TW201302417A - Method and apparatus for inspecting endless belt - Google Patents

Method and apparatus for inspecting endless belt Download PDF

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Publication number
TW201302417A
TW201302417A TW101107575A TW101107575A TW201302417A TW 201302417 A TW201302417 A TW 201302417A TW 101107575 A TW101107575 A TW 101107575A TW 101107575 A TW101107575 A TW 101107575A TW 201302417 A TW201302417 A TW 201302417A
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TW
Taiwan
Prior art keywords
roller
belt
endless belt
distance
inspection
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TW101107575A
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Chinese (zh)
Inventor
Toshinao Arai
Hidekazu Yamazaki
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Fujifilm Corp
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Publication of TW201302417A publication Critical patent/TW201302417A/en

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/86Investigating moving sheets
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/20Metals
    • G01N33/204Structure thereof, e.g. crystal structure

Abstract

External force at a predetermined level is applied to a rotary shaft of an inspection roller by a driver. Tension is applied to a belt wound around the inspection roller. A sensor unit measures a distance A from a measurement position MP1 to a measuring window. The sensor unit measures a distance B from a measurement position MP2 to the measuring window. A controller calculates a curving level CL by using the distance A, the distance B, and a band width D read from a memory. The controller judges the belt as an inspection target to be ''an acceptable product'' when all the curving levels CL of the belt are equal to or less than a threshold value TH1. The controller judges the belt as the inspection target to be ''a disqualified product'' when any one of the curving levels CL of the belt exceeds the threshold value TH1.

Description

環狀帶的檢查方法及裝置Endless belt inspection method and device

本發明係有關於一種環狀帶的檢查方法及裝置。The present invention relates to an inspection method and apparatus for an endless belt.

隨著液晶顯示器(LCD)的大畫面化,對使用在LCD上之光學薄膜也要求大面積化。光學薄膜製造成長形後,根據LCD的尺寸切割成預定的尺寸。因此,為了製造更大面積的光學薄膜,需要製造寬度大於習知之長形光學薄膜。With the large screen of a liquid crystal display (LCD), an optical film used on an LCD is also required to have a large area. After the optical film is formed into a shape, it is cut into a predetermined size according to the size of the LCD. Therefore, in order to manufacture a larger area optical film, it is required to manufacture a long optical film having a larger width than conventional ones.

作為長形光學薄膜的代表性製造方法有連續方式的溶液製膜方法。總所周知,連續方式的溶液製膜方法為如下方法:將聚合物溶於溶劑中之濃液流延在移動之流延支撐體上,並在流延支撐體上形成由濃液組成之流延膜,從流延支撐體剝下流延膜並乾燥,從而製造薄膜。As a representative manufacturing method of the elongated optical film, there is a continuous method of forming a solution. It is generally known that a continuous mode solution film forming method is a method in which a dope in which a polymer is dissolved in a solvent is cast on a moving casting support, and a flow composed of a dope is formed on the casting support. The film is stretched, the cast film is peeled off from the casting support, and dried to produce a film.

作為流延支撐體,使用掛繞在驅動輥之金屬製帶。能夠製造的薄膜的最大寬度受該帶寬度的制約。因此,製造更大寬度的薄膜時需要更大寬度的帶。但是,至今為止只得到寬度最大為2m左右的帶。As the casting support, a metal belt wound around a driving roller is used. The maximum width of a film that can be manufactured is limited by the width of the tape. Therefore, a tape of a larger width is required when manufacturing a film of a larger width. However, only belts having a width of at most about 2 m have been obtained so far.

因此,在韓國專利公開公報第2009-0110082號中,藉由向長邊方向焊接成為寬度方向的中央部的中央部帶和成為帶的各側部的一對側部帶來得到比以往更大寬度的帶。Therefore, in the Korean Patent Laid-Open Publication No. 2009-0110082, the center portion of the center portion in the width direction and the pair of side portions of the side portions of the belt are welded to each other in the longitudinal direction. The width of the belt.

但是,在韓國專利公開公報第2009-0110082號中記載的帶由於向長邊方向延伸之焊接線而易於在寬度方向上產生翹曲。尤其是在帶的寬度方向端部,亦即從中央部帶遍及側部帶而容易產生翹曲。若利用寬度方向端部翹曲之帶實施溶液製膜方法,則由於該翹曲而產生流延膜的厚度不均。厚度不均是指厚度不均勻。即便乾燥產生這種厚度不均之流延膜,也會成為產生厚度不均之薄膜。並且,當剝離產生厚度不均之流延膜時,易產生剝離殘留故障。剝離殘留故障是指流延膜沒有從帶上完全剝離而流延膜的一部份留在帶上之現象。並且,當乾燥產生厚度不均之流延膜時,容易在流延膜上產生起泡。除此之外,當以由於翹曲而彎曲之帶的內側面(與形成流延膜之其中一方的帶面相反一側的帶面)與驅動輥的周面接觸之方式將帶掛繞在驅動輥時,帶端在帶的側部局部接觸於驅動輥的周面。如果持續帶端局部接觸於驅動輥的周面之狀態,則由於帶的側部變形增大,因此容易引起起因於上述厚度不均之問題。However, the belt described in Korean Patent Laid-Open Publication No. 2009-0110082 is likely to be warped in the width direction due to the welding line extending in the longitudinal direction. In particular, warpage is likely to occur at the end portion in the width direction of the belt, that is, from the center portion to the side belt. When the solution film forming method is performed by the belt in which the end portion is warped in the width direction, the thickness of the cast film is uneven due to the warpage. Uneven thickness means uneven thickness. Even if such a cast film having uneven thickness is produced by drying, a film having uneven thickness is produced. Further, when a cast film having uneven thickness is peeled off, a peeling residual failure is liable to occur. The peeling residual failure means that the cast film is not completely peeled off from the belt and a part of the cast film remains on the belt. Further, when a cast film having uneven thickness is produced by drying, foaming easily occurs on the cast film. In addition, when the inner side surface of the belt which is bent due to the warpage (the belt surface on the side opposite to the belt surface on which one of the casting films is formed) is in contact with the circumferential surface of the driving roller, the tape is hung When the roller is driven, the belt end partially contacts the peripheral surface of the driving roller at the side of the belt. If the belt end is partially in contact with the peripheral surface of the driving roller, the deformation of the side portion of the belt is increased, so that the problem of uneven thickness is likely to occur.

並且,藉由技術開發,當能夠製造超過目前的製造界限寬度之帶時,由於使用該帶,因此由於焊接線引起之翹曲會消失。但是,由於帶寬的增大而產生在寬度方向上翹曲的問題。Further, with the development of technology, when a belt exceeding the current manufacturing limit width can be manufactured, since the belt is used, warpage due to the welding line disappears. However, there is a problem of warpage in the width direction due to an increase in bandwidth.

如此,不管有無焊接線,在使用寬度寬於習知之帶時,都會產生在寬度方向上翹曲的問題。Thus, regardless of the presence or absence of the weld line, when the width is wider than that of the conventional belt, the problem of warpage in the width direction occurs.

本發明的目的在於,提供一種當製造寬度寬於習知之帶時,不實施溶液製膜方法,即可檢測帶翹曲的環狀帶的檢查方法及裝置。An object of the present invention is to provide an inspection method and apparatus for detecting a warped endless belt without performing a solution film forming method when the manufacturing width is wider than that of the conventional belt.

本發明的金屬製環狀帶的檢查方法,其中,前述環狀帶具備表面和裏面。在前述表面上設定從流延模流下之濃液所到達之到達位置,並形成由前述到達之濃液組成之流延膜。當前述環狀帶循環移動時,前述裏面由製膜用輥支撐。環狀帶的檢查方法具備距離計算步驟(A步驟)、浮起量計算步驟(B步驟)及判定步驟(C步驟)。A步驟計算從前述表面上的測定位置到檢查用輥的支撐面的距離H。前述測定位置對應前述到達位置。針對前述裏面由前述檢查用輥支撐並且外加移動張力之狀態的前述環狀帶計算前述距離H。B步驟根據式(1)計算前述測定位置上的從前述支撐面至前述裏面的浮起量CL。前述式(1)為CL=H-D。前述D為前述測定位置上的前述環狀帶的厚度。C步驟判定前述計算出之浮起量CL是否在閾值以下。In the method for inspecting a metal endless belt according to the present invention, the endless belt has a front surface and a back surface. The arrival position reached from the dope under the casting die flow is set on the aforementioned surface, and a casting film composed of the aforementioned concentrated liquid is formed. When the endless belt is cyclically moved, the inside is supported by a film forming roller. The inspection method of the endless belt includes a distance calculation step (A step), a floating amount calculation step (B step), and a determination step (C step). The step A calculates the distance H from the measurement position on the aforementioned surface to the support surface of the inspection roller. The aforementioned measurement position corresponds to the aforementioned arrival position. The aforementioned distance H is calculated for the aforementioned endless belt in which the aforementioned inspection roller is supported and the moving tension is applied. In the step B, the amount of floating CL from the support surface to the inside is calculated according to the formula (1). The above formula (1) is CL=H-D. The aforementioned D is the thickness of the endless belt at the measurement position. The C step determines whether or not the aforementioned calculated floating amount CL is below the threshold.

在上述的環狀帶的檢查方法中,前述檢查用輥在軸向中央部支撐前述環狀帶,以便軸向端部露出,在前述A步驟中利用測距單元測定從前述測定位置到前述測距單元的距離A和從前述測定位置上的前述軸向端部至前述測距單元的距離B,並根據式(2)計算前述距離H為較佳。In the above-described method for inspecting an endless belt, the inspection roller supports the endless belt at a central portion in the axial direction so as to be exposed at an axial end portion, and measures the measurement from the measurement position to the aforementioned measurement by the distance measuring unit in the step A. The distance A from the unit and the distance B from the aforementioned axial end portion to the aforementioned distance measuring unit are preferably calculated from the equation (2).

式(2)為H=B-A。Formula (2) is H=B-A.

在前述B步驟中,從存儲部讀取環狀帶的厚度D,利用從前述存儲部讀取之前述環狀帶的厚度D計算前述浮起量CL為較佳。存儲部中,關聯存儲有從設定在前述環狀帶上之基準位置到前述測定位置的位置情報和前述測定位置上的前述環狀帶的厚度D。In the above-described step B, it is preferable to read the thickness D of the endless belt from the storage portion and calculate the floating amount CL by the thickness D of the endless belt read from the storage portion. The storage unit stores, in association with the position information set at the reference position on the endless belt to the measurement position, and the thickness D of the endless belt at the measurement position.

前述環狀帶由金屬製第1網和焊接在該第1網的寬度方向一側之金屬製第2網組成為較佳。It is preferable that the endless belt is composed of a first mesh made of metal and a second mesh made of metal welded to one side in the width direction of the first net.

前述製膜用輥和前述檢查用輥為同一輥為較佳。It is preferable that the film forming roller and the inspection roller are the same roller.

前述移動張力為60N/mm2,且前述閾值為0.1mm以下為較佳。The moving tension is 60 N/mm 2 , and the threshold is preferably 0.1 mm or less.

本發明的金屬製環狀帶的檢查裝置,其中,前述環狀帶具備表面和裏面。在前述表面上設定從流延模流下之濃液所到達之到達位置,並形成由前述到達之濃液組成之流延膜。當前述環狀帶循環移動時,前述裏面由製膜用輥支撐。本發明的環狀帶的檢查裝置具備距離計算部、浮起量計算部、判定部。距離計算部計算從前述表面上的測定位置到檢查用輥的支撐面的距離H。前述測定位置對應前述到達位置。針對前述裏面由前述檢查用輥支撐並外加移動張力之狀態的前述環狀帶計算前述距離H。浮起量計算部根據式(1)計算前述測定位置上的從前述支撐面至前述裏面的浮起量CL。前述式(1)為CL=H-D。前述D為前述測定位置上的前述環狀帶的厚度。判定部判定前述計算出之浮起量CL是否在閾值以下。In the inspection apparatus for a metal endless belt according to the present invention, the endless belt has a front surface and a back surface. The arrival position reached from the dope under the casting die flow is set on the aforementioned surface, and a casting film composed of the aforementioned concentrated liquid is formed. When the endless belt is cyclically moved, the inside is supported by a film forming roller. An inspection apparatus for an endless belt according to the present invention includes a distance calculation unit, a floating amount calculation unit, and a determination unit. The distance calculating unit calculates the distance H from the measurement position on the surface to the support surface of the inspection roller. The aforementioned measurement position corresponds to the aforementioned arrival position. The distance H is calculated for the aforementioned endless belt in which the above-described inspection roller is supported and the moving tension is applied. The floating amount calculation unit calculates the floating amount CL from the support surface to the inside at the measurement position according to the formula (1). The above formula (1) is CL=H-D. The aforementioned D is the thickness of the endless belt at the measurement position. The determination unit determines whether or not the calculated floating amount CL is equal to or less than a threshold.

上述的環狀帶的檢查裝置具備測定距離A和距離B之測距單元為較佳。前述距離A係從前述測距單元到前述測定位置的距離。前述距離B係從前述測距單元至在軸向中央部支撐前述環狀帶之前述檢查用輥所露出之軸向端部的距離。前述距離計算部根據式(2)計算前述距離H。It is preferable that the above-described inspection device for the endless belt includes a distance measuring unit that measures the distance A and the distance B. The aforementioned distance A is the distance from the aforementioned distance measuring unit to the aforementioned measurement position. The distance B is a distance from the distance measuring unit to an axial end portion of the endless belt that is exposed by the inspection roller in the axial center portion. The distance calculating unit calculates the aforementioned distance H based on the equation (2).

式(2)為H=B-A。Formula (2) is H=B-A.

環狀帶的檢查裝置具有存儲部,前述浮起量計算部利用存儲在前述存儲部中之前述環狀帶的厚度D計算前述浮起量CL為較佳。存儲部中,關聯存儲有從設定在前述環狀帶上之基準位置至前述測定位置的位置情報和前述測定位置上的前述環狀帶的厚度D。The inspection device for the endless belt has a storage portion, and the floating amount calculation unit preferably calculates the floating amount CL by the thickness D of the endless belt stored in the storage portion. The storage unit stores, in association with the position information set at the reference position on the endless belt to the measurement position, and the thickness D of the endless belt at the measurement position.

前述製膜用輥和前述檢查用輥為同一輥為較佳。It is preferable that the film forming roller and the inspection roller are the same roller.

根據本發明,不實施溶液製膜方法即可檢測帶的翹曲。According to the present invention, the warpage of the tape can be detected without performing the solution film forming method.

圖1及圖2所示之帶製造設備10係製作由長形中央構件12和設置在中央構件12的寬度方向兩側之側構件11構成之長形帶構件13者。The belt manufacturing apparatus 10 shown in Figs. 1 and 2 is formed of an elongated belt member 13 composed of an elongated central member 12 and side members 11 provided on both sides in the width direction of the center member 12.

側構件11和中央構件12分別係金屬製片材料。側構件11係寬度相對狹窄的窄幅片材料。側構件11和中央構件12由相互相同的原材料形成為較佳,由相互相同的原料及經形成製程而形成為更佳。例如,作為側構件11及中央構件12使用由不銹鋼形成者為較佳。The side member 11 and the center member 12 are respectively made of a metal sheet material. The side members 11 are narrow web materials of relatively narrow width. The side member 11 and the center member 12 are preferably formed of the same material as each other, and are preferably formed of the same raw material and a forming process. For example, it is preferable to use a stainless steel as the side member 11 and the center member 12.

作為中央構件12,使用一直以來用作流延支撐體之帶即可。中央構件12的寬度比側構件11寬。在本實施方式中的中央構件12的寬度在1500mm以上2100mm以下的範圍內是恆定的,側構件11的寬度在50mm以上500mm以下的範圍內是恆定的。As the center member 12, a belt which has been conventionally used as a casting support may be used. The central member 12 is wider than the side members 11. In the present embodiment, the width of the center member 12 is constant within a range of 1500 mm or more and 2100 mm or less, and the width of the side member 11 is constant within a range of 50 mm or more and 500 mm or less.

帶製造設備10具備送出部16、對接部17、焊接單元18、加熱部19及捲取裝置20。The tape manufacturing apparatus 10 includes a delivery unit 16 , a butt portion 17 , a welding unit 18 , a heating unit 19 , and a winding device 20 .

送出部16具有送出側構件11之第1送出裝置23和送出中央構件12之第2送出裝置24。送出部16將側構件11和中央構件12分別獨立送往對接部17。在第1送出裝置23上設置捲成輥狀之側構件11,捲出側構件11並送至對接部17。第2送出裝置24上設置捲成輥狀之中央構件12,捲出中央構件12並送至對接部17。The delivery unit 16 has a first delivery device 23 that feeds the side members 11 and a second delivery device 24 that sends out the central member 12. The delivery unit 16 separately sends the side member 11 and the central member 12 to the abutting portion 17, respectively. The side member 11 wound in a roll shape is provided in the first delivery device 23, and the side member 11 is wound up and sent to the abutting portion 17. The second delivery device 24 is provided with a central member 12 wound in a roll shape, and the central member 12 is wound up and sent to the abutting portion 17.

對接部17使獨立引導過來之側構件11和中央構件12對接,以便側構件11的側緣11e和中央構件12的側緣12e相互接觸。對接部17具有第1輥26及第2輥27、第3輥28、第4輥29為較佳。在中央構件12的傳送路上從上游側依次配設第1輥26及第2輥27。在側構件11的傳送路上配設第3輥28。第4輥29在傳送路上配設成支撐側構件11及中央構件12雙方。The abutting portion 17 abuts the independently guided side member 11 and the center member 12 such that the side edge 11e of the side member 11 and the side edge 12e of the center member 12 are in contact with each other. The butt portion 17 preferably has the first roller 26 and the second roller 27, the third roller 28, and the fourth roller 29. The first roller 26 and the second roller 27 are disposed in this order from the upstream side on the conveyance path of the center member 12. A third roller 28 is disposed on the conveying path of the side member 11. The fourth roller 29 is disposed to support both the side member 11 and the center member 12 on the conveying path.

第4輥29係在對接位置Ph支撐送來之側構件11和中央構件12之對接支撐輥。對接位置Ph係側構件11的其中一方的側緣11e和中央構件12的其中一方的側緣12e開始接觸的位置。The fourth roller 29 supports the butted support roller of the side member 11 and the center member 12 that are fed at the butt position Ph. The side edge 11e of one of the butt position Ph-side members 11 and the side edge 12e of one of the center members 12 come into contact with each other.

第2輥27和第3輥28分別調整中央構件12的傳送路徑和側構件11的傳送路徑,以便中央構件12和側構件11在第4輥29的周面接觸。The second roller 27 and the third roller 28 respectively adjust the conveying path of the center member 12 and the conveying path of the side member 11 so that the center member 12 and the side member 11 are in contact with each other on the circumferential surface of the fourth roller 29.

第2輥27調整中央構件12的傳送路徑,朝向對接位置Ph控制應和側構件11焊接之側緣12e的通過路徑。第2輥27在中央構件12的寬度方向Y上移動自如。位移機構32向寬度方向Y移動第2輥27。The second roller 27 adjusts the conveying path of the center member 12, and controls the passage path of the side edge 12e to be welded to the side member 11 toward the butting position Ph. The second roller 27 is movable in the width direction Y of the center member 12. The displacement mechanism 32 moves the second roller 27 in the width direction Y.

在第2輥27和第4輥29之間配設位置檢測手段34。位置檢測手段34檢測中央構件12的各側緣12e中的其中一方的通過位置,將檢測之通過位置信號送到控制器33。控制器33根據送來之通過位置信號求出第2輥27在寬度方向Y上的變位量,將變位量信號送到位移機構32。位移機構32根據送來之變位量信號改變第2輥27的傾斜度或第2輥27在中央構件12的寬度方向Y上的位置。這樣,藉由改變第2輥27的傾斜度或位置,中央構件12在寬度方向Y上變位。A position detecting means 34 is disposed between the second roller 27 and the fourth roller 29. The position detecting means 34 detects the passing position of one of the side edges 12e of the center member 12, and sends the detected passing position signal to the controller 33. The controller 33 obtains the amount of displacement of the second roller 27 in the width direction Y based on the transmitted position signal, and sends the displacement amount signal to the displacement mechanism 32. The displacement mechanism 32 changes the inclination of the second roller 27 or the position of the second roller 27 in the width direction Y of the center member 12 based on the transmitted displacement amount signal. Thus, the center member 12 is displaced in the width direction Y by changing the inclination or position of the second roller 27.

第1輥26上設置位移機構37為較佳。第1輥26藉由該位移機構37從其中一方的構件面按壓朝向第2輥27之中央構件12。根據該第1輥26的變位量改變第1輥26相對於中央構件12的按壓壓力,並調整按壓壓力。由此,能夠控制捲繞在第2輥27的中央構件12的捲繞中心角。根據該捲繞中心角的控制,能夠以更加精確地控制中央構件12根據第2輥27的在寬度方向Y上的變位量。It is preferable to provide the displacement mechanism 37 on the first roller 26. The first roller 26 is pressed toward the center member 12 of the second roller 27 from the one member surface by the displacement mechanism 37. The pressing pressure of the first roller 26 with respect to the center member 12 is changed according to the displacement amount of the first roller 26, and the pressing pressure is adjusted. Thereby, the winding center angle of the center member 12 wound around the second roller 27 can be controlled. According to the control of the winding center angle, the amount of displacement of the center member 12 in the width direction Y according to the second roller 27 can be controlled more accurately.

第3輥28調整側構件11的傳送路徑,朝向對接位置Ph調整應和中央構件12焊接之其中一方的側緣11e的通過路徑。在第3輥28上具備控制長邊方向的朝向之控制器38。該控制器38例如沿著側構件11的構件面改變第3輥28的長邊方向,以便在與側構件11接觸期間的接觸區域中的周向和中央構件12的傳送方向X所成之角θ1發生變化。The third roller 28 adjusts the transport path of the side member 11, and adjusts the passage path of the side edge 11e to be welded to the central member 12 toward the docking position Ph. The third roller 28 is provided with a controller 38 that controls the orientation in the longitudinal direction. The controller 38 changes the longitudinal direction of the third roller 28, for example, along the member faces of the side members 11, so as to be at an angle of the circumferential direction in the contact region during contact with the side members 11 and the conveying direction X of the center member 12. Θ1 changes.

如同以上使用第1輥26~第3輥28以對接位置Ph位於第4輥29上的方式進行控制為較佳。第1輥26~第3輥28均為沿周向旋轉之驅動輥為較佳。藉由沿周向旋轉,第1輥26及第2輥27還作為中央構件12的傳送手段發揮作用,第3輥28還作為側構件11的傳送手段發揮作用。藉由將第1輥26~第3輥28設為驅動輥,側構件11和中央構件12的傳送路的控制變得更可靠,並且藉由防止側構件11和中央構件12在第1輥26~第3輥28上的滑動來防止劃傷構件面。It is preferable to control the first roller 26 to the third roller 28 so that the butting position Ph is located on the fourth roller 29 as described above. It is preferable that each of the first roller 26 to the third roller 28 is a driving roller that rotates in the circumferential direction. By rotating in the circumferential direction, the first roller 26 and the second roller 27 also function as a conveying means of the center member 12, and the third roller 28 also functions as a conveying means of the side member 11. By setting the first roller 26 to the third roller 28 as the driving roller, the control of the conveying path of the side member 11 and the center member 12 becomes more reliable, and by preventing the side member 11 and the center member 12 from being in the first roller 26 The sliding on the third roller 28 prevents the surface of the member from being scratched.

焊接單元18係在彼此的側緣11e、12e接觸之狀態下焊接從對接部17供給之側構件11和中央構件12。藉由從對接部17連續供給,能夠進行在長邊方向上焊接側構件11和中央構件12之長邊焊接製程。焊接單元18具備焊接裝置42。作為焊接裝置42例如可以舉出雷射焊接裝置。作為雷射焊接裝置,例如能夠使用CO2雷射焊接裝置或釔鋁石榴石(YAG)雷射焊接裝置。在本實施態樣中,對利用CO2雷射焊接裝置作為焊接裝置42之情況進行說明。The welding unit 18 welds the side member 11 and the center member 12 supplied from the butting portion 17 in contact with each other with the side edges 11e, 12e. By continuously supplying from the butting portion 17, the long side welding process of welding the side member 11 and the center member 12 in the longitudinal direction can be performed. The welding unit 18 is provided with a welding device 42. As the welding device 42, for example, a laser welding device can be cited. As the laser welding device, for example, a CO 2 laser welding device or a yttrium aluminum garnet (YAG) laser welding device can be used. In the present embodiment, a case where a CO 2 laser welding device is used as the welding device 42 will be described.

焊接裝置42射出聚光之雷射,藉由對作為照射對象的側構件11及中央構件12照射雷射來熔融並接合側構件11和中央構件12。焊接裝置42具備雷射振盪器43、對從該雷射振盪器43引導過來之雷射進行聚光並射出之焊接裝置主體46、及每照射雷射時供給CO2氣體之氣體供給部(未圖示)。CO2氣體防止側構件11和中央構件12的氧化。此外,在圖2中,為了避免附圖的繁雜化而省略雷射振盪器43的圖示。The welding device 42 emits a concentrated laser beam, and the side member 11 and the center member 12 are irradiated with a laser to illuminate and fuse the side member 11 and the center member 12. The welding device 42 includes a laser oscillator 43, a welding device main body 46 that condenses and emits a laser beam guided from the laser oscillator 43, and a gas supply unit that supplies CO 2 gas every time the laser is irradiated (not Graphic). The CO 2 gas prevents oxidation of the side member 11 and the center member 12. Further, in FIG. 2, the illustration of the laser oscillator 43 is omitted in order to avoid complication of the drawing.

可以使用鎢惰性氣體焊接(Tungsten Inert Gas(TIG)welding)裝置來代替雷射焊接裝置。衆所周知,TIG焊接係以電弧為熱源之電弧焊接的一種。TIG焊接係使用惰性氣體(非活性氣體)作為保護氣體且關於電極使用鎢或鎢合金之惰性氣體電弧焊接的一種。雷射焊接與TIG焊接相比更為佳。並且,亦可設為組合TIG焊接和雷射焊接之混合焊接。Instead of a laser welding device, a tungsten inert gas welding (Tungsten Inert Gas (TIG) welding) device can be used. It is well known that TIG welding is one of arc welding in which an electric arc is used as a heat source. TIG welding is one in which an inert gas (inactive gas) is used as a shielding gas and an inert gas arc welding using tungsten or a tungsten alloy is used for the electrode. Laser welding is better than TIG welding. Moreover, it can also be used as a hybrid welding combining TIG welding and laser welding.

在側構件11和中央構件12的傳送路上,以與焊接裝置主體46的雷射的射出口對置的方式具備由周面支撐側構件11和中央構件12之焊接支撐輥41。焊接支撐輥41的旋轉軸與側構件11及中央構件12的寬度方向Y平行。設定根據焊接支撐輥41支撐側構件11和中央構件12的支撐位置,以便雷射照射於由焊接支撐輥41的周面支撐期間之側構件11和中央構件12為較佳。亦即,在焊接支撐輥輥41上進行焊接為較佳。由此,側構件11和中央構件12在側緣11e、12e相互接觸之狀態下變得穩定,能夠對應照射之部位可靠地照射雷射。A welding support roller 41 that supports the side member 11 and the center member 12 by the circumferential surface is provided on the conveyance path of the side member 11 and the center member 12 so as to face the discharge port of the laser of the welding device main body 46. The rotation axis of the welding support roller 41 is parallel to the width direction Y of the side member 11 and the center member 12. It is preferable to set the support position of the side member 11 and the center member 12 in accordance with the welding support roller 41 so that the side member 11 and the center member 12 are irradiated with laser light during the support by the circumferential surface of the welding support roller 41. That is, it is preferable to perform welding on the welding support roll 41. Thereby, the side member 11 and the center member 12 are stabilized in a state in which the side edges 11e and 12e are in contact with each other, and the laser beam can be reliably irradiated corresponding to the irradiated portion.

焊接裝置主體46上具備用於向寬度方向Y變位之位移機構50為較佳。在焊接裝置42的上游側設有位置檢測手段47,該位置檢測手段檢測側構件11的側緣11e和中央構件12的側緣12e相接觸之接觸位置Ps(參考圖5),並將檢測出之接觸位置Ps(參考圖5)的信號送至控制器51。位置檢測手段47配設在對接位置Ph至焊接裝置42(例如焊接位置Pw)之傳送路附近即可。It is preferable that the welding device main body 46 is provided with a displacement mechanism 50 for displacing in the width direction Y. On the upstream side of the welding device 42, a position detecting means 47 for detecting the contact position Ps (refer to FIG. 5) where the side edge 11e of the side member 11 and the side edge 12e of the center member 12 are in contact with each other is detected, and will be detected. The signal of the contact position Ps (refer to FIG. 5) is sent to the controller 51. The position detecting means 47 may be disposed in the vicinity of the transfer path from the docking position Ph to the welding device 42 (for example, the welding position Pw).

控制器51根據送來之接觸位置Ps(參考圖5)的信號求出焊接裝置主體46在寬度方向Y上的變位量,並將變位量的信號送至位移機構50。若被輸入側構件11和中央構件12的傳送速度的信號,則控制器51將變位時刻的信號與應使焊接裝置主體46變位之變位量的信號一同送至位移機構50。位移機構50根據送來之變位量及變位時刻的信號在預定時刻改變焊接裝置主體46的位置。如此藉由在寬度方向Y上改變焊接裝置主體46的位置,更加精確地控制雷射的照射位置,並更加可靠地焊接側構件11和中央構件12。另外,本實施方式中側構件11和中央構件12向焊接裝置42的傳送速度設為0.15m/分鐘以上20m/分鐘以下的範圍。The controller 51 determines the amount of displacement of the welding device main body 46 in the width direction Y based on the signal of the contact position Ps (refer to FIG. 5), and sends a signal of the displacement amount to the displacement mechanism 50. When the signal of the conveyance speed of the input side member 11 and the center member 12 is input, the controller 51 sends the signal of the displacement timing to the displacement mechanism 50 together with the signal of the displacement amount at which the welding device main body 46 is displaced. The displacement mechanism 50 changes the position of the welding device main body 46 at a predetermined timing based on the transmitted displacement amount and the signal of the displacement timing. Thus, by changing the position of the welding device main body 46 in the width direction Y, the irradiation position of the laser is more precisely controlled, and the side member 11 and the center member 12 are welded more reliably. Further, in the present embodiment, the conveying speed of the side member 11 and the center member 12 to the welding device 42 is in a range of 0.15 m/min or more and 20 m/min or less.

如圖1所示,焊接單元18上設置室52和清潔裝置55更為佳。室52將焊接裝置主體46和焊接支撐輥41隔開為外部空間。清潔裝置55對氣體進行清潔化。此外,圖2中為了避免附圖的繁雜化而省略室52和清潔裝置55的圖示。室52內設有向外部送出內部氣體之第1開口(未圖示)和向內部引導在清潔裝置55中清潔化之氣體之第2開口(未圖示)。第1開口和第2開口分別連接於清潔裝置55。室52的內部氣體從第1開口引導至清潔裝置55,清潔裝置55對從室52引導過來之氣體進行清潔化,並透過第2開口送至室52。如此,室52的內部氣體在與清潔裝置55之間循環。As shown in Fig. 1, it is more preferable to provide the chamber 52 and the cleaning device 55 on the welding unit 18. The chamber 52 separates the welding device main body 46 and the welding support roller 41 into an external space. The cleaning device 55 cleans the gas. Further, in FIG. 2, the illustration of the chamber 52 and the cleaning device 55 is omitted in order to avoid complication of the drawings. The chamber 52 is provided with a first opening (not shown) for sending the internal gas to the outside, and a second opening (not shown) for guiding the gas cleaned in the cleaning device 55 to the inside. The first opening and the second opening are connected to the cleaning device 55, respectively. The internal gas of the chamber 52 is guided from the first opening to the cleaning device 55, and the cleaning device 55 cleans the gas guided from the chamber 52 and sends it to the chamber 52 through the second opening. As such, the internal gas of chamber 52 circulates with cleaning device 55.

藉由對室52的內部氣體進行清潔化,焊接位置Pw及其周邊被清潔化,防止異物等混入焊接部13w。此外,藉由將室52的內部壓力保持為高於外部空間的壓力,能夠更加可靠地保持為對室52的內部進行清潔化之狀態。並且,藉由將焊接位置Pw設為相對送出部16、對接部17、加熱部19、捲取裝置20較高的位置,能夠進一步防止從這些構件引入異物。By cleaning the internal gas of the chamber 52, the welding position Pw and its periphery are cleaned, and foreign matter or the like is prevented from entering the welded portion 13w. Further, by maintaining the internal pressure of the chamber 52 higher than the pressure of the external space, it is possible to more reliably maintain the state in which the inside of the chamber 52 is cleaned. Further, by setting the welding position Pw to a position higher than the delivery portion 16, the abutting portion 17, the heating portion 19, and the winding device 20, it is possible to further prevent introduction of foreign matter from these members.

室52的內部清潔度例如設為在美國聯邦規格FED-STD-209D中規定之1000級以下,設為100級以下更為佳。The internal cleanliness of the chamber 52 is, for example, 1000 or less as defined in the U.S. Federal Regulation FED-STD-209D, and more preferably 100 or less.

加熱部19設置於比焊接單元18更靠下游側為較佳。加熱部19只要係將藉由焊接獲得之帶構件13的焊接部13w加熱成恆定的溫度範圍者,則無特別限定。在焊接部13w及其周邊,由於因焊接產生之應變而引起之應力有時殘留於內部。針對這種焊接部13w及其周邊,能夠藉由加熱部19加熱來去除應力。藉由去除該應力,即使在長時間連續實施溶液製膜方法時,也能夠抑制焊接部13w變形。It is preferable that the heating portion 19 is provided on the downstream side of the welding unit 18. The heating unit 19 is not particularly limited as long as it heats the welded portion 13w of the belt member 13 obtained by welding to a constant temperature range. In the welded portion 13w and its periphery, the stress due to the strain caused by the welding sometimes remains inside. The welded portion 13w and its periphery can be heated by the heating portion 19 to remove stress. By removing this stress, deformation of the welded portion 13w can be suppressed even when the solution film forming method is continuously performed for a long period of time.

焊接部13w基於加熱部19的加熱之溫度只要為可以去除應力的溫度,則無特別限定。例如當帶構件13由不銹鋼構成時,焊接部13w基於加熱部19的加熱之溫度為100℃以上200℃以下為較佳,120℃以上180℃以下更為佳。The temperature of the heating of the welded portion 13w based on the heating portion 19 is not particularly limited as long as it is a temperature at which stress can be removed. For example, when the belt member 13 is made of stainless steel, the temperature of the heating of the welded portion 13w based on the heating portion 19 is preferably 100 ° C or more and 200 ° C or less, more preferably 120 ° C or more and 180 ° C or less.

作為加熱部19例如有送風手段。如圖1所示,作為加熱部19的送風手段有導管56和送風機57。導管56吹出恆定溫度的氣體。送風機57在控制氣體溫度之基礎上,將該氣體送入導管56。此外,圖2中為了避免附圖的繁雜化而省略導管56和送風機57的圖示。As the heating unit 19, for example, there is a blowing means. As shown in FIG. 1, the air blowing means of the heating unit 19 includes a duct 56 and a blower 57. The conduit 56 blows a constant temperature of gas. The blower 57 supplies the gas to the conduit 56 based on the temperature of the control gas. In addition, in FIG. 2, the illustration of the duct 56 and the blower 57 is abbreviate|omitted in order to avoid the complication of a drawing.

加熱部19可以在帶構件13的傳送路上如圖1設置於焊接支撐輥41的相反側,亦可設置於焊接支撐輥41的相同側。The heating portion 19 may be provided on the conveying path of the belt member 13 on the opposite side of the welding support roller 41 as shown in FIG. 1 or on the same side of the welding support roller 41.

被去除應力之帶構件13被送至加熱部19的下游的捲取裝置20,並捲取成輥狀。捲取裝置20上設置捲取帶構件13之卷芯,並設有向周向旋轉該卷芯之驅動手段。The stress-removed belt member 13 is sent to the winding device 20 downstream of the heating portion 19, and is wound into a roll shape. The winding device 20 is provided with a winding core of the take-up belt member 13, and is provided with a driving means for rotating the winding core in the circumferential direction.

捲取裝置20還作為控制焊接位置Pw上的帶構件13和側構件11及中央構件12的張力之焊接張力控制手段發揮作用。在此,將捲取裝置20的轉矩控制成焊接位置Pw上的帶構件13和側構件11及中央構件12的張力保持恆定為較佳。由此,能夠在長邊方向上將焊接部13w設為恆定狀態。The winding device 20 also functions as a welding tension control means for controlling the tension of the belt member 13 and the side members 11 and the center member 12 at the welding position Pw. Here, it is preferable to control the torque of the winding device 20 so that the tension of the belt member 13 and the side members 11 and the center member 12 at the welding position Pw is kept constant. Thereby, the welded portion 13w can be set to a constant state in the longitudinal direction.

當開始焊接時,例如利用捲取裝置20如下進行為較佳。首先,在從送出部16至捲取裝置20之傳送路設置側構件11和中央構件12,將側構件11和中央構件12的各前端捲繞在捲取裝置20的卷芯。開始捲取側構件11和中央構件12。開始捲取,控制側構件11和中央構件12的傳送路徑,並將對接位置Ph保持在預定位置。在側構件11和中央構件12的對接位置Ph保持恆定之後,藉由焊接裝置42開始焊接。When the welding is started, it is preferably carried out, for example, by using the winding device 20 as follows. First, the side member 11 and the center member 12 are provided in the transfer path from the delivery portion 16 to the winding device 20, and the respective ends of the side member 11 and the center member 12 are wound around the winding core of the winding device 20. The winding side member 11 and the center member 12 are started to be wound. The winding is started, the conveying path of the side member 11 and the center member 12 is controlled, and the docking position Ph is maintained at a predetermined position. After the butting position Ph of the side member 11 and the center member 12 is kept constant, the welding is started by the welding device 42.

邊抑制側構件11、中央構件12、帶構件13的位置偏離,邊實施焊接為較佳。例如可以利用具備按壓裝置之如圖3及圖4所示之焊接單元61來代替焊接單元18。焊接單元61係在圖1及圖2所示之焊接單元18進一步具備按壓裝置62者,盡管與焊接單元18相同地具備位移機構50、控制器51、室52及清潔裝置55,但是為了避免附圖的繁雜化在圖3及圖4中省略這些構件的圖示。並且,對圖1及圖2相同的裝置和構件附加與圖1及圖2相同的符號,省略說明。此外,在焊接單元61中,室52以與外部空間隔開的方式包圍按壓構件62和焊接支撐輥41。It is preferable to perform welding while suppressing the positional deviation of the side member 11, the center member 12, and the belt member 13. For example, instead of the welding unit 18, a welding unit 61 as shown in FIGS. 3 and 4 including a pressing device can be used. In the welding unit 61, the welding unit 18 shown in FIGS. 1 and 2 further includes a pressing device 62. Although the displacement mechanism 50, the controller 51, the chamber 52, and the cleaning device 55 are provided in the same manner as the welding unit 18, in order to avoid attachment The complication of the drawings is omitted in FIGS. 3 and 4 . The same components and members as those in FIGS. 1 and 2 are denoted by the same reference numerals as those in FIGS. 1 and 2, and description thereof will be omitted. Further, in the welding unit 61, the chamber 52 surrounds the pressing member 62 and the welding support roller 41 in a manner spaced apart from the external space.

按壓裝置62係抑制側構件11、中央構件12及帶構件13在焊接位置Pw上的位置偏離者。按壓裝置62藉由包括第1傳送帶63及第2傳送帶64之一對傳送帶按壓焊接支撐輥41上的側構件11、中央構件12及帶構件13。The pressing device 62 suppresses the positional deviation of the side member 11, the center member 12, and the belt member 13 at the welding position Pw. The pressing device 62 presses the side member 11, the center member 12, and the belt member 13 on the welding support roller 41 against the conveyor belt by one of the first conveyor belt 63 and the second conveyor belt 64.

第1傳送帶63和第2傳送帶64係形成為環狀之無端傳送帶。第1傳送帶63和第2傳送帶64以向第5輥67~第7輥69的各長邊方向排列的方式捲繞於第5輥67~第7輥69的周面。第5輥67~第7輥69中的至少任一輥成為沿周向旋轉之驅動輥。第1傳送帶63和第2傳送帶64藉由該驅動輥的旋轉邊保持相互平行之傳送路邊被傳送。The first conveyor belt 63 and the second conveyor belt 64 are formed as endless belts in a ring shape. The first conveyor belt 63 and the second conveyor belt 64 are wound around the circumferential surfaces of the fifth roller 67 to the seventh roller 69 so as to be aligned in the longitudinal direction of the fifth roller 67 to the seventh roller 69. At least one of the fifth roller 67 to the seventh roller 69 is a driving roller that rotates in the circumferential direction. The first conveyor belt 63 and the second conveyor belt 64 are conveyed while maintaining the conveying path sides parallel to each other by the rotation of the driving roller.

第5輥67~第7輥69配設成旋轉軸與焊接支撐輥41的旋轉軸平行。The fifth roller 67 to the seventh roller 69 are disposed such that the rotation axis is parallel to the rotation axis of the welding support roller 41.

第5輥67~第7輥69在側構件11和中央構件12的傳送路上配設於第4輥29和焊接支撐輥41所配設之一側的相反側區域。第5輥67設置成與從第4輥29朝向焊接支撐輥41之側構件11和中央構件12的傳送路對置。第6輥68設置成與從焊接支撐輥41朝向加熱部19之側構件11和中央構件12的傳送路對置。第7混69適當配設成確定從第6輥68朝向第5輥67之第1傳送帶63和第2傳送帶64的傳送路。The fifth roller 67 to the seventh roller 69 are disposed on the conveying path of the side member 11 and the center member 12 on the side opposite to the side on which the fourth roller 29 and the welding support roller 41 are disposed. The fifth roller 67 is disposed to face the transport path from the fourth roller 29 toward the side member 11 of the welding support roller 41 and the center member 12. The sixth roller 68 is disposed to face the transport path from the welding support roller 41 toward the side member 11 of the heating portion 19 and the center member 12. The seventh blend 69 is appropriately disposed to define a transport path from the sixth roller 68 toward the first conveyor 63 and the second conveyor 64 of the fifth roller 67.

第5輥67和第6輥68配設成從第5輥67朝向第6輥68之第1傳送帶63和第2傳送帶64以按壓焊接支撐輥41上的側構件11、中央構件12及帶構件13的方式傳送。例如,當從上方焊接焊接支撐輥41上的側構件11、中央構件12時,第5輥67和第6輥68配設成它們的各下端成為低於焊接支撐輥41的上端的位置。The fifth roller 67 and the sixth roller 68 are disposed so as to press the first conveyor belt 63 and the second conveyor belt 64 from the fifth roller 67 toward the sixth roller 68 to press the side member 11, the center member 12, and the belt member on the welding support roller 41. 13 way to transfer. For example, when the side member 11 and the center member 12 on the welding support roller 41 are welded from above, the fifth roller 67 and the sixth roller 68 are disposed such that their lower ends become lower than the upper end of the welding support roller 41.

第5輥67和第6輥68設置成如下:第1傳送帶63的傳送路與側構件11和由側構件11形成之帶構件13的側部13s的傳送路對置,並且第2傳送帶64的傳送路與中央構件12和由中央構件12形成之帶構件13的中央部13c的傳送路對置。由此,第1傳送帶63向焊接支撐輥41按壓側構件11和側部13s,第2傳送帶64向焊接支撐輥41按壓中央構件12和中央部13c。The fifth roller 67 and the sixth roller 68 are disposed such that the conveying path of the first conveyor belt 63 faces the conveying path of the side member 11 and the side portion 13s of the belt member 13 formed by the side member 11, and the second conveyor belt 64 The conveying path faces the conveying path of the center member 12 and the center portion 13c of the belt member 13 formed by the center member 12. Thereby, the first conveyor belt 63 presses the side member 11 and the side portion 13s to the welding support roller 41, and the second conveyor belt 64 presses the center member 12 and the center portion 13c to the welding support roller 41.

如以上,第1傳送帶63和第2傳送帶64分別設置成與焊接支撐輥41對置,並以側構件11和中央構件12的高度在焊接位置Pw上的高度相等的方式進行按壓。側構件11和中央構件12的高度為各構件11、12表面的高度。如此將側構件11和中央構件12按壓成高度變得相等,並在該狀態下實施焊接,從而焊接部13w的態樣在長邊方向上變得更加均勻,並且能夠進一步可靠地進行焊接。As described above, the first conveyor belt 63 and the second conveyor belt 64 are respectively disposed to face the welding support roller 41, and are pressed such that the heights of the side members 11 and the center member 12 at the welding position Pw are equal. The height of the side members 11 and the center member 12 is the height of the surface of each of the members 11, 12. Thus, the side member 11 and the center member 12 are pressed so that the height becomes equal, and welding is performed in this state, so that the aspect of the welded portion 13w becomes more uniform in the longitudinal direction, and welding can be further reliably performed.

參考圖5及圖6,進一步詳細說明長邊焊接製程。第1傳送帶63和第2傳送帶64以相互分開之狀態傳送。第1傳送帶63和第2傳送帶64以焊接位置Pw通過第1傳送帶63與第2傳送帶64的間隙的方式設定傳送路。由此,側構件11的側緣11e和中央構件12的側緣12e相接觸之接觸位置Ps如圖5所示通過第1傳送帶63與第2傳送帶64的間隙,並在第1傳送帶63與第2傳送帶64之間焊接。另外,圖5中省略焊接裝置主體46的圖示。The long side welding process will be described in further detail with reference to FIGS. 5 and 6. The first conveyor belt 63 and the second conveyor belt 64 are conveyed in a state of being separated from each other. The first conveyor 63 and the second conveyor 64 set the transmission path so that the gap between the first conveyor 63 and the second conveyor 64 is at the welding position Pw. Thereby, the contact position Ps at which the side edge 11e of the side member 11 and the side edge 12e of the center member 12 contact each other passes through the gap between the first conveyor belt 63 and the second conveyor belt 64 as shown in FIG. 5, and is in the first conveyor belt 63 and the 2 Welding between the conveyor belts 64. In addition, the illustration of the welding apparatus main body 46 is abbreviate|omitted by FIG.

第1傳送帶63與第2傳送帶64的間隔D1設為6mm以上12mm以下的範圍為較佳。側構件11和中央構件12在寬度方向Y上的截面中,接觸位置Ps與第1傳送帶63的距離D2及接觸位置Ps與第2傳送帶64的距離D3分別設為3mm以上且小於6mm的範圍為較佳。The interval D1 between the first conveyor belt 63 and the second conveyor belt 64 is preferably in the range of 6 mm or more and 12 mm or less. In the cross section in the width direction Y of the side member 11 and the center member 12, the distance D2 between the contact position Ps and the first conveyor 63, and the distance D3 between the contact position Ps and the second conveyor 64 are set to be 3 mm or more and less than 6 mm, respectively. Preferably.

可以分別在焊接裝置主體46的上游和下游配設具有與焊接支撐輥41的旋轉軸平行之旋轉軸之輥(未圖示)來代替按壓裝置62。此時,能夠藉由由上游的其中一方的輥按壓側構件11和中央構件12且由下游的另一方的輥按壓帶構件13來按壓焊接位置Pw上的側構件11和中央構件12。Instead of the pressing device 62, a roller (not shown) having a rotation axis parallel to the rotation axis of the welding support roller 41 may be disposed upstream and downstream of the welding device main body 46, respectively. At this time, the side member 11 and the center member 12 at the welding position Pw can be pressed by pressing the side member 11 and the center member 12 by one of the upstream rollers and pressing the belt member 13 by the other downstream roller.

如圖6所示,在接觸位置Ps及其周邊由於焊接裝置42的熱被溶解而形成焊接液珠72。從該焊接液珠72向兩側傳熱,分別在側構件11和中央構件12產生受焊接中的熱影響之熱影響區域73。該熱影響區域73有時會立刻或經時性地顯出與不受熱影響之其他區域不同之性狀。例如若利用如此廣範圍產生熱影響者作為流延支撐體,則當長時間連續實施溶液製膜方法時,產生焊接部13w變形或流延膜起泡等弊端。As shown in FIG. 6, the welding bead 72 is formed at the contact position Ps and its periphery due to the heat of the welding device 42 being dissolved. Heat is transferred from the welding bead 72 to both sides, and a heat-affected zone 73 which is affected by heat during welding is generated in the side member 11 and the center member 12, respectively. The heat-affected zone 73 sometimes exhibits traits that are different from other zones that are not affected by heat, either immediately or over time. For example, when a heat-affected person is used as a casting support in such a wide range, when the solution film forming method is continuously performed for a long period of time, disadvantages such as deformation of the welded portion 13w or foaming of the cast film occur.

因此,如圖5所示,在焊接支撐輥41的周面中接觸位置Ps所通過之通過區域形成由熱傳導率高於側構件11及中央構件12之原材料構成之高熱傳導部71為較佳。由此,能夠使來自焊接裝置42(參考圖3、圖4)的熱更快地擴散。為了在焊接支撐輥41側更快地擴散熱,能夠進一步縮小側構件11和中央構件12的熱影響區域73的寬度,或者還使熱影響區域73的深度變淺。Therefore, as shown in FIG. 5, it is preferable to form the high heat conduction portion 71 composed of a material having a higher thermal conductivity than the side member 11 and the center member 12 in the passing region through which the contact position Ps passes in the circumferential surface of the welding support roller 41. Thereby, the heat from the welding device 42 (refer to FIGS. 3 and 4) can be diffused more quickly. In order to spread heat more quickly on the side of the welding support roller 41, the width of the heat-affected zone 73 of the side member 11 and the center member 12 can be further reduced, or the depth of the heat-affected zone 73 can be made shallower.

成為高熱傳導部71之通過區域的寬度D4為26mm以上32mm以下的範圍為較佳。It is preferable that the width D4 of the passage region of the high heat conduction portion 71 is in the range of 26 mm or more and 32 mm or less.

並且,第1傳送帶63及第2傳送帶64的兩面也形成由熱傳導率高於側構件11及中央構件12之原材料構成之高熱傳導部更為佳。由此,能夠在寬度方向或厚度方向上縮小熱影響區域73的大小。Further, it is preferable that both surfaces of the first conveyor belt 63 and the second conveyor belt 64 have a high heat conduction portion having a higher thermal conductivity than the materials of the side members 11 and the center member 12. Thereby, the size of the heat-affected zone 73 can be reduced in the width direction or the thickness direction.

側構件11的側緣11e和中央構件12的側緣12e為在焊接位置Pw上黏附成間隙為0(零)之狀態為較佳。因此,側構件11和中央構件12預先形成為對接各側緣11e及12e時不產生間隙之類的形狀為較佳。由此,能夠更加可靠地製造焊接部無空隙之帶構件。It is preferable that the side edge 11e of the side member 11 and the side edge 12e of the center member 12 are adhered to a gap of 0 (zero) at the welding position Pw. Therefore, it is preferable that the side member 11 and the center member 12 are formed in advance so as not to form a gap when the side edges 11e and 12e are butted. Thereby, it is possible to more reliably manufacture the belt member having no gap in the welded portion.

上述長邊焊接製程可以僅為在側構件11和中央構件12的長邊方向上連續實施焊接之連續焊接製程,除此之外,還可以實施斷續焊接之斷續焊接製程。若斷續焊接,則連續送至焊接裝置42之側構件11和中央構件12被間歇地焊接。這種斷續焊接製程在連續焊接製程之前進行為較佳。此時,在斷續焊接製程中,首先臨時接合側構件11和中央構件12之後,在連續焊接製程中遍及長邊方向的整個區域進行接合即可。The above-described long-side welding process may be a continuous welding process in which welding is continuously performed only in the longitudinal direction of the side members 11 and the center member 12. In addition, a intermittent welding process of intermittent welding may be performed. If the welding is intermittent, the side member 11 and the center member 12 continuously fed to the welding device 42 are intermittently welded. This intermittent soldering process is preferably performed prior to the continuous soldering process. At this time, in the intermittent welding process, first, the side member 11 and the center member 12 are temporarily joined, and then the entire area in the longitudinal direction is joined in the continuous welding process.

當在斷續焊接製程中臨時接合之後,在連續焊接製程中進行接合時,從對接部17(參考圖1、圖2)向焊接單元18引導側構件11和中央構件12並斷續焊接。另外,當對側構件11和中央構件12設定與用作後面的流延支撐體時的流延面對應之表面和與非流延面對應之裏面時,斷續焊接製程中的焊接針對裏面進行為較佳。因此,以裏面與焊接裝置主體46(參考圖1)對置而通過的方式傳送側構件11和中央構件12。When the joining is performed in the continuous welding process after the temporary joining in the intermittent welding process, the side member 11 and the center member 12 are guided from the butting portion 17 (refer to Figs. 1, 2) to the welding unit 18 and intermittently welded. Further, when the opposite side member 11 and the center member 12 are set to the surface corresponding to the casting surface when used as the rear casting support and the inner surface corresponding to the non-casting surface, the welding in the intermittent welding process is performed for the inside. It is better. Therefore, the side member 11 and the center member 12 are conveyed in such a manner that the inside faces the welding device main body 46 (refer to FIG. 1).

進行斷續焊接製程之後,引導並捲取於捲取裝置20。另外,亦可在捲取之前藉由加熱部19對焊接部進行加熱。藉由送出裝置(未圖示)捲出由經斷續焊接製程而捲取之側構件11和中央構件12構成之臨時接合構件(未圖示),並再次送至焊接單元18。關於該送出,以臨時焊接構件的表面與焊接裝置主體46(參考圖1)對置而通過的方式進行。在焊接單元18中進行連續焊接,獲得帶構件13。此外,代替該方法,亦可在上游和下游相對排列配設兩個焊接單元18,由上游的其中一方的焊接單元18實施斷續焊接,由下游的另一方的焊接單元18實施連續焊接。After the intermittent welding process, the winding device 20 is guided and taken up. Further, the welded portion may be heated by the heating portion 19 before winding. A temporary joining member (not shown) composed of the side member 11 and the center member 12 wound by the intermittent welding process is wound up by a feeding device (not shown), and sent to the welding unit 18 again. This delivery is performed such that the surface of the temporary welding member faces the welding device main body 46 (refer to FIG. 1). Continuous welding is performed in the welding unit 18 to obtain the belt member 13. Further, instead of this method, two welding units 18 may be arranged in the upstream and downstream directions, and intermittent welding may be performed by one of the upstream welding units 18, and continuous welding may be performed by the other welding unit 18 downstream.

若進行焊接,則有時比側構件11和中央構件12更凸起而形成焊接液珠72。因此,關於如以上實施在長邊方向焊接其中一方的面之第1製程和在長邊方向上焊接另一方的面之第2製程時使用之焊接支撐輥41,如圖5所示在焊接支撐輥41的周面中在接觸位置Ps所通過之通過區域形成有槽76為較佳。以由在第1製程中凸起之焊接液珠72形成之焊接部通過該槽76的方式傳送側構件11和中央構件12來實施第2製程即可。由此,能夠獲得更平滑且殘留應力更少之帶構件13。隨此,即使在溶液製膜中使用,在作為流延支撐體的帶上產生變形或形狀變化也更少,而且流延膜不起泡,能夠更加可靠地製造無厚度不均的薄膜。When welding is performed, the welding bead 72 may be formed more convex than the side member 11 and the center member 12. Therefore, the welding support roller 41 used in the first process of welding one of the faces in the longitudinal direction and the second process of welding the other face in the longitudinal direction is as shown in FIG. It is preferable that a groove 76 is formed in the peripheral surface of the roller 41 at a passing region through which the contact position Ps passes. The second process may be carried out by transporting the side member 11 and the center member 12 so that the welded portion formed by the welding bead 72 raised in the first process passes through the groove 76. Thereby, the belt member 13 which is smoother and has less residual stress can be obtained. As a result, even if it is used for film formation in a solution, deformation or shape change is less in the belt as the casting support, and the cast film is not foamed, and a film having no thickness unevenness can be more reliably produced.

槽76的寬度D5為6mm以上12mm以下的範圍為較佳,槽的深度D6為1mm左右即可。The width D5 of the groove 76 is preferably in the range of 6 mm or more and 12 mm or less, and the depth D6 of the groove may be about 1 mm.

在以上實施方式中,利用第3輥28作為調整對接部17上的側構件11的傳送路徑的手段,但是亦可利用如圖7所示之錐狀輥81來代替第3輥28。錐狀輥81係以直徑d從一端朝向另一端連續遞減的方式形成之截面圓形輥。直徑d從一端朝向另一端以恆定比例連續遞減。將錐狀輥81配設成直徑d較大的一端朝向中央構件12的傳送路且直徑d較小的另一端朝向中央構件12的相反側(側構件11的傳送路側)。In the above embodiment, the third roller 28 is used as a means for adjusting the conveying path of the side member 11 on the abutting portion 17, but the third roller 28 may be replaced by a tapered roller 81 as shown in FIG. The tapered roller 81 is a cross-sectional circular roller formed in such a manner that the diameter d continuously decreases from one end toward the other end. The diameter d is continuously decreased in a constant ratio from one end toward the other end. The tapered roller 81 is disposed such that the one end having the larger diameter d faces the conveying path of the center member 12 and the other end having the smaller diameter d faces the opposite side of the center member 12 (the conveying path side of the side member 11).

傳送中之側構件11藉由與該錐狀輥81接觸向朝向中央構件12之箭頭A方向改變傳送路徑,靠近中央構件12。由此,側構件11可靠地朝向對接位置Ph(參考圖1、圖2)傳送。The side member 11 during conveyance changes the conveyance path toward the center member 12 by the contact with the tapered roller 81, and approaches the center member 12. Thereby, the side member 11 is reliably conveyed toward the docking position Ph (refer to FIGS. 1 and 2).

錐狀輥81上具備有沿周向旋轉之驅動手段82為較佳。旋轉軸插通一端面的中央和另一端面的中央而形成。藉由由驅動手段82旋轉之錐狀輥81傳送側構件11,從而側構件更有效地靠近中央構件12。It is preferable that the tapered roller 81 is provided with a driving means 82 that rotates in the circumferential direction. The rotating shaft is inserted through the center of one end surface and the center of the other end surface. The side member 11 is conveyed by the tapered roller 81 rotated by the driving means 82, so that the side member is more effectively approached to the central member 12.

亦可利用如圖8所示之作為把持手段的夾子85來代替第3輥28。夾子85具備開口為字狀之夾子主體86和設置於夾子主體86的各前端部之1對挾持針87,挾持把持側構件11。挾持針87移動自如地設置於挾持側構件11之挾持位置與從挾持位置退避之退避位置之間。夾子85具備移動機構88,在開始把持之把持開始位置與解除把持之把持解除位置之間移動自如。並且,夾子85在寬度方向Y上也移動自如。Instead of the third roller 28, a clip 85 as a holding means as shown in Fig. 8 can be used. The clip 85 has an opening The clip-shaped main body 86 and the pair of gripping fingers 87 provided at the respective distal end portions of the clip main body 86 grip the grip side member 11. The gripping needle 87 is movably disposed between the gripping position of the grip side member 11 and the retracted position retracted from the gripping position. The clip 85 is provided with a moving mechanism 88 that is movable between a grip start position at which gripping is started and a grip release position at which gripping is released. Further, the clip 85 is also freely movable in the width direction Y.

隨著挾持針87向挾持位置移動,夾子85在把持開始位置把持側構件11。夾子85以把持側構件11之狀態向朝向中央構件12之方向A靠近,並向下游傳送。As the gripping needle 87 moves toward the gripping position, the clip 85 grips the side member 11 at the gripping start position. The clip 85 approaches the direction A of the holding side member 11 toward the center member 12, and is conveyed downstream.

錐狀輥81和夾子85為了使側構件11向中央構件12靠近而使用,除此之外,還可以為了使中央構件12向側構件11靠近而使用。此時,由錐狀輥81、夾子85支撐或傳送中央構件12即可。The tapered roller 81 and the clip 85 are used to bring the side member 11 toward the center member 12, and may be used in order to bring the center member 12 closer to the side member 11. At this time, the central member 12 may be supported or conveyed by the tapered roller 81 and the clip 85.

在上述實施方式中,中央構件12上同時焊接兩個側構件11,但是亦可將其中一方的側構件11焊接於中央構件12之後,將另一方的側構件11焊接於中央構件12。In the above embodiment, the two side members 11 are simultaneously welded to the center member 12. However, one of the side members 11 may be welded to the center member 12, and the other side member 11 may be welded to the center member 12.

如圖9所示,用作流延支撐體之帶91係呈環狀之無端(endless)帶。帶91係焊接帶構件13的長邊方向上的一端與另一端而成者。另外,用於製作帶91之帶構件13可以剪切為預定長度,當根據預先剪切為預定長度之側構件11和中央構件12製作帶構件13時,亦可以未剪切狀態製作帶91。該焊接部中的針孔直徑不到40μm為較佳。As shown in Fig. 9, the belt 91 used as the casting support is a ring-shaped endless belt. One end and the other end in the longitudinal direction of the 91-series welded belt member 13 are formed. Further, the belt member 13 for producing the belt 91 can be cut to a predetermined length, and when the belt member 13 is produced from the side member 11 and the center member 12 which are previously cut to a predetermined length, the belt 91 can be produced in an unsheared state. The pinhole diameter in the welded portion is preferably less than 40 μm.

向與寬度方向Y交叉的方向剪切帶構件13為較佳。以剪切方向與寬度方向Y所成之角成為大致5°以上15°以下範圍的方式剪切帶構件13更為佳。焊接如此剪切之帶構件13的長邊方向上的一端與另一端之焊接部91v和寬度方向Y所成之角θ2在大致5°以上15°以下的範圍內。在如此使長形帶構件13成為環狀之環狀焊接製程中,可以利用在長邊焊接製程中使用之焊接裝置42,亦可利用公知的其他焊接裝置。It is preferable to cut the belt member 13 in a direction crossing the width direction Y. It is more preferable that the tape member 13 is cut so that the angle formed by the shear direction and the width direction Y is approximately 5 or more and 15 or less. An angle θ2 between one end in the longitudinal direction of the strip member 13 to be welded and the welded portion 91v and the width direction Y at the other end is in a range of approximately 5° or more and 15° or less. In the annular welding process in which the elongated belt member 13 is formed into a ring shape, the welding device 42 used in the long-side welding process can be used, and other known welding devices can be used.

藉由焊接製造之帶91包括由側構件11(參考圖1~圖8)形成之側部91s和由中央構件12(參考圖1~圖8)形成之中央部91c,側部91s及中央部91c的焊接部91w露出於帶的表面91a或裏面91b。焊接部91w係相當於焊接部13w之部份。線狀焊接部91w設置成與帶91的長邊方向平行為較佳。如此獲得之帶91的寬度在2000mm以上3000mm以下的範圍內。The belt 91 manufactured by welding includes a side portion 91s formed by the side members 11 (refer to Figs. 1 to 8) and a central portion 91c formed by the center member 12 (refer to Figs. 1 to 8), a side portion 91s and a central portion The welded portion 91w of the 91c is exposed on the surface 91a or the inner surface 91b of the belt. The welded portion 91w corresponds to a portion of the welded portion 13w. It is preferable that the linear welded portion 91w is provided in parallel with the longitudinal direction of the belt 91. The width of the belt 91 thus obtained is in the range of 2000 mm or more and 3000 mm or less.

所獲得之帶91在經表面研磨並作成鏡面之後,用於溶液製膜設備。接著,以下對在溶液製膜設備中製造薄膜之方法進行說明。聚合物的種類不特別限定,使用在溶液製膜中能夠作成薄膜之公知的聚合物即可。以下實施方式中,以使用纖維素醯化物作為聚合物的情況為例子進行說明。The obtained belt 91 is used for a solution film forming apparatus after being surface-ground and mirror-finished. Next, a method of producing a film in a solution film forming apparatus will be described below. The type of the polymer is not particularly limited, and a known polymer which can form a film in a solution film formation may be used. In the following embodiments, a case where a cellulose halide is used as a polymer will be described as an example.

如圖10所示,溶液製膜設備110從上游側依次具備薄膜形成裝置117、第1拉幅機120、輥乾燥裝置124、第2拉幅機125、分切機126及捲取裝置127。薄膜形成裝置117由纖維素醯化物111溶解於溶劑112中而得到之濃液113形成薄膜116。第1拉幅機120邊由保持構件120a保持薄膜116的各側部邊進行乾燥。輥乾燥裝置124邊由複數個輥122支撐薄膜116邊進行乾燥。第2拉幅機125由保持構件125a保持薄膜116的各側部,對薄膜116賦予朝向寬度方向的張力。分切機126切除藉由第2拉幅機125的保持構件125a保持之各邊緣。捲取裝置127將切除邊緣之薄膜116捲在卷芯上作成輥狀。As shown in FIG. 10, the solution film forming apparatus 110 includes a film forming apparatus 117, a first tenter 120, a roll drying device 124, a second tenter 125, a slitter 126, and a winding device 127 in this order from the upstream side. The film forming apparatus 117 forms a film 116 from the dope 113 obtained by dissolving the cellulose halide 111 in the solvent 112. The first tenter 120 is dried while holding the side portions of the film 116 by the holding member 120a. The roll drying device 124 is dried while supporting the film 116 by a plurality of rolls 122. The second tenter 125 holds the side portions of the film 116 by the holding member 125a, and applies tension to the film 116 in the width direction. The slitter 126 cuts off the edges held by the holding members 125a of the second tenter 125. The winding device 127 rolls the film 116 on the cut edge onto the core to form a roll.

薄膜形成裝置117具備沿周向旋轉之1對製膜用輥131、132。1對製膜用輥131、132在水平面上以相互平行的方式排列,製膜用輥131與製膜用輥132上捲繞帶91。製膜用輥131為主動輥(驅動輥),製膜用輥132為自由輥。製膜用輥131、132上分別具備將周面溫度控制在預定溫度內的第1控制器(未圖示)及第2控制器(未圖示)。The film forming apparatus 117 includes a pair of film forming rollers 131 and 132 that rotate in the circumferential direction. The pair of film forming rollers 131 and 132 are arranged in parallel with each other on the horizontal surface, and the film forming roller 131 and the film forming roller 132 are formed. The upper belt 91 is wound. The film forming roller 131 is a driving roller (driving roller), and the film forming roller 132 is a free roller. Each of the film forming rollers 131 and 132 includes a first controller (not shown) and a second controller (not shown) that control the peripheral surface temperature within a predetermined temperature.

薄膜形成裝置117中,從帶91的移動方向上游側朝向下游側依次設置流出濃液113之流延模133、膜乾燥裝置134及剝離輥135。In the film forming apparatus 117, a casting die 133 that discharges the dope 113, a film drying device 134, and a peeling roller 135 are sequentially disposed from the upstream side toward the downstream side in the moving direction of the belt 91.

如圖11及圖12所示,流延模133係朝向支撐於製膜用輥131之帶91的表面91a流下濃液113(參考圖10)者。流延模133在前端具備流出濃液113(參考圖10)之流出口133a。流延模133以流出口133a與帶91的表面91a正對的方式配設。As shown in FIG. 11 and FIG. 12, the casting die 133 is configured such that the dope 113 (see FIG. 10) flows toward the surface 91a of the belt 91 supported by the film forming roller 131. The casting die 133 is provided at the front end with an outflow port 133a through which the dope 113 (refer to Fig. 10) flows. The casting die 133 is disposed such that the outflow port 133a faces the surface 91a of the belt 91.

從流延模133流下之濃液113(參考圖10)落在帶91的表面91a上的到達位置DP。由於帶91為移動狀態,所以落在到達位置DP上之濃液113(參考圖10)在設定於帶91的表面91a之流延區CA內流動並延伸。這樣,流延區CA內形成由濃液113(參考圖10)組成且流延寬度CW的流延膜136。The dope 113 (refer to FIG. 10) flowing down from the casting die 133 falls on the arrival position DP on the surface 91a of the belt 91. Since the belt 91 is in a moving state, the dope 113 (refer to FIG. 10) that has fallen on the reaching position DP flows and extends in the casting zone CA set on the surface 91a of the belt 91. Thus, a casting film 136 composed of the dope 113 (refer to FIG. 10) and having a casting width CW is formed in the casting zone CA.

流延模133配設成到達位置DP成為如以下敘述之位置。如圖11及圖13所示,到達位置DP設定於帶91的表面91a中支撐於製膜用輥131之部份。到達位置DP設定於比製膜用輥131的頂部TP更靠進帶91的移動方向上游側為較佳。並且,從旋轉軸131a的旋轉中心O131a朝向頂部TP延伸之面LTP與從旋轉軸131a的旋轉中心O131a朝向到達位置DP延伸之面LDP所成角之角度φ1為0°以上45°以下為較佳。The casting die 133 is disposed such that the arrival position DP becomes a position as described below. As shown in FIGS. 11 and 13, the arrival position DP is set to a portion of the surface 91a of the belt 91 that is supported by the film forming roller 131. It is preferable that the arrival position DP is set to be on the upstream side in the moving direction of the feed belt 91 from the top TP of the film forming roller 131. Further, the direction from the rotation center O 131a rotating shaft 131a of the plane L TP extending the top TP angle L DP by an angle of orientation reaches surface extending the position DP from the rotation center O 131a rotating shaft 131a of φ1 less than 0 ° 45 ° The following are preferred.

如圖10所示,膜乾燥裝置134具有第1導管141~第3導管143。朝向流延膜136送出乾燥風之第1導管141~第3導管143從上游側沿帶91的移動路依次配設。第1導管141設置於從製膜用輥131向製膜用輥132移動之帶91的表面91a側及裏面91b側。第2導管142設置於支撐在製膜用輥132之帶91的表面91a側。第3導管143設置於從製膜用輥132朝向製膜用輥131移動之帶91的表面91a側及裏面91b側。As shown in FIG. 10, the membrane drying device 134 has a first duct 141 to a third duct 143. The first duct 141 to the third duct 143 that send dry air toward the casting film 136 are sequentially disposed from the upstream side along the movement path of the belt 91. The first duct 141 is provided on the surface 91a side and the inner surface 91b side of the belt 91 that moves from the film forming roller 131 to the film forming roller 132. The second duct 142 is provided on the surface 91a side of the belt 91 supported by the film forming roller 132. The third duct 143 is provided on the surface 91a side and the inner surface 91b side of the belt 91 that moves from the film forming roller 132 toward the film forming roller 131.

第1導管~第3導管141~143分別連接於送風機(未圖示)。送風機上連接獨立控制分別供給至第1導管~第3導管141~143之氣體的溫度、濕度及流量之送風控制器(未圖示)。在第1~第3導管141~143上設置將從送風機供給之氣體作為乾燥風送出之送出口。設置於第1導管~第3導管141~143之送出口以與帶91的表面91a及裏面91b對置的方式形成。Each of the first to third conduits 141 to 143 is connected to a blower (not shown). A blower controller (not shown) that independently controls the temperature, humidity, and flow rate of the gas supplied to the first to third conduits 141 to 143 is connected to the blower. The first to third conduits 141 to 143 are provided with a delivery port that sends the gas supplied from the blower as dry air. The delivery ports provided in the first to third conduits 141 to 143 are formed to face the surface 91a and the inner surface 91b of the belt 91.

設置於第1導管141~第3導管143之流出口形成為狹縫狀,且從帶91的其中一端遍及另一端而延設。各流出口在帶91的寬度方向上的長度成為如乾燥風接觸於流延膜136整體者即可。The outflow ports provided in the first duct 141 to the third duct 143 are formed in a slit shape, and are extended from one end of the belt 91 to the other end. The length of each of the outflow ports in the width direction of the belt 91 may be such that the dry air contacts the entire casting film 136.

乾燥風的溫度隨著從帶91的移動路的上游側朝向下游側而變低為較佳。來自第1導管141的乾燥風的溫度為50℃以上140℃以下為較佳,來自第2導管142的乾燥風的溫度為50℃以上140℃以下為較佳,來自第3導管143的乾燥風的溫度為40℃以上100℃以下為較佳。The temperature of the dry wind is preferably lowered as it goes from the upstream side to the downstream side of the moving path of the belt 91. The temperature of the dry air from the first duct 141 is preferably 50° C. or higher and 140° C. or lower, and the temperature of the dry air from the second duct 142 is preferably 50° C. or higher and 140° C. or lower, and the dry air from the third duct 143 is preferably used. The temperature is preferably from 40 ° C to 100 ° C.

如圖11所示,製膜用輥131由旋轉軸131a和固定於旋轉軸131a之輥主體131b構成。製膜用輥132的結構與製膜用輥131相同。如圖12所示,旋轉軸131a上連接馬達171和驅動部172。製膜用輥131藉由馬達171以旋轉軸131a為中心旋轉。驅動部172向旋轉軸131a外加從製膜用輥132(參考圖10)朝向製膜用輥131之外力。藉由向旋轉軸131a外加外力F1,對帶91外加移動張力T1。並且,旋轉軸131a上安裝力量感測器173。力量感測器173檢測旋轉軸131a所承受之外力F1的大小。控制部(未圖示)以存儲於內部記憶體中之值除力量感測器173檢測出之外力F1來計算移動張力T1。移動張力T1的大小根據帶91的尺寸或移動路確定即可,例如為60N/mm2As shown in Fig. 11, the film forming roller 131 is composed of a rotating shaft 131a and a roller main body 131b fixed to the rotating shaft 131a. The structure of the film forming roller 132 is the same as that of the film forming roller 131. As shown in FIG. 12, the motor 171 and the driving portion 172 are connected to the rotating shaft 131a. The film forming roller 131 is rotated about the rotating shaft 131a by the motor 171. The driving unit 172 applies an external force from the film forming roller 132 (refer to FIG. 10) toward the film forming roller 131 to the rotating shaft 131a. The external force F1 is applied to the rotating shaft 131a, and the moving tension T1 is applied to the belt 91. Further, a force sensor 173 is attached to the rotating shaft 131a. The force sensor 173 detects the magnitude of the external force F1 that the rotating shaft 131a receives. The control unit (not shown) calculates the movement tension T1 by the force sensor 173 detecting the external force F1 with the value stored in the internal memory. The magnitude of the moving tension T1 may be determined according to the size of the belt 91 or the moving path, for example, 60 N/mm 2 .

接著,對藉由溶液製膜設備110進行之溶液製膜方法進行說明。溶液製膜方法中,依次進行膜形成製程、膜乾燥製程、剝離製程及薄膜乾燥製程。另外,“膜”是指位於帶91上之膜,而“薄膜”是指從帶91上剝下之膜。Next, a solution film forming method by the solution film forming apparatus 110 will be described. In the solution film forming method, a film forming process, a film drying process, a peeling process, and a film drying process are sequentially performed. Further, "film" means a film located on the belt 91, and "film" means a film peeled off from the belt 91.

如圖11所示,膜形成製程中,流延模133向帶91的表面91a連續流出濃液113(參考圖10)。藉由膜形成製程在流延區CA(參考圖12)內形成由濃液113組成且流延寬度CW(參考圖12)的流延膜136。As shown in Fig. 11, in the film forming process, the casting die 133 continuously flows out of the dope 113 to the surface 91a of the belt 91 (refer to Fig. 10). A casting film 136 composed of the dope 113 and having a casting width CW (refer to FIG. 12) is formed in the casting zone CA (refer to FIG. 12) by a film forming process.

如圖10及圖11所示,膜形成製程中,第1導管141朝向流延膜136及帶91的裏面91b送出乾燥風,第2導管142朝向流延膜136送出乾燥風,第3導管143朝向流延膜136及帶91的裏面91b送出乾燥風。若乾燥風接觸到流延膜136,則溶劑112從流延膜136中蒸發。並且,藉由乾燥風的接觸來加熱帶91的裏面91b,其結果促進溶劑從流延膜136中的蒸發。另外,製膜用輥132的周面溫度藉由第2控制器調節為高於流延膜136的溫度。藉由與製膜用輥132的接觸,製膜用輥132的熱傳遞至流延膜136,並從裏面91b側加熱帶91。這樣,促進溶劑從流延膜136中的蒸發。As shown in FIGS. 10 and 11, in the film forming process, the first duct 141 sends dry air toward the casting film 136 and the inner surface 91b of the belt 91, and the second duct 142 sends dry air toward the casting film 136, and the third duct 143 Dry air is sent toward the casting film 136 and the inner surface 91b of the belt 91. If the dry wind contacts the casting film 136, the solvent 112 evaporates from the casting film 136. Further, the inner surface 91b of the belt 91 is heated by the contact of the dry air, and as a result, the evaporation of the solvent from the casting film 136 is promoted. Further, the peripheral surface temperature of the film forming roller 132 is adjusted to be higher than the temperature of the casting film 136 by the second controller. The heat of the film forming roller 132 is transferred to the casting film 136 by the contact with the film forming roller 132, and the belt 91 is heated from the inner surface 91b side. In this way, evaporation of the solvent from the casting film 136 is promoted.

在剝離製程中,藉由溶劑的蒸發,以包含溶劑之狀態從帶91中剝下成為可以向第1拉幅機120傳送之程度的流延膜136。剝離時,用剝離輥135支撐薄膜116,並且將從帶91剝下流延膜136之剝離位置PP保持為恆定。另外,剝離輥135可以係具備驅動手段且沿周向旋轉之驅動輥。In the peeling process, the casting film 136 which is peeled off from the belt 91 in a state containing a solvent to the extent that it can be conveyed to the first tenter 120 is removed by evaporation of the solvent. At the time of peeling, the film 116 is supported by the peeling roller 135, and the peeling position PP at which the casting film 136 is peeled off from the belt 91 is kept constant. Further, the peeling roller 135 may be a driving roller that is provided with a driving means and that rotates in the circumferential direction.

被剝離流延膜136之帶91的溫度藉由膜乾燥裝置134變得高於從流延模133流出之濃液113的溫度。若直接對這種帶91流出濃液113,則導致引起濃液113的起泡。因此,利用第1控制器,將製膜用輥131的周面溫度調節為低於從流延模133流出之濃液113的溫度。由此,支撐於製膜用輥131之帶91的溫度變得低於從流延模133流出之濃液113的溫度,所以能夠防止濃液113的起泡。The temperature of the belt 91 of the peeled casting film 136 becomes higher than the temperature of the concentrated liquid 113 flowing out from the casting die 133 by the film drying device 134. If the concentrated liquid 113 is directly discharged from the belt 91, foaming of the concentrated liquid 113 is caused. Therefore, the temperature of the peripheral surface of the film forming roller 131 is adjusted to be lower than the temperature of the concentrated liquid 113 flowing out from the casting die 133 by the first controller. Thereby, the temperature of the belt 91 supported by the film forming roller 131 becomes lower than the temperature of the concentrated liquid 113 flowing out from the casting die 133, so that the foaming of the dope 113 can be prevented.

被剝離之流延膜136,亦即薄膜116依次引導至第1拉幅機120、輥乾燥裝置124及第2拉幅機125。在第1拉幅機120、輥乾燥裝置124及第2拉幅機125中進行薄膜116與預定的乾燥氣體接觸之薄膜乾燥製程。藉由薄膜乾燥製程進行薄膜116的乾燥。The peeled cast film 136, that is, the film 116 is sequentially guided to the first tenter 120, the roll drying device 124, and the second tenter 125. A film drying process in which the film 116 is brought into contact with a predetermined dry gas is performed in the first tenter 120, the roll drying device 124, and the second tenter 125. Drying of film 116 is carried out by a film drying process.

分切機126進行切除薄膜116的邊緣之切邊製程。被切除邊緣之薄膜116藉由捲取裝置127捲成輥狀。The slitter 126 performs a trimming process for cutting the edges of the film 116. The film 116 of the cut edge is wound into a roll shape by the winding device 127.

(帶檢查裝置)(with inspection device)

接著,對關於藉由帶製造設備10(參考圖1)製造之帶91進行在溶液製膜方法中使用時是否因帶91的翹曲而產生厚度不均的檢查之帶檢查裝置進行說明。Next, a tape inspection device for inspecting whether or not the thickness of the tape 91 is caused by the warpage of the tape 91 when the tape 91 manufactured by the tape manufacturing apparatus 10 (refer to FIG. 1) is used in the solution film forming method will be described.

如圖14及圖15所示,帶檢查裝置200具備1對檢查用輥201、202、位移部203、馬達205、驅動部206、力量感測器207、感測器單元208及控制部210(參考圖16)。As shown in FIGS. 14 and 15, the tape inspection device 200 includes a pair of inspection rollers 201 and 202, a displacement unit 203, a motor 205, a driving unit 206, a force sensor 207, a sensor unit 208, and a control unit 210 ( Refer to Figure 16).

1對檢查用輥201、202係用於捲繞作為檢查對象的帶91者,在水平面上排列成相互平行。檢查用輥201為主動輥,檢查用輥202為自由輥。檢查用輥201、202的形狀及尺寸採用與製膜用輥131、132相同者為較佳。例如,檢查用輥201、202的直徑與製膜用131、132的直徑相同為較佳。The pair of inspection rollers 201 and 202 are used to wind the belt 91 to be inspected, and are arranged in parallel on the horizontal plane. The inspection roller 201 is a driving roller, and the inspection roller 202 is a free roller. The shape and size of the inspection rollers 201 and 202 are preferably the same as those of the film forming rollers 131 and 132. For example, it is preferable that the diameters of the inspection rollers 201 and 202 are the same as the diameters of the film forming members 131 and 132.

另外,即使在檢查用輥201、202的直徑與製膜用輥131、132的直徑不同時,只要在作用於捲繞在檢查用輥201、202之帶91的垂直應力與作用於捲繞在製膜用輥131、132之帶91的垂直應力相等的條件下,都能夠應用本發明。作用於在直徑Dr的輥上捲繞之帶91的垂直應力N能夠以下述式表示。其中,T1為帶91的移動張力,THb為帶91的厚度。In addition, even when the diameters of the inspection rollers 201 and 202 are different from the diameters of the film forming rollers 131 and 132, the vertical stress acting on the belt 91 wound around the inspection rollers 201 and 202 acts on the winding. The present invention can be applied to the condition that the vertical stress of the belt 91 of the film forming rolls 131 and 132 is equal. The vertical stress N acting on the belt 91 wound on the roller of the diameter Dr can be expressed by the following formula. Among them, T1 is the moving tension of the belt 91, and THb is the thickness of the belt 91.

N=THb×T1/0.5DrN=THb×T1/0.5Dr

檢查用輥201由旋轉軸201a和軸著於旋轉軸201a之輥主體201b構成。檢查用輥202由旋轉軸202a和軸著於旋轉軸202a之輥主體202b構成。The inspection roller 201 is composed of a rotating shaft 201a and a roller main body 201b that is axially coupled to the rotating shaft 201a. The inspection roller 202 is composed of a rotating shaft 202a and a roller main body 202b that is axially coupled to the rotating shaft 202a.

旋轉軸202a在張力外加位置Pt與鬆弛位置Pr(參考圖17)之間移動自如。張力外加位置Pt為對掛繞於檢查用輥201、202之帶91外加預定張力之位置。鬆弛位置Pr為掛繞於檢查用輥201、202之帶91鬆弛之位置。驅動部206向旋轉軸201a外加從輥主體202b朝向輥主體201b之外力F2。藉由向旋轉軸201a外加外力F2,對掛繞於檢查用輥202、201之帶91外加移動張力T2。力量感測器207檢測旋轉軸201a所承受之外力F2的大小。The rotating shaft 202a is freely movable between the tension applied position Pt and the slack position Pr (refer to FIG. 17). The tension applied position Pt is a position at which a predetermined tension is applied to the belt 91 wound around the inspection rollers 201, 202. The slack position Pr is a position where the belt 91 wound around the inspection rollers 201 and 202 is slack. The driving unit 206 applies a force F2 from the roller main body 202b toward the roller main body 201b to the rotating shaft 201a. By applying an external force F2 to the rotating shaft 201a, a moving tension T2 is applied to the belt 91 wound around the inspection rollers 202, 201. The force sensor 207 detects the magnitude of the external force F2 that the rotating shaft 201a receives.

在支撐於檢查用輥201上之帶91的表面91a上設定向帶91的寬度方向延伸之測定位置MP1。測定位置MP1係與到達位置DP(參考圖11)對應者。亦即,從旋轉軸201a的旋轉中心O201a朝向檢查用輥201的頂部TP延伸之面MTP與從旋轉軸201a的旋轉中心O201a朝向測定位置MP1延伸之面MMP1所成角的角度φ2等於角度φ1(參考圖11)。The measurement position MP1 extending in the width direction of the belt 91 is set on the surface 91a of the belt 91 supported on the inspection roller 201. The measurement position MP1 corresponds to the arrival position DP (refer to FIG. 11). That is, the angle of the face direction measurement position M of MP1 MP1 extends and an angle from the rotation axis center O of surfaces 201a 201a extends M TP TP of the top roller 201 φ2 from the rotation center O of the rotating shaft 201a 201a toward the inspection Equal to the angle φ1 (refer to Figure 11).

周面201bx上設定測定位置MP2。測定位置MP2為面MMP1與軸向端部201be的交線。The measurement position MP2 is set on the circumferential surface 201bx. The measurement position MP2 is the intersection of the surface M MP1 and the axial end portion 201be.

感測器單元208配設於帶91的表面91a側,亦即面MMP1上為較佳。感測器單元208具備與測定位置MP1正對之測定窗208a。測定窗208a從支撐帶91之輥主體201b的軸向一端遍及另一端朝向帶91的寬度方向延設。The sensor unit 208 is disposed on the side of the surface 91a of the belt 91, that is, on the surface M MP1 . The sensor unit 208 includes a measurement window 208a that is opposite to the measurement position MP1. The measurement window 208a extends from one end in the axial direction of the roller main body 201b of the support belt 91 to the width direction of the belt 91 over the other end.

並且,感測器單元208具備距離感測器208x和基準位置檢測感測器208y。距離感測器208x測定從測定窗208a至測定位置MP1的距離或從測定窗208a至測定位置MP2的距離。基準位置檢測感測器208y檢測設定於帶91的表面91a之基準位置是否在測定位置MP1上。距離感測器208x具有感測器件(未圖示)、內置CPU(未圖示)及內置記憶體(未圖示)。作為基準位置檢測感測器208y,例如能夠利用反射型光感測器。另外,關於在帶91的表面91a上設定之基準位置進行後述。Also, the sensor unit 208 is provided with a distance sensor 208x and a reference position detecting sensor 208y. The distance sensor 208x measures the distance from the measurement window 208a to the measurement position MP1 or the distance from the measurement window 208a to the measurement position MP2. The reference position detecting sensor 208y detects whether or not the reference position set on the surface 91a of the belt 91 is at the measuring position MP1. The distance sensor 208x has a sensing device (not shown), a built-in CPU (not shown), and a built-in memory (not shown). As the reference position detecting sensor 208y, for example, a reflective photo sensor can be utilized. The reference position set on the surface 91a of the belt 91 will be described later.

向帶91的寬度方向延伸之厚度測定線ST(j)[j=1,2,3,......,n]設定為向帶91的長邊方向排列。並且,向帶91的長邊方向延伸之厚度測定線SM(i)[i=1,2,3,......,m]設定為向帶91的寬度方向排列。另外,相鄰之厚度測定線ST的間隔及相鄰之厚度測定線SM的間隔預先設定為預定值。The thickness measurement lines ST(j) [j = 1, 2, 3, ..., n) extending in the width direction of the belt 91 are set to be aligned in the longitudinal direction of the belt 91. Further, the thickness measurement lines SM(i) [i = 1, 2, 3, ..., m) extending in the longitudinal direction of the belt 91 are set to be aligned in the width direction of the belt 91. Further, the interval between the adjacent thickness measurement lines ST and the interval between the adjacent thickness measurement lines SM are set to a predetermined value in advance.

如圖16所示,控制部210具備CPU211、存儲部212、距離計算部216、浮起量計算部217及判定部218。As shown in FIG. 16 , the control unit 210 includes a CPU 211 , a storage unit 212 , a distance calculation unit 216 , a floating amount calculation unit 217 , and a determination unit 218 .

CPU211透過總線222與存儲部212或各部216~218電性連接。存儲部212中儲存有程序或各資料。作為儲存於存儲部212中之程序,有帶的檢查用程序等。並且,作為儲存於存儲部212中之資料,有帶的厚度情報225(參考圖18)、閾值TH1或移動張力T1等。The CPU 211 is electrically connected to the storage unit 212 or the respective units 216 to 218 via the bus 222. A program or each material is stored in the storage unit 212. As a program stored in the storage unit 212, there is a check program for the tape or the like. Further, as the data stored in the storage unit 212, the tape thickness information 225 (refer to FIG. 18), the threshold value TH1, the movement tension T1, and the like are included.

如圖18所示,帶的厚度情報225由各個厚度測定線ST(參考圖15)的位置情報MD和各個厚度測定線ST(參考圖15)上的帶91的厚度分佈情報DB構成。位置情報MD表示帶91的長邊方向上從基準位置B1(參考圖15)至任意的厚度測定線ST(j)的距離L(j)(參考圖15)。其中,基準位置B1露出於帶91的表面91a之焊接部91v(參考圖15)。As shown in FIG. 18, the tape thickness information 225 is composed of the position information MD of each thickness measurement line ST (refer to FIG. 15) and the thickness distribution information DB of the belt 91 on each thickness measurement line ST (refer to FIG. 15). The positional information MD indicates the distance L(j) from the reference position B1 (refer to FIG. 15) to the arbitrary thickness measurement line ST(j) in the longitudinal direction of the belt 91 (refer to FIG. 15). Here, the reference position B1 is exposed to the welded portion 91v of the surface 91a of the belt 91 (refer to FIG. 15).

厚度分佈情報DB由厚度測定線ST與厚度測定線SM的各交點P上的帶91的厚度測定值D構成,按每個厚度測定線ST分組測定值D。例如,當任意的厚度測定線ST(j)與任意的厚度測定線SM(i)的交點P(i,j)上的帶91的厚度測定值表示為D(i,j)時,任意的厚度測定線ST(j)的厚度分佈情報DB(j)中包含D(1,j)、D(2,j)、D(3,j)、......、D(i-1,j)、D(i,j)、D(i+1,j)、......、D(m,j)。此外,測定值D(i,j)能夠預先藉由超音波感測器等得到。The thickness distribution information DB is composed of the thickness measurement value D of the belt 91 at each intersection P of the thickness measurement line ST and the thickness measurement line SM, and the measurement value D is grouped for each thickness measurement line ST. For example, when the measured value of the thickness of the belt 91 on the intersection P(i, j) of the arbitrary thickness measurement line ST(j) and the arbitrary thickness measurement line SM(i) is expressed as D(i, j), any The thickness distribution information DB(j) of the thickness measurement line ST(j) includes D(1, j), D(2, j), D(3, j), ..., D(i-1). , j), D(i, j), D(i+1, j), ..., D(m, j). Further, the measured value D(i, j) can be obtained in advance by an ultrasonic sensor or the like.

如圖16所示,距離計算部216根據式(2)計算從輥主體201b的周面201bx至帶91的表面91a的距離H(參考圖19)。As shown in FIG. 16, the distance calculating unit 216 calculates the distance H from the circumferential surface 201bx of the roller main body 201b to the surface 91a of the belt 91 according to the formula (2) (refer to FIG. 19).

式(2)為H=B-A。Formula (2) is H=B-A.

A為從測定窗208a至測定位置MP1的距離(參考圖19),B為從測定窗208a至測定位置MP2的距離(參考圖19)。A is the distance from the measurement window 208a to the measurement position MP1 (refer to FIG. 19), and B is the distance from the measurement window 208a to the measurement position MP2 (refer to FIG. 19).

浮起量計算部217根據式(1)計算從周面201bx至帶91的裏面91b的浮起量CL(參考圖20)。The floating amount calculation unit 217 calculates the floating amount CL from the circumferential surface 201bx to the inner surface 91b of the belt 91 according to the formula (1) (refer to FIG. 20).

式(1)為CL=H-D。Formula (1) is CL=H-D.

判定部218判定藉由浮起量計算部217計算出之所有CL是否在閾值TH1以下。閾值TH1儲存於存儲部212內。閾值TH1根據帶91的目標質量確定即可。在溶液製膜方法中,為了抑制厚度不均故障或起因於厚度不均故障之剝離殘留故障或起泡,將閾值TH1設定在0.1mm以下為較佳。The determination unit 218 determines whether or not all of the CLs calculated by the floating amount calculation unit 217 are equal to or smaller than the threshold TH1. The threshold TH1 is stored in the storage unit 212. The threshold TH1 may be determined according to the target quality of the belt 91. In the solution film forming method, in order to suppress the thickness unevenness failure or the peeling residual failure or foaming due to the thickness unevenness failure, it is preferable to set the threshold TH1 to 0.1 mm or less.

接著,對如圖14所示之帶檢查裝置200中的帶檢查製程230(參考圖21)進行說明。Next, a tape inspection process 230 (refer to FIG. 21) in the tape inspection apparatus 200 shown in FIG. 14 will be described.

首先,位移部203將旋轉軸202a設置在鬆弛位置Pr上(參考圖17)。將作為檢查對象的帶91掛繞在檢查用輥201、202上。之後,位移部203將旋轉軸202a設置在張力外加位置Pt上(圖21的S10)。First, the displacement portion 203 sets the rotation shaft 202a at the slack position Pr (refer to FIG. 17). The tape 91 to be inspected is hung on the inspection rollers 201 and 202. Thereafter, the displacement portion 203 sets the rotation shaft 202a at the tension application position Pt (S10 of Fig. 21).

如圖15及圖16所示,驅動部206在控制部210的控制下,對旋轉軸201a外加外力F2。力量感測器207檢測外力F2。控制部210從力量感測器207讀取外力F2,從存儲部212讀取值BS。值BS係帶91的平均截面積Sav乘以2而獲得者。接著,控制部210將外力F2除以值BS來計算移動張力T2。而且,控制部210調節外力F2的大小,以便計算出之移動張力T2變得與從存儲部212讀取之移動張力T1相同。這樣,對帶91外加與製膜時相同的移動張力(圖21的S11)。As shown in FIGS. 15 and 16, the drive unit 206 applies an external force F2 to the rotating shaft 201a under the control of the control unit 210. The force sensor 207 detects the external force F2. The control unit 210 reads the external force F2 from the force sensor 207 and reads the value BS from the storage unit 212. The average cross-sectional area Sav of the value BS strap 91 is multiplied by 2 to obtain. Next, the control unit 210 divides the external force F2 by the value BS to calculate the movement tension T2. Moreover, the control unit 210 adjusts the magnitude of the external force F2 so that the calculated movement tension T2 becomes the same as the movement tension T1 read from the storage unit 212. Thus, the same movement tension as that at the time of film formation is applied to the belt 91 (S11 of Fig. 21).

如圖14及圖15所示,若馬達205旋轉旋轉軸201a,則帶91向長邊方向移動。基準位置檢測感測器208y利用光源向測定位置MP1放出測試光。從基準位置檢測感測器208y放出之測試光在測定位置MP1反射並成為反射光入射到測定窗208a。基準位置檢測感測器208y檢測從測定窗208a入射之反射光的量。當檢測出之反射光的量小於基準量時,內置CPU向CPU211發送基準位置檢測信號。其中,基準量係在測定位置MP1上照射測試光時除了基準位置B1以外的帶91的表面91a上之反射光的量。這樣,基準位置檢測感測器208y在測定位置MP1上進行基準位置B1的檢測(圖21的S12)。As shown in FIGS. 14 and 15, when the motor 205 rotates the rotating shaft 201a, the belt 91 moves in the longitudinal direction. The reference position detecting sensor 208y emits test light to the measurement position MP1 using the light source. The test light emitted from the reference position detecting sensor 208y is reflected at the measurement position MP1 and becomes reflected light incident on the measurement window 208a. The reference position detecting sensor 208y detects the amount of reflected light incident from the measuring window 208a. When the amount of reflected light detected is less than the reference amount, the built-in CPU transmits a reference position detection signal to the CPU 211. Here, the reference amount is the amount of reflected light on the surface 91a of the belt 91 other than the reference position B1 when the test light is irradiated on the measurement position MP1. In this way, the reference position detecting sensor 208y performs the detection of the reference position B1 at the measurement position MP1 (S12 of Fig. 21).

CPU211使檢查用輥201透過馬達205從接收基準位置檢測信號之時刻僅旋轉預定時間t1。藉由檢查用輥201的旋轉,向長邊方向送出與時間t1相應之距離L量的帶91。例如,若從基準位置B1僅送出距離L(j)量的帶91,則厚度測定線ST(j)位於測定位置MP1上(圖21的S13)。The CPU 211 rotates the inspection roller 201 through the motor 205 only for a predetermined time t1 from the timing of receiving the reference position detection signal. By the rotation of the inspection roller 201, the belt 91 of the distance L corresponding to the time t1 is sent in the longitudinal direction. For example, when only the belt 91 having the distance L(j) is sent from the reference position B1, the thickness measurement line ST(j) is located at the measurement position MP1 (S13 in Fig. 21).

如圖19所示,感測器單元208利用距離感測器208x(參考圖16)按每個測定位置MP1上的交點P(參考圖15)測定從帶91的表面91a至測定窗208a的距離A(圖21的S14)。例如,當厚度測定線ST(j)位於測定位置MP1上時(參考圖15),距離感測器208x(參考圖16)測定厚度測定線ST(j)上的交點P(i,j)[i=1,2,3,......m]上的距離A(i,j)[i=1,2,3,......m]。As shown in FIG. 19, the sensor unit 208 measures the distance from the surface 91a of the belt 91 to the measurement window 208a at the intersection point P (refer to FIG. 15) at each measurement position MP1 by the distance sensor 208x (refer to FIG. 16). A (S14 of Fig. 21). For example, when the thickness measurement line ST(j) is located at the measurement position MP1 (refer to FIG. 15), the distance sensor 208x (refer to FIG. 16) measures the intersection P(i, j) on the thickness measurement line ST(j) [ The distance A(i,j)[i=1,2,3,...m] on i=1, 2, 3, ... m].

並且,感測器單元208利用距離感測器208x(參考圖16)在測定位置MP2(參考圖15)測定從軸向端部201be至測定窗208a的距離B。當厚度測定線ST(j)位於測定位置MP1上時,距離感測器208x(參考圖16)測定從軸向端部201be至測定窗208a的距離B(j)(圖21的S15)。另外,若距離B(j)的測定點為設定在測定位置MP2上之點,則可以為1個點,亦可為複數個點。將距離B(j)的測定點設定為1個點時,將其測定點上的測定值設為距離B(j)即可。並且,將距離B(j)的測定點設定為複數個點時,可以將各個測定點上的測定值的平均值設為距離B(j)。Further, the sensor unit 208 measures the distance B from the axial end portion 201be to the measurement window 208a at the measurement position MP2 (refer to FIG. 15) by the distance sensor 208x (refer to FIG. 16). When the thickness measurement line ST(j) is located at the measurement position MP1, the distance sensor 208x (refer to FIG. 16) measures the distance B(j) from the axial end portion 201be to the measurement window 208a (S15 of FIG. 21). Further, if the measurement point of the distance B(j) is a point set at the measurement position MP2, it may be one point or a plurality of points. When the measurement point of the distance B (j) is set to one point, the measured value at the measurement point may be set to the distance B (j). Further, when the measurement point of the distance B(j) is set to a plurality of points, the average value of the measured values at the respective measurement points can be set to the distance B (j).

距離A和距離B的測定值分別儲存於存儲部212中(參考圖16)(圖21的S16)。The measured values of the distance A and the distance B are stored in the storage unit 212 (refer to FIG. 16) (S16 of FIG. 21).

CPU211進行是否結束有關所有厚度測定線ST的測定之判定(圖21的S17)。當判定為結束有關所有厚度測定線ST的測定時,進入下一個處理(圖21的S20)。另一方面,當判定為未結束有關所有厚度測定線ST的測定時,反覆進行使帶91移動至下一個厚度測定線ST到達測定位置MP1上之步驟(圖21的S18)和對該厚度測定線ST進行測定之一連串的步驟(S14~S16)。The CPU 211 determines whether or not the measurement of all the thickness measurement lines ST is completed (S17 of Fig. 21). When it is determined that the measurement regarding all the thickness measurement lines ST is ended, the process proceeds to the next process (S20 of Fig. 21). On the other hand, when it is determined that the measurement of all the thickness measurement lines ST has not been completed, the step of moving the belt 91 to the next thickness measurement line ST to the measurement position MP1 (S18 of FIG. 21) and the thickness measurement are repeatedly performed. The line ST performs a series of steps (S14 to S16).

距離計算部216根據式(2)計算從軸向端部201be至帶91的表面91a的距離H(參考圖20)(圖21的S20)。計算出之距離H儲存於存儲部212中(參考16)。The distance calculating unit 216 calculates the distance H from the axial end portion 201be to the surface 91a of the belt 91 (refer to FIG. 20) according to the formula (2) (S20 of FIG. 21). The calculated distance H is stored in the storage unit 212 (refer to 16).

式(2)為H(i,j)=B(j)-A(i,j)。Equation (2) is H(i,j)=B(j)-A(i,j).

[j=1,2,3,......n][i=1,2,3,......m][j=1,2,3,...n][i=1,2,3,...m]

浮起量計算部217從存儲部212讀入帶的厚度情報225,根據式(1)計算浮起量CL(i,j)(參考圖21)(圖21的S21)。計算出之浮起量CL儲存於存儲部212中(參考圖16)。The floating amount calculation unit 217 reads the thickness information 225 of the tape from the storage unit 212, and calculates the floating amount CL(i, j) (refer to FIG. 21) according to the formula (1) (S21 of FIG. 21). The calculated floating amount CL is stored in the storage unit 212 (refer to FIG. 16).

式(1)為CL(i,j)=H(i,j)-D(i,j)。Equation (1) is CL(i,j)=H(i,j)-D(i,j).

[j=1,2,3,......n][i=1,2,3,......m][j=1,2,3,...n][i=1,2,3,...m]

判定部218判定該帶91的所有浮起量CL(i,j)是否在閾值TH1以下(圖21的S22)。當判定為所有浮起量CL(i,j)在閾值TH1以下時,判定該帶91為“合格品”(圖21的S23)。另一方面,判定為在容許範圍外之帶91判定為“不合格品”(圖21的S24)。在容許範圍外是指浮起量CL(i,j)中的至少一個大於閾值TH1。The determination unit 218 determines whether or not all the floating amounts CL(i, j) of the belt 91 are equal to or smaller than the threshold TH1 (S22 in Fig. 21). When it is determined that all the floating amounts CL(i, j) are equal to or less than the threshold TH1, it is determined that the belt 91 is "good product" (S23 of Fig. 21). On the other hand, it is determined that the belt 91 outside the allowable range is judged as "non-conforming product" (S24 of Fig. 21). Outside the allowable range means that at least one of the floating amounts CL(i, j) is greater than the threshold TH1.

在將判定為“不合格品”之帶91使用在溶液製膜方法中時,導致流延膜136上產生厚度不均。在本發明中,由於根據與製膜條件相同條件下的浮起量CL檢查製造出之帶91,因此不實施溶液製膜方法即可檢測是否為引發流延膜136的厚度不均之帶。When the belt 91 judged to be "nonconforming product" is used in the solution film forming method, thickness unevenness occurs in the casting film 136. In the present invention, since the produced tape 91 is inspected based on the floating amount CL under the same conditions as the film forming conditions, it is possible to detect whether or not the tape is caused to cause uneven thickness of the casting film 136 without performing the solution film forming method.

此外,如圖11及圖12所示,可以在流延模133的移動方向上游側設置對液珠的背面側(帶91的移動方向上游側)進行減壓之減壓室237。其中,液珠係藉由從流延模133流出之濃液從流出口133a遍及帶91的表面91a而形成者。能夠藉由減壓室237抑制隨著帶91的移動在帶91的表面91a附近產生且因流向帶91的移動方向之攜帶風引起之液珠的振動,甚至能夠防止流延膜或薄膜的厚度不均等。當帶91的移動速度超過30m/分鐘時,因攜帶風引起之液珠的振動會成為問題。因此,當帶91的移動速度超過30m/分鐘時,設置減壓室237為較佳。Further, as shown in FIG. 11 and FIG. 12, a decompression chamber 237 that decompresses the back side of the liquid droplet (the upstream side in the moving direction of the belt 91) on the back side of the casting die 133 can be provided on the upstream side in the moving direction of the casting die 133. Among them, the liquid bead is formed by passing the concentrated liquid flowing out from the casting die 133 from the outflow port 133a over the surface 91a of the belt 91. By the decompression chamber 237, it is possible to suppress the vibration of the bead caused by the wind accompanying the movement of the belt 91 in the vicinity of the surface 91a of the belt 91 and the moving direction of the belt 91, and it is possible to prevent the thickness of the casting film or the film even. Not equal. When the moving speed of the belt 91 exceeds 30 m/min, the vibration of the liquid bead caused by the wind is a problem. Therefore, when the moving speed of the belt 91 exceeds 30 m/min, it is preferable to provide the decompression chamber 237.

減壓室237在帶91的移動方向上比流延模133更靠近上游側,以在帶91的表面91a的法線方向上靠近帶91的表面91a的方式配設。減壓室237與帶91的表面91a的間隔例如為0.7mm以下。減壓室237上透過吸引管連接用於吸引減壓室237內的氣體之減壓扇(未圖示)。The decompression chamber 237 is disposed closer to the upstream side than the casting die 133 in the moving direction of the belt 91, and is disposed closer to the surface 91a of the belt 91 in the normal direction of the surface 91a of the belt 91. The interval between the decompression chamber 237 and the surface 91a of the belt 91 is, for example, 0.7 mm or less. A decompression fan (not shown) for sucking the gas in the decompression chamber 237 is connected to the decompression chamber 237 through a suction pipe.

減壓室237由箱形的室主體、用於提高室主體內的密封性之密封構件、及為了使減壓室237內的氣體的流動成為預定方向而進行整頓之整流構件構成。室主體係用於包圍液珠的背面側者,具有上游側遮風板237a、1對側方遮風板237b、頂板237c及前面板。上游側遮風板237a設置成以相對帶91的表面91a豎立之姿勢,在比流出口133a(參考圖11)更靠近帶91的移動方向上游側,在帶91的表面91a的法線方向上靠近帶91的表面91a。上游側遮風板237a從帶91的其中一方的側部遍及另一方的側部延設,上游側遮風板237a的兩端部分別與側部正對。1對側方遮風板237b分別以相對側部的表面豎立之姿勢,從上游側遮風板237a的兩端部朝向帶91的移動方向下游側延設。1對側方遮風板237b上掛繞頂板237c和前面板。The decompression chamber 237 is composed of a box-shaped chamber main body, a sealing member for improving the sealing property in the chamber main body, and a rectifying member for rectifying the flow of the gas in the decompression chamber 237 in a predetermined direction. The room main system is used to surround the back side of the liquid bead, and has an upstream side windshield 237a, a pair of side windshields 237b, a top plate 237c, and a front panel. The upstream side windshield 237a is disposed in a posture that is erected with respect to the surface 91a of the belt 91, on the upstream side in the moving direction of the belt 91 than the outflow port 133a (refer to FIG. 11), in the normal direction of the surface 91a of the belt 91 Near the surface 91a of the belt 91. The upstream side windshield 237a extends from the side of one of the belts 91 to the other side, and both end portions of the upstream side windshield 237a are opposed to the side portions. Each of the pair of side windshields 237b is extended from the both end portions of the upstream side windshield 237a toward the downstream side in the moving direction of the belt 91 in a posture in which the surfaces of the opposite side portions are erected. A pair of side windshields 237b are hung around the top plate 237c and the front panel.

減壓室主體被上游側遮風板237a、1對側方遮風板237b、頂板237c及前面板包圍而形成,且具有朝向帶91的表面91a開口之吸引口(未圖示)。減壓室237藉由減壓扇(未圖示)從吸引口吸引位於液珠的上游側之氣體。吸引位於液珠的上游側之氣體的結果,液珠的上游側的氣壓下降,從而能夠產生液珠的上游側與下游側的壓力差ΔP。由該壓力差ΔP,能夠抑制隨著帶91的移動而在帶91的表面91a附近產生且因流向帶91的移動方向之攜帶風引起之液珠的振動,甚至能夠防止流延膜或薄膜的厚度不均等。The decompression chamber main body is formed by the upstream side windshields 237a and 1 and the side windshield 237b, the top plate 237c, and the front panel, and has a suction port (not shown) that opens toward the surface 91a of the belt 91. The decompression chamber 237 attracts a gas located on the upstream side of the liquid droplet from the suction port by a pressure reducing fan (not shown). As a result of attracting the gas located on the upstream side of the liquid bead, the air pressure on the upstream side of the liquid bead drops, and the pressure difference ΔP between the upstream side and the downstream side of the liquid bead can be generated. By the pressure difference ΔP, it is possible to suppress the vibration of the bead which is generated in the vicinity of the surface 91a of the belt 91 in the moving direction of the belt 91 as the belt 91 moves, and even the cast film or the film can be prevented. The thickness is not uniform.

如圖11及圖13所示,帶91的表面91a上形成減壓區BA。減壓區BA為支撐於製膜用輥131之帶91的表面91a中被減壓室237覆蓋之部份。As shown in FIGS. 11 and 13, a pressure reducing area BA is formed on the surface 91a of the belt 91. The decompression zone BA is a portion of the surface 91a of the belt 91 supported by the film forming roller 131 covered by the decompression chamber 237.

此時,利用帶檢查裝置200(參考圖14)除了進行有關測定位置MP1的浮起量CL的測定,還對與減壓區BA對應之測定位置MA(參考圖15)進行浮起量CL的測定為較佳。更具體而言,在設定於帶91的表面91a之測定位置MA設定沿寬度方向延伸之測定線ML,按每個該測定線ML進行上述的帶檢查製程230(參考圖21)為較佳。測定線ML從測定位置MA的帶91的移動方向上流端遍及帶91的移動下游端排列設定為較佳。由此,能夠在測定位置MA的整個區域進行帶91的檢查。At this time, the belt inspection device 200 (see FIG. 14) performs the measurement of the floating amount CL of the measurement position MP1, and also performs the floating amount CL on the measurement position MA (refer to FIG. 15) corresponding to the pressure reduction area BA. The measurement is preferably. More specifically, it is preferable to set the measurement line ML extending in the width direction at the measurement position MA set on the surface 91a of the belt 91, and perform the above-described tape inspection process 230 (refer to FIG. 21) for each of the measurement lines ML. It is preferable that the measurement line ML is arranged from the flow end in the moving direction of the belt 91 at the measurement position MA to the moving downstream end of the belt 91. Thereby, the inspection of the belt 91 can be performed over the entire area of the measurement position MA.

測定位置MA設定在支撐於檢查用輥201上之帶91的表面91a上。如圖11及圖22所示,從旋轉中心O131a朝向減壓區BA的帶91的移動方向上游端BAu延伸之面LBAu與面LTP所成角的角度φBAu等於從旋轉中心O201a朝向測定位置MA的帶91的移動方向上游端MAu延伸之面LMAu與面LTP所成角的角度φMAu。並且,從旋轉中心O131a朝向減壓區BA的帶91的移動方向下游端BAd延伸之面LBAd與面LTP所成角的角度φBAd等於從旋轉中心O201a朝向測定位置MA的帶91的移動方向下游端MAd延伸之面MMAd與面MTP所成角的角度φMAdThe measurement position MA is set on the surface 91a of the belt 91 supported on the inspection roller 201. 11 and 22, the angle and the plane surface L BAu L TP are angled to extend toward the area BA reduced pressure from the rotation center O 131a to the upstream end of the moving direction of the belt 91 equal BAu φ BAu from the rotation center O 201a An angle φ MAu at which the surface L MAu extending toward the upstream end MAu of the belt 91 of the measurement position MA is at an angle with the plane L TP . And, φ BAd from the rotation center O 131a BAd orientation angle and the plane surface L L TP extends the downstream end of the moving direction of the belt 91 BAd pressure area BA is equal to the angular position of the belt 91 toward MA measured from the rotation center O 201a The angle φ MAd at which the surface M MAd of the downstream end MAd of the moving direction is at an angle with the plane M TP .

在將測定位置MA上的浮起量CL超過閾值TH1之帶91使用於溶液製膜方法中時,因帶91的移動而產生減壓單元的密封性的偏差。而且,液珠因減壓單元的密封性的偏差而振動之結果,導致產生流延膜的厚度不均。因此,藉由對與減壓區BA對應之測定位置MA(參考圖22)測定浮起量CL,並對測定位置MA的整個區域進行帶91的檢查,不實施溶液製膜方法即可檢測是否為引發流延膜的厚度不均之帶。When the belt 91 in which the floating amount CL at the measurement position MA exceeds the threshold TH1 is used in the solution film forming method, the sealing property of the decompression unit varies depending on the movement of the belt 91. Further, as a result of the vibration of the liquid bead due to the variation in the sealing property of the decompression unit, uneven thickness of the cast film is caused. Therefore, the floating amount CL is measured by the measurement position MA (refer to FIG. 22) corresponding to the pressure reduction zone BA, and the tape 91 is inspected over the entire area of the measurement position MA, and it is possible to detect whether or not the solution film formation method is performed. In order to induce uneven thickness of the cast film.

接著,對厚度測定線SM的設定方法的一例進行說明。圖23中,對未產生翹曲之帶,亦即浮起量CL均為“0”的帶示出距離感測器208x的感測器件所檢測之距離資料,圖24中,對產生翹曲之帶示出距離感測器208x的感測器件所檢測之距離資料。圖23及圖24的橫軸表示帶91的寬度方向的位置,圖23及圖24的縱軸表示感測器件所檢測之距離。Next, an example of a method of setting the thickness measurement line SM will be described. In Fig. 23, the band in which the warpage is not generated, that is, the band in which the floating amount CL is "0" indicates the distance data detected by the sensing device of the distance sensor 208x, and in Fig. 24, the warpage is generated. The strip shows the distance data detected by the sensing device of the sensor 208x. 23 and 24 show the position of the belt 91 in the width direction, and the vertical axes of Figs. 23 and 24 indicate the distance detected by the sensing device.

距離感測器208x的感測器件從寬度方向的一端遍及另一端對帶91測定從測定窗208a至帶91的表面91a或軸向端部208be的距離。距離感測器208x的內置CPU從其中一方的寬度方向外側朝向寬度方向中央側將感測器件測定之距離的資料(以下稱為距離資料)讀取至另一方的寬度方向外側。接著,內置CPU將距離資料中的初始值E1判定為軸向端部201be的端,將峰值E2判定為帶91的端。其中,初始值E1係從其中一方的寬度方向外側讀取至另一方的寬度方向外側之內置CPU最初檢測之初始值部份,峰值E2係表示距離資料中最大值之位置。The sensing device of the distance sensor 208x measures the distance from the measurement window 208a to the surface 91a or the axial end portion 208be of the belt 91 from one end in the width direction to the belt 91 at the other end. The built-in CPU of the distance sensor 208x reads the data (hereinafter referred to as distance data) of the distance measured by the sensing device from the outer side in the width direction of the one side toward the center side in the width direction to the outer side in the width direction. Next, the built-in CPU determines the initial value E1 in the distance data as the end of the axial end portion 201be, and determines the peak value E2 as the end of the belt 91. The initial value E1 is an initial value portion that is initially detected by the built-in CPU that is read from the outer side in the width direction of one of the width directions to the outer side in the width direction, and the peak value E2 indicates the position of the maximum value in the distance data.

接著,內置CPU在初始值E1的位置與從初始值E1向寬度方向中央側僅遠離預定量之位置之間選擇任意的距離資料。而且,根據該選出之距離資料計算距離B。Next, the built-in CPU selects an arbitrary distance data between the position of the initial value E1 and the position which is only a predetermined amount away from the initial value E1 toward the center in the width direction. Moreover, the distance B is calculated based on the selected distance data.

另外,內置CPU在峰值E2的位置與從峰值E2向寬度方向中央側僅遠離預定量ε之位置之間選擇任意的距離資料。如此,內置CPU根據該選出之距離資料計算距離A。Further, the built-in CPU selects an arbitrary distance data between the position of the peak E2 and the position from the peak E2 to the center side in the width direction by only a predetermined amount ε. Thus, the built-in CPU calculates the distance A based on the selected distance data.

厚度測定線SM中在帶91的寬度方向上位於最端側者,亦即厚度測定線SM(1)或厚度測定線SM(m)設定在相當於圖23或圖24中的峰值E2之位置,亦即帶91的其中一方的端或另一方的端為較佳。由此,內置CPU能夠將峰值E2的位置認定為厚度測定線SM(1)或厚度測定線SM(m)。並且,由於能夠預先設定相鄰之厚度測定線SM的間隔ε,因此能夠將從峰值E2向寬度方向中央側僅遠離預定距離之位置認定為厚度測定線SM(2)或厚度測定線SM(m-1)。The thickness measurement line SM is located at the extreme end in the width direction of the belt 91, that is, the thickness measurement line SM (1) or the thickness measurement line SM (m) is set at a position corresponding to the peak E2 in FIG. 23 or FIG. That is, the end of one of the belts 91 or the other end is preferred. Thereby, the built-in CPU can recognize the position of the peak E2 as the thickness measurement line SM(1) or the thickness measurement line SM(m). In addition, since the interval ε of the adjacent thickness measurement lines SM can be set in advance, the position from the peak E2 to the center in the width direction only a predetermined distance can be regarded as the thickness measurement line SM (2) or the thickness measurement line SM (m). -1).

如此,即使帶91的寬度方向端部翹曲,也能夠將厚度測定線SM在寬度方向上的位置的誤差限制在最小限度內。In this manner, even if the end portion of the belt 91 in the width direction is warped, the error in the position of the thickness measurement line SM in the width direction can be minimized.

上述實施方式中,以帶91的其中一方的端或另一方的端為基準設定厚度測定線SM,但本發明不限於此,可以以未產生翹曲之部份(例如,帶91的寬度方向中央部)為基準,在從該部份僅遠離預定距離之位置設定厚度測定線SM。並且,當為具有焊接部91w之帶91時,亦可以以焊接部91w的位置為基準,在從該部份僅遠離預定距離之位置設定厚度測定線SM。另外,亦可以設定於帶91的表面91a之另外的記號為基準,在從該部份僅遠離預定距離之位置設定厚度測定線SM。In the above embodiment, the thickness measurement line SM is set based on one end or the other end of the belt 91. However, the present invention is not limited thereto, and a portion where warpage does not occur (for example, the width direction of the belt 91) may be employed. Based on the center portion, the thickness measurement line SM is set at a position away from the portion only by a predetermined distance. Further, in the case of the belt 91 having the welded portion 91w, the thickness measurement line SM may be set at a position away from the portion by a predetermined distance from the position of the welded portion 91w. Further, the thickness measurement line SM may be set at a position away from the predetermined distance by the other mark set on the surface 91a of the belt 91 as a reference.

上述帶檢查製程230均可應用於僅具有焊接部91v之帶91和具有焊接部91v及焊接部91w之帶91。The tape inspection process 230 can be applied to the tape 91 having only the welded portion 91v and the tape 91 having the welded portion 91v and the welded portion 91w.

在上述的薄膜形成裝置117(參考圖10)中,在藉由製膜用輥131支撐之帶91的表面91a上設定到達位置DP和剝取位置PP,但本發明不限於此。例如,有時利用到達用支撐輥和剝離用支撐輥來代替製膜用輥131。此時,在掛繞於到達用支撐輥和剝離用支撐輥上之帶91的表面91a上,在到達用支撐輥所支撐之部份設定到達位置DP,在剝離用支撐輥所支撐之部份設定剝離位置PP。另外,當設置減壓室237時,在到達用支撐輥所支撐之部份設定減壓區BA。可以對與這種到達位置DP或減壓區BA對應之位置進行本發明的帶檢查製程230。In the above-described film forming apparatus 117 (refer to FIG. 10), the arrival position DP and the peeling position PP are set on the surface 91a of the belt 91 supported by the film forming roller 131, but the present invention is not limited thereto. For example, the film forming roller 131 may be replaced by the reaching support roller and the peeling support roller. At this time, on the surface 91a of the belt 91 which is hung on the support roller and the peeling support roller, the reaching position DP is set at the portion supported by the supporting roller, and the portion supported by the peeling supporting roller is supported. Set the peeling position PP. Further, when the decompression chamber 237 is provided, the decompression zone BA is set to reach the portion supported by the support roller. The inspection process 230 of the present invention can be performed at a position corresponding to such an arrival position DP or a pressure reduction zone BA.

基準位置B1可以不是焊接部91v。例如可以將設定在帶91的表面91a上之另外的記號設為基準位置B1。The reference position B1 may not be the welded portion 91v. For example, another symbol set on the surface 91a of the belt 91 can be set as the reference position B1.

製膜用輥131、132和評價用輥201、202為同一輥為較佳。並且,可以在溶液製膜設備110上進行帶檢查製程230。It is preferable that the film forming rolls 131 and 132 and the evaluation rolls 201 and 202 are the same roll. Also, the tape inspection process 230 can be performed on the solution film forming apparatus 110.

藉由如圖10所示之溶液製膜設備110得到之薄膜116能夠使用於相位差薄膜或偏光板保護薄膜。The film 116 obtained by the solution film forming apparatus 110 shown in Fig. 10 can be used for a retardation film or a polarizing plate protective film.

薄膜116的寬度為600mm以上3000mm以下為較佳,2000mm以上3000mm以下更為佳。並且,即使薄膜116的寬度超過3000mm時,也能夠應用本發明。薄膜116的膜厚為30μm以上120μm以下為較佳。The width of the film 116 is preferably 600 mm or more and 3000 mm or less, more preferably 2,000 mm or more and 3,000 mm or less. Further, the present invention can be applied even when the width of the film 116 exceeds 3,000 mm. The film thickness of the film 116 is preferably 30 μm or more and 120 μm or less.

(聚合物)(polymer)

能夠使用於本發明之聚合物只要是熱塑性樹脂就不特別限定,例如可以舉出纖維素醯化物、含內酯環聚合體、環狀烯烴、聚碳酸酯等。其中,纖維素醯化物、環狀烯烴為較佳,其中,包含醋酸基、丙酸酯基之纖維素醯化物以及藉由加成聚合得到之環狀烯烴為較佳。The polymer which can be used in the present invention is not particularly limited as long as it is a thermoplastic resin, and examples thereof include a cellulose halide, a lactone-containing cyclic polymer, a cyclic olefin, and a polycarbonate. Among them, a cellulose halide and a cyclic olefin are preferable, and among them, a cellulose halide containing an acetate group or a propionate group and a cyclic olefin obtained by addition polymerization are preferred.

(纖維素醯化物)(cellulose cellulose)

作為纖維素醯化物,係醯基向纖維素的羥基的取代度滿足下述式(I)~(III)者為較佳。在下述式(I)~(III)中,A及B表示醯基對纖維素的羥基中的氫原子之取代度,A為乙醯基的取代度,B為碳原子數3~22的醯基的取代度。纖維素醯化物的90質量%以上為0.1~4mm的顆粒為較佳。其中,本發明在使用二醋酸纖維素(DAC)作為纖維素醯化物時,具有特別大的效果。As the cellulose halide, it is preferred that the degree of substitution of the thiol group to the hydroxyl group of the cellulose satisfies the following formulas (I) to (III). In the following formulae (I) to (III), A and B represent the degree of substitution of a sulfhydryl group with a hydrogen atom in a hydroxyl group of cellulose, A is a degree of substitution of an acetyl group, and B is a ruthenium having a carbon number of 3 to 22. The degree of substitution of the base. It is preferred that 90% by mass or more of the cellulose halide is 0.1 to 4 mm. Among them, the present invention has a particularly large effect when cellulose diacetate (DAC) is used as the cellulose oxime.

(I)2.0A+B3.0(I) 2.0 A+B 3.0

(II)0A3.0(II)0 A 3.0

(III)0B2.9(III)0 B 2.9

構成纖維素的進行β-1,4鍵合的葡萄糖單位在2位、3位及6位具有游離之羥基。纖維素醯化物為藉由碳數2以上的醯基對這些羥基的一部份或整體進行酯化的聚合體(聚合物)。醯基取代度是指纖維素的羥基分別在2位、3位及6位被酯化之比例(將100%酯化時設為取代度1)。The glucose unit which constitutes β-1,4 linkage of cellulose has free hydroxyl groups at the 2, 3 and 6 positions. The cellulose oxime is a polymer (polymer) which esterifies a part or the whole of these hydroxyl groups by a fluorenyl group having 2 or more carbon atoms. The thiol substitution degree refers to a ratio at which the hydroxyl groups of cellulose are esterified at the 2, 3, and 6 positions, respectively (when 100% is esterified, the degree of substitution is 1).

總醯化取代度,亦即DS2+DS3+DS6的值為2.00~3.00為較佳,2.22~2.90更為佳,2.40~2.88尤為佳。並且,DS6/(DS2+DS3+DS6)的值為0.28為較佳,0.30以上更為佳,0.31~0.34尤為佳。其中,DS2為葡萄糖單位中的2位羥基的氫被醯基取代之比例(以下稱為“2位醯基取代度”),DS3為葡萄糖單位中的3位羥基的氫被醯基取代之比例(以下稱為“3位醯基取代度”),DS6為在葡萄糖單位中6位羥基的氫被醯基取代之比例(以下稱為“6位醯基取代度”)。The total degree of substitution is, that is, the value of DS2+DS3+DS6 is preferably 2.00 to 3.00, more preferably 2.22 to 2.90, and particularly preferably 2.40 to 2.88. Further, the value of DS6/(DS2+DS3+DS6) is preferably 0.28, more preferably 0.30 or more, and particularly preferably 0.31 to 0.34. Wherein DS2 is a ratio in which a hydrogen of a 2-hydroxyl group in a glucose unit is substituted by a mercapto group (hereinafter referred to as a "2-position thiol substitution degree"), and DS3 is a ratio in which a hydrogen of a 3-hydroxy group in a glucose unit is substituted by a mercapto group. (hereinafter referred to as "3-position thiol substitution degree"), and DS6 is a ratio in which hydrogen of the 6-position hydroxyl group in the glucose unit is substituted by a mercapto group (hereinafter referred to as "6-position thiol substitution degree").

在本發明的纖維素醯化物中使用之醯基可以僅為1種,或者亦可使用2種以上醯基。在使用2種以上醯基時,其中1個為乙醯基為較佳。若將2位、3位及6位羥基被乙醯基取代之程度的總和設為DSA,並將2位、3位及6位羥基被除乙醯基以外的醯基取代之程度的總和設為DSB,則DSA+DSB的值為2.22~2.90為較佳,2.40~2.88尤為佳。The mercapto group used in the cellulose halide of the present invention may be used alone or in combination of two or more kinds. When two or more kinds of sulfhydryl groups are used, one of them is preferably an ethylidene group. When the sum of the degree of substitution of the 2, 3, and 6 hydroxyl groups by the ethyl fluorenyl group is set to DSA, and the sum of the 2, 3, and 6 hydroxyl groups is replaced by a thiol group other than the ethyl fluorenyl group, For DSB, the value of DSA+DSB is preferably 2.22 to 2.90, and particularly preferably 2.40 to 2.88.

並且,DSB為0.30以上為較佳,0.7以上尤為佳。另外,DSB其20%以上為6位羥基的取代基為較佳,25%以上更為佳,30%以上為進一步較佳,33%以上尤為佳。另外,纖維素醯化物的6位上的DSA+DSB的值為0.75以上、進一步較佳為0.80以上、尤其較佳為0.85以上的纖維素醯化物亦較佳,藉由使用這些纖維素醯化物,能夠製作溶解性更加優異之濃液。尤其是,若使用非氯系有機溶劑,則能夠製作顯示優異之溶解性且低黏度、過濾性優異之濃液。Further, DSB is preferably 0.30 or more, and more preferably 0.7 or more. Further, a substituent of 20% or more of the DSB having a hydroxyl group of 6 is preferably 25% or more, more preferably 30% or more, and particularly preferably 33% or more. Further, a cellulose halide having a value of DSA + DSB at the 6-position of the cellulose halide of 0.75 or more, more preferably 0.80 or more, particularly preferably 0.85 or more is also preferable by using these cellulose halides. It is possible to produce a concentrated liquid which is more excellent in solubility. In particular, when a non-chlorine-based organic solvent is used, a concentrated liquid exhibiting excellent solubility and having low viscosity and excellent filterability can be produced.

作為纖維素醯化物的原料之纖維素可以係從棉絨纖維、漿料中的任一種獲得者。The cellulose which is a raw material of the cellulose halide may be obtained from any one of cotton wool fibers and a slurry.

作為本發明中的纖維素醯化物的碳數2以上的醯基,可以是脂肪族基亦可為芳基,並不特別限定。例如可以舉出纖維素的烷羰基酯、烯羰基酯、芳香族羰基酯、芳香族烷羰基酯等,亦可分別具有進一步被取代的基團。作為它們的較佳例子,可以舉出丙醯基、丁醯基、戊醯基、己醯基、辛醯基、癸醯基、十二烷醯基、十三烷醯基、十四烷醯基、十六烷醯基、十八烷醯基、異丁醯基、三級丁醯基、環己烷羰基、油醯基、苯甲醯基、萘羰基、肉桂醯基等。其中,丙醯基、丁醯基、十二烷醯基、十八烷醯基、三級丁醯基、油醯基、苯甲醯基、萘羰基、肉桂醯基等更為佳,丙醯基、丁醯基尤為佳。The fluorenyl group having 2 or more carbon atoms of the cellulose halide in the present invention may be an aliphatic group or an aryl group, and is not particularly limited. For example, an alkylcarbonyl ester, an olefinic carbonyl ester, an aromatic carbonyl ester, an aromatic alkylcarbonyl ester, or the like of cellulose may be mentioned, and each may have a further substituted group. As preferred examples thereof, a propyl group, a butyl group, a pentyl group, a hexyl group, a octyl group, a decyl group, a dodecyl group, a tridecyl fluorenyl group, a tetradecyl fluorenyl group, and a hexadecane group may be mentioned. An alkanoyl group, an octadecyl fluorenyl group, an isobutyl fluorenyl group, a tertiary butyl fluorenyl group, a cyclohexanecarbonyl group, an oil fluorenyl group, a benzamyl group, a naphthylcarbonyl group, a cinnamyl group, and the like. Among them, a propyl fluorenyl group, a butyl decyl group, a dodecyl fluorenyl group, an octadecyl fluorenyl group, a tertiary butyl fluorenyl group, an oil fluorenyl group, a benzamidine group, a naphthylcarbonyl group, a cinnamyl group, etc. are more preferable, and a propyl sulfonyl group and a butyl fluorenyl group are particularly good.

(溶劑)(solvent)

作為製備濃液的溶劑,可以舉出芳香族烴(例如苯、甲苯等)、鹵代烴(例如二氯甲烷、氯苯等)、醇(例如甲醇、乙醇、正丙醇、正丁醇、二甘醇等)、酮(例如丙酮、甲乙酮等)、酯(例如乙酸甲酯、乙酸乙酯、乙酸丙酯等)及醚(例如四氫呋喃、甲基溶纖劑等)等。Examples of the solvent for preparing the dope include aromatic hydrocarbons (for example, benzene, toluene, etc.), halogenated hydrocarbons (for example, dichloromethane, chlorobenzene, etc.), and alcohols (for example, methanol, ethanol, n-propanol, n-butanol, Diethylene glycol or the like), a ketone (e.g., acetone, methyl ethyl ketone, etc.), an ester (e.g., methyl acetate, ethyl acetate, propyl acetate, etc.) and an ether (e.g., tetrahydrofuran, methyl cellosolve, etc.).

上述鹵代烴中,使用碳原子數1~7的鹵代烴為較佳,使用二氯甲烷最為佳。從纖維素醯化物的溶解性、流延膜從支撐體上的剝離性、薄膜的機械強度及光學特性等物性觀點考慮,除了二氯甲烷之外,混合一種乃至數種碳原子數1~5的醇為較佳。醇的含量相對於整個溶劑為2~25質量%為較佳,5~20質量%更為佳。作為醇,可以舉出甲醇、乙醇、正丙醇、異丙醇、正丁醇等,但使用甲醇、乙醇、正丁醇或它們的混合物為較佳。Among the above halogenated hydrocarbons, a halogenated hydrocarbon having 1 to 7 carbon atoms is preferably used, and dichloromethane is most preferred. From the viewpoint of the solubility of the cellulose halide, the peelability of the cast film from the support, the mechanical strength of the film, and the optical properties, one or several kinds of carbon atoms of 1 to 5 are mixed in addition to dichloromethane. The alcohol is preferred. The content of the alcohol is preferably 2 to 25% by mass based on the entire solvent, more preferably 5 to 20% by mass. The alcohol may, for example, be methanol, ethanol, n-propanol, isopropanol or n-butanol, but methanol, ethanol, n-butanol or a mixture thereof is preferred.

最近以對環境的影響抑制到最小限度為目的,對不使用二氯甲烷的溶劑組成也進行研究。在這種情況下,碳原子數為4~12的醚、碳原子數為3~12的酮、碳原子數為3~12的酯及碳原子數為1~12的醇為較佳,有時還適當地混合這些來使用。例如,可以舉出乙酸甲酯、丙酮、乙醇、正丁醇的混合溶劑。這些醚、酮、酯及醇係可以具有環狀結構者。而且,具有2個以上醚、酮、酯及醇的官能團(亦即,-O-、-CO-、-COO-及-OH)中的任意一種之化合物亦能夠用作溶劑。Recently, the solvent composition without using methylene chloride has also been studied for the purpose of minimizing the influence on the environment. In this case, an ether having 4 to 12 carbon atoms, a ketone having 3 to 12 carbon atoms, an ester having 3 to 12 carbon atoms, and an alcohol having 1 to 12 carbon atoms are preferred. These are also mixed as appropriate for use. For example, a mixed solvent of methyl acetate, acetone, ethanol, and n-butanol can be mentioned. These ethers, ketones, esters, and alcohols may have a cyclic structure. Further, a compound having any one of two or more ether, ketone, ester, and alcohol functional groups (that is, -O-, -CO-, -COO-, and -OH) can also be used as a solvent.

[實施例][Examples]

以下,為了確認本發明的效果,進行了實驗1~6。各實驗的詳細內容用實驗1進行說明,關於實驗2~6僅表示與實驗1不同之條件。Hereinafter, in order to confirm the effect of the present invention, Experiments 1 to 6 were carried out. The details of each experiment are explained by Experiment 1, and the experiments 2 to 6 only show conditions different from Experiment 1.

(實驗1)(Experiment 1)

在圖1所示之帶製造設備10中,根據SUS316製的側構件11(寬度150mm)和SUS316製的中央構件12(寬度2000mm)製造出了帶(A-1)。In the belt manufacturing apparatus 10 shown in Fig. 1, a belt (A-1) was produced from a side member 11 (width: 150 mm) made of SUS316 and a center member 12 (width: 2000 mm) made of SUS316.

利用圖14所示之帶檢查裝置200對帶(A-1)進行圖21所示之帶檢查製程230。帶檢查製程230中對測定位置MP1上的浮起量CL及測定位置MA上的浮起量CL。測定位置MP1上的浮起量CL的最大值CLMP及測定位置MA上的浮起量CL的最大值CLMA如表1所示。進行帶檢查製程230時,外加於成為被檢查對象之帶之移動張力T2為60N/mm2The tape inspection process 230 shown in Fig. 21 is performed on the tape (A-1) by the tape inspection device 200 shown in Fig. 14. The floating amount CL at the measurement position MP1 and the floating amount CL at the measurement position MA in the inspection process 230. The maximum value of the floating quantity measurement positions MP1 CL CL of MP and floating quantity measurement position of maximum CL MA MA CL as shown in Table 1. When the inspection process 230 is performed, the movement tension T2 applied to the belt to be inspected is 60 N/mm 2 .

在溶液製膜設備110(參考圖10)中,由包含二醋酸纖維素(DAC)及溶劑之濃液113製造出了薄膜116。使用帶(A-1)作為帶91。帶91的移動速度為40m/分鐘。流延模133向移動狀態的帶91連續流出濃液113。在帶91的表面91a上形成了由濃液113組成之流延膜136。In the solution film forming apparatus 110 (refer to FIG. 10), the film 116 is produced from a dope 113 containing cellulose diacetate (DAC) and a solvent. The belt (A-1) is used as the belt 91. The belt 91 has a moving speed of 40 m/min. The casting die 133 continuously flows out of the dope 113 to the belt 91 in the moving state. A casting film 136 composed of a dope 113 is formed on the surface 91a of the belt 91.

利用來自各導管141~143的乾燥風,使溶劑從帶91上的流延膜136中蒸發。剝離輥135從帶91剝離流延膜136並作為薄膜116。薄膜116依次被送至第1拉幅機120、輥乾燥裝置124、第2拉幅機125及分切機126。The solvent is evaporated from the casting film 136 on the belt 91 by the dry air from the respective conduits 141 to 143. The peeling roller 135 peels the casting film 136 from the belt 91 and serves as the film 116. The film 116 is sequentially sent to the first tenter 120, the roll drying device 124, the second tenter 125, and the slitter 126.

(實驗2~6)(Experiment 2 to 6)

代替帶(A-1)使用藉由帶製造設備10得到之帶(A-2)~(A-6)作為帶91,除此以外,與實驗1相同地製造出了薄膜116。其中,浮起量CL的最大值CLMP及浮起量CL的最大值CLMA如表1所示。A film 116 was produced in the same manner as in Experiment 1 except that the belts (A-2) to (A-6) obtained by the belt manufacturing equipment 10 were used as the belt 91 instead of the belt (A-1). The maximum value CL MP of the floating amount CL and the maximum value CL MA of the floating amount CL are as shown in Table 1.

對在實驗1~實驗6中得到之薄膜進行了如下評價。The films obtained in Experiments 1 to 6 were evaluated as follows.

1.剝離殘留評價1. Peel residue evaluation

對帶中有無剝離殘留流延膜進行了調查。The presence or absence of peeling residual cast film in the belt was investigated.

A:未在帶中產生流延膜的剝離殘留。A: No peeling of the cast film was caused in the belt.

B:在帶中產生了流延膜的剝離殘留。B: Peeling residue of the cast film was generated in the belt.

2.有無厚度不均的評價2. Evaluation of thickness unevenness

按以下順序評價有無流延膜的厚度不均。從利用捲取裝置127捲取在卷芯之前的薄膜切出樣品薄膜。向樣品薄膜透射光時,目視觀察樣品薄膜的表面出現之陰影。當在樣品薄膜中觀察到之陰影的強弱大於通過作為相位差薄膜或偏光板保護薄膜的厚度不均評價試驗之產品薄膜者時,判定為無法容許該厚度不均(B)。並且,當在樣品薄膜中觀察到之陰影的規模與通過作為相位差薄膜或偏光板保護薄膜的性能試驗之產品薄膜者相同程度,或者小於其時,判定為能夠容許該厚度不均(A)。The thickness unevenness of the cast film was evaluated in the following order. The sample film is cut out from the film before the core is taken up by the take-up device 127. When light is transmitted to the sample film, the shadow appearing on the surface of the sample film is visually observed. When the intensity of the shadow observed in the sample film is larger than that of the product film which is the thickness unevenness evaluation test as the retardation film or the polarizing plate protective film, it is judged that the thickness unevenness (B) cannot be tolerated. Further, when the scale of the shadow observed in the sample film is the same as or smaller than that of the product film as the performance test of the retardation film or the polarizing plate protective film, it is determined that the thickness unevenness can be tolerated (A) .

表1示出實驗1~6的評價結果。另外,表1中附加於評價結果之序號表示附加於上述評價項目之序號。Table 1 shows the evaluation results of Experiments 1 to 6. In addition, the serial number attached to the evaluation result in Table 1 indicates the serial number attached to the above evaluation item.

10...帶製造設備10. . . Belt manufacturing equipment

11...側構件11. . . Side member

11e、12e...側緣11e, 12e. . . Side edge

12...中央構件12. . . Central component

13...帶構件13. . . Belt member

13c、91c...中央部13c, 91c. . . Central department

13s、91s...側部13s, 91s. . . Side

13w、91v、91w...焊接部13w, 91v, 91w. . . Welding department

16...送出部16. . . Delivery department

17...對接部17. . . Docking

18、61...焊接單元18, 61. . . Welding unit

19...加熱部19. . . Heating department

20、127...捲取裝置20, 127. . . Winding device

23...第1送出裝置twenty three. . . First delivery device

24...第2送出裝置twenty four. . . Second delivery device

26...第1輥26. . . First roller

27...第2輥27. . . Second roller

28...第3輥28. . . Third roller

29...第4輥29. . . 4th roller

34、47...位置檢測手段34, 47. . . Position detection

32、37、50...位移機構32, 37, 50. . . Displacement mechanism

33、38、51...控制器33, 38, 51. . . Controller

41...焊接支撐輥41. . . Welding support roller

42...焊接裝置42. . . Welding device

43...雷射振盪器43. . . Laser oscillator

46...焊接裝置主體46. . . Welding device body

52...室52. . . room

55...清潔裝置55. . . Cleaning device

56、141、142、143...導管56, 141, 142, 143. . . catheter

57...送風機57. . . Blower

62...按壓構件62. . . Pressing member

63...第1傳送帶63. . . 1st conveyor belt

64...第2傳送帶64. . . 2nd conveyor belt

67...第5輥67. . . Fifth roller

68...第6輥68. . . 6th roller

69...第7輥69. . . 7th roller

71...高熱傳導部71. . . High heat conduction section

72...焊接液珠72. . . Welding bead

73...熱影響區域73. . . Heat affected zone

76...槽76. . . groove

81...錐狀輥81. . . Cone roller

82...驅動手段82. . . Driving means

85...夾子85. . . Clip

86...夾子主體86. . . Clip body

87...挾持針87. . . Holding needle

88...移動機構88. . . Mobile agency

91...帶91. . . band

91a...帶的表面91a. . . Belt surface

91b...帶的裏面91b. . . Inside the belt

110...溶液製膜設備110. . . Solution film making equipment

111...纖維素醯化物111. . . Cellulose telluride

112...溶劑112. . . Solvent

113...濃液113. . . Concentrate

116...薄膜116. . . film

117...薄膜形成裝置117. . . Film forming device

120...第1拉幅機120. . . 1st tenter

120a、125a...保持構件120a, 125a. . . Holding member

122...輥122. . . Roll

124...輥乾燥裝置124. . . Roll drying device

125...第2拉幅機125. . . 2nd tenter

126...分切機126. . . Slitting machine

131、132...製膜用輥131, 132. . . Film roll

131a...旋轉軸131a. . . Rotary axis

131b...輥主體131b. . . Roller body

133、136...流延模133, 136. . . Casting die

133a...流出口133a. . . Outflow

134...膜乾燥裝置134. . . Membrane drying device

135...剝離輥135. . . Stripping roller

171、205...馬達171, 205. . . motor

172、206...驅動部172, 206. . . Drive department

173、207...力量感測器173, 207. . . Power sensor

200...帶檢查裝置200. . . With inspection device

201、202...檢查用輥201, 202. . . Inspection roller

201a、202a...旋轉軸201a, 202a. . . Rotary axis

201b、202b...輥主體201b, 202b. . . Roller body

201be...軸向端部201be. . . Axial end

201bx...輥主體的周面201bx. . . The circumference of the roller body

203...位移部203. . . Displacement section

208...感測器單元208. . . Sensor unit

208a...測定窗208a. . . Measurement window

208x...距離感測器208x. . . Distance sensor

208y...基準位置檢測感測器208y. . . Reference position detection sensor

210...控制部210. . . Control department

211...CPU211. . . CPU

212...存儲部212. . . Storage department

216...距離計算部216. . . Distance calculation department

217...浮起量計算部217. . . Floating amount calculation unit

218...判定部218. . . Judgment department

222...總線222. . . bus

225...厚度情報225. . . Thickness information

230...帶檢查製程230. . . With inspection process

237...減壓室237. . . Decompression chamber

237a...上游側遮風板237a. . . Upstream side windshield

237b...側方遮風板237b. . . Side shelter

237c...頂板237c. . . roof

A...箭頭A. . . arrow

A(i,j)...厚度測定線ST(j)上的交點P(i,j)上的距離A(i,j). . . Distance on the intersection P(i,j) on the thickness measurement line ST(j)

B(j)...從軸向端部201be至測定窗208a的距離B(j). . . Distance from axial end 201be to measurement window 208a

B1...基準位置B1. . . Reference position

BA...減壓區BA. . . Decompression zone

BAd...下游端BAd. . . Downstream end

BAu...上游端BAu. . . Upstream

CA...流延區CA. . . Casting zone

CL(i,j)...浮起量CL(i,j). . . Floating amount

CW...流延寬度CW. . . Cast width

d...直徑d. . . diameter

D(i,j)...交點P(i,j)上的帶91的厚度測定值D(i,j). . . Thickness measurement of strip 91 at intersection P(i,j)

D1...第1傳送帶63與第2傳送帶64的間隔D1. . . The interval between the first conveyor belt 63 and the second conveyor belt 64

D2...接觸位置Ps與第1傳送帶63的距離D2. . . The distance between the contact position Ps and the first conveyor belt 63

D3...接觸位置Ps與第2傳送帶64的距離D3. . . The distance between the contact position Ps and the second conveyor belt 64

D4...通過區域的寬度D4. . . Through the width of the area

D5...槽76的寬度D5. . . Width of slot 76

D6...槽76的深度D6. . . Depth of slot 76

DB...厚度分佈情報DB. . . Thickness distribution information

DP...到達位置DP. . . Arrival location

E1...初始值E1. . . Initial value

E2...峰值E2. . . Peak

H(i,j)...從軸向端部201be至帶91的表面91a的距離H(i,j). . . Distance from the axial end 201be to the surface 91a of the belt 91

L(j)...從基準位置B1至任意的厚度測定線ST(j)的距離L(j). . . Distance from the reference position B1 to an arbitrary thickness measurement line ST(j)

LBAd...從旋轉中心O131a朝向減壓區BA的帶91的移動方向下游端BAd延伸之面L BAd . . . The surface extending from the rotation center O 131a toward the downstream end BAd of the moving direction of the belt 91 of the decompression zone BA

LBAu...從旋轉中心O131a朝向減壓區BA的帶91的移動方向上游端BAu延伸之面L BAu . . . The surface extending from the rotation center O 131a toward the upstream end BAu of the movement direction of the belt 91 of the decompression zone BA

LDP...從旋轉軸131a的旋轉中心O131a朝向到達位置DP延伸之面L DP . . . The surface extending from the rotation center O 131a of the rotation shaft 131a toward the arrival position DP

LTP...從旋轉軸131a的旋轉中心O131a朝向頂部TP延伸之面L TP . . . a surface extending from the rotation center O 131a of the rotating shaft 131a toward the top TP

MA...測定位置MA. . . Measuring position

MAd...測定位置MA的帶91的移動方向下游端MAd. . . Measuring the downstream end of the belt 91 in the moving direction of the position MA

MAu...測定位置MA的帶91的移動方向上游端MAu. . . Measuring the upstream end of the moving direction of the belt 91 of the position MA

MD...位置情報MD. . . Location information

ML...測定線ML. . . Measuring line

MMAd...從旋轉中心O201a朝向測定位置MA的帶91的移動方向下游端MAd延伸之面M MAd . . . The surface extending from the rotation center O 201a toward the downstream end MAd of the moving direction of the belt 91 of the measurement position MA

MMAu...從旋轉中心O201a朝向測定位置MA的帶91的移動方向下游端MAu延伸之面M MAu . . . The surface extending from the rotation center O 201a toward the downstream end MAu of the movement direction of the belt 91 at the measurement position MA

MMP1...從旋轉軸201a的旋轉中心O201a朝向測定位置MP1延伸之面M MP1 . . . The surface extending from the rotation center O 201a of the rotating shaft 201a toward the measurement position MP1

MP1...向帶的寬度方向延伸之測定位置MP1. . . Measuring position extending in the width direction of the belt

MP2...面MMP1與軸向端部201be的交線MP2. . . The intersection of the surface M MP1 and the axial end 201be

MTP...從旋轉軸201a的旋轉中心O201a朝向檢查用輥201的頂部TP延伸之面M TP . . . The surface extending from the rotation center O 201a of the rotating shaft 201a toward the top TP of the inspection roller 201

O131a...旋轉軸131a的旋轉中心O 131a . . . The center of rotation of the rotating shaft 131a

O201a...旋轉軸201a的旋轉中心O 201a . . . The center of rotation of the rotating shaft 201a

P(i,j)...厚度測定線ST(j)與厚度測定線SM(i)的交點P(i,j). . . The intersection of the thickness measurement line ST(j) and the thickness measurement line SM(i)

Ph...對接位置Ph. . . Docking position

PP...剝離位置PP. . . Peeling position

Pr...鬆弛位置Pr. . . Relaxed position

Ps...接觸位置Ps. . . Contact position

Pt...張力外加位置Pt. . . Tension plus position

Pw...焊接位置Pw. . . Position of welding

SM(i-1)、SM(i)、SM(i+1)、ST(j-1)、ST(j)、ST(j+1)...厚度測定線SM(i-1), SM(i), SM(i+1), ST(j-1), ST(j), ST(j+1). . . Thickness measurement line

S10、S11、S12、S13、S14、S15、S16、S17、S18、S20、S21、S22、S23...步驟S10, S11, S12, S13, S14, S15, S16, S17, S18, S20, S21, S22, S23. . . step

TP...頂部TP. . . top

X...傳送方向X. . . Transfer direction

Y...寬度方向Y. . . Width direction

θ1...接觸區域中的周向和中央構件12的傳送方向X所成之角Θ1. . . The angle between the circumferential direction in the contact area and the conveying direction X of the central member 12

θ2...焊接部91v和寬度方向Y所成之角Θ2. . . The angle formed by the welded portion 91v and the width direction Y

φ1...面LTP與面LDP所成角之角度Φ1. . . The angle between the surface L TP and the surface L DP

φ2...面MTP與面MMP1所成角的角度Φ2. . . Angle at which the face M TP is at an angle to the face M MP1

φBAd...面LBAd與面LTP所成角的角度φ BAd . . . L BAd angle and the plane surface of the angled L TP

φBAu...面LBAu與面LTP所成角的角度φ BAu . . . The angle between the surface L BAu and the surface L TP

φMAd...面MMAd與面MTP所成角的角度Φ MAd . . . Angle of the angle between the surface M MAd and the surface M TP

φMAu...面MMAu與面MTP所成角的角度Φ MAu . . . The angle between the surface M MAu and the surface M TP

圖1係表示帶的製造設備的概要之側視圖。Fig. 1 is a side view showing an outline of a manufacturing apparatus of a belt.

圖2係表示帶製造設備的概要之俯視圖。Fig. 2 is a plan view showing an outline of a belt manufacturing apparatus.

圖3係表示焊接單元的概要之側視圖。Fig. 3 is a side view showing an outline of a welding unit.

圖4係表示焊接單元的概要之俯視圖。Fig. 4 is a plan view showing an outline of a welding unit.

圖5係表示焊接支撐輥的概要之V-V線截面圖。Fig. 5 is a cross-sectional view taken along the line V-V of the outline of the welding support roller.

圖6係焊接液珠及其周邊的說明圖。Fig. 6 is an explanatory view of the welding bead and its periphery.

圖7係錐狀輥的概要圖。Fig. 7 is a schematic view of a tapered roller.

圖8係夾子的概要圖。Figure 8 is a schematic view of a clip.

圖9係帶的概要圖。Figure 9 is a schematic view of the strap.

圖10係表示溶液製膜設備的概要之側視圖。Fig. 10 is a side view showing an outline of a solution film forming apparatus.

圖11係表示到達位置DP、減壓區BA的概要之側視圖。Fig. 11 is a side view showing an outline of the arrival position DP and the pressure reduction area BA.

圖12係表示流延模、減壓室、及製膜用輥的概要之立體圖。Fig. 12 is a perspective view showing an outline of a casting die, a decompression chamber, and a film forming roller.

圖13係表示到達位置DP及減壓區BA的概要之立體圖。Fig. 13 is a perspective view showing an outline of the arrival position DP and the decompression zone BA.

圖14係表示在張力外加位置設置旋轉軸時的帶檢查裝置的概要之側視圖。Fig. 14 is a side view showing an outline of a tape inspection device when a rotary shaft is provided at a tension application position.

圖15係表示捲繞在檢查用輥上之帶的概要之立體圖。Fig. 15 is a perspective view showing an outline of a belt wound around an inspection roller.

圖16係表示帶檢查裝置的概要之塊圖。Fig. 16 is a block diagram showing an outline of a tape inspection device.

圖17係表示在鬆弛位置設置旋轉軸時的帶檢查裝置的概要之側視圖。Fig. 17 is a side view showing an outline of a tape inspection device when a rotary shaft is provided at a slack position.

圖18係表示厚度情報的概要之說明圖。Fig. 18 is an explanatory diagram showing an outline of thickness information.

圖19係設置在測定位置MP1上之厚度測定線ST(j)上的帶的截面圖,係表示距離A、B及H的概要者。Fig. 19 is a cross-sectional view of the belt on the thickness measurement line ST(j) provided at the measurement position MP1, showing the outlines of the distances A, B, and H.

圖20係設置在測定位置MP1上之厚度測定線ST(j)上的帶的截面圖,係表示距離A、H、帶的厚度D及浮起量CL的概要者。Fig. 20 is a cross-sectional view of the belt on the thickness measurement line ST(j) provided at the measurement position MP1, and shows an outline of the distances A, H, the thickness D of the belt, and the floating amount CL.

圖21係表示帶檢查製程的概要之流程圖。Figure 21 is a flow chart showing an outline of the inspection process.

圖22係表示在張力外加位置設置旋轉軸時的帶檢查裝置的概要之側視圖。Fig. 22 is a side view showing an outline of a tape inspection device when a rotary shaft is provided at a tension application position.

圖23係表示未在帶上產生翹曲時距離感測器的感測器件所檢測之距離的概要之說明圖。Fig. 23 is an explanatory view showing an outline of a distance detected by a sensing device of the distance sensor when warpage does not occur on the belt.

圖24係表示在帶上產生翹曲時距離感測器的感測器件所檢測之距離的概要之說明圖。Fig. 24 is an explanatory view showing an outline of a distance detected by a sensing device of the distance sensor when warpage occurs on the belt.

91...帶91. . . band

91a...帶的表面91a. . . Belt surface

91b...帶的裏面91b. . . Inside the belt

200...帶檢查裝置200. . . With inspection device

201、202...檢查用輥201, 202. . . Inspection roller

201a、202a...旋轉軸201a, 202a. . . Rotary axis

201b、202b...輥主體201b, 202b. . . Roller body

201bx...輥主體的周面201bx. . . The circumference of the roller body

203...位移部203. . . Displacement section

207...力量感測器207. . . Power sensor

208...感測器單元208. . . Sensor unit

208a...測定窗208a. . . Measurement window

208x...距離感測器208x. . . Distance sensor

208y...基準位置檢測感測器208y. . . Reference position detection sensor

MMP1...從旋轉軸201a的旋轉中心O201a朝向測定位置MP1延伸之面M MP1 . . . The surface extending from the rotation center O 201a of the rotating shaft 201a toward the measurement position MP1

MP1...向帶的寬度方向延伸之測定位置MP1. . . Measuring position extending in the width direction of the belt

MP2...面MMP1與軸向端部201be的交線MP2. . . The intersection of the surface M MP1 and the axial end 201be

MTP...從旋轉軸201a的旋轉中心O201a朝向檢查用輥201的頂部TP延伸之面M TP . . . The surface extending from the rotation center O 201a of the rotating shaft 201a toward the top TP of the inspection roller 201

O201a...旋轉軸201a的旋轉中心O 201a . . . The center of rotation of the rotating shaft 201a

Pt...張力外加位置Pt. . . Tension plus position

TP...頂部TP. . . top

φ2...面MTP與面MMP1所成角的角度Φ2. . . Angle at which the face M TP is at an angle to the face M MP1

Claims (10)

一種金屬製環狀帶的檢查方法,前述環狀帶具備表面和裏面,前述表面上設定從流延模流下之濃液所到達之到達位置,並形成由前述到達之濃液組成之流延膜,當前述環狀帶循環移動時,前述裏面由製膜用輥支撐,其特徵為,環狀帶的檢查方法具備以下步驟:(A)計算從前述表面上的測定位置到檢查用輥的支撐面的距離H,前述測定位置對應前述到達位置,針對藉由前述檢查用輥支撐前述裏面並外加移動張力之狀態的前述環狀帶計算前述距離H;(B)根據式(1)計算前述測定位置上的從前述支撐面至前述裏面的浮起量CL,前述式(1)為CL=H-D,前述D為前述測定位置上的前述環狀帶的厚度;及(C)判定前述計算出之浮起量CL是否在閾值以下。A method for inspecting a metal endless belt, the endless belt having a surface and a back surface, wherein the surface is set to a position at which a concentrated liquid flowing from a casting die reaches, and a cast film composed of the aforementioned concentrated liquid is formed When the endless belt is cyclically moved, the inside is supported by a film forming roller, and the method for inspecting the endless belt includes the following steps: (A) calculating the support from the measurement position on the surface to the inspection roller The distance H of the surface, the measurement position corresponds to the arrival position, and the distance H is calculated for the endless belt in a state in which the inside of the inspection roller is supported by the inspection roller and the movement tension is applied; (B) the measurement is calculated according to the formula (1) The floating amount CL from the support surface to the inside of the position, the formula (1) is CL = HD, the D is the thickness of the endless belt at the measurement position; and (C) the above calculated Whether the floating amount CL is below the threshold. 如申請專利範圍第1項所述之環狀帶的檢查方法,其中,前述檢查用輥在軸向中央部支撐前述環狀帶,以便軸向端部露出,在前述A步驟中利用測距單元測定從前述測定位置到前述測距單元的距離A和從前述測定位置上的前述軸向端部至前述測距單元的距離B,並根據式(2)計算前述距離H,其中,式(2)為H=B-A。The inspection method of the endless belt according to the first aspect of the invention, wherein the inspection roller supports the endless belt at a central portion in the axial direction so that the axial end portion is exposed, and the distance measuring unit is used in the aforementioned step A. Measuring a distance A from the aforementioned measurement position to the distance measuring unit and a distance B from the aforementioned axial end portion to the aforementioned distance measuring unit, and calculating the aforementioned distance H according to the formula (2), wherein the formula (2) ) is H=BA. 如申請專利範圍第1項所述之環狀帶的檢查方法,其中,在前述B步驟中,從存儲部讀取前述環狀帶的厚度D,並利用從前述存儲部讀取之前述環狀帶的厚度D計算前述浮起量CL,其中存儲部中從設定在前述環狀帶上之基準位置至前述測定位置的位置情報和前述測定位置上的前述環狀帶的厚度D相關聯而被存儲。The method for inspecting an endless belt according to claim 1, wherein in the step B, the thickness D of the endless belt is read from the storage portion, and the ring is read from the storage portion. The thickness D of the belt is used to calculate the floating amount CL in which the positional information from the reference position set on the endless belt to the measurement position is associated with the thickness D of the endless belt at the measurement position. storage. 如申請專利範圍第1項所述之環狀帶的檢查方法,其中,前述環狀帶由金屬製第1網和焊接在該第1網的寬度方向一側之金屬製第2網組成。The method for inspecting an endless belt according to claim 1, wherein the endless belt is composed of a first mesh made of metal and a second mesh made of metal welded to one side in the width direction of the first net. 如申請專利範圍第1項所述之環狀帶的檢查方法,其中,前述製膜用輥和前述檢查用輥為同一輥。The method for inspecting an endless belt according to the first aspect of the invention, wherein the film forming roller and the inspection roller are the same roller. 如申請專利範圍第1項所述之環狀帶的檢查方法,其中,前述移動張力為60N/mm2,前述閾值為0.1mm以下。The method for inspecting an endless belt according to claim 1, wherein the moving tension is 60 N/mm 2 and the threshold is 0.1 mm or less. 一種金屬製環狀帶的檢查裝置,前述環狀帶具備表面和裏面,前述表面上設定從流延模流下之濃液所到達之到達位置,並形成由前述到達之濃液組成之流延膜,當前述環狀帶循環移動時,前述裏面由製膜用輥支撐,其特徵為,前述環狀帶的檢查裝置具備:距離計算部,計算從前述表面上的測定位置到檢查用輥的支撐面的距離H,前述測定位置對應前述到達位置,針對藉由前述檢查用輥支撐前述裏面並外加移動張力之狀態的前述環狀帶計算前述距離H;浮起量計算部,根據式(1)計算前述測定位置上的從前述支撐面至前述裏面的浮起量CL,前述式(1)為CL=H-D,前述D為前述測定位置上的前述環狀帶的厚度;及判定部,判定前述計算出之浮起量CL是否在閾值以下。An inspection device for a metal endless belt, wherein the endless belt has a surface and a back surface, and the surface is provided with a position reached from a concentrated liquid flowing under a casting die, and a cast film composed of the aforementioned concentrated liquid is formed. When the endless belt is circulated, the inside is supported by a film forming roller, and the inspection apparatus for the endless belt includes a distance calculating unit that calculates a support from the measurement position on the surface to the inspection roller. The distance H of the surface, the measurement position corresponds to the arrival position, and the distance H is calculated for the endless belt in a state in which the inside of the inspection roller is supported by the inspection roller and the movement tension is applied; the floating amount calculation unit according to the formula (1) Calculating the floating amount CL from the support surface to the inside at the measurement position, wherein the formula (1) is CL=HD, the D is the thickness of the endless belt at the measurement position, and the determination unit determines the foregoing It is calculated whether the floating amount CL is below the threshold. 如申請專利範圍第7項所述之環狀帶的檢查裝置,其中,具備測定距離A和距離B之測距單元,前述距離A係從前述測距單元到前述測定位置的距離,前述距離B係從前述測距單元到在軸向中央部支撐前述環狀帶之前述檢查用輥所露出之軸向端部的距離,前述距離計算部根據式(2)計算前述距離H,其中,式(2)為H=B-A。The inspection apparatus for an endless belt according to claim 7, comprising: a distance measuring unit that measures a distance A and a distance B, wherein the distance A is a distance from the distance measuring unit to the measurement position, and the distance B a distance from the distance measuring unit to an axial end portion of the annular belt that supports the inspection roller exposed at the central portion in the axial direction, wherein the distance calculating unit calculates the distance H according to the formula (2), wherein 2) is H=BA. 如申請專利範圍第7項所述之環狀帶的檢查裝置,其中,具有從設定在前述環狀帶上之基準位置至前述測定位置的位置情報和前述測定位置上的前述環狀帶的厚度D相關聯而被存儲的存儲部,前述浮起量計算部利用存儲在前述存儲部中之前述環狀帶的厚度D計算前述浮起量CL。The inspection device for an endless belt according to the seventh aspect of the invention, wherein the inspection device includes a positional information set at a reference position on the endless belt to a position of the measurement position, and a thickness of the endless belt at the measurement position. In the storage unit in which D is associated, the floating amount calculation unit calculates the floating amount CL by the thickness D of the endless belt stored in the storage unit. 如申請專利範圍第7項所述之環狀帶的檢查裝置,其中,前述製膜用輥和前述檢查用輥為同一輥。The inspection device for an endless belt according to claim 7, wherein the film forming roller and the inspection roller are the same roller.
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