TW201414550A - Method and apparatus for continuous separation of cleaning solvent from rinse fluid in a dual-solvent vapor degreasing system - Google Patents

Method and apparatus for continuous separation of cleaning solvent from rinse fluid in a dual-solvent vapor degreasing system Download PDF

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Publication number
TW201414550A
TW201414550A TW102128956A TW102128956A TW201414550A TW 201414550 A TW201414550 A TW 201414550A TW 102128956 A TW102128956 A TW 102128956A TW 102128956 A TW102128956 A TW 102128956A TW 201414550 A TW201414550 A TW 201414550A
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Taiwan
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solvent
rinsing
rinse
contaminants
tank
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TW102128956A
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Chinese (zh)
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Kyle J Doyel
Michael L Bixenman
Ram Wissel
Alan William Mccready
Robert Eugene Scheidegger
Eddie Joe Mcchesney
Kent Dwayne Tedder
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Kyzen Corp
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Publication of TW201414550A publication Critical patent/TW201414550A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/14Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/102Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration with means for agitating the liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/106Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by boiling the liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50Solvents
    • C11D7/5004Organic solvents
    • C11D2111/22

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

A method for cleaning a precision component which includes the steps of immersing the component in a heated solvating agent disposed in a pre-clean module tank to thereby remove an adherent contaminant; treating the component with a rinsing solvent to remove any remaining contaminants and residual solvating agent in a separate rinse degreaser whereby contaminants removed from the component collect in the rinse degreaser; and removing contaminated solvent from the rinse degreaser to a micro-still to separate the contaminants from the rinse solvent and direct the purified rinse solvent to the rinse degreaser. An apparatus is also provided for cleaning contaminants from a precision component including a pre-clean module tank containing a heated solvating agent, a degreaser containing a rinsing solvent, and a micro-still which separates the contaminants from the rinsing solvent and directs the purified rinsing solvent to the rinse degreaser.

Description

在雙溶劑氣相脫脂系統中自沖洗流體連續分離清潔溶劑之方法及裝置 Method and apparatus for continuously separating cleaning solvent from flushing fluid in dual solvent vapor phase degreasing system

本發明係關於一種在用於清潔電子及其他組件之系統中自沖洗流體連續分離污染物之方法及裝置。 This invention relates to a method and apparatus for the continuous separation of contaminants from a flushing fluid in a system for cleaning electronic and other components.

助焊劑及其他污染物經常會於電子及其他組件之製造中殘留於其上。污染物係利用溶劑自組件移除。溶劑及殘留污染物係利用沖洗溶劑移除。 Flux and other contaminants often remain on the manufacture of electronics and other components. Contaminants are removed from the assembly using solvents. Solvents and residual contaminants are removed using a rinse solvent.

在多種產品(尤其係諸如電路板、醫療裝置、航空組件、及軍事組件之電子組件)之製造中係使用雙溶劑清潔系統。通常,使用第一溶劑(亦稱為「溶劑合劑」)來移除諸如助焊劑、油、潤滑油、及其類似物的黏附污物,然後再使用第二溶劑(亦稱為「沖洗劑」)來沖洗產品。在如此進行時,會有一定量的清潔溶劑及製造碎屑聚集於沖洗溶劑中。必需定期將沖洗溶劑中之此等污染物清除,而不至造成成本昂貴的生產線停機。 A dual solvent cleaning system is used in the manufacture of a variety of products, particularly electronic components such as circuit boards, medical devices, aerospace components, and military components. Typically, a first solvent (also known as a "solvent") is used to remove adhering dirt such as fluxes, oils, lubricants, and the like, and then a second solvent (also known as a "flushing agent") ) to rinse the product. In doing so, a certain amount of cleaning solvent and manufacturing debris are accumulated in the rinsing solvent. It is necessary to periodically remove such contaminants from the flushing solvent without causing costly downtime of the production line.

本發明係基於在系統操作期間連續地進行,以自動分離多種溶劑及污染物,同時回收昂貴的沖洗溶劑供於脫脂器中再利用的雙溶劑製程。該製程將產生高百分比的回收溶劑,其品質不會影響清 潔作用,導致對溶劑、設備、及被清潔產品之任何損害,及自動地離析廢棄物流以自系統定期去除。此雙溶劑製程包含在噴流清洗(spray-under-immersion)、超音波或其他攪拌製程中在一種特異性化學物質應用之類型中使用溶劑合劑的起始清潔步驟,及隨後用於二次清潔及沖洗作用以去除殘留污染物或溶劑合劑之第二個不同的溶劑製程。 The present invention is based on a two-solvent process that is continuously performed during system operation to automatically separate multiple solvents and contaminants while recovering expensive flushing solvents for reuse in the degreaser. The process will produce a high percentage of recovered solvent, the quality of which will not affect the Cleansing results in any damage to solvents, equipment, and products being cleaned, and automatically separates the waste stream for periodic removal from the system. The dual solvent process includes an initial cleaning step using a solvent mixture in a type of specific chemical application in a spray-under-immersion, ultrasonic or other agitation process, and subsequent use in secondary cleaning and A second different solvent process that rinses to remove residual contaminants or solvent mixtures.

此清潔模組製程將提供污物去除之起始階段,從而對第二沖洗溶劑產生較少負荷,因此延長溶劑浴液壽命,同時增進清潔度。 This cleaning module process will provide an initial stage of soil removal, resulting in less load on the second rinse solvent, thereby extending solvent bath life while increasing cleanliness.

本發明利用製程步驟之組合來有效地自基板去除黏附污物。術語「基板」在此係廣義地用來指示任何可能受到不期望物質污染的裝置或製造物件。因此,術語「基板」涵蓋,例如,機器零件、工具、或電子組件諸如印刷電路板、醫療裝置、航空組件、及軍事組件。同樣地,術語「黏附污物」亦係廣義地用來指示,例如,不易藉由一般的機械方式自基板去除之不期望物質。因此,術語「黏附污物」涵蓋無機及有機物質,例如,油脂、蠟、油、黏著劑、松香及基於樹脂之助焊劑。而申請人意圖將本發明特定地結合清潔來自印刷電路板之松香及/或樹脂助焊劑及結合清潔來自機器零件之蠟、油脂及/或油。 The present invention utilizes a combination of process steps to effectively remove adhering contaminants from the substrate. The term "substrate" is used broadly herein to refer to any device or article of manufacture that may be contaminated with undesirable materials. Thus, the term "substrate" encompasses, for example, machine parts, tools, or electronic components such as printed circuit boards, medical devices, aerospace components, and military components. Similarly, the term "adhesive soil" is also used broadly to indicate, for example, undesirable materials that are not easily removed from the substrate by conventional mechanical means. Therefore, the term "adhesive soil" encompasses inorganic and organic substances such as greases, waxes, oils, adhesives, rosins and resin-based fluxes. The Applicant intends to specifically combine the present invention with cleaning rosin and/or resin flux from printed circuit boards and in combination with cleaning waxes, greases and/or oils from machine parts.

用於本發明之溶劑合劑係一或多種技藝中所熟知之清潔劑。該等清潔劑之實例係彼等於下列專利案中所教示者:Bixenman等人之美國專利第5,128,057號;Doyel等人之美國專利第7,288,511 B2號;Hayes等人於美國專利第5,679,175號第4欄第64行至第5欄第12行中教示之清潔劑;於Doyel等人之專利公開案第20120152286號中所教示者;及於Doyel等人之美國專利第6,130,195號中所教示者。 清潔劑亦可具有其他期望特徵及特性。舉例來說,溶劑合劑較佳將不會不利地影響基板之構造材料或其組分的強度、整體性或可操作性。關於組成印刷電路板之基板,溶劑合劑較佳對經含浸環氧樹脂之纖維玻璃為惰性且不為其之溶劑。溶劑合劑較佳亦具低表面張力以改良加工特性且毒性低,且具有高閃點以改善安全性特徵。溶劑合劑係極佳地對大氣、土壤及水無害。化學及光化學穩定性亦係溶劑合劑之其他較佳特徵。溶劑合劑之一額外期望特徵係由熟悉技藝人士與沖洗劑之沸點匹配的沸點,其將有利於增進回收沖洗劑。 The solvent mixture for use in the present invention is a cleaning agent well known in the art. Examples of such cleaners are those taught by the following patents: U.S. Patent No. 5,128,057 to Bixenman et al., U.S. Patent No. 7,288,511, issued to Doyel et al., and U.S. Patent No. 5,679,175, the entire disclosure of U.S. Patent No. 5,679,175. </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> </ RTI> <RTIgt; Detergents can also have other desirable characteristics and characteristics. For example, the solvent mixture will preferably not adversely affect the strength, integrity or operability of the materials of construction or components of the substrate. Regarding the substrate constituting the printed circuit board, the solvent mixture is preferably inert to the fiber glass impregnated with the epoxy resin and is not a solvent thereof. The solvent mixture preferably also has a low surface tension to improve processing characteristics and is low in toxicity, and has a high flash point to improve safety characteristics. Solvent mixtures are excellent for the atmosphere, soil and water. Chemical and photochemical stability are also other preferred features of the solvent mixture. One of the additional desirable characteristics of the solvent mixture is the boiling point that is matched by the skilled artisan to the boiling point of the rinsing agent, which will facilitate the recovery of the rinsing rinse.

沖洗劑較佳亦具有極少或不具有已知之引起臭氧層耗乏的傾向。更特定言之,沖洗劑係極佳地具有不大於約0.15、更佳不大於約0.05、及甚至更佳約零之臭氧耗乏因子(ODP)。臭氧耗乏因子係揮發性物質對地球臭氧層之負面效應的熟知量度。 Preferably, the rinsing agent also has little or no tendency to cause ozone layer depletion. More specifically, the rinsing agent desirably has an ozone depletion factor (ODP) of no greater than about 0.15, more preferably no greater than about 0.05, and even more preferably about zero. Ozone depleting factors are well-known measures of the negative effects of volatile substances on the Earth's ozone layer.

熟悉技藝人士應明瞭目前使用的沖洗劑至少部分由於在組成沖洗劑之分子中不存在或減少存在氯而對大氣臭氧相當溫和。然而,亦當明瞭減少的氯含量會導致沖洗劑將許多黏附污物(包括松香助焊劑)溶劑合的能力減低。然而,較佳沖洗劑之相當低的溶劑合能力無損於本發明方法之清潔效用。因此,當明瞭本沖洗劑自待清潔基板洗滌溶劑合劑,且沖洗劑無需具有任何將黏附污物溶劑合的能力,儘管此能力可能存在於本發明之特定具體例中。 Those skilled in the art will recognize that the rinsing agents currently in use are relatively mild to atmospheric ozone due, at least in part, to the absence or reduction of the presence of chlorine in the molecules that make up the rinsing agent. However, it is also apparent that the reduced chlorine content will result in a reduced ability of the rinsing agent to solvate many adhering soils, including rosin fluxes. However, the relatively low solvating power of the preferred rinsing agent does not detract from the cleaning utility of the method of the present invention. Thus, it will be apparent that the rinsing agent will wash the solvent mixture from the substrate to be cleaned and that the rinsing agent need not have any ability to solvate the adhering soil, although this ability may be present in a particular embodiment of the invention.

使用於本發明之沖洗劑亦可具有其他期望及有利的特性。舉例來說,沖洗劑較佳不會不利地影響其組件之基板之構造材料的強度、完整性或可操作性。關於組成印刷電路板之基板,沖洗劑較佳對含浸環氧樹脂之纖維玻璃為惰性且不為其溶劑。沖洗劑較佳亦為低毒性且具有高閃點以改良安全性特徵。沖洗劑對大氣、土壤及水溫 和亦極佳。化學及光化學穩定性亦係沖洗劑之其他較佳特徵。以上針對沖洗劑所指出之各項特徵對於整體沖洗組成物同樣為較佳。沖洗劑之其他期望特徵應係熟悉技藝人士所明暸,諸如沸點及有利於沖洗劑與清潔劑分離之在沸點時之性質。 The rinsing agents used in the present invention may also have other desirable and advantageous properties. For example, the rinsing agent preferably does not adversely affect the strength, integrity, or operability of the materials of construction of the substrate of its components. Regarding the substrate constituting the printed circuit board, the rinsing agent is preferably inert to the fiber glass impregnated with the epoxy resin and is not a solvent thereof. The rinsing agent is preferably also low toxicity and has a high flash point to improve safety characteristics. Flushing agent to the atmosphere, soil and water temperature And also excellent. Chemical and photochemical stability are also other preferred features of the rinsing agent. The features indicated above for the rinsing agent are also preferred for the overall rinsing composition. Other desirable characteristics of the rinsing agent will be apparent to those skilled in the art, such as boiling point and properties at the boiling point that facilitate separation of the rinsing agent from the cleaning agent.

因此,在一態樣中,本發明係一種用於自精密組件清潔污染物之裝置,其特徵在於包括:a.裝有自精密組件去除污染物之經加熱溶劑合劑的預清潔模組槽,b.作為裝有自精密組件去除殘留溶劑合劑及黏附污物之沖洗劑之沖洗槽的氣相脫脂器,及c.自沖洗劑分離該殘留溶劑合劑及黏附污物,將沖洗劑引導回至沖洗槽,及將殘留溶劑合劑及污染物引導至廢棄物處置之微蒸餾器。 Accordingly, in one aspect, the present invention is a device for cleaning contaminants from a precision component, comprising: a. a pre-cleaning module tank containing a heated solvent mixture for removing contaminants from a precision component, b. As a gas phase degreaser with a rinse tank for removing the residual solvent mixture and adhering the dirt from the precision component, and c. separating the residual solvent mixture and adhering the dirt from the rinse agent, guiding the rinse agent back to Flush the tank and direct the residual solvent mixture and contaminants to the waste micro-distillator.

在本發明之裝置中,沖洗槽係操作性地連接至微蒸餾器,以傳送來自預清潔模組槽之受殘留溶劑合劑及黏附污物污染之沖洗劑及將沖洗劑傳送回至沖洗槽。 In the apparatus of the present invention, the rinsing tank is operatively coupled to the micro distiller to deliver rinsing agent from the pre-cleaning module tank contaminated with residual solvent mixture and adhering dirt and to transfer the rinsing agent back to the rinsing tank.

在本發明之另一態樣中,提供一種在用於清潔電子及其他組件之系統中自沖洗溶劑連續分離污染物之方法,其特徵在於其包括:a.在獨立的沖洗槽中利用沖洗溶劑處理已經過溶劑合劑處理之受污染基板,以去除任何殘留的污染物及殘留溶劑合劑,藉此將自組件去除之污染物收集於沖洗槽中;及b.將受污染的沖洗溶劑自沖洗槽移至微蒸餾器,以自沖洗溶劑中分離污染物,將沖洗劑引導回至沖洗槽,及將殘留溶劑合劑及污染物引導至廢棄物處置。 In another aspect of the invention, there is provided a method of continuously separating contaminants from a rinse solvent in a system for cleaning electronic and other components, characterized in that it comprises: a. utilizing a rinse solvent in a separate rinse tank Treating the contaminated substrate that has been treated with the solvent mixture to remove any residual contaminants and residual solvent mixture, thereby collecting contaminants removed from the assembly in the rinse tank; and b. contaminating the rinse solvent from the rinse tank Move to the micro-distiller to separate contaminants from the rinse solvent, direct the rinse back to the rinse tank, and direct the residual solvent mixture and contaminants to waste disposal.

在本發明之又另一態樣中,提供一種清潔精密組件之方 法,其特徵在於其包括:a.將組件浸泡在置於預清潔模組槽中之經加熱溶劑合劑中,因而去除黏附污染物;b.在獨立的沖洗脫脂器中用沖洗溶劑處理組件以去除任何殘留的污染物及殘留溶劑合劑,藉此將自組件去除之污染物收集於沖洗脫脂器中;及c.將受污染的沖洗溶劑自沖洗脫脂器移至微蒸餾器,以自沖洗溶劑分離污染物及將沖洗溶劑引導至沖洗脫脂器。 In still another aspect of the present invention, a method of cleaning a precision component is provided The method is characterized in that it comprises: a. immersing the component in a heated solvent mixture placed in a pre-cleaning module tank, thereby removing adhering contaminants; b. treating the component with a rinse solvent in a separate rinse degreaser Removing any residual contaminants and residual solvent mixture to collect contaminants removed from the assembly in the rinsing degreaser; and c. moving the contaminated rinsing solvent from the rinsing degreaser to the micro distiller to self rinsing the solvent Separate the contaminants and direct the rinse solvent to the rinse degreaser.

在本發明之一較佳具體例中,利用沖洗劑處理組件之步驟包括:d.藉由將該組件暴露至置於沖洗脫脂器上之沖洗劑的熱蒸氣來使該組件經歷預浸漬作用;e.將該組件浸泡在置於沸騰池中之沸騰沖洗劑中,因而去除任何殘留的黏附污物及殘留溶劑合劑;及f.將該組件自沸騰池移出及將該組件浸泡在置於沖洗室中之純化溶劑中。 In a preferred embodiment of the invention, the step of treating the assembly with the rinsing agent comprises: d. subjecting the assembly to a pre-impregnation by exposing the assembly to a hot vapor of a rinsing agent disposed on the rinsing degreaser; e. soaking the assembly in a boiling rinse placed in a boiling tank to remove any residual adhering dirt and residual solvent mixture; and f. removing the assembly from the boiling tank and immersing the assembly in a rinse In the purified solvent in the chamber.

10‧‧‧雙溶劑清潔系統 10‧‧‧Double Solvent Cleaning System

12‧‧‧預清潔模組槽 12‧‧‧Pre-cleaning module slot

14‧‧‧沖洗脫脂器 14‧‧‧ Flushing degreaser

16‧‧‧微蒸餾器 16‧‧‧Microstiller

18‧‧‧浸泡室 18‧‧‧Infusion room

20‧‧‧溶劑合劑 20‧‧‧ solvent mixture

22‧‧‧電浸入式加熱器 22‧‧‧Electric immersion heater

24‧‧‧恆溫控制器 24‧‧‧ thermostat controller

26‧‧‧噴流清洗作用;浸泡噴霧集管器 26‧‧‧Spray cleaning; soaking spray collector

28‧‧‧密封泵 28‧‧‧Seal pump

30‧‧‧過濾系統 30‧‧‧Filter system

32‧‧‧機器 32‧‧‧ Machine

34‧‧‧壓縮空氣掃掠集管器 34‧‧‧Compressed air sweeping collector

36‧‧‧電磁閥 36‧‧‧Solenoid valve

38‧‧‧沖洗脫脂器沸騰池 38‧‧‧ Flushing degreaser boiling pool

40‧‧‧輸送泵 40‧‧‧Transport pump

42‧‧‧抽吸軟管 42‧‧‧ suction hose

44‧‧‧原始溶液容器 44‧‧‧Original solution container

46‧‧‧壓縮空氣供給閥,脫脂器槽 46‧‧‧Compressed air supply valve, degreaser tank

48‧‧‧熱溶劑蒸氣 48‧‧‧Hot solvent vapour

50‧‧‧沖洗池 50‧‧‧washing pool

52‧‧‧主冷凝器螺管 52‧‧‧Main condenser coil

54‧‧‧乾舷區 54‧‧‧Floating area

56‧‧‧輸送泵 56‧‧‧Transport pump

58‧‧‧蒸餾器液位控制器 58‧‧‧Distiller level controller

60‧‧‧加熱器 60‧‧‧heater

62‧‧‧外部熱交換器/冷凝器 62‧‧‧External heat exchanger/condenser

64‧‧‧底部傾卸電磁閥 64‧‧‧Bottom dumping solenoid valve

66‧‧‧可撓性管件 66‧‧‧Flexible fittings

68‧‧‧廢棄物容器 68‧‧‧Waste container

圖1係本發明之清潔系統的示意圖,其顯示清潔及沖洗及脫脂模式;及圖2係顯示清潔、沖洗、及溶劑回收之步驟的流程圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic illustration of the cleaning system of the present invention showing cleaning and rinsing and degreasing modes; and Figure 2 is a flow chart showing the steps of cleaning, rinsing, and solvent recovery.

圖1顯示根據本發明之雙溶劑清潔系統10。雙溶劑清潔系統10大致包括預清潔模組槽12及沖洗脫脂器14。微蒸餾器16較佳 容納在預清潔模組12之艙室中用於連續低體積蒸餾溶劑。熟悉技藝人士當明瞭文中所述之裝置可由任何技藝中熟知之適當材料構成,諸如不鏽鋼或赫史特合金7(Hastelloy7;Haynes International,Inc.之註冊商標;該商標係用作稱為「超合金」之一系列22種不同的高度抗腐蝕金屬合金之前置名稱)。 Figure 1 shows a dual solvent cleaning system 10 in accordance with the present invention. The dual solvent cleaning system 10 generally includes a pre-cleaning module tank 12 and a flush degreaser 14. The micro distiller 16 is preferably It is contained in the chamber of the pre-cleaning module 12 for continuous low volume distillation of solvent. It will be apparent to those skilled in the art that the device described herein can be constructed of any suitable material known in the art, such as stainless steel or Hastelloy 7 (Hastelloy 7; registered trademark of Haynes International, Inc.; the trademark is used as a "superalloy" One series of 22 different highly corrosion-resistant metal alloys are pre-named).

第1階段預清潔製程循環: Stage 1 pre-cleaning process cycle:

透過材料處理系統(未圖示)使待清潔之工件降低至預清潔模組槽12中之浸泡室18中,使其在此暴露至經加熱的溶劑合劑20,以當處於槽中時達成「浸漬」作用。材料處理系統係技藝中熟知之類型,其可為以手動方式或藉由自動系統控制而降低至槽中之載體(諸如網架或籃),其皆係技藝中所熟知。溶劑合劑20係藉由安裝在與恆溫控制器24偏置之槽中的電浸入式加熱器22加熱。藉由偏置加熱器22,其經凹室屏蔽,而防止進入的零件/籃意外地接觸及可能損壞加熱器。溶劑合劑20之組成物對基板及污物之類型具特異性且為技藝中所熟知。溶劑合劑之組成物可包含,但不限於,一或多個不同相,或包含改變反應性、溶解度參數、閃點、酸度或鹼度、沸點、及各種其他熟悉技藝人士應知曉之化學及物理性質的添加劑。 The workpiece to be cleaned is lowered through a material handling system (not shown) into the infusion chamber 18 in the pre-cleaning module tank 12 where it is exposed to the heated solvent mixture 20 to achieve "when in the tank" Impregnation. Material handling systems are of a type well known in the art and can be reduced to the carrier (such as a grid or basket) in a tank either manually or by automated system control, as is well known in the art. The solvent mixture 20 is heated by an electric immersion heater 22 mounted in a tank biased from the thermostat controller 24. By biasing the heater 22, it is shielded by the recesses to prevent accidental contact between the incoming parts/basket and possibly damage to the heater. The composition of solvent mixture 20 is specific to the type of substrate and soil and is well known in the art. The composition of the solvent mixture can include, but is not limited to, one or more different phases, or include changes in reactivity, solubility parameters, flash point, acidity or alkalinity, boiling point, and various other chemical and physical knowledge that should be known to those skilled in the art. Nature of additives.

浸泡室18中之經加熱的溶劑合劑20自髒污零件之表面去除黏附污物。視黏附污物之性質而定,溶液產生溶劑作用或清潔劑與待去除之黏附污物的化學反應。在一些應用中,所使用之流體與黏附污物化學反應形成乳液,或將其軟化以在未來容易利用沖洗溶劑使其自基板釋放。 The heated solvent mixture 20 in the infusion chamber 18 removes adhering dirt from the surface of the soiled component. Depending on the nature of the adherent soil, the solution produces a solvent action or a chemical reaction of the cleaning agent with the adhering dirt to be removed. In some applications, the fluid used reacts chemically with the adherent soil to form an emulsion, or softens it to readily release it from the substrate in the future using a flushing solvent.

當工件浸沒於溶劑合劑20中時,使用液體室18中之噴流清洗作用26作為機械輔助來自基板表面移除顆粒物質及黏附污物。 應注意噴流清洗活動與對所清潔零件之效用的關係可能受零件暴露/網架/籃設計的影響。浸泡噴霧集管器26最常安裝在槽底部,以提供經加熱溶液之方向向上的流動來在槽中心產生擾流清潔活動區。經加熱溶液藉由密封泵28再循環通過過濾系統30,以在流體經再循環時自浴液去除脫離的污染物並保護噴霧噴嘴。 When the workpiece is immersed in the solvent mixture 20, the jet cleaning action 26 in the liquid chamber 18 is used as a mechanical aid to remove particulate matter and adhere to dirt from the surface of the substrate. It should be noted that the relationship between jet cleaning activities and the effectiveness of the parts being cleaned may be affected by the part exposure/grid/basket design. A soak spray header 26 is most often installed at the bottom of the tank to provide upward flow in the direction of the heated solution to create a spoiler cleaning active area in the center of the tank. The heated solution is recirculated through the filtration system 30 by a seal pump 28 to remove detached contaminants from the bath and protect the spray nozzle as the fluid is recirculated.

浸泡循環期間係由使用者基於期望清潔結果來決定。一旦完成在具有噴流清洗作用26之溶劑合劑20中之浸泡浸漬,即將工件提升至機器32之乾舷區,在此將使其停留以在槽上方進行重力排液。此作用容許自零件及工件籃將溶液排回至製程槽中以減少帶出/節約溶液。 The soaking cycle is determined by the user based on the desired cleaning result. Once the impregnation immersion in the solvent mixture 20 with the jet cleaning effect 26 is completed, the workpiece is lifted to the freeboard region of the machine 32 where it will be allowed to settle for gravity drainage above the tank. This action allows the solution to be drained back into the process tank from the part and the workpiece basket to reduce carry-out/saving of solution.

若需要,可將視需要的壓縮空氣掃掠集管器34(透過電磁閥36藉由用於定位及持續期間之材料處理系統控制)安裝在槽中,以幫助自零件/籃去除流體,因此減少溶液帶出及逸散性排放物。一旦完成此動作,即可將工件自系統12移出及轉移至製程中之下一步驟。 If desired, an optional compressed air sweeping header 34 (controlled by a solenoid valve 36 via a material handling system for positioning and duration) can be installed in the tank to assist in removing fluid from the part/basket, thus Reduce solution carry-over and fugitive emissions. Once this action is completed, the workpiece can be removed from system 12 and transferred to the next step in the process.

於已將工件清潔並自預清潔模組12移出後,將有少量溶液於工件(零件/籃)上帶出。當此等物件被輸送至沖洗脫脂器14中進行該製程循環時,殘留的帶出物將沈積至沖洗脫脂器沸騰池38中。 After the workpiece has been cleaned and removed from the pre-cleaning module 12, a small amount of solution is carried over the workpiece (parts/basket). When such items are delivered to the rinsing degreaser 14 for the process cycle, residual carry-over will be deposited into the rinsing degreaser boiling tank 38.

因此,清潔模組12中之溶液液位將開始隨時間而減少體積。為維持正常的溶液操作液位,透過抽吸軟管42將輸送泵40連接至原始溶液容器44。 Therefore, the solution level in the cleaning module 12 will begin to decrease in volume over time. To maintain a normal solution operating level, the transfer pump 40 is coupled to the original solution container 44 via a suction hose 42.

標準的輸送泵40係氣動泵,及當開啟手動操作的壓縮空氣供給閥46時,此泵將自容器44拉引新溶液及將其轉移至預清潔模組浸泡池18中。此轉移泵40係由操作人員根據操作人員定期觀察得之模組槽12中之液位手動控制。化學組成亦可作為選項自動進行。 第2階段沖洗脫脂器製程循環:於自預清潔模組12移出工件後,將其轉移至沖洗脫脂器14進行第二清潔/沖洗製程。一旦其在脫脂器14上方降入至脫脂器槽46中,在此其暴露至熱溶劑蒸氣48進行「預浸漬」作用,同時向下轉移至沸騰池38中。工件向下轉移且浸泡於脫脂器之沸騰室38中。此室中之沸騰溶劑自零件表面移除任何殘留的污染物及殘留溶劑合劑。由室38中之沸騰溶劑所產生之擾流產生機械作用來洗滌零件以提昇清潔製程。 The standard transfer pump 40 is a pneumatic pump, and when the manually operated compressed air supply valve 46 is opened, the pump will draw a new solution from the container 44 and transfer it to the pre-cleaning module soaking tank 18. The transfer pump 40 is manually controlled by an operator based on the liquid level in the module tank 12 that the operator periodically observes. The chemical composition can also be automated as an option. Stage 2 Flush Degreaser Process Cycle: After the workpiece has been removed from the pre-cleaning module 12, it is transferred to the rinse degreaser 14 for a second cleaning/rinsing process. Once it has been lowered into the degreaser tank 46 above the degreaser 14, it is exposed to the hot solvent vapor 48 for "pre-impregnation" while being transferred downward into the boiling tank 38. The workpiece is transferred downward and immersed in the boiling chamber 38 of the degreaser. The boiling solvent in this chamber removes any residual contaminants and residual solvent mixture from the surface of the part. The turbulence generated by the boiling solvent in chamber 38 creates a mechanical action to wash the part to enhance the cleaning process.

另外,脫脂器可於沸騰池38中具有超音波或其他攪動能力。熟悉技藝人士可將其他添加劑納入至沖洗劑中,以改良諸如(但不限於)混溶性、沸點、溶劑合特性、及共沸物或類似共沸物行為的期望性質。 Additionally, the degreaser can have ultrasonic or other agitation capabilities in the boiling pool 38. Those skilled in the art can incorporate other additives into the rinsing agent to modify desirable properties such as, but not limited to, miscibility, boiling point, solvation characteristics, and azeotrope or azeotrope-like behavior.

依照基板、黏附污物之性質、所使用溶劑系統之類型、及於製程室中使用之機械作用之類型(超音波/噴流清洗/擾流等等),將工件處理預定時間長度後,將工件自沸騰池38提起,轉移至蒸氣管線(其係介於蒸氣區48與乾舷區54之間之主冷凝器螺管52的垂直中點)下方,及於機器之沖洗池50中於純化沖洗溶劑中浸泡歷時第二總浸泡以提昇工件清潔度。 Depending on the substrate, the nature of the adhering dirt, the type of solvent system used, and the type of mechanical action used in the process chamber (ultrasonic/jet cleaning/spoiler, etc.), the workpiece is processed for a predetermined length of time and the workpiece is processed. Lifted from the boiling tank 38, transferred to a vapor line (which is below the vertical midpoint of the main condenser coil 52 between the vapor zone 48 and the freeboard zone 54), and in the washing tank 50 of the machine for purification and rinsing The second total immersion is immersed in the solvent to improve the cleanliness of the workpiece.

當沖洗循環完成時,將工件自液體提升出且使其於蒸氣區48中停留以進行排液停留。過量的沖洗溶劑將藉由重力自零件/籃排液及落回至沖洗槽中以節約溶劑。在此,工件藉由暴露至純的清潔溶劑蒸氣48再加熱以達成最終冷凝液沖洗及乾燥效應。 When the flush cycle is complete, the workpiece is lifted from the liquid and allowed to stay in the vapor zone 48 for draining. Excessive flushing solvent will drain from the parts/basket by gravity and fall back into the rinse tank to save solvent. Here, the workpiece is reheated by exposure to pure cleaning solvent vapor 48 to achieve a final condensate rinse and drying effect.

當冷凝液沖洗完成時,將工件提升至機器之乾舷區54中,在此將使其停留相當於冷凝液沖洗/乾燥時間之三分之一的時間 或延長時間,以減少任何的殘留沖洗溶劑帶出,因此節約沖洗溶劑。 When the condensate rinse is complete, the workpiece is lifted into the machine's freeboard area 54 where it will remain for one-third of the condensate rinse/dry time Or extend the time to reduce any residual rinse solvent, thus saving the rinse solvent.

一旦此步驟完成,即可將工件自脫脂器14移出及視需要以新的待加工工件重複製程。 Once this step is completed, the workpiece can be removed from the degreaser 14 and re-replicated with a new workpiece to be machined as needed.

第3階段微蒸餾器製程循環: Stage 3 micro-distillator process cycle:

當工件於脫脂器14中沖洗時,藉由溶劑合劑自產品去除之污染物的質量開始於沸騰池38中隨時間增加。為將溶劑純度值保持在可接受範圍內以不致影響清潔及/或沖洗能力及蒸氣產生容量,需定期地自沸騰池38去除污染物。 When the workpiece is rinsed in the degreaser 14, the mass of contaminants removed from the product by the solvent mixture begins to increase in the boiling pool 38 over time. To maintain the solvent purity value within an acceptable range so as not to affect cleaning and/or rinsing capabilities and vapor generation capacity, it is desirable to periodically remove contaminants from the boiling tank 38.

此係藉由使用溶劑蒸餾系統來完成。「微蒸餾器」16連接至脫脂器沸騰池38,以連續低體積地蒸餾受污染的沖洗溶劑。 This is done by using a solvent distillation system. The "microstiller" 16 is connected to a degreaser boiling tank 38 to continuously distill the contaminated rinse solvent in a low volume.

微蒸餾器16定期地自藉由蒸餾器液位控制器58控制之輸送泵56接受受污染的沖洗溶劑。蒸餾器容器係藉由加熱器60加熱以蒸發混合物之內部溶劑部分。黏附污物/污染物通常將不會基於用於沖洗溶劑之溶劑類型而在所應用的較低溫設計範圍內蒸發,且因此將在熱沖洗溶劑蒸氣上升時殘留於容器中及透過蒸氣遷移至外部熱交換器/冷凝器62而離開。 The micro distiller 16 periodically receives the contaminated rinsing solvent from the transfer pump 56 controlled by the distiller level controller 58. The distiller vessel is heated by a heater 60 to evaporate the internal solvent portion of the mixture. Adhesive contaminants/contaminants will generally not evaporate within the lower temperature design range applied based on the type of solvent used to rinse the solvent, and will therefore remain in the container as the hot rinse solvent vapor rises and migrate to the outside through the vapor The heat exchanger/condenser 62 leaves.

此空氣冷卻外部冷凝器62降低熱溶劑蒸氣溫度,使其變為液體,在此其藉由重力排液且經由管件流至相連的脫脂器14。經蒸餾/回收之沖洗劑之流動經引導至脫脂器沸騰池38中以與現有溶劑摻和,在此其於正常脫脂器作用期間蒸發。 This air-cooled external condenser 62 lowers the temperature of the hot solvent vapor to become a liquid, where it is drained by gravity and flows through the tube to the associated degreaser 14. The flow of the distilled/recovered rinsing agent is directed to a degreaser boiling tank 38 for blending with existing solvents where it evaporates during normal dehumidifier action.

在標準設計中,文中所述之微蒸餾器及組件係裝在如圖1所示之預清潔模組10的艙室中。 In a standard design, the microdistillers and components described herein are housed in the compartment of the pre-cleaning module 10 as shown in FIG.

自動傾卸特徵: Automatic dumping features:

基於蒸餾器容器16之所選製程參數,將定期啟動蒸餾 器熬煮,而不使其他受污染的沖洗劑進入微蒸餾器容器16。輸送泵56自動地鎖住。微蒸餾器容器16中之現存流體將持續經加熱器60加熱,直至大部分/高產量的可回收沖洗溶劑經排除為止。製程參數將下列因素列入考慮:使用溶劑、自再循環沖洗溶劑流移除之污染物/黏附污物的類型及體積、系統操作之經過時間、基於所處理基板種類/污染物/黏附污物種類之污染物/黏附污物負載量的變化、終端使用者基於期望溶劑純度值對微蒸餾器熬煮的偏好、及基板清潔度。 Based on the selected process parameters of the retort vessel 16, the distillation will be initiated periodically The kettle is boiled without passing other contaminated rinsing agents into the micro distiller container 16. The transfer pump 56 is automatically locked. The existing fluid in the micro distiller vessel 16 will continue to be heated by the heater 60 until most of the high yield recyclable rinse solvent is removed. Process parameters take into account the following factors: the use of solvents, the type and volume of contaminants removed from the recirculating rinse solvent stream, the elapsed time of system operation, based on the type of substrate being processed / contaminants / adhering dirt Changes in the type of contaminant/adhesive contaminant loading, the end user's preference for micro-distiller cooking based on the desired solvent purity value, and substrate cleanliness.

一旦監測裝置達到預設條件,則加熱器60將被停止供電及底部傾卸電磁閥64將被供電而「開啟」。此底部閥64經可撓性管件66連接至廢棄物容器68,該廢棄物容器68接受蒸餾器「底部殘留液」用於由消費者作定期適當處置。 Once the monitoring device reaches the preset condition, the heater 60 will be powered off and the bottom dump solenoid valve 64 will be powered "on". The bottom valve 64 is connected to the waste container 68 via a flexible tube 66 which receives the "bottom residual liquid" of the distiller for regular disposal by the consumer.

一旦自動傾卸循環經完成預定時段,則底部閥64將自動關閉。程式隨後將藉由透過輸送泵56再填充微蒸餾器容器16而重新開始正常操作。一旦由液位感測器58所測定,容器液位處在正常操作液位,則泵56將被停止供電且隨後加熱器60將被供電而使微蒸餾器16回復至正常操作。 Once the automatic dump cycle has completed a predetermined period of time, the bottom valve 64 will automatically close. The program will then resume normal operation by refilling the micro distiller container 16 through the transfer pump 56. Once the container level is at the normal operating level as determined by the level sensor 58, the pump 56 will be de-energized and then the heater 60 will be powered to return the micro-stiller 16 to normal operation.

一旦微蒸餾器16達成加熱及產生蒸氣,則輸送泵56將視需要循環而用來自脫脂器沸騰池38之受污染的沖洗溶劑再填充蒸餾器。 Once the micro-distiller 16 has reached heating and steam generation, the transfer pump 56 will circulate as needed to refill the distiller with the contaminated rinsing solvent from the degreaser boiling tank 38.

此設計自動控制微蒸餾器操作、熬煮、及傾卸循環,同時使操作人員與製程隔離。此功能展現在用於製程監控的HMI螢幕上。 This design automatically controls the operation of the microstiller, cooking, and dumping cycles while isolating the operator from the process. This feature is displayed on the HMI screen for process monitoring.

微蒸餾器B溶劑循環: Micro distiller B solvent cycle:

同時地,當微蒸餾器處理來自脫脂器沸騰池之受污染的沖洗溶劑時,沖洗溶劑自脫脂器循環至微蒸餾器回到脫脂器,而有少 量隨蒸餾器底部殘留液定期地棄置。將有特定量的沖洗溶劑連同溶劑合劑及經由上述「自動傾卸」循環自蒸餾器定期去除之黏附污物/污染物保持懸浮。 Simultaneously, when the micro distiller processes the contaminated rinsing solvent from the degreaser boiling tank, the rinsing solvent circulates from the degreaser to the micro distiller back to the degreaser, with less The amount is periodically discarded with the residual liquid at the bottom of the distiller. A specific amount of rinsing solvent is maintained in suspension together with the solvent mixture and the adherent soil/contaminants periodically removed from the distiller via the "automatic dumping" cycle described above.

微蒸餾器容器液體體積當自脫脂器供給時將經自動控制。因此,脫脂器沸騰池將需視操作時數、所處理零件/籃之類型/尺寸/組態、及蒸餾器傾卸循環而定期補充溶劑。 The micro distiller container liquid volume will be automatically controlled when supplied from the degreaser. Therefore, the degreaser boiling tank will periodically replenish the solvent depending on the operating hours, the type/size/configuration of the parts/basket being processed, and the retort dump cycle.

溶劑流程之概述: Overview of the solvent process:

參照圖2,將看到在第1階段處,將工件浸泡於溶劑合劑中,引入原始溶劑以及經使用並過濾的溶劑。然後使工件移至第2階段,在此其於蒸氣及液體沖洗劑中經歷沖洗及額外清潔。 Referring to Figure 2, it will be seen that at stage 1, the workpiece is immersed in a solvent mixture, the original solvent is introduced, and the solvent used and filtered. The workpiece is then moved to stage 2 where it undergoes rinsing and additional cleaning in the vapor and liquid rinsing agent.

被帶出的溶劑合劑及黏附污物以及沖洗劑被送至微蒸餾器單元,此單元將低沸點的沖洗劑與高沸點的溶劑合劑及其他污染物熱分離。濃縮進入的受污染之沖洗劑,以減少廢棄物流中之物質量。 The solvent mixture and adherent dirt and rinsing agent that is carried out are sent to a micro distiller unit which thermally separates the low boiling rinsing agent from the high boiling solvent mixture and other contaminants. Concentrate the incoming contaminated rinsing agent to reduce the quality of the waste stream.

使蒸發的沖洗劑凝結及回到氣相脫脂器沸騰池。將主要為溶劑合劑及經去除污物之濃縮的蒸餾器底部殘留液轉移至廢棄物容器作為生態上可接受的處置。 The evaporated rinsing agent is condensed and returned to the gas phase dehumidifier boiling tank. The condensate bottoms, which are primarily a solvent mixture and a decontaminated concentrate, are transferred to a waste container as an ecologically acceptable treatment.

應瞭解本發明不欲受文中陳述之說明性具體例及實施例不當地限制,且該等實施例及具體例僅係提出作為實例。在實施例中,所有百分比係重量百分比。 It is to be understood that the present invention is not intended to be limited by the particular embodiments and examples disclosed herein. In the examples, all percentages are by weight.

實施例1: Example 1:

為證明自沖洗劑分離清潔劑之效率,將沖洗脫脂器填充2,3-二氫十氟戊烷及使其於54℃(約129℉)下沸騰。啟動微蒸餾器且程式控制受污染之沖洗溶劑的添加至微蒸餾器及微蒸餾器之溫度。每小時將250毫升份量之主要由四氫呋喃甲醇、連同活化劑、表面活性劑、 及腐蝕抑制劑組成之溶劑合劑(其調配物與美國專利第5,128,057號一致)添加至沖洗劑。此250毫升份量較當清潔PCB時預期將被帶出之溶劑合劑的體積大25倍。沸騰池中在添加溶劑合劑之前及之後之沖洗劑的氣相層析樣本主要由四氫呋喃甲醇、連同活化劑、表面活性劑、及腐蝕抑制劑所組成,其調配物與美國專利第5,128,057號、以及來自微蒸餾器之餾出液及來自微蒸餾器之底部殘留液一致。微蒸餾器可將黏附污物及主要由四氫呋喃甲醇、連同活化劑、表面活性劑、及腐蝕抑制劑所組成之溶劑合劑(其調配物與美國專利第5,128,057號一致)濃縮至低於2重量%之純度,沖洗劑之污染顯著地降低當將此等蒸餾器底部殘留液作為廢棄物棄置時將被棄置之有價值沖洗劑的量。來自微蒸餾器之餾出液基本上為純的沖洗劑(低於1重量%之溶劑合劑及黏附污物污染),證實微蒸餾器確實有效地自沖洗劑移除溶劑合劑及黏附污物。 To demonstrate the efficiency of separating the cleaning agent from the rinsing agent, the rinsing degreaser was filled with 2,3-dihydrodecafluoropentane and allowed to boil at 54 ° C (about 129 ° F). The micro-distillator is activated and the program controls the temperature of the addition of the contaminated rinse solvent to the micro-distillator and the micro-distillator. 250 ml parts per hour mainly consisting of tetrahydrofuran methanol, together with activators, surfactants, A solvent mixture of a corrosion inhibitor (the formulation of which is identical to U.S. Patent No. 5,128,057) is added to the rinsing agent. This 250 ml portion is 25 times larger than the volume of the solvent mixture that is expected to be carried out when the PCB is cleaned. The gas chromatographic sample of the rinsing agent in the boiling pool before and after the addition of the solvent mixture is mainly composed of tetrahydrofuran methanol, together with an activator, a surfactant, and a corrosion inhibitor, and the formulation thereof is combined with U.S. Patent No. 5,128,057, The distillate from the microstiller and the bottom residue from the microstiller are identical. The micro-distillator can concentrate the adhering dirt and a solvent mixture mainly composed of tetrahydrofuran methanol, together with an activator, a surfactant, and a corrosion inhibitor (the formulation of which is consistent with U.S. Patent No. 5,128,057) to less than 2% by weight. The purity, rinsing agent contamination significantly reduces the amount of valuable rinsing agent that will be disposed of when the bottoms of the distiller are disposed of as waste. The distillate from the microstillator is essentially a pure rinsing agent (less than 1% by weight of solvent mixture and adherent dirt contamination), confirming that the micro distiller is indeed effective in removing solvent mixture and adhering dirt from the rinsing agent.

實施例2: Example 2:

為進一步說明可在此製程中使用之各種清潔劑及溶劑合劑,將沖洗脫脂器填充乙基九氟丁基醚及使其於78℃(約172℉)下沸騰。啟動微蒸餾器且程式控制受污染之沖洗溶劑的添加至微蒸餾器及微蒸餾器之溫度。每小時250毫升份量之主要由3-甲氧基-3-甲基-1-丁醇、與少量四氫呋喃甲醇、表面活性劑、活化劑、及腐蝕抑制劑組成之溶劑合劑(其調配物與Doyel等人之美國專利第6,130,195號一致)。沸騰池中在添加溶劑合劑前及後之沖洗劑的氣相層析樣本主要由3-甲氧基-3-甲基-1-丁醇、與少量四氫呋喃甲醇、表面活性劑、活化劑、及腐蝕抑制劑、以及來自微蒸餾器之餾出液及來自微蒸餾器之底部殘留液所組成。微蒸餾器可將黏附污物及主要由3-甲氧基-3-甲基-1-丁醇、與少量四氫呋喃甲醇、表面活性劑、活化劑、及腐蝕抑制劑所組 成之溶劑合劑濃縮至低於2重量%之純度,沖洗劑之污染顯著地降低當將此等蒸餾器底部殘留液作為廢棄物棄置時將被棄置之有價值沖洗劑的量。來自微蒸餾器之餾出液基本上為純的沖洗劑(低於1重量%之溶劑合劑及黏附污物污染),證實微蒸餾器確實有效地自沖洗溶劑分離溶劑合劑及黏附污物。 To further illustrate the various cleaners and solvent combinations that can be used in this process, the rinse degreaser is filled with ethyl nonafluorobutyl ether and allowed to boil at 78 ° C (about 172 ° F). The micro-distillator is activated and the program controls the temperature of the addition of the contaminated rinse solvent to the micro-distillator and the micro-distillator. a 250 ml portion of a solvent mixture consisting essentially of 3-methoxy-3-methyl-1-butanol, a small amount of tetrahydrofuran methanol, a surfactant, an activator, and a corrosion inhibitor (the formulation and Doyel) U.S. Patent No. 6,130,195, et al. The gas chromatographic sample of the rinsing agent before and after the addition of the solvent mixture in the boiling pool is mainly composed of 3-methoxy-3-methyl-1-butanol, a small amount of tetrahydrofuran methanol, a surfactant, an activator, and A corrosion inhibitor, and a distillate from the microstillator and a bottom liquid from the microstiller. The micro-distillator can adhere to the soil and is mainly composed of 3-methoxy-3-methyl-1-butanol, a small amount of tetrahydrofuran methanol, a surfactant, an activator, and a corrosion inhibitor. The resulting solvent mixture is concentrated to a purity of less than 2% by weight, and the contamination of the rinsing agent significantly reduces the amount of valuable rinsing agent that will be disposed of when the bottom liquid of the distiller is disposed of as waste. The distillate from the microstillator is essentially a pure rinsing agent (less than 1% by weight of solvent mixture and adherent dirt contamination), confirming that the micro distiller does effectively separate the solvent mixture from the solvent and adhere to the soil.

雖然已展示及說明本發明之目前較佳具體例,但應清楚明瞭本發明並不受限於此,而係可以其他不同方式在以下申請專利範圍之範疇內具體實施。熟悉技藝人士當明瞭不脫離本發明之範疇及精神之本發明的各種修改及變化。 While the present invention has been shown and described, it is understood that the invention is not limited thereto, but may be embodied in other different ways within the scope of the following claims. Various modifications and alterations of the present invention will be apparent to those skilled in the art.

10‧‧‧雙溶劑清潔系統 10‧‧‧Double Solvent Cleaning System

12‧‧‧預清潔模組槽 12‧‧‧Pre-cleaning module slot

14‧‧‧沖洗脫脂器 14‧‧‧ Flushing degreaser

16‧‧‧微蒸餾器 16‧‧‧Microstiller

18‧‧‧浸泡室 18‧‧‧Infusion room

20‧‧‧溶劑合劑 20‧‧‧ solvent mixture

22‧‧‧電浸入式加熱器 22‧‧‧Electric immersion heater

24‧‧‧恆溫控制器 24‧‧‧ thermostat controller

26‧‧‧噴流清洗作用;浸泡噴霧集管器 26‧‧‧Spray cleaning; soaking spray collector

28‧‧‧密封泵 28‧‧‧Seal pump

30‧‧‧過濾系統 30‧‧‧Filter system

32‧‧‧機器 32‧‧‧ Machine

34‧‧‧壓縮空氣掃掠集管器 34‧‧‧Compressed air sweeping collector

36‧‧‧電磁閥 36‧‧‧Solenoid valve

38‧‧‧沖洗脫脂器沸騰池 38‧‧‧ Flushing degreaser boiling pool

40‧‧‧輸送泵 40‧‧‧Transport pump

42‧‧‧抽吸軟管 42‧‧‧ suction hose

44‧‧‧原始溶液容器 44‧‧‧Original solution container

46‧‧‧壓縮空氣供給閥,脫脂器槽 46‧‧‧Compressed air supply valve, degreaser tank

48‧‧‧熱溶劑蒸氣 48‧‧‧Hot solvent vapour

50‧‧‧沖洗池 50‧‧‧washing pool

52‧‧‧主冷凝器螺管 52‧‧‧Main condenser coil

54‧‧‧乾舷區 54‧‧‧Floating area

56‧‧‧輸送泵 56‧‧‧Transport pump

58‧‧‧蒸餾器液位控制器 58‧‧‧Distiller level controller

60‧‧‧加熱器 60‧‧‧heater

62‧‧‧外部熱交換器/冷凝器 62‧‧‧External heat exchanger/condenser

64‧‧‧底部傾卸電磁閥 64‧‧‧Bottom dumping solenoid valve

66‧‧‧可撓性管件 66‧‧‧Flexible fittings

68‧‧‧廢棄物容器 68‧‧‧Waste container

Claims (5)

一種用於自精密組件清潔污染物之裝置,其特徵在於其包括:a.裝有自該精密組件去除污染物之經加熱溶劑合劑的預清潔模組槽,b.作為裝有自該精密組件去除殘留溶劑合劑及黏附污物之沖洗劑之沖洗槽的氣相脫脂器,及c.自該沖洗劑分離該殘留溶劑合劑及黏附污物,將該沖洗劑引導回至該沖洗槽,及將該等殘留溶劑合劑及污染物引導至廢棄物處置之微蒸餾器。 A device for cleaning contaminants from a precision component, comprising: a. a pre-cleaning module tank containing a heated solvent mixture for removing contaminants from the precision component, b. as being mounted from the precision component a gas phase degreaser for removing the residual solvent mixture and the rinsing agent for adhering the dirt, and c. separating the residual solvent mixture and adhering dirt from the rinsing agent, guiding the rinsing agent back to the rinsing tank, and The residual solvent mixture and contaminants are directed to a microdistiller for waste disposal. 如申請專利範圍第1項之裝置,其中,該沖洗槽係操作性地連接至該微蒸餾器,以傳送來自該預清潔模組槽之受溶劑合劑及殘留污染物污染之沖洗劑及將沖洗劑傳送回至該沖洗槽。 The apparatus of claim 1, wherein the rinsing tank is operatively coupled to the micro distiller to deliver a rinsing agent contaminated with a solvent mixture and residual contaminants from the pre-cleaning module tank and to rinse The agent is delivered back to the rinse tank. 一種用於在清潔電子及其他組件之系統中自沖洗溶劑連續分離污染物之方法,其特徵在於其包括:a.在獨立的沖洗槽中利用沖洗溶劑處理已經過溶劑合劑處理之受污染基板,以去除任何殘留的污染物及殘留溶劑合劑,藉此將自該組件去除之污染物收集於該沖洗槽中;及b.將受污染的沖洗溶劑自該沖洗槽移至微蒸餾器,以自該沖洗溶劑中分離該等污染物,將該沖洗劑引導回至該沖洗槽,及將該等殘留溶劑合劑及污染物引導至廢棄物處置。 A method for continuously separating contaminants from a rinse solvent in a system for cleaning electronic and other components, characterized in that it comprises: a. treating a contaminated substrate that has been treated with a solvent mixture by a flushing solvent in a separate rinse tank, To remove any residual contaminants and residual solvent mixture, thereby collecting contaminants removed from the assembly in the rinsing tank; and b. moving the contaminated rinsing solvent from the rinsing tank to the micro distiller to The rinsing solvent separates the contaminants, directs the rinsing agent back to the rinsing tank, and directs the residual solvent mixture and contaminants to waste disposal. 一種清潔精密組件之方法,其特徵在於其包括:a.將該組件浸泡在置於預清潔模組槽中之經加熱溶劑合劑中,因而去除黏附污染物;b.在獨立的沖洗脫脂器中用沖洗溶劑處理該組件以去除任何殘留 的污染物及殘留溶劑合劑,藉此將自該組件去除之污染物收集於該沖洗脫脂器中;及c.將受污染的沖洗溶劑自該沖洗脫脂器移至微蒸餾器,以自該沖洗溶劑分離該等污染物及將該沖洗溶劑引導至該沖洗脫脂器。 A method of cleaning a precision component, comprising: a. immersing the component in a heated solvent mixture placed in a pre-cleaning module tank to thereby remove adhering contaminants; b. in a separate rinse degreaser Treat the assembly with a rinse solvent to remove any residue a contaminant and residual solvent mixture whereby the contaminants removed from the assembly are collected in the rinse degremer; and c. the contaminated rinse solvent is transferred from the rinse deliter to the microdistiller to be flushed therefrom The solvent separates the contaminants and directs the rinsing solvent to the rinsing degreaser. 如申請專利範圍第4項之方法,其中,該利用沖洗劑處理該組件之步驟包括:d.藉由將該組件暴露至置於沖洗脫脂器中之沖洗劑的熱蒸氣來使該組件經歷預浸漬作用;e.將該組件浸泡在置於沸騰池中之沸騰沖洗劑中,因而去除任何殘留的黏附污物及殘留溶劑合劑;及f.將該組件自該沸騰池移出及將該組件浸泡在置於沖洗室中之純化沖洗溶劑中。 The method of claim 4, wherein the step of treating the component with a rinsing agent comprises: d. subjecting the component to a pre-exposure by exposing the component to a hot vapor of a rinsing agent disposed in the rinsing degreaser Immersion; e. immersing the assembly in a boiling rinse placed in a boiling tank to remove any residual adhering dirt and residual solvent mixture; and f. removing the assembly from the boiling pool and soaking the assembly In a purification rinse solvent placed in the rinse chamber.
TW102128956A 2012-08-20 2013-08-13 Method and apparatus for continuous separation of cleaning solvent from rinse fluid in a dual-solvent vapor degreasing system TW201414550A (en)

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