TW201301627A - Battery device with electric potential generated by oxidation-reduction reaction - Google Patents

Abstract

The present invention provides a battery device with electric potential generated by oxidation-reduction reaction, which comprises: a battery cell device, an electrocatalyst device, a buffer battery device, and a rectification charging device. The battery cell device employs various salt water solution as electrolyte, and has its anode as metal without having chemical reaction with electrolyte, and its cathode as carbon material with conductivity and breathing pores. The carbon material may breathe air and release negative ions containing hydroxyls when the air is dissolved in electrolyte. The battery cell device may implement the catalysis through the electrochemical damping effect of electrocatalyst for catalyzing the power generation, and then charge the electric energy into the buffer battery device through the rectification charging device, so as to produce the power generation battery resulting from the electric resonance effect. The present invention provides a self-generating battery device with no toxicity, no waste heat, no noise and zero emission.

Description

Battery device that generates potential by oxidation-reduction reaction

The invention relates to a battery device for generating a potential by a redox reaction, which mainly uses an electrocatalyst (Catalyst) technology to use a positive electrochemical damping effect for oxidative power generation, and a negative electrochemical damping effect to generate a reduction reaction to form a physical resonance. Closed loop, reaching 100% pollution, zero emission of green energy.

According to the fuel cell, the device is a student electric device, in which hydrogen and oxygen are directly combined into water, and the energy released by the synthesis reaction is electric energy (Cell). The battery can be divided into two properties: acid (Acid) and alkaline (Alkaline). According to Arrhenius's theory of acid-base ion, the hydroxide ion (OH ^- ) can be ionized in aqueous solution, and no other anion compound is produced, that is, hydrogen ion ion (OH ^- ) or hydrogen absorption is provided. A compound of ion (H ⁺ ), called alkaline. Ionization is a physical property that indicates the process by which atoms and molecules form ions under the action of energy. If the hydrogen ion (H ⁺ ) in the solution is greater than the concentration of hydrogen ions in the pure water, that is, the cations released when dissolved in water are all hydrogen ion (H ⁺ ) compounds, or electrons (e ^- ) The recipient is called acid. Therefore, the oxygen ion (O ^2- ) is the conjugate base of the hydroxide ion (OH ^- )

O ^2- +H ₂ O → 2 OH ^-

Please refer to Figure 2. When hydrogen or oxygen is used as the fuel, the pure water 20 is first electrolyzed. At this time, the electrons are emitted from the anode to be an oxidation reaction, and the cathode is subjected to a reduction reaction, which is called an electrolytic reaction. In Fig. 2, zinc oxide 21 is used as the anode, carbon rod 22 is used as the cathode, and arrows indicate the charge flow direction 23.

Anode: 2H ₂ O → O ₂ +4H ⁺ +4e ^-

Cathode: 2H ₂ O+2e ^- → H ₂ + 2OH ^-

Electrolytic total reaction: 2H ₂ O → 2H ₂ +O ₂

The reverse electrolysis reaction, that is, the addition of hydrogen to the anode and the addition of oxygen to the cathode, produces pure water, electromotive force, and heat (ie, water vapor), which is called a hydrogen-oxygen fuel stack.

Anode: H ₂ → 2H ⁺ + 2e ^- Ea: 0V

Cathode: O ₂ +4H ⁺ +4e ^- → 2H ₂ O Ec: 1.22PV

Reverse electrolysis: 2H ₂ +O ₂ → 2H ₂ O+heat Ec-Ea=1.22PV

Electrolysis is a chemical reaction that represents the process of redox reactions on the cathode and anode when energy is applied to the electrolyte. When electrolyzing a metal-air fuel stack, it is alkaline when the electrodes are acidic and the single metal is the electrode. Please refer to Figure 1. The invention takes an alkaline zinc-air fuel stack as an example;

Anode: Zn+2OH ^- → ZnO+H ₂ O+2e ^- Ea: 0V

Cathode: O ₂ +2H ₂ O+4e ^- → 4OH ^- Ec: 1.22PV

Charging reaction: 2Zn+O ₂ → 2ZnO Ec-Ea=1.22PV

This chemical reaction produces electromotive force and also produces pure water and heat. Among them, the electrolyte 10 is a potassium hydroxide solution (KOH); it also absorbs carbon dioxide (CO ₂ ), which causes the fuel cell to fail to operate continuously. In Fig. 1, the zinc plate 11 is used as the anode and the carbon rod 12 is used as the cathode. In Figure 1, the number K is the cathode; the number A is the anode; the arrow numbered 13 indicates the direction of the electron flow.

The battery device for generating a potential by a redox reaction according to the present invention comprises: a battery cell device, an electrical catalyst device, a buffer battery device, and a rectifying charging device. The battery tank device salt aqueous solution is an electrolyte, and the anode thereof is a metal that does not chemically react with the electrolyte, and the cathode thereof is a carbon material having conductivity and respiratory pores; the carbon material can breathe air and dissolve in the air. An anion containing hydroxide is released in the electrolyte. The electrical catalyst device is an electrochemical damping effect catalyst for catalyzing the oxidation reaction and the reduction reaction in the battery cell device, and the battery cell device is oxidized and reduced. The rectification charging device can convert the AC type potential output from the battery cell device into a DC mode and charge the buffer battery device.

The battery device for generating a potential by a redox reaction according to the present invention, wherein the buffer battery device is a secondary battery having reproducible charge and discharge capabilities. The buffer battery device may be one of an acidic secondary battery and an alkaline secondary battery, and may be a resonance secondary battery used in an acidic secondary battery or an alkaline secondary battery string/parallel connection.

The invention provides a battery device for generating a potential by a redox reaction, wherein the electrical catalyst device comprises a pulse generator, and an electron release circuit and a charge release circuit. The pulse generator is capable of generating positive and negative pulses to cause the charge release loop to release charge and the electron release loop to release electrons. When the electrical catalyst device discharges electrons to the battery cell device, a reduction reaction of reverse electrolysis can be generated in the battery cell device, and a potential difference is generated between the anode and the cathode of the battery cell device. When the electric catalyst device discharges electric charge to the battery cell device, an electrolytic oxidation reaction can be generated in the battery cell device, and a potential difference is generated between the anode and the cathode of the battery cell device.

The battery device for generating a potential by a redox reaction according to the present invention, wherein the electric charge generated by the electrical catalyst device differs from the phase of the electron by 180 degrees. The negative electrochemical damping effect is used to generate a reduction reaction, so that the internal structure of the battery cell device constitutes a physical resonance closed loop, achieving 100% pollution and zero emission of green energy.

Please refer to Figure 3 and Figure 4. The present invention relates to a battery device using a metal-air fuel stack as a main body of regenerative energy, and a battery device for generating a potential by a redox reaction. The device structure of the present invention is shown in FIG. 3, and includes a battery cell device 30, an electrical catalyst device 40, a rectifying charging device 50, and a buffer battery device 60.

Among them, the battery tank device 30 has a salt aqueous solution as the electrolytic solution 31, and the anode 32 is a metal that does not chemically react with the electrolytic solution 31, and the cathode 33 is a carbon material having conductivity and respiratory pores. The carbon material can breathe air and release negative ions containing hydroxide when the air is dissolved in the electrolyte 31.

Match Figure 5. The electrical catalyst device 40 is a catalyst for electrochemical damping effect for catalyzing the progress of the oxidation reaction and the reduction reaction in the battery cell device 30. The electrical catalyst device 40 releases electrons and charges to the battery cell device 30 to catalyze the progress of the oxidation reaction and the reduction reaction in the battery cell device 30. When the electric catalyst device 40 discharges electric charge to the battery cell device 30, an electrolytic oxidation reaction can be generated in the battery cell device 30, and a potential difference is generated between the anode 32 and the cathode 33 of the battery cell device 30. When the electron catalyst device 40 emits electrons, a negative electrochemical damping effect is generated, and a reduction reaction of reverse electrolysis can be generated in the battery cell device 30, and a potential difference is generated between the anode 32 and the cathode 33 of the battery cell device 30. The negative electrochemical damping effect produces a reduction reaction, which enables the internal structure of the battery cell device 30 to form a physical resonance closed loop, achieving 100% pollution and zero emission of green energy. The electric charge generated by the electrical catalyst device 40 is different from the phase of the electron by 180 degrees.

The buffer battery device 60 is a secondary battery having reproducible charging and discharging capabilities. The rectifying and charging device 50 is capable of converting the electric potential of the AC type output from the battery tank device 30 into a DC mode and charging the buffer battery device 60.

Taking the aforementioned zinc-air fuel stack as an example, the oxidation reaction of the reverse electrolysis shown in FIG. 1 is a charging reaction:

2Zn+O ₂ → 2ZnO Ec-Ea=1.22PV

The reduction reaction of electrolysis shown in Figure 2 is a charging reaction:

2H ₂ O → 2H ₂ +O ₂

In the present invention, the above two are combined to function in the same battery cell device 30, as shown in FIG. The electrolyte 31 is changed to neutral seawater, and the chemical reaction (electrolysis) of oxidation and reduction is changed to the ionization mode of the physical reaction, that is, the phase of charge and discharge is 180 degrees out of phase, and acts on the same battery cell device 30. Taking a zinc-air fuel stack as an example, the anode 32 is zinc metal and the cathode 33 is a carbon material that can absorb oxygen (O ₂ ). When the battery cell device 30 obtains electrons, a reduction reaction of the reverse electrolysis can be generated in the battery cell device 30, and a potential difference is generated between the cathode and the anodes 33 and 32 of the re-sink device 30. The reaction equation is:

Anode: Zn+2OH ^- → ZnO+H ₂ O+2e ^- Ea: 0V

Cathode: O ₂ +2H ₂ O+4e ^- → 4OH ^- Ec: 1.22PV

Discharge reaction: 2Zn+O ₂ → 2ZnO Ec-Ea=1.22PV

When the battery cell device 30 obtains a charge (positive charge), an oxidation reaction of the reverse electrolysis can be generated in the battery cell device 30, and a potential difference is generated between the cathode and the anode 33, 32 of the re-battery cell device 30. The reaction equation is:

Anode: ZnO+H ⁺ → Zn+H ₂ O+2c ⁺ Ea: 1.22PV

Cathode: O ₂ +H ₂ O+c ⁺ → H ⁺ Ec: 0V

Charging reaction: 2ZnO → Zn+O ₂ Ec-Ea=-1.22PV

In the foregoing, the electrical catalyst device 40 can release electrons or charges to the battery cell device 30 to trigger an oxidation reaction or a reduction reaction in the battery cell device 30. Therefore, the electrons and charges released by the electrical catalyst device 40 are the catalysts for the oxidation reaction and the reduction reaction, respectively.

In the catalytic process of the foregoing discharge reaction and charging reaction, the discharge is reversed and the polarity is opposite, and the phases of charge and discharge are 180 degrees out of phase (controlled by the electrical catalyst device 40), that is, the alternating current stack is generated. After the stack is converted to DC by the rectifying charging device 50, the buffer battery device 60 can be charged.

The present invention focuses on physical reactions (ionization) and requires an ion generating device to complete the reaction. The electrical catalyst device 40 is an ion generator. The electrical catalyst device 40 generates charge (positive ions) in the battery cell device 30 to generate a charging function; it can generate electrons (negative ions) in the battery cell device 30 to generate a discharge. The electrical catalyst device 40 can be referred to as an electrochemical damper. The electrical catalyst device 40 includes a pulse generator 41, and an electron release circuit 43 and a charge release circuit 42. The pulse generator 41 is capable of generating positive and negative pulses. Among them, the positive pulse can initiate the charge release circuit but the charge, and the negative pulse can activate the electron release circuit but the electron. The electron emission circuit 43 includes a transistor 431, an electrically damped resonance chamber 432, and a step-up transformer 433 that are configured to convert a frequency into electrons. The charge release circuit 42 includes a transistor 421, an electrically damped resonance chamber 422, and a step-up transformer 423 that are configured to convert a frequency into an electric charge. The electron release circuit 43 and the transformers 433, 423 of the charge release circuit 42 are capable of outputting electrons at the negative ion output terminal 434, outputting charge at the positive ion output terminal 424, and outputting a neutral potential at the neutron potential terminal 44. Since the electrochemical redox reaction of charge and discharge must reach the conservation of charge, which is equivalent to the physical resonance effect, the inventor of the present invention needs the inventor's Republic of China No. 098128110 "super inductor of infinite-order resonance cabin". Infinite level resonance cabin technology. The electrochemical dampers 422, 432 complete the positive and negative electrolysis reactions, which are called electrical catalysts. The power required by the electrical catalyst device 40 can come from the P and N of the buffer battery device 60. The electrons output by the electrical catalyst device 40 are strong oxidants, and the outputted charges are strong reducing agents. The electron and charge output of the electrical catalyst device 40 extends into the cell slot device 30, and the electrode 34 is a carbon nanotube that selects a strong electron flow dielectric material. When the positive and negative step-up transformers are OFF, there is a counter electromotive force generated by the resonance chamber to form a resonance with the positive and negative pulse generators, thereby controlling the amount of ion generation; and the resonance chamber can generate the counter electromotive force generated by the pulse generator. Absorption, resulting in more stable operation of the electron and charge output loop.

The aforementioned buffer battery device 60 may be the acidic secondary battery 61 shown in FIG. The acidic secondary battery 61 is composed of an equivalent inductor 611 and a capacitor 612, and is a parallel resonance type. The buffer battery device 60 may be the alkaline secondary battery 62 shown in FIG. The alkaline secondary battery 62 is composed of an equivalent inductor 621 and a capacitor 622, and is a series resonant resonance type. The resonant battery 63 used in parallel with the acidic secondary battery 61 shown in Fig. 6 and the alkaline secondary battery 62 of Fig. 7 can be used as the buffer battery device 60, as shown in Fig. 8.

The charging and discharging behavior of the zinc-air battery is a chemical behavior, so the electrolysis and the reverse electrolysis cannot be carried out in the same battery tank device at the same time. During the oxidation and reduction reaction, the electrolytic aqueous solution (such as KOH) directly participates in the reaction, such as absorbing CO ₂ , causing the reactor itself to be poisoned and unable to operate. For example, if the electrolytic aqueous solution is directly changed into an aqueous solution of sodium chloride, toxic gas (chlorine gas) is generated. ) and NaOH. In the reaction process of the oxidative charging and the reduction discharge of the present invention, the electrolytic solution 31 is used only for physical reaction without participating in a chemical reaction. The electrolyte 31 can be selected from neutral sea water solutions in addition to pure water. Since the electrolyte 31 does not undergo a chemical reaction (ie, electrolysis), no harmful gas is generated. As the electrode material of the cathode 33, a material which does not participate in the reaction, such as graphite, carbon rod, carbon nanotube, carbon fiber or the like, is selected. The metal electrode 32 portion excludes metals other than lithium metal (Li) which are liable to chemically react with seawater. The metal electrode portion may also be a lithium alloy. In the case of a physical reaction, the capacity density is determined by ions. Therefore, as long as the ion solubility increases, the capacity density increases even if the volume is reduced.

In summary, the battery device for generating a potential by a redox reaction according to the present invention generates a physical resonance closed loop by using a negative electrochemical damping effect generated by an electrical catalyst device to generate a reduction reaction. Replacing chemical changes with physical reactions to achieve 100% pollution and zero-emissions of green energy. Further, the potential of the alternating current type generated by the oxidation discharge and the reduction charging of the present invention can be converted into a direct current type by a rectifying and charging device and charged into the buffer battery device, thereby improving the efficiency of the self-generated power of the present invention.

The above description is intended to be illustrative, and not restrictive, and many modifications, variations and equivalents may be made without departing from the spirit and scope of the invention. However, they all fall within the scope of protection of the present invention.

10. . . Electrolyte

11. . . anode

12. . . cathode

13. . . Electron flow direction

20. . . Pure water

twenty one. . . Zinc oxide

twenty two. . . Carbon rod

twenty three. . . Charge flow direction

30. . . Battery slot device

31. . . Electrolyte

32. . . anode

33. . . cathode

34. . . electrode

40. . . Electrical catalyst

41. . . Positive and negative pulse generator

42. . . Charge generation loop

421. . . Transistor

422. . . Electrochemical damper

423. . . transformer

424. . . Charge output

43. . . Electronic generation loop

431. . . Transistor

432. . . Electrochemical damper

423. . . transformer

434. . . Electronic output

44. . . Neutron output

50. . . Rectification charging device

60. . . Buffer battery device

61. . . Acid secondary battery

611. . . Inductor

612. . . Capacitor

62. . . Alkaline secondary battery

621. . . Inductor

622. . . Capacitor

63. . . Resonant battery

P. . . anode

N. . . cathode

A. . . anode

K. . . cathode

Figure 1 is a schematic diagram of a zinc-air fuel stack.

Figure 2 is a schematic diagram of a known oxyhydrogen generator.

Figure 3 is a structural view of the present invention.

Figure 4 is a schematic view of the battery cell device of the present invention.

Figure 5 is a circuit diagram of an embodiment of an electrical catalyst device.

Fig. 6 is an equivalent circuit structure diagram of an acidic secondary battery.

Figure 7 is an equivalent circuit structure diagram of an alkaline secondary battery.

Figure 8 is an equivalent circuit structure diagram of a resonant battery.

30. . . Battery slot device

40. . . Electrical catalyst device

50. . . Rectification charging device

60. . . Buffer battery device

Claims (13)

A battery device for generating a potential by a redox reaction, comprising: a battery tank device, wherein a salt aqueous solution is used as an electrolyte, and an anode thereof is a metal that does not chemically react with the electrolyte, and the cathode is electrically conductive a carbon material with a breathing pore; the carbon material can breathe air and release a negative ion containing hydroxide when the air is dissolved in the electrolyte; and an electrical catalyst device, which is an electrochemical damping effect catalyst for catalyzing The oxidation reaction and the reduction reaction in the battery cell device; the electrical catalyst device comprises a pulse generator, and an electron release circuit and a charge release circuit; the pulse generator can generate positive and negative pulses; The positive pulse can initiate the charge release circuit to release the charge; the negative pulse can activate the electron release circuit to release the electron; and the electrical catalyst device can cause the reverse electrolysis in the battery cell device when the battery cell device releases electrons. a reduction reaction that creates a potential difference between the anode and the cathode of the battery cell device; the electrical catalyst device enables electricity when the battery cell device discharges charge An electrolytic oxidation reaction is generated in the tank device, and a potential difference is generated between the anode and the cathode of the battery tank device; a buffer battery device which is a secondary battery having reproducible charge and discharge capability; and a rectification charging device It is possible to convert the potential of the AC type output from the battery cell device into a DC mode and charge the buffer battery device. For example, in the first aspect of the patent application, a battery device that generates a potential by a redox reaction, wherein the chemical damping effect of the electrons emitted by the electrical catalyst device is oxidative power generation, and the chemical damping effect of releasing the charge is to restore the power generator. A battery device that generates a potential by a redox reaction according to the first aspect of the patent application, wherein the electric charge generated by the electrical catalyst device differs from the phase of the electron by 180 degrees. A battery device for generating a potential by a redox reaction according to the first aspect of the patent application, wherein the electronic release circuit of the electrical catalyst device comprises a transistor for setting a frequency to be converted into an electron, an electrically damped resonance chamber, and a boosting device. Transformer. A battery device that generates a potential by a redox reaction according to the first aspect of the patent application, wherein the charge release circuit of the electrical catalyst device includes a transistor that can convert a frequency into a charge, an electrically damped resonance chamber, and a boost Transformer. A battery device for generating a potential by a redox reaction according to the first aspect of the invention, wherein the anode metal of the battery cell device is one of copper, aluminum, zinc, or the like. A battery device for generating a potential by a redox reaction according to the first aspect of the invention, wherein the cathode carbon material of the battery cell device is one of graphite, carbon rod, carbon nanotube, carbon fiber or the like. A battery device for generating a potential by a redox reaction according to the first aspect of the invention, wherein the electrolyte in the battery cell device is a neutral seawater. A battery device that generates a potential by a redox reaction according to the first aspect of the invention, wherein the buffer battery device is one of an acidic secondary battery and an alkaline secondary battery. A battery device that generates a potential by a redox reaction according to the first aspect of the invention, wherein the buffer battery device is an acid secondary battery, an alkaline secondary battery string, or a resonant battery used in parallel. A battery device for generating a potential by a redox reaction according to the first aspect of the invention, wherein the rectifying and charging device is a fast rectifier, and the fast rectifier may be a fast diode. A battery device that generates a potential by a redox reaction according to the first aspect of the invention, wherein the rectifying and charging device is a converter capable of exchanging direct current and alternating current. A battery device for generating a potential by a redox reaction according to the first aspect of the invention, wherein a power source required for the operation of the electrical catalyst device can be provided by the buffer battery device.