TW201316426A - System and method for semiconductor wafer processsing with side/bevel protection - Google Patents

System and method for semiconductor wafer processsing with side/bevel protection Download PDF

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TW201316426A
TW201316426A TW100136533A TW100136533A TW201316426A TW 201316426 A TW201316426 A TW 201316426A TW 100136533 A TW100136533 A TW 100136533A TW 100136533 A TW100136533 A TW 100136533A TW 201316426 A TW201316426 A TW 201316426A
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wafer
polymer
layer
liquid
polymer coating
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TWI473192B (en
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Meng-Tsung Ko
Yung-Tai Hung
Chin-Ta Su
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Macronix Int Co Ltd
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Abstract

A system is provided that includes a power supply connectable to a semiconductor wafer including opposing, major front and back surfaces joined by a circumferential side, with the wafer undergoing processing including electroplating a damascene layer on the wafer. The system also includes an arrangement configured to apply a polymer coating to the side of the wafer before electroplating the damascene layer, with the system being configured to apply a polymer coating in accordance with an electrophoresis technique driven by the power supply. In this regard, the polymer coating is applied to the side but not at least a portion of the front and back surfaces of the wafer, and the polymer coating provides a barrier to formation of the damascene layer on the side of the wafer.

Description

具有側面保護之半導體晶圓製程方法及系統Semiconductor wafer processing method and system with side protection

本發明之範例實施例係關於半導體晶圓的製程,且更具體而言,是與於製程中保護晶圓側面之方法與系統相關。Example embodiments of the present invention relate to processes for semiconductor wafers and, more particularly, to methods and systems for protecting wafer sides in a process.

在半導體產業中,一半導體裝置的製造包括對一晶圓的製程,其包括前段製程及後段製程以將電子元件(例如電晶體、電阻、電容等)於晶體中圖案化且形成內連線以構成積體電路。於晶圓製程結束之後,此晶圓被切割成單獨的晶粒然後進行封裝。In the semiconductor industry, the fabrication of a semiconductor device includes a process for a wafer that includes a front-end process and a back-end process to pattern electronic components (eg, transistors, resistors, capacitors, etc.) into the crystal and form interconnects. Form the integrated circuit. After the wafer process is completed, the wafer is diced into individual dies and then packaged.

於前段製程中的一部份,此晶圓可以進行嵌鑲製程以形成例如是導線、接觸窗或是介層孔的電子內連線。為了形成嵌鑲結構,介電層形成於具有導電區域於其中的一基板之上。然後形成一開口於介電層中。此開口可以是接觸窗開口、介層孔開口、導線溝渠或是嵌鑲開口。此開口將此基板中的導電區域一部分裸露出來。一層金屬層然後形成於基板之上且完全覆蓋此開口。許多合適的金屬材料做以作為此金屬層,但此處所描述的係根據一範例,此金屬層是使用銅或是銅合金(通常稱為銅)。在一範例中,此金屬層可以先形成一層薄的銅種子層然後再形成一層厚的金屬層,其通常被稱為"嵌鑲層"。在一範例中,此層薄的銅種子層可以使用物理氣相沈積(PVD)、或是化學氣相沈積(CVD)形成,而銅嵌鑲層可以使用電化學鍍(ECD)方式形成。In a portion of the front-end process, the wafer can be embedded to form an electronic interconnect such as a wire, a contact window, or a via. To form the damascene structure, a dielectric layer is formed over a substrate having a conductive region therein. An opening is then formed in the dielectric layer. The opening can be a contact window opening, a via opening, a wire trench or a mosaic opening. This opening exposes a portion of the conductive area in the substrate. A layer of metal is then formed over the substrate and completely covers the opening. Many suitable metallic materials are used as the metal layer, but as described herein, according to an example, the metal layer is copper or a copper alloy (commonly referred to as copper). In one example, the metal layer may first form a thin layer of copper seed and then form a thick layer of metal, commonly referred to as a "mosaic layer." In one example, the thin copper seed layer can be formed using physical vapor deposition (PVD) or chemical vapor deposition (CVD), and the copper inlay can be formed using electrochemical plating (ECD).

在施加金屬層於基板上之後,此晶圓可以藉由將其浸泡於溶液中來清潔以除去於施加此銅層時所產生的微粒。此清潔後的晶圓也可以利用例如是藉由旋轉此晶圓的方式加以乾燥。最後,進行退火及化學機械研磨(CMP)以除去開口外的多餘金屬材料。After applying the metal layer on the substrate, the wafer can be cleaned by immersing it in a solution to remove particles generated when the copper layer is applied. The cleaned wafer can also be dried, for example, by rotating the wafer. Finally, annealing and chemical mechanical polishing (CMP) are performed to remove excess metal material outside the opening.

此晶圓通常包括相對的主要前表面及後表面,其由一側邊連接在一起,此側邊通常是傾斜的。在嵌鑲製程中,通常希望電鍍沈積的金屬層次靠近晶圓的側邊但不會覆蓋其側邊。類似地,通常也不希望電鍍沈積的金屬層次延伸於晶圓的側邊。因此,某些技術被開發以除去形成於晶圓側邊的電鍍沈積金屬層的部分,但仍希望對現存的技術做進一步的改進。The wafer typically includes opposing major front and back surfaces joined together by one side, which is generally inclined. In a damascene process, it is often desirable to have a metal layer deposited by electroplating close to the sides of the wafer but not to the sides. Similarly, it is generally undesirable to have a metal layer of electroplated deposition extending over the sides of the wafer. Therefore, certain techniques have been developed to remove portions of the electroplated deposited metal layer formed on the sides of the wafer, but further improvements to existing technologies are still desired.

根據之前背景段落中所描述的,本發明之範例實施例提供於形成電鍍層的製程中保護晶圓側面之方法與系統。根據本發明之一目的係提供一種積體電路製造系統,包含:一電源供應可與一半導體晶圓連接,該晶圓具有相對的主要前表面及後表面,其由一側邊連接在一起,該晶圓可以進行包括電鍍一嵌鑲層於該晶圓上的前段製程。此系統也包含一安排組態為可以於電鍍該嵌鑲層之前施加一高分子塗佈於該晶圓的該側邊,該高分子塗佈施加於該晶圓的該主要前表面及後表面之一部分以及該側邊,其中該系統係組態為由一電源所驅動之一電泳技術來施加該高分子塗佈層。該高分子塗佈係作為防止該嵌鑲層形成於該晶圓的該側邊之一阻障層。Exemplary embodiments of the present invention provide methods and systems for protecting the sides of a wafer in a process for forming a plating layer, as described in the preceding paragraphs. SUMMARY OF THE INVENTION According to one aspect of the present invention, an integrated circuit manufacturing system includes: a power supply connectable to a semiconductor wafer having opposing major front and back surfaces joined together by one side, The wafer can be subjected to a front-end process including plating an inlay on the wafer. The system also includes an arrangement configured to apply a polymer to the side of the wafer prior to electroplating the inlay layer, the polymer coating applied to the major front and back surfaces of the wafer A portion and the side, wherein the system is configured to apply the polymeric coating layer by an electrophoresis technique driven by a power source. The polymer coating system serves as a barrier layer for preventing the mosaic layer from being formed on one side of the wafer.

更具體而言,高分子塗佈係施加於該晶圓的該主要前表面及後表面之一部分以及該側邊,即高分子塗佈係施加於該晶圓的側邊,且可以選擇性地施加於該晶圓的該主要前表面及後表面之一部分,而不是施加於整個晶圓的該主要前表面及後表面上。在一範例中,施加於該晶圓的該主要前表面及後表面之該高分子塗佈的寬度介於3~5mm,且該主要前表面及後表面具有大於3~5mm之半徑。More specifically, a polymer coating is applied to one of the main front and back surfaces of the wafer and the side, that is, a polymer coating system is applied to the side of the wafer, and may be selectively Applied to a portion of the major front and back surfaces of the wafer, rather than being applied to the major front and back surfaces of the wafer. In one example, the polymer applied to the major front and back surfaces of the wafer has a width of between 3 and 5 mm, and the major front and back surfaces have a radius greater than 3 to 5 mm.

在一範例中,該安排包含一基座以及一熱源。該基座以組態為將該晶圓與一高分子液體接觸使得該高分子塗佈於該晶圓的該主要前表面及後表面之外以及該側邊。且該熱源組態為熱固化該晶圓的該側邊之該高分子液體塗佈以形成該高分子塗佈。In one example, the arrangement includes a pedestal and a heat source. The susceptor is configured to contact the wafer with a polymeric liquid such that the polymer is applied outside of the major front and back surfaces of the wafer and to the sides. And the heat source is configured to thermally cure the polymer liquid on the side of the wafer to form the polymer coating.

在一範例中,該安排包含組態為施加該高分子塗佈係在於形成一薄的銅種子層之後及在電鍍形成該嵌鑲層之前所施加。在此範例中,該系統更包含一反應室,在其中可將該晶圓密封以進行該熱源的熱固化該高分子塗佈。而且在此範例中,該反應室具有降低壓力或惰性氣體的環境,以至少降低該種子層於該高分子液體固化時被氧化。In one example, the arrangement includes being configured to apply the polymeric coating after the formation of a thin copper seed layer and prior to electroplating to form the mosaic layer. In this example, the system further includes a reaction chamber in which the wafer can be sealed for thermal curing of the heat source. Also in this example, the reaction chamber has an environment of reduced pressure or inert gas to at least reduce the oxidation of the seed layer upon solidification of the polymeric liquid.

在一範例中,該安排更包括充滿一高分子液體的一承載容器。在此範例中,其中該承載容器具有一個多個滾輪組態為將該晶圓支撐於該承載容器之上使得該晶圓的該主要前表面及後表面大致與該高分子液體一上表面之平面垂直,且使得該側邊的至少一部分以及該主要前表面及後表面的一部分浸入該高分子液體中;以及其中該一個多個滾輪組態為將該晶圓在大致與該主要前表面及後表面垂直之一軸向上旋轉以將該晶圓的該側邊連續接觸部分可以被浸入及移出該高分子液體中。In one example, the arrangement further includes a carrier container filled with a polymeric liquid. In this example, the carrier container has a plurality of rollers configured to support the wafer on the carrier container such that the major front and back surfaces of the wafer are substantially parallel to the upper surface of the polymer liquid. The plane is vertical and such that at least a portion of the side and a portion of the major front and back surfaces are immersed in the polymeric liquid; and wherein the one or more rollers are configured to substantially surround the wafer with the major front surface and One of the rear surfaces is vertically rotated to allow the side continuous contact portion of the wafer to be immersed and removed from the polymer liquid.

根據本發明之另一目的係提供一種積體電路電鍍系統,包含一第一機台組態為施加一高分子塗佈於一半導體晶圓上。在不同的實施例中,此第一機台可以是前述之系統或是包含前述系統中的元件。在此範例中,此積體電路電鍍系統更包含一第二機台組態為自該第一機台接收該晶圓。此第二機台組態為自該第一機台接收該晶圓,該第二機台組態為電鍍一嵌鑲層於晶圓上,該高分子塗佈係作為防止該嵌鑲層形成於該晶圓的該側邊之一阻障層。在此範例中,此積體電路電鍍系統更包含一機械手臂以將晶圓自第一機台傳送至第二機台。Another object of the present invention is to provide an integrated circuit plating system comprising a first machine configured to apply a polymer onto a semiconductor wafer. In various embodiments, the first machine can be the system described above or comprise the elements of the aforementioned system. In this example, the integrated circuit plating system further includes a second machine configured to receive the wafer from the first machine. The second machine is configured to receive the wafer from the first machine, and the second machine is configured to plate an insert layer on the wafer, the polymer coating system is used to prevent the formation of the mosaic layer a barrier layer on the side of the wafer. In this example, the integrated circuit plating system further includes a robot arm to transfer the wafer from the first machine to the second machine.

在一範例中,此積體電路電鍍系統更包含一第三機台組態為自該第二機台接收該晶圓,該第三機台用來在該電鍍之後清潔及乾燥該晶圓;以及一第四台組態為自該第三機台接收該晶圓,該第四機台用來對該晶圓退火。在此範例中,此積體電路電鍍系統更包含該機械手臂以將晶圓自第二機台傳送至第三機台以及自第三機台傳送至第四機台。In an example, the integrated circuit plating system further includes a third machine configured to receive the wafer from the second machine, the third machine for cleaning and drying the wafer after the plating; And a fourth device configured to receive the wafer from the third machine, the fourth machine being used to anneal the wafer. In this example, the integrated circuit plating system further includes the robot arm to transfer the wafer from the second machine to the third machine and from the third machine to the fourth machine.

本發明之某些實施例,會在下列實施方式的章節中搭配圖式被描述,其中僅顯示某些而並非全部的實施例。然而,本發明不同的實施例可以具有不同的型態且不應視為限制本發明;而是這些實施例之提供係為使本說明書之揭露滿足專利法之要求。Certain embodiments of the invention are described in the following description of the embodiments of the invention, in which only some, but not all, embodiments are shown. However, the various embodiments of the present invention may have different types and should not be construed as limiting the present invention; rather, these embodiments are provided so that the disclosure of the present specification satisfies the requirements of the patent law.

請參閱第1圖,其顯示根據本發明一範例實施例之半導體晶圓10的上視及剖面(係沿著虛線)圖。如圖中所示,此晶圓包括相對的主要前表面12及後表面14,其由一側邊16連接在一起,此側邊可以是傾斜或不傾斜的(圖中顯示傾斜的側邊)。此側邊因此在某些時候被稱為傾斜的側邊、傾斜的邊緣、斜邊或側邊。此晶圓可以進行前段製程或後段製程以將電子元件(例如電晶體、電阻、電容等)於晶體中圖案化且形成內連線以構成積體電路。Referring to FIG. 1, there is shown a top view and a cross-section (along the dashed line) of a semiconductor wafer 10 in accordance with an exemplary embodiment of the present invention. As shown in the figures, the wafer includes opposing major front and rear surfaces 12, 14 that are joined together by one side 16 that may or may not be inclined (the side of the slope is shown) . This side is therefore sometimes referred to as a slanted side, a slanted edge, a beveled edge or a side. The wafer can be subjected to a front-end process or a back-end process to pattern electronic components (eg, transistors, resistors, capacitors, etc.) in the crystal and form interconnects to form an integrated circuit.

以類似於在背景段落中解釋過的方式,於前段製程中的一部份,此晶圓10可以進行嵌鑲製程以形成例如是導線、接觸窗或是介層孔的電子內連線。為了形成嵌鑲結構,介電層形成於具有導電區域於其中的一基板之上。然後形成一開口於介電層中。此開口可以是接觸窗開口、介層孔開口、導線溝渠或是嵌鑲開口。此開口將此基板中的導電區域一部分裸露出來。一層金屬層然後形成於基板之上且完全覆蓋此開口。許多合適的金屬材料做以作為此金屬層,但此處所描述的係根據一範例,此金屬層是使用銅或是銅合金(通常稱為銅)。在一範例中,此金屬層可以先形成一層薄的銅種子層然後再形成一層厚的銅嵌鑲層。在一範例中,此層薄的銅種子層可以使用物理氣相沈積(PVD)、或是化學氣相沈積(CVD)形成,而銅嵌鑲層可以使用電化學鍍(ECD)方式形成。In a manner similar to that explained in the background paragraph, the wafer 10 can be embedded in a portion of the front-end process to form an electronic interconnect such as a wire, a contact or a via. To form the damascene structure, a dielectric layer is formed over a substrate having a conductive region therein. An opening is then formed in the dielectric layer. The opening can be a contact window opening, a via opening, a wire trench or a mosaic opening. This opening exposes a portion of the conductive area in the substrate. A layer of metal is then formed over the substrate and completely covers the opening. Many suitable metallic materials are used as the metal layer, but as described herein, according to an example, the metal layer is copper or a copper alloy (commonly referred to as copper). In one example, the metal layer may first form a thin layer of copper seed and then form a thick layer of copper inlay. In one example, the thin copper seed layer can be formed using physical vapor deposition (PVD) or chemical vapor deposition (CVD), and the copper inlay can be formed using electrochemical plating (ECD).

在施加金屬層於基板上之後,此晶圓10可以藉由將其浸泡於溶液中來清潔以除去於施加此銅層時所產生的微粒。此清潔後的晶圓也可以利用例如是藉由旋轉此晶圓的方式加以乾燥。最後,進行退火及化學機械研磨(CMP)以除去開口外的多餘金屬材料。After applying the metal layer on the substrate, the wafer 10 can be cleaned by immersing it in a solution to remove particles generated when the copper layer is applied. The cleaned wafer can also be dried, for example, by rotating the wafer. Finally, annealing and chemical mechanical polishing (CMP) are performed to remove excess metal material outside the opening.

如同在背景段落中解釋過的,通常不希望電鍍沈積的層次延伸於晶圓10的側邊16。根據本發明之某些範例實施例,然後,於形成嵌鑲層之前,一非導電高分子層18可以塗佈或是用其他方式施加於晶圓的週邊。在一實施例中,於形成薄的銅種子層之後及在形成嵌鑲層之前,此非導電高分子層可以施加於晶圓的週邊。此高分子層可以具有一種或多種特性例如與電鍍溶液相容,以及/或可溶於某些化學品中但通常是不溶於電鍍溶液。As explained in the background paragraph, it is generally undesirable to have a layer of electroplated deposition extending over the side edges 16 of the wafer 10. In accordance with certain exemplary embodiments of the present invention, a non-conductive polymer layer 18 may then be applied or otherwise applied to the periphery of the wafer prior to forming the inlay layer. In one embodiment, the non-conductive polymer layer can be applied to the periphery of the wafer after forming a thin copper seed layer and before forming the inlay layer. The polymeric layer may have one or more properties such as compatibility with the plating solution, and/or may be soluble in certain chemicals but is generally insoluble in the plating solution.

此高分子層18可以覆蓋於晶圓10的側邊16,且可以額外的包覆於主要前表面12及後表面14各自的環狀週邊區域之表面。在包含主要前表面12及後表面14的直徑為150~450毫米(mm)之晶圓中,此高分子層在一範例中額外包覆3~5毫米(mm)的前表面12及後表面14。於形成嵌鑲層時,此高分子層可以作為防止嵌鑲層在側邊以及被高分子包覆於晶圓主要前表面12及後表面14部分形成的阻障層。此高分子層然後可以於進行化學機械研磨(CMP)期間、之前或之後利用例如是某些溶液或研磨液除去,因此保留嵌鑲層不會在側邊以及被高分子包覆於晶圓主要前表面12及後表面14部分形成。The polymer layer 18 can cover the side edges 16 of the wafer 10 and can be additionally coated on the surface of the respective annular peripheral regions of the major front surface 12 and the back surface 14. In a wafer having a main front surface 12 and a rear surface 14 having a diameter of 150 to 450 millimeters (mm), the polymer layer is additionally coated with a front surface 12 and a rear surface of 3 to 5 millimeters (mm) in one example. 14. When the insert layer is formed, the polymer layer can serve as a barrier layer for preventing the insert layer from being formed on the side and partially covered by the polymer on the main front surface 12 and the back surface 14 of the wafer. The polymer layer can then be removed, for example, by some solution or slurry during, during or after chemical mechanical polishing (CMP), so that the embedded layer is not left on the side and the polymer is coated on the wafer. The front surface 12 and the rear surface 14 are partially formed.

此高分子層18可以使用許多不同的方式來施加於晶圓10之上。如第2圖中所示,根據一範例實施例,使用一系統20來施加高分子層18於晶圓10之上。此系統包括一承載溶液之容器22其中填滿高分子液體24。此系統也包括一基座以支撐晶圓且將晶圓與高分子液體24接觸以在晶圓10的側邊16塗佈此高分子液體24,且可以選擇性地塗佈在主要前表面12及後表面14之週邊表面的邊緣部分-且不會部分塗佈在主要前表面12及後表面14之週邊表面的內緣部分。如圖中所示,此系統也包括一滾輪26以支撐晶圓10的側邊16塗佈此高分子液體承載容器之上使得晶圓的主要前表面12及後表面14大致與此高分子液體上表面之平面垂直,且使得側邊的至少一部分(如果沒有也包含主要前表面12及後表面14的一部分)浸入此高分子液體中。如圖中所示,在此範例中滾輪26支撐住晶圓,使得晶圓的主要前表面12及後表面14之各自區段及與此各自區段連接之側邊部份被浸入此高分子液體中。在此範例中,晶圓浸入此高分子液體中的深度可以設定為主要前表面12及後表面14之邊緣部份可以被高分子液體包覆。This polymeric layer 18 can be applied to the wafer 10 in a number of different ways. As shown in FIG. 2, a system 20 is used to apply a polymer layer 18 over wafer 10, in accordance with an exemplary embodiment. The system includes a container 22 carrying a solution which is filled with a polymeric liquid 24. The system also includes a susceptor to support the wafer and to contact the polymer liquid 24 to coat the polymer liquid 24 at the side 16 of the wafer 10 and to be selectively coated on the primary front surface 12 The edge portions of the peripheral surface of the rear surface 14 are not partially coated on the inner edge portions of the peripheral surfaces of the main front surface 12 and the rear surface 14. As shown in the figure, the system also includes a roller 26 for supporting the side 16 of the wafer 10 to coat the polymer liquid carrying container such that the main front surface 12 and the rear surface 14 of the wafer are substantially associated with the polymer liquid. The plane of the upper surface is perpendicular and such that at least a portion of the sides (if not also including a portion of the major front surface 12 and the back surface 14) is immersed in the polymeric liquid. As shown in the figure, in this example, the roller 26 supports the wafer such that the respective sections of the main front surface 12 and the rear surface 14 of the wafer and the side portions connected to the respective sections are immersed in the polymer. In the liquid. In this example, the depth at which the wafer is immersed in the polymer liquid can be set such that the edge portions of the main front surface 12 and the rear surface 14 can be coated with the polymer liquid.

此範例中的滾輪26可以進一步用來將晶圓在大致與主要前表面12及後表面14垂直之軸向上旋轉。如第3A~3D圖中所示(僅顯示此系統20的一部分),當滾輪26將晶圓旋轉時,側邊16的連續接觸部分可以被浸入及移出高分子液體24中。類似地,對於主要前表面12及後表面14任何需要被高分子液體覆蓋的部分,其各自邊緣的連續接觸部分28可以被浸入及移出高分子液體24中。當晶圓的主要前表面12及後表面14之各自區段及與此各自區段連接之側邊部份被浸入此高分子液體中,此高分子溶液會覆蓋於各自的區段上。在一範例中,此系統可以根據由一與此晶圓連接之電源30所驅動電泳技術來實施。The roller 26 in this example can further be used to rotate the wafer in an axial direction generally perpendicular to the major front surface 12 and rear surface 14. As shown in Figures 3A-3D (only a portion of this system 20 is shown), as the roller 26 rotates the wafer, the continuous contact portion of the side 16 can be immersed and removed from the polymer liquid 24. Similarly, for any portion of the primary front surface 12 and rear surface 14 that need to be covered by the polymeric liquid, the continuous contact portions 28 of their respective edges can be immersed and removed from the polymeric liquid 24. When the respective sections of the main front surface 12 and the rear surface 14 of the wafer and the side portions joined to the respective sections are immersed in the polymer liquid, the polymer solution covers the respective sections. In one example, the system can be implemented in accordance with an electrophoresis technique driven by a power source 30 coupled to the wafer.

當晶圓的主要前表面12及後表面14之各自週邊區段及與此各自區段連接之側邊部份被自此高分子液體24中抽出時,塗佈於這些各自區段上的高分子液體可以被固化以形成高分子層18。在一範例中,此高分子層可以使用例如是燈泡32或是紫外線光源系統的熱源加以熱固化。在一範例實施中,高分子層18係在於形成薄的銅種子層之後及在形成嵌鑲層之前所施加,至少包含晶圓及通常包含系統中的許多部件被放置於具有降低壓力和惰性氣體的反應室34中,這些惰性氣體舉例而言可以是氮、氬或是類似的氣體。此反應室中的壓力可以至少降低或是至防止種子層於塗佈此高分子液體時被氧化。When the respective peripheral sections of the main front surface 12 and the rear surface 14 of the wafer and the side portions connected to the respective sections are extracted from the polymer liquid 24, the coating on the respective sections is high. The molecular liquid can be cured to form the polymer layer 18. In one example, the polymeric layer can be thermally cured using a heat source such as bulb 32 or an ultraviolet light source system. In an exemplary implementation, the polymeric layer 18 is applied after forming a thin copper seed layer and prior to forming the inlay layer, at least the wafer and many of the components typically included in the system are placed with reduced pressure and inert gas In the reaction chamber 34, these inert gases may be, for example, nitrogen, argon or the like. The pressure in the reaction chamber can be at least reduced or to prevent oxidation of the seed layer upon application of the polymeric liquid.

再者,此高分子層可以在電鍍形成嵌鑲層以在晶圓上構成嵌鑲結構之前,施加於晶圓10的周邊。於之後的電鍍步驟時,此高分子層18則可以作為防止嵌鑲層在側邊以及被高分子包覆於晶圓主要前表面12及後表面14之一部分形成的阻障層。Furthermore, the polymer layer may be applied to the periphery of the wafer 10 prior to electroplating to form an inlay layer to form a damascene structure on the wafer. In the subsequent electroplating step, the polymer layer 18 can serve as a barrier layer for preventing the embedding layer from being formed on the side and a portion of the main front surface 12 and the back surface 14 of the wafer.

第4圖顯示根據本發明一範例實施例之電鍍晶圓10的系統36之剖面圖。此系統包括一承載溶液之容器38,其裝滿例如是硫酸銅之電鍍液40。此晶圓及一銅金屬42被浸入此溶液中-此晶圓作為隂極而銅金屬42作為陽極。此晶圓隂極與銅金屬陽極連接至一電源44,其在晶圓隂極與銅金屬陽極產生一電位差,且施加一直接電流至銅金屬陽極。此電流導致銅金屬陽極中的銅原子氧化且溶解於此溶液中。介於晶圓隂極與銅金屬陽極之間的電位差會驅使溶液中的溶解之銅原子朝向晶圓隂極。通常而言,溶解之銅原子晶圓隂極與銅金屬陽極之間的接面會逐漸減少,如此會在晶圓隂極表面形成一銅電鍍層。但是在包括高分子18的晶圓週邊,此高分子層可以作為阻障層以防止銅被電鍍在側邊16以及被高分子包覆於晶圓主要前表面12及後表面14之一部分。4 shows a cross-sectional view of a system 36 for electroplating a wafer 10 in accordance with an exemplary embodiment of the present invention. The system includes a container 38 carrying a solution filled with a plating solution 40 such as copper sulfate. The wafer and a copper metal 42 are immersed in the solution - the wafer serves as a cathode and the copper metal 42 serves as an anode. The wafer cathode and copper metal anode are connected to a power source 44 which creates a potential difference between the cathode of the wafer and the copper metal anode and applies a direct current to the copper metal anode. This current causes the copper atoms in the copper metal anode to oxidize and dissolve in the solution. The potential difference between the wafer cathode and the copper metal anode drives the dissolved copper atoms in the solution toward the wafer cathode. Generally, the junction between the dissolved copper atomic wafer cathode and the copper metal anode is gradually reduced, thus forming a copper plating layer on the wafer cathode surface. However, in the periphery of the wafer including the polymer 18, the polymer layer can serve as a barrier layer to prevent copper from being plated on the side edges 16 and coated with a polymer on one of the major front surface 12 and the back surface 14 of the wafer.

請參閱第5圖,本發明之範例實施例可以進一步提供一整合電鍍系統46以進行此晶圓10電鍍及嵌鑲製程中相關製程的許多不同操作。系統46可以包括一承載基座48以將晶圓送入及送出此系統。此系統也包括複數個機台以進行電鍍及嵌鑲製程中相關製程,以及一機器手臂50或其他電動機械以將晶圓自一第一機台傳送至另一機台及後續機台,且繼續至最後一個機台。Referring to FIG. 5, an exemplary embodiment of the present invention may further provide an integrated plating system 46 for performing many different operations of the wafer 10 plating and associated processes in the damascene process. System 46 can include a carrier base 48 for feeding wafers in and out of the system. The system also includes a plurality of machines for performing processes in electroplating and inlay processes, and a robotic arm 50 or other electromechanical machine to transfer wafers from one first machine to another and subsequent machines, and Continue to the last machine.

如圖中所示,此系統中的機台可以包括第一機台52以施加高分子層18於晶圓上;且在此目的下,第一機台可以包括如第2圖中所示的系統20之一個系統。此系統中的機台也可以包括第二機台54以將含有高分子層18之晶圓進行電鍍銅。此第二機台可以包括如第4圖中所示的系統36之一個系統。此外,此系統中的機台也可以包括第三機台56,其包括一清潔溶液及乾燥設備以在電鍍之後將晶圓進行清潔及乾燥,以及一第四機台58對此晶圓進行退火。As shown in the figure, the machine in this system may include a first machine 52 to apply a polymer layer 18 on the wafer; and for this purpose, the first machine may include as shown in FIG. A system of system 20. The machine in this system may also include a second machine 54 to electroplate the wafer containing the polymer layer 18. This second machine can include a system of system 36 as shown in FIG. In addition, the machine in the system may also include a third machine 56 including a cleaning solution and drying device to clean and dry the wafer after plating, and a fourth machine 58 to anneal the wafer. .

請參閱第6及第7圖,其顯示根據本發明之範例實施例之許多不同操作之製程流程圖。此方法包括提供一個包括相對的主要前表面及後表面,其由一側邊連接在一起之晶圓,此晶圓可以進行包括電鍍一嵌鑲層於此晶圓上的前段製程。如方塊60中所示,此方法可以包括於電鍍之前施加一高分子塗佈層覆蓋於晶圓的側邊,但是沒有包覆於晶圓的主要前表面及後表面之至少一部分。此高分子塗佈層可以作為防止在由一電源所驅動電泳技術來實施時以形成嵌鑲層結構於側邊的阻障層。Referring to Figures 6 and 7, there are shown process flow diagrams for many different operations in accordance with an exemplary embodiment of the present invention. The method includes providing a wafer comprising opposing major front and back surfaces joined together by one side, the wafer being capable of performing a front-end process including plating a layer on the wafer. As shown in block 60, the method can include applying a polymeric coating layer over the sides of the wafer prior to electroplating, but without coating at least a portion of the major front and back surfaces of the wafer. The polymer coating layer can be used as a barrier layer to prevent the side layer from being formed on the side when the electrophoresis technique is driven by a power source.

施加此高分子塗佈層可以包括將此晶圓浸泡於高分子液體中以形成高分子塗佈層覆蓋於晶圓的側邊,但是沒有包覆於晶圓的主要前表面及後表面之至少一部分,然後將其熱固化以形成高分子塗佈層。更具體而言,舉例而言,施加此高分子塗佈層可以包括將晶圓支撐於一高分子液體承載容器之上使得晶圓的主要前表面及後表面大致與此高分子液體上表面之平面垂直,且使得側邊的至少一部分以及包含主要前表面及後表面的一部分浸入此高分子液體中。在此範例中,晶圓可以在大致與主要前表面及後表面垂直之軸向上旋轉以將晶圓的側邊連續接觸部分可以被浸入及移出高分子液體中。此外,在此範例中,此高分子層可以在晶圓的側邊連續接觸部分被移出高分子液體後加以熱固化。Applying the polymer coating layer may include immersing the wafer in the polymer liquid to form a polymer coating layer covering the side of the wafer, but not covering at least the main front surface and the back surface of the wafer A portion is then thermally cured to form a polymer coating layer. More specifically, for example, applying the polymer coating layer may include supporting the wafer on a polymer liquid carrying container such that the main front surface and the back surface of the wafer substantially correspond to the upper surface of the polymer liquid The plane is vertical and at least a portion of the sides and a portion including the major front and back surfaces are immersed in the polymeric liquid. In this example, the wafer can be rotated in an axial direction substantially perpendicular to the major front and back surfaces to allow the side continuous contact portions of the wafer to be immersed and removed from the polymeric liquid. Further, in this example, the polymer layer may be thermally cured after the continuous contact portion of the side of the wafer is removed from the polymer liquid.

在一範例中,此高分子層係在於形成薄的銅種子層之後及在形成嵌鑲層之前所施加。在此範例中,此高分子層塗佈可以在具有降低壓力或惰性氣體的反應室中進行,以至少降低或是至防止種子層於塗佈此高分子液體時被氧化。In one example, the polymeric layer is applied after forming a thin copper seed layer and prior to forming the inlay layer. In this example, the polymer layer coating can be carried out in a reaction chamber having a reduced pressure or inert gas to at least reduce or prevent oxidation of the seed layer upon application of the polymer liquid.

無論此高分子層係利用何種方式施加,此方法也包括於施加高分子層之後,電鍍形成嵌鑲層於晶圓之上,此嵌鑲層包覆蓋未被高分子包覆之晶圓主要前表面及後表面的部分,如方塊62中所示。此方法也包括在電鍍形成嵌鑲層之後將此高分子塗佈層移除。此後段製程還包括對晶圓進行化學機械研磨(CMP)。如方塊64中所示,此高分子塗佈層可以藉由化學機械研磨(CMP)移除。或是如第7圖之方塊66中所示,此高分子塗佈層可以藉由溶劑或是研磨液在進行化學機械研磨(CMP)之前就移除,之後於方塊68進行化學機械研磨(CMP)。Regardless of the manner in which the polymer layer is applied, the method also includes electroplating to form an inlay layer on the wafer after applying the polymer layer, the inlay layer covering the wafer not covered by the polymer. Portions of the front and back surfaces are as shown in block 62. The method also includes removing the polymeric coating layer after electroplating to form the inlay layer. The subsequent process also includes chemical mechanical polishing (CMP) of the wafer. As shown in block 64, the polymeric coating layer can be removed by chemical mechanical polishing (CMP). Alternatively, as shown in block 66 of Figure 7, the polymer coating layer can be removed prior to chemical mechanical polishing (CMP) by solvent or slurry, followed by chemical mechanical polishing (CMP) at block 68. ).

雖然本發明係已參照實施例來加以描述,然本發明創作並未受限於其詳細描述內容。替換方式及修改樣式係已於先前描述中所建議,且其他替換方式及修改樣式將為熟習此項技藝之人士所思及。特別是,所有具有實質上相同於本發明之構件結合而達成與本發明實質上相同結果者,皆不脫離本發明之精神範疇。因此,所有此等替換方式及修改樣式係意欲落在本發明於隨附申請專利範圍及其均等物所界定的範疇之中。Although the present invention has been described with reference to the embodiments, the present invention is not limited by the detailed description thereof. Alternatives and modifications are suggested in the foregoing description, and other alternatives and modifications will be apparent to those skilled in the art. In particular, all combinations of components that are substantially identical to the invention can achieve substantially the same results as the present invention without departing from the spirit of the invention. Therefore, all such alternatives and modifications are intended to be within the scope of the invention as defined by the appended claims and their equivalents.

10...半導體晶圓10. . . Semiconductor wafer

12...主要前表面12. . . Main front surface

14...後表面14. . . Back surface

16...側邊16. . . Side

18...高分子層18. . . Polymer layer

20...高分子層塗佈系統20. . . Polymer coating system

22...承載溶液之容器twenty two. . . Container for carrying solution

24...高分子液體twenty four. . . Polymer liquid

26...滾輪26. . . Wheel

30...電源30. . . power supply

32...熱源32. . . Heat source

34...反應室34. . . Reaction chamber

36...電鍍晶圓的系統36. . . Plating wafer system

38...承載溶液之容器38. . . Container for carrying solution

40...電鍍液40. . . Plating solution

42...陽極42. . . anode

44...陰極44. . . cathode

46...電鍍系統46. . . Plating system

48...承載基座48. . . Carrying base

50...機器手臂50. . . Robotic arm

52...第一機台52. . . First machine

54...第二機台54. . . Second machine

56...第三機台56. . . Third machine

58...第四機台58. . . Fourth machine

本發明係由申請專利範圍所界定。這些和其它目的,特徵,和實施例,會在下列實施方式的章節中搭配圖式被描述,其中:The invention is defined by the scope of the patent application. These and other objects, features, and embodiments are described in the following sections of the accompanying drawings, in which:

第1圖顯示根據本發明一範例實施例之半導體晶圓的上視及剖面(係沿著虛線)圖。1 shows a top view and a cross section (along a broken line) of a semiconductor wafer in accordance with an exemplary embodiment of the present invention.

第2圖顯示根據本發明一範例實施例,用來施加高分子層於晶圓之上的系統示意圖。2 is a schematic diagram of a system for applying a polymer layer on a wafer in accordance with an exemplary embodiment of the present invention.

第3a~3d圖顯示根據第2圖中本發明一範例實施例的系統一部份,當晶圓被旋轉時的示意圖。Figures 3a to 3d show schematic views of a portion of the system according to an exemplary embodiment of the present invention in Figure 2 when the wafer is rotated.

第4圖顯示根據本發明一範例實施例之電鍍晶圓的系統之剖面圖。4 is a cross-sectional view showing a system for plating a wafer in accordance with an exemplary embodiment of the present invention.

第5圖顯示本發明之範例實施例可以進一步提供一整合電鍍系統以進行此晶圓電鍍及嵌鑲製程中相關製程的許多不同操作的方塊示意圖。Figure 5 shows a block diagram of an exemplary embodiment of the present invention that may further provide an integrated plating system for performing many different operations in the wafer plating and inlay process.

第6及第7圖顯示根據本發明之範例實施例之許多不同操作之製程流程圖。Figures 6 and 7 show a process flow diagram for many different operations in accordance with an exemplary embodiment of the present invention.

20...高分子層塗佈系統20. . . Polymer coating system

22...承載溶液之容器twenty two. . . Container for carrying solution

24...高分子液體twenty four. . . Polymer liquid

26...滾輪26. . . Wheel

30...電源30. . . power supply

32...熱源32. . . Heat source

34...反應室34. . . Reaction chamber

Claims (23)

一種積體電路製造方法,包含:提供一半導體晶圓,該晶圓具有相對的主要前表面及後表面,其由一側邊連接在一起,該晶圓可以進行包括電鍍一嵌鑲層於該晶圓上的製程;於電鍍該嵌鑲層之前,施加一高分子塗佈於該晶圓的該側邊,該高分子塗佈施加於該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分,該高分子塗佈係作為防止該嵌鑲層形成於該晶圓的該側邊之一阻障層;其中該高分子塗佈層係由一電源所驅動之一電泳技術來實施。An integrated circuit manufacturing method comprising: providing a semiconductor wafer having opposite major front and back surfaces, which are connected by one side, and the wafer can be plated to include an inlay layer thereon a process on the wafer; before plating the inlay layer, applying a polymer to the side of the wafer, the polymer coating is applied to the side but not to the main front surface of the wafer And at least a part of the rear surface, the polymer coating system is formed as a barrier layer for preventing the mosaic layer from being formed on the side of the wafer; wherein the polymer coating layer is driven by a power source Technology to implement. 如申請專利範圍第1項所述之方法,其中施加於該晶圓的該主要前表面及後表面之該高分子塗佈的寬度介於3~5mm,且該主要前表面及後表面具有大於3~5mm之半徑。The method of claim 1, wherein the polymer coated on the main front surface and the back surface of the wafer has a width of 3 to 5 mm, and the main front surface and the back surface have a larger diameter. Radius of 3~5mm. 如申請專利範圍第1項所述之方法,其中施加該高分子塗佈包含:將該晶圓與一高分子液體接觸使得該高分子塗佈於該晶圓的該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分;以及熱固化該晶圓的該側邊之該高分子液體塗佈以形成該高分子塗佈。The method of claim 1, wherein applying the polymer coating comprises: contacting the wafer with a polymer liquid such that the polymer is coated on the side of the wafer but not in the crystal At least a portion of the major front and back surfaces of the circle; and the polymeric liquid that thermally cures the side of the wafer is coated to form the polymer coating. 如申請專利範圍第3項所述之方法,其中施加該高分子塗佈係在於形成一薄的銅種子層之後及在電鍍形成該嵌鑲層之前所施加,以及該高分子塗佈的施加係在具有降低壓力或惰性氣體下進行,以至少降低該種子層於該高分子液體固化時被氧化。The method of claim 3, wherein applying the polymer coating is performed after forming a thin copper seed layer and before plating to form the mosaic layer, and the polymer coated application system It is carried out under a reduced pressure or inert gas to at least reduce the oxidation of the seed layer upon solidification of the polymer liquid. 如申請專利範圍第3項所述之方法,其中施加該高分子塗佈包括:將該晶圓支撐於該高分子液體的一承載容器之上使得該晶圓的該主要前表面及後表面大致與該高分子液體一上表面之平面垂直,且使得該側邊的至少一部分但是沒有於該晶圓的該主要前表面及後表面之至少一部分浸入該高分子液體中;以及將該晶圓在大致與該主要前表面及後表面垂直之一軸向上旋轉以將該晶圓的該側邊連續接觸部分可以被浸入及移出該高分子液體中。The method of claim 3, wherein applying the polymer coating comprises: supporting the wafer on a carrier of the polymer liquid such that the main front surface and the back surface of the wafer are substantially And the polymer liquid is perpendicular to a plane of the upper surface, and at least a portion of the side but not at least a portion of the main front and back surfaces of the wafer is immersed in the polymer liquid; and the wafer is One of the portions perpendicular to the major front surface and the rear surface is axially rotated to continuously contact the side of the wafer to be immersed in and removed from the polymer liquid. 如申請專利範圍第5項所述之方法,其中熱固化該高分子液體包含在該晶圓的該側邊連續接觸部分被移出該高分子液體時加以熱固化該高分子液體。The method of claim 5, wherein thermally curing the polymer liquid comprises thermally curing the polymer liquid when the continuous contact portion of the side of the wafer is removed from the polymer liquid. 如申請專利範圍第1項所述之方法,更包括:於施加該高分子塗佈之後,電鍍形成該嵌鑲層於該晶圓之上,該嵌鑲層包覆蓋未被該高分子塗佈所包覆之該主要前表面及後表面的部分。The method of claim 1, further comprising: after applying the polymer coating, electroplating to form the mosaic layer on the wafer, the cladding layer covering is not coated with the polymer The portion of the major front and back surfaces that are coated. 如申請專利範圍第1項所述之方法,更包括:於電鍍形成該嵌鑲層之後將該高分子塗佈移除。The method of claim 1, further comprising: removing the polymer coating after electroplating to form the mosaic layer. 如申請專利範圍第8項所述之方法,其中該製程更包括對該晶圓進行化學機械研磨,以及其中該高分子塗佈係由該化學機械研磨移除。The method of claim 8, wherein the process further comprises chemical mechanical polishing of the wafer, and wherein the polymer coating is removed by the chemical mechanical polishing. 如申請專利範圍第8項所述之方法,其中該製程更包括對該晶圓進行化學機械研磨,以及其中該高分子塗佈係於該化學機械研磨之前由一溶劑或是研磨液移除。The method of claim 8, wherein the process further comprises chemical mechanical polishing of the wafer, and wherein the polymer coating is removed by a solvent or a slurry prior to the chemical mechanical polishing. 一種積體電路製造系統,包含:一電源供應可與一半導體晶圓連接,該晶圓具有相對的主要前表面及後表面,其由一側邊連接在一起,該晶圓可以進行包括電鍍一嵌鑲層於該晶圓上的製程;一安排組態為可以於電鍍該嵌鑲層之前施加一高分子塗佈於該晶圓的該側邊,該高分子塗佈施加於該晶圓的該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分,該高分子塗佈係作為防止該嵌鑲層形成於該晶圓的該側邊之一阻障層;其中該系統係組態為由一電源所驅動之一電泳技術來施加該高分子塗佈層。An integrated circuit manufacturing system comprising: a power supply connectable to a semiconductor wafer having opposite major front and back surfaces, connected by one side, the wafer can be electroplated a process of inserting a layer on the wafer; a configuration configured to apply a polymer to the side of the wafer before plating the inlay layer, the polymer coating being applied to the wafer The side layer is not at least a portion of the main front surface and the back surface of the wafer, and the polymer coating system serves as a barrier layer for preventing the mosaic layer from being formed on the side of the wafer; The system is configured to apply the polymer coating layer by an electrophoresis technique driven by a power source. 如申請專利範圍第11項所述之系統,其中施加於該晶圓的該主要前表面及後表面之該高分子塗佈的寬度介於3~5mm,且該主要前表面及後表面具有大於3~5mm之半徑。The system of claim 11, wherein the polymer coated on the main front surface and the back surface of the wafer has a width of 3 to 5 mm, and the main front surface and the rear surface have a larger diameter. Radius of 3~5mm. 如申請專利範圍第11項所述之系統,其中該安排包含:一基座以組態為將該晶圓與一高分子液體接觸使得該高分子塗佈於該晶圓的該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分;以及一熱源組態為熱固化該晶圓的該側邊之該高分子液體塗佈以形成該高分子塗佈。The system of claim 11, wherein the arrangement comprises: a susceptor configured to contact the wafer with a polymeric liquid such that the polymer is applied to the side of the wafer but not At least a portion of the major front and back surfaces of the wafer; and a heat source configured to thermally cure the polymeric liquid on the side of the wafer to form the polymer coating. 如申請專利範圍第13項所述之系統,其中該安排組態為施加該高分子塗佈係在於形成一薄的銅種子層之後及在電鍍形成該嵌鑲層之前所施加,以及該系統更包含:一反應室,在其中可將該晶圓密封以進行該熱源的熱固化該高分子塗佈,該反應室具有降低壓力或惰性氣體的環境,以至少降低該種子層於該高分子液體固化時被氧化。The system of claim 13, wherein the arrangement is configured to apply the polymer coating after the formation of a thin copper seed layer and before plating to form the mosaic layer, and the system is further The invention comprises: a reaction chamber in which the wafer can be sealed for thermal curing of the heat source, and the reaction chamber has an environment for reducing pressure or an inert gas to at least reduce the seed layer to the polymer liquid It is oxidized when it is cured. 如申請專利範圍第13項所述之系統,其中該安排更包括:充滿一高分子液體的一承載容器,其中該承載容器具有一個多個滾輪組態為將該晶圓支撐於該承載容器之上使得該晶圓的該主要前表面及後表面大致與該高分子液體一上表面之平面垂直,且使得該側邊的至少一部分但是沒有於該晶圓的該主要前表面及後表面之至少一部分浸入該高分子液體中;以及其中該一個多個滾輪組態為將該晶圓在大致與該主要前表面及後表面垂直之一軸向上旋轉以將該晶圓的該側邊連續接觸部分可以被浸入及移出該高分子液體中。The system of claim 13, wherein the arrangement further comprises: a carrying container filled with a polymer liquid, wherein the carrying container has a plurality of rollers configured to support the wafer in the carrying container The main front surface and the rear surface of the wafer are substantially perpendicular to a plane of the upper surface of the polymer liquid, and at least a portion of the side surface is not at least the main front surface and the back surface of the wafer Partially immersed in the polymeric liquid; and wherein the one or more rollers are configured to rotate the wafer axially about one of the major front and back surfaces to continuously contact the side of the wafer It is immersed in and removed from the polymer liquid. 如申請專利範圍第15項所述之系統,其中該熱源組態為在該晶圓的該側邊連續接觸部分被移出該高分子液體時加以熱固化該高分子液體。The system of claim 15, wherein the heat source is configured to thermally cure the polymer liquid when the continuous contact portion of the side of the wafer is removed from the polymer liquid. 一種積體電路電鍍系統,包含:一第一機台組態為施加一高分子塗佈於一半導體晶圓上,該晶圓具有相對的主要前表面及後表面,其由一側邊連接在一起,該高分子塗佈施加於該晶圓的該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分;以及一第二機台組態為自該第一機台接收該晶圓,該第二機台組態為電鍍一嵌鑲層於晶圓上,該高分子塗佈係作為防止該嵌鑲層形成於該晶圓的該側邊之一阻障層。An integrated circuit plating system comprising: a first machine configured to apply a polymer coated on a semiconductor wafer, the wafer having opposite major front and back surfaces, connected by one side Together, the polymer coating is applied to the side of the wafer but not to at least a portion of the major front and back surfaces of the wafer; and a second machine is configured to receive from the first machine The wafer is configured to plate an inlay layer on the wafer, the polymer coating being a barrier layer that prevents the inlay layer from being formed on the side of the wafer. 如申請專利範圍第17項所述之積體電路電鍍系統,其中施加於該晶圓的該主要前表面及後表面側邊之該高分子塗佈的寬度介於3~5mm,且該主要前表面及後表面具有大於3~5mm之半徑。The integrated circuit plating system according to claim 17, wherein the polymer coated width applied to the main front surface and the rear surface side of the wafer is between 3 and 5 mm, and the main front The surface and the back surface have a radius greater than 3 to 5 mm. 如申請專利範圍第17項所述之積體電路電鍍系統,其中該第一機台包含:一基座以組態為將該晶圓與一高分子液體接觸使得該高分子塗佈於該晶圓的該側邊但是沒有於該晶圓的該主要前表面及後表面之至少一部分;以及一熱源組態為熱固化該晶圓的該側邊之該高分子液體塗佈以形成該高分子塗佈。The integrated circuit plating system of claim 17, wherein the first machine comprises: a base configured to contact the polymer with a polymer liquid such that the polymer is coated on the crystal The side of the circle but not at least a portion of the major front and back surfaces of the wafer; and a heat source configured to thermally cure the polymer liquid on the side of the wafer to form the polymer Coating. 如申請專利範圍第17項所述之積體電路電鍍系統,其中該第一機台組態為施加該高分子塗佈係在於形成一薄的銅種子層之後及在電鍍形成該嵌鑲層之前所施加,以及該第一機台更包含:一反應室,在其中可將該晶圓密封以進行該熱源的熱固化該高分子塗佈,該反應室具有降低壓力或惰性氣體的環境,以至少降低該種子層於該高分子液體固化時被氧化。The integrated circuit plating system of claim 17, wherein the first machine is configured to apply the polymer coating after forming a thin copper seed layer and before plating to form the mosaic layer. Applied, and the first machine further comprises: a reaction chamber in which the wafer can be sealed for thermal curing of the heat source, the reaction chamber having an environment for reducing pressure or inert gas, At least the seed layer is reduced to be oxidized when the polymer liquid is cured. 如申請專利範圍第19項所述之積體電路電鍍系統,其中該第一機台更包括:充滿一高分子液體的一承載容器,其中該承載容器具有一個多個滾輪組態為將該晶圓支撐於該承載容器之上使得該晶圓的該主要前表面及後表面大致與該高分子液體一上表面之平面垂直,且使得該側邊的至少一部分但是沒有於該晶圓的該主要前表面及後表面之至少一部分浸入該高分子液體中;以及其中該一個多個滾輪組態為將該晶圓在大致與該主要前表面及後表面垂直之一軸向上旋轉以將該晶圓的該側邊連續接觸部分可以被浸入及移出該高分子液體中。The integrated circuit plating system according to claim 19, wherein the first machine further comprises: a carrying container filled with a polymer liquid, wherein the carrying container has a plurality of rollers configured to the crystal a circular support on the carrier such that the major front and back surfaces of the wafer are substantially perpendicular to a plane of the upper surface of the polymer liquid, and such that at least a portion of the side but not the primary of the wafer At least a portion of the front surface and the back surface are immersed in the polymeric liquid; and wherein the one or more rollers are configured to rotate the wafer axially about one of the major front and back surfaces to substantially The side continuous contact portion can be immersed in and removed from the polymer liquid. 如申請專利範圍第21項所述之積體電路電鍍系統,其中該熱源組態為在該晶圓的該側邊連續接觸部分被移出該高分子液體時加以熱固化該高分子液體。The integrated circuit plating system of claim 21, wherein the heat source is configured to thermally cure the polymer liquid when the continuous contact portion of the side of the wafer is removed from the polymer liquid. 如申請專利範圍第17項所述之積體電路電鍍系統,更包括:一第三機台組態為自該第二機台接收該晶圓,該第三機台用來在該電鍍之後清潔及乾燥該晶圓;以及一第四台組態為自該第三機台接收該晶圓,該第四機台用來對該晶圓退火。The integrated circuit plating system of claim 17, further comprising: a third machine configured to receive the wafer from the second machine, the third machine being used for cleaning after the plating And drying the wafer; and a fourth station configured to receive the wafer from the third machine, the fourth machine for annealing the wafer.
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