TW201243497A - Photosensitive resin composition for color filter and color filter using the same - Google Patents

Abstract

A photosensitive resin composition for color filter is disclosed, which comprises alkali-soluble resin (A), a compound (B) containing vinyl unsaturated group(s), photo initiator (C), organic solvent (D) and pigment (E). By controlling a total residual amount of a monomer (a-2-1) and a monomer (a-2-2) of the alkali-soluble resin (A) in the photosensitive resin composition and Q value of the alkali-soluble resin (A), a color filter with excellent contrast and less chromatic aberration between pre- and post-development can be fabricated.

Description

201243497 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a photosensitive resin composition for a color light-emitting sheet of a liquid crystal display, and a color light-receiving sheet formed thereof, and particularly related to Photosensitive resin composition for color light film with good contrast and small color difference before and after development 0 [Prior Art] Color filters have been widely used in applications such as color liquid crystal displays, color facsimile machines, color cameras, and the like. With the increasing market demand for office equipment such as color liquid crystal displays, the production techniques of color filters are also diversified. Methods such as dyeing, printing, electroplating, and dispersion have all been developed, and the dispersion method is now the mainstream. Usually, the color filter can be obtained by forming a red, green, blue or the like on a transparent glass substrate by a method such as a dyeing method, a printing method, an electrophoresis method, or a pigment dispersion method. In general, in order to improve the contrast of the color filter, a light shielding layer (or a black matrix) may be further disposed between the layers of the pigment. In general, the process of the dispersion method is carried out by dispersing a coloring pigment in a photosensitive resin, applying the photosensitive resin to a glass substrate, and subjecting to exposure, development, and the like to obtain a specific pattern. This process is repeated three times to produce a pattern of red (R), green (G) and blue (B) pixel layers. Thereafter, a protective film may be applied on the pattern of the elemental layer as needed. The process of the pigment dispersion method is generally performed by forming a black matrix on a transparent support such as a glass substrate with a metal such as chromium or chrome or a photosensitive resin light-shielding film, and then dispersing the red pigment. Resin group 201243497 '> agent) by the spin coating method, the photosensitive resin composition ♦ is exposed on the support body by exposure to a photomask, and exposure is developed to determine the color of the color. In the same operation mode, the three-color pixels such as green can be divided on the support by repeating blue, exposure, and development. Specifically, for example, a copolymer obtained by polymerizing ruthenium acrylic acid as a monomer component, the photosensitive resin used in the above-mentioned method is used as a photosensitive resin. The related documents of the above-mentioned sensitizing resin can be referred to, for example, Japanese Patent Publication No. Hei 6 95211, Japanese Patent Publication No. Hei 9/31121 (). However, 'pure S, light film manufacturing process towel, need to undergo multiple heat treatment 2 ' such as red (8), green (G) and blue (8) and other pixel layer pattern after post-bake step and transparent conductive The formation step of the film (IT film), etc., the step is generally required to be completed at 2 (Krc or higher temperature, but the above-mentioned conventional 2 (four) & right under 18QC, i hour or so heating, but prone to occur In the layer, the production of the pigment agglomerated particles (the particle diameter of the pigment-aggregated particles is in the range of 1 to 10 μm) and the heat resistance are not good, and a photosensitive resin is disclosed in Japanese Patent Laid-Open Publication No. 2001-075273. It is used to improve the above-mentioned problems by using a polymer containing a filament-containing non-fresh monomer and a polymer containing a glycidyl group as a solvent to improve the above-mentioned problems. As liquid crystal displays are increasingly demanding for color saturation, the requirements for pigments contained in color photosensitive resin compositions are increasing. If the above-mentioned known resin is used, it is easy to compare. Poor and before and after development In view of the above, it is urgent to propose a photosensitive resin composition to improve the conventional photosensitive resin composition, which is prone to poor contrast and high color difference before and after development in a high-temperature process. Therefore, an aspect of the present invention provides a photosensitive resin composition for a color filter comprising at least an alkali-soluble resin (A) and an ethylenically unsaturated composition. The compound (B), the photoinitiator (C), the organic solvent (〇), and the pigment (other aspect of the present invention) provide a color filter having the color filter described above. The present invention provides a liquid crystal display element comprising the above-described color filter, thereby improving the temperature of the conventional photosensitive resin composition at a high temperature. After the process, there are disadvantages such as poor contrast and excessive color difference before and after development. The photosensitive resin composition for a color filter of the present invention includes a soluble resin (A) and ethylene-containing resin. The unsaturated group compound (B), the photoinitiator, the organic solvent (D), and the pigment (E) are described below. Hereinafter, (meth)acrylic acid means acrylic acid and/or methacrylic acid, and The fluorenyl acrylate represents acrylate and/or methacrylate; likewise, the fluorenyl fluorenyl group and/or the decyl propylene group are represented by a (fluorenyl) acrylonitrile group. The alkali-soluble resin (A) The test of the present invention The soluble resin (A) is composed of a carboxylic acid group-containing unsaturated monomer (a_1), an unsaturated monomer (a_2-1) containing a tricyclodecane skeleton and an unsaturated functional group in one molecule, and/or Dicyclopentadiene 6 201243497 (dicyclopentadiene) skeleton and unsaturated functional group unsaturated monomer (a-2-2), and unsaturated monomer (a-1), unsaturated monomer (a_2_i) And a copolymer obtained by copolymerizing a copolymerizable vinyl monomer (a-3) other than the unsaturated monomer (a-2-2). Specific examples of the above-mentioned carboxylic acid group-containing unsaturated monomer (a-fluorene) include acrylic acid, methacrylic acid (hereinafter abbreviated as MAA), 2-propenyl ethoxy succinate, 2-methyl propylene ethoxylate Butadiene ester (hereinafter referred to as HOMS), 2-propenyl ethoxylate phthalate, 2-mercapto propylene ethoxylate phthalate, crotonic acid, α-chloropropionic acid, ethacrylic acid and An unsaturated monobasic oleic acid such as cinnamic acid; an unsaturated dicarboxylic acid (anhydride) such as maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, citraconic acid or stannic anhydride; And trivalent or higher unsaturated polyvalent carboxylic acids (anhydrides) and the like. The above enumerated is preferably methacrylic acid (hydrazine) and 2-mercapto acrylonitrile ethoxy succinate (HOMS). The above-mentioned carboxylic acid group-containing unsaturated monomer (a-fluorene) may be used singly or in combination of plural kinds. The total amount used based on the monomer (a-fluorene), the monomer (a-2-l), the monomer (a-2-2), and the monomer (a-3) is 100 parts by weight, when the monomer (a_) When the amount of use of :1) is from 5 parts by weight to 30 parts by weight, a photosensitive resin composition for color filters excellent in developability can be obtained. Specific examples of the unsaturated monomer (a-2-l) having a tricyclodecane skeleton and an unsaturated functional group in the above molecule are, for example, dimethylol tricyclodecane diacrylate, diterpene alcohol Dimethyldec tricyclodecane dimethacrylate, tricyclodecanediol diacrylate, and tricyclodecanediol dimethacrylate The following are trade names: NK ester DCP, NK ester 7 201243497 Α-DCP (manufactured by Shin-Nakamura Chemical Industry Co., Ltd.). Next, a specific one of the unsaturated monomer (a-2-2) having a dicyclopentadiene skeleton and an unsaturated functional group in one molecule is, for example, dicyclopentanyl methacrylate; Referred to as FA-513M), dicyclopentanyl acrylate; 曰立化成工业; hereinafter referred to as FA-513AS; dicyclopentenyl methacrylate; dicyclopentenyl acrylate Dicyclopentenyl acrylate; Hitachi Chemical Industry Co., Ltd., hereinafter referred to as FA-511A, FA-511AS), dicyclopentanyloxyethyl methacrylate, dicyclopentanyloxyethyl acrylate, mercaptopropyl acrylate Dicyclopentenyloxyethyl methacrylate (dicyclopentenyloxyethyl methacrylate; hereinafter referred to as FA_512M, FA-512MT) and dicyclopentenyloxyethyl acrylate; 曰立化成工业; hereinafter referred to as FA-512A , FA-512AS). The above-mentioned early body (a_2-1) and/or early body (a-2-2) may be used singly or in combination of plural kinds. Based on the total amount of the monomer (a-fluorene), the monomer (a-2-l), the monomer (a_2-2), and the monomer (a-3), the amount used is 1 part by weight, when the monomer (a When the total amount of use of -2-l) and the monomer (a-2-2) is from 5 parts by weight to 40 parts by weight, a photosensitive resin composition for a color filter having a small color difference before and after development can be obtained. The other copolymerizable vinyl monomer (a-3) may be a vinyl monomer (a_3_1) having an epoxy group structure and a vinyl monomer (a_3·2) having no epoxy group structure. Specific examples of the vinyl monomer having an epoxy group structure include unsaturated carboxylic acid glycidyl esters such as glycidyl acrylate and glycidyl methacrylate (hereinafter referred to as 201243497 GMA); acrylic acid; (3-ethyl_3_epoxybutyl) decyloxy decyl ester monomer, methacrylic acid (3-ethyl_3_epoxybutyl) decyloxy decyl ester monomer (hereinafter referred to as OXMA) Unsaturated epoxidized carboxylic acid esters such as butyl butyl carboxylate; allyl epoxidized propyl ether and methallyl epoxypropyl ether. Specific examples of the vinyl monomer (a-3-2) having no epoxy group structure include aromatics such as styrene, α-methylstyrene, vinyltoluene, p-styrene, and decyloxystyrene. Vinyl compound; Ν-phenyl maleimide, Ν-o-hydroxyphenyl maleimide, Ν-m-hydroxyphenyl maleimide, Ν-p-hydroxyphenyl mala Imine, Ν-o-methylphenylmaleimide, Ν-m-nonylphenylmaleimide, Ν-p-methylphenylmaleimide, Ν-o-methoxy Phenyl-maleimide, anthracene-m-decyloxyphenylmaleimide, anthracene-p-methoxyphenylmaleimide, anthracene-cyclohexylmaleimide, etc.醯 imines; decyl acrylate, decyl methacrylate, ethyl acrylate, ethyl methacrylate, n-propyl acrylate, n-propyl methacrylate, isopropyl acrylate, isopropyl methacrylate, N-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, second butyl acrylate, second butyl methacrylate, third butyl acrylate, third methacrylate , 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, acrylic acid 2-hydroxybutyl ester, 2-hydroxybutyl methacrylate, 3-hydroxybutyl acrylate, 3-hydroxybutyl methacrylate, 4-hydroxybutyl acrylate, 4-hydroxybutyl methacrylate, acryl allyl Ester, allyl methacrylate, benzyl acrylate, phenyl decyl acrylate, phenyl acrylate, phenyl methacrylate, methoxy 9 201243497 triethylene glycol acrylate, methyl Methoxy triethylene glycol methacrylate, lauryl methacrylate, tetradecyl methacrylate, methacrylic acid Cetyl methacrylate, octadecyi methacrylate, eicosyl methacrylate, behenyl methacrylate (d〇c〇syl)Unsaturated carboxylic acid esters such as methacrylate; n,N-didecylaminoethane acrylate, N,N-didecylaminoethyl acetate, n,N-diethylamino acrylate Propyl ester, N,N-dimethylaminopropyl methacrylate, N,N-dibutylaminopropyl acrylate, N-isobutylaminoethyl acrylate, etc. ; vinyl carboxylate such as ethyl acetate, ethyl propionate, vinyl butyrate; unsaturated ethers such as vinyl oxime ether, vinyl ether; acrylonitrile, mercapto acrylonitrile, α-chloropropene A cyanide vinyl compound such as nitrile or vinyl cyanide; acrylamide, mercapto acrylamide, α-gas acrylamide, hydrazine-hydroxyethyl acrylamide, hydrazine-hydroxyethyl decyl acrylamide An unsaturated decylamine such as 1,3-butadiene, isoamylene or gasified butadiene. The above monomers (a-3) may be used singly or in combination of plural kinds. The total amount used for the monomer (a-Ι), the monomer (a-2-i), the monomer (a_2_2), and the monomer (a-3) is 100 parts by weight, when the monomer (a-3) is used. When the amount is from 3 parts by weight to 90 parts by weight, a photosensitive resin composition for a color filter excellent in transparency and heat resistance can be obtained. The solvent used in the production of the alkali-soluble resin (A) of the present invention is generally ethylene glycol monopropyl ether (ethyiene glyc〇1 m〇n〇pr〇pyl ether) monoethanol. Diethylene glycol dimethyl 201243497 ether ; diglyme, tetrahydrofuran, ethylene glycol monomethyl mystery, ethylene glycol monoethyl ether, methyl cellosolve acetate, 3-ethoxypropionic acid Ethyl ester (ethyl 3-ethoxypropionate; EEP), ethyl cellosolve acetate, diethylene glycol monothiol bond, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol Monodecyl ether acetate, propylene glycol monoethyl acetate acetate, propylene glycol monopropyl sulphate acetate, acetophenone and acetone. The above enumerated ones are preferably diethylene glycol didecyl ether, propylene glycol monodecyl ether acetic acid and 3-ethoxypropionic acid ethyl acetate, and may be used singly or in combination of plural kinds. The initiator used in the production of the alkali-soluble resin (A) is generally a radical polymerization initiator, and specifically, for example, 2,2'-azobisisobutyronitrile, 2,2,-azobis ( 2,2'-azobis(2,4-dimethylvaleronitrile; ADVN), 2,2'-azobis(4.nonyloxy-2,4-didecylpentene Even H(azo) compounds such as nitrile), 2,2,-azobis-2-methylbutyronitrile (AMBN), benzoylperoxide The peroxy compound is used. Among them, the photosensitive resin composition based on the color filter is 100% by weight. The above unreacted unsaturated monomer (a_2_i) and unsaturated monomer (a) -2-2) When the total amount of the residual monomer is more than 1 〇〇〇ppm, the viscosity of the photosensitive resin composition for the color filter tends to increase as the standing time increases, and the color filter is used for sensitization. After the coating and development of the resin composition, the problem of excessive color difference before and after development occurs. Therefore, the total amount of residual monomers of the unreacted monomer (a-2_1) and monomer (a_2-2) is generally Is less than 1〇〇0??111, Best 9〇〇 less than 111 d 'is more preferably less than 80〇1) 1) 111. Secondly, when the Q value of the alkali-soluble resin (A) is more than 2.5, there is a problem that the film thickness is uneven after coating 201243497, resulting in a decrease in brightness. Therefore, the Q value of the alkali-soluble resin (A) is generally less than 25, preferably less than 2 3 and z - less than 2.1. The two types of the invention (4) can generally be used in a single type. The ethylenically unsaturated group-containing compound (B) The above-mentioned ethylenically unsaturated group-containing compound (B) is an ethylenically unsaturated compound having at least one or more ethylenically unsaturated groups, and specific examples thereof include: propylene brewing, (Methyl) acrylonitrile, (mercapto) acrylamidooctyl octyl acrylate, isobutoxymethyl (decyl) acrylamide, isobornyl methacrylate (fluorenyl) isobornyl acrylate, (mercapto)acrylic acid 2_ethyl = vinegar, ethyl diethylene glycol (fluorenyl) acrylate, trioctyl (meth) acrylamide, acetone (mercapto) acrylamide, (methyl) dimethyl dimethyl acetonitrile, dodecyl (meth) acrylate, dicyclopentenyl oxy (meth) acrylate, Dicyclopentyl acrylate, N,N-dimercapto (meth) acrylamide, tetrachlorophenyl (meth) acrylate, (meth)acrylic acid __ tetraphenoxyethyl ester, ( Mercapto) tetrahydrofuran acrylate, tetrabromophenyl (meth) acrylate, 2-tetrabromophenoxyethyl (meth) acrylate, (mercapto) acrylate 2_ tri-gas oxyethyl ester, (tri) bromophenyl (meth) acrylate, 2 - tribromophenoxy ethyl acrylate ( 2 - hydroxymethyl acrylate ), 2- By-propyl-(meth)acrylic acid, ethyl hexylamine, N-ethylglycine D, phenoxyethyl methacrylate, (phenoxy) phenoxyethyl acrylate, (meth)acrylic acid, five gas benzene Ethyl ester, pentabromophenyl (meth) acrylate, polyethylene mono(methyl) acrylate, propylene (meth) acrylate, borneol (meth) acrylate, etc. Unsaturated ethylenically unsaturated compound; ethylene glycol di(meth)acrylate, dicyclopentenyl di(meth)acrylate, triethylene glycol di 12 201243497 (fluorenyl) propylene _, four Ethylene glycol ^. - 聚聚酉日一 (meth) acrylate vinegar, polyethylene glycol bis (1) acrylic acid slightly, E 〇 gtf (four) a = vinegar, PO 1 double A A (methyl) C The second round of A two (A, "the purpose, p〇 modified gasification (four) A two (methyl: acid vinegar, EO ^ quality decoration F two (methyl) propylene _, Lin = methyl has 2 B Ethylene group of hetero-unsaturated group = saturated θ thing 'bis(2-hydroxyethyl) ) Three-acetic acid isocyanate modified (2 rhyme ethyl) isocyanate three (10)) __, tri (methyl) propylene fosphate tri (tetra) _, epoxy ethene (hereinafter referred to as soil) ketone Acid tri-methyl propyl vinegar, epoxy propylene: (3 methyl) acrylic acid tri-methyl propyl vinegar, penta pentane: Κ) modified glycerol tris(methyl) propionic acid material has three B counties Non-base, B, f-unsaturated compounds; pentaerythritol tetrakis(meth) acrylate vinegar, dipentaerythritol tetrakis(mercapto) acrylic acid §, two-three (tetra) propyl acrylate vinegar, etc. An ethylenically unsaturated compound having an ethylenically unsaturated group; dipentaerythritol = (meth)acrylic acid, and having five ethylene groups, such as dipentaerythritol penta(methyl) propyl hydride Unsaturated ethylenically unsaturated compound; dipentacrythritol hexaacrylate; 2 pentaerythritol hexa(methyl) acrylate, caprolactone modified diquaternary alcohol, (methyl) Propionate vinegar, Ethylene ethoxide (hereinafter referred to as E0) is not full π, she has six ethyl sulphate unsaturated groups, which are equivalent to ethylene. 13 201243497 Among them, it is preferable to have 3 or 3 The above-mentioned B-unsaturated compound 'more preferably has 4 or more = less than the non-saturated compound and the ethylenically unsaturated compound, and more preferably has 5 or more ethylenic unsaturation Base B miscellaneous and chemical. The above ethylenically unsaturated compound (B) having an ethylenically unsaturated group may be used alone or in combination of plural. In general, the ethylene-containing resin of the present invention is based on 1 part by weight of the alkali-soluble resin (VIII). The compound (B) of the unsaturated group is usually used in an amount of 5 to 45 Å, preferably 10 to 400 parts by weight, more preferably 2 to 3 parts by weight. Photoinitiator (C) The photoinitiator (C) of the present invention comprises a photoinitiator (C-1) of a fluorene-fluorenyl (0_acetyi 〇xime) and a photoinitiator of a triazine Agent (C-2). Specific examples of the 0-fluorenylfluorene photoinitiator (C-1) in the present invention are, for example, ^[4-(phenylthio)phenyl]-heptan-1,2-dione 2-(0 -Benzyl phenyl])[4-(phenylthio)phenyl]-heptane-l, 2-dione 2-(0- benzoyloxime)], 1-[4-(phenylthio)phenyl]-octane _ι,2-diketone 2-(0-phenylhydrazinyl)[l-[4-(phenylthio)phenyl]-octane-l, 2-dione 2-(0-benzoyloxime)], 1-[4- (phenylphenyl)phenyl]-heptane-1,2-di-2-(0-phenylylphenyl)-heptane-l,2-dione 2-( 0-benzoyloxime)], l-[9-ethyl-6-(2-mercaptobenzoyl)-911-0 card 0--3-substituted]-ethene-indole 1-(0-ethenyl)躬) [l-[9-ethyl-6-(2- methy lbenzoyl)-9H-carb azole-3-yl]-ethanone 1-(0- acetyloxime)], l-[9-ethyl-6-( 3-mercaptophenyl styrene)-9Η-^σ^·3-substituent]-ethane ketone 1-(〇-乙醯基肟)[卜[9 <Let 丫1-6-(3-11^1;1^化61^〇丫1)-9H-carbazole-3-yl]-ethanone l-(O-acetyloxime)], 1-[9-B 201243497 -6-phenylhydrazino-9H-carbazole-3-substituted]-ethane ketone 1-(0-ethylindenyl)[1-[9-ethyl-6-benzoyl-9H-carbazole-3 -yl]-ethanone 1-(0- acetyloxime)], acetone-l-[9-ethyl-6-(2-mercapto-4-tetrahydrofurfurylbenzoyl)-9H-oxime Oxazol-3-substituent]-1 (〇-acetamidopurine) [ethanone-1 -[9-ethyl-6-(2-methyl-4-tetrahydrofuranylbenzoyl)-9H-carbazole-3-yl]-l- (0-acetyloxime)], Ethyl Ketone-1_[9-Ethyl-6-(2-indolyl-4-tetrahydropyranylphenyl)-9H-indazole-3-Substituent]-1 -(0-乙醯基任) [ethanone -l-[9-ethyl-6-(2-methyl-4-tetrahydropyranylbenzoyl)-9H-carbazole-3-yl]-1 -(0-acetyloxime)], B Ketone-l-[9-ethyl-6-(2-methyl-5-tetrahydrofuranyl adenyl)-9Η-σ卡唾-3-substituent]-1-(0-acetamidine) *^)[ethanone-l-[9-ethyl-6-(2-methyl-5-tetrahydrofuranylbenzoyl)-9H-carbazole-3-yl]-l_(0-acetyloxime)], ethionone_1·[9 -ethyl-6-(2-methyl-5-tetrahydropyranylphenyl)-9H-indazole-3-substituted]-1-(0-ethyl fluorene brick) [ethanone -l- [9 -ethyl-6-(2-methyl-5-tetrahydropyranylbenzoyl)-9H-carbazole-3-yl]-1-(0-acetyloxime)], ethene-l-[9-ethyl-6-(2- Methyl-4·tetrazofurfuranyloxybenzene aryl)-9H-indole-3-substituted]-1-(0-acetamidine*t^)[ethanone-l-[9-ethyl -6-(2-methyl-4-tetrahydrofuranylmethoxybenzoyl)-9H-carbazole-3-yl]-l-(0-acetyloxime)], E-burning ll-[9-ethyl-6-(2-methyl- 4-tetrahydrofurfuryloxyphenyl fluorenyl)-9H-carbazole-3-substituent]-1-(0-ethylhydrazine)[ethanone -l-[9-ethyl-6-(2 -methyl-4-tetrahydropyranylmethoxybenzoyl)-9H-carbazole-3-yl]-1-(0-acetyloxime)], ketone-l-[9-ethyl-6-(2-methyl-5-tetrahydrofuranyl) Methoxybenzoinyl)-9H-°carbazol-3-substituent]-1-(0-acetamidine*^)[ethanone-l-[9-ethyl-6-(2-methyl-5-tetrahydrofuranylmethoxybenzoyl) )- 15 201243497 9H-carbazole-3-yl]-l_(〇-acetyloxime)], acetone-l_[9-ethyl-6-(2·indolyl-5-tetrahydropyranyloxybenzene)醯基)_9H_carbazole_3 substituent]_ 1 (0 ethoxylated) [ethanone _l-[9-ethyl-6-(2-methyl-5. tetrahydropyranylmethoxybenzoyl)-9H-carbazole-3-yl] -l-(〇- acetyloxime)], Alkanone·ι_[9-ethyl_6_{2_methyl_4-(2,2-dimercapto-1,3-dioxolanyl)phenylhydrazino}-9H-indazole-3- Substituent]_ι_(〇_乙醯基肟)[ethanone -l-[9-ethyl-6-{2-methyl-4-(2,2-dimethyl-l,3- dioxolanyl)benzoyl}-9H-carbazole -3-yl]-l-(〇.  Acetyloxime)], ketone-l-[9-ethyl·6-{2-methyl-4·(2,2-dimercapto-1,3-1,3-oxapentyl)decyloxybenzene醯基}_9Η-α卡唾_3-substituent]-ΐ_(〇_乙醯基肟)[ethanone -l-[9-ethyl_6-{2-methyl-4-(2,2-dimethyM,3- Dioxollanyl)methoxybenzoyl}-9H-carbazole-3-yl]-l-(0-acetyloxime)]. Among the above-mentioned 0-fluorenyl fluorene photoinitiators, preferred are phenylthio)phenyl]-octane-1,2-dione 2-(0-benzoquinone), ι·[9 -ethyl-6-(2-mercaptobenzoyl)-9H-indazole-3-substituted]-ethanone 1-(anthracene-ethenyl), ethane ketone _ 1·[9- Ethyl-6-(2-methyl-4-tetrahydrofuranmethoxyphenyl)]9H-indazole-3-substituted]-1-(0-ethylindenyl), ethane ketone-l-[ 9-ethyl-6-{2-methyl-4-(2,2-dimercapto-1,3-dioxolanyl)nonyloxyphenylhydrazino}_9H-carbazole-3-substituted Base]-H0-Ethyl hydrazine) and the like. Specific examples of the triazine-based photoinitiator (C-2) in the present invention are, for example, a vinyl-il-mercapto-s-triazabenzene compound, 2-(naphtho-1-substituted) -4,6-bis-halogenated fluorenyl-s-triazabenzene compound and 4-(p-aminophenyl)-2,6-di-di-methyl-s-triazabenzene compound Wait. 201243497 Specific examples of the above vinyl-ii-mercapto-s-triazabenzene compound, for example: 2,4-bis(trichloromethyl)-6-p-nonyloxystyryl-s-triazabenzene [2,4-Bis(trichloromethyl)-6-(p-metlioxy)styryl-s-triazine], 2,4·bis(trichloromethyl)-6-(1-p-dimethylaminophenyl) · 1,3-butadienyl-s-triaza- 6-(l-p-dimethylaminophenyl-l,3-butadienyl)-s-triazine]曱______-amino-l-chlorophenyl-4-amino-6-(p-methoxy)styryl-s_triazine]. Specific examples of the above 2-(naphtho-1-substituted)-4,6-bis-haloindenyl-s-triazabenzene compound are as follows: 2-(naphtho-1-substituted)-4,6 _Bis-trichlorodecyl-s-triazabenzene [2-(naphtho,l,yl)-4,6-bis-trichloromethyl-s-triazine], 2-(4-decyloxy-naphtho- 1-Substituted-4,6-bis-tris-mercapto-s-triaza-p-(4-methoxy-naphtho-1 -yl)-4,6-bis-trichloromethyl-s-triazine], 2-(4-ethoxy-carotene-1-substituted)-4,6-bis-trichloroindolyl-s-triazabenzene [2-(4-ethoxy-naphtho-l-yl)- 4,6-bis-trichloromethyl-s-triazine], 2-(4-butoxy-naphthoquinone-1-substituted)-4,6-bis-trichloroindenyl-s-triazabenzene [2 -(4-butoxy-naphtho-l-yl)-4,6-bis-trichloromethyl-s-triazine], 2-[4-(2-decyloxyethyl)-naphthyl-1] substituent]- 4,6-bis-triseodecyl-s-triazabenzene [2_(4-(2-11161:11〇父}^1;11>4-naphtho-l-yl)-4,6-bis -trichloromethyl-s-triazine] '2-[4-(2-ethoxyethyl)-naphthyl-1-substituted]-4,6-bis-tris-mercapto-s-triazabenzene [ 2-(4-(2-ethoxyethyl-naphtho-l-yl)-4,6-bis-trichloromethyl-s-triazine], 2-[4-(2-butoxyethyl)-naphtho-1- take代基]-4,6-bis-tris-methyl-s-triazabenzene [2-(4-(2-1)111;〇\丫6111丫1-11已卩1^11〇-1 -丫1)-4,6_bis-trichloromethyl-s_triazine], 2-(2·methoxy-naphtho-1-in 17 201243497 alkenyl)-4,6-bis-trichloroindenyl-s-triazole [2-(2-methoxy-naphtho-l_yl)-4,6-bis-trichloromethyl-s-triazine], 2-(6-methoxy-5-methyl-naphtho-2-substituted group )-4,6-bis-trichloroindolyl-s-triazabenzene [2-(6-1^〇〇\丫-5-methyl-naphtho-2-yl)-4,6-bis-trichloromethyl -s-triazine] '2-(6-Methoxy-naphtho-2-substituted)-4,6-bis-triseodecyl-s-triazabenzene [2-(6-methoxy-naphtho) -2-yl)-4,6-bis-trichloromethyl-s-triazine], 2-(5-fluorenyl-causine-1-substituted)-4,6-bis-tris-decyl-s- Triazabenzene [2-(5-11161; 11〇和丫-11&1>111;11〇-1-丫1)-4,6-1^~114.111〇1'〇11161:11> ^-s-triazine], 2-(4,7-dimethoxy-naphthyl-1-substituted)-4,6-bis-tris-decyl-s-triazabenzene [2-(4) ,7-dimethoxy_naphtho-l-yl)-4,6-bis-trichloromethyl-s-triazine], 2-(6-ethoxy-naphtho-2-substituted)- 4. 6-bis-trichloroindolyl-s-triazabenzene [2-(6-6 〇〇父丫-11&卩11〇〇-2_丫1)-4,6-bis-trichloromethyl-s- Triazine], 2-(4,5-dimethoxy-naphtho-1-substituted)-4,6-bis-trichloromethyl-s-triazabenzene [2-(4,5-dimethoxy) -naphtho-l-yl)-4,6-bis-trichloromethyl-s-triazine]. Specific examples of the above 4-(p-aminophenyl)-2,6-di-haloindenyl-s-triazabenzene compound are as follows: 4-[p-indole, indole-di(ethoxycarbonylcarbonyl) Aminophenyl]- 2. 6- bis(ethoxymethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[ o-Mercapto-p-N,N-bis(ethoxycarbonylindenyl)aminophenyl]-2,6-bis(trichloromethyl)-s-triazabenzene [4-[o- methyl-pN, N-di(ethoxycarbonylmethyl)aminophenyl] - 2. 6- di(trichloromethyl)-s-triazine], 4-[p-N,N-bis(gasethyl)aminophenyl]-2,6-di(trismethyl)-s_triaza Benzene [4_[p_N,N-di(chloroethyl)aminophenyl] -2,6-di(trichloromethyl)-s- 18 201243497 triazine], 4-[o-indolyl-p-N,N-di(gas ethyl) Aminophenyl]-2,6-di(trichloroindenyl)-s-triazabenzene [4-[o-methyl-pN,N-di(chloroethyl)aminophenyl]-2,6-di( Trichloromethyl)-s-triazine], 4-(p-N-chloroethylaminophenyl)-2,6-di(trimethylsulfonyl)-s-triazabenzene [4-[p-N-chloroethylaminophenyl] -2,6-di(trichloromethyl)-s-triazine], 4-(p-N-ethoxymethylaminophenyl)-2,6-di(dichloroindenyl)-s-three Azabenzene [4-[ρ-Ν·ethoxycarbonylmethylaminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4_[p-anthracene, fluorenyl-di(phenyl)aminophenyl]·2,6 - bis(tris)-s-triazabenzene [4-[pN,N-di(phenyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-(p-N) -Chloroethylcarbonylaminophenyl)-2,6-bis(trimethylsulfonyl)-s-triazabenzene [4-7-chloroethylcarbonylaminopheny] l]-2,6-di(trichloromethyl)-s-triazine], 4-[p-N-(p-methoxyphenyl)carbonylaminophenyl]-2,6-di(trismethyl) )-s-tris-[3-[pN-(p-methoxyphenyl) carbonylaminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[m-N,N-di(ethoxycarbonylhydrazine) (amino) benzylamino]-2,6-di(trimethyl fluorenyl)-s_ diazabenzene [4-[mN,N-di(ethoxycarbonylmethyl)aminophenyl]-2,6-di(trichloromethyl)-s -triazine], 4-[m-bromo-p-N,N-bis(ethoxycarbonylindenyl)aminophenyl]-2,6-di(trismethyl)-s-triazabenzene [4_[111·· bromo-pN, N-di(ethoxycarbonylmethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[m-chloro-p-N,N-di(ethoxy) Aminophenyl]-2,6-di(dimethylmethyl)-s-triazabenzene [4-[111-chloro-pN,N-di(ethoxycarbonylmethyl)aminophenyl]- 2,6-di(trichloromethyl)-s-triazine], 4-[m-fluoro-p-anthracene, fluorenyl-bis(ethoxy 201243497 carbonylmethyl)aminophenyl]-2,6-di(three Gas-based)-s-triazabenzene [4-[111-fluoro-pN,N-di(ethoxycarbonylmethyl)aminophenyl]-2,6-di(t Richloromethyl)-s-triazine], 4-[o-----p-N,N-bis(ethoxylated fluorenyl)aminophenyl]-2,6·di(trichloroindenyl)- S-[3-[o-bromo_p-N,N-di(ethoxycarbonylmethyl)aminophenyl]2,6-di(trichloromethyl)-s-triazine], 4-[o-chloro-p-N,N - bis(ethoxycarbonylcarbonyl)aminophenyl-2,6-bis(trimethyl)-s-triazabenzene [4-[〇-chloro-pN, N-di(ethoxycarbonylmethyl)aminophenyl] -2,6-di(trichloromethyl)-s_triazine], 4_[o-fluoro-p-anthracene, fluorenyl-bis(ethoxycarbonylindenyl)aminophenyl]-2,6-di(trichloropurine) -s-tris-fluoro-pN, N-di(ethoxycarbonylmethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[o----- -N,N-bis(gasethyl)aminophenyl]-2,6-di(dioxadecyl)-s-di-homostyrene [4-[〇-131*〇111〇-卩-N , N-di(chloroethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[o-g-p-p-N,N-di(chloroethyl)amino styryl]-2 ,6-di(tris-chloro-pN,N-di(chloroethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazi Ne], 4-[o-fluoro-p-N,N-bis(chloroethyl)aminophenyl]·2,6·di(triseodecyl)-s-triazabenzene [4-[ o-fluoro-pN, N-di(chloroethyl)aminophenyl]-2,6-di(trichloromethyl)-s-triazine], 4-[m-bromo-p-anthracene, fluorene-bis(gasethyl)amino group Streptomynyl-2,6-di(trichloroindenyl)-s-triazabenzene-[4-[m-bromo-pN,N-di(chloroethyl)aminophenyl]-2,6-di(trichloromethyl)- S-triazine], 4-[m-gas-p-N,N-bis(gasethyl)aminophenyl]-2,6-di(trismethyl)-s-triazabenzene [4 -[m-chloro-pN,N-di(chloroethyl)aminophenyl]-2,6-di(trichloromethyl)-s- 20 201243497 triazine], 4-[inter-fluoro-p-N,N-di(chloroethane) Aminophenyl]-2,6-di(trichloroindenyl)-s-triazabenzene [4-[m-fluoro-pN,N-di(chloroethyl)aminophenyl]-2,6-di (trichloromethyl)-s-triazine], 4-(m-bromo-p-N-ethoxycarbonyldecylaminophenyl)-2,6-di(trichloromethyl)-s-triazabenzene [4-(m-bromo-pN-ethoxycarbonylmethylaminophenyl)-2,6-di(trichloromethyl)-s-triazine], 4-(m-gas-p-N-ethoxycarbonyldecylaminophenyl)_2 , 6_ two (trichloro 4-(m-chloro-pN-ethoxycarbonylmethylaminophenyl-2,6-di(trichloromethyl)-s-triazine], 4-(m-fluoro-p-N-ethoxyl) Alkyl-decylaminophenyl)-2,6-bis(trichloroindenyl)-s-tri-isophenyl [4-(111-:〇11〇1*〇-卩-^[-ethoxycarbonylmethylaminophenyl]- 2,6-di(trichloromethyl)-s-triazine], 4-(o-bromo-p-N-ethoxycarbonyldecylaminophenyl)-2,6-di(trichloroindenyl)-s -4-(O-bromo-pN-ethoxycarbonylmethylaminophenyl-2,6-di(trichloromethyl)-s-triazine], 4_(o-gas-p-N-ethoxycarbonyldecylamino) Phenyl)-2,6-bis(trichloromethyl)-s-triazino-[4-(o-chloro-pN-ethoxycarbonylmethylaminophenyl-2,6-di(trichloromethyl)-s-triazine], 4 -(o-fluoro-p-N-ethoxycarbonylmethylaminophenyl)-2,6-bis(trichloroindenyl)-s-triazabenzene [4-(m-fluoro-pN-) Ethoxycarbonylmethylaminophenyl)-2,6-di(trichloromethyl)-s-triazine], 4-(m-bromo-p-N-chloroethylaminophenyl)-2,6-di(trisethoxy)-s -Tri-gas benzene [4-(111-1)1*〇111〇-卩-]^-〇111〇1:〇61;1171111111〇卩11611>4)-2 ,6-di(trichloromethyl)-s-triazine], 4-(m-gas-p-N-gas ethylaminophenyl)-2,6-di(trismethyl)-s-triaza Benzene [4-(111-(;111〇1>〇-卩-]^-chloroethylaminophenyl)-2,6-di(trichloromethyl)-s- 21 201243497 triazine], 4-(m-fluoro-p-N- Chloroethylaminophenyl)-2,6-di(trichloroindenyl)-s-triazabenzene [4-(m-fluoro-pN-chloroethylaminophenyl)- 2. 6- di(trichloromethyl)-s-triazine], 4-(o-o-p-p-N-gas ethylaminophenyl)-2,6-di(dimethylmethyl)-s-dioxabenzene [4-(〇-151'〇111〇-卩-1'4-chloroethylaminophenyl)-2,6-di(trichloromethyl)-s-triazine], 4-(o-chloro-p-N-chloroethylamine) Phenyl)-2,6-di(trismethyl)-s-triseobenzene [4-(〇-(^1〇1'〇-卩-]^-〇111〇1*〇61; 11>^111111〇卩11611丫1)- 2. 6-di(trichloromethyl)-s-triazine], 4-(o-fluoro-p-N-methylethylaminophenyl)-2,6-di(trichloroindenyl)-s-triaza [4-(〇-£111〇1:〇-卩-]^· chloroethylaminophenyl)-2,6-di(trichloromethyl)-s-triazine], 2,4-bis(trichloroindenyl)-6-[ 3-bromo-4-[indole, fluorenyl-bis(ethoxycarbonylindenyl)amino]phenyl]-1,3,5-triazabenzene [2,4_bis(trichloromethyl)-6-[3 -bromo-4-[N,N-di(ethoxycarbonylmethyl)amino]phenyl]-l,3,5-triazine] and the like. Among the photoinitiators (C-2), preferred is: 4-[m-.bromo-p-_n,N-di(ethoxycarbonylmethyl)aminophenyl]-2,6-di (Trichloromethyl)-s_triazabenzene [4·, 2,4·bis(trimethylsulfonyl)-6-p-methoxystyryl-s-triazabenzene and the like. In the photosensitive resin composition for a color filter of the present invention, the photoinitiator ((>1) and (C-2)) may be added as needed without affecting the physical properties. (C-3). Specific examples of the photoinitiator (C-3) are: acetophenone compounds, biimidazole, benzophenone compounds, α -A-diketone compound, aCyl〇in compound, acyloin ether compound, aeylph〇sphine()xide compound, quinone a compound, a halogen-containing compound, a peroxide 22 201243497, etc., wherein the above acetophenone is specifically exemplified by: p-dimethylamino-acetophenone, α, α, -dimethoxyoxyazobenzophenone (α,α,_ dimethoxyazoxyacetophenone), 2,2,-dimercapto-2-phenylacetophenone (2,2'-dimethyl-2-phenylacetophenone) , p-methoxyacetophenone, 2-mercapto-1-(4-mercaptothiophenyl)_2_ 淋 代 -1 Acetone (2-methyl-l-(4-methylthio phenyl)-2-morpholino propane, l-on), 2-benzyl-2-N,N-dimethylamine-1·(4·吗琳代phenyl )-1- T_[2-benzyl-2-N,N-dimethylamino-l-(4-morpholinophenyl)-l-butanone] The above bimeidazole (biimidazole) such as: 2,2'-double ( O-gas phenyl)-4,4',5,5'-tetraphenyl dimi-[2,2,-1^(〇-〇111〇1'〇卩1161^1)-4,4' ,5,5'-tetraphenyl-biimidazole], 2,2'-bis(o-fluorophenyl)· 4,4',5,5'-tetraphenyl 2°m 11 sitting [2,2'-bis (o_fluorophenyl)-4,4',5,5'-tetraphenyl biimidazole], 2,2'-bis(o-nonylphenyl)-4,4',5,5'-tetraphenyl 2°°° [2,2'-bis(o-methyl phenyl)-4,4',5,5'-tetraphenyl biimidazole], 2,2'-bis(o-methoxyphenyl)-4,4',5 , 5'·tetraphenyldiimidine [2,2,-bis(o-methoxyphenyl)-4,4,5,5,-tetrapheny lbiimidazole], 2,2'-bis(o-ethylbenzene) 4,4',5,5'-tetraphenyldiimidazole [2,2'-bis(o,ethylphenyl)-4,4',5,5'-tetraphenyl biimidazole], 2,2'- Bis(p-methoxyphenyl)-4,4' ,5,5'-tetraphenyldiimidazole [2,2'-1^(?-methoxyphenyl)-4,4',5,5'-tetraphenylbiimidazole], 2,2,-double P,2,,4 ,4,-tetramethoxyphenyl)-4,4,5,5'-tetraphenyl bis[2,2',4,4'-tetramethoxyphenyl-4 ,4',5,5'- 23 201243497 tetraphenylbiimidazole], 2,2'-bis(2- chlorophenyl)_4,4',5,5,_tetraphenyl*- σ米0 sitting[2,2 ~bis(2-chlorophenyl)-4,4,5,55-tetraphenyl biimidazole], 2,2'-bis(2,4-dichlorophenyl)·4,4,5,5,-tetraphenyl 2,2'-bis(2,4-dichlorophenyl-4,4',5,5'-tetraphenylbiimidazole] and the like. The above benzophenone-like compounds such as thioxanthone, 2,4-diethylthioxanthanone, thioxanthone-4-sulfone , benzophenone, 4,4'-bis(dimethylamino)benzophenone, 4,4'-bis(diethylamine) diphenyl Oxanone [4,4'-bis (diethylamino) benzophenone] and the like. Specific examples of the above α-diketone compound include: benzil, acetyl, etc.; specific examples of the keto alcohol compound: benzoin, etc.; specific of the ketol ether compound For example: benzoin methylether, benzoin ethylether, benzoin isopropyl ether, etc.; specific examples of phosphine oxide compounds: 2, 4 ,6-trimethyl-benzoyl diphenylphosphine oxide, bis-(2,6-dimethoxybenzoquinone)-2,4,4-tridecylbenzene (bis-(2,6-dimethoxy-benzoyl)-2,4,4-trimethylbenzyl phosphineoxide], etc.; specific examples of terpenoids such as anthraquinone, 1,4-naphthalene (l , 4-naphthoquinone), etc.; specific examples of halogen-containing compounds such as: phenacyl chloride, tribromomethyl phenylsulfone, tris(trichloroindenyl)-s-three It benzene [tris(trichloromethyl)-s-triazine] 24 201243497 Second butyl peroxide (di_ et al; peroxides For example: two tertbutylperoxide) and the like. Among the above photoinitiators (C_3), preferred are: 2-gangyl-2·indole, indole dimethylamine-1-(4-ifu-like phenyl) dibutyl _, 2, 2, _ Bis(2,4-dichloro 4,4',5:5' tetraphenyl di-salt, di-bis(diethylamine)-benzonitrile-bens 2 base 2)··· bis(o-chlorophenyl) )-4,4',5,5'-four stupid base two p meters saliva and so on. The light-initiating agent of the photoinitiator (c-i), the photoinitiator (c_2), and the photoinitiator on both sides of the photoinitiator may be used in combination or in combination. The amount of the photoinitiator (C) based on the ethylenically unsaturated group-containing compound (B) (10) is generally 2 to a part by weight, preferably 5 to 10 parts by weight, more preferably 10 to 150 parts by weight. Parts by weight. Organic solvent (D) In the present invention, the solvent (D) is capable of dissolving the soluble resin (VIII), the compound (B) containing ethylenic unsaturation, and the photoinitiator (〇, and does not react with the above components, It is preferred to have a suitable volatility. Specific examples of the above solvent (D) are: ethylene glycol monodecyl ether, ethylene glycol monoethyl hydrazine, diethylene glycol monoethyl ether, diethylene glycol single positive Propyl ether, diethylene glycol mono-n-butyl sulphate, triethylene glycol monomethyl sulphate, triethylene glycol monoethyl propylene glycol, propylene glycol f methyl hydrazine, propylene glycol monoethyl amide, dipropylene glycol monomethyl phthalate, dipropylene glycol Monoethyl (tetra), dipropylene glycol mono-n-propyl sulphide, dipropylene glycol mono-n-butyl fluorene, tripropylene glycol monomethyl acetonide, tripropylene glycol monoethyl sulphide (poly) singly diol singly; A pair of vinegar vinegar _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Dimethyl ether (d material (10)), 25 201243497 diethylene glycol decyl ethyl ether, diethylene glycol diethyl ether, tetrahydrofuran and other scales, 曱乙_ a ketone of cyclohexanone, 2-glycol I, 3-heptane, etc.; 2 argon; a lactic acid esterified ester such as methyl propyl propionate or ethyl 2-hydroxypropionate; Ethyl propionate, 2-ethyl 2-mercaptopropionate, decyl 3-methoxypropionate, ethyl decyloxypropionate, decyl 3-ethoxypropionate, 3- Ethyl ethoxy propionate, ethyl ethoxyacetate, ethyl acetate, 2-methyl 3-methylbutyric acid, 3-methyl-3-decyloxybutyl acetate, 3 _曱基_3_曱 butyl butyl propionate ^ ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isopropyl acetate, n-amyl acetate, isoamyl acetate, C N-butyl acrylate, acetoacetate, n-propyl butyrate, isopropyl butyrate, n-butyl butyrate, methyl pyruvate, ethyl pyruvate, n-propyl pyruvate, methyl acetate , other esters such as ethyl acetate, ethyl 2-oxybutyrate; aromatic furnaces such as toluene and xylene; N. mercapto pyrrolidone, n, N-dimercaptomethylamine, n, An acid-reducing amine such as n-dimethyletheneamine. The solvent (D) listed above is ethyl 3-ethoxypropionate or propylene glycol monoethyl. Acetate is preferred. The above solvent (D) may be used singly or in combination of two or more. The solvent (p) is usually used in an amount of 500 to 3,500 parts by weight based on 100 parts by weight of the soluble resin (Α). It is preferably from 8 Å to 3,2 Å (parts by weight); more preferably from 1,000 to 3,000 parts by weight. Pigment (Ε) The pigment (Ε) of the present invention may be an inorganic pigment or an organic pigment. A metal compound such as a metal oxide, a metal salt or the like, which is specifically, for example, a metal oxide of iron, chromophoric, copper, titanium, magnesium, lanthanum, ytterbium, yttrium, and the like, and a composite oxide of the foregoing metal 26 201243497 Specific examples of organic pigments: c.  I. Pigment Yellow 1,3,11,12,13,14,15,16,17,20,24,31,53,55,60,61,65,71,73,74,8 1,83,93,95 , 97,98,99,100,101,104,106,108,109,110,113,114,1 16,117,119,120,126,127,128,129,138,139,150,151,152,153,1 54,155,156,166,167,168,175; C.  I. Pigment orange 1,5,13,14,16,17,24, 34,36,38,40,43,46,49,51,61,63,64,71,73; C.  I·Pigment Red 1,2,3,4, 5,6,7,8,9,10,11,12,14,15,16,17,18,19,21,22,23,30,31, 32,37,3 8,40,41,42,48:1,48:2,48:3,48:4,49:1,49:2,50:1,52:1,53:1,57 , 5 7:1,57:2,58:2,58:4,60:1,63:1,63:2,64:1,81:1,83,88,90:1,97,10 1,102,104,105,106,108,112,113,114,122,123,144,146,149 , 15 0,151,155,166,168,170,171,172,174,175,176,177,178,179,18 0,185,187,188,190,193,194,202,206,207,208,209,215,216,22 0.  224. 226. 242. 243. 245. 254. 255. 264. 265 ; C.  I. Pigment Violet 1,19,23,29,32,36,38,39 ; C.  I. Pigment blue 1,2,15,15:3,15:4,15:6, 16,22,60,66; C.  I. Pigment Green 7,36,37 ; C.  I. Pigment brown 23,25,28 ; C.  1.  Pigment black 1, 7, etc. These pigments may be used alone or in combination of two or more. In the photosensitive resin composition for a color filter of the present invention, the average particle diameter of the pigment (E) is usually from 60 nm to 140 nm, preferably from 70 nm to 130 nm', more preferably from nm to 120 nm. A photosensitive resin composition for a color filter using the pigment (E) having the above average particle diameter, particularly when the average particle diameter of the pigment (E) is from 70 nm to 130 nm, high contrast and high color can be obtained. Saturation color filter. Additive (F) The photosensitive resin composition for a color filter as described above may more preferably include 27 201243497 Additive (F) 'wherein the additive (F) may include, but is not limited to, for example, a filler, an adhesion promoter, and an anti-resistance An oxidizing agent, an ultraviolet absorber, an anti-agglomerating agent, and the like. Specific examples of the above additive (F) include: a filler of glass and aluminum; a vinyl dimethoxy oxy-stone, a vinyl triethoxy stone, and an ethylene tris(2-methoxyethoxy) stone eve , N-(2-aminoethyl)_3_aminopropyldecyldimethoxyxanthine, N_(2-aminoethyl)_3_aminopropyltrimethoxyl residue, 3-aminopropyl three Ethoxy Wei, 3·glycidylpropyltrimethoxymethane, 3_glycidylpropylpropyl, dimethoxyoxywei, 2·(3,4-epoxycyclohexyl)ethyltriazine Oxygen Wei, 3_ isopropyl propyl dimethoxy wei, 3 • propyl propyl trimethoxy wei, 3 methyl propyloxy propyl tri methoxy wei (for example, trade name ΚΒΜ·5〇3; Shin-Etsu Chemical Co., Ltd.) 3 thiol-propyl dimethyl oxalate, such as sulphur, etc.; thiobis(4-methyl-6-heptene benzene), 2,6-di-butyl, etc. Antioxidant; ^ (3-t-butyl · 5 · methyl 2, phenyl) _ 5 • silk based Wei, benzophenone and other ultraviolet absorber; and sodium polyacrylate anti-aggregation agent. In general, the amount of the above-mentioned additive (F) is generally from 〇 to 1 G by weight, preferably from q to 6 parts by weight, and from 0 to 3 parts by weight based on 1 part by weight of the soluble resin (Α). The best is the best. . In addition, the above additive (7) may further include a surfactant, which is specifically, for example, a polyethylene oxide eleven-burning bond, a polyepoxysulfonate, a polyepoxybutene (IV), an epoxy (tetra) silk polyepoxy. Ethylene-based squid, such as polyethylene-based fine, polyepoxy-b-butadiene base, polyethylene glycol lauric acid vinegar, polyethylene glycol distearate, etc. Transesterified fatty acid _, · fatty acid changed to f polyg-type; grade 3 amine modified polyamino carboxylic acid vinegar; the following is the trade name: KP (Shin-Etsu Chemical Co., Ltd.), SF-8427 (Ding Dow C〇) Rning Silic〇ne), ton - (Kyoeisha Grease 28 201243497 Industrial), F_T〇P (made by Tochem Products), Megafac (made by Otsuka Ink Chemical Industry Co., Ltd.), Fluorade (Sumitomo 3M), Surfl〇n (Asahi Glass) and so on. The above surfactant may be used alone or in combination of plural or more. 0 Based on 100 parts by weight of the alkali-soluble resin (A), the surfactant is generally used in an amount of from 0 to 6 parts by weight, and from 3 to 6 parts by weight. It is better. The above surfactant can contribute to the improvement of the coatability of the photosensitive resin composition for a color filter described above. Photosensitive resin composition for color calendering sheet The photosensitive resin composition for color filters of the present invention generally comprises the above alkali-soluble resin (A), an ethylenically unsaturated group-containing compound (B), and a light-initiating layer. The agent (C), the organic solvent (D) and the pigment (E) are placed in a stirrer and stirred to be uniformly mixed into a solution state, and if necessary, a filler, a adhesion aid, an antioxidant, an ultraviolet absorber, or the like may be added. Additives such as anti-aggregation agents and surfactants. The method for producing the photosensitive resin composition for a color filter of the present invention is not particularly limited. For example, the pigment (£) may be directly added to a photosensitive resin composition for color filter dispersion, or A part of the pigment (A) is dispersed in a part of the medium containing the alkali-soluble resin (A) and the organic solvent (D) to form a pigment dispersion liquid, and then the compound (B) containing an ethylenically unsaturated group is further mixed. The photoinitiator (C), the alkali-soluble resin (A) and the remainder of the solvent (D) are obtained. The dispersion step of the above pigment (E) can be carried out, for example, by a bead mill.  Mixing the above components with a mixer such as (beads mil1) or a roll mill to carry out the composition of the photosensitive resin composition of the color filter obtained by FW, and the E-type viscosity meter (Dongji Industry Co., Ltd.) The system "eld-type sticky jump") is a paste with a temperature of 25t and a rotation speed of 2〇qing, measured and manufactured, and stored under the pressure of temperature and hunger for 7 days. When the time-dependent viscosity of the composition of the silk resin is 7 days, and the change rate of the initial viscosity _ degree before storage is less than ig %, the pigment dispersion property can be obtained, so that the photosensitive color of the comparatively preferred color light-receiving sheet can be obtained. The resin composition, and the viscosity change rate is preferably less than 9%, more preferably less than 8%. Method for manufacturing color filter The color filter and light forming method of the present invention can be mixed into a color of a state by a rotary coating, a cast coating or a (four) coating coating method, and the light sheet is made of a photosensitive composition. The object is coated on a substrate. After coating, firstly dry under reduced pressure|except for most of the solvent' and then pre-baked ((4) as (4) way to remove the _ into - pre-baked film. Among them, under reduced pressure and pre-baked conditions, according to The type of each component varies depending on the ratio. Usually, the drying under reduced pressure is carried out for 1 second to 60 seconds under the house temperature of 〇~mHg, and the pre-baking is carried out at 7〇~ ii〇Cjm degrees for 丨 minutes~ 15 minutes. After pre-baking, the pre-baked coating film is exposed between the specified masks, and is immersed in the developing solution at a temperature of 23±rc for 15 seconds to 5 minutes for development, and is not partially removed to form The light used in the pattern 匕 exposure is preferably an ultraviolet ray such as an α g line, an h line, or an i line, and the external line device may be a (super) high pressure mercury lamp and a metal _ element lamp. The specific material of the above substrate is, for example, for liquid crystal display. An alkali-free glass-sodium dance glass, a hard glass (Pyrus glass), a quartz glass, and a transparent conductive film attached to the 201243497 glass, etc.; or a photoelectric conversion device substrate for a solid-state imaging device or the like (eg, 矽Substrate), etc. These substrates are generally formed by isolating each element The black matrix of the color layer. Further, for example, sodium hydroxide, hydrogen hydroxide, sodium carbonate, sodium hydrogencarbonate, potassium carbonate, potassium hydrogencarbonate, sodium citrate, sodium decyl citrate , ammonia, ethylamine, diethylamine, dimethylethanolamine, tetramethylammonium hydroxide, tetraethylammonium hydroxide, choline, pyrrole, piperidine, 1,8-diazabicyclo-5 (5,4, 〇) _7_ undecene and other basic compounds. The concentration of the developer is generally 〇. 〇〇1 to wt%, preferably 0. 005 to 5 wt% ’ is better. 〇; [to 1 wt%. When such a developer is used, it is usually washed with water after development. Next, the pattern is air-dried with compressed air or compressed nitrogen, and then post-baked by a heating device such as a hot plate or an oven. The post-baking temperature is usually 150 to 250. (:, wherein the heating time of the hot plate is 5 minutes to 60 minutes, and the heating time of the oven is 15 minutes to 150 minutes. The colors (mainly including red, green and blue) are repeated for the above steps. The color layer of the color filter is obtained. Secondly, an indium tin oxide (IT0) vapor-deposited film is formed on the halogen layer at a temperature of 220 ° C to 250, and if necessary, the etching and wiring of the IT 〇 coating is performed. Further, a polyimine for a liquid crystal alignment film is coated and fired to obtain a color filter for a liquid crystal display element. Method for Producing Liquid Crystal Display Element The liquid crystal display element of the present invention is formed by the above color filter A color filter substrate formed by a method for manufacturing a light sheet, and a driving substrate provided with a thin film transistor (TFT), and an intervening gap (cell gap) is disposed between the two substrates In the peripheral portion of the two substrates, the 201243497 is bonded with a sealing agent to fill the gap between the surface of the substrate and the sealing agent to fill the liquid crystal to seal the injection hole to form a liquid crystal cell. Then, On the outer surface of the liquid crystal cell, that is, on the other side surface of each substrate constituting the liquid crystal cell, the polarizing plate is bonded to obtain a liquid crystal display element. As for the liquid crystal to be used, that is, a liquid crystal compound or a liquid crystal composition The liquid crystal compound and the liquid crystal composition are used in any case, and the liquid crystal alignment film to be used is used to restrict liquid crystal molecules, and is not particularly limited herein. The technique of forming a liquid crystal alignment film by any of the organic materials may be any one of the technical fields of the present invention, which is well known to those skilled in the art of the invention, and is not the focus of the present invention, so that it is implemented at several additional costs. The method is used to illustrate the application of the present invention, but it is not a departure from the subject of the present invention. In the spirit and scope of the month, various changes and retouchings can be made. [Embodiment] -1: The method for manufacturing the soluble resin (A1), the nitrogen gas population of the four-necked cone bottle of the two-dimensional product G (10) ml, the amount of the scrambled mixture, and the nitrogen gas and the nitrogen gas are shown in Table 1. oxygen Propylene I ethyl ester (hereinafter referred to as EEP) 200 weight l〇〇t, the solvent is disturbed when the 'oil bath temperature is raised to the base of the two" table shows the monomer mixture: 2_methyl propylene ethoxylated曰草体 (hereinafter referred to as HOMS) 20 parts by weight, dicyclopentanyl acrylate 32 201243497 FA 酉 酉 monomer (hereinafter referred to as FA_512A) 30 parts by weight, methacrylic acid methoxy butyl methoxymethyl ester Monomer (hereinafter referred to as 〇XMA) 1〇重里十: 10 parts by weight of methyl propyl phthalate monomer (hereinafter referred to as hydrazine), styrene monomer monomer, abbreviated as SM) 3G parts by weight, and initiator for polymerization: 2,2,_ azobis-2·methylbutyronitrile (hereinafter _ ΑΜΒΝ) 6 parts by weight were added to the four necks = bottle. . The monomer mixture and the initiator for polymerization are continuously added in the first stage of the polymerization. The reaction temperature in the first stage polymerization process is maintained at loot: and the polymerization time is 3 hours. Then heat up to 120. (: The second stage polymerization process is carried out, the polymerization time is 4 hours. After the polymerization is completed, the polymerization product is taken out from the four-necked flask, and the solvent is devolatilized to obtain an alkali-soluble resin (A-1), which is infiltrated by the gel. The weight average molecular weight, the arithmetic mean molecular weight, and the Q value were measured by a chromatography method, and the results are shown in Table 1. Synthesis Example A-2 to A-10: Method for Producing Alkali Soluble Resin (A-2 to A-10) Synthesis Examples A-2 to A-10 were carried out in the same manner as in the synthesis example VIII-丨, except that the types and mixing amounts of the monomers for polymerization, the types and amounts of the initiators, and the manner of monomer feeding were changed. The reaction temperature, the polymerization time, and the like, the formulation, the reaction conditions, and the Q value are all shown in Table 1. Method for Producing Photosensitive Resin Composition for Color Filters The following Tables 1 to 7 were prepared according to Table 2 and compared. The color filter of Examples 1 to 5 was made of a photosensitive resin composition. Example 1 100 parts by weight (solid portion) of the alkali-soluble resin (Al) obtained in the above Synthesis Example, and dipentaerythritol hexaacrylate shown in Table 2 were used. (DPHA, hereinafter referred to as B-1) 140 parts by weight, 1-[ 9-ethyl-6-(2-methylphenylhydrazino)-9H-flavor 33 201243497 -3--3-Substituent]-Ethyl ketone 1-(0-Ethyl ketone) (hereinafter referred to as C i5 parts by weight) , phenylthio)phenyl]-Xinyuan], 2_H (〇_benzene-based base 5 parts by weight, 2,4·bis (trimethyl fluorenyl)-6-p-methoxy group stupid vinyl + three gas Benzene (hereinafter referred to as C-2) 4 parts by weight, 2,2, fluorene (o-phenylene)_4,4,5,5,-tetraphenyldiimene (hereinafter referred to as 03) 4 parts by weight, CI Pigment Red 254 (hereinafter referred to as Ei) m parts by weight, adding solvent 3_ethoxypropionic acid B (hereinafter referred to as D-1) 1,300 parts by weight and propylene glycol 曱 醋酸 acetic acid vinegar (hereinafter referred to as d_2) 700 After the weight portion is dissolved and mixed by "shaking stirring", a photosensitive tree test composition for a color calender sheet can be prepared, and the color fiber sheet is evaluated by the measurement evaluation method described later for the photosensitive resin composition. The results obtained are shown in Table 2. Examples 2 to 7 and Comparative Examples i to 5 Examples 2 to 7 and Comparative Examples 1 to 5 were produced in the same manner as in the case of the photosensitive resin composition of the color light sheet of Example i. The method of operation differs in Examples 2 to 7 and Comparative Examples i to 5 The type and amount of the photosensitive resin composition material for the color filter are changed. The details and subsequent δ parity results are shown in Table 2. Evaluation method: 匕月|| The resin composition and the sensitized sapphire layer (or the glutinous layer) can be tested according to the following steps: Q value, residual monomer 耋 'viscosity change rate, contrast and color difference before and after development to evaluate the spider Yes. Q value: The weight average of the alkali-soluble resin (Α) prepared by the method is 201234 201243497 (Mw), the arithmetic mean molecular weight (Μη), and the Q value (Mw/Mn), which are based on the gel permeation of the Waters Company. Gel Permeation Chromatography (GPC) and determined according to the following conditions: Liquid Chromatograph: Waters 1515 Isocratic HPLC Pump Column: GPC/SEC Columns, PL gel: 5μιη 100/500/1000/ 10000 A (manufactured by Polymer Laboratories Co., Ltd.) Detector: Waters 2414 Refractive Index Detector Mobile phase: tetrahydrogen ° ° South (flow rate l. Oml/min) 2. Residual monomer amount: First, an unsaturated monomer (a-2_1) containing a tricyclodecane skeleton and an unsaturated functional group in one molecule and/or a dicyclopentadiene skeleton and an unsaturated group in one molecule are confirmed. The standard of the residual monomer of the functional group unsaturated monomer (a-2-2) is formulated into a standard solution, and then a gas chromatograph equipped with a flame ion detector (Agilent Technologies, Agilent Technologies, model HP7890A) GC; HP-5 capillary column) analysis and establishment of a calibration curve. Then, 'the color filter is diluted with sterol by 1 〇 times with a photosensitive resin composition, filtered, and analyzed by a gas chromatograph equipped with a flame ion detector' and compared with a calibration curve. The amount of residual monomer (ppm). 3. Viscosity change rate: The color sensitivity of the color filter was measured under the conditions of a temperature of 25 ° C and a rotation speed of 20 rpm using an E-type viscosity meter (ELD type viscosity meter (rE_80l), manufactured by Toki Sangyo Co., Ltd.). The viscosity of the resin composition. The initial viscosity of the photosensitive resin composition for a color ray sheet which has just been produced is measured, and (b) the photosensitive resin composition for a color filter which is stored for 7 days at an atmospheric pressure of 45 〇C. The viscosity of time. The obtained viscosity value can be calculated by the following formula (IV). 35 201243497 Viscosity change rate = viscosity lnrw, τν^ * (3⁄43⁄43⁄4-χ brain (ιν) 4. Contrast: The color and the light-sensitive sheet are coated on a glass substrate of 100 mm×100 mm by spin coating, and dried under reduced pressure at a pressure of 100 mmHg for 30 seconds, and then pre-baked. The temperature is 8 〇.匚, time 2 minutes, can form a film thickness 2. 5/zm pre-baked film. The pre-baked coating film was irradiated with ultraviolet light (exposure machine Canon PLA-501F) at a light amount of l〇〇mj/cm2, and then impregnated with a developing solution at 23 ° C for 1 minute, washed with pure water, and then with 235 °. After baking for 60 minutes, it can form a film thickness on the glass substrate. Photosensitive resin layer. 1A and 1B are schematic views showing a partial device for evaluating the contrast of a photosensitive resin layer according to an embodiment of the present invention, wherein the polarizing plate 10a of FIG. 1A has a polarization direction and a polarizing plate. The polarization directions of 3b are parallel to each other, and the polarization direction of the polarizing plate 10a of FIG. 1B and the polarization direction of the polarizing plate i〇4b are perpendicular to each other. For the contrast measurement, the photosensitive resin layer 101 is placed between the polarizing plate 10a and the polarizing plate 103b by taking the apparatus of Fig. 1A as an example. The light emitted from the light source 1〇5 is sequentially transmitted through the polarizing plate 103a, the photosensitive resin layer 1〇1, and the polarizing plate 103b, and then measured by a luminance meter 1〇7 (Model BM-5A, manufactured by Topcon Corporation, Japan). The amount of light (cd/cm 2 ) of the polarizing plate 10 〇 3b is A. Similarly, with the apparatus of FIG. 1B, the light irradiated from the light source 丨〇5 sequentially passes through the polarizing plate 10a, the photosensitive resin layer 1〇1, and the polarizing plate i〇4b, and is then illuminated by a luminance meter 1〇7. The amount of light (cd/cm 2 ) transmitted through the polarizing plate 104b was measured as B. By calculating the ratio of the amount of light a to the amount of light B (light amount a / amount of light B), the contrast of the photosensitive resin layer can be obtained, 36 201243497 and the evaluation criteria are as follows: ◎: contrast 22500 〇: 2000 $ contrast <2500 △ : 1500$ contrast <2000 X : Contrast <1500 5. Color difference before and after development: The color filter was coated on a glass substrate of 100 mm×100 mm by spin coating with a photosensitive resin composition, and dried under reduced pressure at a pressure of about 100 mmHg. About 30 seconds. Then, it was prebaked at a temperature of 80 ° C for 2 minutes to form a prebaked coating film having a film thickness of 2.5 / zm. Thereafter, the chromaticity (L*, a*, b*) was measured with a colorimeter (manufactured by Otsuka Electronics Co., Ltd., model MCPD). Next, the pre-baked coating film was irradiated with ultraviolet light (exposure machine Canon PLA-501F) at a light amount of 100 mJ/cm 2 , and then the prebaked coating film was immersed in a developing solution at 23 ° C for 1 minute, and washed with pure water. . After that, the chromaticity change is measured again, and the chromaticity change (AEab*) is calculated and evaluated by the following formula (V): AEab* = ^{(AL)2+(Aa)2+(Ab)2} (V) ◎: chromaticity change AEab* <2 〇: 2$ chromaticity change AEab* <4 △ : 4$ Chromaticity change AEab* <6 X : Chromaticity change Z\Eab* 26 From the results of the first to seventh embodiments, it is understood that the unreacted monomer (a-2-) in the photosensitive resin composition for a color filter l) and the monomer (a-2-2) has a residual monomer content of less than 1000 ppm, and when the Q value of the soluble resin (A) is less than 2.5, the color filter used for the photosensitive filter is composed of a photosensitive resin layer. Will perform better 37 201243497 chromatic aberration and contrast before and after development, so it is better to compare m to "=^ can achieve the purpose of the present invention. The contrast is less than ideal. The color difference of the composition layer before and after development The compound, the composition, and the reaction strip feel ==:: The present invention has been disclosed in the above-described embodiments of the present invention. Any of the technical fields in which the present invention pertains can be deviated from the spirit and scope of the present invention, and t can be variously = green in the absence of the protection scope of the present invention. Included in the patent scope = the simple description of the figure] μ ΐ = map and 1 b ® miscellaneous according to the present invention - the implementer A schematic diagram of a partial device for evaluating the contrast of a photosensitive resin layer. [Description of main component symbols] 101 · Photosensitive resin layer: Light source 103a/103b/104a/104b: Polarizing plate 107: Luminometer 38 201243497 5Μ^ΉΙ^ί香^ 4nw(v)l^#lii, 姨Je-迤: < I hide g oc CC· CnJ cvi CO ςνί crs C5 iTsI iO ςνί ^r csi <x> c^i c <t second segment S? contains Φ7 CM CO Cvl i -c· it reaction temperature (t) § o to o § 1 § II § tired one P segment s ^ _ 铋, one CC *«r *»r CC CO ΙΓ5 !M iT? OJ reaction s degree CC) ggo 〇ggo monomer feed mode continuous addition 1 continuous addition | 1 continuous addition 1 continuous addition I 1 continuation addition 1 |-time addition | add I once Add 1 to the flail and add 1 in succession. | Composition (f£) Solvent HEP Ο <>* ο ο S ο s ο s o Ο S ο r < ο <s ο 沄 starter ADVN v〇rr·, Ό Ό v〇1 Ό m JTi d \om \D | Co-polymerization | (a-3) 1 (a-3-2) 1 HEMA m沄S Ο 沄•Λ *r, S •λ S BzMA •r, S 1 Ο ooo 〇ο Ο 丨(a-3-1) 1 OXMA Ο sos GMA ο (a-2) r? A vS FA-512A沄FA-512M ssss FA-511 A s 1 i>2-l) J NK ester A-DCP Ο § NK ester DCP m (a-1) MAA o 沄o HOMS »n «Λ 8 Synthesis Example 7 - < cp - < • <r · < L〇 4: CO -S: - < cc <σ; - < 1 Λ-10 --XJUU-qwxxo-lslusdopxus --XJOClpslu^q^&OIXSSad-ox-Q §ι&-λ§π3 <!-0χ-ω p'-UBUflxJUBtpsp^ .s^oaos this ^^饨

--"uu-aul IxqlsxxoJPXH- •Itdx^ STO%5«^§ ^Nsffl -qxjurt—xtpwj.-5 51-/0:^-3-11=111,^0-301(-1123^0- 2^13-) Oiqxjueqsn-XPP-Q 6ε 3-°3«蝤^0—TM^^dsf ^ .v&i-lr8----^^绞.--- 滔幻一-激-^结敢"-^8- Love 054 迓^讲笾踅15^8-harmonic^趑15 洇8-^"8-(硪卜^s77^°-co)5sse硪5-s-feu铨 chain费哫硪8- Child visit"¥你姝H^'-+it a7f^ hair? ^铃^-笾货'·1 so硪*^费砭铉^笾发^硪8- ^ sa^•卜硪^-00*^'?®--Lian 2 dw3 ΗΛΟΥ za>wIsκκ νκζω vs 1X0 vwo doa-VSS^M SQUl^ v--v£ s-'vi vu'vi WH SKOH 雄涅201243497 I Compare Η I λ 1 ίο» 1 1 1 »r, V, inch | 1300 I 1 "QQ 1 130 | 1 ri ON X 〇丨(10) 1 1 wo 1 •Λ. V» ••t | 1300 I 1 700 | 1 130 1 not | 00 ri o XX 1 100 1 1 140 1 V, »r· | 1300 I 1 700 1 1 u〇1 | 1266 I 1 2.4__1 MX <] Π 1 100 1 1] Milk 1 V, • Ti to inch | 1300 I 1 700_I 130 | 1337 1 2,6__1 v〇X \/ - M 〇〇1 1 140 1 »Γ, V, rt inch | 1300 I 1 —jo. —” 丨(9) 1 〇\ ri 0\ 0 \/ 1 tr Example 1 r- •Λ 1_140 | *Λ_ V, | 1300 I 丨7〇〇1 1 1 | 990 | 对 ri 二〇0 Ό 1_140 1 • Λ. Λ 1300 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I〇o 1 140 1 Vi V. Vi | 1300 I 1 700 | 1 130 1 503 1 r^i ri CO ◎ ◎ |__ 100! 1 100 1 〇«Λ •Λ TT | 900 I 1 lloo | 1L0 | 435 1 ri r- ◎ ◎' n 丨100 I | l_20" «Λ ir. 对 | lloo | | 900 1 | 130_ | 1 621 1 <·«% ri ON ◎ © - 1 100 I 1 140 I *Λ· , *r. ”· 1 | 1300 I 1 7〇〇__1 1 13〇I 00 ir. ◎ ◎. Ingredients|Α-Λ _ 1 |A-2 I [Α·3_ | Μ_1 lA^_I Μ 1 | A-7... I |AS I |A-9 I |a-io I |B-1 I _I \Czhl_ 1 ^_I |ς-2 1 Μ_I _1 jD〇___________ | ώ Ε-2 I _1 l(a-2)^6j Monomer 殳| Block c? Viscosity stability rate (%) 1 Before 彩彩浚I £ Alkali soluble tree wax (Λ) C4:Sf>>) Ethylene Unresolved compound (B.) (Respective part) Light-starting 剞(C) (Ί明份) Solvent (D) (Parts by weight) Dish (Κ) (heavy loan) Evaluation result 9 :-H To times 0 Ίϋ tss τ° SBno^dpIdxxotiJa-^'--w aJ0zt-e'3;3qIX8J=dcJJ?-.-.-,.t-xuu-dpt-q?o)ss-r! Rl «^ΝαΈ·«·^&^^χ05§·αν^Λ5ϊ30.δ3υ^βνδ4·Μ [(s-ax-xozui>q I o)r,all'2p — ".--. iuuso - "δη-οιφ-δη3—II] [(s-=xol&v:>u .. o) i Ϊ§3Ψ3-[JX-7-ozuq.ts. H6,--oy^ll-- Sf - c)· 9-i-ljv, 6]..I] ?Jelx.1un(-sut)efaluJ-ol'r-np.<.w2uud,-Q vl-iooeex'-q-ojfjlpx.we -uad·-0 s5r ϊ*4: 0 inch 9-1?3"-ι-Ίυ-3 times^core^one 0'3 sr,"^g.Iu1-3 83*2^®·^- ^·5z_a --0^^^^^-ΐ·α f^M^!,!Ki ,·°·0·'-·μ 2^^^.-^)^---^ υ ^65^ -^.5-^^0^^^-^0(^^^4)^-7: 'υ("•^cnv--'-s^^rsl^^-L't'ios·0 '^^)·1'-'Ι-υ a^-f^^.st^eo-f-vi'-c •tt-lG 二蜱沼讲泊』-〒珅°--77υ ^3⁄4.^ 3⁄4^^^) 5-sy 3-frrr s ^笾货^二1'-^^^^- i ώ ^ss

Claims (1)

201243497 VII. Patent application scope: I A photosensitive resin composition for color filters, comprising: a soluble resin (A), wherein the alkali-soluble resin is composed of a carboxylic acid group-containing unsaturated monomer (a-Ι) An unsaturated monomer having a tricyclodecane skeleton and an unsaturated functional group in one molecule (a-2-l) and/or an unsaturated monomer having a dicyclopentadienyl skeleton and an unsaturated functional group in one molecule ( A-2-2), and the monomer (a_i), the monomer (a_2-1), and other copolymerizable ethylenic monomers (a_3) other than the monomer (a_2-2) a copolymer obtained by polymerization, and the Q value of the alkali-soluble resin (A) is less than 2.5; a compound (B) containing an ethylenically unsaturated group; a photoinitiator (C); an organic solvent (D); and a pigment ( E), . The photosensitive resin composition for the color filter is 100% by weight, and the total monomer amount of the unreacted monomer (a-2-l) and the monomer (a_2_2) is less than 1000 ppm. 2. The photosensitive composition for the color filter described in the patent range of the above-mentioned patent range, wherein the color (four) light sheet is stored for 7 days under the atmospheric pressure of the temperature using the photosensitive tree test substance and has a The viscosity at the time, and the viscosity change at 1 degree is less than 1% by weight relative to the pre-preservation-initial viscosity. 3. The color filter according to the third paragraph of the patent application is composed of a photosensitive composition. The towel molecule contains a tricyclic ten-yard skeleton and an unsaturated monomer (a·2·1). It is selected from the group consisting of dimethanol tricyclodecaned acid 201243497 vinegar, dimethanol, tricyclic ten yards, dimethyl propylene ketone, tricyclic decyl diol dipropylene vinegar, and tricyclic phthalic acid dipropylene. A group of thioglycolic vinegars. 4. The photosensitive resin composition for a color filter according to the invention of claim 1, wherein the molecule contains an unsaturated monomer (a_2-2) having a dicyclopentadiene skeleton and an unsaturated functional group. It is selected from the group consisting of dicyclopentanyl (meth) acrylate, bicyclononene (meth) acrylate, dicyclopentyloxy (meth) (tetra) acid, and dicyclopentenyl (meth) acrylate. Ethyl ester is classified into one group. 5. The photosensitive resin composition for a color-fired sheet according to the first aspect of the invention, wherein the photosensitive resin composition for the color (four) light sheet is 100% by weight, and the monomer is unreacted (&;_2_丨) and the total amount of residual precursor of the monomer (a_2_2) is less than 900 ppm. 6. The photosensitive resin composition for a color light-receiving sheet according to the first aspect of the invention, wherein the photosensitive color composition for the color light-passing sheet is 100% by weight. The unreacted monomer (a_2_1} and the monomer (a_2_2) total residual grass body system is less than 800 ppm. 7. The photosensitive resin for color light film according to the above-mentioned patent scope a composition wherein the ethyl-monomer (IV) comprises a vinyl monomer (a-3-l) having an epoxy group structure. 42 201243497 A tree composed of a compound of the white group r-propyl and a compound of an epoxy-t-group The color filter for the color filter and the light sheet described in item 1 of the monthly profit range, η\ , and the amount of the monomer for copolymerization based on the alkali-soluble resin (Α) is ιοΓ*^^2·1), the single The total amount of the body (a·2.2) and the monomer (a_3) is 1 part by weight of the 'G. The monomer (4) is 5 parts by weight to 3 parts by weight, and the total of the monomers: -1) and the monomer (a_2_2). The amount is 5 parts by weight to 30 parts by weight to 9 parts by weight of the precursor (a.3). The color filter used in the first aspect of the invention is the photosensitive yttrium, and the object, wherein the Q value of the soluble resin (A) is less than 23. The color enamel and light sheet used in the first paragraph of the patent patent range, the sensation, 曰, and the product 'the Q value of the soluble resin (A) is less than 2. Bu 1 to the flute 11 color county film' It has the use of the record as set forth in the scope of the patent application. —Xie Lai's color filter phase money (10) lipid composition 43