TW201434243A - Motor bobbin - Google Patents

Motor bobbin Download PDF

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Publication number
TW201434243A
TW201434243A TW102148387A TW102148387A TW201434243A TW 201434243 A TW201434243 A TW 201434243A TW 102148387 A TW102148387 A TW 102148387A TW 102148387 A TW102148387 A TW 102148387A TW 201434243 A TW201434243 A TW 201434243A
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TW
Taiwan
Prior art keywords
paper
bobbin
motor
winding
resin molded
Prior art date
Application number
TW102148387A
Other languages
Chinese (zh)
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TWI621322B (en
Inventor
Shinji Naruse
Tatsushi Fujimori
Chihiro Kondo
Yasunori Tanaka
Original Assignee
Dupont Teijin Advanced Papers Japan Ltd
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Publication of TW201434243A publication Critical patent/TW201434243A/en
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Publication of TWI621322B publication Critical patent/TWI621322B/en

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Classifications

    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K3/00Details of windings
    • H02K3/32Windings characterised by the shape, form or construction of the insulation
    • H02K3/34Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation
    • H02K3/345Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation between conductor and core, e.g. slot insulation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K3/00Details of windings
    • H02K3/30Windings characterised by the insulating material
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K3/00Details of windings
    • H02K3/46Fastening of windings on the stator or rotor structure
    • H02K3/52Fastening salient pole windings or connections thereto
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K3/00Details of windings
    • H02K3/46Fastening of windings on the stator or rotor structure
    • H02K3/52Fastening salient pole windings or connections thereto
    • H02K3/521Fastening salient pole windings or connections thereto applicable to stators only
    • H02K3/522Fastening salient pole windings or connections thereto applicable to stators only for generally annular cores with salient poles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2277/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as reinforcement
    • B29K2277/10Aromatic polyamides [Polyaramides] or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0003Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular electrical or magnetic properties, e.g. piezoelectric
    • B29K2995/0007Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/34Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3406Components, e.g. resistors
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K2203/00Specific aspects not provided for in the other groups of this subclass relating to the windings
    • H02K2203/12Machines characterised by the bobbins for supporting the windings

Abstract

Provided is a motor bobbin around which a winding wire is wound, said motor bobbin comprising insulating paper and a resin moulded body. The insulating paper and the resin moulded body are coupled and fixed together without using an adhesive agent. Surfaces of the insulating paper which are in contact with the resin moulded body are configured using aramid paper comprising an aramid fibrid and aramid short fibres. Resin is melt extruded and thermal-fusion bonded upon the aramid paper comprising the aramid fibrid and the aramid short fibres, and the surfaces configured from the aramid paper are surface treated to obtain the insulating paper. The motor bobbin is obtained by bringing melted portions of the resin moulded body into contact with the top of the aramid paper.

Description

用於馬達之捲線軸 Winding spool for motor

本發明係關於一種用於馬達之捲線軸,更詳細而言,係關於一種用於馬達的捲線軸,例如,在構成油電混合車或電動車等的馬達發電機的馬達定子等之中,於纏繞有捲線的狀態下,嵌入磁芯捲線等的芯材。 The present invention relates to a bobbin for a motor, and more particularly to a bobbin for a motor, for example, in a motor stator or the like of a motor generator constituting a hybrid electric vehicle or an electric vehicle, A core material such as a magnetic core winding wire is embedded in a state in which a winding is wound.

油電混合車或電動車中,搭載有具電動馬達及發電機之選擇性機能的馬達發電機。這種馬達發電機,例如具備:圓柱狀轉子,固定於以可繞著軸心旋轉的輸出軸並被該輸出軸支撐;馬達定子,具有相對該轉子的外周面隔著一預定間隙的內周面;馬達殼體,收納該馬達定子。構成這種馬達發電機的馬達定子,一般係由芯材與捲線所構成,為了使該芯材與捲線之間絕緣,會將捲線纏繞在馬達用的捲線軸上,再將該纏繞有捲線的捲線軸嵌入芯材。過去,作為該等用於馬達之捲線軸,一般係由合成樹脂所構成,例如集中繞組定子(Concentrated winding Stator)的情況中,係使用聚苯硫醚等(例如參照日本特開2005-102454號公報及日本特開2002-142399號公報)。 In a hybrid electric vehicle or an electric vehicle, a motor generator having a selective function of an electric motor and a generator is mounted. Such a motor generator includes, for example, a cylindrical rotor fixed to and supported by an output shaft rotatable about an axis; and a motor stator having an inner circumference with a predetermined gap interposed with respect to an outer peripheral surface of the rotor a motor housing that houses the motor stator. The motor stator constituting such a motor generator is generally composed of a core material and a winding wire. In order to insulate the core material from the winding wire, the winding wire is wound around the winding bobbin for the motor, and the winding wire is wound. The spool is embedded in the core material. In the past, as the winding bobbin for the motor, it is generally composed of synthetic resin. For example, in the case of a concentrated winding stator, polyphenylene sulfide or the like is used (for example, refer to JP-A-2005-102454 Bulletin and Japanese Patent Laid-Open Publication No. 2002-142399.

然而,以該等合成樹脂構成捲線軸的情況中,該捲線軸的厚度之下限為0.6mm左右,未必能充分對應近年來馬達發電機類逐漸地高效率化、高輸出化及小型化的趨勢。要求高效率及高輸出的用於馬達發電機之捲線軸,必須同時滿足下列四個特性: 1)薄(低厚度);2)可防止捲線與芯材的接地故障(高耐電壓、耐局部放電);3)可承受捲線之發熱(耐熱性);4)具有機械性強度。 However, in the case where the bobbin is composed of the synthetic resin, the lower limit of the thickness of the bobbin is about 0.6 mm, which does not necessarily correspond to the trend of increasing efficiency, high output, and miniaturization of the motor generators in recent years. . High-efficiency and high-output spools for motor generators must meet the following four characteristics: 1) Thin (low thickness); 2) It can prevent grounding fault of coiled wire and core material (high withstand voltage, partial discharge resistance); 3) can withstand heat generation (heat resistance) of coiled wire; 4) has mechanical strength.

特別是低厚度,其意味著變薄的部分可使捲線的量增加,並增加繞組因數(winding factor),且可高輸出化,故被認為是極為重要的特性。 In particular, the low thickness means that the thinned portion can increase the amount of the winding wire, increase the winding factor, and can be outputted high, and is considered to be an extremely important characteristic.

本發明之目的在於提供一種用於馬達之捲線軸,其可承受馬達發電機等的高效率化、高輸出化。 An object of the present invention is to provide a bobbin for a motor that can withstand high efficiency and high output of a motor generator or the like.

本案發明人等鑒於此情況,為了開發可承受馬達發電機等的高效率化、高輸出化的用於馬達之捲線軸,而進行詳細研討,進而完成本發明。 In view of the above, the inventors of the present invention have conducted detailed studies to develop a bobbin for a motor that can withstand high efficiency and high output of a motor generator, and the like.

在第一態樣中,本發明提供一種纏繞有捲線的用於馬達之捲線軸,其係由絕緣紙及樹脂成型體所構成,其中:該絕緣紙及該樹脂成型體,係不用黏合劑而可連接固定;該絕緣紙與該樹脂成型體相接的面,係由醯胺紙所構成,該醯胺紙係由醯胺纖條體與醯胺短纖維所構成;該絕緣紙,係將樹脂熔融並押出於醯胺纖條體與醯胺短纖維所構成的醯胺紙上,且使其熱融合,再對由醯胺紙所構成的面進行表面處理而得之;以及使樹脂成形體之熔融部分接觸醯胺紙以形成該捲線軸。 In a first aspect, the present invention provides a winding bobbin for a motor wound with a winding wire, which is composed of an insulating paper and a resin molded body, wherein the insulating paper and the resin molded body are not bonded. The surface of the insulating paper that is in contact with the resin molded body is composed of amide paper, which is composed of melamine fibrids and guanamine short fibers; the insulating paper is The resin is melted and pressed onto a ruthenium paper composed of melamine fibrids and guanamine short fibers, and thermally fused, and then surface-treated with a surface composed of guanamine paper; and a resin molded body is obtained. The molten portion is contacted with the amide paper to form the bobbin.

在第二態樣中,本發明提供一種如第一態樣之用於馬達之捲線軸,其中更具備:捲線軸本體部,其至少一部分為該絕緣紙。 In a second aspect, the present invention provides a bobbin for a motor as in the first aspect, further comprising: a bobbin body portion, at least a portion of which is the insulating paper.

在第三態樣中,本發明提供一種如第一態樣之用於馬達之捲 線軸,其中更具備:一對樹脂成型體,連接於該捲線軸本體部的兩端。 In a third aspect, the present invention provides a roll for a motor as in the first aspect The bobbin further includes a pair of resin molded bodies connected to both ends of the bobbin main body portion.

在第四態樣中,本發明提供一種如第一態樣之用於馬達之捲線軸,其中,該表面處理為電漿表面處理。 In a fourth aspect, the invention provides a bobbin for a motor as in the first aspect, wherein the surface treatment is a plasma surface treatment.

在第五態樣中,本發明提供一種如第一態樣之用於馬達之捲線軸,其中,該絕緣紙與該樹脂成型體接觸的面浸漬於樹脂成型體 In a fifth aspect, the present invention provides a bobbin for a motor according to a first aspect, wherein a surface of the insulating paper in contact with the resin molded body is immersed in a resin molded body

在第六態樣中,本發明提供一種如第一態樣之用於馬達之捲線軸,其中,於樹脂成型體上,具有用以決定捲線之位置的溝槽。 In a sixth aspect, the present invention provides a bobbin for a motor as in the first aspect, wherein the resin molded body has a groove for determining the position of the winding.

在第七態樣中,本發明提供一種用於第一態樣之用於馬達之捲線軸的製造方法,該方法在使樹脂成型體成型時,同時進行與絕緣紙的黏合。 In a seventh aspect, the present invention provides a method for manufacturing a bobbin for a motor according to a first aspect, which simultaneously performs bonding with an insulating paper when molding a resin molded body.

在第八態樣中,本發明提供一種馬達,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於第一至第六態樣中任一種態樣的用於馬達之捲線軸上。 In an eighth aspect, the present invention provides a motor using a stator assembled with a core material and a winding wire, wherein the winding wire is wound around a winding bobbin for a motor in any one of the first to sixth aspects on.

在第九態樣中,本發明提供一種馬達發電機,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於第一至第六態樣中任一種態樣的用於馬達之捲線軸上。 In a ninth aspect, the present invention provides a motor generator using a stator assembled with a core material and a winding wire, wherein the winding wire is wound around any one of the first to sixth aspects for a motor On the spool.

在第十態樣中,本發明提供一種發電機,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於第一至第六態樣中任一種態樣的用於馬達之捲線軸上。 In a tenth aspect, the present invention provides a generator using a stator assembled with a core material and a winding wire, wherein the winding wire is wound around a winding wire for a motor in any one of the first to sixth aspects On the shaft.

1‧‧‧用於馬達之捲線軸 1‧‧‧Rolling spool for motor

2‧‧‧捲線軸本體 2‧‧‧Rolling spool body

4‧‧‧樹脂成型體 4‧‧‧Resin molded body

6‧‧‧中央部分 6‧‧‧ central part

6a‧‧‧外側面 6a‧‧‧Outside

8‧‧‧彎折部 8‧‧‧Bend

8a‧‧‧外側面 8a‧‧‧Outside

10‧‧‧本體部 10‧‧‧ Body Department

10a‧‧‧側面 10a‧‧‧ side

10b‧‧‧側面 10b‧‧‧ side

10c‧‧‧背面 10c‧‧‧back

12‧‧‧簷部 12‧‧‧檐

12a‧‧‧突出部 12a‧‧‧Protruding

12b‧‧‧內側面 12b‧‧‧ inside side

14‧‧‧溝槽 14‧‧‧ trench

16‧‧‧突起 16‧‧‧ Protrusion

18‧‧‧凹部 18‧‧‧ recess

第一圖係本發明之一實施態樣的用於馬達之捲線軸的立體圖。 The first figure is a perspective view of a bobbin for a motor in an embodiment of the present invention.

第二圖係構成第一圖的用於馬達之捲線軸中,彎折狀絕緣紙的立體圖。 The second drawing is a perspective view of the bent insulating paper in the bobbin for the motor of the first figure.

第三圖係構成第一圖的用於馬達之捲線軸中,樹脂成型體的立體圖。 The third drawing is a perspective view of a resin molded body in the bobbin for the motor of the first drawing.

第四圖係顯示第一圖中用於馬達之捲線軸,在與定子芯組裝時之配置的立體圖。 The fourth figure shows a perspective view of the configuration of the winding bobbin for the motor in the first figure when assembled with the stator core.

以下參照圖式,對本發明之較佳實施態樣的用於馬達之捲線軸進行詳細說明,但本發明並非特別限定於此實施態樣。第一圖係本發明之較佳實施態樣的用於馬達之捲線軸1的立體圖。 Hereinafter, a bobbin for a motor according to a preferred embodiment of the present invention will be described in detail with reference to the drawings, but the present invention is not particularly limited to the embodiment. The first figure is a perspective view of a bobbin 1 for a motor in accordance with a preferred embodiment of the present invention.

用於馬達之捲線軸1具備:捲線軸本體2,其剖面為「」狀;及一對樹脂成型體4,安裝於捲線軸本體2的兩端。 The bobbin 1 for a motor includes: a bobbin body 2 having a section of " And a pair of resin molded bodies 4 are attached to both ends of the bobbin main body 2.

如第二圖、即捲線軸本體2的立體圖所示,捲線軸本體2,係將長方形絕緣紙的兩側邊緣部以大致形成直角的方式往同一方向彎折,而使得剖面形成「」狀,其中具備中央部分6及位於兩側邊緣的一對彎折部8、8。 As shown in the perspective view of the second figure, that is, the bobbin main body 2, the bobbin main body 2 is formed by bending the both side edge portions of the rectangular insulating paper in the same direction at substantially right angles, so that the cross section is formed. The shape has a central portion 6 and a pair of bent portions 8, 8 located at both side edges.

如第三圖、即樹脂成型體4的立體圖所示,樹脂成型體4具備:本體部10,為長方體狀;及一對簷部12、12,設於本體部10的兩端。本實施態樣之用於馬達之捲線軸1中,本體部10與一對簷部12、12為一體成型。各簷部12具有相同形狀,簷部12的前端側部分,形成從本體部10突出的突出部12a。結果,樹脂成型體4具有大致為「」狀的剖面形狀。接著,樹脂成型體4中,以各簷部12的突出部12a之內側面12b,與本體部10在突出部12a之突出方向上的側面10a,形成三個面被圍住、剖面為矩形的空間。一對簷部12的突出部12a之內側面12b的間隔,與捲線軸本體2之中央部分6的 寬度大約相等。 As shown in the perspective view of the resin molded body 4, the resin molded body 4 includes a main body portion 10 having a rectangular parallelepiped shape, and a pair of weir portions 12 and 12 provided at both ends of the main body portion 10. In the spool 1 for a motor of the present embodiment, the body portion 10 and the pair of flange portions 12, 12 are integrally formed. Each of the crotch portions 12 has the same shape, and the distal end side portion of the crotch portion 12 forms a protruding portion 12a that protrudes from the main body portion 10. As a result, the resin molded body 4 has substantially " Shape of the section. Next, in the resin molded body 4, the inner side surface 12b of the protruding portion 12a of each of the flange portions 12 and the side surface 10a of the main body portion 10 in the protruding direction of the protruding portion 12a are formed to have three faces surrounded and have a rectangular cross section. space. The interval between the inner side faces 12b of the projections 12a of the pair of crotch portions 12 is approximately equal to the width of the central portion 6 of the bobbin main body 2.

捲線軸本體2在長邊方向上的兩端,分別連接有各樹脂成型體4。詳細而言,剖面為「」狀的捲線軸本體2,中央部分6之外側面6a的兩端,與樹脂成型體4之本體部10的側面10a接合,且各彎折部8之外側面8a,與樹脂成型體4之突出部12a的內側面12b接合,藉此連接並固定於各樹脂成型體4。 Each of the resin molded bodies 4 is connected to both ends of the bobbin main body 2 in the longitudinal direction. In detail, the profile is " The bobbin main body 2 of the shape, the both ends of the outer side surface 6a of the center portion 6 are joined to the side surface 10a of the main body portion 10 of the resin molded body 4, and the outer side surface 8a of each bent portion 8 and the resin molded body 4 are The inner side faces 12b of the protruding portions 12a are joined, thereby being joined and fixed to the respective resin molded bodies 4.

捲線軸本體2,與各樹脂成型體4的接合部分,不需透過黏合劑,即可與各樹脂成型體4連接。更進一步,捲線軸本體2與樹脂成型體4接合的面,係由醯胺紙所構成,該醯胺紙係由醯胺纖條體與醯胺短纖維所構成。更進一步,絕緣紙,係將樹脂熔融押出於醯胺纖條體與醯胺短纖維所構成的醯胺紙上,且使其熱融合,再對以醯胺紙所構成之面進行表面處理而得之。 The joint portion of the spool main body 2 and each of the resin molded bodies 4 can be connected to each of the resin molded bodies 4 without passing through a binder. Further, the surface of the bobbin main body 2 joined to the resin molded body 4 is composed of a ruthenium paper which is composed of a guanamine fibrid and a guanamine short fiber. Further, the insulating paper is obtained by melting a resin onto a ruthenium paper composed of a melamine fibril and a guanamine short fiber, and thermally fusion, and then surface-treating the surface composed of amide paper. It.

本實施態樣之用於馬達之捲線軸1中,各樹脂成型體4之本體部10中,向外的側面10b的整體上,形成有多條在水平方向上延伸、用於決定捲線位置的溝槽14。 In the bobbin 1 for a motor of the present embodiment, in the main body portion 10 of each of the resin molded bodies 4, a plurality of outwardly extending side faces 10b are formed in the horizontal direction for determining the position of the winding. Trench 14.

如第四圖所示,本實施態樣之用於馬達之捲線軸1中,一邊的樹脂成型體4的本體部10之背面10c上形成有突起16,另一邊的樹脂成型體4的本體部10之背面10c上形成有凹部18。該等突起16及凹部18,係用於下述情形:以如第四圖所示的配置,將一對用於馬達之捲線軸1隔開配置,並使配置於該一對用於馬達之捲線軸之間的定子芯,與用於馬達之捲線軸1連接。 As shown in the fourth embodiment, in the bobbin 1 for a motor of the present embodiment, the projection 16 is formed on the back surface 10c of the main body portion 10 of the resin molded body 4 on one side, and the main body portion of the resin molded body 4 on the other side is formed. A recess 18 is formed in the back surface 10c of 10. The projections 16 and the recesses 18 are used in a configuration in which a pair of bobbins 1 for a motor are disposed apart from each other in a configuration as shown in the fourth figure, and are disposed in the pair for the motor. The stator core between the bobbins is connected to the bobbin 1 for the motor.

(醯胺) (guanamine)

在本發明中,醯胺係指60%以上的醯胺鍵直接與芳香環鍵結的線狀高分子化合物(芳香族聚醯胺)。作為這樣的醯胺,可列舉:聚間伸苯基間苯二甲醯胺及其共聚物、聚對伸苯基對酞醯胺及其共聚物、聚(對苯)-共聚(3,4’-二苯基醚)對酞醯胺等。該等醯胺,可藉由例如,使用間苯二甲酸氯化物及間苯二胺的習知的界面聚合法、溶液聚合法等,來進行工業上的製造,且其可作為市售品而取得,但並不限定於此。在該等醯胺中,從具有良好的成型加工性、熱黏合性、阻燃性、耐熱性等特性的觀點來看,較宜使用聚間伸苯基間苯二甲醯胺。 In the present invention, guanamine refers to a linear polymer compound (aromatic polyamine) in which 60% or more of a guanamine bond is directly bonded to an aromatic ring. Examples of such guanamines include poly(phenylene isophthalamide) and copolymers thereof, polyparaphenylene phthalamide and copolymers thereof, and poly(p-phenylene)-copolymerization (3,4). '-Diphenyl ether) to guanamine and the like. These guanamines can be industrially produced by, for example, a conventional interfacial polymerization method using a isophthalic acid chloride or m-phenylenediamine, a solution polymerization method, or the like, and can be used as a commercial product. Acquired, but is not limited to this. Among these decylamines, poly(m-phenylene phthalamide) is preferably used from the viewpoint of having characteristics such as good moldability, thermal adhesiveness, flame retardancy, and heat resistance.

(醯胺纖條體) (melamine fiber strip)

在本發明中,醯胺纖條體,係具有造紙性之薄膜狀的醯胺粒,亦稱醯胺紙漿(參照日本特公昭35-11851號公報、日本特公昭37-5732號公報等)。 In the present invention, the guanamine fibrids are paper-like melamine granules, which are also known as melamine pulps (see Japanese Patent Publication No. Sho 35-11851, Japanese Patent Publication No. Sho 37-5732, etc.).

醯胺纖條體,已為人所知與一般的木材紙漿相同地實施分解、打漿處理,並使用作為造紙原料;可對其實施以保持適合造紙之品質為目的之所謂的打漿處理。該打漿處理,可藉由碟狀磨漿設備、打漿設備及其他可發揮機械性切斷作用之造紙原料處理設備來實施。在該操作中,纖條體之形態變化,可以日本工業規格(JIS)P8121所規定的游離度試驗方法(freeness test)進行監控。本發明中,實施打漿處理後的醯胺纖條體的游離度,在10cm3~300cm3(加拿大標準游離度(JISP8121))的範圍內為較佳。在游離度大於該範圍的纖條體中,具有後續步驟中所成形的醯胺紙,其強度降低的可能性。另一方面,若欲得到比10cm3更小的游離度,則具有很多「所輸入之機械動力的使用效率變小,且每單位時間之處理量變少」的情況, 更進一步,因為纖條體過度地微細化,容易導致所謂「黏著功能」的降低。因此,即使像這樣得到小於10cm3的游離度,亦不被認為具有特別的優點。 The guanamine fibrids are known to be decomposed and beaten in the same manner as ordinary wood pulp, and are used as a raw material for papermaking; so-called beating treatment for the purpose of maintaining the quality suitable for papermaking can be carried out. The beating treatment can be carried out by a disk refining device, a beating device, and other papermaking material processing equipment capable of exerting a mechanical cutting action. In this operation, the morphology of the fibrids is changed and can be monitored by the freeness test prescribed by Japanese Industrial Standards (JIS) P8121. In the present invention, the freeness of the guanamine fibrid after the beating treatment is preferably in the range of 10 cm 3 to 300 cm 3 (Canada standard freeness (JISP8121)). In the fibrids having a freeness greater than the range, there is a possibility that the strength of the lysine paper formed in the subsequent step is lowered. On the other hand, if a degree of freeness smaller than 10 cm 3 is to be obtained, there are many cases where the use efficiency of the input mechanical power is small and the amount of processing per unit time is small, and further, because of the sliver body Excessive miniaturization tends to reduce the so-called "adhesive function". Therefore, even if a freeness of less than 10 cm 3 is obtained as such, it is not considered to have a particular advantage.

(醯胺短纖維) (melamine short fiber)

醯胺短纖維,係將以醯胺作為材料之纖維切斷,而作為這種纖維,可列舉:帝人股份有限公司的「TEIJIN CONEX(註冊商標)」、杜邦公司的「NOMEX(註冊商標)」等,但並不限定於此。 In the case of the fiber, the "TEIJIN CONEX (registered trademark)" of Teijin Co., Ltd. and the "NOMEX (registered trademark) of DuPont" are listed as the fiber. Etc., but not limited to this.

醯胺短纖維的長度,一般可從1mm以上,未滿50mm的範圍內選擇,較佳係從2~10mm的範圍內選擇。若短纖維的長度小於1mm,則薄片材料的力學特性降低,另一方面,若在50mm以上,以濕式法製造醯胺紙時,容易發生「糾結」、「纏繞成束」等情況,而容易成為造成缺陷的原因。 The length of the guanamine short fibers can be generally selected from the range of 1 mm or more and less than 50 mm, and is preferably selected from the range of 2 to 10 mm. When the length of the short fibers is less than 1 mm, the mechanical properties of the sheet material are lowered. On the other hand, when the polyamide paper is produced by a wet method at 50 mm or more, "tangling" and "winding into bundles" are likely to occur. It is easy to be the cause of defects.

(醯胺紙) (amide paper)

本發明中,醯胺紙係主要由該醯胺纖條體及醯胺短纖維所構成的片材,一般而言,其厚度係在20μm~1000μm的範圍內。更進一步,醯胺紙,一般而言,其基重係在10g/m2~1000g/m2的範圍內。此處,醯胺纖條體與醯胺短纖維可以任意比例混合,但較宜為使醯胺纖條體/醯胺短纖維的比例(質量比)為1/9~9/1,更宜為2/8~8/2,但並不限定於該範圍。 In the present invention, the guanamine paper is a sheet mainly composed of the guanamine fibrid and the guanamine short fibers, and generally has a thickness in the range of 20 μm to 1000 μm. Further, the guanamine paper generally has a basis weight in the range of 10 g/m 2 to 1000 g/m 2 . Here, the guanamine fibrid and the guanamine short fiber may be mixed in any ratio, but it is more preferable to make the ratio (mass ratio) of the guanamine fibrid/melamine short fiber 1/9 to 9/1, more preferably It is 2/8~8/2, but it is not limited to this range.

醯胺紙,一般係以將上述醯胺纖條體與醯胺短纖維混合後再將其薄片化的方法進行製造。具體而言,可應用例如:將上述醯胺纖條體及醯胺短纖維進行乾式混合後,利用氣流形成薄片的方法;將醯胺纖條體及醯胺短纖維在液體介質中分散混合後,排出至具有液體通透性(liquid permeability)的支撐體(例如網或帶),以將其薄片化,再去除液體以將其乾燥的方法等;該等方法之中,宜選擇將水使用為介質的通稱的濕式製造法。 The guanamine paper is generally produced by a method in which the above guanamine fibrids and guanamine short fibers are mixed and then flaky. Specifically, for example, a method in which the above-described guanamine fibrids and guanamine short fibers are dry-mixed and then formed into a sheet by a gas flow; and the guanamine fibrids and the guanamine short fibers are dispersed and mixed in a liquid medium; a method of discharging to a support having a liquid permeability (for example, a mesh or a belt) to exfoliate it, removing the liquid to dry it, and the like; among the methods, it is preferred to use water A general term for wet manufacturing of media.

濕式製造法中,一般方法,係將至少含有醯胺纖條體、醯胺短纖維之單一或混合物的水性漿液供給至抄紙機以使其分散之後,進行脫水、擠水及乾燥操作,以作為片材而將其捲繞。可利用長網造紙機、圓網造紙機、傾斜型造紙機及將該等裝置組合的混合造紙機等作為造紙機。在以混合造紙機進行製造的情況中,可使摻合比例不同的漿液薄片成形並合為一體,而得到複數的紙層所形成之複合薄片。製造時,可相應於需求,使用分散性提升劑、消泡劑、紙力增強劑等的添加劑。 In the wet manufacturing method, a general method is to supply an aqueous slurry containing at least a single or a mixture of guanamine fibrids and guanamine short fibers to a paper machine to disperse, and then perform dehydration, squeezing and drying operations. It is wound as a sheet. A paper machine can be used as a paper machine by using a Fourdrinier paper machine, a cylinder paper machine, a tilt type paper machine, and a hybrid paper machine in which the devices are combined. In the case of manufacturing in a mixed paper machine, the slurry sheets having different blending ratios can be formed and integrated to obtain a composite sheet formed of a plurality of paper layers. At the time of manufacture, an additive such as a dispersibility enhancer, an antifoaming agent, a paper strength enhancer or the like may be used depending on the demand.

將以上述方法所得之醯胺紙,在一對滾筒之間,以高溫高壓進行熱壓,藉此可提高其密度、機械強度。例如,在使用金屬製滾筒的情況中,熱壓的條件雖例示為溫度100~400℃、線壓50~400kg/cm的範圍內,但並不限定於此。熱壓時亦可堆疊複數之醯胺紙。上述熱壓加工亦可以任意順序進行多次。 The guanamine paper obtained by the above method is hot-pressed at a high temperature and a high pressure between a pair of rolls, whereby the density and mechanical strength can be improved. For example, in the case of using a metal drum, the conditions of hot pressing are exemplified by a temperature of 100 to 400 ° C and a linear pressure of 50 to 400 kg/cm, but the invention is not limited thereto. A plurality of polyamide papers may also be stacked during hot pressing. The above hot press processing can also be performed multiple times in any order.

(絕緣紙) (Insulating paper)

在本發明中,於絕緣紙之中,至少該絕緣紙與樹脂成型體接合側的面,係由醯胺紙所構成,而該醯胺紙係由醯胺纖條體與醯胺短纖維所構成,即相當於對「將樹脂熔融並押出於醯胺紙上而使其熱融合後的絕緣紙」進行表面處理所得到的絕緣紙。作為該樹脂,較宜使用聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚醯亞胺、聚四氟乙烯、聚苯硫醚、聚醯胺、半芳香族聚醯胺、苯氧基等的聚合物、或是該等聚合物之混合物、合金等,但並不限定於此。 In the present invention, among the insulating papers, at least the surface on the side where the insulating paper and the resin molded body are joined is composed of guanamine paper, and the guanamine paper is made of guanamine fibrid and guanamine short fibers. The structure is equivalent to the insulating paper obtained by surface-treating the "insulating paper which melts the resin and presses it on the amide paper and heat-fused it." As the resin, polyethylene terephthalate, polyethylene naphthalate, polyimide, polytetrafluoroethylene, polyphenylene sulfide, polyamine, semi-aromatic polyamine, A polymer such as a phenoxy group, or a mixture or alloy of the polymers, but is not limited thereto.

醯胺紙層與樹脂層的堆疊層數,可對應堆疊體的用途、目的而適當選擇,但因為若至少一邊的表層為醯胺紙層,可使滑動性良好,進 而具有「在馬達中,例如使上述捲線軸,容易插入設於馬達定子的芯材與捲線之間、即設於芯材的縫隙(slot)之間」的效果,故為較佳。可列舉如日本特開2006-321183號公報所記載之聚合物與醯胺紙的雙層堆疊片材,該聚合物係由芳香族聚醯胺樹脂與含環氧基之苯氧基樹脂(其在分子內具有環氧基)所構成,而該含環氧基之苯氧基樹脂的比例為30~50質量%;或是三層堆疊片材,係由醯胺紙、該聚合物及醯胺紙所形成;但並不限定於此。 The number of stacked layers of the guanamine paper layer and the resin layer can be appropriately selected according to the purpose and purpose of the stacked body. However, if at least one surface layer is a guanamine paper layer, the slidability is improved. In the motor, for example, it is preferable that the bobbin is easily inserted between the core material and the winding wire of the motor stator, that is, between the slots of the core material. A double-layered stacked sheet of a polymer and a guanamine paper as described in JP-A-2006-321183, which is composed of an aromatic polyamide resin and an epoxy group-containing phenoxy resin. It is composed of an epoxy group in the molecule, and the ratio of the epoxy group-containing phenoxy resin is 30 to 50% by mass; or a three-layer stacked sheet is made of guanamine paper, the polymer and ruthenium. The amine paper is formed; however, it is not limited thereto.

堆疊體的厚度,可對應堆疊體的用途及目的而適當選擇,只要在彎折、纏繞等的加工性上沒有問題,則可選擇任意厚度。一般從加工性的觀點來看,其厚度宜在50μm~1000μm的範圍內,但並不限定於此。 The thickness of the stacked body can be appropriately selected in accordance with the use and purpose of the stacked body, and any thickness can be selected as long as there is no problem in workability such as bending or winding. Generally, the thickness is preferably in the range of 50 μm to 1000 μm from the viewpoint of workability, but is not limited thereto.

(表面處理) (surface treatment)

本發明中之表面處理,可列舉:電漿表面處理、電暈放電表面處理、利用液體浸漬之表面處理等。藉由實施該等表面處理,提高絕緣紙表面之表面能量,並降低與樹脂成型體的界面能量,其結果,提高與樹脂成型體的黏合性。從處理之簡便性來看,特別宜使用電漿表面處理。 The surface treatment in the present invention may, for example, be a plasma surface treatment, a corona discharge surface treatment, a surface treatment by liquid impregnation, or the like. By performing such surface treatment, the surface energy of the surface of the insulating paper is increased, and the interface energy with the resin molded body is lowered, and as a result, the adhesion to the resin molded body is improved. From the standpoint of ease of handling, it is particularly desirable to use a plasma surface treatment.

(電漿表面處理) (plasma surface treatment)

本發明中之電漿表面處理,係指以下述方式所進行的處理:藉由在電極間施加直流或交流的高電壓而開始持續放電,使處理基材暴露於,例如,大氣壓下的電暈放電或是真空中的輝光放電等。此時,雖並無特別限定,但宜為在處理氣體之選擇較為廣泛的真空中所進行的處理。作為處理氣體,雖並無特別限定,但可單獨使用氦(He),氖(Ne)、氬(Ar)、氮、氧、碳酸氣體、空氣、水蒸氣等氣體,或是在將該等氣體混合的狀態下使用。其中,從放電起始效率的觀點來看,較宜為氬(Ar)、碳酸氣體。處理壓 力雖並無特別限定,但從處理效率的觀點來看,較宜為在0.1Pa~1330Pa的壓力範圍進行持續放電的輝光放電處理,即所謂的低溫電漿處理。更宜為1Pa~266Pa的範圍。 The plasma surface treatment in the present invention refers to a treatment performed by applying a high voltage of direct current or alternating current between electrodes to initiate continuous discharge, exposing the treated substrate to, for example, corona at atmospheric pressure. Discharge or glow discharge in vacuum. In this case, although it is not particularly limited, it is preferably a treatment performed in a vacuum in which the treatment gas is widely selected. The processing gas is not particularly limited, but gases such as helium (He), neon (Ne), argon (Ar), nitrogen, oxygen, carbonic acid gas, air, water vapor, or the like may be used alone. Used in a mixed state. Among them, from the viewpoint of discharge initiation efficiency, argon (Ar) or carbonic acid gas is preferred. Processing pressure Although the force is not particularly limited, from the viewpoint of the treatment efficiency, it is preferred to perform a glow discharge treatment for sustain discharge in a pressure range of 0.1 Pa to 1330 Pa, that is, a so-called low-temperature plasma treatment. More preferably in the range of 1 Pa to 266 Pa.

在本發明中,更具體而言,藉由使醯胺紙表面上的氧原子(O)與碳原子(C)之組成比X(O/C),在理論值的120%以上,250%以下的範圍內,可得到作為目的之良好的熱融合性。此處,組成比X(O/C),係指以X射線光電子能譜(XPS;X-rays Photoelectron Spectroscopy)測定醯胺紙表面之碳原子數(C)與氧原子數(O)的原子數比(測量值)。又,該理論值係指在構成樹脂的樹脂組成中,從高分子化學結構式的重複單元所算出的原子數比例的值。 In the present invention, more specifically, by making the composition ratio of the oxygen atom (O) to the carbon atom (C) on the surface of the guanamine paper X (O/C), it is 120% or more of the theoretical value, 250%. In the following ranges, good thermal fusion properties are obtained for the purpose. Here, the composition ratio X(O/C) refers to an atom which determines the number of carbon atoms (C) and the number of oxygen atoms (O) on the surface of the guanamine paper by X-ray photoelectron spectroscopy (XPS; X-rays Photoelectron Spectroscopy). Number ratio (measured value). In addition, the theoretical value refers to the value of the atomic ratio calculated from the repeating unit of the polymer chemical structural formula in the resin composition constituting the resin.

例如,在NOMEX(註冊商標)紙的情況中,作為主成分的聚間伸苯基間苯二甲醯胺之中,C/O/N=14/2/2,若以碳(C)基準,則碳原子數(C)與氧原子數(O)之組成比X(O/C)的理論值為2/14=0.143。一般而言,為了使烴系物質微量附著於表面,會使實測值小於理論值。若該組成比X(O/C)的值,若在理論值的120%以上、250%以下的範圍,亦即以120%~150%的範圍大於理論值,則可得到良好的熱融合性。較宜為150%以上、230%以下的範圍。組成比X,若為未滿理論值的120%,則無法得到良好的熱融合性。又,在超過理論值的250%的情況中,亦無法得到良好的熱融合性。 For example, in the case of NOMEX (registered trademark) paper, C/O/N=14/2/2 among the poly(phenylene phthalamide) as a main component, if based on carbon (C) Then, the theoretical ratio of the composition ratio X (O/C) of the number of carbon atoms (C) to the number of oxygen atoms (O) is 2/14 = 0.143. In general, in order to cause a trace amount of a hydrocarbon-based substance to adhere to a surface, the measured value is smaller than the theoretical value. If the composition ratio X (O/C) is in the range of 120% or more and 250% or less of the theoretical value, that is, in the range of 120% to 150%, which is larger than the theoretical value, good thermal fusion can be obtained. . It is preferably in the range of 150% or more and 230% or less. If the composition ratio X is less than 120% of the theoretical value, good thermal fusion properties cannot be obtained. Moreover, in the case where it exceeds 250% of the theoretical value, good thermal fusion property cannot be obtained.

又,作為得到該組成比X(O/C)在上述範圍內之醯胺紙的方法,可舉例如,藉由低溫電漿處理裝置,對以上述方法所得到的醯胺紙之表面,進行低溫電漿處理的方法等。藉此,可得到熱融合性良好的醯胺紙。 Further, as a method of obtaining the guanamine paper having the composition ratio X (O/C) in the above range, for example, the surface of the guanamine paper obtained by the above method is subjected to a low-temperature plasma processing apparatus. Low temperature plasma treatment method, etc. Thereby, a ruthenium paper having good heat fusion properties can be obtained.

此時,在使用內部電極式的電漿處理裝置,對醯胺紙進行低溫電漿處理的情況中,宜使低溫電漿處理的處理強度(輸出)在30W. min/m2~1500W.min/m2的範圍。藉此,可使醯胺紙表面的組成比X(O/C),在上述組成比X(O/C)的範圍之內。在低溫電漿處理的強度低於上述範圍的情況中,上述組成比X變小,而在低溫電漿處理的強度高於上述範圍的情況中,上述組成比X變大,兩者皆無法得到良好的熱融合性。更宜為130W.min/m2~1200W.min/m2的範圍。 At this time, in the case of low-temperature plasma treatment of the ruthenium paper using the internal electrode type plasma processing device, the treatment intensity (output) of the low-temperature plasma treatment should be 30 W. Min/m 2 ~1500W. The range of min/m 2 . Thereby, the composition ratio X (O/C) of the surface of the amide paper can be made within the range of the above composition ratio X (O/C). In the case where the strength of the low-temperature plasma treatment is lower than the above range, the composition ratio X becomes small, and in the case where the strength of the low-temperature plasma treatment is higher than the above range, the composition ratio X becomes large, and neither of them can be obtained. Good thermal integration. More preferably 130W. Min/m 2 ~1200W. The range of min/m 2 .

(樹脂成型體) (resin molded body)

在本發明中,樹脂成型體係表示藉由熔融射出成型法所製作的成型體;該熔融射出成型法,係將下述聚合物或混合物在溶融狀態下,置入預設的模具,並在冷卻之後進行脫模:例如,聚苯硫醚樹脂(Poly(phenylene sulfide)樹脂;PPS樹脂)、丙烯腈.丁二烯.苯乙烯共聚物樹脂、聚醯亞胺系樹脂、聚對苯二甲酸乙二酯系樹脂、聚縮醛系樹脂、含有醯胺鍵的聚醯胺6、聚醯胺66、聚醯胺612、聚醯胺11、聚醯胺12、共聚合聚醯胺、聚醯胺MXD6、聚醯胺46、甲氧甲酯化聚醯胺、半芳香族聚醯胺等的聚合物;或是如日本特開2006-321951號公報所示的含有聚醯胺樹脂組成物之聚合物或是該等的混合物;或是上述聚合物與玻璃纖維等無機物的混合物。特別是半芳香族聚醯胺與玻璃纖維之混合物的成型體,因耐熱性高,故為較佳。作為該等混合物之例,可舉例如杜邦公司的ZYTEL(註冊商標)HTN51G、52G等,但並不限定於此。 In the present invention, the resin molding system represents a molded body produced by a melt injection molding method in which the following polymer or mixture is placed in a molten state in a predetermined mold and cooled. Then demoulding: for example, polyphenylene sulfide resin (PPS resin), acrylonitrile. Butadiene. a styrene copolymer resin, a polyamidene resin, a polyethylene terephthalate resin, a polyacetal resin, a polyamide amine 6 containing a guanamine bond, a polyamide 66, a polyamide 612, a polymer of polyamine 11, polyamine 12, copolymerized polyamine, polyamidamine MXD6, polyamidamide 46, methoxymethylated polyamine, semi-aromatic polyamide, or the like; or A polymer containing a polyamide resin composition shown in JP-A-2006-321951 or a mixture thereof; or a mixture of the above polymer and an inorganic material such as glass fiber. In particular, a molded article of a mixture of a semi-aromatic polyamide and a glass fiber is preferred because of its high heat resistance. Examples of the mixture include, for example, ZYTEL (registered trademark) HTN51G and 52G of DuPont, but are not limited thereto.

在樹脂成型體與捲線接觸的部分,形成用以決定捲線之位置的溝槽,可使捲線的位置穩定,並可達到捲線纏繞成列的高精密度,而具有提高馬達發電機等效率的效果,故為較佳。 In the portion where the resin molded body is in contact with the winding wire, a groove for determining the position of the winding wire is formed, the position of the winding wire can be stabilized, and the high precision of winding the winding wire can be achieved, and the efficiency of the motor generator and the like can be improved. Therefore, it is better.

(用於馬達之捲線軸的製造方法) (Manufacturing method for the winding bobbin of the motor)

將預先進行該電漿表面處理之絕緣紙,以至少已經過電漿表面處理的一部分與樹脂成形體的熔融部分接觸的方式,配置於該模具內,藉此可使絕緣紙中至少已經過電漿表面處理之表面部分,浸漬於熔融之聚合物。以這樣的方式,製作樹脂成型體的部分與絕緣紙連接固定的用於馬達之捲線軸,則不需要使用黏合劑,就可在製作樹脂成型體時,同時進行連接固定。又,藉由將醯胺紙使用於本體部分,可使本體部分變薄,並提高繞組因數及熱傳導性。本發明之用於馬達之捲線軸,在安裝芯材並纏繞捲線後作為定子,可作為馬達、馬達發電機、發電機等使用。 The insulating paper which is subjected to the surface treatment of the plasma in advance is disposed in the mold so that at least a portion of the surface treated by the plasma is in contact with the molten portion of the resin formed body, whereby at least the insulating paper can be overcharged The surface portion of the surface treatment of the slurry is immersed in the molten polymer. In such a manner, the bobbin for the motor in which the portion of the resin molded body is bonded to the insulating paper can be joined and fixed at the same time when the resin molded body is produced without using a binder. Further, by using the ruthenium paper for the body portion, the body portion can be thinned, and the winding factor and thermal conductivity can be improved. The bobbin for a motor of the present invention can be used as a motor, a motor generator, a generator, or the like after being mounted as a stator after winding a core material and winding the wire.

以下列舉實施例對本發明進行說明。另外,該等實施例,係用於舉例說明本發明的內容,並無對本發明的內容有任何限定。 The invention is illustrated by the following examples. In addition, these examples are for exemplifying the contents of the present invention, and are not intended to limit the scope of the present invention.

【實施例】 [Examples]

(測量方法) (Measurement methods)

(1)基重、厚度之測量 (1) Measurement of basis weight and thickness

依據JIS C2300-2進行。 According to JIS C2300-2.

(2)密度之計算 (2) Calculation of density

以基重÷厚度計算。 Calculated by basis weight ÷ thickness.

(3)黏合性 (3) Adhesiveness

以目視觀察絕緣紙與樹脂成型體的黏合部分。 The adhesive portion of the insulating paper and the resin molded body was visually observed.

(4)絕緣紙部分之外觀 (4) Appearance of the insulating paper portion

以目視判定絕緣紙的部分在成型時,因熱而產生翹曲的程度。 It is visually judged that the portion of the insulating paper is warped due to heat during molding.

(參考例) (Reference example)

(原料調製) (raw material modulation)

使用日本特開昭52-15621號公報記載的,以定子與轉子之組合所構成的紙漿粒之製造裝置(濕式沉澱機),來製造聚間伸苯基間苯二甲醯胺之纖條體。將其以分解設備、打漿設備進行處理,並將纖維長度的加權平均值調節為0.9mm。所得之醯胺纖條體的游離度為90cm3A sliver of poly(phenylene isophthalamide) is produced by using a pulp granule manufacturing apparatus (wet precipitator) comprising a combination of a stator and a rotor described in JP-A-52-15621. body. This was treated with a decomposition apparatus, a beating apparatus, and the weighted average of the fiber lengths was adjusted to 0.9 mm. The obtained guanamine fibrids had a freeness of 90 cm 3 .

另一方面,將杜邦公司製的甲基醯胺纖維(NOMEX(註冊商標)、單線纖度2丹尼),切斷為長度6mm(以下記載為「醯胺短纖維」)。 On the other hand, methyl amide fiber (NOMEX (registered trademark), single-strand fineness 2 Danny) manufactured by DuPont was cut into a length of 6 mm (hereinafter referred to as "melamine short fiber").

(醯胺紙之製造) (Manufacture of guanamine paper)

分別使調製之醯胺纖條體與醯胺短纖維在水中分散,並製成漿液。以使纖條體與醯胺短纖維的摻合比例(重量比)為1/1的方式,將該等漿液混合,並以TAPPI式手工造紙設備(剖面面積625cm2)製作片材。接著,將其以金屬製砑光輥(Calender Roll),在溫度330℃、線壓300kg/cm的條件下熱壓加工,得到表1及表2所示的醯胺紙。 The prepared guanamine fibrids and guanamine short fibers are separately dispersed in water and slurried. The slurry was mixed so that the blending ratio (weight ratio) of the fibrids and the polyamide short fibers was 1/1, and a sheet was produced by a TAPPI type hand-made papermaking apparatus (cross-sectional area: 625 cm 2 ). Subsequently, this was hot-pressed under the conditions of a temperature of 330 ° C and a linear pressure of 300 kg/cm using a metal calender roll to obtain a guanamine paper shown in Tables 1 and 2.

(絕緣紙之製造) (Manufacture of insulating paper)

以日本特開2006-321183號公報的段落【0024】所記載之方法,使用上述醯胺紙與包含50重量%的具有環氧基之苯氧基樹脂的半芳香族聚醯胺樹脂組成物(日本特開2006-321183號公報之摻合例6),得到表1之實施例1及2、以及表2之比較例1及2所示之包含醯胺紙的絕緣紙,而該絕緣紙,係由將醯胺紙配置於外側的「醯胺紙/樹脂組成物/醯胺紙」(重量比37/54/37)的三層結構所形成。 The above-described guanamine paper and a semi-aromatic polyamide resin composition containing 50% by weight of a phenoxy resin having an epoxy group are used in the method described in paragraph [0024] of JP-A-2006-321183 ( JP-A-2006-321183, the blending example 6), obtained in Examples 1 and 2 of Table 1, and the insulating paper containing the guanamine paper shown in Comparative Examples 1 and 2 of Table 2, and the insulating paper, It is formed of a three-layer structure of "amide paper/resin composition/protonium paper" (weight ratio 37/54/37) in which a guanamine paper is disposed outside.

(實施例1及2) (Examples 1 and 2)

(已經過電漿表面處理的絕緣紙之製造) (Manufacture of insulating paper that has been subjected to plasma surface treatment)

將表1所示的絕緣紙,通過日本專利第4607826號公報的第一 圖所記載之內部電極式的低溫電漿處理設備,並對其任意一側之表面以處理強度650W.min/m2,進行低溫電漿處理。此時,絕緣紙表面的氧原子(O)與碳原子(C)的原子數之組成比X(O/C)為原子數比例之理論值的206%。 The insulating paper shown in Table 1 was passed through the internal electrode type low-temperature plasma processing apparatus described in the first drawing of Japanese Patent No. 4607826, and the surface of either side thereof was treated with a treatment strength of 650 W. Min/m 2 , low temperature plasma treatment. At this time, the composition ratio X (O/C) of the number of atoms of the oxygen atom (O) to the carbon atom (C) on the surface of the insulating paper is 206% of the theoretical value of the atomic ratio.

(用於馬達之捲線軸之製造) (for the manufacture of the winding bobbin of the motor)

使用上述已經過電漿表面處理的絕緣紙,及作為聚合物的寶理塑料公司製的聚苯硫醚(FORTRON(註冊商標)1140A64)),並以表1所示條件實施插入成型,而得到用於馬達之捲線軸。以此方式所得到的用於馬達之捲線軸,其主要的特性值顯示於表1。 Using the above-mentioned insulating paper which has been subjected to plasma surface treatment, and polyphenylene sulfide (FORTRON (registered trademark) 1140A64) manufactured by Polyplastics Co., Ltd. as a polymer, and insert molding was carried out under the conditions shown in Table 1, The spool for the motor. The main characteristic values of the bobbin for a motor obtained in this manner are shown in Table 1.

吾人認為,實施例之用於馬達之捲線軸,因捲線軸本體部係由絕緣紙所形成,故厚度小,而可藉由捲線的高密度化,預期達到高效率化;因絕緣紙與樹脂成型體之間充分地連接固定,而更使得絕緣紙未產生翹曲,故與芯材的密合性高,因此可期待極高的絕緣破壞電壓;更進一步,因所使用的醯胺紙與聚合物之耐熱性高,故可充分承受捲線之發熱,從上述觀點來看,其作為可承受馬達發電機等的高效率化、高輸出化的用於馬達之捲線軸十分有用。 It is considered that the bobbin for the motor of the embodiment is formed of insulating paper because the main body of the bobbin is small in thickness, and it is expected to achieve high efficiency by the high density of the winding wire; Since the molded articles are sufficiently connected and fixed, the insulating paper is not warped, so that the adhesion to the core material is high, so that an extremely high dielectric breakdown voltage can be expected. Further, the amide paper used is Since the heat resistance of the polymer is high, it is possible to sufficiently withstand the heat generation of the winding wire. From the above viewpoint, it is useful as a winding bobbin for a motor that can withstand high efficiency and high output of a motor generator or the like.

(比較例1~6) (Comparative examples 1 to 6)

(絕緣紙之製造) (Manufacture of insulating paper)

將該醯胺紙與東麗公司製的聚對苯二甲酸乙二酯薄膜(S28#16,厚度16μm)以黏合劑貼合,得到表2之比較例3~6所示之包含醯胺紙的絕緣紙,其係由將醯胺紙配置於外側的「醯胺紙/聚對苯二甲酸乙二酯薄膜/醯胺紙」(重量比37/24/37)之三層結構所形成。 The polyamide paper and the polyethylene terephthalate film (S28 #16, thickness: 16 μm) manufactured by Toray Industries Co., Ltd. were bonded together with an adhesive to obtain a guanamine paper as shown in Comparative Examples 3 to 6 of Table 2. The insulating paper is formed of a three-layer structure of "amide paper/polyethylene terephthalate film/amide paper" (weight ratio 37/24/37) in which the guanamine paper is disposed outside.

(已經過電漿表面處理的絕緣紙之製造) (Manufacture of insulating paper that has been subjected to plasma surface treatment)

將表2之比較例5及6所示之絕緣紙,通過日本專利第4607826號公報的第一圖所記載之內部電極方式的低溫電漿處理設備,並於其任意一側之表面以處理強度650W.min/m2,實施低溫電漿處理。此時,絕緣紙表面的氧原子(O)與碳原子(C)的原子數之組成比X(O/C)為原子數比例之理論值的206%。 The insulating papers shown in Comparative Examples 5 and 6 of Table 2 were passed through the internal electrode type low-temperature plasma processing apparatus described in the first drawing of Japanese Patent No. 4607826, and the treatment strength was applied to the surface of either side thereof. 650W. Min/m 2 , low temperature plasma treatment. At this time, the composition ratio X (O/C) of the number of atoms of the oxygen atom (O) to the carbon atom (C) on the surface of the insulating paper is 206% of the theoretical value of the atomic ratio.

(用於馬達之捲線軸之製造) (for the manufacture of the winding bobbin of the motor)

使用上述絕緣紙,及作為聚合物的寶理塑料公司製的聚苯硫醚(FORTRON(註冊商標)1140A64)),以表2所示條件實施嵌入成型(Insert Molding),進而得到用於馬達之捲線軸。以此方式所得到的用於馬達之捲線軸,其主要的特性值顯示於表2。 Insertion molding (Insert Molding) was carried out under the conditions shown in Table 2 using the above-mentioned insulating paper and polyphenylene sulfide (FORTRON (registered trademark) 1140A64) manufactured by Polyplastics Co., Ltd. as a polymer, thereby obtaining a motor for use. Winding spool. The main characteristic values of the bobbin for the motor obtained in this manner are shown in Table 2.

比較例1~4之用於馬達之捲線軸,具有絕緣紙未浸漬於樹脂的部分,以目視可確認絕緣紙與樹脂成型體之間具有間隙之部分。吾人認為,這是因為在將其用於馬達等時,發生部分放電,以及間隙的部分變厚, 故導致捲線的繞組因素減少而引起的效率降低,並成為嵌入芯材時之障礙的原因等,因此,吾人認為其並不適合作為可承受馬達發電機等的高效率化、高輸出化的用於馬達之捲線軸。又,比較例3~6的用於馬達之捲線軸,因將醯胺紙與薄膜堆疊,故薄膜之部分因收縮發生翹曲。翹曲使其與芯材的密合性降低,具有絕緣破壞電壓下降的可能性。更進一步,吾人認為,若翹曲較大,則成為嵌入芯材時之障礙的原因,因此吾人認為其並不適合作為可承受馬達發電機等的高效率化、高輸出化的用於馬達之捲線軸。 The bobbins for motors of Comparative Examples 1 to 4 have a portion where the insulating paper is not immersed in the resin, and a portion having a gap between the insulating paper and the resin molded body can be visually confirmed. I think this is because when it is used in a motor or the like, partial discharge occurs, and a part of the gap becomes thick, Therefore, the efficiency of the coiled wire is reduced, and the efficiency is lowered, and it is a cause of the obstacle when the core material is embedded. Therefore, it is considered that it is not suitable for high efficiency and high output of a motor generator or the like. Motor spools. Further, in the winding bobbins for motors of Comparative Examples 3 to 6, since the ruthenium paper was stacked with the film, the film portion was warped due to shrinkage. The warp is reduced in adhesion to the core material, and there is a possibility that the dielectric breakdown voltage is lowered. Furthermore, it is considered that the warpage is a cause of the obstacle when the core material is embedded, and therefore it is considered that it is not suitable as a winding wire for a motor that can withstand high efficiency and high output of a motor generator or the like. axis.

如此,一般將薄膜延伸的情況,大多係在以熔融射出成型法製造用於馬達之捲線軸的樹脂成形體的同時,進行與絕緣紙之捲線軸本體部連接固定的情況,故成為因為熱而造成緩和、收縮以及絕緣紙變形的原因。 As described above, in general, when the film is stretched, the resin molded body for the bobbin of the motor is produced by the melt injection molding method, and the main body of the bobbin of the insulating paper is connected and fixed. Causes relaxation, shrinkage, and deformation of insulation paper.

1‧‧‧用於馬達之捲線軸 1‧‧‧Rolling spool for motor

2‧‧‧捲線軸本體 2‧‧‧Rolling spool body

4‧‧‧樹脂成型體 4‧‧‧Resin molded body

8‧‧‧彎折部 8‧‧‧Bend

8a‧‧‧外側面 8a‧‧‧Outside

10‧‧‧本體部 10‧‧‧ Body Department

10a‧‧‧側面 10a‧‧‧ side

12‧‧‧簷部 12‧‧‧檐

12a‧‧‧突出部 12a‧‧‧Protruding

12b‧‧‧內側面 12b‧‧‧ inside side

14‧‧‧溝槽 14‧‧‧ trench

Claims (10)

一種用於馬達之捲線軸,纏繞有捲線,該捲線軸係由一絕緣紙及一樹脂成型體所構成,其中:該絕緣紙及該樹脂成型體,係不使用黏合劑而連接固定;該絕緣紙與該樹脂成型體相接的面,係由一醯胺紙所構成,該醯胺紙係由一醯胺纖條體與一醯胺短纖維所構成;該絕緣紙,係將樹脂熔融並押出於該醯胺纖條體與該醯胺短纖維所構成的該醯胺紙上且使其熱融合,再對以該醯胺紙所構成的面進行表面處理而得之;以及使該樹脂成形體之熔融部分接觸該醯胺紙以形成該捲線軸。 A winding bobbin for a motor, which is wound with a winding wire, the winding bobbin is composed of an insulating paper and a resin molded body, wherein: the insulating paper and the resin molded body are connected and fixed without using an adhesive; the insulation The surface of the paper which is in contact with the resin molded body is composed of a ruthenium paper which is composed of a ruthenium fibril strip and a ruthenium amide short fiber; the insulating paper is obtained by melting the resin and And the surface of the amide paper formed by the amide paper and the amide paper is thermally fused, and the surface formed by the amide paper is surface-treated; and the resin is formed. The molten portion of the body contacts the amide paper to form the bobbin. 如申請專利範圍第1項之用於馬達之捲線軸,其中更包含:一捲線軸本體部,其至少一部分為該絕緣紙。 The winding bobbin for a motor of claim 1, further comprising: a bobbin body portion, at least a portion of which is the insulating paper. 如申請專利範圍第1項之用於馬達之捲線軸,其中更包含:一對樹脂成型體,連接於該捲線軸本體部的兩端。 A winding bobbin for a motor according to the first aspect of the invention, further comprising: a pair of resin molded bodies connected to both ends of the bobbin main body portion. 如申請專利範圍第1項之用於馬達之捲線軸,其中,該表面處理為電漿表面處理。 The winding bobbin for a motor of claim 1, wherein the surface treatment is a plasma surface treatment. 如申請專利範圍第1項之用於馬達之捲線軸,其中,該絕緣紙與該樹脂成型體接觸的面浸漬於樹脂成型體。 A winding bobbin for a motor according to the first aspect of the invention, wherein the surface of the insulating paper in contact with the resin molded body is immersed in a resin molded body. 如申請專利範圍第3項之用於馬達之捲線軸,其中,該樹脂成型體上具有用以決定捲線位置的溝槽。 A winding bobbin for a motor according to the third aspect of the invention, wherein the resin molded body has a groove for determining a winding position. 一種如申請專利範圍第1項之用於馬達之捲線軸的製造方法,其中:在使該樹脂成型體成型的同時,進行與該絕緣紙的黏合。 A method for producing a bobbin for a motor according to the first aspect of the invention, wherein the resin molded body is molded and bonded to the insulating paper. 一種馬達,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於申請專利範圍第1至6項中任一項之用於馬達之捲線軸上。 A motor using a stator assembled with a core material and a winding wire, wherein the winding wire is wound around a bobbin for a motor of any one of claims 1 to 6. 一種馬達發電機,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於申請專利範圍第1至6項中任一項之用於馬達之捲線軸上。 A motor generator using a stator in which a core material and a winding wire are assembled, wherein the winding wire is wound around a bobbin for a motor of any one of claims 1 to 6. 一種發電機,其使用組裝有芯材及捲線之一定子,其中該捲線係纏繞於申請專利範圍第1至6項中任一項之用於馬達之捲線軸上。 A generator using a stator assembled with a core material and a winding wire, wherein the winding wire is wound around a bobbin for a motor of any one of claims 1 to 6.
TW102148387A 2013-01-24 2013-12-26 Reel for motor, manufacturing method thereof, motor using the reel, motor generator and generator TWI621322B (en)

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US20150288238A1 (en) 2015-10-08
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WO2014115452A1 (en) 2014-07-31
US9812916B2 (en) 2017-11-07
JP6119076B2 (en) 2017-04-26
KR20150108835A (en) 2015-09-30
EP2950425A1 (en) 2015-12-02
EP2950425A4 (en) 2016-10-05
JP2014143845A (en) 2014-08-07
CN104937820A (en) 2015-09-23
CN104937820B (en) 2018-01-23
KR102046681B1 (en) 2019-11-19

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