201224192 六、發明說明： 【發明所屬之技術領域】 ，詳言之，係 本發明係關於一種生色裝置及其製造方法 關於一種裝飾性生色裝置及其製造方法。 【先前技術】201224192 VI. Description of the Invention: [Technical Field to Which the Invention Is Applicable] In particular, the present invention relates to a chromogenic device and a method of manufacturing the same relating to a decorative chromogenic device and a method of manufacturing the same. [Prior Art]
習知的裝飾性鍍膜’其既有的製作方式可區分為乾式激 鑛以及濕式染色製程方式。乾式濺鑛如物理滅鐘（pvD)裝 飾性鐘膜為既有習知技術，常見組成中，氧化鈦所製作的 ㈣鑛膜，其顏色變化雖然多樣但鍍製時間往往較費時’ 且具有較高之製作成本，對於商品化製作將會受到偈限。 濕式製程如陽極處理，是以添加染料進行外觀裝飾製 作特ι±上，濕製程染色具有較賤鑛製作之低價格優勢， 但在顏色表現上就沒有濺鍍製作的具有干涉性色彩多樣變 化相對上，濕式製程較強調單一性色彩呈現與製作。 在習知技術中，氮化鋁鈦（TlA3N)是應用在工具鍍如鑽 員或活塞等載體上’鍍膜本身具有耐磨耗與高硬度性能展 現，然而習知氮化鋁鈦鍍膜的顏色較為單調，僅有半光澤 鉻 η (Dark Semi-GJ〇ss Chrome)與酒紅（Red Tint)色彩。 因此，有必要提供一創新且富有進步性之裝飾性生色裝 置及其製造方法，以解決上述問題。 【發明内容】 本發明提供一種裝飾性生色裝置，包括一基材及一色 層及基材具有一表面。該色層設置於該基材之該表面， 其材質為鈦或/及鋁之氮化物’該色層之厚度係小於】微米 152JJ3.doc 201224192 (μπι)。 本發明另提供— Μ & Lt 、種裝飾性生色裝置之製造方 下步驟：（a)提供一其# 匕枯以 基材，該基材具有一表面；及 一色層於該基材之兮砉； ^成 表面，該色層之材質為鈦或/及鋁之 氮化物，層之厚度係小於】微米(μιη)。 本發明之袭飾性生色裝置之製造方法係形成_Μ於且 平坦或具隨結構之基材表φ，以直接達到具料色彩變 化之功效。藉由調整該色層之組成及製程參數形成具干 涉性之色I，以達到光干涉的顏色變化。藉此，本發明之 裝飾性生色裝置之製造方法可製造出能呈現多種不同顏色 之裝飾性生色裝置，且可同時符合耐磨耗及耐刮痕之表面 硬度要求。 【實施方式】 圖1顯示本發明裝飾性生色裝置之第一實施例示意圖。 該裝飾性生色裝置1包括一基材η、一色層12及一外層 13。該基材11具有一表面】U。該色層12設置於該基材η 之該表面Π 1 ’該色層1 2之材質為鈦或/及鋁之氮化物，該 色層1 2之厚度係小於1微米（μηι)。該色層丨2之材質可為氮 化鈦（TiN)、氮化銘（Α1Ν)或氮化銘鈦（TiAiN)。在本實施例 中，該色層1 2之材質為氮化鋁鈦（TiAiN)，該色層]2之硬 度為2H至9H。該色層12之厚度小於工具鐘之鑛膜厚度（J μιη以上），且該色層]2之硬度小於工具鑛之鍍膜硬度。 在本實施例中，該基材1〗之該表面Π1係為一單純之平 整表面，該色層1 2係為單層’在其他實施例中，該色層1 2 152il3.doc 201224192 可包括複數個子色層]2 1 (總厚度小於1微米），如圖2所示， 其中該等子色層12 I較佳係具有不同之顏色。該外層丨3至 少覆盍該色層12，用以附加其他功能於該色層丨2。較佳 地’該外層1 3為耐磨耗、抗菌或抗油脂之應用性薄膜。 圖3顯示本發明裝飾性生色裝置之第二實施例示意圖； 圖4顯示本發明裝飾性生色裝置之第二實施例中具有表面 圖紋結構之基材示意圖。其中’與上述第一實施例之裝飾 性生色裝置1相同之元件係以相同之元件符號表示。配合 參考圖3及圖4，與上述第一實施例之裝飾性生色裝置](圖 】）不同之處在於，在本實施例中該裝飾性生色裝置2之基 材】1之表面Π 1另包括一圖紋結構n 2，（例如以電磁脈衝、 触亥]或雕寺成型形成之葉片圖紋結構）’該裝倚性生色 裝置2之色層22係至少覆蓋該圖紋結構]]2的一部份，以本 實施例而言，該裝飾性生色裝置2之色層22係完全覆蓋該 圃紋、特構Π 2，且一覆層〗4形成於該圖紋結構112外之該基 材11之該表面111。較佳地’該圖紋結構112之尺度係小於 5〇微米。並且，該覆層14較佳係與該色層22具有不同顏色 表現’以使該裝飾性生色裝置2展現出不同之顏色變化。 可理解的是’在具有複數個子色層之色層中，該等子色 層中之部分子色層可更覆蓋該圖紋結構丨12外之該基材】i 之該表面]Π。參考圖5，其顯吊本發明裝飾性生色裝置之 第三實施例示意圖。與上述第二實施例之裝飾性生色裝置 2(圖3)不同之處在於，在本實施例中’該裝飾性生色裝置3 不包括覆層’且該裝飾性生色裝置3之色層32具有3層子色 152113.doc 201224192 層321、322、323，其中與上述第二實施例之裝飾性生色 裝置2相同之元件係以相同之元件符號表示。 在具有複數個子色層321、322、323之該色層32中，該 等子色層32〗、322、323中之子色層323覆蓋該圖紋結構外 之该基材1】之該表面11〗。可理解的是，亦可為該等子色 層 321、322、323 中之-子辛厚 322、番―,Conventional decorative coatings can be distinguished from dry ores and wet dyeing processes. Dry splashing, such as physical clock (pvD) decorative clock film, is a well-known technique. Among the common compositions, (4) mineral film made of titanium oxide, although the color change is varied, the plating time is often time-consuming and High production costs will be limited for commercial production. The wet process, such as anodizing, is made by adding dye to the exterior decoration. The wet process dyeing has a lower price advantage than that of the antimony ore. However, there is no interference color change in the color performance. In contrast, the wet process emphasizes the presentation and production of a single color. In the prior art, titanium aluminum nitride (TlA3N) is applied on a tool such as a drill or a carrier such as a piston. The coating itself exhibits wear resistance and high hardness performance. However, the color of the aluminum nitride titanium coating is relatively good. Monotonous, only half-gloss chrome η (Dark Semi-GJ〇ss Chrome) and red wine (Red Tint) color. Therefore, it is necessary to provide an innovative and progressive decorative coloring device and a manufacturing method thereof to solve the above problems. SUMMARY OF THE INVENTION The present invention provides a decorative chromogenic device comprising a substrate and a color layer and a substrate having a surface. The color layer is disposed on the surface of the substrate, and the material is titanium or/and aluminum nitride. The thickness of the color layer is less than 512JJ3.doc 201224192 (μπι). The invention further provides the following steps: Μ & Lt, a decorative chromogenic device; (a) providing a substrate, the substrate having a surface; and a color layer on the substrate成; ^ into the surface, the material of the color layer is titanium or / and aluminum nitride, the thickness of the layer is less than [micron (μιη). The manufacturing method of the glazing coloring device of the present invention is formed to be flat or have a substrate φ according to the structure to directly achieve the effect of color change of the material. The color I of the interference is formed by adjusting the composition of the color layer and the process parameters to achieve a color change of the light interference. Thereby, the manufacturing method of the decorative chromogenic device of the present invention can produce a decorative chromogenic device capable of exhibiting a plurality of different colors, and can simultaneously meet the surface hardness requirements of abrasion resistance and scratch resistance. [Embodiment] Fig. 1 is a view showing a first embodiment of the decorative chromogenic apparatus of the present invention. The decorative chromogenic device 1 comprises a substrate η, a color layer 12 and an outer layer 13. The substrate 11 has a surface U. The color layer 12 is disposed on the surface Π 1 ' of the substrate η. The material of the color layer 12 is titanium or aluminum nitride, and the thickness of the color layer 12 is less than 1 micrometer (μηι). The material of the color layer 丨2 may be titanium nitride (TiN), nitriding (Α1Ν) or nitriding titanium (TiAiN). In this embodiment, the material of the color layer 12 is titanium aluminum nitride (TiAiN), and the color layer 2 has a hardness of 2H to 9H. The thickness of the color layer 12 is smaller than the thickness of the mineral film of the tool clock (J μιη or more), and the hardness of the color layer 2 is smaller than the hardness of the coating of the tool ore. In this embodiment, the surface Π 1 of the substrate 1 is a simple flat surface, and the color layer 12 is a single layer. In other embodiments, the color layer 1 2 152il3.doc 201224192 may include A plurality of sub-color layers] 2 1 (total thickness less than 1 micron), as shown in FIG. 2, wherein the sub-color layers 12 I preferably have different colors. The outer layer 3 covers at least the color layer 12 for additional functions to the color layer 丨2. Preferably, the outer layer 13 is an abrasion resistant, antibacterial or anti-grease applied film. Fig. 3 is a view showing a second embodiment of the decorative chromogenic apparatus of the present invention; and Fig. 4 is a view showing the substrate having a surface pattern structure in the second embodiment of the decorative chromogenic apparatus of the present invention. The same elements as those of the decorative chromogenic apparatus 1 of the first embodiment described above are denoted by the same reference numerals. Referring to FIG. 3 and FIG. 4, the difference from the decorative chromogenic device of the first embodiment (FIG.) is that the surface of the substrate of the decorative chromogenic device 2 is Π in the embodiment. 1 further comprising a pattern structure n 2 (for example, an electromagnetic pulse, a touch of the sea) or a blade pattern formed by the carving of the temple] the color layer 22 of the accommodating coloring device 2 covers at least the pattern structure In the embodiment, the color layer 22 of the decorative chromogenic device 2 completely covers the crepe pattern and the embossed structure 2, and a coating layer 4 is formed on the pattern structure. The surface 111 of the substrate 11 outside the 112. Preferably, the scale of the pattern structure 112 is less than 5 microns. Moreover, the cover layer 14 preferably has a different color appearance than the color layer 22 such that the decorative chromogenic device 2 exhibits a different color change. It can be understood that in a color layer having a plurality of sub-color layers, a part of the sub-color layers of the sub-color layers may cover the surface of the substrate other than the pattern structure 】12. Referring to Figure 5, there is shown a schematic view of a third embodiment of the decorative chromogenic apparatus of the present invention. The difference from the decorative chromogenic device 2 (Fig. 3) of the second embodiment described above is that in the present embodiment, the decorative chromogenic device 3 does not include a coating layer and the color of the decorative chromogenic device 3 The layer 32 has three layers of sub-colors 152113.doc 201224192 layers 321, 322, 323, wherein the same elements as the decorative chromogenic device 2 of the second embodiment described above are denoted by the same reference numerals. In the color layer 32 having a plurality of sub-color layers 321, 322, 323, the sub-color layer 323 of the sub-color layers 32, 322, 323 covers the surface 11 of the substrate 1 outside the pattern structure. 〗. It can be understood that the sub-color layers 321 , 322 , and 323 can also be 322 , 番 ,
構外之該基材1 ]之該表面。該外層〗3覆蓋該色層32之 子色層323，該外層13可為一耐磨耗膜層，以保護該色層 32。該等子色層321、322、323較佳係具有不同之顏色， 且不同顏色之子色層321、322、323堆疊後之顯色不同 因此亦可突顯出該圖紋結構11 2處之顏色光影變化。 圖6顯示本發明裝飾性生色裝置之製造方法之流程圖。 配合參考圖1及圖6,參考步驟S61，首先提供一基材u， 該基材11具有一表面]11。 參考步驟S62，形成一色層12於該基材丨丨之該表面丨^， 該色層12之材質為鈦或/及鋁之氮化物，該色層】2之厚度 係小於1微米（μπι)。 可理解的是，在步驟S62中可形成複數個不同顏色之子 色層]21於該基材〗1之該表面l n，以形成該色層12(配合 參考圖2)。藉由該等子色層121之配合，在不同角度下， s亥裝飾性生色裝置】具有不同之光干涉的顏色變化。 要說明的是，該基材]!之該表面】可另包括一圖紋結 構112，在步驟S62中，該色層12係至少覆蓋該圖紋結構 ]12(參考圖3至圖5)。舉例而言，該裝飾性生色裝置2之色 152113.doc 201224192 層22覆蓋該圖紋結構112，且一覆層14形成於該圖紋結構 112外之該基材11之該表面】〗〗（參考圖3);或者，該裝飾性 生色裝置3之色層32覆蓋該圖紋結構1 12，且該色層32之子 色層223更覆蓋該圖紋結構外之該基材11之該表面1丨丨（參 考圖5)。The surface of the substrate 1]. The outer layer 3 covers the sub-color layer 323 of the color layer 32, and the outer layer 13 can be a wear-resistant film layer to protect the color layer 32. Preferably, the sub-color layers 321 , 322 , and 323 have different colors, and the color colors of the sub-color layers 321 , 322 , and 323 of different colors are different after stacking, so that the color and light of the pattern structure 11 2 can also be highlighted. Variety. Figure 6 is a flow chart showing a method of manufacturing the decorative chromogenic apparatus of the present invention. Referring to FIG. 1 and FIG. 6, referring to step S61, a substrate u is first provided, and the substrate 11 has a surface 11 . Referring to step S62, a color layer 12 is formed on the surface of the substrate, and the color layer 12 is made of titanium or aluminum nitride. The thickness of the color layer is less than 1 micrometer (μπι). . It can be understood that a plurality of sub-layers of different colors can be formed in the surface 1 n of the substrate 1 to form the color layer 12 (in conjunction with FIG. 2). With the cooperation of the sub-color layers 121, the decorative color grading device has different color interferences at different angles. It is to be noted that the surface of the substrate] may further include a pattern structure 112, and in step S62, the color layer 12 covers at least the pattern structure 12 (refer to Figs. 3 to 5). For example, the color 152113.doc 201224192 layer 22 of the decorative chromogenic device 2 covers the pattern structure 112, and a coating layer 14 is formed on the surface of the substrate 11 outside the pattern structure 112. (refer to FIG. 3); or, the color layer 32 of the decorative chromogenic device 3 covers the pattern structure 12, and the sub-color layer 223 of the color layer 32 further covers the substrate 11 outside the pattern structure. The surface is 1丨丨 (refer to Figure 5).
再配合參考圖1及圖6，在本實施例中，在步驟S62之後 另包括一步驟S63:形成一外層〗3至少覆蓋該色層12，以 附加功能於該色層12。該外層1 3可為耐磨耗、抗菌或抗油 脂之應用性薄膜。 配合參考圖3、圖4及圖6，在該基材η之表面1U具有圖 紋結構112之實施例中，在步驟S63中係形成該外層]3以覆 蓋該色層22及該覆層14，以保護該色層22及該覆層14。 配合參考圖5及圖6,在該基材丨】之表面lu具有圖紋結 構112之另一實施例中，在步驟S63中係形成該外層]3以覆 蓋該色層32之子色層323，以附加功能於該色層32。 圖7顯示本發明在不同製程條件下形成之色層的色彩《 化示意圖。配合參考圖!及圖7，以製造本發明第一實施丫: 之裝錦性生色裝置】為例說明，在本實施例中，該色Μ 係以錢鍍方法形成，其係使用二個鈦乾材及二個叫 (但乾材的配置方式不以此為限），並通人氬氣與氮氣1 鑛形成該色層12。其中，_之卫作壓力為5GmT〇rr^ 鍍工作距離為7.5 c m ’在呂m s耙材使用功率為]5 KW，鈦 使用功率為9〇〇〜1 KW，氬氣μ & ' 、冰 虱比為3〜6 2，濺鍍時間為13〜2 刀，里。實際結果顯示，機 踢矸間大於25分鐘後，所形成安 152H3.doc 201224192 色層12之顏色會再唐番 度重歿濺鍍時間13〜25分鐘之色系， 此實務上較佳僅需進行_製程至多⑽鐘即可。- 田濺鍍衣程中之鼠氮比約為3 ’濺鍍時間約為 時，係可形成金黃色之該色層】2。（八點） 當濺鍍製程中之蠱^ 虱比，，勺為5.7，濺鍍時間約為I 5分鐘 時，係可形成墨綠色之該色層12。⑺點） 田滅鑛裝辛王t之虱氮比約為6，減鑛時間約為Μ分鐘 時，係可形成桃紅色之該色層〗2。（(：;點）Referring to FIG. 1 and FIG. 6, in this embodiment, after step S62, a step S63 is further included to form an outer layer 3 covering at least the color layer 12 to additionally function on the color layer 12. The outer layer 13 can be an abrasion resistant, antibacterial or oil resistant application film. Referring to FIG. 3, FIG. 4 and FIG. 6, in the embodiment in which the surface 1U of the substrate η has the pattern structure 112, the outer layer 3 is formed in step S63 to cover the color layer 22 and the cladding layer 14. To protect the color layer 22 and the cladding layer 14. Referring to FIG. 5 and FIG. 6, in another embodiment in which the surface of the substrate has a patterned structure 112, the outer layer 3 is formed in step S63 to cover the sub-color layer 323 of the color layer 32. Additional functions are applied to the color layer 32. Fig. 7 is a view showing the color of the color layer formed by the present invention under different process conditions. Referring to the reference figure! and FIG. 7, in order to manufacture the first embodiment of the present invention: the brocade coloring device is exemplified, in the embodiment, the color enamel is formed by a money plating method, and the system uses two The titanium dry material and the two are called (but the dry material is not limited to this), and the color layer 12 is formed by argon gas and nitrogen gas. Among them, the pressure of _ wei is 5GmT 〇 rr ^ plating working distance is 7.5 cm 'In the Lm ms coffin power is 5 KW, titanium power is 9 〇〇 ~ 1 KW, argon μ & ', ice The ratio is 3 to 6 2, and the sputtering time is 13 to 2 knives. The actual results show that after the machine kicks more than 25 minutes, the color of the formed 152H3.doc 201224192 color layer 12 will be repeated for 13~25 minutes of coloring time. The process can be carried out for up to (10) minutes. - When the mouse nitrogen ratio in the field of sputtering is about 3 ′, the color of the layer can be formed when the sputtering time is about 2]. (Eight points) When the sputtering process is 蛊^ 虱, the scoop is 5.7, and the sputtering time is about I 5 minutes, the color layer 12 of the dark green color can be formed. (7) Point) The nitrogen ratio of the 灭 矿 矿 辛 辛 田 田 田 田 田 田 田 田 田 田 田 田 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛 辛((:;point)
田減鍍製私中之氬氮比約為6 2，減鑛時間約為η鐘 時，係可形成藍紫色之該色層丨2。（D點） 可理解的是’可選擇形成單層之該色層12(如圖】所示: 或多層之該色層12(如圖2所示），且該基材u之表面iu可 另包括一圖紋結構112(如圖3至圖5所示）。關於具有複數個 子色層12!之該色層]2(圖2)，該等子色層]2]較佳係具有不 同之顏色，如此，藉由該等子色層121之配合堆疊出設定 之該裝飾性生色裝置1之成色，在不同角度下，該裝飾性 生色裝置1具有不同之光干涉的顏色變化，具有更多變之 顏色表現。 配合參考圖3及圖4在該基材Π之表面111具有圖紋結構 11 2下，形成該色層22之方法說明如下。 形成一遮蔽材覆蓋該圖紋結構1 ] 2外之該基材]]之該表 面111 ;濺鍍形成該色層2 2 (可為單層或多層）覆蓋該圖紋結 構Π 2 ;及移除該遮蔽材。 可理解的是，在移除該遮蔽材之後，可另形成一覆層】4 152ll3.doc 201224192 於該圖紋結構11 2外之該基材丨丨之該表面〗丨】，接著再濺鍍 形成該色層22。該覆層]4可以濕式陽極處理方法或濺鍍方 法形成。其中’濕式陽極處理方法較佳應用於不具圖紋結 構之表面’濺鍍方法較佳應用於具有圖紋結構之表面。該 覆層14之材質及顏色可依據不同之需求而選擇。 配合參考圖4及圖5，在該基材丨]之表面]n具有圖紋結 構Π 2下’形成該色層3 2之方法說明如下。 形成一遮蔽材覆蓋該圖紋結構112外之該基材n之該表 面111;濺鍍形成至少一層第一子色層（圖5中之子色層 32〗、322)覆蓋該圖紋結構112 ;移除該遮蔽材；及濺鍍形 成至少一第二子色層（圖5中之子色層323)覆蓋該至少第一 子色層（321、322)及該基材〗〗之該表面。 在上述方法中’係利用高分子材料作為該遮蔽材，以網 印方式進行該基材U之該表面⑴的覆蓋。該遮蔽材自覆 蓋至移除之過程簡要說明如下： 上選取適當遮蔽材如blue_7416〇東洋油墨，與溶劑以配 比]:0.25〜0.4稀釋調勻後，進行網印覆蓋該圖紋結構】】^外 之該基材1〗之該表面丨。 b. 油墨乾燥（例如陰乾）後，以85它〜1〇5艺進行烘烤或以 紫外光照射方式將油墨固化成型。 c. 形成該色層22、32(可為單層或多層）覆蓋該圖紋結構 1]2。 d. 以溶劑’如丙嗣或酒精’移除該油墨。 本發明之裝飾性生色裝置之製造方法係形成一色層於具 l52H3.doc 201224192 平坦或具圖紋結構之基 化之功效。藉由㈣ 以直接達到具裝飾色彩變 锈 °形成該色層之組成及製程參數（例如 透過濺鍍製程中之盡_ 欠、賤錄時間等製程條件形成不同 顏色之色層），形成且千 色變化。藉此，本發明之二之層’以達到光干涉的顏 、 各月之裝飾性生色裝置之製造方法可製 造出月&王現多種$⑸么 5 >、色之裝飾性生色裝置，且可同時符 合耐磨耗及耐刮痕之表面硬度要求。The argon-nitrogen ratio in the field-reduced plating system is about 6 2, and when the time for the reduction is about η, the color layer 丨2 of blue-violet color can be formed. (point D) It is understood that 'the color layer 12 of a single layer can be selectively formed (as shown in the drawing): or the color layer 12 of the plurality of layers (as shown in FIG. 2), and the surface iu of the substrate u can be In addition, a pattern structure 112 (shown in Figures 3 to 5) is included. With respect to the color layer 2 (Fig. 2) having a plurality of sub-color layers 12!, the sub-color layers [2] are preferably different. The color of the decorative chromogenic device 1 is stacked by the cooperation of the sub-color layers 121. The decorative chromogenic device 1 has different color interferences of light interference at different angles. There is more variation in color performance. With reference to Fig. 3 and Fig. 4, the surface 111 of the substrate has a pattern structure 11 2, and the method of forming the color layer 22 is as follows. A masking material is formed to cover the pattern structure. 1] The surface 111 of the substrate] is sputtered to form the color layer 2 2 (which may be a single layer or a plurality of layers) covering the pattern structure Π 2; and the masking material is removed. After removing the masking material, a coating layer may be additionally formed. 4 152 ll3.doc 201224192 The surface of the substrate 外 outside the pattern structure 11 2 丨] Then, the color layer 22 is formed by sputtering. The coating layer 4 can be formed by a wet anodizing method or a sputtering method, wherein the 'wet anode processing method is preferably applied to a surface having no pattern structure'. It is applied to the surface with the pattern structure. The material and color of the coating layer 14 can be selected according to different needs. With reference to Fig. 4 and Fig. 5, the surface of the substrate ]] has a pattern structure Π 2 The method of forming the color layer 3 2 is as follows. A masking material is formed to cover the surface 111 of the substrate n outside the pattern structure 112; and at least one first color layer is formed by sputtering (the color layer in FIG. 5) 32, 322) covering the pattern structure 112; removing the masking material; and sputtering to form at least a second sub-color layer (the sub-color layer 323 in FIG. 5) covering the at least first sub-color layer (321, 322) And the surface of the substrate. In the above method, the polymer material is used as the masking material, and the surface (1) of the substrate U is covered by screen printing. The masking material is covered to be removed. The process is briefly described as follows: Select the appropriate masking material such as blue_7416〇 After the ink is diluted with the solvent by a ratio of 0.25 to 0.4, the screen is covered with the screen structure. The surface of the substrate 1 is 丨. b. After the ink is dried (for example, dried), The ink is baked or cured by ultraviolet light irradiation at a temperature of 85. 1 c. The color layer 22, 32 (which may be a single layer or a plurality of layers) is formed to cover the pattern structure 1] 2. d. The ink is removed by a solvent such as propylene or alcohol. The method of making the decorative chromogenic device of the present invention forms a color layer having the effect of a flat or patterned structure of l52H3.doc 201224192. By forming (4) directly forming the composition and process parameters of the color layer with decorative color rust (for example, forming a color layer of different colors through process conditions such as owing and recording time in the sputtering process), Color change. Therefore, the second layer of the present invention can be manufactured by the method of manufacturing the color ray-receiving color and the decorative color grading device of each month. The king can display a variety of $(5) 5 > The device can meet the surface hardness requirements of wear resistance and scratch resistance.
上述實施例僅為說明本發明之原理及其功效，並非限制 ，發θ目此習於此技術之人士對上述實施例進行修改及 變化仍不脫本發明之精神。本發明之權利範圍應如後述之 申請專利範圍所列。 【圖式簡單說明】 圖1顯示本發明裝飾性生色裝置之第一實施例示意圖； 圖2顯示本發明具有複數個子色層之色層之裝飾性生色 裝置不意圖； 圖3顯不本發明裝飾性生色裝置之第二實施例示意圖； 圖4顯不本發明裝飾性生色裝置之第二實施例中具有表 面圖紋結構之基材示意圖； 圖5顯示本發明裝飾性生色裝置之第三實施例示意圖； 圖6顯示本發明裝飾性生色裝置之製造方法之流程圖；及 圖7顯示本發明在不同製程條件下形成之色層的色彩變 化示意圖。 【主要元件符號說明】 1 本發明第一實施例之裝飾性生色裝置 152113.doc •10- 201224192 2 本發明第 3 本發明具 飾性生色 11 基材 12 色層 13 外層 14 覆層 22 色層 3 2. 色層 111 基材之表 112 圖紋結構 121 子色層 321 ' 322 ' 323 子色層 二實施例之裝飾性生色裝置 有複數個子色層之色層之裝 裝置The above-described embodiments are merely illustrative of the principles of the present invention and its effects, and are not intended to be limiting, and modifications and variations of the embodiments described above will be apparent to those skilled in the art. The scope of the invention should be as set forth in the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing a first embodiment of a decorative coloring device of the present invention; FIG. 2 is a view showing a decorative coloring device having a color layer of a plurality of sub-color layers of the present invention; BRIEF DESCRIPTION OF THE DRAWINGS FIG. 4 is a schematic view showing a substrate having a surface pattern structure in a second embodiment of the decorative coloring device of the present invention; FIG. 5 is a view showing the decorative coloring device of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 6 is a flow chart showing a method of manufacturing a decorative chromogenic apparatus of the present invention; and Fig. 7 is a view showing a color change of a color layer formed by the present invention under different process conditions. [Description of main component symbols] 1 Decorative chromogenic device of the first embodiment of the present invention 152113.doc •10-201224192 2 The third invention of the present invention is characterized by a chromogenic color 11 substrate 12 color layer 13 outer layer 14 cladding layer 22 Color layer 3 2. Color layer 111 Substrate table 112 Pattern structure 121 Sub-color layer 321 '322' 323 Sub-color layer Two embodiment of the decorative chromogenic device has a plurality of sub-color layer color layer mounting device
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