TW201240602A - Herbicidal bis-nitrogen-containing oxo heterocycles - Google Patents

Abstract

Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, A is a radical selected from the group consisting of and B1, B2, B3, T, R1, R2 R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling undesired vegetation comprising contacting the undesired vegetation or its environment with an effective amount of a compound or a composition of the invention.

Description

201240602, invention description: [Technical field to which the invention pertains] 0X0 The present invention relates to certain bis-nitroxyl heterocyclic rings (bis_nitmgen), salts and compositions thereof, and their use for controlling undesired plants Some intermediates and methods for preparing the nitrogen heterocycle and its salts. [Prior Art] The control of unwanted plants is required to achieve high crop yields. Selective control for weed growth (selective con_e is extremely desirable, especially for deuterated contr〇i) 疋 corn 'potato nr=r, soybeans, beets, useful crop towel Ml, ship crop weeds here 15 = This reduces the cost of the consumer. It is important to be a non-user. There are many things for this purpose = ’ ’ 但 对 对 对 对 : : : : : : : : : : : : : : : 更 更 更 更 更 更 更 更 更 更 更 更 更 更 更 更.H No. 2007/088876 Revealing *D D biting ketone compound \

Ri r2 5 201240602 wherein, in particular, R1 is a CrC6 leukox group; a amide group or a nitro group; and A is a herbicide as described in the disclosure of hydrogen and cyanide. A.1 to A" of the present invention The bis-nitrogen-containing heterocyclic ring of the present invention is not disclosed in the publication. SUMMARY OF THE INVENTION The present invention is directed to a compound of the formula (including all stereoisomers =), And its salt, the agricultural product containing the same, and the use thereof as a herbicide: 10

Wherein A is a radical selected from the group consisting of 15

201240602 B1 and B3 are each independently a free radical selected from the group consisting of

C-1 R20 and C-2 B are radicals selected from the group consisting of: 10

C-5

(〇)„ II C-6 and R20 I VIII C-7 or 15

Rl is -wic(=EV4, -Wilc(=E2)r25, WlC(=E3)LR26 ' -W1S(0)xNR-C(=0)R27 ^ ^^(0)^^0(-0)^ 27, w1s(0)xnr28s〇2lr27 or -W1CN; or R1 is N(R4G)R41; or R1 is _GA or -W2GA; each GA is a 4- to 7-membered carbocyclic ring including a selected from c ( =〇), C(:S), C(=NR29), C(iv), or (iv)% of n(r29)2, or a 6- to 12_ member and or partially saturated carbon snail 20 ring (Carb°SpiIOCydic Or a heterospirocyclic %_system, which optionally includes an element selected from the group consisting of 〇), C(-S), c(=NR29), C(=N_OR3〇), or <^NN(R) a ring of 2, each ring or ring is selectively substituted by a substituent on the ring member of r21 and on the ring member; or a partially saturated ring system containing a carbon ring member Protecting a nitrogen 3 coater, the ring is selectively subjected to up to 2 selected from the group: the substitution of r21 on the member and the substitution of r22 on the nitrogen ring member with E as 〇, s, 服28, n〇r28,丽(π)〗, n-cn or N_N〇2; each 1 is independently 〇, 卿31) or 8; 条: is tE3 is 0, then L is not Ο; 匸R, R26 and R27 are independently hydrogen; 4Ci_C6 Alkyl, 2 G alkenyl, C^-C: 6 alkynyl or C3_C6 cycloalkyl, each selected ^ Substituted with one or more substituents, the substituents are selected from the group C consists of halogen, CN, N02, hydroxy, alkoxy CRC4,

Cl C4 alkylsulfinyl group, CrC4 alkanesulfonyl group, crC4 alkylamino group, C^C:8 dialkylamino group, c3_c6 cycloalkylamino group and (Ci_c4,yl)cvc:6 cycloalkylamine group Group; R29 is independently H, Ci-C0 alkyl or Cl-C6 alkyl; R = H, C] -C6 alkyl, CrC6 i alkyl, Ci-C6, carboxyl, CrC6 alkanesulfonyl Or crc6 torsansulfonyl; each Q and Q2 is independently 〇, S or N(R3)); q3 is a C1-C4 exudyl group which is selectively substituted with up to 4 substituents' Substituted from a substituent of a CrC6 alkyl group, a C2-C6 alkenyl group, a C2-C6 alkynyl group and a C3_C6 cycloalkyl group; r30 is independently hydrazine, Ci_C6 alkyl group or (^-〇6 halogen-based group; R31 is independently Η, C "C6 alkyl or c]-C6 _ Hyun• base; R32 is Η or Ci-C6 炫•基, each X is 0, 1 or 2; W5 is CrC6 alkyl; W1 is CVC6 alkyl, C2- C6 alkenyl or C2-C6 alkynyl; or -(CH2)2〇CH2- or -(ch2)3〇CH2-; W2 is CrCdt alkyl; R2 is phenyl or -W3(phenyl)' Optionally substituted with up to five substituents selected from R21 on the ring member; or -G or -W4G; or hydrazine, cyano, hydroxy, amine, nitro, _CHO, -C(=0)0H' -C(=0)NH2 ' -C (=S)NH2 '-C(=0)NHCN, -C(=〇)NHOH, -SH, -S02NH2, -S02NHCN, _S〇fine OH, -SF5, -NHCHO, -NHNH2 ' -NHOH ^ -NHCN '-NHC(=0)NH2 'CrC6 alkyl, c2-c6 alkenyl, c2-C6 alkynyl, crc6 haloalkyl, C2-C6 S alkenyl, C2_C6-alkynyl, c3_c8 cycloalkyl, C3-C8 Licycloalkyl, c4_Cidecanecycloalkyl, c4_Cl〇 ring alkyl, CVC14 cycloalkane, c4-C10 halocycloalkyl, CVCu alkanealkyl, C3_C8 cycloalkenyl, CrC8 ring Alkenyl, Crc8 alkoxyalkyl, c3_Cl0 alkoxyalkenyl, CVCh)cyclodecyloxyalkyl, c3_Ci()alkoxyalkyloxyalkyl, G-Cs sulphidealkyl, c2-c8 alkylsulfinylalkyl , c2-c8 烧烧炫" base, C2-Cg amine burning base, C3-C1G two-yard amine base, C2-C8 halogen amine amine base, C4-C10 cyclic amine burning base, (: 2- (: 8 alkylcarbonyl, c2-c8 halocarbonyl, c4-c10 cycloalkylcarbonyl, c2-c8 alkoxycarbonyl, c4-c1()cycloalkoxycarbonyl, c5-c 12 cycloalkaneoxycarbonyl, c2_c8 alkylamine Carbonyl, C3-C1Q dialkylamine, C4-C1Q cyclodextrin, amine-Wei, C2-C5, nitrogen-based, Ci-C6, alkyl, C4-C10 ring, C2-C8 Base, C2-C8 oxy-hydrogen group, C2-C8 halogen Oxyhaloalkyl, C4-C10 halocyclic oxyalkyl, C4-C10 cyclooxyalkyl, c4-c10 halocyclooxyalkyl, c3_c10 dialkyloxyalkyl, C3-C1Q alkoxycarbonyl, C3 -CH) alkoxycarbonylalkyl, c2-c8 haloalkoxycarbonyl, crc6 alkoxy, crc6 haloalkoxy, c3-c8 cycloalkoxy, C3-C8 halocycloalkoxy, (:4-( : 10 ring-burning oxy group, C2-C6-d-oxyl group, C2-C6-halooxy group, C3-C6 alkynyloxy group, c3-c6-alkynyloxy group, c2-c8 alkoxylated alkoxy group, 〇2- <:8 alkylcarbonyloxy, C2-C8 halocarbonyloxy, (: 4-(:10 cycloalkylcarbonyloxy, c3_c1G alkylcarbonyloxy, crc6 alkylthio, C]-C6 halogen sulphur Base, C3-C8 ring sulphur-based, Ci_C6 yue yue base, Ci-C6 halal yoghurt base, C]-C6 burn-and-broil base, Ci-C6 halogen calcined base, C3_Cg bad burnt yellow Stuffed base, C3_Cs trialkyl fluorenyl, c3-c8 cycloalkenyloxy, c3-c8 halocycloalkenyloxy, c2-c8 ii alkoxyalkoxy, c2-c8 alkoxyhaloxy, c2-c8 Alkoxyhaloalkoxy, c3-c10 alkoxycarbonylalkoxy, c2-c8 alkyl(thiocarbonyl)oxy, c2-c8 alkylcarbonylthio, c2_c8 alkane(thiocarbonyl)thio, c3_c8cycloalkane Sulfonyl, Ci-C6 compound amine base, C2-C g II compound continuation base, C3-C10 li trialkyl fluorenyl group, CrC6 alkylamino group, c2-c8 dialkylamino group, Ci-C6 halogenated amine group, C2-Cg halogen dialkyl amine group, C3- C8 ring amine group, C2-C8 succinylamine, C2-C8 _ s-amino group, Ci_C6 calcined amine group, Ci_C6 tooth-burning amine group or C4-C1G ring-burning (alkyl) amine group; or

R2 is _W6C(=E4)R33, -W6L1C(=E5)R34, -\ν6ί:(=Ε6)Ι^35, -W6S(0)yNR37C(=0)R36 or -W6S(0)yNR37C(= 0) L1R36; each E, E5 and E6 are independently 〇, S, NR37, NOR37, NN(R37)2, N-CN or N-N02; each L1 is independently 〇, n(R38) or S; Is hydrogen; or crc6 alkyl, each R33, R34, R35 C^C: 6 alkenyl, Cz-C6 alkynyl or CVC6 cycloalkyl, each optionally substituted with one or more substituents, which are free Halogen, CN, N02, fluorenyl, CrC4 alkoxy, Ci-C4 alkylsulfinyl, CrC: 4 alkanesulfonyl, Ci-q alkylamino, CVC8 dialkylamino, cycloalkylamino and alkane Group CVC: group consisting of 6 cycloalkylamino groups; 4 ^ R: 7 independently H, Cl_C6 or Ki_Q _ alkyl, · Valley Q and Q5 are independently 0, s or N (R38); Q For C "C4 extended alkyl", which is optionally substituted with up to 4 substituents selected from the group consisting of CVC6, C2-C6, c2-C6, and c3-c6 cycloalkyl; R38 is independently CrC6 alkyl or CVQ alkyl; R39 is hydrazine or CrC6 alkyl; each y is 0, 1 or 2; W7 is CrC6 alkyl; W6 is CrC6 alkyl, C2-C6 extended alkenyl or C2-C6 Extending alkynyl; or -(CH2)2OCH2- or -(CH2)3OCH2-; W3 is a CrC6 alkylene group, (: 2-(:6-alkenyl or c2-c6-alkenyl; W4 is crc6-alkyl; R3 is H, halogen, cyano, hydroxyl, -0_M+, amine group, nitro group, -CHO, -C(=0)0H, -C(=0)NH2, -C(=S)NH2, -SH, -so2nh2, -so2nhcn, -S02NH0H, -OCN , -SCN, -SF5, -NHNH2, -NHOH, -N=C=0, -N=C=S, Ci-Cg, alkoxy, Ci_C6, halo-oxyl, c3-c8 cycloalkoxy, c3- C8 halocycloalkoxy, c4-c10 cycloalkanoyloxy, c2-c6 alkenyloxy, c2-c6 haloalkenyloxy, c3-c6 alkynyloxy, c3-c6 haloalkoxy, c2-c8 Oxykoxy, oxy-C2-C8, carbonyl, C2-C8, carbonyloxy, C4-Ch)cycloalkaneoxy, C3-C1G alkylcarbonyloxy, Ci-C6, sulfur-based, C! -C6 lil sulphur-based, C3.Cs cyclosulphur-based, CrC6 alkylsulfinyl, CrC6 halosulfinyl, Ci-C6 dazzle (continued base, C!-C6 _ calcined base, C3 -C8 naphthylsulfonyl, crc6 alkanesulfonyloxy, crc6 alkylamino, C2_Cg dialkylamine, Ci_C6 functional amine, C2-C8 iii dihydro-amine, CVC8 cycloalkylamine, c2- C8 alkanoamine, c2-c8 #院carbonylamino, Crc6 alkanesulfonylamino or crC6-alkylsulfonylamino; or benzyloxy , phenoxy, benzyloxyoxy, phenylcarbonyloxy, phenylsulfonyloxy, benzylsulfonyloxy, phenylthio, benzylthio, phenylsulfinyl, sulfinyl, benzene a fluorenyl or a sulfonyl group, each optionally substituted with up to five substituents selected from R21 on the ring member; M+ is an alkali metal cation or a monoammonium cation; RR, R and R are each independently H, halogen , mercapto, Ci_c6, c2-c6 alkenyl, c2-c6 alkynyl, Cl_c6 haloalkyl,

Ci-c6 alkoxy, crC6 haloalkoxy, C3-C8 cycloalkoxy or CrC8 functional cycloalkoxy; or phenyl or benzyl, each selectively up to five on the ring member selected from R21 Substituted by a substituent; i is H, CrC6 alkyl, c2-C6 dilute, C2-C6 block, crc6 4 alkyl, c2-c6 haloalkenyl, c2-c6 haloalkynyl, c3_c8 cycloalkyl or CyC8 a halocycloalkyl group; or a benzyl group, which is optionally substituted with up to five substituents selected from R21 on the ring member; i R9 is fluorene, crc6 alkyl, c2_c6 alkenyl, c2_c6 alkynyl, Ci_C6 dentate ,CrQ letter r group, CVC6 i block group, c3_c8 cycloalkyl, c3-c8 _cycloalkyl, c4_ClG alkane 4, 8 C4-C1G cycloalkyl, C6_Ci4 cycloalkane, C4_Ci〇i Ring-burning group, c5-c12 ring-burning group, c3_C8 4 ring' group, C3_c8-cycloalkenyl group, c2_c8 alkoxyalkyl group, c4_Ci〇cycloalkoxyalkyl group, c3-c1() alkoxyaloxane Or a c2-c8 alkylthioalkyl group;

Rl() is hydrazine, halogen, cyano, hydroxy, amine, nitro, SH, -S〇2NH2 ' -S02NHCN ' -SO2NHOH ' -OCN ' -SCN, -SF5, -NHCHO, ·ΝΗΝΗ2, -N3, -NHOH, •NHCN, -NHC(=0)NH2, -N=C=0, -N=C=S, CrC6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, CrC6 haloalkyl, C2 -C6 halogenated, C2-C6 haloalkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C4-C10 alkylcycloalkyl, C4-C10 cycloalkanyl, c6-c14 cycloalkane Alkyl, c4-c10 halocycloalkyl, c5-c12 alkancycloalkyl, c3-c8 cycloalkenyl, c3-c8 halocycloalkenyl, c2-c8 alkoxyalkyl, c4-c10 cycloalkoxy Alkyl, c3-c1Q alkoxyalkoxyalkyl or c2-c8 alkylsulfanyl; R is H, halogen, cyano, thio, amino, Ci-C6, crc6, c2-c6 , crc6 haloalkyl, c2-c6 haloalkenyl, c2-c6 haloalkynyl, c3-c8 cycloalkyl, c3-c8 halocycloalkyl, c4-c10 alkanecycloalkyl, c4-c10 cycloalkane , c4-c10 halocycloalkyl, c5-c12 alkancycloalkyl, c3-c8 cycloalkenyl, c3-c8 functional cycloalkenyl, c2-c8 alkoxyalkyl, C4-C1G cyclodane Burning base, C3-C1G smoldering > oxyalkyl, c2-c8 alkylsulfanyl, c2-c8 alkylsulfinane Or a C2-c8 alkanesulfonyl group; or a phenyl group, which is optionally substituted with up to five substituents selected from R21;

Rl2 is anthracene, halogen, cyano, hydroxy, amine, C "C6 alkyl, C2-C6 alkenyl, c2-c6 alkynyl, crc6 haloalkyl, c2-c6 haloalkenyl, c2-c6 haloalkynyl , c3-c8 cycloalkyl, c3-c8 fluorenyl, c4-Cl0 pyrrolidine, C4_Ci ring, c6-c14 ring (tetra), " _ parent group, kb ring fluorenyl group, c3- C8 cyclodecyl, c3_c8 ring-dense or C2-Cg-indenylamine; R13 is H, dentate, cyano, hydroxy, amine, nitroalkoxy; η is 0, 1 or 2; , R and Han 19 are independent of Η, 素, cyano, thiol or CVC6; or - R14 and R18 - from the wire or C2_C6 stretching; R is H'CVQ tooth burning, c2_c6 halogen Dilute, Ci_c6 alkoxy, Cl-C6 neooxy, c3-c8 cycloalkoxy, C!-C6 alkyl, CVC6 alkenyl, CVQ alkynyl or c3_Cpf alkyl; τ is CrC6 alkyl or c2 -c6 is an alkenyl group; each G is independently a 5- or 6-membered heterocyclic ring or an 8-, 9- or 10-membered fused bicyclic ring system, each ring or ring system optionally being selected from up to five R2] on the carbocyclic member is substituted with a substituent of R22 on the nitrogen ring member; each R is independently halogen, cyano, hydroxy, amine, schiffyl, _CH〇 -C(=〇)〇H, -C(=〇)NH2, -C(=S)NH2, -C(=〇)NHCN, -C(=0)NHOH, -SH, -S02NH2, -S02NHCN, -S02NH0H, -OCN, -SCN, -SF5, Ci-c6 alkyl, c2-C6 alkenyl, C2-C6 alkynyl, Crc6 halo, CrC6, C2-C6 _block, C3-C8 Cycloalkyl, c3-c8 i cycloalkyl, c4-c1()alkylcycloalkyl, c4-c10 201240602 cycloalkyl, c3-c8 cycloalkenyl, c3-c8 halocycloalkenyl, c2-c8 alkane Oxyalkyl, c4-c1G cycloalkoxyalkyl, C3_C1G alkoxyalkane, C2-C8 Institute of Sulfur, C2-C8 Institute of sulfhydryl, c2-c8 alkoxyhaloalkyl, c2- C5 cyanoalkyl, c "c6 5 hydroxyalkyl, crc6 alkoxy, crc6 haloalkoxy, c3-c8 cycloalkoxy, c3-c8 halocycloalkoxy, c4-c10 cycloalkylalkoxy, C2-c6 alkenyloxy, c2-c6 haloalkenyloxy, c2-c8 alkoxyalkoxy, c2-c8 alkylcarbonyloxy, crc6 alkylthio, Ci_C6 halogenothiol, C3-C8 cyclosulphur Base, Ci_C6 烧亚10 continuation brewing base, C!-C6 halogen burning Yazhen brewing base, Ci-C6 dazzling brewing base, C!-C6 _ academic performance brewing base, C3_Cg ring hospital continuation base, Ci-C6 hospital Amino, C2-C8 dialkylamine, C1-C6 halogen amphotery, C2-C8 haloalkylamine or c3-c8 cycloalkylamine Each R22 is independently a Ci-C6 alkyl group, a C2-C6 dilute group, a C2-C6 fast group, a 15 Ci_C6 halogen group, a C3-C8 cyclohexyl group or a C2-C8 azepine group; 114 () is a crc6 alkane And R41 is a CrC6 alkyl group; or R40 and R41 together are -(CH2)4-, -(CH2)5-, -ch2ch=chch2- or -(ch2)2o(ch2)2-. The present invention relates to a compound of the formula 1 (including all stereoisomers), an oxide thereof or a salt thereof. The invention also relates to a herbicidal composition comprising a compound of the invention (i.e., in a herbicidally effective amount) and at least one component selected from the group consisting of surfactants, solid diluents, and liquid diluents. The invention further relates to a method for controlling the growth of an unwanted plant comprising contacting the plant or its environment 25 201240602 with a herbicidally effective amount of a compound of the invention (e.g., as described herein). The invention also relates to a herbicidal mixture of (a) - a compound of formula 1 and (b) at least one additional active ingredient. The invention also relates to an intermediate compound of the formula 1Q (including all stereoisomers), its #oxide and its salts:

R1 R2 ίο where A' is a free radical selected from the group consisting of

A compound defined by the compound which can be used to prepare a compound of formula 1. 15 The present invention also relates to a compound of the formula 1R (including all stereoisomers), its #oxide and its salts: 17 201240602 Ο Ο

R1 R2 where R1 is 5

Or R1 is -WiCpEbR24, ^LC(=E2)R25 or -WiCpE3)!^26; or ίο R1 is N(R40)R41; or R1 is GA; each GA is a 5- to 6-membered carbocyclic ring, It comprises a ring member selected from C(=0), C(=N_OR3G) or C=NN(R29)2; or a 9- to 11-membered saturated or partially saturated carbon spiro or heterospiro ring system, Is optionally comprising a ring member selected from C(=0), C(=N-OR3G) or C=NN(R29)2, each ring or ring system selectively being selected from up to three selected from the ring member R21 is substituted with a substituent of R22 on the nitrogen ring member; or each GA is a 9-membered partially saturated fused ring system containing a carbocyclic member 20 and 2 nitrogen ring members, the ring selectively passing at most Two are selected from R21 on a carbon ring member and a substituent on R22 on a nitrogen ring member; each E, E2 and E3 is independently 〇, N〇R28 or NN(R28)2; L is independently Ο or N ( R31); each R24, R2, R26 is independently hydrogen; or crc4 alkyl or c3-c5 alkyl, each optionally one or more selected from the group consisting of dentate, CN, hydroxyl, Cl<:2 alkoxy Substituted by a group consisting of a Ci_C2 alkylsulfinyl group and a CrC4 sulfonyl group; each R = independently is hydrazine, Ci-C3 alkyl or crc3 ii Alkyl; each R is independently H, crc3 alkyl, crC3 alkyl, CrC3 alkyl, CrC3 alkanesulfonyl or Crc3 alkanesulfonyl; each Q1 and Q2 is independently 〇 or N(R31); CrCr3 is optionally substituted with up to 2 substituents selected from CrC; 4 alkyl; R3i is independently hydrazine, CrC3 alkyl or crC3 haloalkyl; R 1 is independently H, CrC3 alkyl or crC3 haloalkyl; R is hydrazine or CrC3 alkyl; w is crc4 stretching; w^ is C2-C4 alkyl, _(CH2)2OCH2- or -(ch2)3och2-; R is phenyl or - W3 (phenyl), each substituted on the ring member with up to two substituents selected from R21; or 〇; or CrC6 alkyl or €3<:8 cycloalkyl; w3 is CrC6 alkyl, CH: 6-alkenyl or (: 2-<:6-exetylene; each G is independently a 5- or 6-membered heterocyclic ring or an 8-, 9- or 10-membered slightly sigma double % soil, each ring Or the ring system is selectively substituted with up to five substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; 201240602 each R21 is independently halogen, cyano, hydroxy, amine, nitro, -CHO, -C(=0)0H, -C(=0)NH2, -C(=S)NH2, -C(=0)NHCN, -C(=0)NH0H, -SH, -S02NH2, - S02NHCN ' -SO2NHOH ' -OCN ' -SCN ' -SF5 ' 5 C1-C6 alkyl, C2-C6 dilute, C2-C6 fast radical, Ci-C6 _ alkyl, C2-C6 halogenated base, C2-C6 halogen fast Base, C3-C8 cycloalkyl, C3-C8 functional ring alkyl, C4-Ci oxime ring, C4-C10 ring alkyl, C3-C8 ring, C3-C8 _ ring, C2 -C8 Institute of Oxygen, C4-C10 Ring Oxygen Burning, C3-C1G Oxygen Burning, Oxygen Base, C2-C8 Sulphur Burning Base, C2-C8 Sintering, C2-C8 Hyun* Oxyhaloalkyl, C2-C5 azafenyl, Ci_C6 trans-system, C1-C6 alkoxy, C1-C6 halogen-oxyl, C3-C8 cyclooxy, C3-C8 halo alkoxy, C4 -C10 ring-burning oxy group, 〇2·〇6-diloxy group, C2-C6 halo-butoxy group, C2-C8 15 alkoxy alkoxy group, C2-C8 alkylcarbonyloxy group, CrC6 alkylthio group, crc6 halogen Alkylthio, c3-c8 cycloalkylthio, crc6 alkane sulphate, Ci-C6 halogenated succulent, C]-C6 sinter, Ci-C6 broth, C3_Cg 》Continuous base, Ci-C6 amine group, C2-C8 diamined amine group, C1-C6 halogenated amine group, C2-C8 20 halogen II compound or C3-C8 cycloarthryl group; each R22 is independent CVC6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, crc6 haloalkyl, c3_c8 naphthenic Or c2-c8 alkoxyalkyl; R40 is C丨-C6 alkyl; and R41 is CrC6 alkyl; or 25 R40 together with R41 as -(CH2)4-, -(CH2)5-, -CH2CH= CHCH2- or -(CH2)20(CH2)2-. 20 201240602 It can be used to prepare a compound of formula 1 β. The invention also relates to a compound of formula ls (including all stereoisomers), its W oxides and salts thereof: ” 15 wherein R1 is R1

, W5'R32 · or -W1LC(=E2)R25 or -W1C(=E1)R24, -W]C(=E3)LR26; or R1 is N(R40)R41; or R1 is GA; each Upt'b a carbon ring comprising a ring member selected from the group consisting of C(=〇), 11 member saturated or c=NN(R29)2, or a 9-to-select==carbon cr ring or a heterospiro ring system, C=NNm^ is selected from C(-O), C(=N-OR30) or more than one shell' each ring or county is selectively substituted with up to two substituents selected from r21R22 on a carbocyclic member; or 20 on the staff member 201240602 Each G is a 9-member partially saturated fused ring system containing a carbon ring member and two nitrogen ring members, the ring selectively having up to 2 R2 selected from the carbon ring members. 】 substituted with a substituent of R22 on a nitrogen ring; each E1, E2 and E3 is independently 〇, n〇r28 or 28)2; L is independently Ο or N(R31): each R: R25 is independent of R26 Is hydrogen; or alkyl or ca cycloalkyl, each selectively consisting of one or more selected from the group consisting of halogen, 10 CN, hydroxyl, CrC 2 alkoxy, Cl_c 2 alkylsulfinyl and CrC4 Substituted substituents; each R = independently Η, C1-C3 alkyl or crc3 haloalkyl; 15 each R29 is independently Η, CrC3 alkyl, c丨-c3 IS alkyl c丨-C3 alkylcarbonyl, Q-C3 alkanesulfonyl or Cl_c3 alkylsulfonyl; each Q1 and Q2 is independently 〇 or n(r31); Q is an eye: 3 alkyl group, which selectively undergoes at most 2 selected from

Substituted by a substituent of CrC4 alkyl; 20\independently fluorene, CrC3 alkyl or CrC3 dentate; R31 is independently hydrazine, CrC3 alkyl or Cl_C3 _alkyl; r32 is hydrazine or CrC3 alkyl; W5 is CrC4 alkylene W1 is C2-C4 alkyl, -(ch2)2och2- or -(CH2)3〇CH2-; R is phenyl or -W3(phenyl), each of which is selected from two at most Substituted by a substituent of R21; or -G; or CrC6 alkyl or hydrazine <:8 cycloalkyl; W3 is Crc6 alkyl, C2-C6 stretching or c2-C6 alkynyl; 22 25 201240602 each G Independently a 5- or 6-membered heterocyclic ring or an 8-, 9- or 10-membered slightly bicyclic ring system, each ring or ring system optionally having up to five R21 selected from a carbon ring member Substituted by a substituent of R22 on a nitrogen ring member; 5 each R21 is independently halogen, cyano, hydroxy, amine, nitro, -CHO, -C(=0)0H '-C(=0)NH2 ' - C(=S)NH2 ' -C(=0)NHCN, -C(=0)NH0H, -SH, -S02NH2, -S02NHCN, -S02NHOH, -OCN, -SCN, -SF5, CVC6 alkyl, c2- C6 alkenyl, c2-c6 alkynyl, crc6 halo 10 alkyl, c2-c6 haloalkenyl, c2-c6 halo fast radical, c3-c8 cyclodextrin, C3-C8 halo ring, C4-C10 ring Hyun 1 base, C4-C10 soil burnt * , C3-C8 ί 稀, C3-C8 halo ring, C2_Cg oxyalkyl, C4-C1G ring oxyalkyl, C3-CiQ oxynitride, C2-C8 sulphur-burning, C2-C8 Institute is continuously brewed with 15 bases, c2-c8 alkoxyhaloalkyl, c2-c5 cyanoalkyl, crc6 hydroxyalkyl, crc6 alkoxy, crc6 haloalkoxy, c3_c8 cycloalkoxy, c3 -c8 halocycloalkoxy, c4-c10 cycloalkanoyloxy, c2-c6 alkenyloxy, c2-c6 haloalkenyloxy, c2-c8 alkoxyalkoxy, c2-c8 alkoxycarbonyl, crc6 Alkylthio, 20 CVC6 halogen thiol, C3-C8 ring thiol, CVC6 sinter sulphate, halogen sulphide, subcontinental, C^-Cg calcined, crc6 halosulfonyl, C3-c8 cycloalkanesulfonyl, crc6 amphoteric, C2-C8 dialkylamine, C1-C6 haloalkyl, C2-C8 haloalkylamine or C3-C8 cycloalkylamine; 23 201240602 R22 is independently Ci_C6, C2-C6 alkenyl, C2-C6 alkynyl, CrC6 alkyl, C3-C8 cycloalkyl or C2-C8 alkoxyalkyl; and R23 is a selectively substituted carbon a carbon moiety; 114() is a CrC6 alkyl group; R41 is a CrC6 alkyl group; or R40 and R41 together are _(CH2)4-, -(CH2)5-, CH2CH=CHCH2- or -(ch2 ) 2o(ch2) 2- It can be used to prepare a compound of formula 1. [Embodiment] 15 20 "As used herein, the terms "including", "including", "having", "including", "characteristic" or any other variation thereof are intended to cover non-exclusive. And any composition, mixture, process, or method that is not specifically limited to 1 ', but may be included in the composition, mixture, process Other elements. The conjunction "by . * ^ ^^ ^ ..., and into" excludes any unspecified meta-words that will be sealed (four) t st in the application for financial resources, such as the use of impurities, in addition to the usual And the related words "by ·····. group, L include those substances other than enumerated. When the connection is not followed by 20%", the clause of the subject of the patent scope is now requested, and the elements are generally; The elements mentioned in the clause; the other conjunctions "main I, excluded from the scope of the patent. The literal disclosure of '··..·" is used to define materials, steps, features, components or elements other than those defined. 24 25 201240602 The composition or element 1 is just like these extra materials, (4), features, inclusions and "by! Γ mainly consists of ·····." The middle ground. Some open-ended terms such as "contains" are defined as - inventions or their stipulations are not otherwise stated.) The narrative should be interpreted as "master again,; 4" or "by ···· ". Composition" describes the invention. Sexual bite = otherwise expressly stated to the contrary, "or" means a case involving 10 15 20 (, Β Β Α疋 Α疋 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 Α ( ( ( ( ( ( ( (or exist), and ΑΗ are all true (or exist). 疋 「 一 一 一 一 位于 位于 位于 位于 之前 之前 之前 之前 之前 之前 之前 之前 之前 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在 旨在An element or a component, and the singular form of the dollar is also plural, unless the number is obviously singular. Or bloody, as mentioned in the article, the term "seedling" is used alone. Smoke, which means a young plant that develops from the seed germ. For example, the term "broad leaf" is used alone or in combination with other words to make it "broad weed", which means A dicotyledonous or dicotyledonous plant, a term used to describe a group of angiosperms characterized by two cotyledons of the embryo. As used herein, the term "alkylating agent" refers to a compound in which three free radicals are passed through a Carbon atom bonding to a detachment base 25 25 201240602 a halide or a sulfonate which can be replaced by bonding a nucleophilic agent to the aforementioned carbon atom. Unless otherwise indicated, the term "alkylating agent" does not limit the carbon radical of Shai as a hospital base; The carbon-containing radicals in the oxidizing agent include various radicals of the ruthenium-bonding substituents, which are designated, for example, for R1, R2 and R3. The term "dealkylating agent" means pyrolysis of carbon-carbon or carbon. _ Oxygen-bonding reagent. In the above description, the term "alkyl" is used alone or in compound words such as "alkylthio" or "dentate alkyl", and includes straight-chain or branched alkyl groups, such as Base, ethyl, n-propyl, isopropyl or different butyl, pentyl or hexyl isomers. "Alkenyl" includes straight or branched olefins such as vinyl, 1-propenyl, 2-propenyl The dilute group and the different butylon, pentenyl and hexenyl isomers. "Alkenyl" also includes polyene such as anthracene, 2-propadienyl and 2,4-hexadienyl. Included are straight-chain or branched alkyne such as ethynyl, 1-propynyl, 2-propanyl and the different butyl, pentyl and hexynyl isomers. "Alkynyl" may also include The moieties of the plural oxime bond are, for example, 2,5·hexadiynyl. "Alkylene" means a straight chain or a branched alkanediyl group. Examples of "alkylene group" include CH2, CH2CH2, CH(CH3), CHKI^CH2, CH2CH(CH3) and different butyl isomers. "Extend alkenyl" means a straight or branched olefinic diyl group containing an ethylenic bond. Examples of "alkenyl" include CH=CH, CH2CH=CH, CH=C(CH3) and different butenyl isomers. When the examples provided indicate that the two variants are "along together as a alkenyl group", these examples do not limit the point of attachment. For example, when rh and Ri8 together act as -CH=CHCH2-, the point of attachment of this exemplary group is interpreted as being attached to one of the R14 or R18 variants (ie, equivalent to -CH2CH=CH_). "Extend alkynyl" means a straight chain or branched alkyne 2 26 201240602 group which contains a hydrazone bond. Examples of "alkynyl" include ceC, CHzOC, C^CCH2 and different butynyl isomers. "Alkoxy" includes, for example, decyloxy, ethoxy, n-propoxy, isopropoxy and various butoxy, pentyloxy and hexyloxy isomers. "Alkane 5 oxyalkyl" means an alkoxy group substituted on the alkyl group. Examples of the "alkoxyalkyl group" include CH3〇CH2, CH3OCH2CH2, CH3CH2OCH2, CH3CH2CH2CH2OCH2^CH3CH2OCH2CH2 group" means that an alkoxy group is substituted on the alkoxy group. "Alkenyloxy" includes a straight or branched alkenyloxy moiety. Examples of the "alkenyloxy group" include 10 H2C=CHCH20, (CH3)2C=CHCH20, (CH3)CH=CHCH20. (CH3)CH=C(CH3)CH20 and CH2=CHCH2CH2〇. "Alkynyloxy" includes a straight or branched alkynyloxy moiety. Examples of "alkynyloxy" include HOCCH20, ch3c=cch2o and CH3〇CCH2CH2〇. "Alkoxyalkenyl" includes a straight or branched alkenyl group substituted with an alkoxy group 15. Examples of "alkoxyalkenyl" include CH3OCH=CH, CH3C(OCH3)=CH and CH3CH2〇CH=CHCH2. "Alkoxyalkyloxyalkyl" means an alkoxyalkoxy group substituted on the alkyl group. Examples of the "alkoxyalkyloxyalkyl group" include CH3OCH2OCH2, CH3OCH2OCH2CH2, 20CH3CH2OCH2OCH2 and CH3OCH3CH2OCH2CH2. "Alkylthio" includes branched or straight chain alkylthio moieties such as methylthio, ethylthio and propylthio, butylthio, pentylthio and hexylthio isomers. "Alkylene" also contains two mirror image isomers of a sulfhydryl group. Examples of "alkylsulfinyl" include CH3S(0)_, 25ch3ch2s(o)-, CH3CH2CH2S(0)-, (CH3)2CHS(0)- and different sulfinyl, sulfinamide Base and hexylsulfinyl isomer. Examples of "alkane 27 201240602 sulfonyl" include CH3S(0)2-, CH3CH2S(0)2-, CH3CH2CH2S(0)2., (CH3)2CHS(0)2- and different butasulfonyl, pentane It is confirmed that the sulfhydryl group and the hydrazine isomer. The definitions of "circulating sub-items" and "cycloalkylsulfonyl" are similar to the above terms "alkylsulfinyl" 5 and "alkylsulfonyl". "Ceramic sulfur base" means that there is a sulfur-substituted group on the base. Examples of the "sulfur-saturated alkyl group" include ch3sch2, ch3sch2ch2, CH3CH2SCH2, CH3CH2CH2CH2SCH2 and CH3CH2SCH2CH2; "alkylsulfinylalkyl" and "alkylsulfonylalkyl" 10 respectively include corresponding sulfoxide and sulfone. The "alkylamino group" includes an NH radical substituted with a linear or branched alkyl group. Examples of the "alkylamino group" include CH3CH2NH, CH3CH2CH2NH and (CH3)2CHCH2NH. Examples of the "dialkylamino group" include (CH3)2N, (CH3CH2CH2)2N and CH3CH2(CH3)N. "Alkylaminoalkyl" means that the alkylamine group has 15 alkyl groups on the alkyl group. Examples of the "alkylaminoalkyl group" include CH3NHCH2, ch3nhch2ch2, ch3ch2nhch2, CH3CH2CH2CH2NHCH2 and CH3CH2NHCH2CH2. Examples of the "dialkylamine alkyl group" include ((ch3)2ch)2nch2, (CH3CH2CH2)2NCH2 and CH3CH2(CH3)NCH2CH2. The term "alkane 20 carbonylamino" denotes an alkyl group bonded to a C(=0)NH group. Examples of the "alkylcarbonylamino group" include ch3ch2c(=o)nh and ch3ch2ch2c(=o)nh. "Alkylcarbonylthio" means a straight or branched alkylcarbonyl group attached to a sulfur atom and bonded via a sulfur atom. Examples of the "alkylcarbonylthio group" include 25 ch3c(=o)s, ch3ch2ch2c(=o)s and (CH3)2CHC(=0)S. The term "alkyl(thiocarbonyl)oxy" denotes an alkyl group bonded to a thiocarbonyl group 28 201240602 (attached to an oxygen atom and bonded via an oxygen atom). Examples of the "alkyl(thiocarbonyl)oxy group" include ch3ch2c(=s)o and CH3CH2CH2C(=S)0. The term "alkyl (thiocarbonyl)thio" refers to an alkyl group bonded to a sulfur atom. Examples of the "alkyl (thiocarbonyl)thio group" include CH3CH2C(=S;)S. "二烧烧基" includes three branched and/or straight-bonded radicals linked to a broken atom and linked via a broken atom, such as trimethyl sulfanyl, triethyl decyl and tert-butyl dimethyl矽基. Examples of the "halotrialkylsulfonyl group" include CF3(CH3)2Si-, (CF3)3Si- and CH2Cl(CH3)2Si-. "Hydroxyl 10 15 20 alkyl" means an alkyl group substituted with one hydroxy group. Examples of "hydroxyalkyl" include HOCH2CH2, CH3CH2(OH)CH and HOCH2CH2CH2CH2. "Cyanoalkyl" means an alkyl group substituted by a cyano group. Examples of "cyanoalkyl" include NCCH2, ncch2ch2 and ch3ch(cn)ch2. "Cycloalkyl" includes, for example, cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. The term "alkylcycloalkyl" denotes an alkyl group substituted on a cycloalkyl group and includes, for example, ethylcyclopropyl, isopropylcyclobutyl, 3-indolecyclopentyl and =methylcyclohexyl. The term "rings" means that there is a % alkyl group substitution on the alkyl group. Examples of "households" include cyclopropenyl, cyclohexylethyl and other cycloalkyl groups which are bonded to a straight or branched alkyl group. The term "alkoxy" means a cycloalkyl group bonded via an oxygen atom, such as a pentyloxy group and a cyclohexyloxy group. The term "burning ring-burning group" means not finding a silk H-based group on a t-alkyl group. Examples of the fluorene-based group include a fluorenyl group, a butyl group, and a straight bond or a branch group which is condensed to a ring group. . The silk "material Wei" means that the lysyl group is substituted with an alkoxy group. Examples of the aerobic cycloalkyl group include a methoxycyclopropane 29 25 201240602 group, an ethoxycyclohexane, and other straight or branched alkoxy groups bonded to a weiyl group. The "cyclic oxy group" means a ring-yard base to which an oxygen atom is bonded, and the oxygen atom is bonded to the alkyl chain. Examples of the "aristocratic oxy group" include a cyclodecyloxy group, a cycloerythroxy group, and other cycloalkyl groups bonded to a linear 5- or branched alkoxy group. Examples of the "cyanocycloalkyl group" include 4-cyanohexyl and 3-cyanocyclopentyl/cycloalkenyl groups including groups such as a cyclopentenyl group and a cyclohexenyl group, and a group having more than one double bond. 'such as 1,3- and 1,4-cyclohexadienyl. The term "fun" is used either alone or in compound words such as "haloalkyl 10" or when used in the description of "passage substituted by dentate", including fluorine, gas, bromine or iodine. . Furthermore, when used in a compound such as "haloalkyl" or when used in the description of "alkyl substituted by halogen", the alkyl group may be partially or completely substituted with the same or different halogen atoms. . Examples of "dental base" or "halogen substituted by halogen" include F3C-, C1CH2-, CF3CH2- and CF3CC12-. The terms "halocycloalkyl", "haloalkoxy", "haloalkylthio", haloalkylsulfinyl, alkanesulfonyl, "haloenyloxy", "haloalkoxy", "halogen" Alkenyl", "haloalkynyl", "haloalkoxyalkyl", "haloalkoxyalkoxy", "haloalkanooxyalkoxy", "haloalkoxyhaloalkyl", "haloalkylamino" "Homo 20 alkylaminoalkyl", "cycloalkoxy", "dental cycloalkyloxyalkyl", "halocycloalkylalkyl", "halocycloalkenyl", "halocycloalkenyloxy", "halocycloalkenyloxy", "ring ring oxygenation base", "burning oxygen 13⁄4 courtyard oxygen", oxygen-burning functional group, haloalkylcarbonyloxy and the like are defined by the term "||alkyl "similar. Examples of "haloalkoxy" include cf3o-, cci3ch2o-, hcf2ch2ch2o-25 and CF3CH20-. Examples of "haloalkylthio" include CC13S-, CF3S-, CC13CH2S- and C1CH2CH2CH2S-. The example of "haloalkyl sulfinyl" is cf3s(o)·, CC13S(0)-, cf3ch2s(o)- and cf3cf2s(o)-. Examples of "haloalkylsulfonyl" include CF3S(0)2-, cci3s(o)r, cf3ch2s(o)2• and cf3cf2s(o)2-. Examples of "haloalkenyl" include (C1)2C=CHCH2- and CF3CH2CH=CHCH2-. The "_ 5 alkynyl group" actually includes HC=CCHC1-, CF3CeC-, CC13C=C- and FCH2〇CCH2-. Examples of the "haloalkoxyalkoxy group" include CF30CH20-, C1CH2CH20CH2CH20-, C13CCH20CH20-, and a branched-chain derivative. Examples of the "halogenated amine group" include CF3(CH3)CHNH, (CF3)2CHNH and CH2C1CH2NH. The phrase "ii dialkyl", whether used alone or in a compound such as "i dialkylamino", means that at least one of the two alkyl groups is substituted with at least one halogen atom, and each The dentate alkyl group can be independently substituted partially or completely by the same or different functional atom. Examples of the "dentate dialkylamino group" include (BrCH2CH2)2N and 15BrCH2CH2(ClCH2CH2)N. "Alkylcarbonyl" means a straight or branched alkyl group bonded to a c(=o) group. Examples of "alkylcarbonyl" include CH3C(=0)-, CH3CH2CH2C(=0)- and (CH3)2CHC(=0)-. Examples of "alkoxycarbonyl" include ch3oc(=o)-, ch3ch2oc(=o)-, 20ch3ch2ch2oc(=o)_, (ch3)2choc(=o), and different butoxy- or pentyloxycarbonyl groups Isomer. The terms "decanecarbonyl", "haloalkoxycarbonyl", "alkoxycarbonyl", "cycloalkoxycarbonyl", "cycloalkaneoxycarbonyl" and "cycloalkylaminecarbonyl" are all similar. The term "alkoxycarbonylamino" denotes a straight or branched alkoxy group bonded to the 25 C (=0) group of a monoamino group. Examples of the "alkoxycarbonylamino group" include ch3oc(=o)nh_ and CH3CH20C(=0)NH-. Examples of the "alkylamine 31 201240602 carbonyl group" include ch3nhc (=o), ch3ch2nhc (=〇), ch3ch2ch2nhc (=o), (ch3)2chnhc (=o) and different butylamine- or pentylamine carbonyl isomers. Examples of the "dialkylaminecarbonyl group" include (CH3)2NC(=0), (ch3ch2)2nc(=o), 5CH3CH2(CH3)NC(=0), (CH3)2CH(CH3)NC(=0) With CH3CH2CH2(CH3)NC (=0). The term "alkylcarbonyloxy" denotes a straight or branched alkyl group bonded to a c(=o)o group. Examples of the "alkylcarbonyloxy group" include CH3CH2C(=0)0 and (CH3)2CHC(=0)0. The term "alkanoalkoxy" denotes an alkylcarbonyl group bonded to an alkoxy group. Examples of the "alkylcarbonyl 10 alkoxy group" include CH3C(=0)CH2CH20 and CH3CH2C(=0)CH20. Examples of the "alkoxycarbonyloxy group" include CH3CH2CH20C(=0)0 and (CH3)2CH0C(=0)0. The term "cycloalkylcarbonyloxy" means a cycloalkylcarbonyl group bonded to an oxygen. Examples of the "cycloalkylcarbonyloxy group" include cyclopropyl-c(0)0- and cyclohexyl-c(0)0-. 15 "Alkylsulfonylamino" means an NH radical substituted by an alkanesulfonyl group. Examples of the "alkylsulfonylamino group" include CH3CH2S(=0)2NH- and (CH3)2CHS(=0)2NH-. The term "halo sulfonyloxy" means a thiol group bonded to an oxygen atom. Examples of "burning oxime" include ch3s(=o)2o-, CH3CH2S(=0)20-, 20ch3ch2ch2s(=o)2o-, (ch3)2chs(=o)2o- and different butyrene Alkoxy, pentylsulfonyloxy and hexapyloxyl isomers. The term "cycloalkoxyalkyl" denotes a cycloalkoxy group substituted on an alkyl group. Examples of the "cycloalkoxyalkyl group" include a cyclopropoxymethyl group, a cyclopentyloxyethyl group and other cycloalkoxy 25 groups bonded to a linear or branched alkyl group. The term "cycloalkylthio" denotes a cycloalkyl group attached to a sulfur atom and bonded via a sulfur atom, such as a cyclopropylthio group and a cyclopentylthio group; "ring 32 201240602 alkanesulfonyl group" includes its corresponding sulfone. "Alkylcycloalkyl" means a group which is substituted with a cycloalkyl group. Examples of the "ring-burning group" include a 2-, 3- or 4-methyl group or an ethylcyclohexylmethyl group. The term "cycloalkoxyalkyloxyalkyl" denotes a 5-cycloalkoxy group attached to an alkoxy group of an alkoxyalkyl group. Examples of the "cycloalkoxyalkyloxyalkyl group" include (cyclopropyl)OCH2OCH2-, (cyclobutyl)OCH2CH2〇CH2_ or (cyclohexyl) OCH2〇CH2CH2_. The term "cycloalkanecycloalkyl" denotes a cycloalkyl substitution on the other cycloalkyl ring wherein each cycloalkyl ring independently has from 3 to 7 carbon atoms. Examples of the "cycloalkanecycloalkyl group" include a cyclopropylcyclopropyl group (e.g., a bicyclopropyl-1-yl group, a 1,1,-dicyclopropyl-2-yl group), a cyclohexylcyclopentyl group (e.g., a 4-ring group). Pentocyclohexyl) and cyclohexylcyclohexyl (for example U'-dicyclohexyl-1-yl) with different cis- and trans-cycloalkylcycloalkyl isomers (for example (1 foot 2, 1) 1'-bicyclopropyl-2-yl and (1 foot 2 and)-1, fluorene-bicyclopropyl-2-yl). 15 "Secondary oxyalkyl" means the same in the base of the compound a separate alkoxy group substituted on carbon. Examples of "dialkoxyalkyl" include (ch3o)2ch- and ch3ch2o(ch3o)ch-. "Cycloalkylamino" means a NH radical substituted by a phenolic group. Examples of the "cycloalkylamino group" include a cyclopropylamino group and a cyclohexylamino group. "Cycloalkyl (alkyl)amino group means a ring of 20 aromatized groups wherein the hydrogen atom is derived from a radical Examples of "cycloalkyl (alkyl) amine groups include, for example, cyclopropyl (methyl) amine groups, cyclobutyl (butyl) amine groups, cyclopentyl (propyl) amine groups, cyclohexyl groups ( Alkyl group, etc. The term "ring-burning amine "base" means a base The group has a cycloalkylamino group substituted. Examples of "cycloalkylaminoalkyl" include cyclopropylaminomethyl, 25-cyclopentylaminoethyl and other cyclic aminino groups bonded to a linear or branched alkyl group. 33 201240602 "Cycloalkylcarbonyl" means a cycloalkyl group bonded to a c(=〇) group, which includes, for example, cyclopropylcarbonyl and cyclopentylcarbonyl. The term "cycloalkoxycarbonyl" means bonded to a cycloalkoxy group of a c(=o) group, such as cyclopropoxycarbonyl and %: pentoxy. "cyclohexylamine" means a cycloalkane bonded to a c(=o) group of 5 An amine group such as a cyclopentylamine carbonyl group and a cyclohexylamine carbonyl group. "Cycloalkaneoxycarbonyl group" means a cycloalkylalkoxy group bonded to a c(=o) group. The present invention includes a cyclopropyloxymethyl group and a cyclopentanyloxy group. "Alkoxy" means a cycloalkylcarbonyl group bonded to an oxygen atom and bonded via an oxygen atom. Examples of "cycloalkaneoxy" include a ring. Hexacarbonyl 10 oxy and cyclopentylcarbonyl. The term "cycloalkyl" means a ring-substituent substitution on a group. "Cycloalkenyl" examples include cyclobutenyl and cyclopentane. dilute Ethyl and other cycloalkenyl groups bonded to a straight or branched alkyl group. The term "cycloalkenyloxy" means a cycloalkenyl group bonded via an oxygen atom, such as a ring 15 penteneoxy group and a ring. Hexenyloxy. The term "cycloalkenyloxyalkyl" means a cycloalkenyloxy group substituted on an alkyl group. Examples of "cycloalkenyloxyalkyl" include cyclobutenyloxy, cyclopenteneoxy a cycloalkenyloxy group bonded to a straight or branched alkyl group. The term "alkylamine" means a 20-bond or branched-chain bond bonded to a continuation group. Amino group. An example of an "alkali thiol" group includes CH3NHS(0)2- or CH3CH2CH2NHS(0)2-. The term "dialkylamine sulfonyl" denotes a straight or branched dialkylamino group bonded to a monosulfonyl group. Examples of a "dialkylamine sulfonyl" group include (CH3)2NS(0)2- or (CH3CH2CH2)2NS(0)r. The total number of carbon atoms in the 25-substituent group is indicated by the prefix "Ci-Cj", where i and j are numbers from 1 to 14. For example, CrC4 Institute 34 201240602 Sulfonyl represents methanesulfonyl to butasulfonyl; c2 alkoxyalkyl represents CH3OCH2-; c3 alkoxyalkyl represents, for example, CH3CH(OCH3)-, CHsOCHzCH2. or CH3CH2OCH2-; The alkoxyalkyl group means various isomers of an alkyl group substituted by an alkoxy group having a total of four carbon atoms, and examples include ch3ch2ch2och2- and CH3CH2OCH2CH2-. When a compound is substituted with a substituent and the substituent bears a subscript (indicating that the number of such substituents may exceed one), the substituents (when they exceed one) are independently selected from the defined substituents. Group, 10 15 20 For example (Rv)r, in the U-1 of the show 3! · is 1, 2, 3, 4 or 5. When a group contains a substituent which may be hydrogen, such as R2, R3, r4, R5, R6, R7, r8, r9, ri〇, rii, Ru, r13, r14, r15 R _, R19 or R2q, Then, when the substituent is hydrogen, it is considered that the group is unsubstituted. When the -variable base_ is shown as being selectively coupled to a position, such as (RV)r in display 2, then hydrogen may be at that position (ie, when F is G), even if the variable base is gj This statement is not included in the definition. When the - or a plurality of positions on the group are described as "untaken or unsubstituted", the hydrogen atom is attached to occupy any of the "rings" or "," For example, the substituent GA) is a carbocyclic or heterocyclic ring. The term "ring system" is:, a nucleus of copper. The terms "bicyclic" and "fused bicyclic" form a ring system consisting of L (d) and unless otherwise stated: diterpenes may be saturated, partially unsaturated or fully unsaturated. The term ', no mourning', means that the two bonds are in a single atom as a carbon spiro or a heterocyclic ring. The use of this "production of the heart and the use of b J-clothes" refers to the formation of a ring or ring system 35 25 201240602 main chain of atoms or other groups (such as c (= o), c (= s), s (o) or S(〇)2) 0 s = "Carbon ring", "carbocyclic compound" or "carbocyclic ring" means a % or ring system in which the atoms forming the ring backbone are selected only from carbon. Unless otherwise stated, a slave ring can be saturated, partially unsaturated or fully unsaturated. When a fully unsaturated carbon ring satisfies the Httcke丨, s rule, the ring is also referred to as the "aromatic ring". "Saturated carbocycle" means a ring in which the main chain is in the domain of a carbon atom which is bonded to each other by a single bond; unless otherwise indicated, the remaining carbon valence is occupied by a hydrogen atom. The term "heterocycle" or "heterocycle" means a ring or ring system wherein the atom forming the primary bond of the ring is not carbon, such as nitrogen, oxygen or sulfur. A heterocyclic ring typically contains no more than 4 nitrogen atoms, no more than 2 oxygen atoms and no more than 2 sulfur atoms. Unless otherwise stated, a heterocyclic ring can be a 77 unsaturated or fully unsaturated ring. When the "completely unsaturated impurity % meets the shock formula" then the ring is also referred to as a "heteroaryl ring" or "aryl heterocycle". Unless otherwise indicated, a heterocyclic ring and a ring system can be attached via any available carbon or nitrogen by replacing the hydrogen on the carbon or nitrogen. "Aromatic" means that each ring atom is substantially in the same plane and has a domain perpendicular to the plane of the ring, and (4η + 2) π electrons (which are positive integers) are associated with the ring to emit shock (4). The word "fang"

"Ring system" means a carbocyclic or heterocyclic ring wherein the ring of the ring system is aromatic. U As used herein, the following definitions shall apply to this document unless otherwise stated. Lai's "replacement by substitution" is interchangeable with the phrase "via or without substitution". Unless otherwise indicated, a group optionally substituted by 36 201240602 may have a substituent at each substitutable position of the group, and each substituent is independent of each other. As noted above, G can be, in particular, a 6- to 12-membered saturated or partially saturated carbon spiro or hetero-spirocyclic ring (optionally including a ring member), each ring or ring system selectively passing up to five Substituents substituted as defined in the Summary of the Invention (i.e., R21 or R22). 6- to 12-membered saturated or partially saturated carbon spiro or heterospiro ring systems (optionally selected from the group consisting of c(=〇), C(=S), C(=NR29), C(=N-OR3 Examples of °) or 环NN(R29)2 ring members and optionally substituted with up to five substituents include rings %1 to %104 as illustrated in Exhibit 1, where y is any as described in the Summary of the Invention for GA The substituents defined (i.e., or r22), and 1> are typically integers from 0 to 4. It is worth noting that when the point of attachment on the v group is depicted as floating, the V group can be attached to the remainder of Formula 1 via any available carbon or nitrogen of the V group by replacing a hydrogen atom. unit

201240602 (RV)rUl V-10 K V-13 p V-ll

V-12 V-15

V-17

, 0 V-20

S-

(RV)r (RV)r

Si V-23 N-V-24

V-27

V-26

V-29

V-32

38)1201240602

V-34

V-39

(RV)r

(RV)r

39 201240602 (RV)r

(Rv)r

V-56 (RV)r

V-61 (Rv)r

N* V-62

(RV)r

V-64 (Rv)r

V-65

V-66 N*

V-67 (Rv)r

(RV)r

V-69

V-70

V-71 N*

V-72

V-73 (Rv)r

V-75

40 201240602 V-76

V-82

O v 〇 V-77

V-78

V-81

V-86

V-91

(Rv)r Q

V-101

41 201240602

And (RV)r

V-104 5 When GA is a 9-membered part and a slightly enclosed ring system containing a carbon ring member and 2 nitrogen ring members, the ring selectively passes through at most 2 R21 selected from the carbon ring member. Substituted by a substituent of R22 on the nitrogen ring member. Show 1A shows an example of a 9-member partially saturated fused ring system containing a carbocyclic member and two nitrogen ring members and which is optionally substituted with Rv (i.e., R21 or R22). It is worth noting that when the point of attachment on the T group is depicted as floating, the T group can be attached to the remainder of Formula 1 by replacing one hydrogen atom via any available carbon or nitrogen of the T group. . 10

When G is a 5- or 6-membered heterocyclic ring, it can be attached to the remainder of Formula 1 via any available carbon or nitrogen ring atom unless otherwise stated. When G is (especially) a 5- or 6-membered heterocyclic ring, it may be saturated or unsaturated, 15 optionally via one or more substituents selected from the group of substituents as defined in the Summary of the Invention. Replace. Examples of 5- or 6-membered heterocyclic rings which are optionally substituted by one or more substituents include ring Q-1 42 201240602, which is illustrated in Figure 2, wherein R is the selective substituent and is any such as the invention ^ In the valley, the substituents for R21 on the carbon ring member or R22 on the nitrogen ring member, and! * is an integer from 〇 to 4, which is limited to the number of available positions on each q group. Because q-29, Q 3〇, Q 36, Q 37, Q-38, Q-39, Q-40, Q-41, Q-42 and Q-43 have only one available position for these Q groupsΓ It is limited to the integer 0 or 1, and r is 〇 means that the Q group is unsubstituted and a hydrogen is present at the position indicated by (RV). ^

Q-1 (Rv 〇 Q-6

Q-16

Q-26 shows 2 3 (RV)r Ti; 4 (RV)r, male Q-2 Q-3 (RV)r (Rv)r '-N Q-7 Q-8 Xi; Q-12 Q-13 (Rv)r Q-17 Q-18 4 (Rv)r WN—S 3 (RV)r Q-22 Q-23 3 (RV)r s'—N 4 (R\ , YV N—N Q-27 Q-28 3 (RV)r

Q-9 4 (RV)r

Q-19 4 (RV)r Q-14 4 (Rv)r

, YV S-N Q-24

Q-29 Q-25

43 201240602 •N \=N Q-31 (RV)r Q-36

(RV)r Q-41

N-N (RV)r N

Q-51 XN/? Q-56 n-n Q-32 Ν/Γ (Rv)r I N-N Q-33 (R\ N=( Q-37

N (Rv>r N Q-42 Q-38 N.

N (RV)r Q-43

Strict (Rv N-N Q-47

Q-52

, NT 6 Q-57 N=N Q-48

Q-53

XT N Q-58

And Q-59 Q-60 is worthy of 4 G § G is - selectively - or a plurality of substituents selected from the substituents defined in R21 for the replacement of R21, or 5 In the ring, the heterocyclic ring or the two carbocyclic members may optionally be in the oxidized form of a carbonyl moiety. Examples of a 5- or 6-membered heterocyclic ring include the rings U-1 to U-36 as illustrated in the scheme 3. It is worth noting that when the 1; linkage point on the group is depicted as floating, then the U group can be attached to the formula i via any available carbon or nitrogen of the U group by replacing a hydrogen atom. The rest. The 44 201240602 selective substituent corresponding to Rv can be attached to any available carbon or nitrogen by displacement of a hydrogen atom. For these U rings, r is typically an integer from 〇 to 4, which is limited to the number of available positions on each U group. When 5 = is when G contains a ring selected from (10) to 6: nitrogen. It is worth noting that when U2 is N, the content H or the corresponding to the substituent (such as the definition in the second order for (10), that is, _ _ 满 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^

U-7

U-5

U-6

U-16 (RV)r

U-12 ^V)r υ'8 υ-9 ττ° Ν U·]0 υ·13 U-14 τ〇 , 2

(R\ Ν U-18 U-15 (RV)r U-π (RV)r U-19 (Rv), , i) U-20 (Rv)r xV,,/;π θ β U'29 U -30 45 201240602

U-31 and

U-36

U-33

U-34

U-35 As described above, G may be, in particular, an 8-, 9- or 1 fluorene-fused bicyclic ring system optionally substituted with one or more substituent groups selected from the group of the invention as defined in the Summary of the Invention. The substituents of the group are substituted (ie R2) or R22). Examples of 8-, 9- or 1-membered fused bicyclic ring systems optionally substituted with one or more substituents include the rings q_81 to Q-123 illustrated in Figure 4, wherein Rv is any as specified in the Summary of the Invention The substituent defined by G (i.e., R21 or R22), and r is typically an integer from 〇 to 4.

Q-81

Show 4

)r V V)r )r Jiang L Q-85 Q-86 Q-89 Q-90 Q-93

v^-y i , 0:^ Q-95

Q-84

Q'92 N (Rv)r

Q-96 (Rv)r 46 201240602

Q-121 Q-122

Although the R group has been shown in the structures Q-1 to Q-60 and Q-81 to Q-123, it is worth noting that it is not necessarily present because they are optional substituents. The nitrogen atom that needs to be substituted to fill its valence is replaced by hydrazine or Rv. It is worth noting that when (the point of attachment between RV\ and the q group is depicted as floating, (RV)r can be attached to any available carbon or nitrogen atom of the q group. It is worth noting that when When the point of attachment on the Q group is depicted as being floating, the Q group can be attached to the remainder of formula i via any available carbon or nitrogen of the Q group by displacement of a hydrogen atom. Note that certain Q groups can only be substituted with fewer than 4 RV 47 201240602 groups (eg Q-1 to Q-5, Q-7 to Q-48 and Q-52 to Q-60) 〇known There are a wide variety of synthetic methods in the art for the preparation of aromatic and non-aromatic heterocyclic rings and ring systems. For a review of the relevant methods, please refer to the Comprehensive Heterocyclic Chemistry, AR Katritzky and CW Rees editors-in-chief , Pergamon

Press, Oxford, 1984 ’ and the 12-volume collection

Heterocyclic Chemistry //, A. R. Katritzky, C. W. Rees 10 20 and E. F. V. Scriven editors-in-chief, Pergamon Press, Oxford, 1996. The compounds of the invention may exist in one or more stereoisomers. Various stereoisomers include mirror image isomers, non-image isomers, atropisomers, and geometric isomers. It will be apparent to those skilled in the art that a stereoisomer may be more active when it is concentrated relative to other stereoisomers or when isolated from other stereoisomers and may not be beneficial. Effect. Moreover, those skilled in the art know how to separate, concentrate, and/or selectively prepare the stereoisomers. The compounds of the invention may exist as a mixture of stereoisomers, individual stereoisomers or optically active forms. Those skilled in the art will recognize that many of the compounds of the present invention, as well as the intermediate compounds used in their preparation, exist in multiple tautomeric forms. For example, when the compound of formula 1 is designated as A or A-3 by A, and the R3 variable is hydroxy or 〇_Μ+, the compound of formula 1 may exist as - "trione (8) ketGne)". A construct or a "diketoenol" tautomer or a combination thereof. Similarly, the preparation is identified by A as Μ, A_2 or A_3, and the "48 25 201240602 sen" is the formula "the oxime isomer "diketosulfo-c-ol" tautomer or A combination of an isomer or a "ketothiononene compound (wherein A, is: as an example of -in-step, -r or A'-3) may exist as a dithiol" interconversion diketone" Tautomers or two or A'-3) ketones or combinations thereof. Further, the "ketoenol" tautomeric fragment 犯 which is exemplified may exist as a tautomer of the present invention in the context of the present invention having the definition of C variant A. In the species, and H species interconversion ^ = residual functional equivalents of the compound _ _ _ _ = = = = refers to the salt-related compounds blood type = meta isomers, heart compounds: including Two 15 20 body examples such as two: two applications: = her body. The crystalline form includes only the examples which substantially represent a single crystal type of U and a mixture of a polymorph (i.e., different crystal types). The term "polymorph" means a specific crystalline form of a compound which crystallizes in different crystalline forms which have different molecular arrangements and/or configurations within the crystal lattice. Although polymorphs may have the same chemical composition, they may also differ in composition due to the presence or absence of co-crystallized water or other molecules that may be weakly or strongly bound in the crystal lattice. . Polymorphs can differ in chemical, physical, and biological properties, such as crystal shape, density, hardness, color, chemical stability, melting point, hygroscopicity, suspensibility, dissolution rate, and bioavailability. Those skilled in the art will appreciate that a polymorph of a compound of Formula 1 may exhibit advantageous effects (e.g., suitable for preparing a useful formulation, as compared to another polymorph 49 25 201240602 or a mixture of polymorphs of a compound of Formula 1). Improve biological performance). A particular polymorph of a compound of formula 1 can be prepared and isolated by methods known to those skilled in the art, including, for example, crystallization using selected solvents and temperatures. Those skilled in the art will understand that not all nitrogen-containing heterocycles can form oxides because nitrogen requires a usable electron pair to oxidize to form oxides. Those skilled in the art will be able to discern those A nitrogen-containing heterocycle of 7V-oxide is formed. Those skilled in the art will also appreciate that the synthesis of 10 tertiary amines to form oxides 6 to prepare heterocyclic and tertiary amine cerium oxides is well known to those skilled in the art, including peroxyacids. Oxyacetic acid and m-peroxybenzoic acid (MCPBA), hydrogen peroxide, peroxides such as tributyl butyl peroxide, sodium perborate and diethylene oxide such as dimethyl dioxirane Ring and tertiary amine. These methods for preparing oxides have been extensively described and reviewed in the literature, for example, TL Gilchrist in Comprehensive Organic Synthesis, vol. 7, pp 748-750, SV Ley, Ed., Pergamon Press; M. Tisler and B. Stanovnik in Comprehensive Heterocyclic Chemistry, vol. 3, pp 18-20, AJ Boulton and A. 2〇 McKillop, Eds., Pergamon Press; MR Grimmett and BRT Keene in Advances in Heterocyclic Chemistry, vol. 43, pp 149-161, AR Katritzky, Ed., Academic Press; M. Tisler and B. Stanovnik in Advances in Heterocyclic Chemistry, vol. 9, pp 285-291, AR Katritzky and AJ 25 Boulton, Eds., Academic Press; and GW H_ Cheeseman and ESG Werstiuk in Advances in Heterocyclic 50 201240602

Chemistry, vol. 22, pp 390-392, A. R. Katritzky and A. j.

Boulton, Eds, Academic Press. Those skilled in the art will appreciate that gj is a salt of a compound and that its non-salt form will be in equilibrium under environmental and physiological conditions, so that the salt will share the biological form of the heteroform. Therefore, the compound of the formula l's various salts can be used to control undesired plants, that is, agriculture. The salt of formula 1 includes acid addition salts with inorganic or organic acids, such as wind acid, hydrochloric acid, nitric acid, Tannic acid, sulfuric acid, acetic acid, butyric acid, trans-butyl, diacid, lactic acid, maleic acid, malonic acid, oxalic acid, propionic acid, water = 酉 = / tartaric acid, 4 · benzoic acid or pentane acid. When the formula compound contains raw such as carboxylic acid or phenol' then the salt also includes those with organic or no dance / if, such as 0 bite, triethylamine or ammonia, or steel, unloading, bell, town or hydrazine, hydrogenation a substance, a hydroxide or a carbonate. Thus, the embodiment of the invention as described in the inclusion of a salt selected from the group consisting of the oxides of the formula and the agriculturally applicable salts also includes (wherein the formula 1 in the following examples includes the oxides thereof Further, Example 1. Compound 1 of Formula 1 as described in the Summary of the Invention, wherein A is A-1, A-3, A-4, A-5 or α·6. Embodiment 2, a compound of Embodiment i, wherein eight is A-5 or a_6. Embodiment 3. The compound of Embodiment 2 wherein A is a- or A-5. Embodiment 4. A compound of Embodiment 3 wherein A is 八^A-3. Embodiment 5. A compound of Embodiment 4 wherein eight are eight. 25 201240602 Embodiment 6. The compound of Embodiment 4 wherein A is A-3. Embodiment 7. The compound of Formula 1 or any one of Embodiments 1 to 4 wherein A is not A-1. The compound of any one of the above formulas, wherein B1 is C-1. Embodiment 9. The compound of Si or any one of Embodiments 1 to 7 wherein B1 is C-2. Embodiment 10. The compound of Formula 1 or any one of Examples 9 to 9 wherein B2 is C-3. ° 10 Embodiment 11. Formula 1 or an embodiment wherein any of the compounds is 'C 2 '. 15 Example 12·Formula 1 or Example 1 ' wherein Β3 is CM. Embodiment I3. Formula 1 or Example 1 wherein B3 is c-2. To any of the above, to any of the examples of Embodiment 14.4 1 or the embodiment, wherein R1 is from 13 to 13

R is -W] -^CBu E3)LR26; or R1 is -GA or -w2GA. - ν ΙΧ Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε Ε 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 , ,

Embodiment 16. The compound of Embodiment 15, wherein each Q1 and Q2 is independently hydrazine or N (R31). Embodiment 17. The compound of Embodiment 16, wherein each Q1 and Q2 is deuterium. The compound of any one of the above formulas, wherein Q3 is a C2_C3 alkylene group, which is optionally substituted with up to 4 substituents selected from the group consisting of CrC4 alkyl groups. Embodiment 19. The compound of Embodiment 18 wherein Q3 is a C2-C3 alkylene group which is optionally substituted with up to 2 substituents selected from the group consisting of CrC2 alkane. Embodiment 20. The compound of Embodiment 19, wherein Q3 is C2-alkylene, which is optionally substituted with up to two substituents selected from the group consisting of CrC2 alkyl. Embodiment 21. The compound of Embodiment 20, wherein Q3 is C2-extended 20 alkyl, which is optionally substituted with up to 2 substituents selected from methyl. Embodiment 22. The compound of Formula 1 or any one of Embodiments 1 to 21 wherein W5 is a CrC4 alkylene group. 53. The compound of any one of the above formulas, wherein W5 is a C2-C3 alkylene group. Embodiment 22B. The compound of Embodiment 22 wherein w5 is C2 alkyl or C3 alkyl. Embodiment 23. The compound of Formula 1 or any one of Embodiments 1 to 22 wherein R32 is hydrazine or CrC3 alkyl. Embodiment 23A. The compound of Embodiment 23 wherein R32 is H or methyl. Embodiment 24. The compound of Embodiment 23, wherein r32 is η. Embodiment 25. The compound of Embodiment 23 wherein R32 is cpc3 alkyl. Embodiment 26. The compound of Embodiment 25 wherein R32 is methyl. The compound of Formula 1 or any one of Embodiments 1 to 14, wherein R1 is -WipE1)!^4, -WtCpEqR25 or -WiCpEiLR26. Example 27. The compound of Embodiment 26A wherein ri is -WWEbR24. Example 28. The compound of Embodiment 26A wherein Ri is -WlC^E2^25. Example 29. The compound of Embodiment 26A wherein Ri is -WiCpE3)!^26. The compound of any one of Formula 1 or Embodiments 1 to 13, wherein R1 is not -N(R40)R41. Embodiment 30. A compound of Formula 1 or any one of Embodiments 1 to 14 or 26A to 29 wherein each of E1, E2 and E3 is independently 0, NOR28 or NN(R28)2. 54. The compound of embodiment 27, wherein E1 is 0. Example 32. The compound of Embodiment 27 wherein Ε1 is NOR28. Embodiment 33. The compound of Embodiment 27 wherein E1 is NN(R28)2. Example 34. The compound of Embodiment 28 wherein E2 is hydrazine. 5. The compound of embodiment 28, wherein E2 is NOR28. Example 36. The compound of Embodiment 28 wherein E2 is NN(R28)2. Embodiment 37. The compound of Embodiment 29 wherein E3 is hydrazine. Example 38. The compound of Embodiment 29 wherein E3 is NOR28. The compound of Embodiment 29, wherein E3 is ίο NN(R28)2, 。 。 。 。 。 。 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或 或C1-C3 halogenated group. Embodiment 40. The compound of Formula 1 or Embodiment 26A, 28, 29 or 34 to 39 15 wherein each L is independently Ο or N(R31); the limitation is that when E3 is 0, then L is not Is 0. Embodiment 41. The compound of Embodiment 40 wherein L is hydrazine. Embodiment 42. The compound of Embodiment 40 wherein L is N(R31). Embodiment 42A. The compound of any one of embodiments 40 or 42, wherein R31 is independently hydrazine, CrC3 alkyl or Ci-C3 halo. The compound of Formula 1 or any one of Embodiments 1 to 42 wherein W1 is C2-C4 alkylene, -(CH2)2OCH2- or -(ch2)3och2_. The compound of Embodiment 42B wherein W1 is a CrC4 stretching base. The compound of any one of the above formulas, wherein W2 is a Crc3 alkylene group. Embodiment 44. The compound of Formula 1 or any one of Embodiments 1 to 14 or 27 to 39 wherein each of R24, R25 and R26 is independently hydrogen; or CrC4 alkyl or C3-C5 cycloalkyl, each selectively Substituting one or more substituents selected from the group consisting of halogen, CN, hydroxyl, CrC2, 〇ν〇ν 亚 醢 与, and (^_(^4) 醯 醯 group. 45. The compound of embodiment 44, wherein each R24, R25 and r26 are independently hydrogen; or CrC2 alkyl or C3-C4 cycloalkyl, each optionally one or more selected from the group consisting of halogen, hydroxyl and CrC2 alkoxy The compound of any one of Formula 1 or Embodiments i to 14 wherein R1 is _(^. Example 47. Formula 1 or Examples i to 14 The compound of any one of Embodiment 46 or 47 wherein each GA is a 4- to 7-membered carbocyclic ring comprising a group selected from C (==). 〇), C(=N-〇R30) or C, (R29)2 ring members; or - 6_ to 12-membered saturated or partially saturated carbon spiro or heterocyclic ring systems, optionally including From, C (= N-0R, or C, (r29) 2 Ring members, rings or ring systems, are suitably substituted with up to three R2i on a carbon ring member and a substituent on R22 on a nitrogen member. 201240602 Example 47B. Example 46 or 47 a compound wherein each GA is a 4- to 6-membered carbocyclic ring comprising a ring member selected from C(=0), C(=N-0R3()) or C=NN(R29)2; or a 9 a to a 11-membered saturated or partially saturated carbon spiro or heterospiro-5 ring ring system, optionally comprising a ring selected from the group consisting of C(=0), C(=N-OR3Q) or C=NN(R29)2 Optionally, each ring or ring system is substituted with up to three substituents of R21 on the carbocyclic member and R22 on the nitrogen ring member. Embodiment 48. The compound of Example 47A wherein GA is a 4- a 1 to 7-membered carbocyclic ring comprising a ring member selected from C(=0), C(=N-OR3Q) or C=NN(R29)2, each ring optionally being selected from up to three selected from R21 The compound of Embodiment 48, wherein GA is a 5- or 6-membered carbocyclic ring comprising a group selected from C=0, C(=N-OR3()) 15 or C=NN a ring member of (R29) 2, each ring optionally substituted with up to three substituents selected from R21. Embodiment 49A. Combination of any of Examples 47A to 49 , wherein each R29 is independently hydrazine, QQ alkyl, CrQ haloalkyl, CrC3 alkylcarbonyl, CrC3 alkanesulfonyl or Q-C3 20 _ 醢 醢. Example 49B. The compound of Example 49A, wherein each R29 Independently C1-C6 alkyl, C1-C6 halogenated or C1-C6 burnt. The compound of any one of embodiments 47A to 49, wherein R3G is independently hydrazine, CrC3 alkyl or CVC3 halo. 57 201240602 Embodiment 50·Formula 1 or Example 47A < is a 6- to 12-membered saturated or partially s species, wherein a Ga ring ring system selectively encapsulates a carbon spiro or a heterospiro C (=N) - 〇R3.) or 〇(R29) selected from C(=〇), optionally via up to three members selected from the group consisting of R, each ring or ring system on the nitrogen ring member, R21 on the substituent The compound of Embodiment 50, wherein the GA is a 9- to 11-membered saturated or partially saturated carbon spiro or hetero-spirocyclic ring system, optionally comprising a group selected from the group consisting of c(=〇), a ring member of c(=n_〇r3〇) or C-NN(R29), each ring or ring system optionally having up to three R2 selected from the ring member and R22 on the ring member Substituent substitution. Embodiment 50. The compound of Embodiment 50 wherein R3 is independently hydrazine, Ci-C3 alkyl or CrC3 alkyl. 15C. The compound of Example 5 wherein each r29 is a CrC6 alkyl group, a CrC6-alkyl group, or a Crc6 alkylcarbonyl group. Embodiment 51. The compound of Embodiment 50, wherein ga is selected from the group consisting of

58 201240602

Wherein r is from 0 to 3; and Rv is selected from the group consisting of r2i. Embodiment 52. The compound of Embodiment 51 wherein ga is selected from the group consisting of GA-1, GA-2, GA-3, GA-7, G'8 and ga-9. The compound of Embodiment 52, wherein ga is selected from the group consisting of GA_2 and GA-3. The compound of Example 53A. The compound of Example 53 wherein qA is 2, the compound of Example 53B. Formula 1 or Examples 1 to 53A, wherein each GA is not a -9 moiety saturated fused 10 A ring system comprising a carbocyclic ring member and two nitrogen ring members, the ring being substituted with up to two substituents selected from the group consisting of rZ1 on a carbocyclic member and R22 on a nitrogen ring member. PCT Example 53C. Formula 1 or Example 丨 to "any of them" wherein each GA is a 9-member partially saturated fused and containing a ring of 2 members and 2 nitrogen ring members, the ring Substituted by a substituent selected from R22 on a nitrogen ring member. Embodiment 53D. The compound of Example 53c, each of which is 59 15 201240602

The bond extending to the left represents the point of attachment to the remainder of the compound of Formula 1. 'Example 53E - the compound of Example 53D, wherein each ga

Embodiment 54: Formula 1 or any one of Embodiments 1 to 53E, wherein R 2 is phenyl or -W 3 (phenyl), each selectively up to five selected from ring members a substitution of a substituent of R21; or -G; or a Ci-C6 group, a C2-C6 dilute group, a fast group, a C1-C6 halogen compound, a C2-C6 halogen group, a C2-C; a 6-haloalkynyl group, a C3 group -C8 cycloalkyl, C3-C8 ii cycloalkyl, c4_c1Q 15 ring alkyl, CVCiq ring calcination, CVCi4 cycloalkyl, C4-C1G _ ring calcination, C5-C12 calcination Base, C3-C8 ring dilute base, C3-Cs halo ring dilute base, C2_Cg alkoxy burnt group, Cs-Cio alkoxyalkylene group, C4-C1G ring oxyalkylene group, c4-C1() ring hospital oxygen-burning oxygen Burning base, C3-Ci() aerobic oxygen-burning base, c2-C8 20 sulfur-burning base, C2_C8-burning yam-yield base, C2-C8-situ simmering base, C2-Cg burning base, C4- C10 cycloalkyl, C2-C8 haloalkoxy, C2-C8 alkoxyhaloalkyl, C2-C8 halohalooxyalkyl, C4_C10 halocycloalkane, c4-c10 cycloalkoxy , C4-C10, Cyclooxyxanthene, C3_C10, Di-Oxygen, 60, 201240602, CrG alkoxy, CVC6 haloalkoxy, c3-c8 cycloalkoxy, CrC8 dentate alkoxy, C4-C1Q ring Alkane gas , c2-c6 alkenyloxy, c2-c6 i diloxy, C3_c6 siloxy, C3-C6 haloalkoxy, c2-c8 alkoxyalkoxy, c2-c8 5 decyloxy, C2_Cs halogen a oxy group, a CU-Cio ring-terminated oxy group, a C3-C1G alkylcarbonyl alkoxy group, a CrC6 alkylthio group, (:, <:6 halogenated sulfur group, C3-C8 cyclodextryl group, Ci_C6 burnt) The sub-stone brewing base, the CrC6 halogen-fired sub-base, the CrC6 yard, the CrC6, the halogen-burning base, the C3-C8 ring-burning, the C3-Cs, the three-color, the C3-C8 ring Dilute oxy, C3-C8 halocyclooxyl, C2-C8 halooxynoxy, CVCs, oxyhaloxy, c2-C8 haloalkoxy alkoxy, C3-C10 alkoxycarbonyl alkoxy Base, c2-c8 alkyl (thiocarbonyl)oxy, C3-C8 cycloalkylsulfinyl or C3-C10 ii|Sanyuan Shiheji; or 15 R2 is · W6C (=E4)R33, _w6l1c (= And e.g., r. Up to two members are selected from R21; or _G; or CrC6 alkyl 20 or C3-C8 ring. The compound of Example 54 wherein r2 is -W6C(=E4)R24, -\ Ι6Ι^(:(= 5) Ι125 or -ν ^ ΡΕ6)! ^ 26. Embodiment 56 The compound of Embodiment 55, wherein R2 is 25-W6C(=E4)R24. 61. The compound of Embodiment 57, wherein R2 is -\νν<:(=Ε5)Ι125. Embodiment 58. The compound of Embodiment 55, wherein R2 is 5. Embodiment 59. Compound of Formula 1 or Embodiments 1 to 58 wherein Ε4, Ε5 and Ε6 are independently 〇, N〇R37 or NN (R37 The compound of any one of Embodiment 1 or Embodiment 1 to 56 wherein E4 is hydrazine. 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。. Embodiment 62. The compound of Formula 1 or any one of Embodiments 1 to 56 wherein E4 is NN(R37)2. The compound of any one of Formula 1 or any one of Embodiments 1 to 55 or 57, wherein E5 is hydrazine. Embodiment 64. Compound 1 of Formula 1 or Embodiment 1 to 55 or 57 wherein E5 is NOR37. Embodiment 65. A compound of Formula 1 or any one of Embodiments 1 to 55 or 57 wherein E5 is NN(R37)2. The compound of any one of Formula 1 or any one of Embodiments 1 to 55 or 58 wherein E6 is hydrazine. Embodiment 67. Compound of Formula 1 or Example 丨 to 55 or %' wherein E6 is NOR37. The compound of Formula 1 or Embodiment 丨 to ^ or " any of 25, wherein E6 is NN(R37) 2. 62 201240602 Example 68A. Formula 1 or Examples 1 to 68 A compound of the formula C-C4 alkyl, -(CH2)2OCH2- or _(CH2)3〇CH2_0, wherein the compound of any one of the embodiments 69 or 1 to 68, wherein 6 is a C2-C4 alkylene group. Embodiment 70. The compound of any one of Formula 1 or Embodiment 1 to 55 or 57 to 59 or 63 to 69, wherein each L1 is independently Ο or N(R38). 70A. The compound of any one of embodiments 59, 61, 64 to 65 or 68, wherein each R37 is independently hydrazine, CrC3 danyl or C1-C3 halogen. Example 71. Formula 1 or Examples 1 to 70 a compound according to any one, wherein each R33, R34 and R35 are independently hydrogen; or a Q-C6 alkyl or C3-C6 cycloalkyl, each optionally one or more selected from the group consisting of halogen, CN, N〇2 Substituted by a group consisting of a group of Q-C4, an alkyl group, a C1-C4 alkyl group, and a C1-C4 group. Example 71B. The compound of Example 71, wherein each r33 , r34 and R35 are independently hydrogen; or CrC4 alkyl, C3-C a 5-cycloalkyl group, each optionally one or more selected from the group consisting of halogen, CN, a mercapto group, a Ci-C2 alkoxy group, a Ci-C2 fluorene group, and a Q-C2 alkanesulfonyl group Substituting a substituent of the group. Embodiment 72. The compound of Embodiment 71B wherein each R33, R34 and R35 are independently hydrogen; or CrC2 alkyl or c3-C4 cycloalkyl, each optionally selected from one or more selected from _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Each of which is optionally substituted on the ring member with up to two substituents selected from R21; or -G; or a CrC6 alkyl group or a C3-C8 cycloalkyl group. Embodiment 74. The compound of Embodiment 73, wherein R2 is a phenyl group which is optionally substituted on the ring member with up to two substituents selected from R21; or -G; or a CrC6 alkyl group or a C3-C8 cycloalkyl group. Embodiment 74A. The compound of Embodiment 73, wherein R2 is phenyl; ίο or -G; or C3-C8 cycloalkyl. Embodiment 74B. The compound of Embodiment 74A wherein R2 is phenyl, 2-. Or soil propyl. 74C. The compound of Embodiment 74A, wherein R2 is phenyl, 3-σ-septenyl or cyclopropyl.. The compound of Embodiment 74, wherein R2 is phenyl, 2-methylphenyl, 3 _Methylphenyl, 4-phenylphenyl, 3-fluorophenyl or 3,5-difluorophenyl. Embodiment 76. The compound of Embodiment 74 wherein R2 is phenyl, 3-bromophenyl, 3-phenylphenyl or 2-nonylphenyl. 2) The compound of Embodiment 74, wherein R 2 is a 5-gas-2-°tb bite. Embodiment 77. The compound of Embodiment 74 wherein R2 is phenyl. Embodiment 78. The compound of Formula 1 or any one of Embodiments 1 to 76 wherein R2 is not phenyl. The compound of Embodiment 74, wherein R2 is 3-thienyl, 2-. The thiophene or 3-° ratio bite base. 64. The compound of Embodiment 79, wherein R2 is 2-thiophenyl. Embodiment 80. The compound of Embodiment 79 wherein R2 is 3-pyridyl. The compound of Embodiment 76, wherein R2 is n-propyl, n-butyl or cyclopropyl. Embodiment 81A. The compound of Embodiment 81 wherein R2 is cyclopropyl. Embodiment 82. The compound of Formula 1 or any one of Embodiments 1 to 75, wherein W3 is -CH2-. Embodiment 83. The compound of Formula 1 or any one of Embodiments 1 to 75 wherein W4 is -CH2-. Embodiment 84. The compound of any one of Formula 1 or Embodiments 1 to 83, wherein R3 is hydroxy, -0-M+, C2-C8 alkoxycarbonyl-15, C2-C8 halooxy, C4-C10 ring a oxy or a c3-c1()alkylcarbonylalkoxy group; or a benzyloxy group, a phenoxy group, a benzylcarbonyloxy group, a phenylcarbonyloxy group, a benzenesulfonyloxy group or a benzylsulfonyloxy group, each selectively Substituted at most two substituents selected from R21 on the ring member. The compound of Embodiment 84, wherein R3 is hydroxy, -0_M+ or C2-C8 alkyloxy; or phenylsulfonyloxy, which is optionally substituted with up to two substituents selected from R21. . Embodiment 86. The compound of Embodiment 85 wherein M+ is monosodium or metal cation. The compound of Embodiment 86, wherein R3 is hydroxy or C2-Cg oximeoxy. 65. The compound of Embodiment 87, wherein r3 is a trans group or -oc(=o)ch2ch(ch3)2. Embodiment 89. The compound of any one of Formula 1 or Embodiment 7 and 14 to 88, wherein r4, R5, R6 and R7 are each independently hydrazine or CrC6 alkyl. The compound of any one of the above formulas, wherein R is Ci-C; 6 or C3_C8 cycloalkyl. Embodiment 91 The compound of Embodiment 90, wherein R8 is CH, CH2CH3 or cyclopropyl. Embodiment 92. A compound of Formula 1 or any one of Embodiments 1 to 3 or 14 to 91 wherein R9 is CrC6 alkyl. Embodiment 93. The compound of Embodiment 92 wherein R9 is CH2CH3. The compound of Formula 1 or any one of Embodiments 1 to 3 or 14 to 93, wherein R10 is H, dentate or Ci_Q alkyl. Embodiment 95. The compound of Embodiment 94, wherein the ruler 1 is H or CH3. Example 96. Formula 1 or Example 1, 2 or 14 to 95 is a compound of Φ/工-, wherein R" Or the compound of Embodiment 96, wherein Rii is H. Embodiment 98. The compound of Formula 1 or any one of Embodiment 1, 2 or 14 to 97 wherein R12 is H, halogen, cyano, thiol, amine or CVCg. Embodiment 99. A compound of Embodiment 98 which is H, halo, cyano, CrC6 alkyl or CrC8 cycloalkyl. 66. The compound of Embodiment 99, wherein Rn is CH, CH2CH3 or cyclopropyl. Embodiment 101. Compound 1 of Formula 1 or Embodiment 1 or 14 to 1 wherein Rl3 is hydrazine, imine, cyano or nitro group. Embodiment 102. The compound of Embodiment 1 wherein r13 is a nitrogen group or a nitro group. The compound of any one of the above formulas, wherein the R14 and the R1S are individually considered (i.e., R14 and R18 are not taken together as an alkylene group or an alkenyl group), then the R14 Independent of the example of R18, it is a hydrazine or a Ci_C6 alkyl group. Embodiment 104 - The compound of Embodiment 103, wherein when the examples of R1々 and R8 are taken into consideration separately, the examples of "Han" and "8" are independently Η or CH3.

Embodiment 105. The compound of Embodiment 104, wherein when the examples of rM and R18 are individually considered, the example of rm and κ1Γ is independently Η. Embodiment 106. The compound of Formula 1 or Embodiment 1 to 1〇5, wherein when R14 and W are taken together, the examples of R1^Rl8 are taken together as even CH2CH2- or -ch=chch2- . Embodiment 107. All of the examples of the compound of Formula 1 or Examples 1 to 10's are considered separately. 67 25 201240602 Embodiment 108. Compound of Formula 1 or any of Embodiments 1 to 106' wherein each of R15 and R19 is independently hydrazine or Cl_C6. Embodiment 109. The compound of Embodiment 108 wherein each of R19 is independently hydrazine or CH3. Embodiment 110. The compound of Embodiment 109, wherein each independently of R19 is hydrazine. The compound of any one of embodiments 104 to 109, wherein each of R14, R15, R18 and R19 is deuterium or CH3. Embodiment 11 The compound of Embodiment 110A wherein each of r14, R15, R18 and R19 is hydrazine. Embodiment 111. A compound of Formula 1 or any one of Embodiments 1 to 110, wherein R20 is hydrazine, CrC6 alkyl, Crc6 or C3-Cpf&lt;alkyl. Embodiment 112 - The compound of Embodiment 111, wherein the rule 2 is H or CH3. </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> <RTIgt; τ is -CH2CH2-. The compound of Formula 1 or any one of Embodiments 1 to 54, 75 or 84 to 114, wherein each G is independently a 5- or 6-membered heterocyclic ring, which is selectively selected from up to five selected from carbon R21 on the ring member is substituted with a substituent of R22 on the nitrogen ring member. 68. The compound of embodiment 115, wherein g is

G-16 G-17 G-18 G-19 where r is 0, 1, 2 or 3. Embodiment 117 - The compound of Example 116 wherein G is G_2, G-3 or G-15 0 Example 118. Compound of Example 117 wherein 〇 is 〇_2 or G-3. Embodiment 119 - The compound of Embodiment 118, wherein hydrazine is G_2. Embodiment 120. The compound of Example 118 wherein g is. Embodiment 120A. The compound of Embodiment 116, wherein hydrazine is G-15. Embodiment 121. The compound of Formula 1 or Embodiments 1 to 120 wherein each R21 is independently halogen, cyano, hydroxy, 69 201240602 nitro, -CHO, -SH, Ci-C6 alkyl, C2- C6 alkenyl, C2-C6 alkynyl, CVC6-alkyl, C2-C6 i alkenyl, c2-c6 haloalkynyl, C3-C8 cycloalkyl, C; rC8 halocycloalkyl, C4-C10 alkane Base, C4-C1G cycloalkyl, c3-c8 cycloalkenyl, C3-C8 ring-and-ring, C2-C8 azepine, C4-C10 ring oxyalkyl, C3-C10 calcined oxygen plant Base, C2-Cg sulphur sulphur*, C2-C8 sinter sinter, C2-Cs alkoxy S, c2-c5 cyano, crc6 hydroxyalkyl, crc6 alkoxy, CrC6 halane Oxy, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C4-C1G cycloalkanoyloxy, c2-c6 alkenyloxy, c2-c6 haloenyloxy, c2-c8 alkoxylated Oxygen, c2-c8 alkoxy, Ci-C6 sulphur, Ci_C6 halogen thiol, C3-C8 cyclosulphur thio, C!-C6 sinter, Ci_C6 , Ci-C6 burned the brewing base, Ci_C6 halogen burning or brewing base or C3-C8 ring hospital continued. The compound of any one of Embodiment 121, wherein each R21 is independently halogen, nitro, CrC6 alkyl, Ci-C6 halogen-based, Ci-C6 alkoxy, C!-C6 halogenated alkoxy Or crc6 alkylthio. Embodiment 122. The compound of Embodiment 121A wherein R21 is independently fluoro, ethane, bromo, CH3, CF3, och3, 〇cf3 or SCH3. Embodiment 123. A compound of Formula 1 or Embodiments 1 to 122 wherein each R22 is independently a Ci-C6 or a Ci-C6 halogen. Embodiment 124. Compound of Embodiment 123 wherein each R22 is independently CH3 or CH2CF3. 70. The compound of Embodiment 124, wherein R22 is CH3. Embodiment 124B. A compound of Formula 1 or Embodiments 1 to 124A wherein R4G is ethyl or isopropyl. Embodiment 124C. A compound of Formula 1 or Embodiments 1 to 124A wherein R41 is ethyl or isopropyl. Embodiment 124D. A compound of Formula 1 or Embodiments 1 to 124A wherein R40 and R41 together are -(CH2)5-, -CH2CH=CHCH2- or -(CH2)20(CH2)2-. The compound of Embodiment 124D, wherein R40 and R41 together are as -(CH2)5- or -((:ί12)20((:ϋ2)2-. Example 124F. The compound of Example 124, wherein R40 and R are taken as -(CH2)2〇(CH2)2-. 15 20 The present invention also encompasses a herbicidal mixture comprising (a compound selected from Formula 1, its oxides and salts thereof, and (b) At least one additional active ingredient selected from the group consisting of (bi) photosystem π inhibitors, (b2) acetate synthase (HAS) inhibitors, (b3) acetamidine C () Amase (ACCase) inhibitors , (b4) auxin mimetic, (b5) 5-enol-acetone oxalic acid _3_phosphoric acid (EPSP) synthetase inhibitor, (10) photosystem 〗 electronic diverters (diverters), (b7) primary violet oxidation Enzyme (pp〇) inhibits Qib &amp; indoleamine (GS) inhibitor, (iv) very long bond fatty acid extender, (M0) auxin transport inhibitor, octohydrochlorin = = = inhibitor, _4_ silk-pyruvate dioxygen s# (hppd) inhibitor, R + agent, _ other herbicides (, =, urinary transfer enzyme (abdominal) inhibits sub-speed rotten, oats, two splitting interfering agents , organic Kunming, Wu Butai, grass Ding, cycloheptyl ether, benzalkonium, 25 201240602 Mailon, T. chinensis, Methylidene, acetophene, chlorpyrifos, chlorpyrifos, Weibai, oxazin , oleic acid, pelarg〇nic acid oxadicarb and (M5) herbicide protectant; and (bl) to (bl5) a salt of the compound. Example 125. A herbicidal mixture comprising (0) 1 or a compound of any of embodiments 1 to 125E, and (b) at least one selected from the group consisting of (bl), (b2), (b3), (bl2), (bl3) and (M5). The herbicidal mixture of embodiment 125, wherein component (b) comprises at least one additional active ingredient selected from the group consisting of (bl), (bl2), (bl3) and (bl5). Embodiment 127. The herbicidal mixture of Example 126, wherein the ingredients (b) comprises at least one additional active ingredient selected from (bl). Embodiment 128. The herbicidal mixture of embodiment 127, wherein component (b) comprises bromoxynil. Example 129. Herbicidal mixture of Example 127 The ingredient (b) comprises a dimethametryn. Embodiment 130. The herbicidal mixture of embodiment 126, wherein component (b) comprises at least one selected from the group consisting of An additional active ingredient of bl3). Embodiment 131. The herbicidal mixture of embodiment 130, wherein component (b) comprises haloxydine. Embodiment 132 - the herbicidal mixture of embodiment 126, wherein component (b) comprises at least one An additional active ingredient selected from (bl5). Embodiment 133. The herbicidal mixture of embodiment 132, wherein component (b) comprises at least one additional active ingredient selected from the group consisting of chlorpyrifos, chlorpyrifos, 1-bromo-4-[(methylmethyl)sulfonyl] Benzene, solution 72 201240602 toxic quinquin, benzalkon, acetochloronitrile, pyridine azide, chlorpyrifos, a random propylene amine, two ring ang g (Cyc丨〇n〇n), 4_ (two gas B Mercapto)-1-oxa-4-azospiro[4 5]decane (M〇N 4660), 2-(dichloromethyl)_2_methyl_13_dioxolane (MG) 191), piperidan, oxazolidine, oxadiazepine, oxalic acid, flubendiate, chlorpyrifos, diphenyl chelate, salivary, mephenate, benzophenone, Naphthalic anhydride and 8 oxalic acid. 134. The herbicidal mixture of embodiment 133, wherein component (b) comprises at least one additional active ingredient selected from the group consisting of chlorpyrifos, detoxified quinine, beta-fixamidine, chlorpyrifos, sulforaphane, oxazole Herbicide, Mevoto and oxalic acid. Embodiment 135. The herbicidal mixture of Embodiment 134, wherein the component (b) comprises at least one additional active ingredient selected from the group consisting of detoxified quinoxaline, zoresin and oxaliconitrile. Embodiment 136. The herbicidal mixture of embodiment 135, wherein component (b) comprises at least one additional active ingredient selected from the group consisting of detoxified quinoxanes. Embodiment 137. The herbicidal mixture of embodiment 135, wherein component (b) comprises at least one additional active ingredient selected from the group consisting of oxaliconitrile. Embodiments of the invention (including the above Examples 1-124F and any other embodiments described herein) may be combined in any manner, and the description of the variations in the examples applies not only to the compound of Formula 1, but also to Starting compounds and intermediate compounds (including compounds of Formulas 1Q, 1R and 1S) which are useful in the preparation of compounds of Formula 1. Furthermore, the embodiments of the present invention (including the above-described Examples 1 to 124E or 125 to 137 to 73 201240602 and any other embodiments described herein, in combination with any of them) are applicable to the compositions and methods of the present invention. The combinations of Examples 1 to 124F are illustrated by the following: Example A. The compound of Formula 1, wherein A is Α·1, A-3, A-4, A-5 or Α·6; R1 is

Or ίο R1 is -WtpE1)!^24, -WlLC(=E2)R25 or -WtpEiLR26; or R1 is N(R4Q)R41; or R1 is GA or -W2GA; GA is a 9- to 11-member saturated or a partially saturated carbon spiro or heterospirois is ring system, optionally comprising a ring member selected from C(=0), C(=N-0R3(&gt;) or C=NN(R29), each ring or The ring system is selectively substituted with up to three substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; or each GA is a 9-membered partially saturated fused and carbocyclic ring member and 2 a ring of nitrogen 20 ring members substituted by a substituent selected from R22 on a nitrogen ring; each of E1, E2 and E3 is independently Ο, NOR28 or NN(R28)2; L is independently Ο or N (R31); 74 201240602 and 11 are independently hydrogen; or CrC4 alkyl or C3-C5% alkyl, each optionally one or more selected from the group consisting of a functional element, a CN, a hydroxyl group, a Cl_C2 alkoxy group, and a Ci_c2 alkane a substituent of a group consisting of a sulfonyl group and a fluorene group; each R28 is independently a fluorene, a CrC3 alkyl group or a Cl_C3 haloalkyl group; each R is independently a hydrazine, a CrC3 alkyl group, a CrC3 4 alkyl group, crC3 alkylcarbonyl, CV-C: 3 alkanesulfonyl or crC3 halosulfonyl; each Q1 and Q2 are independently 〇 or N(R31); Q is a C^-C3 extended alkyl group which is optionally substituted with up to two substituents selected from the group consisting of Ci-C4 alkyl; R30 is independently hydrazine, CrC3 alkyl or CrC3 dentate R31 is independently hydrazine, CrC3 alkyl or CrC3 dentate; R32 is hydrazine or crc3 alkyl; W1 is c2-c4 alkyl, -(CH2)2OCH2^_(CH2)3〇CH2_; W2 is Crc3 An alkyl group; W is a C1-C4 stretching group; R2 is a phenyl group or a -w3 (phenyl group), each selectively having up to five members selected from R21; or -G; or CrC6 alkyl group, C2; -C6 dilute group, C2_C6 fast group, Ci_C6 halogen compound group, C2_C6 alkenyl group, c2-c6 haloalkynyl group, c3-c8 cycloalkyl group, c3-c8 halocycloalkyl group, c4-c1G alkane cycloalkyl group, c4 -c1G cycloalkane, c6-c14 cycloalkylcycloalkyl, c4-c10 functional cycloalkylalkyl, c5-c12 alkanealkyl, C3-C8 cycloaliphatic, C3-C8 halocyclo, C2 -C8 alkoxyalkyl, CrC1G alkoxyalkenyl, C4-C1G cycloalkoxyalkyl, C4-C1Q cycloalkoxyalkyl, c3_c1G alkoxyalkyl, CrC8 alkylthio, C2-C8 Alkylsulfinylalkyl, 75 201240602 〇2_匸8 Hyun&gt; Continued Brewing Base, 匚2_匚8 Burning No Base, C4-C1Q 环佛烧基, C2-C8 牙院氧院, C2_C8 Oxygen , c2-c8 haloalkoxyalkyl, c4-c10 halocycloalkoxyalkyl, CrC10 cycloalkenyloxyalkyl, C4-C10 halocycloalkenyloxyalkyl, C3-C10 dialkyloxyalkyl, CrC6 alkoxy , CVQ haloalkoxy, C3-C8 cycloalkoxy, C3-C8 ill ring oxime, c4-c10 cycloalkanoxy, c2-c6 alkenoxy, c2-c6 haloenyloxy, c3 -c6 alkynyloxy, c3-c6 haloalkoxy, c2-c8 alkoxyalkoxy, c2-c8 alkylcarbonyloxy, c2-c8 ii alkylcarbonyloxy, C4-C10 cyclopentyloxy, C3 -C1G burns several oxy groups, thiol groups, Cl-Cg. sulphur-based, C3-C8 rings; thiol, CVC6 alkylsulfinyl, CVC6 halosulfinyl, CrC6 alkanesulfonyl, CVC6 haloalkylsulfonyl, c3-c8 cyclodextrin, C3-C8 three-yard base, C3-C8 cycloaliphatic, C3-C8 functional cycloalkenyloxy, C2-C8 alkoxylated oxygen Base, c2-c8 alkoxyhaloalkoxy, c2-c8 haloalkoxyhalooxy, c3-c1() alkoxycarbonylalkoxy, C2-C8 alkyl(thiocarbonyl)oxy, c3-c8 Substituted with a cycloalkylsulfinyl or a c3-c1G-trialkylsulfonyl substituent; or R2 is -W6C(=E4)R33, -^/6LlC(=E5)RM or -W6C(=E6)L1R35; E4, E5 and E6 are independent of ο, NOR37 or NN(R37)2; each L1 is independent Is o or N(R38); each R, R and R are independently hydrogen; or Ci_C4, C3_C5 cycloalkyl, each optionally one or more selected from the group consisting of dentate, CN, thiol, crc2 alkoxy Substituted by a group consisting of a group consisting of a group consisting of a Crc2 alkanesulfonyl group; each of R37 is independently a fluorene, a CrC3 alkyl group or a crc3 haloalkyl group 28 independently as a fluorene, a C1-C3 courtyard group. Or C1-C3 haloalkyl; W3 is _CH2-; ]〇w6 is C2-C4 alkyl, -(CH2)2〇CH2- or -(ch2)3och2-; R3 is a trans group, c2-c8 Alkylcarbonyloxy, c2-c8 halocarbonyloxy, c4-c1Gcycloalkaneoxy or c3-c1G alkylcarbonyloxy; or benzyloxy, phenoxy, benzylcarbonyloxy, phenylcarbonyloxy a benzenesulfonyloxy or a sulfonyloxy group, each optionally substituted with up to two substituents selected from R21 on the ring member; M+ is a monosodium or a metal cation; R is a Ci-C6 alkyl group;

RlG is hydrazine, halogen or CiC6_alkyl; 15

Rl1 is Η or CrCVJ^; 12 R is H, halogen, cyano, hydroxy, amine or c-C6 alkyl; each R14, R15, R18 and R19 is Η or CH3; r2Q is Η or CH3; Is -CH2CH2- or -CH=CH-; 20 each G is G-1 to G-20 (as described in Example 116); r is 〇, ι, 2 or 3; each R21 is independently halogen, cyanide Base, hydroxyl, nitro, -CHO, -SH,

Ci-C6, C2-C6 dilute, C2-C6 fast radical, Ci-C6 haloalkyl, c2-c6 haloalkenyl, C2-C6 haloalkynyl, C3-C8 cycloalkyl, C3-C8 halo Cycloalkyl, C4-C10 alkyl group, C4-C10 cycloalkyl, (3-(:8-cycloalkenyl, C3-C8 halocycloalkenyl, c2-c8 77 25 201240602 alkoxyalkyl, CVCn) cycloalkoxyalkyl, c3-C1G alkoxy alkoxy, C2-Cg sulphur-burning, C2_Cg sulphide, c2-c8 alkoxyhalo, c2-C5 cyano , crc6 hydroxyalkyl, CrC6 alkoxy, crC6 li alkoxy, c3-c8 5 cycloalkoxy, C3_c8 cycloalkoxy, c4-c1G cycloalkanoxy, C2-C6 dioxy, c2 -c6 haloenyloxy, c2-c8 alkoxyalkoxy, C2-C8 alkoxycarbonyl, crc6 alkylthio, Ci_C6 halogenated thio, C3-C8 cyclosulphonyl, Ci_C6 sulfinyl, Crc6 haloalkyl sulfinyl, crc6 alkanesulfonyl 10, Crc6 4 alkanesulfonyl or C3-C8 cycloalkylsulfonyl; each R22 is independently CrC6 alkyl or CrC6-alkyl; R40 is ethyl or different a propyl group; and R is an ethyl group or an isopropyl group; or R40 and r41 together as -(CH2)5-, -CH2CH=CHCH2- or 15-(CH2)2〇(CH2)2-. a compound of example a, Wherein A is A-1, A-3 or A-5; B1 is C-1; B2 is C-3; 20β is C-1; R1 is -GA; each GA is selected from GA-1, GA- 2. GA-3, GA-7, GA-8 and GA-9; or each GA is

7S 25 201240602

R2 is phenyl or _W3 (phenyl), each optionally substituted with up to two substituents selected from R21 on the ring member; or -G; or CrC6 5 or 〇3~(^8 ring-burning R3 is hydroxy or CVC8 alkoxycarbonyl; R9 is CH2CH3; R1G is Η or CH3; T is -CH2CH2-; 10G is G-2, G-3 or G-15; and r21 is independently dentate, Nitro, CrC6 alkyl, CrC6 aldentyl,

CrC6 alkoxy, Ci_C6 i alkoxy or CrC6 alkylthio; each R22 is independently CH3 or CH2CF3; and r4〇 together with r41 as _(CH2)5-, -CH2CH=CHCH2- or 15-(CH2)2 〇(CH2)2-. Embodiment C. A compound of Embodiment B wherein A is A-1 or A-3; each GA is selected from the group consisting of GA-2 and ga-3; or each GA is

, benzene^; or -G; or (: 3-(:8 cyclization; and R~ as _(CH2)5- or -(CH2)20(CH2)2-. 79 201240602 Example D. Examples a compound of c, wherein A is A-1; each 〇4 is

R2 is phenyl; r3G is fluorenyl or fluorenyl; R21 is halogen or (: 丨-(:3 alkyl; and R22 is CH3. Example E. The compound of Example b, wherein A is A-1; GA is GA-2; R2 is phenyl, 2-thienyl, 5-chloro-2-pyridyl or cyclopropyl; R3 is a trans group; and each of R14, R15, R18 and R19 is H. Example F. Examples A compound of B, wherein A is A-3; GA is GA-2; R2 is phenyl, 2-thienyl 5-chloro-2-pyridyl or cyclopropyl; and R3 is a trans group. A compound of the formula wherein A is A-1; R1 is 80 25 201240602

Each Q1 and Q2 is Ο; 5 Q3 is C2_stretching base; R32 is fluorene or fluorenyl; W5 is C2-C3 alkyl; R2 is phenyl, 2-mercaptophenyl, 3-methylphenyl , 3-bromophenyl, 3-phenylphenyl, 4-p-phenyl, 3-fluorophenyl, 3,5-difluorophenyl, ίο 3-nonyl or 2-nonyl, R3 is hydroxy Or -0C(=0)CH2CH(CH3)2; and each of R14, R15, R18 and R19 is Η or CH3. Embodiment H. The compound of Embodiment G wherein W5 is C2 alkyl or C3 alkyl; is R2 is phenyl, 3-thienyl or cyclopropyl; and R3 is hydroxy. Specific examples include a compound of formula 1 selected from the group consisting of 3-(1,4-dioxaspiro[4.5]dec-8-yl)-5.[(2-hydroxy-6-o-oxyl_1. ί 己 -1- ) ] ] ] ] ] ] ] ] -2- -2- -2- -2- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- 3- - 6-oxo-l-cyclohexen-l-yl)carbonyl]-2-phenyl-4(3 //)-pyrimidinone) (Compound 1), 5-[(2-hydroxy-6-sideoxy-1- Cyclohexene-1-yl)carbonyl]-6-sideoxy-2-phenyl-1(6//)-mouth bite acetic acid · 1-(0-曱 base fat) 201240602 (5-[(2- Hydroxy-6-oxo-l-cyolohexen-l-yl)carbony l]-6-oxo-2-phenyl-l(6//)-pyrimidineacetaldehyd e l-(C)-methyloxime)) (Compound 2), 2 -(5-aza-3-acridinyl)-3-(1,4-dioxaspiro[4.5]dec-8-5yl)-5-[(2-carbyl-6-sideoxy- 1-(5-//)-pyrimidinone (2-(5-chloro-3-pyridinyl)-3-(l,4-dioxaspiro[4.5] dec- 8-yl)-5-[(2-hydroxy-6-oxo-l-cyclohexen-lyl)carbonyl]-4(3//)-pyrimidinone) (Compound 7), ίο 2-ί哀propyl-3 -(l,4-dioxaspiro[4.5]dec-8-yl)-5-[(2_carbyl-6-o-oxy-1-cyclohex-1-yl)yl]-4 (3//) - shouting (2-cyclopropyl-3-(i,4-dioxas) Piro[4.5]dec-8-yl)-5-[(2-hydroxy-6-oxo-l-cyclohexen-l-yl)carbonyl]-4(3//)-pyrimidinone) (Compound 10), 15 3 -(1,4-Dioxaspiro[4.5]dec-8-yl)-5-[(2-hydroxy-4-oxobicyclo[3.2.1]oct-2-en-3-yl)carbonyl] -2-(2·thienyl)-4(3//)-pyrimidinone (-(l,4-dioxaspiro[4.5]dec-8-yl)-5-[(2-hydroxy-4 -oxobicyclo[3.2 .1]oct-2-en-3-yl)carbonyl]-2-(2-2〇thienyl)-4(3ii)-pyrimidinone) (Compound 15) and 5-[(2-Pheptyl-6-side) Oxy-1-cyclohexyl-1-yl)methyl]-2-phenyl-3-(4,5,6,7-tetrahydro-2-methyl-2//-carbazole-5- Base)-4(3//)- ketone (5-[(2-hydroxy-6-oxo-l-cyclohexen-l-yl)carbony 25 l]-2-phenyl-3-(4,5, 6,7-tetrahydro-2-methyl-2//-i ndazol-5_yl)-4(3//)-pyrimidinone) (Compound 19). 82 201240602 The embodiments of the invention as described in the Summary of the Invention also include (wherein Formula 1Q as used in the Summary of the Examples below includes its cerium oxide and salts thereof): Example 1Q. Compound of Formula 1Q, wherein A' is A'-l, A'-3 5 or A'-5. Embodiment 2Q. The compound of Embodiment 1Q wherein A is Α··1 or Α,-3. Embodiment 3Q. The compound of Embodiment 2Q wherein Α· is A’-1. Embodiment 4Q. A compound of Embodiment 2Q wherein A. is A'-3. 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。. Embodiment 6Q. A compound of Formula 1Q or any one of Embodiments 1Q to 4Q, wherein B1 is C-2. Embodiment 7Q. A compound of Formula 1Q, or any one of Embodiments 1Q to 6Q, wherein B2 is C-3. Embodiment 8Q. A compound of Formula 1Q or any one of Embodiments 1Q to 6Q, wherein B2 is C-4. Embodiment 9Q. A compound of Formula 1Q or any one of Embodiments 1Q to 8Q, wherein .B3 is C-1. The compound of the formula 1Q or any one of the embodiments 1Q to 8Q, wherein B3 is C-2. Embodiment 11Q. A compound of Formula 1Q or any of Embodiments 1Q to 10Q, wherein R1 is 83 201240602

R1 is -WiCpEbR24, -\¥士(:(= ugly 2)1125 or -W^pEiLR26; or R1 is -GA or -W2GA. Example 12Q. Compound of Formula 1Q or any of Examples 1Q to 11Q , where R1 is 10

Embodiment 13Q. The compound of Embodiment 12Q wherein each of Q1 and Q2 is hydrazine. The compound of Embodiment 12Q wherein Q3 is a C2-alkylene group which is optionally substituted with up to two substituents selected from the group consisting of CrC2 alkyl groups. Embodiment 15Q. The compound of Embodiment 14Q wherein Q3 is C2.alkylene, which is optionally substituted with up to 2 substituents selected from thiol. Embodiment 16Q. A compound of Formula 1Q or any one of Embodiments 1Q to 15Q wherein W5 is a CrC4 alkylene group. Embodiment 17Q. A compound of Formula 1Q or any one of Embodiments 1Q to 16Q wherein R32 is hydrazine or CrC3 alkyl. 84201240602 Embodiment 17QA. The compound of Embodiment 17Q wherein R32 is hydrazine or methyl. Embodiment 18Q. The compound of Embodiment 17Q wherein R32 is methyl. The compound of any one of the above formulas 1Q or 1Q to 11Q, wherein R1 is -WtpEbR24, -WtceE^R25 or _W1C(=E3)LR26. Embodiment 12QA. A compound of Formula 1Q or any one of Embodiments 1Q to 19Q wherein W1 is C2-C4 alkyl, ίο-(CH2)2OCH2- or -(CH2)3OCH2-. Embodiment 20Q. A compound of Formula 1Q or any one of Embodiments 1Q to 11Q or 19Q, wherein each of E1, E2 and E3 is independently Ο, NOR28 or NN(R28)2. Embodiment 20QA. A compound of Formula 1Q or any one of Embodiments 1Q to 20Q, wherein R28 is independently H, CrC3 alkyl or C1-C3 13⁄4. Courtamentally Example 20QB. Formula 1Q or Examples 1Q to 10Q A compound of the formula wherein R1 is not -N(R4G)(R41). Embodiment 21Q. The compound of any one of Formula 1Q or Embodiment 1Q to 11Q or 19Q, wherein each L is independently Ο or N(R31); the limitation is that when E3 is 0, L is not 0. Embodiment 22Q. A compound of Formula 1Q or any one of Embodiments 1Q to 21Q, wherein W1 is a CrC4 alkylene group. </ RTI> </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> </ RTI> <RTIgt; Substituting one or more substituents selected from the group consisting of _, CN, hydroxy and CrC 2 alkoxy, compound of Example 24Q. Formula 1Q or Example 1Q to any of them, wherein R1 is -GA. The compound of Embodiment 24Q, wherein # is a 5- to 6-membered carbocyclic ring comprising a ring member selected from O〇, or C=NN(R29)2, each ring optionally being at most Two substituents selected from R21 are substituted. Embodiment 26Q. The compound of Embodiment 25Q wherein R29 is independently hydrazine, CrC3 alkyl, CrC3-alkyl or Ci_C3 alkylcarbonyl. Embodiment 26QA. The compound of Embodiment 25Q wherein r3〇 is independently hydrazine, CrC3 alkyl or CVQ dentate. Embodiment 27Q. The compound of Embodiment 24Q wherein ga is a 9- to 10-membered hetero-spirocyclic ring system, optionally comprising a moiety selected from C(=0) or C(=N-OR3()) a ring member, each ring or ring system is optionally substituted with up to two substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; Embodiment 28Q. A compound of Embodiment 27Q wherein R30 is independently Η, C1-C3, or C1-C3 halogen; Example 29Q. Compound of Example 27Q or 28Q' wherein GA is selected from the group consisting of GM, GA-2, GA-3, GA-7, GA-8 and GA-9 (as described in Example 51). Embodiment 30Q. The compound of Embodiment 29Q wherein the GA is selected from the group consisting of GA-2 and GA-3. 86 201240602 Example 30QA. Compound of Example 30Q, GA-2. Wherein GA is the compound of Example 30QB. Formula 1Q or the compound of Example to 4 is a member:: and a ring system which is fused and contains a ring member and two nitrogen ring members. Up to two substituents selected from R22 on the ring member of the nitrogen ring member are substituted. And a compound of any one of the embodiments 30QC·Formula 1 or Examples iq to 24q, wherein each # is a 9-membered partially fused ring system comprising a carbocyclic ring member and 2 nitrogen ring members, the ring Substituted by i substituents selected from R22 on a nitrogen ring member. Embodiment 30QD. The compound of Example 30QC wherein each gA is 15

22 wherein the key extending to the left represents the point of attachment to the remainder of the compound of Formula 1. Embodiment 30QE. The compound of Example 30QD, wherein each

87. The compound of any one of the above formulas, wherein R 2 is phenyl or -W 3 (phenyl), each selectively having up to two selected from R 21 on the ring member. Substituent substitution; or -G; or CrC6 alkyl or C3-C8 cycloalkyl. The compound of Embodiment 31Q, wherein R 2 is phenyl, which is optionally substituted with up to two substituents selected from R 21 on the ring member; or -G; or CrC6 alkyl or C3-C8 ring Burning base. Embodiment 32QA. The compound of Embodiment 32Q wherein R2 is benzyl hydrazide; or -G; or C3-C8 cycloalkyl. Embodiment 32 QB. The compound of Embodiment 32QA wherein R2 is phenyl, 2-σ-saltyl 5-a-2-one ratio dimethyl or cyclopropyl. Embodiment 32 QC. The compound of Embodiment 32QA wherein R 2 is phenyl, 3 exemplyl or cyclopropyl. 15. The compound of Embodiment 32Q wherein R 2 is phenyl, 2-nonylphenyl, 3-mercaptophenyl, 3-bromophenyl, 3-phenylphenyl, 4-chlorophenyl, 3 - fluorophenyl or 3,5-difluorophenyl. Embodiment 33QA. The compound of Embodiment 32Q wherein R2 is phenyl, 3-. Queenyl or cyclopropyl. The compound of Embodiment 33Q wherein R2 is phenyl. Embodiment 35. A compound of Formula 1Q, or any one of Embodiments 1Q to 31Q, wherein R2 is not phenyl. Embodiment 36. The compound of Embodiment 35Q wherein R2 is 3-25 ° thiophene, 2-° thiophene or 3-° ratio thiol. 88 201240602 Embodiment 36Qa. The compound of Embodiment 36Q wherein R2 is a 3-0 ratio to a bite group. Embodiment 37. A compound of Formula 1Q or any one of Embodiments 1Q to 36Q, wherein W3 is -CH2.

5 Embodiment 38Q. A compound of Formula 1Q or any of Embodiments 1Q to 3Q, 7Q and 11Q to 37Q, wherein 119 is a CrC6 alkyl group. Embodiment 39. The compound of Embodiment 38Q wherein R9 is CH2CH3. The compound of any one of Formula 1Q or Embodiment 1Q or 11Q to 39Q wherein R1Q is H, halogen or CrC6 alkyl. Embodiment 41. The compound of Embodiment 40Q wherein R1G is Η or CH3. The compound of any one of the formulas 1Q or 1Q to 41Q, wherein when the examples of R14 and R18 are considered separately (ie, R14 and R18 are not taken together as an alkylene group or an alkenyl group), Examples of R14 and R18 are independently hydrazine or CrC6 alkyl. 2. The compound of Embodiment 42Q wherein, when the examples of R14 and R18 are individually considered, the examples of R14 and R18 are independently hydrazine or CH3. Embodiment 44Q. The compound of Embodiment 43Q wherein, when the examples of R14 and R18 are considered separately, then Example 25 of R14 and R18 is independently oxime. 89 201240602 Embodiment 45Q. A compound of the formula 1Q or any of the examples 1Q to 44Q wherein each of R15 and R19 is independently hydrazine or CH3. Embodiment 46. The compound of Embodiment 45Q wherein each R!5 and 5R19 are independently H. Embodiment 47Q. A compound of Formula 1Q or any of Embodiments 1Q to 46Q wherein R2G is hydrazine, CrC6 alkyl, Ch: 6 alkenyl or (: 3-(:8 cycloalkyl). Example 48Q. The compound of any one of the compounds of the formula 47Q, wherein is H 10 or CH 3 0, or a compound of the formula 1Q, 2Q, 4Q, 7Q, 8Q and 11Q to 48Q, wherein T is -CH2CH2- or -CH The compound of Example 49Q, wherein τ is 15-CH2CH2-. Example 51Q. Compound of Formula 1Q or any of Examples 1Q to 50Q wherein G is G-2, G- 3 or G-15 (as described in Example 51). Embodiment 52Q. The compound of Example 51Q wherein G is G 2 20 (as described in Example 51). Example 53Q. Example 51Q A compound, wherein G is G_3 (as described in Example 51). Embodiment 54Q. A compound of Formula 1Q or any of Examples iq to 54q, wherein each R21 is independently dentate, nitro, 25 Crc6 alkane a group, CrC6 from an alkyl group, a crc6 alkoxy group, a Ci_c6 haloalkoxy group or a crc6 alkylthio group. 16 90 201240602 a you as a compound of 54Q, wherein R is independent of the example 55Q. Example 5 ^^ 噃, CH3 , CF3, OCH3, OCF3 or Helmet Gas, Fluorine, / Schöning SCH3 ° Example 56Q. Formula 1Q or each of R22 independently is C1-C6 Hyun* or Ci-C6 Halogen*. Example 57Q. Example And a compound of the formula QQ. A compound wherein R41 is ethyl or isopropyl. Embodiment 60Q. A compound of Formula 1Q or Examples 1Q to 57Q, wherein R40 and R41 together are -(CH2)5-, -CH2CH=CHCH2- or _(CH2 2〇(CH2)2_. 15 Embodiment 61. The compound of Embodiment 60Q wherein R4G together with R41 is -(CH2)5, or _(CH2)2〇(CH2)2. Example 62Q. A compound of 61Q, wherein R40 and R41 together act as -(ch2)2o(ch2)2-. Embodiments of the invention as described in the Summary of the Invention also include (wherein, for example, the formula for the invention in the following examples) 1R includes its ruthenium-oxide and its salts): Example 1R. A compound of formula 1R wherein Ri is 201240602 each Q1 and Q2 are oxime; Q3 is C2-alkylene; R32 is oxime or methyl; 5 W5 is c2 -c3 alkylene R2 is phenyl, 2-mercaptophenyl, 3-mercaptophenyl, 3-bromophenyl, 3-phenylphenyl, 4-p-phenyl, 3-fluorophenyl, 3,5·difluoro Phenyl, 3-thienyl, 2-thienyl or 3-pyridyl; and each of R14, R15, R18 and R19 is deuterium. Ίο Embodiment 1RA. A compound of Formula 1R or Example 1, wherein R1 is other than -N(R, (R41). Embodiment 1 RB. A compound of Formula 1R wherein R 2 is phenyl; or -G; or (: 3- (8 Cycloalkyl. Example 1 RC. The compound of Example 1 RB, wherein R 2 is phenyl 15 yl, 2-° thiophene 5-chloro-2-° ratio dimethyl or cyclopropyl. Example 1 RD. The compound of Example 1 RB, wherein R 2 is phenyl, 3-β-thenyl or cyclopropyl. Embodiment 2R. The compound of Example 1R wherein R 2 is phenyl, 2-methylphenyl, 3-mercaptobenzene , 4-phenylphenyl, 3-fluorophenyl-2-indenyl or 3,5-difluorophenyl. Embodiment 3R. The compound of Example 1R wherein R 2 is phenyl, 3-t»septenyl or cyclic The compound of Example 1R, wherein R2 is phenyl, 3-bromophenyl, 3-phenylphenyl or 2-mercaptophenyl. 25 Example 4R. The compound of Example 1R, wherein R2 is 3-thienyl, 2-thinyl or 3-octyl. 92 201240602 Embodiment 5R. The compound of Embodiment 1R, wherein R2 is phenyl. Embodiment 6R. A compound of Formula 1R wherein R1 is -WkpEbR24 ; E1 is NOR28; 5 R28 is hydrazine or fluorenyl; and R2 is phenyl, 2- Phenylphenyl, 3-methylphenyl, 3-bromophenyl, 3-phenylphenyl, 4-chlorophenyl, 3-fluorophenyl, 3,5-difluorophenyl, 3-°-septyl , a compound of the formula 6R, wherein R 2 is phenyl, ίο 2-decylphenyl, 3-mercaptophenyl, 4-chlorobenzene. a compound of the compound of Example 6R wherein R 2 is phenyl, 3-bromophenyl, 3-chlorophenyl or 2-methylbenzene. The compound of Embodiment 6R, wherein R2 is 3-thiaisyl, 2-nonyl or 3-ton. The compound of Example 6R, wherein R2 is phenyl. Embodiment 11R. A compound of Formula 1R wherein R1 is -GA; each GA is a 5- to 6-membered carbocyclic ring comprising a ring member selected from C(=0) or 2〇C(=N_OR3()) Or a 9- to 10-membered saturated heterospiro ring system optionally comprising a ring member selected from C(=0) or C(=N-OR3()), each ring or ring system selectively Substituted by at least two substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; 25 R3() is hydrazine or methyl; R21 is halogen or CrC3 alkyl; 93 201240602 1122 is crc3 Embodiment 12. R. The compound of Embodiment 11R, wherein the GA is selected from the group consisting of GA-Bu G'2, GA-3, GA-7, GA-8, and GA-9 (as described in Example 51), And 5 R2 is phenyl, 2-mercaptophenyl, 3-mercaptophenyl, 3-bromophenyl, 3-chlorophenyl, 4-chlorophenyl, 3-fluorophenyl, 3,5-di Fluorophenyl, 3-σsecenyl 2-. The compound of Example 11R, wherein R 2 is phenyl, 2-methylphenyl, 3-mercaptophenyl, 4-chlorophenyl, 3_ ίο fluoro Phenyl or 3,5-difluorophenyl. Embodiment 14R. The compound of Embodiment 11R wherein R2 is phenyl, 3-bromophenyl, 3-phenylphenyl or 2-methylphenyl. Embodiment 15 R. The compound of Embodiment 11R wherein R 2 is 3 σ thiophene, 2-. The thiophene or 3-° ratio bite base. Is a compound of Embodiment 11R wherein R2 is phenyl. Embodiment 16RA. A compound of Formula 1R wherein each GA is

The bond extending to the left represents the point of attachment to the remainder of the compound of formula 1R. Embodiment 16 RB. The compound of Example 16RA, wherein each Ga 94 201240602

The bond extending to the left represents the point of attachment to the remainder of the compound of Formula 1. Embodiment 17R. A compound of Formula 1R or Embodiments 1R to 16R wherein R4G is ethyl or isopropyl. Embodiment 18R. A compound of Formula 1R or Embodiments 1R to 16R wherein R41 is ethyl or isopropyl. 10 15 Embodiment 19R. A compound of Formula 1R or Embodiments 1R to 16R, wherein R4() is taken together with R41 as -(CH2)5-, -CH2CH=CHCH2_ or -(CH2)20(CH2)2-. Embodiment 20R. The compound of Embodiment 19R, wherein R4G together with R41 is -(CH2)5- or -(&lt;:Η2)20((:Η2)2-. Example 21R. The compound of Example 20R, wherein R4G together with R41 is -(CH2)20(CH2)2-. Embodiments of the invention as described in the Summary of the Invention also include (wherein Formula 1S as used in the following examples includes, oxides and Its salt): Example 1S. A compound of formula 1S, wherein R1 is

Each Q1 and Q2 is 〇; 95 201240602 Q3 is C2_alkylene; R32 is hydrazine or methyl; W5 is C2-C3 alkyl; R2 is phenyl, 2-mercaptophenyl, 3-mercaptobenzene Base, 3-bromophenyl, 5-trioxophenyl, 4-phenylphenyl, 3-fluorophenyl, 3,5-difluorophenyl, 3-°-septyl, 2-β-septenyl or The 3-σ ratio bite group, each of R14, R15, R18 and R19 is Η; and R23 is a fluorenyl group or an ethyl group. Embodiment 1 SA. A compound of Formula 1S or Embodiment 1S, wherein ίο R1 is not -N(R4°) (R41). Embodiment 1SB. A compound of Formula 1S or Embodiment 1S wherein R2 is phenyl; or -G; or C3-C8 cycloalkyl. Embodiment 1SC. The compound of Embodiment 1SB wherein R2 is phenyl, 2-σ-saltyl 5-a-2-α ratio dimethyl or cyclopropyl. Is the compound of Example 1 SB, wherein R2 is phenyl, 3-. Queenyl or cyclopropyl. Embodiment 2S. The compound of Embodiment 1S wherein R2 is phenyl, 2-methylphenyl, 3-mercaptophenyl, 4-phenylphenyl, 3-fluorophenyl or 3,5-difluorophenyl . 2A. The compound of Embodiment 1S wherein R2 is phenyl, -3-cyano or cyclopropyl. Embodiment 3S. The compound of Embodiment 1S wherein R2 is phenyl, tribromophenyl, 3-phenylphenyl or 2-methylphenyl. Embodiment 4S. The compound of Embodiment 1S wherein R2 is 3-thiophene 25, 2-. The thiophene or 3-° ratio bite base. Embodiment 5S. The compound of Embodiment 1S wherein R2 is phenyl. 96 201240602 Example 6S. A compound of formula IS wherein R1 is -WtpEbR24; E1 is NOR28; R28 is hydrazine or methyl; and 5R2 is phenyl, 2-mercaptophenyl, 3-mercaptophenyl, 3 - bromophenyl, 3-chlorophenyl, 4-chlorophenyl, 3-fluorophenyl, 3,5-difluorophenyl, 3-thienyl, 2-thienyl or 3-pyridyl. Embodiment 7S. The compound of Embodiment 6S wherein R 2 is phenyl, 2-nonylphenyl, 3-methylphenyl, 4-phenylphenyl, 3-fluorophenyl ε or 3,5-difluorobenzene base. Embodiment 8S. The compound of Embodiment 6S wherein R2 is phenyl, 3-bromophenyl, 3-chlorophenyl or 2-methylphenyl. Embodiment 9S. The compound of Embodiment 6S wherein R2 is 3-thienyl, 2-π-thenyl or 3-alpha ratio. Is a compound of Embodiment 6S wherein R2 is 2-thienyl. Embodiment 10S. The compound of Embodiment 6S wherein R2 is phenyl. Embodiment 11S. A compound of Formula 1S wherein R1 is -GA; 20 each GA is a 5- to 6-membered carbocyclic ring comprising a ring selected from C(=0) or C(=N-OR3()) Or a 9- to 10-membered saturated spirocyclic ring system optionally comprising a ring member selected from C(=0) or C(=N-OR3()), each ring or ring system selective The ground is substituted with at most two substituents selected from R21 on a carbocyclic ring and 25 R22 on a nitrogen ring member; or R3() is a hydrazine or a methyl group; 97 201240602 R21 is a halogen or a CrC3 alkyl group; R22 is a Ci -Q alkyl. Embodiment 12S. The compound of Embodiment 11S wherein the GA is selected from the group consisting of GA-1, GA_2, GA-3, GA-7, GA-8, and GA-9; and R2 is phenyl, 2-methylphenyl, 3-decylphenyl, 3-bromophenyl, 3-phenylphenyl, 4-phenylphenyl, 3-fluorophenyl, 3,5-difluorophenyl, 3-°-septyl, 2-° The thiophene or 3-° ratio bite base. 10 Embodiment 12. The compound of Embodiment 12S wherein the GA is selected from the group consisting of GA-2; and R2 is phenyl or 2-thienyl. Embodiment 13S. The compound of Embodiment 11S wherein R2 is phenyl, 2-methylphenyl, 3-methylphenyl, 4-chlorophenyl, 3-fluorophenyl or 3,5-difluorophenyl. The compound of Embodiment 11S wherein R2 is phenyl, 3-bromophenyl, 3-chlorophenyl or 2-methylphenyl. Embodiment 15S. The compound of Embodiment 11S wherein R2 is 3-nonyl, 2-. The thiophene or 3-° ratio bite base. Embodiment 16S. A compound of Formula 1S wherein each GA is 20

The key extending to the left represents the point of attachment to the remainder of the compound of formula 1S. 25 Embodiment 17S. The compound of Embodiment 16S wherein each GA is 98 201240602

The bond extending to the left represents the point of attachment to the remainder of the compound of Formula 1. Embodiment 17 SA. A compound of Formula 1S or Embodiments 1S to 16S wherein R4() is ethyl or isopropyl. Embodiment 18S. A compound of Formula 1S or Embodiments 1S to 16S wherein R41 is ethyl or isopropyl. Ίο Embodiment 19S. A compound of Formula 1S or Embodiments 1S to 16S, wherein R4G and R41 together are -(CH2)5-, -CH2CH=CHCH2- or -(CH2)20(CH2)2-. Embodiment 20S. The compound of Embodiment 19S wherein R4G together with R41 is -(ch2)5- or -(ch2)2o(ch2)2-. The compound of Embodiment 20S wherein R4G together with R41 is taken as -(CH2)20(CH2)2-. The invention is also directed to compounds of formula 1P (including all stereoisomers), their oxides and salts, agricultural compositions containing them, and their use as herbicides:

1P where 99 201240602 A is a free radical selected from the group consisting of

as well as

B1 and B3 are each independently a free radical selected from the group consisting of

R

15

C-l C-2 B2 is a radical selected from the group consisting of 15

C-3 C-4 C-5 C-6 C-7 R1 is

Or 201240602 R1 is -w; C(, 〆, -w1lc(=e2)r25 _W such as lr26, _w1s(qxnr28c 7 ^^(0)^^0(=0)^27 wls(0)xNR28so post 7 or _wiCN; or R1 is _GA or -W2GA; each GA is a 4- to 7-member carbon ring, which includes a group selected from c(=〇), C(-S)^'C(-NR). C( =N-OR30)^ C=NN(R29)2 10 ring member, or 6- to i2_ member saturated or partially saturated carbon thread or heterospinal ring system, optionally comprising a group selected from C (-〇) ) 'C(-S) ' C(=nr29) &gt; C(=N-OR30) ^ C=NN(R29)2 ring members' rings or ring systems selectively up to five selected from carbon rings R2i on the member is substituted with a substituent of R22 on the nitrogen ring member; 15 each E, E2 and E3 is independently 〇, s, NR28, NOR28, NN(R28)2, N-CN or NN〇2; Independently 〇, NR31 or S; the restriction is that when E3 is 〇, then l is not 〇; 20 each R24, R25, R26 and R27 are independently hydrogen; or CrC6 alkyl, C2_C6 alkenyl, C2-C6 alkynyl Or a C3-C6 cycloalkyl group, each optionally substituted by one or more substituents selected from the group consisting of halogen, CN, N〇2, thiol, CrC4 methoxy, C1-C4 Base, C1-C4 Institute 醮 、, C1-C4 amine group, c2_c8 a group consisting of an alkylamino group, a c3-c6 cycloalkylamino group and a (C!-c4 alkyl)c3-c6 cycloalkylamino group; each R28 is independently a hydrazine, a CrC6 alkyl group or a CrC6 haloalkyl group; R29 is independently hydrazine, CrC6 alkyl, CrC6 haloalkyl, CrQ alkylcarbonyl, CrC6 alkanesulfonyl or ci-c6 alkane sulfonyl; each Q1 and Q2 is independently 0, S or -NR31; Q3 is CrC4 An alkyl group optionally substituted with up to 4 substituents selected from the group consisting of Ci-C6 alkyl, C2-C6, c2-c6 alkynyl and c3-c6 cycloalkyl; R30 is independently Η, C]-C6 alkyl or Ci-C6 _ alkyl; R31 is independently Η, C]-C6 alkyl or CrC6 _alkyl; R32 is hydrazine or CrQ alkyl; each X is 〇, 1 Or 2; W5 is C--C6-extension base; W1 is C"C6 alkyl, c2-C6-alkenyl or c2-c6-alkenyl; or -(CH2)2〇CH2- or -(CH2) 3〇CH2-; W2 is crc6 alkyl; R2 is phenyl or -W3(phenyl), each optionally substituted with up to five substituents on the ring member, the substituent being selected from R21; G or -W4G; or hydrazine, cyano, hydroxy, amine, nitro, CHO, -C(=〇)〇H, _C(=0)NH2, _C(=S)NH2, -C(=0) NHCN, -C(=0)NH0H, -SH, -S02NH2 -S02NHCN, _S02NH0H, -SF5, -NHCHO, -NHNH2, -NHOH, -NHCN, -NHC(=0)NH2, CrC6, C2-C6 alkenyl, C2-C6 alkynyl, crC6 halogen, c2 -c6 from alkenyl, CrC6-block, C3_C8 ring, c3-c8 13⁄4 cycloalkyl, c4_Cl oxime, c4_Ci decane, CVc! 4 cycloalkane, c4-c10 Cycloalkylalkyl, CVC]2alkylcycloalkanyl, C3_C8 cycloalkenyl, C3_C8 halocycloalkyl, C2-Cg alkoxyalkyl, C3-C10 oxynitride, c4-c1G cycloalkoxyalkyl , C3-C1G alkoxyalkoxyalkyl, sulfur-burning base. 2-. 8 烧 烧 烧 烧 烧 , , , , , , , , , , , , , , , , , , -C8 calcined, C2-C8 halo, c4-Ci anthracenyl, c2-c8 alkoxycarbonyl, c4-c 1G cycloalkoxycarbonyl, c5-c 12 cycloalkaneoxycarbonyl, C2-c8 alkylamine carbonyl, C3_C1G dialkylamine group, C4-C1G cycloalkamine group, C2-C5 cyanocarbyl group, Cl-C6 group, C4-C10 ring group, C2-C8 halide Oxygen-burning base, C2~C8 oxy-halogen group, C2-C8 13⁄4 oxy-halogen group, c4-cK, ii cycloalkoxyalkyl, c4-c1G cycloalkenyloxy, C4-C10 halogen ring Oxygen group, C3-C10 di-oxygen group, C3-C1G alkoxypyrazine, C3-C1G alkoxy group, C2-C8 haloalkoxycarbonyl group, crc6 alkoxy group, crc6 haloalkoxy group, C3-c8 cycloalkoxy, C3-C8 halocycloalkoxy, (: 4_(:10 cycloalkylalkoxy, c2-c6 alkenyloxy, c2-c6 haloalkenyloxy, c2-c6 alkynyloxy) , c3-c6 haloalkoxy, c2-c8 alkoxyalkoxy, c2-c8 alkylcarbonyloxy, c2_c8-alkylcarbonyloxy, c4-c10 cycloalkaneoxy, c3-c1G alkylcarbonyl alkoxy , crc6 alkylthio, crc6 haloalkylthio, c3-c8 naphthenic Base, crc6 alkane, brewing base, Ci-C6 halogenated arsenic, Ci-C6 calcined base, Ci-C6 halogen calcined base, C3-C8 ring dazzle &gt; exact brewing base, C3_Cs trioxane Mercapto, c3-c8 cycloalkenyloxy, c3-c8 halocycloalkenyloxy, c2-c8 haloalkoxy alkoxy, c2-c8 alkoxyhaloxy, c2-c8 halohalo alkoxy , c3-c10 alkoxycarbonyl alkoxy, C2-Cg alkyl (thiol)oxy, C2-Cg thiol, C2-C8 alkyl (thio)thio, C3-C8 ring Sulfhydryl group, CVC6 alkylamine sulfonyl group, C2-C8 dialkylamine sulfonyl group, c3_c10 halotrialkyl fluorenyl group, crc6 alkylamino group, c2-c8 amphoteric amine group, C1-C6 halogen compound amine group, C2_Cg letter II compound amine group, c3-c8 cycloalkylamino group, c2-c8 alkylcarbonylamino group, c2-c8 haloalkylcarbonylamino group, crc6 alkanesulfonylamino group, crc6 alkanesulfonylamino group or c4-c1G a cycloalkyl (alkyl) amine group; or

R2 is -W6C(=E4)R33, -W6L1C(=E5)R34, -\ν6(:(=Ε6)1^35, -w6s(o)xnr37c(=o)r36 or -W6S(0)xNR37C( =0) L1R36 ; Each E4, E5 and E6 are independently o, s, nr37, nor37, nn(r37)2, N-CN or N-N02; each L1 is independently 0, NR38 or s; each R33, R34, R35 and R36 are independently hydrogen; or CrC6 alkyl, Q-C6 alkenyl, CrC6 alkynyl or C3-C6 cycloalkyl, each optionally substituted by one or more substituents selected from halogen, CN, N02, hydroxy, CrC4 alkoxy, C1-C4 Institute Yasaki, C1-C4 Institute, C1-C4 amine, C2-C8 dialkylamine, C3-C6 cycloalkylamine a group consisting of (CrC4 alkyl) Cs-C: 6 cycloalkylamine groups; 201240602 each R37 is independently hydrazine, CrC6 alkyl or C--C6 haloalkyl; each Q4 and Q5 are independently 〇, s or NR38; Q6 is a Crc4 alkylene group which is optionally substituted with up to 4 substituents selected from the group consisting of Ci-C6 alkyl, C2-C6, C2-C6, and C3-C6 cycloalkyl; R38 independent Is H, CrC6 alkyl or Crc6 haloalkyl; R39 is hydrazine or CrC6 alkyl; each X is 0, 1 or 2; W7 is crc6 alkyl; 10 W is crC6 alkyl, C2-C6 stretching Or C2-C6 stretch Or: (ch2)2〇ch2- or ·(CH2)3〇CH2-; w3 is a CrC6 alkylene group, a c2-c6 extended alkenyl group or a c2_c6 alkynyl group; W4 is a crC6 alkylene group; 15 R3 is Η, halogen, cyano, hydroxy, _〇_M+, amine, nitro, -CHO, -C(=0)0H, -C(=〇)NH2, -C(=S)NH2, -SH ' -S02NH2 ' -SO2NHCN ' -SO2NHOH ' 20 •OCN, _SCN, -SF5, _NHNH2, -NHOH, -N=C=0, -N=C=S, CrC6 alkoxy, CrC6 haloalkoxy, CVC8 ring Alkoxy, C3_C8 cycloalkoxy, G-Cio cycloalkyloxy, C2-C6 alkenoxy, C2-C6 halooxy, c2-c6 oxy, c3-c6 haloalkoxy, c2 -c8 oxy-alkoxy, C2-C8 hexaoxy, C2-C8 aryloxy, C4-C1G cycloalkaneoxy, C3-C]G alkylcarbonyloxy, CrC6 alkyl sulphide Base, CrC6 haloalkylthio, c3-C8 cycloalkylthio, Ci-C6 Hyun sub (four) brewing base, Ci_Cg halogen calcination, CrC6 alkanesulfonyl, crc6 halosulfonyl, c3-c8 Ring 105 25 burnt broth, C!-C6 Institute indeed oxy, C!-C6 amine group, 匸2_匚8 bisamine group, Ci_C6 halogen compound amine, C2-C8 halogen diamine , C3-C8 ring-burning amine group, C2-C8 burnt amine group, C2_Cg haloalkylcarbonyl group, CrQ alkane Amino or crc6 halosulfonylamino; or benzyloxy, phenoxy, benzylcarbonyloxy, phenylcarbonyloxy, phenyl acid oxy, decyloxy, phenylthio, thiol, a phenyl sulfonium group, a hydrazine group, a benzoindolyl group or a benzylsulfonyl group, each optionally substituted with up to five substituents selected from R21 on the ring member; M+ is an alkali metal cation or a Ammonium cation; R4, R5, R6 and R7 are each independently fluorene, halogen, hydroxy, CrC6, 〇2·〇6, C2-C6, C1-C6 halogen, CrC6 alkoxy, CrC6 a haloalkoxy group, a CrC8 cycloalkoxy group or a C3-C8 halocycloalkoxy group; or a phenyl or benzyl group, each optionally substituted with up to five substituents selected from R21 on the ring member; R8 is hydrazine , Q-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, Q-C6 functional group, C2_C6-thyl, C2-C6 halo, C3-C8 cycloalkyl or c3-c8 halo ring An alkyl group; or a benzyl group, which is optionally substituted with up to five substituents selected from R21 on the ring member; R9 is fluorene, QG alkyl, C2-C6 alkenyl, C2-C6 alkynyl, Q-C6 Halogen-based, 〇2·〇6-haloenyl, C2-C6 halo-based, C3-C8 cycloalkyl, c3-c 8-halocycloalkyl, c4_c10 alkylcycloalkyl, c4-c1()cycloalkyl, c6-c14 cycloalkylcycloalkyl, c4-c10 halocycloalkyl, c5-c12 alkanealkyl, c3 a -c8 cycloalkenyl group, a c3-c8 halocycloalkenyl group, a c2-c8 alkoxyalkyl group, a c4-C1() cycloalkyloxyalkyl group, a CVCh) an alkoxy oxyalkyl group or a C2-C8 sulphur alkyl group; R1G is hydrazine, halogen, cyano, hydroxy, amine, nitro, SH, so2nh2, -so2nhcn, -so2nhoh, -OCN, -SCN, -SF5, -NHCHO, -NHNH2, -N3, -ΝΗΟΗ, -NHCN , _NHC (=0) NH2, -N=C=〇, _N=C=S, crc6 alkyl, c2-c6 alkenyl, C2-C6 alkynyl, crc6 haloalkyl, C2-C6-alkenyl, C2 -C6 13⁄4 alkynyl, C3-C8 cycloalkyl, CrC8 halocycloalkyl, c4-c10 alk cycloalkyl, C4-C1() cycloalkyl, cvcH cycloalkane, c4_ClG _ environmental alkyl, Cg-Cn alk cycloalkylalkyl, C3-C8 cycloalkenyl, c3-c8 halocycloalkenyl, C^C:8 alkoxyalkyl, c4-C10 cycloalkoxyalkyl, C3-C1G alkoxyalkoxy Hyun or c2-c8 sulphide; R11 is hydrazine, i, cyano, hydroxy, amine, Cl-c6 alkyl, c2-c6 alkenyl, C2-C6 alkynyl, crc6 dentate, c2 -c6 tooth alkenyl, C2-C6 self-fasting group, C3-C8 cycloalkyl, c3-c8 Halocycloalkyl 'C4-C10 alkylcycloalkyl, c4-c10 cycloalkylalkyl, C4-C10 halocycloalkyl, C5-Ci2 alkoxyalkyl, c3-C8 cycloaliphatic, CVC8 ii ring Base, c2-C8 calcined oxygen base, C^Cio ring oxygenated hospital base, C3_C1() oxygenated oxygenate, C2_Q alkylsulfanyl, CrC8 alkylsulfinyl or c2-C8 Or a phenyl group which is optionally substituted with up to five substituents selected from R21; 12 R is hydrazine, halogen, cyano, hydroxy, amine, Cl_c6 alkyl, c2-c6 alkenyl, (: 2 -(:6 alkynyl, CVC6 haloalkyl, C2-C6 haloalkenyl, C2-C6 haloalkynyl, c3-C8 cycloalkyl, c3-c8 halocycloalkyl, CVC10 alkanecycloalkyl, C4-C10 a cycloalkylalkyl group, a C6-C14 ring-ring ring, a c4_ClG ring-ring, a c5_Ci2 alk cycloalkanyl group, a C3_C8 cycloalkenyl group, a c3-c8 halocycloalkenyl group or a C2-C8 alkoxycarbonylamino group; R13 is fluorene, halogen, cyano, hydroxy, amine, nitro or c2_c8 alkoxycarbonyl; η is 0, 1 or 2; each R14, R15, R18 and Ri9 are independently hydrazine, halogen, cyano, hydroxy or Ci_C6 Or a pair of R14 and R18 together as a C2-C6 alkylene group or a C2-C6 alkylene group; 20 R is H, a CrC6 haloalkyl group, &lt; 2_(: 6 haloalkenyl, CrC6 alkoxy, crc6 to alkoxy, C3_C8 cycloalkoxy, CrC6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl or 〇3-(:8 cycloalkyl T is Ci-C: 6 alkyl or c2_cd-alkenyl; each G is independently a 5- or 6-membered heterocyclic ring or an 8-, 9- or 10-membered fused bicyclic ring system, each ring or The ring system is selectively substituted with up to five substituents selected from the group consisting of r2 on the carbocyclic ring member and R22 on the nitrogen ring member; each &amp; independently is _ s, cyano, thiol, amine, nitro Base, -CHO, -C(=0)0H ^ -C(=0)NH2 ^ -C(=S)NH2 ^ -C(=0)NHCN, -C(=0)NH0H, -SH, -S02NH2 , _S02NHCN, -S02NH0H, -OCN, -SCN, _SF5, C1-C6 alkyl, c2-C6 alkenyl, C2-C6 alkynyl, crC6 halogen compound, (VQ i dilute, CVC6 alkynyl, c3- C8 ring 201240602 Hyun • base, C3-C8 halocycloalkyl, C4-C10 ring cycloalkyl, C4_Cl〇 cycloalkyl, c3-c8 cycloalkenyl, c3-c8 halocycloalkenyl, c2-c8 oxygenated Alkyl, C4-C1G ring oxyalkyl, C3-C1G oxyalkyloxy, c2-c8 alkylsulfanyl, c2-c8 alkylsulfinyl 5, crc8 alkoxy ii alkyl, c2- C5 cyanoalkyl, crc6 hydroxyalkyl, crc6 alkoxy, crc6 i Oxy, c3-c8 cycloalkoxy, c3_c8 halocycloalkoxy, c4-c10 cycloalkanoxy, C2-C6 diloxy, C2-C6 halooxy, C2-C8 alkoxyalkoxy , c2-c8 alkylcarbonyloxy, crc6 alkylthio, 10 Crc6 haloalkylthio, C3-C8 cycloalkylthio, CVC6 alkylsulfinyl, CrC6 sulfinyl, CrC6 alkanesulfonyl, Ci-C6 brothel, C3-C8 ring thiol, Ci-C6 alkylamine, c2-c8 dialkylamine, crc6 haloalkylamine, c2-c8 haloamine or C3-Cg a ring amine group; and 15 each R22 is independently a crc6 alkyl group, a c2-c6 alkenyl group, a c2-c6 alkynyl group,

CrC6-alkyl, (: 3-(:8-cycloalkyl or C2-C8 alkoxyalkyl. Examples of the compound of formula 1P include: Example PA is A-1, A-3, A-4, A- 5 or A-6; R1 is 20

R1 is -WkpEbR24, -W^C^E^R25 or V^CpE3)!^26; or R1 is GA or -w2GA; each GA is -5_ to 6. Member carbon ring, =2rNN(R29)2 Ring ^ or. To a saturated carbon spiro or heterospiro ring system, the selectivity of which includes a ring member selected from c(=0), c(=n_or30) or hired (R)2, each ring or ring system selectively After the third, three substituents selected from r2i on the carbon ring member and R on the nitrogen ring member are substituted; each E, E and E is independently 〇, N〇R28 or nn(r28)2; L is independently 〇 Or nr31; each R24, R25 and R26 are independently hydrogen; or C]_C4 or GA cycloalkyl, each optionally one or more selected from the group consisting of dentate, CN, hydroxyl, crC2 alkoxy, CrC2 alkane Substituted by a group consisting of a sulfinyl group and a CrC4 alkanesulfonyl group; each R28 is independently a fluorene, a CrC3 alkyl group or a Cl-C3 dentate alkyl group; R is independently a fluorene, a C1-C3 alkyl group, and C1- C3 halogenated group, C]-C3 yard carbonyl, CrC3 degree orthoquinone or CrQj halogen sulfonate; each Q1 and Q2 is independently 0 or N (R31); Q is C2_c; 3 extensible, its selectivity The ground is substituted with up to 2 substituents selected from the group consisting of crc4 alkyl; R3G is independently hydrazine, CrC3 alkyl or CrC3 haloalkyl; R31 is independently hydrazine, (:]-(: 3 alkyl or CrC3 haloalkyl; R32 Is Η or CrC3 alkyl; W1 is C2-C4 stretching, -(CH2)2OCH2- or -(CH2)3OCH2-; ~2 is CrC 3 alkylene 201240602 W5 is crc4 alkyl; R2 is phenyl or -W3 (phenyl), each optionally substituted with up to five substituents on the ring member, the substituent is selected from R21; or - G; or CrC6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, 5 Ci_C6 haloalkyl, C2-C6 halo, C2-C6 haloalkynyl, C3-Cgi mournyl, C3-C8 halo Cycloalkyl, C4-C10 ring cycloalkyl, C4-C1G ring furnace base, C6-C14 ring-burning ring base, C4_Ci〇 halocycloalkyl, c5-c12 alkanealkyl, c3_c8 cycloalkenyl , C3-C8 halocycloalkyl, C2-C8 alkoxyalkyl, C3-C10 10 alkoxyalkenyl, C4-C10 cycloalkoxyalkyl, C4-C10 cycloalkoxy alkoxy, c3-c1G alkane Oxyalkoxyalkyl, c2-c8 alkane sulphonyl, C2-C8 sulphide sulphate, C2_C8 炫, continuous calcination, c2-c8 alkylcarbonyl, c4-c10 cycloalkenyl, c2 -c8 haloalkyloxyalkyl, c2-c8 alkoxyhaloalkyl, c2_c8 haloalkyloxyhalo 15 alkyl, C4-C10 halocyclooxylate, C4-C10 cyclooxyalkyl, C4-C10 halo ring Dilute oxygen, C3-C10 di-Oxygen, CVC6 alkoxy, crc6 haloalkoxy, c3-c8 cycloalkoxy, c3-c8 halocycloalkoxy, c4-cl0 cycloalkaneoxy , c2-c6 Oxy, C2-C6 haloenyloxy, 02-(:6 alkynyloxy, 20 c3-c6 halooxy, c2-c8 oxooxy, c2-c8 carbonyloxy, c2-c8 Alkylcarbonyloxy, c4-c10 cycloalkaneoxy, C3-C1G alkylcarbonyloxy, CrC6 alkylthio, Q-C6 halogen thio, C3-C8 cyclosulphur, Ci-C6 Stuffed base, Ci-C6 halogen Hyun" Asian stone yellow brewing base, Ci_C6 $ continuous brewing base, Ci-C6 25 _ burned brewing base, C3-C8 ring burning brewing base, C3-C8 second courtyard broken base, c3 -c8 cycloalkenyloxy, c3_c8 halocycloalkenyloxy, c2-c8 111 haloalkoxy alkoxy, c2-c8 alkoxyhalooxy, c2-c8 haloalkoxy il alkoxy, C3-CiG alkane Oxycarbonyl alkoxy group, C2-C8 alkyl (thiocarbonyl)oxy group, QrCs cycloalkyl sulfinyl group or C3-C10 halotrialkyl fluorenyl group; or r2 is -W6C(=E4)R33, -W6L1C(= E5) R34 or -W6C(=E6)L1R35; each E4, E5 and E6 are independently ο, NOR37 or NN(R37)2; each L1 is independently 〇 or nr38; each R33, R34 and R35 are independently hydrogen; or Cl -C4 alkyl, C3_C5 cycloalkyl' each selectively via one or more groups selected from the group consisting of a hydroxyl group, a CN, a hydroxyl group, a CrC2 alkoxy group, a CrC2 alkylsulfinyl group or a CrC2 alkane group Substituent 3R37 is independently hydrazine, CrC3 alkyl or CrC3 dentate; R is independently Η, C 〖-C3 alkyl or Ci-Cs comon; W3 is -CH2-; W6 is c2-c4 alkyl , -(Ch2)2〇CH2_ or _(Ch2)3〇CH2_ ; R3 is hydroxy, -0·Μ+, c2-c8 alkylcarbonyloxy, c2_c8 halocarbonyloxy, CVCh)cycloalkaneoxy or a c3_Cig alkylcarbonyl alkoxy group; or a benzyloxy group, a phenoxy group, a benzyloxyoxy group, a phenylcarbonyloxy group, a benzenesulfonyloxy group or an sulfonyloxy group, each selectively having up to two Substituted for a substituent selected; M+ is a monosodium or potassium metal cation; R is a crc6 hospital base;

RlG is hydrazine, halogen or Clc6•alkyl; R11 is hydrazine or crc6 alkyl; 201240602 R12 is hydrazine, halogen, cyano, hydroxy, amine or Cl_c6 alkyl; each R14, R15, R18 and R19 is Η or CH3 D 1 4 μ | g κ and R together as _CH2CH2CH2^_CH=CHCH2_; R20 is Η or CH3; τ is -CH2CH2- or -CH=CH-; each G is G1 to G-20 (as in the example (described in 116); r is 0, 1, 2 or 3; each R21 is independently halogen, cyano, hydroxy, nitro, -CHO, -SH,

CrC6 alkyl, C2_C6 alkenyl, C2_C6 alkynyl, Ci_C6 haloalkyl, C2-C6-dilute, C2-C6 alkynyl, C3-C8 cycloalkyl, C; j-C8 halo, C4 -C10 烧环院基, C:rCi〇环院, (:3_(:8-cycloalkenyl, C3-C8 halocycloalkenyl, C2-C8 oxime, CVC1()cycloalkoxyalkyl , C3-C1G alkoxy alkoxy group, CrC8 alkylsulfanyl, c2-c8 alkylsulfinyl' C2_c8 alkoxy-alkyl, c2_c5 cyanoalkyl, Crc6 alkyl, crc6 alkoxy, Crc6 Alkoxy, c3-c8 cycloalkoxy, C3-C8 halocycloalkoxy, CrC10 cycloalkanoxy, C2-C6 dioxy, crC6^enyloxy, c2-c8 aerobic alkoxy , C2-C8 alkylcarbonyloxy, Crc6 alkylthio, C1-C6-sulfuryl, c3_c8 cycloalkylthio, Ci_c6 alkyl sulfite, CVC6 lialkylsulfinyl, crc6 alkanesulfonyl, CrC6 haloalkylsulfonyl or (: 3-(:8-cycloalkanesulfonyl; and each R22 is independently CrQ alkyl or crc6 ii alkyl. Example PB. Compound of Example PA' wherein A is A-1 , a-3 or A-5; 113 201240602 B1 is Cl; B2 is C-3; B3 is Cl; R2 is phenyl or -w3 (phenyl), each selectively on the ring member Up to two substituents selected from R21; or _G; or (:1_(:6) or C3-C8 cycloalkyl; R3 is hydroxy or c2-c8 alkylcarbonyloxy; R9 is ch2ch3;

RlG is Η or CH3; G is G-2, G-3 or G-15; and R21 is independently halogen, nitro, CrC6 alkyl, crc6 haloalkyl, Ci-C6 alkoxy, Ci-C6 halogen Oxyl or crc6 burns sulfur. Embodiment PC. A compound of Embodiment PB wherein A is A-1; R1 is

Each Q1 and Q2 is Ο; Q3 is c2-alkylene; R32 is η or methyl; W is C3-C4 stretching; 201240602 R2 is phenyl, 2-mercaptophenyl, 3-mercaptophenyl , 3-bromophenyl, 3-chlorophenyl, 4·oxyphenyl, 3-fluorophenyl, 3,5·difluorophenyl, 3-deseptenyl or 2-σsecenyl, R3 is hydroxy Or -〇C(=0)CH2CH(CH3)2; 5 Each R14, R15, R18 and R19 is Η or CH3. Embodiment PD. The compound of Example B, wherein A is A_1; R1 is -WtpE1)!^4; E1 is NOR28; ίο R28 is fluorenyl or fluorenyl; R2 is phenyl, 2-methylphenyl, 3- Methylphenyl, 3-bromophenyl, 3-chlorophenyl, 4-chlorophenyl, 3-fluorophenyl, 3,5-difluorophenyl, 3-thienyl, 2-thienyl or 2- Pyridyl; R3 is hydroxy or -0C(=0)CH2CH(CH3)2; and 15 each R14, R15, R18 and R19 are hydrazine. Example 化合物. The compound of Example ,, wherein Α is Α-1; R1 is -GA; each GA is a 5- to 6-membered carbocyclic ring comprising a group selected from C(=0) or 2〇C (= a ring member of N-OR3G); or a 9- to 10-membered saturated heterospiro ring system optionally comprising a ring member selected from C(=0) or C(=N_OR3G), each ring or ring system Optionally substituted with up to two substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; 25 R3G is hydrazine or methyl; R21 is halogen or CrC3 alkyl; 115 201240602 alkyl; Example PF. The compound of Example pE wherein ga is selected from the group consisting of GA-1, GA-2, GA-3, GA-7, GA_8 and GA-9. R2 is phenyl, 2-methylphenyl, 3-mercaptophenyl, 4-phenylphenyl, 3-fluorophenyl or 3,5-difluorophenyl; R3 is a trans-group; and each R14, R15 , R18 and R19 are Η. Specific examples include a compound of the formula 1 selected from the group consisting of: 3_(丨,4-dioxaspiro[4 5]fluorene_8-yl)_5_[(2 hydroxy-6 oxo 1 hexyl-l- Alkyl]-2-phenyl-4(3//)-pilotone (compound 1) with 5-[(2-carbyl-6-oxylcyclohexene)carbonyl]_6_ Sideoxy_2_phenyl-1(6//)-alkidineacetaldehyde 1-(0.methylhydrazine) (Compound 2) The present invention also relates to a method for controlling the growth of unwanted plants And comprising administering to the locus of the plant a herbicidally effective amount of a compound of the invention (e.g., as described herein). It is worth noting that the examples relating to the method of use are those relating to the compounds of the above examples. As mentioned above, the present invention also encompasses a herbicidal mixture comprising (a) - a compound selected from the group consisting of Formula 1, its oxides and salts thereof, and hydrazine) at least one additional active ingredient selected from the group consisting of (bl) light System II inhibitor, (b2) acetaminolate synthase (AHAS) inhibitor, (b3) acetoin CoA carboxylase (ACCase) inhibitor, (b4) auxin mimetic, (b5) 5-enol - Acetone oxalic acid-3-phosphate (EPSP) synthetase inhibitor, (b6) Photosystem I electron diverting agent, 〇7) Proto-violet oxidase (PPO) inhibitor, (b8) 醯201240602 Amino acid synthesis Enzyme (GS) inhibitor, _ very long bond fatty acid (VLCFA) elongase inhibitor, _) auxin transport inhibitor, (bu) octanitrocoumarin desaturase (PDS) inhibitor, (b丨2 4_hydroxyphenyl-pyruvate dioxygenase (HPPD) inhibitor, (b丨3) black uric acid solanide transferase (HST) inhibition 5, (Μ4) other herbicides, including mitotic interference agents, organic Arsenic, sub-speed rotten, oatmeal, bromobutene, chlorpyrifos, cycloheptyl ether, benzalkon, melon, ticlopron, methyl chlorpyrifos, acetochlor, chlorpyrifos, Killing phospha-ammonium Mu, oxazine metribuzin, oleic acid, pelargonic acid and pyributicarb and (BL5) herbicide protecting agent; and (BL) to the salt (BL5) of the compound. 10 "Photosystem 11 inhibitor" (bl) is a chemical compound that binds to the d-1 protein at the QB binding site (QB-bindingniche), and thus is in the chloroplast thylakoid membrane (chl〇r〇piast thylakoid membrane) Blocking electrons are transmitted from qa to qb. Electrons that are blocked and unable to pass through photosystem II form a toxic compound via a series of reaction shifts that disrupt cell membranes and cause chloroplast swelling, membrane leakage, and ultimately cell destruction. The qb binding site has three different binding sites: binding site A binds three. Triazine such as atrazine, triazinone such as hexazinone and uracil such as bromacil, binding point B to phenylurea 20 Diuron), while binding point C binds benzopyrene such as bentazon, nitrile such as bromoxynil and phenyl-pyridazine such as pyridate. Examples of photosystem II inhibitors include ametryn, atrazine, cyanazine, desmetryne, dimethametryn, prometon, Prometryne, propazine, simazine, 117 201240602 simetryn, terbumeton, terbuthylazine, cast net ( Terbutryne), trietazine, hexazinone, metamitron, metribuzin, amicarbazone, bromacil, cycloheximidine (lenacil), terbacil, chloridazon, desmedipham, phenmedipham, chlorobromuron, chlorotoluron, chloroxuron, Dimefuron, diuron, continuation ίο thiomeron, fenuron, fluometuron, iSOpr〇turon, isouron ), Hnuron, methabenzthiazuron, Moglong (m Etobromuron), metoxuron, monolinuron, neburon, siduron, tebuthiuron, propanil, pentanochlor ), bromofenoxim, bromoxynil, carbonisir (bentazon), pyridate and pyridafol. "AHAS inhibitor" (b2) a chemical compound that inhibits acetamidine synthase 2 〇 (AHAS), also known as acetolactate synthase (ALS), and thus inhibits branched aliphatic amino acids such as valine, The production of leucine and isoleucine kills plants. The aforementioned amino acids are required for DNA synthesis and cell growth. Examples of AHAS inhibitors include amidosulfuron and scorpion sacred 25 s Azimsulfuron), bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, sagitar 201240602 (cinosulfuron), cyclosulfamuron, ethametsulfuron -methyl), ethoxysulfuron, voltose (flazasulfuron), flupyrsulfuron-methyl (including sodium salt), foramsulfuron, halosulfuron-methyl, imazosulfuron, methyl magnetic continuation Iodosulfuron-methyl (including sodium salt), mesosulfuron-methyl, diether gas alpha than metazosulfuron, metsulfuron-methyl, and smoke Nicosulfuron), oxasulfuron, fluorine, primisulfuron-methyl, propyrisulfuron, prosulfuron, pyrazosulfuron-ethyl, jade Mimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl ), trifloxysulfuron (including sodium salt), triflusulfuron-methyl, tritosulfuron, imazapic, imazethide Imazamethabenz-methyl), 曱 oxygen 11 m grass smoke (imazamox), 灭Grass (imazapyr), imazaquin, imazethapyr, cloransulam-methyl, diclosulam, florasulam , ° sitting * &gt; flumetsulam, metosulam, penoxsulam, bispyribac-sodium, pyribenzoxim, vinegar Pyrifalid, pyrithiobac-sodium, pyriminobac-methyl, thiencarbazone, flucarbazone-sodium and propylbenzene (propoxycarbazone-sodium) ° "ACCase inhibitor" (b3) is a chemical compound that inhibits acetamidine c〇A carboxylase, which is responsible for the early steps in catalyzing the synthesis of a lipid and a fatty acid in plants. Lipids are essential components of cell rafts and cannot produce new cells without lipids. Inhibition of acetamidine CoA catalyzed enzymes and the lack of lipid production by them can result in loss of integrity of the cell membrane, particularly in active growth areas such as meristematic tissues. Eventually, the buds (sh〇〇t) and rhizome stopped growing, and the bud meristems and rhizome buds began to wither. Examples of ACCase inhibitors include ci〇dinafop, cyhalofop, did〇f〇p, fenoxaprop, fluazifop, aerated fluorine ( Hal〇xyf〇p), propaquizafop, quizal〇f〇p, alloxydim, butyl ketone (butr〇xydim), clethodix, Cydoxydim, pinoxaden, benzoquinone _ (pr〇f〇Xydim), sethoxydim, teprai〇xydim and tralkoxydim , including analytical forms such as fennelicide _p, voltazone _p, chlorofluoro-P and valprox-P, and ester forms such as propargyl acetyl oxalic acid, butyl 20 keisin, sulfhydryl Cao Ling and Ethyl Fenicide·ρ. &gt; Auxin is a plant hormone that regulates the growth of many plant tissues. The auxin mimetic (b4) is a chemical compound that mimics the auxin auxin, resulting in unregulated and chaotic growth, leading to the death of susceptible plant species. Examples of auxin mimetics include, but are not limited to, aminocyclopyrachlor, aminopyralid, benzazin Hn_ethyi, chlorampen 201240602 (chloramben), Kappa (ci〇mepr〇p), ci〇pyraiid, dicamba, 2,4-D, 2,4-DB, dichlorprop, fluroxypyr, A Chlorpropionic acid (mec〇pr〇p), mcpa, MCPB, 2,3,6-TBA, picloram, triclopyr, quinci〇rac and oxyquinoline (quinmerac). 10 20 "EPSP (5-enol-acetone oxalic acid_3_phosphate) synthase inhibitor" (b5) is a chemical compound that inhibits 5-enol-acetone shikimic acid_3_phosphate synthase It relates to the synthesis of aromatic amino acids such as tyrosine, tryptophan and phenylalanine. Epsp inhibitor herbicides are rapidly absorbed through the leaves of the plant and translocated at the bast to the point of growth. Glyphosate is a non-selective (n〇nsdective) post-emergence herbicide. Carbophosphonates include esters and salts such as ammonium salts, isopropylammonium salts, potassium salts, sodium salts (including sesquisodium) and trisylsulfate (tdmesium) (also known as sulforaphane). Sate)). solitary

Photosystem I Electron Diverting Agent (b6) is a chemical compound that accepts electrons from photosystem I and produces hydroxyl radicals after several cycles. These free radicals are highly reactive and rapidly destroy unsaturated lipids, including membrane fatty acids and chlorophyll. This will destroy the integrity of the cell membrane, thus causing leakage of cells and organelles, leading to rapid wilting and drying of the leaves, and eventually 40% of the plants die. Examples of this second type photosynthetic inhibitor include paraquat and diquat. The PPO inhibitor (b7) is a chemical compound which inhibits the proto-puron oxidase, which rapidly causes high reactivity in plants and destroys the formation of a combination of cell membranes, resulting in loss of cell fluid. Examples of PPO inhibitors include acifluorfen-sodium, bifem x, 121 25 201240602 chlomethoxyfen, fluoroglycofen_ethyl, flucarbazone Fomesafen, halosafen, lactofen, oxyfluorfen, isopropyl fluazolate, 0 oxalic acid 10 15 20 (pyraflufen-ethyl ), cinidon-ethyl, flumioxazin, flumiclorac-pentyl, fluthiacet-methyl, thidiazimin, Le Oxadizon, oxadiargyl, saflufencil, azafenidin, carfentrazone, oxazolone (carfentrazone_ethy丨), acesulfame ( Sulfentrazone), pent〇xazone, benzfendizone, butafenacil, pyraclonil, flurazepam 1) with flufenpyr-ethyl. "GS (facetamine * synthetase) inhibitor" (10)) is a chemical compound that inhibits the activity of the face glutamate synthase, and is converted to glutamic acid by a simple method. Therefore, ammonia will accumulate and the level of glutamic acid will decrease. —* (phosphinothricin) derivatives, bianaphos ° Ammonia toxicity and the lack of amino acids required for other metabolic processes should cause damage to plants. ..., the agent includes;; phosphine (gl-i her) and its vinegar and salt such as glufosinate ammonium salt and: fnhrKnliirmthriniri, 么; 丄·ι# to. 素单 and Bila grass VLCFA (very long chain fatty acid) elongase A herbicide having a wide variety of chemical structures is inhibited as an enzyme in the sputum having an enzyme located in or near the chloroplast. Prolong the enzyme - biosynthesis. In plants, 'very long bond diacids are = 122 25 201240602 main component of the polymer' which prevents the surface of the leaves from drying out and provides stability to the pollen grains. Such herbicides include acetochk r), alachlor, butachlor, dimethachlor, dimethanamid, and methamphetamine 5 (metazachl〇). r), metolachlor, pethoxamid, pretilachlor, propachlor, prasepisochi〇r, pyrocene Pyroxasulfone), thenylchlor, diphenamid, napr〇painide, naproanilide, fenoxasuif〇ne. Flufenacet, indanofan, mefenacet, fentrazamide, anilofos, cafenstrole, and piper Ph〇s) includes analytical forms such as s_ modal and chl〇r〇acetamide and oxyacetamide ° auxin inhibitor (b 10) for growth inhibition A chemical substance that is transmitted in a plant, such as by binding to an auxin carrier protein. Examples of auxin transport inhibitors include, but are not limited to, naptalam (also known as hydrazine (1 • naphthyl) o-amine benzoic acid and 20 2 —[(1-naphthylamino)carbonyl]benzene Formic acid) and difluoro "diflufenzopyr ° ° "PDS (octahydrolyser desaturase inhibitor)" (bl 1) is a carotenoid biosynthesis pathway for the inhibition of octahydroparaffin desaturase Chemical compound. Examples of PDS inhibitors include norflurzon 25, diflufenican, picolmafen, beflubutamide, flucarbazone 123 201240602 (fluridone), fluoride Flurochloridone and flurtamone ° "HPPD (4-hydroxyphenyl-pyruvate-dioxygenase) inhibitor" (b 12) to inhibit 4-hydroxy-phenyl-pyruvate - Chemical synthesis of biosynthesis 5 of dioxygenase synthesis. Examples of HPPD inhibitors include, but are not limited to, mesotrione, sulcotrione, benzene, topramezone, tefuryltrione, tembotrione, Isoxachlortole, isoxaflutole, benzofenap.硫 酉 酉 ί ί py py py py py py ο ο ο ο ο ο ο ο Inhibitors (bl3) interfere with plants to convert black uric acid to 2-methyl-6-solanyl-l,4-benzoquinone The ability to dry up for carotenoid biosynthesis. Examples of HST inhibitors include haloxydine, pyridol and compounds of formulas a, B and c.

HST inhibitors also include compounds of formula D and E 201240602

Where Rdl is Η, Cl or CF3; Rd2 is Η, Cl or Br; Rd3 is Η or Cl; Rd4 is Η, Cl or CF3; Rd5 is CH3, CH2CH3 or CH2CHF2; and Rd6 is OH or -OC(=〇) · Pr; and Η, F, α, CH3 or CH2CH3; Re2 is H or CF3; Re3 is Η, CH3 or CH2CH3; Re4 is Η, F or Br; Re5 is c, CH3, CF3, OCF3 or CH2CH3; Re6 is Η, CH3, CH2CHF2 or OCH; Re7 is OH, -0C(=0)Et, -〇C(=〇H-Pr or -0C(=0) small Bu; and Ae8 is N or CH. Other weeding Agent (bl4) includes herbicides acting through various modes of action, such as mitotic disruptors (eg, flamprop-M-methyl and flampiOp-M-isopropyi), organically Arsenic agents (eg DSMA and MSMA), 7,8-dihydropteroate SynthaSe inhibitors, chloroplast isoprenoid synthesis inhibitors and cell wall biosynthesis inhibitors. Other weeding Agents include herbicides with unknown mode of action or specific classifications not listed in (bl) to (M2) or via the above listed mode of action Combining herbicides. Examples of other herbicides include alexifen, sub-altered 125 201240602 (asulam), amitrol (atomole), domezone, fluometuron, Difenzoquat, bromobutide, flurenol, cinmethylin, cumyluron, dazome, dymron, methyl Methyldymr〇n, methiozolon, ipfencarbazone, etobenzanid, f0samine, fosamine- Ammonium), metam, oxaziclomefone, oleic acid, citric acid and pyributicarb. "herbicide protectant" (bl5) is added to the herbicide preparation to eliminate or A substance that mitigates the phytotoxic effects of the herbicide on certain crops. These compounds protect crops from herbicides, but typically do not prevent the herbicide from controlling unwanted plants. Examples of herbicide protectants include, but are not limited to, allidochlor, benoxacor, 1-bromo-4-[(methylmethyl)sulfonyl]benzene, cloquintocet-mexyl, Cuyluron, cyometrinil, cyprosuifamide, daimuron, dichlorniid, dicyclonon, 4-(di) Gas oxime)·ι_oxater·4_azospiro[4 5]decane (ΜΟΝ 4660), 2-(di-mercapto)_2methyl-1,3-dioxolane ( MG 191), dimepiperate, fenchlorazole-ethyl, fenci〇rim, flurazole, fluxofenim, and grass vomiting Furilazole), isoxadifen-ethyl, mefenpyr-diethyl, mefrica, meth〇xyphenone, naphthalene dicarboxylic acid needle and oxabetrinil . 126 201240602 One or more of the methods and variations described below in Schemes 1 through 18 can be used to prepare a compound of Formula 1. A, B1, B2, B3, R1, R2, R3, 1^4, 115, 1^, 117, 118, ]19, 1^, 1112 and 1113 are defined in the following formulas 1 to 34 as in the above summary. Defined in the text unless otherwise stated. The compound of formula la-1h is a subset of the compound of formula 1, and all substituents of formula la-lh are as defined above for formula j. Compounds of formula la, lb or lc (wherein R3 is hydroxy) may be prepared via the two-step process shown in Schemes 1a, 115, respectively. Intermediates, 4b or 4c may be obtained by reacting diketone 2 with intermediate 3 (wherein Gl is prepared by nucleophilic reaction detachment, for example, Gi is a dentate, an alkoxycarbonyl group, a halooxyhalo-oxyoxy group, a β-bite group or an imidazoyl group. The intermediate 4a, 4b or 4c is reacted with a suitable cyano group (e.g., acetone cyanohydrin, potassium cyanide, sodium cyanide) in the presence of a base such as triethylamine or pyridine to form a compound of formula la, lb or lc. Alternatively, a source of a fluoride anion such as potassium fluoride or cesium fluoride (optionally in the presence of a phase transfer catalyst such as tetrabutylammonium bromide, etc.) can be used for this conversion. A solvent such as dimethyl sulfoxide, #,# • dimethylformamide, acetonitrile or di-methane (at ambient temperature to the reflux temperature of the solvent) to form a compound of formula la, lb or ic. (Formula la is a formula 1 wherein a is a_i; A is a formula of A.2; where lc is a formula in which A is A-3; or 'formula la, lb or lc can be obtained by method 2 (in each case) La, 11) and lc) are prepared by reacting a diketone 2a, 2b or an intermediate 3 with a gas-based compound or a monofluoride anion source and a base. Additional to this general coupling method Reaction conditions 'See Edmunds, A· in (10) CVc?; 尸 _ on 127 201240602

Compounds; Kramer, W. and Schirmer, U.5 Eds.; Wiley, Weinheim, 2007; Chapter 4.3 and references cited therein. Scheme la

Scheme lb π η

3, cyano compound or fluoride anion source and base ίο scheme lc rv r\

3. A source of a nitrogen-based compound or a fluoride anion and a compound of the formula la, lb or lc may also be prepared as shown in Scheme 2 by using a diketone 2a, 2b or 2c with an intermediate 3a in a base or a route. 128 201240602 Reaction in the presence of Lewis acid. For the reaction conditions for this general coupling method, see Edmunds, A. in

Compounds; Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.3 and references cited therein. Scenario 2

As shown in Scheme 3, the intermediate 4a, 4b or 4c can be produced by the following method, even if the diketone 2a, 2b or 2c and the acid 6 are in a dehydrating condensing agent such as 2-gas·1·carbon. It is reacted in the presence of a bite (also known as Mukaiyama coupling agent), dicyclohexylcarbodiimide (DCC) or the like and optionally in the presence of a base. For additional reaction conditions for this general enol ester coupling method, see Edmunds, A. in Crop (7) (9) (10)

Compounds; Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.3 and references cited therein. Option 3

R2 dehydrating condensing agent 4a, 4b or 4c 129 20 201240602 Intermediate 4a, 4b or 4c can also be obtained by palladium-catalyzed carbonylation of a compound of formula 7 in the presence of diketone 2a, 2b or 2c (Scheme 4) . For additional reaction conditions for this general enol ester formation process, see Edmunds, A. in Crop Pro/eciiow

Compounds ; Kramer, W. and Schirmer, U., Eds. ; Wiley,

Weinheim, 2007; Chapter 4.3 and references cited therein. Option 4

A compound of formula la, lb or lc (wherein r3 is bonded via oxygen) by derivatizing a compound of formula la, lb or lc with an intermediate 8 (wherein X is a nucleophilic reaction, also referred to as a nucleofuge) )) Prepared by reaction in the presence of a base, as shown in Scheme 5. Alternatively, the compounds of formula la, lb and lc (wherein R3 is bonded via nitrogen, sulfur or carbon) can be prepared by subsequent nucleophilic addition using a suitable ilifying agent. For the reaction conditions of this general month &amp; method, see Edmunds, A. or Almisick AV in Modern Crop Protection Compounds \ Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.3 or Chapter 4_4, with references cited therein. 201240602 1) Halogenating agent la, lb or lc R3 is bonded via nitrogen, sulfur or carbon 2) nucleophile

Scheme 5 X-R3 la, lb or lc —-~► Verify that R3 is OH X is Cl, Br or I la, lb or lc R3 is via an oxygen bond as shown in Scheme 6, a compound of formula I (ie where A is Formula 1) wherein A-4 and R3 are OH can be obtained by allowing intermediate 9 and intermediate 3 in the presence of a Lewis base such as n-butyllithium or lithium diisopropylamide in a suitable solvent such as tetrahydrofuran or Prepared by reaction in diethyl ether. See JP 2003327580 for reaction conditions for such conversions. 10

Option 6

The compound of formula le (i.e., Formula 1 wherein A is A-5 and R3 is OH) can be prepared via a two-step process as shown in Scheme 7. The intermediate 12 can be deactivated by the pyrazole 11 and the intermediate 3 (wherein G1 is a nucleophilic reaction, that is, G1 is a halogen atom, an alkoxycarbonyl group, a halocarbonyloxy group, a benzamidineoxy group, a pyridine group) The base or imidazolyl group is prepared by reaction. Reaction of the intermediate product 12 with a suitable cyano compound in the presence of a base produces a compound of the formula le. Alternatively, a compound of the formula can be prepared directly by reacting the intermediate 11 with the intermediate 3 (Method 2, Scheme 7) in the presence of a cyano compound or a monofluoro 131 201240602 anion source and a base. For the reaction conditions of this general coupling method, see Almisick A. V. in Modern Crop Protection Compounds; Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.4, and references cited therein.

The compound of the formula R 2r 10 (wherein A is A-5 and the R 3 is bonded via oxygen) can be obtained by deriving a formula le and an intermediate 8 (wherein X is a nucleophilic reaction, The core is prepared by reacting in the presence of a base, as shown in Scheme 8. Alternatively, Formula If (wherein R3 is bonded via nitrogen, sulfur or carbon) can be prepared by subsequent nucleophilic displacement using a suitable halogenating agent. For the reaction conditions of this general functionalization method, see

Almisick A. V. in Modern Crop Protection Compounds \ Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.4, references cited therein. 132 201240602 Option 8

R3 is bonded via nitrogen, sulfur or carbon

The compound of the formula 17 can be produced by reacting the intermediate 3 with a monovalent solvent in the presence of a solvent. Thus, the intermediate 17 can be recombined into a compound of the formula lg (i.e., Formula 1 wherein A is A_7), which is carried out in the presence of a cyano compound and a base, as shown in Scheme 9. For the reaction conditions of this general coupling method, see Almisick A. V. in Modern Crop Protection Compounds; Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.4, and references cited therein. Option 9

The compound of the formula 19 can be obtained from the corresponding compound of the formula lg (wherein r is 3 a calcination group) in the presence of a monoacid such as hydrogenated hydrogen, sulfuric acid or acetic acid and optionally in a solvent such as tetrahydrofuran, diethyl ether or dioxane. The burn was prepared in the presence of 20 as shown in Scheme 10. The intermediate 19 is then reacted with an ortho-acidic acid 133 201240602 (orthoformate ester) or dimethylformamide (DMF-DMA) in the presence of a monoacid to obtain an intermediate 20. Reacting the intermediate 20 with hydroxylamine hydrochloride in a solvent such as ethanol, acetonitrile, water or acetic acid provides an isoxazole compound of the formula lh (i.e., 5 wherein A is A-6 and R11 is Η Equation 1). For reaction conditions for this general cyclization process, see Almisick AV in Μθί/erw Protection Compounds; Kramer, W. and Schirmer, U., Eds.; Wiley, Weinheim, 2007; Chapter 4.4, and references cited therein . Ίο Scheme 10

As described in Scheme 11, 'sulfoxide of formula 1 and sulfone (wherein R 2 is a substituent bonded via a sulfoxide or sulfone radical) can be oxidized by a straight compound (wherein R is a sulphur-free radical) Prepared by the substituent of the base bond). In a typical process, depending on the oxidation state of the desired product; &quot; an amount of 1 to 4 equivalents of the oxidizing agent is added to the solution of the compound compound dissolved in a solvent. Useful oxidizing agents include 〇x〇ne® (peroxymonosulfate potassium hydrogen hydride), hydrogen peroxide, sodium periodate, peracetic acid, and tris-benzoic acid. The choice of refining is related to the oxidant used. The aqueous ethanol solution or aqueous acetone solution is preferably used together with potassium peroxymonohydrogen monosulfate, and the second gas broth is usually preferably used in combination with 3. chloroperoxybenzoic acid. The reaction temperature of ^ 134 201240602 is usually in the range of 〇 to 9 (TC). The specific procedure used to oxidize sulfides to sulfoxides and sulfones is described in Brand et 1 jgnc· C/^w· 1984, 32, 221- 226 and references cited therein.

Option 11

Alternatively, it will be appreciated that those skilled in the art will recognize that the brewing gas of Formula 3d (i.e., where 10 G is C1 Formula 3) can be readily prepared by a variety of well-known methods from the acid of Formula 6 (Scheme 12). For example, the acid can be reacted with a gasification reagent such as chloroform or sulfoxide in a solvent such as di-methane or toluene and optionally in the presence of a catalytic amount of dimethyl decylamine to provide Formula 3d. Corresponding to chlorine. 15

Argonizer Scheme 12

3d The compound of formula 6 can be prepared from the ester of formula 23 by a number of well-known methods (for example using standard aqueous saponification procedures such as u〇H, Na〇H or K〇H) in a solvent such as methanol or ethanol, as in the scheme 13 stated. 135 20 201240602 Alternatively, a de-farming agent such as Aihua or Sanf can be used in the presence of a base in a solvent such as pyridine or ethyl acetate. Additional reaction procedures for deesterification can be found in PCT Patent Publication No. WO 2006/133242. Alternatively, boron tribromide (??) can be used to prepare a compound of formula 6 from a compound of formula 23 in a solvent such as dioxane methane 5. The procedure using boron tribromide can be found in calendar (8) rg. ά MW. 2009, 19(16), 4733-4739. Scheme 13 0 0 6 L^TMSI Aik. 1 or ΒΒγ3 An-r, MOH base] C person 2 -► Solvent 6 10 Aik is C丨-06 alkyl 23 M is Li, Na or Κ 15 Pyridine of formula 23a Ketoesters (i.e., formula 23 wherein Aik is ethyl, hydrazine is CH and Y is C(O)) are prepared as described in Scheme 14, by making the fluorenone of formula 26 and the agent The compound is subjected to a decaneization reaction and is carried out in the presence of a base such as sodium hydride or potassium carbonate in a solvent such as hydrazine, tetrahydroanion or diethyl hydrazine. Ο 0

Option 14 0 〇

R1 R2 provides the pitting agent of R1. Alkali Solvents of the formula 23a can be obtained by the method of Scheme 15. In this method, 'methylene 136 20 201240602 malonate' is a salt of the formula 29 (wherein the hydrazine is a halogen or a sulfonate relative ion) in excess of the test such as sodium oxide or The cyclization in a suitable solvent such as ethanol in the presence of carbonic acid (usually at the reflux temperature of the solvent) is the same as the counterpart of formula 3f. Examples of such synthetic methods are described in PCT Patent Publication Nos. WO 2006/133242 and (10) 2001, 57, 2689. C02Et EtO^jjA^COjEt 28 + Scheme 15

Rk, human X N , NH Η 29 ΗΧ base, solvent 23a 15 The pyrimidine ester of formula 26 can be obtained by the method of Scheme 16. In this method, the ethyiene malonate of the formula 28 is obtained by the sulfonium salt of the formula 29a (the scorpion is a physin or a sulphonate relative ion) In the presence of potassium carbonate, it is cyclized in a suitable solvent (usually at the temperature of the solvent), corresponding to pyrimidinone. An example of such a synthetic procedure is described in the patent publications No. WO 2006/133242 and Qiao (10) 2001, 57, 2689. Scheme 16 + R2 29a, solvent 137 26 28 201240602 The pyrimidone ester of formula 23-X1 can be converted to the pyrimidone ester of formula 23-X3 and 23-X4 by the method of Scheme 17. In this method, the 23-X1 system is combined with an acid such as HCl or H2S04 in an aprotic solvent such as dioxane or a protic solvent such as methanol or ethanol at a temperature between 0 ° C and 5 The temperature is contacted to produce an aldehyde or ketone of the formula 23-X2. Next or simultaneously, the aldehyde or ketone of formula 23-X2 can be combined with a substituted hydroxylamine or a hydrazine catalyst such as HCl or H2S04 in an aprotic solvent such as dioxane or a protic solvent such as methanol or ethanol. Contact is made at a temperature between 〇 ° C and the boiling point of the solvent to yield compounds of the formula 23-X3 and 23-X4 ί, which can be further reacted as described in Schemes 1-16. Those skilled in the art will recognize that the aldehydes and ketones of Figure 23-X2 can be further converted to a number of other functional groups by various methods known in the chemical literature. Option 17 0 0 0 0

23-X3 23-X4 15 The formula 29 can be prepared from the amine of the formula 29X and the nitrile of the formula 29Y according to a number of methods including, but not limited to, those described in the following literature: 138 201240602

European Patent Application EP 80592; J. Org. Chem. 2010, 75, 945-947 &gt; Chemistry - A European Journal 2009, 15, 7292-7296; Organic Process Research & Development 2008, U 1201-1208 ; Og. I Therefore, 2008, Sichuan, 445-448.

,nh2 29X

Option 18 R2‘N - 29Y

N H

29

NH will recognize that some of the above-mentioned reagents and reaction conditions for the preparation of the compound of formula 1 may be incompatible with certain functional groups present in the intermediate. In these examples, the incorporation of a protecting/deprotecting sequence or functional group into the synthesis will aid in obtaining the desired product. The use and selection of such protecting groups will be readily apparent to those skilled in the art of chemical synthesis (see, e.g., Greene, T_W.; Wuts, P. G. M. iVoiecizve 15 Groups in Organic Synthesis, 2nd ed.; Wiley: New York, 1991). Those skilled in the art will recognize that, in some instances, after introducing a particular reagent (as described in any of the individual schemes), it may be necessary to perform additional conventional steps not detailed to complete the synthesis of formula t. Those skilled in the art will also recognize that a combination of the steps set forth in the above schemes may be carried out in an order different from that which is presented in a particular order to produce a compound of formula 1. Those skilled in the art will also recognize that the compounds of Formula 1 and the intermediates described herein can undergo various types of electrophilic, nucleophilic, free radical, organic 139 201240602 f, oxidation and reduction reactions to add human substituents or modifications. Existing substituents 0, even if there is no further step-by-step, it is believed that those who have the usual knowledge of using the 5 15 domain can still make the best use of the fact that I use the real (four) as the key to limit the invention. Valley. The steps of the following examples illustrate an overall procedure - and the starting materials for each step are not necessarily required to be prepared by a preparative test strip, the procedure of which is described in other examples. Or step. Percentages are by weight, except for the chromatographic solution or otherwise indicated, the solvent mixture is given as a percentage and percentage. The twisted spectrum is described as offset from the tetramethyl residue in CDC13 and in the low field ppm of tin, unless otherwise noted; "s" means a single peak and "m" means a multi-peak '" "br s" means wide single peak, "d" means double peak, "如" means double peak, "t" means three peaks, "td" means triplet, "out" means double triple and " q" means the four peaks. Example 1 3-(1,4-Dioxaspiro[4.5]anthracene)_5_[(2_carbyl-6-o-oxycyclohexanyl)carbonyl]-2-phenyl_4 ( 3/f&gt; Preparation of pyrimidinone (compound oxime) Step A · 1-(1,4-dioxaspiro[4.5]dec-8-yl)-1,6-dihydro-6-sideoxy-2 Preparation of methyl phenyl-5-pyrimidinecarboxylate 込4 was added to ethy丨benzimidate hydrochloride (li g, 5.9 mmol) (dissolved in 15 ml of methanol). - Dioxa-spiro[4.5]dec-8-ylamine (1.0 g, 6.8 mmol). The mixture was stirred at ambient temperature for 16 h then added 25% w/w 201240602 of sodium methoxide (1.3 g, 6.1 mmol The solution, and continued to scramble for 20 minutes. The mixture was concentrated to dryness, and the residual dioxaspiro[4.5]dec-8-ylbenzene succinimide hydrochloride (7V-1,4-dioxaspiro [ 4.5] dec-8-ylbenzenecarboximidamide 5 hydrochloride) was suspended in 20 ml of acetonitrile and treated with dimethyl methoxymethylenemalonate (1.13 g, 6.5 mmol) followed by dbu (0.9 g) , 5.9 mmol) treatment. The reaction mixture was refluxed for 16 hours before decompression Concentrate and purify by medium pressure liquid chromatography (extracted from 3 〇〇 / 〇 to 1 〇〇〇 4 in acetonitrile in acetonitrile) to provide 1.2 g of oil The title compound. lH NMR (CDC13) δ 8.61 (d, 1H), 7.49-7.61 (m, 3 H), 7.42-7.48 (m, 2H), 3.98-4.08 (m, ih), 3.86-3.94 (m , 7H), 3.09 (m, 2H), 1.76 (d, 2H), 1.64 (d, 2H), 1.27-1.34 (m, 15 2H). 'Step B: 1-(1,4-Dioxaspiro) [4 5 ] 癸 ) ) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Addition of lithium iodide to each of the dioxo-oxo 20-phenyl-5-pyrimidinecarboxylate (Example 1, product of Step A) (0.40 g, 1.1 mmol) in 10 mL of ethyl acetate (0.43) The reaction mixture was refluxed for 6 hours and then cooled to ambient temperature. The combined 25 organic layers were then extracted with 1N Na〇H. The resulting aqueous layer was made acidic by concentration of HC1 and was extracted three times with a second gas 201240602. The combined organic layers were dried with EtOAc (EtOAc)EtOAc. lU NMR (CDCI3) δ 8.95 (s, 1H), 7.59 (m, 3H), 7.51 (s, 2H), 4.19 (m, 1H), 3.99 (s, 2H), 3.92 (s, 2H), 3.06 ( m, 5 2H), 1.82 (d, 2H), 1.73 (d, 2H), 1.34 (m, 2H). Step C: 3-(1,4-Dioxaspiro[4·5]indole-8-yl)-5-[2-hydroxy-6-oxooxycyclohexen-1-yl]carbonyl]- Preparation of 2-phenyl-4(3H)-pyrimidinone (Compound 1) ίο 1-(1,4-Dioxaspiro[4.5]癸-8-yl)_1,6·dihydro-6-side A solution of oxy-2-phenyl-5-pyrimidinecarboxylic acid (Example 1, product of step b) (0.39 g, 1.1 mmol) in 10 mL of di-methane methane (1⁄4, 2.3 mmol) Drip conditions, dimercaptoamine treatment. The reaction was stirred for 1 hour and then concentrated and re-dissolved in 10 mL of dioxane. 1,3-Cyclohexyl 15dione (0.14 g, 1.2 mmol) and triethylamine (310 μM, 2.2 mmol) were added and the reaction mixture was stirred at ambient temperature for 20 min then with additional triethylamine (310 μM, 2.2 mmol) was treated with 2 drops of acetone cyanohydrin. The reaction mixture was stirred at ambient temperature for 6 hours and then concentrated under reduced pressure and purified by medium pressure liquid chromatography (on a silica gel, 〇% to 3% methanol in chloro 20) to yield 0.060. The title compound of g, a compound of the invention. ]H NMR (CDCI3) δ 16.58 (s, 1H), 7.98 (s5 1H), 7.50 (m, 5H), 3.99 (s, 1H), 3.89 (m, 4H), 2.95 (d, 2H), 2.72 ( t, 2H), 2.50 (m, 2H), 2.08 (m5 2H), 1.72 (m, 4H)S 1.29 (m, 25 2H). 142 201240602 Example 2 5-[(2-Hydroxy-6-oxooxy_ι·cyclohexene small)carbonyl]_6_sideoxy_2•phenyl_1(6//)-biting acetaldehyde Preparation of 丨_(〇-methyloxime) (Compound 2) Step A: 2·(2,2·Dioxaxyethyl)phenylcarbonylindolamine 5 (N-(2,2-dimethoxyethyl)benzenecarboximida Preparation of mide) Deuterium (0.75 g, 14.56 mmol) was added portionwise to a solution of benzoquinone (15.0 g, 145.6 mmol) in MeOH (150 mL) and stirred in a nitrogen atmosphere at room temperature and stirred. 12 hours. Acetic acid (0.5 mL) was added and the mixture was stirred for 20 min, then 2,2-dioxyethylamine (18.34 g, 174.75 mmol) was added and the mixture was stirred overnight and concentrated under reduced pressure. The residue was dissolved in di-methane and washed with water. The organic layer was dried <RTI ID=0.0> 15 lH NMR (CDC13) δ 7.49-7.61 (m, 5H), 4.64 (m, 1H), 3.55 (m, 2H), 3.44 (s, 6H). Step B: Preparation of 1_(2,2-dioxaxyethyl)·ι,6-dihydro-6·sideoxy-2·phenyl-5-spoken bite tartare vinegar 20 Ν Ν(2, 2. Dimethoxyethyl) phenylcarbimimine decylamine (15 g5 72.1 mmol) in acetonitrile (150 mL) was added to a stirred solution of dimethyl methoxymethylenemelonate. (13.8 g, 79·3 mmol) followed by DBU (3.28 g, 21.6 mmol). The reaction mixture was heated to 25 °C for 6 hours at i20 ° C and cooled to room temperature and concentrated under reduced pressure. The residue was purified by column chromatography </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> <RTIgt; ]H NMR (CDC13) δ 8.73 (s, 1H), 7.49-7.57 (m, 5H), 4.87 (m, 1H), 4·16 (m, 2H), 3.94 (s, 3H), 3.3! (s , 6H). Step C: Preparation of methyl dihydro[2-(methoxyimino)ethyl]-6•oxo-2-phenyl-5-pyrimidinecarboxylate in 1-(2,2-dimethoxy Ethyl; H,6-dihydro-oxyl-2-phenyl-5-pyrimidinecarboxylate methyl ester (3.5 g, 11.0 mmol) in ethanol (1 mL) p-Toluene acid and o-methyl-amine hydrochloride (2.0 g, 24.2 mmol). The reaction mixture was warmed to reflux for 4 hours and then concentrated under reduced pressure. The residue was purified by column chromatography (M.sub.2) (m.). NMR (CDCI3) δ 8.65 (s, 1Η), 7.40-7.51 (m, 5H), 6.72 (m, 1H), 4.73 (m5 1H), 4.61 (m5 1H), 3.86 (s, 3H), 3.72 (s ,3H) 〇2〇Step D. l6-: Hydrogen·1 曱 曱 oxyimino)ethyl]-6-oxophenyl-5-pyrimidinecarboxylic acid was prepared in ruthenium, 6-dihydrogen small [ 2-(methoxyimino)ethyl]_6_sideoxy_2_benzene f ·5· shout acid A.8 g, 2.6 m_ in acetic acid ethyl acetate (10 mL) = stirring solution Add moth to (10) g, 6 6 faces.丨). Heat the anti 25 =&amp; to shout and _4 hours. The reaction mixture was concentrated. The residue was taken from water, and then 1N hydrochloric acid was added until </ RTI> 4, 201240 602 and then extracted with di-methane (100 mL). The organic layer was dried (MgSO4). NMR (CDC13) δ 8.93 (s, 1H), 7.45-7.55 (m, 5H), 5 6.72 (m, 1H), 4.84 (m, 1H), 4.22 (m, 1H), 3.68 (s, 3H) . Step E: 3-Sideoxy-1-cyclohexen-1-yl 1,6-dihydro-indole-[2-(methoxyimino)ethyl]6-oxo-2-phenyl -5·Preparation of β-Carmeline Acidate 1〇16-Dihydro-sodium [2-(methoxyimino)ethyl]-6-oxooxy-2-phenyl-5-pyrimidinecarboxylic acid ( 〇·25 g, 0.87 mmol) A 2-methylpyridinium iodide (0.33 g, 1.3 mmol) was added to a stirred solution of di-methane (1 mL) and The resulting mixture was stirred at room temperature for 15 minutes. Cyclohexanedione (〇, 14 g, 1 3 15 mmol) followed by triethylamine (0.21 g, 2.17 mmol) was added and the mixture was stirred at room temperature for 12 h. The reaction mixture was diluted with EtOAc (EtOAc) (EtOAc)EtOAc. The residue was purified by column chromatography (EtOAc EtOAc) LCMS: 382 (M +1) 〇 Step F: 5-[(2-amino-6-o-oxy-1-cyclohexan-1-yl)-yl]-6- oxo-2-phenyl- Preparation of 1(6//)- shouting acetic acid 1·(〇_Methyl fat) 25 in the side gas-based small soil, -1-yl 1,6-diaza-1-[2·(曱氧亚Amino)ethyl]-6-oxo-2-phenyl-5-pyrimidinecarboxylate (0.2 g, 0.52 145 201240602 mmol) in triethylamine in acetonitrile (5 mL) (〇〇7 g, 0.78 mmol) ' Then cyanohydrin (3 drops, (10)) was added and stirred at room temperature for 6 hours. The reaction mixture was concentrated under reduced pressure and the residue was evaporated and evaporated. The residue was purified by EtOAc (EtOAc): *HNMR(CDC13) 6 8.93 (s, IH), 7.45-7.59 (m, 5H) 6.68 (m, 1H), 4.70 (m, 1H), 4.57 (m, 1H), 3.68 (s, 3H): io 2.96 (m, 2H), 2.49 (m, 2H), 0.94 (m, 2H). 'Example 3 2-Cyclopropyl-5-[(2-hydroxy·6· pendant oxy small cyclohexene small)carbonyl]_3_(4-morpholinyl)·4(3//)·pyrimidine g Preparation of (Compound 22) 15 Step A: 2·Cyclopropyl-1,6-dihydro-small (4·morpholinyl)_6_sideoxy_5_ σ Methylene-based morpholine (1.37 g, 13.4 mmol) was added to a solution of ethyl cyclopropylimidate hydrochloride (2. 〇g^4 mmol) in methanol (19 mL) and then at room temperature Stir for 2 to 16 hours. A solution of sodium methoxide (25% w/w in methanol, 3 18 g, 14.7 mmol) was added and the solution was stirred for 30 min. The solution was concentrated in vacuo and dissolved in EtOAc (20 mL). Methyl dimethyl methoxymalonate (2.56 g, 14.7 mmol) and 1,8-diazabicyclo [5.4.0] eleven _7_ dilute (0.83 g, 5.3 mmol) were added and the mixture was heated After refluxing for 4 hours, it was concentrated under reduced pressure and was subjected to medium pressure liquid chromatography (on 0 to 100% ethyl acetate in hexane on 201240602) to provide 114 g of yellow. The title compound of the oil. !H NMR (500 MHz) δ ppm 8.46 (s, 1H), 4.31 (td, 2H)? 3.97 (m, 2H), 3.89 (s, 3H), 3.71 (td, 2H), 2.97 (m, 5 1H ), 2 83 (m, 2H), 1.25 (s, 2H), 1.17 (m, 2H). Step B: Preparation of 2-cyclopropyl-1,6-dihydro-ι·(4-morpholinyl)-6-sideoxy-5-pyrimidinecarboxylic acid 2-Cyclopropyl-1,6-di Hydrogen-1-(4-morpholinyl)-6-oxo-5-pyrimidine monodecanoate (ie product from step A) (i_i4g, 4.1 mmol) dissolved in acetonitrile (2% water in volume) It was treated with lithium bromide (powder, 丨77 g, 20.4 mmol) and triethylamine (0.63 g, 6.1 mmol), and was stirred at room temperature for 16 hours. The crude reaction mixture was diluted with aq. EtOAc (EtOAc (EtOAc) (EtOAc (EtOAc) Yield 0.942 g of the title compound as a white solid. NMR (500 MHz) δ ppm 12.68 (br s, 1H), 8.71 (s, 1H), 4.25 (td, 2H), 4.02 (m, 2H), 3.74 (d, 2H), 3.02 (m, 1H), 2.91 (m, 2H), 1.34 (d, 2H), 1.27 (d, 2H). 20 Step C: 2-cyclopropyl-5-[(2-hydroxy-6-oxyl small cyclohexene small) carbonyl]-3-(4-morpholinyl)-4(3//)-pyrimidine Preparation of a ketone (Compound 22) in 2-cyclopropyl-1,6-dihydro·1·(4·morpholinyloxy-5-pyrimidine 25 tarenic acid (ie from the product of the step) (0.5 g , 1.9 mmol) (in 6 mL of a gas hospital) was added 2-gas-1-mercaptopyrene (θ α g, 2 8 147 201240602 mmol) and cyclohexanedione (0.32 g, 2.8 mmol). Triethylamine (〇48 g 4.7 mmol) was added dropwise and the solution was stirred for 16 hours in atmosphere A. The solution was then diluted with a gas (50 mL) and washed with brine and brine. NaAO 4), filtered and concentrated in vacuo. The crude material was filtered and washed with ethyl acetate. The organic layer was concentrated in vacuo. The crude material was placed in acetonitrile (10 mL) and 2-hydroxy- 2-mercapto-propanenitrile (0-015 g, 0.15 mmol) and triethylamine (0 48 g, 47 mmol) was added. The solution was stirred at ambient temperature for 16 h. Pressure liquid chromatography (on the broken glue, ίο to the second gas smoldering Purification by alcohol elution to provide the title compound as a solid. NMR (500 ΜΗζ) δ ppm 16.47 (s, 1H), 7.88 (s 1H), 4.19 (m, 2H), 3.95 (dd5 2H), 3.71 (m, 2H), 2.94 (m 1H), 2.87 (d, 2H), 2.69 (t, 2H), 2.48 (t, 2H), 2.06 (m, 2H), 15 1.22 (m, 2H), 1.12 (m, 2H). 'Example 4 2-Cyclopropyl-5_[(2-hydroxy-4-oxobicyclo[3 2 oct-2-ene]-3-yl)carbonyl](4- morphaki Preparation of 4-(3-camididine-(Compound 23) 20 Release A: 2_cyclopropyl-5 low-oxyl-4-oxobicyclo[3.2.1]octyl 3) &amp; Preparation of -3-(4-morphinyl)-4(3//)-mouth ketone (Compound 23) in 2-cyclopropyl-1,6-dihydro-κ(4) hydrazino)_6_ side oxygen ·5_嚷 bit carboxylic acid (ie from the product of Example 3, step )) (〇5 g, i 9 咖μ (in 6 candichloromethane) added 2-gas-i-methyl heart than bite (〇72 g, 2.8 mmol) with bicyclo [3.2·n-octane_24_dione (〇39 g, 201240602 mmol). Diethylamine (〇48 g, 4.7 mmol) was added dropwise and the solution was applied to nitrogen Stir for 16 hours under the atmosphere. The solution was then diluted with dioxane (5 〇 mL) and washed with distilled water and brine. The organic layer was dried (Na2SO 4) filtered and concentrated in vacuo. The crude material was filtered through a pad of Celite and eluted with ethyl acetate. The organic layer was concentrated in vacuo. The crude material was taken up in acetonitrile (10 mL) and 2-hydroxy-2-methyl-propanenitrile (0 015 g, 〇 15 mm 〇i) and triethylamine (0.481 g, 4.7 mmol) was added. The solution was stirred at ambient temperature for 16 hours. The reaction mixture was then concentrated under reduced pressure and purified by medium pressure liquid chromatography (eluent eluted with hydrazine to 5 〇 / 甲 in methylene chloride in dichloromethane) to provide 0.199 g as solid. Title compound. lU NMR (500 MHz) δ ppm 16.64 (s, 1H), 7.82 (s, 1H), 4.21 (m, 2H), 3.96 (dd, 2H), 3.71 (m, 2H), 3.07 (m5 1H), 2.93 (m, 2H), 2.88 (d, 2H), 2.22 (d, 1H), 2.13 (m, 2H), 2.00 (m, 1H), 1.85 (m, 1H), 1.71 (m, 1H), 1.20 ( m, is 2H), 1.11 (m, 2H). The compounds of Tables 1 to 12 below can be prepared by the procedures described herein and by methods well known in the art. The following abbreviations are used in the table: Me means thiol, Et means ethyl, n-Pr means n-propyl, z'-Pr means isopropyl, c-Pr means cyclopropyl, "-Bu Means n-butyl, 20 /-Bu means isobutyl, s-Bu means secondary butyl, c-Bu means cyclobutyl, /Bu means tributyl, "-pent means n-pentyl c-Pent means cyclopentyl, "-Hex means n-hexyl, hep means heptyl, c-Hex means cyclohexyl, Ph means phenyl, OMe means decyloxy, OEt means ethoxy, SMe Is a nail thiol, SEt means ethylthio 'thp meaning 25 means tetrahydro 0 bottom 0 south, thtp means tetrahydrothiopyran, thf means tetrahydrofuran, -CN means cyanide 149 201240602, -N02 means nitro, S(0)Me means sulfinyl, S02 means sulfonyl and S(0)2Me means sulfonyl. Table 1

R2 is Ph

201240602

R1 R1 R1 ΓΛ ΓΛ ΓΛ S. NH '(CH2)2 h , S NH (CH2)3 h , s (CH2)4 h ΓΛ ΓΛ 〇 , 〇 NH ch2, ch3 , 〇NH (CH2)2 CHi , 0 NH (CH〇)^ CH-i r\ r\ ΓΛ 0 NH (ch2)4, ch3, S NH ch2, ch3 (ch2)2, ch3 ΓΛ, s test (ch2)3, ch3 ΓΛ, sXm (ch2)4 , ch3 /CH3, 〇X〇, ch2 h /CH3 ΓΛ , X〇(CH2)2 h /CH3 , °x〇^2)3 H /ch3 , °x〇/CH3 , sxs , ch2 h /CH3 \SXS ^2)2 H /CH3 , sxs /CH3 \SXS ^2)4 H Corpse 3 r\ , X〇ch2 ch3 /CH3 (ch2)2, ch3 /CH3 r\ Corpse 3 /~\ /CH3 ΓΛ , X ( CH2&gt;3, ch3, 〇X〇(CH2)4, ch3, sxs ch2, ch3 /CH3 (CH2)2XCH3 ch3 /ch3 (CH2CXCH3 h3c ΓΛ h3c /~~\ h3c ΓΛ , 0 KH ch2 h , 〇NH (CH2 ) 2 h , 0 NH (CH2)3 H 151 201240602

R1 R1 R1 h3c r\ , 0 NH (CH2)4 h H3C S NH , ch2 h h3c , S NH nTch2)TS'h h3c , S NH '(CH2CSH h3c S NH ^ch2)T^h H3C ΓΛ , 0 NH Ch2, ch3 H3C ΓΛ H3Cv f\ H3Cv f\ , 0 NH (ch2)2, ch3, 0 NH (ch2)3, ch3 0 NH (ch2)4, ch3 h3c NH CH2 CH3 H3C, SQh (ch2)2, ch3 H3C (ch2)3, ch3 h3c, S NH /CH3 /( , 0xm ch2 h /CH3 , 0 NH /CH3 (CH2)3 h /CH3 , 0 NH /CH3 /( , s π ch2 h yCH3 S NH /CH3 /( , S NH (CH2)3 h /CH3 , S NH ^2)4 H /CH3 , 0 NH ch^^ch3 /CH3 /( , 0 NH (CH2)2, ch3 /CH3, 0 NH vTch2^sch3 yCH3 /( (CH2)4, ch3 /CH3 ri CH2 CH3 yCH3 , S NH 152 201240602 R1 R1 R1

-(CH2)2CH=NOH -ch2c(ch3)=noh

-(CH2)4C(CH3)=NOH -(CH2)4CH=NOCH3

-(CH2)3C(CH3)=NOH -(CH2)3CH=NNH2 -(ch2)2c(ch3)=nnh2 -(CH2)2CH=NNHCH3 -CH2C(CH3)=NNH2

• (ch2)4c(ch3)=nnh2 -(CH2)2C(CH3)=NOH -(CH2)2CH=NOCH3 •ch2c(ch3)=noch3

-(CH2)4C(CH3)=NOH »(CH2)4CH=NNH2 -(CH2)3C(CH3)=NNH2 •(ch2)3ch=nnhch3 -(CH2)2C(CH3)=NNH2 -(CH2)2CH= NN(CH3)2

-(CH2)4CH=NOH

-(CH2)3C(CH3)=NOH -(CH2)3CH=NOCH3 -(ch2)2c(ch3)=noh -(CH2)2CH=NNH2 -CH2C(CH3)=NNH2 -(CH2)4C(CH3)= NNH2 -(CH2)4CH=NNHCH3 -(CH2)3C(CH3)=NNH2 -(CH2)3CH=NN(CHj)2 153 201240602 R1 R1 R1 -(CH2)4CH=NN(CH3)2 -CH2C(CH3) =NN(CH3)2 -(CH2)2C(CH3)=NN(CH3)2 -(CH2&gt;3C(CH3)=NN(CH3)2 -(CH2)3C(CH3)=NN(CH3)2 •( Ch2)4c(ch3)=nn(ch3)2 -(CH2)2CH=NS02CH3 •(ch2)3ch=nso2ch3 -(CH2)4CH=NS02CH3 -CH2C(CH3)=NS〇2CH3 -(ch2)2c(ch3) =nso2ch3 -(CH2)3C(CH3)=NS02CH3 -(ch2)4c(ch3&gt;=nso2ch3 *(CH2)2CH=NCOCH3 -(CH2)3CH=NCOCH3 -(CH2)4CH=NCOCH3 -CH2C(CH3)=NCOCH3 *(CH2)2C(CH3)=NCOCH3 -(CH2)3C(CH3)=NCOCH3 •(ch2)4c(ch3)=ncoch3 -ch=chch2ch=noch3 -(CH2)2CH=CHCH=NOCH3 -ch2ch=chc( Ch3)=noch3 -(CH2)2ch=CHC(CH3)=NOCH3 -ch2conh2 -(CH2)2CONH2 -(CH2)3CONH2 -ch2conhch3 -(CH2)3CONHCH3 -ch2con(ch3)2 -(CH2)2CON(CH3)2 -(ch2)3con(ch3)2 -ch2coch3 -(CH2)2COCH3 -(CH2)3COCH3 -ch2coch2ch3 -(CH2)2COCH2CH3 -(ch2)3coch2ch3 -(CH2)2OCH2CN •(ch2)3och2cn _(ch2)2och2conh2 -ch2och2conh2 -&lt;^y^=NOH —^&gt;=noch3 —^^&gt;=NOCH2CH3 -\ =NNH2 —&lt;^^=nnhch3 —&lt;^&gt;=nnhch2ch3 —&lt;^&gt;=NN(CH3)2 —&lt;(^&gt;=nso2ch3 —\=ncoch3 NOH NOCH3 NOCH2CH3 nnh2 ^nnhch3 nnhch2ch3 , Nn(ch3)2 /—\ nso2ch3 Factory V ^ncoch3 -( V=NOH — ί \=noch3 -( \=NOCH2CH3 —1 \=nnh2 —< ^=nnhch3 —< nnhch2ch3 —&gt;=nn(ch3)2 —<^=nso2ch3 —< ^=ncoch3 face \ V=noch3 ^ NOCH2CH3 154 201240602 R1 R1 R1

2 NN(CH3)2

NNHCH3

\=nso2ch3

\=nnhch2ch3

NCOCH3

NN(CH3)2 )=nhoch3 y )=nnhch3 y )=nso2ch3 y

155 201240602

156 201240602

157 201240602 R1 R1 R1

158 201240602 The disclosure also includes Tables 1A to 101A, each of which is constructed as in Table 1, except that the headings in Table 1 (ie, "R2 is Ph") are the column headings replaced below. For example, in Table 1A, the column heading is "R2 is Me", and R1 is as defined in Table 1 above. Thus, the first item of 5 in Table 1A specifically discloses a compound of formula 1, wherein R1 is ΓΛ, X0 ch2 η; R2 is Me; R3 is OH; Α is Al; Β1 is C_1; Β2 is ίο C-3; Β3 is Cl ; and each of R14, R15, R18 and R19 is Η. Tables 2 to 101 are structured in a similar manner. Table headings Table column headings 1A R2 is Me 19A R2 is Ph(4-F) 2A R2 is Et 20A R2 is OMe 3A R2 is "-Pr 21A R2 is OEt 4A R2 is c-Pr 22A R2 is CH2Ph 5A R2 is SMe 23A R2 is 2-° pyridine group 6A R2 is S〇2Me 24A R2 is 3-&quot; pyridine group 7A R2 is CF3 25A R2 is 4-&quot; pyridine group 8A R2 is Ph(2-Cl) 26A R2 is Η 9A R2 is Ph(3-Cl) 27A R2 is Ph(3,5-di-F) 10A R2 is Ph(4-Cl) 28A R2 is Ph(3,4-di-F) 11A R2 is Ph(2-Me) 29A R2 is Ph(3,4,5-tri-F) 12A R2 is Ph(3-Me) 30A R2 is Ph(2,3-di-F) 13A R2 is Ph(4- Me) 31A R2 is Ph(3-CF3) 14A R2 is Ph(2-OMe) 32A R2 is Ph(4-CF3) 15A R2 is Ph(3-OMe) 33A R2 is Ph(3,5-di-CF3 16A R2 is Ph(4-OMe) 3.4 A R2 is w-Bu 17A R2 is Ph(2-F) 35A R2 is CH2OCH3, 18A R2 is Ph(3-F) 36A R2 is CH2CH2OCH3 159 201240602 Table heading table Column heading 37A R2 is CH2CH2CF3 71A R2 is 4-isoxazolinyl 38A R2 is CH2CF3 72A R2 is 5-Me-3-pyridyl 39A R2 is w-pent 73A R2 is 5-C1-2-pyridyl 40A R2 For c-pent 74A R2 is Ph(3,4-di-OMe) 41A R2 is c-Hex 75A R2 is Ph(3,5-di-OMe) 42A R2 is &quot;-Hex 76A R2 is Ph(3-OEt) 43A R2 is thp-4-yl 77A R2 is Ph(4-OEt) 44A R2 is Ph (2-CN) 78A R2 is Ph(3,4-di-OEt) 45A R2 is Ph(3-CN) 79A R2 is Ph(3,5-di-OEt) 46A R2 is Ph(4-CN) 80A R2 is Ph(3,4-di-Me) 47A R2 is Ph(2-OCH) 81A R2 is Ph(3,5-di-Me) 48A R2 is Ph(3-OCH) 82A R2 is Ph(3, 4,5-Tri-OEt) 49A R2 is Ph(4-OCH) 83A R2 is Ph(3-OCH2CH=CH2) 50A R2 is Ph(3-Me,2-F) 84A R2 is Ph(4-OCH2CH= CH2) 51A R2 is Ph(3-Me,4-F) 85A R2 is 3,5-(MeO)2-pyrimidinyl 52A R2 is Ph(3-Me, 5-F) 86A R2 is 3,5-( EtO)2-pyrimidinyl 53A R2 is Ph(3-Me,6-F) 87A R2 is 3,5-(MeO)2-triazinyl 54A R2 is Ph(3-F,2-Me) (triazinyl) 55A R2 is Ph(3-F,4-Me) 88A R2 is 3,5-(EtO)2-triazinyl 56A R2 is Ph(3-F,5-Me) 89A R2 is -CH2CH=NOCH3 57A R2 Is Ph(3-F,6-Me) 90A R2 is -(CH2)2CH=NOCH3 58A R2 is i-Pr 91A R2 is -(CH2)3CH=NOCH3 R2 is -CH=CHCH2CH=NOCH3 59A R2 is i- Bu 92A 60A R2 is 2-thienyl 93A R2 is 61A R2 is 3-thienyl-(CH2)2CH=CHCH=NOCH3 62A R2 is 2-furyl 94A R2 is -CH2C(CH3)=NOCH3 63A R2 is 3-furyl 95A R2 is 64A R2 is 2-isooxazolinyl 96A -(ch2)2c(ch3 ==noch3 R2 is -CH2CONHCH3 65A R2 is 2-oxazolinyl 97A R2 is -(CH2)2CONHCH3 66A R2 is 1-Me-3-pyrazolyl 98A R2 is -(CH2)3CONHCH3 67A R2 is 3-thiazole 99A R2 is -CH2CON(CH3)2 68A R2 is 2-thiazolyl 100A R2 is -(CH2)2CON(CH3)2 69A 70A R2 is 2-thiazolinyl (R) is 2-oxazolyl 101A R2 is -(CH2)3CON(CH3)2 201240602 Table 2 Table 2 is constructed as in Table 1, except that the structure is replaced by the following: Ο Ο

The disclosure also includes Tables 1B to 101B, the columns of which are the same as those in Tables 1A to 101A. Table 3 ίο Table 3 is constructed as in Table 1, except that the structure is replaced by the following

The disclosure also includes Tables 1C to 101C, the column of which is the same as that of Tables 1A to 101A. Table 4 Table 4 is constructed as in Table 1, except that the structure is replaced by the following: 161 201240602

R1 R2 Table 5 10 The present disclosure also includes Tables 1D to 101D, and the column headings of R2 are the same as those in 1A to 101A. Table 5 Table 5 is constructed as in Table 1, except that the structure is replaced by the following ΟΗ Ο Ο

The disclosure also includes Tables 1E to 101E, the column of which is the same as that of 1A to 101A. Table 6 15 Table Table 6 is constructed as in Table 1, except that the structure is replaced by the following OH 0 0

R1 R2. The table disclosure also includes Tables 1F to 101F, and the column headings of R2 are the same as those of 1A to 101A. 162 201240602 Table 7 Table 7 is constructed as in Table 1, except that the structure is replaced by the following

The disclosure also includes Tables 1G to 101G, and the column headings of R2 are the same as those in Tables 1A to ι〇ι. Table 8 is constructed as in Table 1, except that the structure is replaced by the following

The disclosure also includes Tables 1H to ιοίΗ, and the column headings of R2 are the same as those in Tables 1A to 01A. Table 9 Table 9 is constructed as in Table 1, except that the structure is replaced by the following: 163 201240602

R1 R2 This disclosure also includes Tables 11 through 1011, the columns of which are the same as those in Tables 1A to 101A. Table 10 Table 10 is constructed as in Table 1, except that the structure is replaced by the following

The disclosure also includes Tables 1J to 101J, and the column headings of R2 are the same as those in Tables 1A to 101A. 15 Table 11 Table 11 is constructed as in Table 1, except that the structure is replaced by the following

164 201240602 The disclosure also includes Tables 1K to 101K, and the column headings of R2 are the same as those in Tables 1A to 101A. Table 12 Table 12 is constructed as in Table 1, except that the structure is replaced by the following

The disclosure also includes Tables 1L to 101L, the column heading of which is the same as that of ίο Tables 1A to 101A. Table 13 Table 13 is constructed as in Table 1, except that the structure is replaced by the following Ο 0

The disclosure also includes Tables 1M through 101M, the columns of which are the same as those in Tables 1A through 101A. 2〇 Table 14 Table 14 is constructed as in Table 1, except that the structure is replaced by the following 165 201240602 Ο Ο

The disclosure also includes tables IN to 101, and the column headings of R2 are the same as those in Tables 1A to 101A. 5 Formulation / Utility The compound of the formula 1 of the present invention will generally be used as a herbicidal active ingredient in a composition (i.e., a preparation) accompanied by at least one selected from the group consisting of a surfactant, a solid diluent, and a liquid diluent. The additional ingredients of Group 10 are used as carriers. The formulation or composition ingredients are selected to match the physical properties of the active ingredient, the type of application and the environmental factors such as soil type, humidity and temperature. Useful formulations include liquid and solid compositions. Liquid compositions include solutions (including emulsifiable concentrates), suspensions, emulsions (including micro 15 emulsions and/or suspoemulsions) and the like, and are optionally added to a gel. Typical types of aqueous liquid compositions are soluble concentrates, suspension concentrates, capsule suspensions, concentrated emulsions, microemulsions, and suspension emulsions. The general types of non-aqueous liquid 2 steroid compositions are emulsifiable concentrates, microemulsifiable concentrates, dispersible concentrates and oil dispersions. The general type of solid compositions is dust powder. (dust), powders, granules, pellets, prills, pastilles, tablets, envelopes (filled 166 201240602 and the like, which may have a water-dispersible film and coating It is particularly useful for the formation of a film-forming solution or a flowable suspension (micro) 朦舂 / in the treatment. The active ingredient can be formed into a suspension or a solid preparation by a tempering component; or (or "covered"). Capsules can be used in the presence or absence of active ingredients. The emulsifiable particles combine the advantages of ke, s, and S and dry granules.邛 Sprayable formulations are usually extended in a suitable medium prior to spraying. These liquid and solid formulations are formulated to be rapidly diluted in a spray medium (usually water). The amount sprayed can be from each hectare. About one to several thousand liters but more From about ten to several hundred liters per hectare. The sprayable formulation can be mixed with water or other suitable medium in a bucket for application to the leaf treatment by aerial or ground application, or to the growth medium of the plant. The agent and the dry preparation can be directly metered into the drip irrigation system or furrow at the time of sowing. The preparation usually contains an effective amount of the active ingredient, a diluent and a surfactant, which fall within the following general range and the weight will add up. Equal to 100%. 20% by weight water-dispersible granules and water-soluble granules 0.001-90 Thinner 0-99.999 Surfactant 0-15, tablet and powder oil dispersion, suspension, emulsion, 1-50 40- 99 0-50 solution (including emulsifiable concentrate) dust powder 1-25 70-99 0-5 granules and pills 0.001-99 5-99.999 0-15 still strength composition 90-99 0-10 0-2 167 201240602 Solid diluents include, for example, clay such as bentonite, microcrystalline kaolinite, eucalyptus and kaolin, gypsum, cellulose, titanium dioxide, zinc oxide, starch, dextrin, sugar (eg lactose, Yan sugar), dioxide Shi Xi, talc Mica, diatomaceous earth, urea, calcium carbonate, sodium carbonate and sodium bicarbonate and sodium sulfate. Typical solid diluents are described in Watkins et al., Handbook of Insecticide Dust Diluents and Carriers, 2nd Ed_, Dorland Books, Caldwell, New Liquid diluents include, for example, water, A^V-dimethyl decylamine (such as monomethyl amide), hydrazine, dimethyl sulphur, and hospital-based alpha to η each biting ketone (for example, TV-methyl pirone, ethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, propyl carbonate, butyl carbonate, paraffin (eg 'white mineral oil, normal paraffin, Isoalkane, phenyl, ketone, glycerol, glycerol triacetate, sorbitol, quaternary hydrocarbon, dearomatized, phenyl, naphthyl, such as cyclohexanone, 2- Heptanone, isophorone and 4-keto-4-methyl-2-pentanone ketone, such as isoamyl acetate, hexyl acetate, heptyl acetate, octyl acetate, acetic acid, tridecyl acetate And an acetate of isodecyl acetate, such as an alkylated lactate ester, a dibasic ester, and γ_ Other esters of lactones, and alcohols, which may be linear, branched, saturated or unsaturated, such as methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, n-hexanol, 2- Ethylhexanol, n-octanol, decyl alcohol, isodecyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, tridecyl alcohol, oleyl alcohol, cyclohexanol, tetrahydrofurfuryl alcohol, diacetone alcohol and benzofuranol . Liquid diluents also include glycerides of saturated and unsaturated fatty acids (typically C6_C22), such as plant seeds and fruit oils (eg olives, ramie, linseed, sesame, corn, peanuts, 168 201240602 to hollyhock, grape vine , safflower, cotton stalk, soybean, rapeseed, coconut and palm kernel oil), animal-derived fat (such as butter, pork fat, lard, cod liver oil, fish oil) and mixtures thereof. Liquid diluents also include hospitalized fatty acids (e.g., methylated, ethylated, butylated) wherein the 5 fatty acids are obtained by hydrolysis of glycerides from plant and animal sources and can be purified by distillation. Typical liquid diluents are described in Marsden, Solvents Guide, 2nd Ed., Interscience, New York, 1950. The solid and liquid compositions of the present invention typically comprise one or more interfacial surfactants. Surfactants (also known as "surfactants") typically change (most often reduce) the surface tension of a liquid when added to a liquid. Depending on the nature of the hydrophobic and lipophilic groups in the surfactant molecule, the surfactant can be used as a wetting, dispersing, emulsifying or antifoaming agent. 15 Surfactants can be classified as nonionic, anionic or cationic. Nonionic surfactants useful in the compositions of the present invention include, but are not limited to, alcohol alkoxides such as alcohol alkoxides based on natural and synthetic alcohols which may be branched or linear and prepared from the alcohols, and Ethylene oxide, propylene oxide, butylene oxide and mixtures thereof; ethoxylated amine, decyl alcohol 20 decylamine and ethoxylated alkanolamine; alkoxylated triglyceride such as ethoxylated Soybean, medicinal and rapeseed oil; alkylphenol alkoxides such as octylphenol ethoxylate, phenol ethoxylate, dinonyl phenol ethoxylate and dodecyl phenol ethoxylate (from phenol And ethylene oxide, propylene oxide, butylene oxide or a mixture thereof; a block polymer prepared from cyclooxyethylene or propylene oxide and a terminal block thereof prepared from propylene oxide Reverse block polymer; ethoxylated 169 201240602 fatty acid; ethoxylated fatty esters and oils; ethoxylated methyl esters; ethoxylated tristyrene phenol (including ethylene oxide, epoxy Prepared from propane, butylene oxide or a mixture thereof; fatty acid esters, Oleate, lanolin-based derivatives, polyethoxylated g such as polyethoxylated sorbitol needle 5 fatty acid ester, polyethoxylated sorbitan fatty acid ester and polyethoxylated glycerol Fatty acid esters; other sorbitan derivatives such as sorbitan esters; such as polymeric surfactants such as random copolymers, block copolymers, alkyd peg (polyethylene glycol), grafted or comb polymers And star polymers; polyethylene glycol (peg); polyethylene glycol fatty acid ester; polyoxyl-based interface ίο active agent; and sugar derivatives such as sucrose esters, alkyl polyglucosides and alkylpolysaccharides . Useful anionic surfactants include, but are not limited to, alkylaryl sulfonic acids and salts thereof; carboxylated alcohols or alkylphenol ethoxylates; diphenyl sulfonate derivatives, lignin and lignin derivatives, such as wood Acid 15 salt; maleic acid or succinic acid or its anhydride; olefin sulfonate; phosphate ester such as alcohol alkoxide wall acid ester, alkyl phenol oxide oxide acid ester and styryl phenol Phosphate oxides; protein-based surfactants; sarcosine derivatives; styrene sulfates; sulfates and sulfonates of oils and fatty acids; sulfates and sulphates of ethoxylated alkylphenols Acid 20 salt, alcohol sulfate; ethoxylated alcohol sulfate; amine and brewing amine continuous acid salt such as vinegar; benzene, cumene, toluene, diphenylbenzene and dodecene And sulfonate of triphenylbenzene; sulfonate of condensed naphthalene; sulfonate of naphthalene and alkylnaphthalene; fraction of petroleum sulfonate; sulfosuccinamide; and sulfosuccinate (suifosuccinate) And its 25 derivatives such as dialkyl sulfosuccinate. 201240602 Useful cationic surfactants include, but are not limited to, decylamine and ethoxylated decylamine; amines such as iV-alkyl propylene diamine, triexamine propylene and dipropylene propylene tetraamine, and ethoxylated amines , ethoxylated diamines and propoxylated amines (from amines and ethylene oxide, propylene oxide, butylene oxide or mixtures thereof); amine salts such as amine acetates and diamine salts a quaternary ammonium salt such as a quaternary salt, an ethoxylated quaternary salt, and a quaternary salt; and an amine oxide such as an alkyl decylamine oxide and a bis-(2-hydroxyethyl)alkylamine Oxide. Also useful in the compositions of the present invention is a mixture of a nonionic surfactant and an anionic surfactant, or a mixture of a nonionic surfactant and a cationic surfactant. Nonionic, anionic, and cationic surfactants and their suggested uses are disclosed in various published references, including McCutcheon s Emuhifiers and Detergents, annual American and International Editions published by McCutcheon s Division, The Manufacturing Confectioner 15 Publishing Co.» Sisely and Wood, Encyclopedia of Surface

Active Agents, Chemical Publ. Co., Inc., New York, 1964, with A S. Davidson and B. Milwidsky, Office

Detergents, Seventh Edition, John Wiley and Sons, New York, 1987. 2 The compositions of the present invention may also contain formulation adjuvants and additives, and formulation auxiliaries well known to those skilled in the art (some of which may also be considered to provide a solid diluent, a liquid diluent or a surfactant). Agents and additives can regulate pH (buffer solution), foaming during treatment (anti-foaming agent such as polyorganosiloxane), precipitation of active ingredients (suspension), viscosity (thixotropy thickener) , microbial growth (antibacterial agent) in the container, product freezing (antifreeze), color (dye/yan 171 201240602 dispersion), washing (film former or adhesive), evaporation (evaporation blocker), and Other formulation characteristics include, for example, polyvinyl acetate, polyvinyl acetate copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, polyvinyl alcohol, polyvinyl alcohol copolymer, and wax. Examples of formulation adjuvants and additives Includes those listed in the following literature: McCutcheon^s Volume 2: Functional Materials, annual

International and North American editions published by

McCutcheon s Division, The Manufacturing Confectioner

Publishing Co.; and PCT Publication No. 04/024222. The compound of formula 1 as well as any other active ingredient is typically incorporated into the compositions of the invention by dissolving the active ingredient in a solvent or grinding in a liquid or dry diluent. The liquid extracting agent, including the emulsifiable concentrate, can be prepared by simply mixing the ingredients. If the solvent intended to be used as the liquid composition of the emulsifiable concentrate is immiscible with water, an emulsifier is usually added to dilute the solvent containing the active ingredient when diluted with water. The slurry of the active ingredient having a particle size of up to 2,000 μm can be wet-milled using a media mill to obtain particles having an average diameter of 3 μm or less. The aqueous slurry can be made into a finished suspension concentrate (see, e.g., u s 3, 〇6〇, 〇84) or further processed into a water-dispersible granule by spray drying. Dry formulations typically require a dry milling process that produces an average particle size in the range of 2 to 10 μΐΏ. Dust and powder can be prepared by blending and usually by grinding (e.g., by a clock mill or a liquid 3b mill). Granules and pills are prepared by spraying the active material onto a preformed particulate carrier or by cohesive techniques. See Browning, Agglomeration", CTze/mca/ Ewgzweer/wg, December 4, 1967, pp 147-48, Perry's Chemical

Engineer's Handbook, 4th Ed., McGraw-Hill, New York, 172 201240602 1963, pages 8-57 and below, and WO 91/13546. Pellets can be prepared as described in U.S. 4,172,714. The water-dispersible and water-soluble granules can be prepared as taught in U.S. Patent No. 4,144,050, U.S. Patent No. 3,920,442, the entire disclosure of which is incorporated herein by reference. Lozenges can be prepared as taught by U.S. Patent No. 5,180,587, U.S. 5,232,701, and U.S. Patent No. 5,208,030. Film coats can be prepared as taught by GB 2,095,558 and U.S. Patent 3,299,566. For further information on formulation techniques, see T. S. Woods, “The Formulator’s Toolbox - Product Forms for Modern Agriculture” in PeWic/i/e million/asc^nce, 77?e ίο Food-Environment Challenge, T. Brooks and T. R.

Roberts, Eds., Proceedings of the 9th International Congress on Pesticide Chemistry, The Royal Society of

Chemistry, Cambridge, 1999, pp. 120-133. See also US 3,235,361, Col. 6, line 16 through Col. 7, line 19 and 15 Examples 10-41; US 3,309,192, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182; US 2,891, 855, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4; Klingman, Weed Control as a Science, John 2〇Wiley and Sons, Inc., New York, 1961, pp 81-96; Hance et al., Weed Control Handbooks 8th Ed., Blackwell Scientific Publications, Oxford, 1989; and Deve /op state bh formulation technology, PJB Publications, Richmond, UK, 2000. 25 In the example below, all percentages are by weight and

Some formulations are prepared in a conventional manner. The compound number refers to the compound in Index Table A 173 201240602 to B. Even without further elaboration, it is believed that those of ordinary skill in the art in the <RTIgt; Therefore, the following examples are for illustrative purposes only and are not intended to limit the disclosure of the invention. Percentages are by weight unless otherwise stated.

Example A 98.5% 0.5% 1.0% High Strength Concentrate Compound 1 Cerium Oxide Aerogel Synthesis of amorphous fine cerium oxide

Example B Wettable powder Compound 1 65.0% Dodecylphenol polyglycol ether 2.0% Sodium lignosulfonate 4.0% Sodium strontium aluminate 6.0% Montmorillonite (calcined) 23.0%

Example C Granules Compound 1 10.0% Eituprite granules (low volatiles, 0.71/0.30 mm; 90.0% U.S.S. No. 25 to 50 sieves)

Example D Extrusion Pills Compound 1 25.0% anhydrous sodium sulphate 10.0% calcium crude lignosulfonate 5.0% phthalocyanine sodium 1.0% calcium/magnesium bentonite 59.0% 174 201240602

Example E Emulsifiable Concentrate Compound 1 10.0% 20.0% 70.0% 5.0% 30.0% 30.0% 15.0% 20.0% Poly, sorbitol hexoleate C^-Cio fatty acid methyl vinegar

Example F

Microemulsion J Compound 1 Polyvinylpyrrolidone-vinyl acetate copolymer alkyl, glucoside (alkylp〇lyglyc〇side) glycerol monooleate (g丨yceryl m〇n〇〇丨eate) water These compounds are usually for early stage After the post-emergence weed control, the weed flute is still applied when it is young) and the pre-emergence weeds are applied before the germination of the soil, showing the highest area for all plants, such as fuel storage and work. = domain, parking lot, open-air car cinema, airport, ", J = his waterway, kanbans and highways and railway facilities, many of these, for the vast majority of the surface of the pre-emergence or weed control is effective Selective control of grasses and broadleaf grasses in crops/weeds, including selective metabolism of weeds in crops, or in crops and weeds Physiological inhibition sites have selective activity, selective or selective in the environment of crops and weeds, or the skilled person will recognize that a compound or group of compounds is hot A preferred combination of selectivity factors can be quickly determined by this conventional biological and/or biochemical assay. The important curves are shown by the implementation of the article 175 201240602 15 20 for the compounds of the invention, including But not limited to alfalfa, wheat, cotton, wheat, rape, beet, corn, sorghum, soybeans, rice, oats, peanuts, vegetables, tomatoes, potatoes, perennial plantings including coffee, cocoa, oil palm, rubber, sugar cane , citrus, grapes, fruit trees, nut trees, bananas, plantains, pineapples, dried hops, teas and = woody eucalyptus and conifers (such as Pinus taeda) and lawn species (such as Kentucky bluegrass, St. Augustine, fox grass and Bermuda compounds. The compounds of the invention are particularly useful for the selective control of weeds in wheat, barley, especially corn, yellow ugly, cotton and perennial planting crops such as sugar cane and citrus. The compounds of the invention may be used for genetic modification or colonization. To introduce herbicide-resistant crops and to express proteins that are toxic to invertebrate pests (eg, sclerotium (five) (10) Fine • Kiss (10) (4) Toxins) and/or other useful characteristics. Those skilled in the art will appreciate that not all compounds have a (four) effect on all weeds. Or, that alter plant growth. ^ Due to the compounds of the present invention At the same time, there is a post-emergence and pre-emergence herbicidal activity by killing or poisoning undesired plants or reducing their growth to prevent and control the 'object' can be achieved by various methods_ground method to make a herbicidal effective amount only 20,000 Characters and to + - this hair, or - containing the #丨 ^ # ^ agent, @ body thinner or liquid dilution =:, contact with the leaves of the unintended plant = the environment or the environment around the water The undesired plant grows in the colon (pr〇pa_. 4 seeds of undesired plants or other complex herbicides: the herbicidal effective amount is determined by considering various factors. These factors include the formulation selected, the method of application, the number and type of plants present, and the growth conditions. The herbicidal effective amount of a &amp; matter is about 〇〇 至 1 to 2. In general, the present invention is compounded at about 0.004 to 1 kg/ha. Familiar with g/ha' and the typical range of weeds required for weed control (4) can be determined to achieve the compound of the present invention can also be mixed with a formula or agent to form - more other beta activity Combined agricultural protection, including herbicides, in addition to two = 'and provide a wider range of insecticides, nematicides, known protective agents, fungicides, chlorpyrifos, fungicides, killing 10 15 20 mink Inhibition of side and raw __, chemical insecticides, insecticides, attractants, pheromones, stimulating factors, plant succulents, bioactive compounds, granules, and fungi. The a composition of the invention and its valerian mixture expands against the activity of additional weed species and suppresses the proliferation of any resistant biotype. The invention is therefore also applicable to the inclusion of a compound of formula 1 (in a herbicidally effective amount) and at least one additional biologically active compound or composition of a pharmaceutical agent, and may further comprise at least one surfactant, solid diluent or liquid diluent. Other biologically active compounds or agents may be formulated in the composition, and the composition of the invention comprises at least one surfactant, solid or liquid diluent. For the mixtures of the invention, one or more other biologically active compounds or agents may be formulated with a compound of formula 1 to form a premix, or one or more other biologically active compounds or agents may be formulated separately from the compound of formula j. The formulations are combined together (e.g., in a spray tank) prior to administration, or successively. Mixtures of one or more of the following herbicides with the compounds of the invention are especially useful for weed control: acetochlor (acet〇cW〇r), acifluorfen and its sodium salt, aci〇nifen, propylene Aldehyde 177 25 201240602 (acrolein, 2-propenal), alachlor, alloxydim, ametryn, amicarbazone, amidosulfuron, amine ring Aminocyclopyrachlor and its esters (eg, oxime esters, ethyl esters) and salts (eg, 5, such as sodium, potassium), 4-amino-3- gas-6-(4-gas-2-fluoro-3- Methoxyphenyl)-2-pyridinecarboxylic acid and its esters (such as methyl ester) and salts (such as sodium salt, _salt), aminopyralid (aminopyralid), amitrelation (amitrole), amino acid (ammonium sulfamate), anilofos, asulam, atrazine, azimsulfuron, beflubutamid, benazolin , benzallin-ethyl, bencarbazone, benfluralin, benfuresate, free speed (ben Sulson-methyl), bensulide, bentazone, benzobicyclon, benzofenap, bicyclopyrone, bifenox Bilanafos, bispyribac and its sodium salt, bromacil, bromobutide, bromofenoxim, bromoxynil, indiprozil octanoic acid g (bromoxynil octanoate), butachlor, butafenacil, butamifos, butralin, butroxydim, diquat (butylate), benzene_cafenstrole, carbetamide, carfentrazone-ethyl, catechin, chlomethoxyfen, gram stop 25 (chloramben), chlorbromuron, chlorflurenol-methyl, chloridazon, qi sheng continued 178 201240602 (chlorimuron-ethyl), chlorotoluron, kepufen (chlorpropham), chlorsulfuron, chlorthal-dimethyl, grass Chlorthiamid, cinidon-ethyl, cinmethylin, cinosulfuron, clefoxydim, clethodim, acetylene CG (clodinafop-propargyl), clomazone, clomeprop, clopyralid, clopyralid-olamine, cloransulam-methyl , cumyluron, cyanazine, cycloate, cyclosulfamuron, cycloxydim, cyhalofop-butyl, 2, 4-D with butotyl ester, butyl ester, isoctyl ester and isopropyl ester and its dimethylammonium salt, diethanolamine salt and triethanolamine (trolamine) salt, herbicide Dai (daimuron), dalapon, dalapon-sodium, dazome, 2,4-DB and its dimethyl salt, unsalted salt and sodium salt, beet amp (desmedipham ), desmetryn, dicamba and its diglycolammonium, diammonium, potassium and sodium salts, Dichlobenil, dichlorprop, diclofop-methyl, diclosulam, difenzoquat metilsulfate, diflufenic acid (difenzoquat metilsulfate) Diflufenican), diflufenzopyr, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, Dimethicin-di, dimethipin, dimethyl 179 201240602 dimethylarsinic acid and its sodium salts, dinitramine, dinoterb, diphenamid, diquat Diquat dibromide, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, amine benzene Ethametsulfuron-methyl, ethiozin, ethofumesate, ethoxyfen, ethoxysulfuron, etoxbenzan , fenoxaprop-ethyl, fennel-p (fen0xapr0p_p_ethyl), heterosexual ο fenoxasulfone, fentrazamide, fenuron, fenuron-TCA, flamprop-methyl, flamprop- M-isopropyl), high-efficiency flamprop-M-methyl, flazasuifuron, florasulam, fluazifop-butyl, voltapril • P ( fluazifop-P-butyl), fluazolate, flucarbazone, flucetosulfuron, fluchloralin, flufenacet, fluoride Flufe叩yr, fiufenpyr-ethyi, flumetsulam, flumiclorac-pentyl, flumioxazin, volt Fluometuron, fluoroglycofen-ethyl, flupoxam, flupyrsulfuron-methyl and its sodium salt, fluren〇i, 芴丁Flurenol-butyl, fluridone, flurochloridone, fluroxypyr, furosterone Amone), fluthiacet-methyl, sulfamethoxazole 201240602 ether (fomesafen), foramsulfuron, fosamine-ammonium, glufosinate, grass Glufosinate-ammonium, glyphosate and salts such as salt, isopropylammonium, potassium, sodium (including sesquisulfate) and trimethylsulfonate (also known as grass sulphur) Sulfosate, halosulfuron-methyl, haloxyfop-etotyl, haloxyfop-methyl, hexazinone, imazeth vinegar Imazamethabenz-methyl), imazamox, imazapic, imazapyr, imazaquin, imazaquin-ammonium , indaziflam, imazethapyr, imazethapyr-ammonium, imazosulfuron, indanofan, iodosulfuron-methyl, moth sin Ioxynil), ioxynil octanoate, ioxynil-sodium, acicle Ip (ipfencarbazone), IR6396, isoproturon, isouron, isoxaben, isoxaflutole, isoxachlortole, milk Lactofen, lenacil, linuron, maleic hydrazide, MCPA and its salts (eg MCPA·dimethylammonium salt, MCPA-) Potassium salt and MCPA-sodium salt), esters (eg MCPA-2-ethylhexyl ester, MCPA-butoxyethyl ester and thioester (eg MCPA-thioethyl ester), MCPB and its salts (eg MCPB-sodium salt) And S (for example, MCPB-B), mecoprop, 25 mecoprop-P, mefenacet, mefluidide, methylamine Mesosulfuron-methyl, nitriceps

181 S 201240602 Ketone (mesotrione), metam-sodium, metamifop, benzoquinone g (metamitron), metazachlor (metazachlor), double-turn gas (metazosulfuron), methabenzthiazuron, methylarsonic acid 5 and its calcium, monoammonium, monosodium and disodium salts, and methyldymron. Metobenzuron, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, extinction Meribuzin, metsulfuron-methyl, rice, mololinuron, naproanilide, napropamide, naptalam, grass Neburon, nicosulfuron, norflurazon, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, ping Oxadizon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat dichloride, gram grass Pebulate), pelargonic acid, pendimethalin, penoxsulam, pentanochlor, pentoxazone, perfluidone, acetochlor Pethoxamid), pethoxyamid, phenmedipham, poison Picloram, picloram-potassium, picolinium, picoxaden, piperophos, pretilachlor, fluoride Primisulfuron-methyl, prodiamine, benzoquinone 201240602 profoxydim, prometon, prometryn, propachlor, herbicide (propanil), propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propyzamide, benzyl Prosulfocarb, prosulfuron, pyraclonil, D pyraflufen-ethyl, sorghum*»pyrasulfotole, pyrazogyl ), pyrazolynate, pyrazoxyfen, pyrazosulfuron-ethyl, pyribenzoxim, pyributicarb, pyridate, 4-Amino-3-gas-6-(4-Gas-2-fluoro-3-methoxyphenyl)-2-pyridinecarboxylic acid (CAS number 943832-60 -8), 4-amino-3-chloro-6-(4-a-2,fluoro-3-methoxyphenyl)-2-pyridinecarboxylic acid methyl ester (CAS No. 943831-98-9), ring Iridium (isriftalid), pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyrocide Pyroxasulfone, pyroxulam, quinclorac, quinmerac, quinoclamine, quizalofop-ethyl, quick grass -P(quizalofop-P-ethyl), quizalofop-P-tefuryl, rimsulfuron, saflufenacil, sethoxydim, cyclopsone (siduron), simazine, simetryn, sulcotrione, sulfentrazone, sulfometuron-methyl, sulfosulfuron ), 2,3,6-TBA, TCA, TCA-sodium, forage (tebutam), butyl thiol 183 201240602 (tebuthiuron), tefuryltrione, tembotrione, tepraloxydim Special grass (terb Acil), terbumeton, terbuthylazine, terbutryn, thenylchlor, thiazopyr, 5 ketone gland (thiencarbazone) , thifensulfuron-methyl, thiobencarb, tiocarbazil, benzene. Topazone, tralkoxydim, tri-allate, triasulfuron, triaziflam, tribenuron-methyl , triclopyr, triclopyr-butotyl, triclopy-triethylammonium, tridiphane, trietazine, trifed bite Trifloxysulfuron, trifluralin, triflusulfuron-methyl, tritosulfuron and vernolate. Other herbicides also include biological herbicides such as J. sylvestris (J/Simmons), C. sinensis (Co//e(6)nc/zwm (Penz.) Penz. &amp; Sacc.) Helicobacter spp. (ZVec/wiem wowocer, MTB-951), Myro echw 2〇 (Albertini &amp; Schweinitz Ditmar: Fries), palm plague (/&gt;/如〇/?/ ^〇^2/?0//^0^*&lt;3(Ugly 111;1.)81^1.) and T. sinensis (Pwcc/m'a Schub·). The compounds of the present invention can also be used in combination with the following substances, including plant growth regulators such as aviglycine, #-(phenylmethyl)-1//-25 ° 吟-6-amine, propyl chlorite Endoester (ep〇ch〇leone), gibberellic acid, gibberellin A4 and A7, hypersensitive egg 184 201240602 white (harpin protein), mepiquat chloride, ring Prohexadione calcium, prohydrojasmon, sodium nitrophenolate and trinexapac-methyl, and plant growth modifying organisms such as Cactus bacillus/ZMs cerews strain BP01. General reference for agricultural protective agents (herbicides, herbicide protectants, insecticides, fungicides, nematicides, acaricides and biological agents)

The Pesticide Manual, 13th Edition, C. Ό S

Tomlin, Ed., British Crop Protection Council, Farnham, 10 15 20 by mey, \j.K_, 2Q03 Anti The BioPesticide Manual, 2nd

Edition, LG Copping, Ed., British Crop Protection Council, Farnham, Surrey, UK, 2001 〇 For examples in which one or more of these various mixed partner agents are used, these various mixed partner agents (total) pairs The weight ratio of the hydrazine compound is typically between about 1:3000 and about 3 〇〇〇:1. The value to be noted is a weight ratio between about 1:3 GG to about 3 GG:1 (e.g., &quot; ratio between about 1:30 and about 30:1). Those skilled in the art can quickly determine the biologically effective amount necessary for the active ingredient to achieve the desired range of biological activity via a simple experiment. However, the range that can be controlled by the use of the formula or compound alone may include an expansion of these additional ingredients. For the control range of weeds. Table A1 lists the specific combinations of component (4) and component (b) which illustrate the mixture, composition and method. Composition (4) in the block of the combination of Jie eight:, marked in the index table A. The second column of Table A1 lists the specific compound of the knife (b) (for example, "2, 4" in the first row). The third, fourth and fifth bars of the table list the range of weight ratios of the component (b) compound to the component (a) at a typical application rate for field growing crops 185 25 201240602. Thus, for example, the first row of Table A1 specifically discloses that the composition of component (a) (i.e., Compound 1 in Index Table a) and 2,4-D is typically applied in a weight ratio of from 丨Η] to &amp; The remaining rows of Table A1 are structured in a similar manner. -1

186 201240602 Ingredient (a) Ingredient (b) Typical weight ratio More typical weight ratio Most typical weight ratio Compound 1 Bicyclopyrone 1:42 to 27:1 1:14 to 9:1 1:5 to 2 :1 Compound 1 Bifenox 1:257 to 5:1 1:85 to 2:1 1:32 to 1:4 Compound 1 Bispyribac-sodium 1:10 to 1 12:1 1 :3 to 38:1 1:1 to 7:1 Compound 1 Bromacil 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Bromobutide 1 :384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Bromoxynil 1:96 to 12:1 1:32 to 4:1 1:12 to 1:2 Compound 1 Butachlor 1:768 to 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Fluorine 0^ Grass S (Butafenacil) 1:42 to 27:1 1: 14 to 9:1 1:5 to 2:1 Compound 1 Butylate 1:1542 to 1:2 1:514 to 1:5 1:192 to 1:22 Compound 1 Benzene. Carfenstrole 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Carfentrazone-ethyl 1:128 to 9:1 1:42 to 3:1 1:16 to 1:2 Compound 1 Chlorimuron-ethyl 1:8 to 135:1 1:2 to 45:1 1:1 to 9:1 Compound 1 Chlorotoluron 1:768 To 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Chlorsulfuron 1:6 to 168:1 1:2 to 56:1 1:1 to 11:1 Compound 1 West Cincosulfuron 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Cinidon-ethyl 1:384 to 3:1 1:128 to 1 :1 1:48 to 1:6 Compound 1 Cinmethylin 1:34 to 34:1 1:11 to 12:1 1:4 to 3:1 Compound 1 Clethodim 1:48 To 24:1 1:16 to 8:1 1:6 to 2:1 Compound 1 Propdinafop-propargyl 1:20 to 56:1 1:6 to 19:1 1:2 to 4: 1 Compound 1 can be eliminated (Clomazone) 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Clomeprop 1:171 to 7:1 1:57 to 3 :1 1:21 to 1:3 Compound 1 Clopiralid 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Chlororanium-methyl 1:12 to 96:1 1:4 to 32:1 1:1 to 6:1 Compound 1 Benzene Cumyluron 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Cyanazine 1:384 to 3:1 1:128 to 1:1 1: 48 to 1:6 Compound 1 Cyclosulfamuron 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Cycloxydim 1:96 to 12:1 1 :32 to 4:1 1:12 to 1:2 Compound 1 Cyhalofop 1:25 to 45:1 1:8 to 15:1 1:3 to 3:1 Compound 1 Daimuron 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Desmedipham 1:322 to 4:1 1:107 to 2:1 1:40 to 1:5 Compound 1 Dicamba 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Dichlobenil 1:1371 to 1:2 1:457 to 1:4 1:171 to 1:20 187 201240602 Ingredient (a) Ingredient (b) Typical weight ratio More typical weight ratio Most typical weight ratio Compound 1 DicklcKprop 1:925 to 2:1 1:308 to 1:3 1:115 to 1:13 Compound 1 曱基禾草灵(Diclofop-methyl) 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Diclosulam 1:10 to 112:] 1:3 to 38:1 1:1 to 7:1 Compound 1 Difenzoquat 1:288 to 4:1 1:96 to 2:1 1:36 to 1:4 Compound 1. Diflufenican 1:857 to 2:1 1:285 to 1:3 1:107 to 1:12 Compound 1 Diflufenzopyr 1:12 to 96:1 1:4 to 32 :1 1:1 to 6:1 Compound 1 Dimethachlor 1:768 to 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Dimethametryn 1:192 To 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Dimethenamid-P 1:384 to 3:1 1:128 to 1:1 1:48 to 1: 6 Compound 1 Dithiopyr 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 has a Diuron 1:384 to 3:1 1:128 to 1 :1 1:48 to 1:6 Compound 1 EPTC 1:768 to 2:1 1:256 to 1:2 1:96 to 1:1] Compound 1 Esprocarb 1:1371 to 1:2 1 :457 to 1:4 1:171 to 1:20 Compound 1 Ethalfluralin 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Amisulfuron (Ethametsulfuron-methyl) 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Ethoxyfen 1:8 to 135:1 1:2 to 45:1 1 :1 to 9:1 Compound 1 Ethoxysulfuron 1:20 to 56:1 1:6 to 19:1 1:2 to 4:1 Compound 1 Etobenzanid 1:257 to 5:1 1:85 to 2:1 1:32 to 1:4 Compound 1 Ethylpropanate (Fenoxaprop-ethyl) 1:120 to 10:1 1:40 to 4:1 1:15 to 1:2 Compound 1 Fenoxasulfone 1:85 to 14:1 1:28 to 5:1 1:10 to 1:2 Compound I Fentrazamide 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Flazasulfuron 1:17 to 68:1 1:5 to 23: 1 1:2 to 5:1 Compound 1 Florasulam 1:2 to 420:1 1:1 to 140:1 2:1 to 27:1 Compound 1 Fluazifop-butyl ) 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Flucarbazone 1:8 to 135:1 1:2 to 45:1 1:1 to 9:1 Compound 1 Fluorotosulfuron 1:8 to 135:1 1:2 to 45:1 1:1 to 9:1 Compound 1 Flufenacet 1:257 to 5:1 1 :85 to 2:1 1:32 to 1:4 Compound 1 Flumetsulam 1:24 to 48:1 1:8 to 16:1 1:3 to 3:1 Compound 1 Fluoric acid ( Flumiclorac-pentyl) 1:10 to 112:1 1:3 to 38:1 1:1 to 7:1 compound 1 Flumioxazin 1:25 to 45:1 1:8 to 15:1 1:3 to 3:1 Compound 1 Fluometuron 1:384 to 3:1 1:128 to 1 :1 1:48 to::6 Compound 1 Flunarsulfuron 1:3 to 336:1 1:1 to 112:1 2:1 to 21:1 188 201240602 Composition (a) Composition (b) Typical weight ratio More typical weight ratio most typical weight ratio (Flupyrsulfuron-methyl) Compound 1 Fluridone]: 384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Fluorine ratio (Fluroxypyr ) 1:96 to 12:1 1:32 to 4:1 1:12 to 1:2 Compound 1 Flurtamone 1:857 to 2:1 1:285 to 1:3 1:107 to 1 :12 Compound 1 Fluthiacet-methyl 1:48 to 42:1 1:16 to 14:1 1:3 to 3:1 Compound 1 Fomesafen 1:96 to 12 :1 1:32 to 4:1 1:12 to 1:2 Compound 1 Diamsulfuron 1:13 to 84:1 1:4 to 28:1 1:1 to 6:1 Compound 1 Grass Glufosinate 1:288 to 4:1 1:96 to 2:1 1:36 to 1:4 Compound 1 Glyphosate 1:288 to 4:1 1:96 to 2:1 1: 36 to 1:4 Compound 1 Halosulfuron-methyl 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Haloxy fop-methyl 1:34 to 34:1 1:11 To 12:1 1:4 to 3:1 Compound 1 Hexazinone 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 methoxy 0 rice straw (Imazamox ) 1:13 to 84:1 1:4 to 28:1 1:1 to 6:1 Compound 1 Astringency. Imazapic 1:20 to 56:1 1:6 to 19:1 1:2 to 4:1 Compound 1 Imazapyr 1:85 to 14:1 1:28 to 5:1 1 :10 to 1:2 Compound 1 Imazaquin 1:34 to 34:1 1:11 to 12:1 1:4 to 3:1 Compound 1 Imazethabenz-methyl 1:171 to 7 :1 1:57 to 3:1 1:21 to 1:3 Compound 1 Imazamox 1:24 to 48:1 1:8 to 16:1 1:3 to 3:1 Compound 1 Izozosulfuron 1:27 to 42:1 1:9 to 14:1 1:3 to 3:1 Compound 1 Indanofan 1:342 to 4:1 1:114 to 2:1 1:42 to 1:5 Compound 1 Indaziflam 1:25 to 45:1 1:8 to 15:1 1:3 to 3:1 Compound 1 Iodosulfuron-methyl 1:3 to 336:1 1:1 to 112:1 2:1 to 21:1 Compound 1 Ioxynil 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Ipfencarbazone 1:85 To]4:1 1:28 to 5:1 1:10 to 1:2 Compound 1 Isoproturon 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Isoxaben 1:288 to 4:1 1:96 to 2:1 1:36 to 1:4 Compound 1 Isomalt _ (Isoxaflutole) 1:60 to 20:1 1:20 to 7:1 1:7 to 2:1 Compound 1 Lactofen 1:42 to 27:1 1:14 to 9:1 1: 5 to 2:1 Compound 1 Lenacil 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 has a dragon (Linuron) 1:384 to 3:1 1 :128 to 1:1 1:48 to 1:6 Compound 1 MCPA 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 MCPB 1:288 to 4:1 1:96 To 2:1 1:36 to 1:4 189 201240602 Composition (a) Ingredient (b) Typical weight ratio More typical weight ratio Most typical weight ratio Compound 1 Hecoprop 1:768 to 2:1 1: 256 to 1:2 1:96 to 1:11 Compound 1 Mefenacet 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Mefluidide 1 :192 to 6:1 ]:64 to 2:1 1:24 to 1:3 Compound 1 Mesosulfuron-methyl 1:5 to 224:1 1:1 to 75:1 1:1 to 14 :1 Compound 1 Mesotrione 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 Compound 1 tam 〇 Me Me Me (Metamifop) 1:42 to 27:1 1 :14 to 9:1 1:5 to 2:1 Compound 1 Metazamide (Metazachlo r) 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Diether gas Metazosulfuron 1:25 to 45:] 1:8 to 15:1 1 :3 to 3:1 Compound 1 Methabenzthiazuron 1:768 to 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Metolachlor 1:768 to 2: 1 1:256 to 1:2 1:96 to 1:11 Compound 1 Mesosulam 1:8 to 135:1 1:2 to 45:1 1:1 to 9:1 Compound 1 Metribuzin 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Metsulfuron-methyl 1:2 to 560:1 1:1 to 187:1 3 :1 to 35:1 Compound 1 Molinate 1:1028 to 2:1 1:342 to 1:3 1:128 to 1:15 Compound 1 Napropamide 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Naptalam 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Nicosulfuron 1:12 to 96:1 1:4 to 32:1 1:1 to 6:1 Compound 1 Norflurazon 1:1152 to 1:1 1:384 to 1:3 1:144 to 1: 16 Compound 1 Orbencarb 1:1371 to 1:2 1:457 to 1:4 1:171 to 1:20 Compound 1 Orthosulfamuron 1:20 to 56:1 1:6 to 19:1 1:2 to 4:1 Compound 1 Oryzalin 1:514 to 3:1 1:171 To 1:2 1:64 to 1:8 Compound 1 Fast 0 Oxadiargyl 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Oxadiazon 1:548 to 3:1 1:182 to 1:2 1:68 to 1:8 Compound 1 Oxasulfuron 1:27 to 42:1 1:9 to 14:1 1:3 to 3 :1 Compound 1 βoxa 17 oxolone (Oxaziclomefone) 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 Compound 1 Oxyfluorfen 1:384 to 3:1 1 :128 to 1:1 1:48 to 1:6 Compound 1 Paraquat 1:192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Pendimethalin 1:384 To 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Penoxsulam 1:10 to 112:1 1:3 to 38:1 1:1 to 7:1 Compound 1 Benzene Penthoxamid 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Pentoxazone 1:102 to 12:1 1:34 to 4: 1 1:12 to 1:2 Compound 1 Behenedipham 1:102 to 12: 1 1:34 to 4:1 1:12 to 1:2 Compound 1 Picloram 1:96 to 12:1 1:32 to 4:1 1:12 to 1:2 190 201240602 Composition (a) Composition (b) Typical weight ratio More typical weight ratio Most typical weight ratio Compound 1 Fluorophene (Picolinafen) 1:34 to 34:1 1:11 to 12:1 1:4 to 3:1 Compound 1 σ sit Pinoxaden 1:25 to 45:1 1:8 to 15:1 1:3 to 3:1 Compound 1 Pretilachlor 1:192 to 6:1 1:64 to 2:1 1 :24 to 1:3 Compound 1 Primisulfuron-methyl 1:8 to 135:1 1:2 to 45:1 1:] to 9:1 Compound 1 Prodiamine 1:384 To 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Profoxydim 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 Compound 1 Prometryn 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Propachlor 1:1152 to 1:1 1:384 to 1:3 1:144 to 1:16 Compound 1 Propanil 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Propaquizafop 1:48 to 24:1 1:16 to 8:1 1:6 to 2:1 Compound 1 Propoxycarbazone 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Propyrisulfuron 1:17 to 68:1 1:5 to 23: 1 1:2 to 5:1 Compound 1 Propyzamide 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Prosulfocarb 1:1200 to 1:2 1:400 to 1:4 1:150 to 1:17 Compound 1 Prosulfuron 1:6 to 168 1 1:2 to 56:1 1:1 to 11:1 Compound 1 Double sitting Pyraclonil 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 Compound 1 ° Pyraflufen-ethyl 1:5 to 224:1 1:1 to 75: 1 1:1 to 14:1 Compound 1 Continued σ σ (Pyrasulfotole) 1:13 to 84:1 1:4 to 28:1 1:1 to 6:1 Compound 1 Pyrazolynate 1 :857 to 2:1 1:285 to 1:3 1:107 to 1:12 Compound 1 Pyrazosulfuron-ethyl 1:10 to 112:1 1:3 to 38:1 1:1 to 7: 1 Compound 1 Pyrazoxyfen 1:5 to 224:1 1:1 to 75:1 1:1 to 14:1 Compound 1 Pyrybenzoxim 1:10 to 112:1 1:3 to 38:1 1:1 to 7:1 Compound 1 pyributicarb 1 :384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Pyridate 1:288 to 4:1 1:96 to 2:1 1:36 to 1:4 Compound 1 Ring Syrup (Pyriftalid) 1:10 to 112:1 1:3 to 38:1 1:1 to 7:1 Compound 1 Pyryminobac-methyl 1:20 to 56:1 1:6 Until 19:1 1:2 to 4:1 Compound 1 Shouting Pyrimisulfan 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Shyrithiobac 1:24 to 48:1 1:8 to 16:1 1:3 to 3:1 Compound 1 Pyroxasulfone 1:85 to 14:1 1:28 to 5:1 1:10 to 1:2 Compound 1 Pyroxsulam 1:5 to 224:1 1:1 to 75:1 1:1 to 14:1 Compound 1 Quinclorac 1:192 to 6:1 1: 64 to 2:1 1:24 to 1:3 Compound 1 Ethyl fast-moving grass 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 191 201240602 Composition (a) Composition (b) Typical weight ratio more typical weight ratio most typical weight ratio (Quizalofop-ethyl) Compound 1 Jade 0 Rimsulfuron 1:13 to 84:1 1:4 to 28:1 1:1 to 6:1 Compound 1 Saflufenacil 1:25 to 45: 1 1:8 to 15:1 1:3 to 3:1 Compound 1 Sethoxydim 1:96 to 12:1 1:32 to 4:1 1:12 to 1:2 Compound 1 Simazine) 1:384 to 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Sulcotrione 1:120 to 10:1 1:40 to 4:1 1:15 to 1 :2 Compound 1 Sulfentrazone 1:147 to 8:1 1:49 to 3:1 1:18 to 1:3 Compound] Sulfometuron-methyl 1:34 to 34:1 1:11 to 12:1 ]:4 to 3:1 Compound 1 Sulfosulfuron 1:8 to 135:1 1:2 to 45:1 1:1 to 9:1 Compound 1 Tebuthiuron 1:384 to 3:1 1:128 to 1:1 1:48 to]:6 Compound 1 Tefuryltrione 1:42 to 27:1 1:14 to 9:1 1:5 to 2:1 Compound 1 Ring 嗣(Tembotrione) 1:31 to 37:1 1:10 to 13:1 1:3 to 3:1 Compound 1 Depraloxydim 1:25 to 45:1 1:8 to 15:1 1:3 to 3:1 Compound 1 Terbacil 1:288 to 4:1 1:96 to 2:1 1:36 to 1:4 Compound 1 Terbuthylatrazine 1:857 to 2:1 1:285 to 1:3 1 :107 to 1:12 Compound 1 Terbutryn ]: 192 to 6:1 1:64 2:1 1:24 to]:3 Compound 1 Thenylchlor 1:85 to 14:1 1:28 to 5:1 1:10 to]:2 Compound 1 Thiazopyr 1:384 To 3:1 1:128 to 1:1 1:48 to 1:6 Compound 1 Thiencarbazone 1:3 to 336:] 1:1 to 12:1 2:1 to 21: 1 Compound 1 Thifensulfuron-methyl ]: 5 to 224:1 1:1 to 75:1 1:1 to 14:1 Compound 1 Thiobencarb 1:768 to 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Topramazone 1:6 to 168:1 1:2 to 56:1 1:1 to 11:1 Compound 1 Tralkoxydim 1 :68 to]7:1 1:22 to 6:1 1:8 to 2:1 Compound 1 Triallate 1:768 to 2:1 1:256 to 1:2 1:96 to 1:11 Compound 1 Triasu丨furon 1:5 to 224:1 1:1 to 75:1 1:1 to 14:1 Compound 1 Triaziflam 1:171 to 7:1 1: 57 to 3:1 1:21 to 1:3 Compound 1 Tribenuron 1:3 to 336:1 1:1 to 112:1 2:1 to 21:1 Compound 1 Triclopyr 1 :192 to 6:1 1:64 to 2:1 1:24 to 1:3 Compound 1 Trifloxys Ulfuron) 1:2 to 420:1 1:1 to 140:1 2:1 to 27:1 Compound] Trifluralin 1:288 to 4:1 1:96 to 2:1 1:36 to 1 :4 Compound 1 Triflusulfuron-methyl 1:17 to 68:1 1:5 to 23:1 1:2 to 5:1 Compound 1 Tritosulfuron 1:13 to 84: 1 1:4 to 28:1 1:1 to 6:1 192 201240602 Table A2 is constructed as shown in the above table Ai, except that the items below the heading of the “Component (a)” column are the following components (a) Replacement. The compound 2 in the component (a) 襕 is shown in the index table A. Therefore, for example, in Table A2 5, the "Component (a)" block headers all describe "Compound 2" (ie, Compound 2 indicated in Index Table A), and the first line below the heading of Table A2 is specifically disclosed. Mixture of Compound 2 with 2,4-D. Tables A3 through A34 are structured in a similar manner. Table No. Component (a) Shed Item A2 Compound 2 A3 Compound 3 A4 Compound 4 A5 Compound 5 A6 Compound 6 A7 Compound 7 A8 Compound 8 A9 Compound 9 A10 Compound 10 All Compound 11 A12 Compound 12 A13 Compound 13 A14 Compound 14 A15 Compound 15 A16 Compound 16 A17 Compound 17 A18 Compound 18 Table No. Component (a) Block A19 Compound 19 A20 Compound 20 A21 Compound 21 A22 Compound 22 A23 Compound 23 A24 Compound 24 A25 Compound 25 A26 Compound 26 A27 Compound 27 A28 Compound 28 A29 Compound 29 A30 Compound 30 A31 Compound 31 A32 Compound 32 A33 Compound 33 A34 Compound 34 In some instances, a combination of a compound of the present invention with other biologically active (especially herbicidal) compounds or agents (i.e., active ingredients) may cause greater than weeds The effect of greater-than-additive (ie, synergy) and/or for crops or other plants to be preserved may result in an effect of 193 201240602 being less than additive (iess-th). Rationality is the ability to reduce the amount of active ingredient in the dose, to ensure effective control, and to use a larger amount of active ingredient to provide effective weed control without causing damage to unwanted crops. When the herbicidal active ingredient produces a synergistic effect on weeds (under the application of agronomics: the rate of application of the level of weed control), the combination of such production costs and environmental burden can bring benefits. When weeding activity When the ingredients have a protective effect on the crop, such a composition can bring about the benefit of enhancing crop protection by reducing weed competition. It is noted that the composition of the present invention and at least one other herbicidal active ingredient are worthy of special attention. A composition which is different from the compound of the present invention in the action of other herbicidal active ingredients. In some examples, at least one composition having a similar control range but different action positions: a composition of other herbicidal active ingredients, which is particularly useful in resistance management Benefits. Accordingly, the compositions of the present invention may further comprise at least one additional herbicidal active ingredient (with a herbicidally effective amount) which has a similar range of control but different positions of action. The compounds of the invention may also be combined with a herbicide protectant Improve the completeness of certain crops, such as grass poisoning (aiiid〇chl〇r), solution Grasshopper (ben〇XaC〇r), BCS (1·bromo-4-[(gas f)sulfonyl]benzene), cloquintocet-mexyl, cy〇metrinil, ring Cyprosulfonamide, dixypropylamine (dichl〇rmid), 4-mercaptoethyl)-1-oxa-4-azospiro[4 5]decane (M〇N466〇), 2_ (dioxamethyl)-2-mercapto-1,3-dioxolane (MG 191), dicyclodonone (dicydonon), synergistic phosphorus (dieth〇丨), fenchlorazole -ethyl), fend 〇rim, oxalic acid 201240602 (flurazole), flusofenim, furilazole, isoxadifen-ethyl, hydrazine Mefenpyr-diethyl, mefrica, methoxyphenone ((4-methoxy-3-methylphenyl)(3-mercaptophenyl)fluorenone), naphthalene dinonanoate Naphthalic anhydride (1,8-naphthalene dicarboxylic anhydride) and oxabetrinil. A detoxifying effective amount of the herbicide protecting agent can be applied simultaneously with the compound of the present invention or as a seed treatment. One aspect of the invention relates to a herbicidal mixture comprising a hair A compound and a detoxifying effective amount of a herbicide protectant. Seed treatment is particularly useful for the selective control of weeds because it physically limits detoxification to crop plants. Thus, a particularly useful embodiment of the invention is a A method for selectively controlling the growth of an undesired plant in a crop, comprising contacting the locus of the crop with a herbicidally effective amount of a compound of the invention, wherein the seed of the crop (the crop line is grown therefrom) is effective as a detoxification Amount of protective agent treatment. The detoxifying effective amount of the protective agent is easily determined by a simple experiment. ‘ ' Λ Table 1 lists specific combinations of component (a) and component (b), which illustrate the mixtures, compositions and methods of the present invention. The second shed of Table B1 lists the specific component (b) compounds (for example, the first row of "Aidoch (A)"). The third, fourth and fifth of Table B i are listed for growing crops in the field. (4) The range of the weight ratio of the component (b) to the component (8) in the case of the Wei material. Therefore, for example, the first line of Table B1 specifically discloses the component (8) (that is, the compound indicated by the index table A and the herbicide composition is typically Apply in a weight ratio of 1:48 to 6:1. The remaining rows of Table 1 are structured in a similar manner. 195 25 201240602 Table ingredients (a) Compound 1 Compound 1 Compound 1 Compound 1 Compound 1 Compound 1 Compound 1 Compound 1 Compound 1 Compound Compound 1 Compound 1 Compound Compound 1 Compound 1 Compound 1 Compound Compound Compound 1 Compound 1 Ingredient (b) Allidochlor Benoxacor Detoxification (Cloquintocet-mexyl) Beclozil (Cloquintocet-mexyl) Cumyluron) Cyometrinil Cyprosu丨famide Diamuron Dichlormid • Dicyclonon Synergistic (Diethpipe) Dimepiperate, Fenchlorazole-ethyl, Fenburrim, Flurofenim, Furilazole, Bismuth oxalate Isoxadifen-ethyl) Mefenpyr-diethyl Mephenate Methotone Sodium (Naphthalic _anhydride) Oxabetrinil -2--methyl- 1, dioxolane (MG-191) 1-(oxa-4-nitro-spiro[4.5]indol-4-yl)-ethanone (AD-67) 1,6·dihydro-1 -(2-methoxyphenyl)-6-oxo-2-phenyl-5-pyrimidinecarboxylate ethyl ester _ weight ratio 1:48 to 6:1 take typical liiZl 17:1 1:6 to 168: 1 iil to 3:1 1:48 to 12:1 1:48 to 12:1

1:12 to]68:1 1:4 to 1:1 to 6: Table B2 is constructed as shown in Table B1 above. Except for the component (a), the item below the title is the following item (4). . Thus, for example, 196 201240602 In Table B2, the headings of the "Component (8)" column all describe "Compound 2" (ie, Compound 2 indicated in Index Table A), and the first row below the heading of Table B2 specifically discloses the compound. 2 mixture with grass poison. Tables B2 through B34 are structured in a similar manner. Table No. Component (a) Rotten Item B2 Compound 2 B3 Compound 3 B4 Compound 4 B5 Compound 5 B6 Compound 6 B7 Compound 7 B8 Compound 8 B9 Compound 9 B10 Compound 10 B11 Compound 11 B12 Compound 12 B13 Compound 13 B14 Compound 14 B15 Compound 15 B16 Compound 16 B17 Compound 17 B18 Compound 18 Table No. Component (a) Column Item B19 Compound 19 B20 Compound 20 B21 Compound 2] B22 Compound 22 B23 Compound 23 B24 Compound 24 B25 Compound 25 B26 Compound 26 B27 Compound 27 B28 Compound 28 B29 Compound 29 B30 Compound 30 B31 Compound 31 B32 Compound 32 B33 Compound 33 B34 Compound 34 It is noted that the composition comprises a compound of the invention (in a herbicidally effective amount), at least one selected from the group consisting of other herbicides and herbicides. An additional active 10 component of the group of agents (in an effective amount) and at least one component selected from the group consisting of surfactants, solid diluents, and liquid diluents. For better control of undesired plants (eg, due to lower usage rates such as synergistic effects, broader range of weed control or improved crop safety) or prevention of development of resistant weeds, a combination of the invention is preferred. 197 201240602 A mixture of a herbicide and a herbicide selected from the group consisting of 2,4-D, ametryne, aninocyclopyrachlor, aminopyralid, and turf Atrazine, bromacil, bromoxynil, br〇moxynil octanoate, carfentrazone-ethyl, chlorimuron-ethyl , chlorsulfuron, clopyralid, clopyralid-olamine, dicamba and its diethylene glycol ammonium salt, dimethylammonium salt, potassium salt and steel salt, °Diflufenican, dimethenamid, 10 dimethenamid-P, diuron, florasulam, flufenacet , flumetsulam, flomioxazin, fluoride Flupyrsulfuron-methyl, flupyrsulfuron-methyl-sodium's fluroxypyr, glyphosate (especially jiaphosphine isopropylammonium, jiaphos) Sodium, Jiaphosate potassium, Jiachao trimethylsulfate), hexazinone, imazamethabenz-methyl, imazaquin, imazethapyr, sulfhydryl Iodosulfuron-methyl, lactofen, lenacil, linuron, MCPA and its dimethylammonium salt, potassium and sodium salts, MCPA-iso Octyl, MCPA-thioethyl, mesosulfuron-methyl, S-metolachlor, metribuzin, metsulfuron-methyl, cigarette holder Nicosulfuron), oxyfluorfen, pendimethalin, pinoxaden, pronamide, prosulfuron, pyroxasulfone, 201240602 (pyroxasulfone), Bitroxsulam, quinclorac, rimsulfuron, shouting (saflu) Fenacil), sulfentrazone, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, triclopyr, butoxyethyl The triclopyr-butotyl and trigaster (trilopyr-triethylammonium). 10 15 20 The following test demonstrates the herbicidal effect of the compounds of the invention on specific weeds. However, the weed control provided by the compound is not limited to the plant species tested. See index table A for a description of the compound. The following abbreviations are used in the index table as follows: "Cmpd" means a compound, 吣 is methyl 'Ph is phenyl, thiophene means thiophene and c_pr means ciprofloxacin NMR spectroscopy to shift from CDC13 The base stone Xi burning ^ is described in the low field ppm of 400 MHz, unless otherwise noted; "s sound single peak, "m" means multi-peak 'rbr s" means wide single peak,: double peak, "dd" It means double peaks, "t" means three peaks, "td ^j double peaks, "dt" means double triplets and "q" means quadruple peaks. Shrinking "writes two" means "instance", and the following number means that the compound is prepared in ^. In the following index table: Example "Dioxaspiro[4.5]癸_8-yl" means

"Tetrahydro-2-methyl-carbazole _5•yl" means 199 25 201240602

"A-1A" means: Ο

ο

"Α-1Β" means: ο

15 “Α-3Α” means ο

201240602 1-(1,3-Di-heterocyclic pyridin-2-yl)propan-3-yl" means

; and 5 "2_(1,3_dioxol-2-yl)pent-5-yl" means

10 Index Table A 〇〇Compound Ν R1 , R2 R2 A mp(°C) 1 (Ex. 1) Dioxaspiro[4.5]癸-8-yl Ph A-1A 氺2 (Ex. 2) -CH2CH= NOCH3 Ph A-1A 氺3 Dioxaspiro[4.5]癸-8-yl Ph(3-F) A-1A 氺氺4 Dioxaspiro[4.5]癸-8-yl Ph(3-F) A -3A * * 5 Dioxaspiro[4.5]癸-8-yl Ph(3-Me) A-1A Benzo 6 Dioxaspiro[4.5]癸-8-yl Ph(3-Me) A-3A氺氺7 Dioxaspiro[4.5]癸-8-yl 5-C1-3-pyridyl A-1A Ben 8 Dioxaspiro[4.5]癸-8-yl 3-d ratio bite A-1A氺9 dioxaspiro[4.5]癸-8-yl Ph A-3A 氺氺10 dioxaspiro[4.5]癸-8-yl c-Pr A-1A 氺氺11 dioxaspiro[4.5]癸-8-based c-Pr A-3A 氺12 dioxaspiro[4.5]癸-8-yl Ph(3-OMe) A-1A 本氺201240602 13 Dioxaspiro[4.5]癸-8-yl Ph(3-OMe) A-3A Ben 氺14 Dioxaspiro[4.5]癸-8-yl 2-thienyl A-1A * * 15 Dioxaspiro[4.5]癸-8-yl 2- porphin Base A-3A Ben16 Dioxaspiro[4.5]dec-8-yl 2-thienyl A-1B**17 Dioxaspiro[4.5]癸-8-yl 3-supplemental A-1A 18 II Oxaspiro[4.5]dec-8-yl 3-thienyl A-1A 19 tetrahydro-2-indenyl-indole. Sodium-5-yl Ph A-1A 20 1-morpholinyl Ph A-1A 21 1-morpholinyl Ph A-3A 22 (Ex. 3) 1-morpholinyl c-Pr A-1A 氺氺23 (Ex. 4) 1-morpholinyl c-Pr A-3A 5 24 1-morpholinyl Ph(3-F) A-1A *本25 1-morpholinyl Ph(3-F) A-3A * * 26 1-(3-dioxol-2-yl)propan-3-yl c-Pr A-1A * * 27 1-(3-dioxol-2-yl)propene- 3-based Ph A-1A * * 28 1-(3-dioxol-2-yl)propan-3-yl Ph A-3A The present 29 1-(3-dioxolane-2 -yl)prop-3-yl c-Pr A-3A 氺30 1-(3-dioxol-2-yl)propan-3-yl 3-thienyl A-1A * * 31 1- 0,3-dioxol-2-yl)propan-3-yl 3-thienyl A-1B 32 1-(1,3-dioxolan-2-yl)propane-3 -yl 3-g phenyl A-3A 33 2-(1,3-dioxolan-2-yl)pent-5-yl Ph A-3A * * 34 2-(1,3-two Oxol-2-yl)pent-5-yl Ph A-1A *氺* See Synthesis Examples for 1H NMR Data. See Index Table E for 咕 NMR Data

Index table B

Compound _____A' mp (°〇7Q dioxaspiro[4.5]癸-8-yl 5-C1-3-pyridyl Α·-1 ** 201240602 8Q Dioxaspiro[4.5]癸-8-yl 3 -° ratio bite A' 19Q tetrazo-2-indolyl-α bow|β sit-5-yl Ph A, 22Q 1-morpholinyl c-Pr A, 24Q 1-morpholinyl Ph (3-F A, 26Q 1-(3-dioxanthracen-2-yl)propan-3-yl c-Pr A, see Synthesis Examples for 1H NMR data.

Index table C

Compound R1 R2 mp (°C) 1R (Ex. 1) Dioxaspiro[4.5]癸-8-yl Ph This 2R (Ex. 2) -CH2CH=NOCH3 Ph Ben 7R Dioxaspiro[4.5]癸- 8-based 5-C1-3-pyridine basic 8R dioxaspiro[4.5]癸-8-yl 3-° ratio bite base * 1 HR dioxaspiro[4.5]癸-8-yl c-Pr 氺The 14R dioxaspiro[4.5]dec-8-yl 2-thienyl sulfonyl 17R dioxaspiro[4.5]dec-8-yl 3-thienyl 19R tetrazir-2-yl-yl-anthracene -5 -yl Ph ** 22R 1-morpholinyl c-Pr water 25R 1-morpholinyl Ph(3-F) Ben 26R 1 bis(3-di-heterocyclic oxime-2_yl)- 3_based c-Pr, 3 OR 1-(3-dioxol-2-yl)propan-3-yl-3-thienylindole 1 33R 2·(3-dioxanthene-2 -基)-戍_5·基P 氺本10 1

See Synthesis Examples for 1H NMR data. 2 See index table E for 1H 2 NMR data 201240602

Index Table D ο ο Compound R1 R2 R23 mp (°C) IS (Ex. 1) Dioxaspiro[4.5]癸-8-yl Ph Me ♦ 2S (Ex. 2) -CH2CH=NOCH3 Ph Me * 7S II Oxyspiro[4.5]癸-8-yl 5-C1-3-pyridyl Me 氺8S Dioxaspiro[4.5]癸-8-yl 3·° ratio biting base Me 氺氺11S dioxaspiro[ 4.5] 癸-8-yl c-Pr Me 19S tetrahydro-2-indenyl-0. Sodium-5-based Ph Me woody 22S 1-morpholinyl c-Pr Me 25S 1-morpholinyl Ph(3-F) Me * * 26S 1-(3-dioxol-2-yl )prop-3-yl c-Pr Me * * 30S 1-(3_dioxolan-2-yl)propan-3-yl 3-thinyl Me 氺

Κ ^R2 5 * Please refer to the synthesis example to obtain 1H NMR data.

Index table E

Cmpd.咕NMR data or MS data '_ 3 469 4 495 5 465 6 491 δ 16.42 (s, 1H), 8.68 (d, 1H), 8.58 (s, 1H), 7.86 (s, 1H), 7.79 (s , 1H), 7 3.85-3.82 (m, 5H), 2.96-2.81 (m, 2H), 2.66 (t, 2H), 2.42 (t, 2H), 2.03-2.00 (m, 2H), 1.76-1.59 ( m, 4H), 1.28 (td, 2H) δ 16.46 (br s, 1H), 8.72 (br s, 2H), 7.89 (s, 1H), 7.77 (d, 1H), 7.43-7.34 (m, 1H) , 3.92-3.67 (m, 5H), 2.89 (d, 2H), 2.65 (br s, 2H), 2.54 (t, 2H), 2.43 (br s, 2H), 2.05-1.86 (m, 2H), 1.76 -1.53 (m, 2H), 1.29-1.18 (m, 2H) 9 477 10 415 11 441 204 201240602 12 481 13 507 14 457 (AP+) 15 483 (AP+) 16 485 (AP+) 17 457 (AP+) 18 483 (AP+) δ 16.54 (br s,1H), 8.05 (s,1H), 7.49 (m,5H),7.01 (s,1H), 4.36 (m, 19 1H), 3.77 (s, 3H), 3.70 ( m, 1H), 3.10 (m, 1H), 2.85 (dd, 1H), 2.73 (m, 2H), 2.64 (dd, 1H), 2.50 (m, 2H), 2.42 (m, 1H), 2.07 (m , 3H) 20 396 21 422 22 360 ESI+ 23 386 ESI+ 24 414 25 440 26 375 27 413 ESI+ 28 437 ESI+ 29 401 30 417 31 445 32 443 33 465 34 439 δ 8.72 (s, 1H), 8.63-S.48 (m, 2H), 7.78 (s, 1H), 5.93 (s, 1H), 3.99-3.7 1 7Q (m, 5H), 3.02-2.88 (m, 2H), 2.61 (t, 2H), 2.38 (t, 2H), 2.05 (m, 2H), 1.74 (d, 2H), 1.62 (d, 2H) ), 1.31 (td, 2H) δ 8.77 (d, 1H), 8.71 ( s, 1H), 8.61 (s, 1H), 7.77 (d, 1H), 7.48-7.38 (m, n 1H), 5.93 (s , 1H), 3.99-3.76 (m, 5H), 3.08-2.84 (m, 2H), 2.61 (t, 2H), ^ 2.42-2.28 (m, 2H), 2.10-1.97 (m, 2H), 1.72 ( d, 2H), 1.66-1.57 (m, 2H), 1.33-1.20 (m, 2H) δ 8.73 (s, 1H), 7.52 (m, 5H), 7.02 (s, 1H), 6.02 (s, 1H) , 4.42 (m, 1H), 19Q 3.82 (m, 1H), 3.78 (s, 3H), 3.22 (m, 1H), 2.88 (m, 1H), 2.69 (m, 2H), 2.61 (m, 1H) , 2.45 (s, 3H), 2.12 (m, 2H), 2.07 (m, 1H) 22Q 360 ESI + 26Q 375 δ 8.87 (s, 1H), 8.75 (d, 1H), 8.59 (d, 1H), 7.83 (t, 1H), 4.07-3.98 (m, 7R 1H), 3.94-3.90 (m, 2H), 3.88-3.82 (m, 2H), 3.06-2.94 (m, 2H), 1.79 (d, 2H), 1.68 (d, 2H), 1.35 (td, 2H) 205 201240602

8R 11R 14R 17R 19R 22R 25R 26R 3 OR 33R 7S 8S 11S 19S 22S 25S 26S 30S 34S 323 345 5 8.70 δ 8.88 (s,1H),8,0 (s,1H),8.74 (s,1H),7.81 ( d im 7 47 m, 4.11-3.99 (m, 1H), 3.96-3.78 (m, 4H), 3.〇8-2 Q〇vl om i \ λ (m, 4H), 1.31 (t, 2H) (m, 2H), 1.81-1.62 321 377 377 δ 8.98 (s, 1H), 7.54 (m, 5H), 7.05 (s, 1H), 4.56 3.78 (m, 1H), 3.18 (m, 1H), 2.93 (m, 1H), 2.67 2.09 (m, 1H) ih), 2.48 (m, 1H), 266 ESI+ 320 (500 MHz) δ 13.09 (br s,1H), 8.76 (S, 1H), Μ 4.01 ( m, 2H), 3.89 (m, 2H), 2.23 (m, 2H), 2.15 ^ ^ * 1.30 (m, 2H) 1H), 1.44 (m, 2H), (s, 1H), 8.58-8.49 (m , 2H), 7.77 (S) lHx , Q8 , 70 , , nu, 3.01 (d, 2H), 1.73 (d, 2H), 1.29 (br s, 2H) )&gt; 3.98-3.72 (m, 10H), δ 8.75 (dd, 1H), 8.70 (d, 1H), 8.53 (S, 1H), 7 1H), 3.88-3.78 (m, 8H), 3.07-2.95 (m, 2H), l 7l ^ 1.25 (td , 2H) (d, 2H), 1.59 (d, 2H), 335 δ 8.66 (s, 1H), 7.49 (m, 5H), 7.01 (s, 1H), 4.39 ( 3.80 (m, 1H), 3.77 ( s, 3H), 3.23 (m, 1H), 2.87 m * 2.44 (m, 1H), 2.04 (m, 1H) Vms 1H), 2.59 (dd , 1H), 280 ESI+ 334 295 295 359 All M.S. data are expressed as AP+ unless otherwise stated.

Test A will be selected from the group consisting of valerian cms-ga//, ), large (Lg) crabgrass (D/gziana Siawgwzmz/b), and foxtail (giant 201240602 foxtail) («Setoziz /Mer&quot;), Seeds of plant species of morning glory (morning 〇ry spp.), religios reiro/Zexwj), velvetleaf (Abutilon theophrasti), wheat (7H&quot;cww aeWzvwm) and corn (Ζβ0 mays) In the blend of soil 5 and sand, and pre-emergence treatment with a directional soil spray, the spray uses a test chemistry formulated in a non-phytotoxic solvent mixture, the mixture comprising a surfactant. At the same time, these species were also subjected to post-emergence treatment with test compounds which were formulated in the same manner. 10 Post-emergence treatment is carried out using plants with a height ranging from 2 to 10 cm and in the leaf to bilobal stage. The treated plants were compared with the untreated control group for about 10 days in the greenhouse. After treatment, all treated plants were compared with the untreated control group and the degree of damage was visually evaluated. The plant response ratings summarized in Table A are based on a scale of 〇 to 1〇〇, where 〇 15 is ineffective and is completely controlled. The reaction shown as a dash (-) means no test results. Table A Compounds Table A Compound 500 g ai/ha 1 125 g ai/ha 29 30 31 32 33 34 Post-emergence and post-emergence Valerian 100 Valerian 80 90 70 100 90 80 Corn 80 Corn 20 30 40 50 10 0 100 Great Horsegrass 80 90 90 100 80 90 French foxtail 100 French foxtail 70 80 80 100 70 50 Morning Glory 100 Morning Glory 100 100 100 100 90 20 Anti-branches 100 Anti-branches 100 100 90 100 100 90 Ramie 100 Ramie 100 100 100 100 100 100 Wheat 20 Wheat 0 20 30 10 0 0 207 201240602 Table A Compound 125 g ai/ha 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Post-emergence valerian 100 60 90 100 100 100 100 90 90 90 100 90 70 100 Corn 40 10 70 40 60 30 40 20 10 20 20 30 0 20 Large horse grass 100 80 90 90 90 90 100 90 90 90 90 90 50 100 French foxtail 100 30 100 100 90 90 100 90 90 80 90 100 100 100 Morning Glory 100 50 100 90 100 100 100 100 90 90 100 100 100 100 Anti-branches 100 90 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 90 100 100 100 100 100 Wheat 10 0 0 0 20 20 0 10 0 0 20 0 0 20 Table A Compound 125 g ai/ha 15 16 17 18 19 20 21 22 23 24 25 26 27 28 Post-emergence valerian 100 50 90 100 100 90 100 70 50 90 100 90 60 100 Corn 30 20 30 40 10 20 50 0 0 50 50 50 20 30 Great horse grass 100 90 90 80 100 90 90 90 90 80 90 90 90 90 French foxtail 100 90 100 100 90 90 100 60 40 - - 70 80 100 Morning glory 100 100 100 100 90 100 90 90 90 100 100 100 80 100 Inverse branches 100 100 100 100 100 100 100 90 90 90 100 100 100 100 100 Ramie 100 100 100 100 100 100 100 - - 100 100 100 100 100 Wheat 40 0 10 20 20 0 10 - - 10 0 0 0 0 Table A Compound 31 g ai/ha 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Post-emergence valerian 10 90 90 100 100 100 30 20 80 90 20 10 30 70 Corn 0 30 20 10 10 10 0 0 10 10 20 0 10 10 Great horse grass 50 90 80 80 70 80 80 70 70 70 50 20 90 80 French foxtail 10 100 90 90 90 90 70 70 60 70 100 50 100 100 Morning glory 10 90 90 80 100 90 100 80 90 100 80 70 100 100 Inverse branches 60 100 100 100 90 100 100 90 90 100 100 80 100 100 tube hemp 100 100 100 100 100 100 100 70 100 100 100 80 100 100 Wheat 0 0 0 0 0 0 0 0 0 0 0 0 0 208 201240602 Table A Compound 31 g ai/ha 16 17 18 19 20 21 22 23 24 25 26 27 28 29 萌萌稗20 60 90 80 70 90 30 10 80 90 70 20 30 30 Corn 10 20 30 0 10 10 0 0 0 0 0 0 30 0 大马唐草70 70 50 60 50 70 70 50 70 70 70 90 70 50 foxtail sage 80 90 90 80 70 90 10 0 - - 30 60 90 40 Morning Glory 100 100 100 90 90 90 90 70 100 100 100 70 90 100 Anti-branches 100 90 80 100 100 80 80 50 100 100 90 100 90 80 Hemp 100 100 80 100 90 100 - - 90 90 100 100 100 100 Wheat 0 0 0 0 0 0 - - 0 0 0 0 0 Table A Compounds Table A Compound 31 g ai/ha 30 31 32 33 34 500 g ί ai/ha 1 After the germination of the geranium 60 20 90 80 60 稗草 90 corn 10 20 20 0 0 corn 0 马马唐草70 70 60 60 70 大马唐草100 法氏狗草70 70 90 40 30 French foxtail 100 Morning Glory 100 100 100 70 10 Morning vine 90 Anti-branches 90 80 100 90 70反 苋 100 筒 100 100 100 100 90 100 麻麻 100 Wheat 0 0 0 0 0 Wheat 10 Table A Compound 125 g ai/ha 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Pre-emergence 60 10 70 50 50 60 90 50 40 90 90 20 10 60 Corn 0 0 0 0 0 0 0 0 0 0 0 0 0 Big horse grass 90 70 60 50 60 70 ]00 70 70 90 80 70 70 100 Phnom Penh 60 0 80 40 80 60 100 50 60 60 70 90 60 90 Morning Glory 60 0 40 - 50 60 80 10 20 70 70 20 0 90 Anti-branches 100 90 90 100 90 80 100 90 100 60 30 90 90 100 Ramie 80 80 80 60 60 50 60 30 70 70 50 80 40 90 Wheat 0 0 0 0 0 0 0 0 0 0 0 10 0 209 201240602 Table A 125 g ai/ha 15 16 17 18 Before the germination 0 10 50 100 Corn 0 0 0 0 大马唐草30 40 50 80 法氏狗草70 20 50 70 Morning Glory 70 30 10 20 反 苋 90 80 80 90 Hemp 50 50 50 70 Wheat 0 0 0 - Table A Compound 125 g ai/ha 29 30 31 32 Pre-emergence valerian 50 70 40 50 Corn 0 0 0 0 Large horse grass 60 90 80 30 French foxtail 10 20 50 20 Morning glory 10 0 10 10 Anti-branches 9 0 90 100 90 Cannabis 70 90 70 70 Wheat 0 0 0 - Table A 31 g ai/ha 2 3 4 5 Before the germination 0 0 10 0 Corn 0 0 0 0 Large horse grass 10 10 10 10 French foxtail 0 40 10 20 Morning Glory 0 0 20 0 Anti-branches 0 60 40 50 Hemp 0 50 40 50 Wheat 0 0 0 0 Compound 20 21 22 23 24 25 26 27 28 70 50 70 80 80 70 70 50 40 0 0 0 0 0 20 0 0 0 70 30 90 100 90 90 80 60 60 50 30 50 30 60 20 20 30 40 10 30 80 80 70 80 70 10 10 70 80 100 100 100 90 90 90 90 60 40 90 90 100 80 90 80 70 0 0 0 10 0 0 0 0 0 Table A Compound 34 31 g ai/ha 30 31 32 33 34 Pre-emergence 30 Valerian 10 0 10 0 0 0 Corn 0 0 0 0 0 70 Big horse Tang grass 40 50 10 10 10 0 Lawn's foxtail 0 10 0 0 0 0 Morning Glory 0 0 0 0 0 60 Anti-branches 50 50 70 - 10 70 4 Ma 70 50 50 10 30 0 Wheat 0 0 0 0 0 Compound 7 8 9 10 11 12 13 14 15 10 0 10 20 40 0 0 10 0 0 0 0 0 0 0 0 0 0 70 60 40 40 50 60 10 90 30 80 30 20 40 40 60 10 50 10 20 0 0 0 10 0 0 20 10 90 40 30 30 0 90 20 90 40 50 0 40 60 10 20 0 60 20 0 0 0 0 0 0 0 0 0 210 201240602 Table A 31 g ai/ha 16 17 18 Pre-emergence valerian 0 10 10 Corn 0 0 0 Large horse grass 10 20 30 French foxtail 0 20 0 Morning glory 0 0 0苋10 0 60 ramie 20 40 20 wheat 0 0 0 compound 19 20 21 22 23 24 25 26 27 28 29 0 10 0 40 10 20 0 10 10 10 0 0 0 0 0 0 0 0 0 0 0 10 10 0 50 60 30 20 40 20 10 10 - 0 0 0 0 10 0 0 10 0 0 0 0 - 50 10 50 10 0 30 0 0 40 30 10 80 50 70 70 20 40 40 10 30 20 10 70 50 40 10 80 60 50 10 0 0 0 0 0 0 0 0 0 0 0

Test B will be selected from blackgrass {Alopecurus mjoswro We*s), downy bromegrass (Bromws 5 ieciorww), green foxtail, Italian ryegrass (Zo// Wm mw/iz//orw7«), winter wheat (7W&quot;cwm 0 aga", wild oatmeal/plus (10)), galium (catchweed bedstraw, G^f/zww, Bermuda grass i/ &lt;2C*(y/o«), Suriname grass i〇decumbens), cocklebur (common cocklebur,

Jianihitim strumarium), Zea mays, Digitaria sanguinalis, woolly cupgrass (Eriochha villosa), Setaria faberii, goosegrass (five /ew illusion&gt;ze z«i//c&lt;3), Johnsongrass is (Sorghum halepense), $ (kochio) (Kochia scoparia), lam (lambsquarters) (Chenopodium a!bum), morning glory ^ (Ipomoea coccinea) ' ^ (nightshade) (eastern black nightshade, Wammz 〆 所), sedge (yellow 211 201240602 nutsedge) {Cyperus esculentus), anti-twig (nightshade) (Amaranthus retroflexus), grazing ) (common ragweed, Ambrosia elatior) ' 3. {Glycine max) ' ( /3⁄4 # )

To the blend of Z/e/ί(10), Russian 蓟 (&amp;/奶/ak//) and ramie 5 (Abutilon theophrasti) JiH sand, and prepared in a mixture of non-phytotoxic solvents The chemical is pre-emerged and the mixture comprises a surfactant. At the same time, plants selected from these crops and weed species, as well as Hordeum \m丨gare, gold silk, and cmarygrass (Phalaris) , chickweed (common chickweed, //ark, chickweed/) and deadnettle (henbit deadnettle, Low/ww planted in Reddi-Earth® containing medium (Scotts Company, 14111) 15 Scottslawn Road, Marysville, Ohio 43041), the planting medium contains peat moss 3§111111111 mouth 6&amp;1|11055), warp, wetting agent and starting nutrients' and with some test chemicals ( Prepared in the same manner) for post-emergence treatment. Plants with a height range of 2 to 18 cm (1 to 4 leaf stage) are used for post-emergence treatment. 20 The plant species in the modified paddy field test is from rice. &quot;(10)), Umbrella (umbrel) La sedge), a different drug t (duck salad) (Ι^βηιηώβρα Iimosa) and 稗草 (barnyardgrass^fc/^ijc/z/i^cms-^///), which has grown into a 2-leaf stage For testing. When processing, immerse the test tank to a high level! 5 on the soil surface 3 cm. The treatment is applied directly to the field water and maintained at this water depth during the test. 212 201240602 Treated plant and control group The plants were maintained in the greenhouse for 13 to 15 days, after which all species were compared and visually evaluated. The plant response ratings summarized in Table B were based on a scale of 0 to 100, with 0 being ineffective and 100 being complete. The reaction shown as a dash (-) means no test results. Table B Compound 250 g ai/ha Immersion 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Valerian 80 0 85 85 80 65 - 40 40 75 80 50 40 65 Heterophylla 80 0 95 95 80 85 90 85 95 90 90 85 70 85 Rice 80 0 85 15 65 30 15 40 20 50 50 40 35 80 Round umbrella 95 0 90 75 75 80 85 100 95 75 90 85 80 80 Table B Compound 250 g ai/ha Immersion 15 16 17 18 19 20 21 22 23 24 25 26 27 28 40 30 20 0 60 55 60 80 75 75 0 .60 0 0 Heterophyllum 80 75 70 50 95 60 80 95 80 100 0 85 75 50 Rice 0 60 0 10 20 45 0 80 75 90 0 25 0 0 85 70 75 65 85 30 30 90 85 100 30 80 75 75 Table B Compound 250 g ai/ha Immersion 29 30 31 32 33 34 Valerian 0 20 30 15 0 30 Isolate 60 60 70 0 40 90 Rice 0 10 20 15 0 0 omnivorous grass 75 100 80 30 30 90 Table B Compound 125 g ai/ha Immersion 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Herborist 60 0 30 0 0 20 - 0 0 65 65 15 15 40 213 201240602 Heterophylla 75 0 65 30 80 85 75 75 85 85 80 80 40 75 Rice 20 0 0 10 20 0 10 0 0 15 0 40 20 60 Umbrella 85 0 80 30 60 65 80 80 70 75 80 80 75 75

Table B 125 g ai/ha Immersion 15 16 17 18 19 Valerian 0 0 15 0 15 Heterophylla 75 70 70 40 75 Rice 0 0 0 0 0 Umbrella 80 30 70 60 80 Compound 20 21 22 23 24 25 26 27 28 40 0 75 60 60 0 30 0 0 40 0 85 80 75 0 65 70 50 25 0 75 60 35 0 15 0 0 30 0 90 75 75 0 75 40 50 Compound

Table B 125 g ai/ha Immersion 29 30 稗草 0 0 异药花 0 0 Rice 0 0 车草草 0 80 31 32 33 34 0 0 0 10 0 0 0 0 0 0 0 30 0 0 70

Table B 62 g ai/ha Immersion 1 2 3 4 5 Valerian 0 0 0 0 0 Heterophyllum 70 0 40 0 45 Rice 0 0 0 0 0 Round Umbrella 85 0 80 0 50 Compound 6 7 8 9 10 11 12 13 14 0 _ 0 0 50 0 0 0 20 75 50 50 80 80 75 60 20 75 0 0 0 0 10 0 20 0 20 30 70 60 0 60 70 70 50 75

Table B 62 g ai/ha Immersion 15 16 17 18 19 Valerian 0 0 0 0 0 Heterophylla 75 30 50 0 60 Rice 0 0 0 0 0 Round Umbrella 70 0 50 0 70 Compound 20 21 22 23 24 25 26 27 28 0 0 55 40 20 0 0 0 0 0 0 75 50 50 0 30 20 0 10 0 45 25 20 0 10 0 0 0 0 80 50 30 0 60 20 30 5 201240602 Table B Compound 62 g ai/ha 29 30 31 32 33 34 Immersion 稗 0 0 0 0 0 0 异药花 0 0 0 0 0 0 稻 0 0 0 0 0 0 轮草草 0 30 0 0 0 70 Table B Compound 31 g ai/ha 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Immersion 稗草 0 0 0 0 0 0 -0 0 0 0 0 0 20 Ivory flower 70 0 0 0 0 0 0 0 0 80 50 50 0 70 Rice 0 0 0 0 0 0 0 0 0 0 0 10 0 20 omnivorous straw 70 0 40 0 0 0 0 0 0 40 0 0 0 45 Table B Compound 31 g ai/ha Immersion 15 16 17 18 19 20 21 22 23 24 25 26 27 28 稗草0 0 0 0 0 0 0 30 0 20 0 0 0 0 异药花65 30 0 0 40 0 0 45 0 40 0 20 0 0 Rice 0 0 0 0 0 0 0 20 20 10 0 0 0 0 65 0 0 0 60 0 0 0 0 0 0 20 0 0 Table B Compound 31 g ai/ha Immersion 29 30 31 32 33 34 稗草0 0 0 0 0 0 异药花0 0 0 0 0 - Rice 0 0 0 0 0 0 轮草草0 0 0 0 0 - Table B Compound 250 g ai/ha After the sprout 1 3 4 5 6 8 12 14 15 16 18 19 20 21 Barley 80 50 5 10 5 50 15 50 5 35 5 80 5 0 Bermuda grass 85 90 85 85 65 98 65 90 95 90 90 95 95 90 215 201240602 Black grass 85 85 55 40 5 70 80 15 60 5 70 80 55 10 Buttercup - 5 5 35 35 90 35 70 70 10 40 95 - 15 Canary grass 100 85 85 85 40 100 90 55 60 90 70 100 40 10 Traditional 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Xanthium - 100 98 98 100 100 100 100 100 100 100 - 100 100 Corn 80 85 80 90 65 80 85 75 60 50 60 90 75 80 Horse Grass, Large 98 90 90 85 95 98 80 100 98 98 75 100 95 95 Ulivia 98 90 95 90 95 98 95 100 100 100 100 98 100 95 Komgrass - 100 100 100 100 100 100 100 100 100 100 100 100 100 Phnom Penh 100 90 95 95 95 98 95 98 98 85 98 95 98 95 Valerian 95 100 100 95 90 90 90 98 60 70 98 100 95 100 Eight Grasses - 95 95 60 - 85 85 95 85 90 80 95 70 90 Goosegrass 95 85 90 - 85 98 90 95 98 85 95 90 98 85 Johnson grass 95 95 98 95 98 100 90 98 100 85 100 - 85 98 Kochia 90 90 75 15 65 100 65 100 80 75 98 100 100 100 藜100 100 100 100 100 100 100 100 100 100 100 100 100 - Morning Glory 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Papyrus 80 85 80 85 45 85 85 85 75 65 65 85 80 80 Wild oats 90 95 85 60 35 98 90 95 55 85 70 95 20 5 Anti-branches 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Ragweed 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Italian ryegrass 45 35 40 5 5 35 20 10 10 20 20 95 5 5 Soybean 100 98 98 98 98 100 98 100 100 100 100 100 95 98 Suriname grass 90 85 95 75 85 98 85 95 98 85 98 100 85 85 Cannula 100 95 85 85 80 98 100 100 95 90 90 100 100 95 Wheat 35 0 0 5 5 40 5 20 30 0 30 95 20 20 Wind-cut grass 95 85 90 45 55 98 65 90 80 65 85 100 80 85 Table B Compound 250 g ai/ha After the attack 22 23 24 25 26 28 29 30 31 32 Barley 80 55 35 30 10 35 35 20 50 5 Bermuda grass 98 95 98 98 95 100 95 95 85 95 Black grass 25 30 80 40 30 65 85 50 35 40 毛白草草 35 80 80 10 10 45 35 45 40 55 Canary grass 80 95 90 60 50 40 50 50 80 45 Traditional 100 100 100 100 100 100 100 100 100 100 Xanthium 100 98 100 100 100 - - 100 98 98 216 201240602 Maize 80 90 85 100 35 85 80 55 75 65 Da Ma Tang Cao 98 100 95 98 90 100 98 95 85 98 Wu Li Cup Grass 90 98 98 100 80 100 98 85 80 98 Bao Gai Grass 100 100 100 100 100 100 100 100 100 100 foxtail sage 90 95 95 95 100 100 95 90 90 98 莠草90 98 100 100 70 100 95 95 70 95 八仙草95 98 95 90 90 85 90 95 95 90 牛草草95 98 98 95 85 100 95 75 85 95 Johnson grass 80 100 100 100 75 98 95 75 80 100 Kochia 98 100 98 98 95 100 100 100 55 95 藜100 100 98 100 100 100 100 100 98 100 Morning glory 100 100 100 100 100 100 100 100 98 100 sedges 90 90 90 55 85 45 85 80 60 100 wild oats 60 95 85 45 15 50 40 50 45 50 prune 98 98 100 100 100 100 100 100 98 100 ragweed 100 100 100 100 100 100 100 100 95 100 Italian ryegrass 30 35 5 5 40 10 30 45 30 30 Soybeans 98 98 95 98 98 100 100 100 98 98 Suriname Grass 85 95 95 98 70 95 80 85 85 95 Tubes 98 98 100 98 100 100 100 100 95 98 Wheat 90 90 30 35 25 50 40 40 40 60 Wind shears Grass 90 80 100 80 55 80 70 80 60 80 Table B Compound 125 g ai/ha 1 3 4 5 6 8 10 12 14 15 16 18 19 20 Post-emergence barley 70 30 5 5 0 15 0 5 5 0 20 0 55 5 Bermuda grass 85 85 80 80 50 98 90 35 75 85 85 85 95 95 Lane 85 85 40 35 5 35 10 70 15 15 0 20 75 40 Mao Bailu - 0 5 0 0 90 10 20 50 45 10 20 90 - Canary grass 100 80 85 65 35 65 20 70 30 60 60 50 100 40 繁繁 100 100 100 98 100 100 100 100 100 100 100 100 100 98 Xanthium 100 100 98 95 100 100 100 100 100 100 100 100 - 100 Maize 75 85 80 80 65 65 65 80 75 25 35 45 85 70 Large horse grass 95 90 90 85 90 95 95 60 98 85 98 70 98 85 Uli cup grass 90 90 95 85 90 98 65 95 98 100 98 98 98 98盖盖草-100 100 100 100 100 100 100 100 100 100 100 85 100 foxtail foxtail 98 85 90 90 90 98 85 90 95 95 85 95 95 95 217 20124060 2 莠草95 95 95 八仙草-85 90 牛草草 95 85 85 Johnson grass 90 95, 98 地肤85 65 60 藜100 100 100 Morning glory 100 100 100 sedge 75 80 65 Wild oats 90 90 80 Twigs 100 100 100 ragweed 100 100 100 Italian ryegrass 45 35 35 Soybeans 100 95 98 Suriname grass 85 80 90 Casing 100 95 75 Wheat 30 0 0 Wind-cut grass 85 75 80 Table B 125 g ai/ha 21 22 Post-emergence barley 0 60 Bermuda grass 90 98 Black grass 10 25 Hairy white grass 5 35 Canary grass 5 70 Traditional 98 100 Xanthium 100 95 Corn 80 80 Large horse grass 85 98 Uli cup grass 85 85 100 100 French foxtail 95 85 莠草100 85 八仙草85 90 牛筋草80 90 强生草95 70 地肤90 95 90 90 70 90 85 55 70 90 98 90 80 70 90 60 85 85 90 75 90 70 80 95 85 85 95 90 85 85 90 90 90 100 65 85 95 98 80 98 - 75 10 98 100 45 98 75 65 65 100 100 98 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 25 80 90 80 85 60 40 60 65 80 35 95 15 70 90 50 50 65 95 20 100 100 100 100 100 100 100 10 0 100 98 100 100 100 100 100 100 100 100 100 98 0 30 5 20 10 10 20 5 70 5 98 100 100 98 100 100 100 100 100 95 80 95 50 85 95 95 80 90 100 80 75 80 85 95 100 80 80 80 100 95 5 30 5 0 15 5 0 0 90 5 30 95 60 65 65 75 60 65 100 75 24 Compound 25 26 28 29 30 31 32 35 15 5 15 35 5 35 0 98 98 90 100 95 90 85 90 80 30 10 50 70 45 30 40 50 10 5 40 10 35 30 35 75 45 45 15 45 35 55 45 100 98 100 98 100 100 100 100 98 100 - - - 100 95 95 85 95 20 75 70 50 65 45 95 98 85 100 98 90 85 85 98 100 75 100 90 75 70 95 100 100 98 100 - 100 85 100 95 95 100 100 95 80 85 95 98 100 40 90 90 85 70 90 85 90 85 85 90 85 90 90 95 95 75 100 90 65 80 85 98 100 55 75 75 70 70 95 95 95 100 100 100 80 95 95 218 201240602 藜- 100 Morning Glory 100 100 Oil Sedge 65 90 Wild Oats 5 60 Anti-branches 95 1 98 Ragweed 100 100 Italian ryegrass 0 30 Soybean 98 95 Suriname Grass 80 80 Castor 80 1 98 Wheat 10 1 90 Wind Cut Grass 45 60 Table B 62 g ai/ha 1 3 4 Post-emergence Barley 50 5 0 Bermuda Grass 85 60 75 Black Grass 60 70 30 White Dew 55 0 5 Canary Grass 95 80 75 Traditional 100 100 100 Xanthium - 100 98 Corn 75 70 80 Large Horse Grass 95 80 85 Uli Cup 85 85 90 60 95 100 foxtail sage 95 85 85 valerian 75 90 95 october grass 90 60 90 tendon grass 85 75 80 strong grass 85 85 95 terracotta 75 25 50 藜100 100 100 morning glory 100 100 100 sedge 75 80 50 Wild oats 85 85 60 Anti-branches 100 100 100 98 100 100 100 100 100 98 100 100 100 95 100 100 100 98 100 90 45 80 20 70 70 40 95 60 40 10 45 30 45 45 45 100 98 100 100 100 100 95 100 100 100 100 100 100 100 95 100 5 5 30 10 15 30 20 10 90 98 90 100 100 98 98 98 95 98 65 95 75 85 75 85 90 95 100 100 100 100 95 98 15 35 0 35 35 40 35 40 98 80 50 10 50 55 60 60 Compound 6 7 8 10 11 12 14 15 16 17 0 35 5 0 0 0 0 0 0 0 45 85 95 85 80 5 75 75 80 75 5 70 30 5 55 65 10 5 0 20 0 - 60 5 30 10 40 45 5 15 35 80 55 15 35 60 20 45 40 30 100 100 100 100 100 100 100 100 100 100 95 - 100 98 100 100 95 100 98 100 45 9 0 10 20 20 65 35 25 10 60 75 100 95 85 85 60 90 75 90 80 85 100 90 60 85 85 98 90 95 98 100 85 100 100 100 100 100 100 100 100 85 98 90 80 90 85 85 90 80 85 85 100 60 50 85 50 80 50 50 80 55 85 50 70 85 60 85 60 50 80 65 100 75 85 80 75 75 80 85 45 90 100 90 25 85 60 80 98 65 70 5 100 75 95 70 10 75 25 20 98 98 100 100 100 100 100 100 100 100 100 100 98 100 100 100 100 95 100 100 100 25 85 75 85 75 80 80 50 25 90 30 90 85 5 20 60 90 50 50 60 100 100 98 100 100 100 100 100 100 100 219 201240602 猪草100 100 100 Italian ryegrass 40 25 30 Soy 100 95 98 Suriname grass 85 75 90 tube stalk 95 85 70 Wheat 20 0 0 Wind cut grass 70 45 60 Table Β 62 g ai/ha 18 19 20 Post-emergence barley 0 35 0 Bermuda grass 70 95 90 Black grass 5 65 40 White dew 5 90 - Canary grass 40 95 35 Traditional 100 100 98 Xanthium 100 - 100 Corn 35 85 25 Large horse grass 65 95 85 Uli Cup Grass 98 95 95 baocai 100 70 100 foxtail sage 85 95 95 sedge 50 95 85 october 65 80 - tendon grass 70 85 85 Grass 85 - 75 Kochia 65 100 98 藜100 100 98 Morning Glory 100 100 100 Papyrus 55 65 75 Wild Oats 45 80 10 Anti-branches 100 100 98 Rag 100 100 98 Italian Ryegrass 0 70 0 Soybeans 100 98 85 Suriname grass 85 100 80 ramie 75 100 90 100 100 100 100 100 100 100 100 75 100 0 20 10 0 50 10 5 5 15 0 98 100 100 98 98 98 100 98 100 100 75 100 80 35 40 75 75 80 75 80 70 95 75 85 65 90 90 80 75 90 5 30 25 0 35 0 5 0 0 0 5 60 70 25 60 50 55 55 40 50 22 23 Compound 24 25 26 28 29 30 31 32 35 10 20 5 0 5 15 0 10 0 95 95 95 95 80 100 95 90 70 90 20 10 30 15 5 40 50 35 10 30 30 15 40 5 5 30 10 5 15 10 50 45 60 30 10 10 25 35 30 20 98 95 98 98 98 98 100 100 100 100 90 - 70 98 - - - 100 85 95 65 20 65 95 15 55 65 25 35 25 98 98 90 95 75 80 95 80 75 75 85 95 90 98 70 95 85 45 65 95 90 80 98 100 98 100 90 70 75 100 85 90 80 95 100 85 90 75 75 95 70 90 90 100 35 65 90 65 70 90 90 90 75 90 85 80 85 80 90 85 85 90 85 90 70 85 90 55 65 80 65 80 98 98 50 75 65 45 70 80 85 98 85 85 90 98 100 75 15 75 100 100 98 98 100 100 100 98 95 100 98 90 100 100 95 100 100 100 80 100 90 70 80 45 75 15 70 50 35 80 60 40 30 30 0 15 15 25 35 20 95 95 98 95 100 100 100 100 90 100 100 95 95 100 100 100 100 100 65 98 25 5 0 0 0 5 10 10 20 0 95 95 85 95 85 100 100 95 95 98 80 75 85 95 60 75 70 75 70 75 95 95 80 90 100 80 98 100 95 95 220 201240602 Wheat 0 85 0 Wind-cut grass 50 98 60 Table Β 31 g ai/ha 1 3 4 Post-emergence barley - 0 0 Bermuda grass 70 55 60 Black grass 45 40 20 hair白露草55 0 5 Canary grass 85 45 60 繁繁 100 100 100 Xanthium - 98 98 縠物45 40 60 大马唐草85 75 80 乌利杯草75 75 75 宝盖草45 95 70 法氏草草95 80 70 莠草70 80 85 八仙草85 60 80 牛草草80 75 65 健生草75 85 80 地肤40 10 20 藜100 100 98 Morning Glory 100 85 98 sedge 65 70 45 Wild oats 80 55 45 100 100 95 ragweed 98 100 100 Italian ryegrass 15 25 30 soybean 100 95 95 Suriname grass 75 75 75 ramie 85 75 60 wheat 2 0 0 0 Wind cut grass 55 25 50 Table B 31 g ai/ha 18 19 20 55 55 15 25 0 10 15 35 25 35 50 30 85 70 10 10 40 50 40 30 Compound 6 7 8 10 11 12 14 15 16 17 0 20 0 0 0 0 0 0 0 0 35 85 95 80 70 5 55 75 70 25 5 60 10 5 50 - 5 0 0 5 0 - 25 5 20 10 35 40 5 10 5 45 25 5 30 35 5 35 35 20 98 100 100 100 98 100 100 100 98 100 90 - 98 98 100 95 95 98 80 100 20 80 5 10 15 65 15 5 5 15 65 98 80 80 70 15 75 65 65 75 75 100 75 45 55 70 80 85 95 95 60 85 80 100 100 100 100 100 100 100 75 95 80 70 85 80 75 75 75 80 45 100 35 25 60 50 40 40 35 40 45 70 25 70 50 50 75 40 50 80 65 100 75 75 75 75 65 65 70 40 85 90 80 20 65 60 75 95 60 70 5 85 70 75 60 5 50 10 5 75 80 100 98 100 100 100 100 98 90 100 95 98 90 98 100 98 95 100 85 100 10 75 75 80 70 75 75 40 15 85 10 45 40 0 5 40 45 40 45 50 95 100 80 100 90 98 100 95 95 190 98 100 100 100 100 100 100 100 60 100 0 5 0 0 15 10 5 5 10 0 90 100 95 98 98 98 98 98 98 100 70 100 75 25 20 60 70 75 70 65 70 90 60 80 60 80 80 65 70 80 0 30 15 0 10 0 5 0 0 0 60 60 5 50 30 45 55 30 25 Compound 22 23 24 25 26 28 29 30 31 32 221 201240602 Post-emergence barley 0 30 0 Bermuda grass 70 85 75 Black grass 0 60 10 毛白草草5 80 - Canary grass 35 95 5 Traditional 100 100 90 Xanthium 98 - - Cereal 5 - 15 Large horse grass 55 90 75 Uli cup grass 90 95 75 Komgrass 100 70 98 Pharis sylvestris 85 90 75 莠草10 75 80 八仙草45 80 70 牛草草70 80 85 恒生草75 - 60 地面15 98 90 藜100 100 98 Morning Glory 100 - 100 sedge 40 55 75 Wild Oats 40 60 5 Anti Twigs 100 100 90 ragweed 100 100 98 Italian ryegrass 0 55 0 Soybean 100 95 80 Suriname grass 80 100 75 Cannabis 70 98 75 Wheat 0 70 0 Wind-cut grass 30 95 35 Table Β Compound 16 g ai/ha 10 11 post-emergence barley 0 0 Bermuda grass 75 65 black grass 5 50 hair white dew 0 5 10 0 0 0 0 0 5 0 0 90 90 80 95 75 80 85 80 65 85 5 10 10 10 0 30 15 35 5 0 5 10 10 0 0 10 5 5 5 5 45 25 10 10 0 5 10 30 30 10 98 95 55 95 98 85 100 100 85 100 90 - 0 - - - - 98 80 85 35 5 5 85 5 55 65 10 25 25 95 95 60 80 70 75 95 75 65 65 75 85 75 95 60 25 65 25 60 85 90 70 95 95 80 80 90 70 75 85 80 80 55 95 100 75 85 65 65 75 50 70 85 90 20 55 90 60 50 75 80 85 50 85 70 70 85 55 85 85 85 85 75 85 65 70 85 50 55 75 55 75 80 80 45 65 65 45 50 80 80 95 5 70 75 50 100 45 10 65 100 100 90 98 85 85 98 95 85 95 98 85 100 98 80 95 100 85 80 80 80 60 55 5 65 0 60 40 20 80 35 35 5 10 0 5 10 10 10 15 95 80 98 85 90 80 98 98 85 98 100 90 85 98 100 98 100 80 65 95 20 0 0 0 0 5 10 0 5 0 85 80 70 75 75 95 95 95 85 85 75 75 70 75 45 60 65 60 65 70 95 90 65 75 98 80 95 95 90 95 40 50 0 5 0 10 5 15 25 25 30 10 40 30 0 5 30 30 30 30 Table B Compound 8 g ai/ha 11 17 Post-emergence barley 0 0 Bermuda grass 55 5 Black grass 0 0 White dew 5 5 222 201240602 Canary grass 0 15 Traditional 98 95 Xanthium 95 90 Corn 5 5 Large horse grass 70 60 Uli cup grass 20 55 Pomgrass 95 100 French foxtail 65 75 Alfalfa 10 40 Eight grass grass 30 50 cattle Rista 75 60 Johnson Grass 5 45 Ground 75 55 藜100 85 Morning Glory 65 85 Oil sedge 70 60 Wild oats 0 0 Anti-branches 85 85 Ragweed 100 98 Italian ryegrass 0 5 Soy 95 95 Suriname grass 15 0 Tubes 80 15 Wheat 0 5 Wind-cut grass 5 10 Table B Compound 250 g ai/ha 7 14 Pre-emergence Bermuda 100 100 Black Grass 85 5 Mao Lulu 15 45 Xanthium 100 100 Maize 25 25 Large Horsegrass 100 100 Uli Cup Grass 95 98 Fascia 100 100 莠草100 70 Canary grass 5 5 繁繁 50 ]00 Xanthium 90 100 Corn 0 0 Big horse grass 45 55 Uli cup grass 15 75 Kombu 90 100 Phnom Penh 70 70 莠草25 10 八仙草50 45 Goosegrass 35 5 Johnson grass 10 60 Kochia 55 25 藜85 100 Morning glory 85 85 Oil sedge 45 80 Wild oats 0 40 Anti-branches 85 100 Herbs 90 65 Italian ryegrass 0 0 Soybeans 85 90 Suriname Grass 0 25 Tube 10 10 Wheat 0 0 Wind Cut Grass 5 5 Table B Compound 125 g ai/ha 7 14 25 Pre-emergence Bermuda 100 100 100 Black Grass 25 0 0 White Dew 0 0 0 Xanthium 100 98 - Corn 20 20 0 Large唐草100 100 100 乌利杯草95 85 85 氏草草 95 100 25 莠草98 40 0 223 201240602 八仙草95 98 90 八仙草95 95 牛筋草100 100 100 牛筋草100 100 强生草98 95 100 Johnson Grass 80 90 Kochia 98 100 100 Koto 95 100 藜100 100 100 藜100 100 Morning Glory 98 100 - Morning Glory 80 100 Belladonna 100 100 98 %% 100 100 Oil sedge 95 95 70 Oil sedge 95 90 Wild oats 10 55 0 Wild oats 0 0 Anti-branches 100 100 100 Anti-branches. 100 100 Ragweed 100 100 100 Ragweed 100 100 Russian Li 95 100 90 Russian Li 90 90 Italian ryegrass 30 5 0 Italian ryegrass 0 0 Soybean 95 98 90 Soybean 85 95 Xiang Yu Cai 98 98 98 Xiang Yu Cai 95 95 Suriname Grass 95 100 98 Suriname Grass 90 80 Tube 100 100 - Tube 100 100 Wheat 0 0 0 Wheat 0 0 90 98 60 98 100 98 45 0 90 100 90 0 75 90 80 0 Table B Compound Table B Compound 62 g ai/ha 7 14 25 31 g ai/ha 7 14 Pre-emergence Bermuda 100 98 100 Bermuda 100 95 Black Grass 0 0 0 Black Grass 0 0 White Dew 0 0 0 White Dew 0 5 Cang 100 65 - Xanthium 100 45 Corn 20 20 0 Corn 0 5 Large horse grass 98 100 45 Large horse grass 95 95 Uli grass 75 75 75 Uri grass 45 30 French foxtail 80 95 5 French foxtail 75 75 莠Grass 90 5 0 莠草 55 5 八仙草85 90 85 八仙草80 65 牛筋草100 98 95 牛筋草98 95 强生草20 65 25 Johnson Grass 0 15 地肤90 80 90 地肤85 70 藜100 100 100藜100 100 Morning Glory 65 98 - Morning Glory 0 5 Belladonna 100 100 98 Belladonna 100 98 25 98 0 0 0 5 70 0 0 85 75 0 70 98 224 95 201240602 Oil sedge 95 85 5 Oil sedge 95 65 0 Wild oats 0 0 0 Wild oats 0 0 0 Anti-branches 100 100 85 Anti-branches 100 100 75 Ragweed 100 100 100 Ragweed 100 100 85 Russian 蓟90 90 85 Russian 蓟85 85 80 Italian ryegrass 0 0 0 Italian ryegrass 0 0 0 Soybean 80 80 60 Soybean 5 75 0 To the hollyhock 85 85 80 To the hollyhock 60 65 70 Suriname grass 90 60 40 Suriname grass 45 45 0 Ask Ma 85 100 - 苘蔚: 50 75 - Wheat 0 0 0 Wheat 0 0 0 Test c will be selected from the group consisting of Bermuda grass, Brachiaria decumbens, and great horse grass (Digitaria 5 sanguinalis), Setaria viridis, Eleusine indica, Sorghum haiepeme, Kochia scoparia, pitted morningglory, Ipomoea, purple nutsedge ) rotundus)' ^ (common ragweed, Ambrosia elatior)' M, 10 (Brassica nigra), guineagrass (Panicum maximum), Echinochloa cms-galli, sandbur (southern sandbur) Cenchrus echinatus) 'prickly sida, Italian ryegrass multiflorum, purslane (common purslane, 15 Portulaca oleracea), signal grass (broadleaf signalgrass, 10,000 nae/nar/a, European jaundice ( Groundsel) (common groundsel, Senecio vulgaris) ' (common chickweed, , dayflower (Virginia (VA) 225 201240602 dayflower, Commelina virginica), bluegrass (annual bluegrass, Poa annua), Roche grass (itchgrass) (and coc/nwc/nwewsh), quackgrass, field bindweed (Cowvo/vw/ws iarvew·?/5), spanishneedles (B/i/) Seeds of plant species of e/w, mallow (common mallow, Μα/να and Russian tle (Russian thistle) (5W(10)/α绐/ί) are planted in a blend of loam and sand and formulated The pre-emergence treatment is carried out on a test chemistry in a non-phytotoxic solvent mixture comprising a surfactant. At the same time, plants from these weed species were treated with a test chemical for post-emergence treatment, which was formulated in the same manner. Post-emergence treatment is carried out using plants ranging in height from 2 to 18 cm (1 to 4 leaf stage). All treated species and control groups were maintained in the greenhouse for 14 to 21 days&apos; after which all species were compared to the control group and visually assessed. The plant response ratings summarized in Table C are based on a scale from 0 to 100, where 0 is no effect and 1 is full control. The reaction shown as a dash (_) means no test results. Table C Compound 250 g ai/ha Post-emergence 25 Valerian 90 Bermuda Grass 95 Black Mustard 95 Blue Grass 70 Traditional 95 Large Horse Grass Duck 56 Grass 80 Table C Compound 125 g ai/ha 19 25 Post-emergence Valerian 90 80 Bermuda Grass 90 90 Black Mustard 95 95 Blue Grass 75 60 Traditional 100 95 Large Horse Grass 75 80 Duck Road Grass 90 226 201240602 Field Spin Flower 75 Field Spin Flower 60 70 Valerian 90 Valerian 90 80 Beetle Grass 70 Beef Grass 70 70 European Astragalus 100 European Astragalus 95 100 Big grass 90 Big grass 80 80 Roche grass 85 Roche grass 70 75 Johnson grass 85 Johnson grass 85 80 Koto 70 Kochia 70 50 Mallow 60 Mallow 70 50 Morning Glory 90 Morning Glory 90 90 Aconite 10 Aromatic Aconite 60 0 Yellow flower steady 40 Yellow flower steady 50 40 Purslane 60 Purslane 60 60 Quaker wheat grass 40 Quaker wheat 75 30 Rag grass 95 Ragweed 90 95 Italian ryegrass 0 Russian Li 95 95 Valerian 85 Italian Ryegrass 50 0 Signal Grass 90 Valerian 85 75 Suriname Grass 90 Signal Grass 90 85 Bidens - 90 Suriname Grass 90 85 Table C Compound Table C Compound 62 g ai/ha 19 25 31 g ai/ha 19 25 Post-emergence and post-emergence Valerian 85 80 Valerian 85 75 Bermuda grass 80 75 Bermuda grass 70 75 Black mustard 80 85 Black mustard 80 50 Blue grass 70 30 Blue grass 50 10 Traditional 95 80 Traditional 95 75 Malaysia Tang Cao 70 75 Da Ma Tang Cao 70 60 Duck Road Grass 70 Duckweed 60 Field Convolvulus 50 70 Field Convolvulus 50 - Valerian 85 70 Valerian 80 - Goosegrass 70 60 Goosegrass 65 50 European Jaundice 95 100 Europe Yellow 90 95 Big grass 60 80 Big grass 50 55 Roche grass 65 65 Roche grass 50 40 227 201240602 Johnson grass 70 80 Johnson grass 60 75 Kochia 60 40 Kochia 50 30 Mallow 70 50 Jin Cai 50 50 Morning glory 90 80 Morning Glory 85 75 Aromatic Aconite 60 0 Aconite 50 0 Aesculus 30 20 Aesculus 30 20 Purslane 50 50 Purslane 50 40 Quaker Wheat 70 70 Quaker Wheat 50 5 Ragweed 90 90 Ragweed 80 90 Russian 蓟90 70 Russian rhyme 20 - Italian ryegrass 30 0 Italian ryegrass 15 - 蒺藜草75 70 蒺藜草70 60 Signal grass 90 80 Signal grass 80 75 Bidens grass 95 85 Bidens grass 85 - Suriname grass 80 80 Suriname Grass 80 75

Test D will be selected from the bird's-eye speedwell (Feromca, blue grass (annual bluegrass), Alopecurus myosuroides, gold silk, Phalaris minor, common chickweed , *SVe//an&lt;3 wei/ζύτ), catchweed bedstraw, downy bromegrass (ie ieororww), field poppy (Pizpaver, field violet) F/o/&lt;3 ίο, 莠草(Se/ar/a WWiZ/s), 盖bit grass (henbit deadnettle,

Lamium amplexicaule), Lo丨ium multiflorum, Kochia scoparia, Chenopodium a/6ww, oilseed rape (Wanguang illusion~mz/?w5), anti-branches苋reir〇y7ejcw5), Russian AeWca), scentless chamomile (A/air/caWa, spring barley (Hordeum vu!gare), spring wheat (Triticum aestivum), wild branch Qin 201240602 wheat (Polygonum cowo/ Vw/(10)), wild mustard (public shirt), wild oats (yve like (four), wild radish π叩 (10) like raphanistmm), wind 萆 (Apera spica_ventf), winter barley (Hordeum vulgare) and winter wheat (Triticum aestivum Seeds of plant species 5 are planted and pre-emerged with test chemicals formulated in a mixture of non-phytotoxic solvents, the mixture comprising a surfactant. Meanwhile, plants from these crops and weed species are tested in part. The chemical is subjected to post-emergence application, and the test chemicals are formulated in the same manner. The plants range from 2 to 18 cm (1 to 41 〇 leaf stage). The treated plants and control groups are All species were compared with the control group and evaluated visually in a controlled growth environment for 14 to 21 days. The plant response ratings summarized in Table D are based on a scale of 〇 to 1〇() where 〇 is ineffective and 100 For complete control, the reaction shown as dash 15 (-) means no test results. Table D 125 g ai/ha 3 4 5 7 Post-emergence spring barley 30 25 10 80 Winter barley 40 30 35 35 Black grass 100 60 50 80 Blue Grass 85 85 75 90 White Buckwheat 35 25 40 65 Wild Buckwheat 55 70 90 100 Canary Grass 100 100 95 100 White Chrysanthemum 100 100 100 100 Traditional 100 100 98 100 Baogao Grass 100 100 100 100 Wild Ghost Poppy 85 100 70 70 Wilderness Violet 100 100 100 100 Compound 21 24 25 26 28 29 30 31 32 0 20 20 10 10 20 20 35 25 10 25 10 10 5 10 20 30 20 25 35 20 30 40 15 80 30 40 40 30 30 20 60 10 45 50 30 15 10 35 10 20 10 40 35 50 80 75 80 100 35 100 85 85 75 20 40 30 10 20 10 70 90 70 100 100 100 100 98 100 100 90 100 85 100 90 100 90 95 100 95 85 100 95 100 98 100 100 100 90 90 90 40 85 95 100 60 90 70 100 80 100 95 100 100 100 85 70 229 201240602 莠草100 95 八仙草90 85 地肤50 45 藜95 98 Wild mustard 100 90 Wild oats 100 100 Rapeseed 100 95 Inverse 苋100 95 Wild radish 100 100 Russian 蓟75 40 Italian black Wheat straw 35 40 Pomna 100 100 Spring wheat 35 25 Winter wheat 35 25 Wind cut grass 90 90 100 100 75 90 80 80 40 90 85 100 85 75 75 75 90 75 85 90 90 95 80 95 85 95 85 100 85 85 95 100 90 100 90 98 85 100 98 85 95 100 85 90 85 95 80 75 100 95 95 90 20 20 60 10 25 15 65 60 30 100 90 80 80 100 85 95 100 80 100 100 85 100 95 100 90 100 80 75 75 100 80 75 80 98 90 80 100 85 100 90 80 95 .90 90 90 100 80 70 100 40 10 0 0 10 15 10 25 50 10 100 100 85 100 90 100 100 100 100 100 15 10 20 10 10 45 15 40 45 50 20 15 10 10 10 25 10 40 60 60 85 55 85 75 35 30 15 60 35 75 Table D 62 g ai/ha Post-emergence 3 4 Spring barley 25 20 Winter barley 30 20 Black grass 95 60 Blue grass 75 80 White dew 35 20 wild buckwheat 35 40 canary grass 100 100 white chrysanthemum 100 98 繁缕 98 100 baocai 100 90 original Wild Ghost Poppy 40 98 Wilderness Violet 100 100 Valerian 90 85 Eight Immortals 85 85 Kochia 30 25 藜95 90 Wild Mustard 98 80 Wild Oats 98 85 Rapeseed 100 80 Compound 7 21 24 25 26 28 29 30 31 32 10 0 15 10 0 5 10 10 15 10 25 5 10 5 0 0 10 0 20 5 50 5 20 10 5 20 5 40 20 20 70 15 15 20 15 20 10 35 40 20 35 15 10 25 10 20 5 40 25 40 98 80 75 75 95 25 80 85 80 50 90 10 20 20 5 10 5 40 70 50 100 95 90 90 100 90 95 100 90 100 98 80 100 90 90 75 95 90 75 85 100 98 95 95 98 90 70 98 80 90 70 85 40 80 85 98 50 80 60 100 100 70 100 75 95 - 95 80 80 60 100 90 70 80 65 70 40 80 80 95 85 70 60 70 80 75 60 85 85 85 85 50 85 80 90 75 100 80 95 95 100 90 100 80 98 85 100 85 85 85 100 80 80 75 90 80 60 95 65 95 90 15 10 20 10 20 5 30 20 25 100 75 75 75 85 80 80 95 75 75 230 201240602 Anti-branches 85 100 95 100 85 100 90 95 80 100 95 75 Wild radish 100 80 100 100 60 70 70 90 90 75 100 75 Russian 蓟75 40 80 75 70 75 90 85 85 100 60 50 Italian ryegrass 25 20 10 40 0 0 0 5 10 0 10 30 Po Po Na 100 100 100 100 100 65 100 30 100 75 95 100 Spring Wheat 20 15 10 15 10 10 5 5 25 15 25 35 Winter Wheat 25 20 10 10 10 5 5 5 25 5 30 30 Wind Cut Grass 60 55 40 60 35 65 35 10 20 5 35 35 75 85 90 10 100 40 35 35 Table D Compound 31 g ai/ha 3 5 7 21 24 25 26 28 29 30 31 32 Spring after spring 15 5 10 0 10 5 0 0 0 0 10 0 Winter Barley 30 10 15 0 5 0 0 0 0 5 0 Black Grass 70 30 30 5 0 0 0 10 0 20 10 15 Blue Grass 70 30 40 0 10 10 5 10 10 10 20 20 White Dew 30 20 20 10 10 5 0 15 0 20 15 30 Wild buckwheat 25 60 80 75 40 75 85 15 70 75 75 30 Canary grass 90 60 70 0 15 10 0 10 0 20 50 30 White chrysanthemum 98 85 100 90 85 60 100 75 90 100 - 98繁繁 90 85 95 70 95 90 85 65 90 80 70 80 baocai 100 100 100 85 90 80 85 80 70 85 70 80 Wilderness Ghost Poppy 50 60 60 85 40 60 80 85 50 80 60 95 Wilderness Violet 100 90 100 70 95 60 95 - 90 80 40 - 莠草85 70 98 75 50 20 35 60 40 75 65 80 八仙草85 60 80 60 50 65 75 75 55 80 80 85 地肤25 30 75 25 70 75 85 50 100 50 35 70 藜85 90 90 85 75 70 95 80 90 90 75 85 Wild mustard 95 90 100 50 50 65 80 80 50 90 45 85 Wild oats 90 10 30 5 10 10 5 15 0 15 10 10 Rapeseed 80 80 100 70 50 70 85 50 75 85 50 60 反 苋 80 85 98 70 95 80 95 70 100 75 70 65 Wild radish 98 95 100 60 35 70 90 65 60 95 70 85 Russian Li 60 80 65 30 75 80 80 75 80 40 50 70 Italian ryegrass 20 0 10 0 0 0 0 10 0 0 20 0 婆婆纳100 100 100 100 60 90 20 75 60 95 100 100 Spring wheat 15 5 10 0 10 0 0 10 5 10 5 25 Winter wheat 15 5 5 5 5 0 0 10 0 15 10 15 Wind cut grass 50 20 35 15 40 25 0 10 0 20 10 25 231 201240602 Compound 3 4 5 7 21 24 25 26 28 29 30 31 32 10 5 5 5 0 0 0 0 0 0 0 5 0 0 5 10 0 0 0 0 0 0 0 0 0 0 60 5 10 30 0 0 0 0 0 0 5 0 0 60 35 20 15 0 10 0 0 0 0 10 10 5 20 10 10 15 0 10 0 0 0 0 10 5 10 20 20 50 50 70 25 75 85 20 40 50 45 20 70 70 25 25 0 15 0 0 5 0 10 30 10 90 90 50 100 90 85 50 80 60 80 100 70 90 80 85 85 85 60 95 70 85 50 80 70 60 75 95 85 95 100 85 90 60 85 75 60 85 65 75 10 85 60 60 85 40 50 70 85 40 40 50 90 100 90 85 95 60 90 50 80 - 75 80 40 50 80 0 55 80 75 0 10 5 55 20 75 55 70 80 65 60 75 60 50 60 75 60 50 75 80 80 20 10 20 55 20 70 75 65 45 90 40 20 50 75 80 85 70 85 60 70 80 75 75 85 75 80 95 60 95 98 50 30 60 75 50 20 60 30 65 55 40 10 10 0 10 0 0 5 0 5 0 5 75 70 75 98 50 50 60 80 40 75 75 20 30 80 70 85 90 70 95 80 90 70 90 65 70 65 85 80 90 40 30 35 85 35 50 80 40 50 50 30 50 55 30 75 40 .75 60 60 35 50 50 10 0 0 0 0 0 0 0 5 0 0 0 0 100 100 100 100 100 30 90 20 70 50 80 85 100 0 5 0 5 0 0 0 0 5 0 0 5 5 10 10 0 5 0 0 0 0 0 0 5 5 5 20 35 20 25 0 25 10 0 0 0 10 5 15

Table D 16 g ai/ha Post-emergence spring barley winter barley black grass blue grass hair white dew wild buckwheat canary grass white chrysanthemum prosperous treasure cover grassland wild ghost poppy wilderness violet valerian eight grassland grass skin wild mustard wild oats rapeseed苋Wild radish Russian Lily Italian rye grass mother-in-law spring wheat winter wheat wind cut grass

Test E will be selected from the group consisting of corn (Zefl, Gfyczwe wax, ramie 5 (Abutilon iheophrasti), rim (Chenopodium album), and later grass

Cfi'wpb叻b //e, palm pigweed 232 201240602 (Jmizrawi/mspa/merz·), common waterhemp (d/warflwi/zws rwi/b), resistant broad-leaved vine (ALS &amp; HPPD resistant, Jwariz «ww rwi//*s), springsthumb smartweed {Polygonum persicaria), Brachiaria 5 decumbens, Digitafia sanguinalis, Brazilian crabgrass ( DzgzYizrifii /zorzzowia/b), fall panicum (Panicum dichotomiflorum), foxtail faberii, Setaria vifidis, Eleusine indica, !k (Sorghum halepense), ragweed ( Common ragweed, 10 Ambrosia elaiior), Echinochloa crus-galli, southern sandbur (Cenchrus echinatus) ' # ^ M(10)ό%/ζ·(3), Italian ryegrass (ZWwm, duck 56 grass ( Virginia (VA) dayflower, (?〇/?2Teng&quot;&gt;2&lt;3 WrgWcYz), Tianxuanhua (Co«v6&gt;/vw/ws arve/wb), Xanthium (common cocklebur, 15 Such as, the morning glory [(7) cc / off a), the blessing (eastern black nightshade, koto (Kochia sc Seeds of plant species of oparia), Cyperus esculentus and hairy beggarticks (like Chuan/osa) are planted in muddy loam and formulated in a mixture of non-phytotoxic solvents. The test chemistry is pre-emerged and the mixture comprises a surfactant. At the same time, the plants from these crops and weed species are treated with a portion of the test chemistry for post-emergence treatment. The test chemistry is formulated in the same manner. Plants ranging from 2 to 18 cm (丄 to 4 leaf stage) are used for post-emergence treatment. 25 Treated plants and control groups are maintained in the greenhouse for 14 to 21 days, after which all species are compared with the control group and visually evaluated. . The plant response ratings summarized in Table 233 201240602 are based on a scale of 0 to 100, where 0 is no effect and 100 is complete control. The reaction shown as a dash (-) means no test results. Table Ε Compound Table E Compound 250 g ai/ha 15 125 g ai/ha 15 Post-emergence post-emergence Valerian 98 Valerian 98 Salty grass 100 Salty grass 100 Corn 50 Corn 35 Brazilian crabgrass 95 Brazilian crabgrass 80 Duckling duck跖草田旋花85 田旋花80 洋野黍95 洋野黍90 反枝苋100 苋枝苋100 Orangutan grass 100 Orangutan grass 95 Italian ryegrass 0 Italian ryegrass 0 蒺藜草75 蒺藜草60 金午时花98 Golden Noon Flower 95 Soybean 98 Soybean 98 Amaranth vine 100 Amaranth vine 98 Resistant amaranth vine 95 Resistant amaranth vine 95 Table E Compound Table E Compound 62 g ai/ha 1 15 31 g ai/ha 1 15 After germination Grass 80 95 稗草70 90 咸丰草90 98 咸丰草80 95 corn 30 15 corn 25 5 Brazilian crabgrass 65 80 Brazilian crabgrass 60 60 duck 55 grass 75 duck 55 grass 65 field convolvulus 70 60 field convolvulus 60 50 ocean黍95 95 野野黍95 75 反 苋100 100 反 苋 95 98 猩 草 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80蒺藜草50 35 蒺藜草45 0 Golden afternoon flower 80 90 Golden afternoon flower 65 80 Spring 蓼100 - Spring 蓼95 - Soybean 100 95 Soy bean 95 95 苋菜藤子 98 98 苋菜藤子90 98 Resistant 苋菜藤子80 85 Resistant 苋菜藤子80 75 Table E Compounds Ε Compound 16 g ai/ha 1 15 8 g ai/ha 1 Post-emergence geranium 50 75 稗草30 咸丰草75 75 咸丰草60 Corn 20 0 Corn 5 Brazilian crabgrass 50 50 Brazil Matangcao 40 Duck 55 grass 15 Duck road grass field Convolvulus 40 50 Field convolvulus 40 Ocean field 75 35 Ocean field 60 Anti-branches 95 95 Inversion 苋 95 Orangutan 70 75 Orangutan grass 50 Italian ryegrass 10 0 Yida Ryegrass 0 蒺藜草40 0 蒺藜草30 金午时花60 70 金午时花50 春蓼90 - 春蓼70 豆豆95 95 豆豆95 苋菜藤子85 95 苋菜藤子75 Resistant 苋菜藤子60 70 Resistant 苋菜藤子50 Table E Compounds Table E Compounds 4 g ai/ha 1 4 g ai/ha 1 Post-emergence geranium 20 Orangutan 30 Xianfengcao 55 Italian ryegrass 0 Maize 0 Valerian 20 Brazilian crabgrass 30 Golden afternoon flower 50 Δδ草春蓼60 田旋花30 Soybean 85 洋野黍40 苋菜藤子70 苋枝苋85 Resistant 苋菜藤子50 235 201240602 Table E Compound Table E Compound 250 g ai/ha 14 25 125 g ai/ha 14 25前萌前稗草65 0 稗草 - 0 Xanthium 100 98 Xanthium - 95 Corn 0 0 Corn 0 0 Brazilian horse grass 98 95 Brazilian horse grass 98 90 Large horse grass 100 95 Large horse grass 100 20 Duck ίδ grass 25 Duck 56 草 - 田旋花100 65 田旋花 35 5 法氏狗草草 - 30 法氏尾草0 20 莠草20 20 莠草15 20 牛牛草98 98 牛草草80 98 Johnson Grass 98 85 Johnson Grass 70 85 Ground Skin 98 65 Kochia 98 35 藜100 98 藜100 98 Morning Glory 95 90 Morning Glory 90 65 Belladonna 100 100 %% 100 100 Oil sedge 95 50 Oil sedge 85 10 Ocean 黍 - 98 洋野黍100 75反 苋 100 100 反 苋 100 100 100 草 98 75 75 75 75 75 95 95 95 95 95 95 95 95 95 95 95 95 95 95 95 0 95 95 95 95 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 98 100 100 0 金午时花0 0 Soybean 90 60 Soybean 70 50 Suli South Grass 98 95 Suriname Grass 75 50 Hemp 95 35 Qing Ma 85 0 Amaranth vine 100 100 Amaranth vine 100 100 Table Ε Compound Table E Compound 62 g ai/ha 14 25 31 g ai/ha 14 25 Pre-emergence 稗草0 0 稗草0 0 Xanthium 10 50 Maize 0 0 Maize 0 0 Brazilian crabgrass 25 10 236 201240602 Brazilian crabgrass 90 Da Ma Tang Cao 90 Duck Jffi grass - Tianxuanhua 0 French foxtail - 莠草10 牛筋草80 Johnson Grass 40 Kochia 50 藜100 Morning Glory 70 Belladonna 100 Oil sedge 70 Ocean 黍 50 Inverse 苋 100 Orangutan 60 Truffle 100 Italian ryegrass 0 蒺藜草 0 Golden afternoon flower 0 Soybean 30 Suriname grass 20 @麻80 苋菜藤子100 Table E Compound 16 g ai/ha Pre-emergence 14 Valerian 0 Xanthium - Corn 0 Brazilian crabgrass 0 Large horse grass 25 Acacia grass 0 Field squid 0 French foxtail 0 莠草 0 牛筋草0大马唐草90 0 Duck 55 草 - 0 田旋花0 0 法氏尾草0 0 莠草10 0 牛筋草65 5 强生草5 20 地肤0 0 藜98 98 Morning Glory 70 5 顚% 100 0 Oil Sedge 10 5 洋野黍 0 0苋100 100 Orangutan grass 10 - ragweed 70 60 Italian ryegrass 0 0 蒺藜草0 0 Golden afternoon flower 0 0 Soybean 20 0 Suriname grass 10 0 Qingma 65 0 Amaranth vine 0 0 Table E Compound 16 g ai/ha 14 25 萌前颠茄 95 - »1 **· rLt 油沙草0 0 野野黍0 0 苋枝苋100 - Orangutan 0 0 猪草 - 10 Italian ryegrass 0 0 蒺藜草0 0 金午时花0 0 Soybean 20 0 237 201240602 Johnson Grass 0 0 Suriname Grass 0 0 Kochi 0 0 Ramie 10 0 藜98 98 Amaranth vine 0 0 Morning Glory 50 5

Test F 5 10 15 Three plastic cans (about 16-cm diameter) of each application rate were partially filled with sterilized Tama mud loam containing 35:50:15 ratio of sand, silt and clay and 2.6% organic substance. Three plastic cans of each group were planted as follows. Each application rate will come from the US of monochoria vag/wfir/'X), the sylvestris sylvestris, the ricefield bulrush (Scirpus mucronatus) and the purple redstem (the seed planting of Ammannia). In a 16-cm jar, each application rate will be from a seed of rice flatsedge /r/a), bearded sprangletop /(10):/(3) sputum, a bunch of 9 or 10 seedlings of rice seedlings (〇〇; Zfl cv 'Japonica - M2〇r) and two bundles of 3 or 4 transplanted rice seedlings (the application rate of the 仏 种 cn//〇 and 稗 water waterg The seeds of the gallbladder) are planted in a 16-cm jar and the plants are sequenced so that the crop and weed species are treated at the 2.0 to 2.5 leaf stage. The growth in the room H is set and the day/night temperature is set to: , and supplemental balanced illumination is provided to maintain the tank in the greenhouse until the end of the test. Photogate period 238 20 201240602 During processing, the test tank is immersed above the soil surface 3 cm, its treatment applied the test compound directly to the field water, and during the test period Here, the water depth. After 21 days, the treatment effect of rice and weeds was visually evaluated by comparison with the untreated control group. The plant response ratings summarized in Table F are based on a scale of 0 to 1 (10), where 0 is No effect and 100 is complete control. The reaction shown as a dash (1) is actually the result of the benefit test.

Table F 500 g ai/ha Immersion 稗草水毛花 碎 米 鸭 鸭 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水 水

Table F 125 g ai/ha Immersion 稗草水毛花碎米草草鸭草水荒菜Transplantation Rice Water species Rice Round Umbrella 粗毛千金水稗草化合物7 19 100 85 100 100 100 85 90 100 90 100 100 40 100 70 90 100 100 - 75 80 Compound 7 19 40 0 75 100 75 85 75 95 0 0 20 0 25 0 85 95 100 - 20 0

Table F 250 g ai/ha Immersion 稗草水毛花碎米草草鸭草水苋 Transplanted rice Water-type rice Round umbrella grass Thick-brown gold Water sedge

Table F 64 g ai/ha Immersion 稗草水毛花碎米草草鸭草水苋菜 transplant rice water rice 轮草草粗毛千金水草草化合物7 19 85 55 85 100 80 85 80 100 75 100 45 20 60 25 85 100 100 30 0 Compound 7 19 35 0 40 95 40 85 20 85 0 0 0 0 0 0 75 90 75 201240602 [Simple description of the diagram] No [Main component symbol description] None 5

Claims (1)

201240602 VII. Patent application scope: 1. A compound selected from the group consisting of formula 1, its #· oxide and its salt, Wherein A is a free radical selected from the group consisting of Ίο B1 and B3 are each independently a radical selected from the group consisting of: B2 is a radical selected from the group consisting of 241 15 20 201240602 乂9, and C-3 C-4 C-5 C-6 C-7 R1 is Or R1 is -WtpE1)!^24, -V^LCpE2)!^5, -WtpE3)!^26, ^^(0)^^0(=0)^7, -W1S(0)xNR28C(=0 ) LR27 ' -W^CO^NR^SOzLR27 ίο or -WtN ; or R1 is N(R4G)R41 ; or R1 is -GA or -W2GA; each GA is a 4- to 7-membered carbocyclic ring, including From C (=0), C (= S), C (= NR29), C (= N-OR30) or C = NN (R29) 2 ring members; or 15 a 6- to 12-member saturation or part a saturated carbon spiro or heterospiro ring system, optionally comprising a member selected from the group consisting of c(=o), c(=s), C(=NR29), C(=N-OR30), or C=NN(R29) 2 ring members, each ring or ring system is selectively substituted with up to five substituents selected from R21 on a carbon ring member and R22 on a nitrogen ring member; or 2 〇 each GA is a 9-member partial saturation a ring system which is fused and contains a carbocyclic ring member and two nitrogen ring members, the ring optionally being substituted with up to two substituents selected from R21 on a carbocyclic member and R22 on a nitrogen ring member; 242 201240602 E, E2 and E3 are independently 〇N-CN or ν-νο2; s, NR28, NOR28, NN(R28)2, each L is independently 〇, N(R3i) or s, · The constraint is when E3 is 〇, 贝'i L is not 〇; each R 4, R25, p26 version and 27 Λ &amp; KR The ruler is independently hydrogen; or a CrC6 alkyl group, a CK:6 alkenyl group, a CVC6 alkynyl group or a C:3_C6 cycloalkyl group, each optionally substituted with 10 or more substituents selected from the group consisting of dentate, CN, N02, hydroxy, crC4 alkoxy, crC4 alkylsulfinyl, Crc4 alkanesulfonyl, Cl_c4 alkylamino, C2_C8 dialkylamino, CVC6 cycloalkylamino and (crC4 alkyl) c3-c6 ring a group consisting of alkylamine groups; each R is independently Η, C]-C6 alkyl or Ci-C6 _ alkyl; each R29 is independently hydrazine, CVC6 alkyl, Ci-Q-alkyl, crC6 alkylcarbonyl, CrC6 alkanesulfonyl or CkQ-dentanesulfonyl; each Qi and Q2 is independently 0, S or N (R31); Q is a CrC4 extender, which is selectively subjected to up to 4 selected from the group consisting of crC6, C2_C :6, a C2_C:6 alkynyl group substituted with a C3-C6 cycloalkyl group; R3G is independently fluorene, crc6 alkyl or crc6 dentate; R31 is independently η, crc6 alkyl or crc6 ii alkyl; R32 is fluorene or CrC6 alkyl; each X is 0, 1 or 2; w5 is crc6 alkyl; wl is CrQ alkyl, C2-C6 extended alkenyl or (: 2-(:6) alkynyl; -(CH2)2OCH2- or (CH2)3OCH2-; W2 is crc6 alkyl; 243 25 2〇124〇6 〇2 is a strepyl or -w(phenyl)' each optionally substituted with up to five substituents selected from R" on the ring member; or _G 4_W4G; or H, cyano, hydroxy, amine, Nitro, _CHO, -C(=〇)〇H, 5 -C(=〇)NH2 ' -C(=S)NH2 &gt; -C(=0)NHCN &gt; •C(=〇)NHOH,- SH, -S〇2NH2, -S02NHCN, -S02NH0H, -SF5, -NHCHO, -NHNH2, -NHOH, -NHCN, -NHC(=0)NH2, CrC6 alkyl, C2-C6 alkenyl, C2-C6 alkyne Base, Ci-C6 group, C2-C6 ii, C2-C6 10 坱, C3-C8 ring, c3-c8 _ ring alkyl, c4-C1C) alk cycloalkyl, C4-C1G ring Alkylalkyl, C6-C14 cycloalkanecycloalkyl, CVCio haloalkyl, CVCi2 ring, c3-Cg cycloalkenyl, C3-C8 halocyclo, C2-C8 oxygenated base, c3-C1q hospital oxygenated base, C^-ClQ ring courtyard oxygen base, C3-C1Q courtyard oxygen institute oxygen base, C2-C8 burnt sulfur base, 〇2-〇8 sulfinyl alkyl, c2- C8 15 calcination • • • base, G-C8 burnt amine base, C3-Ci 〇 diamine amine base, C2_C8 ii hexamine base, C4_C10 ring burn amine base, c2-C8 burn carbonyl, C2-C8 Haloalkylcarbonyl, c4-c10 cycloalkanecarbonyl, c2-C8 aerobic acid group, G-Cig ring-burning oxygen , C5-C12 ring alkoxy group, C2-C8 alkylamine carbonyl, c3-c1() dialkylamine carbonyl, c4_Ci〇20 cycloalkylamine carbonyl, c2-c5 cyanoalkyl, Crc6 hydroxyalkyl, c4 -c10 cycloalkenyl, c2-c8 ii alkoxyalkyl, crc8 alkoxyalkyl, C2-C8 alkoxy il alkyl, C4_C10 dental alkoxyalkyl, c4_cl anthracene oxygen, C4_Ci 〇 环 ring dilute oxygen, C3-Ci 〇 di- oxyalkyl, C3-C1G alkoxycarbonyl, C3-C1G alkoxycarbonyl, 25 C2-Cs 炫 • 乳 乳, Cl-C6 Alkoxy, C丨-C6 halooxy, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, c4_Ci〇244 201240602 cycloalkaneoxy, C2_C6 alkenyloxy, c2-c6 haloolefin Oxyl, c3-c6 alkynyloxy, C3_(]6 haloalkoxy, c2-c8 alkoxyalkoxy, c2-c8 calcined thiolate, C2_Cs halogenated alkoxy, C4_Ci〇 ringhouse Base, C; 3-C10 Institute alkoxy group, CrC6 system sulfur group, CrC6 halogen compound sulfur 5 group, C3-C8 ring-burning sulfur group, Ci-C6 pyrene sulfhydryl group, Ci-C6 halogen sulfoximine Base, C1-C6 burnt ruthenium, Ci-C6 halogenated ruthenium, C3-C8 ring sulphate base, c3-c8 trialkyl fluorenyl, c3-c8 cycloalkenyloxy, CVC8 dentate , C2- C8 halogen courtyard oxygen alkoxy, C^-C: 8 alkoxyhalo alkoxy, c2-c8 haloalkoxy alkoxy, 10 C3_C10 alkoxycarbonyl alkoxy, c2-c8 alkyl (thiocarbonyl) Oxygen, . 2-. 8 sulphur-based, C2_Cg alkyl (stone dangerous) thio, C3-C8 cycloalkyl sulfinyl, crc6 alkyl sulfonyl, c2-c8 dialkylamine sulfonyl, C3_C10 halotrioxane Base, crc6 alkylamino, c2_c8 monoamine, Ci_C6 _ acrylamine, C2_Cs haloalkylamine, 15 C3-C8 cycloalkylamine, c2-c8 alkylcarbonylamine, c2-c8 haloalkylamine a group, a crc6 alkanesulfonylamino group, a crc6-alkylsulfonylamino group or a c4_c1()cycloalkane (alkyl)amine group; R2 is -W6C(=E4)R33, -W6L]C(=E5)R34, -WtO^E6)!^35, -W6S(0)yNR37C(=0)R36 or -W6S(0)yNR37C(=〇 ) L1R36 ; 245 201240602 Each E4, E5 and E6 are independently Ο, S, NR37, NOR37, NN(R37)2, N-CN or N-N02; each L1 is independently 〇, N(R38) or S; each R33 R34, R35 and R36 are independently hydrogen; or a CrC6 alkyl group, a C2_C6 5 dilute group, a C2_C6 alkynyl group or a CrC6 cycloalkyl group, each optionally substituted by one or more substituents selected from the group consisting of dentate , CN, N02, thiol, CrC4 alkoxy, CVCU, sulfinyl, C1-C4, aryl, C1-C4, amine, C2-C8, amine, Q-C6, cycloalkanamine a group consisting of (CrC4 alkyl)c3-c6 cycloalkylamino group 10; each R37 is independently hydrazine, CVC6 alkyl or crc6 haloalkyl; each Q4 and Q5 are independently 0, S or N (R38); Q6 is a Q-C4 extended alkyl group which is optionally substituted with up to 4 substituents selected from the group consisting of a crC6, a C2_C:6 alkenyl group, a (156 substituent of a VC6 alkynyl group and a C3-C6 cycloalkyl group; , CrC6 alkyl or CrC6 haloalkyl; R39 is hydrazine or Q-C6 alkyl; each y is 0, 1 or 2; W7 is CrC6 alkyl; 20 W is Ci-C6 stretching, C2_ C; 6 stretching or C2-C6 alkynyl; or -(CH2)2OCH2- or -(CH2)3OCH2-; W3 is CrC6 alkyl, CVC6 extended alkenyl or c2-c6 alkynyl; W4 is Crc6 alkyl; R3 is H, halogen, cyano, hydroxy, -0·Μ+, amine, nitro, -CHO, 25 -C(=0)0H, -C(=0)NH2, -C (=S)NH2, -SH, -S02NH2' -S02NHCN' -S02NH0H' -OCN &gt; -SCN ' 246 201240602 _SF5, ·ΝΗΝΗ2, _NHOH, -N=C=0, -N=C=S, CrC6 alkane Oxy, CVC6 haloalkoxy, c3-c8 cycloalkoxy, c3-c8 halocycloalkoxy, c4-c10 cycloalkanoyloxy, c2_c6 alkenyloxy, c2-c6 haloenyloxy, c3- C6 alkynyloxy, c3-c6 haloalkoxy, 5 c2-c8 alkoxyalkoxy, c2_c8 alkylcarbonyloxy, c2-c8 halocarbonyloxy, C4-CiG cycloalkyloxy, C3-C1G A few oxy groups, Ci_C6 sulphur group, Ci_C6 _ sulphur group, C3-C8 ring sulphur group, C1-C0 焼 subunit thiol group, halogen saponin, alkane sulfonyl group, CrG halane Sulfonyl, C3-C8 naphthylsulfonyl, 1〇Ci_C6 pyroxenyloxy, C!-C6 dazzle &gt; Amine, C2-C8 dialkylamine, Ci-C6 halogen amine, C2 -C8 13⁄4 II Amine, C3-C8 cycloalkylamino, c2-c8 alkylcarbonyl, c 2-c8 haloalkylcarbonylamino, CrG alkanesulfonylamino or CrC6 halosulfonylamino; or benzyloxy, phenoxy, benzylcarbonyloxy, phenylcarbonyloxy, phenylsulfonyloxy, 15 a phenolic oxy group, a phenylthio group, a sulfhydryl group, a phenyl sulfonyl group, a sulfinyl group, a benzenesulfonyl group or a sulfonyl group, each selectively having up to five selected from ring members Substituted by a substituent of R21; M+ is a metal cation or a cation; R4, R5, R6 and R7 are each independently hydrazine, halogen, hydroxy, CrC6 alkane 2 fluorenyl, C2-C6 alkenyl, C2-C6 alkynyl , CrC6 haloalkyl, CrC6 alkoxy, CrC6 haloalkoxy, C3_C8 cycloalkoxy or C3_C8 halocycloalkoxy; or phenyl or a benzyl group, each selectively up to five selected on the ring member Substituted from a substituent of R21; R8 is anthracene, CrC6 alkyl, C2_C6 alkenyl, C2-C6 alkynyl, CA 25 haloalkyl, 〇2·〇6 halo, C2-C6 _ fast radical, C3-Cg Cyclo Burn 247 201240602 or C; 3-C8 functional cycloalkyl; or benzyl, which is optionally substituted on the ring member with up to five substituents selected from R21; R9 is fluorene, CrC6 alkyl, C2- C6 alkenyl, C2-C6 alkynyl, CrC6 halogen , CrC6 haloalkenyl, C2-C6 halo block, C3-C8 ring, c3-c8 halocycloalkyl, C4-C10 alkanecycloalkyl, C4-C10 cyclodextrin, C^-C]4 J clothing ring alkyl, C4-C10 tooth ring yard base, CVCi2 alkanecycloalkyl, c3-c8 cycloalkenyl, c3-c8 halocycloalkenyl, C2-C8 alkoxyalkyl, C4-C1 ( a cycloalkoxyalkyl group, a c3-c10 alkoxyalkoxyalkyl group or a c2-c8 alkylsulfanyl group; R10 is H, halogen, cyano, hydroxy, amine, nitro, sh, -S02NH2, -SO2NHCN' -SO2NHOH ' -OCN ' -SCN ' -SF5 ' -NHCHO, ·ΝΗΝΗ2, -N3, -ΝΗΟΗ, -NHCN, -NHC(=0)NH2, -N=C=0, -N=C=S, CrC6 Alkyl, C2-C6, C2-C6 alkynyl, C1-C6 13⁄4, C2-C6 haloalkenyl, C2-C6 haloalkynyl, (3-(8-cycloalkyl), c3- C8 halocycloalkyl, c4-c1Q alkanecycloalkyl, c4-c1G cycloalkylalkyl, c6-c14 cycloalkylcycloalkyl, C4-C10 i cycloalkylalkyl, c5-c12 alkanecycloalkyl, Crc8 Cycloalkenyl, c3-c8 halocycloalkyl, c2-c8 alkoxyalkyl, c4-c1Q cycloalkoxyalkyl, c3-c1G alkoxyalkoxyalkyl or C2_c8 alkylthioalkyl; R11 is hydrazine, halogen , cyano, hydroxy, amine, Crc6 alkyl, c2_c6 alkenyl, C2-C6 alkyne ,crC6 haloalkyl, c2-c6 haloalkenyl, C2-C6 haloalkynyl, C3-C8 cyclodextrin, c3-c8 halo ring, C4-C, G ring, c4-Cig ring Burning base, C4-C10 _ ring yard base, C5-C12 burnt ring base, C3-C8 ring thin base, C3-C8 li cycloalkenyl, c2_c8 alkoxyalkyl, c4-c1G cycloalkoxy Base, 248 201240602 C3_CiG alkoxyalkoxyalkyl, C2_C8 alkylsulfanyl, c2-c8 alkylsulfinyl or C2_C8 alkanesulfonyl; or phenyl, optionally up to five selected from R21 Substituted by a substituent; R12 is anthracene, halogen, cyano, hydroxy, amine, CVC6 alkyl, c2-c6 alkenyl, c2-c6 alkynyl, crc6 haloalkyl, c2-c6 i alkenyl, C2-C6 Alkynyl, C3-C8 cycloalkyl, C3-C8-cyclohexanyl, c4-c1G alkanealkyl, C4C1G cycloalkane, c6-c14 cycloalkylcycloalkyl, CrC10 ii cycloalkyl , c5_c12 alk cycloalkylene, CVC8 cycloalkenyl, c3-c8 4 cycloalkenyl or c2-c8 alkoxycarbonylamino; 13 R is hydrazine, halogen, cyano, hydroxy, amine, nitro or (^ -(^ alkoxy group; η is 0, 1. or 2; each R14, R15, R18 and R19 are independently oxime, halogen, cyano, hydroxy or Crc6 alkyl; A pair of R14 and R18 together with C2_C6 alkyl or C2_C6 alkylene; p20 or lt octaalkyl, C2-C6 haloalkenyl, CrC6 alkoxy, Ci-C6-alkoxy, C3-C8 Cycloalkoxy, crC6 alkyl, C2-C6 dilute, C2_C6 alkynyl or (: 3-(:8 cycloalkyl; T is CVC6 alkyl or C2-C6 extended alkenyl; each G is independently 5 a 6-membered heterocyclic ring or an 8_, 9- or ι〇_ member fused bicyclic ring system, each ring or ring system selectively passing up to five R21 selected from a ring member and a nitrogen ring member Substituted by a substituent of R22; each R21 is independently halogen, cyano, hydroxy, amine '', _CH0, -C(==0)0H, -C(=〇)NH2, -C(=S) NH2, 249 201240602 -C(=〇)NHCN, _c(=0)NH0H, -SH, _S02NH2, -S02NHCN, _s〇2NHOH, _OCN, -SCN, -SF5, 10 20 Cl_C6, C2-C6 alkenyl , C2-C6 alkynyl, CrC6 haloalkyl, c2-c6 haloalkenyl, c2_c6 haloalkynyl, c3-c8 cycloalkyl, C3-C8 i cycloalkyl, C4_CiG; ^cycloalkyl, c4_Ci(^f Alkyl, 匚3-(:8-cycloalkenyl, c3-c8 halocycloalkenyl, c2-c8 alkoxyalkyl, C4-C1G cycloalkoxyalkyl, c3_CiG alkoxyalkoxy, CH:8 hospital Alkyl, C2_C8 alkylsulfinyl, c2_c8 alkoxy S, c2-c5 cyano, CVC6 hydroxyalkyl, CVC6 alkoxy, c丨-C: 6 haloalkoxy, c3-c8 Cycloalkoxy, c3-c8 halocyclohexyloxy, C4-C1Q cycloalkanoxy, (2-(:6-alkenyloxy), c2-c6 i-dioxyoxyl, C2-C8 alkoxylated alkoxy Base, c2-c8 alkoxycarbonyl, CrC6 alkylthio, Ci_c6 haloalkylthio, c3_c8 cycloalkylthio, Ci-C6 alkylsulfinyl, Ci_c6 sulfinyl, Q-C6 Base, CVC6 haloalkylsulfonyl, c3-c8 cycloalkylsulfonyl, C1-C6 alkylamino, c2_c8 dialkylamino, Ci_c6 dentate, CH:8-dialkylamino or c3-c8 An alkylamino group; each R22 is independently c rc6 alkyl, c2-c6 alkenyl, c2-c6 alkynyl, c rc6 δ alkyl, (3-(:8-cycloalkyl or C2-C8 alkoxyalkyl; P4〇 is a crC6 alkyl group; and R is a crc6 alkyl group; or R 〇 and r41 are -(ch2)4-, _(ch2)5_, _ch2ch=chch2_ or -(CH2)2〇(CH2)2- . 25 2. If the compound described in J, 1 is printed, where A is A-1, A-3, A-4, Α·5 or A-6; 201240602 R1 is ' -WlLC(=E2)R25 ^-w^^E^LR26; R1 is N(R4())R41; or R1 is ga or -w2ga; ίο how and or partially saturated carbon or heteroscrew a spear system, which, in nature, comprises a ring member selected from the group consisting of c(=〇), C(=N30) or C-NN(R), each ring or ring system being selectively selected from up to three selected from carbon The r21 on the ring member is replaced with the ^2 base of the r22 on the ring member; or 15 each is a partially saturated and fused ring with a ring ring member and two nitrogen ring members. Substituted by r22 groups selected from gas ring members; % E1, E2 and E3 are independently 〇, N〇R28 or nn(r28)2 L is independently 〇 or n(R3i); 20 G is a 9- To each of 11-members R24, R25 and r26 are independently hydrogen; or a heart-burning group or a ca-ring group, each optionally one or more selected from the group consisting of halogen, cN, hydroxy, CrC2 alkoxy, Q-C2 alkane Substituted by a group consisting of a sulfinyl group and a crc4 sulfonyl group; each R28 is independently hydrazine, CrC3 alkyl or CVC3 _alkyl; 251 201240602 Each R29 is independently Η, (VC3 alkyl, CrC3 halogen Alkyl, Cl_C3 alkyl, C1-C3, or C1-C3 halogen calcined base; each Q1 and Q2 is independently 0 Or N(R31); Q is a C^C3 stretching group which is optionally substituted with up to two substituents selected from a crc4 alkyl group; R3G is independently hydrazine, CrC3 alkyl or CrC3 haloalkyl; R31 is independently Η, CVC3 alkyl or CrC3 haloalkyl; R32 is hydrazine or crc3 alkyl; W1 ^ C2-C4&gt;it^* ' -(CH2)2OCH2-^-(CH2)3〇CH2-; ~2 is CVC3 Alkyl; w5 is crc4 alkyl; R2 is phenyl or -w3(phenyl), each optionally substituted on the ring member with up to five substituents selected from R21; or -G; or CrC6 alkyl , C2-C6 dilute base, C2-C6 block base, Ci_C6 ΐ courtyard base, C2-C6 halogenated base, C2-C6 haloalkynyl group, C3-Cs cycloalkyl, C3-C8 halogen ring base, C4-C1Q Burning cycloalkyl, C4-C1Q ring alkyl, C6-Ci4 cycloalkylcycloalkyl, C4-C10 halocycloalkyl, (5-(: 12 alkancycloalkyl, c3-c8 cycloalkenyl) , c3_c8 halocycloalkenyl, c2-c8 alkoxyalkyl, C3-C1G alkoxyalkenyl, C4-C1G cycloalkoxyalkyl, c4-c10 cycloalkoxyalkyloxy, C3-C1G alkoxyalkoxy Alkyl, (: 2-(:8 alkylsulfanyl, c2-c8 alkylsulfinyl, c2-c8 alkanesulfonyl, C2_Cg burnt, C4_C! anthracene ring (base, C2_C8 tooth) Burning oxygen base, c2- C8 alkoxyhaloalkyl, c2-c8 halohalooxyhaloalkyl, c4-c10 halocycloalkoxyalkyl, C4-C10 cycloalkoxyalkyl, C4-C i〇i cycloalkoxyalkyl, c3- C1() dialkoxyalkyl, crc6 alkoxy, crc6 haloalkoxy, c3-c8 cycloalkoxy, C3-C8 i cycloalkoxy, 252 201240602 C4_C10 cycloalkyloxy' c2_c6 alkenyloxy , C2_C6 haloenyloxy, CH: 6 alkynyloxy, c3-c6 haloalkoxy, c2-c8 alkoxyalkoxy, C2-C8 decyloxy, C2_C8 4 alkoxy, c4_Ci 〇 naphthenic Carbonyloxy, C3-C1G alkylcarbonyl alkoxy, Ci_Cr^thio, 5 CrC6 halosulfonyl, C3-C8 cycloalkylthio, crC6 alkylsulfinyl, Crc6 from alkylsulfinyl, Crc6 alkane Sulfonyl, Ci_c6 halosulfonyl, CrC8 cycloalkylsulfonyl, c3_c8 trialkylsulfonyl, C3_c: 8 cycloaliphaticoxy, cvq halocycloalkenyloxy, c2-c8 ii alkoxyoxy, CH : 8 oxyhexyloxy, C2_C8 halohalo oxahalo 10 oxy, C3_Cl() alkoxycarbonyl alkoxy, crc8 alkyl (thiocarbonyl)oxy, OH: 8 cycloalkyl sulfinyl or c3_Ci 〇halotrialkyl fluorenyl; or R2 is -W6C(=E4)R33, -W6L1C(=E5)R34 or ^W6C(=E6)LlR35; 15 each E4, E5 and E6 independent ο, NOR37 or NN(R37)2; each L1 is independently o or N(R38); each R33, R34 and R3·' is independently hydrogen; or CrC4 alkyl, (^^cycloalkyl, each selectively One or more substituents selected from the group consisting of halogen, CN, hydroxy, CrC2 alkoxy, crC2 alkylsulfinyl and crc2 20 sulfonyl sulfonyl; each R37 is independently hydrazine, CrC3 alkyl or CrC3 haloalkyl; R is independently Η, C1-C3 or K1-C3 fluorenyl; W3 is -CH2-; W6 is C2-C4 alkyl, -(CH2)2OCH2- or -(CH2)3OCH2 - 25 R3 is hydroxy, -〇·Μ+, c2-c8 alkylcarbonyloxy, c2-c8 halocarbonyloxy, C4_C1()cycloalkaneoxy or C3_Cl() alkanoalkoxy; or benzyl Oxygen 253 201240602, phenoxy, benzylcarbonyloxy, phenylcarbonyloxy, benzenesulfonyloxy or alkoxy, each selectively having up to two substituents selected from R21 on the ring member Substituted; = is a sodium or potassium metal cation; r9 is a CrC6 alkyl group; ϋ 10 v. U is hydrazine, halogen or CiC6 alkyl; Rl1 is hydrazine or CrC6 alkyl; 10 20 R is H, halogen, cyano, a hydroxyl group, an amine group or a cardinyl group; each of R14, R15, R18 and R19 is Η or c H3; r2Q is Η or CH3; τ is -CH2CH2- or ·CH=CH·; each G is G-1 to G-20 (as described in Example 116); r is 0, 2 or 3; Each R21 is independently halogen, cyano, hydroxy, nitro, -CHO, -SH, QQ, C2-C6, C2-C6 alkynyl, CrC6-dentyl, c2-c6-haloenyl, c2_c6 Alkynyl, c3-C8 cycloalkyl, CH: 8 4 cycloalkyl, C4_Cl noncycloalkyl, c4_Ci 〇 cycloalkanyl, c3-c8 cycloalkenyl, c3-c8 i cycloalkenyl, c2_c8 alkoxy Alkyl, C4-C1G cycloalkoxyalkyl, c3-C1G alkoxyalkyloxy, CrC8 alkylsulfanyl, Qj-C: 8 alkylsulfinyl, C2_C8 alkoxyhaloalkyl, CH: 5 Cyanoalkyl, Ci-C: 6 hydroxyalkyl, CrC6 alkoxy, Crc6 i alkoxy, c3-c8 cycloalkoxy, c3_c8 halocyclooxy, C4-C1G cycloalkanoxy, c2- C6 diloxy, C2-C6 i-alkenyl, crc8 alkoxyalkoxy, crc8 alkoxycarbonyl, CrC6 alkylthio, crC6 ii alkylthio, C3-C8 cycloalkylthio, 254 25 201240602 CrC6 Sulfosyl group, crC6 haloalkyl sulfinyl group, CrC6 alkanesulfonyl group, CrQ alkanesulfonyl group or C3-C8 cycloalkanesulfonyl group; each R22 is independently a CrC6 alkyl group or a CrC6 haloalkyl group R4G is ethyl or isopropyl; and R41 is ethyl or isopropyl; or R40 and R41 together as _(CH2)5_, -CH2CH=CHCH2- or -(CH2)2〇(CH2)2 -. 3. The compound of claim 2, wherein A is A-1, A-3 or A-5; B1 is C-1; B2 is C-3; B3 is C-1; and R1 is -GA; GA is selected from GA-Bu GA-2, GA-3, GA-7, GA-8 and GA-9; or each GA is R2 is phenyl or -w3(phenyl), each optionally substituted with up to two substituents selected from R21 on the ring member; or -G; or Cl_c6 or C3-C8 ring; R3 is Hydroxy or C2-C8 alkylcarbonyloxy; R9 is ch2ch3; 255 25 201240602 R1G is Η or CH3; τ is -ch2ch2·; G is G-2, G-3 or G-15; and R21 is independently halogen, indeed Base, Crc6, KirC6, CrC6 5 oxime, Ci-C6 haloalkoxy or crC6 alkylthio; each R22 is independently ch3 or CH2CF3; and R40 and R41 together as _(CH2)5- , -CH2cH=CHCH2- or -(CH2)2〇(CH2)2-. 10. The compound of claim 3, wherein A is A-1; each G, R2 is phenyl; R3() is hydrazine or methyl; R21 is i or crc3 alkyl, and R22 is ch3. 5. The compound according to claim 3, wherein A is 1, GA is GA-2; R2 is phenyl, 2-thienyl, 5·chloro-2-pyridyl or cyclopropyl; and R 3 is hydroxy; 256 201240602 Each R14, R15, R18 and R19 is Η. 6. The compound according to claim 3, wherein Α is Α·1; 5 Α is Α·3, GA is GA-2; R2 is phenyl, 2-thienyl 5-chloro-2-acridinyl or Cyclopropyl; and R3 is hydroxy. Ίο 7. The compound of claim 2, wherein A is A_1; R1 is Each Q1 and Q2 is 0; Q3 is C2-alkylene; R32 is hydrazine or methyl; W5 is C2-C3 alkyl; 2〇R2 is phenyl, 2-methylphenyl, 3-mercaptobenzene , 3-bromophenyl, 3-phenylphenyl, 4-phenylphenyl, 3-fluorophenyl 3,5-difluorophenyl, 3-thienyl or 2-nonyl; R3 is hydroxy or - 〇C(=0)CH2CH(CH3)2; and each of R14, R15, R18 and R19 is Η or CH3. The compound of claim 7, wherein W5 is (: 2 alkyl or C3 alkyl; R2 is phenyl, 3-thienylcyclopropyl; and 5 R3 is hydroxy. The compound of formula 1 in claim 1 which is selected from the group consisting of 3-(1,4-dioxaspiro[4.5]dec-8-yl)-5-[(2-hydroxy-6-o-oxy-1-cyclo) Benzene-1-yl)yiji]-2-phenyl-4(3//)-°3⁄4 ketone, ίο 5_[(2_-carbyl-6-sideoxy-1-cyclohexene-1 -yl) keto]-6-o-oxy-2-phenyl- 1(6//)-pyrimidine acetaldehyde 1-(0-methylindole) 2-(5-chloro-3-.pyridyl ) 3-(1,4-dioxaspiro[4.5]dec-8-yl)_5_[(2_ylamino-6-o-oxy-1-cyclohex-1-yl) base]-4( 3//)-mouth bite 15 ketone, 2-cyclopropyl-3-(1,4-dioxaspiro[4.5]dec-8-yl)-5-[(2-hydroxy-6-sideoxy) 1-cyclohexen-1-yl)carbonyl]-4(3//)-pyrimidinone, 3-(1,4-dioxaspiro[4.5]dec-8-yl)-5-[(2- Hydroxy-4-sided oxybicyclic P.2.1]oct-2-en-3-yl)carbonyl]-2-(2-thienyl)-4(3//)-pyrimidine ketone with 5-[( 2-carbyl-6-side lactyl-1-ylide-1-yl)monoyl]-2-phenyl-3-(4,5,6,7-tetrahydro-2-indenyl-2 //, carbazole-5-yl)-4(3//)-pyrimidinone. 25 10. A herbicidal mixture comprising (a) - a compound of formula 1 and (b) at least one additional active ingredient selected from the group consisting of (M) photosystem II inhibitors, (b2) 258 201240602 AHAS inhibitors, (iv) ACCase inhibition Agent (= inhibitor, photosystem...transfer i=P〇2; L==, (b8) GS (flanderine synthase) inhibition=:i, (bll)PDS (octahydrofuran desaturation) Enzyme) t ::12) _ (4. phenyl-propanol-dioxygenase) inhibition 3) HST (black urine nematic transferase) inhibitor, _ other = grass 10 including mitotic interference agents, organic nucleating agents , 亚速烂,益=, 演布泰, inhibition of grass, cycloheptyl ether, (four) 隆, 迈隆, ti _ 曱, 曱 汰 草 、, acetophene, chlorhexidine, killing wood scales Syrian, Weibai, cetophenone, oleic acid, (4) grass and (Μ5) herbicide protectant; and (bl) to (bl5) compound salt. 15 11_ The herbicidal mixture according to claim 1 , which comprises (8) - a compound of claim i and (8) at least one additional active ingredient selected from the group consisting of (bl) photosystems </ RTI> inhibitors. a herbicidal mixture, wherein (b) is bromoxynil. 20 I3. The herbicidal mixture of claim 10, comprising (a) - a compound of claim i and (b) at least one selected from the group consisting of (bl5) herbicide protection Additional active ingredient of the agent M. A herbicidal composition comprising a compound of claimant at least one component selected from the group consisting of a surfactant, a solid diluent and a liquid diluent. 259 25 201240602 15. A method for controlling the growth of an unintended plant comprising contacting the plant or its environment with a herbicidally effective amount of a compound of claim 1. 201240602 IV. Designated representative figure: (1) The representative representative of the case is: (No) Figure (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 4