TW201514356A - Washing machine - Google Patents

Washing machine Download PDF

Info

Publication number
TW201514356A
TW201514356A TW103121360A TW103121360A TW201514356A TW 201514356 A TW201514356 A TW 201514356A TW 103121360 A TW103121360 A TW 103121360A TW 103121360 A TW103121360 A TW 103121360A TW 201514356 A TW201514356 A TW 201514356A
Authority
TW
Taiwan
Prior art keywords
hydrophilic
washing machine
machine according
washing
hydrophilic performance
Prior art date
Application number
TW103121360A
Other languages
Chinese (zh)
Other versions
TWI548794B (en
Inventor
Kenji Kojima
Tsutomu Hatayama
Tetsuyuki Kono
Original Assignee
Toshiba Kk
Toshiba Lifestyle Products & Services Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Kk, Toshiba Lifestyle Products & Services Corp filed Critical Toshiba Kk
Publication of TW201514356A publication Critical patent/TW201514356A/en
Application granted granted Critical
Publication of TWI548794B publication Critical patent/TWI548794B/en

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F35/00Washing machines, apparatus, or methods not otherwise provided for
    • D06F35/005Methods for washing, rinsing or spin-drying
    • D06F35/008Methods for washing, rinsing or spin-drying for disinfecting the tub or the drum
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F37/00Details specific to washing machines covered by groups D06F21/00 - D06F25/00
    • D06F37/02Rotary receptacles, e.g. drums
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F23/00Washing machines with receptacles, e.g. perforated, having a rotary movement, e.g. oscillatory movement, the receptacle serving both for washing and for centrifugally separating water from the laundry 
    • D06F23/04Washing machines with receptacles, e.g. perforated, having a rotary movement, e.g. oscillatory movement, the receptacle serving both for washing and for centrifugally separating water from the laundry  and rotating or oscillating about a vertical axis
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F23/00Washing machines with receptacles, e.g. perforated, having a rotary movement, e.g. oscillatory movement, the receptacle serving both for washing and for centrifugally separating water from the laundry 
    • D06F23/06Washing machines with receptacles, e.g. perforated, having a rotary movement, e.g. oscillatory movement, the receptacle serving both for washing and for centrifugally separating water from the laundry  and rotating or oscillating about an inclined axis
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F37/00Details specific to washing machines covered by groups D06F21/00 - D06F25/00
    • D06F37/02Rotary receptacles, e.g. drums
    • D06F37/04Rotary receptacles, e.g. drums adapted for rotation or oscillation about a horizontal or inclined axis
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F37/00Details specific to washing machines covered by groups D06F21/00 - D06F25/00
    • D06F37/30Driving arrangements 
    • D06F37/304Arrangements or adaptations of electric motors
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/12Casings; Tubs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B40/00Technologies aiming at improving the efficiency of home appliances, e.g. induction cooking or efficient technologies for refrigerators, freezers or dish washers

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Main Body Construction Of Washing Machines And Laundry Dryers (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

The present invention relates to a washing machine comprising a rotary drum that is rotatably disposed in a water tank, a hydrophilic property portion disposed on the rotary drum and a functional element imparting means used for imparting functional elements to the hydrophilic property portion.

Description

洗衣機 washing machine

本發明的實施形態是關於一種洗衣機。 Embodiments of the present invention relate to a washing machine.

根據以往,能想到在洗衣機的水槽設置各種的功能性皮膜。例如在專利文獻1揭示有,必須謀求減低烘乾時的消耗電力,而在水槽的內面具備斷熱塗料的皮膜之技術。又,在該專利文獻1揭示有,藉由讓具親水性的中空珠粒含在撥水性的斷熱塗料的皮膜,使附著在皮膜的表面的水膜擴大而蒸發,藉此,謀求烘乾時的更進一步的消耗電力的減低。 Conventionally, it has been conceivable to provide various functional films in the water tank of a washing machine. For example, Patent Document 1 discloses that it is necessary to reduce the power consumption during drying, and to provide a film of a heat-insulating paint on the inner surface of the water tank. Further, Patent Document 1 discloses that by allowing a hydrophilic hollow bead to be contained in a film of a water-repellent heat-insulating paint, the water film adhering to the surface of the film is expanded and evaporated, thereby drying Further power consumption is reduced.

然而,近年開發有發揮親水性所為的防污功能的塗料,且若這類的塗料適用於洗衣機的水槽的內面的話,則藉由其防污功能可清潔地保持水槽的內面。可是,在水槽的內面,除了洗滌運轉或洗清運轉時蓄積在該水槽內的水接觸之外,脫水運轉時從內部的旋轉槽飛散的水也會接觸。因此,水槽的內面即使不是用具有這類的防污功能的塗料也可比較清潔地保持,故即使在水槽的內面保持防污 功能,也不能有效活用其功能。 However, in recent years, a paint having an antifouling function which is hydrophilic has been developed, and if such a paint is applied to the inner surface of a water tank of a washing machine, the inner surface of the water tank can be cleanly maintained by its antifouling function. However, the inner surface of the water tank is in contact with the water accumulated in the water tank during the washing operation or the washing operation, and the water scattered from the inner rotation groove during the dehydrating operation is also in contact. Therefore, the inner surface of the water tank can be relatively cleanly maintained even if it is not coated with such an antifouling function, so that the antifouling is maintained even on the inner surface of the water tank. Function, and can not effectively use its function.

[先行技術文獻] [Advanced technical literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特開2010-172436號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2010-172436

本實施形態,是提供一種可將親水性所為的防污功能適用在最能有效地活用在該功能的部位的洗衣機。 In the present embodiment, a washing machine capable of applying the antifouling function of hydrophilicity to a portion that can most effectively utilize the function is provided.

本實施形態的洗衣機,是可旋轉地被設在水槽內的旋轉槽具備親水性能部。 The washing machine of the present embodiment is provided with a hydrophilic performance portion in a rotary groove that is rotatably provided in the water tank.

又,本實施形態的洗衣機,是在可旋轉地被設在水槽內的旋轉槽施加有抑制黴菌的繁殖的親水性的塗料。 Further, the washing machine of the present embodiment is a hydrophilic paint which is applied to a rotary groove which is rotatably provided in a water tank to suppress the growth of mold.

又,本實施形態的洗衣機,是在可旋轉地被設在水槽內的旋轉槽施加有抑制污垢的附著的親水性的塗料。 Further, the washing machine of the present embodiment is a hydrophilic paint which is applied to a rotary groove rotatably provided in a water tank to suppress adhesion of dirt.

又,本實施形態的洗衣機,是在可旋轉地被設在水槽內的旋轉槽施加有抑制洗劑的附著的親水性的塗料。 Further, in the washing machine of the present embodiment, a hydrophilic paint that suppresses adhesion of the lotion is applied to a rotary groove that is rotatably provided in the water tank.

106‧‧‧操作面板 106‧‧‧Operator panel

107‧‧‧控制裝置 107‧‧‧Control device

134‧‧‧水容器 134‧‧‧ water container

100‧‧‧洗衣機 100‧‧‧Washing machine

101‧‧‧外箱 101‧‧‧Outer box

135‧‧‧連接管 135‧‧‧Connecting tube

133‧‧‧給水閥 133‧‧‧Water supply valve

131‧‧‧水位感應器 131‧‧‧Water level sensor

104‧‧‧洗滌物出入口 104‧‧‧Washing entrances and exits

123‧‧‧波紋管 123‧‧‧ bellows

136‧‧‧機內給水軟管 136‧‧‧In-machine water supply hose

108‧‧‧水槽 108‧‧‧Sink

132‧‧‧氣管 132‧‧‧ trachea

105‧‧‧門扇 105‧‧‧ door leaf

119‧‧‧隔板 119‧‧ ‧ partition

118‧‧‧孔 118‧‧‧ hole

117‧‧‧補強構件 117‧‧‧ reinforcing members

127‧‧‧蓋子 127‧‧‧ cover

121‧‧‧開口部 121‧‧‧ openings

120‧‧‧開口部 120‧‧‧ openings

122‧‧‧平衡環 122‧‧‧balance ring

110‧‧‧馬達 110‧‧‧Motor

114‧‧‧軸承托架 114‧‧‧bearing bracket

115‧‧‧軸承 115‧‧‧ bearing

113‧‧‧旋轉軸 113‧‧‧Rotary axis

112‧‧‧轉子 112‧‧‧Rotor

111‧‧‧定子 111‧‧‧ Stator

116‧‧‧滾筒 116‧‧‧Roller

124‧‧‧排水口 124‧‧‧Drainage

130‧‧‧氣阱 130‧‧‧ gas trap

300‧‧‧親水性能膜 300‧‧‧Hydrophilic film

103‧‧‧箱本體 103‧‧‧ box body

126‧‧‧過濾盒 126‧‧‧Filter box

128‧‧‧排水閥 128‧‧‧Drain valve

129‧‧‧排水管 129‧‧‧Drainage pipe

109‧‧‧懸吊裝置 109‧‧‧suspension device

125‧‧‧機內排水軟管 125‧‧‧In-house drainage hose

132‧‧‧氣管 132‧‧‧ trachea

102‧‧‧基台 102‧‧‧Abutment

200‧‧‧洗衣機 200‧‧‧Washing machine

217‧‧‧操作面板 217‧‧‧Operator panel

204‧‧‧旋轉槽 204‧‧‧Rotating trough

215‧‧‧蓋子 215‧‧‧ cover

214‧‧‧頂殼罩 214‧‧‧ top cover

201‧‧‧外箱 201‧‧‧Outer box

206a‧‧‧螺絲 206a‧‧‧screw

202‧‧‧水槽 202‧‧‧Sink

203‧‧‧彈性吊持機構 203‧‧‧Elastic hanging mechanism

206‧‧‧平衡環 206‧‧‧balance ring

205‧‧‧孔 205‧‧‧ hole

204a‧‧‧第1構件 204a‧‧‧1st component

204b‧‧‧第2構件 204b‧‧‧2nd component

204c‧‧‧補強構件 204c‧‧‧ reinforcing members

211‧‧‧氣管 211‧‧‧ trachea

210‧‧‧氣阱 210‧‧‧ gas trap

Rb‧‧‧未塗覆部 Rb‧‧‧Uncoated

Ra‧‧‧塗覆部 Ra‧‧‧ Coating Department

T‧‧‧旋轉槽T T‧‧‧Rotating trough T

207‧‧‧攪拌體 207‧‧‧ stirring body

209‧‧‧排水閥 209‧‧‧Drain valve

208‧‧‧排水路徑 208‧‧‧Drainage path

213‧‧‧驅動機構部 213‧‧‧Drive Department

118a‧‧‧端面 118a‧‧‧ end face

205a‧‧‧端面 205a‧‧‧ end face

[圖1]是概略性地表示第1實施形態的滾筒式洗衣機的構造的縱剖剖視圖。 FIG. 1 is a longitudinal cross-sectional view schematically showing a structure of a drum type washing machine according to a first embodiment.

[圖2]是概略性地表示第1實施形態的縱軸型洗衣機的構造的縱剖側視圖。 FIG. 2 is a longitudinal cross-sectional side view schematically showing a structure of a vertical axis type washing machine according to the first embodiment.

[圖3]是模式表示旋轉槽的展開圖的圖。 Fig. 3 is a view showing a developed view of a rotary groove.

[圖4]是表示實用試驗的條件及試驗結果的圖。 Fig. 4 is a view showing conditions and test results of a practical test.

[圖5]是視覺性地表示實用試驗的試驗結果的圖。 Fig. 5 is a view visually showing test results of a practical test.

[圖6]是表示模擬污垢洗滌試驗的試驗結果的圖。 Fig. 6 is a view showing test results of a simulated soil washing test.

[圖7]是視覺性地表示模擬污垢洗滌試驗的試驗結果的圖。 Fig. 7 is a view visually showing the test results of the simulated soil washing test.

[圖8]表示黴菌附著及發育抑制確認試驗的試驗對象部位的一例的相當圖3的圖。 FIG. 8 is a view corresponding to FIG. 3 showing an example of a test target portion of a mold adhesion and development inhibition confirmation test.

[圖9]表示黴菌附著及發育抑制確認試驗的試驗結果的圖。 Fig. 9 is a view showing test results of a mold adhesion and development inhibition confirmation test.

[圖10]是第2實施形態的相當於圖1的圖。 Fig. 10 is a view corresponding to Fig. 1 of the second embodiment.

[圖11]是第2實施形態的相當於圖2的圖。 Fig. 11 is a view corresponding to Fig. 2 in the second embodiment.

[圖12]是第3實施形態的相當於圖1的圖。 Fig. 12 is a view corresponding to Fig. 1 of the third embodiment.

[圖13]是第3實施形態的相當於圖2的圖。 Fig. 13 is a view corresponding to Fig. 2 in the third embodiment.

[圖14]是變形實施形態的相當於圖1的圖(之1)。 Fig. 14 is a view (1) corresponding to Fig. 1 in a modified embodiment.

[圖15]是變形實施形態的相當於圖1的圖(之2)。 Fig. 15 is a view (No. 2) corresponding to Fig. 1 in a modified embodiment.

[圖16]是變形實施形態的相當於圖2的圖。 Fig. 16 is a view corresponding to Fig. 2 in a modified embodiment.

[圖17]是關於變形實施形態者,(a)是表示在孔的端面不具備親水性能部的構造的一例的孔周邊的放大圖,(b)是表示在孔的端面具備親水性能部的構造的一例的孔周邊的放大圖。 [Fig. 17] Fig. 17 is an enlarged view showing a periphery of a hole in which an end face of a hole does not have a hydrophilic performance portion, and (b) shows a portion having a hydrophilic property at an end surface of the hole. An enlarged view of the periphery of a hole as an example of a structure.

以下,一面參照圖面一面針對洗衣機的複數個實施形態進行說明。此外,在各實施形態在實質上相同的要素標示同一符號,並省略說明。 Hereinafter, a plurality of embodiments of the washing machine will be described with reference to the drawings. In the embodiments, substantially the same elements are denoted by the same reference numerals, and description thereof will be omitted.

(第1實施形態) (First embodiment)

圖1所示的洗衣機100,是旋轉槽的旋轉中心軸為水平、或稍微傾斜的所謂橫軸型的滾筒式的洗衣機,構成其外廓的外箱101,是由合成樹脂製的基台102、與結合於基台102的箱本體103所構成。在圖1成為左側的箱本體103的前面部,在其大致中央部設有洗滌物出入口104。又,在箱本體103的前面部設有開閉洗滌物出入口104的門扇105。在箱本體103的前面部的上部設有操作面板106。在操作面板106的裏側設有控制洗衣機100的全盤動作的控制裝置107。在外箱101內設有閉塞底部的背面部側的有底圓筒狀的水槽108。水槽108,是藉由懸吊裝置109被彈性支承而使其中心軸在圖1位於朝向成為右方的後方下降的稍微傾斜的軸線上。 The washing machine 100 shown in Fig. 1 is a so-called horizontal-axis type drum type washing machine in which the central axis of rotation of the rotary groove is horizontal or slightly inclined, and the outer casing 101 constituting the outer periphery thereof is a base 102 made of synthetic resin. And the box body 103 combined with the base 102 is comprised. In Fig. 1, the front portion of the box body 103 on the left side is provided with a laundry inlet and outlet 104 at a substantially central portion thereof. Further, a door fan 105 that opens and closes the laundry inlet and outlet 104 is provided in the front portion of the tank body 103. An operation panel 106 is provided at an upper portion of the front portion of the box body 103. A control device 107 that controls the overall operation of the washing machine 100 is provided on the back side of the operation panel 106. A bottomed cylindrical water tank 108 that closes the back side of the bottom portion is provided in the outer casing 101. The water tank 108 is elastically supported by the suspension device 109 such that its central axis is slightly inclined on the axis which is lowered toward the rear in FIG.

在水槽108的背面部的外側設有馬達110。該馬達110,是例如由直流的無刷馬達所構成,且為外轉子型,並具備有定子111及轉子112。定子111被固定在水槽108的背面部的外側。在轉子112的中心部設有旋轉軸113。旋轉軸113,是經由軸承115被支承於軸承托架114,且被插通到水槽108的內部。在水槽108的內部設 有閉塞底部的背面部側的有底圓筒狀的滾筒116。 A motor 110 is provided outside the back surface of the water tank 108. The motor 110 is composed of, for example, a DC brushless motor, and is of an outer rotor type, and includes a stator 111 and a rotor 112. The stator 111 is fixed to the outside of the back surface portion of the water tank 108. A rotating shaft 113 is provided at a center portion of the rotor 112. The rotating shaft 113 is supported by the bearing bracket 114 via the bearing 115 and is inserted into the inside of the water tank 108. In the interior of the sink 108 There is a bottomed cylindrical drum 116 that closes the back side of the bottom.

滾筒116,是例如由不銹鋼板等形成的金屬製。滾筒116,是將其背面部的中心部固定在馬達110的旋轉軸113的前端部,且被設成可以水槽108的軸線,亦即,被設成可以朝向後方下降傾斜的軸線為中心旋轉。此時,馬達110,是作為使滾筒116旋轉的驅動裝置發揮功能。在滾筒116的底部,換言之在背面部的外面,設有補強該滾筒116的背面部用的補強構件117。該補強構件117,是例如由不銹鋼的壓鑄等形成的金屬製。在構成滾筒116的胴部的周壁部,是在全域形成有許多個孔118。該等孔118,是貫穿,且可通水及通氣。又,在滾筒116的內周部,設有撥起洗滌物用的複數個合成樹脂製的隔板119。此外,水槽108也可設成位在其中心軸沒有傾斜的水平的軸線上,此時,滾筒116,是設成可以水平的軸線為中心旋轉。 The drum 116 is made of, for example, a metal formed of a stainless steel plate or the like. The drum 116 has a center portion of the back surface portion fixed to the front end portion of the rotating shaft 113 of the motor 110, and is provided so as to be rotatable about an axis of the water tank 108, that is, an axis that can be inclined downward toward the rear. At this time, the motor 110 functions as a drive device that rotates the drum 116. At the bottom of the drum 116, in other words, on the outer surface of the back surface portion, a reinforcing member 117 for reinforcing the back surface portion of the drum 116 is provided. The reinforcing member 117 is made of, for example, metal formed by die casting of stainless steel or the like. In the peripheral wall portion constituting the crotch portion of the drum 116, a plurality of holes 118 are formed in the entire region. The holes 118 are penetrating and can be ventilated and ventilated. Further, a plurality of separators 119 made of synthetic resin for picking up the laundry are provided on the inner peripheral portion of the drum 116. Further, the water tank 108 may be disposed on an axis on which the center axis is not inclined, and at this time, the drum 116 is set to be rotatable about a horizontal axis.

滾筒116及水槽108皆是前面側開口,且成為開口部120及開口部121。在滾筒116的開口部120的周圍,是設有例如封入有鹽水等的液體的合成樹脂製的平衡環122。該平衡環122,是例如藉由由不銹鋼等形成的金屬製的未圖示的螺絲從滾筒116的外側面被固定。水槽108的開口部121,是例如經由由橡膠等的彈性材料形成的環狀的波紋管123被連結於洗滌物出入口104。藉此,洗滌物出入口104,是經由:波紋管123、水槽108的開口部121、及滾筒116的開口部120和滾筒116的內部連結。 Both the drum 116 and the water tank 108 are open on the front side, and are the opening 120 and the opening 121. Around the opening 120 of the drum 116, a balance ring 122 made of synthetic resin, for example, in which a liquid such as brine is sealed is provided. The balance ring 122 is fixed from the outer surface of the drum 116 by, for example, a metal (not shown) made of stainless steel or the like. The opening 121 of the water tank 108 is connected to the laundry inlet and outlet 104, for example, via an annular bellows 123 formed of an elastic material such as rubber. Thereby, the laundry inlet and outlet 104 is connected via the bellows 123, the opening 121 of the water tank 108, and the opening 120 of the drum 116 and the inside of the drum 116.

在水槽108的背面側的底部設有排水口124。在該排水口124,連接機內排水軟管125的一端部。機內排水軟管125的另一端部,是連接於被設在外箱101的基台102的前部的過濾盒126。在過濾盒126的前端部,蓋子127可裝脫地被安裝。在過濾盒126的內部收納有和蓋子127設成一體的未圖示的棉絮濾網。又,在過濾盒126的下部連接有排水閥128。在該排水閥128的出口部連接有排水管129。排水管129的前端部,是從外箱101的基台102被導出到機外,而連接於未圖示的機外排水軟管。 A drain port 124 is provided at the bottom of the back side of the water tank 108. At the drain port 124, one end portion of the in-machine drain hose 125 is connected. The other end portion of the in-machine drain hose 125 is connected to a filter cartridge 126 provided at the front of the base 102 of the outer casing 101. At the front end portion of the filter cartridge 126, the cover 127 is detachably mounted. Inside the filter cartridge 126, a bat filter (not shown) integrally formed with the lid 127 is housed. Further, a drain valve 128 is connected to the lower portion of the filter cartridge 126. A drain pipe 129 is connected to an outlet portion of the drain valve 128. The front end portion of the drain pipe 129 is led out from the base 102 of the outer casing 101 to the outside of the machine, and is connected to an off-board drain hose (not shown).

在過濾盒126的上部設有氣阱130。該氣阱130與配設在外箱101內的上部的水位感應器131,是藉由氣管132被連接。水位感應器131,是經由機內排水軟管125、過濾盒126、氣阱130及氣管132檢出水槽108內的水位輸出到控制裝置107。 A gas trap 130 is provided at an upper portion of the filter cartridge 126. The gas trap 130 and the water level sensor 131 disposed in the upper portion of the outer casing 101 are connected by a gas pipe 132. The water level sensor 131 detects the water level in the water tank 108 via the internal drain hose 125, the filter box 126, the air trap 130, and the air tube 132, and outputs it to the control device 107.

在外箱101內的上部設有給水閥133及給水容器134。在給水閥133的入口部,連接有從未圖示的水道的龍頭延伸的機外給水軟管。又,在給水閥133的出口部連接有連接管135的一端部。連接管135的另一端部連接於給水容器134。在給水容器134的內部設有未圖示的洗劑類貯留部。在給水容器134,連接有機內給水軟管136的一端部。機內給水軟管136的另一端部被連接在水槽108的上部。從水道經由給水閥133被供給的水,是經由連接管135、給水容器134及機內給水軟管136被供給到水槽108內。 A water supply valve 133 and a water supply container 134 are provided in an upper portion of the outer casing 101. An external water supply hose extending from a faucet of a water passage (not shown) is connected to an inlet portion of the water supply valve 133. Further, one end portion of the connection pipe 135 is connected to the outlet portion of the water supply valve 133. The other end of the connecting pipe 135 is connected to the water supply container 134. A lotion storage unit (not shown) is provided inside the water supply container 134. At the water supply container 134, one end portion of the organic inner water supply hose 136 is connected. The other end of the in-machine water supply hose 136 is connected to the upper portion of the water tank 108. The water supplied from the water channel via the water supply valve 133 is supplied into the water tank 108 via the connection pipe 135, the water supply container 134, and the in-machine water supply hose 136.

圖2所示的洗衣機200,是所謂旋轉槽的旋轉中心軸朝垂直方向延伸的縱軸型的洗衣機,在構成其外廓的外箱201的內部藉由彈性吊持機構203彈性支承上面開放的有底圓筒狀的水槽202。在該水槽202的內部,上面開放的有底圓筒狀的旋轉槽204可旋轉地被設置。 The washing machine 200 shown in FIG. 2 is a vertical axis type washing machine in which the rotation center axis of the rotation groove extends in the vertical direction, and the inside of the outer case 201 constituting the outer periphery thereof is elastically supported by the elastic suspension mechanism 203. A bottomed cylindrical sink 202. Inside the water tank 202, a bottomed cylindrical rotary groove 204 that is open on the upper surface is rotatably provided.

旋轉槽204,是例如藉由由不銹鋼等形成的金屬製的第1構件204a構成胴部,並藉由合成樹脂製的第2構件204b構成底部。在構成旋轉槽204的底部的第2構件204b的外側,設有補強該第2構件204b,換言之設有補強旋轉槽204的底部用的補強構件204c。該補強構件204c,是例如由不銹鋼板等形成的金屬製。該旋轉槽204,是構成以垂直的軸線為中心旋轉,且同時作為洗洗滌物的洗衣行程及洗清洗滌物的洗清行程的洗滌槽;以及將洗滌物脫水的脫水行程的脫水槽。旋轉槽204,是在其周壁部具有許多個孔205。該等孔205,是貫穿,且可通水及通氣。此外,在圖面僅表示該等孔205的一部分。在旋轉槽204的上部,安裝有例如封入有鹽水等的液體的合成樹脂製的平衡環206。該平衡環206,是例如藉由由不銹鋼等形成的金屬製的螺絲206a從旋轉槽204的外側面被固定。在旋轉槽204內的底部,合成樹脂製的攪拌體207可旋轉地被設置。 The rotary groove 204 is formed by, for example, a first member 204a made of stainless steel or the like, and a second member 204b made of synthetic resin. A reinforcing member 204c for reinforcing the second member 204b, in other words, a bottom portion for reinforcing the rotary groove 204, is provided outside the second member 204b constituting the bottom portion of the rotary groove 204. The reinforcing member 204c is made of, for example, a metal formed of a stainless steel plate or the like. The rotary groove 204 is a washing tank that is configured to rotate around a vertical axis and serves as a washing course for washing the laundry and a washing course for washing the laundry, and a dewatering groove for dehydrating the washing. The rotary groove 204 has a plurality of holes 205 in its peripheral wall portion. The holes 205 are continuous and can be ventilated and ventilated. Moreover, only a portion of the holes 205 are shown on the drawing. A balance ring 206 made of a synthetic resin in which a liquid such as saline is sealed is attached to the upper portion of the rotary tub 204. The balance ring 206 is fixed from the outer surface of the rotary groove 204 by, for example, a metal screw 206a made of stainless steel or the like. At the bottom in the rotation groove 204, a synthetic resin stirring body 207 is rotatably provided.

在水槽202的下部設有排水路徑208。在該排水路徑208設有排水閥209,藉由開放該排水閥209,將水槽202內的水排出到機外。又,在外槽202的底部設有水位感測 用的氣阱210。在該氣阱210經由氣管211連接有無圖示的水位感應器。該水位感應器此時是由壓力感應器形成,且是依據氣阱210內的壓力感測水槽202內的水位。 A drain path 208 is provided at a lower portion of the water tank 202. A drain valve 209 is provided in the drain path 208, and the drain valve 209 is opened to discharge the water in the water tank 202 to the outside of the machine. Moreover, water level sensing is provided at the bottom of the outer tank 202. Air trap 210 used. A water level sensor (not shown) is connected to the gas trap 210 via a gas pipe 211. The water level sensor is now formed by a pressure sensor and senses the water level in the water tank 202 based on the pressure within the air trap 210.

在水槽202的下部的中央部設有驅動機構部213。該驅動機構部213具備有:可變速驅動的馬達、離合器機構、減速裝置、制動裝置等。在洗衣行程時或洗清行程時,驅動機構部213,是藉由減速裝置減速馬達的旋轉力,並且藉由離合器機構傳達到攪拌體207。在脫水行程時,驅動機構部213沒有藉由減速裝置減速馬達的旋轉力,而藉由離合器機構以高速傳達到旋轉槽204及攪拌體207。 A drive mechanism portion 213 is provided at a central portion of a lower portion of the water tank 202. The drive mechanism unit 213 includes a variable speed drive motor, a clutch mechanism, a speed reducer, a brake device, and the like. At the time of the washing stroke or the washing stroke, the drive mechanism portion 213 decelerates the rotational force of the motor by the speed reducer, and transmits it to the agitating body 207 by the clutch mechanism. At the time of the dehydration stroke, the drive mechanism unit 213 does not decelerate the rotational force of the motor by the deceleration device, but is transmitted to the rotary groove 204 and the agitating body 207 at a high speed by the clutch mechanism.

在外箱201的上部設有頂殼罩214。在該頂殼罩214將開閉洗滌物出入口的例如兩褶式的蓋子215設成可開閉。此外,在水槽202的上部未圖示的槽蓋可開閉地被安裝。在頂殼罩214的前部設有操作面板217。在操作面板217的裏側設有控制洗衣機200的全盤動作的未圖示的控制裝置。在頂殼罩214內的後部設有將來自水道的水供給到水槽202內的未圖示的給水機構部。 A top cover 214 is provided at an upper portion of the outer casing 201. In the top cover 214, for example, a double-pleated cover 215 that opens and closes the laundry inlet and outlet is opened and closed. Further, a tank cover (not shown) on the upper portion of the water tank 202 is attached to the opening and closing. An operation panel 217 is provided at a front portion of the top cover 214. A control device (not shown) that controls the overall operation of the washing machine 200 is provided on the back side of the operation panel 217. A water supply mechanism unit (not shown) that supplies water from the water channel into the water tank 202 is provided in the rear portion of the top cover 214.

如圖1所示,上述的洗衣機100,是至少在滾筒116的側部的外面具備作為親水性能部的一例的親水性能膜300。此時,作為親水性能部的親水性能膜300常時發揮親水性能。親水性能膜300被形成在滾筒116側部的外面整體。又,如圖2所示,上述的洗衣機200,是至少在構成旋轉槽204的側部的第1構件204a的外面具備作為親 水性能部的一例的親水性能膜300。此時,親水性能膜300被形成在旋轉槽204側部的外面整體。接著,針對該親水性能膜300進一步詳細地說明。親水性能膜300,是例如將具有氧化矽系的無機塗料等具有親水性能的塗料(以下,稱為「親水性材料」)噴吹到滾筒116的側部的外面或旋轉槽204的側部的外面而形成塗覆者。 As shown in FIG. 1, the washing machine 100 described above is provided with a hydrophilic performance film 300 as an example of a hydrophilic performance portion on at least the outer surface of the side portion of the drum 116. At this time, the hydrophilic performance film 300 as the hydrophilic performance portion constantly exhibits hydrophilic properties. The hydrophilic property film 300 is formed on the outer surface of the side portion of the drum 116 as a whole. Moreover, as shown in FIG. 2, the above-described washing machine 200 is provided as a pro at least on the outer surface of the first member 204a constituting the side portion of the rotary groove 204. A hydrophilic performance film 300 as an example of a water performance portion. At this time, the hydrophilic performance film 300 is formed on the outer surface of the side portion of the rotary groove 204 as a whole. Next, the hydrophilic performance film 300 will be described in further detail. The hydrophilic performance film 300 is, for example, a coating material having a hydrophilic property such as a cerium oxide-based inorganic coating material (hereinafter referred to as "hydrophilic material") is sprayed onto the outer surface of the side portion of the drum 116 or the side portion of the rotary groove 204. The outside is formed by the applicator.

此時,由於滾筒116及旋轉槽204皆為金屬製,所以將親水性材料噴吹到該等滾筒116的外面或旋轉槽204的外面,並藉由烘烤這個而可塗覆,且可使塗料堅固。此外,親水性材料的烘烤溫度,是用比一般的有機物可能分解的溫度的250℃更高的溫度進行設定為理想,例如可用所謂300℃、500℃的溫度進行設定。藉由用這樣的高溫烘烤親水性材料,可幾乎或完全分解該親水性材料所含有的有機物,而可形成幾乎或完全被無機化的親水性能膜300。 At this time, since the drum 116 and the rotary groove 204 are both made of metal, the hydrophilic material is sprayed to the outside of the drum 116 or the outside of the rotary groove 204, and can be coated by baking, and can be The paint is strong. Further, the baking temperature of the hydrophilic material is preferably set to a temperature higher than 250 ° C which may be decomposed by a general organic substance, and may be set, for example, at a temperature of 300 ° C or 500 ° C. By baking the hydrophilic material at such a high temperature, the organic substance contained in the hydrophilic material can be almost or completely decomposed, and the hydrophilic property film 300 which is almost or completely inorganicized can be formed.

又,塗覆這種的材料時,在將材料噴吹到基材前,對該基材的表面進行脫脂的脫脂處理為一般。在本實施形態,由於作為基材的滾筒116及旋轉槽204皆為不銹鋼製,所以在親水性材料的噴吹前進行的脫脂處理,可使用例如PH14的強鹼性的脫脂劑進行脫脂。因此,可從作為基材的滾筒116的表面或旋轉槽204的表面幾乎或確實地去除油脂成分之後噴吹親水性材料,且對滾筒116的表面或旋轉槽204的表面容易塗佈親水性材料。 Further, when such a material is applied, the degreasing treatment for degreasing the surface of the substrate before blowing the material onto the substrate is common. In the present embodiment, since both the drum 116 and the rotary groove 204 as the base material are made of stainless steel, the degreasing treatment performed before the injection of the hydrophilic material can be degreased using a strong alkaline degreasing agent such as PH14. Therefore, the hydrophilic material can be sprayed from the surface of the drum 116 as the substrate or the surface of the rotary groove 204, or the hydrophilic material can be easily applied to the surface of the drum 116 or the surface of the rotary groove 204. .

又,在本實施形態,適用形成至少具有以下的性能的 親水性能膜300的親水性材料。亦即,本實施形態的親水性能膜300,是具有水的接觸角成為未滿相對於玻璃的水的接觸角的下限值的親水性能。一般可想到相對於玻璃的水的接觸角的下限值為20度。因此,在本實施形態,適用形成水的接觸角未滿20度之例如成為13度的親水性能膜300的親水性材料。 Further, in the present embodiment, it is applied to form at least the following properties. A hydrophilic material of the hydrophilic property film 300. In other words, the hydrophilic performance film 300 of the present embodiment has a hydrophilic property in which the contact angle of water is less than the lower limit of the contact angle of water with respect to the glass. It is generally conceivable that the lower limit of the contact angle of water with respect to the glass is 20 degrees. Therefore, in the present embodiment, a hydrophilic material which forms a hydrophilic performance film 300 of, for example, 13 degrees, in which the contact angle of water is less than 20 degrees is applied.

又,在本實施形態,作為形成親水性能膜300的親水性材料適用含有矽氧化物的材料,由該親水性材料所形成的親水性能膜300至少具有鉛筆硬度為5H以上的硬度特性。亦即,在本實施形態的親水性能膜300,是所謂形成有由矽氧烷骨架與強鹼性金屬或鹼土金屬形成的堅固構造,藉此,親水性能膜300具有所謂鉛筆硬度5H以上的堅固的構造。 Further, in the present embodiment, a material containing a cerium oxide is used as the hydrophilic material forming the hydrophilic performance film 300, and the hydrophilic performance film 300 formed of the hydrophilic material has at least a hardness characteristic of a pencil hardness of 5H or more. In other words, the hydrophilic performance film 300 of the present embodiment is formed with a strong structure formed of a siloxane skeleton and a strong alkali metal or an alkaline earth metal, whereby the hydrophilic property film 300 has a firmness of a pencil hardness of 5H or more. Construction.

又,本實施形態的親水性能膜300具有矽醇基,且成為其親水性能極高者。具體而言,親水性能膜300,是具有只讓水接觸附著在該親水性能膜300的一般的油性墨水便可去除的程度的親水性能。因此,即使讓一般的油性筆的墨水附著在親水性能膜300,也可藉由讓水接觸其部分,並可藉由水使該墨水浮起來加以剝離並去除。 Further, the hydrophilic performance film 300 of the present embodiment has a sterol group and is extremely high in hydrophilicity. Specifically, the hydrophilic performance film 300 has a hydrophilic property to such an extent that water can be removed only by contact with a general oily ink adhering to the hydrophilic performance film 300. Therefore, even if the ink of the general oil-based pen is attached to the hydrophilic performance film 300, it can be peeled off and removed by allowing water to contact the portion thereof and floating the ink by water.

又,本實施形態的親水性能膜300具有10μm以下的厚度,且其膜厚成為極薄者。亦即,一般想要提高親水性能時,必須重複親水性材料的塗覆,因此,會有所獲得的親水性能部的膜厚會有變厚的傾向。在本實施形態,適用藉由1次的親水性材料的塗覆及烘烤,便可形成具有極高 的親水性能的親水性能膜300的親水性材料。因此,即使不重複親水性材料的塗覆,也可形成具有極高的親水性能的親水性能膜300,藉此,可將親水性能膜300的厚度控制在所謂10μm以下的薄度。此外,在圖面,方便上將親水性能膜300的膜厚表現的比實際更厚。 Further, the hydrophilic performance film 300 of the present embodiment has a thickness of 10 μm or less and the film thickness thereof is extremely thin. That is, in general, when it is desired to improve the hydrophilic property, it is necessary to repeat the coating of the hydrophilic material, and therefore, the film thickness of the hydrophilic portion obtained tends to be thick. In the present embodiment, it is possible to form a very high temperature by applying and baking a hydrophilic material once. The hydrophilic property of the hydrophilic property of the membrane 300 is a hydrophilic material. Therefore, even if the coating of the hydrophilic material is not repeated, the hydrophilic property film 300 having extremely high hydrophilic properties can be formed, whereby the thickness of the hydrophilic property film 300 can be controlled to a thickness of 10 μm or less. Further, in the drawing, it is convenient to express the film thickness of the hydrophilic performance film 300 more than actually.

又,本實施形態的親水性能膜300,是所謂表面粗度在2μm以內。在本實施形態,適用形成有如此具有極為平滑的表面的親水性能膜300的親水性材料。又,在本實施形態所適用的親水性材料,在噴吹之前的狀態雖為乳白色,可是在噴吹之後成為幾乎不能判視乳白色的程度的透明,且在燒烤之後形成幾乎或完全的透明。 Further, the hydrophilic performance film 300 of the present embodiment has a surface roughness of 2 μm or less. In the present embodiment, a hydrophilic material in which the hydrophilic performance film 300 having such an extremely smooth surface is formed is applied. Further, the hydrophilic material to which the present embodiment is applied is milky white in the state before the blowing, but is transparent to the extent that it is almost impossible to judge milky white after the blowing, and is formed to be almost or completely transparent after the baking.

接著,針對為了評價本實施形態的洗衣機的防污性能所進行的試驗結果進行說明。於此,例如進行下述所示的「實用試驗」、「模擬污垢洗滌試驗」、以及「黴菌附著及發育抑制確認試驗」。此外,在各試驗,是例如使用在圖3模式表示試驗用的旋轉槽T作為展開圖,亦即,使用具備在側部外面的半周部Ra塗覆親水性能膜300,在剩餘的半周部Rb沒有塗覆親水性能膜300的旋轉槽T的試驗用的洗衣機。以下,將塗覆了親水性能膜300的部分Ra稱為「塗覆部Ra」,將沒有塗覆親水性能膜300的部分Rb稱為「未塗覆部Rb」。 Next, the test results performed to evaluate the antifouling performance of the washing machine of the present embodiment will be described. Here, for example, the "utility test", the "simulated soil washing test", and the "mold adhesion and development inhibition confirmation test" described below are performed. Further, in each test, for example, the rotary groove T for the test is shown in the mode of Fig. 3 as a developed view, that is, the hydrophilic performance film 300 is coated with the semicircular portion Ra provided on the outer surface of the side portion, and the remaining half-circumferential portion Rb is used. There is no test washing machine for coating the rotary tank T of the hydrophilic performance film 300. Hereinafter, the portion Ra to which the hydrophilic property film 300 is applied is referred to as "coating portion Ra", and the portion Rb to which the hydrophilic property film 300 is not applied is referred to as "uncoated portion Rb".

≪實用試驗≫ ≪Practical test≫

該「實用試驗」,是實際在A宅及B宅用在以下的 條件下使用試驗用的洗衣機。而且,在使用後用各自不同的布擦拭旋轉槽的塗覆部Ra的表面及未塗覆部Rb的表面,並將擦拭後各布的重量的增加量分別作為塗覆部Ra的污垢附著量、未塗覆部Rb的污垢附著量進行觀測。此外,污垢附著量的單位,是用「mg/25cm2」,亦即,用每25平方公分的重量表示。且,在使用後附著於旋轉槽的污垢,也可能包含在試驗運轉時所使用的洗劑類,更正確是也可能含有「在運轉終了後稍微殘存的洗劑類」。 This "practical test" is a washing machine that is actually used in the following conditions under the conditions of the A house and the B house. Further, after use, the surface of the coating portion Ra of the rotary groove and the surface of the uncoated portion Rb are wiped with different cloths, and the increase in the weight of each cloth after wiping is used as the amount of dirt adhering to the coating portion Ra, respectively. The amount of dirt adhering to the uncoated portion Rb was observed. Further, the unit of the amount of dirt adhesion is expressed by "mg/25 cm 2 ", that is, by weight per 25 square centimeters. Further, the dirt adhering to the rotary groove after use may include the lotion used in the test operation, and more accurately, it may contain "a lot of detergent which remains after the end of the operation".

‧A宅 ‧A house

例如如圖4所示,在A宅,是使用一般市售的液體洗劑a及柔軟完成劑a,進行通常的洗滌運轉,亦即進行75回「由洗衣行程、洗清行程、脫水行程形成的一般的洗滌運轉」,並進行30回通常的烘乾運轉。此外,在A宅,是使用浴池水進行運轉。 For example, as shown in Fig. 4, in the A house, the liquid washing agent a and the softening agent a which are generally commercially available are used, and the normal washing operation is performed, that is, 75 times "by the laundry stroke, the washing course, and the dehydration stroke. The general washing operation is performed, and 30 normal drying operations are performed. In addition, in the A house, it is operated using bath water.

此時,塗覆部Ra的污垢附著量,是在檢出界限值的「0.01mg/25cm2」以下。另一方面,未塗覆部Rb的污垢附著量,是在0.5mg/25cm2。亦即,在A宅的使用條件,可確認塗覆部Ra比未塗覆部Rb更能發揮高的防污性能。 At this time, the amount of the dirt adhering to the coating portion Ra is equal to or less than "0.01 mg / 25 cm 2 " of the detection limit value. On the other hand, the amount of dirt adhering to the uncoated portion Rb is 0.5 mg/25 cm 2 . In other words, in the use condition of the A house, it was confirmed that the coated portion Ra exhibited higher antifouling performance than the uncoated portion Rb.

‧B宅 ‧B House

例如如圖4所示,在B宅,是使用一般市售的粉末洗劑b與液體洗劑b以及柔軟完成劑b,進行通常的洗滌運 轉,亦即進行76回「由洗衣行程、洗清行程、脫水行程形成的一般的洗滌運轉」,並進行數回通常的烘乾運轉。此外,在B宅,是使用自來水進行運轉。 For example, as shown in FIG. 4, in the B house, a general commercially available powder lotion b, a liquid lotion b, and a soft finish agent b are used for the usual washing and transporting. Turning, that is, performing 76 "general washing operations by the laundry stroke, the washing course, and the dehydration stroke", and performing a plurality of normal drying operations. In addition, in the B house, it is operated using tap water.

此時,塗覆部Ra的污垢附著量,是在檢出界限值的「0.01mg/25cm2」以下。另一方面,未塗覆部Rb的污垢附著量,是在0.2mg/25cm2。亦即,在B宅的使用條件,也可確認塗覆部Ra比未塗覆部Rb更能發揮高的防污性能。此外,在圖5,以藉由該「實用試驗」所獲得的試驗結果來說,此時視覺性地表示「污垢附著量」。 At this time, the amount of the dirt adhering to the coating portion Ra is equal to or less than "0.01 mg / 25 cm 2 " of the detection limit value. On the other hand, the amount of dirt adhering to the uncoated portion Rb is 0.2 mg/25 cm 2 . In other words, in the use conditions of the B house, it was confirmed that the coating portion Ra exhibited higher antifouling performance than the uncoated portion Rb. In addition, in FIG. 5, the test result obtained by this "practical test" shows the "stain adhesion amount" visually at this time.

≪模擬污垢洗滌試驗≫ ≪ Simulated dirt washing test≫

在該「模擬污垢洗滌試驗」,是將模擬污垢附著的衣類投入試驗用的洗衣機的旋轉槽,執行預定次數的通常的洗滌運轉。然後,在執行預定次數的洗滌運轉之後,進行通常的槽洗淨運轉,亦即,進行「為了洗淨水槽內,而在該水槽內蓄積水,使旋轉槽旋轉的運轉」。此外,此時,讓大概2.8g的泥巴污垢及大概1.2g的豬油形成合計4.0左右的模擬污垢附著在衣類。又,在洗滌行程,是使用一般市售的粉末洗劑,而以作為洗滌用或洗清用的水來說,是使用硬度50ppm的水。 In the "simulated soil washing test", the clothes in which the simulated dirt adhered are put into the rotation tank of the washing machine for the test, and the normal washing operation is performed a predetermined number of times. Then, after the predetermined number of washing operations are performed, the normal tank washing operation is performed, that is, "the operation of storing the water in the water tank to rotate the rotating tank in order to clean the water tank". In addition, at this time, approximately 2.8 g of mud dirt and approximately 1.2 g of lard were formed to form a total of about 4.0 simulated soil adhering to the clothes. Further, in the washing course, a commercially available powder lotion is used, and water used for washing or washing is water having a hardness of 50 ppm.

在圖6,在該「模擬污垢洗滌試驗」表示進行槽洗淨運轉前與進行之後被觀測的塗覆部Ra的污垢附著量及未塗覆部Rb的污垢附著量。此外,此時在附著於旋轉槽的污垢,也可能包含在試驗運轉時所使用的洗劑類,更正確 是也可能含有「在運轉終了後稍微殘存的洗劑類」。 In the "simulated soil washing test", the amount of dirt adhering to the coating portion Ra and the amount of dirt adhering to the uncoated portion Rb before and after the tank washing operation are shown in Fig. 6 . In addition, the dirt adhering to the rotating tank at this time may also contain the lotion used in the test operation, which is more correct. It may also contain "a lot of detergents that remain after the end of the operation."

例如執行30回的通常的洗滌運轉時,塗覆部Ra的污垢附著量,在槽洗淨運轉前是在檢出界限值的「0.01mg/25cm2」以下,在槽洗淨後也在檢出界限值的「0.01mg/25cm2」以下。另一方面,未塗覆部Rb的污垢附著量,在槽洗淨運轉前是在0.3mg/25cm2,在槽洗淨後也在0.1mg/25cm2。亦即,在未塗覆部Rb相對於即使進行槽洗淨運轉也有0.1mg/25cm2的污垢殘存的情況,在塗覆部Ra,是即使不進行槽洗淨運轉也可將污垢的附著量抑制在檢出界限值以下。如此,可確認塗覆部Ra比未塗覆部Rb更能發揮高的防污性能。此外,在圖7(a),以執行30回的通常的洗滌運轉時的試驗結果來說,此時視覺性地表示「污垢附著量」。 For example, when the normal washing operation is performed for 30 times, the amount of dirt adhering to the coating portion Ra is equal to or less than "0.01 mg/25 cm 2 " of the detection limit value before the tank washing operation, and is also checked after the tank is washed. The limit value is "0.01 mg/25 cm 2 or less". On the other hand, the amount of dirt adhering to the uncoated portion Rb was 0.3 mg/25 cm 2 before the tank washing operation, and was also 0.1 mg/25 cm 2 after the tank washing. In other words, in the case where the uncoated portion Rb has 0.1 mg/25 cm 2 of dirt remaining even in the tank washing operation, the coating portion Ra is a scale capable of adhering dirt even without performing the tank washing operation. The suppression is below the detection limit value. Thus, it was confirmed that the coating portion Ra can exhibit higher antifouling performance than the uncoated portion Rb. In addition, in FIG. 7(a), the test result at the time of the normal washing operation of 30 times is performed, and the "soil adhesion amount" is visually shown at this time.

又,例如執行90回的通常的洗滌運轉時,塗覆部Ra的污垢附著量,在槽洗淨運轉前是在檢出界限值的「0.01mg/25cm2」以下,在槽洗淨後也在檢出界限值的「0.01mg/25cm2」以下。另一方面,未塗覆部Rb的污垢附著量,在槽洗淨運轉前是在0.7mg/25cm2,在槽洗淨後也在0.3mg/25cm2。亦即,在未塗覆部Rb相對於即使進行槽洗淨運轉也有0.3mg/25cm2的污垢殘存的情況,在塗覆部Ra,是即使不進行槽洗淨運轉也可將污垢的附著量抑制在檢出界限值以下。如此,可確認塗覆部Ra比未塗覆部Rb更能發揮高的防污性能。此外,在圖7(b),以執行90回的通常的洗滌運轉時的試驗結果來說,此時視覺 性地表示「污垢附著量」。 In addition, for example, when the normal washing operation is performed for 90 times, the amount of dirt adhering to the coating portion Ra is equal to or less than "0.01 mg/25 cm 2 " of the detection limit value before the tank washing operation, and after the tank is washed. It is below the detection limit value of "0.01mg/25cm 2 ". On the other hand, the amount of dirt adhering to the uncoated portion Rb was 0.7 mg/25 cm 2 before the tank washing operation, and was also 0.3 mg/25 cm 2 after the tank washing. In other words, in the case where the uncoated portion Rb has a residual amount of 0.3 mg/25 cm 2 even if the tank cleaning operation is performed, the coating portion Ra can be used to remove the dirt even if the tank washing operation is not performed. The suppression is below the detection limit value. Thus, it was confirmed that the coating portion Ra can exhibit higher antifouling performance than the uncoated portion Rb. In addition, in FIG. 7(b), the result of the test at the time of the normal washing operation of 90 times is performed, and the "soil adhesion amount" is visually shown at this time.

≪黴菌附著及發育抑制確認試驗≫ Test for confirming the adhesion and developmental inhibition of mites

該「黴菌附著及發育抑制確認試驗」,是以下的內容。 The "mold adhesion and development inhibition confirmation test" is as follows.

‧試驗對象部位 ‧ test subject

如圖8所示,以塗覆部Ra中用虛線表示的12處,亦即,「縱3列×橫4列」的12處,及未塗覆部Rb中用虛線表示的12處,亦即,「縱3列×橫4列」的12處作為試驗對象部位。此外,各試驗對象部位的大小,是具有80mm×32mm的面積,亦即,具有相當於25cm2的面積。 As shown in Fig. 8, 12 points indicated by broken lines in the coating portion Ra, that is, 12 positions of "3 columns in length × 4 rows in width" and 12 portions indicated by broken lines in the uncoated portion Rb are also In other words, 12 points of "3 columns in length × 4 columns in width" are used as test target portions. Further, the size of each test target portion has an area of 80 mm × 32 mm, that is, an area equivalent to 25 cm 2 .

‧運轉條件 ‧ Operating conditions

進行由接下來的行程形成的洗滌運轉。 A washing operation formed by the next stroke is performed.

洗滌運轉:洗衣行程→第1中間脫水行程→第1洗清行程→第2中間脫水行程→第2洗清行程→最終脫水行程 Washing operation: washing stroke → first intermediate dehydration stroke → first washing stroke → second intermediate dehydration stroke → second washing stroke → final dehydration stroke

‧試驗所使用的黴菌 ‧ mold used in the test

在試驗,是使用接下來的黴菌。 In the test, the next mold was used.

Exophiala dermatitidis NBRC 6421(外瓶黴) Exophiala dermatitidis NBRC 6421 (outside mold)

‧試驗方法(概略) ‧Test method (summary)

使用上述的試驗用的洗衣機,在旋轉槽T的塗覆部Ra及未塗覆部Rb塗佈黴菌孢子液,亦即塗佈「含有上述 的黴菌的孢子的液體」。然後,放置24小時後,擦拭塗佈了黴菌孢子液之處。之後,實施上述的洗滌運轉,在洗滌運轉終了後同樣擦拭上述的地方。再者,放置3天後,同樣擦拭上述的地方。再者,放置7天後,同樣擦拭上述的地方。利用周知的培養法培養在上述的各時機所擦拭的黴菌並加以計算。然後,依據其計算結果,評價親水性塗材的有無對於黴菌的去除效果及發育抑制效果。以下,表示該試驗的詳細。 Using the washing machine for the test described above, the mold spore liquid is applied to the coating portion Ra of the rotary tub T and the uncoated portion Rb, that is, the coating "containing the above The mold of the spore liquid". Then, after standing for 24 hours, the place where the mold spore liquid was applied was wiped off. Thereafter, the above washing operation is carried out, and the above-mentioned places are also wiped after the end of the washing operation. Furthermore, after standing for 3 days, the above places were also wiped. Furthermore, after standing for 7 days, the same place was also wiped. The mold wiped at each of the above timings was cultured by a known culture method and calculated. Then, based on the calculation results, the presence or absence of the hydrophilic coating material for the mold removal effect and the development inhibition effect was evaluated. The details of the test are shown below.

(1)污垢對旋轉槽的附著 (1) Adhesion of dirt to the rotating groove

將模擬污垢所附著的衣類投入旋轉槽,執行25回上述的洗滌運轉。藉此,讓污垢附著在旋轉槽。 The clothes to which the simulated dirt adhered were placed in a rotating tank, and the above washing operation was performed 25 times. Thereby, the dirt is allowed to adhere to the rotating groove.

(2)黴菌孢子液的塗佈 (2) Coating of mold spore solution

在塗覆部Ra的試驗對象部位,將約107CFU/ml(CFU:colony forming unit)的黴菌孢子液分開任意20處各滴下10μl(10μL×20處),花約3小時讓其乾燥。另一方面,在未塗覆部Rb的試驗對象部位,滴下20μl約108CFU/ml的黴菌孢子液,並用菌液塗抹棒塗開。 In the test target portion of the coating portion Ra, about 10 7 CFU/ml (CFU: colony forming unit) of the mold spore solution was dropped into 10 μl (10 μL × 20 portions) at any of 20 places, and it was allowed to dry for about 3 hours. On the other hand, 20 μl of about 10 8 CFU/ml of the mold spore solution was dropped on the test target portion of the uncoated portion Rb, and spread with a bacterial solution stick.

此外,塗覆部Ra因塗覆而具備極高的親水性能,而相對於此,未塗覆部Rb並不具備親水性能。因此,兩者的表面的性質不同,在兩者用同樣的塗佈方法塗佈黴菌孢子液是困難的。因此,在該試驗,在塗覆部Ra的試驗對象部位及未塗覆部Rb的試驗對象部位,用各自不同的塗 佈方法塗佈黴菌孢子液。此外,在塗佈方法不同的兩者被塗佈的黴菌孢子液的量是相同的。 Further, the coating portion Ra has extremely high hydrophilic properties due to coating, whereas the uncoated portion Rb does not have hydrophilic properties. Therefore, the properties of the surfaces of the two are different, and it is difficult to apply the mold spore solution by the same coating method. Therefore, in this test, the test target portion of the coating portion Ra and the test target portion of the uncoated portion Rb are coated with different ones. The cloth method coats the mold spore solution. Further, the amount of the mold spore liquid applied to both of the coating methods was the same.

(3)試驗操作 (3) Test operation

如上述將黴菌孢子液塗佈在試驗對象部位使其乾燥之後,關閉洗衣機的門扇放置24小時。在該放置期間,洗衣機內部,溫度在21.5~25.8℃左右,相對濕度(RH:Relative Humidity)在65~87%左右。24小時放置後,在進行上述的洗滌運轉之前,用滅菌粒條亦即「拭菌用紗布」擦拭塗覆部Ra的試驗對象部位中的任意3處(在圖9以n1、n2、n3表示);及未塗覆部Rb的試驗對象部位中的任意的3處(在圖9以n1、n2、n3表示)。之後,進行上述的洗滌運轉,同樣擦拭,並關閉門扇再放置。在該放置期間,洗衣機內部,溫度在22.8~26.6℃左右,相對濕度(RH:Relative Humidity)大概在90%以上。進一步,在放置起3日後同樣進行擦拭。進一步,在7日後同樣進行擦拭。在上述的各時機擦拭後的滅菌粒條,是與培養基一起放入各自的滅菌用袋。然後,藉由周知的均漿器(Stomachere)處理,亦即藉由「粉碎樣品予以均質化後在抽出菌類進行處理」,洗出黴菌。 After the mold spore solution was applied to the test subject portion and dried as described above, the door leaf of the washing machine was turned off for 24 hours. During the placement, the temperature inside the washing machine is about 21.5~25.8 °C, and the relative humidity (RH: Relative Humidity) is about 65~87%. After the above-described washing operation, any three of the test target portions of the coated portion Ra are wiped with a sterilized granular strip, that is, n1, n2, and n3. And any three of the test target portions of the uncoated portion Rb (indicated by n1, n2, and n3 in Fig. 9). Thereafter, the above washing operation is performed, and the same is wiped, and the door leaf is closed and placed. During the placement, the temperature inside the washing machine is about 22.8~26.6 °C, and the relative humidity (RH: Relative Humidity) is about 90%. Further, the wiping was performed similarly 3 days after the placement. Further, the wiping was performed similarly after 7 days. The sterilized pellets wiped at each of the above timings are placed in respective sterilization bags together with the medium. Then, the mold is washed out by a well-known homogenizer (Stomachere), that is, by "pulverizing the sample and homogenizing and then extracting the fungus."

(4)黴菌數量的計測 (4) Measurement of mold quantity

將從滅菌粒條被洗出的液體作為樣品液,利用生理食鹽水液將其樣品液分別調整成10階段的濃度的稀釋液。 然後,將其樣品液及稀釋液各0.1ml塗布在PDA培養基。又,用薄膜過濾器過濾1ml的樣品液,並將其薄膜過濾器黏貼在其他的PDA培養基的表面。將該等培養基在約28℃(28℃±1℃)培養7天。之後,計測發育後的集落亦即「菌落」的數量,求取每25cm2的黴菌數。 The liquid washed out from the sterilized pellets was used as a sample solution, and the sample solution was adjusted to a 10-stage dilution by a physiological saline solution. Then, 0.1 ml of each of the sample solution and the diluent was applied to a PDA medium. Further, 1 ml of the sample solution was filtered with a membrane filter, and the membrane filter was adhered to the surface of other PDA medium. The medium was incubated at about 28 ° C (28 ° C ± 1 ° C) for 7 days. Thereafter, the number of colonies after development, that is, the number of "colony" was measured, and the number of molds per 25 cm 2 was determined.

(5)黴菌數的去除率的算出 (5) Calculation of removal rate of mold number

藉由以下的式子,算出黴菌數的去除率(%)。 The removal rate (%) of the number of molds was calculated by the following formula.

去除率=(1-(B/A))×100 Removal rate = (1-(B/A)) × 100

A:洗滌運轉前的黴菌數 A: Number of molds before washing operation

B:洗滌運轉後的黴菌數 B: Number of molds after washing operation

‧試驗結果 ‧test results

在圖9表示其試驗結果。亦即,洗滌運轉終了後第0日的黴菌數的去除率,在塗覆部Ra大概99.92%左右,而相對於此,在未塗覆部Rb大概94.3%左右。此外,洗滌運轉終了後第3天起到第7天,在塗覆部Ra及未塗覆部Rb黴菌皆沒有增殖。這是因為可推測與黴菌一起被塗佈的營養素因洗滌運轉而被洗掉。 The test results are shown in Fig. 9. That is, the removal rate of the number of molds on the 0th day after the end of the washing operation is about 99.92% in the coating portion Ra, and about 94.3% in the uncoated portion Rb. Further, on the third day from the end of the washing operation to the seventh day, no mold was propagated in the coated portion Ra and the uncoated portion Rb. This is because it is presumed that the nutrient coated with the mold is washed away by the washing operation.

根據以上的試驗結果,可觀測到在塗覆部Ra有極高的或然率,此時,近100%的或然率去除了黴菌,因此,塗覆部Ra可確認比未塗覆部Rb可發揮更高的防污性能。 According to the above test results, it is observed that there is an extremely high probability in the coating portion Ra, and at this time, the probability of nearly 100% is removed, and therefore, the coating portion Ra can be confirmed to be higher than the uncoated portion Rb. Antifouling properties.

根據本實施形態的洗衣機100、200,在可旋轉地被 設在水槽108、202內的旋轉槽116、204的側部的外面具有極高的親水性能的親水性能膜300。根據該構成,可藉由親水性能膜300所為的防污功能保持不能容易進行手不能達到的清掃等維護的旋轉槽116、204的側部的外面的清潔,且在洗衣機100、200可最有效地活用親水性所為的防污功能。 The washing machines 100 and 200 according to the present embodiment are rotatably The hydrophilic performance film 300 having extremely high hydrophilic properties is provided on the outer surface of the side portions of the rotary grooves 116, 204 in the water tanks 108, 202. According to this configuration, the antifouling function of the hydrophilic performance film 300 can keep the outer surface of the side portions of the rotary grooves 116 and 204 that cannot be easily maintained by maintenance such as cleaning, and the washing machine 100 and 200 can be most effective. It uses the antifouling function of hydrophilicity.

又,根據洗衣機100、200,由於在旋轉的旋轉槽116、204的側部的外面具備親水性能膜300,所以在旋轉槽116、204的旋轉時,從該旋轉槽的表面剝離的污垢也受到離心力的作用而容易被去除,而可進一步維持旋轉槽116、204的表面的清潔。 Further, according to the washing machines 100 and 200, since the hydrophilic performance film 300 is provided on the outer surface of the side portions of the rotating rotary grooves 116 and 204, the dirt peeled off from the surface of the rotary groove during the rotation of the rotary grooves 116 and 204 is also affected. The centrifugal force is easily removed, and the surface of the rotary grooves 116, 204 can be further cleaned.

又,根據洗衣機100、200,親水性能膜300是被設在旋轉槽116、204的側部的外面整體。因此,可藉由親水性能膜300所為防污功能保持旋轉槽116、204的側部的外面整體的清潔。又,根據洗衣機100、200,旋轉槽116、204並不是合成樹脂製而是金屬製,所以藉由對旋轉槽116、204的金屬部分的外面烘烤親水性材料可進行被覆。藉此,可形成被高度無機化的堅固且具有耐久性的親水性能膜300。 Further, according to the washing machines 100 and 200, the hydrophilic performance film 300 is provided on the outer surface of the side portions of the rotary grooves 116 and 204 as a whole. Therefore, the entire outer surface of the rotary grooves 116, 204 can be kept clean by the antifouling function of the hydrophilic performance film 300. Further, according to the washing machines 100 and 200, since the rotary grooves 116 and 204 are not made of synthetic resin but made of metal, the hydrophilic material can be coated by baking the outer surface of the metal portions of the rotary grooves 116 and 204. Thereby, a highly hydrophilic and durable hydrophilic property film 300 which is highly inorganicized can be formed.

又,根據洗衣機100、200,親水性能膜300,是水的接觸角為相對於玻璃的水的接觸角的未滿下限值,且具有矽醇基。因此,親水性能膜300可發揮極高的親水性能。因此,水容易浸入親水性能膜300的表面與附著在該親水性能膜300的污垢之間,而可使附著在親水性能膜300的 污垢浮起並加以去除。 Further, according to the washing machines 100 and 200, the hydrophilic performance film 300 has a contact angle of water of a lower limit value of a contact angle with respect to water of the glass, and has a sterol group. Therefore, the hydrophilic property film 300 can exert extremely high hydrophilic properties. Therefore, water is easily immersed between the surface of the hydrophilic property film 300 and the dirt adhering to the hydrophilic property film 300, and can be attached to the hydrophilic property film 300. The dirt floats and is removed.

又,根據洗衣機100、200,親水性能膜300具有矽氧化物,而具有鉛筆硬度成為5H以上的硬度特性。因此,可防止傷到親水性能膜300,而使親水性能膜300剝落的情況。又,根據洗衣機100、200,親水性能膜300,是10μm以下的厚度,能實現極薄的親水性能膜300。又,根據洗衣機100、200,親水性能膜300,其表面粗度在2μm以內,能實現極平滑的親水性能膜300。 Moreover, according to the washing machines 100 and 200, the hydrophilic performance film 300 has a cerium oxide and has a pencil hardness of 5H or more. Therefore, it is possible to prevent the hydrophilic property film 300 from being damaged and the hydrophilic property film 300 from being peeled off. Further, according to the washing machines 100 and 200, the hydrophilic performance film 300 has a thickness of 10 μm or less, and an extremely thin hydrophilic film 300 can be realized. Further, according to the washing machines 100 and 200, the hydrophilic performance film 300 has a surface roughness of 2 μm or less, and an extremely smooth hydrophilic property film 300 can be realized.

又,洗衣機100,也可進一步作成在安裝在滾筒116的金屬製的螺絲、或在滾筒116的內面也具備親水性能膜300的構造。又,洗衣機200,也可進一步作成在安裝在滾筒204的金屬製的螺絲206a、或在旋轉槽204的內面也具備親水性能膜300的構造。亦即,在本實施形態形成親水性能膜300的部分,並不限於滾筒116的側部的外面或旋轉槽204的側面的外面。此外,在金屬製的螺絲形成親水性能膜300的時候,不必在螺絲整體形成親水性能膜300,只要在成為其外面的螺絲頭的表面形成親水性能膜300就足夠。又,在滾筒116或旋轉槽204的內面形成親水性能膜300時,也可在內面整體形成親水性能膜300,也可在內面的一部分形成親水性能部300。 Further, the washing machine 100 may be further configured to have a metal screw attached to the drum 116 or a hydrophilic performance film 300 on the inner surface of the drum 116. Further, the washing machine 200 may be further configured to have a metal screw 206a attached to the drum 204 or a hydrophilic performance film 300 on the inner surface of the rotary groove 204. That is, the portion in which the hydrophilic performance film 300 is formed in the present embodiment is not limited to the outer surface of the side portion of the drum 116 or the outer surface of the side surface of the rotary groove 204. Further, when the metal-made screw forms the hydrophilic performance film 300, it is not necessary to form the hydrophilic property film 300 as a whole in the screw, and it is sufficient to form the hydrophilic property film 300 on the surface of the screw head which is the outer surface. Further, when the hydrophilic performance film 300 is formed on the inner surface of the drum 116 or the rotary groove 204, the hydrophilic performance film 300 may be formed entirely on the inner surface, or the hydrophilic performance portion 300 may be formed on a part of the inner surface.

又,親水性能膜300也可被著色。亦即,作為形成親水性能膜300的親水性材料,也可適用在對基材噴吹之後及烘烤之後留下顏色的材料。藉此,可容易用目視等確認在被形成的親水性能膜300上是否有不均產生,例如可將 沒有被均一地形成親水性能膜300的旋轉槽特定為不良品。 Further, the hydrophilic performance film 300 can also be colored. That is, as the hydrophilic material forming the hydrophilic property film 300, a material which leaves a color after the substrate is blown and after baking can be applied. Thereby, it is easy to visually confirm whether or not unevenness is generated on the formed hydrophilic performance film 300 by visual observation or the like, for example, The rotary groove which is not uniformly formed with the hydrophilic performance film 300 is specified as a defective product.

又,在洗衣機100、200,也可在包含洗滌行程、洗清行程、脫水行程等的洗滌行程的終了後或在該洗滌行程的執行中設定,執行將水蓄積在水槽108、202使滾筒116、旋轉槽204旋轉的洗淨行程。在該洗淨行程,藉由水接觸親水性能膜300,可去除附著在該親水性能膜300的污垢。此外,在該洗淨行程,是根據洗滌行程使蓄積在水槽108、202的內部的水量增加,並用比洗滌行程或洗清行程的旋轉速度更快的速度設定滾筒116、旋轉槽204的旋轉速度即可。 Further, the washing machines 100 and 200 may be set after the end of the washing course including the washing course, the washing course, the dehydration course, or the like, or during the execution of the washing course, and the water is stored in the water tanks 108 and 202 to make the drum 116. The washing stroke of the rotation groove 204 is rotated. In the washing course, the hydrophilic film 300 is contacted with water to remove the dirt adhering to the hydrophilic film 300. Further, in the washing course, the amount of water accumulated in the inside of the water tanks 108, 202 is increased in accordance with the washing stroke, and the rotation speed of the drum 116 and the rotary groove 204 is set at a speed faster than the rotation speed of the washing stroke or the washing stroke. Just fine.

又,根據洗衣機100、200也可期待親水性能膜300所為的防鏽效果。 Further, the rust preventive effect of the hydrophilic performance film 300 can also be expected from the washing machines 100 and 200.

(第2實施形態) (Second embodiment)

本實施形態,並不是在滾筒116的側部的外面整體或旋轉槽204的側部的外面整體設置親水性能膜300,而是在滾筒116側部的外面的一部分或旋轉槽204側部的外面的一部分設置親水性能膜300者。 In the present embodiment, the hydrophilic performance film 300 is not integrally provided on the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204, but is a part of the outer surface of the side portion of the drum 116 or the outer side of the side of the rotary groove 204. Part of the hydrophilic performance film 300 is set.

亦即,如圖10或圖11所示,在洗衣機100的滾筒116的側部或洗衣機200的旋轉槽204的側部,是在洗滌運轉時或洗清運轉時蓄積在水槽108內或蓄積在水槽202內的水接觸比由一點鏈線所示的設定水位L更低的部分。因此,滾筒116側部的外面或旋轉槽204側部的外面中比 設定水位L更低的部分即使不設親水性能膜300也可比較清潔地保持。可是,滾筒116側面的外面或旋轉槽204側部的外面中比設定水位L更高的位置的部分,是在洗滌運轉時或洗清運轉時蓄積在水槽108內或水槽202內的水不易接觸的部位,因此污垢容易殘留。 That is, as shown in FIG. 10 or FIG. 11, the side portion of the drum 116 of the washing machine 100 or the side portion of the rotation groove 204 of the washing machine 200 is accumulated in the water tank 108 or accumulated in the washing operation or the washing operation. The water in the water tank 202 is in contact with a portion lower than the set water level L indicated by the one-point chain line. Therefore, the outer side of the side of the drum 116 or the outer side of the side of the rotary groove 204 is more than The portion where the water level L is set lower can be relatively cleanly maintained even if the hydrophilic property film 300 is not provided. However, the outer surface of the side surface of the drum 116 or the outer surface of the side portion of the rotary groove 204 is higher than the position where the water level L is set, and the water accumulated in the water tank 108 or the water tank 202 during the washing operation or the washing operation is not easily contacted. The part, so the dirt is easy to remain.

因此,在本實施形態,是如圖10或圖11所示,在滾筒116側部的外面或旋轉槽204側部的外面中比設定水位L更高的部分設有親水性能膜300。藉此,可在滾筒116側部的外面或旋轉槽204側部的外面中,尤其在污垢容易殘留的部分集中賦予親水性能,而可有效活用其親水性能所為的防污功能。又,可謀求親水性材料的使用量的減低。此外,因為設定水位L可變更,所以按照所想定的水位適宜調整形成親水性能膜300的區域即可。此時,形成親水性能膜300的區域,例如在洗衣機100、200中包含可設定的最低水位,或包含到該水位有可變動的可能性的範圍為止廣泛地設定 Therefore, in the present embodiment, as shown in FIG. 10 or FIG. 11, the hydrophilic performance film 300 is provided in a portion of the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204 that is higher than the set water level L. Thereby, the hydrophilic property can be imparted to the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204, particularly in a portion where the dirt easily remains, and the antifouling function by the hydrophilic property can be effectively utilized. Moreover, the amount of use of the hydrophilic material can be reduced. Further, since the set water level L can be changed, the region where the hydrophilic performance film 300 is formed can be appropriately adjusted in accordance with the desired water level. At this time, the region where the hydrophilic performance film 300 is formed, for example, includes the settable minimum water level in the washing machines 100 and 200, or is widely set to include a range in which the water level is variable.

(第3實施形態) (Third embodiment)

本實施形態,並不是在滾筒116的側部的外面整體或旋轉槽204的側部的外面整體設置親水性能膜300,而是在滾筒116側部的外面的一部分或旋轉槽204側部的外面的一部分設置親水性能膜300者。 In the present embodiment, the hydrophilic performance film 300 is not integrally provided on the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204, but is a part of the outer surface of the side portion of the drum 116 or the outer side of the side of the rotary groove 204. Part of the hydrophilic performance film 300 is set.

亦即,如上述,滾筒116側部的外面或旋轉槽204側部的外面中比設定水位L更低的部分,雖是水容易接觸且 比較清潔地被保持的部分,可是並不是完全不會殘留污垢的部分。尤其,滾筒116側面的外面或旋轉槽204側部的外面中比設定水位L在更低的位置的部分,是在洗滌運轉時或洗清運轉時水接觸的部分。因此,污垢殘留在該部分時,其污垢因時間變化等而變質,且變質後的污垢在洗滌運轉中或洗清運轉中會有移轉到洗滌物的可能性。 That is, as described above, the outer surface of the side portion of the drum 116 or the outer portion of the side portion of the rotary groove 204 is lower than the set water level L, although water is easily contacted. The portion that is relatively cleanly held, but not the part that does not completely leave the dirt. In particular, the outer surface of the side surface of the drum 116 or the outer surface of the side portion of the rotary groove 204 at a position lower than the set water level L is a portion where water contacts during the washing operation or the washing operation. Therefore, when the dirt remains in this portion, the dirt is deteriorated due to a change in time or the like, and the deteriorated dirt may be transferred to the laundry during the washing operation or the washing operation.

因此,在本實施形態,是如圖12或圖13所示,在滾筒116側部的外面或旋轉槽204側部的外面中比設定水位L在更低的部分設有親水性能膜300。藉此,可在滾筒116側部的外面或旋轉槽204側部的外面中,會有污垢殘留在比較清潔地被保持者的可能性的部分,集中賦予作為親水性能,且可防止在洗滌運轉時或洗清運轉時變質的污垢轉移到洗滌物的情況。又,可謀求親水性材料的使用量的減低。此外,因為設定水位L可變更,所以按照所想定的水位適宜調整形成親水性能膜300的區域即可。此時,形成親水性能膜300的區域,例如在洗衣機100、200中包含可設定的最低水位,或包含到該水位有可變動的可能性的範圍為止廣泛地設定 Therefore, in the present embodiment, as shown in Fig. 12 or Fig. 13, the hydrophilic performance film 300 is provided on the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204 at a lower portion than the set water level L. Thereby, in the outer surface of the side portion of the drum 116 or the outer surface of the side portion of the rotary groove 204, there is a possibility that the dirt remains in the relatively cleanly held portion, and the concentration is imparted as a hydrophilic property, and the washing operation can be prevented. At the time of washing or washing, the deteriorated dirt is transferred to the laundry. Moreover, the amount of use of the hydrophilic material can be reduced. Further, since the set water level L can be changed, the region where the hydrophilic performance film 300 is formed can be appropriately adjusted in accordance with the desired water level. At this time, the region where the hydrophilic performance film 300 is formed, for example, includes the settable minimum water level in the washing machines 100 and 200, or is widely set to include a range in which the water level is variable.

(其他的實施形態) (Other embodiments)

本實施形態,是可例如如以下地擴張或變形。 This embodiment can be expanded or deformed, for example, as follows.

例如如圖14所示,洗衣機100進一步也可作成在滾筒116的背面部的底部的外面也具備親水性能膜300的構成。此時,也可在滾筒116的背面部的外面整體設置親水 性能膜300,在滾筒116的背面部的外面的一部分也可設置親水性能膜300。又,雖未圖示,可是洗衣機200,是例如由不鏽鋼等形成的金屬構成底部的第2構件204b的時候,也可作成在由其金屬製的第2構件所形成的底部的外面具備親水性能膜300的構造。此時,在金屬製的底面的外面整體也可設置親水性能膜300,在金屬製的底面的外面的一部分也可設置親水性能膜300。 For example, as shown in FIG. 14, the washing machine 100 may further have a configuration in which the hydrophilic performance film 300 is provided on the outer surface of the bottom portion of the back surface portion of the drum 116. At this time, it is also possible to provide a hydrophilic whole on the outer surface of the back portion of the drum 116. The performance film 300 may be provided with a hydrophilic performance film 300 on a portion of the outer surface of the back surface portion of the drum 116. Further, although not shown, the washing machine 200 may have a hydrophilic property on the outer surface of the bottom portion formed of the second member made of metal when the second member 204b of the bottom portion is made of a metal formed of stainless steel or the like. The construction of the membrane 300. At this time, the hydrophilic performance film 300 may be provided on the entire outer surface of the metal bottom surface, and the hydrophilic performance film 300 may be provided on a part of the outer surface of the metal bottom surface.

又,例如如圖15所示,洗衣機100也可進一步作成在補強構成滾筒116的背面部的底部的補強構件117也具備親水性能膜300的構造。此時,也可在補強構件117的表面整體設置親水性能膜300,也可在補強構件117的表面的一部分設置親水性能膜300。又,例如如圖16所示,洗衣機200也可進一步作成在補強旋轉槽204的底部的補強構件204c具備親水性能膜300的構造。此時,也可在補強構件204c的表面整體設置親水性能膜300,也可在補強構件204c的表面的一部分設置親水性能膜300。又,在補強構件204c的上面及下面的雙方也可設置親水性能膜300,在補強構件204c的上面及下面的任一方也可設置親水性能膜300。 Further, for example, as shown in FIG. 15, the washing machine 100 may further have a structure in which the reinforcing member 117 that reinforces the bottom portion of the back surface portion of the drum 116 also has the hydrophilic performance film 300. At this time, the hydrophilic performance film 300 may be provided on the entire surface of the reinforcing member 117, or the hydrophilic performance film 300 may be provided on a part of the surface of the reinforcing member 117. Moreover, for example, as shown in FIG. 16, the washing machine 200 may further have a structure in which the reinforcing member 204c at the bottom of the reinforcing rotary groove 204 is provided with the hydrophilic performance film 300. At this time, the hydrophilic performance film 300 may be provided on the entire surface of the reinforcing member 204c, or the hydrophilic performance film 300 may be provided on a part of the surface of the reinforcing member 204c. Further, the hydrophilic performance film 300 may be provided on both the upper surface and the lower surface of the reinforcing member 204c, and the hydrophilic performance film 300 may be provided on either of the upper surface and the lower surface of the reinforcing member 204c.

又,例如圖17(a)所示,洗衣機100、200也可作成在構成孔118、205的內周面的端面118a、205a不具備親水性能膜300的構造,例如如圖17(b)所示,洗衣機100、200也可作成在孔118、205的端面118a、205a具備親水性能膜300的構造。 Further, for example, as shown in Fig. 17 (a), the washing machines 100 and 200 may have a structure in which the end faces 118a and 205a constituting the inner circumferential surfaces of the holes 118 and 205 do not have the hydrophilic performance film 300, for example, as shown in Fig. 17 (b). It is to be noted that the washing machines 100 and 200 may have a structure in which the hydrophilic performance film 300 is provided on the end faces 118a and 205a of the holes 118 and 205.

在第1實施形態所示的試驗結果,可推測即使在其他的實施形態的洗衣機進行同樣的試驗時也能同樣獲得。 The test results shown in the first embodiment can be similarly obtained even when the same test is carried out in the washing machine of another embodiment.

又,也可適當組合上述的各實施形態及變形實施形態加以實施。 Further, the above-described respective embodiments and modified embodiments may be combined as appropriate.

以上所說明的各實施形態的洗衣機,是在可旋轉地被設在水槽內旋轉槽具備親水性能部。根據該構成,可在洗衣機能保持不能容易進行手不能達到的清掃等維護的部分之旋轉槽的清潔,且可最有效地活用親水性所為的防污功能。 The washing machine according to each of the embodiments described above is provided with a hydrophilic performance portion in a rotary groove that is rotatably provided in the water tank. According to this configuration, it is possible to clean the rotary tub in a portion where the washing machine can not easily perform maintenance such as cleaning that cannot be reached by hand, and it is possible to most effectively utilize the antifouling function of hydrophilicity.

又,根據各實施形態的洗衣機,如由上述的各試驗結果可明白,藉由在旋轉槽施予親水性的塗料,可達成抑制黴菌的繁殖的效果、抑制污垢的附著的效果、抑制洗劑類的附著的效果等之優秀的效果。 Moreover, according to the test results of the above-described respective embodiments, it is understood that by applying a hydrophilic coating material to the rotating tank, the effect of inhibiting the growth of mold, the effect of suppressing the adhesion of dirt, and the suppression of the lotion can be achieved. Excellent effect such as the effect of adhesion of the class.

又,在沒有塗覆親水性材料的通常的不銹鋼製的旋轉槽,例如即使每月使用氯氣系的槽洗淨劑進行1次左右的槽洗淨運轉,也會慢慢堆積污垢。根據本實施形態的洗衣機,依據上述的試驗結果可確認藉由在旋轉槽塗覆親水性材料,即使重複洗滌運轉污垢也幾乎不會堆積。因此,可抑制槽洗淨運轉的實施頻率,或可不需要槽洗淨運轉,且可減低伴隨槽洗淨運轉的運轉成本,亦即可減低例如槽洗淨劑、水、電等的使用量、費用等。 In addition, in a normal stainless steel rotary groove which is not coated with a hydrophilic material, for example, even if a chlorine gas-based tank detergent is used for a tank cleaning operation once a month, dirt is gradually accumulated. According to the washing machine of the present embodiment, it has been confirmed from the above test results that the hydrophilic material is applied to the rotary groove, and the dirt is hardly accumulated even if the washing operation is repeated. Therefore, it is possible to suppress the frequency of implementation of the tank washing operation, or to eliminate the need for the tank washing operation, and to reduce the running cost associated with the tank washing operation, and to reduce the amount of use such as tank detergent, water, electricity, etc. Fees, etc.

此外,上述的各實施形態,是作為例子所提示者,並沒有限定發明的範圍的意圖。該等新規的實施形態可在其他的各式各樣的形態被實施,在不脫離發明的要旨的範 圍,可進行各種的的省略、置換、變更。本實施形態及其變形,是包含在發明的範圍、要旨,並且,包含在申請專利範圍的範圍所記載的發明與其均等的範圍。 Further, each of the above-described embodiments is presented as an example, and does not limit the scope of the invention. The implementation of these new rules can be implemented in a variety of other forms, without departing from the gist of the invention. Various omissions, substitutions, and changes can be made. The present invention and its modifications are intended to be included in the scope of the invention and the scope of the invention as defined in the scope of the claims.

100‧‧‧洗衣機 100‧‧‧Washing machine

101‧‧‧外箱 101‧‧‧Outer box

102‧‧‧基台 102‧‧‧Abutment

103‧‧‧箱本體 103‧‧‧ box body

104‧‧‧洗滌物出入口 104‧‧‧Washing entrances and exits

105‧‧‧門扇 105‧‧‧ door leaf

106‧‧‧操作面板 106‧‧‧Operator panel

107‧‧‧控制裝置 107‧‧‧Control device

108‧‧‧水槽 108‧‧‧Sink

109‧‧‧懸吊裝置 109‧‧‧suspension device

110‧‧‧馬達 110‧‧‧Motor

111‧‧‧定子 111‧‧‧ Stator

112‧‧‧轉子 112‧‧‧Rotor

113‧‧‧旋轉軸 113‧‧‧Rotary axis

114‧‧‧軸承托架 114‧‧‧bearing bracket

115‧‧‧軸承 115‧‧‧ bearing

116‧‧‧滾筒 116‧‧‧Roller

117‧‧‧補強構件 117‧‧‧ reinforcing members

118‧‧‧孔 118‧‧‧ hole

119‧‧‧隔板 119‧‧ ‧ partition

120‧‧‧開口部 120‧‧‧ openings

121‧‧‧開口部 121‧‧‧ openings

122‧‧‧平衡環 122‧‧‧balance ring

123‧‧‧波紋管 123‧‧‧ bellows

124‧‧‧排水口 124‧‧‧Drainage

125‧‧‧機內排水軟管 125‧‧‧In-house drainage hose

126‧‧‧過濾盒 126‧‧‧Filter box

127‧‧‧蓋子 127‧‧‧ cover

128‧‧‧排水閥 128‧‧‧Drain valve

129‧‧‧排水管 129‧‧‧Drainage pipe

130‧‧‧氣阱 130‧‧‧ gas trap

131‧‧‧水位感應器 131‧‧‧Water level sensor

132‧‧‧氣管 132‧‧‧ trachea

133‧‧‧給水閥 133‧‧‧Water supply valve

134‧‧‧水容器 134‧‧‧ water container

135‧‧‧連接管 135‧‧‧Connecting tube

136‧‧‧機內給水軟管 136‧‧‧In-machine water supply hose

300‧‧‧親水性能膜 300‧‧‧Hydrophilic film

Claims (25)

一種洗衣機,是在可旋轉地被設在水槽內的旋轉槽具備親水性能部。 A washing machine having a hydrophilic performance portion in a rotary groove rotatably provided in a water tank. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部,是在前述旋轉槽的外面塗覆親水性材料者。 The washing machine according to claim 1, wherein the hydrophilic performance portion is a material coated with a hydrophilic material on the outer surface of the rotary tub. 如申請專利範圍第1項記載的洗衣機,其中,在前述旋轉槽的側部的外面具備前述親水性能部。 The washing machine according to claim 1, wherein the hydrophilic performance portion is provided on an outer surface of a side portion of the rotary tub. 如申請專利範圍第3項記載的洗衣機,其中,在前述旋轉槽的側部的外面整體具備前述親水性能部。 The washing machine according to claim 3, wherein the hydrophilic performance portion is provided on the outer surface of the side portion of the rotary tub. 如申請專利範圍第3項記載的洗衣機,其中,在前述旋轉槽的側部的外面的一部分具備前述親水性能部。 The washing machine according to claim 3, wherein the hydrophilic portion is provided in a part of the outer surface of the side portion of the rotary tub. 如申請專利範圍第1項記載的洗衣機,其中,在前述旋轉槽的底部的外面具備前述親水性能部。 The washing machine according to claim 1, wherein the hydrophilic performance portion is provided on an outer surface of a bottom portion of the rotary tub. 如申請專利範圍第6項記載的洗衣機,其中,在前述旋轉槽的底部的外面整體具備前述親水性能部。 The washing machine according to claim 6, wherein the hydrophilic performance portion is provided on the outer surface of the bottom portion of the rotary tub. 如申請專利範圍第6項記載的洗衣機,其中,在前述旋轉槽的底部的外面的一部分具備前述親水性能部。 The washing machine according to claim 6, wherein the hydrophilic portion is provided in a part of the outer surface of the bottom of the rotary tub. 如申請專利範圍第1項記載的洗衣機,其中,被安裝在前述旋轉槽的螺絲也具備前述親水性能部。 The washing machine according to the first aspect of the invention, wherein the screw attached to the rotary groove also has the hydrophilic performance portion. 如申請專利範圍第1項記載的洗衣機,其中,在前述旋轉槽的內面也具備前述親水性能部。 The washing machine according to claim 1, wherein the inner surface of the rotary groove also includes the hydrophilic performance portion. 如申請專利範圍第1項記載的洗衣機,其中,在前述旋轉槽設有許多個孔,且在該等的孔的端面也具備前 述親水性能部。 The washing machine according to claim 1, wherein the rotating groove is provided with a plurality of holes, and the end faces of the holes are also provided. The hydrophilic performance section. 如申請專利範圍第1項記載的洗衣機,其中,前述旋轉槽是金屬製,前述親水性能部,是藉由將前述親水性材料烘烤在前述旋轉槽的外面而塗覆者。 The washing machine according to claim 1, wherein the rotating groove is made of metal, and the hydrophilic portion is coated by baking the hydrophilic material on the outer surface of the rotating groove. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部,是10μm以下的厚度。 The washing machine according to the first aspect of the invention, wherein the hydrophilic performance portion has a thickness of 10 μm or less. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部,是表面粗度在2μm以內。 The washing machine according to claim 1, wherein the hydrophilic property portion has a surface roughness of 2 μm or less. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部被著色。 The washing machine according to claim 1, wherein the hydrophilic performance portion is colored. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部具有矽氧化物,且具有鉛筆硬度成為5H以上的性能。 The washing machine according to the first aspect of the invention, wherein the hydrophilic property portion has a cerium oxide and has a pencil hardness of 5H or more. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部,是具有水的接觸角相對於玻璃的水的接觸角成為未滿下限值的性能。 The washing machine according to the first aspect of the invention, wherein the hydrophilic property portion has a performance that a contact angle of water with respect to water of the glass is less than a lower limit value. 如申請專利範圍第1項記載的洗衣機,其中,前述旋轉槽,是以朝向水平的軸線或後方下降傾斜的軸線為中心旋轉的滾筒。 The washing machine according to the first aspect of the invention, wherein the rotating groove is a drum that rotates about an axis that is inclined toward a horizontal axis or a rear side. 如申請專利範圍第18項記載的洗衣機,其中,補強前述滾筒的底部的補強構件也具備前述親水性能部。 The washing machine according to claim 18, wherein the reinforcing member that reinforces the bottom of the drum also includes the hydrophilic performance portion. 如申請專利範圍第1項記載的洗衣機,其中,前述旋轉槽,是構成以垂直的軸線為中心進行旋轉。 The washing machine according to claim 1, wherein the rotating groove is configured to rotate about a vertical axis. 如申請專利範圍第20項記載的洗衣機,其中,補強前述旋轉槽的底部的補強構件也具備前述親水性能部。 The washing machine according to claim 20, wherein the reinforcing member that reinforces the bottom of the rotating groove also includes the hydrophilic portion. 如申請專利範圍第1項記載的洗衣機,其中,前述親水性能部,是常時發揮親水性者。 The washing machine according to the first aspect of the invention, wherein the hydrophilic performance portion is a person who constantly exhibits hydrophilicity. 一種洗衣機,其中,在可旋轉地被設在水槽內的旋轉槽施加有抑制黴菌的繁殖的親水性的塗料。 A washing machine in which a hydrophilic coating for inhibiting the growth of mold is applied to a rotary groove rotatably provided in a water tank. 一種洗衣機,其中,在可旋轉地被設在水槽內的旋轉槽施加有抑制污垢的附著的親水性的塗料。 A washing machine in which a hydrophilic coating for suppressing adhesion of dirt is applied to a rotary groove rotatably provided in a water tank. 一種洗衣機,其中,在可旋轉地被設在水槽內的旋轉槽施加有抑制洗劑的附著的親水性的塗料。 A washing machine in which a hydrophilic coating for suppressing adhesion of a lotion is applied to a rotary groove rotatably provided in a water tank.
TW103121360A 2013-06-21 2014-06-20 Washing machine TWI548794B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2013130554A JP5690878B2 (en) 2013-06-21 2013-06-21 Washing machine

Publications (2)

Publication Number Publication Date
TW201514356A true TW201514356A (en) 2015-04-16
TWI548794B TWI548794B (en) 2016-09-11

Family

ID=52104694

Family Applications (1)

Application Number Title Priority Date Filing Date
TW103121360A TWI548794B (en) 2013-06-21 2014-06-20 Washing machine

Country Status (6)

Country Link
JP (1) JP5690878B2 (en)
KR (3) KR20160002965A (en)
CN (1) CN105308232B (en)
SG (1) SG11201510354QA (en)
TW (1) TWI548794B (en)
WO (1) WO2014203968A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI641740B (en) * 2016-04-18 2018-11-21 日商日立空調 家用電器股份有限公司 Washing machine

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015156881A (en) * 2014-02-21 2015-09-03 株式会社東芝 washing machine
KR102396321B1 (en) 2016-07-12 2022-05-10 삼성전자주식회사 Washing machine
CN108342873B (en) * 2017-01-24 2020-12-15 青岛海尔滚筒洗衣机有限公司 Washing machine tripod and washing machine

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07185194A (en) * 1993-12-27 1995-07-25 Hitachi Ltd Centrifugal dewatering machine
JPH11253696A (en) * 1998-03-12 1999-09-21 Matsushita Electric Ind Co Ltd Spinning tub
JP2000308860A (en) * 1999-02-24 2000-11-07 Toto Ltd Cleaning method of composite material and self-cleaning composite material structure
JP4023418B2 (en) * 2003-08-22 2007-12-19 松下電器産業株式会社 Drum type washer / dryer
JP5033146B2 (en) * 2009-01-29 2012-09-26 日立アプライアンス株式会社 Washing and drying machine, heat insulating paint for outer tub of washing and drying machine, and coating method thereof
JP2010227834A (en) * 2009-03-27 2010-10-14 Panasonic Corp Washing machine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI641740B (en) * 2016-04-18 2018-11-21 日商日立空調 家用電器股份有限公司 Washing machine

Also Published As

Publication number Publication date
JP5690878B2 (en) 2015-03-25
JP2015002906A (en) 2015-01-08
KR20170058461A (en) 2017-05-26
KR102078196B1 (en) 2020-02-17
WO2014203968A1 (en) 2014-12-24
CN105308232B (en) 2017-09-05
KR20160002965A (en) 2016-01-08
SG11201510354QA (en) 2016-01-28
CN105308232A (en) 2016-02-03
TWI548794B (en) 2016-09-11
KR20180081156A (en) 2018-07-13

Similar Documents

Publication Publication Date Title
TWI548794B (en) Washing machine
CN100519883C (en) Washing machine
CN102628205B (en) Sterilizing, disinfecting and mildew-proof barrel-cleaning washing machine and barrel-cleaning control method thereof
CN105463790A (en) Impeller full-automatic washing machine
CN101187130A (en) Drum washing machine
JP6706735B2 (en) Washing machine
CN106170589A (en) Washing machine
EP2737254A1 (en) Cooking device
TWI568905B (en) Washing machine and method of the same
CN106715780A (en) Washing machine and washing machine manufacturing method
JP2020185473A (en) Washing machine
CN204251891U (en) A kind of full-automatic pulsator washing machine
JP6591761B2 (en) Washing machine
JP6411724B2 (en) Washing machine
JP6416467B2 (en) Washing machine
EP2868794A1 (en) Washing machine
JP6469984B2 (en) Washing machine
CN208121875U (en) A kind of stainless steel water tank
JP6411719B2 (en) Washing machine
CN110593394A (en) A cistern for glass tempering manure pit
CN218049228U (en) Cleaning and disinfecting device for water quality detection equipment
CN209907046U (en) Cleaning device for socks
CN209171195U (en) A kind of steck water tank of bilayer constant temperature
CN102727917A (en) Sterilizing and disinfecting infiltration machine
JP6305104B2 (en) Washing machine and method for manufacturing washing machine