), lead (Pb), titanium (Ti) or a combination thereof. 如請求項16所述之封裝材料,其中該非金屬包含石墨(graphite)、石墨烯(graphene)、奈米碳管(carbon nanotube)、鑽石(diamond)。 The encapsulating material of claim 16, wherein the non-metal comprises graphite, graphene, carbon nanotubes, diamonds. 如請求項11所述之封裝材料,其中該波長轉換物質與該第一、第二導熱材料之間,以及該第一導熱材料與該第二導熱材料之間,分別包含至少一交互作用力,令使部分該波長轉換物質與該第一導熱材料及該第一導熱材料與該第二導熱材料彼此連結,且該交互作用力係為凡得瓦爾力(van der Waal force)、π-π作用力、極性作用力、金屬配位共價鍵結或其組合。 The encapsulating material according to claim 11, wherein the wavelength conversion substance and the first and second heat conductive materials, and the first heat conductive material and the second heat conductive material respectively comprise at least one interaction force, Having a portion of the wavelength converting material and the first heat conductive material and the first heat conductive material and the second heat conductive material are coupled to each other, and the interaction force is Van der Valli (van) Der Waal force), π-π force, polar force, metal coordination covalent bond or a combination thereof. 一種發光二極體的封裝結構,包含:至少一發光二極體晶片;以及一如請求項11至19任一項所述之封裝材料,覆蓋於該發光二極體晶片上。 A package structure of a light-emitting diode, comprising: at least one light-emitting diode wafer; and a packaging material according to any one of claims 11 to 19, covering the light-emitting diode wafer.
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