TWI737838B - Insulating component and its manufacturing method - Google Patents
Insulating component and its manufacturing method Download PDFInfo
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- TWI737838B TWI737838B TW106135898A TW106135898A TWI737838B TW I737838 B TWI737838 B TW I737838B TW 106135898 A TW106135898 A TW 106135898A TW 106135898 A TW106135898 A TW 106135898A TW I737838 B TWI737838 B TW I737838B
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K1/00—Details of the magnetic circuit
- H02K1/04—Details of the magnetic circuit characterised by the material used for insulating the magnetic circuit or parts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K15/00—Methods or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines
- H02K15/10—Applying solid insulation to windings, stators or rotors
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K3/00—Details of windings
- H02K3/30—Windings characterised by the insulating material
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K3/00—Details of windings
- H02K3/32—Windings characterised by the shape, form or construction of the insulation
- H02K3/34—Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K3/00—Details of windings
- H02K3/32—Windings characterised by the shape, form or construction of the insulation
- H02K3/34—Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation
- H02K3/345—Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation between conductor and core, e.g. slot insulation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/206—Insulating
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Insulation, Fastening Of Motor, Generator Windings (AREA)
- Insulating Bodies (AREA)
- Manufacturing Of Electric Cables (AREA)
- Inorganic Insulating Materials (AREA)
Abstract
本發明提供一種絕緣部件,其裝設在形成於定子芯部的內周面之溝槽,其特徵包含: 基材,其係由1片絕緣片所形成,具有覆蓋該溝槽之內部的溝槽部、設於該溝槽部之軸線方向的至少一端且從溝槽部略垂直地向外延伸的拗摺部;及 樹脂成型體,與該拗摺部密合地安裝。此絕緣部件可達成馬達、馬達發電機等的旋轉電機的小型化、高效率化、大輸出化。The present invention provides an insulating component, which is installed in a groove formed on the inner peripheral surface of a stator core, and is characterized by comprising: a base material, which is formed by one insulating sheet and has a groove covering the inside of the groove A groove portion, a bent portion provided at at least one end of the groove portion in the axial direction and slightly perpendicularly extending outward from the groove portion; and a resin molded body that is closely attached to the bent portion. This insulating member can achieve miniaturization, high efficiency, and large output of rotating electrical machines such as motors and motor generators.
Description
本發明係關於一種耐熱性、絕緣性優異的絕緣部件及其製造方法,特別係關於一種嵌入馬達、發電機、其他旋轉電機之芯材的溝槽以確保芯部與線圈之間的電絕緣性的絕緣部件及其製造方法。The present invention relates to an insulating component with excellent heat resistance and insulation and a manufacturing method thereof, and in particular to a groove embedded in the core material of motors, generators, and other rotating electrical machines to ensure electrical insulation between the core and the coil Insulating parts and manufacturing methods thereof.
馬達或發電機等的旋轉電機的定子,係由在內周面的圓周方向上具有多個溝槽的環狀定子芯部與捲繞在該溝槽上的線圈所構成,為了確保電絕緣性,該定子芯部與線圈之間插入有絕緣片。The stator of a rotating electric machine such as a motor or a generator is composed of a ring-shaped stator core having a plurality of grooves in the circumferential direction of the inner peripheral surface and a coil wound around the grooves to ensure electrical insulation. , An insulating sheet is inserted between the stator core and the coil.
以往,這樣的絕緣片使用聚間苯二甲醯間苯二胺(以下稱為間位聚芳醯胺)的纖條體及纖維所構成的紙(商品名稱NOMEX(註冊商標))、聚對苯二甲酸乙二酯等的樹脂膜、該間位聚芳醯胺紙與該樹脂膜積層而成的聚芳醯胺-樹脂膜積層體等。In the past, such insulating sheets used paper (trade name NOMEX (registered trademark)) composed of fibrids and fibers of polymeta-phenylene diamine (hereinafter referred to as meta-polyarylene diamine), and polymer A resin film such as ethylene phthalate, a polyaramide-resin film laminate formed by laminating the meta-polyaramide paper and the resin film, and the like.
又,一般而言該絕緣片,例如專利文獻1的第3圖所記載,係將兩端部反折,再以該反折部為外側而彎曲成略U字型所形成,之後則插入溝槽。此時,反折部係以在軸線方向上從芯材端面突出的狀態存在,藉由使反折的前端與芯材端面接觸,構成絕緣片不會在溝槽軸線方向上錯位之情況。Generally speaking, the insulating sheet, for example, as described in Figure 3 of Patent Document 1, is formed by folding both ends back, and then bending the back-folded part into a U-shape, and then inserting it into the groove. groove. At this time, the reverse-folded portion exists in a state protruding from the end surface of the core material in the axial direction, and the tip of the reversed-fold contact with the end surface of the core material prevents the insulating sheet from shifting in the axial direction of the groove.
然而,若以這樣的構成配置絕緣片,則因為該反折部的存在而導致芯材在軸線方向上的長度變長,故捲繞於溝槽部上的線圈亦必須相應地變長。意即,用於線圈之銅線等的使用量增加,結果導致旋轉電機的尺寸及重量增加,又因為線圈變長而導致旋轉電機的效率及輸出降低,而不適合用於例如配置於車載用等的有限空間內的馬達等。However, if the insulating sheet is arranged in such a configuration, the length of the core material in the axial direction is increased due to the existence of the reflexed portion, so the coil wound on the groove portion must also be lengthened accordingly. This means that the use of copper wires for coils has increased, resulting in an increase in the size and weight of the rotating electrical machine, and the increase in the efficiency and output of the rotating electrical machine due to the lengthening of the coil, which is not suitable for use in, for example, automotive applications. Motor, etc. within the limited space.
作為解決此等問題的絕緣部件,有人提出一種以下述方式形成的絕緣部件:在芯材端部反折的絕緣紙中,使用具有該芯材兩端面與嵌入溝槽之突出部的模具形成孔洞,在該絕緣紙的反折部配置於該孔洞內的狀態下,將熔融樹脂注入孔洞內,該熔融樹脂將絕緣片的反折部包埋,且與芯材端部密合(專利文獻2)。As an insulating part to solve these problems, some people propose an insulating part formed in the following manner: in the insulating paper with the end of the core material folded back, a mold having both ends of the core material and protrusions embedded in the groove is used to form holes In the state where the folded portion of the insulating paper is arranged in the hole, molten resin is injected into the hole, and the molten resin embeds the folded portion of the insulating sheet and is in close contact with the end of the core material (Patent Document 2 ).
然而,此技術中,絕緣紙的反折部係以相對芯材端面具有角度的方式配置,因為係在該反折部未充分固定於孔洞內的狀態下即注入熔融樹脂,可能因為樹脂的注入壓力使絕緣紙變形而導致樹脂無法包埋反折部的絕緣紙。又,關於絕緣紙及熔融樹脂的種類並未記載,在選擇熔融樹脂與絕緣紙之接著性不佳的材料時,若像這樣在包埋不充分的狀態下形成絕緣部件,則在旋轉電機運作時可能具有樹脂與絕緣紙剝離等的問題。However, in this technology, the folded part of the insulating paper is arranged at an angle relative to the end surface of the core material, because the melted resin is injected when the folded part is not sufficiently fixed in the hole. This may be due to the injection of resin. The pressure deforms the insulating paper so that the resin cannot embed the insulating paper in the reversed part. In addition, there is no description about the types of insulating paper and molten resin. When selecting a material with poor adhesion between the molten resin and the insulating paper, if the insulating member is formed in a state of insufficient embedding like this, the rotating machine will operate There may be problems such as peeling of resin and insulating paper.
[先前技術文獻] [專利文獻] [專利文獻1]日本實開昭60-162951號公報 [專利文獻2]日本專利第3921985號公報[Prior Art Document] [Patent Document] [Patent Document 1] Japanese Patent Publication No. 60-162951 [Patent Document 2] Japanese Patent No. 3921985
本發明之目的在於提供一種可達到馬達、馬達發電機等的旋轉電機之小型化、高效率化、大輸出化之效果的絕緣部件其製造方法。The object of the present invention is to provide a method for manufacturing an insulating component that can achieve the effects of miniaturization, high efficiency, and large output of rotating electrical machines such as motors, motor generators, and the like.
本案發明人鑒於此狀況,為了得到可達成馬達、發電機等的旋轉電機之小型化、高效率化、大輸出化之效果的絕緣部件而詳盡研究的結果,完成本發明。In view of this situation, the inventors of the present invention have made detailed studies in order to obtain an insulating member that can achieve the effects of miniaturization, high efficiency, and high output of rotating electric machines such as motors and generators, and completed the present invention.
意即,本案發明的一實施態樣係提供一種絕緣部件,其裝設在形成於定子芯部內周面之溝槽,其特徵包含:基材,其係由1片絕緣片形成,具有覆蓋該溝槽內部的溝槽部、設於該溝槽部之軸線方向的至少一端且從溝槽部略垂直地往外延伸的拗摺部;及樹脂成型體,以與該拗摺部密合地安裝。That is, one embodiment of the present invention provides an insulating component which is installed in a groove formed on the inner peripheral surface of the stator core, and is characterized by including: a base material, which is formed by a piece of insulating sheet and has a covering A groove portion inside the groove, a bent portion provided at at least one end of the groove portion in the axial direction and slightly perpendicularly extending outward from the groove portion; and a resin molded body to be mounted in close contact with the bent portion .
以從軸線方向觀察之溝槽的彎曲部為起點,切開該拗摺部的絕緣片。Starting from the curved part of the groove viewed from the axial direction, cut the insulating sheet of the bent part.
該絕緣片的兩端亦可相對於溝槽部略垂直地拗摺。The two ends of the insulating sheet can also be bent slightly perpendicular to the groove portion.
亦可不使用接著劑使該拗摺部與該樹脂成型體密合。It is also possible to make the folded portion and the resin molded body adhere to each other without using an adhesive.
絕緣片可選自聚芳醯胺纖條體與聚芳醯胺短纖維所構成的聚芳醯胺紙、該聚芳醯胺紙與樹脂膜積層而成的聚芳醯胺-樹脂膜積層體,或將樹脂熔融壓出於該聚芳醯胺紙上所形成之片材的任一者。The insulating sheet can be selected from polyaramide paper composed of polyaramide fibrids and polyaramide short fibers, and a polyaramide-resin film laminate formed by laminating the polyaramide paper and a resin film , Or melt and press the resin out of any of the sheets formed on the polyaramide paper.
樹脂成型體可為使用具有醯胺鍵的聚合物所形成之樹脂成型體;與樹脂成型體接觸之絕緣片的表面,亦可為由聚芳醯胺纖條體與聚芳醯胺短纖維所構成的聚芳醯胺紙。The resin molded body may be a resin molded body formed by using a polymer with an amide bond; the surface of the insulating sheet contacting the resin molded body may also be composed of polyaramide fibrids and polyaramide staple fibers. Composition of polyaramide paper.
本案發明的另一實施態樣,係提供一種絕緣部件的製造方法,其中絕緣部件裝設在形成於定子芯部的內周面之溝槽,其特徵為:將相當於絕緣片之拗摺部之處,從軸線方向觀察為溝槽之彎曲部位置,在軸線方向上切開後,將其山摺而使其相對絕緣片之溝槽部略為垂直,再沿著溝槽的形狀拗摺,之後以射出成型將已熔融之樹脂組成物填充至絕緣片的拗摺部,形成凸緣狀的芯部端面部。Another aspect of the present invention is to provide a method of manufacturing an insulating component, wherein the insulating component is installed in a groove formed on the inner peripheral surface of the stator core, and the feature is: When viewed from the axial direction, it is the position of the bend of the groove. After cutting it in the axial direction, fold it so that it is slightly perpendicular to the groove of the insulating sheet, and then bend it along the shape of the groove. The melted resin composition is filled into the folded part of the insulating sheet by injection molding to form a flange-shaped core end face.
本案發明的另一實施態樣,係提供一種絕緣部件的製造方法,其中絕緣部件裝設在形成於定子芯部的內周面之溝槽,其特徵為:將相當於絕緣片的拗摺部之處從軸線方向觀察為溝槽之彎曲部的位置,在軸線方向上切開後,將其山摺而使其相對絕緣片之溝槽部略為垂直,更沿著溝槽的形狀拗摺後,以射出成型將已熔融的樹脂組成物填充至絕緣片之拗摺部中面向溝槽部的片材表面,而形成凸緣狀的芯部端面部,若從絕緣片之拗摺部中未面向溝槽部之片材表面的一側觀察,絕緣片在芯部端面部的表面露出。Another aspect of the present invention is to provide a method for manufacturing an insulating component, wherein the insulating component is installed in a groove formed on the inner peripheral surface of the stator core, and the feature is: When viewed from the axial direction, it is the position of the curved part of the groove. After cutting it in the axial direction, fold it so that it is slightly perpendicular to the groove part of the insulating sheet, and then bend along the shape of the groove. The melted resin composition is filled by injection molding on the surface of the sheet facing the groove in the folded part of the insulating sheet to form a flange-like core end face. If the folded part of the insulating sheet is not facing Observing from one side of the sheet surface of the groove part, the insulating sheet is exposed on the surface of the end face of the core part.
本案發明的另一實施態樣,係提供一種絕緣部件的製造方法,中絕緣部件裝設在形成於定子芯部的內周面之溝槽,其特徵為:將相當於絕緣片的拗摺部之處從軸線方向觀察為溝槽之彎曲部的位置,在軸線方向上切開後,將其山摺而使其相對絕緣片之溝槽部略為垂直,再沿著溝槽的形狀拗摺後,以射出成型將已熔融的樹脂組成物填充至絕緣片之拗摺部中面向溝槽部的片材表面,而形成凸緣狀的芯部端面部,在形成從絕緣片之拗摺部中未面向溝槽部的片材表面側觀察為絕緣片露出之態樣的芯部端面部後,以射出成型將已熔融的樹脂組成物填充至露出絕緣片的芯部端面部,而形成絕緣片完全被樹脂成型體覆蓋的凸緣狀芯部端面部。Another aspect of the present invention is to provide a method for manufacturing an insulating component. The insulating component is installed in a groove formed on the inner peripheral surface of the stator core. When viewed from the axial direction, it is the position of the curved part of the groove. After cutting it in the axial direction, fold it so that it is slightly perpendicular to the groove part of the insulating sheet, and then bend it along the shape of the groove. The melted resin composition is filled by injection molding on the surface of the sheet facing the groove in the folded portion of the insulating sheet to form a flange-like core end surface. After observing the end face of the core part with the insulating sheet exposed from the surface side of the sheet facing the groove part, the molten resin composition is filled by injection molding to the end face of the core part where the insulating sheet is exposed to form a complete insulating sheet. The flange-shaped core end surface covered by the resin molded body.
本案發明的另一實施態樣係提供一種馬達,其特徵為:在內周面裝設有上述絕緣部件的溝槽中,具有捲繞有線圈的芯部。Another aspect of the present invention is to provide a motor, which is characterized in that the groove in which the above-mentioned insulating member is installed on the inner peripheral surface has a core part around which a coil is wound.
本案發明的另一實施態樣係提供一種發電機,其特徵為:在內周面裝設有上述絕緣部件的溝槽中,具有捲繞有線圈的芯部。Another aspect of the present invention is to provide a generator, which is characterized in that the groove in which the above-mentioned insulating member is installed on the inner peripheral surface has a core part around which a coil is wound.
本案發明的另一實施態樣係提供一種旋轉電機,其特徵為:在內周面裝設有上述絕緣部件的溝槽中,具有捲繞有線圈的芯部。Another aspect of the present invention is to provide a rotating electric machine, which is characterized in that the groove in which the above-mentioned insulating member is installed on the inner peripheral surface has a core around which a coil is wound.
以下雖參照圖式詳細說明本發明的較佳實施形態的絕緣部件,但不特別限定於此。第一圖係本發明之較佳實施形態的絕緣部件1的立體圖。Although the insulating member of the preferred embodiment of the present invention will be described in detail below with reference to the drawings, it is not particularly limited thereto. The first figure is a perspective view of an insulating member 1 according to a preferred embodiment of the present invention.
絕緣部件1包含:基材4,其係由1片絕緣片所形成,具有覆蓋定子芯部之溝槽內面且剖面為略U字型的溝槽部2、設於略U字型之溝槽部的軸線方向兩端且從溝槽部2略垂直地往外延伸的拗摺部3。此外,本說明書中,溝槽部的軸線方向係指與定子芯部對向之溝槽部的面中,從一邊的芯部端面部朝向另一邊之芯部端面部的方向。The insulating component 1 includes: a
圖示之實施形態中,溝槽部2的剖面為略U字型,但溝槽部的剖面不限於U字型,亦可因應定子芯部之溝槽的形狀及絕緣部件1所要求之強度等,具有矩形、正方形、五角形、V字型等的剖面。In the embodiment shown in the figure, the cross section of the
拗摺部3包含:一對矩形的側部拗摺部3a、3a,其從溝槽部2中U字型之端緣上對向的各長邊向外延伸;及矩形的底部拗摺部3b,其從U字型的底邊向外延伸。The folded
絕緣部件1更包含安裝於拗摺部3的樹脂成型體5。樹脂成型體5,如第一圖所示,係以樹脂所形成且具有略馬蹄形狀。詳細而言,樹脂成型體5,覆蓋側部拗摺部3a、3a的背面,更覆蓋底部拗摺部3b的背面及周緣。底部拗摺部3b的周圍,具有半圓形狀,其與底部拗摺部3b的表面形成一個平面。本實施形態中,係以拗摺部3與樹脂成型體5構成芯部端面部6。藉由採用這種形成芯部端面部6的構造,相較於形成反折部的情況,可縮短絕緣部件之芯材在軸線方向上的長度。此外,本說明書中,「略垂直/略直角」係指90°±15°,較佳為90°±10°,更佳為90°±5°。The insulating member 1 further includes a resin molded
絕緣部件1,在與定子芯部的溝槽嵌合時,若只有拗摺部3並無法完全被覆溝槽在軸線端部方向外側之端部。然而,本實施形態的絕緣部件1中,樹脂成型體5可覆蓋無法以拗摺部3被覆之處(略U字的側底部)。在軸線方向上之端部的絕緣部件的高度,較佳係在芯部端面部6的整個面上相同。又,此時,不透過接著劑將樹脂成型體5與絕緣片7接合較佳。When the insulating member 1 is fitted into the groove of the stator core, only the
第二圖係顯示與第一圖不同的本發明之一實施形態的絕緣部件10的立體圖。如第二圖所示,絕緣部件10中,樹脂成型體50雖與第一圖所示之絕緣部件1相同地具有馬蹄形狀,但具有從上下覆蓋側部拗摺部3a、3a及底部拗摺部3b的形狀。第二圖所示之態樣中,絕緣片的表面及背面被樹脂所被覆,故可更牢固地將絕緣片與樹脂成型體密合。The second figure is a perspective view showing an
此外,作為不透過接著劑將樹脂成型體與絕緣片接合的態樣,較佳係下述5個態樣中的任一態樣。In addition, as an aspect of bonding the resin molded body and the insulating sheet impermeable to the adhesive, any one of the following five aspects is preferable.
絕緣片:樹脂成型體Insulation sheet: resin molded body
聚芳醯胺紙:聚醯胺樹脂組成物的成型體Polyaramide paper: molded body of polyamide resin composition
聚芳醯胺紙/樹脂膜/聚芳醯胺紙的3層積層體:聚醯胺樹脂組成物的成型體3-layer laminate of polyaramide paper/resin film/polyaramide paper: molded body of polyaramide resin composition
聚芳醯胺紙/片狀聚醯胺樹脂組成物/聚芳醯胺紙的3層積層體:聚醯胺樹脂組成物的成型體A 3-layer laminate of polyaramide paper/sheet-like polyaramide resin composition/polyaramide paper: molded body of polyaramide resin composition
聚芳醯胺紙/樹脂膜的雙層積層體:聚醯胺樹脂組成物的成型體A two-layer laminate of polyaramide paper/resin film: a molded body of a polyaramide resin composition
聚芳醯胺紙/片狀聚醯胺樹脂組成物的雙層積層體:聚醯胺樹脂組成物的成型體Two-layer laminate of polyaramide paper/sheet-like polyamide resin composition: molded body of polyamide resin composition
此處,使用聚芳醯胺紙/樹脂膜或片狀聚醯胺樹脂組成物的雙層積層體作為絕緣片的情況下,樹脂成型體可設於雙層積層體的任一表面,但設於聚芳醯胺紙側較佳。又,以熔融壓出形成片狀聚醯胺樹脂組成物較佳。Here, when a two-layer laminate of polyaramide paper/resin film or sheet-like polyamide resin composition is used as an insulating sheet, the resin molded body can be provided on any surface of the two-layer laminate, but It is better on the polyaramide paper side. Furthermore, it is preferable to form a sheet-shaped polyamide resin composition by melt extrusion.
針對構成絕緣部件1之基材4的製造方法進行說明。第三圖係用以形成本發明之較佳實施形態的絕緣部件1、10之基材4的絕緣片7的前視圖。標示於長方形之絕緣片7的長邊方向兩端的鏈線部7a與絕緣片7的端部7b之間的區域,係後續加工為拗摺部3之處。絕緣片7的2條鏈線7a、7a間的距離為絕緣部件1在軸線方向上的長度,此軸線方向上的長度對應於定子芯部之軸線方向的長度。首先,在將7c~7d間的點線部切開後,將鏈線部7a山摺而使其從正面觀察成為略垂直。之後,再沿著溝槽的形狀將虛線部(上下的7d間)拗摺,意即從正面觀察係進行谷摺,藉此形成構成絕緣部件的基材4(第四圖)。在將絕緣片拗摺加工為第四圖所示之形狀後,形成樹脂成型體5以覆蓋拗摺部3。The manufacturing method of the
第一圖及第二圖所示的絕緣部件,係以與芯材內周面之溝槽嵌合的方式使用。此時,拗摺部3與樹脂成型體5(第二圖的情況為50)所構成的芯部端面部6,係在與芯部端面接觸的狀態下存在,故在將線圈捲繞於溝槽時,可防止絕緣部件的位置偏離。The insulating members shown in the first and second figures are used to fit into the grooves on the inner peripheral surface of the core material. At this time, the
(聚芳醯胺)(Polyaramide)
本發明中,聚芳醯胺係指醯胺鍵的60%以上直接鍵結於芳香環的線狀高分子化合物。作為這樣的聚芳醯胺,可列舉例如:聚間苯二甲醯間苯二胺及其共聚物、聚對苯二甲醯對苯二胺及其共聚物、共聚對亞苯基·3, 4'-二苯醚對苯二甲醯胺等。該等的聚芳醯胺,可藉由例如,與芳香族酸二氯化物及芳香族二胺的縮合反應所進行的溶液聚合法、二階段界面聚合法等工業地進行製造,而作為市售品取得,但並不限定於此。該等的聚芳醯胺之中,因為聚間苯二甲醯間苯二胺具備良好的成型加工性、阻燃性、耐熱性等的特性,故從此點來看,較佳係使用聚間苯二甲醯間苯二胺。In the present invention, polyaramide refers to a linear polymer compound in which 60% or more of the amide bond is directly bonded to an aromatic ring. As such polyarylene amines, for example, poly(m-xylylenediamine) and its copolymers, poly(p-xylylenediamine) and its copolymers, copolymerized p-
(聚芳醯胺纖條體)(Polyaramid fibrids)
本發明中,聚芳醯胺纖條體為聚芳醯胺所構成的膜狀微小粒子,亦稱為聚芳醯胺漿液。製造方法可例示如日本特公昭35-11851號、日本特公昭37-5732號公報等所記載的方法。聚芳醯胺纖條體,因為與一般木材漿液相同地具有抄紙性,故在分散於水中之後,可在抄紙機中形成片狀。此情況下,以確保適用於抄紙之品質為目的,可實施所謂的打漿處理。該打漿處理可藉由碟形磨漿機、打漿機、其他具有機械裁切作用的抄紙原料處理機器來實施。該操作中,可以JIS P8121所規定之濾水度(游離度)監測纖條體的形態變化。本發明中,實施打漿處理後的聚芳醯胺纖條體的濾水度較佳為10~300cm3 (加拿大標準游離度)的範圍內。濾水度比該範圍大的纖條體,其後續成形的片材的強度可能降低。另一方面,若欲得到小於10cm3 的濾水度,則會有許多投入之機械動力的利用效率變小且每單位時間的處理量變少的情形,再者,因為過度進行纖條體的微細化,容易導致所謂的黏結功能降低。In the present invention, polyaramide fibrids are thin film-like particles composed of polyaramide, and are also called polyaramide slurry. Examples of the manufacturing method include methods described in Japanese Patent Publication No. 35-11851 and Japanese Patent Publication No. 37-5732. Polyaramide fibrids have the same papermaking properties as general wood pulp, so after being dispersed in water, they can be formed into flakes in a paper machine. In this case, for the purpose of ensuring the quality suitable for papermaking, a so-called beating treatment can be implemented. The beating process can be implemented by a dish-shaped refiner, a beating machine, or other paper-making raw material processing machines with a mechanical cutting function. In this operation, the morphological changes of fibrids can be monitored by the degree of drainage (freeness) specified in JIS P8121. In the present invention, the drainage degree of the polyaramide fibrids after the beating treatment is preferably in the range of 10 to 300 cm 3 (Canadian standard freeness). The fibrids having a water drainage degree larger than this range may have lower strength of the subsequently formed sheet. On the other hand, if it is desired to obtain a water filtration degree of less than 10cm 3 , the utilization efficiency of many input mechanical power will be reduced and the processing volume per unit time will be reduced. Furthermore, because of excessive fineness of fibrids It is easy to cause the so-called bonding function to decrease.
(聚芳醯胺短纖維)(Polyaramide staple fiber)
本發明中,聚芳醯胺短纖維,係將以聚芳醯胺作為原料的纖維裁切成既定長度者,作為這樣的纖維,例如,可例示帝人股份有限公司的「CONEX(註冊商標)」、「TECHNORA(註冊商標)」、杜邦公司的「NOMEX(註冊商標)」、「KEVLAR(註冊商標)」、帝人ARAMID公司的「TOWARON(註冊商標)」等,但不限於此等。In the present invention, polyaramide staple fibers are those obtained by cutting polyaramide as a raw material to a predetermined length. Examples of such fibers include "CONEX (registered trademark)" manufactured by Teijin Co., Ltd. , "TECHNORA (registered trademark)", "NOMEX (registered trademark)", "KEVLAR (registered trademark)" of DuPont, "TOWARON (registered trademark)" of Teijin ARAMID, etc., but not limited to these.
聚芳醯胺短纖維,較佳可具有0.05dtex以上、未滿25dtex的範圍內的纖度。纖度未滿0.05dtex的纖維,在以濕式法的製造(後述)中,容易導致凝集,又,纖度在25dtex以上的纖維,因為纖維直徑變得太大,導致長寬比降低,力學的補強效果下降,而可能發生聚芳醯胺紙的均勻性不良。The polyaramide staple fiber may preferably have a fineness in the range of 0.05 dtex or more and less than 25 dtex. Fibers with a fineness of less than 0.05 dtex tend to cause agglomeration in the wet process (described later). In addition, for fibers with a fineness of 25 dtex or more, the fiber diameter becomes too large, which reduces the aspect ratio and strengthens the mechanics. The effect is reduced, and poor uniformity of the polyaramide paper may occur.
聚芳醯胺短纖維的長度可選自1mm以上、未滿25mm,較佳為2~12mm的範圍。短纖維的長度若小於1mm,則聚芳醯胺紙的力學特性降低,另一方面,在25mm以上者,在以後述之濕式法製造聚芳醯胺紙時,容易發生「交纏」、「結束」等,而容易成為缺陷的原因。The length of the polyaramide staple fiber can be selected from the range of 1 mm or more but less than 25 mm, preferably 2-12 mm. If the length of the short fiber is less than 1mm, the mechanical properties of the polyaramide paper will be reduced. On the other hand, if the length is 25mm or more, when the polyaramide paper is produced by the wet method described later, "interlacing" is likely to occur. "End" and so on, and easily become the cause of the defect.
(聚芳醯胺紙)(Polyaramide paper)
本發明中,聚芳醯胺紙,係以該聚芳醯胺纖條體及聚芳醯胺短纖維為主所構成的片狀物,一般而言具有20μm~1000μm之範圍內的厚度。較佳為25~500μm。再者,聚芳醯胺紙,一般具有10g/m2 ~1000g/m2 的範圍內的單位面積重量。較佳為20~500g/m2 。此處,可任意決定聚芳醯胺纖條體與聚芳醯胺短纖維的混合比例,較佳係使聚芳醯胺纖條體/聚芳醯胺短纖維的比例(質量比)為1/9~9/1,更佳為2/8~8/2,但不限於此範圍。In the present invention, the polyaramide paper is a sheet mainly composed of the polyaramide fibrids and polyaramide short fibers, and generally has a thickness in the range of 20 μm to 1000 μm. Preferably it is 25 to 500 μm. Furthermore, polyaramide paper generally has a weight per unit area in the range of 10 g/m 2 to 1000 g/m 2. Preferably it is 20 to 500 g/m 2 . Here, the mixing ratio of polyaramide fibrids and polyaramide staple fibers can be arbitrarily determined, and it is preferable to set the ratio (mass ratio) of polyaramide fibrids/polyaramide staple fibers to 1 /9-9/1, more preferably 2/8-8/2, but not limited to this range.
聚芳醯胺紙,一般係以將上述聚芳醯胺纖條體與聚芳醯胺短纖維混合後進行片材化的方法製造。具體而言,可使用例如,在將上述聚芳醯胺纖條體及聚芳醯胺短纖維以乾式混合後使用氣流形成片材的方法;在將聚芳醯胺纖條體及聚芳醯胺短纖維於液體媒介中分散混合後,吐出至液體穿透性的支持體,例如網子或帶狀體上進行片材化,再去除液體以將其乾燥之方法等,但該等方法之中,較佳係選擇使用水作為媒介的所謂的濕式抄造法。The polyaramide paper is generally manufactured by a method of mixing the above-mentioned polyaramide fibrids and polyaramide short fibers to form a sheet. Specifically, it is possible to use, for example, a method of forming a sheet using airflow after the above-mentioned polyaramide fibrids and polyaramide staple fibers are dry mixed; After the amine short fibers are dispersed and mixed in a liquid medium, they are spit out to a liquid-penetrating support, such as a net or a ribbon, to form a sheet, and then remove the liquid to dry it. However, these methods are Among them, it is preferable to select the so-called wet papermaking method using water as a medium.
濕式抄造法中,一般係將至少含有聚芳醯胺纖條體、聚芳醯胺短纖維的單一或混合物的水性漿液送至抄紙機並進行分散後,藉由脫水、擠水及乾燥,再捲繞作為片材的方法。作為抄紙機,可使用長網抄紙機、圓網抄紙機、傾斜型抄紙機及將該等組合的複合式抄紙機等。在以複合式抄紙機進行製造的情況,藉由將摻合比例不同的漿液形成片材並使其合而為一,可得到複數的紙層所構成的複合體片材。抄造時可因應需求,使用分散性提升劑、消泡劑、紙力增強劑等的添加劑。In the wet papermaking method, an aqueous slurry containing at least a single or a mixture of polyaramide fibrids and polyaramide staple fibers is generally sent to a paper machine and dispersed, followed by dehydration, squeezing and drying. Rewind as a sheet method. As the paper machine, a Fourdrinier paper machine, a cylinder paper machine, an inclined paper machine, a hybrid paper machine combining these, and the like can be used. In the case of manufacturing with a composite paper machine, by forming a sheet of slurries with different blending ratios and combining them into one, a composite sheet composed of a plurality of paper layers can be obtained. In papermaking, additives such as dispersibility enhancers, defoamers, and paper strength enhancers can be used according to the needs.
如上所述,在一對滾筒間以高溫高壓將所得之聚芳醯胺紙進行加熱加壓加工,藉此可提升密度、機械強度。加熱加壓加工的條件,在使用例如金屬製滾筒的情況下,可例示為溫度100℃~400℃、線壓50~400kg/cm的範圍,但不限於此等條件。熱壓時,亦可將複數的聚芳醯胺紙積層。又,可以任意的順序多次進行上述的加熱加壓加工。As described above, the obtained polyaramide paper is heated and pressurized between a pair of rollers at high temperature and high pressure, thereby improving the density and mechanical strength. The conditions of the heating and pressing process, when a metal roll is used, for example, a temperature of 100°C to 400°C and a linear pressure of 50 to 400 kg/cm can be exemplified, but are not limited to these conditions. During hot pressing, multiple polyaramide papers can also be laminated. In addition, the above-mentioned heating and pressing processing may be performed multiple times in any order.
(絕緣片)(Insulation sheet)
本發明中,絕緣片係指具有電絕緣性的片材。絕緣片較佳為具有1×1010 ~1×1020 Ω·cm的體積電阻率,更佳為具有1×1012 ~1×1020 Ω·cm的體積電阻率。該聚芳醯胺紙單體,可舉例如,將該聚芳醯胺紙與樹脂膜積層,再以接著劑等接著的聚芳醯胺-樹脂膜積層體,或是將樹脂熔融壓出於該聚芳醯胺紙上所形成的片材。In the present invention, the insulating sheet refers to a sheet having electrical insulation. The insulating sheet preferably has a volume resistivity of 1×10 10 to 1×10 20 Ω·cm, and more preferably has a volume resistivity of 1×10 12 to 1×10 20 Ω·cm. The polyaramide paper monomer may include, for example, a polyaramide-resin film laminate formed by laminating the polyaramide paper and a resin film, and then using an adhesive or the like, or by melting and pressing the resin out The sheet formed on the polyaramide paper.
作為聚芳醯胺-樹脂膜積層體中所使用的樹脂膜,可例示:聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯、聚醯胺、芳香族聚醯胺、聚醯亞胺、聚四氟乙烯、聚苯硫醚等。該等可單獨使用,又,亦可使用將2種以上混合的樹脂或共聚物。又,作為用以積層聚芳醯胺紙的接著劑,可使用在本技術領域中常用的任何接著劑,可列舉例如:環氧系、丙烯酸系、苯酚系、胺甲酸酯系、矽氧樹脂系、聚酯系、醯胺系等的接著劑,但不限於此等。Examples of the resin film used in the polyaramide-resin film laminate include: polyethylene terephthalate, polyethylene naphthalate, polyamide, aromatic polyamide, and polyamide Amine, polytetrafluoroethylene, polyphenylene sulfide, etc. These can be used alone, and resins or copolymers in which two or more kinds are mixed can also be used. In addition, as an adhesive used to laminate polyaramide paper, any adhesive commonly used in this technical field can be used, and examples include epoxy-based, acrylic-based, phenol-based, urethane-based, and silicone-based adhesives. Adhesives such as resin-based, polyester-based, and amide-based adhesives, but are not limited to these.
在使用接著劑將聚芳醯胺紙與上述膜積層的情況下,一般係將膜延伸,而以後述方法製造絕緣部件的情況下,因為收縮而容易引起聚芳醯胺-樹脂膜積層體的變形,故在必須盡可能抑制變形的情況下,較佳係使用以預先將聚合物熔融所製成的膜與該聚芳醯胺紙重合,再進行加熱加壓,接著使聚合物熔融含浸於聚芳醯胺紙中的方法、或將樹脂熔融壓出於聚芳醯胺紙上使其熱融著的方法等,不透過接著劑而將樹脂直接積層於聚芳醯胺紙的片材。In the case of laminating the polyaramide paper with the above-mentioned film using an adhesive, the film is generally stretched. However, in the case of manufacturing insulating parts by the method described later, the polyaramide-resin film laminate is likely to be caused by shrinkage. Therefore, when the deformation must be suppressed as much as possible, it is better to use the film made by melting the polymer in advance and the polyaramide paper to overlap, then heat and press, and then melt and impregnate the polymer in The method in the polyaramide paper, or the method of melting and pressing the resin onto the polyaramide paper to heat it, etc., directly laminate the resin on the polyaramide paper sheet without passing through the adhesive.
積層的層數可因應積層體的用途、目的適當選擇,但若在至少單側的表層配置聚芳醯胺紙,其平滑性變好,而具有在馬達中容易將上述絕緣部件插入例如設於芯材之溝槽這樣的效果,因而較佳。可列舉例如:日本特開2006-321183號所記載的,將樹脂熔融壓出於聚芳醯胺紙上以將其熱融著的方法所製作、由芳香族聚醯胺樹脂與分子內具有環氧基的含環氧基之苯氧樹脂所構成,且該含環氧基之苯氧樹脂的比率為30~50質量%的聚合物與聚芳醯胺紙的雙層積層片、或聚芳醯胺紙、該聚合物與聚芳醯胺紙的3層的積層片,但不限於此等。The number of layers of the laminate can be appropriately selected according to the use and purpose of the laminate. However, if the polyaramide paper is arranged on at least one side of the surface layer, its smoothness becomes better, and it is easy to insert the above-mentioned insulating member in the motor. The effect of the groove of the core material is therefore better. For example, the method described in JP 2006-321183, the resin is melted and pressed onto the polyaramide paper, and the method is made by heat fusion. It is made of an aromatic polyamide resin and an epoxy resin in the molecule. A two-layer laminated sheet of polymer and polyaramide paper, or polyarylene, composed of epoxy group-containing phenoxy resin, and the ratio of the epoxy group-containing phenoxy resin is 30-50% by mass Amine paper, a 3-layer laminated sheet of the polymer and polyaramide paper, but not limited to these.
絕緣片的厚度、單位面積重量(基重)及密度,可因應芯材的尺寸、溝槽形狀及用途、目的適當選擇,只要拗摺加工性沒有問題,則可選擇任意的厚度。一般而言,從加工性的觀點來看,其為50μm~1000μm,較佳為50μm~500μm,再佳為70~300μm,但並不限定於此。又,單位面積重量較佳為30~1000g/m2 ,更佳為50~750g/m2 。密度較佳為0.1~2.5g/cm3 ,更佳為0.5~2.0g/cm3 。The thickness, weight per unit area (basis weight) and density of the insulating sheet can be appropriately selected according to the size of the core material, groove shape, application, and purpose. Any thickness can be selected as long as there is no problem with the folding processability. Generally speaking, from the viewpoint of workability, it is 50 μm to 1000 μm, preferably 50 μm to 500 μm, more preferably 70 to 300 μm, but it is not limited to this. In addition, the weight per unit area is preferably 30 to 1000 g/m 2 , more preferably 50 to 750 g/m 2 . The density is preferably 0.1 to 2.5 g/cm 3 , more preferably 0.5 to 2.0 g/cm 3 .
(樹脂成型體)(Resin molded body)
本發明中,樹脂成型體係表示藉由將已熔融之樹脂組成物填充至預期之模具,並在冷卻後脫模的射出成型法所製作的成型體。In the present invention, the resin molding system refers to a molded body produced by an injection molding method in which a molten resin composition is filled into a desired mold, and the mold is released after cooling.
作為本發明的樹脂成型體中所使用的樹脂組成物,較佳係單獨為具有醯胺鍵之樹脂或是包含該樹脂者。作為具有醯胺鍵的樹脂,可列舉:聚醯胺6、聚醯胺66、聚醯胺612、聚醯胺11、聚醯胺12、共聚合聚醯胺、聚醯胺MXD6、聚醯胺46、甲氧基甲基化聚醯胺、半芳香族聚醯胺等的聚醯胺樹脂單獨或該等的混合物。此處,作為半芳香族聚醯胺,可列舉:芳香族二羧酸成分與具有碳原子數4~10之直鏈脂肪族二胺的二胺成分所構成的聚醯胺。作為這樣的半芳香族聚醯胺,可列舉:己二胺、2-甲基戊二胺、對苯二甲酸的3元聚合的聚醯胺樹脂的杜邦公司的「ZYTEL(註冊商標)HTN501」等,但不限於此等。或是日本特開2006-321951所示之含有聚醯胺樹脂組成物的聚合物、或該等的混合物或該聚合物與玻璃纖維等無機物的混合物等。此處,作為該聚合物,係由芳香族聚醯胺樹脂與分子內具有環氧基之含環氧基的苯氧樹脂所構成、並含有30~50質量%之該含環氧基之苯氧樹脂而成的聚醯胺樹脂組成物。特別是半芳香族聚醯胺與玻璃纖維的混合物的成型體,其耐熱性高故佳。作為這樣的混合物,可舉例如杜邦公司的「ZYTEL(註冊商標)HTN51G、52G」等,但不限於此等。The resin composition used in the resin molded body of the present invention is preferably a resin having an amide bond alone or containing the resin. Examples of resins having an amide bond include:
本發明中,樹脂成型體中所使用的樹脂組成物具有絕緣特性,以該樹脂組成物所形成之樹脂成型體,較佳為具有1×1010 ~1×1020 Ω·cm的體積電阻率,更佳為具有1×1012 ~1×1020 Ω·cm的體積電阻率。In the present invention, the resin composition used in the resin molded body has insulating properties, and the resin molded body formed from the resin composition preferably has a volume resistivity of 1×10 10 to 1×10 20 Ω·cm , And more preferably have a volume resistivity of 1×10 12 to 1×10 20 Ω·cm.
本發明中,作為具有這種絕緣特性的樹脂組成物,較佳係單獨為上述具有醯胺鍵的樹脂或是包含該樹脂者。In the present invention, as the resin composition having such insulating properties, it is preferable to be the above-mentioned resin having an amide bond alone or to include the resin.
樹脂成型體的厚度較佳為100~5000μm,更佳為500~2000μm。The thickness of the resin molded body is preferably 100 to 5000 μm, more preferably 500 to 2000 μm.
(絕緣部件的製造方法)(Method of manufacturing insulating parts)
本發明的絕緣部件的製造方法,可使用下述製造方法:使用上述的絕緣片形成如第四圖所示之形狀後,配置於模具中,以使已熔融的樹脂組成物與拗摺部3中面向溝槽部的一側接觸以進行射出成型,藉此形成拗摺部3與樹脂成型體5接著的凸緣狀的芯部端面部6。The manufacturing method of the insulating part of the present invention can use the following manufacturing method: use the above-mentioned insulating sheet to form the shape as shown in the fourth figure, and then arrange it in a mold so that the melted resin composition and the folded
如第一圖,在形成絕緣片的一部份於表面露出之芯部端面部的情況中,配置成拗摺部3與模具接觸,藉此固定絕緣片7,再藉由射出成型,使樹脂組成物填入拗摺部3的缺口部分(略U字的側底部),藉由拗摺部3與樹脂成型體5,可得到表面形成略U字型的芯部端面部6。As shown in the first figure, in the case of forming a part of the end face of the core part exposed on the surface of the insulating sheet, it is arranged so that the folded
如第二圖,為了得到絕緣片的表面完全被樹脂成型體被覆的絕緣部件,可列舉下述方法:形成第一圖之絕緣部件1之後,另外進行射出成型而得到樹脂成型體50的方法;或是以不使絕緣片7的拗摺部3的表面接觸模具的方式形成孔洞,以一次的射出成型形成樹脂成型體50的方法等,但不限於此等方法。又,第二圖中,拗摺部3的側面(前側)雖露出一部份,但亦可為完全覆蓋該側面的構造。此時,作為固定拗摺部3在芯部端面部內的位置的方法,可舉例如:在模具內使可插拔的銷抵住拗摺部3而進行暫時固定,之後在射出成型的途中(填充樹脂組成物的過程中)移除銷等的方法,但並不限定於此。如上所述進行射出成型,形成絕緣片與樹脂成型體接著的芯部端面部,可得到本發明的絕緣部件。As shown in the second figure, in order to obtain the insulating part whose surface of the insulating sheet is completely covered by the resin molded body, the following method can be cited: after forming the insulating member 1 of the first figure, injection molding is additionally performed to obtain the resin molded
因為僅以絕緣片構成溝槽部,故本發明之絕緣部件中的溝槽部的厚度即為絕緣片的厚度。又,芯部端面部的厚度較佳為0.3mm~5mm,更佳為0.4mm~3mm,再佳為0.5mm~2mm。Since only the insulating sheet constitutes the groove portion, the thickness of the groove portion in the insulating member of the present invention is the thickness of the insulating sheet. In addition, the thickness of the end portion of the core is preferably from 0.3 mm to 5 mm, more preferably from 0.4 mm to 3 mm, and still more preferably from 0.5 mm to 2 mm.
[實施例][Example]
以下舉實施例更具體說明本發明。此外,該等的實施例僅為例示,並未對於本發明的內容有任何限定。The following examples illustrate the present invention in more detail. In addition, these examples are only examples, and do not limit the content of the present invention in any way.
[實施例1][Example 1]
(原料調製)(Raw material preparation)
使用日本特開昭52-15621號公報中記載的定子與滾子的組合所構成的漿液粒子製造裝置(濕式沉澱機),製造聚間苯二甲醯間苯二胺的纖條體。將其以粉碎機、打漿機進行處理,將長度加重平均纖維長調整為0.9mm。所得之纖條體的濾水度為90cm3 。另一方面,將杜邦公司製的間位聚芳醯胺纖維(NOMEX(註冊商標),單線纖度2.2dtex)裁切為長度6mm,作為抄紙用原料。A slurry particle manufacturing apparatus (wet precipitator) composed of a combination of a stator and a roller described in JP-A-52-15621 was used to manufacture fibrids of polymetaphenylene diamine. Treat it with a crusher and a beater, and adjust the length-weighted average fiber length to 0.9mm. The filterability of the obtained fibrids was 90 cm 3 . On the other hand, meta-aramide fiber (NOMEX (registered trademark), single-thread fineness 2.2 dtex) manufactured by DuPont was cut to a length of 6 mm and used as a raw material for papermaking.
(聚芳醯胺紙的製造)(Manufacturing of polyaramide paper)
分別將如上述調製的聚芳醯胺纖條體與聚芳醯胺短纖維分散於水中,以製作漿液。將該等的漿液以聚芳醯胺纖條體與聚芳醯胺短纖維成為1/1之摻合比例(重量比)的方式混合後,以TAPPI式手抄機(剖面積625cm2 )製作片狀物。接著,使用金屬製砑光輥以溫度330℃、線壓300kg/cm對其進行加熱加壓加工,得到聚芳醯胺紙。The polyaramide fibrids and polyaramide short fibers prepared as described above were dispersed in water to prepare a slurry. After mixing these slurries with polyaramide fibrids and polyaramide staple fibers at a blending ratio (weight ratio) of 1/1, they are produced with a TAPPI type hand machine (cross-sectional area of 625 cm 2) Flakes. Then, it was heated and pressurized at a temperature of 330°C and a linear pressure of 300 kg/cm using a metal calender roll to obtain polyaramide paper.
再者,以接著劑將聚芳醯胺紙與聚萘二甲酸乙二酯膜(TeijinDuPont Film 股份有限公司製,「TEONEX(註冊商標)Q51」,厚度100μm)貼合,得到將聚芳醯胺紙配置於外側的、聚芳醯胺紙/聚萘二甲酸乙二酯膜/聚芳醯胺紙的3層構造所構成的聚芳醯胺-樹脂膜積層體。Furthermore, polyaramide paper and polyethylene naphthalate film (manufactured by Teijin DuPont Film Co., Ltd., "TEONEX (registered trademark) Q51", thickness 100μm) were bonded together with an adhesive to obtain polyaramide A polyaramide-resin film laminate composed of a three-layer structure of polyaramide paper/polyethylene naphthalate film/polyaramide paper in which the paper is arranged on the outside.
(絕緣部件的製造)(Manufacture of insulating parts)
使用上述聚芳醯胺-樹脂膜積層體,如第三圖所示將其切開,切開第三圖的點線部後,將鏈線部山摺,從正面觀察其略為垂直,再沿著溝槽的形狀將虛線部拗摺,得到形成立體狀的絕緣片。使用此絕緣片與作為樹脂組成物的半芳香族聚醯胺(杜邦公司製「ZYTEL(註冊商標)HTN51G35EF」),以表1所示之條件進行射出成型,形成絕緣片與樹脂組成物接著的芯部端面部,得到形狀如第一圖所示的絕緣部件,其從溝槽部與芯部端面部的接合部至芯部端面部之邊緣的距離為10mm、芯部端面部的厚度為1mm。以下述方法評估如此所得之絕緣部件的主要特性值。結果顯示於表1。 [測定方法]Use the above-mentioned polyaramide-resin film laminate and cut it as shown in the third figure. After cutting the dotted line part of the third figure, fold the chain line part, which is slightly vertical when viewed from the front, and then follow the groove The shape of the groove folds the dotted line to obtain a three-dimensional insulating sheet. Using this insulating sheet and a semi-aromatic polyamide (“ZYTEL (registered trademark) HTN51G35EF” manufactured by DuPont Co., Ltd.) as a resin composition, injection molding was performed under the conditions shown in Table 1 to form a bond between the insulating sheet and the resin composition The end face of the core is obtained as an insulating part in the shape shown in the first figure. The distance from the junction of the groove part and the end face of the core to the edge of the end face of the core is 10mm, and the thickness of the end face of the core is 1mm. . The main characteristic values of the insulating parts thus obtained were evaluated by the following methods. The results are shown in Table 1. [test methods]
(1)單位面積重量、厚度、密度(1) Weight per unit area, thickness, density
依照JIS C 2300-2實施,以(單位面積重量/厚度)算出密度。It is implemented in accordance with JIS C 2300-2, and the density is calculated by (weight per unit area/thickness).
(2)絕緣片外觀(2) Appearance of insulating sheet
針對絕緣片的外觀,以目視觀察因成型時的熱導致翹曲的程度,將無翹曲者判斷為「良好」,具有些許翹曲者判斷為「大致良好」,明顯觀察到翹曲者判斷為「不良」。Regarding the appearance of the insulating sheet, visually observe the degree of warpage caused by the heat during molding. Those with no warpage are judged as "good", those with a little warpage are judged as "substantially good", and those with obvious warping are judged Is "bad".
(3)接著性(3) Adhesion
針對絕緣部件的芯部端面部,從略U字的上部,沿著絕緣片與樹脂成型體的界面以裁刀畫出深度1mm的切口,從該切口部分將絕緣片與樹脂成型體剝開,以目視觀察剝開後的樹脂成型體的表面。將樹脂成型體表面殘留有絕緣片表面之紙層者判斷為「良好」,將殘留有絕緣片表面之紙材料者判斷為「大致良好」,將完全未殘留絕緣片的紙材料者判斷為「不良」。With respect to the end face of the core of the insulating component, from the upper part of the U-shape, make a cut with a depth of 1 mm along the interface between the insulating sheet and the resin molded body, and peel off the insulating sheet and the resin molded body from the cut portion. The surface of the resin molded body after peeling was observed visually. If the paper layer on the surface of the insulating sheet remains on the surface of the resin molded body is judged as "good", the paper material on the surface of the insulating sheet is judged as "substantially good", and the paper material with no insulating sheet left at all is judged as " bad".
[實施例2][Example 2]
使用實施例1中所得之聚芳醯胺紙、具有50重量%的含環氧基之苯氧樹脂的半芳香族聚醯胺樹脂組成物(使用50重量份的杜邦公司製ZYTEL(註冊商標)HTN501、50重量份的含環氧基之苯氧樹脂,以日本特開2006-321183號公報[0027]記載的方法所調製的半芳香族聚醯胺樹脂組成物),以日本特開2006-321183號公報的[0024]記載的方法,將聚芳醯胺紙配置於外側,得到聚芳醯胺紙/樹脂組成物/聚芳醯胺紙的3層構造所構成的積層片。使用該積層片,以與實施例1相同的方式,得到第一圖所示之形狀的絕緣部件。以與實施例1相同的方式,評估如此所得之絕緣部件的主要特性値。結果顯示於表1。Using the polyaramide paper obtained in Example 1, a semi-aromatic polyamide resin composition having 50% by weight of epoxy-containing phenoxy resin (using 50 parts by weight of ZYTEL (registered trademark) manufactured by DuPont) HTN501, 50 parts by weight of epoxy group-containing phenoxy resin, a semi-aromatic polyamide resin composition prepared by the method described in JP 2006-321183 A [0027], according to JP 2006- According to the method described in [0024] of 321183 Gazette, the polyaramide paper is arranged on the outside to obtain a laminated sheet having a three-layer structure of polyaramide paper/resin composition/polyaramide paper. Using this laminated sheet, in the same manner as in Example 1, an insulating member having the shape shown in the first figure was obtained. In the same manner as in Example 1, the main characteristic values of the insulating member thus obtained were evaluated. The results are shown in Table 1.
[實施例3][Example 3]
將絕緣片變更為具有表1所示之特性的聚芳醯胺紙,除此之外以與實施例1相同的方式實施,得到第一圖所示之形狀的絕緣部件。以與實施例1相同的方式,評估如此所得之絕緣部件的主要特性値。結果顯示於表1。Except changing the insulating sheet to polyaramide paper having the characteristics shown in Table 1, it was implemented in the same manner as in Example 1, and an insulating member having the shape shown in the first figure was obtained. In the same manner as in Example 1, the main characteristic values of the insulating member thus obtained were evaluated. The results are shown in Table 1.
表1
從表1的結果來看,本發明的絕緣部件,外觀亦為均質,芯部端面部的厚度在實施例中小至1mm,也就是即使嵌入定子芯部亦可抑制端部的突出。因此,本發明的絕緣部件,相較於一般的旋轉電機,可抑制軸線方向上的長度,而可期待使用該絕緣部件的旋轉電機的小型化、高效率化、大輸出化。From the results of Table 1, the insulating member of the present invention also has a homogeneous appearance, and the thickness of the end face of the core is as small as 1 mm in the examples, that is, even if it is embedded in the stator core, the end protruding can be suppressed. Therefore, the insulating member of the present invention can suppress the length in the axial direction compared with a general rotating electric machine, and it is expected that the rotating electric machine using the insulating member can be reduced in size, efficiency, and output.
從實施例1~3的比較可得知,藉由使用選自聚芳醯胺纖條體與聚芳醯胺短纖維所構成的聚芳醯胺紙單體、及將樹脂熔融壓出於該聚芳醯胺紙上所形成的片材所構成之群組,可抑制在成型時因熱所造成的翹曲,而可呈現更佳的外觀。From the comparison of Examples 1 to 3, it can be seen that by using a polyaramide paper monomer composed of polyaramide fibrids and polyaramide staple fibers, and melting and pressing the resin out of the polyaramide paper monomer The group formed by the sheets formed on the polyaramide paper can suppress the warpage caused by heat during molding, and can present a better appearance.
1‧‧‧絕緣部件10‧‧‧絕緣部件2‧‧‧溝槽部3‧‧‧拗摺部3a‧‧‧側部拗摺部3b‧‧‧底部拗摺部4‧‧‧基材5‧‧‧樹脂成型體50‧‧‧樹脂成型體6‧‧‧芯部端面部7‧‧‧絕緣片7a‧‧‧絕緣片鏈線部7b‧‧‧絕緣片端部7c‧‧‧絕緣片端部與點線部的交點7d‧‧‧絕緣片鏈線部與點線部的交點1‧‧‧
第一圖係顯示本發明之一實施形態的絕緣部件的立體圖。The first figure is a perspective view showing an insulating member according to an embodiment of the present invention.
第二圖係顯示本發明之另一實施形態的絕緣部件的立體圖。The second figure is a perspective view of an insulating member according to another embodiment of the present invention.
第三圖係用於本發明之一實施形態的絕緣片的前視圖。The third figure is a front view of the insulating sheet used in one embodiment of the present invention.
第四圖係將第三圖之絕緣片拗摺時(使樹脂成型體密合之前)的立體圖。The fourth figure is a perspective view when the insulating sheet of the third figure is folded (before adhering the resin molded body).
1‧‧‧絕緣部件 1‧‧‧Insulation parts
2‧‧‧溝槽部 2‧‧‧Groove
3‧‧‧拗摺部 3‧‧‧Folding part
3a‧‧‧側部拗摺部 3a‧‧‧Side bending part
3b‧‧‧底部拗摺部 3b‧‧‧Bottom fold
4‧‧‧基材 4‧‧‧Substrate
5‧‧‧樹脂成型體 5‧‧‧Resin molding
6‧‧‧芯部端面部 6‧‧‧Core end face
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