TW201323204A - Housing of electronic apparatus and processing method thereof - Google Patents

Housing of electronic apparatus and processing method thereof Download PDF

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TW201323204A
TW201323204A TW100145107A TW100145107A TW201323204A TW 201323204 A TW201323204 A TW 201323204A TW 100145107 A TW100145107 A TW 100145107A TW 100145107 A TW100145107 A TW 100145107A TW 201323204 A TW201323204 A TW 201323204A
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Taiwan
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coating
electronic device
substrate
device housing
carbon fiber
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TW100145107A
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Chinese (zh)
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fu-sheng Teng
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Acer Inc
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  • Casings For Electric Apparatus (AREA)

Abstract

A housing of an electronic apparatus is disclosed. The housing comprises a base and a coating. The base is manufactured with carbon fiber and comprises an outside surface. The coating is formed on the outside surface of the base, wherein the coating is a saturated solution formed with 60v/v% alcohols added Sodium Bicarbonate. An alkaline environment is formed by the coating to prevent or process a chalking produced on the outside surface of the base.

Description

電子裝置殼體及其處理方法Electronic device housing and processing method thereof

本發明係關於一種電子裝置殼體,特別是一種可防止或解決碳纖維殼體產生白化現象之電子裝置殼體及其處理方法。The invention relates to an electronic device housing, in particular to an electronic device housing capable of preventing or solving the whitening phenomenon of the carbon fiber housing and a processing method thereof.

碳纖維材料在科技產業或電子產品上的應用已成為一種趨勢,由於碳纖維材料具有質地輕而堅硬、抗磨損、耐熱性及耐腐蝕性佳等特性,使得碳纖維材料已成為製造電子產品之殼體的常用材質之一。目前碳纖維材料主要是以碳纖維母材結合環氧樹脂所組成之複合材料,而在其製造過程中,為了降低成本或賦予複合材料之其他特性,通常會在樹脂中加入填充劑或添加劑,例如碳酸鈣、氫氧化鋁、矽酸鹽類等,藉以改善樹脂原本之物理或機械性質。The application of carbon fiber materials in the technology industry or electronic products has become a trend. Because carbon fiber materials have the characteristics of light and hard texture, abrasion resistance, heat resistance and corrosion resistance, carbon fiber materials have become the shell of electronic products. One of the commonly used materials. At present, the carbon fiber material is mainly a composite material composed of a carbon fiber base material combined with an epoxy resin, and in the manufacturing process, in order to reduce the cost or impart other characteristics to the composite material, a filler or an additive such as carbonic acid is usually added to the resin. Calcium, aluminum hydroxide, silicates, etc., to improve the physical or mechanical properties of the resin.

然而在碳纖維殼體固化成型、鍍膜或包裝過程中,若是有汙染物質滲入碳纖維或樹脂中,汙染物質可能會與前述填充劑或添加劑產生化學反應,容易造成碳纖維殼體之白化現象(chalking)。舉例來說,空氣中常帶有酸性物質,例如乙酸(CH3COOH),在碳纖維殼體無法完全隔絕空氣與水氣的狀況下,乙酸等酸性物質將會與碳酸鈣(CaCO3)產生酸化作用而生成白色結晶狀之乙酸鈣(Ca(CH3COO)2),其化學反應式如下:However, in the process of solidification molding, coating or packaging of the carbon fiber casing, if a pollutant is infiltrated into the carbon fiber or the resin, the pollutant may chemically react with the aforementioned filler or additive, which may easily cause chalking of the carbon fiber casing. For example, the air often contains acidic substances, such as acetic acid (CH 3 COOH). Acidic substances such as acetic acid will be acidified with calcium carbonate (CaCO 3 ) in the case where the carbon fiber shell cannot completely block air and moisture. The white crystal form of calcium acetate (Ca(CH 3 COO) 2 ) is formed, and the chemical reaction formula is as follows:

CaCO3+2CH3COOH→Ca(CH3COO)2+H2CO3 (1)CaCO 3 +2CH 3 COOH→Ca(CH 3 COO) 2 +H 2 CO 3 (1)

當碳纖維殼體處於酸性環境下生成乙酸鈣後,即可能產生前述之白化現象,如此將影響碳纖維殼體之結構外觀一致性。When the carbon fiber shell is in an acidic environment to form calcium acetate, the aforementioned whitening phenomenon may occur, which will affect the structural appearance uniformity of the carbon fiber shell.

因此如何能解決碳纖維殼體所產生之白化現象,實為一值得研究的課題。Therefore, how to solve the whitening phenomenon produced by the carbon fiber shell is a subject worthy of study.

本發明之主要目的係在提供一種可防止或解決碳纖維殼體產生白化現象之電子裝置殼體。SUMMARY OF THE INVENTION A primary object of the present invention is to provide an electronic device housing that prevents or resolves the whitening of a carbon fiber housing.

為達到上述之目的,本發明之電子裝置殼體包括基材及塗層。基材係以碳纖維材料製成,基材包括外表面;塗層係形成於基材之外表面,其中塗層為將碳酸氫鈉溶於濃度約60v/v%以上之醇類溶液所形成之飽和溶液。藉由塗層特性可形成鹼性環境,以防止基材遇到酸性物質時產生白化現象或改善基材已生成之白化現象。To achieve the above object, the electronic device housing of the present invention includes a substrate and a coating. The substrate is made of a carbon fiber material, and the substrate comprises an outer surface; the coating is formed on the outer surface of the substrate, wherein the coating is formed by dissolving sodium hydrogencarbonate in an alcohol solution having a concentration of about 60 v/v% or more. saturated solution. An alkaline environment can be formed by the coating property to prevent whitening of the substrate when it encounters an acidic substance or to improve the whitening phenomenon that the substrate has formed.

在本發明之一實施例中,電子裝置殼體更包括保護層,係貼覆於塗層上,使得塗層於基材與保護層之間保持鹼性環境。In an embodiment of the invention, the electronic device housing further includes a protective layer attached to the coating such that the coating maintains an alkaline environment between the substrate and the protective layer.

在本發明之一實施例中,醇類溶液為異丙醇溶液或乙醇溶液,其中醇類溶液之較佳濃度約介於70v/v%至80v/v%之間,且最佳濃度約為75v/v%。In an embodiment of the present invention, the alcohol solution is an isopropyl alcohol solution or an ethanol solution, wherein a preferred concentration of the alcohol solution is between about 70 v/v% and 80 v/v%, and the optimal concentration is about 75v/v%.

本發明更包括前述電子裝置殼體之處理方法,該方法包括以下步驟:提供一碳纖維材料之基材;以及形成一塗層於基材之外表面,其中塗層為將碳酸氫鈉溶於濃度約60v/v%以上之醇類溶液中所形成之飽和溶液。The present invention further includes a method of processing the electronic device housing, the method comprising the steps of: providing a substrate of a carbon fiber material; and forming a coating on the outer surface of the substrate, wherein the coating is to dissolve sodium hydrogencarbonate in the concentration A saturated solution formed in an alcohol solution of about 60 v/v% or more.

在本發明之一實施例中,電子裝置殼體之處理方法更包括以下步驟:貼覆一保護層於塗層上。In an embodiment of the invention, the method of processing the electronic device housing further comprises the step of: attaching a protective layer to the coating.

為能讓 貴審查委員能更瞭解本發明之技術內容,特舉出較佳實施例說明如下。In order to enable the reviewing committee to better understand the technical contents of the present invention, the preferred embodiments are described below.

請參考圖1係本發明之電子裝置殼體1之結構示意圖。在本發明之一實施例中,電子裝置殼體1可應用於可攜式電腦,但亦可應用於其他具備外部殼體之各類電子裝置,例如智慧型手機、個人數位助理、數位相機等,不以本實施例為限。Please refer to FIG. 1 , which is a schematic structural view of an electronic device casing 1 of the present invention. In an embodiment of the present invention, the electronic device housing 1 can be applied to a portable computer, but can also be applied to other electronic devices having an external housing, such as a smart phone, a personal digital assistant, a digital camera, etc. It is not limited to this embodiment.

如圖1所示,本發明之電子裝置殼體1包括基材10及塗層20。基材10係以碳纖維材料製成,此處所指之碳纖維材料主要為包括碳纖維母材及樹脂之複合材料,並可於此複合材料中加入填充劑或添加劑,例如碳酸鈣、氫氧化鋁等,以改善此複合材料之特性;而基材10包括外表面11。As shown in FIG. 1, the electronic device housing 1 of the present invention includes a substrate 10 and a coating 20. The substrate 10 is made of a carbon fiber material, and the carbon fiber material referred to herein is mainly a composite material including a carbon fiber base material and a resin, and a filler or an additive such as calcium carbonate, aluminum hydroxide, or the like may be added to the composite material. To improve the properties of the composite; the substrate 10 includes an outer surface 11.

塗層20係形成於基材10之外表面11上,其中塗層20為將碳酸氫鈉溶於濃度約60v/v%(體積百分比)以上之醇類溶液所形成之飽和溶液,其可藉由噴塗或塗覆方式形成於基材10之外表面11。此飽和溶液之製備方式以水為溶劑,醇類為溶質,依據所設定之濃度將對應體積比例之水和醇類混合,形成濃度約60v/v%以上之醇類溶液,再加入碳酸氫鈉(NaHCO3)使其溶解於製備好之醇類溶液中,以形成飽和溶液。在本發明之一實施例中,此醇類溶液可為異丙醇溶液或乙醇溶液,但亦可採用其他具類似性質之醇類溶液所取代,不以本實施例為限。The coating layer 20 is formed on the outer surface 11 of the substrate 10, wherein the coating layer 20 is a saturated solution formed by dissolving sodium hydrogencarbonate in an alcohol solution having a concentration of about 60 v/v% or more by volume. It is formed on the outer surface 11 of the substrate 10 by spraying or coating. The saturated solution is prepared by using water as a solvent and alcohol as a solute, and mixing the corresponding volume ratio of water and alcohol according to the set concentration to form an alcohol solution having a concentration of about 60 v/v% or more, and then adding sodium hydrogencarbonate. (NaHCO 3 ) is dissolved in the prepared alcohol solution to form a saturated solution. In an embodiment of the present invention, the alcohol solution may be an isopropyl alcohol solution or an ethanol solution, but may be replaced by other alcohol solutions having similar properties, and is not limited to the embodiment.

目前推論碳纖維材料會產生白化現象,起因是基材10在進行固化、鍍膜或包裝過程中,其本身碳纖維材料內所包含之碳酸鈣,與外界之酸性物質發生了如先前技術中式(1)之酸化反應,進而生成白色結晶之乙酸鈣所導致。因此,當基材10已產生白化現象後,藉由塗層20對基材10進行浸濕滲透鹼化處理,使得塗層20中所含之碳酸氫鈉與乙酸鈣產生化學反應,使得乙酸鈣還原成碳酸鈣,並生成乙酸鈉(CH3COONa),其化學反應式如下:At present, it is inferred that carbon fiber material will produce whitening phenomenon. The reason is that the base material 10 is in the process of curing, coating or packaging, and the calcium carbonate contained in the carbon fiber material itself is formed with the external acidic substance as in the prior art (1). The acidification reaction is followed by the formation of white crystal calcium acetate. Therefore, after the substrate 10 has been whitened, the substrate 10 is wetted and alkalized by the coating 20, so that the sodium bicarbonate contained in the coating 20 reacts with calcium acetate to cause calcium acetate. Reduction to calcium carbonate and the formation of sodium acetate (CH 3 COONa), the chemical reaction formula is as follows:

Ca(CH3COO)2+NaHCO3→2CH3COONa+CaCO3 (2)Ca(CH 3 COO) 2 +NaHCO 3 →2CH 3 COONa+CaCO 3 (2)

由於乙酸鈉具有吸濕性,可溶於水和醇類,因此生成之乙酸鈉可藉由塗層20帶出,即可達到去除白化現象之效果。Since sodium acetate is hygroscopic and soluble in water and alcohol, the resulting sodium acetate can be taken out by the coating 20 to achieve the effect of removing whitening.

而在基材10尚未產生白化現象時,藉由塗層20之特性可達到可形成鹼性環境來保護基材10,使得基材10遇到酸性物質或處於酸性環境時,可產生酸鹼中和之效果。When the substrate 10 has not been whitened, the substrate 10 can be protected by the characteristics of the coating 20 to protect the substrate 10, so that the substrate 10 can be acid or alkali when it encounters an acidic substance or is in an acidic environment. And the effect.

在本發明之一實施例中,經反覆試驗以確認塗層20採用不同濃度之醇類溶液時之處理狀態,發現所採用之醇類溶液之較佳濃度約介於70v/v%至80v/v%之間,且其最佳濃度約為75v/v%,可達到快速且良好之去除白化效果。In an embodiment of the present invention, after repeated tests to confirm the treatment state of the coating 20 using different concentrations of the alcohol solution, it is found that the preferred concentration of the alcohol solution used is about 70 v/v% to 80 v/ Between v%, and its optimum concentration is about 75v/v%, a fast and good whitening effect can be achieved.

請參考圖2係本發明之電子裝置殼體1a另一實施例之結構示意圖。如圖2所示,在本發明之另一實施例中,電子裝置殼體1a更包括保護層30,係貼覆於塗層20上。由於塗層20本身主要為醇類溶液,若電子裝置殼體1a放置在一般環境條件下,醇類溶液會被揮發蒸散掉而使得塗層20失去原本之特性,因此藉由保護層30提供塗層20隔離效果,使得塗層20於基材10與保護層30之間保持鹼性環境。在本發明之一實施例中,保護層30可為PET膜,但保護層30亦可採用其他具類似隔離效果之物件所取代,本發明不以此為限。2 is a schematic structural view of another embodiment of the electronic device housing 1a of the present invention. As shown in FIG. 2, in another embodiment of the present invention, the electronic device housing 1a further includes a protective layer 30 attached to the coating 20. Since the coating 20 itself is mainly an alcohol solution, if the electronic device housing 1a is placed under normal environmental conditions, the alcohol solution is volatilized and evaporated to cause the coating 20 to lose its original characteristics, so that the coating layer 30 is provided. The layer 20 is isolated so that the coating 20 remains in an alkaline environment between the substrate 10 and the protective layer 30. In an embodiment of the present invention, the protective layer 30 may be a PET film, but the protective layer 30 may be replaced by other articles having similar isolation effects, and the invention is not limited thereto.

請參考圖3係本發明之電子裝置殼體之處理方法之流程圖。如圖3所示,本發明之電子裝置殼體之處理方法包括步驟S31至步驟S32。以下將配合圖1及圖2詳細說明本發明之電子裝置殼體之處理方法之各個步驟。Please refer to FIG. 3, which is a flow chart of a method for processing an electronic device housing of the present invention. As shown in FIG. 3, the processing method of the electronic device housing of the present invention includes steps S31 to S32. Hereinafter, each step of the processing method of the electronic device casing of the present invention will be described in detail with reference to FIGS. 1 and 2.

步驟S31:提供一碳纖維材料之基材10。為執行本發明之電子裝置殼體之處理方法,首先提供以碳纖維材料製成之基材10,此基材10可為尚未產生或已產生白化現象之電子裝置殼體1或1a之基材10,而此基材10包括外表面11。Step S31: providing a substrate 10 of a carbon fiber material. In order to perform the processing method of the electronic device casing of the present invention, first, a substrate 10 made of a carbon fiber material, which may be a substrate 10 of an electronic device casing 1 or 1a that has not been produced or has been whitened, is provided. And the substrate 10 includes an outer surface 11.

步驟S32:形成一塗層20於基材10之外表面,其中塗層為將碳酸氫鈉溶於濃度約60v/v%以上之醇類溶液中所形成之飽和溶液。依前所述,先以異丙醇或乙醇等醇類與水依比例配製成濃度約60v/v%以上之醇類溶液,再加入碳酸氫鈉以製成此醇類溶液之飽和溶液;之後,將此飽和溶液以噴塗或塗覆方式於基材10之外表面形成塗層20,以藉由塗層20對基材10進行浸濕滲透鹼化處理。當基材10因生成乙酸鈣而產生白化現象時,可藉由碳酸氫鈉對乙酸鈣產生還原反應,以去除白化現象。需注意的是,由於醇類溶液具有揮發性,在基材10上形成塗層20之狀態下,最好將其放置在不易揮發之環境中靜置一段時間,以供塗層20與基材10上之乙酸鈣等物質進行反應,達到較佳效果。Step S32: forming a coating layer 20 on the outer surface of the substrate 10, wherein the coating layer is a saturated solution formed by dissolving sodium hydrogencarbonate in an alcohol solution having a concentration of about 60 v/v% or more. As described above, an alcohol solution having a concentration of about 60 v/v% or more is prepared by using an alcohol such as isopropyl alcohol or ethanol in proportion to water, and then sodium hydrogencarbonate is added to prepare a saturated solution of the alcohol solution; Thereafter, the saturated solution is sprayed or coated to form a coating layer 20 on the outer surface of the substrate 10 to wet the substrate and alkalinize the substrate 10 by the coating 20. When the substrate 10 is whitened by the formation of calcium acetate, the reduction reaction can be carried out by sodium bicarbonate to reduce the whitening phenomenon. It should be noted that, in view of the volatility of the alcohol solution, in the state where the coating layer 20 is formed on the substrate 10, it is preferable to leave it in a non-volatile environment for a certain period of time for the coating layer 20 and the substrate. The substance such as calcium acetate on the 10 is reacted to achieve a better effect.

在本發明之電子裝置殼體之處理方法之另一實施例中,於步驟S32後更包括步驟S33。In another embodiment of the processing method of the electronic device housing of the present invention, step S33 is further included after step S32.

步驟S33:貼覆一保護層30於塗層20上。如圖2所示,若無法提供不易揮發之環境來放置經前述處理後之電子裝置殼體1a時,為避免塗層20經揮發後失去原有特性,可藉由貼覆保護層30於塗層20上,以保持塗層20於基材10與保護層30間所形成之鹼性環境,同時提供隔離效果以保護基材10不易與空氣中之酸性物質直接接觸,減少發生白化現象之機會。Step S33: A protective layer 30 is applied on the coating 20. As shown in FIG. 2, if the non-volatile environment cannot be provided to place the electronic device casing 1a after the above treatment, in order to prevent the coating 20 from losing its original characteristics after volatilization, the protective layer 30 can be applied by coating. The layer 20 is formed to maintain the alkaline environment formed between the substrate 10 and the protective layer 30 while providing a barrier effect to protect the substrate 10 from direct contact with acidic substances in the air, thereby reducing the chance of whitening. .

藉此設計,本發明可有效防止電子裝置之碳纖維殼體產生白化現象,或針對已產生白化現象之碳纖維殼體進行對應處理,使得電子裝置在製造或出貨等過程中,可保持其整體外觀一致性。By this design, the invention can effectively prevent whitening of the carbon fiber casing of the electronic device, or correspondingly deal with the carbon fiber casing which has been whitened, so that the electronic device can maintain its overall appearance during manufacturing or shipping. consistency.

綜上所陳,本發明無論就目的、手段及功效,在在均顯示其迥異於習知技術之特徵,為一大突破,懇請貴審查委員明察,早日賜准專利,俾嘉惠社會,實感德便。惟須注意,上述實施例僅為例示性說明本發明之原理及其功效,而非用於限制本發明之範圍。任何熟於此項技藝之人士均可在不違背本發明之技術原理及精神下,對實施例作修改與變化。本發明之權利保護範圍應如後述之申請專利範圍所述。In summary, the present invention is a breakthrough in terms of its purpose, means and efficacy, and it is different from the characteristics of the prior art. It is a great breakthrough for the reviewer to ask for an early patent, and to benefit the society. Debian. It is to be noted that the above-described embodiments are merely illustrative of the principles of the invention and its advantages, and are not intended to limit the scope of the invention. Modifications and variations of the embodiments can be made by those skilled in the art without departing from the spirit and scope of the invention. The scope of protection of the present invention should be as described in the scope of the patent application to be described later.

1、1a...電子裝置殼體外殼本體1, 1a. . . Electronic device housing body

10...基材10. . . Substrate

11...外表面11. . . The outer surface

20...塗層20. . . coating

30...保護層30. . . The protective layer

圖1係本發明之電子裝置殼體之結構示意圖。1 is a schematic structural view of a housing of an electronic device of the present invention.

圖2係本發明之電子裝置殼體之另一實施例之結構示意圖。2 is a schematic structural view of another embodiment of the electronic device housing of the present invention.

圖3係本發明之電子裝置殼體之處理方法之流程圖。3 is a flow chart of a method of processing an electronic device housing of the present invention.

1...電子裝置殼體1. . . Electronic device housing

10...基材10. . . Substrate

11...外表面11. . . The outer surface

20...塗層20. . . coating

Claims (10)

一種電子裝置殼體,包括:一基材,係以一碳纖維材料製成,該基材包括一外表面;以及一塗層,係形成於該基材之該外表面,其中該塗層為將一碳酸氫鈉溶於一濃度約60v/v%以上之醇類溶液所形成之飽和溶液。An electronic device housing comprising: a substrate made of a carbon fiber material, the substrate comprising an outer surface; and a coating formed on the outer surface of the substrate, wherein the coating is A saturated solution of sodium bicarbonate dissolved in an alcohol solution having a concentration of about 60 v/v% or more. 如申請專利範圍第1項所述之電子裝置殼體,更包括一保護層,係貼覆於該塗層上。The electronic device housing of claim 1, further comprising a protective layer attached to the coating. 如申請專利範圍第1項或第2項所述之電子裝置殼體,其中該醇類溶液為一異丙醇溶液或一乙醇溶液。The electronic device casing according to claim 1 or 2, wherein the alcohol solution is an isopropanol solution or an ethanol solution. 如申請專利範圍第3項所述之電子裝置殼體,其中該醇類溶液之較佳濃度約介於70v/v%至80v/v%之間,且最佳濃度約為75v/v%。The electronic device housing of claim 3, wherein the preferred concentration of the alcohol solution is between about 70 v/v% and 80 v/v%, and the optimum concentration is about 75 v/v%. 如申請專利範圍第2項所述之電子裝置殼體,其中該保護層係為一PET膜。The electronic device housing of claim 2, wherein the protective layer is a PET film. 一種電子裝置殼體之處理方法,包括以下步驟:提供一碳纖維材料之基材;以及形成一塗層於該基材之一外表面,其中該塗層為將一碳酸氫鈉溶於一濃度約60v/v%以上之醇類溶液中所形成之飽和溶液。A method for processing an electronic device housing, comprising the steps of: providing a substrate of a carbon fiber material; and forming a coating on an outer surface of the substrate, wherein the coating dissolves sodium bicarbonate at a concentration of about A saturated solution formed in an alcohol solution of 60 v/v% or more. 如申請專利範圍第6項所述之電子裝置殼體之處理方法,更包括以下步驟:貼覆一保護層於該塗層上。The method for processing an electronic device housing according to claim 6, further comprising the step of: attaching a protective layer to the coating. 如申請專利範圍第6項或第7項所述之電子裝置殼體之處理方法,其中該醇類溶液為一異丙醇溶液或一乙醇溶液。The method for processing an electronic device housing according to the above-mentioned item 6, wherein the alcohol solution is an isopropanol solution or an ethanol solution. 如申請專利範圍第8項所述之電子裝置殼體之處理方法,其中該醇類溶液之較佳濃度約介於70v/v%至80v/v%之間,且最佳濃度約為75v/v%。The method for processing an electronic device casing according to claim 8, wherein the preferred concentration of the alcohol solution is between about 70 v/v% and 80 v/v%, and the optimum concentration is about 75 v/ v%. 如申請專利範圍第6項所述之電子裝置殼體之處理方法,其中該塗層係以噴塗或塗覆方式形成於該基材之該外表面。The method of processing an electronic device housing according to claim 6, wherein the coating is formed on the outer surface of the substrate by spraying or coating.
TW100145107A 2011-12-07 2011-12-07 Housing of electronic apparatus and processing method thereof TW201323204A (en)

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