TW201519791A - Emulsified oil composition - Google Patents

Emulsified oil composition Download PDF

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Publication number
TW201519791A
TW201519791A TW103107649A TW103107649A TW201519791A TW 201519791 A TW201519791 A TW 201519791A TW 103107649 A TW103107649 A TW 103107649A TW 103107649 A TW103107649 A TW 103107649A TW 201519791 A TW201519791 A TW 201519791A
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Taiwan
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fatty acid
mass
oil
fat
emulsified
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TW103107649A
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Chinese (zh)
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Masataka Andou
Sachiko Murakami
Yuto Nakazawa
Tae Sugiyama
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Nisshin Oillio Group Ltd
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Publication of TW201519791A publication Critical patent/TW201519791A/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0053Compositions other than spreads
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • A21D2/165Triglycerides

Abstract

The problem addressed by the present invention is to provide: an emulsified oil composition that obtains high foaming power and foam stability and can impart to confectionary/bread a conventionally nonexistent soft sensation and moist sensation; and confectionary/bread that uses the emulsified oil composition and can favorably maintain the soft sensation and moist sensation even if put in chilled storage or if frozen/defrosted. The emulsified oil composition contains the below mentioned (A), (B), (C), and (D): (A) is 10-40 mass% of a dietary oil containing a triacylglycerol containing a fatty acid having 6-10 carbon atoms as a constituent fatty acid; (B) is 2-20 mass% of a monoacylglycerol having a saturated fatty acid as a constituent fatty acid; (C) is 2-20 mass% of at least one type of emulsifier selected from among a propylene glycol fatty acid ester, a sucrose fatty acid ester, a sorbothane fatty acid ester, and a polyglycerol fatty acid ester; and (D) is 10-50 mass% of water.

Description

乳化油脂組成物 Emulsified oil composition

本發明有關一種乳化油脂組成物,該乳化油脂組成物使用於製造點心及麵包,尤其適合用來製造蛋糕。 The present invention relates to an emulsified oil and fat composition for use in the manufacture of snacks and breads, and is particularly suitable for use in the manufacture of cakes.

在大量生產海綿蛋糕(sponge cake)、戚風蛋糕(chiffon cake)、蒸蛋糕(steamed cake)等蛋糕類時,會採用將所有原料一次混合之所謂的一次加料法(all-in method),並且基於提升蛋糕麵糊的發泡性和賦予油脂帶來的溼潤口感的目的等,而使用具有發泡性的乳化油脂組成物。乳化油脂組成物,其除了含有飽和脂肪酸之單酸甘油酯(monoacylglycerol),也含有丙二醇脂肪酸酯(propylene glycol fatty acid ester)、蔗糖脂肪酸酯(sucrose fatty acid ester)、去水山梨醇脂肪酸酯(sorbitan fatty acid ester)、聚甘油脂肪酸酯(polyglycerol fatty acid esters,PGEF)等乳化劑,在製造蛋糕時,賦予蛋糕麵糊優異的發泡性、乳化性、分散性及烘焙時的氣泡安定性。 In the mass production of cakes such as sponge cakes, chiffon cakes, steamed cakes, etc., a so-called all-in method in which all the raw materials are mixed at once is used, and An emulsified fat or oil composition having a foaming property is used for the purpose of improving the foaming property of the cake batter and imparting a moist mouthfeel to the fat or the like. An emulsified oil and fat composition containing propylene glycol fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid, in addition to monoacylglycerol containing a saturated fatty acid An emulsifier such as sorbitan fatty acid ester or polyglycerol fatty acid esters (PGEF), which imparts excellent foaming properties, emulsifying properties, dispersibility, and bubble stability during baking when baking a cake. Sex.

一般來說,乳化油脂組成物,為了帶出蛋糕類的柔軟和溼潤口感等,會使用即使在冷藏下也呈現液態的沙拉油作為基底的油脂。但是,像現在將蛋糕類作冷藏或冷凍保存時,即使是使用了較多油脂的蛋糕類,仍會喪失柔軟和溼潤 口感等,而成為很大的問題。 In general, in order to bring out the soft and moist texture of the cake, the emulsified fat or oil composition uses a vegetable oil which is liquid as a base even under refrigeration. However, when cakes are now refrigerated or frozen, even cakes that use more oil will lose their softness and moisture. The taste, etc., becomes a big problem.

推測其原因主要是由於澱粉質老化所導致,因此,一般而言會進行乳化劑增量。但是,若為使用乳化油脂組成物所製造的蛋糕類的情況,因為其已使用較多的乳化劑量,所以會強烈帶出乳化劑的不佳風味,因此,要增加乳化劑的量較為困難。又,例如:專利文獻1中記述一種方法,其將A.卵磷脂(lecithin)及/或植物性蛋白水解物與B.三氯庶糖併用;專利文獻2中記述一種方法,其使用醚化或酯化之小粒子澱粉;但是,此等方法的效果皆不足。 It is speculated that the cause is mainly due to aging of starch, and therefore, emulsifier increment is generally performed. However, in the case of a cake manufactured using the emulsified oil-fat composition, since a large amount of emulsifier is used, the odor of the emulsifier is strongly brought out, and therefore it is difficult to increase the amount of the emulsifier. Further, for example, Patent Document 1 describes a method in which A. lecithin and/or a vegetable protein hydrolysate is used in combination with B. trichloropyrene; and Patent Document 2 describes a method in which etherification or Esterified small particle starch; however, the effects of these methods are insufficient.

[先前技術文獻] [Previous Technical Literature] (專利文獻) (Patent Literature)

專利文獻1:日本特開2003-219819號公報 Patent Document 1: Japanese Laid-Open Patent Publication No. 2003-219819

專利文獻2:日本特開2006-129789號公報 Patent Document 2: Japanese Laid-Open Patent Publication No. 2006-129789

因此,本發明的問題在於提供一種乳化油脂組成物及一種點心麵包,該乳化油脂組成物除了可獲得高發泡力和高氣泡安定性等,同時可賦予點心麵包以往所沒有的柔軟和溼潤口感等;該點心麵包是使用該乳化油脂組成物而成,即使將其冷藏或冷凍解凍,仍可良好地維持柔軟和溼潤口感等。 Therefore, the problem of the present invention is to provide an emulsified fat or oil composition and a snack bread which can impart a high foaming power and a high bubble stability, and can impart a soft and moist taste to the snack bread. The confectionery bread is obtained by using the emulsified oil and fat composition, and even if it is refrigerated or frozen and thawed, the soft and moist mouthfeel can be favorably maintained.

本發明人為了解決上述問題而專心進行研究,著眼於構成乳化油脂組成物之油脂的三酸甘油酯(triacylglycerol) 的構成,結果發現,藉由使用含有三酸甘油酯之食用油脂來作為油脂,該三酸甘油酯包含碳數6~10的脂肪酸來作為構成脂肪酸,除了仍可獲得具有高發泡力和高氣泡安定性等的乳化油脂組成物,同時可獲得具有以往所沒有的柔軟口感及溼潤口感之蛋糕,進而完成本發明。 The present inventors focused on the above problems in order to solve the above problems, and focused on triacylglycerol which constitutes the oil of the emulsified fat composition. As a result, it was found that by using an edible fat or oil containing triglyceride as a fat or oil, the triglyceride contains a fatty acid having 6 to 10 carbon atoms as a constituent fatty acid, in addition to high foaming power and high air bubbles. The present invention can be completed by obtaining an emulsified oil-and-fat composition such as stability and a cake having a soft mouthfeel and a moist mouthfeel which have not been conventionally obtained.

亦即,本發明的一態樣是一種乳化油脂組成物,其含有以下的成分(A)、(B)、(C)及(D):(A)食用油脂10~40質量%,其含有包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯;(B)單酸甘油酯2~20質量%,其以飽和脂肪酸作為構成脂肪酸;(C)乳化劑2~20質量%,其是選自丙二醇脂肪酸酯、蔗糖脂肪酸酯、去水山梨醇脂肪酸酯、及聚甘油脂肪酸酯中的1種以上;(D)水10~50質量%。 That is, an aspect of the present invention is an emulsified fat or oil composition comprising the following components (A), (B), (C) and (D): (A) edible fats and oils 10 to 40% by mass, which contain a fatty acid having 6 to 10 carbon atoms as a triglyceride constituting a fatty acid; (B) 2 to 20% by mass of a monoglyceride, a saturated fatty acid as a constituent fatty acid; and (C) an emulsifier 2 to 20% by mass. It is one or more selected from the group consisting of a propylene glycol fatty acid ester, a sucrose fatty acid ester, a sorbitan fatty acid ester, and a polyglycerol fatty acid ester; (D) water is 10-50 mass %.

作為一較佳態樣,是一種乳化油脂組成物,其中,前述(A)食用油脂是含有三酸甘油酯10~90質量%之食用油脂,該三酸甘油酯包含碳數6~10的脂肪酸作為構成脂肪酸。 In a preferred embodiment, the emulsified fat or oil composition is the edible fat or oil containing 10 to 90% by mass of triglyceride, and the triglyceride comprises a fatty acid having 6 to 10 carbon atoms. As a constituent fatty acid.

作為一較佳態樣,是一種乳化油脂組成物,其中,前述(A)食用油脂含有M2L型三酸甘油酯與ML2型三酸甘油酯,合計10~80質量%。 In a preferred embodiment, the edible fat and oil composition comprises the M2L-type triglyceride and the ML2-type triglyceride in a total amount of 10 to 80% by mass.

(其中,M表示碳數6~10的脂肪酸,L表示碳數16以上的脂肪酸) (wherein M represents a fatty acid having 6 to 10 carbon atoms, and L represents a fatty acid having 16 or more carbon atoms)

本發明的一態樣,是一種點心麵包,其使用上述乳化油 脂組成物所製造而成。 One aspect of the present invention is a snack bread using the above emulsified oil Made from a lipid composition.

本發明的一態樣,是一種點心麵包的製造方法,該方法是將麵糊進行加熱,該麵糊是使用上述乳化油脂組成物,並且藉由一次加料法所配製而成。 One aspect of the present invention is a method for producing a snack bread which is obtained by heating a batter which is prepared by using a emulsified oil composition as described above and by a single addition method.

藉由本發明,可獲得一種乳化油脂組成物,其具有高發泡能力和高氣泡安定性等,且可賦予點心麵包以往所沒有的柔軟和溼潤口感等;又,可提供一種點心麵包,藉由使用該乳化油脂組成物,即使將該點心麵包進行冷藏或冷凍解凍,仍可良好地維持柔軟和溼潤口感等。 According to the present invention, it is possible to obtain an emulsified fat or oil composition which has high foaming ability, high bubble stability, and the like, and can impart a soft and moist mouthfeel which has not been conventionally obtained in a snack bread; and a snack bread can be provided by using In the emulsified fat or oil composition, even if the confectionery bread is refrigerated or frozen and thawed, the soft and moist texture and the like can be favorably maintained.

以下,關於本發明,進行更詳細的說明。 Hereinafter, the present invention will be described in more detail.

本發明的實施形態的乳化油脂組成物,是一種水包油型(oil-in-water)乳化之油脂組成物,其含有:(A)食用油脂;(B)單酸甘油酯,其以飽和脂肪酸作為構成脂肪酸;(C)乳化劑,其是選自丙二醇脂肪酸酯、蔗糖脂肪酸酯、去水山梨醇脂肪酸酯、及聚甘油脂肪酸酯中的1種以上;及,(D)水。 The emulsified fat or oil composition according to the embodiment of the present invention is an oil-in-water emulsified fat or oil composition comprising: (A) edible fat; (B) monoglyceride, which is saturated (C) an emulsifier which is one or more selected from the group consisting of a propylene glycol fatty acid ester, a sucrose fatty acid ester, a sorbitan fatty acid ester, and a polyglycerin fatty acid ester; and (D) water.

本發明的實施形態的乳化油脂組成物所使用之(A)食用油脂(以下,有時簡稱成分(A)),其含有:包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯(以下,有時簡稱MTAG)。此處,包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯,是指至少有1個碳數6~10的脂肪酸以酯鍵結於三酸甘油酯的甘油骨架上之三酸甘油酯。碳數6~10的脂肪酸,較佳是直鏈的飽和脂肪酸。更具體而言,較佳是選自 己酸、辛酸、癸酸中的1種以上,更佳是選自辛酸、癸酸中的1種以上。 (A) Edible fat or oil (hereinafter, abbreviated as component (A)) used in the emulsified oil-fat composition of the embodiment of the present invention, which contains a fatty acid having 6 to 10 carbon atoms as a triglyceride constituting a fatty acid ( Hereinafter, sometimes referred to as MTAG). Here, the fatty acid having 6 to 10 carbon atoms as the triglyceride constituting the fatty acid means a triglyceride having at least one fatty acid having 6 to 10 carbon atoms bonded to the glycerol skeleton of the triglyceride. ester. The fatty acid having 6 to 10 carbon atoms is preferably a linear saturated fatty acid. More specifically, it is preferably selected from the group consisting of One or more of hexanoic acid, octanoic acid, and citric acid are more preferably one or more selected from the group consisting of octanoic acid and citric acid.

本發明的實施形態的乳化油脂組成物中,(A)食用油脂的含量是10~40質量%,較佳是10~35質量%,更佳是10~30質量%。(A)食用油脂中,包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯(MTAG)的含量,較佳是10~90質量%,更佳是20~80質量%,進而更佳是30~70質量%。又,食用油脂(A),作為MTAG的一部分或全部,較佳是含有M2L型三酸甘油酯(以下,有時簡稱M2L)與ML2型三酸甘油酯(以下,有時簡稱ML2)合計10~80質量%,更佳是含有20~70質量%,進而更佳是含有20~65質量%。又,M2L與ML2的質量比,較佳是在1:1~1:20之範圍內,更佳是在1:2~1:20之範圍內,進而更佳是在1:2~1:10之範圍內。此處,M是代表碳數6~10的脂肪酸,L則是代表碳數16以上的脂肪酸。亦即,M2L是由2個M及1個L作為脂肪酸殘基來鍵結之三酸甘油酯,並且各脂肪酸殘基在甘油骨架上的鍵結位置未特別限制。同樣地,ML2是由1個M及2個L作為脂肪酸殘基來鍵結之三酸甘油酯,並且各脂肪酸殘基在甘油骨架上的鍵結位置未特別限制。L較佳是碳數16~22的脂肪酸,更佳是16~18的脂肪酸。又,L較佳是L中的不飽和脂肪酸含量是60~100質量%,更佳是70~100質量%,進而更佳是80~100質量%。本發明的實施形態的乳化油脂組成物中的成分(A)的含量、及成分(A)中的MTAG的含量,若在上述範圍內,則可賦予使用乳化油脂組成物之點心麵包產品柔軟和溼 潤口感等,因此較佳。 In the emulsified fat or oil composition of the embodiment of the present invention, the content of the edible fat or oil (A) is 10 to 40% by mass, preferably 10 to 35% by mass, more preferably 10 to 30% by mass. (A) The edible fat or oil contains a fatty acid having 6 to 10 carbon atoms as a triglyceride (MTAG) constituting the fatty acid, preferably 10 to 90% by mass, more preferably 20 to 80% by mass, and still more preferably It is 30 to 70% by mass. In addition, the edible fat or oil (A) is preferably a part or all of MTAG, and preferably contains M2L-type triglyceride (hereinafter, abbreviated as M2L) and ML2-type triglyceride (hereinafter, abbreviated as ML2). ~80% by mass, more preferably 20 to 70% by mass, and even more preferably 20 to 65% by mass. Moreover, the mass ratio of M2L to ML2 is preferably in the range of 1:1 to 1:20, more preferably in the range of 1:2 to 1:20, and more preferably in the range of 1:2 to 1: Within the scope of 10. Here, M is a fatty acid having a carbon number of 6 to 10, and L is a fatty acid having a carbon number of 16 or more. That is, M2L is a triglyceride in which two M and one L are bonded as a fatty acid residue, and the bonding position of each fatty acid residue on the glycerin skeleton is not particularly limited. Similarly, ML2 is a triglyceride in which one M and two L are bonded as a fatty acid residue, and the bonding position of each fatty acid residue on the glycerin skeleton is not particularly limited. L is preferably a fatty acid having 16 to 22 carbon atoms, more preferably a fatty acid having 16 to 18 carbon atoms. Further, L is preferably such that the unsaturated fatty acid content in L is 60 to 100% by mass, more preferably 70 to 100% by mass, still more preferably 80 to 100% by mass. When the content of the component (A) and the content of the MTAG in the component (A) in the emulsified fat or oil composition of the embodiment of the present invention are within the above range, the softness of the confectionery product using the emulsified fat or oil composition can be imparted. wet It is better to moisturize and the like.

本發明的實施形態的乳化油脂組成物所使用之(A)食用油脂,只要能將構成食用油脂之三酸甘油酯依上述條件來調整其組成,則藉由任何方法調整皆可,但較佳是在配製包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯(MTAG)後,視需要而將構成脂肪酸的90質量%以上為碳數16以上的脂肪酸之油脂(以下,有時簡稱LCT)進行混合,藉此,調整三酸甘油酯之組成。 The (A) edible fat or oil used in the emulsified fat or oil composition according to the embodiment of the present invention may be adjusted by any method as long as the triglyceride constituting the edible fat or oil can be adjusted according to the above conditions, but preferably In the case of preparing a fatty acid having a carbon number of 6 to 10 as a triglyceride (MTAG) constituting a fatty acid, 90% by mass or more of the fatty acid constituting the fatty acid having a carbon number of 16 or more (hereinafter sometimes referred to as a short name) LCT) is mixed, whereby the composition of the triglyceride is adjusted.

作為成分(A)所包含的MTAG的一較佳態樣,可列舉(A-1)中鏈脂肪酸三酸甘油酯(以下,有時簡稱MCT)。中鏈脂肪酸三酸甘油酯,依照已知的方法,可由碳數6~10的脂肪酸和甘油來合成,亦可使用市售品(例如,商品名:ODO,The Nisshin OilliO Group,Ltd.製造)。可藉由將MCT照原樣地混合、或與構成脂肪酸的90質量%以上為碳數16以上的脂肪酸之油脂(LCT)混合來調整成分(A)。LCT只要是構成脂肪酸的90質量%以上為碳數16以上的脂肪酸之油脂,並未特別限制,具體而言,可列舉:大豆油、菜籽油、棕櫚油、玉米油、葵花籽油、紅花油、芝麻油、棉籽油、米油、橄欖油、花生油、亞麻仁油、可可脂、娑羅樹油脂(sal butter)、牛油樹油脂(shea butter)、牛脂、豬脂、魚油等;及該等的複數混合油、該等個別之油或複數混合油的氫化油、酯交換油、分餾油等加工油。LCT中,構成LCT的脂肪酸中的不飽和脂肪酸含量較佳是60~100質量%,更佳是70~100質量%,進而更佳是80~100質量%。成分(A)中的MCT含量較佳是10~100 質量%,更佳是10~50質量%,進而更佳是10~40質量%。 A preferred embodiment of the MTAG contained in the component (A) is (A-1) a medium chain fatty acid triglyceride (hereinafter sometimes abbreviated as MCT). The medium chain fatty acid triglyceride can be synthesized from a fatty acid having 6 to 10 carbon atoms and glycerin according to a known method, and a commercially available product (for example, trade name: ODO, manufactured by The Nisshin Oilli O Group, Ltd.) can also be used. . The component (A) can be adjusted by mixing the MCT as it is, or by mixing with 90% by mass or more of the fatty acid (LCT) of a fatty acid having a carbon number of 16 or more. The LCT is not particularly limited as long as it is 90% by mass or more of a fatty acid constituting a fatty acid having a carbon number of 16 or more, and specific examples thereof include soybean oil, rapeseed oil, palm oil, corn oil, sunflower oil, and safflower. Oil, sesame oil, cottonseed oil, rice oil, olive oil, peanut oil, linseed oil, cocoa butter, sal butter, shea butter, tallow, pig fat, fish oil, etc.; The plurality of mixed oils, the processing oils such as hydrogenated oils, transesterified oils, and fractionated oils of the individual oils or the plurality of mixed oils. In the LCT, the content of the unsaturated fatty acid in the fatty acid constituting the LCT is preferably 60 to 100% by mass, more preferably 70 to 100% by mass, still more preferably 80 to 100% by mass. The MCT content in the component (A) is preferably from 10 to 100. The mass % is more preferably 10 to 50% by mass, and even more preferably 10 to 40% by mass.

作為成分(A)所包含的MTAG的一較佳態樣,可列舉(A-2)上述中鏈脂肪酸三酸甘油酯(MCT)與油脂(LCT)之混合油的酯交換油(以下,有時簡稱MLCT),該油脂(LCT)的構成脂肪酸的90質量%以上為碳數16以上的脂肪酸。酯交換之MCT與LCT之混合油的混合比(質量比),較佳是3:97~90:10,更佳是7:93~50:50,進而更佳是10:90~30:70。可藉由將MLCT照原樣地混合、或與LCT混合來調整成分(A)。成分(A)中的MLCT含量較佳是20~100質量%,更佳是50~100質量%,進而更佳是70~100質量%。酯交換的方法,並無特別限制,可藉由一般方法進行,也可以藉由下列其中一種方法來進行:使用甲醇鈉(sodium methoxide)等合成催化劑之化學酯交換、以脂肪酶(lipase)作為催化劑之酵素酯交換。 As a preferred aspect of the MTAG contained in the component (A), (A-2) a transesterified oil of a mixed oil of the above-mentioned medium chain fatty acid triglyceride (MCT) and fat (LCT) (hereinafter, In the case of MLCT), 90% by mass or more of the constituent fatty acids of the oil and fat (LCT) are fatty acids having 16 or more carbon atoms. The mixing ratio (mass ratio) of the transesterified MCT and LCT mixed oil is preferably 3:97 to 90:10, more preferably 7:93 to 50:50, and even more preferably 10:90 to 30:70. . The component (A) can be adjusted by mixing the MLCT as it is or by mixing with the LCT. The MLCT content in the component (A) is preferably from 20 to 100% by mass, more preferably from 50 to 100% by mass, still more preferably from 70 to 100% by mass. The method of transesterification is not particularly limited and may be carried out by a general method or by one of the following methods: chemical transesterification using a synthetic catalyst such as sodium methoxide, and lipase as a lipase Catalyst ester exchange.

化學酯交換,例如可依下述方式進行:使原料油脂充分乾燥,並且將相對於原料油脂為0.1~1質量%之甲醇鈉添加至原料油脂中後,在減壓下,在80~120℃一面進行攪拌一面進行反應0.5~1小時。酵素酯交換,例如可依下述方式進行:將相對於原料油脂為0.02~10質量%(較佳是0.04~5質量%)之脂肪酶製劑亦即脂肪酶粉末或固化脂肪酶(immobilized lipase),添加至原料油脂中後,在40~80℃(較佳是在40~70℃)一面進行攪拌一面進行反應0.5~48小時(較佳是0.5~24小時)。 Chemical transesterification can be carried out, for example, by sufficiently drying the raw material fats and oils, and adding sodium methoxide of 0.1 to 1% by mass based on the raw material fats and oils to the raw material fats and oils, and then under reduced pressure at 80 to 120 ° C. The reaction was carried out for 0.5 to 1 hour while stirring. The transesterification of the enzyme can be carried out, for example, in the following manner: a lipase preparation which is 0.02 to 10% by mass (preferably 0.04 to 5% by mass) based on the raw material fat or oil, that is, a lipase powder or an immobilized lipase. After adding to the raw material fats and oils, the reaction is carried out for 0.5 to 48 hours (preferably 0.5 to 24 hours) while stirring at 40 to 80 ° C (preferably 40 to 70 ° C).

如上所述,成分(A),只要成分(A)中含有包含碳數6~10的脂肪酸之三酸甘油酯,下述成分可個別使用,亦可混 合使用:上述(A-1)中鏈脂肪酸三酸甘油酯(MCT);(A-2)中鏈脂肪酸三酸甘油酯(MCT)與油脂(LCT)之混合油之酯交換油(MLCT),該油脂(LCT)的構成脂肪酸的90質量%以上為碳數16以上的脂肪酸。又,亦可視需要而將上述(A-1)、(A-2)的油脂與LCT混合配製。 As described above, the component (A) may be used alone or in combination as long as the component (A) contains a triglyceride containing a fatty acid having 6 to 10 carbon atoms. Use: (A-1) medium chain fatty acid triglyceride (MCT); (A-2) medium chain fatty acid triglyceride (MCT) and oil (LCT) mixed oil ester exchange oil (MLCT) 90% by mass or more of the constituent fatty acids of the oil and fat (LCT) are fatty acids having 16 or more carbon atoms. Further, the fats and oils of the above (A-1) and (A-2) may be mixed with LCT as needed.

本發明的實施形態的乳化油脂組成物,其含有2~20質量%之(B)單酸甘油酯(以下,有時簡稱成分(B)),該成分(B)是以飽和脂肪酸作為構成脂肪酸。成分(B)的含量,較佳是3~12質量%,更佳是4~10質量%,進而更佳是5~8質量%。又,雖然上述飽和脂肪酸並無特別限制,但是較佳是碳數14~22之飽和脂肪酸,更佳是碳數16~18之飽和脂肪酸,亦即棕櫚酸(palmitic acid)、硬脂酸(stearic acid)。成分(B)可由鍵結1種飽和脂肪酸之單酸甘油酯所構成,亦可由鍵結2種以上飽和脂肪酸之單酸甘油酯所構成。本發明的實施形態的乳化油脂組成物所使用之成分(B),若其為上述含量及構成飽和脂肪酸,則可藉由使用該乳化油脂組成物,作出有份量之點心麵包,因此較佳。 The emulsified fat or oil composition according to the embodiment of the present invention contains 2 to 20% by mass of (B) monoglyceride (hereinafter sometimes referred to as component (B)), and the component (B) is a saturated fatty acid as a constituent fatty acid. . The content of the component (B) is preferably from 3 to 12% by mass, more preferably from 4 to 10% by mass, still more preferably from 5 to 8% by mass. Further, although the above saturated fatty acid is not particularly limited, it is preferably a saturated fatty acid having 14 to 22 carbon atoms, more preferably a saturated fatty acid having 16 to 18 carbon atoms, that is, palmitic acid or stearic acid. Acid). The component (B) may be composed of a monoglyceride in which one type of saturated fatty acid is bonded, or may be composed of a monoglyceride in which two or more kinds of saturated fatty acids are bonded. In the component (B) used in the emulsified oil-fat composition of the embodiment of the present invention, if it is the above-mentioned content and constitutes a saturated fatty acid, it is preferable to use the emulsified oil-fat composition to obtain a portion of the snack bread.

本發明的實施形態的乳化油脂組成物,其含有2~20質量%之(C)乳化劑(以下,有時簡稱成分(C)),該成分(C)是選自丙二醇脂肪酸酯、蔗糖脂肪酸酯、去水山梨醇脂肪酸酯、及聚甘油脂肪酸酯中的1種以上。成分(C)的含量,較佳是3~15質量%,更佳是4~12質量%,進而更佳是5~10質量%。又,成分(C)中,HLB值為2~8之乳化劑的含量,較佳是2~15質量%,更佳是3~10質量%,進而更佳是4~8質 量%。又,成分(C)中,HLB值為9~20之乳化劑的含量,較佳是1~10質量%,更佳是2~8質量%,進而更佳是3~7質量%。構成成分(C)乳化劑的脂肪酸並無特別限制,可列舉:月桂酸(lauric acid)、肉荳蔻酸(myristic acid)、棕櫚酸、硬脂酸、二十二酸(behenic acid)、油酸(oleic acid)、芥子酸(erucic acid)等。本發明的實施形態的乳化油脂組成物所使用之成分(C),若為上述含量,則可藉由使用該乳化油脂組成物,作出有份量之點心麵包,因此較佳。 The emulsified fat or oil composition according to the embodiment of the present invention contains 2 to 20% by mass of (C) an emulsifier (hereinafter sometimes referred to as a component (C)), and the component (C) is selected from a propylene glycol fatty acid ester and sucrose. One or more of a fatty acid ester, a sorbitan fatty acid ester, and a polyglycerin fatty acid ester. The content of the component (C) is preferably from 3 to 15% by mass, more preferably from 4 to 12% by mass, still more preferably from 5 to 10% by mass. Further, in the component (C), the content of the emulsifier having an HLB value of 2 to 8 is preferably 2 to 15% by mass, more preferably 3 to 10% by mass, and still more preferably 4 to 8 mass%. the amount%. Further, in the component (C), the content of the emulsifier having an HLB value of from 9 to 20 is preferably from 1 to 10% by mass, more preferably from 2 to 8% by mass, still more preferably from 3 to 7% by mass. The fatty acid constituting the component (C) emulsifier is not particularly limited, and examples thereof include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, and oleic acid. (oleic acid), erucic acid, etc. When the component (C) used in the emulsified oil-fat composition of the embodiment of the present invention has the above content, it is preferable to use the emulsified oil-fat composition to obtain a portion of the snack bread.

本發明的實施形態的乳化油脂組成物,其含有10~50質量%之(D)水。水(以下,有時稱為成分(D)),其只要可飲用,並無特別限制,可使用自來水、礦泉水、去離子水、蒸餾水等。本發明的實施形態的乳化油脂組成物中的水的含量,較佳是15~45質量%,更佳是20~40質量%。若水的含量在上述範圍內,則乳化較穩定,而且保存性較好,因此較佳。再者,本發明的實施形態的乳化油脂組成物中之水的含量,是指水的調配量,並未考量後述之副原料等所含的水分。也就是說,並非將所調配的水的量及副原料等所含的水分合計而得的含量。 The emulsified fat or oil composition according to the embodiment of the present invention contains 10 to 50% by mass of (D) water. Water (hereinafter sometimes referred to as component (D)) is not particularly limited as long as it is drinkable, and tap water, mineral water, deionized water, distilled water or the like can be used. The content of water in the emulsified oil and fat composition of the embodiment of the present invention is preferably 15 to 45% by mass, and more preferably 20 to 40% by mass. If the content of water is within the above range, the emulsification is relatively stable and the preservability is good, which is preferable. In addition, the content of the water in the emulsified oil and fat composition of the embodiment of the present invention means the amount of water to be blended, and the moisture contained in the by-product or the like described later is not considered. In other words, the amount of water to be blended and the amount of water contained in the auxiliary materials and the like are not obtained.

本發明的實施形態的乳化油脂組成物,只要在不損及本發明之功效的範圍內,其亦可包含上述以外之其他乳化劑。作為其他乳化劑,可列舉:卵磷脂、有機酸單甘油酯(organic acid monoglycerides)、聚山梨糖醇酯(polysorbate)等。其他乳化劑的含量,較佳是0.05~5質量%,更佳是0.1~3質量%,進而更佳是0.3~2質量%。作為其他乳化劑,較 佳是卵磷脂。卵磷脂,其較佳是使用選自粗製卵磷脂、精製卵磷脂、酵素分解卵磷脂等中的1種以上。 The emulsified oil and fat composition of the embodiment of the present invention may contain other emulsifiers other than the above, as long as the effects of the present invention are not impaired. Examples of the other emulsifier include lecithin, organic acid monoglycerides, and polysorbate. The content of the other emulsifier is preferably 0.05 to 5% by mass, more preferably 0.1 to 3% by mass, still more preferably 0.3 to 2% by mass. As other emulsifiers, Good is lecithin. The lecithin is preferably one or more selected from the group consisting of crude lecithin, purified lecithin, and enzyme-decomposed lecithin.

本發明的實施形態的乳化油脂組成物,在不損及本發明之功效的範圍內,除了上述各種成分以外,亦可包含一般使用於乳化油脂組成物之副原料。作為副原料,可列舉例如:醇類、醣類、增稠多醣類(thickening polysaccharides)、澱粉類、無機鹽、有機鹽、乳製品、蛋製品、香料、食用色素、調味料、抗氧化劑(antioxidant)、防腐劑、pH調整劑等。 The emulsified fat or oil composition of the embodiment of the present invention may contain, in addition to the above various components, an auxiliary raw material generally used for the emulsified fat or oil composition, within a range not impairing the effects of the present invention. Examples of the auxiliary material include alcohols, sugars, thickening polysaccharides, starches, inorganic salts, organic salts, dairy products, egg products, flavors, food colorings, seasonings, and antioxidants. Antioxidant, preservative, pH adjuster, etc.

作為上述醇類,可列舉例如:乙醇(ethanol)、丙二醇(propylene glycol)、洋酒等。作為上述醣類,可列舉例如:細白糖(蔗糖)、葡萄糖、果糖、乳糖、液糖(liquid sugar)、水飴、酵素糖化水飴等醣;及將醣進行還原處理而成之山梨醇(sorbitol)、還原澱粉醣化物等糖醇。作為上述增稠多醣類,可列舉例如:三仙膠(xanthan gum)、結蘭膠(gellan gum)、關華豆膠(guar gum)、纖維素(cellulose)、羧甲基織維素(carboxymethyl cellulose,CMC)。作為上述澱粉類,可列舉例如:玉米澱粉(corn starch)、樹薯澱粉(tapioca starch)等澱粉、及對澱粉施加下述處理之化工澱粉。酵素處理、預糊化處理(pregelatinization)、分解處理、醚化處理(etherification)、酯化處理(esterification)、交聯處理、接枝化處理(grafting)等。作為上述無機鹽,可列舉例如:氯化鈉(sodium chloride)、碳酸氫鈉(sodium bicarbonate)等;作為上述有機鹽,可列舉例如:脂肪酸、脂肪酸納、檸檬酸(citric acid)、檸檬酸鈉(sodium citrate)等。作為上述乳製品,可列舉例如:全脂奶粉、脫脂 奶粉、乳清粉(whey powder)等。作為上述蛋製品,可列舉例如:全蛋、蛋黃、蛋白、及將該等進行下述處理之蛋製品。冷凍、乾燥、加糖、加鹽、殺菌、酵素處理等。副原料,亦可將選自此等中的1種或2種以上組合使用。 Examples of the alcohols include ethanol, propylene glycol, and wine. Examples of the saccharide include sugars such as fine white sugar (sucrose), glucose, fructose, lactose, liquid sugar, leeches, and enzyme saccharified mash; and sorbitol obtained by reducing sugar. And reducing sugar alcohols such as starch saccharides. Examples of the above-mentioned thickening polysaccharides include xanthan gum, gellan gum, guar gum, cellulose, and carboxymethyl avermectin ( Carboxymethyl cellulose, CMC). Examples of the starch include starch such as corn starch and tapioca starch, and chemical starch which is subjected to the following treatment with starch. Enzyme treatment, pregelatinization, decomposition treatment, etherification, esterification, cross-linking treatment, grafting, and the like. Examples of the inorganic salt include sodium chloride and sodium bicarbonate; and examples of the organic salt include fatty acid, sodium fatty acid, citric acid, and sodium citrate. (sodium citrate) and so on. Examples of the above dairy product include whole milk powder and degreasing. Milk powder, whey powder, etc. Examples of the egg product include whole eggs, egg yolks, proteins, and egg products subjected to the following treatments. Freezing, drying, sugaring, salting, sterilization, enzyme treatment, etc. One or a combination of two or more selected from the above may be used in combination.

本發明的實施形態的乳化油脂組成物中,上述副原料的含量,在乳化油脂組成物中,較佳是60質量%以下,更佳是50質量%以下。作為各個成分,在乳化油脂組成物中,例如,醇類較佳是1~8質量%,醣類較佳是20~40質量%,增稠多醣類較佳是0.02~0.5質量%,乳製品較佳是0.5~5質量%。若副原料的含量在上述範圍內,則較易於配製乳化油脂組成物,並且乳化較穩定,因此較佳。 In the emulsified oil and fat composition of the embodiment of the present invention, the content of the above-mentioned auxiliary material is preferably 60% by mass or less, and more preferably 50% by mass or less in the emulsified fat or oil composition. As the respective components, in the emulsified oil and fat composition, for example, the alcohol is preferably 1 to 8% by mass, the saccharide is preferably 20 to 40% by mass, and the thickening polysaccharide is preferably 0.02 to 0.5% by mass. The product is preferably from 0.5 to 5% by mass. When the content of the auxiliary raw material is within the above range, it is easier to prepare the emulsified oil and fat composition, and the emulsification is relatively stable, which is preferable.

本發明的實施形態的乳化油脂組成物,可藉由將油相及水相混合乳化的一般方法進行製造。例如,視需要而將水溶性乳化劑、增稠多醣類、醣類、乳製品、醇類等添加至水中,一面攪拌一面升溫,而配製水相部分。同時,將以飽和脂肪酸為構成脂肪酸之單酸甘油酯等油溶性乳化劑,添加至食用油脂中,升溫使其溶解,而配製油相部分。一面將上述油相部分慢慢加至水相部分一面攪拌乳化,進而一面攪拌一面使其冷卻,而可獲得水包油型之乳化油脂組成物。上述油相部分及上述水相部分之質量比,較佳是1:1~1:4,更佳是1:1.5~1:3,若在此範圍內,可獲得乳化穩定之乳化油脂組成物,因此較佳。 The emulsified fat or oil composition of the embodiment of the present invention can be produced by a general method in which an oil phase and an aqueous phase are mixed and emulsified. For example, a water-soluble emulsifier, a thickening polysaccharide, a saccharide, a dairy product, an alcohol, or the like is added to water as needed, and the mixture is heated while stirring to prepare an aqueous phase portion. At the same time, an oil-soluble emulsifier such as a monoglyceride in which a saturated fatty acid is a constituent fatty acid is added to an edible fat or oil, and the mixture is heated to dissolve, thereby preparing an oil phase portion. While the oil phase portion was gradually added to the aqueous phase portion, the mixture was stirred and emulsified, and further cooled while stirring, and an oil-in-water emulsified fat or oil composition was obtained. The mass ratio of the oil phase portion to the aqueous phase portion is preferably 1:1 to 1:4, more preferably 1:1.5 to 1:3, and if it is within this range, an emulsified and stable emulsified oil composition can be obtained. Therefore, it is better.

本發明的實施形態的乳化油脂組成物,其使用於點心麵包之製造。較佳是使用於必須有發泡性之蛋糕類,尤其 較佳是使用於藉由一次加料法製造之蛋糕類。一次加料法,無須預先使蛋發泡,而是同時加入所有材料,再使麵糊發泡的一種配製方法。作為蛋糕類,可列舉:海綿蛋糕、戚風蛋糕、瑞士蛋糕捲、小蛋糕(snack cake)、法式海綿小蛋糕(bouchée)、奶油蛋糕(butter cake)、蒸蛋糕等,尤其較佳是將該乳化油脂組成物使用於海綿蛋糕或蒸蛋糕。 The emulsified fat or oil composition of the embodiment of the present invention is used for the production of snack bread. It is preferably used in cakes that must have foaming properties, especially It is preferably used in cakes produced by a one-time feeding method. The one-time feeding method does not require the egg to be foamed in advance, but a method of preparing all the materials at the same time and foaming the batter. Examples of the cake include a sponge cake, a hurricane cake, a Swiss cake roll, a snack cake, a bouchée, a butter cake, a steamed cake, etc., and it is particularly preferable to use the cake. The emulsified fat composition is used for a sponge cake or a steamed cake.

使用本發明的實施形態的乳化油脂組成物所製造的點心麵包,是以加熱麵糊的方式製造,該麵糊包含本發明之乳化油脂組成物,並且是以榖粉為主體。尤其是蛋糕類,是以加熱蛋糕麵糊的方式製造,該蛋糕麵糊包含本發明之乳化油脂組成物,且至少含有榖粉、蛋製品及醣類。作為加熱的方法,較佳是烘焙或蒸煮。從獲得良好口感及風味的觀點來看,蛋糕類之製造方式較佳是配製一蛋糕麵糊,並且將該蛋糕麵糊進行烘焙或蒸煮來製造,該蛋糕麵糊含有氣體,且至少是混合下述成分而成:榖粉;相對於榖粉100質量份之蛋製品50~300質量份、醣類20~250質量份、本發明之乳化油脂組成物3~100質量份。更佳是將蛋糕麵糊進行烘焙或蒸煮的方式來製造蛋糕,該蛋糕麵糊含有氣體,且是以下述方式混合:相對於榖粉100質量份,以蛋製品80~250質量份、醣類50~180質量份、本發明之乳化油脂組成物5~50質量份的比例來混合。 The confectionery bread produced by using the emulsified oil-fat composition of the embodiment of the present invention is produced by heating a batter, and the batter contains the emulsified fat or oil composition of the present invention, and is mainly composed of enamel powder. In particular, the cake is produced by heating a cake batter comprising the emulsified oil composition of the present invention and containing at least glutinous rice flour, egg products and saccharides. As a method of heating, baking or cooking is preferred. From the viewpoint of obtaining a good taste and flavor, the cake is preferably produced by preparing a cake batter and baking or cooking the cake batter, the cake batter containing a gas, and at least mixing the following ingredients.成 榖 powder; 50 to 300 parts by mass of the egg product of 100 parts by mass of the glutinous rice powder, 20 to 250 parts by mass of the saccharide, and 3 to 100 parts by mass of the emulsified fat and oil composition of the present invention. More preferably, the cake batter is baked or cooked to produce a cake. The cake batter contains a gas and is mixed in such a manner that 80 to 250 parts by mass of the egg product and 50 to 50 parts by mass of the egg product are added to 100 parts by mass of the glutinous rice powder. 180 parts by mass of the emulsified fat or oil composition of the present invention are mixed in a ratio of 5 to 50 parts by mass.

作為上述蛋糕麵糊的原料中的榖粉,並無特別限制,可列舉例如:麵粉(低筋麵粉、中筋麵粉、高筋麵粉)、小麥胚芽、全麥麵粉、小麥麩皮、硬質小麥粉(durum flour)、大 麥粉、米榖粉、裸麥粉、全裸麥粉、大豆粉、薏仁粉等,並且可從此等之中任選1種或2種以上使用。關於上述蛋糕麵糊的原料中之蛋製品、醣類,亦可使用與本實施形態的乳化油脂組成物的原料所述相同的蛋製品、醣類。上述蛋糕麵糊,亦可進而包含乳製品、發粉、食用油脂、香料等來作為其原料。 The tantalum powder in the raw material of the cake batter is not particularly limited, and examples thereof include flour (low-gluten flour, medium-gluten flour, high-gluten flour), wheat germ, whole wheat flour, wheat bran, and durum wheat flour (durum). Flour) The wheat flour, the rice bran powder, the rye flour, the whole rye flour, the soy flour, the barley powder, etc. are used, and one or two or more types can be used. The egg product or the saccharide in the raw material of the cake batter may be the same as the egg product or the saccharide described in the raw material of the emulsified fat or oil composition of the present embodiment. The cake batter may further contain a dairy product, a hair powder, an edible fat, a flavor, or the like as a raw material thereof.

使用本發明的實施形態的乳化油脂組成物所製造的蛋糕類,具有以往所沒有的柔軟又溼潤的口感,即使將該點心麵包進行冷藏或冷凍解凍,仍可良好地維持柔軟和溼潤口感等。因此,該乳化油脂組成物適合於冷藏或冷凍解凍用。 The cake produced by using the emulsified oil-fat composition of the embodiment of the present invention has a soft and moist texture which has not been conventionally used, and even if the confectionery bread is refrigerated or frozen and thawed, the soft and moist mouthfeel can be favorably maintained. Therefore, the emulsified oil composition is suitable for refrigerating or freezing and defrosting.

以下,舉出實施例對本發明作更詳細說明,但是本發明並不限於此等實施例。 Hereinafter, the present invention will be described in more detail by way of examples, but the invention is not limited to the examples.

再者,實施例中之三酸甘油酯的分析,是藉由使用毛細管柱(DB-1HT;J&W Scientific,Folsom,CA)之氣相層析法來進行。 Further, the analysis of the triglyceride in the examples was carried out by gas chromatography using a capillary column (DB-1HT; J&W Scientific, Folsom, CA).

[實施例] [Examples]

<食用油脂之配製> <Preparation of edible fats and oils>

(油脂A-1) (Fat A-1)

以中鏈脂肪酸三酸甘油酯(商品名稱:ODO,MTAG含量97.0質量%,The Nisshin OilliO Group,Ltd.製造)作為油脂A-1。 The medium chain fatty acid triglyceride (trade name: ODO, MTAG content: 97.0% by mass, manufactured by The Nisshin Oilli O Group, Ltd.) was used as the fat and oil A-1.

(油脂A-2) (Oil A-2)

將MCT(商品名:ODO,The Nisshin OilliO Group,Ltd.製造)14質量份與菜籽油(商品名稱:Nissin Canola Oil,碳數 16以上之不飽和脂肪酸92質量%,The Nisshin OilliO Group,Ltd.製造)86質量份進行混合,基於常規方法,以甲醇鈉作為催化劑進行酯交換反應。酯交換反應後,進行水洗、脫色、脫臭之精製處理,而獲得油脂A-2(MTAG含量44.9質量%,M2L含量9.1質量%,ML2含量35.2質量%)。 14 parts by mass of MCT (trade name: ODO, The Nisshin OilliO Group, Ltd.) and rapeseed oil (trade name: Nissin Canola Oil, carbon number) 86 parts by mass of an unsaturated fatty acid of 16 or more, manufactured by The Nisshin Oilli O Group, Ltd., was mixed, and a transesterification reaction was carried out using sodium methoxide as a catalyst based on a conventional method. After the transesterification reaction, the water was washed, decolorized, and deodorized to obtain an oil and fat A-2 (MTAG content: 44.9 mass%, M2L content: 9.1 mass%, and ML2 content: 35.2 mass%).

(其他原料油脂) (other raw materials and fats)

準備菜籽油(商品名稱:Nissin Canola Oil,碳數16以上之不飽和脂肪酸92質量%,The Nisshin OilliO Group,Ltd.製造)、棕櫚油(商品名稱:Refined Palm Oil,碳數16以上之不飽和脂肪酸49.6質量%,The Nisshin OilliO Group,Ltd.製造)作為其他原料油脂。 Preparation of rapeseed oil (trade name: Nissin Canola Oil, 92% by mass of unsaturated fatty acid having a carbon number of 16 or more, manufactured by The Nisshin OilliO Group, Ltd.), palm oil (trade name: Refined Palm Oil, no more than 16 carbon atoms) As a raw material fat or oil, saturated fatty acid (49.6% by mass, manufactured by The Nisshin OilliO Group, Ltd.).

<乳化油脂組成物之配製> <Preparation of emulsified oil composition>

使用以下成分作為食用油脂以外之原料,並依照表1的調配方式,配製實施例1、2及比較例1、2的乳化油脂組成物。乳化油脂組成物之配製是藉由下述步驟進行:將油相部分的原料及水相部分的原料分開各自混合,並加熱溶解而配製出油相與水相部分,再一面將油相部分慢慢添加至水相部分中,一面使用乳化均質機將其攪拌乳化,並一面攪拌一面使其冷卻。將配製之乳化油脂組成物,在室溫下靜置一晚後,作為各種評估用。 The following components were used as raw materials other than edible fats and oils, and the emulsified fat or oil compositions of Examples 1 and 2 and Comparative Examples 1 and 2 were prepared in accordance with the formulation of Table 1. The preparation of the emulsified oil and fat composition is carried out by separately mixing the raw materials of the oil phase portion and the raw materials of the aqueous phase portion, and heating and dissolving to prepare the oil phase and the water phase portion, and then slowly slowing the oil phase portion. Slowly added to the aqueous phase portion, the mixture was emulsified by stirring using an emulsifier homogenizer, and cooled while stirring. The prepared emulsified fat and oil composition was allowed to stand at room temperature for one night and used as various evaluations.

(食用油脂以外之原料) (Materials other than edible fats and oils)

(成分(B)) (ingredient (B))

硬脂酸單甘油酯(monoglyceride stearate,商品名稱:Emaruji MS,HLB值4.3,RIKEN VITAMIN Co.,Ltd.製造) Monoglyceride stearate (trade name: Emaruji MS, HLB value 4.3, manufactured by RIKEN VITAMIN Co., Ltd.)

(成分(C)) (ingredient (C))

丙二醇單二十二酸酯(propylene glycol mono-behenic acid ester,商品名稱:Rikemaru PB-100,HLB值3.0,RIKEN VITAMIN Co.,Ltd.製造) Propylene glycol mono-behenic acid ester (trade name: Rikemaru PB-100, HLB value 3.0, manufactured by RIKEN VITAMIN Co., Ltd.)

去水山梨醇硬脂酸酯(sorbitan mono-stearic acid ester,商品名稱:Emasol S-10V,HLB值4.7,Kao Corporation製造) Sorbitan mono-stearic acid ester (trade name: Emasol S-10V, HLB value 4.7, manufactured by Kao Corporation)

蔗糖硬脂酸酯(sucrose stearic acid ester,商品名稱:DK ester F-110,HLB值11,Dai-ichi Kogyo Seiyaku Co.,Ltd.製造) Sucrose stearic acid ester (trade name: DK ester F-110, HLB value 11, manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.)

(成分(D)) (ingredient (D))

自來水 Tap water

(其他成分) (other ingredients)

卵磷脂(商品名稱:Lecithin DX,The Nisshin OilliO Group,Ltd.製造) Lecithin (trade name: Lecithin DX, manufactured by The Nisshin OilliO Group, Ltd.)

乙醇(商品名稱:Amano SD,Amakasu Chemical Industries製造) Ethanol (trade name: Amano SD, manufactured by Amakasu Chemical Industries)

丙二醇(propylene glycol,商品名稱:propylene glycol,Asahi Glass Co.,Ltd.製造) Propylene glycol (trade name: propylene glycol, manufactured by Asahi Glass Co., Ltd.)

砂糖(商品名稱:細白糖,Mitsui Sugar Co.,Ltd.製造) Granulated sugar (trade name: fine white sugar, manufactured by Mitsui Sugar Co., Ltd.)

水飴(商品名稱:High Maltose Syrup MC-45,Nihon Shokuhin Kako Co.,Ltd.) Leech (trade name: High Maltose Syrup MC-45, Nihon Shokuhin Kako Co., Ltd.)

乳清蛋白濃縮物(商品名稱:Mirai 80,德國Mirai Co.,Ltd.製造) Whey protein concentrate (trade name: Mirai 80, manufactured by Mirai Co., Ltd., Germany)

三仙膠(商品名稱:VIS TOP D-3000-DF,San-Ei Gen F.F.I., Inc.製造) Sanxianjiao (commodity name: VIS TOP D-3000-DF, San-Ei Gen F.F.I., Made by Inc.)

<乳化油脂組成物之發泡力之評估> <Evaluation of foaming power of emulsified oil composition>

依上述所配製之實施例1、2及比較例1、2之乳化油脂組成物,使用表2之蛋糕麵糊之調配方式,並依以下條件,進行蛋糕麵糊之比重測量,而評估其發泡力。結果如表3所示。 According to the emulsified oil composition of Examples 1 and 2 and Comparative Examples 1 and 2 prepared above, the cake batter of Table 2 was used, and the specific gravity of the cake batter was measured according to the following conditions, and the foaming power was evaluated. . The results are shown in Table 3.

(蛋糕麵糊之比重測量條件) (measurement conditions for the proportion of cake batter)

將冷凍全蛋、細白糖、乳化油脂組成物混合,一面用攪拌機(美國Hobart Corporation製造)以低速(50rpm)攪拌,一面添加低筋麵粉及發粉,並攪拌30秒。進而切換為中速(100rpm),並於3、5、10分鐘後測量其比重(g/ml)。 The frozen whole egg, the white sugar, and the emulsified oil and fat composition were mixed, and while stirring at a low speed (50 rpm) with a stirrer (manufactured by Hobart Corporation, USA), low-gluten flour and hair powder were added, and the mixture was stirred for 30 seconds. Further, it was switched to medium speed (100 rpm), and its specific gravity (g/ml) was measured after 3, 5, and 10 minutes.

<蛋糕之製造及感官品評> <Cake Making and Sensory Reviews>

依上述所配製之實施例1、2及比較例1、2之乳化油脂組成物,使用表2之蛋糕麵糊之調配方式,利用以下的一次加料法製造蛋糕,並依照以下的評估基準進行感官品評。結果如表3所示。 According to the emulsified fats and oils compositions of Examples 1 and 2 and Comparative Examples 1 and 2 prepared above, cakes were prepared by the following one-time feeding method using the cake batter of Table 2, and sensory evaluation was carried out according to the following evaluation criteria. . The results are shown in Table 3.

(蛋糕之製造方法) (How to make a cake)

將冷凍全蛋、細白糖、乳化油脂組成物混合,一面用攪拌機(美國Hobart Corporation製造)以低速(50rpm)攪拌,一面添加低筋麵粉及發粉,攪拌30秒。進而切換為中速(100rpm),攪拌使蛋糕麵糊之比重至0.45(g/ml)為止,之後將330g之此蛋糕麵糊倒入6號蛋糕模,於烤箱內,以上火190℃、下火170℃烘焙28分鐘。將烘焙之蛋糕保存於室溫一個晚上,作為感官評估用。又,將蛋糕冷凍保存於-35℃ 1週,並於20℃ 解凍,亦作為感官評估用。 The frozen whole egg, the white sugar, and the emulsified oil and fat composition were mixed, and while stirring at a low speed (50 rpm) with a stirrer (manufactured by Hobart Corporation, USA), low-gluten flour and hair powder were added, and the mixture was stirred for 30 seconds. Then switch to medium speed (100 rpm), stir to make the cake batter specific gravity to 0.45 (g / ml), then 330g of this cake batter into the No. 6 cake mold, in the oven, above the fire 190 ° C, under fire 170 Bake at °C for 28 minutes. The baked cake was stored at room temperature for one night for sensory evaluation. Also, the cake was stored frozen at -35 ° C for 1 week and at 20 ° C Thawing is also used as a sensory evaluation.

(感官品評基準) (sensory evaluation benchmark)

依照以下的基準,由5位官能品評員進行綜合評估。 A comprehensive evaluation was conducted by five functional reviewers based on the following criteria.

〔柔軟感‧溼潤感〕 [soft feeling, moist feeling]

實施例1~2的乳化油脂組成物,對於使海綿蛋糕發泡方面,具有充分的機能。又,使用實施例1~2之乳化油脂組成物所製造的蛋糕,不會有烘焙後氣泡破裂而凹陷的情形,氣泡安定性較高,並且柔軟及溼潤口感優異,且在冷凍解凍後仍可良好地維持柔軟及溼潤口感。另一方面,雖然比較例1、2的乳化油脂組成物的發泡力與實施例1、2相同,但是冷凍解凍後的口感較差。 The emulsified oil and fat compositions of Examples 1 and 2 have sufficient functions for foaming the sponge cake. Further, the cake produced by using the emulsified oil composition of Examples 1 to 2 does not have a bubble collapse after baking, and the bubble is highly stable, and the softness and wet texture are excellent, and it is still after freezing and thawing. Maintain a soft and moist mouthfeel well. On the other hand, although the foaming power of the emulsified oil-fat composition of Comparative Examples 1 and 2 was the same as that of Examples 1 and 2, the texture after freezing and thawing was inferior.

Claims (5)

一種乳化油脂組成物,其含有以下的成分(A)、(B)、(C)及(D):(A)食用油脂10~40質量%,其含有包含碳數6~10的脂肪酸作為構成脂肪酸之三酸甘油酯;(B)單酸甘油酯2~20質量%,其以飽和脂肪酸作為構成脂肪酸;(C)乳化劑2~20質量%,其是選自丙二醇脂肪酸酯、蔗糖脂肪酸酯、去水山梨醇脂肪酸酯、及聚甘油脂肪酸酯中的1種以上;(D)水10~50質量%。 An emulsified fat or oil composition comprising the following components (A), (B), (C), and (D): (A) 10 to 40% by mass of edible fats and oils, comprising a fatty acid having 6 to 10 carbon atoms as a constituent a fatty acid triglyceride; (B) a monoglyceride 2 to 20% by mass, which uses a saturated fatty acid as a constituent fatty acid; (C) an emulsifier 2 to 20% by mass, which is selected from a propylene glycol fatty acid ester, sucrose fat One or more of an acid ester, a sorbitan fatty acid ester, and a polyglycerin fatty acid ester; (D) 10 to 50% by mass of water. 如請求項1所述之乳化油脂組成物,其中,前述(A)食用油脂是含有三酸甘油酯10~90質量%之食用油脂,該三酸甘油酯包含碳數6~10的脂肪酸作為構成脂肪酸。 The emulsified fat or oil composition according to claim 1, wherein the (A) edible fat or oil is an edible fat or oil containing 10 to 90% by mass of triglyceride, and the triglyceride comprises a fatty acid having 6 to 10 carbon atoms as a constituent. fatty acid. 如請求項1或2所述之乳化油脂組成物,其中,前述(A)食用油脂含有M2L型三酸甘油酯與ML2型三酸甘油酯,合計10~80質量%。 (其中,M表示碳數6~10的脂肪酸,L表示碳數16以上的脂肪酸)。 The emulsified fat or oil composition according to claim 1 or 2, wherein the (A) edible fat or oil contains M2L-type triglyceride and ML2-type triglyceride in a total amount of 10 to 80% by mass. (wherein M represents a fatty acid having 6 to 10 carbon atoms, and L represents a fatty acid having 16 or more carbon atoms). 一種點心麵包,其使用如請求項1~3中任一項所述之乳化油脂組成物所製造而成。 A snack bread manufactured by using the emulsified fat or oil composition according to any one of claims 1 to 3. 一種點心麵包的製造方法,該方法是將麵糊進行加熱,該麵糊是使用如請求項1~3中任一項所述之乳化油脂組成物,並且藉由一次加料法所配製而成。 A method for producing a snack bread, which comprises heating the batter, which is prepared by using the emulsified oil composition according to any one of claims 1 to 3, and by a one-time addition method.
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