TW201420022A - Acidic liquid flavoring containing sesame - Google Patents

Acidic liquid flavoring containing sesame Download PDF

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TW201420022A
TW201420022A TW101144299A TW101144299A TW201420022A TW 201420022 A TW201420022 A TW 201420022A TW 101144299 A TW101144299 A TW 101144299A TW 101144299 A TW101144299 A TW 101144299A TW 201420022 A TW201420022 A TW 201420022A
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liquid seasoning
flax
acid
aroma
acetic acid
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TW101144299A
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Chinese (zh)
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TWI598045B (en
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Hiroko Furukawa
Takuya Yanagisawa
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Kewpie Corp
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Abstract

The present invention provides an acidic liquid flavoring containing sesame, having not only an excellent sesame-specific aroma, but also a unique aroma that is highly addictive and habit-forming. The liquid flavoring of this invention includes sesame, acetic acid, vinylfuran, thiazole and/or dihydrothiophene. The liquid flavoring of this invention has not only an excellent sesame-specific aroma, but also a unique aroma that is highly addictive and habit-forming.

Description

含胡麻之酸性液狀調味料 Acidic liquid seasoning containing flax

本發明係關於液狀調味料,更詳細而言,係關於不僅是胡麻特有的芳香佳,並具有容易上癮而成習慣之獨特芳香之含胡麻之酸性液狀調味料。 The present invention relates to a liquid seasoning, and more particularly to an acidic liquid seasoning containing flax which is not only a unique aroma of flax but also has a unique aroma which is easily addictive.

美乃滋、沙拉醬等之酸性液狀調味料係賦予各種風味、及藉由酸味而清爽的後味之調味料。其使用用途係各式各樣的,可使用於蕃茄、生菜、高麗菜、玉米等之生菜沙拉用、蘋果、奇異果、柳橙等之水果沙拉用、火鍋等鍋料理之沾醬用、水煮馬鈴薯等之溫蔬菜用、豆腐料理或肉料理之醬料用等之所有料理之萬能調味料。接著,各種種類之酸性液狀調味料中,使用清爽酸味的醋,以胡麻特有的芳香為特徵之含胡麻之酸性液狀調味料博得很多人氣。 An acidic liquid seasoning such as mayonnaise or salad dressing is a seasoning which imparts various flavors and a refreshing aftertaste by sourness. It can be used in a wide variety of uses, such as lettuce salad for tomatoes, lettuce, Korean cabbage, corn, apple salad, kiwi, orange, etc. A panacea for cooking all kinds of vegetables such as warm vegetables, tofu dishes or sauces for meat dishes. Next, various kinds of acidic liquid seasonings use a refreshing sour vinegar, and the flax-containing acidic liquid seasoning characterized by the unique aroma of flax has gained a lot of popularity.

含胡麻之酸性液狀調味料係因胡麻特有的芳香容易劣化,所以為維持胡麻特有的芳香,進行各種研究。例如為長期間維持焙炒胡麻剛研磨之輕微香氣,揭示摻混特定香料(例如專利文獻1)。然而,該技術係僅長期間維持焙炒胡麻剛研磨之輕微香氣,並非具有引起消費者食欲之嶄新的獨特風味者。 Since the acidic liquid seasoning containing flax is easily deteriorated by the aroma specific to flax, various studies have been conducted to maintain the aroma unique to flax. For example, it is possible to maintain a slight aroma of roasted roast flax just for a long period of time, and it is revealed that a specific fragrance is blended (for example, Patent Document 1). However, this technology only maintains the slight aroma of roasting flax just for a long period of time, and is not a unique and unique flavor that causes the appetite of consumers.

先前技術文獻 Prior technical literature 專利文獻 Patent literature

專利文獻1:特開2008-154476號公報 Patent Document 1: JP-A-2008-154476

本發明者等重複努力研究的結果,發現首先將胡麻過度焙炒,產生新的天然胡麻不存在的多數香氣成份。新發現的香氣成份係不存在於天然的胡麻,為市售胡麻醬等之液狀調味料所使用之粒狀或磨碎狀的焙炒胡麻亦不能確認之成份。具體上,將胡麻以通常的150℃左右,即使高以180℃程度之加熱溫度焙炒時,亦不能確認之成份。另外,如此香氣成份係以胡麻單體食用會被視為異味之成份,即使將各成份分別單獨地含於含胡麻之酸性液狀調味料中,亦同樣可感到異味。另一方面,即使為異味的成份,使含胡麻之酸性液狀調味料含有特定的多數成份,發現可感到獨特的芳香。 As a result of repeated efforts by the inventors, it was found that the flax was first over-baked to produce a majority of the aroma components which were not present in the new natural flax. The newly discovered aroma components are not found in natural flax, and are not confirmed as granulated or pulverized roasted flax used for liquid seasonings such as commercially available flax sauce. Specifically, the flax is not normally confirmed when it is roasted at a heating temperature of about 150 ° C or about 180 ° C. In addition, such an aroma component is considered to be an odor component when it is eaten by a flax monomer, and even if each component is separately contained in an acidic liquid seasoning containing flax, an odor can be felt. On the other hand, even if it is an odor component, the acidic liquid seasoning containing flax contains a specific majority of ingredients, and it is found that a unique aroma can be felt.

因此,本發明者等想到,不是如焙炒胡麻剛磨好的輕微香氣般僅在含入口中前直接通過鼻腔感到的香氣(鼻腔香氣),而是藉由含胡麻之酸性液狀調味料黏著於舌頭時的知覺及與特定香氣成份比之相乘效果,而在含液狀調味料於舌頭上之後,胡麻特有的芳香上升經過鼻腔(口腔香氣)時,更可感到容易上癮而成習慣之獨特芳香。 Therefore, the inventors of the present invention thought that it is not the aroma (nasal aroma) which is directly felt through the nasal cavity just before the inlet, as in the slightly aroma of the roasted flax, but is adhered by the acidic liquid seasoning containing flax. The perception of the tongue and the specific aroma components are multiplied, and after the liquid seasoning is applied to the tongue, the unique aroma of the flax rises through the nasal cavity (oral aroma), and it is more susceptible to addiction. Unique aroma.

本發明係有鑑於前述之背景技術所實施者,其目的係提供不僅是胡麻特有的芳香風味佳,並具有容易上癮而成習慣之獨特芳香的含胡麻之酸性液狀調味料。 The present invention has been made in view of the above-described background art, and an object thereof is to provide a flax-containing acidic liquid seasoning which is not only a unique aroma of flax but also has a unique aroma which is easily addictive.

本發明者等為解決前述課題,努力檢討的結果,發現將過度焙炒胡麻而產生天然胡麻原本未含之特定的多數個成份,摻混於含胡麻之酸性液狀調味料以調節香氣成份,可解決前述課題。本發明係基於相關發現所完成者。 In order to solve the above problems, the inventors of the present invention have tried to review the results, and found that excessively roasted flax is produced to produce a specific plurality of components which are not originally contained in natural flax, and are blended in an acidic liquid seasoning containing flax to adjust the aroma components. The above problems can be solved. The present invention is based on the completion of related findings.

亦即,依據本發明之一種型態,提供含胡麻、醋酸、乙烯基呋喃、噻唑及/或二氫噻吩而成之液狀調味料。 That is, according to one form of the present invention, a liquid seasoning containing flax, acetic acid, vinyl furan, thiazole and/or dihydrothiophene is provided.

本發明之型態中,將前述液狀調味料之香氣成份,以固相微量萃取-氣相層析質譜分析法測定時,乙烯基呋喃、噻唑及二氫噻吩之各波峰面積對醋酸之波峰面積的比係以滿足下述條件(a)~(c): In the form of the present invention, when the aroma component of the liquid seasoning is determined by solid phase microextraction-gas chromatography mass spectrometry, the peak areas of vinylfuran, thiazole and dihydrothiophene are peaks of acetic acid. The area ratio is such that the following conditions (a) to (c) are satisfied:

(a)乙烯基呋喃:0.00002~0.005 (a) Vinyl furan: 0.00002~0.005

(b)噻唑:0.00006~0.02 (b) Thiazole: 0.00006~0.02

(c)二氫噻吩:0.00001~0.003 (c) Dihydrothiophene: 0.00001~0.003

中任一項以上為宜。 Any one or more of them are appropriate.

本發明之型態中,前述胡麻含量相對於前述液狀調味料總量係以1~40質量%為宜。 In the form of the present invention, the content of the flax is preferably from 1 to 40% by mass based on the total amount of the liquid seasoning.

本發明之型態中,前述液狀調味料係以進一步含有符合L*a*b*表色系中L*=34~62之強濃焙煎胡麻而成為宜。 In the form of the present invention, the liquid seasoning is preferably further comprising a strong concentrated roast flax that meets L*=34-62 in the L*a*b* color system.

本發明之型態中,醋酸含量相對於前述液狀調味料總量係以0.1~1質量%為宜。 In the form of the present invention, the acetic acid content is preferably 0.1 to 1% by mass based on the total amount of the liquid seasoning.

本發明之型態中,以前述液狀調味料進一步含有選自山梨酸、苯甲酸及此等之鹽所成群中之至少一種而成為 宜。 In the aspect of the present invention, the liquid seasoning further contains at least one selected from the group consisting of sorbic acid, benzoic acid, and the like. should.

本發明之型態中,以前述液狀調味料進一步含有選自己二酸、反丁烯二酸、順丁烯二酸及此等之鹽所成群中之至少一種而成為宜。 In the form of the present invention, it is preferred that the liquid seasoning further contains at least one selected from the group consisting of adipic acid, fumaric acid, maleic acid, and the like.

本發明之型態中,前述液狀調味料之黏度係以0.1~50Pa‧s為宜。 In the form of the present invention, the viscosity of the liquid seasoning is preferably from 0.1 to 50 Pa‧s.

本發明之型態中,前述液狀調味料係以水中油型乳化液狀調味料為宜。 In the form of the present invention, the liquid seasoning is preferably an oily emulsified liquid seasoning.

本發明之型態中,前述液狀調味料係以進一步含有蛋黃而成為宜。 In the aspect of the invention, the liquid seasoning is preferably further composed of egg yolk.

本發明之型態中,前述蛋黃係以經磷脂酶A處理之蛋黃為宜。 In the form of the present invention, the egg yolk is preferably egg yolk treated with phospholipase A.

依據本發明,可提供不僅是胡麻特有的芳香佳,並具有容易上癮而成習慣之獨特芳香的含胡麻之酸性液狀調味料。藉此可引起消費者的食慾,可期待摻混含胡麻之酸性液狀調味料之加工食品市場的更加擴大。 According to the present invention, it is possible to provide a flax-containing acidic liquid seasoning which is not only a flavour unique to flax, but also has a unique aroma which is easily addictive. This can lead to an appetite for consumers, and it is expected that the market for processed foods containing flax-containing acidic liquid seasonings will be further expanded.

用以實施發明之最佳型態 The best form for implementing the invention 液狀調味料 Liquid seasoning

本發明之液狀調味料係含胡麻、醋酸、乙烯基呋喃、噻唑及/或二氫噻吩而成者,以含有乙烯基呋喃、噻唑、及二氫噻吩之3種而成為宜。含胡麻之酸性液狀調味料含 有乙烯基呋喃、噻唑及/或二氫噻吩,不僅胡麻特有的芳香佳,成為具有容易上癮而成習慣之獨特芳香風味者。使含有乙烯基呋喃、噻唑、及二氫噻吩,可更增加前述效果。另外,所謂乙烯基呋喃,可含2-乙烯基呋喃及3-乙烯基呋喃中任一種,亦可含二者。所謂二氫噻吩,可含2,3-二氫噻吩及2,5-二氫噻吩中任一種,亦可含二者。 The liquid seasoning of the present invention is preferably composed of flax, acetic acid, vinyl furan, thiazole and/or dihydrothiophene, and contains three kinds of vinyl furan, thiazole and dihydrothiophene. Acidic liquid seasoning containing flax There are vinyl furan, thiazole and / or dihydrothiophene, not only the unique aroma of flax, but also a unique aromatic flavor with an addictive habit. The above effects can be further enhanced by containing vinylfuran, thiazole, and dihydrothiophene. Further, the vinyl furan may contain either 2-vinylfuran or 3-vinylfuran, or both. The dihydrothiophene may contain any one of 2,3-dihydrothiophene and 2,5-dihydrothiophene, and may also contain both.

在此,乙烯基呋喃、噻唑、及二氫噻吩中任一種皆非天然胡麻原本所含的成份。乙烯基呋喃係咖啡等所含之特徵香味,噻唑係洋芋片或奶油等所含之特徵香味,二氫噻吩係牛排等所含之特徵香味。任一種成份以單體食用時,僅為異味之成份,進而,於含胡麻之酸性液狀調味料含有各單體之乙烯基呋喃、噻唑、及二氫噻吩,同樣地僅為異味。 Here, any of vinyl furan, thiazole, and dihydrothiophene is not a component originally contained in natural flax. A characteristic flavor contained in a vinyl furan-based coffee or the like, a characteristic flavor contained in a thiazole-based artichoke tablet or cream, and a characteristic flavor contained in a dihydrothiophene-based steak. When any one of the ingredients is used as a monomer, it is only an odor component, and further, the acidic liquid seasoning containing the flax contains vinylfuran, thiazole, and dihydrothiophene of each monomer, and is similarly an odor.

本發明之液狀調味料係發現天然胡麻原本所不含的成份之乙烯基呋喃、噻唑、及/或二氫噻吩不僅是增強胡麻持有的芳香,並可賦予容易上癮而成習慣之獨特芳香,使液狀調味料含有此等者。使液狀調味料含有乙烯基呋喃、噻唑、及二氫噻吩之方法並無特別限定,可列舉摻混含有此等成份之食品或食品添加物之方法。例如若食用單體時,可使用施以加熱處理直至呈現苦味或異味之胡麻。 The liquid seasoning of the present invention finds that the vinyl furan, thiazole, and/or dihydrothiophene which are not originally contained in the natural flax are not only enhance the aroma of the flax, but also impart a unique aroma to the addictive habit. So that the liquid seasoning contains these. The method of containing the vinyl furan, the thiazole, and the dihydrothiophene in the liquid seasoning is not particularly limited, and a method of blending the food or the food additive containing the components may be mentioned. For example, if a monomer is used, it is possible to use a heat treatment to give a bitter or odor.

本發明之液狀調味料係以如下詳述之固相微量萃取-氣相層析質譜分析法測定時,乙烯基呋喃、噻唑及二氫噻吩之各波峰面積對醋酸之波峰面積的比係下述條件(a)~(c): The liquid seasoning of the present invention is determined by solid phase microextraction-gas chromatography mass spectrometry as detailed below, and the ratio of the peak area of vinylfuran, thiazole and dihydrothiophene to the peak area of acetic acid is Conditions (a) to (c):

(a)乙烯基呋喃:0.00002~0.005 (a) Vinyl furan: 0.00002~0.005

(b)噻唑:0.00006~0.02 (b) Thiazole: 0.00006~0.02

(c)二氫噻吩:0.00001~0.003 (c) Dihydrothiophene: 0.00001~0.003

滿足任一項以上為宜。 It is advisable to satisfy any one or more.

(a)乙烯基呋喃:0.00004~0.003 (a) Vinyl furan: 0.00004~0.003

(b)噻唑:0.0008~0.01 (b) Thiazole: 0.0008~0.01

(c)二氫噻吩:0.00002~0.002 (c) Dihydrothiophene: 0.00002~0.002

滿足任一項以上尤佳。 It is especially good to satisfy any one or more.

(a)乙烯基呋喃:0.00006~0.002 (a) Vinyl furan: 0.00006~0.002

(b)噻唑:0.0001~0.006 (b) Thiazole: 0.0001~0.006

(c)二氫噻吩:0.00004~0.0015 (c) Dihydrothiophene: 0.00004~0.0015

滿足任一項以上更好。 It is better to satisfy any one or more.

乙烯基呋喃、噻唑及二氫噻吩之各波峰面積對醋酸之波峰面積的比若於前述範圍程度,不僅使更強烈地感到胡麻特有的芳香,可增加容易上癮而成習慣之獨特芳香。 When the ratio of the peak area of the vinyl furan, the thiazole, and the dihydrothiophene to the peak area of the acetic acid is within the above range, not only the aroma unique to the flax is more strongly felt, but also the unique aroma which is easily addictive.

本發明之液狀調味料中之乙烯基呋喃、噻唑及二氫噻吩之含量係因應液狀調味料中之醋酸含量,以固相微量萃取-氣相層析質譜分析法(SPME-GC-MS)之分析值,可適當調整成為本發明之比率。例如相對於液狀調味料中0.1~1質量%的醋酸,以含有0.1~1000ppb為宜。 The content of vinylfuran, thiazole and dihydrothiophene in the liquid seasoning of the present invention is determined by solid phase microextraction-gas chromatography mass spectrometry (SPME-GC-MS) in response to the acetic acid content in the liquid seasoning. The analysis value can be appropriately adjusted to the ratio of the present invention. For example, it is preferable to contain 0.1 to 1000 ppb of acetic acid in an amount of 0.1 to 1% by mass based on the liquid seasoning.

本發明之液狀調味料所使用之胡麻含量係只要具有胡麻特有的芳香,並無特別限定,但以1~40質量%為宜,以2~30質量%尤佳,以3~15質量%更好。胡麻含量為1質量%以上時,從剛製好時,可具有強烈的胡麻特有的芳 香。若為40質量%以下時,可更發揮增強胡麻特有的芳香。進而,醋酸之摻混量於前述範圍內,不僅使更強烈地感到胡麻特有的芳香,亦可增強容易上癮而成習慣之獨特芳香風味。 The flax content used in the liquid seasoning of the present invention is not particularly limited as long as it has a specific aroma of flax, but is preferably 1 to 40% by mass, particularly preferably 2 to 30% by mass, and preferably 3 to 15% by mass. better. When the flax content is 1% by mass or more, it can have a strong flax-specific fragrance when it is just prepared. Fragrant. When it is 40% by mass or less, the aroma which is unique to the flax can be more enhanced. Further, the blending amount of acetic acid is within the above range, and not only the fragrance unique to flax is more strongly felt, but also the unique aromatic flavor which is easy to addiculous and habitual.

本發明之液狀調味料所使用之胡麻係以含有乙烯基呋喃、噻唑及二氫噻吩之強濃焙炒胡麻為宜。強濃焙炒胡麻係以例如190~210℃的高溫1秒~10分鐘,以195℃~205℃的高溫10秒~5分鐘為宜,可過度焙炒未焙炒胡麻或傳統的焙炒胡麻直至食用單體時為異味而可得。強濃焙炒胡麻係與含有乙烯基呋喃、噻唑及二氫噻吩之食品或食品添加物組合摻混時,因應需要,對於液狀調味料整體,以含有2~20質量%為宜,以3~15質量%尤佳。藉此不僅可使更強烈地感到胡麻特有的芳香,亦可增加容易上癮而成習慣之獨特芳香。尤其,摻混強濃焙炒胡麻於液狀調味料,使胡麻含有過度焙炒所產生的乙烯基呋喃、噻唑、及二氫噻吩,調節香氣成份為宜。 The flax used in the liquid seasoning of the present invention is preferably a strong roasted roast flax containing vinylfuran, thiazole and dihydrothiophene. Strong concentrated roasting flax is, for example, at a high temperature of 190-210 ° C for 1 second to 10 minutes, and at a high temperature of 195 ° C to 205 ° C for 10 seconds to 5 minutes, which can be over-roasted unroasted flax or traditional roast flax. It is available until the monomer is consumed. When the strong-flavored roasted flax is blended with a food or a food additive containing vinylfuran, thiazole or dihydrothiophene, it is preferably contained in an amount of 2 to 20% by mass for the liquid seasoning as a whole, if necessary. ~15% by mass is especially good. This not only makes you feel the unique aroma of flax, but also increases the unique aroma of addictive habits. In particular, blending strong concentrated roast flax in a liquid seasoning, so that the flax contains vinyl furan, thiazole, and dihydrothiophene produced by excessive roasting, and adjusting the aroma component is preferred.

胡麻的色調係以於L*a*b*表色系中顯示黑白明度之L*=30~65為宜,以34~62尤佳,以42~61更好。通常焙炒胡麻的色調係63~65程度,強濃焙炒胡麻的色調係62以下。因為強濃焙炒胡麻比焙炒胡麻之焙炒程度強,所以L*變小。焙炒胡麻或強濃焙炒胡麻之色調於前述範圍內,不僅使更強烈地感到胡麻特有的芳香,亦可增加容易上癮而成習慣之獨特芳香。另外,L*a*b*表色系中L*係使用分光測色計CM-508d(Konica Minolta製),依 據JISZ8729而可測定。 The hue of the flax is suitable for displaying L*=30~65 of black and white brightness in the L*a*b* color system, preferably 34~62, more preferably 42~61. Generally, the color of the roasted flax is about 63 to 65, and the color of the strong roasted roast is 62 or less. Because strong roasted roast is stronger than roasted roast, L* becomes smaller. The color of roasting flax or strong roasting flax is within the above range, which not only makes the aroma unique to flax more intense, but also increases the unique aroma of the addictive habit. In addition, in the L*a*b* color system, the L* system uses a spectrophotometer CM-508d (manufactured by Konica Minolta), It can be measured according to JISZ8729.

胡麻的比重係以0.8以下為宜,以0.35~0.75尤佳。通常,焙炒胡麻的比重為0.8程度,強濃焙炒胡麻的比重為0.75以下。因為強濃焙炒胡麻比焙炒胡麻之焙炒程度強,比重變小。焙炒胡麻或強濃焙炒胡麻的比重於前述範圍內,不僅使更強烈地感到胡麻特有的芳香,亦可增加容易上癮而成習慣之獨特芳香。另外,焙炒胡麻或強濃焙炒胡麻的比重係將對象物放入容積為200ml之量杯,刮平量杯上緣後,測定減去量杯重量之胡麻重量,算出胡麻比重。 The specific gravity of flax is preferably 0.8 or less, and preferably 0.35 to 0.75. Usually, the specific gravity of the roasted flax is 0.8, and the specific gravity of the strong roasted roast is 0.75 or less. Because strong roasted roast is more roasting than roasted roast, the specific gravity becomes smaller. The specific gravity of roasting flax or strong roasting flax is within the above range, which not only makes the flavour unique to flax more intense, but also increases the unique aroma of easy addiction. In addition, the specific gravity of the roasted flax or the strong roasted roast is placed in a measuring cup having a volume of 200 ml, and after scraping the upper edge of the measuring cup, the weight of the flax minus the weight of the measuring cup is measured, and the specific gravity of the flax is calculated.

本發明使用的胡麻並無特別限定,作為原料胡麻,可列舉白胡麻、金胡麻、黑胡麻、茶胡麻等。本發明所使用的胡麻形態並無特別限定,可為整粒狀,亦可以石臼、膠體研磨機、食物切碎機、粉碎機(milder)、滾輪粉碎器等所粉碎處理者。 The flax used in the present invention is not particularly limited, and examples of the raw flax include white flax, golden flax, black flax, and tea flax. The flax form used in the present invention is not particularly limited, and may be in the form of a whole granule, or may be pulverized by a stone shovel, a colloid mill, a food chopper, a miller, a roller pulverizer or the like.

本發明之液狀調味料係可摻混香料。所謂香料係指精油、油樹脂、回收香料、萃取物等之天然香料、或包含合成香料中之未於自然界發現的合成酯類、醇類、醛類、酮類等之人工香料(artficial flavor)或合成香料中僅以存在於自然界的化合物所製作之天然同等香料(Nature identical flavor)中任一種。作為摻混於液狀調味料之香料,以天然香料或天然同等香料為宜,以天然同等香料尤佳。但是,一般使用香料時,芳香成份之力價變強,另一方面,因選擇性地使用特定的成份,所以與天然芳香比較 時,有感到不自然芳香的問題。 The liquid seasoning of the present invention may be blended with a fragrance. The term "perfume" refers to natural flavors such as essential oils, oleoresins, recycled flavors, extracts, etc., or artificial perfumes containing synthetic esters, alcohols, aldehydes, ketones, etc., which are not found in nature. Or the synthetic fragrance is only one of the natural identical flavors produced by the compounds present in nature. As the flavor to be blended in the liquid seasoning, it is preferred to use a natural flavor or a natural flavor, and it is preferable to use a natural flavor. However, when a perfume is generally used, the strength of the aromatic component becomes strong, and on the other hand, since the specific component is selectively used, it is compared with the natural aroma. At the time, there is a problem of feeling unnaturally aromatic.

本發明之液狀調味料係以摻混胡麻風味香料為宜。所謂胡麻風味香料係指回收來自胡麻的香味成份者、或人工調製吡嗪類所代表之胡麻特有的芳香成份者。摻混胡麻風味香料於本發明之液狀調味料時,合併含有本發明之液狀調味料所含之乙烯基呋喃、噻唑及/或二氫噻吩與胡麻風味香料,不僅是增強胡麻特有芳香之效果,意外地亦一併解除前述香料特有的問題之芳香的不自然。 The liquid seasoning of the present invention is preferably a blend of flax flavors. The term "flavor flavor" refers to a person who recovers a flavor component derived from flax or artificially modulates the aroma component unique to hemp represented by pyrazine. When the flax flavor is blended in the liquid seasoning of the present invention, the vinyl furan, thiazole and/or dihydrothiophene and the flax flavor contained in the liquid seasoning of the present invention are combined to enhance the unique aroma of the flax. The effect is unexpectedly also to remove the unnaturalness of the fragrance of the problem specific to the aforementioned fragrance.

本發明之液狀調味料所使用之胡麻風味香料之摻量係只要摻混良好而可得到乙烯基呋喃、噻唑及/或二氫噻吩之前述作用即可,以0.01~10質量%為宜,以0.01~3質量%尤佳。 The amount of the flax flavoring agent used in the liquid seasoning of the present invention may be as long as it is blended to obtain the above-mentioned effects of vinylfuran, thiazole and/or dihydrothiophene, preferably 0.01 to 10% by mass. It is preferably 0.01 to 3% by mass.

本發明之液狀調味料係摻混醋酸而成酸性之液狀調味料。本發明之液狀調味料之pH係即使降低pH以使酸味明顯,仍可得到保持胡麻芳香之效果,所以於較低的pH,可發揮效果。pH係以3.0~6.5為宜,以3.3~5.5尤佳,以3.8~4.6更好。pH若為3.0以上,即使使酸味明顯,仍可保持胡麻的芳香。pH若為6.5以下,藉由酸味可突顯胡麻的芳香。進而,液狀調味料之pH為前述範圍內,不僅使更強烈地感到胡麻特有的芳香,亦可增加容易上癮而成習慣之獨特芳香。 The liquid seasoning of the present invention is an acidic liquid seasoning in which acetic acid is blended. The pH of the liquid seasoning of the present invention can obtain an effect of maintaining the aroma of flax even if the pH is lowered to make the acidity clear, so that the effect can be exhibited at a low pH. The pH system is preferably 3.0 to 6.5, preferably 3.3 to 5.5, and more preferably 3.8 to 4.6. When the pH is 3.0 or more, the aroma of flax can be maintained even if the acidity is marked. If the pH is 6.5 or less, the aroma of flax can be highlighted by the sour taste. Further, the pH of the liquid seasoning is within the above range, and not only the aroma unique to the flax is more strongly felt, but also the unique aroma which is easily addictive.

本發明之液狀調味料所使用之醋酸之摻混量係以0.1~1質量%為宜,以0.2~0.9質量%尤佳,以0.4~0.8質量%更好。醋酸之摻混量若為0.1質量%以上時,容易得到 醋酸與乙烯基呋喃、噻唑及/或二氫噻吩之相乘效果。若為1質量%時,可賦予胡麻芳香而不會過度突顯醋酸酸味。進而,醋酸之摻混量於前述範圍內,不僅使更強烈地感到胡麻特有的芳香,亦可增加容易上癮而成習慣之獨特芳香。 The blending amount of acetic acid used in the liquid seasoning of the present invention is preferably 0.1 to 1% by mass, particularly preferably 0.2 to 0.9% by mass, more preferably 0.4 to 0.8% by mass. When the blending amount of acetic acid is 0.1% by mass or more, it is easy to obtain The effect of mixing acetic acid with vinyl furan, thiazole and/or dihydrothiophene. When it is 1% by mass, the flax can be imparted with an aromatic acid taste without excessively accentuating. Further, when the blending amount of acetic acid is within the above range, not only the aroma unique to flax is more strongly felt, but also the unique aroma which is easily addicted to the habit can be increased.

本發明之液狀調味料所使用之酸性材料係除了醋酸之外,並無特別限制,可使用例如檸檬酸、蘋果酸、乳酸、山梨酸等之有機酸、磷酸、鹽酸等之無機酸、檸檬汁、蘋果汁、柳橙汁、乳酸發酵乳等。 The acidic material used in the liquid seasoning of the present invention is not particularly limited, and may be, for example, an organic acid such as citric acid, malic acid, lactic acid or sorbic acid, a mineral acid such as phosphoric acid or hydrochloric acid, or a lemon. Juice, apple juice, orange juice, lactic acid fermented milk, etc.

本發明之液狀調味料係含有特定質量比之醋酸與選自山梨酸、苯甲酸、及此等鹽所成群中之至少1種,將可得到容易上癮而成習慣之芳香而適宜的。本發明之液狀調味料中,醋酸與選自山梨酸、苯甲酸、及此等鹽所成群中之至少1種之質量比係以1:0.005~1:1為宜,以1:0.01~1:0.5尤佳。 The liquid seasoning of the present invention contains at least one selected from the group consisting of acetic acid and a salt selected from the group consisting of sorbic acid, benzoic acid, and the like, and is suitable for obtaining a habit which is easily addictive. In the liquid seasoning of the present invention, the mass ratio of acetic acid to at least one selected from the group consisting of sorbic acid, benzoic acid, and the like is preferably 1:0.005 to 1:1, and is 1:0.01. ~1:0.5 is especially good.

本發明之液狀調味料係適當地含有相對於醋酸為前述比率之選自山梨酸、苯甲酸、及此等鹽所成群中之至少1種即可。具體上,選自山梨酸、苯甲酸、及此等鹽所成群中之至少1種之合計量係以0.01~1質量%為宜,以0.03~0.3質量%尤佳。 The liquid seasoning of the present invention may suitably contain at least one selected from the group consisting of sorbic acid, benzoic acid, and the like, in an amount of the above ratio with respect to acetic acid. Specifically, the total amount of at least one selected from the group consisting of sorbic acid, benzoic acid, and the like is preferably 0.01 to 1% by mass, particularly preferably 0.03 to 0.3% by mass.

本發明之液狀調味料係含有特定質量比之醋酸與選自己二酸、反丁烯二酸、順丁烯二酸、及此等鹽所成群中之至少1種,將可得到容易上癮而成習慣之芳香而適宜。本發明之液狀調味料中,醋酸與選自己二酸、反丁烯二酸、 順丁烯二酸、及此等鹽所成群中之至少1種之質量比係以1:0.1~1:10為宜,以1:0.2~1:5尤佳。 The liquid seasoning of the present invention contains at least one of a specific mass ratio of acetic acid and selected adipic acid, fumaric acid, maleic acid, and the like, and is easily addictive. It is suitable for the aroma of habit. In the liquid seasoning of the present invention, acetic acid and adipic acid, fumaric acid, The mass ratio of maleic acid and at least one of the groups of such salts is preferably from 1:0.1 to 1:10, more preferably from 1:0.2 to 1:5.

本發明之液狀調味料係適當地含有相對於醋酸為前述比率之選自己二酸、反丁烯二酸、順丁烯二酸、及此等鹽所成群中之至少1種即可。具體上,選自己二酸、反丁烯二酸、順丁烯二酸、及此等鹽所成群中之至少1種之合計量係以0.1~1質量%為宜,以0.2~0.7質量%尤佳,以0.3~0.7質量%更好。 The liquid seasoning of the present invention may suitably contain at least one selected from the group consisting of adipic acid, fumaric acid, maleic acid, and the like in the above ratio. Specifically, the total amount of at least one selected from the group consisting of diacyl acid, fumaric acid, maleic acid, and the like is 0.1 to 1% by mass, and 0.2 to 0.7% by mass. % is particularly good, preferably 0.3 to 0.7% by mass.

前述之各有機酸及此等鹽之測定方法係基於「營養表示用之成份分析重點」(財團法人日本食品分析中心編,2007年10月20日發行)所揭示之藉由高效液相層析法(HPLC法)之有機酸分子之測定方法而行。具體上,例如將水溶液中之以山梨酸及/或山梨酸鹽狀態存在之山梨酸分子,以過氯酸萃取,利用有機酸類之紫外線吸收,以高效液相層析法(HPLC法)分別定量。 The above-mentioned methods for measuring each of the organic acids and the salts are based on "Key Points of Analysis for Nutritional Expressions" (edited by the Japan Food Analysis Center, published on October 20, 2007) by high performance liquid chromatography. The method for measuring organic acid molecules by the method (HPLC method) is carried out. Specifically, for example, a sorbic acid molecule in an aqueous solution in the form of sorbic acid and/or sorbate is extracted with perchloric acid and quantified by high performance liquid chromatography (HPLC) using ultraviolet absorption of organic acids. .

本發明之液狀調味料之黏度係0.1~50Pa‧s,以0.1~30Pa‧s為宜,以0.5~4Pa‧s尤佳。首先,賦予液狀調味料0.1 Pa‧s以上的黏度,舌頭可更感到含胡麻之酸性液狀調味料之黏著性。另外,液狀調味料之黏度為50Pa‧s以下,於舌頭上溶解擴散,前述之乙烯基呋喃、噻唑及二氫噻吩之香氣成份更加揮發。接著,藉由以舌頭感到的黏著性與前述乙烯基呋喃、噻唑及二氫噻吩之香氣成份之相乘效果,含液狀調味料於舌頭上後,胡麻特有的芳香上升於鼻腔時(口腔香氣),可使更感到容易上癮而 成習慣之獨特芳香。 The viscosity of the liquid seasoning of the present invention is 0.1 to 50 Pa‧s, preferably 0.1 to 30 Pa‧s, and preferably 0.5 to 4 Pa‧s. First, the liquid seasoning is given a viscosity of 0.1 Pa ‧ or more, and the tongue can feel the adhesion of the acidic liquid seasoning containing flax. In addition, the viscosity of the liquid seasoning is 50 Pa ‧ or less, and it dissolves and spreads on the tongue, and the aroma components of the aforementioned vinyl furan, thiazole and dihydrothiophene are more volatile. Then, by the adhesion felt by the tongue and the aroma components of the aforementioned vinylfuran, thiazole and dihydrothiophene, after the liquid seasoning is applied to the tongue, the unique aroma of the flax rises in the nasal cavity (the mouth aroma) ), making it more addictive A unique aroma of habit.

本發明之液狀調味料係以水中油型乳化液狀調味料為宜。乳化分散食用油脂,密封本發明之芳香成份於油滴中,進而可增強容易上癮而成習慣之獨特芳香。 The liquid seasoning of the present invention is preferably an oily emulsified liquid seasoning. The emulsified and dispersed edible oil and fat seals the aromatic component of the present invention in the oil droplets, thereby enhancing the unique aroma of the addictive habit.

所謂水中油型乳化液狀調味料係例如於清水中混合醋酸及檸檬酸等之酸性材料、與澱粉、膠類、蛋黃及蔗糖脂肪酸酯等之乳化材料後,以攪拌器等邊攪拌邊注入油脂而進行粗乳化,接著以剪斷力佳之處理機等均質化。 The oil-in-water emulsion-like seasoning is mixed with an acidic material such as acetic acid or citric acid, or an emulsified material such as starch, gum, egg yolk or sucrose fatty acid ester in water, and then injected while stirring with a stirrer or the like. The oil is coarsely emulsified, and then homogenized by a processor having a good shearing force.

本發明之液狀調味料所使用之食用油脂之摻混量係可密封本發明之芳香成份於油滴中即可,以1~70質量%為宜,以5~50質量%尤佳,以15~50質量%更好。 The blending amount of the edible oil and fat used in the liquid seasoning of the present invention can seal the aromatic component of the present invention in the oil droplets, preferably from 1 to 70% by mass, more preferably from 5 to 50% by mass, 15~50% by mass is better.

本發明使用之食用油脂並無特別限制,具體上,可使用例如菜籽油、大豆油、棕櫚油、棉籽油、玉米油、葵花油、紅花油、胡麻油、橄欖油、亞麻仁油、米油、椿油、野胡麻油、葡萄籽油、花生油、杏仁油、酪梨油、魚油、牛脂、豬脂、雞脂、或如MCT(中鏈肪酸三甘油酯)、二甘油酯、硬化油、酯交換油等之施以化學或酵素處理等所得之油脂等。以含有菜籽油、大豆油或棕櫚油為宜,以含有棕櫚油尤佳。 The edible fat and oil to be used in the present invention is not particularly limited, and specifically, for example, rapeseed oil, soybean oil, palm oil, cottonseed oil, corn oil, sunflower oil, safflower oil, flax oil, olive oil, linseed oil, rice oil can be used. , oyster sauce, wild flax oil, grape seed oil, peanut oil, almond oil, avocado oil, fish oil, tallow, pig fat, chicken fat, or such as MCT (medium chain fatty acid triglyceride), diglyceride, hardened oil, ester Oil or the like obtained by chemical or enzyme treatment, such as oil exchange. It is preferred to contain rapeseed oil, soybean oil or palm oil, and it is especially preferable to contain palm oil.

食用油脂之測定方法係基於「關於營養表示基準之營養成份等之分析方法等」(平成11年4月26日衛新第13號)所揭示之醚萃取法而進行。 The method of measuring the edible fats and oils is carried out based on the ether extraction method disclosed in "Analytical Method for Nutrient Compositions and the like for Nutritional Representation" (Aug. 26, 2002, Weishin No. 13).

本發明之水中油型乳化液狀調味料所使用之乳化材料係因為具有增強、保持容易上癮而成習慣之獨特芳香之效 果,所以以使用蛋黃為宜。蛋黃的摻混量係以0.1~20質量為宜,以0.1~5質量尤佳。蛋黃的摻混量若為0.1質量%以上,水中油型乳化液狀調味料可充份地維持乳化狀態。蛋黃的摻混量若為20質量%以下,蛋黃的風味不會變得過強,可保持胡麻的芳香。進而,醋酸之摻混量於前述範圍內,不僅使更強烈地感到胡麻特有的芳香,並可增加容易上癮而成習慣之獨特芳香。另外,蛋黃之摻混量係以敲破雞蛋所得之蛋黃液換算者,因為蛋黃液之膽固醇含量為1.4質量%,所以可依據日本厚生勞働省於平成11年4月26日所發行之衛新第13號「4膽固醇」之「(1)氣相層析法」所表示之膽固醇測定方法測定。 The emulsified material used in the oil-in-water emulsion seasoning of the present invention has the unique aroma effect of being enhanced and maintaining an addictive habit. Therefore, it is advisable to use egg yolk. The blending amount of egg yolk is preferably 0.1 to 20 mass, and particularly preferably 0.1 to 5 mass. When the blending amount of the egg yolk is 0.1% by mass or more, the oily emulsified liquid seasoning in the water can sufficiently maintain the emulsified state. When the blending amount of the egg yolk is 20% by mass or less, the flavor of the egg yolk does not become too strong, and the flavor of the flax can be maintained. Further, the blending amount of acetic acid is within the above range, and not only makes the aroma unique to flax more intense, but also increases the unique aroma which is easily addictive. In addition, the blending amount of egg yolk is based on the egg yolk liquid obtained by breaking the egg, because the cholesterol content of the egg yolk liquid is 1.4% by mass, so it can be issued according to the Japanese Ministry of Health, Labour and Welfare issued on April 26, 2011. The measurement method of the cholesterol measured by "(1) Gas Chromatography" of "13 Cholesterol" No. 13 is measured.

進而,關於前述蛋黃係使食用油脂分散於水中油型液狀調味料中,因為可容易得到長期保管後之抑制分離效果,接著風味的保持效果亦高,所以以使用經磷脂酶處理之蛋黃尤佳。 Further, the egg yolk is obtained by dispersing edible fats and oils in an oily liquid seasoning in water, since the segregation-preventing effect after long-term storage can be easily obtained, and the effect of maintaining the flavor is also high. Therefore, the egg yolk treated with the phospholipase is used. good.

本發明之液狀調味料係除了前述原料以外,於不損害本發明之效果範圍,可使含有適當選擇液狀調味料通常所使用之各種原料。可舉例如醬油、味醂、鹽、麩胺酸鈉、高湯等之調味料、葡萄糖、果糖、蔗糖、麥芽糖、寡糖、海藻糖等之糖類、黃芥茉粉、胡椒等之香辛料、卵磷脂、溶血卵磷脂、甘油脂肪酸酯、聚甘油脂肪酸酯、蔗糖脂肪酸酯、辛烯基順丁烯二酸化澱粉等之乳化材料、抗壞血酸、維生素E等之抗氧化劑、靜菌劑等。 The liquid seasoning of the present invention can contain various raw materials which are usually used in the liquid seasoning, in addition to the above-mentioned raw materials, without impairing the effect of the present invention. For example, seasonings such as soy sauce, miso, salt, sodium glutamate, broth, sugars such as glucose, fructose, sucrose, maltose, oligosaccharide, trehalose, yellow mustard powder, pepper, etc., lecithin, hemolytic eggs An emulsifier such as a phospholipid, a glycerin fatty acid ester, a polyglycerin fatty acid ester, a sucrose fatty acid ester or an octenyl maleated starch, an antioxidant such as ascorbic acid or vitamin E, or a bacteriostatic agent.

測定、分析方法 Determination and analysis method

本發明之液狀調味料中醋酸含量之測定方法係基於「營養表示用之成份分析重點」(財團法人日本食品分析中心編,2007年10月20日發行)所揭示之高效液相層析法(HPLC法)進行。具體上,例如加入最終濃度成為0.5質量%之過氯酸,萃取有機酸類,利用有機酸類之紫外線吸收,以高效液相層析法(HPLC法)分別定量。 The method for measuring the content of acetic acid in the liquid seasoning of the present invention is based on the "Key Points of Analysis of the Components for Nutritional Expression" (edited by the Japan Food Analysis Center, published on October 20, 2007). (HPLC method). Specifically, for example, perchloric acid having a final concentration of 0.5% by mass is added, and organic acids are extracted and quantified by high performance liquid chromatography (HPLC method) by ultraviolet absorption of organic acids.

本發明之液狀調味料之香氣成份係可依據後述條件,以固相微萃取-氣相層析質譜分析法(SPME-GC-MS)進行測定。 The aroma component of the liquid seasoning of the present invention can be measured by solid phase microextraction-gas chromatography mass spectrometry (SPME-GC-MS) according to the conditions described later.

(1)香氣成份之分離濃縮方法 (1) Separation and concentration method of aroma components

使用固相微萃取吸附纖維(SPME fiber)與揮發成份萃取裝置,依據下述條件,進行香氣成份之分離濃縮。 The solid phase microextraction adsorption fiber (SPME fiber) and the volatile component extraction device are used to separate and concentrate the aroma components according to the following conditions.

<固相微萃取條件> <Solid phase microextraction conditions>

‧固相微萃取吸附纖維StableFlex 50/30μm,DVB/Carboxen/PDMS(Sigma-Aldrich社製) ‧ Solid phase microextraction adsorption fiber StableFlex 50/30μm, DVB/Carboxen/PDMS (Sigma-Aldrich)

‧揮發性成份萃取裝置Combi PAL,CTC Analitics製 ‧Volatile component extraction device Combi PAL, made by CTC Analitics

‧預熱40℃,15min ‧Preheating 40°C, 15min

‧攪拌速度300rpm ‧Stirring speed 300rpm

‧萃取揮發性成份40℃,20min ‧Extract volatile components at 40 ° C for 20 min

‧脫附時間10min ‧ Desorption time 10min

(2)香氣成份之測定方法 (2) Method for determining aroma components

使用氣相層析法及質量分析法,依據下述條件,測定丁酸、己酸、及6-甲基-5-庚烯-2-酮之各波峰面積對液狀調味料中醋酸之波峰面積的比。 Using gas chromatography and mass spectrometry, the peaks of the butyric acid, caproic acid, and 6-methyl-5-hepten-2-one were measured for the peak of acetic acid in the liquid seasoning according to the following conditions. The ratio of the area.

<氣相層析條件> <Gas chromatography conditions>

‧測定機器Agilent 6890N(Agilent Technologies社製) ‧Measurement machine Agilent 6890N (manufactured by Agilent Technologies)

‧管柱SOLGEL-WAX(SGE社製) ‧Tube SOLGEL-WAX (manufactured by SGE)

長度30m,口徑0.25mm,膜厚0.25μm Length 30m, diameter 0.25mm, film thickness 0.25μm

‧溫度條件保持35℃(5 min)→以5℃/min升溫至120℃→以15℃/min升溫至220℃→保持6 min ‧The temperature condition is maintained at 35 ° C (5 min) → 5 ° C / min to 120 ° C → 15 ° C / min to 220 ° C → 6 min

‧載流氣體氦氣,氣體流量1.0 ml/min ‧ Carrier gas helium, gas flow rate 1.0 ml/min

<質量分析條件> <Quality Analysis Conditions>

‧質量分析計Agilent 5973N(Agilent Technologies社製) ‧Analytical analyzer Agilent 5973N (manufactured by Agilent Technologies)

‧掃描質量m/z 29.0~350.0 ‧Scanning quality m/z 29.0~350.0

‧離子化方式EI(離子化電壓70eV) ‧Ionization mode EI (ionization voltage 70eV)

另外,訊號強度低之情況等時,不進行掃描測定,進行選擇離子監測模式(SIM)測定亦可。 Further, when the signal intensity is low, the scanning measurement may not be performed, and the selective ion monitoring mode (SIM) measurement may be performed.

實施例 Example

後述係列舉實施例及比較例,更詳細地說明本發明,但本發明並非受限於後述實施例內容所解釋者。 The invention will be described in more detail in the following examples and comparative examples, but the invention is not limited by the scope of the examples described below.

製造液狀調味料 Making liquid seasonings

首先,將未焙炒胡麻(L*=67,比重1),以150℃之溫度1分鐘,使用鼓型旋轉式焙炒機,以傳統周知之方法焙炒,得到焙炒胡麻(L*=64,比重0.9)。另外,將未焙炒胡麻(L*=67,比重1),以200℃之高溫1分鐘,過度焙炒至若食用單體時有異味,得到強濃焙炒胡麻(L*=55,比重0.7)。接著,基於常法,混合摻混原料,最後邊攪拌(160rpm),緩緩添加大豆油,使乳化,調製表1及表2之配方之含胡麻之酸性液狀調味料(水中油型乳化液狀調味料)。適當添加乙烯基呋喃、噻唑及二氫噻吩而調製成如下述分析值之值。 First, unroasted flax (L*=67, specific gravity 1) was fired at a temperature of 150 ° C for 1 minute using a drum-type rotary roasting machine by a conventionally known method to obtain roasted fried flax (L*= 64, the proportion of 0.9). In addition, the unroasted flax (L*=67, specific gravity 1) was over-baked at a high temperature of 200 ° C for 1 minute until there was an odor when the monomer was eaten, and a strong concentrated roasted flax was obtained (L*=55, specific gravity). 0.7). Then, based on the usual method, the mixed raw materials are mixed, and finally, the soybean oil is gradually added (160 rpm), and the soybean oil is gradually added to be emulsified to prepare the flax-containing acidic liquid seasoning of the formulas of Tables 1 and 2 (oil-in-water emulsion) Flavor seasoning). The vinylfuran, thiazole and dihydrothiophene are appropriately added to prepare a value as shown in the following analysis.

以前述固相微萃取-氣相層析質譜分析法測定各含胡麻之酸性液狀調味料之香氣成份,乙烯基呋喃、噻唑及二氫噻吩之波峰面積、以及乙烯基呋喃、噻唑及二氫噻吩之各波峰面積對醋酸之波峰面積的比如表1及表2所示。 Determination of the aroma components of each of the acidic liquid seasonings containing flax, the peak area of vinylfuran, thiazole and dihydrothiophene, and vinylfuran, thiazole and dihydrogen by solid phase microextraction-gas chromatography-mass spectrometry Table 1 and Table 2 show the peak areas of the thiophene to the peak area of acetic acid.

所得之含胡麻之酸性液狀調味料係分別密封20g於30ml之加蓋玻璃容器。對於各含胡麻之酸性液狀調味料,依據下述基準,進行官能評估。官能評估的結果如表3及表4所示。另外,所得之含胡麻之酸性液狀調味料之pH為4.2,黏度為2Pa‧s。 The obtained flax-containing acidic liquid seasoning was sealed with 20 g of a 30 ml capped glass container, respectively. For each of the acidic liquid seasonings containing flax, the sensory evaluation was performed according to the following criteria. The results of the functional evaluation are shown in Tables 3 and 4. Further, the obtained flax-containing acidic liquid seasoning had a pH of 4.2 and a viscosity of 2 Pa‧s.

[評估基準] [Evaluation Benchmark]

4:胡麻特有的芳香非常優異。感到強烈的容易上癮而成習慣之獨特芳香。 4: The unique aroma of flax is very good. Feel strong and addictive to the unique aroma of the habit.

3:胡麻特有的芳香略優。感到容易上癮而成習慣之獨特芳香。 3: The unique aroma of flax is slightly better. Feel the addiction to the unique aroma of being addicted.

2:胡麻特有的芳香普通。略感到容易上癮而成習慣之獨特芳香。 2: The unique aroma of flax is common. Slightly addicted to the unique aroma of the habit.

1:胡麻特有的芳香差,損及品質。未感到容易上癮而成習慣之獨特芳香。 1: The unique aroma of flax is poor and the quality is compromised. The unique aroma that does not feel addictive and habitual.

檢討強濃焙炒胡麻 Review strong roasting flax

除了調節胡麻之焙炒程度,改變強濃焙炒胡麻的色調如表5所示以外,與實施例3同樣地調製含胡麻之酸性液狀調味料,進行前述之官能評估。結果係如表5所示。 The acid-like seasoning containing flax was prepared in the same manner as in Example 3 except that the degree of roasting of the flax was changed, and the color tone of the strong roasted roast was changed as shown in Table 5. The results are shown in Table 5.

除了調節胡麻之焙炒程度,改變強濃焙炒胡麻的色調如表6所示以外,與實施例3同樣地調製含胡麻之酸性液 狀調味料,進行前述之官能評估。結果係如表6所示。 The acid solution containing flax was prepared in the same manner as in Example 3 except that the degree of roasting of the flax was adjusted and the color tone of the strong roasted roast was changed as shown in Table 6. The flavoring was carried out and the aforementioned functional evaluation was carried out. The results are shown in Table 6.

除了取代0.5%之醋酸成0.47%之醋酸及0.03%之山梨酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例11),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 11) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.47% acetic acid and 0.03% sorbic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.3%之醋酸及0.2%之山梨酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例12),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 12) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.3% acetic acid and 0.2% sorbic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.47%之醋酸及0.03%之苯甲酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例13),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.47% acetic acid and 0.03% benzoic acid (Example 13), and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.3%之醋酸及0.2%之苯甲酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例14),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 14) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.3% acetic acid and 0.2% benzoic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.4%之醋酸及0.2%之己二酸 以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例15),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 In addition to replacing 0.5% acetic acid into 0.4% acetic acid and 0.2% adipic acid The acidic liquid seasoning containing flax (Example 15) was prepared in the same manner as in Example 10, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.1%之醋酸及0.6%之己二酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例16),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 16) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.1% acetic acid and 0.6% adipic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.4%之醋酸及0.2%之反丁烯二酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例17),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 17) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.4% acetic acid and 0.2% fumaric acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.1%之醋酸及0.6%之反丁烯二酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例18),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 18) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.1% acetic acid and 0.6% fumaric acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.4%之醋酸及0.2%之順丁烯二酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例19),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 19) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was added to 0.4% acetic acid and 0.2% maleic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.1%之醋酸及0.6%之順丁烯二酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例20),進行前述之官能評估。結果係胡麻特有的芳香比實施例3更佳。 An acid liquid seasoning containing flax (Example 20) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was replaced with 0.1% acetic acid and 0.6% maleic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was better than that of Example 3.

除了取代0.5%之醋酸成0.8%之醋酸以外,與實施例 10同樣地調製含胡麻之酸性液狀調味料(實施例21),進行前述之官能評估。結果係與實施例3相同。 In addition to replacing 0.5% acetic acid with 0.8% acetic acid, and examples 10 An acidic liquid seasoning containing flax (Example 21) was prepared in the same manner, and the aforementioned sensory evaluation was carried out. The results were the same as in Example 3.

除了取代0.5%之醋酸成0.9%之醋酸以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例22),進行前述之官能評估。結果係胡麻特有的芳香比實施例3稍差。 An acid liquid seasoning containing flax (Example 22) was prepared in the same manner as in Example 10 except that 0.5% acetic acid was replaced with 0.9% acetic acid, and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was slightly worse than that of Example 3.

除了取代經磷脂酶處理之蛋黃成黃原膠以外,與實施例10同樣地調製含胡麻之酸性液狀調味料(實施例23),進行前述之官能評估。結果係胡麻特有的芳香比實施例3稍差。另外,所得之含胡麻之酸性液狀調味料之黏度為3Pa‧s,pH為3.8。 An acidic liquid seasoning containing flax was prepared in the same manner as in Example 10 except that the phospholipase-treated egg yolk was added to xanthan gum (Example 23), and the above-mentioned sensory evaluation was carried out. As a result, the aroma unique to flax was slightly worse than that of Example 3. Further, the obtained flax-containing acidic liquid seasoning had a viscosity of 3 Pa‧s and a pH of 3.8.

Claims (11)

一種液狀調味料,其特徵係含胡麻、醋酸、乙烯基呋喃、噻唑及/或二氫噻吩而成。 A liquid seasoning characterized by containing flax, acetic acid, vinyl furan, thiazole and/or dihydrothiophene. 如請求項1之液狀調味料,其係將前述液狀調味料之香氣成份以固相微量萃取-氣相層析質譜分析法測定時,乙烯基呋喃、噻唑及二氫噻吩之各波峰面積對醋酸之波峰面積的比係滿足下述條件(a)~(c)中任一項以上:(a)乙烯基呋喃:0.00002~0.005(b)噻唑:0.00006~0.02(c)二氫噻吩:0.00001~0.003。 The liquid seasoning of claim 1, wherein the peak content of vinylfuran, thiazole and dihydrothiophene is determined by solid phase microextraction-gas chromatography mass spectrometry when the aroma component of the liquid seasoning is determined by solid phase microextraction-gas chromatography mass spectrometry. The ratio of the peak area of acetic acid satisfies any of the following conditions (a) to (c): (a) vinyl furan: 0.00002 to 0.005 (b) thiazole: 0.00006 to 0.02 (c) dihydrothiophene: 0.00001~0.003. 如請求項1或2之液狀調味料,其中前述胡麻含量相對於前述液狀調味料總量係1~40質量%。 The liquid seasoning of claim 1 or 2, wherein the aforementioned flax content is 1 to 40% by mass based on the total amount of the liquid seasoning. 如請求項1~3中任一項之液狀調味料,其係進一步含有符合L*a*b*表色系中L*=34~62之強濃焙煎胡麻而成。 The liquid seasoning according to any one of claims 1 to 3, which further comprises a strong concentrated roasting flax conforming to L*=34~62 in the L*a*b* color system. 如請求項1~4中任一項之液狀調味料,其中醋酸含量相對於前述液狀調味料總量係0.1~1質量%。 The liquid seasoning according to any one of claims 1 to 4, wherein the acetic acid content is 0.1 to 1% by mass based on the total amount of the liquid seasoning. 如請求項1~5中任一項之液狀調味料,其係進一步含有選自山梨酸、苯甲酸及此等之鹽所成群中之至少一種。 The liquid seasoning according to any one of claims 1 to 5, which further comprises at least one selected from the group consisting of sorbic acid, benzoic acid, and the like. 如請求項1~6中任一項之液狀調味料,其係進一步含有選自己二酸、反丁烯二酸、順丁烯二酸及此等之鹽所成群中之至少一種。 The liquid seasoning according to any one of claims 1 to 6, further comprising at least one selected from the group consisting of adipic acid, fumaric acid, maleic acid, and the like. 如請求項1~7中任一項之液狀調味料,其中前述液狀調味料之黏度係0.1~50Pa‧s。 The liquid seasoning according to any one of claims 1 to 7, wherein the liquid seasoning has a viscosity of 0.1 to 50 Pa‧s. 如請求項1~8中任一項之液狀調味料,其係水中油型乳化液狀調味料。 The liquid seasoning according to any one of claims 1 to 8, which is an oily emulsified liquid seasoning in water. 如請求項1~9中任一項之液狀調味料,其係進一步含有蛋黃而成。 The liquid seasoning according to any one of claims 1 to 9, which further comprises egg yolk. 如請求項10之液狀調味料,其中前述蛋黃係經磷脂酶A處理之蛋黃。 The liquid seasoning of claim 10, wherein the egg yolk is egg yolk treated with phospholipase A.
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