TW201436996A - Stretched film production method and film stretching apparatus - Google Patents

Stretched film production method and film stretching apparatus Download PDF

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Publication number
TW201436996A
TW201436996A TW103106623A TW103106623A TW201436996A TW 201436996 A TW201436996 A TW 201436996A TW 103106623 A TW103106623 A TW 103106623A TW 103106623 A TW103106623 A TW 103106623A TW 201436996 A TW201436996 A TW 201436996A
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Taiwan
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film
preheating
temperature
stretching
roller
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TW103106623A
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Chinese (zh)
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Tetsuya Yoshida
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Fujifilm Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/04Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
    • B29C55/06Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique parallel with the direction of feed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/18Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets by squeezing between surfaces, e.g. rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

An object of the present invention is to provide a stretched film production method and a film stretching apparatus for stretching a film in a transporting direction thereof without generating scratches and corrugated wrinkles on the film. A film is stretched in a transporting direction thereof by utilizing circumferential velocity difference between a low-speed roller pair and a high-speed roller pair. The film before being stretched is preheated by heated air blown thereto in a preheating chamber. According to the present invention, since the film is heated by the heated air, corrugated wrinkles due to thermal expansion are not generated on the film, in comparison with a conventional case where a film is directly heated by conduction of heat from a preheating roller. Since wrinkles are not generated, it is possible to prevent generation of scratches on the film.

Description

拉伸薄膜的製造方法及薄膜拉伸設備 Method for producing stretched film and film stretching device

本發明係有關一種藉由一對輥的圓周速度差向傳送方向拉伸薄膜之拉伸薄膜的製造方法及薄膜拉伸設備。 The present invention relates to a method for producing a stretched film which stretches a film in a conveying direction by a circumferential speed difference of a pair of rolls, and a film stretching apparatus.

通常,熱塑性樹脂薄膜的製造方法被大致分為溶液製膜法和熔融製膜法。溶液製膜法中,使溶劑中溶解有熱塑性樹脂之濃液(dope)從模具流延到支撐體例如冷卻滾筒或乾燥帶上,之後進行剝離以作為熱塑性樹脂。並且,熔融製膜法利用擠出機熔融熱塑性樹脂之後,從模具向支撐體例如冷卻滾筒上擠出,之後進行剝離以作為熱塑性樹脂。 Generally, a method for producing a thermoplastic resin film is roughly classified into a solution film forming method and a melt film forming method. In the solution film forming method, a dope in which a thermoplastic resin is dissolved in a solvent is cast from a mold onto a support such as a cooling drum or a drying belt, and then peeled off to obtain a thermoplastic resin. Further, the melt film forming method melts the thermoplastic resin by an extruder, and then extrudes it from a mold onto a support such as a cooling roll, and then peels it off as a thermoplastic resin.

藉由該些方法製膜之熱塑性樹脂薄膜例如纖維素醯化物薄膜,例如日本專利公表平6-501040號公報、日本專利公開2001-42130號公報所記載,通常沿縱向(傳送方向)、橫向(寬度方向)拉伸,藉此顯現出面內延遲(Re)、厚度方向的延遲(Rth)。藉此,當用作液晶顯示裝置的相位差薄膜時,能夠擴大視角。 A thermoplastic resin film, such as a cellulose oxime film, which is formed by the above-mentioned methods, is described in, for example, Japanese Patent Publication No. Hei 6-501040, Japanese Patent Publication No. 2001-42130, which is generally in the longitudinal direction (transport direction) and the lateral direction ( Stretching in the width direction, thereby exhibiting an in-plane retardation (Re) and a thickness direction retardation (Rth). Thereby, when used as a retardation film of a liquid crystal display device, the viewing angle can be enlarged.

縱向拉伸熱塑性樹脂薄膜時,利用複數根預熱輥對熱塑性樹脂薄膜進行預熱之後,藉由一對拉伸輥的圓周速度差進行縱向拉伸加工。此時,熱塑性樹脂薄膜接觸到複數根預熱輥,從而存在薄膜表面產生擦傷或產生褶皺之問題。因此,在日本專利公開2008-213332號公報的拉伸薄膜的製造方法中,依據熱塑性樹脂薄膜接觸各輥前後的溫度變化,使複數根預熱輥和拉伸輥的圓周速度隨著朝向下游而逐漸加速,而向各預熱輥之間賦予適當的張力來抑制擦傷和褶皺的產生。具體而言,藉由熱塑性樹脂薄膜接觸預熱輥前後的溫差△T乘以一定係數來求出下游側的預熱輥相對於上游側的預熱輥增加之速度量。並且,將熱塑性樹脂薄膜接觸各預熱輥之時間設在0.5秒以上10以下的範圍。 When the thermoplastic resin film is longitudinally stretched, the thermoplastic resin film is preheated by a plurality of preheating rolls, and then longitudinally stretched by a peripheral speed difference of a pair of stretching rolls. At this time, the thermoplastic resin film is in contact with a plurality of preheating rolls, so that there is a problem that the surface of the film is scratched or wrinkled. Therefore, in the method for producing a stretched film of Japanese Laid-Open Patent Publication No. 2008-213332, the peripheral speeds of the plurality of preheating rolls and the stretching rolls are made to face downstream depending on the temperature change before and after the thermoplastic resin film contacts the respective rolls. Gradually accelerated, and appropriate tension is applied between the preheating rolls to suppress the generation of scratches and wrinkles. Specifically, the temperature difference ΔT before and after the thermoplastic resin film is brought into contact with the preheating roll is multiplied by a constant coefficient to determine the amount of increase in the preheating roll on the downstream side with respect to the preheating roll on the upstream side. Further, the time during which the thermoplastic resin film is brought into contact with each of the preheating rolls is set to be in the range of 0.5 second or more and 10 or less.

然而,最近越來越要求液晶顯示裝置的輕質化、薄型化及高品質,對於所使用之熱塑性樹脂薄膜亦要求薄至例如25μm~100μm左右的高品質的薄膜。當藉由縱向拉伸來製造該種薄型熱塑性樹脂薄膜時,採用如日本專利公開2008-213332號公報的藉由預熱輥進行預熱之方法時存在局限性,會在薄膜表面產生擦傷或產生褶皺,因此要求對其進行改善。 However, in recent years, the liquid crystal display device has been increasingly required to be lighter, thinner, and higher in quality, and a high-quality film having a thickness of, for example, about 25 μm to 100 μm is required for the thermoplastic resin film to be used. When the thin thermoplastic resin film is produced by longitudinal stretching, there is a limitation in the method of preheating by a preheating roll as disclosed in Japanese Patent Laid-Open Publication No. 2008-213332, which causes scratching or generation on the surface of the film. Wrinkles, so it is required to improve it.

本發明的目的為提供一種能夠與熱塑性樹脂薄膜的薄型化對應,且不在熱塑性樹脂薄膜上引發擦傷或褶皺的拉伸薄膜的製造方法及薄膜拉伸設備。 An object of the present invention is to provide a method and a film stretching apparatus for a stretched film which can correspond to a reduction in thickness of a thermoplastic resin film and which does not cause scratches or wrinkles on a thermoplastic resin film.

本發明的拉伸薄膜的製造方法具備拉伸步驟(步驟A)及預熱步驟(步驟B),向傳送方向拉伸由玻璃化轉變溫度為Tg之熱塑性樹脂構成之帶狀薄膜來製造拉伸薄膜。步驟A中,藉由在傳送方向上分開配置之低速輥和以高於低速輥的圓周速度旋轉之高速輥來向傳送方向拉伸薄膜。低速輥與薄膜接觸而將薄膜加熱至Tg℃以上(Tg+20)℃以下範圍內的拉伸溫度Te。步驟B中,在步驟A之前向預熱室內部供給加熱風來將薄膜預熱至(Te-40)℃以上(Tg-5)℃以下的範圍內。 The method for producing a stretched film of the present invention comprises a stretching step (step A) and a preheating step (step B), and stretching a strip-shaped film made of a thermoplastic resin having a glass transition temperature of Tg in a transport direction to produce an extruded film. film. In the step A, the film is stretched in the conveying direction by a low speed roller which is disposed separately in the conveying direction and a high speed roller which is rotated at a peripheral speed higher than the low speed roller. The low speed roll is in contact with the film to heat the film to a stretching temperature Te in the range of Tg ° C or more (Tg + 20) ° C or less. In the step B, the heating air is supplied to the inside of the preheating chamber before the step A to preheat the film to a range of (Te - 40) ° C or more (Tg - 5) ° C or less.

藉由高速輥將經由低速輥之薄膜冷卻至(Tg-100)℃以上(Tg-5)℃以下的範圍內為較佳。 It is preferred to cool the film passing through the low speed roll to a range of (Tg - 100) ° C or more (Tg - 5) ° C or less by a high speed roller.

預熱室內的薄膜的張力在20N/m以上200N/m以下的範圍內為較佳。 The tension of the film in the preheating chamber is preferably in the range of 20 N/m or more and 200 N/m or less.

預熱室在傳送方向上被劃分為複數個預熱區域,預熱溫度從被劃分為複數個預熱區域的上游側朝下游側上升,相鄰之下游側預熱區域與上游側預熱區域的溫差為50℃以下為較佳。 The preheating chamber is divided into a plurality of preheating zones in the conveying direction, and the preheating temperature rises from the upstream side divided into a plurality of preheating zones toward the downstream side, and the adjacent downstream side preheating zone and the upstream side preheating zone The temperature difference is preferably 50 ° C or less.

步驟B中的薄膜掛繞於改變傳送方向之複數個傳送方向變更構件上為較佳。 Preferably, the film in step B is wound around a plurality of conveying direction changing members that change the conveying direction.

傳送方向變更構件為自由輥或轉向桿為較佳。 It is preferable that the conveying direction changing member is a free roller or a steering lever.

傳送方向變更構件在傳送方向上被劃分為複數個組,溫度從每一組的上游側開始逐漸向下游側上升為較佳。 The conveying direction changing member is divided into a plurality of groups in the conveying direction, and the temperature is gradually increased from the upstream side of each group to the downstream side.

相鄰之下游側的組和上游側的組的傳送方向變更構件的溫差為50℃以下為較佳。 It is preferable that the temperature difference of the conveyance direction changing member of the group on the downstream side and the group on the upstream side is 50 ° C or less.

本發明的薄膜拉伸設備具備縱向拉伸部、低速輥、高速輥及預熱部,並藉由向傳送方向拉伸由玻璃化轉變溫度為Tg之熱塑性樹脂構成之帶狀薄膜來製造拉伸薄膜。縱向拉伸部向傳送方向拉伸薄膜。低速輥存在於縱向拉伸部,且藉由與薄膜接觸來將薄膜加熱至Tg℃以上(Tg+20)℃以下的拉伸溫度Te。高速輥以高於低速輥的圓周速度旋轉,從而向傳送方向拉伸薄膜。高速輥在傳送方向上與低速輥分開配置於縱向拉伸部。預熱部向預熱室內部供給加熱風來將薄膜預熱至(Te-40)℃以上(Tg-5)℃以下。預熱部配置於縱向拉伸部的上游。 The film stretching apparatus of the present invention comprises a longitudinal stretching portion, a low-speed roller, a high-speed roller, and a preheating portion, and is stretched by stretching a strip-shaped film made of a thermoplastic resin having a glass transition temperature of Tg in a conveying direction. film. The longitudinal stretching portion stretches the film in the conveying direction. The low speed roller is present in the longitudinal stretching portion, and the film is heated to a stretching temperature Te of Tg ° C or more (Tg + 20) ° C or less by contact with the film. The high speed roller is rotated at a peripheral speed higher than the low speed roller to stretch the film in the conveying direction. The high speed roller is disposed in the longitudinal stretching portion separately from the low speed roller in the conveying direction. The preheating section supplies a heating wind to the inside of the preheating chamber to preheat the film to (Te - 40) ° C or more (Tg - 5) ° C or less. The preheating portion is disposed upstream of the longitudinal stretching portion.

不同於如同以往藉由與預熱輥接觸來加熱熱塑性樹脂薄膜之方法,依本發明,不產生擦傷或因預熱輥上的薄膜膨脹引起之波紋板狀的褶皺,且能夠與熱塑性樹脂薄膜的薄壁化對應。 Unlike the conventional method of heating a thermoplastic resin film by contact with a preheating roll, according to the present invention, it does not cause scratches or corrugated plate-like wrinkles due to film expansion on the preheating roll, and can be combined with a thermoplastic resin film. Corresponding to thin walling.

10‧‧‧薄膜拉伸設備 10‧‧‧film stretching equipment

11、51、63、71‧‧‧預熱部 11, 51, 63, 71‧ ‧ preheating department

12‧‧‧縱向拉伸部 12‧‧‧ longitudinal stretching

13‧‧‧前期製程裝置 13‧‧‧Pre-process equipment

14‧‧‧後期製程裝置 14‧‧‧ late process equipment

15‧‧‧薄膜 15‧‧‧film

16‧‧‧張力調節部 16‧‧‧Tensile adjustment department

17a、17b‧‧‧自由輥 17a, 17b‧‧‧ free roll

18‧‧‧張力輥 18‧‧‧ Tension roller

19‧‧‧位移機構 19‧‧‧displacement mechanism

20、50、60、74‧‧‧預熱室 20, 50, 60, 74‧‧‧ preheating room

25、61‧‧‧自由輥 25, 61‧‧‧ free roll

31‧‧‧供氣噴嘴 31‧‧‧Air supply nozzle

32‧‧‧排氣噴嘴 32‧‧‧Exhaust nozzle

33‧‧‧導管 33‧‧‧ catheter

34、72‧‧‧送風機 34, 72‧‧‧ blower

35、73‧‧‧溫度調節器 35, 73‧‧‧temperature regulator

36‧‧‧加熱風 36‧‧‧heating wind

41‧‧‧低速輥組 41‧‧‧Low speed roller set

41a‧‧‧低速輥 41a‧‧‧low speed roller

41b、42b‧‧‧夾持輥 41b, 42b‧‧‧ pinch roller

42‧‧‧高速輥組 42‧‧‧High speed roller set

42a‧‧‧高速輥 42a‧‧‧High speed roller

43‧‧‧冷卻輥 43‧‧‧Cooling roller

49‧‧‧隔板 49‧‧‧Baffle

50a、50b、50c‧‧‧預熱區域 50a, 50b, 50c‧‧‧ preheating area

62a、62b、62c‧‧‧調溫機構 62a, 62b, 62c‧ ‧ tempering mechanism

70‧‧‧轉向桿 70‧‧‧ steering rod

圖1係表示本發明的薄膜拉伸設備的一例之概要側視圖。 Fig. 1 is a schematic side view showing an example of a film stretching apparatus of the present invention.

圖2係表示將預熱室劃分為複數個之其他實施形態的薄膜拉伸設備的一例之概要側視圖。 Fig. 2 is a schematic side view showing an example of a film stretching apparatus in which a plurality of preheating chambers are divided into a plurality of embodiments.

圖3係表示對預熱室內的自由輥進行調溫之其他實施形態的預熱室之概要側視圖。 Fig. 3 is a schematic side view showing a preheating chamber of another embodiment for adjusting the temperature of the free roller in the preheating chamber.

圖4係表示利用轉向桿之其他實施形態的預熱室之概要側視圖。 Fig. 4 is a schematic side view showing a preheating chamber of another embodiment using a steering column.

圖5係表示拉伸溫度Te與預熱溫度Tp的適當範圍之曲線圖。 Fig. 5 is a graph showing an appropriate range of the stretching temperature Te and the preheating temperature Tp.

如圖1所示,本發明的薄膜拉伸設備10具備預熱部11及縱向拉伸部12。薄膜拉伸設備10的入口側連接有前期製程裝置13,出口側連接有後期製程裝置14。作為前期製程裝置13,有未圖示的製膜設備、薄膜送出裝置等。作為製膜設備使用眾所周知的溶液製膜設備、熔融製膜設備等。不同於直接從製膜設備送出薄膜15時,薄膜送出裝置從製膜之後捲取成卷狀之輥薄膜牽引薄膜15來供給薄膜15。作為後期製程裝置14,有在縱向拉伸之後進行橫向拉伸時使用之夾子拉幅機和薄膜捲取裝置等。繼縱向拉伸之後緊接著進行橫向拉伸時,省略夾子拉幅機,薄膜15被薄膜捲取裝置捲取成卷狀。 As shown in FIG. 1, the film stretching apparatus 10 of the present invention includes a preheating portion 11 and a longitudinal stretching portion 12. The front side of the film stretching apparatus 10 is connected to the front process unit 13, and the outlet side is connected to the post-process apparatus 14. As the pre-processing apparatus 13, there are a film forming apparatus (not shown), a film feeding apparatus, and the like. A well-known solution film forming apparatus, a melt film forming apparatus, etc. are used as a film forming apparatus. When the film 15 is directly fed out from the film forming apparatus, the film feeding device winds up the roll film roll pulling film 15 from the film forming film to supply the film 15. As the post-process apparatus 14, there are a clip tenter and a film take-up apparatus which are used for the transverse stretching after the longitudinal stretching. Immediately after the longitudinal stretching, the clip tenter is omitted, and the film 15 is taken up in a roll shape by the film winding device.

拉伸之薄膜15只要是熱塑性樹脂薄膜即可,例如適宜用於相位差薄膜等的光學薄膜之纖維素醯化物或降冰片烯樹脂、丙烯酸、聚碳酸酯製薄膜15為較佳。 The stretched film 15 is preferably a thermoplastic resin film. For example, a cellulose halide or a norbornene resin, an acrylic or polycarbonate film 15 suitable for use in an optical film such as a retardation film is preferable.

前期製程裝置13與薄膜拉伸設備10之間設置有張力調節部16。張力調節部16藉由位移機構19使自由輥17a與自由輥17b之間的張力輥18進行升降,以將預熱部11內的薄膜15的張力恆定維持。預熱部11內的薄膜張力在20N/m以上200N/m以下的範圍內為較佳。若為20N/m以上,則不會產生自由輥25的旋轉不良,薄膜15上的擦傷得到抑制。並且,若為200N/m以下,則預熱部11內不會產生縱向拉伸,且在縱向拉伸部12上進行適當的縱向拉伸。另外,上述薄膜張力(單位:N/m)為每1m寬的張力(單位:N)。 A tension adjusting portion 16 is provided between the preliminary processing device 13 and the film stretching device 10. The tension adjusting unit 16 raises and lowers the tension roller 18 between the free roller 17a and the free roller 17b by the displacement mechanism 19 to constantly maintain the tension of the film 15 in the preheating portion 11. The film tension in the preheating portion 11 is preferably in the range of 20 N/m or more and 200 N/m or less. When it is 20 N/m or more, the rotation failure of the free roller 25 does not occur, and the scratch on the film 15 is suppressed. In addition, when it is 200 N/m or less, longitudinal stretching does not occur in the preheating portion 11, and appropriate longitudinal stretching is performed on the longitudinally stretched portion 12. Further, the film tension (unit: N/m) is a tension per unit width (unit: N).

預熱部11具備預熱室20。預熱室20內沿上下方向分開配置有複數個自由輥(傳送方向變更構件)25。薄膜15交替捲繞在該些自由輥25上,藉此薄膜15在各自由輥25之間沿上向方向傳送,預熱室20內的薄膜路徑(通道)設定得較長。 The preheating unit 11 includes a preheating chamber 20. A plurality of free rollers (transport direction changing members) 25 are disposed apart from each other in the vertical direction in the preheating chamber 20. The film 15 is alternately wound around the free rolls 25, whereby the film 15 is transported in the upward direction between the rolls 25, and the film path (channel) in the preheating chamber 20 is set longer.

預熱室20的薄膜通道長度還取決於預熱溫度Tp和薄膜15的傳送速度,但例如在5m以上50m以下的範圍為較佳。自由輥25,例如直徑為80mm,且因薄膜15的掛繞,使得薄膜15與自由輥25之間的接觸面積變小。自由輥25的直徑在40mm以上150mm以下的範圍為較佳。若為40mm以上,則不會在自由輥25上產生撓曲,且由撓曲引起之旋轉不均和瑕疵得到抑制。並且,若為150mm以下,則與自由輥25之間的接觸時間處於適當的範圍內,除褶皺得到抑制之外,由自由輥25的旋轉不良引起之薄膜的擦傷亦會得到抑制。自由輥25的外周面被鍍上硬鉻為較佳。藉由實施鍍硬鉻,與薄膜15的黏附性得到提高,且薄膜15變得不易打滑。 The length of the film passage of the preheating chamber 20 is also dependent on the preheating temperature Tp and the conveying speed of the film 15, but it is preferably in the range of, for example, 5 m or more and 50 m or less. The free roller 25, for example, has a diameter of 80 mm, and the contact area between the film 15 and the free roller 25 becomes small due to the winding of the film 15. The diameter of the free roller 25 is preferably in the range of 40 mm or more and 150 mm or less. If it is 40 mm or more, the deflection does not occur on the free roller 25, and the unevenness of rotation due to the deflection and the flaw are suppressed. In addition, when it is 150 mm or less, the contact time with the free roller 25 is in an appropriate range, and in addition to the wrinkles being suppressed, the scratch of the film by the rotation failure of the free roller 25 is also suppressed. It is preferable that the outer peripheral surface of the free roller 25 is plated with hard chrome. By performing hard chrome plating, the adhesion to the film 15 is improved, and the film 15 becomes less slippery.

預熱部11內,例如在上側配置有供氣噴嘴31、下側配置有排氣噴嘴32。供氣噴嘴31及排氣噴嘴32上經由導管33連接有送風機34及溫度調節器35。溫度調節器35將作為加熱介質的例如空氣加熱至所希望的溫度。送風機34經由導管33將溫度被溫度調節器35調節之空氣送到供氣噴嘴31。從供氣噴嘴31送出加熱空氣,並藉由該加熱風36將預熱部11內的薄膜15預熱至一定溫度。加熱風36在預熱室20內從薄膜15的側方 開始迂迴進入,並對薄膜15的整個上表面及下表面進行預熱。 In the preheating unit 11, for example, an air supply nozzle 31 is disposed on the upper side and an exhaust nozzle 32 is disposed on the lower side. A blower 34 and a temperature regulator 35 are connected to the air supply nozzle 31 and the exhaust nozzle 32 via a duct 33. The temperature regulator 35 heats, for example, air as a heating medium to a desired temperature. The blower 34 sends air whose temperature is adjusted by the temperature adjuster 35 to the air supply nozzle 31 via the duct 33. The heated air is sent from the air supply nozzle 31, and the film 15 in the preheating portion 11 is preheated to a constant temperature by the heated air 36. The heated air 36 is from the side of the film 15 in the preheating chamber 20. The winding is started and the entire upper surface and the lower surface of the film 15 are preheated.

需要將藉由加熱風36預熱之預熱溫度Tp設為低於能夠拉伸之溫度(拉伸溫度)Te的溫度。為此,將薄膜15的玻璃化轉變溫度設為Tg時,向預熱部11內部供給加熱風36來將薄膜15預熱至(Te-40)℃以上(Tg-5)℃以下的範圍內的一定溫度。拉伸溫度Te在Tg℃以上(Tg+20)℃以下的範圍內。並且,從供氣噴嘴31吹出之加熱風的速度在2m/sec以上15m/sec以下的範圍內為較佳。若為2m/sec以上,則能夠均勻地保持預熱室20的溫度,且不產生拉伸不均。並且,若為15m/sce以下,則不會產生由薄膜15的擺動引起之擦傷。 It is necessary to set the preheating temperature Tp preheated by the heating air 36 to a temperature lower than the temperature (stretching temperature) Te which can be stretched. Therefore, when the glass transition temperature of the film 15 is Tg, the heating air 36 is supplied to the inside of the preheating section 11 to preheat the film 15 to a range of (Te - 40) ° C or more (Tg - 5) ° C or less. a certain temperature. The stretching temperature Te is in the range of Tg ° C or more (Tg + 20) ° C or less. Further, the speed of the heated air blown from the air supply nozzle 31 is preferably in the range of 2 m/sec or more and 15 m/sec or less. When it is 2 m/sec or more, the temperature of the preheating chamber 20 can be uniformly maintained, and stretching unevenness does not occur. Further, if it is 15 m/sce or less, scratching due to the swing of the film 15 does not occur.

經預熱部11被預熱至一定溫度之薄膜15被送往縱向拉伸部12。縱向拉伸部12具備低速輥組41、高速輥組42及冷卻輥43。低速輥組41具有低速輥41a和夾持輥41b。高速輥組42具有高速輥42a和夾持輥42b。從調溫介質循環部分別向低速輥41a、高速輥42a及冷卻輥43供給調溫介質例如油和加壓蒸汽。藉由該調溫介質的循環供給,低速輥41a、高速輥42a及冷卻輥43被設定成所希望的表面溫度。例如低速輥41a的溫度在Tg℃以上(Tg+20)℃以下的範圍內,高速輥42a的溫度在(Tg-100)℃以上(Tg-5)℃以下的範圍內,冷卻輥43的溫度在20℃以上(Tg-100)℃以下的範圍內。薄膜15與該些低速輥41a、高速輥42a及冷卻輥43接觸,藉此薄膜15被加熱或冷卻至與低速輥41a、高速輥42a及冷卻輥43的表面溫度相同的溫度。 The film 15 preheated to a certain temperature by the preheating portion 11 is sent to the longitudinal stretching portion 12. The longitudinal stretching portion 12 includes a low speed roller group 41, a high speed roller group 42, and a cooling roller 43. The low speed roller group 41 has a low speed roller 41a and a nip roller 41b. The high speed roller set 42 has a high speed roller 42a and a nip roller 42b. A temperature control medium such as oil and pressurized steam is supplied from the temperature control medium circulation portion to the low speed roller 41a, the high speed roller 42a, and the cooling roller 43, respectively. The low speed roller 41a, the high speed roller 42a, and the cooling roller 43 are set to a desired surface temperature by the cyclic supply of the temperature control medium. For example, the temperature of the low speed roller 41a is in the range of Tg ° C or more (Tg + 20) ° C or less, and the temperature of the high speed roller 42 a is in the range of (Tg - 100) ° C or more (Tg - 5) ° C or less, and the temperature of the cooling roller 43 is set. It is in the range of 20 ° C or more (Tg - 100) ° C or less. The film 15 is in contact with the low speed rolls 41a, the high speed rolls 42a, and the cooling rolls 43, whereby the film 15 is heated or cooled to the same temperature as the surface temperatures of the low speed rolls 41a, the high speed rolls 42a, and the cooling rolls 43.

雖然省略了圖示,但低速輥41a、高速輥42a及冷卻輥43上分別連接有馬達,並能夠以所希望的轉速旋轉。並且,藉由低速輥41a與高速輥42a之間的圓周速度差,薄膜15向傳送方向拉長而被縱向拉伸。低速輥41a和高速輥42a的“低速”、“高速”分別係指速度相對較低、相對較高。亦即,高速輥42a的圓周速度高於低速輥41a的圓周速度。低速輥41a和高速輥42a的圓周速度差依據縱向拉伸倍率得到適當變更,且將低速輥41a的圓周速度設定為例如20m/min以上80m/min以下的範圍內為較佳。藉由設成20m/min以上從而不降低製造效率。並且,藉由設成80m/min以下能夠確保薄膜15與低速輥41a的接觸時間,且可靠地進行加熱。 Although not shown in the drawings, a motor is connected to each of the low speed roller 41a, the high speed roller 42a, and the cooling roller 43, and is rotatable at a desired number of revolutions. Further, the film 15 is elongated in the conveying direction by the difference in circumferential speed between the low speed roller 41a and the high speed roller 42a, and is longitudinally stretched. The "low speed" and "high speed" of the low speed roller 41a and the high speed roller 42a mean that the speed is relatively low and relatively high, respectively. That is, the peripheral speed of the high speed roller 42a is higher than the peripheral speed of the low speed roller 41a. The circumferential speed difference between the low speed roller 41a and the high speed roller 42a is appropriately changed depending on the longitudinal stretching magnification, and it is preferable to set the peripheral speed of the low speed roller 41a to, for example, 20 m/min or more and 80 m/min or less. By setting it to 20 m/min or more, the manufacturing efficiency is not reduced. Further, by setting it to 80 m/min or less, the contact time between the film 15 and the low speed roller 41a can be ensured, and heating can be reliably performed.

進行縱向拉伸時,縱向拉伸倍率在大於1.0且小於等於1.5 的範圍為較佳。當縱向拉伸倍率在大於1.0且小於等於1.5以下的範圍時,能夠抑制厚度不均,並能夠抑制所顯現出之延遲的變動。 When longitudinally stretching, the longitudinal stretching ratio is greater than 1.0 and less than or equal to 1.5 The range is preferred. When the longitudinal stretching ratio is in the range of more than 1.0 and less than or equal to 1.5 or less, thickness unevenness can be suppressed, and variation in the retardation which appears can be suppressed.

預熱部11中,藉由將薄膜15預熱至(Te-40)℃以上,從而不會使利用縱向拉伸部12的低速輥41a對薄膜15進行加熱時的溫度上升量變得過大,且低速輥41a上的波紋板狀褶皺的產生得到抑制。並且,在預熱部11將薄膜15預熱至(Tg-5)℃以下,能夠不在預熱部11內拉伸薄膜15,而在縱向拉伸部12中均勻地拉伸。 In the preheating portion 11, by preheating the film 15 to (Te - 40) ° C or higher, the amount of temperature rise when the film 15 is heated by the low speed roller 41a of the longitudinal stretching portion 12 is not excessively increased, and The generation of corrugated plate wrinkles on the low speed roller 41a is suppressed. Further, in the preheating portion 11, the film 15 is preheated to (Tg - 5) ° C or lower, and the film 15 can be stretched in the longitudinal stretching portion 12 without stretching the film 15 in the preheating portion 11.

在縱向拉伸部12中被縱向拉伸之薄膜15被後期製程裝置14的例如薄膜捲取機捲取成薄膜卷。 The film 15 which is longitudinally stretched in the longitudinal stretching portion 12 is taken up by a film winding machine of the post-processing apparatus 14 into a film roll.

本實施形態中,向預熱室20送入加熱風36,並藉由加熱風36進行加熱,因此不同於以往的藉由預熱輥來導熱而進行之加熱,不會使薄膜15在預熱輥上因熱膨脹而成為波紋板狀,且褶皺和擦傷的產生得到抑制。尤其,如下薄膜的褶皺和擦傷得到抑制為較佳,亦即薄膜15被拉伸前的厚度在25μm以上100μm以下的範圍內,在25μm以上60μm以下的範圍內。 In the present embodiment, since the heating air 36 is sent to the preheating chamber 20 and heated by the heating air 36, it is different from the conventional heat by the preheating roller, and the film 15 is not preheated. The roller is corrugated due to thermal expansion, and generation of wrinkles and scratches is suppressed. In particular, it is preferable that the wrinkles and scratches of the film are suppressed, that is, the thickness of the film 15 before stretching is in the range of 25 μm or more and 100 μm or less, and is in the range of 25 μm or more and 60 μm or less.

另外,若以相同溫度對一個預熱室20進行預熱,則自由輥25的溫度亦能夠變成接近預熱室50的室溫的溫度。因此,進入到預熱室50之薄膜15與升高至預熱室50的出口溫度之入口側的自由輥25接觸,因此可能出現因薄膜15熱膨脹而成為向薄膜寬度方向重複凹凸之波紋板狀的褶皺的現象。為防止該現象,必須抑制由自由輥25的導熱進行之加熱,盡可能縮小自由輥25的直徑,並縮小其包角。因此當薄膜傳送速度為40m/min時,將自由輥25的直徑設在40mm以上150mm以下的範圍內,以便即使藉由加熱風36加熱的自由輥25接觸薄膜15亦不會因熱膨脹而引起變形。實際上,有時自由輥25的溫度因藉由與連續送來之薄膜15(溫度低於預熱室20的溫度)接觸而變得低於預熱室20內的溫度,因此不會產生因薄膜接觸自由輥25而引起之熱變形。 Further, if one preheating chamber 20 is preheated at the same temperature, the temperature of the free roller 25 can also become a temperature close to the room temperature of the preheating chamber 50. Therefore, the film 15 that has entered the preheating chamber 50 is in contact with the free roller 25 that is raised to the inlet side of the outlet temperature of the preheating chamber 50, so that the film 15 may be thermally expanded to become a corrugated plate shape in which the unevenness is repeated in the film width direction. The phenomenon of wrinkles. In order to prevent this, it is necessary to suppress the heating by the heat conduction of the free roller 25, to reduce the diameter of the free roller 25 as much as possible, and to reduce the wrap angle. Therefore, when the film transport speed is 40 m/min, the diameter of the free roller 25 is set in the range of 40 mm or more and 150 mm or less, so that even if the free roller 25 heated by the heated wind 36 contacts the film 15, it does not cause deformation due to thermal expansion. . Actually, sometimes the temperature of the free roller 25 becomes lower than the temperature in the preheating chamber 20 by contact with the continuously fed film 15 (the temperature is lower than the temperature of the preheating chamber 20), so that no cause is caused. The film is in contact with the free roller 25 to cause thermal deformation.

上述實施形態中,以1個預熱室20對薄膜15進行加熱,但如圖2所示,亦可以由具有藉由隔板49將預熱室50向薄膜傳送方向劃分為複數個之預熱區域50a~50c之預熱部51進行加熱。另外,圖2中,對與上述實施形態相同的結構構件標註相同的元件符號。該第2實施形態中, 在各預熱區域50a~50c設置供氣噴嘴31、排氣噴嘴32、導管33、送風機34及溫度調節器35,並將各預熱區域50a~50c內的溫度設定成在薄膜傳送方向上逐漸升高。相鄰之預熱區域50a~50c之間的溫差例如在20℃以上50℃以下的範圍內。該溫差為20℃以上時,能夠將劃分個數減少至適當範圍來提高設備效率。並且,為50℃以下時,不會在相鄰之預熱區域50a~50c之間產生由空氣的交換引起之溫度不均,且不會有拉伸不均。 In the above embodiment, the film 15 is heated by one preheating chamber 20. However, as shown in Fig. 2, the preheating chamber 50 may be divided into a plurality of preheating directions in the film conveying direction by the partition plate 49. The preheating sections 51 of the regions 50a to 50c are heated. In FIG. 2, the same components as those of the above-described embodiment are denoted by the same reference numerals. In the second embodiment, An air supply nozzle 31, an exhaust nozzle 32, a duct 33, a blower 34, and a temperature regulator 35 are provided in each of the preheating zones 50a to 50c, and the temperatures in the respective preheating zones 50a to 50c are set to gradually increase in the film conveying direction. Raise. The temperature difference between the adjacent preheating zones 50a to 50c is, for example, in the range of 20 ° C or more and 50 ° C or less. When the temperature difference is 20 ° C or more, the number of divisions can be reduced to an appropriate range to improve equipment efficiency. Further, when the temperature is 50 ° C or less, temperature unevenness due to exchange of air is not generated between the adjacent preheating regions 50a to 50c, and stretching unevenness does not occur.

各預熱區域50a~50c的劃分個數依據預熱溫度Tp進行增減。例如,若以相同溫度對1個預熱室50進行預熱,則進入到預熱室50之薄膜15會與升高至預熱室50的出口溫度之入口側的自由輥25接觸,因此可能出現因薄膜15熱膨脹而成為向薄膜寬度方向重複凹凸之波紋板狀的褶皺的現象。為防止該現象,將各預熱區域50a~50c的預熱溫度Tp設定得較小,小至即使藉由加熱風36加熱之自由輥25與薄膜15接觸亦不產生因熱膨脹而變形之程度。並且,階段性地進行預熱,直至能夠藉由複數個預熱區域50a~50c進行縱向拉伸之溫度。 The number of divisions of each of the preheating zones 50a to 50c is increased or decreased according to the preheating temperature Tp. For example, if one preheating chamber 50 is preheated at the same temperature, the film 15 that has entered the preheating chamber 50 will come into contact with the free roller 25 that is raised to the inlet side of the outlet temperature of the preheating chamber 50, so that it is possible There is a phenomenon in which the film 15 is thermally expanded to form corrugated plate-like wrinkles which are irregular in the width direction of the film. In order to prevent this, the preheating temperature Tp of each of the preheating zones 50a to 50c is set to be small, so that even if the free roller 25 heated by the heating wind 36 comes into contact with the film 15, the degree of deformation due to thermal expansion does not occur. Further, the preheating is performed stepwise until the temperature in which the longitudinal stretching can be performed by the plurality of preheating zones 50a to 50c.

並且,可以採用圖3的預熱部63來代替將預熱室50劃分成複數個。預熱部63在1個預熱室60中,藉由調溫機構62a~62c向各自由輥61供給調溫介質,以調節每一組的自由輥61的表面溫度。此時,從入口側依次調高每一組的自由輥61的表面溫度。將各自由輥61的表面溫度設定為,不會因接觸薄膜15而產生由熱膨脹引起之波紋板狀的褶皺之溫度。另外,除對每一組進行調溫之外,可以對每個自由輥61進行調溫。此外,如圖2所示,對被劃分之預熱室50內的自由輥25同樣可以進行調溫。相鄰之下游側的組和上游側的組的自由輥61的溫差為50℃以下,最上游的組的自由輥61的溫度相對於預熱室50的外部室溫在+20℃以上50℃以下的範圍內。 Further, instead of dividing the preheating chamber 50 into a plurality of portions, the preheating portion 63 of Fig. 3 may be employed. The preheating unit 63 supplies the temperature control medium to each of the rolls 61 by the temperature adjustment mechanisms 62a to 62c in one preheating chamber 60 to adjust the surface temperature of the free rolls 61 of each group. At this time, the surface temperature of the free roller 61 of each group is raised in order from the inlet side. The surface temperature of each of the rolls 61 is set so as not to cause a temperature of corrugated plate-like wrinkles due to thermal expansion due to contact with the film 15. Further, in addition to temperature adjustment for each group, each of the free rollers 61 can be tempered. Further, as shown in FIG. 2, the free roller 25 in the divided preheating chamber 50 can be similarly tempered. The temperature difference of the free roller 61 of the group on the downstream side and the group on the upstream side is 50 ° C or less, and the temperature of the free roller 61 of the most upstream group is +20 ° C or more and 50 ° C with respect to the outside room temperature of the preheating chamber 50 . Within the scope below.

上述各實施形態中,利用自由輥25、61將預熱室20、50、60內的薄膜通道長度設長。然而,如圖4所示,亦可以採用利用轉向桿70之預熱部71來代替自由輥25、61。此時,在轉向桿70上連接送風機72及溫度調節器73來向轉向桿70供給懸浮空氣。可以將懸浮空氣設定為與預熱室74的預熱溫度Tp相同,或設定成低於預熱溫度Tp。另外,圖3及圖4中,預熱室60、74具備圖1所示之送風機34及溫度調節器35,但省略 了圖示。並且,與圖2的實施形態相同,可以藉由將預熱室60、74劃分為複數個來形成預熱區域,並在該些各預熱室60、74的預熱區域設置送風機34及溫度調節器35,對每個預熱區域設定預熱溫度Tp,並將預熱溫度Tp設成從入口側逐漸向出口側升高。並且,與圖3的實施形態的自由輥61相同,可以對各轉向桿70或每一組進行來自各轉向桿70的懸浮空氣的溫度的變更,以設成從預熱室74的入口逐漸向出口升高。 In each of the above embodiments, the lengths of the film passages in the preheating chambers 20, 50, and 60 are set to be long by the free rollers 25, 61. However, as shown in FIG. 4, the preheating portion 71 of the steering lever 70 may be employed instead of the free rollers 25, 61. At this time, the blower 72 and the temperature adjuster 73 are connected to the steering lever 70 to supply the suspension air to the steering lever 70. The suspended air may be set to be the same as the preheating temperature Tp of the preheating chamber 74, or set to be lower than the preheating temperature Tp. In addition, in FIGS. 3 and 4, the preheating chambers 60 and 74 are provided with the blower 34 and the temperature regulator 35 shown in FIG. 1, but are omitted. The illustration. Further, as in the embodiment of FIG. 2, the preheating zone can be formed by dividing the preheating chambers 60, 74 into a plurality of, and the blower 34 and the temperature are provided in the preheating zones of the preheating chambers 60, 74. The regulator 35 sets the preheating temperature Tp for each of the preheating zones, and sets the preheating temperature Tp to gradually rise from the inlet side to the outlet side. Further, similarly to the free roller 61 of the embodiment of Fig. 3, the temperature of the suspended air from each of the steering levers 70 can be changed for each of the steering levers 70 or each group so as to be gradually moved from the entrance of the preheating chamber 74. Exports are rising.

上述實施形態中,作為縱向拉伸部12使用低速輥組41及高速輥組42,但不限於夾持式,亦可以將槽紋加工輥等高保持力輥用作低速輥及高速輥。並且,作為縱向拉伸部12採用利用上游側低速輥組41和下游側高速輥組42進行之1級縱向拉伸,但亦可以採用複數級縱向拉伸。 In the above-described embodiment, the low-speed roller group 41 and the high-speed roller group 42 are used as the longitudinal stretching portion 12. However, the high-speed holding roller such as a fluted processing roller may be used as the low-speed roller and the high-speed roller. Further, as the longitudinal stretching portion 12, the first-stage longitudinal stretching by the upstream-side low-speed roller group 41 and the downstream-side high-speed roller group 42 is employed, but a plurality of longitudinal stretching may be employed.

[實施例] [Examples]

作為薄膜15使用厚度為55μm、寬度為600mm、Tg為145℃的纖維素醯化物薄膜,並進行了預熱、縱向拉伸及冷卻。縱向拉伸部12中,進行了利用上游側低速輥組41和下游側高速輥組42進行之1級縱向拉伸。作為前期製程裝置13使用薄膜送出機,從薄膜卷牽引薄膜15來向預熱部11送出。作為後期製程裝置14使用薄膜捲取機,捲取薄膜15來作 為薄膜卷。預熱部11中,在預熱室20內配設直徑為60mm的自由輥25,在該些自由輥上掛繞薄膜15,並將預熱室20內的薄膜通道長度設為20m。並且,供給加熱風36以進行預熱,直至達到所希望的薄膜溫度。將縱向拉伸倍率設為1.3倍、拉伸長度Le(參閱圖1)設為300mm、冷卻溫度設為100℃、並將薄膜傳送速度設為40m/min,如上述表1所示,改變預熱溫度Tp及拉伸溫度Te來進行實驗1~實驗17。另外,實驗1~實驗16中進行利用加熱室供給加熱風之預熱,實驗17中,藉由與預熱輥接觸而進行預熱。 As the film 15, a cellulose vaporized film having a thickness of 55 μm, a width of 600 mm, and a Tg of 145 ° C was used, and preheating, longitudinal stretching, and cooling were carried out. In the longitudinal stretching portion 12, the first-stage longitudinal stretching by the upstream-side low-speed roller group 41 and the downstream-side high-speed roller group 42 is performed. The pre-process apparatus 13 is sent out from the film roll pulling film 15 to the preheating section 11 using a film feeder. As the post-processing device 14, a film winding machine is used, and the film 15 is taken up. For film rolls. In the preheating section 11, a free roller 25 having a diameter of 60 mm is disposed in the preheating chamber 20, and the film 15 is wound around the free rollers, and the length of the film passage in the preheating chamber 20 is set to 20 m. Also, heated wind 36 is supplied to preheat until the desired film temperature is reached. The longitudinal stretching ratio was set to 1.3 times, the stretching length Le (see FIG. 1) was set to 300 mm, the cooling temperature was set to 100 ° C, and the film conveying speed was set to 40 m/min, as shown in Table 1 above, the change was made. Experiment 1 to Experiment 17 were carried out at a thermal temperature Tp and a stretching temperature Te. Further, in Experiments 1 to 16, the preheating of the heated wind by the heating chamber was performed, and in Experiment 17, the preheating was performed by contact with the preheating roll.

針對所獲拉伸薄膜進行了擦傷、褶皺及拉伸不均等評價。藉由顯微鏡觀察擦傷,藉由目視觀察褶皺,藉此進行評價。當沒有擦傷及褶皺時作為優“A”,當擦傷及褶皺為能夠允許之等級時作為良“B”,當擦傷及褶皺不在允許範圍內時作為不合格“C”。關於拉伸不均,當5m長的樣片的長邊方向的最大厚度與最小厚度之差為3μm以下時作為優“A”,當超過3μm小於等於5μm時作為能夠允許之等級的良“B”,當超過5μm時作為不合格“C”。據實驗結果可知,在藉由加熱風進行預熱之實驗1~實驗16中,關於預熱溫度Tp,小於(拉伸溫度Te-40)℃及超過(Tg-5)℃時,評價出擦傷、褶皺及拉伸不均均為不合格“C”。藉此可知,預熱溫度Tp適宜在(Te-40)℃以上(Tg-5)℃以下的範圍內。並且,可知拉伸溫度Te小於Tg及超過(Tg+20)℃時,評價出擦傷、褶皺及拉伸不均均為不合格“C”。藉此可知,拉伸溫度Te適宜在Tg℃以上(Tg+20)℃以下的範圍內。並且,藉由使薄膜接觸預熱輥來進行預熱之實驗17中雖未出現拉伸不均,但擦傷及褶皺都評價為不良“C”。 The obtained stretched film was evaluated for scratches, wrinkles, and uneven stretching. The abrasion was observed by a microscope, and the wrinkles were visually observed to evaluate. When there is no scratch and wrinkle, it is excellent "A", and when the scratch and wrinkle are grades that can be allowed, it is good "B", and when scratches and wrinkles are not within the allowable range, it is regarded as unqualified "C". Regarding the unevenness of the stretching, when the difference between the maximum thickness and the minimum thickness in the longitudinal direction of the sample of 5 m length is 3 μm or less, it is excellent "A", and when it exceeds 3 μm and is less than or equal to 5 μm, it is a good "B" as an allowable grade. When it exceeds 5 μm, it is regarded as unqualified "C". According to the experimental results, it was found that in the experiments 1 to 16 in which the preheating was performed by heating the wind, the preheating temperature Tp was less than (stretching temperature Te-40) ° C and exceeded (Tg - 5) ° C, and the abrasion was evaluated. , wrinkles and uneven stretching are all unqualified "C". From this, it is understood that the preheating temperature Tp is suitably in the range of (Te - 40) ° C or more (Tg - 5) ° C or less. Further, when the stretching temperature Te was less than Tg and exceeded (Tg + 20) °C, it was found that the scratches, wrinkles, and stretching unevenness were all unacceptable "C". From this, it is understood that the stretching temperature Te is suitably in the range of Tg ° C or more (Tg + 20) ° C or less. Further, although the stretching unevenness was not observed in the experiment 17 in which the film was brought into contact with the preheating roll, the scratches and wrinkles were evaluated as poor "C".

圖5係將上述合理範圍繪製成曲線圖之圖,用陰影表示之區域為本申請發明的合理條件範圍。縱軸為預熱溫度Tp(單位為℃),以與Tg之差表示。例如“-10”係指(Tg-10)℃,“5”係指(Tg+5)℃。另外,與Tg之差為0(零)時記為“Tg”。橫軸為拉伸溫度Te(單位為℃),以與Tg之差表示。例如“-5”係指(Tg-5)℃,“15”係指(Tg+15)℃。另外,與Tg之差為0(零)時記為“Tg”。如此,可知為進行均勻的拉伸,需要使拉伸溫度Te處於Tg℃以上(Tg+20)℃以下的範圍內,且需要將預熱溫度Tp設為(Tg-5)℃以下。並且可知,為了避免褶皺和擦傷的產生,預熱溫度Tp需要為(Te-40)℃以上。 Fig. 5 is a diagram in which the above-mentioned reasonable range is plotted as a graph, and the area indicated by hatching is a reasonable condition range of the invention of the present application. The vertical axis is the preheating temperature Tp (unit: °C), expressed as the difference from Tg. For example, "-10" means (Tg - 10) °C, and "5" means (Tg + 5) °C. In addition, when the difference from Tg is 0 (zero), it is referred to as "Tg". The horizontal axis is the stretching temperature Te (unit: °C), which is expressed as the difference from Tg. For example, "-5" means (Tg-5) °C, and "15" means (Tg + 15) °C. In addition, when the difference from Tg is 0 (zero), it is referred to as "Tg". Thus, it is understood that the stretching temperature Te needs to be in the range of Tg ° C or more (Tg + 20) ° C or less in order to perform uniform stretching, and it is necessary to set the preheating temperature Tp to (Tg - 5) ° C or less. Further, it is understood that the preheating temperature Tp needs to be (Te - 40) ° C or more in order to avoid generation of wrinkles and scratches.

10‧‧‧薄膜拉伸設備 10‧‧‧film stretching equipment

11‧‧‧預熱部 11‧‧‧Preheating Department

12‧‧‧縱向拉伸部 12‧‧‧ longitudinal stretching

13‧‧‧前期製程裝置 13‧‧‧Pre-process equipment

14‧‧‧後期製程裝置 14‧‧‧ late process equipment

15‧‧‧薄膜 15‧‧‧film

16‧‧‧張力調節部 16‧‧‧Tensile adjustment department

17a、17b‧‧‧自由輥 17a, 17b‧‧‧ free roll

18‧‧‧張力輥 18‧‧‧ Tension roller

19‧‧‧位移機構 19‧‧‧displacement mechanism

20‧‧‧預熱室 20‧‧‧Preheating room

25‧‧‧自由輥 25‧‧‧Free roll

31‧‧‧供氣噴嘴 31‧‧‧Air supply nozzle

32‧‧‧排氣噴嘴 32‧‧‧Exhaust nozzle

33‧‧‧導管 33‧‧‧ catheter

34‧‧‧送風機 34‧‧‧Air blower

35‧‧‧溫度調節器 35‧‧‧temperature regulator

36‧‧‧加熱風 36‧‧‧heating wind

41‧‧‧低速輥組 41‧‧‧Low speed roller set

41a‧‧‧低速輥 41a‧‧‧low speed roller

41b‧‧‧夾持輥 41b‧‧‧Clamping roller

42‧‧‧高速輥組 42‧‧‧High speed roller set

42a‧‧‧高速輥 42a‧‧‧High speed roller

42b‧‧‧夾持輥 42b‧‧‧Clamping roller

43‧‧‧冷卻輥 43‧‧‧Cooling roller

Claims (10)

一種拉伸薄膜的製造方法,其藉由向傳送方向拉伸由玻璃化轉變溫度為Tg之熱塑性樹脂構成之帶狀薄膜來製造拉伸薄膜,該拉伸薄膜的製造方法具備如下步驟:(A)藉由在前述傳送方向上分開配置之低速輥和以高於前述低速輥的圓周速度旋轉之高速輥向前述傳送方向拉伸前述薄膜之步驟,前述低速輥與前述薄膜接觸以將前述薄膜加熱至Tg℃以上(Tg+20)℃以下範圍內的拉伸溫度Te;及(B)在前述步驟A之前,向預熱室內部供給加熱風以將前述薄膜預熱至(Te-40)℃以上(Tg-5)℃以下範圍內之步驟。 A method for producing a stretched film, which comprises producing a stretched film by stretching a film-shaped film composed of a thermoplastic resin having a glass transition temperature of Tg in a transport direction, and the method for producing the stretched film has the following steps: (A) a step of stretching the film in the conveying direction by a low speed roller disposed separately in the conveying direction and a high speed roller rotating at a peripheral speed higher than the low speed roller, wherein the low speed roller contacts the film to heat the film a stretching temperature Te in a range of Tg ° C or more (Tg+20) ° C or less; and (B) supplying a heating wind to the inside of the preheating chamber to preheat the film to (Te - 40) ° C before the aforementioned step A The above range (Tg-5) °C or less. 如申請專利範圍第1項所述之拉伸薄膜的製造方法,其中,藉由前述高速輥將經由前述低速輥之薄膜冷卻至(Tg-100)℃以上(Tg-5)℃以下的範圍內。 The method for producing a stretched film according to claim 1, wherein the film passing through the low speed roll is cooled to a range of (Tg - 100) ° C or more (Tg - 5) ° C or less by the high speed roller. . 如申請專利範圍第1項或第2項所述之拉伸薄膜的製造方法,其中,前述預熱室內的前述薄膜的張力在20N/m以上200N/m以下的範圍內。 The method for producing a stretched film according to the first or second aspect of the invention, wherein the tension of the film in the preheating chamber is in a range of from 20 N/m to 200 N/m. 如申請專利範圍第1項或第2項所述之拉伸薄膜的製造方法,其中,前述預熱室在前述傳送方向上被劃分為複數個預熱區域,預熱溫度從被劃分為前述複數個預熱區域的上游側向下游側上升,相鄰之下游側預熱區域與上游側預熱區域的溫差為50℃以下。 The method for producing a stretched film according to claim 1 or 2, wherein the preheating chamber is divided into a plurality of preheating zones in the conveying direction, and the preheating temperature is divided into the plurality of preheating temperatures. The upstream side of the preheating zone rises toward the downstream side, and the temperature difference between the adjacent downstream side preheating zone and the upstream side preheating zone is 50 ° C or less. 如申請專利範圍第1項或第2項所述之拉伸薄膜的製造方法,其中,前述步驟B中的前述薄膜掛繞於改變前述傳送方向之複數個傳送方向變更構件上。 The method for producing a stretched film according to the first or second aspect of the invention, wherein the film in the step B is hung on a plurality of conveying direction changing members that change the conveying direction. 如申請專利範圍第5項所述之拉伸薄膜的製造方法,其中,前述傳送方向變更構件為自由輥。 The method for producing a stretched film according to claim 5, wherein the transport direction changing member is a free roller. 如申請專利範圍第5項所述之拉伸薄膜的製造方法,其中,前述傳送方向變更構件為轉向桿。 The method for producing a stretched film according to claim 5, wherein the conveying direction changing member is a steering rod. 如申請專利範圍第5項所述之拉伸薄膜的製造方法,其中,前述傳送方向變更構件在前述傳送方向上被劃分為複數個組,溫度從每一組的上游側逐漸向下游側上升。 The method for producing a stretched film according to claim 5, wherein the transport direction changing member is divided into a plurality of groups in the transport direction, and the temperature is gradually increased from the upstream side to the downstream side of each group. 如申請專利範圍第8項所述之拉伸薄膜的製造方法,其中,相鄰之下游側的前述組和上游側的前述組的前述傳送方向變更構件的溫差為50℃以下。 The method for producing a stretched film according to the eighth aspect of the invention, wherein the temperature difference of the transport direction changing member of the group on the downstream side and the group on the upstream side is 50° C. or less. 一種薄膜拉伸設備,其藉由向傳送方向拉伸由玻璃化轉變溫度為Tg之熱塑性樹脂構成之帶狀薄膜來製造拉伸薄膜,該拉伸薄膜設備具備:縱向拉伸部,向前述傳送方向拉伸前述薄膜;低速輥,存在於前述縱向拉伸部且藉由與前述薄膜接觸來將前述薄膜加熱至Tg℃以上(Tg+20)℃以下的拉伸溫度Te;高速輥,以高於前述低速輥的圓周速度旋轉,從而向前述傳送方向拉伸前述薄膜,前述高速輥在前述傳送方向上與前述低速輥分開配置於前述縱向拉伸部;及預熱部,向預熱室內部供給加熱風來將前述薄膜預熱至(Te-40)℃以上(Tg-5)℃以下,前述預熱部配置於前述縱向拉伸部的上游。 A film stretching apparatus for producing a stretched film by stretching a belt-shaped film composed of a thermoplastic resin having a glass transition temperature of Tg in a conveying direction, the stretched film apparatus comprising: a longitudinal stretching portion, which is conveyed as described above Stretching the film in the direction; the low-speed roll is present in the longitudinal stretching portion and is heated to a stretching temperature Te of Tg ° C or more (Tg+20) ° C or less by contact with the film; the high-speed roll is high Rotating at a peripheral speed of the low speed roller to stretch the film in the conveying direction, the high speed roller being disposed in the longitudinal direction in the conveying direction separately from the low speed roller; and a preheating portion in the preheating chamber The heating film is supplied to preheat the film to (Te - 40) ° C or more (Tg - 5) ° C or less, and the preheating portion is disposed upstream of the longitudinal stretching portion.
TW103106623A 2013-03-26 2014-02-27 Stretched film production method and film stretching apparatus TW201436996A (en)

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