201224098 六、發明說明： 【發明所屬之技術領域】 本&月&關於樹脂組成物。本發明係關於例如黏著 劑、硬被覆劑與使用其而成之電子裝置。 【先前技術】 、 、顯7體之上搭載的觸控面板方面’有電阻膜 式、靜電谷里式、電磁感應式、光學式等。有時會在此等 觸&面板之上貼合裝鄭板或圖標片（i_也㈣)。裝飾板係用 來，外觀的5又5十性良好。圖標片係用以指定觸控位置。靜 電容量式觸控面板係在透明基板之上形成透明電極 ’並具 有在該透明電極之上貼合透明板而成的構造。 以在，上叙料板與觸控面板的貼合、圖標片與觸 控面板的貼合、在靜電容量式觸控面板上之經形成透明電 才，的，明基板與透明板的貼合，係使用片狀的雙面黏著片 Λ進仃’或在被㈣體的單面上進行黏著加王而進行。此 種使用黏著劑的技術，會有黏著不充分、氣泡混入至貼合 問題。尤其是一旦在貼合面上有進行過印刷加工，則 曰=所謂氣泡容㈣留财印狀處與 低差部分之問題。 门 近年來，LCD _抑的玻璃的厚絲做愈薄。一旦 ，則LCD會因外部應力岭易魏。#貼合此薄 =!LCD等顯示體與壓克力板或聚碳酸醋板等光學機能 由於破璃錢克力等線膨脹的差異、壓克力板或 文醋等塑膠成型材之成型時的變形，而導致在耐赦試 ，或耐賴财麵咖賴和或簡/錢、或產生尺寸 4/23201224098 VI. Description of the Invention: [Technical Field of the Invention] This & Month & About Resin Composition. The present invention relates to, for example, an adhesive, a hard coating agent, and an electronic device using the same. [Prior Art] The touch panel mounted on the display body has a resistive film type, an electrostatic valley type, an electromagnetic induction type, and an optical type. Sometimes a Zheng board or an icon (i_ also (4)) is attached to the touch panel. The decorative panel is used, and the appearance of 5 and 50 is good. The icon slice is used to specify the touch position. The electrostatic capacitive touch panel has a structure in which a transparent electrode is formed on a transparent substrate and a transparent plate is bonded to the transparent electrode. The bonding between the upper and the transparent panels is achieved by the bonding of the upper and the touch panels, the bonding of the icon and the touch panel, and the formation of transparent electricity on the electrostatic capacitive touch panel. It is carried out by using a sheet-shaped double-sided adhesive sheet to be inserted into the crucible or by being adhered to the king by a single surface of the (four) body. Such a technique using an adhesive may cause insufficient adhesion and air bubbles to fit into the fit. In particular, once the printing process has been carried out on the bonding surface, 曰 = the so-called bubble volume (4). Doors In recent years, LCDs have become thinner than thicker glass. Once, the LCD will be easy due to external stress. #贴合薄薄=! LCD and other display body and acrylic or polycarbonate plate and other optical functions due to the difference in the expansion of the glass, such as acrylic, acrylic, or vinegar and other plastic molding materials Deformation, which leads to a defamatory test, or grievances for gambling and/or Jane/money, or to produce size 4/23
S 201224098 餐:化與背曲等面精卢雄外 利文獻W)來ί欲以先前的黏著賴列如專 裂、助顯示不均之問題點。 i洛、LCD破 就如上述之問題點的解決對策而言， 之UV硬化型樹脂。其係以如（甲基)丙“=文獻3 h系早版做為基體而成的高彈性樹脂 靠性試驗中盔法紂、6、木仏又曰有在同溫可 能性。 ^以錄者體_驗細發生剝落的可 [先前技術文獻]S 201224098 Meal: Rising and backing, etc. Lu Xiongwai Lili Literature W) Come to the problem of the previous adhesion and help to show unevenness. I-Lo and LCD are broken. For the solution to the above problems, UV-curable resin. It is based on the high-elasticity resin test such as (meth)-propyl"=3h early version of the literature. The helmet method is used in the test of the high-elasticity, and the raft is also in the same temperature. ^ Recorder Body _ fine peeling can occur [previous technical literature]
[專利文獻J (專利文獻丨）日本特開2004-77887號公報 (專利文獻2) W02010/027041號公報 (專利文獻3)日本特開昭64-85209號公報 【發明内容】 [發明欲解決之問題] 使用硬被覆劑，其例如於貼合 靜電容旦板或圖標片時、或當貼合 从日士里板中之形成有透明電極的透明基板與透明 二τ ’可賦予充分的黏著性，且可解決難以於不含氣泡 下貼合之先前技術的問題點。本發明係提供著 皮覆劑，其例如於貼合顯示體與光學機能材料時 題點4者面剝落、顯示體的玻璃破裂等之先前技術的問 [用以解決課題的手段] 即’本發明的範嘴之-，係提供一種樹脂組成物。此 5/23 201224098 樹脂組成物係含有使具有羥基的（甲基）丙烯酸酯單體(A)、 具有羥基的光聚合起始劑(B)與具有異氰酸酯基的異氰酸酯 (C)反應而製得之胺基曱酸酯丙烯酸酯(D);可聚合之（曱基) 丙烯酸酯(E);及矽烷偶合劑(巧之樹脂組成物。 在此樹脂組成物的一個實施形態中，具有羥基的（曱基) 丙稀酸料體(A)為具有2仙上基）丙剌基之化^ 物。此外在另-實施形態巾，具㈣基的光聚合起始劑⑻ 具有2個以上羥基。 本發明之另-齡，係提供—種樹脂組成物的硬化物。 此外從另-方面來看，本發明係提供一種藉由該硬化 物來被覆或接合被黏著體而成之複合物。 在此複合物的-實施形態中，該複合物 選自由三乙喊纖維素'氟系聚合物、城、聚破^ 聚烯烴、玻璃、金屬所構成之群組中的丨種以上。 本發明之又另-範鳴，係提供一種利用該樹脂組成物 貼合被黏著體而成之觸控面板積層體，再者本發明係提供 一種使用觸控面板積層體而成之顯示器。 從另-觀點進而觀之，本發明係提供一種利用該樹脂 組成物貼合被«體而成之液晶面板縣體，此外本發明 係提供一種使用該液晶面板積層體而成之顯示哭。 從另-觀點觀之，本發明係提供一種由前°述樹脂組成 物所成之黏著劑。X ’從另-觀點觀之、本發明係提供一 種由該樹脂組成物所成之硬被覆劑。 [發明的效果] 本發明的樹驗成物具有所謂透明性大、錯筆硬度 201224098 大、黏著性大之效果。 【實施方式】 [用以實施發明之最佳的形態] 具有光聚合起始劑之胺基曱酸酯丙烯酸酯(D)係使具 有經基的（曱基)㈣㈣單體⑷與具錢基的光聚合起始 劑⑼與具有2個以上異氰酸S旨基的異氰酸S旨(C)進行反^ 而製得者。 一 具有羥基的（曱基)丙烯酸酯單體(A)係具有至少i個 基)丙稀酸酯基與經基者。就具有i個（甲基)丙缔酸雖基與 羥基的（甲基)丙烯酸g旨而言，可列舉例如：（曱基歸酸_2、_ 羥乙酯、（曱基)丙烯酸_2_羥丙酯、（曱基)丙烯酸_2_羥丁二及 丙二醇(曱基)丙烯酸酯等。就具有2.個以上(曱基烯二旨 基與羥基的（曱基)丙烯酸g旨化合物而言，可列舉例如：丙三 醇一(―曱基)丙稀酸醋、新戊四醇三（曱基)丙稀酸酿、經基丙 基化一 ^甲基丙烧二（甲基）丙烯義旨、二新戊四醇經基五 (甲基)丙稀酸醋、雙(新戊四醇)四（曱基)丙稀酸酿、四經甲 基曱烧:(曱基)丙稀酸酿、2_經基_3_(曱基)丙稀酿氧基丙基 甲基丙_酯等。具有經基的（甲基)丙烯酸S旨單體(A)之(曱 基)丙烯酸s旨基的數目，較佳為2個以上、更佳為3個以上。 具有經基的（甲基)丙稀酸醋單體⑷之經基的數目，較佳為2 個以上。 >具有減的光聚合起始„_)為具有至少〗個經基者。 就具有1魅基的光聚合起始劑*言，可列舉例如：2 —經 基-曱基-1·苯基·丙烧]-酮(Ciba.Japan公司製，產品名 Dar〇Cur 1173)、⑼基-環己基笨基领公司製， 7/23 201224098 產品名Irgacure 184)等。就具有2個以上經基的光聚合起始 劑而言，可列舉例如1-[4-(經基乙氧基)-苯基]-2-羥基-2-甲 基-1-丙-1-嗣(Ciba.Japan 公司製，產品名 Irgacure2959)、2-羥基-l-{4-[4-(2-羥基-2-甲基-丙醯基)-苄基]-苯基}-2-曱基-丙烧-1-酮(Ciba.Japan公司製、產品名Irgacure 127)等。具 有羥基的光聚合起始劑(B)之羥基的數目，較佳為2個以 上。其理由在於，藉由具有2個以上，在放射線照射後裂 解的光開始劑會進入（甲基）丙烯酸酯單體(A)的丙烯醯基之 反應系統，因此可抑制遷移。又，關於羥基數目的上限並 無特別限定。 具有異氰酸酯基的異氰酸酯(c)，較佳為具有2個以上 異氰酸酯基。具有2個以上異氰酸酯基的異氰酸酯(c)，可 列舉例如芳香族二異氰酸酯、脂環族二異氰酸酯及脂肪族 二異氰酸酯等，宜使用芳香族異氰酸酯或脂環族異氰酸 酯。就異氰酸酯化合物的形態而言，係單體、二聚物及三 聚物，較佳為使用三聚物。 —就芳香族二異氰酸酯而言，可列舉例如二異氰酸曱伸 笨酗、、4,4-二苯基甲烷二異氰酸酯及二異氰酸二曱苯酯等。 就脂％族二異氰酸酯而言，可列舉例如異佛酮二異氰 酸S旨、亞曱基雙(異氰酸_4_環己酿）等。 匕就脂肪族二異氰酸酯而言，可列舉例如二異氰酸六亞 甲酯、二異氰酸三曱基六亞甲酯等。 、亦且使用上述一異氰酸酯之三經曱基丙烧加成物、與 =進行反應而成之縮二脲體、具有異三聚氰㈣環之 物笨。 8/23[Patent Document J] (Patent Document 2) Japanese Laid-Open Patent Publication No. 2004-77887 (Patent Document 2) Japanese Laid-Open Patent Publication No. SHO-64-85209 Problem] A hard coating agent is used, for example, when a static capacitor plate or an icon sheet is attached, or when a transparent substrate formed with a transparent electrode formed from a shirisili plate and a transparent TiO 2 are adhered to impart sufficient adhesion. And it can solve the problem of the prior art which is difficult to fit without bubbles. The present invention provides a coating agent which is used in the prior art for peeling off the surface of the object 4 when the display body and the optical functional material are bonded, and the glass of the display body is broken [a means for solving the problem] In the invention, a resin composition is provided. This 5/23 201224098 resin composition contains a (meth) acrylate monomer (A) having a hydroxyl group, a photopolymerization initiator (B) having a hydroxyl group, and an isocyanate (C) having an isocyanate group. Amino phthalate acrylate (D); polymerizable (fluorenyl) acrylate (E); and decane coupling agent (a resin composition. In one embodiment of the resin composition, having a hydroxyl group) (Amidyl) The acrylic acid material (A) is a chemical compound having 2 fluorene groups. Further, in the other embodiment, the photopolymerization initiator (8) having a (tetra) group has two or more hydroxyl groups. Another age of the present invention provides a cured product of a resin composition. Further, from another aspect, the present invention provides a composite in which an adherend is coated or bonded by the hardened material. In the embodiment of the composite, the composite is selected from the group consisting of the above-mentioned group of the cellulose-fluorine-based polymer, the city, the polysiloxane, the glass, and the metal. In addition, the present invention provides a touch panel laminate in which the resin composition is bonded to an adherend, and the present invention provides a display using a touch panel laminate. The present invention provides a liquid crystal panel body which is bonded to the body by the resin composition, and the present invention provides a display which is formed by using the liquid crystal panel laminate. Viewed from another perspective, the present invention provides an adhesive formed from the resin composition described above. From the standpoint of the present invention, the present invention provides a hard coating agent composed of the resin composition. [Effects of the Invention] The tree test article of the present invention has an effect of having a large transparency, a large pen hardness of 201224098, and a large adhesiveness. [Embodiment] [Best Mode for Carrying Out the Invention] The amino phthalate acrylate (D) having a photopolymerization initiator has a (meth) (tetra) (iv) monomer (4) having a mercapto group and a hydroxyl group. The photopolymerization initiator (9) is obtained by reacting the isocyanate S having two or more isocyanic acid groups (C). A (fluorenyl) acrylate monomer (A) having a hydroxyl group has at least i groups of acrylate groups and a base group. Examples of the (meth)acrylic acid g having i (meth)propionic acid as a hydroxyl group and a hydroxyl group include, for example, (fluorenyl acid-2, hydroxyethyl ester, (mercapto)acrylic acid 2 _ hydroxypropyl ester, (mercapto)acrylic acid 2 - hydroxybutane dipropylene and propylene glycol (fluorenyl) acrylate, etc., which have more than two (nonyl) ketone groups and hydroxyl groups (mercapto) acrylic acid For example, glycerol mono(-mercapto) acrylic acid vinegar, neopentyl alcohol tris(mercapto) acrylic acid, propyl propyl methacrylate ) propylene, dipentaerythritol, pentyl (methyl) acrylate vinegar, bis (neopentitol) tetrakis(mercapto) acrylic acid, tetramethyl ketone: (mercapto) Acrylic acid, 2_ mercapto _3_(indenyl) propylene oxypropyl methyl propyl ester, etc. having a trans-group (meth)acrylic acid S monomer (A) (fluorenyl) The number of acrylic acid s groups is preferably 2 or more, more preferably 3 or more. The number of the radicals of the (meth)acrylic acid vine monomer (4) having a trans group is preferably 2 or more. ; having a reduced photopolymerization start „_) is to have at least one of the bases. The photopolymerization initiator * is, for example, a 2-carbo-indenyl-1·phenyl·propanone]-one (manufactured by Ciba. Japan, product name Dar〇Cur 1173), and (9) a cyclyl group. Manufactured by Stupid Co., Ltd., 7/23 201224098, product name Irgacure 184), etc. In the case of a photopolymerization initiator having two or more groups, for example, 1-[4-(radioethoxy)-benzene is exemplified. 2-hydroxy-2-methyl-1-propan-1-indole (manufactured by Ciba.Japan, product name Irgacure 2959), 2-hydroxy-l-{4-[4-(2-hydroxy-2- Methyl-propenyl)-benzyl]-phenyl}-2-mercapto-propan-1-one (manufactured by Ciba. Japan, product name Irgacure 127), etc. Photopolymerization initiator having a hydroxyl group ( The number of the hydroxyl groups in B) is preferably two or more. The reason is that the photoinitiator which is cleaved after the radiation irradiation has two or more acrylonitriles which enter the (meth) acrylate monomer (A) by two or more. Further, the upper limit of the number of hydroxyl groups is not particularly limited. The isocyanate group-containing isocyanate (c) preferably has two or more isocyanate groups. The isocyanate having two or more isocyanate groups ( c), can For example, an aromatic isocyanate, an alicyclic diisocyanate, an aliphatic diisocyanate, or the like, an aromatic isocyanate or an alicyclic isocyanate is preferably used. In terms of the form of the isocyanate compound, monomers, dimers, and terpolymers are used. Preferably, a trimer is used. Examples of the aromatic diisocyanate include bismuth diisocyanate, 4,4-diphenylmethane diisocyanate, and diphenyl phenyl diisocyanate. Examples of the aliphatic % diisocyanate include, for example, isophorone diisocyanate S, and anthracene bis (isocyanate _4_cyclohexene). The aliphatic diisocyanate may, for example, be hexamethylene diisocyanate or tridecyl hexamethylene diisocyanate. Further, the above-mentioned monoisocyanate is used as a tris-propyl mercapto adduct, a biuret formed by reacting with =, and a heterotrim (tetra) ring. 8/23
201224098 使前述具有的（甲基)丙稀酸醋單體⑷的莫耳數 具有綠的光聚合起始劑⑻之輯的莫耳數的合計 = 時，（A)較佳為6以上、更佳為9以 車又佳為9.9以下、更佳為9.8以下。 “當使前述具有經基的（曱基)丙稀酸醋單體(A)之經基的 吳耳數與前述具有減的光聚合起關(B)之減的 fe- ^、:、 時，具有2個以上異氰酸酯^的異 氘酸酯(c)之異氰酸酯基的莫耳數，較佳為8〜12、更佳為 9〜11。 制前述具有光聚合起始劑之胺基曱酸酯丙烯酸酯(D)之 製造方法並無特別限定。前述具有光聚合起始劑之胺基曱 醪酯丙烯酸酯(D)例如可藉由在乙酸乙酯等之溶劑中^拌 具有羥基的（曱基)丙烯酸酯單體(A)與具有羥基的光聚合起 始劑⑼並同時加溫至4G°C後，花費2小時連續地添加:有 2個以上異氰酸酯基的異氰酸酯(c) ’再進—步攪拌6小時 而製得。 可聚合之（曱基）丙烯酸酯(E)係可聚合之（曱基）丙烯酸 系組成物，只要能進行自由基聚合，則可為任意者，可例 示如下述。此處所謂的（曱基)丙烯酸系組成物係曱基丙烯酸 鲳與丙烯酸酯的總稱（以下如〜(曱基）丙烯酸酯般稱之）。就 可聚合之（曱基)丙細酸S旨@)而§ ’可列舉例如（曱基)丙稀酸 曱酯、（曱基)丙烯酸乙酯、（曱基)丙烯酸丙酯、（曱基）丙烯 峻丁酿、（曱基)丙細酸-2-乙己醋、（曱基)内歸酸異辛自旨、（甲 基)丙柄S欠異癸醋、（曱基)丙稀酸月桂g旨、（甲基)丙稀酸硬脂 鞛、（甲基)丙稀酸苯酯、（曱基)丙稀酸環己酯、（曱基)丙稀 9/23 201224098201224098 When the total number of moles of the photopolymerization initiator (8) having the number of moles of the (meth)acrylic acid vinegar monomer (4) is 0, it is preferable that (A) is preferably 6 or more. Jia is 9 and the car is preferably 9.9 or less, more preferably 9.8 or less. "When the number of Wuer numbers of the above-mentioned (meth)-based acrylic acid vine monomer (A) having a radical group is reduced by the above-mentioned fe- ^, :, The number of moles of the isocyanate group of the isocyanate (c) having two or more isocyanates is preferably from 8 to 12, more preferably from 9 to 11. The above-mentioned amino phthalic acid having a photopolymerization initiator The method for producing the ester acrylate (D) is not particularly limited. The amino oxime ester acrylate (D) having a photopolymerization initiator may be, for example, a solvent having a hydroxyl group in a solvent such as ethyl acetate ( After the acrylate monomer (A) and the photopolymerization initiator (9) having a hydroxyl group are simultaneously heated to 4 G ° C, it is continuously added for 2 hours: isocyanate having two or more isocyanate groups (c) It can be obtained by further stirring for 6 hours. The polymerizable (fluorenyl) acrylate (E) polymerizable (fluorenyl) acrylic composition can be exemplified as long as it can undergo radical polymerization. As described below, the so-called (fluorenyl) acrylic composition is a general term for bismuth methacrylate and acrylate (hereinafter as ~(曱Acrylate-like). The polymerizable (fluorenyl)propionic acid S is intended to be @) and § 'exemplifies, for example, (fluorenyl) decyl acrylate, ethyl (meth) acrylate, ) propyl acrylate, (mercapto) propylene styrene, (mercapto) propionate-2-ethyl hexanoic acid, (mercapto) internal acid, octyl sulphate, (methyl) propyl sulphur , (mercapto) acrylic acid, lauric acid, (meth) benzoate, phenyl (meth) acrylate, (fluorenyl) cyclohexyl acrylate, (mercapto) propylene 9/23 201224098
酯、（曱基)丙稀酸_3_經丙酯、 •經乙酯、（曱基)丙烯酸·2_羥丙 (曱基)丙烯酸-4-羥丁酯、聚乙 -醇(甲基)丙烯酸醋、烧氧基聚丙二醇(甲基)丙稀酸醋、（甲 基)丙烯酸四氫糠I旨、（曱基)丙烯酸·2•錄_3_苯氧基丙醋、 (曱基）丙烯酸環氧丙g旨、己内酷改胃（曱基）丙烯酸四糖 酉旨、（曱基)丙烯酸乙氧基羰基甲酯、齡環氧乙烧改質（甲基) 丙烯酸醋、對Μ香基紛氧乙触f (?基)丙稀酸g|、壬基盼 環氧乙烷改質（曱基）丙烯酸酯、壬基酚聚環氧丙烷改質（曱 基)丙烯酸酯、2-乙己基卡必醇（曱基)丙烯酸酯、聚丙三醇二 (曱基)丙烯酸自曰、1 丁一醇二（曱基)丙稀酸酯、1，4_丁二醇（甲 基)丙烯酸酯、1，6-己二醇二（曱基)丙烯酸酯、新戊二醇二（曱 基)丙烯酸酯、二羥甲基丙烷三（曱基)丙烯酸酯、環氧基（曱 基)丙細酸醋(大阪有機化學公司製，「VISCOTE #540」）、 聚酯（曱基）丙烯酸酯（東亞合成公司製，「Ar〇NIX M-6100」、共榮化學公司製，Γ£ρ〇Χγ ester 3⑻〇M」）、 胺基曱酸酯（曱基）丙稀酸酯（東亞合成公司製，「AR〇NIX M-1100」）、聚乙一醇胺基曱酸酯改質二（曱基)丙烯酸酯、 聚丙二醇胺基曱酸酯改質二（曱基)丙烯酸酯、（甲基)丙烯酸 環氧酯(東亞合成公司製，「ARONIXM-5710」）、聚二（甲基) 丙烯酸丁二烯酯（日本曹達公司製，「TE-2000」）、（曱基)丙 烯酸丙烯腈丁二烯酯（宇部興產公司製，「HyCAr VTBNX」）、（曱基）丙烯酸苄酯、丙三醇（曱基)丙稀酸酯、 丙三醇二（甲基）丙烯酸酯、苯氧基二乙二醇（曱基）丙烯酸 10/23 201224098 醋:2,2·雙(4-(甲基)_氧基笨基)丙m雙(4_( 稀氧基二乙氧基笨基)丙烧、2,2_雙(4_(曱基)两 1 苯基)丙烧、2,2-雙(4·(甲基)丙烯氧基丙氧基笨基)丙烧3 雙(4-(甲基)丙烯氧基四乙氧基苯基)丙烧、a雙[I《甲美 ㈣氧基聚乙氧總基]战、新細醇⑽基）丙^酸 酯、二新戊四醇六（甲基）丙烯酸酯等。 可使用1種或2種以上的上述⑹成分，較佳為由（甲基） 丙婦酸異获醋、二（甲基)丙稀酸二環戊卿旨、三經甲基丙烷 三（曱基）丙烯酸酯所構成之群組中的丨種以上。其理由在 於，以高溫高濕試驗、耐候性試驗為首之耐久性試驗中， 在王現局保持率方面較佳。 在本發明中因提升對於玻璃乃至塑膠之密合力的目 的，可含有矽烷偶合劑做為(F)成分。就矽烷偶合劑而言， 可列舉例如：γ-氯丙基三曱氧基矽烷、乙烯基三甲氧基矽 烷、乙烯基三氣矽烷、乙烯基三乙氧基矽烷、乙烯基_參(|3_ 甲氧基乙氧基)矽烷、γ-(甲基)丙烯氧基丙基三曱氧基矽烷、 β_(3,4-環氧基環己基）乙基三曱氧基矽烷、γ_環氧丙氧基丙 基三曱氧基矽烷、γ-酼基丙基三曱氧基矽烷、胺基丙基三 乙氧基矽烷、Ν-β-(胺基乙基胺基丙基三甲氧基矽烷、 Ν·β_(胺基乙基)个胺基丙基曱基二曱氧基矽烷、γ—脲基丙基 二乙氧基矽烧等。此等之中，在對於玻璃等之密合性方面， 較佳為γ-環氧丙氧基丙基三曱氧基矽烷及/或γ-(曱基)丙烯 氧基丙基三曱氧基矽烷、更佳為厂環氧丙氧基丙基三曱氧 基石夕烧。 在本發明的樹脂組成物中，（D)成分、（Ε)成分的合計 11/23 201224098 ⑽質量份中，較佳為含有5〜95質量份(D)成分、 量份⑹成分；更佳為含有H)〜90質量份⑼成分、二 量份¢)成分；最佳為含有30〜8〇質量份(D)成分、二 量份(E)成分。 U貝 相對於(D)成分、（Ε)成分之合計1〇〇質量份，火 糾使用量於有0.0WG質量份時，組成物之相對^^ 著體的黏著性會格外地升高，且硬化性良好故較 部 為含有0.1〜5質量份。 ’更佳 ，可使用含有聚合禁止 劑 杜維持儲存安定性之目的上 之市售的抗氧化劑等。 對於此等之其他者，亦可依據所期望而使用可塑 填充劑、著色劑或防銹劑等已知物質。 i"" 本發明係對樹脂組成物照射可見光線或紫外 成物硬化而黏著。 ' 、’’吏組 可見光線或紫外線的累計光量，在365nm較佳為 100〜40000mJ/cm2、更佳為 500〜4000mj/cm2。 本發明的樹脂組成物係觸控面板中的形成有透明電極 之透明基板上之做為取代透明基板的保護基材。本發明的 樹脂組成物係不含氣泡而貼合者，且係確保充分的黏著性 者。本發明的樹脂組成物可做為黏著劑、硬被覆劑而使用。 在本發明中，可藉由樹脂組成物的硬化物將被黏著體 接合或被覆而製作複合物。關於被黏著體的各種材料，較 佳為選自由三乙醯基纖維素、氟系聚合物、聚酯、聚碳酸 酯'環烯烴聚合物等聚烯烴、玻璃、金屬所構成群組中的i 種以上；更佳為選自由聚酯、聚碳酸酯、玻璃所構成群組 12/23Ester, (mercapto)acrylic acid _3_ propyl ester, • ethyl ester, (mercapto) acrylic acid, 2-hydroxypropyl (decyl) acrylate 4-hydroxybutyl ester, polyethyl alcohol (methyl) Acrylic vinegar, aerobic polypropylene glycol (meth) acrylate vinegar, tetrahydro hydrazine (meth) acrylate, (fluorenyl) acrylate, 2 • _3 phenoxy propyl vinegar, Acrylic acid, propylene, g, hexapod, succinyl acrylate, ethoxycarbonyl methyl acrylate, epoxide epoxide modified (meth) acrylate vinegar, Μ香基纷乙乙触 f (?) acrylic acid g|, thiophene oxirane modified (mercapto) acrylate, nonylphenol propylene oxide modified (mercapto) acrylate, 2-ethylhexyl carbitol (mercapto) acrylate, polyglycerol bis(indenyl) acrylate, butyl hexanyl bis(mercapto) acrylate, 1,4-butane diol (methyl) Acrylate, 1,6-hexanediol bis(indenyl) acrylate, neopentyl glycol bis(indenyl) acrylate, dimethylolpropane tris(decyl) acrylate, epoxy group ) Acrylic acid vinegar ("VISCOTE #540", manufactured by Osaka Organic Chemical Co., Ltd.), Polyester (mercapto) acrylate (manufactured by Toagosei Co., Ltd., "Ar〇NIX M-6100", manufactured by Kyoei Chemical Co., Ltd., 〇Χ£ρ〇Χγ ester 3(8)〇M"), amino phthalate (fluorenyl) Acrylate ("AR〇NIX M-1100", manufactured by Toagosei Co., Ltd.), modified bis(mercapto) acrylate, polypropylene glycol amide phthalate, Acrylate, epoxy (meth)acrylate ("ARONIXM-5710", manufactured by Toagosei Co., Ltd.), polybutadiene (meth)acrylate ("TE-2000", manufactured by Nippon Soda Co., Ltd.), (Mercapto) acrylic acrylonitrile butadiene ester ("HyCAr VTBNX", manufactured by Ube Industries, Ltd.), benzyl (meth) acrylate, glycerol (mercapto) acrylate, glycerol (A) Acrylate, phenoxy diethylene glycol (mercapto) acrylic acid 10/23 201224098 vinegar: 2,2·bis(4-(methyl)-oxyphenyl)propyl m double (4_(diloxy) Diethoxyphenyl)propane, 2,2-bis(4-(indolyl)bisphenyl)propane, 2,2-bis(4.(methyl)acryloxypropoxyphenyl) Propylene 3 bis(4-(methyl)acryloxytetraethoxyphenyl Acetone, a double [I "Ami (4) oxypolyethoxy group], a new fine alcohol (10)) propyl acid ester, dipentaerythritol hexa (meth) acrylate, and the like. One type or two or more types of the above (6) components may be used, and it is preferably (meth) propyl acetoacetate, bis(methyl) acrylate dicyclopentanyl, and trimethyl propyl propane. More than one species in the group consisting of acrylates. The reason for this is that the durability test including the high temperature and high humidity test and the weather resistance test is preferable in terms of the current retention rate of the king. In the present invention, a decane coupling agent may be contained as the component (F) for the purpose of improving the adhesion to glass or plastic. Examples of the decane coupling agent include γ-chloropropyltrimethoxy decane, vinyl trimethoxy decane, vinyl trioxane, vinyl triethoxy decane, and vinyl _ gin (|3_ Methoxyethoxy)decane, γ-(meth)acryloxypropyltrimethoxy decane, β-(3,4-epoxycyclohexyl)ethyltrimethoxy decane, γ-epoxy Propoxypropyltrimethoxy decane, γ-mercaptopropyltrimethoxy decane, aminopropyltriethoxydecane, Ν-β-(aminoethylaminopropyltrimethoxydecane Ν·β_(aminoethyl)aminopropyl decyl decyloxydecane, γ-ureidopropyldiethoxy oxime, etc. Among these, adhesion to glass or the like In a preferred aspect, it is preferably γ-glycidoxypropyltrimethoxy decane and/or γ-(fluorenyl) propyleneoxypropyltrimethoxy decane, more preferably a glycidoxypropyl group. In the resin composition of the present invention, the total amount of the component (D) and the (Ε) component is preferably from 5 to 95 parts by mass of the component (D) in the total amount of 11/23 201224098 (10) parts by mass. Component (6); more preferably H) 90 parts by mass ⑼ component, an amount of two parts ¢) component; most preferably containing 30~8〇 parts by mass component (D), an amount of two parts of component (E). When the U shell is used in combination with the (D) component and the (Ε) component in a total amount of 1 part by mass, and the fire correction amount is 0.0 WG mass part, the adhesion of the composition to the body is particularly increased. Further, the hardenability is good, so the comparative portion contains 0.1 to 5 parts by mass. More preferably, a commercially available antioxidant or the like containing a polymerization inhibitor to maintain storage stability can be used. For these others, known materials such as plastic fillers, colorants or rust inhibitors may be used as desired. i"" The present invention adheres to the resin composition by irradiation with visible light or ultraviolet light. The cumulative light amount of visible light or ultraviolet light in the ', '' group is preferably 100 to 40000 mJ/cm 2 at 365 nm, more preferably 500 to 4000 mj/cm 2 . The resin composition of the present invention is a protective substrate on which a transparent substrate is formed on a transparent substrate in which a transparent electrode is formed. The resin composition of the present invention is a one which does not contain air bubbles and which adheres to it, and which ensures sufficient adhesiveness. The resin composition of the present invention can be used as an adhesive or a hard coating agent. In the present invention, a composite can be produced by bonding or coating an adherend by a cured product of a resin composition. The various materials for the adherend are preferably selected from the group consisting of polyolefins such as triethylenesulfonyl cellulose, fluorine-based polymers, polyesters, polycarbonate 'cycloolefin polymers, glass, and metals. More than one; more preferably selected from the group consisting of polyester, polycarbonate, and glass 12/23
201224098 中的1種以上。 可藉 作，由==明的樹脂組成物將被黏著體貼合而製 而言，可列舉觸控面板積層體或液晶 面板積層體等電子裝置。結知二上 /.a 觸控面板積層體或液晶面板積層 體寻可使用於顯示器。 [實施例1 本下'用表一 1〜3來說明本發明。本發明並不限定於此 义1絲喊祕具有光聚合起始劑之胺基甲酸g旨丙 =旨_化合物之調配、表2絲3組成物 配及其評價。 <實驗材料的調製> 以下述的處方來製造與實施例相關之黏著劑乃至硬被 覆劑。 表1中所記載於之各化合物為下述者： 八有L基的（曱基)丙烯酸酯單體(A)_曱:2_羥乙基（曱基) 丙嫦酸酯； 具有髮基的（曱基）丙烯酸酯單體(Α)·乙:新戊四醇三丙 稀酸醋(大阪有機化學公司製，產品名ν#3〇〇); 具有經基的（曱基)丙烯酸酯單體(Α)-丙：丙三醇二（曱基） 丙烯酸酯（共榮社化學公司製，產品名UGHT ESTER G-101P)； 具有㉖基的光聚合起始劑(B)-曱：1 -羥基-環己基-苯基-酮(Ciba.Japan 公司製，產品名 Irgacure 184); 具有每基的光聚合起始劑(B)-乙:2·羥基-1 - {4-[4-(2-羥 基·2_曱基-丙酿基)-节基]_笨基卜2_曱基^小酮(Ciba.Japan 13/23 201224098 公司製，產品名Irgacure 127); 具有羥基的光聚合起始劑(B)-丙：1-[4-(羥基乙氧基笨 基]-2-經基-2曱基-1-丙-l-_(ciba.Japan公司製，產品名 Irgacure 2959)； 具有2個以上異氰酸酿基的異氰酸醋(〇-甲：六亞曱基 一異氛酸醋的二聚物(Asahi Kasei Chemicals公司製，產品 名 DURANATETPA-100); 具有2個以上異氰酸酯基的異氰酸酯(c)-乙：曱伸苯基 二異氰酸酯； 可聚合之（曱基)丙稀酸g旨(E>曱:二丙稀酸二環戊稀酯； 可聚合之（曱基）丙烯酸酯(E)-乙：三羥曱基丙烷三丙烯 酸酯； 矽烷偶合劑(F)-曱:γ-曱基丙烯氧基丙基三甲氧基石夕烷； 矽烧偶合劑(F)-乙:γ-環氧丙氡基丙基三曱氧基矽烧 具有光聚合起始劑之胺基曱酸酯丙烯酸酯(〇)係藉由 在遮光條件下，在乙酸乙酯中攪拌具有羥基的（曱基)丙烯酸 酯單體(Α)與具有羥基的光聚合起始劑(Β)的同時加溫至 40°C後，花費2小時連續地添加具有2個以上異氰酸酯基 的異氰酸酯(C)，再進一步搜拌6小時而製得者。 (實施例及比較例） 對應於各實施例及比較例之黏著劑乃至硬被覆劑的主 成分與其調配量係如表1〜3所示。當調製時，除了此等之 於表1所示之成分以外，還有調配上述(E)成分及(F)成分。 在比較例1〜2之中，係使用以胺基曱酸酯丙烯酸酯寡 聚物(根上工業公司製，產品名UN-3320HS)50〜100質量份One or more of the 201224098. In the case where the resin composition of == Ming is bonded to the adhesive body, an electronic device such as a touch panel laminate or a liquid crystal panel laminate can be used. It is known that the second /.a touch panel laminate or the liquid crystal panel laminate can be used for the display. [Example 1] The present invention will be described using Tables 1 to 3. The present invention is not limited to the above, and the evaluation of the composition of the urethane for the photopolymerization initiator, the composition of the compound, the composition of the filaments, and the evaluation thereof. <Preparation of Experimental Material> An adhesive or even a hard coating agent according to the examples was produced by the following formulation. Each of the compounds described in Table 1 is as follows: an octyl acrylate monomer (A) _ 曱: 2 hydroxyethyl (fluorenyl) propyl phthalate; (fluorenyl) acrylate monomer (Α)·B: pentaerythritol triacrylic acid vinegar (manufactured by Osaka Organic Chemical Co., Ltd., product name ν#3〇〇); thiol-based acrylate having a mercapto group Monomer (Α)-propene: glycerol di(indenyl) acrylate (manufactured by Kyoeisha Chemical Co., Ltd., product name UGHT ESTER G-101P); photopolymerization initiator (26) with 26 groups-曱: 1-Hydroxy-cyclohexyl-phenyl-ketone (manufactured by Ciba. Japan, product name Irgacure 184); photopolymerization initiator (B) per group: B: 2·hydroxy-1 - {4-[4 -(2-hydroxy·2_fluorenyl-propyl aryl)-]]]]]]]]]]]]]]]]]]]]]]] Photopolymerization initiator (B)-propene: 1-[4-(hydroxyethoxyphenyl)-2-yl-2-yl-1-propan-1-l-((Ciba.Japan), product name Irgacure 2959); isocyanate with more than 2 isocyanic acid ketones (di-A: hexamethylene sulfonate-isomeric acid vinegar dimer (Asahi Kasei Chem) Icals company, product name DURANATETPA-100); isocyanate (c)-B: phenylene diisocyanate having two or more isocyanate groups; polymerizable (mercapto) acrylic acid g (E> 曱: two Dicyclopentyl acrylate; polymerizable (meth) acrylate (E)-B: trihydroxymercaptopropane triacrylate; decane coupling agent (F)-曱: γ-mercaptopropenyloxy Trimethoxy oxetane; oxime coupling agent (F)-B: γ-glycidyl propyl trimethoxy oxime oxime oxime ester acrylate (〇) system with photopolymerization initiator After heating to a temperature of 40 ° C while stirring a (meth) acrylate monomer having a hydroxyl group in ethyl acetate with a photopolymerization initiator (Β) having a hydroxyl group under light-shielding conditions The isocyanate (C) having two or more isocyanate groups was continuously added over 2 hours, and further prepared by further mixing for 6 hours. (Examples and Comparative Examples) Adhesives and even hard coating agents corresponding to the respective Examples and Comparative Examples The main components and their blending amounts are shown in Tables 1 to 3. When preparing, in addition to the components shown in Table 1, there are also adjustments. The above-mentioned (E) component and the component (F) were used. In Comparative Examples 1 to 2, an amino phthalate acrylate oligomer (manufactured by Kasei Kogyo Co., Ltd., product name UN-3320HS) was used in an amount of 50 to 100. Share
14/23 201224098 與光聚合起始劑(Ciba· Japan公司製，產品名lmgacure 651 )3 質量份取代具有光聚合起始劑之胺基曱酸酯丙烯酸酯(D) 調配而成者來調製組成物。 各種物性係如下進行測定。 [光硬化性] 在溫度23°C下進行測定。關於光硬化性，在TEMPAX 玻璃(25mmx25mmx2mm)的表面上塗布硬化性樹脂組成物 使厚度成為0.1mm。然後利用使用無電極放電燈之Fusion 公司製硬化裝置，在累計光量2000mJ/cm2的條件下照射波 長365nm的UV光而使其硬化。記載硬化率做為光硬化性。 硬化率係使用FT-IR並由下式算出。 (硬化率）=[1 〇〇_((硬化後之碳與碳雙鍵的吸收光譜強 度)/(硬化前之碳與碳雙鍵的吸收光譜強度別X ；! 00(%；) 光硬化性的評價如下。 〇：在表面無黏性（由FT-IR算出之硬化率:90%以上）； △:在表面的一部份有黏性（由FT-IR算出之硬化 率:50%-89%); x :在表面全體有黏性（由FT-IR算出之硬化率:0-49%)。 (評價用構件製造方法：實施例比較例共通） 用棒塗機將製得之組成物塗布在TEMPAX玻璃 (25mmx25mmx2mm)上，使膜厚成為ΙΟμιη’依照[光硬化性] 硬化後，形成組成物的皮膜。 製得之各薄膜的全光線穿透率、霧度、鉛筆硬度的結 果及耐光性試驗的結果之値一併示於表1〜3。 性能試驗方法係如下述： 15/23 201224098 (全光線穿透率及霧度） 使用霧度計(SUGA試驗機公司製），遵循jis K7361及 JISK7136進行測定。 (鉛筆硬度） 使用Scratch試驗機（KASAI公司製），遵循jIS K5600-5-4，在負重ikg下進行測定。 (耐光性試驗） 使用 Sunshine Weather Meter (SUGA 試驗機公司製）， 對試樣的塗布面惻照射紫外線’曝露2〇〇小時(無水噴霧）。 針對曝露後之試樣測定鉛筆硬度。 (對於玻璃之拉伸剪斷黏著.強度(黏著強度、玻璃)） 依照JIS K： 6850進行測定。使用TEMPAX玻璃 (25mmx25mmx2mm)做為被黏著材料。使黏著部位為 8mmcp(所謂使黏著部位為8mm(p，係指稱黏著部位為直徑 8mm的圓）’使用樹脂組成物貼合2片丁EMPAX玻璃。藉 由使用無電極放電燈之Fusi〇n公司製硬化裝置，在365nm 的波長之累計光量2〇〇〇mj/cnl2之條件下使其硬化，製作拉 伸剪斷黏著強度試驗片。試驗片係使用萬能試驗機，在溫 度23°C、濕度50%的環境下，以拉伸速度1〇mm/min測定 拉伸剪斷黏著強度。 (對於聚酯之黏著強度(黏著強度、聚酯)） ；使用PET薄膜（l〇ininx50mmxl85pm)做為被黏著材 料。使黏著部位為10mmx30mm，使用樹脂組成物貼合2 片PET薄膜。藉由使用無電極放電燈之Fusi〇n公司製硬化 裝置，在365nm的波長之累計光量2000mJ/cm2的條件下使 16/2314/23 201224098 The photopolymerization initiator (product name lmgacure 651, manufactured by Ciba Japan Co., Ltd.) was prepared by disposing 3 parts by mass of an amine phthalate acrylate (D) having a photopolymerization initiator to prepare a composition. Things. Various physical properties were measured as follows. [Photocurability] The measurement was carried out at a temperature of 23 °C. Regarding the photocurability, a curable resin composition was applied onto the surface of TEMPAX glass (25 mm x 25 mm x 2 mm) to have a thickness of 0.1 mm. Then, it was cured by irradiating UV light having a wavelength of 365 nm under the condition of a cumulative light amount of 2000 mJ/cm 2 by using a curing device manufactured by Fusion Co., Ltd. using an electrodeless discharge lamp. The hardening rate is described as photocurability. The hardening rate was calculated by the following formula using FT-IR. (hardening rate) = [1 〇〇 _ ((absorption spectrum intensity of carbon and carbon double bonds after hardening) / (absorption spectrum intensity of carbon and carbon double bonds before hardening X; ! 00 (%;) light hardening The evaluation of the properties is as follows: 〇: no tackiness on the surface (hardening rate calculated by FT-IR: 90% or more); △: stickiness in a part of the surface (hardening rate calculated by FT-IR: 50%) -89%); x : Viscosity on the entire surface (hardening rate calculated by FT-IR: 0 to 49%). (Method for producing member for evaluation: common in the comparative examples of the examples) The composition was coated on TEMPAX glass (25 mm x 25 mm x 2 mm) so that the film thickness became ΙΟμηη. After curing according to [photocurability], a film of the composition was formed. The total light transmittance, haze, pencil hardness of each film obtained was obtained. The results and the results of the light resistance test are shown in Tables 1 to 3. The performance test methods are as follows: 15/23 201224098 (total light transmittance and haze) Using a haze meter (manufactured by SUGA Testing Machine Co., Ltd.) The measurement was carried out in accordance with jis K7361 and JISK7136. (Pencil hardness) Using a Scratch tester (manufactured by KASAI), following jIS K5600-5-4, The measurement was carried out under a heavy ikg. (Light resistance test) Using a Sunshine Weather Meter (manufactured by SUGA Testing Machine Co., Ltd.), the coated surface of the sample was irradiated with ultraviolet light for 2 hours (anhydrous spray). Pencil hardness. (For glass tensile shear adhesion. Strength (adhesive strength, glass)) Measured according to JIS K: 6850. Use TEMPAX glass (25mmx25mmx2mm) as the adhesive material. Make the adhesive part 8mmcp (so-called adhesion) The part is 8 mm (p, which means that the adhesive part is a circle having a diameter of 8 mm). Two pieces of butyl EMPAX glass are bonded together using a resin composition. By using a hardening device manufactured by Fusi〇n Co., Ltd. of an electrodeless discharge lamp, at a wavelength of 365 nm The accumulated light amount was hardened under the condition of 2〇〇〇mj/cnl2, and a tensile shear adhesive strength test piece was produced. The test piece was stretched at a temperature of 23 ° C and a humidity of 50% using a universal testing machine. The tensile shear strength was measured at a speed of 1 〇 mm/min (adhesive strength (adhesive strength, polyester) for polyester); PET film (l〇ininx50mmxl85pm) was used as the adhesive material. Bit 10mmx30mm, a resin composition bonded to two PET films. Fusi〇n by using an electrodeless discharge lamp manufactured by means of curing the 16/23 integrated amount of light at wavelengths of 365nm 2000mJ / cm2 of
S 201224098 其硬化，製作剝離黏著強度試驗片。試驗片係使用萬能試 驗機，在溫度23°C、濕度50%的環境下，以拉伸速度 50mm/min測定剝離強度。 (對於聚碳酸酯之拉伸剪斷黏著強度(黏著強度、聚碳酸 酯)） ^q州疋。便用聚碳酸酯板 (25mmx25mmx2mm)做為被黏著材料。使黏著部位為 8ιηηκρ(所謂使黏著部位為8mm(p，係指稱黏著部位為直徑 8麵^)，使卿旨組成物貼合2片聚碳酸喊。藉由使 =^電燈之Fusion公司製硬化裝置，在奶麵的波 斷4;:=00—2的條件下使其硬化，製作拉伸剪 。。、濕度m的環境下，以拉:用侧’在溫度23 剪斷黏著強度。 V度lOmm/min測定拉伸 17/23 201224098 18/23 KT ^ 溫~φ泰 ->ί Λ "> Κ η ^ 犛驷+ # X溫掛 w芦S痒丨抽讲μ 薄g 舞！亩 溫》丧^驷交 r;>Sg、t ^ \ipr ^ K W $溫芦 0 0^ ^ .3 F 3 _ 1 -tsv M： S 3 κ> ^ S命 如0⑧和 ;降幕知 +容溫辦 3 Μ Μ ^ iL -Η ^ (C)-曱 10 (Β)-乙 0.5 (A)-乙 9.5 (D)-甲 1 ! 1 (C)-甲 10 ⑼-乙3 _1 (A)-乙 7 i_ (D)-乙 (C)-曱 9 (Β)-乙 0.5 (A)-乙 9.5 ί_ (D)-丙 J j (C)-甲 11 ⑼-乙0.5 (A)-乙 9.5 1_ (D)-丁 (C)-曱 10 (β)-乙 _0.5 (A)-甲 9.5 (D)-戊 (C)-曱 10 (Β)-甲 0.5 1 (A)-乙 9.5 (D)-己 (C)-乙 10 (Β)-丙 0.5 (A)-丙 9_5 i (D)-庚 【>1】 s 201224098 【<Nd 實施例 (D)-己 50 甲50 甲0.5 弍〇 (Ν On s ο X 寸 X 寸 寸 00 (D)-戊 50 甲50 | 甲 0.5 1 弍〇 (Ν s ο 山 寸 寸 〇 r— ο 寸 (D> 丁 50 甲50 甲0.5 苳〇 (Ν Os ^―· ο ο X 寸 工 寸 r- rn (Ν 卜 (Ν cn (D)-丙 50 I 甲 50 I 甲0_5 芸〇 (Ν S ο 寸 寸 00 Ο CN (D)-乙 50 | 甲 50 1 甲0.5 系〇 (Ν Ον S ο X 寸 工 00 ΓΛ (D)-甲 50 曱50 甲0.5 客〇 (Ν Η ο ο 3： 寸 寸 τ—' rn <Ν 卜 CN 具有光聚合起始劑之胺基甲 酸@旨丙歸酸醋(D)(質量份） (甲基)丙烯酸酯(E)(質量份） 矽烷偶合劑(F)(質量份） 光硬化性（％) 全光線穿透率（％) 霧度（％) 鉛筆硬度 耐光性試驗後的鉛筆硬度 黏著強度（玻璃，MPa) 黏著強度（聚酯，N/cm) 黏著強度（聚碳酸酯，MPa) 調配 Λ *\ιΦ e3/- 201224098 20/23 3 調配 黏著強度（聚碳酸酯，MPa) 黏著強度（聚酯，N/cm) 黏著強度（玻璃，MPa) 耐光性試驗後的鉛筆硬度 鉛筆硬度 霧度（％) 全光線穿透率（％) 光硬化性（％) Irgacure651 (質量份） 矽烷偶合劑(F)(質量份） (曱基)丙烯酸ί旨(Ε)(質量份） S ^ ® Li ~S 〇 i ^ ^ ^ H®⑹爵 ^ S ^ w ^辦 麥 潭·和 眾命 溫為" 3赛 乂逵 Μ®踌 麥‘ w -a 〇 bo Lk) X U) ο s Ό Κ) 〇汔 1 | 曱 0.5 1 曱90 1 (D)-甲 10 實施例 Ui ΙΌ o k) hr ο s ο NJ Ο ϋ 1 I 甲 0.5 I I 曱 7〇 I 1 (D)-甲 30 00 LTi K> X ο s Ό Κ) 〇芝 1 Γ 曱 〇·5 1 曱20 | 1 (D)-甲 80 Q\ — po Ξ Ξ ο b Ο ιο 〇i§ 1 | 甲 0.5 1 I 曱 ίο I 1 (D)-曱 90 Ό U\ hO K) U) X X o s Ό to O i§ 1 乙0.5 乙50 1 ff»)-庚 50 二 p o ΪΧ> 3 h—1 〇汔 U) 曱0.5 1 〇 1 比較例 U) 0 1 二 ro CD CO 〇汔 LO 曱 0.5 | 甲50 | 1 to 比較例 未硬化 未硬化 未硬化 未硬化 未硬化 I未硬化 1未硬化ι X Κ) 1 曱0.5 | 甲 50 I 1 U) 比較例 o L/i 1—* ---^ o s 〇名 1 1 曱90 | 1 (D)-甲 10 比較例 【>3】 s 201224098 由表可传知本發明的樹脂組成物具有下述特徵： ⑴本發明的樹脂組成物可於不含人氣泡下貼合 、透明 性大。本U的樹脂組成物為翻絲的保護基材。 ⑺本發明的娜喊物之料硬度，尤其是耐光性試 驗後的^筆硬度大。本發明_脂組成物可提#重即使 在光曝露的環境下使用亦難以損傷的硬被覆劑广 (3)本發明的樹脂組錢可確絲分的 的樹脂組成物可做為黏著劑使用。 微本《明 【圖式簡單說明】 無。 【主要元件符號說明】S 201224098 It is hardened to produce a peel adhesion test piece. The test piece was subjected to a universal test machine, and the peel strength was measured at a tensile speed of 50 mm/min in an environment of a temperature of 23 ° C and a humidity of 50%. (For the tensile shear strength of polycarbonate (adhesive strength, polycarbonate)) ^q state 疋. Polycarbonate sheets (25mm x 25mm x 2mm) were used as the adhesive material. The adhesion site is 8 ιηηκρ (the so-called adhesive portion is 8 mm (p, which refers to the adhesion site as the diameter of 8 faces ^), so that the composition of the composition is bonded to the two pieces of polycarbonate. By hardening the Fusion company of the ^^ electric lamp The device is hardened under the condition of wave break 4;:=00-2 of the milk surface to make a tensile shear. In the environment of humidity m, pull: use the side 'cutting the adhesive strength at temperature 23. V Degree lOmm/min measurement stretch 17/23 201224098 18/23 KT ^ temperature ~ φ泰-> ί Λ "> Κ η ^ 牦驷+ # X温挂 w芦 S itchy 丨 μ μ thin g dance !亩温》丧^驷交r;>Sg, t ^ \ipr ^ KW $温芦0 0^ ^ .3 F 3 _ 1 -tsv M: S 3 κ> ^ S-like as 08 and;知+容温办3 Μ Μ ^ iL -Η ^ (C)-曱10 (Β)-B 0.5 (A)-B 9.5 (D)-A 1 ! 1 (C)-A 10 (9)-B 3 _1 (A)-B 7 i_ (D)-B (C)-曱9 (Β)-B 0.5 (A)-B 9.5 ί_ (D)-C J j (C)-A 11 (9)-B 0.5 (A )-B 9.5 1_ (D)-丁(C)-曱10 (β)-B_0.5 (A)-A 9.5 (D)-E (C)-曱10 (Β)-A 0.5 1 (A) - B 9.5 (D) - hex (C) - B 10 (Β) - C 0.5 (A) - C 9_5 i (D) - Geng [>1] s 20122 4098 [<Nd Example (D)-Hundred 50 A 50 A 0.5 弍〇 (Ν On s ο X inch X inch inch 00 (D) - 戊50 A 50 | A 0.5 1 弍〇 (Ν s ο 山寸寸 inch R— ο inch (D> Ding 50 A 50 A 0.5 苳〇 (Ν Os ^ —— ο ο X inch inch r- rn (Ν 卜 (Ν cn (D)-C50 I A 50 I A 0_5 芸〇 (Ν S ο inch inch 00 Ο CN (D)-B 50 | A 50 1 A 0.5 system 〇 (Ν S S S S S S X 00 00 D D D D D D D D D 3 3 3 3 3 3 3 3 3 3 3 : inch inch τ—' rn <Ν 卜CN Amino acid with photopolymerization initiator@甲丙酸酸(D) (parts by mass) (meth) acrylate (E) (mass parts) decane coupling agent (F) (parts by mass) Photocurability (%) Total light transmittance (%) Haze (%) Pencil hardness after pencil hardness test Hardness (glass, MPa) Adhesive strength (polyester, N/ Cm) Adhesive strength (polycarbonate, MPa) Blending Λ *\ιΦ e3/- 201224098 20/23 3 Formulated Adhesive Strength (Polycarbonate, MPa) Adhesive Strength (Polyester, N/cm) Adhesive Strength (Glass, MPa) ) Pencil hardness lead after light resistance test Hardness haze (%) Total light transmittance (%) Photohardenability (%) Irgacure651 (parts by mass) decane coupling agent (F) (mass parts) (fluorenyl) acrylic acid 旨 (Ε) (parts by mass) S ^ ® Li ~S 〇i ^ ^ ^ H®(6) 爵^ S ^ w ^Run Maitan·and the life temperature is " 3 Cellulite® Quinoa 'w -a 〇bo Lk) XU) ο s Ό Κ) 〇汔1 | 曱0.5 1 曱90 1 (D)-A 10 Example Ui ΙΌ ok) hr ο s ο NJ Ο ϋ 1 I A 0.5 II 曱7〇I 1 (D)-A 30 00 LTi K> X ο s Ό Κ) 〇芝 1 Γ 曱〇·5 1 曱20 | 1 (D)-甲80 Q\ — po Ξ Ξ ο b Ο ιο 〇i§ 1 | A 0.5 1 I 曱ίο I 1 (D)-曱90 Ό U\ hO K) U) XX os Ό to O i§ 1 B 0.5 B 50 1 ff»)-Geng 50 2 po ΪΧ> 3 h-1 〇汔U) 曱0.5 1 〇1 Comparative Example U) 0 1 二ro CD CO 〇汔LO 曱0.5 | A 50 | 1 to Comparative Example Unhardened Unhardened Unhardened Unhardened Unhardened I Unhardened 1 Unhardened ι X Κ) 1 曱0.5 | A 50 I 1 U) Comparative example o L/i 1—* ---^ os 〇 1 1 曱90 | 1 (D)-A 10 Comparative example [>3] s 201224098 Table Chihpen invention can pass a resin composition having the following characteristics: ⑴ resin composition of the present invention may be in the free bubbles fit person, large transparency. The resin composition of the present U is a protective substrate for a turn. (7) The hardness of the material of the present invention, especially the hardness after the light resistance test. The present invention can be used as an adhesive for the resin composition of the present invention, which is difficult to damage even in the environment of light exposure. (3) The resin composition of the resin group of the present invention can be used as an adhesive. . Microbook "Ming [Simple diagram description] None. [Main component symbol description]