201249475 六、發明說明： 【發明所屬之技術領域】 本發明關於一種油性固形化妝料。進一步詳細而言， 關於一種油性固形化妝料，其毛孔遮蔽效果，分散性、使 用性（柔軟性、滑順性）優異。 【先前技術】 粉底或底妝（base makeup)化妝料等會需要有可使 細紋及毛孔等變得不明顯的修補效果。在這種毛孔遮蔽化 妝料之中’以往一般而言是摻合球狀粉末並藉由粉末的擴 散效果而將毛孔隱藏（參照例如專利文獻1〜4 )。特別是 廣泛採用折射率高的二氧化矽等而能夠與化妝完成時的啞 光效果相輔相乘，然而其毛孔遮蔽效果有限。因此需要有 可勝過這種球狀粉末的毛孔遮蔽效果。 另外，關於使本發明之（b)成分分散於油分中所得 的分散體’在專利文獻5〜7有所記載，然而在這些文獻 中’關於本發明申請案化妝料所使用的其他摻合成分的組 合並無記載或提示。 〔先前技術文獻〕 (專利文獻） 專利文獻1特開平11-349442號公報 專利文獻2特開2002-241226號公報 專利文獻3特開2007-39372號公報 專利文獻4特表2008-544961號公報 201249475 專利文獻5特開2 0 0 8 - 6 3 3 3 0號公報 專利文獻6特開2 Ο Ο 8 - 6 3 3 3 1號公報 專利文獻7特開2009-40720號公報 【發明內容】 〔發明所欲解決之課題〕 本發明鑑於上述以往的狀況而完成，S的爲提供一種 油性固形化妝料，具有比以往的球狀粉末所產生的毛孔遮 蔽效果更加優異的毛孔遮蔽效果，進一步容易製劑化成爲 適當的硬度，不會發生色紋，使用性（柔軟性、滑順性） 優異。 〔用於解決課題之手段〕 爲了解決上述課題，本發明提供一種油性固形化妝料 ，其係含有：（a)固形油分2〜10質量％、（b)有機變 性黏土礦物2.5〜8質量％、（c)下述式（I)所表示之聚 甘油變性聚矽氧0.3〜8質量％、（d)陽離子界面活性劑 〇·1〜2質量％、及（e)碳原子數14〜24之分支飽和脂肪 酸0.2〜7質量％。201249475 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to an oily solid cosmetic. More specifically, an oily solid cosmetic is excellent in pore blocking effect, dispersibility, and usability (softness and smoothness). [Prior Art] A foundation or a base makeup cosmetic material may require a repairing effect which makes the fine lines and pores inconspicuous. In such a pore-blocking cosmetic material, the pores are generally concealed by the spherical powder and the pores are concealed by the powder diffusion effect (see, for example, Patent Documents 1 to 4). In particular, cerium oxide having a high refractive index or the like is widely used and can be multiplied by the matte effect at the time of completion of makeup, but the pore blocking effect is limited. Therefore, it is necessary to have a pore blocking effect that can overcome this spherical powder. In addition, the dispersions obtained by dispersing the component (b) of the present invention in an oil component are described in Patent Documents 5 to 7, but in these documents, the other blending components used in the cosmetic of the present invention are described. There are no records or tips for the combination. [Prior Art Document] (Patent Document) Patent Document 1 JP-A-H09-349442, JP-A-2002-241226, JP-A-2002-241372, JP-A-2007-39372 [Patent Document 5] JP-A-2002-00-3, No. 3, No. 3, No. 3, No. 3, No. 3, No. 3, No. 3, No. 3, No. The present invention has been made in view of the above-described conventional situation, and S provides an oily solid cosmetic which has a pore blocking effect superior to that of a conventional spherical powder, and is further easily formulated. It has an appropriate hardness and does not cause color streaks, and is excellent in workability (softness and smoothness). [Means for Solving the Problem] In order to solve the above problems, the present invention provides an oily solid cosmetic comprising (a) a solid oil component of 2 to 10% by mass, and (b) an organic modified clay mineral of 2.5 to 8% by mass, (c) Polyglycerol-denatured polyfluorene represented by the following formula (I): 0.3 to 8 mass%, (d) cationic surfactant 〇·1 to 2% by mass, and (e) 14 to 24 carbon atoms The branched saturated fatty acid is 0.2 to 7 mass%.
Ri R1 I -OSi— -R20 · -ch2chch2o· —r2- I —SiO- I L Ri J P OH q T L R1 J Si-Ri Ri (I) 〔式（I)中，Ri表示碳原子數1〜12之直鏈或支鏈之烷 基、或苯基；R2表示碳原子數2〜11之伸烷基；p爲10〜 -6- 201249475 120之數；q爲1〜11之數。〕 另外，本發明提供上述油性固形化妝料，其中（b) 成分係以4級銨鹽型陽離子界面活性劑對水膨潤性黏土礦 物作處理所得的陽離子變性黏土礦物。 〔發明之效果〕 藉由本發明可提供一種油性固形化妝料，其係具有比 以往的球狀粉末所產生的毛孔遮蔽效果更加優異的毛孔遮 蔽效果，進一步容易製劑化成爲適當的硬度，不會發生色 紋，使用性（柔軟性、滑順性）優異。 【實施方式】 以下針對本發明詳細敘述。 〔（a)成分〕 作爲（a)成分的固形油分，只要在通常化妝料所使 用的常溫下呈固態至半固態的油分，則並不受特別限定， 而適合採用熔點在50 °C左右以上的固形油分。具體而言， 可列舉例如石蠟、聚乙烯蠟、乙烯丙烯共聚物、微晶蠘' 白地蠟、地蠟、或費托合成蠟等的烴系蠟、另外其他還有 木蠟、卡拿巴蠟、堪地里拉蠟、米蠟、蜜蠟（珠光蠟）、 米蠟、凡士林、硬化荷荷芭油、硬化牛脂、膽固醇、植物 醇、及該等的衍生物等。其中，製劑的「發汗」（因爲溫度 變化等造成蠟結晶的收縮·膨脹，使得製劑中的油分成分 201249475 隨著時間經過在化妝料表面浮現油滴）防止或收縮防止等 的觀點看來，微晶蠟、石蠟等的烴系蠟爲佳。（a)成分 可使用1種或2種以上。 (a)成分的摻合量在本發明化妝料總量中占2〜10 質量％，宜爲3〜7質量％。在未滿2質量％的情況下，難 以將化妝料製成固態，另一方面，在超過1 〇質量％的情況 下，化妝料變得過硬，而變得不易以手由容器取出。 〔（b)成分〕 作爲（b )成分的有機變性黏土礦物，可列舉將黏土 礦物（例如蒙脫石、皂石、水輝石、膨土等）的結晶層間 所夾雜的交換性陽離子以有機極性化合物或有機陽離子取 代而得的物質等。在本發明中，適合採用以4級銨鹽型陽 離子界面活性劑對水膨潤性黏土礦物作處理所得的陽離子 變性黏土礦物。 此處，上述水膨潤性黏土礦物可列舉例如屬於膨潤石 群的層狀矽酸鹽礦物，一般而言，宜爲具有下述式（II) 所表示之三層構造的膠體性含水矽酸鋁等的黏土礦物， (Χ,Υ) 2-3 ( Si,Al) 4〇ιο ( OH) 2Ζ,/3·ηΗ2〇 ( II ) 〔式（II)中，X 表示 Al、Fe(III) 、Mn(III)或 Cr( ΙΠ) ;Y 表示 Mg、Fe(II) 、Ni、Zn、LiSMn(II)； Z 表示 K、Na、l/2Ca 或 l/2Mg〕。 ⑧ 201249475 離子 基； 自獨 素原 蔻基 氯化 銨、 、山 、鯨 山窬 苄基 基二 基甲 箭基 溴化 酸鹽 對上述水膨潤性黏土礦物作處理的4級銨鹽型陽 界面活性劑爲下述式（III )所表示之化合物： χ· (III) R3wR5Ri R1 I -OSi - -R20 · -ch2chch2o· -r2- I - SiO- IL Ri JP OH q TL R1 J Si-Ri Ri (I) [In the formula (I), Ri represents a carbon number of 1 to 12 a linear or branched alkyl group or a phenyl group; R2 represents an alkylene group having 2 to 11 carbon atoms; p is a number of 10 to -6-201249475 120; q is a number of 1 to 11. Further, the present invention provides the above oily solid cosmetic, wherein the component (b) is a cationically modified clay mineral obtained by treating a water-swellable clay mineral with a 4-stage ammonium salt type cationic surfactant. [Effect of the Invention] According to the present invention, it is possible to provide an oily solid cosmetic which has a pore blocking effect which is more excellent than the pore blocking effect by the conventional spherical powder, and is further easily formulated into an appropriate hardness and does not occur. Color pattern, excellent in usability (softness and smoothness). [Embodiment] Hereinafter, the present invention will be described in detail. [Component (a)] The solid oil component as the component (a) is not particularly limited as long as it is a solid to semi-solid oil at a normal temperature used in a normal cosmetic, and is preferably a melting point of about 50 °C or higher. Solid oil. Specific examples thereof include hydrocarbon waxes such as paraffin wax, polyethylene wax, ethylene propylene copolymer, microcrystalline cerium wax, ceresin wax, and Fischer-Tropsch wax, and other waxes and carnauba waxes. , candidella wax, rice wax, beeswax (bead wax), rice wax, petrolatum, hardened jojoba oil, hardened tallow, cholesterol, plant alcohol, and these derivatives. Among them, the "sweating" of the preparation (because of the temperature change or the like causes the shrinkage and swelling of the wax crystal, so that the oil component in the preparation 201249475 evaporates on the surface of the cosmetic material over time) prevention or shrinkage prevention, etc., A hydrocarbon wax such as a crystalline wax or a paraffin wax is preferred. (a) Component One type or two or more types can be used. The blending amount of the component (a) is 2 to 10% by mass, preferably 3 to 7% by mass, based on the total amount of the cosmetic of the present invention. In the case of less than 2% by mass, it is difficult to make the cosmetic into a solid state. On the other hand, in the case of more than 1% by mass, the cosmetic becomes too hard and it is difficult to take it out of the container by hand. [Component (b)] The organically modified clay mineral as the component (b) includes an organic cation which is intercalated between crystal layers of clay minerals (for example, smectite, saponite, hectorite, bentonite, etc.). A substance obtained by substituting a compound or an organic cation. In the present invention, a cationically modified clay mineral obtained by treating a water-swellable clay mineral with a 4-stage ammonium salt type cationic surfactant is suitably used. Here, the water-swellable clay mineral may, for example, be a layered niobate mineral belonging to the bentonite group, and is generally a colloidal aqueous aluminum niobate having a three-layer structure represented by the following formula (II). Clay minerals, (Χ, Υ) 2-3 (Si, Al) 4〇ιο ( OH) 2Ζ, /3·ηΗ2〇( II ) [In the formula (II), X represents Al, Fe(III), Mn(III) or Cr(ΙΠ); Y represents Mg, Fe(II), Ni, Zn, LiSMn(II); Z represents K, Na, l/2Ca or l/2Mg]. 8 201249475 Ion-based; Quaternary ammonium-type cation interfacial activity of the above-mentioned water-swelling clay minerals treated with benzyl sulfonium chloride, yam, and whale behenyl benzyl diylmethyl bromide The agent is a compound represented by the following formula (III): χ· (III) R3wR5
A R, R6 〔式（III)中，R3表示碳原子數10〜22之烷基或苄 R4表示甲基或碳原子數10〜22之烷基；R5與R6各 立表示碳原子數1〜3之烷基或羥基烷基；X表示鹵 子或甲基硫酸鹽殘基〕。 具體而言，可列舉十二烷基三甲基氯化銨、肉豆 三甲基氯化銨、鯨蠟基三甲基氯化銨、硬脂醯三甲基 銨、山嵛基三甲基氯化銨、肉豆蔻基二甲基乙基氯化 鯨蠟基二甲基乙基氯化銨、硬脂醯二甲基乙基氯化銨 嵛基二甲基乙基氯化銨、肉豆蔻基二乙基甲基氯化銨 蠟基二乙基甲基氯化銨' 硬脂醯二乙基甲基氯化銨、 基二乙基甲基氯化銨、苄基二甲基肉豆蔻基氯化銨、 二甲基鯨蠟基氯化銨、苄基二甲基硬脂醯氯化銨、苄 甲基山窬基氯化銨、苄基甲基乙基鯨蠟基氯化銨、苄 基乙基硬脂醯氯化銨、二硬脂醯二甲基氯化銨、二山 二羥乙基氯化銨，以及將上述各化合物的氯化物改成 物而成的化合物等、甚至二棕櫚基丙基乙基銨甲基硫 等。 以4級銨鹽型陽離子界面活性劑對上述水膨潤性黏土 礦物作處理而得到陽離子變性黏土礦物的方法，例如可藉 201249475 由在水、丙酮、或低級醇等的低沸點溶劑中，對上述水膨 潤性黏土礦物與4級銨鹽型陽離子界面活性劑實施分散攪 拌處理’除去低沸點溶劑而得到。另外還可將水膨潤性黏 土礦物與4級銨鹽型陽離子界面活性劑摻合，在配方中使 有機變性，以這種方式得到的物質亦可適合使用。此外， 亦可依照需要倂用4級銨鹽型陽離子界面活性劑與非離子 性界面活性劑。 以4級銨鹽型陽離子界面活性劑對水膨潤性黏土礦物 作處理所得的陽離子變性黏土礦物可列舉二甲基二硬脂醯 鞍水輝石（=Quaternium-18 Hectorite) v 二甲基二硬脂 醯銨膨土（ = Quaternium-18 Bentonite)、或二-十八院基 二甲基銨蒙脫石、十八烷基二甲基苄基銨蒙脫石、二-十 六烷基二甲基銨蒙脫石等。該等係以例如「BENTON 38VCG」（=Quaternium-1 8 H e c t o r i t e ) 、「Β ΕΝ T ON 3 4」（ =Quaternium-1 8 Bentonite ) (任—者皆 ElementisAR, R6 [In the formula (III), R3 represents an alkyl group having 10 to 22 carbon atoms or benzyl R4 represents a methyl group or an alkyl group having 10 to 22 carbon atoms; and R5 and R6 each represent a carbon number of 1 to 3; An alkyl or hydroxyalkyl group; X represents a halogen or methyl sulfate residue]. Specific examples thereof include dodecyltrimethylammonium chloride, nutmethylenetrimethylammonium chloride, cetyltrimethylammonium chloride, stearic acid trimethylammonium, and behenyltrimethylammonium. Ammonium chloride, myristyl dimethylethyl chloride cetyl dimethyl ethyl ammonium chloride, stearic acid dimethyl ethyl ammonium chloride decyl dimethyl ethyl ammonium chloride, nutmeg Diethylmethylammonium chloride waxy diethylmethylammonium chloride' stearin diethylaminoammonium chloride, bisethylmethylammonium chloride, benzyldimethyl myristate Ammonium chloride, dimethyl cetyl ammonium chloride, benzyl dimethyl stearate ammonium chloride, benzyl methyl behenyl ammonium chloride, benzyl methyl ethyl cetyl ammonium chloride, benzyl Base ethyl stearin ammonium chloride, distearyl dimethyl ammonium chloride, diamethylene dihydroxyethyl ammonium chloride, and a compound obtained by modifying a chloride of each of the above compounds, or even Palm propyl ethyl ammonium methyl sulfide and the like. A method for obtaining a cationically modified clay mineral by treating the above water-swellable clay mineral with a 4-stage ammonium salt type cationic surfactant, for example, by using a low-boiling solvent such as water, acetone or a lower alcohol in 201249475 The water-swellable clay mineral and the 4-stage ammonium salt-type cationic surfactant are subjected to a dispersion stirring treatment to obtain a low-boiling solvent. Further, a water-swellable clay mineral may be blended with a grade 4 ammonium salt type cationic surfactant to impart organic denaturation in the formulation, and a substance obtained in this manner may also be suitably used. Further, a grade 4 ammonium salt type cationic surfactant and a nonionic surfactant may be used as needed. The cationic modified clay mineral obtained by treating the water-swellable clay mineral with a 4-stage ammonium salt type cationic surfactant can be exemplified by dimethyl distearyl samarium hectorite (= Quaternium-18 Hectorite) v dimethyl distear Ammonium bentonite ( = Quaternium-18 Bentonite), or two-eighteen yards of dimethylammonium montmorillonite, octadecyldimethylbenzylammonium montmorillonite, di-hexadecyldimethyl Ammonium montmorillonite, etc. These are, for example, "BENTON 38VCG" (=Quaternium-1 8 H e c t o r i t e ), "Β ΕΝ T ON 3 4" (=Quaternium-1 8 Bentonite) (any - all Elementis
Specialities 公司製）、「Claytone 40」'「Claytone SO」（ 任一者皆爲Southern Clay公司製）等的形式在市面販售 ，而可由商業手段取得。（b)成分可使用1種或2種以 上。 (b)成分宜採用分散於油分中的形態之分散體。該 分散體可採用以往技術文獻的專利文獻5所記載的物質。 另外，製造方法亦可藉由專利文獻5所記載的製造方法來 進行。 亦即，有機變性黏土礦物係具有平均厚度爲2 μηι以上 -10- 201249475 的層狀構造，通常會成爲凝集體，因 態下難以分散在油分中。於是，在油 及/或衝撃力對有機變性黏土礦物實 行薄片化而製成具有平均厚度爲0.1μ 0.5〜50μηι左右的板狀粒子構造的有 。藉此，有機變性黏土礦物的各板狀 不會凝集而能夠分散。 具體而言，可藉由如下述般的處 黏度具有流動性的分散體的形式獲得 的有機變性黏土礦物（通常爲具有平 狀構造的凝集體）與油分的混合物t 1mm左右的玻璃珠（或二氧化銷珠等 器（Paint Shaker)、珠磨機等施加书 而薄片化。一旦得到分散體，在聚矽 再次凝集，可維持良好的分散狀態。 使有機變性黏土礦物分散的油分 合爲全體在常溫下爲液態的油分，特 。聚矽氧油除了可使用例如二甲基聚 矽氧烷等的鏈狀聚矽氧烷、八甲基環 五矽氧烷、十二甲基環六矽氧烷等的 只要沒有特別的問題，還可使用形成 氧樹脂、聚矽氧橡膠各種聚矽氧烷（ 烷基變性聚矽氧烷、氟變性聚矽氧烷 黏土礦物的分散性的觀點看來，分散 此在此層狀構造的狀 分中，藉由機械剪力 施剝離處理，藉此進 以下且平均長徑爲 機變性黏土礦物粒子 粒子在油分中實質上 理方法，通常以在低 。亦即，藉由在市售 均厚度2μιη以上的層 戸以同體積加入直徑 )，並使用漆類攪拌 獎械剪力及/或衝撃力 氧油等的油相中不會 並無特別限定，而適 別適合使用聚矽氧油 矽氧烷、甲基苯基聚 四矽氧烷、十甲基環 環狀聚矽氧烷之外， 三維網狀構造的聚矽 胺基變性聚矽氧烷、 等）等。從有機變性 體中的有機變性黏土 -11 - 201249475 礦物之分散量（摻合量）宜設定爲有機變性黏土礦物在分 散體用油分中占0.25〜30質量％左右。藉由使用此有機變 性黏土礦物在油分中的分散體，與直接使用有機變性黏土 礦物的情況相比，可提高化妝料中有機變性黏土礦物的實 際摻合量，藉此可進一步有效地發揮毛孔隱蔽效果，此外 ，在使用性這點上，亦可因爲較優異的增黏效果而能夠更 進一步有效地發揮出如新鮮巧克力般柔軟旦滑順的使用感 〇 (b )成分的摻合量（實際分量）在本發明化妝料總 量中占2.5〜8質量％，宜爲3〜7質量％。在未滿2.5質量 %的情況，難以發揮出摻合（b )成分所產生的效果（例如 柔軟性、滑順性等），另一方面，在超過8質量％的情況 ，化妝料變得過硬，而難以塡充至容器。 〔（c)成分〕 (c)成分爲下述式（I)所表示之直鏈型聚甘油變性 聚矽氧（兩末端聚矽氧化聚甘油）。Forms such as "Claytone 40" and "Claytone SO" (manufactured by Southern Clay Co., Ltd.) are sold in the market and can be obtained by commercial means. (b) The component may be used alone or in combination of two or more. The component (b) is preferably a dispersion in a form dispersed in an oil. As the dispersion, those described in Patent Document 5 of the prior art document can be used. Further, the production method can also be carried out by the production method described in Patent Document 5. That is, the organically modified clay mineral has a layered structure having an average thickness of 2 μηι or more -10- 201249475, and usually becomes an aggregate, which is difficult to disperse in the oil. Then, the organic denatured clay mineral is flaky in oil and/or squeezing force to form a plate-like particle structure having an average thickness of about 0.1 μ 0.5 to 50 μm. Thereby, each plate of the organically modified clay mineral does not aggregate and can be dispersed. Specifically, a glass bead of about 1 mm of a mixture of an organically modified clay mineral (usually an aggregate having a flat structure) and an oil obtained by a dispersion having a fluidity as described below (or A thin film is formed by applying a book such as a Paint Shaker or a bead mill. Once the dispersion is obtained, the polycondensation is again agglomerated to maintain a good dispersion state. The oil dispersed in the organically modified clay mineral is integrated into the whole. An oil which is liquid at normal temperature, in particular, a polyoxyxane, such as a chain polyoxyalkylene such as dimethyl polyoxyalkylene, octamethylcyclopentaoxane or dodecylcyclohexanthene. As long as there is no particular problem with oxane or the like, it is also possible to use the viewpoint of forming dispersibility of various polyoxyalkylene oxides (alkyl-denatured polysiloxanes, fluorine-denatured polyoxane clay minerals) of an oxygen resin or a polyoxyxene rubber. Dispersing this in the layered structure, and applying a stripping treatment by mechanical shearing force, thereby taking the following and the average long diameter is a substantially rational method for the mechanically deformed clay mineral particle particles in the oil component, usually in Low, that is, by adding the diameter in the same volume in the layer of commercially available thicknesses of 2 μm or more, and using the lacquer-like stirring mechanical shearing force and/or the oil phase of the oxylining oil, etc. Restricted, and suitable for the use of polyoxymethane oxime, methylphenyl polytetraoxane, decamethylcyclocyclic polyoxane, three-dimensional network structure of polyamido-based denatured polyfluorene Oxytomane, etc.). Organic Denatured Clay from Organic Denatures -11 - 201249475 The amount of mineral dispersion (mixing amount) should be set to be about 0.25 to 30% by mass of the organically modified clay mineral in the oil content of the dispersion. By using the dispersion of the organically modified clay mineral in the oil, the actual blending amount of the organically modified clay mineral in the cosmetic can be increased as compared with the case of directly using the organic denatured clay mineral, thereby further effectively utilizing the pores Concealing effect, in addition, in terms of usability, it is also possible to more effectively exert the blending amount of the feeling of use (b), such as fresh chocolate, because of the superior viscosity-increasing effect ( The actual component is 2.5 to 8 mass%, preferably 3 to 7 mass%, based on the total amount of the cosmetic of the present invention. When it is less than 2.5% by mass, it is difficult to exhibit the effect (for example, flexibility, smoothness, and the like) of the blended component (b). On the other hand, when it exceeds 8% by mass, the cosmetic material becomes too hard. It is difficult to fill the container. [Component (c)] The component (c) is a linear polyglycerol-denatured polyfluorene (two-end polyfluorene oxide glycerin) represented by the following formula (I).
?1 [1 _ [p I ?1 R—Si— I -OSi— I -r2o- •ch2chch2o r2 —SiO-I S' Ri (I) I Ri I L Ri J D I L OH」 q I L…J 式（I)中，Ri表示碳原子數1〜12之直鏈或支鏈之烷基 、或苯基，R2表示碳原子數2〜11之伸烷基，P爲1〇〜 120之數，q爲1〜11之數。 上述式（I)所表示的共聚物的製造，可藉由例如在 -12- ⑧ 201249475 聚甘油二烯丙基醚與單末端氫化二甲基聚矽氧烷的混合液 中加入氯化鉑酸異丙醇溶液，將其加熱並使其反應，於其 中添加鹽酸水溶液，過熱水解後加入碳酸氫鈉水，中和之 後，進行純化以及蒸發而獲得。但是並不受此製造方法限 定。（C )成分可列舉例如雙丁基二甲基矽酮聚甘油-3等 〇 (C)成分之摻合量在本發明化妝料總量中占0.3〜8 質量％ ’宜爲〇 · 5〜6質量％。在未滿0.3質量％的情況， 塡充至容器時，即使將化妝料成分加熱熔融，也會是流動 性低的狀態，因此難以塡充，另一方面，在超過8質量％ 的情況，化妝料變得容易發生色紋或沾黏。 〔（d)成分〕 作爲（d )成分的陽離子界面活性劑只要是一般化妝 料所可使用的物質，則不受特別限定，可例示例如硬脂醯 三甲基氯化銨、十六烷基三甲基氯化銨、十四烷基三甲基 氯化銨、月桂基三甲基氯化銨等的烷基三甲基銨鹽、二硬 脂醯二甲基氯化銨等的二烷基二甲基銨鹽、氯化聚（ Ν,Ν'-二甲基-3,5-亞甲基哌啶鐺）、氯化鯨蠟基吡啶鑰等 的烷基吡啶鑰鹽、烷基四級銨鹽、烷基二甲基苄基銨鹽、 烷基異喹啉鐵鹽、二烷基嗎啉鑰鹽、聚氧乙烯（以下ΡΟΕ )烷胺、烷胺鹽、聚胺脂肪酸衍生物、戊醇脂肪酸衍生物 、氯化苯二甲經銨（Benzalkonium Chloride)、节索氯錢 (Benzethonium Chloride)等。但是並不受這些例示所限 -13- 201249475 定。（d)成分可使用1種或2種以上。 (d)成分的摻合量在本發明化妝料總量中占0.1〜2 質量％，宜爲0.1〜1 .5質量％。在未滿〇. 1質量％的情況， 塡充至容器時，即使將化妝料成分加熱熔融，也會是流動 性低的狀態，因此難以塡充，另一方面，在超過2質量％ 的情況，化妝料在塗展時變得沉重，使用性有變差的傾向 〔（e)成分〕 (e)成分爲碳原子數14〜24 (宜爲16〜22)之分支 飽和脂肪酸。具體而言，可列舉異肉豆蔻酸、異十五烷酸 、異棕櫚酸、異硬脂酸、異花生酸、異山嵛酸等。宜爲異 硬脂酸。（e)成分可使用1種或2種以上。 在本發明中’使用直鏈飽和脂肪酸、分支不飽和脂肪 酸代替（e )成分情況，會在黏度高的狀態而使得化妝料 變硬，變得難以塡充至容器。 (e )成分的摻合量在本發明化妝料總量中占〇.2〜7 質量％ ’宜爲0 · 5〜5質量％。在未滿〇 . 2質量％的情況， 塡充至容器時’即使將化妝料成分加熱熔融，也會是流動 性低的狀態，因此難以塡充，另一方面，在超過7質量％ 的情況，化妝料變得容易發生色紋或沾黏。 在本發明中，從防止色紋的觀點看來，以（d )成分 :(e)成分=1: 15〜3: 5(質量比）之摻合比來摻合爲 較佳。 -14- 201249475 本發明化妝料係以上述（a )〜（e )成分爲必須成分 的固體製劑。在以往難以大量摻合（b )成分，若大量摻 合’則會有在乳霜基劑中，浮油等現象變得容易發生這樣 的缺點。在本發明中’藉由將劑型設定爲固態、或將（c )〜（e )成分這3種成分加以組合作爲分散劑來使用， 可克服這些缺點，同時可使藉由（b)成分產生的毛孔隱 蔽效果更爲提高。另外’藉由（b)成分的增黏效果，可 發揮出柔軟滑順的使用感。進一步而言，在使用（b)成 分作爲油中分散體的情況，可更有效地抑制製劑的硬度變 得過高’因此在使用時容易以手將化妝料由容器取出，另 外還可發揮出容易塗佈這樣的效果。 在本發明中，除了上述必須成分之外，還加上可進一 步摻合（f)粉末成分。藉由摻合（f)成分，可更進一步 提高毛孔隱蔽效果。粉末成分只要是一般可摻合於化妝料 的物質，則不受特別限定，可列舉例如球狀二氧化矽、球 狀聚乙烯、聚醯胺球狀樹脂粉末（耐綸球狀粉末）、交聯 型聚（甲基）丙烯酸甲酯球狀樹脂粉末等的球狀粉末、或 滑石、雲母、高嶺土、絹雲母、碳酸鈣、碳酸鎂等的體質 顔料、二甲基矽酮交聯聚合物、（二甲基矽酮/乙烯二甲 基矽酮）交聯聚合物、聚甲基倍半矽氧烷等的高分子聚矽 氧系粉末、聚乙烯、聚甲基丙烯酸甲酯、金屬皂等。但是 並不受這些例示所限定。（f)成分可使用1種或2種以 上，粉末的表面亦可不經過處理。 在摻合（f)成分的情況’從毛孔隱蔽效果、使用性 -15- 201249475 等的觀點看來，其摻合量係以定爲在本發明化妝料總量中 占10〜30質量％爲佳，較佳爲20〜30質量％。 此外，本發明之固形油性化妝料係藉由蠟產生的結晶 而固化，因此希望不摻合會導致阻礙蠟產生結晶的成分。 這種成分可列舉油膠體化劑（例如糊精系的油性高分子（ 「Rheopearl KL」；千葉製粉股份有限公司製）等）等。 在本發明中，進一步爲了抑制「浮粉」現象，亦可摻合 (g)酯油。「浮粉」是指化妝料塗佈後，揮發性的油分（ 聚矽氧油等）揮發，粉末呈白色浮起的現象。特別是在大 量摻合球狀粉末這樣的情況，揮發性油分捧發時，粉末表 面的折射率上升’皮膚與粉末表面的折射率差增加，而觀 察到白色浮起物。藉由摻合（g)成分，可有效地抑制浮 粉現象。 酯油可例示例如肉豆蔻酸異丙酯、辛酸鯨蠟酯、肉豆 蔻酸辛酯十二烷基、棕櫚酸異丙酯、硬脂酸丁酯、月桂酸 己酯 '肉豆蔻酸肉豆蔻酯、油酸癸酯、二申基辛酸己基癸 酯、乳酸鯨蠟酯、乳酸肉豆蔻酯、醋酸羊毛脂酯、硬脂酸 異鯨蠟酯、異硬脂酸異鯨蠟酯、12 -羥基硬脂酸膽固醇酯 、二-2-乙基己酸乙二醇酯、二季戊四醇脂肪酸酯、單異硬 脂酸N -烷基二醇酯、二癸酸新戊二醇酯、蘋果酸二異硬 脂酯、二-2 -庚基十一酸甘油酯、三羥甲基丙烷三·2_乙基 己酸酯、二經甲基丙院三異硬脂酸醋、四-2_乙基己酸季戊 四醇醋、三-2-乙基己酸甘油酯、三辛酸甘油酯、三異棕櫚 酸甘油醋、二羥甲基丙烷三異硬脂酸酯、2_乙基已酸鯨蠟 -16- 201249475 酯、棕櫚酸2-乙基己酯、三肉豆蔻酸甘油酯、三. 十一酸甘油酯、蓖麻油脂肪酸甲酯、油酸油酯、乙 酯、棕櫚酸2 -庚基-f--烷酯、己二酸二異丁酯、N- 基-L-麩胺酸-2-辛基十二烷酯、己二酸二-2-庚基十 、乙基月桂酸酯、癸二酸二-2-乙基己基、肉豆蔻固 基癸酯、棕櫚酸2 -己基癸酯、己二酸2 -己基癸酯、 二異丙酯、琥珀酸2 -乙基己酯、檸檬酸三乙酯等。 肉豆蔻酸異丙酯爲特佳。在摻合酯油的情況下，其 係以在本發明化妝料中占0.1〜5質量％左右爲佳， 0 · 5〜5質量％，特佳爲1〜3質量％。 另外，在本發明中，進一步爲了減輕在塗佈化 後摩擦等造成化妝料脫妝，亦可摻合（h)油溶性 。油溶性高分子可例示三甲基矽氧基矽酸、烷基變 氧、聚醯胺變性聚矽氧、高聚合二甲基矽氧烷·甲 丙基）矽氧烷共聚物、（丙烯酸/甲基丙烯酸聚三 氧基）共聚物等。該等爲被膜劑成分。其中以三甲 基矽酸爲特佳。在摻合油溶性高分子的情況，係以 明化妝料中占0.1〜4質量％左右爲佳，較佳爲0.5 量％，特佳爲1〜2質量％左右。 在本發明之化妝料中除了上述成分之外，在不 發明之目的及效果的前提下，可因應必要適當地摻 的化妝品所使用的其他成分。這種成分可列舉乳化 類、液體油脂、聚矽氧油、液狀烴油、高級醇、油 劑、油溶性紫外線吸收劑。但是並不受該等例示所P. •2-庚基 酸甘油 月桂醯 —院基 庚2-己 癸二酸 其中， 摻合量 較佳爲 妝料之 高分子 性聚矽 基（胺 甲基砂 基矽氧 在本發 〜3質 損及本 合通常 劑、醇 溶性藥 艮定。 -17- 201249475 乳化劑可例示POE ·甲基聚矽氧烷共聚 分支型POE·甲基聚矽氧烷共聚物、交聯型 氧烷共聚物、烷基· POE共變性甲基聚矽氧 矽氧鏈分支型烷基· POE共變性甲基聚矽氧 油脂肪酸酯、聚甘油脂肪酸酯、聚氧乙二醇 水山梨醇脂肪酸酯、聚氧乙烯去水山梨醇月旨 鏈烷基的聚氧伸烷基變性有機聚矽氧烷、聚 有機聚矽氧烷等。在本發明中，適合使用含 氧伸烷基變性有機聚矽氧烷（ABIL EM90tm 公司製）、聚氧伸烷基變性有機聚矽氧J KF6026 ；信越化學工業公司製）等的HLB6 系乳化劑。 醇類可例示乙醇、異丙醇等的低級醇、 基十二醇、己基癸醇等的高級醇等。 液態油脂可例示例如酪梨油、山茶油、 夷豆油、玉米油、貂油、橄欖油、菜籽油、 油、桃仁油、小麥胚芽油、茶梅油、蓖麻油 紅花油、棉好油、紫蘇油、大豆油、落花生 榧子油、米糠油、白桐油、日本桐油、荷荷 、三甘油等。 聚矽氧油可例示二甲基聚矽氧烷、甲碁 、甲基氫化二烯聚矽氧烷等的鏈狀聚矽氧烷 氧烷、十二甲基聚矽氧烷、四甲基四氫化二 的環狀聚矽氧烷；形成三維網目構造的聚矽 物、聚矽氧鏈 POE ·甲基聚矽 烷共聚物、聚 烷共聚物、甘 脂肪酸酯、去 肪酸酯、含長 氧伸烷基變性 長鏈烷基的聚 ；Goldschmidt 完（KF6017 、 以下的聚矽氧 異硬脂醇、辛 海龜油、夏威 蛋黃油、芝麻 、亞麻仁油、 油、茶籽油、 芭油、胚芽油 苯基聚矽氧烷 :十甲基聚矽 烯聚矽氧烷等 氧樹脂、聚矽 ⑧ -18- 201249475 氧橡膠等。 液狀烴油可例示流動石蠟等。 高級醇可例示月桂醇、肉豆蔻醇、鯨蠟醇、硬脂醇、 山蓊醇、花生醇、鯊肝醇' 鮫肝醇 '巴西棕櫚醇、蠟醇、 高梁醇、蜂花醇、蟲蠟醇、反油醇、異硬脂醯甘油醚、辛 醇、三十烷醇、鯊油醇、鯨蠟硬脂醇、油醇、羊毛脂醇、 氫化羊毛脂醇、己基癸醇、辛基癸醇等。 油溶性藥劑可列舉油溶性的：美白劑、保濕劑、抗發 炎劑、抗菌劑、荷爾蒙劑、維生素類、各種胺基酸及其衍 生物或酵素、抗氧化劑、育毛劑等的藥劑成分。具體而言 可列舉維生素A (=視黃醇）及其衍生物（例如視黃醇醋 酸酯、視黃醇棕櫚酸酯等）、維生素B 2衍生物（例如核 黃素醋酸酯等）、維生素B 6衍生物（例如吡哆醇二辛酸 酯、吡哆醇二棕櫚酸酯、吡哆醇二月桂酸酯等）、維生素 D (=鈣化醇）及其衍生物（例如麥角鈣化醇、膽鈣化醇 等）、維生素E(=生育酚）及其衍生物〔例如維生素E 醋酸酯（=醋酸生育酚）等〕、必須脂肪酸〔例如亞麻油 酸、次亞麻油酸、花生油酸、二十碳五烯酸、二十二碳六 烯酸、及含有該等的植物萃取精華（例如柏子仁等）等〕 、泛醌（=輔酶Q1 〇 )及其衍生物、維生素K類（例如葉 綠醌、甲基萘醌（menaquinone)、甲萘醌（Menadione) 等）、間苯二酚衍生物（例如4-烷基間苯二酚衍生物及/ 或其鹽等）、甘草酸及其衍生物（例如甘草酸硬脂酯等） 、油溶性的維生素C衍生物〔例如維生素c二棕櫚酸酯（ -19- 201249475 =抗壞血酸二棕櫊酸酯）、抗壞血酸硬脂酸酯等〕、類固 醇化合物（例如女性荷爾蒙或男性荷爾蒙等）、菸鹼酸苄 酯（育毛劑成分）、三氯二苯脲（殺菌劑成分）、三氯羥 基二苯醚（防腐劑成分）、γ -穀維素（抗氧化劑成分） 、二丁基羥基甲苯（抗氧化劑成分）等。 油溶性紫外線吸收劑可列舉例如對胺基安息香酸（ PABA ) 、ΡΑΒΑ單甘油酯、Ν，Ν-二丙氧基ΡΑΒΑ乙酯、 Ν,Ν-二乙氧基ΡΑΒΑ乙酯、Ν，Ν-二甲基ΡΑΒΑ乙酯、Ν，Ν-二甲基ΡΑΒΑ 丁酯、二乙基胺基羥基苯甲醯基安息香酸己 酯等的安息香酸系紫外線吸收劑；高孟基-Ν-乙醯基鄰胺 苯甲酸酯等的鄰胺苯甲酸系紫外線吸收劑；水楊酸戊酯、 水楊酸孟酯、水楊酸高孟酯、水楊酸辛酯、水楊酸苯酯、 水楊酸苄酯、對異丙醇苯基水楊酸酯等的水楊酸系紫外線 吸收劑；桂皮酸辛酯、桂皮酸乙基-4-異丙酯、桂皮酸甲 基-2,5-二異丙酯、桂皮酸乙基-2，4-二異丙酯、桂皮酸甲 基-2,4-二異丙酯、桂皮酸丙基對甲氧酯、桂皮酸異丙基對 甲氧酯、桂皮酸異戊基對甲氧酯、桂皮酸辛基對甲氧酯〔 =桂皮酸2-乙基己基對甲氧酯〕、桂皮酸2-乙氧基乙基對 甲氧酯、桂皮酸環己基對甲氧酯、桂皮酸乙基- α-氰基-苯酯、桂皮酸2-乙基己基氰基-yS-苯酯、桂皮酸甘 油單-2-乙基己醯基-二對甲氧酯、3，4,5_三甲氧基桂皮酸 3-甲基-4-〔甲基雙（三甲基矽氧基）甲矽烷基〕丁酯等的 桂皮酸系紫外線吸收劑；2-苯基-5-甲基苯并噁唑、2,2’·羥 基-5-甲基苯基苯并三唑、2-(2·-羥基- 5’-第三辛基苯基） ⑧ -20- 201249475 苯并三唑、2-( 21-羥基- 5，-甲基苯基苯并三唑、二苯甲醛 肼、二大茴香甲醯甲烷、4-第三丁基-4，-甲氧基二苯甲酿 基甲烷、4-( 1，1-二甲基乙基）_4，_甲氧基二苯甲醯基甲院 、5- (3，3-二甲基-2-降冰片亞基）-3_戊-2_酮、奧克立林 (Octocrylene ) 〔 =2-氰基 _3,3-二苯·2-丙烯酸·2·乙基己 酯〕、聚矽氧烷-15〔=二甲基矽酮亞苄基丙二酸二乙酯 〕等。 本發明之化妝料適合作爲油性固形化妝料，特別是粉 底、底妝（base makeup)化妝料來使用。 〔實施例〕 以下列舉實施例’對本發明作進一步具體說明，然而 本發明完全不受這種方式限定。摻合量只要沒有特別記載 全部爲實際分量（質量％)。 〔毛孔遮蔽效果〕 由專家座談會女性參加者（10名）將各試樣塗在臉部 ，針對其毛孔隱蔽效果，基於下述評估基準作評估。 (評估基準） A:8名以上回答毛孔的隱蔽效果優異 B: 5〜7名回答毛孔的隱蔽效果優異 C: 3〜4名回答毛孔的隱蔽效果優異 D: 2名以下回答毛孔的隱蔽效果優異。 〔塡充至容器的適當性〕 -21 - 201249475 將各試樣塡充至容器，對於其塡充的適當性藉由目視 並基於下述評估基準作評估。 (評估基準） A+:容器內塡充後的試樣表面爲凹面（爲了使內容物 不會脫落，理想情況爲設置面積大的凹面形狀） A:容器內塡充後的試樣表面爲水平 B:容器內塡充後的試樣表面爲稍微隆起的程度（工 廠產線容許範圍內） C:容器內塡充後的試樣表面爲隆起 D:容器內塡充後的試樣表面爲隆起，且呈乳霜狀起 尖 〔色紋（分散性）〕 將各試樣塡充至廣口的扁平樹脂容器，冷卻凝固後’ 對於表面的色紋作評估。 (評估基準） A :完全沒有觀察到色紋 B :幾乎沒有觀察到色紋 C :稍微觀察到色紋 D :觀察到色紋 〔使用性（柔軟性、滑順性）〕 由專家座談會女性參加者（1〇名）將各試樣塗在臉部 時，針對試樣的柔軟性、滑順性，基於下述評估基準作評 -22- ⑧ 201249475 估》 (評估基準） A : 8名以上回答柔軟性、滑順性優異 B : 5〜7名回答柔軟性、滑順性優異 C : 3〜4名回答柔軟性、滑順性優異 D : 2名以下回答柔軟性、滑順性優異。 1.針對各粉末成分進行的毛孔隱蔽效果評估 藉由常法調製出下述表1所揭示的試樣1〜8。使用所 調製出的試樣，依據上述評估方法，針對各粉末的毛孔隱 蔽效果作評估。將結果揭示於表1。 -23- 201249475 i谳 試樣8 〇 78.778 CSI m 一 CO i 1 0.002 卜 〇 S 〇 〇 試樣7 〇 68.778 CSJ m CO 1 1 1 1 〇 0.002 卜 〇 0.02 < 試樣6 〇 68.778 CNJ 1/9 CO 1 1 1 1 1 〇 1 0.002 卜 〇 0.02 Q 試樣5 〇 68.778 <M m — CO 1 1 1 1 〇 1 1 0.002 卜 〇 0.02 D 試樣4 〇 r* 68.778 CVI u> 分· eo 1 1 1 〇 1 1 1 0.002 卜 〇 0.02 〇 試樣3 〇 68.778 esi ΙΛ V 1 1 ο 1 1 1 1 0.002 卜 〇 0.02 〇 試樣2 〇 68.778 CM tn 1 〇 1 1 1 1 1 0.002 卜 〇 S 〇 ω 試樣1 〇 68.778 esi ·* U7 CO ο 1 1 1 1 1 1 0.002 卜 〇 0.02 CD 二甲基矽酮 環甲矽脂 肉豆蔻酸異丙酯 微晶蠟 石蠟 倍半異硬脂酸去水山梨醇 二氧化矽 嘁 备盔 购π 1:嵌 mm 11 聚甲基丙烯酸甲酯 耐輪12 硫酸鋇 聚矽氧處理滑石 二甲基硬脂醯銨水輝石 聚矽氧處理的鐵丹 二甲基甲矽烷基化二氧化矽 生育酚 毛孔遮蔽效果 -24- 201249475 由表1的結果，明顯可確認使用本發明之（b)成分 的試樣7與使用以往的粉體的情況相比，毛孔隱蔽效果較 優異。 2 ·實施例1〜1 8、比較例1〜1 4 藉由常法調製出下述表2〜4所示的各試樣。使用所 調製出的試樣，依據上述評估方法，針對各粉末之毛孔隱 蔽效果’塡充適當性、色紋、使用性作評估。將結果揭示 於表2〜4。 此外’在表2〜4中，「二甲基硬脂醯銨水輝石的分散 體」係藉由以在十甲基環五聚矽氧烷中占10質量％的比例 摻合二甲基硬脂醯銨水輝石，將其以同體積加入直徑1mm 左右的玻璃珠（或二氧化鍤珠），並使用漆類攪拌器（淺 田鐵工股份有限公司）、珠磨機（DISPERMAT，VMA-GETZMAN GMBH Verfarenstechnik )等施加機械剪力及 / 或衝撃而薄片化。有機變性黏土礦物粒子的平均厚度爲 Ο.ίμηι以下，平均長徑爲〇5〜5〇μιη。該分散體在表中的 摻合S係以分散體（總量）的摻合量來表示，實際分量以 括弧內的數値來表示。 -25- 201249475 CN谳 實施例 卜 o 54.078 CSI 1 u> 一 u> ψ» CM 〇 1 ! u,® rsi cm 1 0.002 I N- 〇 S 〇 C0 < CQ < CD o 49.078 CSJ kO χη CNJ 〇 1 1 s s 1 0.002 1 卜 Ο S 〇 m < CO < in o 29.078 CM m 兮 CM Ο 1 1 1 1 s 2 0.002 卜 ο 〇 CO < CD < 寸 o CSI 〇 esj 1 u> 一 u> - <SI ο 1 1 1 1 1 1 S6 CW g 〇 卜 ο S 〇 < < CQ οα 比較例 CO o 78.078 CNi 1 m — esi ο 1 1 1 1 1 1 s o o 卜 ο S 〇 ο < ω υ CM o 77.078 CM 1 m 一 u*> - CM Ο I 1 1 1 1 CNJ 1 CsJ O' ◦. o 卜 ο S 〇 CO < CQ α CO o 76.578 CM 1 m — 1/) - CSJ ο 1 1 1 1 1 u> csi 1 CM g o 卜 ο 〇 m < CQ CO 實施例 CM o 76.078 CSJ 1 m m CM Ο 1 1 1 1 1 CO 1 0.002 卜 ο S 〇 CO < ω < o 74.078 CVJ 1 - m 一 CM Ο 1 1 1 1 1 vr> 1 s. o 卜 ο 〇 ω m CQ 0Q 比較例 o 69.078 CM 1 m — U> • ·— CNJ Ο 1 1 1 1 1 ο 1 CNi g o 卜 ο 〇 < 〇 CO Ο 二甲基矽酮 環甲矽脂 肉豆題酸異丙酯 丨三甲基矽氧基矽酸 丨微晶蠟 丨石蠟 丨雙丁基二甲基矽酮聚甘油-3 1異硬脂酸 1二硬脂醯二甲基氯化銨 1棕櫚酸 1二氧化矽 m 嘁 曙故 麵 ]Μ (二甲基矽酮/乙烯二甲基矽酮)交聯聚合物 騮 E- 趙 线 ΐε m B5- 二甲基硬脂醯銨水輝石 + ^ 。_ 淼鋰 If 豳裔 由。 mm 猶嘁 贐诠 mm 1 1 s- 1聚矽氧處理的鐵丹 丨二甲基甲矽烷基化二氧化矽 丨生育酚 担 菘 嫔 m & 豳 m yr) S m s fl- 睇 娣 1色紋份散性)【4階段評估] 使用性(柔軟性、滑順性)丨4階段評估1 -26- 201249475 e谳 實施例1 CM r— 〇〇 25.778 UO 々 LX> m CSJ 〇 1 〇 CO 卜 LD « S 3 ο ο LO ο 3 ο < < < < 比較例 σ> e〇 | 19.278 I - tn i/> oo CSJ ο 〇 ra 卜 U> S3 CSJ Ο Ο m ο 岂 ο < < m 〇 00 oo | 18.978 - - L/» — o 1 1 〇 CO 卜 U) l s 3 csj ο ο LO ο 巨 ο < Q < 〇 卜 0〇 '27.778 m V l CSI Ο 1 〇 fO 卜 U9 1 s 3 S ο ο in ο 目 ο < Q Q < »— 00 27.278 1— r~ m m o CJ ο 1 〇 CQ 卜 U> 1 ° 3 CSJ ο ο to ο 岂 ο < CO ω < 〇 eo 26.778 ir> - ·— CSJ Ο 1 〇 eo 卜 U> 1 s S Ν ο ο m ο ο < < < < 街 佩 σ> oo 26.278 - ·* ir> to esj ο 1 〇 CO 卜 m 1 s 3 csj g ο to ο ο < < < < 〇〇 oo 22.778 - to 一 ir> CM ο 1 〇 CO 卜 m 1 ® 3 岂 ο ο U3 Ο ο < < < < 比較例 CO oo 17.778 - in o ψ— CM ο 1 〇 CO 卜 m 1 s S OJ ο ο in ο g ο < < m ϋ in o 69.078 CM 1 r— LO 一 LO - CSI ο 1 1 1 1 1 1 〇 ^ 产 Csi ο ο r— ο S ο ο + < < 〇 勺· o 59.078 CM 1 LO m - csi ο 1 1 1 1 1 1 s S ο ο h- 〇 S ο C0 < < 〇 圈 m ffi- 11 甲矽脂 丨肉豆蔻酸異丙酯 趑 訟 m 訟 糊 & in 丨微晶蠟 石蠟 cn 账 m β- II 橄 Η » 1異硬脂酸 1二硬脂醯二甲基氯化銨 棕櫚酸 二氧化矽 祕 m i：鬆 匾1 给账 mm Ui (二甲基矽酮/乙烯二甲基矽酮)交聯聚合物 anr mi 饀 裝 E： m El· 嵌 二甲基硬脂醯銨水輝石 余驷 gi c-E 簡 Φ 〇 隨 mm 漏 齡 mm ώ·摊 1 lffl- 聚矽氧處理的鐵丹 嘁 II m B- m Ba il 1生育酚 毛孔遮蔽效果[4階段評估] 在容器中的塡充適當性[5階段評估] 色紋(分散性)[4階段評估] 使用性(柔軟性、滑順性)[4階段評估] -27- 201249475 比較例丨 寸 r- oo 26.478 LO to 〇 CQ 卜 w> 1 ° 3 S O d in ο ο < Q < < 實施例 CO 00 26.378 *-· 1/9 — in 〇 〇 CO 卜 in 1 s S o o m ο ο < < < < 卜 τ— 00 26.278 IA ι/> OJ 〇 1 〇 ΓΟ 卜 in 1 s 3 o o in ο g ο < < < < i〇 *— oo 25.478 - i/9 V u> I" - 1 〇 〇 卜 in 1 s 3 s o o in ο ο < < < < 比較例 CO oo 23.478 ψ— r»» r~ U> U9 CO 1 〇 CO 卜 U7 1 ® 2 CNi o o ι/> Ο s ο < < 〇 〇 CM oo 26.278 vn m 1 CM 〇 〇 CO 卜 m 1 s S CM o o m ο s ο < 〇 C0 < e〇 20.978 m 1 00 1 1 〇 CO N- m 1 S3 s o o m ο ο < 〇 D < o oo 27.278 LO 一 LO 1 <M Ο 1 〇 ro 卜· \n 1 s 3 o o u> ο g ο < 〇 < < 實施例 CO 26.978 W9 tn ΓΟ 〇 CNi Ο 1 〇 «ο 卜 in 1 s δ s o o in ο ο < m < < oo 26.778 in u> U) 〇 CM Ο 1 〇 CO 卜 m 1 ^ 3 csj o o ι/> Ο S ο < < < < ΓΟ oo 26.278 - - ΙΑ l/> CM Ο 1 〇 ΓΟ 卜 u> 1 s S ca o o u> ο ο < < < < 二甲基矽酮 環甲矽脂 丨肉豆蔻酸異丙酯 1三甲基矽氧基矽酸 丨微晶蠟 m 丨雙丁基二甲基矽酮聚甘油-3 1異硬脂酸 1二硬脂醯二甲基氯化銨 1棕櫚酸 1二氧化矽 并 φ ss m 訟 m 匾1 訟嵌 mm 賴 H§ m (二甲基矽酮/乙烯二甲基矽酮)交聯聚合物 丨聚甲基丙烯酸甲酯 二甲基硬脂醯銨水輝石 +a 。_ 豳φ g脈 〇e Φ。 隨 mu 关遐 mm 纆訟 s嵌 tiw mm Μ III· 聚矽氧處理的鐵丹 訟 嘁 11 m & m & 11 生育酚 毛孔遮蔽效果[4階段評估] 在容器中的塡充適當性[5階段評估] 色紋(分散性)[4階段評估] 使用性(柔軟性、滑順性)[4階段評估] -28- 201249475 由表2〜4的結果明顯可知，以既定範圔的摻合量含 有（a )〜（e )成分的實施例1〜1 8的試樣，關於毛孔隱 蔽效果，塡充適當性、色紋、使用性（柔軟性、滑順性） 任一者皆可得到優異的效果。另一方面，缺乏（a )〜（e )成分之任一者，或以脫離本發明範圍的摻合量摻合的比 較例1〜14之試樣，無法同時具備本發明全部的效果。 3_實施例19〜27、實施例13 藉由常法調製出下述表5所揭示的各試樣。使用所調 製出的試樣，依據上述評估方法，針對各粉末之毛孔隱蔽 效果’塡充適當性、色紋、使用性作評估。同時針對添加 (g)成分所產生的「不發生浮粉」的效果，基於下述評估 基準作評估。將結果揭示於表5。 〔不發生浮粉〕 由專家座談會女性參加者（10名）將各試樣塗在臉部 ’針對其不發生浮粉的效果基於下述評估基準作評估。 (評估基準） A: 8名以上回答不發生浮粉的效果優異 B: 5〜7名回答不發生浮粉的效果優異 C: 3〜4名回答不發生浮粉的效果優異 D: 2名以下回答不發生浮粉的效果優異。 -29- 201249475 實施例 CO CO 26.278 U> in csi o η 卜 ® δ 1 0.002 1 m ο S O < < < < < 卜 CM eo 25.278 CVJ 1 1 1 ** - vn ”· m CM 〇 o r· ro 卜 m s S i 0. 002 ΙΛ Ο 3 o < < < < < (D CO 22.278 in 1 - ιο V in ψ·» CM 〇 〇 «ο 卜 m s S 1 0.002 \Λ Ο s o CQ < < < 〇〇 ΙΩ CM CO 24.278 1 1 1 1 1 CO - in ^a* in ·* CNJ o o eo 卜 in ® s 1 0.002 U) Ο s 〇· < < < < υ 勺· CM oO 24.278 1 1 1 1 1 CO 1 - - m ^ar m ·* CNJ o o m 卜 W7 s 3 1 0.002 m ο o < < < < 〇 CO CM co 24.278 1 1 1 1 Γ» 1 1 - 一 ΧΛ esj o o m 卜 tn « 3 [0.002 m Ο s o < < < < 〇 CM CM oo 24.278 1 1 1 1 1 i U) LT> CSI o o 卜 U7 s 3 1 0.002 U9 Ο s o < < < < υ eo 24.278 1 1 1 m 1 1 1 1 m 1/3 csi o CO 卜 u> s 3 1 0.002 1 U> Ο g o < < < < ω 〇 CM eo 24.278 1 CO 1 1 1 1 1 m 对 i/3 CM 〇 o CO h- LO s S \ 0.002 ΙΑ Ο s o < < < < m <J> r~ oo 24.278 ΨΟ 1 1 1 1 1 1 - - m m - csj O o CO Γ— ® s | 0.002 U) Ο s o < < < < < 二甲基矽酮 丨環甲矽脂 丨肉豆蔻酸異丙酯 丨乙基己酸鯨孅酯 丨癸二酸二異丙酯 sg 碱 « E- m 鱷 ίΗ- 1二甲基矽酮6cs 丨二甲基矽酮l〇〇cs sg 訟 账 m 浒 m Β- 三甲基矽氧基矽酸 丨微晶蠟 丨石蠟 1 丨雙丁基二甲基矽酮聚甘油-3 1 饀 m ma lm i 鍇 喊 m i- 11 m 幻m m \〇U © II 1二氧化矽 Sg 嘁 糊 曙盈 mm Η-g 11« ytn /·*~ν <Π 嵌 罃 i 訟 m El· π 裝 K] i 给 m & II 1聚甲基丙烯酸甲酯 +-^ 。_j 艋鋰 ΦΙϋ g脈 由。 随 踱雔 趟祕 mm fri 1 IB- ft m ：s mil 脚 魆 祕 嵌 Λ II 翠 m ss 訟 B- m B- II 窗 毛孔遮蔽效果[4階段評估] 在容器中的塡充適當性[5階段評估] 色紋汾散性)[4階段評估] 使用性(柔軟性、滑順性)[4階段評估] 不發生浮粉的效果[4階段評估]?1 [1 _ [p I ?1 R-Si-I -OSi- I -r2o- •ch2chch2o r2 —SiO-I S' Ri (I) I Ri IL Ri JDIL OH" q IL...J Formula (I) Wherein, Ri represents a linear or branched alkyl group having 1 to 12 carbon atoms, or a phenyl group, R2 represents an alkylene group having 2 to 11 carbon atoms, P is a number of from 1 to 120, and q is 1 to 1. 11 number. The copolymer represented by the above formula (I) can be produced by adding, for example, chloroplatinic acid to a mixture of polyglycerol diallyl ether and mono-terminal hydrogenated dimethylpolyoxane at -12- 8 201249475. The isopropyl alcohol solution was heated and reacted, and an aqueous hydrochloric acid solution was added thereto, and after superheated hydrolysis, sodium hydrogencarbonate water was added thereto, followed by neutralization, purification, and evaporation. However, it is not limited by this manufacturing method. The component (C) is, for example, a blending amount of the cerium (C) component such as dibutyl dimethyl fluorenone polyglycerol-3, which is 0.3 to 8 mass% in the total amount of the cosmetic of the present invention, which is preferably 〇·5~ 6% by mass. In the case of less than 0.3% by mass, when the cosmetic component is heated and melted, the fluidity is low, so that it is difficult to be filled. On the other hand, when it is more than 8% by mass, the makeup is more than 8% by mass. The material becomes prone to color streaks or stickiness. [Component (d)] The cationic surfactant as the component (d) is not particularly limited as long as it can be used as a general cosmetic, and examples thereof include stearin trimethylammonium chloride and cetyl group. Alkane trimethylammonium salt such as trimethylammonium chloride, tetradecyltrimethylammonium chloride or lauryl trimethylammonium chloride, or dioxane such as distearyl dimethylammonium chloride Alkyl dimethyl ammonium salt, chlorinated poly( Ν, Ν'-dimethyl-3,5-methylene piperidinium), alkyl pyridyl chloride, etc. a quaternary ammonium salt, an alkyl dimethyl benzyl ammonium salt, an alkyl isoquinoline iron salt, a dialkyl morpholine key salt, a polyoxyethylene (hereinafter) alkylamine, an alkylamine salt, a polyamine fatty acid derivative, A pentanol fatty acid derivative, Benzalkonium Chloride, Benzethonium Chloride, or the like. However, it is not subject to these illustrations -13- 201249475. One or two or more kinds of the components (d) can be used. The blending amount of the component (d) is 0.1 to 2% by mass, preferably 0.1 to 1.5% by mass, based on the total amount of the cosmetic of the present invention. In the case of less than 1% by mass, when the container is heated and melted, it is in a state of low fluidity, so that it is difficult to replenish and, in the case of more than 2% by mass. The cosmetic material becomes heavy at the time of spreading, and the usability tends to be deteriorated [(e) component] (e) The component is a branched saturated fatty acid having 14 to 24 carbon atoms (preferably 16 to 22). Specific examples thereof include isomyristate, isopentadecanoic acid, isopalmitic acid, isostearic acid, isoaranic acid, isobehenic acid and the like. It should be iso-stearic acid. The component (e) may be used alone or in combination of two or more. In the present invention, when a linear saturated fatty acid or a branched unsaturated fatty acid is used instead of the component (e), the cosmetic is hardened in a state of high viscosity, and it becomes difficult to fill the container. The blending amount of the component (e) is from 2 to 7% by mass in the total amount of the cosmetic of the present invention, and is preferably from 0.5 to 5% by mass. In the case of less than 5% by mass, when the container is filled with a container, even if the cosmetic component is heated and melted, the fluidity is low, so that it is difficult to charge. On the other hand, when it exceeds 7 mass% The cosmetic material is prone to color streaks or stickiness. In the present invention, from the viewpoint of preventing color bleeding, it is preferred to blend with a blend ratio of (d) component: (e) component = 1: 15 to 3: 5 (mass ratio). -14- 201249475 The cosmetic of the present invention is a solid preparation containing the above components (a) to (e) as essential components. In the past, it has been difficult to blend the component (b) in a large amount, and if it is blended in a large amount, there is a disadvantage that the phenomenon such as oil slick is likely to occur in the cream base. In the present invention, by using a combination of three components of a dosage form as a solid or a component (c) to (e) as a dispersing agent, these disadvantages can be overcome and at the same time, the component (b) can be produced. The pore concealment effect is further improved. Further, by the thickening effect of the component (b), a soft and smooth feeling of use can be exhibited. Further, when the component (b) is used as the dispersion in the oil, the hardness of the preparation can be more effectively suppressed from becoming too high. Therefore, it is easy to take out the cosmetic from the container by hand during use, and it is also possible to exert It is easy to apply such an effect. In the present invention, in addition to the above-mentioned essential components, a powder component which can be further blended (f) is further added. By blending the component (f), the pore concealing effect can be further improved. The powder component is not particularly limited as long as it is generally blendable with a cosmetic, and examples thereof include spherical cerium oxide, spherical polyethylene, and polyamide globular resin powder (nylon spherical powder). a spherical powder such as a poly(methyl) acrylate spherical resin powder, or an extender pigment such as talc, mica, kaolin, sericite, calcium carbonate or magnesium carbonate, or a dimethyl fluorenone cross-linked polymer, (dimethyl ketone/ethylene dimethyl fluorenone) crosslinked polymer, polymer polyoxynized powder such as polymethylsesquioxane, polyethylene, polymethyl methacrylate, metal soap, etc. . However, it is not limited by these illustrations. The component (f) may be used singly or in combination of two or more kinds, and the surface of the powder may be left untreated. In the case of blending the component (f), from the viewpoint of pore concealing effect, usability -15-201249475, etc., the blending amount thereof is set to be 10 to 30% by mass in the total amount of the cosmetic of the present invention. Preferably, it is preferably 20 to 30% by mass. Further, the solid oily cosmetic of the present invention is cured by crystallization of the wax, and therefore it is desirable that the blending does not cause a component which hinders the wax from being crystallized. Examples of such a component include an oil colloidalizing agent (for example, a dextrin-based oily polymer ("Rheopearl KL"; manufactured by Chiba Powder Co., Ltd.) or the like. In the present invention, in order to suppress the "foaming" phenomenon, (g) ester oil may be blended. "Floating powder" refers to a phenomenon in which volatile oil (polyoxygenated oil, etc.) is volatilized after the application of the cosmetic material, and the powder floats in white. In particular, in the case where a large amount of spherical powder is blended, when the volatile oil is added, the refractive index of the surface of the powder rises. The difference in refractive index between the skin and the surface of the powder increases, and white floating matter is observed. By blending the component (g), the floating phenomenon can be effectively suppressed. The ester oil can be exemplified by, for example, isopropyl myristate, cetyl octanoate, octyl myristate lauryl, isopropyl palmitate, butyl stearate, hexyl laurate, myristate myristate, Oxal oleate, hexyl decyl octyl decyl phthalate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, 12-hydroxystearate Acid cholesterol ester, ethylene glycol di-2-ethylhexanoate, fatty acid ester of dipentaerythritol, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisobutyl malate Lipoester, di-2-heptyldecanoic acid glyceride, trimethylolpropane tris-2-ethylhexanoate, dimethicone triisostearic acid vinegar, tetra-2_ethylhexyl Acid pentaerythritol vinegar, tris-2-ethylhexanoic acid glyceride, tricaprylin, triisopalmitic acid glycerin, dimethylolpropane triisostearate, 2-ethylhexanoic acid cetyl-16- 201249475 Ester, 2-ethylhexyl palmitate, glyceryl trimyristate, tridecyl glycerate, castor oil fatty acid methyl ester, oleic acid oil ester, ethyl ester, palmitic acid 2-heptyl-f- -alkyl , diisobutyl adipate, N-yl-L-glutamic acid-2-octyl dodecyl ester, di-2-heptyl adipate, ethyl laurate, sebacic acid di- 2-ethylhexyl, nutmeg solid decyl ester, 2-hexyl decyl palmitate, 2-hexyl decyl adipate, diisopropyl ester, 2-ethylhexyl succinate, triethyl citrate, etc. . Isopropyl myristate is particularly preferred. In the case of blending the ester oil, it is preferably from 0.1 to 5% by mass in the cosmetic of the invention, from 0 to 5 to 5% by mass, particularly preferably from 1 to 3% by mass. Further, in the present invention, in order to reduce makeup discoloration caused by friction or the like after coating, it is also possible to blend (h) oil solubility. The oil-soluble polymer may, for example, be trimethylphosphonium decanoic acid, alkyloxy oxygen, polydecylamine-denatured polyfluorene, high-polymerized dimethyloxane-methylpropyl) decane copolymer, (acrylic acid/ A polytrimethylene methacrylate copolymer or the like. These are the components of the film. Among them, trimethyl phthalic acid is particularly preferred. In the case of blending the oil-soluble polymer, it is preferably about 0.1 to 4% by mass, more preferably 0.5% by weight, particularly preferably about 1 to 2% by mass, based on the cosmetic. In addition to the above-described components, the cosmetic of the present invention may be used in accordance with the purpose and effect of the invention, and may be appropriately blended with other components used in the cosmetic. Examples of such a component include emulsifiers, liquid fats and oils, polyoxygenated oils, liquid hydrocarbon oils, higher alcohols, oils, and oil-soluble ultraviolet absorbers. However, it is not subject to the above-mentioned examples. P. • 2-heptyl glycerol, lauryl hydrazone, and hexyl hexyl 2-hexanoic acid. Among them, the blending amount is preferably a polymeric poly(fluorenyl) group. The sand-based oxime is determined in the present invention. The emulsifier can exemplify the POE-methyl polyoxane copolymerized branched POE·methyl polyoxane. Copolymer, crosslinked oxyalkylene copolymer, alkyl POE co-denatured methyl polyfluorene oxide chain branched alkyl POE co-denatured methyl polyoxylate fatty acid ester, polyglycerin fatty acid ester, poly Oxyethylene glycol sorbitan fatty acid ester, polyoxyethylene sorbitan sorbitol, polyoxyalkylene-denatured polyalkylene oxide, polyorganopolyoxyalkylene, etc. In the present invention, suitable An HLB6-based emulsifier such as an oxygen-containing alkylene-denatured organopolyoxane (manufactured by ABIL EM90mm Co., Ltd.), a polyoxyalkylene-denatured organic polyfluorene J KF6026, or a Shin-Etsu Chemical Co., Ltd. product. The alcohol may, for example, be a lower alcohol such as ethanol or isopropyl alcohol, a higher alcohol such as decyl alcohol or hexyl decyl alcohol. The liquid fat can be exemplified by, for example, avocado oil, camellia oil, soybean oil, corn oil, oyster sauce, olive oil, rapeseed oil, oil, peach kernel oil, wheat germ oil, tea plum oil, castor oil safflower oil, cotton oil, Perilla oil, soybean oil, groundnut hazelnut oil, rice bran oil, white tung oil, Japanese tung oil, jojo, triglycerin, etc. The polyoxyxane oil may, for example, be a chain polyoxyalkoxy alkane such as dimethyl polyoxyalkylene, formamidine or methyl hydrogenated diene polyoxyalkylene, dodecyl polyoxyalkylene or tetramethyltetra Hydrogenated two cyclic polyoxane; polyfluorene forming a three-dimensional network structure, polyoxynoxy chain POE methyl polydecane copolymer, polyalkylene copolymer, sweet fatty acid ester, defatty acid ester, containing long oxygen Polyalkylene-denatured long-chain alkyl group; Goldschmidt finish (KF6017, below polyoxyl isostearyl alcohol, citrus turtle oil, Xiawei egg butter, sesame, linseed oil, oil, tea seed oil, beach oil, Germ oil phenyl polyoxane: oxygen resin such as decamethyl polydecene polyoxane, polyfluorene 8 -18- 201249475 oxygen rubber, etc. Liquid hydrocarbon oil can be exemplified by flowing paraffin, etc. Higher alcohol can be exemplified by lauryl alcohol , myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, arachidyl alcohol, squalyl alcohol 鲛 heparin's palmitol, wax alcohol, sorghumol, bee, alginol, linalool, Isostearyl glycerol ether, octanol, triacontanol, squalene alcohol, cetearyl alcohol, oleyl alcohol, lanolin alcohol, hydrogenated wool Alcohol, hexyl sterol, octyl decyl alcohol, etc. Oil-soluble agents can be listed as oil-soluble: whitening agents, moisturizers, anti-inflammatory agents, antibacterial agents, hormones, vitamins, various amino acids and their derivatives or A pharmaceutical ingredient such as an enzyme, an antioxidant, a hair growth agent, etc., specifically, vitamin A (=retinol) and derivatives thereof (for example, retinol acetate, retinyl palmitate, etc.), vitamin B 2 derived (eg, riboflavin acetate, etc.), vitamin B 6 derivatives (eg, pyridoxine dicaprylate, pyridoxine dipalmitate, pyridoxal dilaurate, etc.), vitamin D (=calciferol) And its derivatives (such as ergocalciferol, cholecalciferol, etc.), vitamin E (= tocopherol) and its derivatives (such as vitamin E acetate (=tocopherol acetate), etc., essential fatty acids (such as linseed oil) Acid, linoleic acid, peanut oleic acid, eicosapentaenoic acid, docosahexaenoic acid, and plant extracts (such as cypress seeds), etc., ubiquinone (=Coenzyme Q1 〇) And its derivatives, vitamin K (such as chlorophyllin , menaquinone, menadione, etc., resorcinol derivatives (such as 4-alkyl resorcinol derivatives and / or their salts), glycyrrhizic acid and its derivatives (eg stearyl glycyrrhizinate, etc.), oil-soluble vitamin C derivatives (eg vitamin c dipalmitate (-19-201249475 = ascorbyl dipalmitate), ascorbyl stearate, etc.), steroid compounds ( For example, female hormones or male hormones, etc., benzyl nicotinic acid (hair-care component), trichlorodiphenyl urea (biocide component), trichlorohydroxydiphenyl ether (preservative component), γ-oryzanol (antibiotic) The oxidizing agent component), dibutylhydroxytoluene (antioxidant component), etc. The oil-soluble ultraviolet absorber may, for example, be an amino benzoic acid (PABA), hydrazine monoglyceride, hydrazine, hydrazine-dipropoxy fluorene ethyl ester, Ν, Ν-diethoxy oxime ethyl ester, hydrazine, hydrazine-dimethyl hydrazine ethyl ester, hydrazine, hydrazine-dimethyl butyl butyl ester, diethylamino hydroxy benzoyl benzoic acid hexyl ester, etc. Benzoic acid ultraviolet absorber; Gao Mengji-Ν-B An ortho-benzoic acid-based ultraviolet absorber such as anthranilic acid benzoate; amyl salicylate, maleic acid salicylate, high-monmonyl salicylate, octyl salicylate, phenyl salicylate, salicylate Salicylic acid-based ultraviolet absorbers such as benzyl acetate and p-isopropanol phenylsalicylate; octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diiso-cinnamic acid Propyl ester, ethyl 2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl methoxy citrate, isopropyl p-methoxy-p-methoxy ester, Isoamyl octyl citrate, octyl p-methoxy cinnamate [ = 2-ethylhexyl p-methoxy cinnamate), 2-ethoxyethyl p-methoxy cinnamate, cyclohexyl cinnamate P-methoxy ester, ethyl-α-cyano-phenyl cinnamate, 2-ethylhexyl cyano-yS-phenyl cinnamate, glycerol mono-2-ethylhexyl-di-methoxy A cinnamic acid-based ultraviolet absorber such as ester, 3,4,5-trimethoxycinnamic acid 3-methyl-4-[methylbis(trimethyldecyloxy)carbenyl]butyl phthalate; 2-benzene 5-methylbenzoxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole , 2-(2·-hydroxy-5'-t-octylphenyl) 8 -20- 201249475 benzotriazole, 2-( 21-hydroxy-5,-methylphenylbenzotriazole, diphenyl Formaldehyde oxime, fennel methymethane, 4-tert-butyl-4,-methoxydibenzoylmethane, 4-(1,1-dimethylethyl)_4,_methoxy Benzoquinone, 5-(3,3-dimethyl-2-norbornyl)-3_pent-2-one, Octocrylene [=2-cyano_3, 3-Diphenyl·2-acrylic acid·2-ethylhexyl ester], polyoxyalkylene-15 [=dimethyl ketone ketobenzylidene malonate], and the like. The cosmetic of the present invention is suitably used as an oily solid cosmetic, particularly a foundation or base makeup cosmetic. [Examples] The present invention will be further specifically described by the following examples, but the present invention is not limited at all. The blending amount is an actual component (% by mass) unless otherwise specified. [Pore occlusion effect] Each sample was applied to the face by a female participant (10 members) of the expert symposium, and the pore concealing effect was evaluated based on the following evaluation criteria. (Evaluation Criteria) A: 8 or more people answered the pores with excellent concealing effect B: 5 to 7 people answered the pores with excellent concealing effect C: 3 to 4 people answered the pores with excellent concealing effect D: 2 or less answered pores with excellent concealing effect . [Adequacy of filling into a container] -21 - 201249475 Each sample was filled into a container, and the appropriateness of the filling was evaluated by visual observation and based on the following evaluation criteria. (Evaluation Criteria) A+: The surface of the sample after filling in the container is concave (in order to prevent the contents from falling off, it is ideal to set a concave shape with a large area) A: The surface of the sample after filling in the container is horizontal B : The surface of the sample after filling in the container is slightly raised (within the allowable range of the factory line) C: The surface of the sample after filling in the container is raised D: The surface of the sample after filling in the container is raised. The creamy shape was sharpened (color pattern (dispersibility)] Each sample was filled into a wide-mouth flat resin container, and after cooling and solidification, the surface color tone was evaluated. (Evaluation criteria) A: No color pattern was observed at all B: No color pattern was observed C: A slight color pattern was observed D: Color pattern was observed (usability (softness, smoothness)] by expert panel women Participants (1〇) applied the samples to the face, and evaluated the softness and smoothness of the sample based on the following evaluation criteria. -22-8 201249475 (Evaluation Criteria) A : 8 The above answer is excellent in softness and smoothness. B: 5 to 7 people have excellent flexibility and smoothness. C: 3 to 4 people have excellent flexibility and smoothness. D: 2 or less answers are excellent in flexibility and smoothness. . 1. Evaluation of pore concealing effect for each powder component Samples 1 to 8 disclosed in Table 1 below were prepared by a usual method. Using the prepared sample, the pore concealing effect of each powder was evaluated in accordance with the above evaluation method. The results are disclosed in Table 1. -23- 201249475 i谳 sample 8 〇78.778 CSI m-CO i 1 0.002 〇S 〇〇 sample 7 〇68.778 CSJ m CO 1 1 1 1 〇0.002 〇 0.02 < sample 6 〇68.778 CNJ 1/ 9 CO 1 1 1 1 1 〇1 0.002 〇 0.02 Q Sample 5 〇68.778 <M m — CO 1 1 1 1 〇1 1 0.002 〇 0.02 D Sample 4 〇r* 68.778 CVI u> Points · eo 1 1 1 〇1 1 1 0.002 〇 0.02 〇 sample 3 〇 68.778 esi ΙΛ V 1 1 ο 1 1 1 1 0.002 〇 0.02 〇 sample 2 〇 68.778 CM tn 1 〇 1 1 1 1 1 0.002 〇 〇 〇ω Sample 1 〇68.778 esi ·* U7 CO ο 1 1 1 1 1 1 0.002 〇 0.02 CD dimethyl fluorenone cyclomethicone isopropyl myristate microcrystalline wax paraffin sesquiisostearic acid Water sorbitol cerium oxide helmets purchased π 1: embedded mm 11 polymethyl methacrylate resistant round 12 sulphate sulphide poly oxime treatment talc dimethyl stearic acid ammonium hectorite polyoxo treated iron dan Methyl hydrazine alkylation cerium oxide tocopherol pore blocking effect-24- 201249475 From the results of Table 1, it is apparent that the use of the (b) component of the present invention The sample 7 was superior in the pore concealing effect as compared with the case of using the conventional powder. 2·Examples 1 to 18, Comparative Examples 1 to 1 4 Each sample shown in the following Tables 2 to 4 was prepared by a usual method. Using the prepared sample, according to the above evaluation method, the pore concealing effect of each powder was evaluated as appropriateness, color tone, and usability. The results are disclosed in Tables 2 to 4. Further, in Tables 2 to 4, "dispersion of dimethyl stearin ammonium hectorite" is obtained by blending dimethyl hard in a ratio of 10% by mass in decamethylcyclopentasiloxane. Ammonium sulphate hectorite, which is added to the same volume of glass beads (or cerium oxide beads) with a diameter of about 1 mm, and uses a paint agitator (Asada Iron Works Co., Ltd.) and a bead mill (DISPERMAT, VMA-GETZMAN) GMBH Verfarenstechnik), etc., is applied by mechanical shearing and/or scouring. The average thickness of the organically modified clay mineral particles is Ο.ίμηι or less, and the average long diameter is 〇5~5〇μιη. The blended S in the table is represented by the blending amount of the dispersion (total amount), and the actual component is represented by the number in the brackets. -25- 201249475 CN谳Examples o 54.078 CSI 1 u> One u> ψ» CM 〇1 ! u,® rsi cm 1 0.002 I N- 〇S 〇C0 < CQ < CD o 49.078 CSJ kO χη CNJ 〇1 1 ss 1 0.002 1 Ο Ο S 〇m < CO < in o 29.078 CM m 兮CM Ο 1 1 1 1 s 2 0.002 οο 〇CO < CD < inch o CSI 〇esj 1 u>u> - <SI ο 1 1 1 1 1 1 S6 CW g 〇卜ο S 〇<< CQ οα Comparative Example CO o 78.078 CNi 1 m — esi ο 1 1 1 1 1 1 soo 卜ο S 〇ο < ω υ CM o 77.078 CM 1 m a u*> - CM Ο I 1 1 1 1 CNJ 1 CsJ O' ◦. o 卜ο S 〇CO < CQ α CO o 76.578 CM 1 m — 1/) - CSJ ο 1 1 1 1 1 u> csi 1 CM go ο 〇m < CQ CO Example CM o 76.078 CSJ 1 mm CM Ο 1 1 1 1 1 CO 1 0.002 οο 〇CO < ω < o 74.078 CVJ 1 - m CM Ο 1 1 1 1 1 vr> 1 s. o οο 〇ω m CQ 0Q Comparative example o 69.078 CM 1 m — U> • · — CNJ Ο 1 1 1 1 1 ο 1 CNi Go 卜ο 〇< 〇CO Ο dimethyl fluorenone ring armor Isopropyl isopropyl trimethyl sulfonate ruthenium phthalate microcrystalline wax 丨 paraffin 丨 butyl dimethyl fluorenone polyglycerol-3 1 isostearic acid 1 distearyl dimethyl ammonium chloride 1 Palmitic acid 1 cerium oxide m 嘁曙 嘁曙 face] Μ (dimethyl ketone / ethylene dimethyl fluorenone) crosslinked polymer 骝 E- Zhao line ΐ ε m B5- dimethyl stearin ammonium hectorite + ^. _ 淼 Li If If 豳 by. Mm 嘁赆 嘁赆 mm 1 1 s- 1 polyoxygenated iron 丨 dimethyl dimethyl hydrazine alkylated cerium oxide tocopherol 菘嫔 m & 豳m yr) S ms fl- 睇娣 1 color Diffuse dispersibility) [4-stage evaluation] Usability (softness, smoothness) 丨 4-stage evaluation 1 -26- 201249475 e谳Example 1 CM r—〇〇25.778 UO 々LX> m CSJ 〇1 〇CO LD « S 3 ο ο LO ο 3 ο <<<< Comparative Example σ > e〇| 19.278 I - tn i/> oo CSJ ο 〇ra 卜 U> S3 CSJ Ο Ο m ο 岂ο << m 〇00 oo | 18.978 - - L/» — o 1 1 〇CO 卜 U) ls 3 csj ο ο LO ο ο ο Q < 〇 〇 0〇 '27.778 m V l CSI Ο 1 〇fO 卜U9 1 s 3 S ο ο in ο 目ο < QQ < » 00 27.278 1— r~ mmo CJ ο 1 〇CQ 卜 U> 1 ° 3 CSJ ο ο to ο 岂ο < CO ω < 〇eo 26.778 ir> - · - CSJ Ο 1 〇eo 卜 U> 1 s S Ν ο ο m ο ο <<<< Street σ σ> oo 26.278 - ·* ir> to esj ο 1 〇CO 卜 m 1 s 3 csj g ο to ο ο <<< &l t; 〇〇oo 22.778 - to one ir> CM ο 1 〇CO 卜 m 1 ® 3 岂ο ο U3 Ο ο <<<< Comparative example CO oo 17.778 - in o ψ - CM ο 1 〇CO m m s S OJ ο ο in ο g ο << m ϋ in o 69.078 CM 1 r- LO a LO - CSI ο 1 1 1 1 1 1 〇^ Production Csi ο ο r- ο S ο ο + << 〇 spoon · o 59.078 CM 1 LO m - csi ο 1 1 1 1 1 1 s S ο ο h- 〇S ο C0 << 〇 m m ffi- 11 矽 丨 丨 丨 丨 蔻Propyl ester 趑 litigation paste & in 丨 microcrystalline wax paraffin cn accounts m β- II olives » 1 isostearic acid 1 distearyl dimethyl ammonium chloride palmitic cerium dioxide secret mi: pine mites 1 Accounted mm Ui (dimethyl ketone / ethylene dimethyl fluorenone) cross-linked polymer anr mi armored E: m El · embedded dimethyl stearin ammonium hectorite 驷 c c Φ 〇 Mm Leakage mm ώ·1 1 lffl- Polyoxygenated iron 嘁 II m B- m Ba il 1 Tocopherol pore shading effect [4 stages evaluation] 适当 filling appropriateness in the container [5 stage evaluation] Grain (dispersibility) [4-stage evaluation] usability (softness, smoothness) ) [4-stage evaluation] -27- 201249475 Comparative example r r- oo 26.478 LO to 〇CQ 卜 w> 1 ° 3 SO d in ο ο < Q << Example CO 00 26.378 *-· 1/ 9 — in 〇〇CO 卜 in 1 s S oom ο ο <<<< 卜 τ — 00 26.278 IA ι/> OJ 〇1 〇ΓΟ 卜 in 1 s 3 oo in ο g ο <<<< i〇*— oo 25.478 - i/9 V u>I" - 1 in in 1 s 3 soo in ο ο <<<<< Comparative example CO oo 23.478 ψ — r» » r~ U> U9 CO 1 〇CO 卜 U7 1 ® 2 CNi oo ι/> Ο s ο << 〇〇CM oo 26.278 vn m 1 CM 〇〇CO 卜 m 1 s S CM oom ο s ο < 〇C0 < e〇20.978 m 1 00 1 1 〇CO N- m 1 S3 soom ο ο < 〇D < o oo 27.278 LO a LO 1 <M Ο 1 〇ro 卜 · \n 1 s 3 oo u> ο g ο < 〇 << Example CO 26.978 W9 tn ΓΟ 〇CNi Ο 1 〇«ο 卜 in 1 s δ soo in ο ο < m << oo 26.778 in u> U ) 〇 CM Ο 1 〇CO 卜 m 1 ^ 3 csj oo ι/> Ο S ο <<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<>矽 丨 丨 myristate isopropyl ester 1 trimethyl hydroxy citrate 丨 microcrystalline wax m 丨 bis butyl dimethyl fluorenone poly glycerol-3 1 isostearic acid 1 distearyl dimethyl chloride Ammonium 1 palmitic acid 1 cerium oxide and φ ss m law m 匾 1 affixed mm 赖 H § m (dimethyl ketone / ethylene dimethyl fluorenone) cross-linked polymer 丨 polymethyl methacrylate II Methyl stearin ammonium hectorite + a. _ 豳φ g pulse 〇e Φ. With mu 遐mm 纆 s ti tiw mm Μ III· 矽 矽 铁 嘁 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 5-stage evaluation] Color pattern (dispersion) [4-stage evaluation] Usability (softness, smoothness) [4-stage evaluation] -28- 201249475 It is apparent from the results of Tables 2 to 4 that the blending with the established range The samples of Examples 1 to 18 containing the components (a) to (e) in combination may have any effect on the pore concealing effect, the appropriateness of the filling, the color tone, and the usability (softness and smoothness). Get excellent results. On the other hand, the absence of any of the components (a) to (e) or the samples of Comparative Examples 1 to 14 blended with the blending amount excluding the scope of the present invention cannot simultaneously provide all the effects of the present invention. 3 - Examples 19 to 27, and Example 13 Each sample disclosed in Table 5 below was prepared by a usual method. Using the prepared sample, the pore concealing effect of each powder was evaluated according to the above evaluation method, and the appropriateness, color pattern, and usability were evaluated. At the same time, the effect of "no floating powder" generated by adding (g) components is evaluated based on the following evaluation criteria. The results are disclosed in Table 5. [No floating powder occurred] Female participants in the expert panel (10) applied each sample to the face. The effect of not floating powder was evaluated based on the following evaluation criteria. (Evaluation criteria) A: 8 or more people answered that the effect of floating powder is not good. B: 5 to 7 people answered that the effect of floating powder is not good. C: 3 to 4 people answered that the effect of floating powder is not good. D: The following two answers do not occur. The effect of the floating powder is excellent. -29- 201249475 Example CO CO 26.278 U> in csi o η 卜 ® δ 1 0.002 1 m ο SO <<<<<< CM eo 25.278 CVJ 1 1 1 ** - vn ”· m CM 〇or· ro 卜ms S i 0. 002 ΙΛ Ο 3 o <<<<<< (D CO 22.278 in 1 - ιο V in ψ·» CM 〇〇«ο 卜 ms S 1 0.002 \Λ Ο so CQ <<< lt Ω CM CO 24.278 1 1 1 1 1 CO - in ^a* in · * CNJ oo eo 卜 in ® s 1 0.002 U) Ο s 〇 · <<<< 勺 spoon · CM oO 24.278 1 1 1 1 1 CO 1 - - m ^ar m ·* CNJ oom Bu W7 s 3 1 0.002 m ο o <<<< 〇CO CM co 24.278 1 1 1 1 Γ» 1 1 - 一ΧΛ esj oom 卜tn « 3 [0.002 m Ο so <<<< 〇CM CM oo 24.278 1 1 1 1 1 i U) LT> CSI oo Bu U7 s 3 1 0.002 U9 Ο so <<<<< lt eo 24.278 1 1 1 m 1 1 1 1 m 1/3 csi o CO ub u> s 3 1 0.002 1 U> Ο go <<<< ω 〇CM eo 24.278 1 CO 1 1 1 1 1 m to i/3 CM 〇o CO h- LO s S \ 0.002 ΙΑ Ο so <<<< m <J> r~ oo 24.278 ΨΟ 1 1 1 1 1 1 - - mm - csj O o CO Γ— ® s | 0.002 U) Ο so <<<<<<矽 矽 丨 丨 矽 矽 丨 丨 丨 丨 丨 丨 丨 丨 丨 丨 丨 « « « « « « « « « « « « « « « « « « « « « « « « « « « « « « « « « « Ketone ketone l〇〇cs sg liability account m 浒m Β- trimethyl methoxy phthalate bismuth microcrystalline wax 丨 paraffin 1 丨 bis butyl dimethyl fluorenone polyglycerol-3 1 饀m ma lm i 锴Shout m i- 11 m 幻mm \〇U © II 1 二2矽 g paste 曙 mm mm Η-g 11« ytn /·*~ν <Π 罃 罃 i litigation m El· π 装 K] i give m & II 1 polymethyl methacrylate +-^. _j 艋 Lithium ΦΙϋ g pulse by. With the secret mm fri 1 IB- ft m : s mil 魆 魆 Λ II II II II II II II II II II II II II II II II II II II II II II II II II II II II II II Stage evaluation] Color smear) [4-stage evaluation] Usability (softness, smoothness) [4-stage evaluation] Effect of no floating powder [4-stage evaluation]
(D -30- 201249475 由表5所揭示的結果，明顯可知以本發明的摻合量範 圍含有（a)〜（e)成分的實施例19〜27、13之試樣， 關於毛孔隱蔽效果，塡充適當性、色紋、使用性（柔軟性 、滑順性），任一者皆可得到優異的效果。除了（ a )〜 (e)成分之外，進一步摻合（g)成分的實施例19〜21、 26〜17、13之試樣，除了可得到上述效果，還加上可進一 步得到「不發生浮粉」效果。 4 .實施例1 3、實施例2 8〜2 9 藉由常法調製出下述表6所揭示的各試樣。使用所調 製的試樣，依據上述評估方法，針對各粉末的毛孔隱蔽效 果’塡充適當性、色紋、使用性作評估。同時針對添加（ h)成分所產生的「不脫妝」的效果，基於下述評估基準作 評估。將結果揭示於表5。 〔不脫妝〕 由專家座談會女性參加者（10名）將各試樣塗在臉部 ，針對其不脫妝的效果基於下述評估基準作評估。 (評估基準） A: 8名以上回答不脫妝的效果優異 B: 5〜7名回答不脫妝的效果優異 C: 3〜4名回答不脫妝的效果優異 D:2名以下回答不脫妝的效果優異。 -31 - 201249475 表6(D -30-201249475 From the results disclosed in Table 5, it is apparent that the samples of Examples 19 to 27 and 13 containing the components (a) to (e) in the blending amount range of the present invention, regarding the pore concealing effect, Excellent performance, color tone, usability (softness, smoothness), and excellent results can be obtained. In addition to (a) to (e) components, further blending of (g) components is carried out. In the samples of Examples 19 to 21, 26 to 17, and 13, in addition to the above effects, the effect of "no floating powder" was further obtained. 4. Example 1 3, Example 2 8 to 2 9 The respective samples disclosed in the following Table 6 were prepared by using the prepared sample, and the pore concealing effect of each powder was evaluated according to the above-mentioned evaluation method, and the appropriateness, color pattern, and usability were evaluated. The effect of "no makeup" produced by (h) ingredients is evaluated based on the following evaluation criteria. The results are shown in Table 5. [No makeup] Female participants (10 people) from the expert symposium will take each sample Applying to the face, the effect of not removing makeup is evaluated based on the following evaluation criteria. (Evaluation criteria) A: 8 or more people answered that the effect of makeup is excellent. B: 5 to 7 people answered that the effect of makeup is excellent. C: 3 to 4 people answered that the effect of not removing makeup is excellent. D: 2 or less answers are not taken off. The effect of makeup is excellent. -31 - 201249475 Table 6
實施例 13 28 29 二甲基矽酮 8 8 8 環甲矽脂 26.278 26.278 26.278 肉豆蔻酸異丙酯 1 1 1 三甲基较氧基较酸 1 — -* 高聚合二甲基矽氧烷·甲基(胺丙基)矽氧烷共聚物 1 - (丙烯酸/甲基丙烯酸聚三甲基矽氧基)共聚物 一 一 1 微晶蠟 1 1 1 石蠟 4.5 4.5 4.5 雙丁基二甲基矽酮聚甘油-3 1.5 1.5 1.5 異硬脂酸 1 1 1 二硬脂醯二甲基氯化銨 0.2 0.2 0.2 二氧化矽 10 10 10 (乙烯二甲基矽酮/甲基矽氧烷倍半矽氧烷)交聯聚合物 3 3 J (二甲基矽酮/乙烯二甲基矽SM)交聯聚合物 7 7 7 聚甲基丙烯酸甲酯 5 5 5 二甲基硬脂醞銨水輝石分散體 30 30 30 (10%分散體。+甲某環五聚矽氬垸稀釋。栝弧內爲窗際分罱） (3) ⑶ (3) 聚矽氧處理的鐵丹 0.002 0.002 0.002 二甲基甲矽烷基化二氧化矽 0.5 0.5 0.5 生育酚 0.02 0.02 0.02 毛孔遮蔽效果[4階段評估] A A A 塡充適當性[5階段評估] A A A 色紋(分散性)[4階段評估] A A A 使用性(柔軟性、滑順性)[4階段評估] A A A 不脫妝的效果[4階段評估1 A B B 由表6所揭示的結果，明顯可知以本發明的摻合量範 圍含有（a)〜（e)成分，進一步添加（h)成分的實施 例1 3、28〜29之試樣任一者皆可得到毛孔隱蔽效果，塡 充適當性、色紋、使用性（柔軟性、滑順性）之效果，還 加上可進一步得到「不脫妝」的效果。 產業上的可利用性 本發明之油性固形化妝料相較於以往的球狀粉末所產 生的毛孔遮蔽效果，具有更優異的毛孔遮蔽效果，進一步 ⑧ -32- 201249475 容易製劑化成爲適當的硬度，不會發生色紋，使用性（柔 軟性、滑順性）亦優異。 -33 -Example 13 28 29 Dimethyl fluorenone 8 8 8 cyclomethicone 26.278 26.278 26.278 Isopropyl myristate 1 1 1 Trimethyl methoxy group is more acidic than 1 - -* Highly polymerized dimethyl methoxy oxane Methyl (aminopropyl) decane copolymer 1 - (polyacrylic acid / polymethyl methacrylate methacrylate) copolymer - 1 microcrystalline wax 1 1 1 paraffin 4.5 4.5 4.5 dibutyl dimethyl hydrazine Ketopolyglycerol-3 1.5 1.5 1.5 Isostearic acid 1 1 1 Distearyl dimethyl ammonium chloride 0.2 0.2 0.2 Ceria 10 10 10 (Ethylene dimethyl fluorenone / methyl oxime sesquiterpene Oxyalkylene) crosslinked polymer 3 3 J (dimethyl fluorenone / ethylene dimethyl hydrazine SM) crosslinked polymer 7 7 7 polymethyl methacrylate 5 5 5 dimethyl stearin ammonium selenite dispersed Body 30 30 30 (10% dispersion. + A certain ring of pentapoly argon argon dilute. The inside of the arc is the window bifurcation) (3) (3) (3) Polyoxane-treated iron Dan 0.002 0.002 0.002 dimethyl Formilated cerium oxide 0.5 0.5 0.5 Tocopherol 0.02 0.02 0.02 Pore shielding effect [4 stage evaluation] AAA filling appropriateness [5 stage evaluation] AAA color pattern (dispersion) [4 stage evaluation] AAA usability (softness, smoothness) [4-stage evaluation] AAA effect of no makeup removal [4-stage evaluation 1 ABB The results disclosed in Table 6 clearly show that the blending amount range of the present invention contains (a) - (e) component, further addition of component (h) Example 1 Any of the samples of 3, 28 to 29 can obtain a pore concealing effect, and the appropriateness, color tone, and usability (softness, smoothness) The effect of the sex, plus the effect of "no makeup". INDUSTRIAL APPLICABILITY The oily solid cosmetic of the present invention has an excellent pore blocking effect compared to the pore blocking effect produced by the conventional spherical powder, and further 8-32-201249475 is easily formulated into an appropriate hardness. The color pattern does not occur, and the usability (softness and smoothness) is also excellent. -33 -