TW201501802A - Vortex reactor - Google Patents
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本發明係關於一種渦流反應裝置，尤指一種利用渦流來進行反應，並將反應後的反應生成物以過濾管濾出之渦流反應裝置。 The present invention relates to a vortex reaction apparatus, and more particularly to an eddy current reaction apparatus which uses a vortex to carry out a reaction and filters the reaction product after the reaction is filtered out by a filter tube.
一般來說，化學反應生成物的反應程序通常都是在反應槽內進行，然後對反應槽進行各種參數的控制。例如在燃料電池中，通常是利用硼氫化鈉(NaBH4)之催化性水解而從反應性溶劑釋出氫氣，以將氫氣作為能源。然而，在利用幫浦將硼氫化鈉水溶液傳送至催化床的過程中，由於硼氫化鈉水溶液具有高度黏性，因此會很難精確唧取所需要的量，而為了解決此問題，有時候會加入非反應性化學物以降低黏性，或是用非化學劑量比率以助唧取。此外，更有一種方式是將氫氧化鈉之類的強鹼加入硼氫化鈉溶液，以使硼氫化鈉溶液安定，但也因此會使溶液呈腐蝕性而更難處理。 In general, the reaction procedure of the chemical reaction product is usually carried out in a reaction tank, and then various parameters are controlled for the reaction tank. For example, in a fuel cell, hydrogen is usually released from a reactive solvent by catalytic hydrolysis of sodium borohydride (NaBH 4 ) to use hydrogen as an energy source. However, in the process of transferring the aqueous sodium borohydride solution to the catalytic bed by means of the pump, since the aqueous sodium borohydride solution is highly viscous, it is difficult to accurately extract the required amount, and in order to solve this problem, sometimes Add non-reactive chemicals to reduce stickiness, or use non-chemical dose ratios to aid in skimming. In addition, a more efficient way is to add a strong base such as sodium hydroxide to the sodium borohydride solution to stabilize the sodium borohydride solution, but also render the solution corrosive and more difficult to handle.
在另一方面，硼氫化鈉的水解反應會產生必須移除的副產物-偏硼酸鈉(NaBO4)。偏硼酸鈉在變冷時傾向於獲得水並形成凝膠，其存在阻礙了對觸媒的接近及使反應 所需的水難以被利用。 On the other hand, the hydrolysis of sodium borohydride produces a by-product, sodium metaborate (NaBO 4 ), which must be removed. Sodium metaborate tends to obtain water and form a gel when it is cooled, and its presence hinders the proximity of the catalyst and makes it difficult to utilize the water required for the reaction.
有鑒於在習知技術中，當硼氫化鈉水溶液在反應槽中進行水解產氫反應時，通常需要加入非反應性的化學物質來降低硼氫化鈉水溶液的黏度，或者降低硼氫化鈉的濃度，甚至需要利用強鹼來安定硼氫化鈉水溶液，才能使反應順利進行；並且，在硼氫化鈉的水解反應時，往往會產生必須移除的副產物-偏硼酸鈉，否則會影響硼氫化鈉水溶液的水解產氫反應。 In view of the prior art, when a sodium borohydride aqueous solution is subjected to hydrolysis in a reaction tank for hydrogen production, it is usually necessary to add a non-reactive chemical to reduce the viscosity of the aqueous sodium borohydride solution or to reduce the concentration of sodium borohydride. It is even necessary to use a strong base to stabilize the aqueous sodium borohydride solution in order to make the reaction proceed smoothly; and, in the hydrolysis reaction of sodium borohydride, a by-product, sodium metaborate, which must be removed, is often generated, otherwise the sodium borohydride aqueous solution may be affected. Hydrolysis hydrogen production reaction.
緣此，本發明之主要目的係提供一種渦流反應裝置，係在原本就具有一個進料部的旋風分離器上更開設有至少一個進料部以作為旋風分離反應器本體，使經由進料部進入旋風分離反應器本體內的溶液可以渦流的方式來增加溶液的流動性與增加反應速率，並藉由過濾管來過濾出反應的主產物，而反應的觸媒與副產物則是利用底流與溢流來分離出。 Accordingly, the main object of the present invention is to provide a vortex reaction apparatus in which at least one feed portion is further provided on a cyclone having a feed portion as a cyclone separation reactor body through a feed portion. The solution entering the cyclone separation reactor can be vortexed to increase the fluidity of the solution and increase the reaction rate, and the main product of the reaction is filtered by a filter tube, and the catalyst and by-products of the reaction are underflow and Overflow to separate.
承上所述，本發明為解決習知技術之問題所採用之必要技術手段係提供一種渦流反應裝置，其係供複數個反應流體進行一化學反應而產生至少一反應生成物，而渦流反應裝置包含一旋風分離反應器本體以及一過濾管。旋風分離反應器本體具有一圓筒部、一圓錐部、一底流部、複數個進料部以及一中空筒體。圓錐部係連結於圓筒部之底端，底流部係連結於圓錐部之底端。進料部係分別自圓筒部之邊緣沿一切線方向向外延伸出，藉以供反應 流體分別自進料部以渦流的方式進入旋風分離反應器本體中，進而反應產生反應生成物。 In view of the above, the necessary technical means for solving the problems of the prior art is to provide a vortex reaction device for performing a chemical reaction of a plurality of reaction fluids to generate at least one reaction product, and the vortex reaction device A cyclone separation reactor body and a filter tube are included. The cyclone separation reactor body has a cylindrical portion, a conical portion, an underflow portion, a plurality of feed portions, and a hollow cylinder. The conical portion is coupled to the bottom end of the cylindrical portion, and the underflow portion is coupled to the bottom end of the conical portion. The feeding part extends outward from the edge of the cylindrical portion in the direction of the line, respectively, for the reaction The fluid enters the cyclone separation reactor body by vortexing from the feed portion, and further reacts to generate a reaction product.
中空筒體係設置於圓筒部，並自圓筒部之頂部凸伸出。 The hollow cylinder system is disposed on the cylindrical portion and protrudes from the top of the cylindrical portion.
過濾管係設置於旋風分離反應器本體與中空筒體之中，並用以過濾出反應生成物。 The filter tube is disposed in the cyclone separation reactor body and the hollow cylinder, and is used to filter out the reaction product.
如上所述，由於本發明所提供之渦流反應裝置是將反應流體以渦流的方式進行反應，因此可以有效的提高反應流體的流動性與反應速率，且反應生成的反應生成物可以由過濾管濾出，而其他副產物與觸媒則可以隨著渦流自底流或溢流流出。 As described above, since the vortex reactor of the present invention reacts the reaction fluid in a vortex manner, the fluidity and reaction rate of the reaction fluid can be effectively increased, and the reaction product formed by the reaction can be filtered by the filter tube. Out, while other by-products and catalysts can flow out of the underflow or overflow with the eddy current.
由上述之必要技術手段所衍生之一附屬技術手段為，進料部包含一第一進料部與一第二進料部，反應流體包含一硼氫化物溶液與一觸媒水溶液，硼氫化物溶液與觸媒水溶液係分別自第一進料部與第二進料部進入旋風分離反應器本體中，且反應生成物係為一氫氣。 An auxiliary technical means derived from the above-mentioned technical means is that the feeding portion comprises a first feeding portion and a second feeding portion, and the reaction fluid comprises a borohydride solution and a catalyst aqueous solution, borohydride The solution and the aqueous solution of the catalyst enter the cyclone separation reactor body from the first feed portion and the second feed portion, respectively, and the reaction product is a hydrogen gas.
較佳者，硼氫化物溶液含有一硼氫化物，硼氫化物的濃度為1-60wt%，且硼氫化物更佳的濃度為20-40wt%。此外，硼氫化物溶液更含有一氫氧化物，氫氧化物的濃度為1-15wt%的氫氧化物。 Preferably, the borohydride solution contains a borohydride having a concentration of 1-60% by weight of borohydride and a more desirable concentration of borohydride of 20-40% by weight. Further, the borohydride solution further contains a hydroxide having a hydroxide concentration of 1 to 15% by weight of hydroxide.
較佳者，上述之觸媒水溶液包含一觸媒，其係選自週期表IB-VIIB族以及VIIIB族中之過渡金屬，尤其如銠、銅、鈷、鐵、鎳、錳、釕、錸、鉑、鈀、鉻、銀、鋨或銥等過渡金屬，且過渡金屬的粒徑大小係介於1-10000μm。藉由過渡金屬對粒徑大小的限定，可利於本發明之回收用。 Preferably, the aqueous solution of the above catalyst comprises a catalyst selected from the group consisting of transition metals of Groups IB-VIIB and VIIIB of the Periodic Table, especially such as ruthenium, copper, cobalt, iron, nickel, manganese, ruthenium, osmium, A transition metal such as platinum, palladium, chromium, silver, ruthenium or osmium, and the transition metal has a particle size ranging from 1 to 1000 μm. The limitation of the particle size by the transition metal can be beneficial to the recycling of the present invention.
較佳者，過濾管係為一防水透氣管，藉以利用防水透氣管將上述之氫氣分離出。 Preferably, the filter tube is a waterproof vent tube, whereby the hydrogen gas is separated by a waterproof vent tube.
由上述之必要技術手段所衍生之一附屬技術手段為，渦流反應裝置更包含一第一電場元件與一第二電場元件，第一電場元件係設置於圓錐部，第二電場元件係設置於過濾管，藉以使第一電場元件與第二電場元件之間產生一電場。較佳者，第一電場元件係為一環型電極板，第二電場元件係為一條型電極棒。因此，藉由第一電場元件與第二電場元件所形成的電場，可以使反應流體反應後所產生的產物受到電場影響而加速分離。 An auxiliary technical means derived from the above-mentioned technical means is that the eddy current reaction device further comprises a first electric field component and a second electric field component, the first electric field component is disposed on the conical portion, and the second electric field component is disposed in the filtering device. a tube whereby an electric field is generated between the first electric field element and the second electric field element. Preferably, the first electric field component is a ring-shaped electrode plate, and the second electric field component is a strip-shaped electrode bar. Therefore, by the electric field formed by the first electric field element and the second electric field element, the product generated after the reaction of the reaction fluid can be accelerated by the electric field.
由上述之必要技術手段所衍生之一附屬技術手段為，過濾管係具有一觸媒，觸媒係選自週期表IB-VIIB族以及VIIIB族中之過渡金屬。 An auxiliary technical means derived from the above-mentioned necessary technical means is that the filter tube has a catalyst, and the catalyst is selected from the transition metals of Groups IB-VIIB and VIIIB of the periodic table.
本發明所採用的具體實施例，將藉由以下之實施例及圖式作進一步之說明。 The specific embodiments of the present invention will be further described by the following examples and drawings.
100、100a‧‧‧渦流反應裝置 100, 100a‧‧ eddy current reactor
1‧‧‧旋風分離反應器本體 1‧‧‧Cyclone separation reactor body
11‧‧‧圓筒部 11‧‧‧Cylinder
12‧‧‧圓錐部 12‧‧‧Cone
13‧‧‧底流部 13‧‧‧Underflow Department
14、15‧‧‧進料部 14, 15‧‧‧ Feeding Department
16‧‧‧中空筒體 16‧‧‧ hollow cylinder
2‧‧‧過濾管 2‧‧‧Filter tube
3‧‧‧第一電場元件 3‧‧‧First electric field component
4‧‧‧第二電場元件 4‧‧‧Second electric field component
R1‧‧‧切線方向 R1‧‧‧ Tangential direction
R2‧‧‧切線方向 R2‧‧‧ tangential direction
第一圖係顯示本發明第一較佳實施例所提供之渦流反應裝置立體示意圖；第二圖係顯示本發明第一較佳實施例所提供之渦流反應裝置剖面示意圖；以及第三圖係顯示本發明第二較佳實施例所提供之渦流反應裝置剖面示意圖。 1 is a schematic perspective view showing a vortex reaction device according to a first preferred embodiment of the present invention; a second view showing a schematic cross-sectional view of a vortex reaction device according to a first preferred embodiment of the present invention; and a third figure showing A schematic cross-sectional view of a vortex reactor according to a second preferred embodiment of the present invention.
請一併參閱第一圖與第二圖，第一圖係顯示本發明第一較佳實施例所提供之渦流反應裝置立體示意圖；第二圖係顯示本發明第一較佳實施例所提供之渦流反應裝置剖面示意圖。如圖所示，一種渦流反應裝置100包含一旋風分離反應器本體1以及一過濾管2。其中，渦流反應裝置100係用以供二個反應流體(圖未示)進行一化學反應，並進而產生一反應生成物(圖未示)。 Referring to the first and second figures, the first figure shows a schematic view of a vortex reaction device according to a first preferred embodiment of the present invention; the second figure shows the first preferred embodiment of the present invention. Schematic diagram of the vortex reactor. As shown, a vortex reactor 100 includes a cyclone reactor body 1 and a filter tube 2. The vortex reaction device 100 is configured to perform a chemical reaction between two reaction fluids (not shown), and further generate a reaction product (not shown).
旋風分離反應器本體1具有一圓筒部11、一圓錐部12、一底流部13、一第一進料部14、一第二進料部15以及一中空筒體16。其中，旋風分離反應器本體1相似於一般常見的旋風分離器，一般的旋風分離器主要是設有一個進料部以供混濁的溶液進行分離，然而在本實施例中，旋風分離反應器本體1具有第一進料部14與第二進料部15，而在其他實施例中則不限於二個，亦可以是二個以上，藉以用來供多種反應流體進行反應。 The cyclone separation reactor body 1 has a cylindrical portion 11, a conical portion 12, an underflow portion 13, a first feed portion 14, a second feed portion 15, and a hollow cylinder 16. Wherein, the cyclone separation reactor body 1 is similar to a common cyclone separator. The general cyclone separator is mainly provided with a feed portion for separation of the turbid solution. However, in the present embodiment, the cyclone separation reactor body is 1 has a first feeding portion 14 and a second feeding portion 15, but in other embodiments, it is not limited to two, and may be two or more, thereby being used for reacting a plurality of reaction fluids.
圓錐部12係連結於圓筒部11之底端，且底流部13係連結於圓錐部12之底端；在本實施例中，圓錐部12係一體成型地連結於圓筒部11，而底流部13係一體成型地連結於圓錐部12，然而在其他實施例中並不限於一體成型，圓錐部與底流部亦可以螺接、卡合、夾合、膠合或銲接等連結方式分別連結於圓筒部與圓錐部。 The conical portion 12 is coupled to the bottom end of the cylindrical portion 11, and the underflow portion 13 is coupled to the bottom end of the conical portion 12. In the present embodiment, the conical portion 12 is integrally coupled to the cylindrical portion 11, and the underflow The portion 13 is integrally coupled to the conical portion 12, but in other embodiments, it is not limited to integral molding, and the conical portion and the underflow portion may be connected to the circle by a screwing, engaging, sandwiching, gluing or welding connection. Tube and cone.
第一進料部14係自圓筒部11之頂端邊緣沿一切線方向R1向外延伸出，而第二進料部15則是自圓筒部11之頂端邊緣沿一切線方向R2向外延伸出。其中，反應流體係分別自第一進料部14與第二進料部15沿切線進入旋風 分離反應器本體1中而產生渦流，進而反應產生反應生成物。 The first feeding portion 14 extends outward from the top end edge of the cylindrical portion 11 in the line direction R1, and the second feeding portion 15 extends outward from the top end edge of the cylindrical portion 11 in the line direction R2. Out. Wherein, the reaction flow system enters the whirlwind from the first feeding portion 14 and the second feeding portion 15 along the tangential line, respectively. The reactor body 1 is separated to generate a vortex, which in turn reacts to produce a reaction product.
中空筒體16係設置於圓筒部11，並一體成型地自圓筒部11之頂部凸伸出，以及自圓筒部11之頂部向下延伸至圓筒部11內。其中，藉由中空筒體16設置於圓筒部11之頂部，當二反應流體在旋風分離反應器本體1內反應後，其反應的副產物與觸媒其中較輕者可以經由中空筒體16溢流出，意即中空筒體16相當於整個渦流反應裝置100的溢流部。 The hollow cylinder 16 is disposed on the cylindrical portion 11 and integrally protrudes from the top of the cylindrical portion 11, and extends downward from the top of the cylindrical portion 11 into the cylindrical portion 11. Wherein, by the hollow cylinder 16 being disposed at the top of the cylindrical portion 11, when the two reaction fluids are reacted in the cyclone separation reactor body 1, the by-products of the reaction and the catalyst among the lighter ones can pass through the hollow cylinder 16 The overflow overflow means that the hollow cylinder 16 corresponds to the overflow portion of the entire vortex reactor 100.
過濾管2係設置於旋風分離反應器本體1之圓筒部11、圓錐部12、底流部13以及中空筒體16與中空筒體2之中，並用以過濾出反應生成物。在其他實施例中，過濾管2更可由一過濾管本體與一觸媒所構成，而觸媒可以蒸鍍或電鍍等方式形成於過濾管本體上，或者觸媒可以吸附的方式設置於過濾管本體上，因此當反應溶液一樣由上述之第一進料部14或第二進料部15進入旋風分離反應器本體1內而接觸到過濾管2時，即會受到觸媒的催化而反應產生氫氣。另外，過濾管本體的材質例如可以是金屬粉末或活性碳燒結而成的多微孔結構，而觸媒則是選自週期表IB-VIIB族以及VIIIB族中之過渡金屬。 The filter tube 2 is disposed in the cylindrical portion 11, the conical portion 12, the underflow portion 13, and the hollow cylindrical body 16 of the cyclone separation reactor body 1, and the hollow cylindrical body 2, and is used to filter out the reaction product. In other embodiments, the filter tube 2 can be formed by a filter tube body and a catalyst, and the catalyst can be formed on the filter tube body by evaporation or electroplating, or the catalyst can be adsorbed in the filter tube. On the body, when the reaction solution enters the cyclone separation reactor body 1 from the first feed portion 14 or the second feed portion 15 as described above and contacts the filter tube 2, it is catalyzed by the catalyst to react. hydrogen. Further, the material of the filter tube body may be, for example, a microporous structure in which metal powder or activated carbon is sintered, and the catalyst is a transition metal selected from Groups IB-VIIB and VIIIB of the periodic table.
在本實施例中，上述之二反應流體分別是一硼氫化物溶液與一觸媒水溶液，硼氫化物溶液例如為硼氫化鈉溶液，但不限於此。亦可為金屬氫化物溶液，如一般化學儲氫反應所教示者，當硼氫化物溶液與觸媒水溶液係分別自第一進料部14與第二進料部15進入旋風分離反應 器本體1內時，其反應所產生之反應生成物係為一氫氣；其中，本實施例所述之硼氫化物溶液含有一硼氫化物，例如是硼氫化鉀，且硼氫化物之濃度為1-60wt%，較佳的濃度則為20-40wt%；此外，硼氫化物溶液含有一氫氧化物，例如是氫氧化鈉或氫氧化鉀等，且氫氧化物之濃度為1-15wt%。 In the present embodiment, the above two reactive fluids are a borohydride solution and a catalyst aqueous solution, respectively, and the borohydride solution is, for example, a sodium borohydride solution, but is not limited thereto. It may also be a metal hydride solution, as taught by a general chemical hydrogen storage reaction, when the borohydride solution and the aqueous catalyst solution enter the cyclone separation reaction from the first feed portion 14 and the second feed portion 15, respectively. In the body 1, the reaction product produced by the reaction is a hydrogen gas; wherein the borohydride solution described in this embodiment contains a borohydride such as potassium borohydride, and the concentration of the borohydride is 1-60 wt%, preferably 20-40 wt%; in addition, the borohydride solution contains a hydroxide, such as sodium hydroxide or potassium hydroxide, and the concentration of the hydroxide is 1-15 wt% .
另外，觸媒水溶液包含一觸媒，觸媒係選自週期表IB-VIIB族以及VIIIB族中之過渡金屬，例如銠、銅、鈷、鐵、鎳、錳、釕、錸、鉑、鈀、鉻、銀、鋨或銥等過鍍金屬，且觸媒之粒徑大小係介於1-10000μm，藉以在觸媒水溶液與硼氫化物溶液反應後便於回收再利用(視觸媒之顆粒比重與大小決定觸媒會由溢流處或底流處流出)。因此，藉由本發明所提供之渦流反應裝置，確實可以有效的使硼氫化物溶液與觸媒水溶液反應所產生的氫氣經由過濾管過濾收集，並使反應後的觸媒水溶液中的觸媒由底流處或溢流處流出，以利後續的回收再利用。 In addition, the aqueous solution of the catalyst comprises a catalyst selected from the group consisting of transition metals of Groups IB-VIIB and VIIIB of the Periodic Table, such as ruthenium, copper, cobalt, iron, nickel, manganese, ruthenium, osmium, platinum, palladium, Chromium, silver, antimony or bismuth is over-plated, and the particle size of the catalyst is between 1 and 1000 μm, so that it can be recycled and reused after reacting the aqueous solution of the catalyst with the borohydride solution (the specific gravity of the catalyst) The size determines that the catalyst will flow from the overflow or the underflow). Therefore, with the vortex reactor of the present invention, it is possible to effectively collect the hydrogen generated by the reaction of the borohydride solution and the aqueous solution of the catalyst through the filter tube, and to make the catalyst in the aqueous solution of the catalyst from the underflow. At the overflow or overflow, for subsequent recycling and reuse.
請參閱第一圖、第二圖與第三圖，第三圖係顯示本發明第二較佳實施例所提供之渦流反應裝置剖面示意圖。如圖所示，一種渦流反應裝置100a與上述之渦流反應裝置100相似，其差異僅在於渦流反應裝置100a更包含一第一電場元件3與一第二電場元件4。 Please refer to the first, second and third figures. The third figure shows a schematic cross-sectional view of the eddy current reaction device according to the second preferred embodiment of the present invention. As shown, a vortex reactor 100a is similar to the vortex reactor 100 described above, except that the vortex reactor 100a further includes a first electric field component 3 and a second electric field component 4.
第一電場元件3係設置於過濾管2之內側，也可以貼附於過濾管2，第二電場元件4係設置於圓錐部12，藉以使第一電場元件3與第二電場元件4之間產生一電場，進而使反應流體反應所產生的反應生成物或觸媒水溶液 中的觸媒受到電場的影響而加速的朝向過濾管2或圓錐部12移動，以增加過濾分離的效果。在實際運用上，可視反應生成物與觸媒水溶液所帶的電性來決定第一電場元件3與第二電場元件4其中正電與負電的連接方式。 The first electric field element 3 is disposed inside the filter tube 2, and may be attached to the filter tube 2, and the second electric field element 4 is disposed on the conical portion 12, thereby between the first electric field element 3 and the second electric field element 4. Producing an electric field, and then reacting the reaction product to produce a reaction product or an aqueous solution of the catalyst The catalyst in the medium is accelerated toward the filter tube 2 or the conical portion 12 by the influence of the electric field to increase the effect of filtration separation. In practical use, the electrical connection between the reaction product and the aqueous solution of the catalyst determines the manner in which the first electric field element 3 and the second electric field element 4 are positively and negatively connected.
綜合以上所述，藉由本發明所提供之渦流反應裝置，由於是利用複數個進料部來導入多個反應流體，使反應流體可以渦流的方式進入旋風分離反應器本體中，並隨著渦流進行反應，有效的增加反應流體的流動性與反應速率。其中，反應後所產生的反應生成物可以經由過濾管濾出，而反應後所產生的副產物與反應所需的觸媒則可分別由底流與溢流流出，有效的增加反應的穩定性。 In summary, according to the eddy current reaction device provided by the present invention, since a plurality of reaction portions are introduced by using a plurality of feed portions, the reaction fluid can be vortexed into the cyclone separation reactor body, and the vortex flow is performed. The reaction effectively increases the fluidity of the reaction fluid and the reaction rate. Wherein, the reaction product produced after the reaction can be filtered out through the filter tube, and the by-products generated after the reaction and the catalyst required for the reaction can flow out from the underflow and the overflow, respectively, effectively increasing the stability of the reaction.
相較於習知技術在反應槽內進行反應時，反應所產生的副產物往往會影響整個反應的持續進行，本發明確實能有效的增加反應流體的流動性與反應速率。 When the reaction is carried out in a reaction tank as compared with the prior art, by-products generated by the reaction tend to affect the continuous progress of the entire reaction, and the present invention can effectively increase the fluidity and reaction rate of the reaction fluid.
藉由以上較佳具體實施例之詳述，係希望能更加清楚描述本發明之特徵與精神，而並非以上述所揭露的較佳具體實施例來對本發明之範疇加以限制。相反地，其目的是希望能涵蓋各種改變及具相等性的安排於本發明所欲申請之專利範圍的範疇內。 The features and spirit of the present invention will be more apparent from the detailed description of the preferred embodiments. On the contrary, the intention is to cover various modifications and equivalents within the scope of the invention as claimed.
100‧‧‧渦流反應裝置 100‧‧‧ eddy current reactor
1‧‧‧旋風分離反應器本體 1‧‧‧Cyclone separation reactor body
11‧‧‧圓筒部 11‧‧‧Cylinder
12‧‧‧圓錐部 12‧‧‧Cone
13‧‧‧底流部 13‧‧‧Underflow Department
14、15‧‧‧進料部 14, 15‧‧‧ Feeding Department
16‧‧‧中空筒體 16‧‧‧ hollow cylinder
2‧‧‧過濾管 2‧‧‧Filter tube
R1‧‧‧切線方向 R1‧‧‧ Tangential direction
R2‧‧‧切線方向 R2‧‧‧ tangential direction
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| WO2016193813A1 (en) * | 2015-06-01 | 2016-12-08 | Cetamax Ventures Ltd. | Systems and methods for processing fluids |
| WO2018100554A1 (en) * | 2016-12-01 | 2018-06-07 | Cetamax Ventures Ltd. | Apparatus and method for generating hydrogen by electrolysis |
| WO2018100552A1 (en) * | 2016-12-01 | 2018-06-07 | Cetamax Ventures Ltd. | Manufacture of graphene materials using a cavitation reactor |
| TWI687258B (en) * | 2019-05-10 | 2020-03-11 | 頂程國際股份有限公司 | Filter apparatus |
| CN112452568A (en) * | 2020-11-03 | 2021-03-09 | 三明学院 | Comprehensive dust raising type circulating separation system and separation method |
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| US5935545A (en) * | 1997-07-11 | 1999-08-10 | E. I. Du Pont De Nemours And Company | Process for producing an aqueous solution comprising ferric chloride |
| JP2006515536A (en) * | 2003-01-14 | 2006-06-01 | ザ ビーオーシー グループ ピーエルシー | Chemical waste treatment |
| TWI244938B (en) * | 2004-12-17 | 2005-12-11 | Ind Tech Res Inst | Apparatus for treating waste gas containing liquid droplet or/and solid particle |
| TWI392644B (en) * | 2008-12-10 | 2013-04-11 | Univ Nat Central | The method of sodium borohydride reacting with water to produce hydrogen |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2016193813A1 (en) * | 2015-06-01 | 2016-12-08 | Cetamax Ventures Ltd. | Systems and methods for processing fluids |
| WO2018100554A1 (en) * | 2016-12-01 | 2018-06-07 | Cetamax Ventures Ltd. | Apparatus and method for generating hydrogen by electrolysis |
| WO2018100552A1 (en) * | 2016-12-01 | 2018-06-07 | Cetamax Ventures Ltd. | Manufacture of graphene materials using a cavitation reactor |
| TWI687258B (en) * | 2019-05-10 | 2020-03-11 | 頂程國際股份有限公司 | Filter apparatus |
| CN112452568A (en) * | 2020-11-03 | 2021-03-09 | 三明学院 | Comprehensive dust raising type circulating separation system and separation method |
| CN112452568B (en) * | 2020-11-03 | 2024-04-16 | 三明学院 | Comprehensive dust-raising type circulating separation system and separation method |
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