TW201333124A - Wall mildew resist material and producing method thereof - Google Patents
Wall mildew resist material and producing method thereof Download PDFInfo
- Publication number
- TW201333124A TW201333124A TW101104297A TW101104297A TW201333124A TW 201333124 A TW201333124 A TW 201333124A TW 101104297 A TW101104297 A TW 101104297A TW 101104297 A TW101104297 A TW 101104297A TW 201333124 A TW201333124 A TW 201333124A
- Authority
- TW
- Taiwan
- Prior art keywords
- montmorillonite
- cellulose
- inhibiting material
- wall cancer
- production inhibiting
- Prior art date
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
Description
本發明係涉及一種壁癌生成之抑制材料及其製造方法。The present invention relates to a suppressing material for wall cancer formation and a method for producing the same.
壁癌是每個屋主難以擺脫的夢靨。壁癌不僅會影響建築物的外觀，嚴重的壁癌將會腐蝕鋼筋混泥土的結構，輕則造成牆壁成塊脫落而砸傷住戶，嚴重者則影響建築物的整體構造。Wall cancer is a nightmare that every homeowner can hardly get rid of. Wall cancer not only affects the appearance of the building, but serious wall cancer will corrode the structure of the reinforced concrete, which will cause the wall to fall off and cause damage to the household. In severe cases, the overall structure of the building will be affected.
既有的油漆用於防制壁癌生成之成效非常不顯著，而專有用於牆面龜裂部位之防水、防漏之材料則通常以非天然或化學合成之防水材料製成，其不僅可能對環境造成危害，更可能影響人體健康。The effect of existing paints on the prevention of wall cancer formation is very insignificant, while the waterproof and leakproof materials that are exclusively used for wall cracking are usually made of non-natural or chemically synthesized waterproof materials, which are not only possible Harm to the environment and more likely to affect human health.
為解決既有之油漆壁癌防治效能不佳，且相關的壁癌防治材料通常為對人體有害物質組成而對人體造成不良影響之技術問題，本發明作之目的在於提出可塗佈於牆表面，以防制牆表面生成壁癌之壁癌防制材料，藉以解決既有技術之諸多缺點，更達到良好的壁癌防治功效。In order to solve the problem that the existing paint wall cancer prevention and treatment performance is not good, and the related wall cancer prevention and treatment materials are usually technical problems that have adverse effects on the human body, the object of the present invention is to propose coating on the wall surface. In order to prevent the wall surface of the wall from forming wall cancer prevention materials, to solve the shortcomings of the existing technology, and to achieve good wall cancer prevention and treatment.
本發明提供一種壁癌生成抑制材料，其為包含改質蒙脫土及天然纖維素之混和物。The present invention provides a wall cancer production inhibiting material which is a mixture comprising modified montmorillonite and natural cellulose.
其中，該改質蒙脫土為比未改質蒙脫土具有相對較高之層間距之蒙脫土。Among them, the modified montmorillonite is a montmorillonite having a relatively high interlayer spacing than the unmodified montmorillonite.
其中，該天然纖維素之含量比例介於為90~10wt%；該蒙脫土之比例範圍為10~90wt%。Wherein, the content ratio of the natural cellulose is between 90 and 10% by weight; and the ratio of the montmorillonite is in the range of 10 to 90% by weight.
其中，該天然纖維素係選自於由纖維素、甲基纖維素、乙基纖維素、醋酸纖維素、氫氧乙基纖維素及其混和物所組成的群組。Wherein the natural cellulose is selected from the group consisting of cellulose, methyl cellulose, ethyl cellulose, cellulose acetate, hydroxyethyl cellulose, and mixtures thereof.
其中，該改質蒙脫土係為與一有機改質劑聚合而產生層間距擴張的改質蒙脫土。Wherein, the modified montmorillonite is a modified montmorillonite which is polymerized with an organic modifier to cause a layer spacing expansion.
其中，該改質蒙脫土之層間距為40A±10A。Wherein, the layer spacing of the modified montmorillonite is 40A±10A.
本發明再提出一種壁癌生成抑制材料之製造方法，其製程步驟包含：以物理或化學方法將一蒙脫土改質以產生具有相對較寬層間距之一改質蒙脫土；取一天然纖維素以一特定比例與該改質蒙脫土於水相環境下混合或聚合。The invention further provides a method for manufacturing a wall cancer formation inhibiting material, the process step comprising: physically or chemically modifying a montmorillonite to produce a modified montmorillonite having a relatively wide layer spacing; taking a natural fiber The mixture is mixed or polymerized with the modified montmorillonite in an aqueous phase at a specific ratio.
其中，該蒙脫土係先以一陽離子型介面活性劑將蒙脫土的表面予以改質，再將該蒙脫土與一有機改質劑聚合，形成具有擴張層間距之該改質蒙脫土。Wherein, the montmorillonite system firstly modifies the surface of the montmorillonite with a cationic surfactant, and then polymerizes the montmorillonite with an organic modifier to form the modified montmorillonite having an expanded layer spacing. earth.
其中，該陽離子型介面活性劑為十六烷基三甲基溴化銨，該有機改質劑係選自於由甲基丙烯酸甲酯、苯乙烯及其混合物或聚合物所組成的群組；該天然纖維素係選自於由纖維素、甲基纖維素、乙基纖維素、醋酸纖維素、氫氧乙基纖維素及其混和物所組成的群組。Wherein the cationic surfactant is cetyltrimethylammonium bromide, and the organic modifier is selected from the group consisting of methyl methacrylate, styrene, and mixtures or polymers thereof; The natural cellulose is selected from the group consisting of cellulose, methyl cellulose, ethyl cellulose, cellulose acetate, hydroxyethyl cellulose, and mixtures thereof.
其中，該天然纖維素與該改質蒙脫土的混合比例範圍為9:1~1:9。Wherein, the mixing ratio of the natural cellulose to the modified montmorillonite ranges from 9:1 to 1:9.
基於前述說明可知，本發明具備下列優點：Based on the foregoing description, the present invention has the following advantages:
(1)主要成分取之於天然，其非常符合環保與友善環境之材料使用趨勢。(1) The main ingredients are taken from nature, which is in line with the trend of material use in environmentally friendly and friendly environments.
(2)構造簡單且原料成本低廉，非常合宜於產業利用。(2) The structure is simple and the raw material cost is low, which is very suitable for industrial utilization.
(3)具備優異之附著能力，即便整個浸入水中仍不會脫落，且可以與其他的牆面或水泥表面塗料混合使用。(3) Excellent adhesion, even if it is immersed in water, it can not be peeled off, and can be mixed with other wall or cement surface coatings.
(4)具備優異的與壁癌防制能力。(4) Excellent ability to prevent wall cancer.
本發明之壁癌生成抑制材料，其製造方法包含下列步驟：The wall cancer production inhibiting material of the present invention comprises the following steps:
(step 1)擴大蒙脫土之層間距：取蒙脫土以物理或化學方法將該蒙脫土之層間距擴張。擴張蒙脫土層間距的方式不限定，本實施例係利用一陽離子型介面活性劑(十六烷基三甲基溴化銨，CTAB)先將蒙脫土的表面予以改質，再使改質後的蒙脫土與一有機改質劑聚合，使蒙脫土之間的間隔擴張而形成一改質蒙脫土。經電子顯微鏡與×光繞射儀之驗證可知，經過本實施例的該改質蒙脫土之層間距由未改質之蒙脫土10A左右擴張至40A±10A。(step 1) Enlarge the interlayer spacing of the montmorillonite: Take the montmorillonite to physically or chemically expand the layer spacing of the montmorillonite. The manner of expanding the spacing of the montmorillonite layer is not limited. In this embodiment, the surface of the montmorillonite is modified by a cationic surfactant (Cetyltrimethylammonium bromide, CTAB), and then modified. The montmorillonite after the mass is polymerized with an organic modifier to expand the interval between the montmorillonites to form a modified montmorillonite. It was confirmed by electron microscopy and X-ray diffractometer that the interlayer spacing of the modified montmorillonite in this example was expanded from about 10 A of unmodified montmorillonite to 40 A ± 10 A.
其中，前述的該有機改質劑選自於由甲基丙烯酸甲酯(MMA，分子式為CH2=C(CH3)CO2CH3)、苯乙烯(Styrene)及其混合物或聚合物所組成的群組。Wherein, the aforementioned organic modifier is selected from the group consisting of methyl methacrylate (MMA, molecular formula CH 2 = C(CH 3 )CO 2 CH 3 ), styrene (Styrene), and mixtures or polymers thereof. Group.
本實施例將蒙脫土與甲基丙烯酸甲酯及/或苯乙烯的聚合，目的是使蒙脫土改質而於後列製成步驟更能更均勻的分散在其他高分子添加物之中，使高分子添加物/改質後之蒙脫土所形成之複合材料達到最好的物性，可以得到效能顯著之奈米複合材料。In this embodiment, the polymerization of montmorillonite and methyl methacrylate and/or styrene is carried out, and the purpose is to modify the montmorillonite to be more uniformly dispersed in other polymer additives in the post-column preparation step. The composite material formed by the polymer additive/modified montmorillonite achieves the best physical properties, and a nano composite material with remarkable performance can be obtained.
(step 2)以天然纖維素在水相環境下與擴大層間距之該改質蒙脫土混合及/或聚合：其中，天然纖維素的種類不限定，例如纖維素、甲基纖維素、乙基纖維素、醋酸纖維素、氫氧乙基纖維素或其混和物等等。本實施例使用甲基纖維素以與該改質蒙脫土混合，其加強本實施例實際施做塗佈於牆表面之附著能力。(step 2) mixing and/or polymerizing the modified montmorillonite with natural cellulose in an aqueous phase and an enlarged layer spacing: wherein the type of natural cellulose is not limited, for example, cellulose, methyl cellulose, and B Cellulose, cellulose acetate, hydroxyethylcellulose or mixtures thereof, and the like. This example uses methyl cellulose to be mixed with the modified montmorillonite, which enhances the ability of the present embodiment to be applied to the surface of the wall.
其中，該天然纖維素與該改質蒙脫土的混合比例範圍為9:1~1:9，較佳之比例為9:1~6:4。Wherein, the mixing ratio of the natural cellulose to the modified montmorillonite ranges from 9:1 to 1:9, and the preferred ratio is from 9:1 to 6:4.
(step 3)將水泥外層塗抹此聚合後之複合材料，最後固定溫度下使此複合材料完全批覆在水泥表面。(Step 3) The outer layer of the cement is applied to the polymerized composite material, and finally the composite material is completely coated on the cement surface at a fixed temperature.
實際試驗時，將本實施例塗佈於一水泥塊A表面後，與對照組(未塗佈本實施例)之一水泥塊B同時浸至水中，本實施例之水泥塊A於試驗相同時間(約1週)後，實驗組水泥塊A僅產生非常微量之晶體，而對造組水泥塊B之表面則佈滿大量晶體，其比較結果可如下表一。In the actual test, after applying the present embodiment to the surface of a cement block A, it is immersed in water at the same time as the cement block B of the control group (not coated with the present embodiment), and the cement block A of the present embodiment is tested at the same time. After about 1 week, the cement block A of the experimental group produced only a very small amount of crystals, and the surface of the cement block B was covered with a large amount of crystals, and the comparison results were as shown in Table 1 below.
由實驗結果可知，本實施例確實具備優異的晶體生成抑制效果，應用於水泥抑或鋼筋混泥土構造表面確實具有壁癌抑制生成之效果。From the experimental results, it is understood that the present embodiment does have an excellent crystal formation suppressing effect, and it is applied to the cement or reinforced concrete structure surface to have an effect of suppressing the formation of wall cancer.
基於前述說明可知，本發明具備下列優點：Based on the foregoing description, the present invention has the following advantages:
(1)主要成分取之於天然，其非常符合環保與友善環境之材料使用趨勢。(1) The main ingredients are taken from nature, which is in line with the trend of material use in environmentally friendly and friendly environments.
(2)構造簡單且原料成本低廉，非常合宜於產業利用。(2) The structure is simple and the raw material cost is low, which is very suitable for industrial utilization.
(3)具備優異之附著能力，即便整個浸入水中仍不會脫落，且可以與其他的牆面或水泥表面塗料混合使用。(3) Excellent adhesion, even if it is immersed in water, it can not be peeled off, and can be mixed with other wall or cement surface coatings.
(4)具備優異的與壁癌防制能力。(4) Excellent ability to prevent wall cancer.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW101104297A TWI456011B (en) | 2012-02-10 | 2012-02-10 | Wall mildew resist material and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW101104297A TWI456011B (en) | 2012-02-10 | 2012-02-10 | Wall mildew resist material and producing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201333124A true TW201333124A (en) | 2013-08-16 |
| TWI456011B TWI456011B (en) | 2014-10-11 |
Family
ID=49479403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101104297A TWI456011B (en) | 2012-02-10 | 2012-02-10 | Wall mildew resist material and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TWI456011B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117264285A (en) * | 2023-09-20 | 2023-12-22 | 内蒙古农业大学 | Ethyl cellulose/montmorillonite composite material and application thereof in improving kinematic viscosity of shinyleaf yellowhorn oil |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2005271259B2 (en) * | 2004-08-05 | 2012-01-19 | A.V. Topchiev Institute Of Petrochemical Synthesis | Adhesive composition |
-
2012
- 2012-02-10 TW TW101104297A patent/TWI456011B/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117264285A (en) * | 2023-09-20 | 2023-12-22 | 内蒙古农业大学 | Ethyl cellulose/montmorillonite composite material and application thereof in improving kinematic viscosity of shinyleaf yellowhorn oil |
| CN117264285B (en) * | 2023-09-20 | 2024-05-28 | 内蒙古农业大学 | Ethyl cellulose/montmorillonite composite material and application thereof in improving kinematic viscosity of shinyleaf yellowhorn oil |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI456011B (en) | 2014-10-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101054492B (en) | Multifunctional protection paste for outside wall | |
| CN107522450B (en) | High-flexibility anti-permeability waterproof mortar | |
| CN103086664A (en) | Internal wall putty and production process thereof | |
| CN105130354A (en) | Plastering gypsum and preparation method thereof | |
| EP2603470B1 (en) | Coating agents for producing permanently flexible coatings | |
| Zheng et al. | Biomimetic swallow nest structure: a lightweight and high-strength thermal insulation material | |
| CN106800384B (en) | A kind of composite modified method for improving magnesium oxychloride cementing material performance | |
| CN101062849A (en) | Low-alkalinity composite cracking-against waterproof agent | |
| CN103351691A (en) | Preparation method of environmentally-friendly interior wall putty powder | |
| CN107805020A (en) | A kind of environment-friendly painting coating for being suitable for classroom | |
| EP2619152B1 (en) | Coating agents for producing permanently flexible coatings | |
| CN102276232B (en) | Novel waterproof dry powder coating | |
| CN105130315A (en) | Organic elastic pseudo-fair-faced concrete paint | |
| CN105419447A (en) | Interior wall putty and preparation method thereof | |
| CN105541230B (en) | Imitative stone material dry powder paint and its construction method | |
| CN106966676A (en) | Environmentally friendly water-fast filleting gypsum and preparation method thereof | |
| CN108046687A (en) | A kind of modified cement-based water-repellent paint of graphene | |
| WO2012038302A1 (en) | Coating agents for producing waterproof infrastructure coatings | |
| TW201333124A (en) | Wall mildew resist material and producing method thereof | |
| CN104402375A (en) | Interior decoration mortar | |
| CN105218010A (en) | A kind of dedicated mortar for making aerated bricks | |
| CN104355564A (en) | Dry mixed mortar additive | |
| CN102795827A (en) | Tile interface treating agent and preparation method thereof | |
| CN107056182A (en) | Imitative clear-water concrete aggregate and preparation method thereof | |
| CN110642584A (en) | Light sound-insulation high-elasticity daub and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |