TW201233644A - Method and installation for the manufacture of thin sheets of glass - Google Patents

Method and installation for the manufacture of thin sheets of glass Download PDF

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Publication number
TW201233644A
TW201233644A TW101100730A TW101100730A TW201233644A TW 201233644 A TW201233644 A TW 201233644A TW 101100730 A TW101100730 A TW 101100730A TW 101100730 A TW101100730 A TW 101100730A TW 201233644 A TW201233644 A TW 201233644A
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Taiwan
Prior art keywords
glass
molten glass
molten
flow
sheet
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TW101100730A
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Chinese (zh)
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Goicoechea Luis Grijalba
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Goicoechea Luis Grijalba
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Publication of TW201233644A publication Critical patent/TW201233644A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • C03B17/064Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/02Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B7/00Distributors for the molten glass; Means for taking-off charges of molten glass; Producing the gob, e.g. controlling the gob shape, weight or delivery tact
    • C03B7/08Feeder spouts, e.g. gob feeders
    • C03B7/092Stirring devices; Homogenisation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention relates to a method and its installation for the manufacture of thin sheets of glass, and comprises the following steps: (a) melting (21) and refining (23) of glass from vitrifiable materials; (b) distribution and dosing in a flat stream of molten glass (38) by means of a dosing group consisting of glass drive modules (27), with rotating devices (29) and an overflow; (c) forming the molten glass into a solid glass sheet including the modification of one of its surfaces with a cleaning element (41), the cooling in a forming body (42), and the final stretching (51); and (d) fractionation into an end item. The final sheet (50) of thin glass can be formed by a single glass or two different glasses, each one occupying half the thickness of the sheet.

Description

201233644 六、發明說明: 【發明所屬之技術領域】 本發明屬於玻璃工業且應用於TFT-LCD發幕及電子領域 中所用之薄片玻璃。 . 【先前技術】 . 當今,TFT_LCD螢幕及電子領域中所用之低厚度薄片玻 璃主要經由「浮式」製程,或藉由向下拉伸之「溢流下 拉」製程製造。 稱為「浮式法」之薄片玻璃製造製程(u s 326688〇 ; U.S· 3771985’ EP 1739062;及 U.S. 2008/0223079)使用熔 融錫浴,玻璃浮於該錫浴上,同時該玻璃經冷卻及拉伸以 形成固體薄片玻璃。在「浮式」法中,溶融玻璃之兩個表 面各自處於不同介質中:a)下表面處於熔融錫中;及b)上 表面處於錫浴氛圍中。由此使得冷卻期間經由兩個玻璃表 面中之每一者的熱交換不同。另一方面因化學組份自溶 融錫浴擴放之故,4片玻璃表面存在污染。此等問題迫使 需要後續拋光製程’從而導致薄片玻璃表面品質比使用 「溢流下拉」法所獲得之品質低。201233644 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention belongs to the glass industry and is applied to sheet glass used in the field of TFT-LCD film and electronics. [Prior Art] Today, the low-thickness thin-film glass used in the TFT_LCD screen and electronic fields is mainly manufactured by a "floating" process or by an "overflow" process of downward stretching. A thin-film glass manufacturing process called "floating method" (us 326688〇; US·3771985' EP 1739062; and US 2008/0223079) uses a molten tin bath on which the glass floats while the glass is cooled and pulled Stretch to form a solid sheet glass. In the "floating" method, the two surfaces of the molten glass are each in a different medium: a) the lower surface is in molten tin; and b) the upper surface is in a tin bath atmosphere. Thereby the heat exchange via each of the two glass surfaces during cooling is different. On the other hand, due to the expansion of the chemical component self-solubilized tin bath, there are contaminations on the surface of the four glass sheets. These problems have forced subsequent polishing processes to result in a sheet glass surface quality that is lower than that obtained using the "overflow pull-down" method.

• 「溢流下拉」法(U.S. 3338696、U.S. 3682_、WO • 2GG5/」2U82)係基於稱為「封閉式隔熱管(―㈣」之主 成型早疋,其同時執行以下功能:a)兩股熔融玻璃扁平流 中玻璃流動速率之靜態分佈;b)玻璃冷卻;C)兩股前述溶 融玻璃流合併或匯合形成適於被拉伸之單股玻璃流。圖i 展不成型體或「封閉式隔熱管」⑴);來自溶爐之溶融玻 161469.doc 201233644 璃經由區域(12)進入,該區域(12)與在成型體(π)之上端區 域上切成之頸部(13)連通;此成型體具有兩個側壁(14), 熔融玻璃於該兩個側壁(14)之上邊緣(15)之上溢流❶玻璃 移動穿過頸部(13)且溢出邊緣(15) ’同時該玻璃之橫截面 在每長度單位必須恆定之流動速率下減小。接著,熔融玻 璃在成型體(11)之兩個側壁外部上以兩股流(丨6)流動,同 時其經冷卻直至到達該成型體(1丨)之下頂點(17),在此處 兩股流接合形成單一熔融玻璃薄片(18),其被拉伸成固體 狀態。形成薄片之兩個表面來自熔融玻璃基質(mass)内 部,該熔融玻璃基質已沿頸部流下且溢出其側壁而不與固 體表面接觸。專利(U.S. 3,338,696)仍為當今所實施之當前 先進技術,然而,「溢流下拉」製程仍具有一些限制,如 專利(U_S· 7,155,935)中所示。 /益流下拉」法之第一缺點為因沿成型體或「封閉式隔 熱管」之頸部兩側溢流之液體玻璃流動速率的複雜分佈所 致之玻璃薄片厚度的變化;此分佈對製程中固有之現象敏 感,諸如:a)在「封閉式隔熱管」入口處熔融玻璃溫度分 佈之變化,此係由於輸入區段之各點遵循其自身穿過頸部 之軌跡且始終指向所形成之薄片之同一位置;…來自熔融 爐之玻璃流動速率之變化,此係由於沿「封閉式隔熱管」 兩側溢流之玻璃流量並非溢流上之玻璃高度的線性函數, 且流量及溫度之瞬間變化導致最終薄片玻璃厚度之變化; c)「封閉式隔熱管」本身之熱塑性變形,此係由於因主體 中之彎曲所致之箭頭改變製造作業期間炼融玻璃之溢 I61469.doc 201233644 . 度,致使厚度可能不合需要地變化;d)上頸部區域之外部 環境及溢流之溫度影響最終薄片中玻璃厚度之分佈;及e) 最接近入口之薄片區域由已在輸入區段之周邊附近流向 「封閉式隔熱管」且可能具有較低品質之玻璃組成。為克 服此等所列舉之缺陷,已提出若干解決方案(w〇 2005/0268657 , U.S. 2005/0268659 ; U.S. 2005/0183455 ; U.S· 2008/0202165 ; WO 2007/070825)。 「溢流下拉」法之第二缺點為外延至較高提取率及薄片 尺寸有困難,此係由於熱變形之「封閉式隔熱管」之彎曲 及侧壁經受熔融玻璃液壓所引起之應力的頸部尺寸。在一 些狀況下,使用額外耦接以增加所製造之薄片玻璃之寬度 (WO 2006/115792)。 「溢流下拉」法之第三缺點係由於玻璃失透之故,此可 能視在#閉式隔熱管」各個區域中玻璃保持處於低於 。為避免成型期間 諸如專利(U.S. 液相線溫度」的溫度下之時長而發生 玻璃失透’已提出解決方案, 2004/0093900 A1)。 因此’在薄>1玻璃生產領域t ’需要解決前述當前製造 法之缺陷。 【發明内容】 所解決之技術問題 本發明之方法及相關製造裝置之設計解決了製造薄片玻 璃之當前方法之缺陷。纟「浮式」法中,在形成熔融玻璃 缚片期間,其兩個表面處於具有不同熱交換係數之兩種不 161469.doc 201233644 同介質中,由此導致玻璃薄片之厚度變化且需要後續拋光 製程。在「溢流下拉」&中’單—成型體在其上端區域中 執行熔融玻璃之靜態分佈且在下端區域中執行熔融玻璃之 冷卻,從而阻礙了最終薄片厚度之均一性,阻礙外延至較 咼尺寸,及因玻璃失透而使生產週期之持續時間受阻。 為了完善本發明之描述且更好地理解其特徵,附上一系 列圖式,其是出於說明之目的且不限制本發明範疇。 本發明之說明 用於製造薄片玻璃之本發明方法包含以下部分:a)用以 獲得熔融玻璃之熔融爐;…用以產生每單位寬度具有均一 流動速率之熔融玻璃扁平流之投配組;c)用以形成連續固 體玻璃薄片之成型器件;及句用以獲得特定尺寸之玻璃物 品的切割構件。 替代「溢流下拉」法所用之靜態玻璃分佈,本發明製程 使用動態分佈以控制及調節各玻璃驅動模組中來自投配組 之玻璃流量,且以此方式,有可能調節多達投配組之玻璃 驅動模組數目之最終薄片玻璃區域的厚度。對穿過各驅動 模組之玻璃流量的調節係由以下完成:改變旋轉速度及/ 或屬於彼模組之旋轉器件之旋轉軸的位置,以更改玻璃之 液壓高度及通過驅動模組之溢流道之熔融玻璃流量。 旋轉器件之主要功能在於投配及調節各驅動模組中玻璃 之質量流量。此外,旋轉器件執行以下功能:以物理及熱 方式混合並均化熔融玻璃,直接影響製品之最終品質。 圖2展示根據本發明方法製造薄片玻璃之裝置之透視 161469.doc 201233644 圖。 圖3及圖4展示本發明方法之兩個特定實施例之整體視 圖;各實施例包含用於熔融可玻璃化材料(22)之熔爐(21) 及精煉容器(23 ),因此,溶融玻璃通過通道(24)以到達投 配組(26),該投配組(26)之目的在於分配及調節玻璃流量 以使该玻璃變成熔融玻璃扁平流(38),該扁平流(38)之寬 度為最終薄片玻璃之寬度且其玻璃流量經由平行定位之多 個玻璃驅動模組(27)控制及調節,該等玻璃驅動模組(27) 之數目在兩幅圖之圖示中均為五個;玻璃驅動模組由側壁 (28)彼此隔開且包含旋轉器件(29),該等旋轉器件(29)執行 驅動熔融玻璃之功能,參見圖5及圖6;此等器件使得熔融 玻璃關於輸入通道之液壓高度增加,同時調節穿過屬於各 驅動模組之溢流道(36)之流動速率。分隔壁(28)延伸直至 溢流道(36)之堰頂,且當此等壁消失時,各驅動模組之熔 融玻璃接合成單股熔融玻璃扁平流(38),其流動並自出口 (37)流下以移動至成型器件中之下一成型階段。 當使用單一投配組時,扁平玻璃流(38)之兩個表面之 一,亦即已與出口(37)接觸之内表面,由屬於成型器件之 清潔το件改I接著’扁平流(38)分成在成型體(42)之兩 側上流下之兩股熔融玻璃流(48及49),同時玻璃經冷卻。 兩股玻璃流到達成型體之下頂點且會合形成連續玻璃薄片 (50),其藉助於牽引機向下拉伸’稍後分成低厚度扁平玻 璃之特定物品。在本發明方法之一個實施例中,清潔元件 包含旋轉圓筒,圖7、圖8及圖9;在本發明方法之另一實 I61469.doc 201233644 施例中’清潔元件包含部分浸沒於玻璃中之平板,圖10 β 圖Π及圖12展示本發明方法之兩個實施例之整體視圖, 其使用兩個不同投配組(26及6〇),該等投配組(26及60)具 有其各別驅動模組(27)、旋轉器件(29)、分隔壁(28)及溢流 道以形成兩股熔融玻璃扁平流(38及61)。兩個投配組(26及 60)由結構(65)部分支撐,該結構(65)為獨立的且與整合並 支標成型體之區域(64)隔開,參見圖13。玻璃薄片由牽引 親(51)拉伸。圖π展示本發明之一特定實施例,其使用兩 個溶融爐’熔爐Α(21)及熔爐Β(66),用於開發兩種不同玻 璃以獲得由兩種不同玻璃-玻璃Α及玻璃Β形成之玻璃薄 片’該兩種不同玻璃各自佔據來自成型體(64)之頂點(47) 之該玻璃薄片之厚度的一半。 本發明方法可呈現一些實施例,諸如: 1) 熔融爐,加上投配組,加上具有旋轉圓筒作為清潔元 件之成型體’加上用以獲得由單一玻璃組成之薄片的切割 構件; 2) 熔融爐,加上投配組,加上具有浸沒板作為清潔元件 之成型體,加上用以獲得由單一玻璃組成之薄片的切割構 件; 3) 炼融爐’加上兩個投配組,加上無清潔元件之成型 體’加上用以獲得由單一玻璃組成之薄片的切割構件; 4) 兩個熔融爐’加上兩個投配組,加上無清潔元件之成 变體’加上用以獲得由兩種不同玻璃構成之薄片的切割構 件。 161469.doc 201233644 【實施方式】 以下【實施方式.】係經由說明之方式提供而不限制本發 明之範疇;其將提供對本發明之全面理解,且足以使熟習 形成玻璃之技術者瞭解到儘管特定細節可能並未陳述於本 文中’但本發明可在其他工業實施例中應用。另一方面, 可略去對所使用之熟知器件、方法及材料的一些描述,以 便不進一步擴展本發明之描述。 本發明提供一種用於製造高品質薄扁平玻璃之製程,其 包含以下步驟:1)使用具有出口通道的熔融爐,熔融及精 煉可玻璃化材料以獲得經熔融及精煉之玻璃基質,該出口 通道包含液位調節器以使熔融玻璃之液壓高度維持恆定; 2)使用包含若干玻璃驅動模組之投配組,以每單位寬度具 有均一流量之熔融玻璃扁平流分配及投配玻璃,此等模組 各自由至少一個旋轉器件及溢流道組成,最終所有驅動模 組之玻璃接合以獲得上述熔融玻璃扁平流,經由出口轉至 下一階段;3)使用包含成型體及牽引構件且視情況包含 「清潔」構件以改良熔融玻璃扁平流之底面的成型器件, 使溶融玻璃扁平流轉變成連續固體玻璃薄片;及4)藉由切 割構件分割連續薄片以獲得既定尺寸之玻璃物品。 參見圖3、圖4、圖11及圖12之概覽,本發明方法始於在 熔融谷器(21)令熔融可玻璃化材料(22)及在精煉容器(23)中 精煉熔融玻璃;熔融玻璃經驅動穿過通道(24)至投配組 (26) ’在通道(24)中’使用由側通道/出口組成之液位調節 器(25)維持恆定玻璃液位h〇,圖5及圖6。 161469.doc 201233644 經驅動以恒定玻璃液位H〇穿過通道(24)之熔融破璃到達 投配組(26)起作用之區域,該投配組(26)之目的在於產生 溶融玻璃扁平流(38),其寬度尺寸類似於即將製造之薄片 玻璃之寬度,且其每單位寬度之流量為均一的。投配組使 來自通道(24)之熔融玻璃聚集且將其分配於平行置放之若 干驅動模組(27)間(在該等圖之圖示中為五個);各玻璃驅 動模組(27)由以鉑及/或铑之合金建構之分隔壁(28)與鄰近 模組隔開。玻璃之驅動由至少一個旋轉器件(29)執行,該 至少一個旋轉器件(29)調節及控制溶融璃在通過屬於同 一驅動模組(27)之溢流道(36)之前的液壓高度H〗;僅有由 驅動模組之旋轉器件(29)控制及調節之玻璃流流經各溢流 道。使驅動模組彼此隔開之壁(28)延伸直至溢流道(36)之 堰頂’且當此等壁(28)消失時,各驅動模組之所有熔融玻 璃接合成單股熔融玻璃扁平流(38),其流動並自出口(37) 落下以移動至下一成型階段^投配組(26)及玻璃驅動模組 (27) 可部分支撐於其基礎結構(33)上及/或部分懸掛於側壁 (28) 之頂部。 如圖5及圖6中所示,熔融玻璃流之投配係由旋轉器件 (29) 執行’促使來自輸入通道p4)之熔融玻璃移位,旋轉 器件(29)執行具有恆定玻璃高度h〇之抽吸區域至具有玻璃 高度H〗之驅動區域(3 5)之功能,其中出口溢流道為(36)。 各模組之旋轉器件與側壁(28)之間在玻璃流之方向(31)上 的空間大於相反方向(32)上之空間;因此,玻璃流在製造 方向上得以推送及驅動。旋轉器件(29)並不限於圖中所示 161469.doc -10· 201233644 之設計,且可使用多種模型:&輪、齒輪、活葉或偏心元 件,所有皆在本發明之範疇或精神内。旋轉器件由至少一 個控制及調節旋轉速度之驅動機構及/或由控制及調節旋 轉器件相對於彼此及相對於其所屬之驅動模組之位置的位 置機構引導。 使用兩個旋轉器件之驅動模組之一特定實施例,圖5, 展示各驅動模組(27)包含基底基礎結構(33),該基底基礎 結構(33)延續至溢流道(36)且結束於出口(37),該出口(37) 將玻璃以每單位寬度具有均一流動速率之熔融玻璃扁平流 (3 8)之形式傾倒至定位於上方出口向下更遠處之成型器 件:各驅動模組亦由側壁(28)組成,該等側壁(28)將該驅 動模組與屬於同一投配組之鄰近驅動模組隔開;此等側壁 (28) 將熔融玻璃導向溢流道(36)之堰頂。熔融玻璃自具有 液壓高度Η0之抽吸區域(34)聚集,且提昇至在液壓高度仏 處緊接溢流道(36)之驅動區域(35)。屬於兩個旋轉器件(29) 之旋轉軸以量值De隔開,且在浸入熔融玻璃中之部分令, 存在葉片(30),其形狀、旋轉軌跡、速度及方向將決定驅 動模組之整個體積中之玻璃移動,該體積可分解成兩個獨 立體積:a)順行體積(3 1)Vd,其中玻璃在製造方向上移 動’及b)回流體積(32)vR,其中玻璃在相反製造方向上移 動。順行體積(3 1)大於回流體積(32),使得玻璃以經調節 方式藉由改變旋轉器件(29)之旋轉速度w及/或旋轉器件 (29) 之旋轉轴相對於該等旋轉器件(29)所屬之驅動模組(27) 之位置DE、d丨及d2來增加該玻璃之液壓高度ah = ΗγΗο。 161469.doc 201233644 圖6展不各驅動模組中包含單一可移動元件之圖,液壓 提昇藉由改變旋轉器件之旋轉速度…及/或旋轉器件之旋轉 軸相對於驅動模組之側壁(28)之偏心位置及旬來達成; 隨著旋轉軸之位置dl及A變化,所提及之兩個體積順行 與回流vR均同時改變。 在本發明方法中用於流量調節之圖5之旋轉器件(29)基 本上由具有兩個平行軸之旋轉泵組成,該旋轉泵收集來自 輸入通道(24)之具有玻璃高度η0之熔融玻璃,且使其提昇 至接近具有厚壁之溢流道(36)的玻璃高度已提昇玻璃 之南度Η〗維持經驅動玻璃之淨流動速率與通過溢流道之玻 璃流動速率之間的平衡。 由於入口區域(34)中之玻璃高度Η〇維持恒定,故出口區 域(35)中之玻璃高度Η!視溢流道堰頂(36)之高度Υ0而定; 熔融玻璃之流量驅動QM產生液壓高度之增加: ΔΗ = Ηι-Η〇 (1) 其中:ΔΗ為由旋轉器件產生之高度增加;Hi為在出口 或驅動區域處之玻璃高度;且H〇為在入口或抽吸區域處之 玻璃尚度。 在每次旋轉或轉動中’圖5 ’旋轉器件使一定體積之順 行玻璃(31 )VD沿模組之兩側朝向驅動區域(3 5)移位,且穿 過中心區域,該等旋轉器件使一定體積之回流玻璃(32)Vr 以旋轉速度w朝向抽吸區域或入口(34)移位;此等體積之 移位在各模組中產生流量Qm :• The “Overflow Pulldown” method (US 3338696, US 3682_, WO • 2GG5/”2U82) is based on a main molding machine called “closed insulated pipe (“(4)”), which performs the following functions simultaneously: a) Static distribution of glass flow rate in a flat stream of molten glass; b) glass cooling; C) two streams of the aforementioned molten glass are combined or merged to form a single stream of glass suitable for stretching. Figure i shows the molded body or "closed insulated pipe" (1)); molten glass from the melting furnace 161469.doc 201233644 The glass enters through the zone (12), and the zone (12) and the upper end zone of the molded body (π) The upper cut neck (13) is connected; the molded body has two side walls (14), and the molten glass overflows over the upper edge (15) of the two side walls (14) and the glass moves through the neck ( 13) and overflow edge (15) 'At the same time the cross section of the glass decreases at a constant flow rate per unit of length. Next, the molten glass flows in two streams (丨6) on the outside of the two side walls of the molded body (11) while it is cooled until reaching the apex (17) below the molded body (1), where two The strands join to form a single molten glass flake (18) that is stretched into a solid state. The two surfaces forming the flakes come from the interior of the molten glass matrix which has flowed down the neck and overflows its side walls without coming into contact with the solid surface. The patent (U.S. 3,338,696) is still the current state of the art implemented today, however, the "overflow pulldown" process still has some limitations, as shown in the patent (U_S. 7, 155, 935). The first shortcoming of the /blow-down method is the variation of the thickness of the glass flakes due to the complex distribution of the flow rate of the liquid glass overflowing along the sides of the molded body or the "closed insulated tube"; this distribution The phenomena inherent in the process are sensitive, such as: a) the change in the temperature distribution of the molten glass at the entrance of the "closed insulated tube", since each point of the input section follows its own path through the neck and always points to The same position of the formed sheet; ...the change in the flow rate of the glass from the melting furnace, because the flow rate of the glass overflowing on both sides of the "closed insulated tube" is not a linear function of the height of the glass on the overflow, and the flow rate and The instantaneous change in temperature causes a change in the thickness of the final sheet glass; c) the thermoplastic deformation of the "closed insulated tube" itself, which is due to the arrow caused by the bending in the body changing the overflow of the molten glass during the manufacturing operation. 201233644 . The thickness may be undesirably varied; d) the external environment of the upper neck region and the temperature of the overflow affect the distribution of the thickness of the glass in the final sheet; and e) Near the entrance area of the sheet has to flow around the periphery of the input section of the "closed-insulated pipes" and may have a lower quality of the glass. In order to overcome these listed deficiencies, several solutions have been proposed (w〇 2005/0268657, U.S. 2005/0268659; U.S. 2005/0183455; U.S. 2008/0202165; WO 2007/070825). The second disadvantage of the "overflow pull-down" method is that it is difficult to extend to a higher extraction rate and sheet size. This is due to the bending of the "closed insulated tube" due to thermal deformation and the stress on the sidewall caused by the molten glass hydraulic pressure. Neck size. In some cases, additional coupling is used to increase the width of the manufactured sheet glass (WO 2006/115792). The third drawback of the "overflow pull-down" method is that the glass remains below the area in each area of the #closed insulated tube due to glass devitrification. A solution has been proposed to avoid glass devitrification during molding, such as the duration of the temperature at the U.S. liquidus temperature, 2004/0093900 A1). Therefore, it is necessary to solve the defects of the aforementioned current manufacturing method in the field of thin >1 glass production. Disclosure of Invention Technical Problem The design of the method and related manufacturing apparatus of the present invention solves the deficiencies of the current method of manufacturing sheet glass. In the "floating" method, during the formation of the molten glass slab, the two surfaces are in the same medium having different heat exchange coefficients, thereby causing the thickness of the glass flake to change and requiring subsequent polishing. Process. In the "overflow pulldown" & 'single-molded body performs the static distribution of the molten glass in its upper end region and the cooling of the molten glass in the lower end region, thereby hindering the uniformity of the thickness of the final sheet, hindering the extension to the The size of the crucible and the duration of the production cycle are hindered by the devitrification of the glass. In order to improve the description of the present invention and to better understand the features thereof, a series of drawings are attached for the purpose of illustration and not limitation. DESCRIPTION OF THE INVENTION The method of the present invention for producing sheet glass comprises the following parts: a) a melting furnace for obtaining molten glass; a dosing group for producing a flat flow of molten glass having a uniform flow rate per unit width; a molding device for forming a continuous solid glass flake; and a cutting member for obtaining a glass article of a specific size. Instead of the static glass distribution used in the "overflow pull-down" method, the process of the present invention uses dynamic distribution to control and regulate the flow of glass from the dosing group in each glass drive module, and in this way, it is possible to adjust up to the dosing group. The number of glass drive modules is the thickness of the final sheet glass area. The adjustment of the flow rate through the glass of each drive module is accomplished by changing the rotational speed and/or the position of the rotary shaft of the rotating device belonging to the module to change the hydraulic height of the glass and the overflow through the drive module The molten glass flow of the road. The main function of the rotating device is to dose and adjust the mass flow of the glass in each drive module. In addition, the rotating device performs the function of mixing and homogenizing the molten glass physically and thermally, directly affecting the final quality of the article. Figure 2 shows a perspective view of a device for making sheet glass in accordance with the method of the invention 161469.doc 201233644. 3 and 4 show an overall view of two specific embodiments of the method of the present invention; each embodiment comprises a furnace (21) for melting the vitrifiable material (22) and a refining vessel (23), whereby the molten glass passes Channel (24) to reach the dosing group (26), the purpose of the dosing group (26) is to distribute and adjust the flow of glass to cause the glass to become a flat flow (38) of molten glass, the width of the flat stream (38) being The width of the final sheet glass and its glass flow rate are controlled and adjusted via a plurality of glass drive modules (27) positioned in parallel. The number of the glass drive modules (27) is five in the two figures; The glass drive modules are separated from each other by side walls (28) and include rotating means (29) that perform the function of driving the molten glass, see Figures 5 and 6; these devices allow the molten glass to be associated with the input channel The hydraulic height is increased while regulating the flow rate through the overflow passages (36) belonging to each of the drive modules. The dividing wall (28) extends up to the dome of the overflow channel (36), and when the walls disappear, the molten glass of each drive module is joined into a single stream of molten glass flat (38) which flows and exits ( 37) Flow down to move to the next forming stage in the forming device. When a single dosing group is used, one of the two surfaces of the flat glass stream (38), i.e., the inner surface that has been in contact with the outlet (37), is modified by a cleaning device belonging to the forming device followed by a 'flat flow' (38). Divided into two streams of molten glass (48 and 49) flowing down on both sides of the shaped body (42) while the glass is cooled. The two streams of glass reach the apex below the shaped body and merge to form a continuous sheet of glass (50) which is stretched downward by means of a tractor to a particular article that is later divided into low-profile flat glass. In one embodiment of the method of the invention, the cleaning element comprises a rotating cylinder, Figures 7, 8 and 9; in another embodiment of the method of the invention, in the embodiment of the method of the invention, the cleaning element comprises a partial immersion in the glass The slab, Fig. 10, Fig. 12 and Fig. 12 show an overall view of two embodiments of the method of the invention using two different dosing groups (26 and 6), the dosing groups (26 and 60) having Each of the drive modules (27), the rotating device (29), the partition wall (28) and the overflow passage form two flat streams of molten glass (38 and 61). The two dosing sets (26 and 60) are partially supported by a structure (65) that is separate and spaced apart from the area (64) where the shaped and shaped bodies are integrated, see Figure 13. The glass flakes are stretched by the traction pro (51). Figure π shows a particular embodiment of the invention using two furnaces 'furnace crucible (21) and furnace crucible (66) for the development of two different glasses to obtain two different glass-glass crucibles and glass crucibles The formed glass flakes 'the two different glasses each occupy half of the thickness of the glass flakes from the apex (47) of the shaped body (64). The method of the present invention may present some embodiments, such as: 1) a melting furnace, plus a dosing group, plus a shaped body having a rotating cylinder as a cleaning element plus a cutting member for obtaining a sheet composed of a single glass; 2) The melting furnace, plus the dosing group, plus the molded body with the immersion plate as the cleaning element, plus the cutting member for obtaining the sheet composed of a single glass; 3) The refining furnace 'plus two dosing Group, plus a molded body without cleaning elements 'plus a cutting member for obtaining a sheet composed of a single glass; 4) Two melting furnaces 'plus two dosing groups plus a variant without cleaning elements 'Adding a cutting member for obtaining a sheet composed of two different glasses. The following [Embodiment] is provided by way of illustration and not of limitation of the scope of the invention; The details may not be stated herein 'but the invention may be applied in other industrial embodiments. In other instances, some description of well-known devices, methods and materials may be omitted in order to not further extend the description of the invention. The present invention provides a process for producing a high quality thin flat glass comprising the steps of: 1) melting and refining a vitrifiable material using a melting furnace having an outlet passage to obtain a molten and refined glass substrate, the outlet passage A level adjuster is included to maintain a constant hydraulic height of the molten glass; 2) a dosing group comprising a plurality of glass drive modules is used, and a flat flow of molten glass having a uniform flow rate per unit width is dispensed and dosed to the glass. Each of the groups consists of at least one rotating device and a spillway, the glass of all the drive modules is finally joined to obtain the above flat flow of molten glass, and is transferred to the next stage via the outlet; 3) the use of the molded body and the traction member is included and optionally included The "cleaning" member is a molding device for modifying the bottom surface of the flat flow of the molten glass to convert the flat flow of the molten glass into a continuous solid glass sheet; and 4) dividing the continuous sheet by the cutting member to obtain a glass article of a predetermined size. Referring to the overview of Figures 3, 4, 11, and 12, the method of the present invention begins with refining molten glass in a molten grain (21) melted vitrifiable material (22) and in a refining vessel (23); Driven through the channel (24) to the dosing group (26) 'in the channel (24)' maintains a constant glass level h〇 using a level regulator (25) consisting of a side channel/outlet, Figure 5 and Figure 6. 161469.doc 201233644 is driven by a constant glass level H〇 through the molten glass of the channel (24) to the area where the dosing group (26) is active. The purpose of the dosing group (26) is to produce a flat flow of molten glass. (38), the width dimension is similar to the width of the sheet glass to be manufactured, and the flow rate per unit width is uniform. The dosing group collects the molten glass from the channel (24) and distributes it between several drive modules (27) placed in parallel (five in the illustrations of the figures); each glass drive module ( 27) A partition wall (28) constructed of an alloy of platinum and/or rhodium is separated from the adjacent module. The driving of the glass is performed by at least one rotating device (29) that adjusts and controls the hydraulic height H of the molten glass before passing through the overflow passage (36) belonging to the same driving module (27); Only the glass flow controlled and regulated by the rotating device (29) of the drive module flows through the overflow channels. Walls (28) that separate the drive modules from each other extend up to the dome of the overflow passage (36) and when the walls (28) disappear, all of the molten glass of each drive module is joined into a single strand of molten glass Flow (38), which flows and falls from the outlet (37) to move to the next forming stage. The dosing group (26) and the glass drive module (27) can be partially supported on its base structure (33) and/or Partially suspended from the top of the side wall (28). As shown in Figures 5 and 6, the dosing of the molten glass stream is performed by the rotating device (29) to "drive the molten glass from the input channel p4" and the rotating device (29) is performed with a constant glass height h〇 The function of the suction zone to the drive zone (35) having a glass height H, wherein the outlet overflow is (36). The space between the rotating means of each module and the side wall (28) in the direction of the glass flow (31) is larger than the space in the opposite direction (32); therefore, the flow of glass is pushed and driven in the manufacturing direction. The rotating device (29) is not limited to the design of 161469.doc -10· 201233644 shown in the figures, and various models can be used: & wheels, gears, flaps or eccentric elements, all within the scope or spirit of the invention . The rotating device is guided by at least one drive mechanism for controlling and adjusting the rotational speed and/or by a position mechanism for controlling and adjusting the position of the rotary device relative to each other and to the drive module to which it belongs. A particular embodiment of a drive module using two rotating devices, Figure 5, shows that each drive module (27) includes a base infrastructure (33) that extends to the overflow passage (36) and Ending at the outlet (37), the outlet (37) pours the glass in the form of a flat flow of molten glass (38) having a uniform flow rate per unit width to a shaped device positioned further down the upper outlet: each drive The module is also comprised of side walls (28) that separate the drive module from adjacent drive modules belonging to the same dosing group; such side walls (28) direct the molten glass to the overflow channel (36) ) The dome. The molten glass is collected from a suction region (34) having a hydraulic height Η0 and raised to a drive region (35) immediately adjacent to the overflow passage (36) at a hydraulic height 仏. The rotating shafts belonging to the two rotating devices (29) are separated by a magnitude De, and the portion immersed in the molten glass causes the blade (30) to have a shape, a rotational trajectory, a speed and a direction which determine the entire driving module. The volume of glass moves, the volume can be broken down into two separate volumes: a) antegrade volume (3 1) Vd, where the glass moves 'in the manufacturing direction' and b) the reflux volume (32) vR, where the glass is manufactured in reverse Move in the direction. The antegrade volume (31) is greater than the reflux volume (32) such that the glass is adjusted in a manner to vary the rotational speed of the rotating device (29) and/or the rotational axis of the rotating device (29) relative to the rotating device ( 29) The position DE, d丨 and d2 of the associated drive module (27) increase the hydraulic height ah = Η γ Η ο of the glass. 161469.doc 201233644 Figure 6 shows a diagram of a single movable component in each drive module. The hydraulic lift is performed by changing the rotational speed of the rotating device... and/or the rotating shaft of the rotating device relative to the side wall of the drive module (28) The eccentric position is achieved in ten days; as the positions of the rotating axes dl and A change, the two volumes antegrade and the return vR are simultaneously changed. The rotary device (29) of Figure 5 for flow regulation in the method of the present invention consists essentially of a rotary pump having two parallel shafts that collect molten glass having a glass height η0 from the input channel (24), And raising it to near the thick-walled overflow channel (36), the height of the glass has increased the south of the glass, maintaining a balance between the net flow rate of the driven glass and the glass flow rate through the overflow. Since the glass height Η〇 in the inlet zone (34) is kept constant, the glass height in the outlet zone (35) is Η! depending on the height 溢0 of the overflow channel dome (36); the flow of molten glass drives the QM to generate hydraulic pressure Height increase: ΔΗ = Ηι-Η〇(1) where: ΔΗ is the height increase produced by the rotating device; Hi is the glass height at the exit or drive area; and H〇 is the glass at the inlet or suction area Shangdu. In each rotation or rotation, the 'Fig. 5' rotating device causes a volume of antegrade glass (31) VD to be displaced along the sides of the module toward the drive region (35) and through the central region, the rotating devices A volume of return glass (32) Vr is displaced at a rotational speed w toward the suction region or inlet (34); the displacement of the volumes produces a flow Qm in each module:

Qm = fi (w) · (Vd-Vr) (2) 161469.doc -12- 201233644 其中:f! (W)為視旋轉器件之旋轉速度而定之函數;Vd 為順行玻璃體積,VR為回流玻璃體積;且Qm為驅動模組 中玻璃之淨流動速率。 溢流道堪頂(36)之長度及高度Y〇對旋轉器件(29)所驅動 之玻璃移動構成阻礙,藉此熔融玻璃獲得液壓高度△11增 加,其可如下表示: ΔΗ = ΚΗ · w . μ . (VD-VR) (3) 其中:KH為常數:…為旋轉器件之旋轉速度;且μ為玻 璃之動態黏度。 對於驅動模組之既定寬度Lm,經驅動玻璃之順行理論體 積VD及回流玻璃體積Vr視旋轉器件之旋轉軸之間的距離 而定,此係根據可如下表示之比率: (Vd-Vr) = f2 (De) k2 (4) 其中:DE為旋轉器件之旋轉軸之間的距離;匕為常數; 且fZ(DE) h為視旋轉器件之幾何形狀、玻璃之動態黏度及 驅動模組中之玻璃高度而定之函數。 因此,液壓高度AH增加可如下表示: ΔΗ = KH · w · μ . f2 (De) k2 (5) 其中:KH為常數。在恆定黏度操作下’液壓高度增加可 藉由改變旋轉器件之旋轉速度w及/或旋轉器件之旋轉軸之 間的距離De來控制及調節。 藉由玻璃在驅動模組中因旋轉器件引起之移動而產生之 剪應力使嫁融玻璃中之現有異質性扭曲,從而使其厚度減 小。在由其速度梯度grad.v界定之速度場中經一定時段1具 161469.doc -13- 201233644 有初始厚度δΐ之異質性之變形由以下陳述式提供: δρ = δι / (t · grad, v) (6) 其中:δΡ為變形之最終厚度;δι為變形之初始厚度;t為 在速度場中變形存在之時間;且(grad.v = dv / dn)為平均 速度梯度Z/Vavdcf.· 「The Technology of Glass andQm = fi (w) · (Vd-Vr) (2) 161469.doc -12- 201233644 where: f! (W) is a function of the rotational speed of the rotating device; Vd is the antegrade glass volume and VR is the reflow Glass volume; and Qm is the net flow rate of the glass in the drive module. The length and height Y of the overflow passage (36) hinders the movement of the glass driven by the rotating device (29), whereby the molten glass obtains an increase in the hydraulic height Δ11, which can be expressed as follows: ΔΗ = ΚΗ · w . μ . (VD-VR) (3) where: KH is a constant: ... is the rotational speed of the rotating device; and μ is the dynamic viscosity of the glass. For a given width Lm of the drive module, the forward theoretical volume VD of the driven glass and the reflow glass volume Vr depend on the distance between the rotational axes of the rotating device, which is based on the ratio that can be expressed as follows: (Vd-Vr) = f2 (De) k2 (4) where: DE is the distance between the rotating axes of the rotating device; 匕 is a constant; and fZ(DE) h is the geometry of the rotating device, the dynamic viscosity of the glass, and the drive module The function of the height of the glass. Therefore, the increase in the hydraulic height AH can be expressed as follows: ΔΗ = KH · w · μ . f2 (De) k2 (5) where: KH is a constant. Under constant viscosity operation, the increase in hydraulic height can be controlled and adjusted by varying the rotational speed w of the rotating device and/or the distance De between the rotating axes of the rotating device. The shear stress generated by the movement of the glass in the drive module due to the rotation of the rotating device distorts the existing heterogeneity in the marshalled glass, thereby reducing its thickness. In a velocity field defined by its velocity gradient grad.v, a certain period of time 161469.doc -13- 201233644 has a variation of the initial thickness δΐ heterogeneity provided by the following statement: δρ = δι / (t · grad, v (6) where: δΡ is the final thickness of the deformation; δι is the initial thickness of the deformation; t is the time at which the deformation exists in the velocity field; and (grad.v = dv / dn) is the average velocity gradient Z/Vavdcf. "The Technology of Glass and

Ceramics」,Elsevier S. P. C·,農0 在本發明中’旋轉器件之主要目的在於控制及調節穿過 溢流道之玻璃之流量,且由此控制及調節最終薄片厚度。 另一方面,旋轉器件亦以類似於在當前先進技術下用於玻 璃製造之機械攪動器「攪拌器」之方式均化熔融玻璃;對 高品質玻璃之需求已允許使用攪拌器來降低異質性及/或 改良炫·融玻璃之熱均質性[抑/办⑽容「Glass Furnaces, Design Construction and Operation j , φ Society of Glass Technology Sheffield翻譯,^175 M] » 由驅動模組(27)中之旋轉器件(29)驅動之熔融玻璃越過 相應溢流道(36)之堰頂,且當其完全越過使驅動模組彼此 隔開之.侧壁(28)時,圖5及圖6,屬於投配組之所有驅動模 組(27)之玻璃流會合且因重力而自出口(37)以熔融玻璃扁 平流(38)之形式向下游流下,進入成型階段。 自出口(37)落下之具有均-厚度之熔融玻璃扁平流⑽ 的兩個扁平表面呈現不同狀態:a)外表面(4〇),圖7至圖 9,為「潔淨」的,此係因為熔融玻璃尚未與靜態固體材 料接觸;及b)與出口接觸之内表面(39),. 、’兩 不規則」的 且應在成型階段期間在藉助於「清潔」元件執行之操作中 161469.doc _ 14_ 201233644 加以改良及/或替換,該操作亦為本發明之一目的。 已在驅動模組中調節及投配之溶融玻璃流通過溢流道, 圖5通過各驅動模組之溢流道堰頂之熔融玻璃之流量遵 循以下陳述式:Ceramics, Elsevier S. P. C., Farm 0 In the present invention, the primary purpose of the rotating device is to control and regulate the flow of glass through the overflow channel, and thereby control and adjust the final sheet thickness. On the other hand, the rotating device also homogenizes the molten glass in a manner similar to the mechanical agitator "mixer" used in glass manufacturing in the current state of the art; the demand for high quality glass has allowed the use of a stirrer to reduce heterogeneity and / or the improvement of the heat homogeneity of the glass and the glass [Glass Furnaces, Design Construction and Operation j, φ Society of Glass Technology Sheffield translation, ^175 M] » by the rotation of the drive module (27) The molten glass driven by the device (29) passes over the dome of the corresponding overflow channel (36), and when it completely passes over the side wall (28) that separates the drive modules from each other, Figures 5 and 6 are assigned. The glass flow of all the drive modules (27) of the group meets and flows downward from the outlet (37) in the form of a flat flow (38) of molten glass due to gravity, and enters the molding stage. The average drop from the outlet (37) - The two flat surfaces of the flat stream of molten glass (10) exhibit different states: a) the outer surface (4 〇), and Figures 7 to 9 are "clean" because the molten glass has not been in contact with the static solid material; b) connected with the exit Touching the inner surface (39), . , 'two irregularities' and during the forming phase should be improved and/or replaced in the operation performed by means of the "clean" element 161469.doc _ 14_ 201233644, which is also One of the objects of the present invention. The flow of molten glass that has been adjusted and dosed in the drive module passes through the overflow passage. Figure 5 shows the flow of molten glass through the overflow dome of each drive module following the following statement:

Qm = K, . μ -1 . Lm . (Ηι.γ〇) 3/2 ⑺ 其中.Qm為通過驅動模組之玻璃之流量;μ為玻璃之動 態黏度;LM為驅動模組之寬度;^為驅動區域中玻璃液位 之南度,Y〇為溢流道堰頂之高度;且Κι為常數。 溢流道之每單位寬度之玻璃流量與最終薄片玻璃之厚度 直接相關’且對應於以下陳述式: q = Qm / lm (8) 其中:q為各驅動模組中每單位寬度之熔融玻璃流量。 上述方程式顯示每單位寬度之流量q為驅動模組及旋轉 器件之幾何形狀、玻璃之黏度、旋轉器件之旋轉速度…及 旋轉器件之旋轉軸之間的距離以之函數;其如下表示: 25 q = f [w, μ, DE] (9) 在使用單一投配組之本發明實施例中’所有驅動模組之 流量之總和等於玻璃薄片製造之總流量;對於構成投配組 之全部N個驅動模組,總流動速率為: Q = (Σ Qm) 1 a N (10) 其中:N為屬於投配組之驅動模組之數目;且Q為玻璃 製造之總流量,等於N個溢流之總和。 所有模組之寬度總和等於所製造之玻璃薄片之總寬度: L = (Σ Lm) 1 a n (11) -15- 161469.doc )·¥* 201233644 其中:L為最終薄片玻璃之總寬度,其基本上與構成投 配組之N個溢流之尺寸總和一致。 驅動模組可具有相同寬度Lm且投配相同流量qm,但邊 緣之模組可投配每單位表面不同之流動速率以有助於拉伸 操作。 在特定操作系統中,旋轉器件及溢流道之組由值H〇、 Η]、Y〇、w、μ、VD及VR界定’該等值產生各驅動模組中 之流量Qm ;此等值經確定以使標稱旋轉速度w足以:昀提 供玻璃流量投配之適當精確度;及b)產生熔融玻璃之充分 均化。因此,旋轉器件與玻璃流量調節元件及熔融玻璃基 質之均化元件同時起作用。 由於旋轉速度w及軸之間的距離De之變化,本發明方法 可進行比傳統「溢流下拉」法更加動態且更加精確之玻璃 流量控制及調節。 自方程式1、3及7,遵循在本發明製程中,玻璃之溫度 降低或黏度增加以彼此補償之兩種方式影響流量變化:a、 藉由增加ΔΗ,其間接增加Qm,此係因為當黏度μ增加 時’ ΔΗ增加(方程式3);及b)藉由增加叫方程式7),苴直接 降低QM。因&,在本發明製程中,溫度變化引起之玻璃 流量之變化小於「溢流下拉」法中之變化,在「溢流下 拉」法中黏度變化直接影響流量變化。 旋轉器件之旋轉速度w之變化以如下定義之係數(c^ 影響驅動模組中之玻璃流量q : (Cqw)i = (% Δ q / %Δ w) (12) 161469.doc -16 - 201233644 其中(Cqwh為當操作點F,處之速度變化時之流量變化係 數;為流量變化之百分比;且%^评為旋轉速度變化 之百分比。兩種變化% A q與。/。A w具有相同方向。 旋轉器件之旋轉軸之間的距離D E之變化以如下定義之係 數(CqDE)〗影響驅動模組中之玻璃流量q : (CqDE)i = (% Δ q / %Δ De) 〇3) 其中:為藉由在操作點匕處改變軸之間的距離而 引起之流量變化之係數;且% 為軸之間的距離變化 之百分比。兩種變化。/。△ (^與%〜具有相反方向。 使玻璃流量自qi、w〗及Dei所界定之初始操作狀態F】改 變至qZ、W2及Du所界定之最終操作狀態&藉由改變旋轉速 度w及/或改變旋轉軸之間的距離De來進行,由此遵照以下 比率: (㈣丨)/ q丨=% Δ w · (CqW) 1 +% △〜· (CqDE)i (14) 其中(q2-q 1) / Q1為流量q自操作點F j之相對變化。 本發明方法允許進行多種選擇以更改投配組之既定驅動 模組中每單位寬度之玻璃流量q,此等效於自流量qi、速 度%及軸之間的距離Dei所界定之操作點匕至 所界定之操作點ί?2 ,更改對應於該模組之區域中薄片玻璃 之最終厚度。此要求旋轉速度之變化0/〇Δ\ν及軸之間的距離 之逆化/。Δ DE應遵照上文所列之(方程式丨4)。 在驅動模組中驅動之玻璃流量之變化或更改主要視以下 而疋· a)模纟耳之幾何形狀;b)旋轉器件之幾何形狀;c)玻 璃之黏度’ d)輸入通道中玻璃之高度H〇; e)溢流道堪頂之 161469.doc •17- 201233644 高度Υ〇 ;及f)聯立之旋轉速度…與軸之間的距離De。一旦 確立模組及驅動器件之幾何形狀以及玻璃高度及溢流道堰 頂每單位寬度之玻璃流量q即遵循上文所述之方程式(9) 之陳述式。 方程式(9)之陳述式q = f [w,μ,De]由以下確定:勾藉由 數值計算,及b)藉由具有旋轉器件及溢流道之驅動模組之 物理模型化,且該陳述式代表黏度力、慣性力、重力及表 面張力。 一旦熔融玻璃已在屬於投配組(26)之各驅動模組(27)中 分配及投配且已通過各模組之溢流道(36),使各模組與鄰 近模組隔開之侧壁(28)即消失且已通過投配組(26)之所有 熔融玻璃再次會合,從而產生熔融玻璃扁平流(38),其因 重力而自出口(37)垂直滴落至成型器件,在此根據本發明 進行玻璃薄片製造之下一階段。 已知熔融玻璃可在稱為失透之過程中朝向形成穩定結晶 物質發展,該過程始於晶核形成且繼以此等晶體之生長; 失透視炫融玻璃維持處於低於「液相線溫度」tl之溫度下 之時長而定,且因此某種製造設備之有效壽命可受此失透 過程制約。在整個玻璃投配期中且甚至在形成玻璃扁平流 (38)之後,本發明方法使用高於失透溫度之溫度,使得投 配組之有效壽命並不視玻璃失透而定且僅由機械強度決 定,從而視諸如鉑、鍺或其任何合金之所用材料之時間而 定。 因重力而自出口(3 7)垂直落下,形成每單位寬度具有均 161469.doc -18- 201233644 一流動速率之熔融破璃 x 扁平流(38)之玻璃具有以下品質: a)尚未與溢流道之固徽从u 體材料接觸之外表面(40)為「潔淨」 的且可直接用於形成gp脸^ 卩將形成之玻璃薄片之兩個表面之 一,及b)已與溢流递及 -汉出口接觸之内表面(39)為不規則的 且不應成為玻璃薄片之最終表面之一部分。 在使用|才史配組之本發明方法之一些特定實施例中, 炼融玻璃扁平流(38)之外表面直接轉至形成玻璃薄片之外 表面之。Μ刀’且福平流(38)之内表面應使用清潔元件加 以改進’ W元件為件之—部分且定位於成型體 上方並與其隔開。本發明之其他特定實施例使用兩個不同 投配組,圖12,且存在兩股熔融玻璃扁平流〇8及61),其 兩個外表面直接形成最終玻璃薄片之兩個表面中之每一 者0 在圖3之概覽及圖7至圖9之詳細視圖中所示之本發明方 法之一特定實施例中,成型器件使用旋轉圓筒(41)作為清 潔7^件以改良或「清潔」扁平流(38)之已與出口(37)接觸 之内表面(39);圓筒(41)以速度评(:在圖中所指示之方向上 旋轉且位於熔融玻璃扁平流(38)下方及成型體(42)上方。 圓ι€紅轉對扁平流(38)之兩個表面的作用如下:a)「潔 淨」之外表面(40)直接轉至成型體(42)之位於高度Z3處之 第邊緣(43),及b)「不規則」之内表面(39)拖良至附著 於圓筒旋轉之玻璃基質内部。 自出口(3 7)落下之熔融玻璃扁平流(3 8)疊加於圓筒周邊 上存在之返回流(56)上’形成液流(53),其由圓筒驅動至 161469.doc •19- 201233644 重力與拖曳力相結合之區域,參見圖7。液流(53)之一部分 轉向成型體之位於高度Z3處之第一邊緣(43),且產生沿成 型體(42)之外側壁下降之液流(48);而液流(53)之其餘部分 形成液流(54),其在旋轉圓筒(41)與成型體(42)之間存在的 空間之間驅動’該空間為具有一定最小間隔(46)之空間。 液流(54)達到成型體之位於高度24處之第二邊緣(44)之高 度;液流(54)之一部分溢出邊緣(44)且產生液流(49),其沿 成型體(42)之另一外側壁落下。其餘玻璃流(54)由旋轉圓 筒(41)拖曳,形成附著於旋轉圓筒之液流(66),其轉向圓 筒拖曳力之方向與玻璃之重力之方向相反的區域;當熔融 玻璃到達玻璃上之重力類似於由旋轉圓筒(4丨)施加之拖曳 力的奇異區域(55)時,具有兩股不同液流之溶融玻璃之表 面上存在斷裂或剝落:a)一部分玻璃流(56)保持附著於旋 轉圓筒(41),且由其驅動直至接合熔融玻璃扁平流(38)之 不規則部分(39)為止且再次成為液流(53)之一部分,從而 循環結束;及b)另一部分玻璃轉向邊緣(44),形成沿成型 體(42)之外部不降之液流(49)之外表面。因此,液流(48及 49)之兩個表面(其將形成最終薄片(5〇)之表面)為潔淨的, 此係由於與出口(37)接觸之熔融玻璃(39)之粒子已併入液 流(53)中之熔融玻璃基質内部。 成型體(42)之上端部分可具有如圖7及圖8中之凹面 (45)’或可如圖9中一般平滑。同時,旋轉圓筒⑼可為: a)具有由_及/或諸如Zr〇2、八12〇3及祕之对火材料組成 之对久性核心的㈣,其帶有或不帶有含始、錄或其某種 161469.doc •20- 201233644 合金之外金屬塗層;或b)中空的且由翻、姥或含有舶及/或 姥之某種合金形成;或具有由翻及/或鶴組成之核心’帶 有含鉑或其合金之外塗層。 旋轉圓筒(41)由用於控制及調整旋轉速度WC之外部機械 構件使之旋轉,該旋轉速度WC為控制圓筒旋轉期間附著 於該圓筒之熔融玻璃層所需,且為調整該旋轉圓筒旋轉期 間施加於熔融玻璃粒子上之慣性力、黏度力及重力所需。 在本發明之一特定實施例中,當旋轉圓筒(41)為中空的 (圖7及圖8),且定位於在成型體(42)中切成之凹面(45)上 時’對應於圓筒重量及其上之玻璃重量的重力FG由圓筒 (41)移位之凹面(45)之玻璃所施加之浮力fe抵消;因此, 圓筒「浮」於熔融玻璃上且不會發生因其自身重量所引起 之變形。 在本發明之另一實施例中,當成型體之上端部分為平滑 的(圖9)且旋轉圓筒(41)定位於此表面上方時,重力fg不會 由浮力FE抵消,且旋轉圓筒表現為類似於兩端受支撐之弯 曲樑。 來自成型體(42)之邊緣(43及44)之兩股流(48及49)沿該成 型體之兩侧流動至其楔形底部區域,從而在其頂點(47)中 形成角度;在到達此頂點時,兩股流(48及49)接合形成單 股玻璃流,其由牵引構件(5丨)拉伸以產生最終薄片玻璃; 最終薄片接著用本文未展示之構件分割以獲得具有特定尺 寸之薄片玻璃。當沿成型體(42)之兩側通過時,兩股流(48 及49)經冷卻以到達具有適合黏度/溫度之頂點(27)以藉由 161469.doc -21 · 201233644 向下拉伸而使其成型。 每單位寬度具有均一流動速率之扁平熔融玻璃流(38)在 實質上類似之兩股流(48及49)之間的分配如下進行,參見 圖7: a)由固定高度Z3及Z4,成型體上邊緣之高度;b)藉 由改變圓筒與成型體(53)之凹面(52)之間的垂直間隔(58); c) 藉由改變玻璃落下軸與旋轉圓筒轴之間的水平間隔 EVC,及旋轉圆筒軸與成型體軸之間的水平間隔ecc ;及 d) 藉由改變旋轉圓筒之旋轉速度Wc。 在圖4之概覽及圖1〇之詳細視圖中所示之本發明方法之 另一實施例中,成型器件使用部分浸沒於玻璃中之板(52) 以清潔因與屬於投配組之出口(37)之基底接觸而產生之熔 融玻璃扁平流(38)之不規則表面(39);前述扁平流轉至部 刀浸/又於在成型體(4 2)中切成之凹面(45)中之板(52),且分 成兩股流:a)第一順行流(57),其通過位於高度4處之成 型體一側且產生沿成型體(42)之外側壁向下移動之液流 (48);及b)第二流(59),其佔據在成型體(42)中切成之凹面 (45)且在定位於距凹面(45)間隔一定距離(46)處之浸沒板 (52)下方通過;此第二流(59)朝向成型體之位於高度”處 之另-邊緣,且產生沿成型體(42)之另一外側壁向;移動 之液流(49)。成型體之凹面(45)之幾何形狀及浸沒板勾之 位置連同熔融玻璃之黏度在浸沒板(52)之背後部分中產生 漩渦流(58),其執行與出口接觸之表面 畀深」功能; 此為液"il (49)如同液流(48)—般為潔淨表面之原因 玻璃流(48及49)沿成型體(42)之壁流動,同時其經冷= 161469.doc •22· 201233644 到達下頂點(47),在此處兩股流接合形成單股玻璃流,其 由牵引構件(51)拉伸以形成薄片玻璃(5〇)。 每單位寬度具有均一流動速率之扁平溶融玻璃(3 8)在兩 股流(48及49)中之分配如下進行,參見圖1〇 : a)藉助於成 型體(42)之上邊緣之高度Zl&Z2 ;…藉由改變成型體(42)之 軸與板(52)上熔融玻璃之垂直滴落平面之間的水平距離 EPC,及c)藉由更改板(52)與成型體(42)之凹面(45)之間間 隔之垂直距離(46)。 本發明方法之另一貫施例使用單一熔爐使玻璃熔融,接 著使用兩個不同玻璃投配組’圖U之整體視圖及圖13之詳 細視圖;兩個投配組(26及60)各自包含若干驅動模組 (27),繼而,各驅動模組由分隔壁(28)、至少一個旋轉器 件(29)及溢流道組成。 對於各投配組,獲得每單位寬度具有均一流量之熔融玻 璃扁平流,且由此產生兩股玻璃扁平流(38及61),其在成 型體(64)之兩個側壁中之每一者上因重力而垂直落下。兩 股嫁融玻璃扁平流(38及61)之外表面直接來自已通過溢流 道之表面玻璃且為「潔淨」表面,同時在液流(62及63)中 仍保持潔淨,其隨後將形成最終玻璃薄片(5〇)之兩個表 面;來自已與溢流道基底接觸之玻璃之熔融玻璃扁平流 (38及61)之内表面在兩股流(62及63)内保持與成型體(64)之 壁接觸,隨後整合至最終玻璃薄片之内部。 兩股流(62及63)各自沿成型體(64)之各側壁下降,同時 當其接近成型體之下端部分時經冷卻◊成型體(64)結束於 161469.doc •23- 201233644 頂點(47),且當兩股側流(62及63)到達上述頂點時,其接 合形成具有適當黏度之單股玻璃流以由牽引輥(51)拉伸且 形成玻璃薄片(50);此薄片接著由本文未展示之構件分割 成特定物品或產品。 兩個投配組(26及60)由獨立於成型體(64)之結構的結構 (65)完全或部分支撐;兩個結構(64及65)可在彼此之間相 對移動以調整成型體(64)與相應出口(37)之間的距離,使 得扁平流(38及61)之垂直滴落為適當的。 在本發明方法之另一特定實施例中,所製造之薄片玻璃 由以玻璃薄片厚度之中央平面分隔之兩種不同玻璃A及B 組成。該製程始於(圖12)可玻璃化原材料A及B在熔融容器 (21及66)中融合,及熔融玻璃在容器(23及67)中精煉。此 後’玻璃A及B經驅動穿過通道(24及68),朝向投配組(26 及60);在通道(24及93)中,玻璃液位經由液位調節器(25 及69)保持恆定。投配組(26及60)各自包含若干驅動模組 (27);且繼而’各驅動模組由分隔壁(28)、至少一個旋轉 器件(29)及其自身之溢流道組成,使得各投配組獲得每單 位寬度具有均一流量之溶融玻璃扁平流,且由此產生兩股 玻璃扁平流(38及61),其在成型器件(64)之兩個側壁中之 每一者上因重力而垂直落下,且依照由兩種不同玻璃形成 之兩股熔融玻璃流(70及71)向下流動,液流(70)由玻璃A形 成且液流(71)由玻璃B形成。 兩股熔融玻璃扁平流(38及61)之外表面直接來自已通過 溢流道之表面玻璃,且為「潔淨」表面且在液流(70及71) 161469.doc -24· 201233644 中仍保持清潔,其隨後將形成最終玻璃薄片之兩個表面。 來自已與溢流道基底接觸之玻璃之熔融玻璃扁平流(38及 61)之内表面在兩股流(70及71)内保持與成型體(64)之壁接 觸,隨後整合至該最終玻璃薄片之内部玻璃基質中。 兩股流(70及71)各自沿成型體(64)之側壁下降,同時當 其接近末端部分時經冷卻;此末端部分在其頂點(47)中具 有角度,且當兩股側流(70及71)到達該頂點時,其接合形 成具有適合黏度之单股玻璃流以由牽引親(51)拉伸且形成 玻璃薄片(72),此薄片接著由本文未展示之構件分割成特 定物品或產品。最終薄片玻璃(72)由以玻璃薄片厚度之中 央平面分隔之兩種玻璃A及B形成,如圖12中所示。 兩個投配組(26及60)由獨立於成型體(64)之結構的結構 (65)完全或部分支撐;兩個結構(64及65)可在彼此之間相 對移動以調整成型體(64)與相應溢流道(36)之間的距離, 使得扁平流(38及61)之垂直滴落為適當的。 本發明製程中玻璃經歷失透溫度或「液相線溫度」TL之 位置或階段如下:a)在使用一個投配組之本發明實施例 中’且由此在成型階段中使用旋轉圓筒清潔元件(圖7至圖 9)或部分浸沒板(圖1 〇),一旦已形成側流(48及49),即達 到失透溫度,該等側流(48及49)沿成型體(42)之側面下 降,同時經冷卻;及b)在使用兩個投配組之本發明實施例 中,圖11至圖13,一旦已形成針對兩個投配組(26及60)中 之每一者的兩股熔融玻璃扁平流(38及61),即達到失透溫 度。兩股流移動至成型體(64),形成兩股側流(62及63), 161469.doc -25- 201233644 其沿該成型體(64)之外部下降,同時經冷卻。 熔融玻璃保持低於失透溫度之時長縮短,與獨立地且在 與冷卻階段不同之器件中進行熔融玻璃投配階段之實情相 結合,使得本發明方法使用之設備的有效壽命長於「溢流 下拉」製造法使用之設備的有效壽命。 結束於頂點(47)之成型體之下端區域之角度影響流量之 穩定性[H.-J.Lin, W.-1C. Chang.· 「Design of a sheet forming apparatus for overflow fusion process by numerical simulation j ; of Non-Crystalline Solids 353 (2007) 2817-252J] ’小角度賦予頂點上方之熔融玻璃流量以更高穩定 性,且本發明方法使頂點(47)能夠具有比「溢流下拉」法 使用之角度小的角度。 拉伸開始之頂點(47)處之較高黏度使流量更均一;然 而’黏度受玻璃失透溫度及玻璃保持低於此溫度之時長影 響。在本發明製程中,在玻璃薄片寬度上之玻璃分配在投 配組中進行,且成型體主要用於冷卻玻璃至拉伸溫度。本 發明方法之優勢係歸因於:a)在内部無玻璃流量約束之成 型體需要較小寬度,其使得頂點(47)處之角度較小;及b) 成型體之高度不受其機械強度及其下邊緣中之箭頭限制, 此係因為此等方面不會影響寬度中之玻璃分配,或同樣不 會影響最終薄片玻璃之厚度的均一性。 在本發明製程中’一旦熔融玻璃之兩股側流到達成型體 之下頂點(47),玻璃即由牵引輥(51)拉伸,而其同時經冷 卻直至變成一定厚度之連續固體薄片玻璃;在此拉伸製程 161469.doc •26· 201233644 中’由表面張力產生之力為不利的,傾向於產生所形成之 玻璃薄片之橫向收縮。 最後,玻璃由切割機分割以產生成品或產品所要之尺 寸。 本發明實例之詳細描述 在以下實例中,本發明方法用於製造2500 mm寬及〇.7〇 mm厚之薄片玻璃。所製造之玻璃之流動速率或提取率為 20公嘴/天。 自可玻璃化原材料熔融及精煉(均化及淨化)熔融玻璃係 根據習知方法依照用於玻璃之當前技術來進行,玻璃之黏 度/溫度比由以下值確定:(μ = 8000泊,Tv = 1321°C); (μ =16 000 泊,Τν = 1279。〇 ; (μ = 25000 泊,Τν = 1253 C),及(μ = 100000泊,τν = 1182。〇。其中:μ為玻 璃之動態黏度;且Τν為玻璃溫度。 在熔融及精煉後,熔融玻璃進入通道,圖2、圖3及圖 5’其設置有保持玻璃液位處於高度H〇處之液位調節器, 從而到達玻璃投配組之入口區域。投配組之此入口區域為 構成彼組之所有驅動模組共用;所有組之泵送係在相同溫 度下及自相同初始液壓高度H〇進行。在熱調節之後,玻璃 到達溫度為1321°C,亦即具有8〇〇〇泊之黏度的驅動模組區 域。 投配組或器件由以下組成:a)由始/錢側面隔板彼此隔開 之五個驅動模組’各模組包含兩個旋轉器件及溢流道;及 b)最終出口,其收集已通過各驅動模組之溢流道中之每一 161469.doc •27- 201233644 者的玻璃且將其以單股熔融玻璃扁平流之形式傾入成型階 段》 各驅動模組之寬度LM為5 00 mm ;抽吸通道中之玻璃高 度H〇由液位調節器確定,以使得驅動模組之操作條件使得 玻璃流越過溢流道,該溢流道之堰頂具有丨8〇 mm之高度 Y〇。 五個驅動模組由厚度為1.5 mm之中間隔板彼此隔開,且 由鉑/铑合金建構,且延續至溢流道之堰頂,在此處五個 模組之液流接合形成寬度為2500 mm之溶融玻璃扁平流。 在各驅動模組之橫截面中’定位外徑D等於220 mm之兩個 旋轉器件;兩個旋轉器件之旋轉軸之間的間隔%為18〇 mm,且連接旋轉轴之線垂直於驅動模組中玻璃之方向。 在各旋轉器件之軸之90 mm直徑的影響下,順行流通過之 寬度AD為230 mm且回流玻璃通過之寬度Ar為9〇 mm。 兩個旋轉器件之標稱旋轉速度你為6轉/分鐘;兩者以相 反方向旋轉,模組側面上玻璃之方向,參見圖5,及與中 心玻璃相反之方向。兩個旋轉器件之驅動葉片及軸由具有 80%鉑及20%铑之材料建構;各旋轉器件之重量為22 0。 在溫度、工作機械應力及鉑·铑合金耐久性之操作條件 下,各旋轉器件之持續時間為18個月。 旋轉器件之移動在各驅動模組中產生〇 〇〇〇46立方公尺/ 秒之回流玻璃流量’其為玻璃製造之流動速率的26倍。备 遭遇諸如溢流道之障料,由旋轉ϋ件驅動之破^加^ 液壓尚度Hl,該液壓高度Η丨限制順行驅動流量直至差異 161469.doc •28- 201233644 VD-VR等於玻璃製造流動速率為止。 玻璃保持處於各驅動模組中之平均時長為37分鐘;在此 時間内,兩個旋轉器件各自進行222次全轉,且各熔融玻 璃粒子已覆蓋63公尺之平均距離。在玻璃黏度μ = 8〇〇〇 泊,溢流道堰頂起點處玻璃通過之高度ζ〇為8 mm,旋轉器 件之軸之間的距離1^為18〇 mm,且旋轉器件之旋轉速度 為6rpm下,由Cqw及Cqde得到之值為: CQW = (% △ q / w) = 〇 91 ;隨著旋轉速度自6轉/分鐘 增至7轉/分鐘,流動速率增加Μ.?%。 CQDE = (% Δ q / %Δ DE) = -6.6 ;隨著旋轉軸之間的距離 自180 mm增至181 mm,流動速率降至3 6%。 在此等值下,當旋轉速度〜自6轉/分鐘增至6.5轉/分鐘 時,驅動模組中之流動速率自4公噸/天躍至4 31公噸/天, 且玻璃薄片之最終厚度自〇·7〇 111111躍至〇 75 mm。此相同作 用係藉由維持旋轉速度恆定於6轉/分鐘且使轴之間的距離 DE自180 mm減至177.8 mm而達成。 藉由使旋轉器件之軸之間的距離De自18〇 mm增至183 mm,且同時使速度自6轉/分鐘增至7轉/分鐘,驅動模組中 之流動速率自4公噸/天躍至41公噸/天,且玻璃薄片之最 終厚度自0.70 mm躍至0.72 mm。 驅動模組中玻璃溫度降低rc,自132rc至132〇。〇,使得 熔融玻璃之黏度自7982泊增至8114泊。對玻璃流動速率4 之衫響如下.a)在通過旋轉器件時,液壓高度ΔΗ增量增 加*其引起流動速率之第—變化心=i 5()% ;及…在通過 I61469.doc -29- 201233644 1.64% 溢流道時,黏度增加y起流動速率之第二變化^ 因此,溫度降低广C使流動速率降低qB==qB = 旋轉器件對驅動模組區域中之破璃溫度具有衰減作0用14%; 穿過既定驅動模組之流量的控制及調節對最 關區域令之厚度具有直接影響,此係因為來古。相 組之最終玻璃由相同成型器件組成 艇動模 伸。 成且由相问牽引構件拉 本發明方法藉由適當組合操作參數,Qm = K, . μ -1 . Lm . (Ηι.γ〇) 3/2 (7) where .Qm is the flow rate of the glass through the drive module; μ is the dynamic viscosity of the glass; LM is the width of the drive module; To drive the south of the glass level in the zone, Y〇 is the height of the overflow dome; and Κι is a constant. The glass flow per unit width of the overflow channel is directly related to the thickness of the final sheet glass' and corresponds to the following statement: q = Qm / lm (8) where: q is the flow per unit width of the molten glass flow in each drive module . The above equation shows that the flow rate q per unit width is a function of the geometry of the drive module and the rotating device, the viscosity of the glass, the rotational speed of the rotating device, and the distance between the rotating axes of the rotating device; it is expressed as follows: 25 q = f [w, μ, DE] (9) In the embodiment of the invention using a single dosing group, the sum of the flow rates of all the drive modules is equal to the total flow of the glass flakes; for all the N components constituting the dosing group Drive module, the total flow rate is: Q = (Σ Qm) 1 a N (10) where: N is the number of drive modules belonging to the dosing group; and Q is the total flow of glass manufacturing, equal to N overflows The sum of them. The sum of the widths of all modules is equal to the total width of the manufactured glass sheets: L = (Σ Lm) 1 an (11) -15- 161469.doc )·¥* 201233644 where: L is the total width of the final sheet glass, It is basically the same as the sum of the sizes of the N overflows that make up the dosing group. The drive modules can have the same width Lm and be dosed with the same flow rate qm, but the edge modules can be dispensed with different flow rates per unit surface to aid in the stretching operation. In a particular operating system, the group of rotating devices and overflow runners are defined by values H〇, Η], Y〇, w, μ, VD, and VR. 'The equivalent value produces the flow rate Qm in each drive module; It is determined that the nominal rotational speed w is sufficient: 昀 provides the appropriate accuracy of the glass flow dosing; and b) produces sufficient homogenization of the molten glass. Therefore, the rotating device functions simultaneously with the glass flow regulating element and the homogenizing element of the molten glass substrate. Due to the change in rotational speed w and the distance De between the axes, the method of the present invention allows for more dynamic and more accurate glass flow control and regulation than conventional "overflow pull-down" methods. From Equations 1, 3 and 7, following the process of the present invention, the temperature decrease or the increase in viscosity of the glass affects the flow change in two ways: a. By increasing ΔΗ, it indirectly increases Qm because of the viscosity. When Δ increases, 'ΔΗ increases (Equation 3); and b) by increasing the equation 7), 苴 directly reduces QM. Because &, in the process of the present invention, the change in the glass flow caused by the temperature change is smaller than the change in the "overflow pull-down" method, and the viscosity change directly affects the flow change in the "overflow pull-down" method. The change in the rotational speed w of the rotating device is as defined by the coefficient (c^ affecting the glass flow rate in the drive module q: (Cqw)i = (% Δ q / %Δ w) (12) 161469.doc -16 - 201233644 Where (Cqwh is the flow rate change coefficient when the speed is changed at the operating point F; is the percentage change of the flow rate; and %^ is rated as the percentage change of the rotational speed. The two changes % A q have the same as ./.A w Direction The change in the distance DE between the rotary axes of the rotating device affects the glass flow in the drive module by the coefficient (CqDE) as defined below: (CqDE)i = (% Δ q / %Δ De) 〇 3) Where: is the coefficient of flow change caused by changing the distance between the axes at the operating point ;; and % is the percentage change of the distance between the axes. Two variations. /. △ (^ and %~ have the opposite The direction of the glass is changed from the initial operational state F defined by qi, w and Dei to the final operational state defined by qZ, W2 and Du & by changing the rotational speed w and / or changing between the rotating axes The distance is De, so follow the following ratio: ((4)丨) / q丨=% Δ w · (CqW) 1 +% △~· (CqDE)i (14) where (q2-q 1) / Q1 is the relative change in flow rate q from the operating point F j. The method of the invention allows for multiple selections to change the intended drive module of the dosing group The glass flow rate q per unit width, which is equivalent to the operating point defined by the distance qi, the speed % and the distance between the axes Dei to the defined operating point ί?2, changing the area corresponding to the module The final thickness of the medium glass. This requires a change in the rotational speed of 0/〇Δ\ν and the inverse of the distance between the axes. Δ DE should follow the above (Equation 丨 4). In the drive module The change or change in the flow rate of the driven glass is mainly as follows: a) the geometry of the mold ear; b) the geometry of the rotating device; c) the viscosity of the glass 'd) the height of the glass in the input channel H〇; e) The overflow channel is topped by 161469.doc •17- 201233644 Height Υ〇; and f) The rotational speed of the joint...the distance De from the axis. Once the geometry of the module and drive components, as well as the glass height and the glass flow rate q per unit width of the overflow dome, are established, the equation of equation (9) described above is followed. The statement q = f [w, μ, De] of equation (9) is determined by: numerical calculation by buck, and b) physical modeling by a drive module having a rotating device and an overflow channel, and Statements represent viscosity, inertial force, gravity, and surface tension. Once the molten glass has been dispensed and dispensed in each of the drive modules (27) belonging to the dosing group (26) and has passed through the overflow channels (36) of the modules, the modules are separated from the adjacent modules. The side wall (28) disappears and all of the molten glass that has passed through the dosing group (26) rejoin, resulting in a flat flow (38) of molten glass that is vertically dripped from the outlet (37) to the forming device due to gravity. This is a stage under the manufacture of glass flakes in accordance with the present invention. It is known that molten glass can develop toward the formation of stable crystalline materials in a process called devitrification, which begins with nucleation and continues with the growth of such crystals; The duration of the temperature of tl depends on the length of time, and therefore the useful life of a certain manufacturing equipment can be limited by this devitrification process. The method of the invention uses a temperature above the devitrification temperature throughout the glass dosing period and even after the formation of the flat stream of glass (38), so that the effective life of the dosing group does not depend on the devitrification of the glass and only by mechanical strength The decision is based on the time of the material used, such as platinum, rhodium or any alloy thereof. The glass which falls vertically from the outlet (3 7) due to gravity and forms a molten glass x flat flow (38) having a flow rate of 161469.doc -18-201233644 per unit width has the following qualities: a) not yet overflowing The solid emblem of the road is "clean" from the surface (40) of the contact of the u body material and can be directly used to form one of the two surfaces of the glass sheet to be formed by the gp face, and b) has been delivered with the overflow The inner surface (39) of the contact with the Han outlet is irregular and should not be part of the final surface of the glass sheet. In some specific embodiments of the method of the invention using the genre group, the outer surface of the flat stream (38) of the fused glass is transferred directly to the outer surface of the glass sheet. The inner surface of the file 'and the flat flow (38) should be cleaned with a cleaning element to improve the portion of the 'W element' and positioned above and spaced apart from the molded body. Other specific embodiments of the invention use two different dosing sets, Figure 12, and there are two molten glass flat flow rafts 8 and 61), the two outer surfaces of which directly form each of the two surfaces of the final glass flake In a particular embodiment of the method of the invention illustrated in the overview of FIG. 3 and the detailed views of FIGS. 7-9, the forming device uses a rotating cylinder (41) as a cleaning element to improve or "clean" The inner surface (39) of the flat stream (38) that has been in contact with the outlet (37); the cylinder (41) is rotated at a speed (in the direction indicated in the figure and below the flat flow (38) of the molten glass and Above the molded body (42). The effect of the round red turn on the two surfaces of the flat flow (38) is as follows: a) The "clean" outer surface (40) is directly transferred to the molded body (42) at the height Z3. The inner edge (43) of the edge (43), and b) the "irregular" is dragged to the inside of the glass substrate that is rotated by the cylinder. The flat stream of molten glass (38) dropped from the outlet (37) is superimposed on the return stream (56) present on the periphery of the cylinder to form a liquid stream (53) which is driven by the cylinder to 161469.doc • 19- 201233644 The area where gravity and drag force are combined, see Figure 7. A portion of the liquid stream (53) is directed to the first edge (43) of the shaped body at a height Z3 and produces a liquid flow (48) that descends along the outer sidewall of the shaped body (42); while the remainder of the liquid flow (53) A portion of the forming liquid stream (54) drives the space between the rotating cylinder (41) and the shaped body (42) to have a space with a certain minimum spacing (46). The liquid stream (54) reaches the height of the second edge (44) of the shaped body at a height 24; one of the liquid streams (54) partially overflows the edge (44) and produces a liquid stream (49) along the shaped body (42) The other outer side wall falls. The remaining glass stream (54) is towed by the rotating cylinder (41) to form a liquid stream (66) attached to the rotating cylinder that deflects the direction of the cylinder drag force in the opposite direction of the gravity of the glass; when the molten glass reaches When the gravity on the glass is similar to the singular region (55) of the drag applied by the rotating cylinder (4丨), there is a break or spalling on the surface of the molten glass with two different streams: a) a portion of the glass stream (56) Keeping attached to the rotating cylinder (41) and driving it until it engages the irregular portion (39) of the flat flow (38) of molten glass and again becomes part of the liquid flow (53), thereby ending the cycle; and b) Another portion of the glass turns to the edge (44) to form an outer surface of the liquid stream (49) that does not fall along the exterior of the shaped body (42). Therefore, the two surfaces of the streams (48 and 49) which will form the surface of the final sheet (5〇) are clean, since the particles of the molten glass (39) in contact with the outlet (37) have been incorporated. The interior of the molten glass matrix in liquid stream (53). The upper end portion of the molded body (42) may have a concave surface (45)' as shown in Figs. 7 and 8 or may be generally smooth as shown in Fig. 9. At the same time, the rotating cylinder (9) can be: a) (4) having a permanent core composed of _ and/or such as Zr 〇 2, 八 12 〇 3 and secret materials for fire materials, with or without Or a certain 161469.doc •20- 201233644 alloy metal coating; or b) hollow and formed by turning, smashing or containing an alloy of some and/or sputum; or having a turn and/or The core of the crane consists of a coating containing platinum or its alloy. The rotating cylinder (41) is rotated by an external mechanical member for controlling and adjusting the rotational speed WC required to control the molten glass layer attached to the cylinder during rotation of the cylinder, and to adjust the rotation Required for inertial force, viscosity and gravity applied to the molten glass particles during rotation of the cylinder. In a particular embodiment of the invention, when the rotating cylinder (41) is hollow (Figs. 7 and 8) and positioned on the concave surface (45) cut into the shaped body (42), 'corresponds to The weight FG of the weight of the cylinder and the weight of the glass thereon is offset by the buoyancy fe applied by the glass of the concave surface (45) displaced by the cylinder (41); therefore, the cylinder "floats" on the molten glass without causing The deformation caused by its own weight. In another embodiment of the present invention, when the upper end portion of the molded body is smooth (Fig. 9) and the rotating cylinder (41) is positioned above the surface, the gravity fg is not offset by the buoyancy FE, and the rotating cylinder It behaves like a curved beam supported at both ends. Two streams (48 and 49) from the edges (43 and 44) of the shaped body (42) flow along the sides of the shaped body to its wedge-shaped bottom region to form an angle in its apex (47); At the apex, the two streams (48 and 49) are joined to form a single stream of glass that is stretched by the traction members (5 turns) to produce the final sheet glass; the final sheet is then divided by members not shown herein to obtain a particular size. Sheet glass. When passing along both sides of the shaped body (42), the two streams (48 and 49) are cooled to reach a vertex (27) having a suitable viscosity/temperature for downward stretching by 161469.doc -21 · 201233644 Make it shape. The distribution of the flat molten glass stream (38) having a uniform flow rate per unit width between substantially similar streams (48 and 49) is carried out as follows, see Figure 7: a) by fixed heights Z3 and Z4, shaped bodies The height of the upper edge; b) by changing the vertical spacing between the cylinder and the concave surface (52) of the shaped body (53) (58); c) by changing the horizontal spacing between the falling axis of the glass and the axis of the rotating cylinder EVC, and a horizontal interval ecc between the rotating cylinder shaft and the molded body shaft; and d) by changing the rotational speed Wc of the rotating cylinder. In another embodiment of the method of the invention illustrated in the overview of FIG. 4 and the detailed view of FIG. 1A, the forming device uses a plate (52) partially immersed in the glass to clean the exit and the outlet belonging to the dosing group ( 37) an irregular surface (39) of the flat flow (38) of the molten glass produced by the contact of the substrate; the flat flow is transferred to the partial knife immersion/in the concave surface (45) cut in the molded body (42) The plate (52) is divided into two streams: a) a first antegrade flow (57) which passes through the side of the shaped body at height 4 and produces a flow that moves downward along the outer sidewall of the shaped body (42). (48); and b) a second stream (59) occupying the concave surface (45) cut into the shaped body (42) and immersing the immersion plate at a distance (46) from the concave surface (45) ( 52) passing under; this second stream (59) is oriented towards the other edge of the shaped body at the height" and produces a flow along the other outer side wall of the shaped body (42); the moving liquid stream (49). The geometry of the concave surface (45) and the position of the immersion plate hook together with the viscosity of the molten glass create a vortex flow (58) in the back portion of the immersion plate (52), which is performed The surface of the mouth contact is deep" function; this is the liquid "il (49) as the liquid flow (48) is generally a clean surface because the glass flow (48 and 49) flows along the wall of the molded body (42) while After cooling = 161469.doc • 22· 201233644 the lower apex (47) is reached, where the two streams join to form a single stream of glass which is stretched by the traction member (51) to form a sheet glass (5 inch). The distribution of the flat molten glass (38) having a uniform flow rate per unit width in the two streams (48 and 49) is carried out as follows, see Fig. 1A: a) by means of the height of the upper edge of the shaped body (42) Zl&amp ;Z2;...by changing the horizontal distance EPC between the axis of the molded body (42) and the vertical drop plane of the molten glass on the plate (52), and c) by modifying the plate (52) and the molded body (42) The vertical distance (46) between the concave surfaces (45). Another embodiment of the method of the present invention uses a single furnace to melt the glass, followed by the use of two different glass dosing groups, the overall view of Figure U and the detailed view of Figure 13; the two dosing groups (26 and 60) each contain several The driving module (27), and then each driving module is composed of a partition wall (28), at least one rotating device (29) and an overflow channel. For each dosing group, a flat flow of molten glass having a uniform flow rate per unit width is obtained, and thereby two flat streams of glass (38 and 61) are produced, each of the two side walls of the shaped body (64) The upper part falls vertically due to gravity. The outer surfaces of the two flat glass streams (38 and 61) are directly from the surface glass that has passed through the overflow channel and are "clean" surfaces, while still remaining clean in the liquid streams (62 and 63), which will subsequently form The two surfaces of the final glass flake (5〇); the inner surface of the molten glass flat stream (38 and 61) from the glass that has been in contact with the overflow channel substrate remains in the two streams (62 and 63) with the shaped body ( 64) The wall contact is then integrated into the interior of the final glass sheet. The two streams (62 and 63) each fall along each side wall of the molded body (64) while the cooled ◊ shaped body (64) ends when it approaches the lower end portion of the molded body at 161469.doc • 23- 201233644 apex (47 And when the two side streams (62 and 63) reach the apex, they join to form a single stream of glass having the appropriate viscosity to be stretched by the pulling rolls (51) and form a glass sheet (50); Components not shown in this article are segmented into specific items or products. The two dosing groups (26 and 60) are fully or partially supported by a structure (65) that is independent of the structure of the shaped body (64); the two structures (64 and 65) are relatively movable between each other to adjust the shaped body ( 64) The distance from the respective outlet (37) such that the vertical drops of the flat streams (38 and 61) are appropriate. In another particular embodiment of the method of the invention, the sheet glass produced consists of two different glasses A and B separated by a central plane of the thickness of the glass sheet. The process begins with (Fig. 12) the vitrifiable materials A and B are fused in the melting vessels (21 and 66) and the molten glass is refined in the vessels (23 and 67). Thereafter, 'glasses A and B are driven through the channels (24 and 68) towards the dosing group (26 and 60); in the channels (24 and 93), the glass level is maintained via the level regulators (25 and 69) Constant. The dosing groups (26 and 60) each comprise a plurality of drive modules (27); and then each drive module consists of a partition wall (28), at least one rotating device (29) and its own overflow channel such that each The dosing group obtains a flat flow of molten glass having a uniform flow rate per unit width, and thereby produces two flat streams of glass (38 and 61) which are gravity-dependent on each of the two side walls of the forming device (64) While falling vertically, and flowing downward according to two streams of molten glass (70 and 71) formed of two different glasses, the liquid stream (70) is formed of glass A and the liquid stream (71) is formed of glass B. The outer surfaces of the two streams of molten glass (38 and 61) are directly from the surface glass that has passed through the overflow channel and are "clean" surfaces and remain in the liquid flow (70 and 71) 161469.doc -24· 201233644 Cleaning, which will then form the two surfaces of the final glass sheet. The inner surface of the molten glass flat stream (38 and 61) from the glass that has been in contact with the overflow channel substrate remains in contact with the wall of the shaped body (64) in both streams (70 and 71) and is subsequently integrated into the final glass. The inner glass matrix of the sheet. The two streams (70 and 71) each descend along the sidewall of the shaped body (64) while being cooled as it approaches the end portion; this end portion has an angle in its apex (47) and when two sides flow (70) And 71) when it reaches the apex, it joins to form a single stream of glass having a suitable viscosity for stretching by the traction parent (51) and forming a glass sheet (72) which is then divided into specific articles by components not shown herein or product. The final sheet glass (72) is formed of two kinds of glasses A and B separated by a central plane of the thickness of the glass sheet as shown in Fig. 12. The two dosing groups (26 and 60) are fully or partially supported by a structure (65) that is independent of the structure of the shaped body (64); the two structures (64 and 65) are relatively movable between each other to adjust the shaped body ( 64) The distance from the respective overflow passage (36) is such that vertical dripping of the flat streams (38 and 61) is appropriate. The position or stage at which the glass undergoes the devitrification temperature or "liquidus temperature" TL in the process of the present invention is as follows: a) in an embodiment of the invention using a dosing group' and thereby using a rotating cylinder for cleaning during the forming stage Element (Fig. 7 to Fig. 9) or partial immersion plate (Fig. 1 〇), once the lateral flow (48 and 49) has been formed, the devitrification temperature is reached, and the side flows (48 and 49) are along the molded body (42) The sides are lowered while being cooled; and b) in the embodiment of the invention using two dosing sets, Figures 11 to 13 once formed for each of the two dosing groups (26 and 60) The two streams of molten glass (38 and 61) reach the devitrification temperature. The two streams move to the shaped body (64), forming two side streams (62 and 63), 161469.doc -25-201233644 which descend along the exterior of the shaped body (64) while being cooled. The duration of the molten glass remaining below the devitrification temperature is shortened, combined with the fact that the molten glass dosing phase is carried out independently and in a different device from the cooling stage, so that the equipment used in the method of the invention has an effective life longer than "overflow" Pull down the effective life of the equipment used in the manufacturing process. The angle of the lower end region of the molded body which ends at the apex (47) affects the flow stability [H.-J. Lin, W.-1C. Chang.· "Design of a sheet forming apparatus for overflow fusion process by numerical simulation j ; of Non-Crystalline Solids 353 (2007) 2817-252J] 'The small angle gives the molten glass flow above the apex a higher stability, and the method of the invention enables the apex (47) to be used than the "overflow pulldown" method The angle is small. The higher viscosity at the apex of the beginning of the stretch (47) makes the flow more uniform; however, the viscosity is affected by the glass devitrification temperature and the length of time the glass remains below this temperature. In the process of the present invention, the glass distribution over the width of the glass sheet is carried out in the dosing group, and the shaped body is mainly used to cool the glass to the stretching temperature. The advantages of the method of the invention are due to: a) the molded body without internal glass flow restriction requires a smaller width, which makes the angle at the apex (47) smaller; and b) the height of the shaped body is not affected by its mechanical strength The arrow in its lower edge limits this because it does not affect the glass distribution in the width or the uniformity of the thickness of the final sheet glass. In the process of the present invention, 'once the two side streams of the molten glass reach the apex (47) below the shaped body, the glass is stretched by the pulling roll (51) while it is cooled until it becomes a continuous solid sheet glass of a certain thickness; In this drawing process 161 469.doc • 26· 201233644 'the force generated by the surface tension is unfavorable, tending to produce a transverse contraction of the formed glass flakes. Finally, the glass is divided by a cutter to produce the desired size of the finished product or product. DETAILED DESCRIPTION OF EXAMPLES OF THE INVENTION In the following examples, the process of the present invention was used to make sheet glass having a width of 2500 mm and a thickness of 〇.7 mm. The flow rate or extraction rate of the produced glass was 20 mp/day. The melting and refining (homogenization and purification) of the vitrified raw material is carried out according to the prior art according to the prior art for glass. The viscosity/temperature ratio of the glass is determined by the following values: (μ = 8000 poise, Tv = 1321°C); (μ = 16 000 poise, Τν = 1279. 〇; (μ = 25000 poise, Τν = 1253 C), and (μ = 100000 poise, τν = 1182. 〇. where: μ is the dynamic of the glass Viscosity; and Τν is the glass temperature. After melting and refining, the molten glass enters the channel. Figure 2, Figure 3 and Figure 5' are provided with a liquid level regulator that maintains the glass level at a height H〇, thus reaching the glass. The entrance area of the matching group. The entrance area of the dosing group is shared by all the drive modules constituting the group; the pumping system of all the groups is performed at the same temperature and from the same initial hydraulic height H〇. After the heat adjustment, the glass The arrival temperature is 1321 ° C, that is, the drive module area with a viscosity of 8 Torr. The dosing group or device consists of the following: a) five drive modules separated from each other by the start/money side partition 'The modules contain two rotating devices and overflow channels And b) the final exit, which collects the glass of each of the 161469.doc •27-201233644 that has passed through the overflow of each drive module and pours it into the forming stage as a single stream of molten glass. The width LM of the drive module is 500 mm; the height H of the glass in the suction channel is determined by the level regulator so that the operating conditions of the drive module cause the glass flow to pass over the overflow channel, the dome of the overflow channel It has a height of 〇 8〇mm Y〇. The five drive modules are separated from each other by a spacer with a thickness of 1.5 mm and are constructed of platinum/rhodium alloy and extend to the dome of the overflow channel where the flow of the five modules is formed to a width of 2500 mm molten glass flat flow. In the cross section of each drive module, 'the two rotating devices whose outer diameter D is equal to 220 mm are positioned; the interval between the rotating shafts of the two rotating devices is 18〇mm, and the line connecting the rotating shafts is perpendicular to the driving mode The direction of the glass in the group. Under the influence of the 90 mm diameter of the shaft of each rotating device, the antegrade flow through has a width AD of 230 mm and the width of the reflow glass through Ar is 9 〇 mm. The nominal rotational speed of the two rotating devices is 6 rpm. Both rotate in opposite directions, the direction of the glass on the side of the module, see Figure 5, and the opposite direction to the center glass. The drive blades and shafts of the two rotating devices are constructed of a material having 80% platinum and 20% bismuth; each rotating device weighs 22 0. The duration of each rotating device was 18 months under operating conditions of temperature, working mechanical stress and durability of the platinum-rhodium alloy. The movement of the rotating device produces a return glass flow of 〇 46 m3/s in each drive module, which is 26 times the flow rate of glass manufacturing. It encounters obstacles such as overflow passages, which are driven by the rotating element, and the hydraulic pressure Hl, which limits the forward flow rate until the difference is 161469.doc •28- 201233644 VD-VR is equal to glass manufacturing The flow rate is up to now. The average length of time that the glass remains in each of the drive modules is 37 minutes; during this time, the two rotating devices each perform 222 full revolutions, and each molten glass particle has covered an average distance of 63 meters. In the glass viscosity μ = 8 〇〇〇, the height of the glass passing through the top of the overflow channel is 8 mm, the distance between the axes of the rotating device is 18 〇 mm, and the rotational speed of the rotating device is At 6 rpm, the values obtained by Cqw and Cqde are: CQW = (% Δ q / w) = 〇91; as the rotation speed increases from 6 rpm to 7 rpm, the flow rate increases by Μ.?%. CQDE = (% Δ q / %Δ DE) = -6.6 ; The flow rate decreases to 3 6% as the distance between the rotating axes increases from 180 mm to 181 mm. At this value, when the rotation speed is increased from 6 rpm to 6.5 rpm, the flow rate in the drive module jumps from 4 metric tons per day to 4 31 metric tons per day, and the final thickness of the glass flakes is 〇·7〇111111 jumps to 〇75 mm. This same effect is achieved by maintaining the rotational speed constant at 6 revolutions per minute and reducing the distance DE between the shafts from 180 mm to 177.8 mm. By increasing the distance De between the shafts of the rotating device from 18 mm to 183 mm and simultaneously increasing the speed from 6 rpm to 7 rpm, the flow rate in the drive module is from 4 metric tons per day. To 41 metric tons per day, and the final thickness of the glass flakes jumped from 0.70 mm to 0.72 mm. The glass temperature in the drive module is reduced by rc from 132rc to 132〇. 〇, the viscosity of the molten glass increased from 7982 poise to 8114 poise. The response to the glass flow rate 4 is as follows. a) The hydraulic height ΔΗ increases as it passes through the rotating device* which causes the first change in the flow rate = i 5 ()%; and... passes I61469.doc -29 - 201233644 1.64% When the overflow channel is increased, the viscosity increases by y and the second change of the flow rate. Therefore, the temperature decreases and the C decreases the flow rate. qB==qB = The rotating device has an attenuation of the glass temperature in the drive module area. 0 with 14%; The control and adjustment of the flow through the given drive module has a direct impact on the thickness of the most critical area, which is because of the ancient times. The final glass of the phase group consists of the same molded device. Pulling and pulling by the interrogating traction member, the method of the present invention, by appropriately combining the operating parameters,

郎玻璃之流動速率成為可能;將(方程式14)應用 Z 得到以下關係: W例 (△q/q) = 0.91 ·%“_66 ·%δ〇ε。 -旦溶融玻璃接近溢流道之堰頂且處於兩個旋轉器件之 影響之外,側面隔板即消失,且已通過驅動模組之溢流道 之所有玻璃接合形成熔融玻璃扁平流,其流動直至通過出 口,同時其自外部藉由輕射而冷卻。 來自溢流道之溶融玻璃扁平料在旋轉圓筒上,該旋轉 圓筒對已與出口接觸之扁平流表面執行清潔元件之功能。 玻璃以16GGG泊之黏度、在1279t之溫度下通過旋轉圓筒 之區域/亦即,a亥玻璃之溫度比屬於驅動模組之旋轉器件 之區域中之溶融玻璃之溫度低43它。 圖7及圖8之詳細視圖描繪以包含旋轉圓筒之清潔元件及 成型體形成之器件;該成型體之寬度為20 cm且在其上端 硭幺中具有深度為14 cmi凹面;旋轉圓筒由鉑_铑合金製 成且具有12 cm之外徑及2 mm之厚度。假定密度對應於鉑_ 161469.doc 201233644 铑合金’熔融玻璃密度為2·60公克/立方公分且旋轉圓筒之 非浸沒區域上之玻璃的平均厚度為15 mm,則中空圓筒浮 於成型體凹面中所含之熔融玻璃上,浸深為55 mm。旋轉 圓筒之旋轉速度為0.5轉/分鐘》 • 定位於成型體凹面之靜態壁與浸入玻璃中之旋轉圓筒部 分之動態壁之間的玻璃之剪切迫使旋轉圓筒經受149牛頓 之總扭力。 一旦旋轉圓筒已改良或「清潔」炫融玻璃扁平流之下表 面且形成通過成型體上邊緣之兩股玻璃流,熔融玻璃即沿 該成型體之兩侧t之每一者流動。此區域中玻璃之黏度為 24000泊,對應M 1255»C之溫度。接著,沿成型體之每一 側流下之兩股流經冷卻以到達下頂點,其黏度為1〇〇,〇〇〇 泊,對應於1182°c之溫度;在此處,兩股玻璃流接合在一 起以形成薄片熔融玻璃。成型體之垂直高度為81 cm,且 玻璃溫度以每公分成型體高度〇 .9。〇之速率降低。 在成型體之下頂點中,熔融玻璃薄片由牽引輥拉伸以形 成連續固體薄片玻璃,其接著經分割以獲得既定尺 平薄片玻璃。 • 【圖式簡單說明】 • 圖根據用於製造薄片玻璃之「溢流下拉」之當前先進 技術之成型器械「封閉式隔熱管」的視圖及橫截面。 02.-根據本發明方法製造薄片玻璃之裝置的透視圖。 圖3:-具有具驅動模組之投配組及設置有旋轉圓筒清潔元 件之成型器件之製造系統的概覽。 161469.doc 201233644 圖4·-具有具驅動模組之投配組及設置有浸沒板清潔元件 之成型器件之製造系統的概覽。 圖5.-具有兩個旋轉器件之玻璃驅動模組之縱剖面及平面 圖。 圖6·-具有單一旋轉器件之玻璃驅動模組之縱剖面及平面 圖。 圖7.-浮於成型體之上端凹面部分中所含之熔融玻璃上之 旋轉圓筒清潔元件的視圖。 圖8.-旋轉圓筒清潔元件之視圖及在上端區域中具有凹面 且在高度與寬度之間具有較高比率之成型體上操作之細 節。 圖9·-末端觉支撲之旋轉圓筒清潔元件之視圖,及其在具 有扁平上端部分之成型體上操作之細節。 圖10·-浸沒板清潔元件之視圖及其在成型體上操作之細 節。 圖11.-具有用於來自單一熔爐之相同玻璃之兩個投配組 且具有配備有成型體之成型器件之製造系統的整體圖及部 分視圖。 圖12.-具有用於來自@個不同炼爐之兩種玻璃之兩個投 配組且具有成型器件之製造系統的整體圖及部分視圖,及 由兩種不同玻璃構成之最終薄片玻璃之厚度的放大詳細視 圖。 圖13·-具有驅動模組、旋轉器件及溢流道之兩個投配組 以及成型體之橫截面之視圖。 161469.doc -32- 201233644 【主要元件符號說明】 21 熔融容器 22 可玻璃化材料 23 精煉容器 24 輸入通道 25 液位調節器 26 投配組A 27 玻璃驅動模組 28 驅動模組隔離壁 29 旋轉器件 30 旋轉器件之葉片 31 順行玻璃體積 32 回流玻璃體積 33 驅動模組基底基礎結構 34 抽吸區域 35 驅動區域 36 溢流道 37 出口 38 、熔融玻璃扁平流 39 不規則内表面 40 潔淨外表面 41 旋轉圓筒清潔元件 42 成型體 43 成型體之第一邊緣 161469.doc -33- 201233644 44 成型體之第二邊緣 45 成型體之凹面 46 旋轉圓筒與成型體之間的最小間隔 47 成型體之下頂點 48 穿過成型體第一側之液流 49 穿過成型體第二側之液流 50 最終薄片玻璃 51 牵引輥 52 浸沒板清潔元件 53 旋轉圓筒上之順行流 54 旋轉圓筒與成型體之間的液流 55 旋轉圓筒上之玻璃中之奇異點 56 旋轉圓筒上之返回流 57 浸沒板中之順行流 58 浸沒板之後之漩滿 59 浸沒板中之第二流 60 投配組B 61 第二熔融玻璃扁平流 62 成型體側面上之玻璃流 63 成型體側面上之玻璃流 64 成型體 65 支撐結構 66 熔融爐B 67 精煉容器B 161469.doc • 34· 201233644 68 69 70 71 72The flow rate of Lang glass is possible; applying Z to (Equation 14) gives the following relationship: W case (Δq/q) = 0.91 ·% "_66 ·%δ〇ε. - Once the molten glass approaches the dome of the overflow channel In addition to the effects of the two rotating devices, the side partitions disappear and all of the glass that has passed through the overflow of the drive module engages to form a flat flow of molten glass that flows through the outlet while being lightly externally The molten glass flat material from the overflow channel is on a rotating cylinder that performs the function of the cleaning element on the flat flow surface that has been in contact with the outlet. The glass has a viscosity of 16 GGG, at a temperature of 1279 t. By rotating the area of the cylinder / that is, the temperature of the a glass is lower than the temperature of the molten glass in the area of the rotating device belonging to the drive module. The detailed views of Figures 7 and 8 are depicted to include a rotating cylinder. a device for forming a cleaning element and a molded body; the molded body has a width of 20 cm and a concave surface having a depth of 14 cmi in the upper end ;; the rotating cylinder is made of a platinum-iridium alloy and has an outer diameter of 12 cm and 2 Thickness of mm Assuming that the density corresponds to platinum _ 161469.doc 201233644 铑 alloy 'molten glass density is 2·60 gram / cubic centimeter and the average thickness of the glass on the non-immersed area of the rotating cylinder is 15 mm, the hollow cylinder floats on the molded body On the molten glass contained in the concave surface, the immersion depth is 55 mm. The rotation speed of the rotating cylinder is 0.5 rpm. • Between the static wall of the concave surface of the molded body and the dynamic wall of the rotating cylindrical portion immersed in the glass The shearing of the glass forces the rotating cylinder to withstand a total torque of 149 Newtons. Once the rotating cylinder has been modified or "cleaned" to the lower surface of the flat flow of the molten glass and forms two streams of glass through the upper edge of the shaped body, the molten glass is Flows along each of the two sides t of the molded body. The viscosity of the glass in this area is 24,000 poise, which corresponds to the temperature of M 1255»C. Then, the two streams flowing down each side of the molded body are cooled to reach the lower apex with a viscosity of 1 〇〇, anchored, corresponding to a temperature of 1182 ° C; where the two glass streams are joined Together to form a sheet of molten glass. The vertical height of the molded body was 81 cm, and the glass temperature was 〇.9 per cm of the molded body. The rate of sputum is reduced. In the apex below the shaped body, the molten glass flakes are stretched by a pulling roll to form a continuous solid sheet glass which is then divided to obtain a predetermined flat sheet glass. • [Simplified Schematic] • The view is based on the view and cross-section of the “closed insulated pipe” of the molding tool used to manufacture the “overflow pull-down” of sheet glass. 02. - Perspective view of a device for making sheet glass in accordance with the method of the present invention. Figure 3: Overview of a manufacturing system with a dosing set with a drive module and a shaped device with a rotating cylinder cleaning element. 161469.doc 201233644 Figure 4 - Overview of a manufacturing system with a dosing set with drive modules and a molded device with immersion plate cleaning elements. Figure 5. Longitudinal section and plan view of a glass drive module with two rotating devices. Figure 6 - Longitudinal section and plan view of a glass drive module with a single rotating device. Figure 7. - View of the rotating cylinder cleaning element floating on the molten glass contained in the concave portion of the upper end of the molded body. Figure 8. - View of the rotating cylinder cleaning element and details of the operation on the shaped body having a concave surface in the upper end region and a higher ratio between height and width. Figure 9 is a view of the rotating cylinder cleaning element of the end spur and its details of operation on a shaped body having a flat upper end portion. Figure 10 - View of the immersion plate cleaning element and details of its operation on the molded body. Figure 11. - Overall view and partial view of a manufacturing system having two dosing sets for the same glass from a single furnace and having shaped devices equipped with shaped bodies. Figure 12. - Overall and partial view of a manufacturing system with two dosing sets for two glasses from @ different furnaces and with a shaped device, and the thickness of the final sheet glass consisting of two different glasses Magnified detailed view. Figure 13 - View of the cross section of the two dosing groups with drive module, rotating device and overflow channel and the shaped body. 161469.doc -32- 201233644 [Main component symbol description] 21 Melting vessel 22 Vitrification material 23 Refining vessel 24 Input channel 25 Level regulator 26 Dosing group A 27 Glass drive module 28 Drive module partition wall 29 Rotation Device 30 Rotating device blade 31 Orthogonal glass volume 32 Reflow glass volume 33 Drive module base structure 34 Suction area 35 Drive area 36 Overflow path 37 Outlet 38, Molten glass flat flow 39 Irregular inner surface 40 Clean outer surface 41 Rotating cylinder cleaning element 42 Molding body 43 First edge of the molded body 161469.doc -33- 201233644 44 Second edge of the molded body 45 Concave surface 46 of the molded body Minimum spacing between the rotating cylinder and the molded body 47 Molded body The lower apex 48 passes through the liquid flow 49 on the first side of the shaped body through the liquid flow 50 on the second side of the shaped body. Final sheet glass 51 traction roll 52 immersion plate cleaning element 53 antegrade flow on the rotating cylinder 54 rotating cylinder The flow 55 with the molded body rotates the singular point 56 in the glass on the cylinder. The return flow on the rotating cylinder 57 is submerged In the antegrade flow 58 vortex after the immersion plate 59 second flow in the immersion plate 60 dosing group B 61 second molten glass flat flow 62 glass flow on the side of the molded body 63 glass flow on the side of the molded body 64 molding Body 65 Support structure 66 Melting furnace B 67 Refining vessel B 161469.doc • 34· 201233644 68 69 70 71 72

玻璃通道B 液位調節器B 玻璃流A 玻璃流B 由兩種玻璃A及B形成之最終薄片 161469.doc -35-Glass Channel B Level Regulator B Glass Flow A Glass Flow B Final sheet formed from two glasses A and B 161469.doc -35-

Claims (1)

201233644 七、申請專利範圍: 1. 一種用於製造薄片玻璃之方法,其特徵在於其包含以下 步驟: (a) 使用熔融爐,自可玻璃化原材料熔融均化及淨化熔 . 融玻璃; (b) 經由玻璃投配器件,使來自熔融爐之熔融玻璃基質 轉變成每單位寬度具有均-流動速率之炫融玻 流; (0藉助於包含清潔元件、成型體及牵引構件之成型器 件,自來自投配器件之熔融玻璃扁平流形成連續固體薄 片玻璃; (d)使連續固體薄片玻璃分割成既定尺寸之物品; 且:中,在經由成型器件自熔融玻璃扁平流形成連續 固體薄片玻璃中’使用由旋轉圓筒組成之清潔元件。 2·如請求们之用於製造薄片玻璃之方法’其中在經由成 型器件’自來自投配器件之熔融玻璃扁平流形成連續固 體薄片破璃中’使用由部分浸人該玻璃中之板組成之 潔元件。 .3. 一種用於製造薄片玻璃之方法,其特徵在於其包含以下 步驟: (a) 藉助於熔融爐,自可玻璃化原材料熔融、均化及 化單一熔融玻璃; (b) 使用兩個玻璃投配器件,使來自熔融爐之熔融玻璃 土質轉變成每單位寬度具有均—流量之兩股溶融玻璃扁 161469.doc 201233644 平流; (C)使用包含所形成之成型體及牵引構件之成型器件, 自來自兩個投配器件之兩股熔融玻璃扁平流形成連續固 體薄片玻璃; (d)使連續固體薄片玻璃分割成既定尺寸之物品; 且其中該玻璃薄片係由單一玻璃形成。 4· 一種用於製造薄片玻璃之方法,其包含以下步驟·· (a) 藉助於兩個熔融爐,自可玻璃化原材料熔融均化及 淨化兩種不同的熔融玻璃; (b) 使用兩個玻璃投配器件,使來自兩個熔融爐之兩個 熔融玻璃基質轉變成每單位寬度具有均一流量之兩股熔 融玻璃扁平流; (0使用包含成型體及牵引構件之成型器件,自來自兩 個投配器件之兩股熔融玻璃扁平流形成連續固體薄片玻 璃; (d)使連續固體薄片玻璃分割成既定尺寸之物品; 且其中該玻璃薄片係由兩種不同玻璃構成,該兩種不 同玻璃各自佔據該玻璃薄片之厚度的一半。 5. —種用以使熔融玻璃基質轉變成每單位寬度具有均一流 量之熔融玻璃扁平流,且可用於如請求項〗至4之用於製 造薄片玻璃之方法中的玻璃投配器件,其特徵在於其包 含: (a) 來自熔融爐之熔融玻璃之入口區域; (b) —組彼此獨立之若干熔融玻璃推進模組,各模組係 161469.doc 201233644 由至j/ 一個玻璃推進旋轉器件組成,該至少一個玻璃推 進旋轉器件具有用於控制該旋轉器件之旋轉速度及該旋 轉器件之旋轉軸相對於其所安裝之該推進模組之側壁之 位置的構件; (C)各驅動模組上之溢流道,其獨立於對應於其餘玻璃 驅動模組之其餘溢流道;及 (d)共用出口,來自該等驅動模組之該等溢流道中之每 一者之熔融玻璃流經該共用出口且以每單位寬度具有均 一流量之扁平熔融玻璃流之形式傾倒。 6. 如請求項5之玻璃投配器件,其中該等玻璃推進模組中 之任一者中之旋轉器件之數目為兩個。 7. 如請求項5及6之玻璃投配器件,其中該等旋轉器件之旋 轉速度及/或料旋轉科之料⑽轴之位置的變化使 得°亥熔融玻璃在其相應推進模組中產生液壓高度變化, 且修改通過該推進模組之該溢流道之熔融玻璃的流動速 率。 8·如請求項5至7之玻璃投配組,其中該等推進模組與該等 旋轉器件之間的分隔壁完全或部分由銘、錄或始或姥合 金製成。 9. 一種經製造以使熔融玻璃扁平流轉變成連續固體薄片玻 璃且可用於如請求項1及2之用於製造薄片玻璃之方法 中的成型器件,其特徵在於其包含: ()/月潔元件,其用以改良該熔融玻璃扁平流之兩個表 面之一; 161469.doc 201233644 (b)成里體,其疋位於該清潔元件下方且兩股玻璃流沿 其兩個側壁流動’當該兩股玻璃流朝向下端部分移動時 逐漸經冷卻,該成型體具有頂點向下之楔形末端,在該 頂點處兩股側流接合形成單一熔融玻璃薄片; ⑷牽㈣件,其詩拉㈣自.成型體之該下頂點之炼 融玻璃薄片,直至變成連續固體薄片玻璃; 且其中該清潔元件係由定位於成型體之上端區域上方 之旋轉圓筒組成’其具有用於控制該圓筒之旋轉速度及 該圓筒相對於該成型體之位置的構件。 如明求項9之用以使熔融玻璃扁平流轉變成連續固體薄 片玻璃之成型器件,其中該清潔元件係由部分浸入該成 型體之上端部分中之板形成。 11. 一種用以使來自兩個玻璃投配器件之兩股熔融玻璃扁平 流轉變成連續固體薄片玻璃,且可用於如請求項3及4之 用於製造薄片玻璃之方法中的成型器件,其特徵在於其 包含: ' (a) 具有兩個側壁之成型體,該兩個侧壁各自接收該兩 股熔融玻璃扁平流之一,當其朝向該成型體之下端區域 移動時經冷卻,該成型體具有頂點向下之楔形末端,在 該頂點處兩股側流接合形成單一熔融玻璃薄片;及 (b) 牽引構件,其用於拉伸來自成型體之該下頂點之熔 融玻璃薄片’直至變成連續固體薄片玻璃。 12. 如凊求項i i之用以使來自兩個玻璃投配組之兩股熔融玻 璃扁平流轉變成連續固體薄片玻璃之成型器件,其中該 161469.doc 201233644 已在不同隔室中熔融及/或均化 兩股熔融玻螭扁平流來自 及淨化之兩種不同玻璃。 13. 種用於製造用以實施如請求項1至4之程序中之任 之薄片玻璃的裝置,其特徵在於其包含: ⑷至少-個用於熔融、均化及淨化可玻璃化材料之隔 (b)至少一個熔融玻璃投配器件; (0成型器件;及 (d)用以將連續固體薄片玻璃分割成既定尺寸之物品的 切割構件。 @、 14. 一種薄片玻璃,其特徵在於其係根據如前述請求項1至* 之程序且使用如請求項13之裝置製造。 15. 如請求項14之薄片玻璃,其中其係由兩種不同破璃形 成’該兩種不同玻璃各自佔據該玻璃薄片之厚度的— 半。 161469.doc201233644 VII. Patent application scope: 1. A method for manufacturing thin glass, characterized in that it comprises the following steps: (a) melting and homogenizing and purifying the glass from the vitrifiable raw material using a melting furnace; Passing a glass dosing device to convert the molten glass substrate from the melting furnace into a dazzling glass flow having a uniform flow rate per unit width; (0 by means of a molding device comprising a cleaning element, a molded body and a traction member, from The flat flow of molten glass of the dosing device forms a continuous solid sheet glass; (d) dividing the continuous solid sheet glass into articles of a predetermined size; and: in the formation of continuous solid sheet glass from a flat flow of molten glass via a molding device A cleaning element consisting of a rotating cylinder. 2. A method for producing sheet glass as requested by the 'in the form of a continuous solid sheet of glass formed from a flat flow of molten glass from a dosing device' A component made of a plate in which the glass is immersed. 3. A method for producing a sheet glass, It is characterized in that it comprises the following steps: (a) melting, homogenizing and melting a single molten glass from a vitrifiable raw material by means of a melting furnace; (b) using two glass dosing devices to transform the molten glass soil from the melting furnace Two molten glass flats with a uniform flow per unit width 161469.doc 201233644 advection; (C) using a molded device comprising the formed shaped body and the traction member, from two molten glass flats from two dosing devices The flow forms a continuous solid sheet glass; (d) the continuous solid sheet glass is divided into articles of a predetermined size; and wherein the glass sheet is formed of a single glass. 4. A method for producing a sheet glass comprising the following steps: (a) Melt homogenization and purification of two different molten glasses from the vitrifiable raw material by means of two melting furnaces; (b) Two molten glass substrates from two melting furnaces using two glass dosing devices Converted into two streams of molten glass having a uniform flow rate per unit width; (0 using a molded device comprising a molded body and a traction member, Two flat streams of molten glass from two dosing devices form a continuous solid sheet glass; (d) dividing the continuous solid sheet glass into articles of a predetermined size; and wherein the glass sheets are composed of two different glasses, the two Each of the different glasses occupies half of the thickness of the glass flakes. 5. A flat stream of molten glass for converting a molten glass substrate into a uniform flow rate per unit width, and can be used for making sheets as claimed in claims 1-4 to 4. The glass dosing device in the method of glass, characterized in that it comprises: (a) an inlet region of molten glass from a melting furnace; (b) a plurality of molten glass propulsion modules independent of each other, each module system 161469. Doc 201233644 consists of a glass push-rotating device having a rotational speed for controlling the rotating device and a rotating shaft of the rotating device relative to a side wall of the propulsion module to which it is mounted Positional component; (C) overflow channel on each drive module, independent of the corresponding glass drive module And (d) a common outlet, the molten glass from each of the overflow passages of the drive modules flowing through the common outlet and having a flat flow of molten glass having a uniform flow rate per unit width Dumped. 6. The glass dosing device of claim 5, wherein the number of rotating devices in any of the glass propulsion modules is two. 7. The glass dosing device of claims 5 and 6, wherein the rotational speed of the rotating device and/or the change in the position of the material (10) axis of the rotating material causes the molten glass to generate hydraulic pressure in its respective propulsion module The height is varied and the flow rate of the molten glass through the overflow passage of the propulsion module is modified. 8. The glass dosing group of claims 5 to 7, wherein the dividing wall between the propulsion module and the rotating means is made entirely or partially of inscriptions, records or beginnings or alloys. 9. A molded device produced by a method for converting a flat flow of molten glass into a continuous solid sheet glass and for use in a method for producing a sheet glass according to claims 1 and 2, characterized in that it comprises: ()/month cleaning element , which is used to improve one of the two surfaces of the flat flow of the molten glass; 161469.doc 201233644 (b) a lining body whose raft is located below the cleaning element and two streams of glass flow along both side walls thereof 'When the two The stream of glass is gradually cooled as it moves toward the lower end portion, and the molded body has a wedge-shaped end with a vertex downward, at which two two side streams are joined to form a single molten glass flake; (4) a (four) piece, which is formed by self-forming Forming the lower apex of the fused glass flakes until it becomes a continuous solid flake glass; and wherein the cleaning element is composed of a rotating cylinder positioned above the upper end region of the shaped body, which has a rotational speed for controlling the cylinder And a member of the cylinder relative to the position of the shaped body. A molding device for converting a flat flow of molten glass into a continuous solid flake glass, wherein the cleaning member is formed of a plate partially immersed in an upper end portion of the molded body. 11. A shaped device for converting two streams of molten glass from two glass dosing devices into a continuous solid sheet glass, and for use in a method for producing sheet glass according to claims 3 and 4, characterized in that It consists in: ' (a) a shaped body having two side walls, each of which receives one of the two flat streams of molten glass, which is cooled as it moves towards the lower end region of the shaped body, the shaped body a wedge-shaped end having a vertex downwardly at which two side streams are joined to form a single molten glass flake; and (b) a traction member for stretching the molten glass sheet from the lower vertex of the shaped body until continuous Solid flake glass. 12. The shaped device of claim ii for converting two streams of molten glass from two glass dosing groups into a continuous solid sheet glass, wherein the 161469.doc 201233644 has been melted in different compartments and/or Homogenize two molten glass flat streams from and purify two different glasses. 13. Apparatus for the manufacture of a sheet glass for carrying out any of the procedures of claims 1 to 4, characterized in that it comprises: (4) at least one partition for melting, homogenizing and purifying the vitrifiable material (b) at least one molten glass dosing device; (0 forming device; and (d) a cutting member for dividing the continuous solid flake glass into articles of a predetermined size. @, 14. A flake glass characterized by Manufactured according to the procedures of the above claims 1 to * and using the apparatus as claimed in claim 13. 15. The glazing of claim 14, wherein the glazing is formed of two different glazes, each of which occupies the glass The thickness of the sheet - half. 161469.doc
TW101100730A 2011-01-07 2012-01-06 Method and installation for the manufacture of thin sheets of glass TW201233644A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
TWI737794B (en) * 2016-08-24 2021-09-01 美商康寧公司 Glass manufacturing apparatus and methods

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US20040093900A1 (en) * 2002-11-15 2004-05-20 Fredholm Allan M. Apparatus and method for producing sheets of glass presenting at least one face of very high surface quality
US7748236B2 (en) * 2005-12-27 2010-07-06 Corning Incorporated Overflow downdraw glass forming method and apparatus
WO2008103250A1 (en) * 2007-02-22 2008-08-28 Corning Incorporated Process to preserve isopipe during coupling
US8196434B2 (en) * 2007-08-08 2012-06-12 Corning Incorporated Molten glass delivery apparatus for optical quality glass

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI737794B (en) * 2016-08-24 2021-09-01 美商康寧公司 Glass manufacturing apparatus and methods
US11319238B2 (en) 2016-08-24 2022-05-03 Corning Incorporated Glass manufacturing apparatus and methods

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