TW201309597A - Desalinization system and desalinization method - Google Patents

Desalinization system and desalinization method Download PDF

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TW201309597A
TW201309597A TW101114364A TW101114364A TW201309597A TW 201309597 A TW201309597 A TW 201309597A TW 101114364 A TW101114364 A TW 101114364A TW 101114364 A TW101114364 A TW 101114364A TW 201309597 A TW201309597 A TW 201309597A
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seawater
membrane
water
domestic sewage
desalination system
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TW101114364A
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Akira Sasaki
Kazuhiko Noto
Yasunori SEKINE
Kotaro Kitamura
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Hitachi Plant Technologies Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/58Multistep processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • C02F3/1273Submerged membrane bioreactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2317/00Membrane module arrangements within a plant or an apparatus
    • B01D2317/02Elements in series
    • B01D2317/022Reject series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2317/00Membrane module arrangements within a plant or an apparatus
    • B01D2317/02Elements in series
    • B01D2317/025Permeate series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies

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  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The desalinization system (S) in the first present invention, which converts seawater and wastewater to fresh water, is provided with a heat exchanger (6) that exchanges heat between wastewater or treated wastewater and seawater. The desalinization system (S) in the second present invention, which also converts seawater and wastewater to fresh water, is provided with the following: a membrane-separation activated-sludge treatment device (1) that treats wastewater using a membrane-separation activated-sludge method; a first RO membrane (2) that removes salt from the output (s5a) of the membrane-separation activated-sludge treatment device (1) by transferring said salt to first concentrated water (s6), thereby producing industrial-use water (s1); a UF membrane (3) that seawater passes through and that removes particulates from said seawater; a second RO membrane (5), to which treated water (s5b) that has passed through the UF membrane (3) is sent, whereby salt is removed from said treated water (s5b) and transferred to second concentrated water (s7), thereby producing drinking water (s2); and a heat exchanger (6) that exchanges heat between the wastewater or treated wastewater (s5a, s6, s1) and seawater.

Description

海水淡化系統以及海水淡化方法 Seawater desalination system and seawater desalination method

本發明係關於將海水與家庭污水予以淡水化(淡化)的海水淡化系統以及海水淡化方法。 The present invention relates to a seawater desalination system and a seawater desalination method for desalination (desalination) of seawater and domestic sewage.

近年來,隨著世界性人口的增多以及包含新興國家在內的大區域性產業的進展,在砂漠地帶等區域的飲用水和工業用水的造水需求顯著地增加中。 In recent years, with the increase in the world population and the progress of large-scale industries including emerging countries, the demand for water for drinking water and industrial water in areas such as sand deserts has increased significantly.

傳統上,作為將海水、家庭污水予以淡水化的系統,係有如第6圖所示的海水淡化系統S100。 Conventionally, as a system for desalination of seawater and domestic sewage, a seawater desalination system S100 as shown in Fig. 6 is provided.

使用海水淡化系統S100中的家庭污水來製造生產水s101(工業用水)的方式係根據以下所述的方式來進行的。又,家庭污水的鹽分濃度是0.1%程度。 The manner in which the produced water s101 (industrial water) is produced using domestic sewage in the seawater desalination system S100 is carried out in the manner described below. Also, the salt concentration of domestic sewage is about 0.1%.

家庭污水是藉由泵浦p101送往適用膜分離活性污泥法的MBR(膜生物反應器;Membrane Bioreactor;以下簡稱MBR)101,利用MBR101來將家庭污水中的活性污泥等予以除去,穿透過MBR101之後的MBR透過水是利用泵浦p102再送往低壓RO膜(逆滲透膜;Reverse Osmosis Membrane;以下簡稱RO膜)102。 The domestic sewage is sent to the MBR (membrane bioreactor; Membrane Bioreactor; MBR) 101 by the pump p101 to separate the activated sludge method, and the MBR101 is used to remove the activated sludge in the domestic sewage and wear it. The MBR permeate water after passing through the MBR 101 is sent to the low pressure RO membrane (Reverse Osmosis Membrane; hereinafter referred to as RO membrane) 102 by the pump p102.

此外,穿透過MBR101之後的MBR透過水,其中的鹽分濃度很低只有0.1%程度而已,因此RO膜係使用低壓的RO膜(逆浸透膜),亦即約1~2MPa(百萬帕斯卡)的低壓RO膜102。 In addition, the MBR permeating water after passing through the MBR101 has a salt concentration of only 0.1%, so the RO membrane system uses a low pressure RO membrane (reverse osmosis membrane), that is, about 1 to 2 MPa (million Pascal). Low pressure RO membrane 102.

被泵浦p102所給送的MBR透過水藉由穿透過低壓RO膜102而被淡化,大約有一半係被當作生產水s101(工業用水)生產出來,剩餘的一半則是作為含有鹽分之類的雜質的濃縮水s104被分離而除去。 The MBR permeated water supplied by the pump p102 is diluted by penetrating the low pressure RO membrane 102, and about half of it is produced as production water s101 (industrial water), and the remaining half is used as salt content. The concentrated water s104 of the impurities is separated and removed.

被低壓RO膜102所除去之含有鹽分等的雜質的鹽分濃度已經被濃縮到達0.2%程度之大約為家庭污水的1/2容量的濃縮水s104,是從低壓RO膜102給送到攪拌槽104。 The salt concentration of the impurity containing salt or the like removed by the low pressure RO membrane 102 has been concentrated to a concentration of about 0.2% of the concentrated water s104 of about 1/2 capacity of the domestic sewage, and is supplied from the low pressure RO membrane 102 to the stirring tank 104. .

從海水淡化系統S100中的海水來製造生產水s102亦即工業用水的方式係根據以下所述的方式來進行的。又,海水的鹽分濃度是3~4%程度。 The manner in which the produced water s102, that is, the industrial water, is produced from the seawater in the seawater desalination system S100 is carried out in the manner described below. Moreover, the salt concentration of seawater is about 3 to 4%.

海水是利用泵浦p103給送到UF膜(超濾膜;Ultrafiltraction Membrane;以下簡稱UF膜)103,利用UF膜103將粒子除去之後,給送到攪拌槽104。在攪拌槽104中,對於這個已經穿透過UF膜103之後的UF膜透過海水、和前述之利用低壓RO膜102來從家庭污水濃縮後之大約為家庭污水1/2程度的容量的濃縮水s104進行攪拌之後,利用泵浦p104給送到中壓RO膜105。 The seawater is sent to the UF membrane (Ultrafiltraction Membrane; UF membrane) 103 by the pump p103, and the particles are removed by the UF membrane 103, and then sent to the agitation vessel 104. In the agitation tank 104, the concentrated water s104 having a capacity of about 1/2 of the domestic sewage for the UF membrane which has penetrated the UF membrane 103 and the seawater after the above-mentioned low-pressure RO membrane 102 is concentrated from the domestic sewage. After the stirring, the pump p104 is fed to the medium pressure RO membrane 105.

穿透過UF膜103之後的UF膜透過海水,雖然是3~4%的鹽分濃度,但是受到鹽分濃度為0.2%的濃縮水s104所稀釋,因此可使用中壓之約3~5MPa的RO膜(逆浸透膜)亦即,中壓RO膜105。 The UF film that has penetrated the UF film 103 permeates seawater, and although it is a salt concentration of 3 to 4%, it is diluted by the concentrated water s104 having a salt concentration of 0.2%, so that an RO film of about 3 to 5 MPa at a medium pressure can be used ( Reverse osmosis membrane), that is, medium pressure RO membrane 105.

從攪拌槽104利用泵浦p104給送到中壓RO膜105的混合水s103係藉由穿透過中壓RO膜105而被淡化, 使得其中1/2程度被當成淡水化後的生產水s102(工業用水)而生產出來,剩餘的1/2程度則是當作含有鹽分等的雜質之鹵水s105被分離除去。換言之,生產水s102(工業用水)的生產量,是相當於海水的1/2再加上家庭污水的1/4的程度的容量。 The mixed water s103 fed from the agitation tank 104 to the intermediate pressure RO membrane 105 by the pump p104 is diluted by the intermediate pressure RO membrane 105. The 1/2 degree is produced as the production water s102 (industrial water) which is desalinated, and the remaining 1/2 degree is separated and removed as the brine s105 containing impurities such as salt. In other words, the production amount of production water s102 (industrial water) is equivalent to 1/2 of seawater plus 1/4 of domestic sewage.

亦即,鹵水s105的排水量是海水的1/2再加上家庭污水的1/4程度的容量。 That is, the displacement of the brine s105 is 1/2 of that of seawater plus a quarter of the capacity of domestic sewage.

此外,鹵水s105的壓力能量,係被動力回收裝置106將其當成旋轉能量加以回收,並且將其當成把迂迴過泵浦p104之後的一部分混合水s103壓送到中壓RO膜105的動力源(能量源)來使用。 Further, the pressure energy of the brine s105 is recovered by the power recovery device 106 as rotational energy, and is taken as a power source for pressing a part of the mixed water s103 after the pumping back to the intermediate pressure RO membrane 105 ( Energy source) to use.

傳統之其他種類的海水淡化系統,係有如第7圖所示的海水淡化系統S200。 A conventional seawater desalination system is a seawater desalination system S200 as shown in Fig. 7.

海水淡化系統S200,對於第6圖的海水淡化系統S100中的家庭污水的濃縮水s104,並不將其給送到攪拌槽204,而是採用:家庭污水的淡水化與海水的淡水化之兩個獨立的處理流程。 The seawater desalination system S200 does not feed the concentrated water s104 of the domestic sewage in the seawater desalination system S100 of FIG. 6 to the agitation tank 204, but adopts two methods: desalination of domestic sewage and desalination of seawater. A separate process.

在海水淡化系統S200中,粒子雖然被UF膜203所除去,但是攪拌槽204內之海水並不受到來自家庭污水的送水(第6圖中的家庭污水的濃縮水s104)所稀釋。因此,鹽分濃度較高,約為3~4%的程度,必須使用高壓的RO膜(逆浸透膜),亦即約6~8MPa的高壓RO膜205。 In the seawater desalination system S200, although the particles are removed by the UF film 203, the seawater in the agitation tank 204 is not diluted by the water supply from the domestic sewage (the concentrated water s104 of the domestic sewage in Fig. 6). Therefore, the salt concentration is relatively high, about 3 to 4%, and a high pressure RO membrane (reverse osmosis membrane), that is, a high pressure RO membrane 205 of about 6 to 8 MPa must be used.

海水淡化系統S200,係將家庭污水穿透過低壓RO膜 202而予以淡水化,可獲得家庭污水的大約一半量的生產水s201(工業用水)。另一方面,海水則是利用UF膜203將粒子除去之後,穿透過高壓RO膜205而予以淡水化,可獲得海水的1/2量的生產水s203(飲用水)。 Seawater desalination system S200, which penetrates domestic sewage through low pressure RO membrane 202 is desalinated to obtain about half of the production water s201 (industrial water) of domestic sewage. On the other hand, in the seawater, the particles are removed by the UF membrane 203, and then passed through the high-pressure RO membrane 205 to be desalinated, and 1/2 amount of production water s203 (drinking water) of seawater can be obtained.

至於其他的結構,則都與第6圖的海水淡化系統S100相同,因此,係針對於海水淡化系統S100的構成要件,改為標示成200字頭編號中的元件符號,並省略其詳細說明。 The other structures are the same as those of the seawater desalination system S100 of Fig. 6, and therefore, the components of the seawater desalination system S100 are replaced with the component symbols in the 200-head number, and the detailed description thereof will be omitted.

傳統的海水淡化系統S100(請參考第6圖)與海水淡化系統S200(請參考第7圖)進行比較,係具有下列的優點。 The conventional seawater desalination system S100 (please refer to Figure 6) is compared with the desalination system S200 (please refer to Figure 7), which has the following advantages.

第1優點是:因為在第6圖的海水淡化系統S100中,係將從家庭污水來製造生產水s101的過程中被分離除去的排水(濃縮水s104),使用於從海水來製造生產水s102的過程當中,因此,具有可提高從海水製造出生產水的生產量之優點。 The first advantage is that, in the seawater desalination system S100 of Fig. 6, the wastewater (concentrated water s104) separated and removed during the process of producing the produced water s101 from domestic sewage is used to produce the produced water s102 from seawater. In the process, therefore, there is an advantage that the production amount of produced water from seawater can be increased.

具體而言,如果未使用來自家庭污水的排水(濃縮水s104)的話,來自海水的生產水是只有海水的1/2程度的容量,但是根據海水淡化系統S100,可增加家庭污水的1/2程度容量的增水量,可多製造出生產水s102(工業用水)。 Specifically, if the wastewater from the domestic sewage (concentrated water s104) is not used, the production water from the seawater is only 1/2 of the capacity of the seawater, but according to the seawater desalination system S100, the domestic sewage can be increased by 1/2. The amount of water in the capacity can be increased to produce water s102 (industrial water).

第2優點是:海水(鹽分濃度3~4%程度)是被加入家庭污水之被低壓RO膜102分離後的濃縮水s104(鹽分濃度0.2%程度),所以海水受到稀釋而鹽分濃度降低 。因此,如果未使用來自家庭污水的排水(濃縮水s104)的情況下,海水因為鹽分濃度較高,必須使用高壓RO膜205,但是因為受到了濃縮水s104所稀釋,所以只要使用中壓RO膜105即可,泵浦p104所需的動力也可較之使用高壓RO膜205的情況更為降低。 The second advantage is that the seawater (the salt concentration is about 3 to 4%) is the concentrated water s104 (the salt concentration is 0.2%) separated from the low-pressure RO membrane 102 by the domestic sewage, so the seawater is diluted and the salt concentration is lowered. . Therefore, if the drainage (concentrated water s104) from domestic sewage is not used, the high-pressure RO membrane 205 must be used because the salt concentration is high, but since it is diluted by the concentrated water s104, the medium-pressure RO membrane is used. 105, the power required to pump p104 can be reduced compared to the case of using high pressure RO membrane 205.

因為,相對於中壓RO膜的穿透壓力(滲透壓力)是約3~5MPa,高壓RO膜的穿透壓力是約6~8MPa,要穿透過高壓RO膜時,必須使用較之穿透中壓RO膜時更大的動力(能量)。 Because the penetration pressure (osmotic pressure) relative to the medium pressure RO membrane is about 3 to 5 MPa, the penetration pressure of the high pressure RO membrane is about 6 to 8 MPa. When it is to penetrate the high pressure RO membrane, it must be used in comparison. Greater power (energy) when pressing the RO membrane.

此外,在本案的說明書中係舉出專利文獻1作為先前技術文獻。 Further, Patent Document 1 is cited as a prior art document in the specification of the present case.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本特許第4481345號公報 [Patent Document 1] Japanese Patent No. 4481345

然而,在傳統的海水淡化系統S100、S200之中,係存在著以下的問題。 However, among the conventional seawater desalination systems S100 and S200, the following problems exist.

第1個問題是:UF膜和RO膜的透過度(滲透度)是與透過液體之間具有很高的溫度依存性。 The first problem is that the permeability (permeability) of the UF film and the RO film is highly temperature-dependent with the permeated liquid.

海水淡化系統S100、S200雖然可將海水予以淡水化,但是因為國家、地域的不同,有時候海水是低溫的。這 種情況下,在海水淡化系統S100中,因為低溫的海水的緣故,海水對於UF膜103和中壓RO膜105的透過度,會因為黏度的上昇等的因素而降低。因此,要使低溫的海水穿透過UF膜103和中壓RO膜105,泵浦p103、p104必需使用更多的動力,係有消耗動力變得更大之問題。 Although the seawater desalination systems S100 and S200 can desalinate seawater, seawater is sometimes low in temperature depending on the country and region. This In the case of the seawater desalination system S100, the permeability of the seawater to the UF membrane 103 and the intermediate pressure RO membrane 105 due to the low-temperature seawater is lowered by factors such as an increase in viscosity. Therefore, in order to allow the low-temperature seawater to penetrate the UF film 103 and the medium-pressure RO film 105, the pumps p103 and p104 must use more power, which is a problem that the power consumption becomes larger.

同樣地,在海水淡化系統S200中,因為低溫的海水的緣故,海水對於UF膜203和高壓RO膜205的透過度會降低。因此,要使低溫的海水穿透過UF膜203和高壓RO膜205,泵浦p203、p204必需使用更多的動力,係有消耗動力變得更大之問題。 Similarly, in the seawater desalination system S200, the permeability of the seawater to the UF membrane 203 and the high pressure RO membrane 205 is lowered due to the low temperature seawater. Therefore, in order to allow the low-temperature seawater to penetrate the UF film 203 and the high-pressure RO film 205, the pumps p203 and p204 must use more power, which is a problem that the power consumption becomes larger.

第2個問題是:在海水淡化系統S100中,被低壓RO膜102所分離的濃縮水s104,雖然是被泵浦p102所壓送,但是濃縮水s104的壓力能量並沒有被利用。同樣地,在海水淡化系統S200中,被低壓RO膜202所分離的鹵水s202,雖然是被泵浦p202所加壓,但是鹵水s202的壓力能量並沒有被利用。 The second problem is that in the seawater desalination system S100, the concentrated water s104 separated by the low pressure RO membrane 102 is pumped by the pump p102, but the pressure energy of the concentrated water s104 is not used. Similarly, in the seawater desalination system S200, the brine s202 separated by the low pressure RO membrane 202 is pressurized by the pump p202, but the pressure energy of the brine s202 is not utilized.

因此,難謂其能源被有效利用。 Therefore, it is difficult to say that its energy is being used effectively.

第3個問題是:海水淡化系統S100、S200都是設有四個泵浦,泵浦的製造成本、設置成本、維持管理成本等都是必要項目,會有導致成本增加的虞慮。 The third problem is that the seawater desalination system S100 and S200 are equipped with four pumps. The manufacturing cost, installation cost, and maintenance cost of the pump are all necessary items, which may cause cost increase.

本發明是有鑒於上述的實際狀況,其目的是提供:可有效地活用能源,能源成本低廉的海水淡化系統以及海水淡化方法。 The present invention has been made in view of the above-described actual circumstances, and an object thereof is to provide a seawater desalination system and a seawater desalination method which can effectively utilize energy, have low energy costs.

為了達成上述目的,本案的第1發明的海水淡化系統,係將海水與家庭污水予以淡水化的海水淡化系統,係具備:係將家庭污水或其處理水與海水進行熱交換之熱交換器。 In order to achieve the above object, the seawater desalination system of the first invention of the present invention is a seawater desalination system that desalinates seawater and domestic sewage, and is a heat exchanger that exchanges heat between domestic sewage or treated water and seawater.

本案的第3本發明的海水淡化方法,係用來達成本案的第1發明的海水淡化系統之方法。 The seawater desalination method of the third invention of the present invention is a method for achieving the seawater desalination system of the first invention of the present invention.

本案的第2發明的海水淡化系統,係將海水與家庭污水予以淡水化的海水淡化系統,係具備:將前述家庭污水利用膜分離活性污泥法來進行處理的膜分離活性污泥處理裝置、令已經穿透過前述膜分離活性污泥處理裝置之後的透過水再透過,將其鹽分含在第1濃縮水中予以除去,並且生成工業用水的第1RO膜、令前述海水穿透過而將該海水中的粒子予以除去的UF膜、令已經穿透過前述UF膜之後的處理水再穿透過,將該處理水的鹽分含在第2濃縮水中予以除去,並且生成飲用水的第2RO膜、將前述家庭污水或其處理水與前述海水進行熱交換的熱交換器。 The seawater desalination system according to the second aspect of the present invention is a seawater desalination system that desalinates seawater and domestic sewage, and includes a membrane separation activated sludge treatment device that treats the domestic sewage by membrane separation activated sludge method, The permeated water which has passed through the membrane separation activated sludge treatment apparatus is re-permeated, and the salt is contained in the first concentrated water to be removed, and the first RO membrane of the industrial water is produced, and the seawater is passed through to the seawater. The UF film to be removed by the particles is passed through the treated water which has passed through the UF film, and the salt of the treated water is removed in the second concentrated water to be removed, and the second RO film of the drinking water is produced. A heat exchanger in which sewage or treated water exchanges heat with the aforementioned seawater.

本案的第4發明的海水淡化方法,係用來達成本案的第2發明的海水淡化系統之方法。 The seawater desalination method of the fourth invention of the present invention is a method for achieving the seawater desalination system of the second invention of the present invention.

根據本發明的海水淡化系統以及海水淡化方法,係可達成:可有效地活用能源,能源成本低廉的海水淡化系統以及海水淡化方法。 According to the seawater desalination system and the seawater desalination method of the present invention, it is possible to achieve a seawater desalination system and a seawater desalination method which can effectively utilize energy, have low energy costs, and have a seawater desalination system.

茲佐以圖式,說明本發明的實施方式如下。 The embodiment of the present invention will be described below with reference to the drawings.

[實施方式1] [Embodiment 1]

第1圖係本發明的實施方式1的海水淡化系統的概念性結構圖。實施方式1的海水淡化系統S,為了從家庭污水來製造出工業用水s1,係具備:將家庭污水利用膜分離活性污泥法來進行處理的MBR(膜生物反應器;Membrane Bioreactor)1、以及可將含在家庭污水中的鹽分和離子等的雜質除去而將家庭污水予以淡水化的低壓RO膜(Reverse Osmosis Membrane)2。 Fig. 1 is a conceptual configuration diagram of a seawater desalination system according to Embodiment 1 of the present invention. In the seawater desalination system S of the first embodiment, in order to produce the industrial water s1 from the domestic sewage, the MBR (membrane bioreactor; Membrane Bioreactor) 1 for treating the domestic sewage by the membrane separation activated sludge method is provided. A low-pressure RO membrane (Reverse Osmosis Membrane) 2 which removes impurities such as salt and ions contained in domestic sewage and desalinates domestic sewage.

MBR1係進行固液分離而從家庭污水中,將活性污泥分離除去。 MBR1 is subjected to solid-liquid separation to separate and remove activated sludge from domestic sewage.

RO膜(逆浸透膜)係可讓水通過,但鹽分之類的低分子物質和離子則不易通過的半透過膜。低壓RO膜2是因為家庭污水的鹽分濃度很低只有0.1%程度而已,只要利用比較低的透過壓(滲透壓)約1~2MPa(百萬帕斯卡)就可將鹽分等予以除去之低壓的RO膜。 The RO membrane (reverse osmosis membrane) is a semi-permeable membrane that allows water to pass through, but low molecular substances such as salt and ions are not easily passed. The low-pressure RO membrane 2 is because the salt concentration of the domestic sewage is as low as 0.1%, and the low-pressure RO can be removed by using a relatively low permeation pressure (osmotic pressure) of about 1 to 2 MPa (million Pascal). membrane.

又,水淡化系統S為了從海水來製造出飲用水s2,係具備:用以除去含在海水中的粒子的UF膜(超濾膜;Ultrafiltration Membrane)3、將已經穿透過UF膜3而被除去粒子之後的海水攪拌均勻的攪拌槽4、將含在粒子已經被除去且在攪拌槽4中被攪拌後的海水中的鹽分和離子 等雜質予以除去,將海水予以淡水化之高壓RO膜5。此外,攪拌槽4也具有另一種功能,是可將準備供給到泵浦p4的海水予以暫時性的累積起來,而可確保泵浦p4進行穩定的作動。 Further, the water desalination system S is provided with a UF membrane (Ultrafiltration Membrane) 3 for removing particles contained in seawater in order to produce drinking water s2 from seawater, and has been penetrated by the UF membrane 3 The stirring tank 4 in which the seawater after the removal of the particles is uniformly stirred, and the salt and ions contained in the seawater after the particles have been removed and stirred in the stirring tank 4 A high-pressure RO membrane 5 which is removed by impurities and is desalinated by seawater. Further, the agitation tank 4 has another function of temporarily accumulating seawater to be supplied to the pump p4, and ensuring stable operation of the pump p4.

UF膜(超濾膜)3係根據膜的孔徑以及海水中的除去對象物質的分子的大小,來執行分子大小程度的篩選過濾處理,而將除去對象的粒子予以除去。 The UF membrane (ultrafiltration membrane) 3 performs screening and filtration processing of a molecular size level according to the pore diameter of the membrane and the size of the molecule of the object to be removed in the seawater, and removes the particles to be removed.

高壓RO膜5,是因為海水的鹽分濃度是3~4%程度,所以必須使用比較高的透過壓,約6~8MPa(百萬帕斯卡)的壓力來將鹽分等予以除去之高壓的RO膜。 Since the high-pressure RO membrane 5 has a salt concentration of 3 to 4%, it is necessary to use a relatively high transmission pressure and a high-pressure RO membrane which removes salt by a pressure of about 6 to 8 MPa (million Pascal).

然而,海水淡化系統S所使用的家庭污水,因為是流經過地面下,所以例如:若在溫帶的地區的話,比較溫暖,約有15~20℃的溫度。另一方面,海水淡化系統S所使用的海水,因為是曝露在大氣之下,容易受到氣候變動的影響,亦即,很容易受到氣溫變動的影響,所以在秋季,有時會有10℃前後的低溫情況發生。 However, the domestic sewage used in the desalination system S is flowed through the ground, so for example, if it is in a temperate zone, it is warmer, and has a temperature of about 15 to 20 °C. On the other hand, the seawater used in the desalination system S is exposed to the atmosphere and is susceptible to climate change, that is, it is easily affected by temperature changes, so in the autumn, there may be 10 °C or so. The low temperature situation occurs.

如前所述,進行海水淡化所使用的UF膜3、高壓RO膜5,對於透過液體的溫度依存性很高,係具有:低溫時透過度(滲透度)很低,高溫時透過度很高的傾向。 As described above, the UF film 3 and the high-pressure RO film 5 used for seawater desalination have high temperature dependence on the permeated liquid, and have low permeability (permeability) at low temperatures and high transmittance at high temperatures. Propensity.

因此,在海水淡化系統S中,係具有:可將家庭污水所保有的熱能施予到海水身上之可進行熱交換的熱交換器6。具體而言,熱交換器6係將流經過用以將家庭污水淡化的路徑之MBR1的上游的流路r11中的家庭污水,與流經過用以將海水淡化的路徑的UF膜3的上游的流路r2中 的海水,進行熱交換,以將家庭污水的熱能藉由熱交換而賦予到海水身上。 Therefore, in the seawater desalination system S, there is a heat exchanger 6 capable of imparting heat exchange to the seawater by the heat energy retained by the domestic sewage. Specifically, the heat exchanger 6 is configured to flow domestic sewage in the flow path r11 upstream of the MBR 1 for the path for desalination of the domestic sewage, and upstream of the UF film 3 flowing through the path for desalination of the sea water. Flow path r2 The sea water is exchanged for heat to transfer the heat of domestic sewage to the sea by heat exchange.

熱交換器6係由以下的各種實施方式來構成的。 The heat exchanger 6 is constructed by the following various embodiments.

第2圖係顯示海水淡化系統中的熱交換器的各種組合變化的概念圖。第2圖(a)係顯示將海水流送到家庭污水的流路中以進行熱交換的熱交換器之概念圖;第2圖(b)係顯示將家庭污水流送到海水的流路中以進行熱交換的熱交換器之概念圖;第2圖(c)係顯示將熱媒體流送到家庭污水的流路與海水的流路中以進行熱交換的熱交換器之概念圖。 Figure 2 is a conceptual diagram showing various combinations of heat exchangers in a desalination system. Fig. 2(a) is a conceptual diagram showing a heat exchanger that transfers seawater to a domestic sewage flow path for heat exchange; and Fig. 2(b) shows a flow of domestic sewage to seawater. A conceptual diagram of a heat exchanger for performing heat exchange; and Fig. 2(c) is a conceptual diagram showing a heat exchanger for transferring a heat medium to a flow path of domestic sewage and a seawater flow path for heat exchange.

第2圖(a)所示的熱交換器6A係製作成:將UF膜3的上游的流路r2內的海水流送到MBR1的上游的家庭污水的流路r11內,藉此,將家庭污水的熱能利用熱交換而賦予到海水身上。 The heat exchanger 6A shown in Fig. 2(a) is formed by flowing seawater in the flow path r2 upstream of the UF membrane 3 to the flow path r11 of the domestic sewage upstream of the MBR 1, thereby The heat energy of the sewage is imparted to the seawater by heat exchange.

第2圖(b)所示的熱交換器6B係製作成:將MBR1的上游的流路r11的家庭污水流送到UF膜3的上游的海水的流路r2內,藉此,將家庭污水的熱能利用熱交換而賦予到海水身上。 The heat exchanger 6B shown in Fig. 2(b) is formed by flowing the domestic sewage of the flow path r11 upstream of the MBR 1 into the flow path r2 of the seawater upstream of the UF membrane 3, thereby discharging the domestic sewage. The heat is transferred to the seawater by heat exchange.

第2圖(c)所示的熱交換器6C係製作成:將容易導熱的液體也就是熱媒體n利用泵浦p9,令其在MBR1的上游之家庭污水的流路r11內與UF膜3的上游之海水的流路r2內進行循環,而將MBR1的上游之流路r11內的家庭污水的熱能,利用熱媒體n來運送而賦予到UF膜3的上游之流路r2內的海水。 The heat exchanger 6C shown in Fig. 2(c) is formed such that the liquid which is easy to conduct heat, that is, the heat medium n, is pumped p9 so that it is in the flow path r11 of the domestic sewage upstream of the MBR 1 and the UF film 3 The flow in the flow path r2 of the upstream seawater is circulated, and the thermal energy of the domestic sewage in the flow path r11 upstream of the MBR 1 is transported by the heat medium n to the seawater in the flow path r2 upstream of the UF film 3.

這些是被稱為:機殼(shell)暨線圈(coil)式;或者機殼(shell)暨管路(tube)式的熱交換器6。 These are referred to as: shell and coil type; or shell and tube type heat exchangers 6.

此外,在第1圖中,雖然是舉例顯示出:將熱交換器6配置在家庭污水的流路r11之泵浦p1的下游且是海水的流路r2的泵浦p3的下游的情況,但是,熱交換器6並不拘泥於家庭污水的流路r11的泵浦p1之上下游,都可以配置,而且也不拘泥於海水的流路r2的泵浦p3的上下游,都可以配置。 In addition, in the first figure, the heat exchanger 6 is disposed downstream of the pump p1 of the domestic sewage flow path r11 and downstream of the pump p3 of the seawater flow path r2, but The heat exchanger 6 is not limited to the upstream and downstream of the pump p1 of the flow path r11 of the domestic sewage, and can be disposed without being restricted to the upstream and downstream of the pump p3 of the seawater flow path r2.

又,在第2圖(a)的熱交換器6A的情況下,海水的流路r2(請參考第1圖)的泵浦p3的下游這一側,係可獲得海水之朝向家庭污水的流路r11的壓送力量(朝向設置在流路r11中的線圈等的壓送力量),所以更好。這種情況下,熱交換器6A無論是設置在家庭污水的流路r11的泵浦p1上下游的任何一側皆可以。 Further, in the case of the heat exchanger 6A of Fig. 2(a), on the downstream side of the pump p3 of the seawater flow path r2 (please refer to Fig. 1), the flow of the seawater toward the domestic sewage can be obtained. It is more preferable that the pressure of the path r11 (the pressure of the coil or the like provided in the flow path r11) is higher. In this case, the heat exchanger 6A may be provided on either side of the upstream and downstream of the pump p1 of the flow path r11 of the domestic sewage.

同樣地,在第2圖(b)的熱交換器6B的情況下,家庭污水的流路r11(請參考第1圖)的泵浦p1的下游這一側,係可獲得家庭污水之朝向海水的流路r2的壓送力量,所以更好。這種情況下,熱交換器6B無論是設置在海水的流路r2的泵浦p3上下游的任何一側皆可以。 Similarly, in the case of the heat exchanger 6B of Fig. 2(b), on the downstream side of the pump p1 of the domestic sewage flow path r11 (please refer to Fig. 1), it is possible to obtain the domestic sewage toward the seawater. The flow of r2 is the pressure of the pressure, so it is better. In this case, the heat exchanger 6B may be provided on either side of the upstream and downstream of the pump p3 of the flow path r2 of the seawater.

此外,熱交換器6亦可從:對向流熱交換器、並行流熱交換器、直交流熱交換器等的任何一種形式的熱交換器來選擇使用。 Further, the heat exchanger 6 may be selectively used from any one of a countercurrent heat exchanger, a parallel flow heat exchanger, a straight AC heat exchanger, and the like.

第3圖係顯示在海水淡化系統中,將家庭污水與海水進行熱交換的位置圖。 Figure 3 is a diagram showing the location of heat exchange between domestic sewage and seawater in a desalination system.

在海水淡化系統S中,將家庭污水與海水進行熱交換的位置,可以是在:MBR1的上游的家庭污水的流路r11的位置A、或者穿透過MBR1之後的流路r12的位置B、或者被低壓RO膜2所除去的鹵水s6的流路r13的位置C、或者穿透過低壓RO膜2之後的流路r14的位置D之任何一個位置皆可。 In the seawater desalination system S, the location where the domestic sewage is exchanged with the seawater may be at the position A of the flow path r11 of the domestic sewage upstream of the MBR1 or the position B of the flow path r12 after the MBR1 is penetrated, or Any position of the flow path r13 of the brine s6 removed by the low pressure RO membrane 2 or the position D of the flow path r14 after passing through the low pressure RO membrane 2 may be used.

但是,位於家庭污水的流路的上游側這一側,因為家庭污水具有較多的熱能,就熱能的觀點而言,最好的位置依序是:上游側的位置A、位置B、位置C、位置D的順序。 However, on the upstream side of the flow path of domestic sewage, since domestic sewage has more heat energy, from the viewpoint of heat energy, the best positions are: upstream position A, position B, position C. , the order of position D.

接下來,說明在第1圖所示的海水淡化系統S中,從家庭污水來製造工業用水s1的造水過程。 Next, a water-producing process for producing industrial water s1 from domestic sewage in the seawater desalination system S shown in Fig. 1 will be described.

家庭污水係利用泵浦p1而被壓送到海水淡化系統S內,經由熱交換器6而與流經過流路r2的海水進行熱交換,而將熱能賦予海水並且被送往MBR1。家庭污水係藉由穿透過MBR1而將活性污泥浮渣和細菌等予以除去。 The domestic sewage system is pumped into the seawater desalination system S by the pump p1, and exchanges heat with the seawater flowing through the flow path r2 via the heat exchanger 6, and heat energy is supplied to the seawater and sent to the MBR 1. The domestic sewage system removes activated sludge scum, bacteria, etc. by penetrating through MBR1.

穿透過MBR1之後的家庭污水之MBR透過水s5a,係利用泵浦p2送往低壓RO膜2,藉由穿透過低壓RO膜2,使得含有鹽分和離子等的雜質的鹵水s6被除去,而被淡水化,進而生產出工業用水s1。 The MBR permeating water s5a of the domestic sewage after passing through the MBR1 is sent to the low pressure RO membrane 2 by the pump p2, and by passing through the low pressure RO membrane 2, the brine s6 containing impurities such as salts and ions is removed, and is Fresh water, and then produce industrial water s1.

可獲得的工業用水s1的量,是家庭污水的1/2程度,另一方面,家庭污水之剩餘的量,亦即,家庭污水的1/2程度的量是成為含有鹽分和離子等的雜質之鹵水s6而被除去。 The amount of industrial water s1 available is 1/2 of that of domestic sewage. On the other hand, the remaining amount of domestic sewage, that is, the amount of 1/2 of domestic sewage is an impurity containing salt and ions. The brine s6 is removed.

接下來,說明在海水淡化系統S中,從海水來製造出生產水,亦即,飲用水s2的造水過程。 Next, in the seawater desalination system S, the production water, that is, the water production process of the drinking water s2, is produced from seawater.

海水係利用泵浦p3而被壓送到海水淡化系統S內,經由熱交換器6利用家庭污水的熱能將海水加溫,並且被送往UF膜3。被熱交換器6加溫後的海水,穿透過UF膜3使得海水中的粒子被除去。被UF膜3除去粒子之後的海水,亦即,UF膜透過海水s5b係在攪拌槽4中被攪拌成均勻狀態。 The seawater is pumped into the seawater desalination system S by the pump p3, and the seawater is heated by the heat energy of the domestic sewage via the heat exchanger 6, and sent to the UF membrane 3. The seawater heated by the heat exchanger 6 penetrates the UF membrane 3 so that the particles in the seawater are removed. The seawater after the particles are removed by the UF film 3, that is, the UF film is stirred into a uniform state in the stirring tank 4 through the seawater s5b.

然後,被攪拌後的UF膜透過海水s5b,係利用泵浦p4送往高壓RO膜5。UF膜透過海水s5b,藉由穿透過高壓RO膜5,大約有一半是被當成含有鹽分和離子等的雜質的鹵水s7而被除去,剩餘的一半則是被淡水化,而被生產作為飲用水s2。 Then, the stirred UF membrane passes through the seawater s5b and is sent to the high pressure RO membrane 5 by the pump p4. The UF membrane passes through the seawater s5b, and by passing through the high-pressure RO membrane 5, about half is removed as brine s7 containing impurities such as salt and ions, and the remaining half is desalinated and produced as drinking water. S2.

根據實施方式1的海水淡化系統S,在熱交換器6中,低溫的海水係回收較之海水更高溫度的家庭污水的熱能而被加溫,所以被加溫之後的海水,可分別很容易且良好地穿透過UF膜3、高壓RO膜5。 According to the seawater desalination system S of the first embodiment, in the heat exchanger 6, the low-temperature seawater is heated by the heat energy of the domestic sewage having a higher temperature than the seawater, so that the seawater after being heated can be easily And the UF film 3 and the high pressure RO film 5 are well penetrated.

如此一來,用來壓送海水的泵浦p3、p4就可分別削減其動力。因此,可達成海水淡化系統S的省能源化。 In this way, the pumps p3 and p4 used to pressurize the seawater can reduce their power separately. Therefore, the energy saving of the seawater desalination system S can be achieved.

[實施方式2] [Embodiment 2]

第4圖係本發明的實施方式2的海水淡化系統的概念性結構圖。 Fig. 4 is a conceptual configuration diagram of a seawater desalination system according to a second embodiment of the present invention.

實施方式2的海水淡化系統2S係設置了用來回收: 實施方式1的海水淡化系統S中的鹵水s6的壓力能量之能源回收裝置21。 The seawater desalination system 2S of the second embodiment is provided for recycling: The energy recovery device 21 for the pressure energy of the brine s6 in the seawater desalination system S of the first embodiment.

至於其他的構成要件都是與實施方式1的海水淡化系統S相同,所以針對於同一個構成要件,都標示與實施方式1相同的元件符號,並且省略其詳細說明。 The other components are the same as those of the seawater desalination system S of the first embodiment. Therefore, the same components as those of the first embodiment are denoted by the same reference numerals, and the detailed description thereof will be omitted.

海水淡化系統2S係設置了:可將被低壓RO膜2所除去的鹵水s6的壓力能量當作電能或者旋轉動能(機械性動能)加以回收之能源回收裝置21。 The seawater desalination system 2S system is provided with an energy recovery device 21 that can recover the pressure energy of the brine s6 removed by the low pressure RO membrane 2 as electrical energy or rotational kinetic energy (mechanical kinetic energy).

能源回收裝置21,例如:係將鹵水s6的壓力能量利用水車或者齒輪等,進行小型水力發電,將機械性動能轉換成電能(電力)來加以回收。能源回收裝置21所回收的電力,係當作用來將海水壓送到UF膜3的泵浦p3的電力來使用(在第4圖中係以虛線來表示)。此外,也可以不當作泵浦p3的電力來使用,而是作為其他的電力用途。 In the energy recovery device 21, for example, the pressure energy of the brine s6 is used for small-scale hydroelectric power generation by using a water truck or a gear, and mechanical kinetic energy is converted into electric energy (electric power) to be recovered. The electric power recovered by the energy recovery device 21 is used as electric power for pumping seawater to the pump p3 of the UF film 3 (indicated by a broken line in Fig. 4). Further, it may not be used as the power of the pump p3, but may be used as another power source.

或者,亦可製作成:利用能源回收裝置21來將鹵水s6的壓力能量當作旋轉動能(機械性動能)加以回收,並且加諸到流經UF膜3的海水身上,而不必設置泵浦p3。 Alternatively, it is also possible to use the energy recovery device 21 to recover the pressure energy of the brine s6 as rotational kinetic energy (mechanical kinetic energy) and apply it to the seawater flowing through the UF membrane 3 without setting the pump p3. .

或者,當能源回收裝置21所回收到的旋轉動能(機械性動能)並不太大的情況下,亦可製作成:設有泵浦p3,但是可減少泵浦p3所需的動力。 Alternatively, when the rotational kinetic energy (mechanical kinetic energy) recovered by the energy recovery device 21 is not too large, it may be made that the pump p3 is provided, but the power required for the pump p3 can be reduced.

或者,亦可採用:習知的壓力直接轉換方式的能源回收裝置21,來將鹵水s6的壓力直接加諸到流經UF膜3 的海水身上的結構。 Alternatively, the pressure recovery device 21 of the conventional direct pressure conversion method may be used to directly apply the pressure of the brine s6 to the UF membrane 3 . The structure of the sea water.

此外,亦可將能源回收裝置21所回收到的旋轉動能(機械性動能)或壓力能量不加諸到流經UF膜3的海水身上,而是應用到其他的地方。 Further, the rotational kinetic energy (mechanical kinetic energy) or pressure energy recovered by the energy recovery device 21 may not be applied to the seawater flowing through the UF membrane 3, but may be applied to other places.

根據實施方式2,係將鹵水s6的壓力能量利用能源回收裝置21加以回收,所以可達成省能源化。因此,可削減能源成本。 According to the second embodiment, the pressure energy of the brine s6 is recovered by the energy recovery device 21, so that energy saving can be achieved. Therefore, energy costs can be reduced.

此外,在實施方式2的海水淡化系統2S中,雖然是舉例說明了設置有熱交換器6的情況,但是在海水的溫度較高的地帶,亦可製作成:不必設置熱交換器6的結構。 Further, in the seawater desalination system 2S of the second embodiment, the case where the heat exchanger 6 is provided is exemplified, but in the zone where the temperature of the seawater is high, the structure of the heat exchanger 6 may not be provided. .

[實施方式3] [Embodiment 3]

第5圖係本發明的實施方式3的海水淡化系統的概念性結構圖。 Fig. 5 is a conceptual configuration diagram of a seawater desalination system according to a third embodiment of the present invention.

實施方式3的海水淡化系統3S的結構,係製作成:將實施方式1的海水淡化系統S之被低壓RO膜2所分離的鹵水s6,匯流到海水的流路r2。 The seawater desalination system 3S of the third embodiment is configured to merge the brine s6 separated by the low pressure RO membrane 2 of the seawater desalination system S of the first embodiment into the seawater flow path r2.

至於其他的構成要件,係與實施方式1的海水淡化系統S相同,因此,針對於相同的構成要件,都標示與實施方式1相同的元件符號,並且省略其詳細說明。 The other components are the same as those of the seawater desalination system S of the first embodiment. Therefore, the same components as those of the first embodiment are denoted by the same reference numerals, and the detailed description thereof will be omitted.

海水淡化系統3S係將被低壓RO膜2所分離的鹵水s6匯流到海水的流路r2,利用鹵水s6的壓力能量,使得海水獲得朝向UF膜3的壓送力量。因此,是採用不必設置泵浦p3的結構。 The seawater desalination system 3S collects the brine s6 separated by the low pressure RO membrane 2 into the seawater flow path r2, and uses the pressure energy of the brine s6 to obtain the pressure of the seawater toward the UF membrane 3. Therefore, a structure in which it is not necessary to set the pump p3 is employed.

這種情況下,由海水製得的生產水s9係當成工業用水。此外,亦可將生產水s9當作飲用水來使用。 In this case, the produced water s9 made from seawater is used as industrial water. In addition, the production water s9 can also be used as drinking water.

根據實施方式3的海水淡化系統3S,因為並未設置泵浦p3,所以可解決:泵浦p3的製造成本、設置成本、維持管理成本之類的問題,而謀求低成本化。 According to the seawater desalination system 3S of the third embodiment, since the pump p3 is not provided, it is possible to solve the problems such as the manufacturing cost of the pump p3, the installation cost, and the maintenance cost, and the cost is reduced.

此外,當鹵水s6的壓力能量不夠大因而海水之對於UF膜3的壓送力不足的情況下,也可以改成設置有泵浦p3的結構。這種情況下,可以削減泵浦p3的動力,因此可謀求省能源化。因此,可削減能源成本。 Further, when the pressure energy of the brine s6 is not sufficiently large and the pressure transmitting force of the seawater to the UF film 3 is insufficient, the structure in which the pump p3 is provided may be changed. In this case, the power of the pump p3 can be reduced, so that energy saving can be achieved. Therefore, energy costs can be reduced.

此外,實施方式3的海水淡化系統3S雖然是舉出設置有熱交換器6的情況,但是,在海水的溫度較高的地帶,亦可製作成不必設置熱交換器6的結構。 In the seawater desalination system 3S of the third embodiment, the heat exchanger 6 is provided. However, in a zone where the temperature of the seawater is high, the heat exchanger 6 may not be provided.

[其他實施方式] [Other embodiments]

此外,在實施方式1~3中,雖然是舉例說明了將家庭污水與海水分別予以淡水化,以製造出工業用水與飲用水的情況,但是,本發明也是可以適用在:將家庭污水與海水分別予以淡水化,但並不製造出飲用水,只製造出工業用水的情況。亦可適用於例如:將第7圖的家庭污水的其中一部分流入將海水予以淡水化的路徑中,來製造出工業用水的情況。 Further, in the first to third embodiments, although the domestic sewage and the seawater are separately desalinated to produce industrial water and drinking water, the present invention is also applicable to: domestic sewage and seawater. They are desalinated separately, but they do not produce drinking water and only produce industrial water. It is also applicable to, for example, the case where part of the domestic sewage of Fig. 7 flows into a path for desalinating seawater to produce industrial water.

是以,只要是將家庭污水與海水分別予以淡化的系統的話,都可以廣泛地適用本發明。 Therefore, the present invention can be widely applied as long as it is a system for desalination of domestic sewage and seawater.

1‧‧‧MBR 1‧‧‧MBR

2‧‧‧低壓RO膜(第1RO膜) 2‧‧‧Low-pressure RO membrane (1RO membrane)

3‧‧‧UF膜 3‧‧‧UF film

5‧‧‧高壓RO膜(第2RO膜) 5‧‧‧High pressure RO membrane (2RO membrane)

6、6A、6B、6C‧‧‧熱交換器 6, 6A, 6B, 6C‧‧ ‧ heat exchanger

21‧‧‧能源回收裝置 21‧‧‧Energy recovery unit

S、2S、3S‧‧‧海水淡化系統 S, 2S, 3S‧‧‧ seawater desalination system

s1‧‧‧工業用水(家庭污水的處理水) S1‧‧‧Industrial water (treated water for domestic sewage)

s2‧‧‧飲用水 S2‧‧‧ drinking water

s5a‧‧‧MBR透過水(透過水、家庭污水的處理水) s5a‧‧‧MBR through water (through water, domestic sewage treatment water)

s5b‧‧‧UF膜透過海水(處理水) S5b‧‧‧UF membrane through seawater (treated water)

s6‧‧‧鹵水(第1濃縮水、家庭污水的處理水) S6‧‧‧ brine (the first concentrated water, domestic sewage treatment water)

s7‧‧‧鹵水(第2濃縮水) S7‧‧‧ brine (2nd concentrated water)

第1圖係本發明的實施方式1的海水淡化系統的概念性結構圖。 Fig. 1 is a conceptual configuration diagram of a seawater desalination system according to Embodiment 1 of the present invention.

第2圖係顯示本發明的實施方式1的海水淡化系統中的熱交換器的各種組合變化的概念圖,第2圖(a)係顯示將海水流送到家庭污水的流路中以進行熱交換的熱交換器之概念圖;第2圖(b)係顯示將家庭污水流送到海水的流路中以進行熱交換的熱交換器之概念圖;第2圖(c)係顯示將熱媒體流送到家庭污水的流路與海水的流路中以進行熱交換的熱交換器之概念圖。 Fig. 2 is a conceptual diagram showing various combinations of heat exchangers in the seawater desalination system according to Embodiment 1 of the present invention, and Fig. 2(a) shows the flow of seawater to the flow path of domestic sewage for heat generation. Conceptual diagram of the exchanged heat exchanger; Figure 2(b) is a conceptual diagram showing a heat exchanger that delivers domestic sewage to the seawater flow path for heat exchange; Figure 2(c) shows the heat A conceptual diagram of a heat exchanger in which a medium stream is sent to a flow path of domestic sewage and a flow path of sea water for heat exchange.

第3圖係顯示本發明的實施方式1的海水淡化系統中,將家庭污水進行熱交換的位置之圖。 Fig. 3 is a view showing a position where heat is exchanged for domestic sewage in the seawater desalination system according to the first embodiment of the present invention.

第4圖係本發明的實施方式2的海水淡化系統的概念性結構圖。 Fig. 4 is a conceptual configuration diagram of a seawater desalination system according to a second embodiment of the present invention.

第5圖係本發明的實施方式3的海水淡化系統的概念性結構圖。 Fig. 5 is a conceptual configuration diagram of a seawater desalination system according to a third embodiment of the present invention.

第6圖係傳統的海水淡化系統的概念性結構圖。 Figure 6 is a conceptual block diagram of a conventional desalination system.

第7圖係傳統的其他種類的海水淡化系統的概念性結構圖。 Figure 7 is a conceptual block diagram of a conventional other type of desalination system.

1‧‧‧MBR 1‧‧‧MBR

2‧‧‧低壓RO膜 2‧‧‧Low-pressure RO film

3‧‧‧UF膜 3‧‧‧UF film

4‧‧‧攪拌槽 4‧‧‧Stirring tank

5‧‧‧高壓RO膜 5‧‧‧High pressure RO membrane

6‧‧‧熱交換器 6‧‧‧ heat exchanger

S‧‧‧水淡化系統(海水淡化系統) S‧‧‧Water desalination system (desalination system)

s1‧‧‧工業用水 S1‧‧‧ industrial water

s2‧‧‧飲用水 S2‧‧‧ drinking water

s5a‧‧‧MBR透過水 s5a‧‧‧MBR through water

s5b‧‧‧UF膜透過海水 S5b‧‧‧UF membrane through seawater

s6‧‧‧鹵水 S6‧‧‧ brine

s7‧‧‧鹵水 S7‧‧‧ brine

p1、p2、p3、p4‧‧‧泵浦 P1, p2, p3, p4‧‧ ‧ pump

r11‧‧‧MBR的上游流路 The upstream flow path of r11‧‧‧MBR

r2‧‧‧UF膜的上游流路 Upstream flow path of r2‧‧‧UF membrane

Claims (9)

一種海水淡化系統,係將海水與家庭污水予以淡水化之海水淡化系統,其特徵為,具備:將前述家庭污水或其處理水與前述海水進行熱交換的熱交換器。 A seawater desalination system is a seawater desalination system that desalinates seawater and domestic sewage, and is characterized in that it includes a heat exchanger that exchanges heat between the domestic sewage or the treated water and the seawater. 一種海水淡化系統,係將海水與家庭污水予以淡水化之海水淡化系統,其特徵為,具備:將前述家庭污水利用膜分離活性污泥法進行處理之膜分離活性污泥處理裝置、令已經穿透過前述膜分離活性污泥處理裝置之後的透過水再穿透過,將其鹽分含在第1濃縮水中予以除去,並且生成工業用水之第1RO膜、令前述海水穿透過而將該海水中的粒子予以除去之UF膜、令已經穿透過前述UF膜之後的處理水再穿透過,將該處理水的鹽分含在第2濃縮水中予以除去,並且生成飲用水之第2RO膜、將前述家庭污水或其處理水與前述海水進行熱交換之熱交換器。 A seawater desalination system is a seawater desalination system that desalinates seawater and domestic sewage, and is characterized in that: the membrane separation activated sludge treatment device that treats the domestic sewage by membrane separation activated sludge method, has been worn The permeated water after the separation of the activated sludge treatment device through the membrane is passed through, and the salt is removed in the first concentrated water to be removed, and the first RO membrane of the industrial water is produced, and the seawater is passed through to the particles in the seawater. The UF film to be removed is passed through the treated water which has passed through the UF film, and the salt of the treated water is removed in the second concentrated water to be removed, and the second RO membrane of the drinking water is produced, and the domestic sewage or the aforementioned domestic sewage or It is a heat exchanger that treats heat exchange between water and the aforementioned seawater. 如申請專利範圍第2項所述的海水淡化系統,其中,前述熱交換器,係將較之前述UF膜更上游的前述海水,與前述膜分離活性污泥處理裝置的上游之家庭污水、或已經穿透過前述膜分離活性污泥處理裝置之後的透過水、或前述第1濃縮水、或前述所生成的工業用水之中的任 何一種進行熱交換。 The seawater desalination system according to claim 2, wherein the heat exchanger separates the seawater upstream of the UF membrane from the domestic sewage upstream of the activated sludge treatment device, or The permeated water after the membrane separation activated sludge treatment device has passed through, or the first concentrated water or the industrial water produced as described above Which kind of heat exchange. 如申請專利範圍第2項或第3項所述的海水淡化系統,其中,具備:用來回收前述第1濃縮水的壓力能量之能源回收裝置。 The seawater desalination system according to the second or third aspect of the invention, further comprising: an energy recovery device for recovering pressure energy of the first concentrated water. 如申請專利範圍第2項或第3項所述的海水淡化系統,其中,係將前述第1濃縮水與前述UF膜的上游之前述海水匯流在一起。 The seawater desalination system according to the second or third aspect of the invention, wherein the first concentrated water and the seawater upstream of the UF membrane are merged. 一種海水淡化方法,係將海水與家庭污水予以淡水化之海水淡化方法,其特徵為:係將前述家庭污水或者將前述家庭污水淡化過程中的處理水與前述海水進行熱交換。 A seawater desalination method is a seawater desalination method for desalinating seawater and domestic sewage, characterized in that the domestic sewage or the treated water in the desalination process of the domestic sewage is heat-exchanged with the seawater. 一種海水淡化方法,係將海水與家庭污水予以淡水化之海水淡化方法,其特徵為:係將前述家庭污水或者將前述家庭污水淡化過程中的處理水與前述海水進行熱交換,令前述家庭污水穿透過膜分離活性污泥處理裝置與第1RO膜而生成工業用水,令前述海水穿透過UF膜與第2RO膜而生成飲用水。 A seawater desalination method is a seawater desalination method for desalinating seawater and domestic sewage, characterized in that: the domestic sewage or the treated water in the desalination process of the domestic sewage is exchanged with the seawater to make the domestic sewage The industrial water is generated by penetrating the membrane separation activated sludge treatment device and the first RO membrane, and the seawater is passed through the UF membrane and the second RO membrane to generate drinking water. 如申請專利範圍第7項所述的海水淡化方法,其中,係將被前述第1RO膜所除去的第1濃縮水的壓力能量加以回收。 The seawater desalination method according to claim 7, wherein the pressure energy of the first concentrated water removed by the first RO membrane is recovered. 如申請專利範圍第7項所述的海水淡化方法,其中,係將被前述第1RO膜所除去的第1濃縮水,與前述UF膜的上游的前述海水匯流在一起。 The seawater desalination method according to the seventh aspect of the invention, wherein the first concentrated water removed by the first RO membrane is condensed with the seawater upstream of the UF membrane.
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