201244679 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種多層複合金鋼且，尤— 鍋具，其兼具導熱效果佳、财高溫、耐種，複合金 量輕與不易變形等功效。 彳貝 '抗沾黏、重 【先前技術】 f閱第五圖，傳統無煙炒鋼(亦即複合鋼 :呂:ΐ外鍋81(經陽極處理)的内表面塗覆二:氟 82，而達到無煙且不沾鋼之產品訴求。 觀龍表面# 成之不錄鋼· · ·）製 傳統複合鋼具產生以下問題： 隙，且無法克服異質金屬== 接σ之乳化層，造成複合鋼具導熱性差。 ‘、 [2]不耐咼溫。當然，複合鋼具間的 ==:熱膠(耐熱度不足)予以填補，但另2 炒二不：，傳被 具、土黏。傳統不錄鋼鋼因導熱不佳(相對受孰不均）， 炒焦並產生油煙)問題:不論是 的密菸 使用L段時合金鋼具’因為紹合金質地較軟，在 制奴時間後，較各易變形損傷。 有鐘於此，必需研發出可革除傳統銷具缺點的多層複合金 201244679 銷具。 【發明内容】 執六月3的’在於提供一種多層複合金銷具，其兼具導 忑優點特二高溫:耐餘抗刮損、抗沾黏、重量輕與不易ΐ形 不決導熱效果較差、 包括解決上述問題之技術手段係提;； -敎、系具有一外表面及一内表面，該外表面用以接觸 低=合si &及該内表面之間包括複數個金屬層及至少- 麵、數二屬 姑你銥鋁-銅·鈦的其中一種複合金屬層； 間，該相鄰的該金屬層之201244679 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a multi-layer composite gold steel and, in particular, a pot, which has good thermal conductivity, high temperature, resistance to seed, light composite weight and deformation resistance, etc. efficacy. Mussel's anti-sticking, heavy [prior art] f read the fifth picture, the traditional surface of the traditional smokeless stainless steel (that is, composite steel: Lu: ΐ outer pot 81 (anodized) is coated with two: fluorine 82, and To achieve the product of smokeless and non-stick steel. Guanlong surface #成之不钢钢 · · ·) The traditional composite steel tool has the following problems: gap, and can not overcome the heterogeneous metal == emulsified layer of σ, resulting in composite steel Poor thermal conductivity. ‘, [2] is not resistant to temperature. Of course, the ==: hot glue (insufficient heat resistance) between the composite steels is filled, but the other 2 is fried: the pass is sticky and the soil is sticky. Traditionally unrecorded steel due to poor thermal conductivity (relatively affected by unevenness), scorching and producing soot) Problem: Regardless of the dense smoke, the alloy steel with the L segment is used because the texture of the alloy is soft, after the slave time More susceptible to deformation damage. In view of this, it is necessary to develop a multi-layer composite gold 201244679 pin that can eliminate the shortcomings of traditional pin. SUMMARY OF THE INVENTION The implementation of June 3 is to provide a multi-layer composite gold pin, which has the advantages of both guides and special high temperature: resistance to scratching, anti-sticking, light weight and difficult to shape. And a technical means for solving the above problem; - the cymbal has an outer surface and an inner surface, the outer surface is for contacting the low = combined si & and the inner surface includes a plurality of metal layers and at least - one or two of the composite metal layers of aluminum-copper and titanium; and the adjacent metal layer
Utr 金、㈣-銅·鋅-稀土合金、紹-石夕-銅- 人金及石々if呂石夕-銅錯斧稀土合金、紹·石夕—銅普錫-稀土 ί：Γ銅普鋅♦稀土合金的其中之一種合金； 該熱術結合於該銷部之内表面上， :曰係l自！呂不鏽鋼、鈦、氧化紹的其中之一種。 本?明之±述目的與優點，不雜下述所選用實施例 、、'田說明與附圖中，獲得深入瞭解。 ° Γ眘3 ΓΓ實細並配合®辆細_本發明於後： I貫施方式】 圖，係為—種多層複合金鋼具，參閱第一、第二及第三 面部10，係、具有一外表面101及一内表面102，該外表 門勺接觸一熱源90 ’該外表面101及該内表面102之 曰匕^复數個金屬層11及至少一低炫點合金12，·其中： "亥複數個金屬層11係選自也銅、銘·銅务紹銅-不傭 201244679 該低熔點合金12 4自手二 ，，合金，♦銅I稀土合二:二J:， Ϊ金錫··稀土合侧呂飾鍺骑稀。 一熱喷塗層20，係以熱魅技術結合於該銷部1〇之内表 面102上，該熱喷塗層2〇係選自鋁、不鏽鋼、鈦、氧化鋁 其中之一種。 實務上，該低熔點合金12之各種合金之比例請參閱下表 (表一) 合金 化學成份(wt%) 矽 (Si) 銅 (Cu) 鍺 (Ge) 鋅 (Zn) 錫 (Sn) 稀土 (Re) 鋁 (A1) 紹-石夕-稀土 (Al-Si-RE) 5-20% — 一 0.05 -0.5% 剩餘 紹-碎-銅-稀土合 細-Si-Cu-RE) 5-20% 5-30% — 0.05 -0.5% 剩餘 在呂-碎-銅-錯-稀 (Al-Si-Cu-Ge-RE) 5-20% 5-30% 5-30% 00.05 -0.5% 剩 紹-碎稀土 (Al-SilZrH® 5-20% 5-30% 5-30% 0.05 -0.5% 剩餘 铭-碎-銅-錫-稀 土处 (Al-Si-Cu-Sn-RE) 5-20% 5-30% 5-30% 0.05 -0.5°/〇 剩餘 崔呂-碎-銅-錯-辞-稀土合金 (Al-Si-Cu-Ge-Zn -RE) 5-20% 5-20% 5-20% 5-20% 0.05 -0.5% 剩餘 201244679 銘-碎-銅-錯-錫-稀土合金 (A1_Si-Cu-Ge-Sn -RE) 5-20%~ 5-20% 5-20% 5-20% 0.05- 0.5% 剩餘 1呂-石夕-銅-錯-辞一 If-稀土合金 (Al-Si-Cu-Ge-Zn -Sn~RE) 5-20% 5-20% 5-20% 5-20% 5-20% 0.05 -0.5% 剩餘 你必冷舶节、1 u〒之稀土合金係選自：鑭(La)、鈽(Ce)、 鎮(Pr)、鈥(Nd)、鉅(pm)、釤(Sm)、銪(Eu)、亂(Gd)、錢(Tb)、 鏑(Dy)、鈥(Ho)、铒(Er)、铥(Tm)、镱(Yb)、镏(Lu)、釔⑼、銳 (Sc)的至少其中一種。 特別要說明的部份，是“熱喷塗技術”主要係將欲喷塗之 f料(例如本發明之熱喷塗層20)加熱熔化，再配合氣體將原料 朝待加工面(例如本發明之鍋部1〇之内表面1〇2)喷塗，進而於 ί工巧上形成一熱噴塗層(即本發明之熱喷塗層20)，在目前而 吕主熱喷塗技術”具有操作簡單、製程成本低、適用於不規 則表面及不受材質限制等優點 6 201244679 (表二) 基材 平均粗糙度 Ra( u m) 最大粗糙度 Ry("m) 對水潤濕角 對食用油潤 濕角 64鈦 (Ti6A14V) 5.2687 38.9563 8Γ 0° (完全潤濕） 銘(A1) 3.3568 17.3867 145° 0° (完全潤濕） 不II鋼 (SUS304) 4.7542 34.0122 141。 0。 (完全潤濕） 更詳細的講’本發明之多層複合金鍋具主要係以硬銲技 術，將邊銷部10之該複數個金屬層11分別以該低溶點合金 12連結’使該複數數個金屬層η之間沒有間隙，減少熱阻， 至於該熱喷塗層20則使該多層複合金鍋具之表面可承$長時 間的碰觸而不會刮損，而為抗沾黏之結構者。 本發明之優點及功效可歸納如下： [1]導熱效果佳。本發明係以銅或鋁(導熱效果佳)作為鍋 部10的其中一金屬層11(假設為接近熱源90的那一層），且複 數金屬層11間係以硬銲技術配合低溶點合金12，構成無孔洞 間隙的緊密接合面，熱源90產生的熱量91(參閱第三圖)可快 速而均勻散佈至整個多層複合金鍋具。故導熱效果佳。 、 P]耐高溫。硬銲技術的操作溫度大約是在攝氏_度左 f，本發明於低熔點(紹)合金添加稀土元素，除改善鋁合^接 二的機械性質，能增強接合強度與接點耐腐蝕性外，亦可耐 溫0 置埶H韻Ϊ刮損。本發日月於鋼部之内表面以熱喷塗技術設 …喷塗層，可形成雜硬質層’可耐鍋鏟在炒菜過程中 才貝。故耐餘抗刮損。 構，黏。該触塗層係於賴部上形祕殊毛細結 崎層，駿本㈣之錢複合金轉產生極佳 量的 [习重量輕。本發明之主要結構為欽及崎，皆為輕 7 201244679 金屬結構。故，故重量輕。 [6]不易變形。本發明包含有不銹鋼或鈦金屬 豆且 良好的耐姓性，強度與硬度均佳，可使本發明 义ς 具耐長時間制科變形。 1複5金鋼 以上僅是藉由較佳實施例詳細說明本發明 改與變化，皆不脫離本發明之精^it。 第一圖係本發明之示意圖 第二圖係本發明之熱噴塗層以触塗技術結合於鋼部内表面 之示意圖 第三圖係本發明之熱傳導均勻之示意圖 第四Α、^四Β及第四C圖係賴為本發明之齡塗技術處 理後之64鈦、鋁及不鏽鋼等不同基材呈現對水潤濕角 之示意圖 第五圖係傳統複合鍋具之示意圖 【主要元件符號說明】 101外表面 11金屬層 20熱喷塗層 82鐵氟龍表面部 91熱量 10鍋部 102内表面 12低熔點合金 81銘合金外锅 90熱源 01、02、03潤濕角 8Utr gold, (4)-copper·zinc-rare earth alloy, Shao-shixi-copper-human gold and stone 々 if Lu Shixi-copper wrong axe rare earth alloy, Shao·Shi Xi—copper tin-rare earth Γ: Γ 普One of the zinc ♦ rare earth alloys; the heat is bonded to the inner surface of the pin portion: 曰 l l from! One of the stainless steel, titanium, and oxidized. The purpose and advantages of the present invention are not limited to the following selected embodiments, 'field descriptions and drawings'. ° Γ慎 3 ΓΓ 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细 细An outer surface 101 and an inner surface 102, the outer door spoon is in contact with a heat source 90', the outer surface 101 and the inner surface 102, a plurality of metal layers 11 and at least one low-point alloy 12, wherein: ; a plurality of metal layers 11 are selected from the group also copper, Ming · copper Wu Shao copper - not commission 201244679 The low melting point alloy 12 4 from the hand two, alloy, ♦ copper I rare earth combination two: two J:, Jin Jinxi · · Rare earth combined side Lu Lu 锗 ride rare. A thermal spray coating 20 is bonded to the inner surface 102 of the pin portion 1 by thermal glazing. The thermal spray coating 2 is selected from the group consisting of aluminum, stainless steel, titanium, and alumina. In practice, the ratio of various alloys of the low melting point alloy 12 is shown in the following table (Table 1). Alloy chemical composition (wt%) 矽(Si) Copper(Cu) 锗(Ge) Zn(Zn) Tin(Sn) Rare earth ( Re) Aluminum (A1) Shao-Shixi-Rare Earth (Al-Si-RE) 5-20% - a 0.05 -0.5% Residual Shao-Crush-Copper-Rare Earth Fine-Si-Cu-RE) 5-20% 5-30% — 0.05 -0.5% Remaining in Lu-Broken-Cu-W-Ge-RE 5-20% 5-30% 5-30% 00.05 -0.5% Rare earth (Al-SilZrH® 5-20% 5-30% 5-30% 0.05 -0.5% Remaining Ming-Crush-Copper-Sil-Rare Earth (Al-Si-Cu-Sn-RE) 5-20% 5 -30% 5-30% 0.05 -0.5°/〇Remaining Cui Lu-Crush-Copper-Wrong-Word-Rare Earth Alloy (Al-Si-Cu-Ge-Zn-RE) 5-20% 5-20% 5- 20% 5-20% 0.05 -0.5% Remaining 201244679 Ming-Crush-Copper-Wrong-Sil-Rare Earth Alloy (A1_Si-Cu-Ge-Sn-RE) 5-20%~ 5-20% 5-20% 5- 20% 0.05- 0.5% Remaining 1 Lu-Shi Xi-Copper-Wrong-Word-If-Rare Earth Alloy (Al-Si-Cu-Ge-Zn-Sn~RE) 5-20% 5-20% 5-20% 5-20% 5-20% 0.05 -0.5% The remaining rare earth alloys are selected from the following: La, Ce, Pr, Nd, Ju (pm), 钐 (Sm), 铕 (Eu), chaos (Gd), At least one of (Tb), Dy, Ho, Er, Tm, Yb, Lu, Y, and Sc. In part, the "thermal spraying technology" mainly heats and melts the material to be sprayed (for example, the thermal spray layer 20 of the present invention), and then mixes the raw material toward the surface to be processed (for example, the pot portion 1 of the present invention) The inner surface of the crucible is sprayed to form a thermal spray coating layer (ie, the thermal spray coating layer 20 of the present invention). At present, the main thermal spray coating technology has simple operation and low process cost. Advantages for irregular surfaces and no material restrictions 6 201244679 (Table 2) Average roughness of substrate Ra( um) Maximum roughness Ry("m) Wetting angle to water for cooking oil 64 Titanium (Ti6A14V) 5.2687 38.9563 8Γ 0° (completely wet) Ming (A1) 3.3568 17.3867 145° 0° (completely wet) Not II steel (SUS304) 4.7542 34.0122 141. 0. (Complete Wetting) In more detail, the multilayer composite gold pot of the present invention mainly uses a brazing technique to connect the plurality of metal layers 11 of the side pin portion 10 to the low melting point alloy 12, respectively. There is no gap between the plurality of metal layers η to reduce the thermal resistance. As for the thermal spray layer 20, the surface of the multi-layer composite gold pot can be touched for a long time without scratching, and is resistant to sticking. The structure of the person. The advantages and effects of the present invention can be summarized as follows: [1] The thermal conductivity is good. The invention adopts copper or aluminum (good thermal conduction effect) as one of the metal layers 11 of the pot portion 10 (assumed to be the layer close to the heat source 90), and the plurality of metal layers 11 are brazed together with the low melting point alloy 12 , forming a tight joint surface without a hole gap, the heat 91 generated by the heat source 90 (refer to the third figure) can be quickly and evenly distributed to the entire multi-layer composite gold pot. Therefore, the heat conduction effect is good. , P] high temperature resistance. The operating temperature of the brazing technology is about Δ degrees left f. The invention adds rare earth elements to the low melting point alloy, in addition to improving the mechanical properties of the aluminum alloy, and enhancing the joint strength and the joint corrosion resistance. It can also be used to withstand temperature 0. On the inner surface of the steel section, the surface of the steel part is sprayed with a thermal spray technology to form a hetero-hard layer, which is resistant to the spatula during the cooking process. Therefore, it is resistant to scratching. Structure, sticky. The touch coating is tied to the top of the Lai section, and the composite of the gold is produced by Junben (4). The main structure of the present invention is Qinsaki, both of which are light 7 201244679 metal structures. Therefore, it is light in weight. [6] Not easily deformed. The invention comprises stainless steel or titanium metal beans and has good resistance to the surname, and has good strength and hardness, so that the invention can resist deformation for a long time. The present invention is not limited to the details of the present invention. The first drawing is a schematic view of the present invention. The second drawing is a schematic view of the thermal spraying layer of the present invention bonded to the inner surface of the steel portion by a touch coating technique. The third drawing is a schematic diagram of the heat conduction uniformity of the present invention. The fourth, fourth and fourth Figure C is a schematic diagram showing the water wetting angle of different substrates such as 64 titanium, aluminum and stainless steel after the treatment of the ageing coating technology of the invention. The fifth figure is a schematic diagram of a conventional composite pot. [Main component symbol description] 101 Surface 11 metal layer 20 thermal spray layer 82 Teflon surface part 91 heat 10 pot part 102 inner surface 12 low melting point alloy 81 Ming alloy outer pot 90 heat source 01, 02, 03 wetting angle 8