TW201222930A - A laminated material for secondary battery container and method for manufacturing the same and secondary battery container - Google Patents

Abstract

The present invention provides a laminated material which can be used in secondary battery container or outer packing material having excellent vibration resistance and a secondary battery using the laminated material thereof. The laminated material is a laminated material formed by laminating a film (A) comprising polyethylene terephthalate, polyethylene naphthalate, poly lactic acid or para-aromatic polyamide, a nylon 6 film (B), a aluminum foil (C) and a polypropylene film (D) in turn, which is characterized in that: A is a biaxial orientation film, B and D are non-orientation films, a modified polyolefine layer set between C and D and the Young's modulus of D is under 500MPa.

Description

201222930 VI. Description of the invention: [Technical field to which the invention relates] The present invention relates to a laminated material used for a secondary thunder, which is known as the secondary battery, and has a β impact resistance as a secondary battery. Excellent I t Μ # ° Resistance to vibration and resistance of the material used, = Excellent laminate and its use [Prior Art] Electricity is also used in Gu Yi. In the case of the use of the battery, the use of the battery is considered to be promising. In the outer coffin for the ion secondary battery, the laminated material of the battery structure. As the performance of ^ aluminum "q female water, it can be 蛊+, the gas permeability is extremely low, (ii) the internal electrolytic characteristics are excellent, and there is no internal after the time; the off = resistance" (1 press forming, forming...: now = 7: After the isomorphism, the inner film does not crack. · S H(7) .^ When the cell is made, the lead and the aluminum in the sound are not turned on' (vi) heat resistance even in the case of u.乜 有 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 暂时 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Two adhesives, the first product of the "knowing k / also sealing film; 'characterized by: the sealing film is composed of α-ene layer 0 / , JS Lima 2~1 〇 / / 丙 肖 α α α olefin The random copolymer consists of 'containing ~25, pm... or oleoamine with: 250〇ppm of ethyl acenaphthylamine, a kind of long-term battery 55 B9 1 material (patent document 2), which has a layer of external wear and pirate, a blush film/adhesive layer / 201222930 A laminate for treating an aluminum pig/primer layer/sealing film, characterized in that the sealing film is a random copolymer of propylene and a heart olefin having an α-olefin content of 2 to 1% by weight, and 2 to 4 Å. The blend of any one or more of the weight % of the elastomer or the polybutene is contained in an amount of 5% by weight or less, and is put into practical use. In addition, the electronic component packaging bag is a packaging bag which is protected from the damage of static electricity or the influence of humidity, and when the electronic component is housed inside the bag, the edge of the electronic component is strongly touched, and the electronic component is packaged in a bag. When the parts are transferred, the electronic components or the external projections are likely to be broken, and in order to improve the puncture resistance, there is a laminated film for electronic component packaging (Patent Document 3), etc., which is provided with a metal foil. A laminated film in which a thermoplastic resin layer (A) is laminated on the side and a thermoplastic resin layer (B) is laminated on the other side, and the metal foil and the thermoplastic resin layer are laminated by extrusion lamination, and a thermoplastic resin layer is used ( The tensile strength of A) is Sa, the elongation at break is Ea, the tensile strength of thermoplastic resin layer (b) is Sb, and the elongation at break is Eb, the thermoplastic resin layer (A) And the thermoplastic resin layer (B) has a tensile strength ratio of

Sa/Sb=l/2 to 1/2〇, the ratio of elongation is Ea/Eb = 1/0 8 to 1/〇〇1 in the thermoplastic resin layer (A) and the thermoplastic resin layer (B) At least one of the layers is laminated on the surface opposite to the metal foil, and this is used as a laminate for a secondary battery container. [PRIOR ART DOCUMENT] [Patent Document 1] JP-A-2003-288866 [Patent Document 3] JP-A-2003-288866 [Patent Document 3] JP-A-7-76375 The problem to be solved] When using the laminated material for secondary battery containers in electric vehicles, hybrid vehicles, electric vehicles, and the like, the turtles in the outer laminated materials are generated due to the vibration of the road in the road. Cracking, or cracking from the inside of the exterior laminated material due to the vibration of the internal battery, and it is transmitted to the outside." The outer laminated material may be broken, and electrolyte leakage may occur, or the electrolyte may not fly. Due to the impact at the time of collision, the power generation elements in the inside destroy the exterior material and fly out to the outside. An object of the present invention is to provide a laminate for a secondary battery container in which a crack occurs in an outer layered material and does not break even when moving through a road. The use of the glutinous rice is also as thin as possible, and the burden of the abandoned temple is reduced. In addition, it is possible to provide a laminate for a secondary battery container and a large container for a large-sized container provided with a deep-drawn portion for enclosing a power-generating element, even when an automobile or the like is impacted by a balance. . [Means for Solving the Problems] In order to solve the above problems, the inventors of the present invention have devoted themselves to reviewing, and it has been found that a layered material is laminated with poly(p-xylylene carbonate) and poly(naphthalene). Ethylene formate, _ _ ^ ♦ 礼® or a film made of para-aromatic polyfluorene (A) 'Nylon 6 film f only, upper... . ^ a enamel film (β), aluminum foil (C ), a laminate of polypropylene film (D) characterized by: a俜-red

The film has a matching film on the upper axis, and the D-line has no alignment film. There is a gap between C and D.

θ 文 文 聚烯烃 polyolefin layer, and the Young's modulus of D is 500 MPa or less, can be used as Λ β 2 a ^ ^ J to make vibration resistance better than the previous one < Battery laminate, finally completed the present invention . 201222930 olefin-based grafting The modified polygraft-modified polypropylene of the modified polyfluorene hydrocarbon layer between C and D is preferably introduced into a functional branch-modified polypropylene via a grafting reaction. In addition, the film (A) formed of polyethylene terephthalate, polyethylene naphthalate or polylactic acid has a high breaking strength of Yanma 1 500 to 250 MPa and an elongation at break of 1 〇〇. ~150%, it can be used as a laminate for secondary batteries that is superior to the past. Further, if the breaking strength of polyethylene terephthalate or polynaphthalene 6 is Λ2, the ratio can be made to be smaller than that of the para-type aromatic polyamine. The film (A) has an elongation at break of from 250 to 480 MPa of 80 to 170%, and is preferably a laminate for a secondary battery which is excellent in vibration resistance and a thickness of a rabbit which is used for thinness. Further, if the degree of aggregation is 100 to the vibration resistance and the laminated material, the film (A) formed by the ethylene terephthalate is preferably 25 MPa, and the elongation at break is 170% or more. A large-sized two-person pool composite material which is superior in impact to the prior art. The present invention is a primary battery container formed by the above-described secondary battery. [Effects of the Invention] According to the present invention, the present invention is not limited to the following: even if it is mounted on an electric car, a hybrid car, or an electric self-wheeled vehicle, it is not the following: The vibration in the middle, the cracking and cracking of the slab in the outer layer is produced. ^ ϋ 201222930 In addition, if the film (A) formed by poly(p-butylene dicarboxylate), polyethylene naphthalate or para-type aromatic polyamine has a breaking strength of 25 〇 to 480 MPa, The elongation at break is 8〇~17〇%, and the thickness of the used foil can be further reduced. In addition, when the film (A) made of polyethylene terephthalate has a breaking strength of 100 to 250 MPa and an elongation at break of 170% or more, it is excellent in vibration resistance and impact resistance. In the case of a large-sized secondary battery laminate, the impact at the time of impact does not cause the outer laminate to be broken, or the internal power generation element to fly out. It is applicable to a large container provided with a deep drawing portion for enclosing a power generating element. [Embodiment] [Embodiment of the Invention] Hereinafter, the present invention will be described in detail. _ In the present invention, a film (A) (hereinafter also referred to as A) formed of polyethylene terephthalate, polyethylene naphthalate, polylactic acid or para-aramid. ' is a film of molecularly oriented polyethylene terephthalate polymerized by ester bond with stearic acid and ethylene glycol as the main component, with 2,6-naphthalene dicarboxylic acid and A film of a polyethylene naphthalate polymerized by an ester bond as a main component of ethylene glycol, a film which is molecularly aligned by extension, a polylactic acid polymerized by a lactic acid via a cold bond, and a molecular alignment of 4 films by biaxial stretching 'When a terephthalic acid derivative and an aromatic polyamine which is bonded to a p-phenylenediamine derivative via a guanamine group are formed into a film by a solution, a known one can be used. As an aromatic polyamine, poly(p-xylylene terephthalamide) obtained by solution polymerization of p-phenylenediamine and p-benzoquinone gas, equivalent to 9〇201222930 mol% of 2-chloro-p-benzene Diamine 'equivalent to 10 mol% of 4,4'-diaminodiphenyl ether, equivalent to 100 mol% of 2-chloroterephthalene gas obtained by solution polymerization of poly-2- gas pair Phenyl 4,4'-diaminodiphenyl ether 2- gas terephthalamide, polybenzamide, poly(phenylene phthalamide), and the like. A part of the hydrogen atom on the aromatic ring may be substituted with a substituent such as a halogen (especially gas), a nitro group, a carbon group having 1 to 3 carbon atoms (especially methyl group), and an alkoxy group having 1 to 3 carbon atoms. The hydrogen in the guanamine bond constituting the polymer may also be substituted by other substituents. Specifically, in the N-decylpyrrolidone (hereinafter referred to as NMP), the 2-di-p-phenylenediamine as an aromatic diamine component relative to 80 mol% and the equivalent of 20 mol% are 4 4'-Diaminodiphenyl group was dissolved, and a polymerization equivalent to stupid dioxane was added thereto, and this was neutralized with lithium hydroxide to obtain an aromatic polyamine solution. The polymer solution is passed through a filter, and then passed through a nozzle having a pair of lips forming a slit gap, cast on a belt, heated by hot air to evaporate the solvent, and the film which is self-retaining is continuously peeled off from the belt. Adhered to the water/NMp in a plurality of water tanks of different ratios of ιη, 2/ι, 5/ι/, and sequentially introduced into the film, and carried out the process of extracting, hj and inorganic salts, and using a tenter to carry out moisture. Heat treatment, while 忐A — / ••', eucalyptus polyamide film. During this period, I chose 280 in the direction of the film. . Dry-welding is carried out in a 1.2-fold, 1.3-fold extension to the knife. After treatment, 'slow cooling, etc., to obtain para-naphthoquinone it zt 'If not using polyethylene terephthalate, poly film (4), then, poly, acid or para-aromatic polyfluorene The L made of amine and the nylon 6 film of 凌绍箔 (C) f ώ ώ 外部 外部 外部 外部 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 , , , , , , , , , , , , , , , , , This is not good. 201222930 From the viewpoint of coexistence of moldability of a battery container and vibration resistance of a battery container, the film formed of polyethylene terephthalate, polyethylene naphthalate or polylactic acid (A) The breaking strength is preferably 150 to 250 MPa, the elongation at break is preferably from 1 to 15%, the breaking strength is more preferably from 160 to 240 MPa, and the elongation at break is more preferably from 11 to 13%. When the breaking strength A is 15 MPa or more, the force at the time of vibration from the outside of the battery is less likely to be deformed by the outer casing, and it is less likely to be cracked and is not easily broken. If the breaking strength is 25 or less, the processing characteristics when forming the battery container are obtained. (Deep drawing property) is good, so the breaking strength is better as ^ 5 〇 ~ 250 MPa. When the elongation is 100% or more, the processing characteristics (deep drawing property) when forming the battery container are good, and if the elongation at break is 15% or less, the vibration force in the battery is less likely to cause cracking in the exterior. It is not easy to be broken, so the elongation at break is preferably 100 to 150%. If the thickness of the 'A is greater than 5_#, the outer layer is not easily broken when the battery container is being formed. _Thin, then add and 'clothing' is good, so the thickness of the crucible is more preferably 5~3 0 μιη. In order to reduce the thickness of the battery container as much as possible, the environmental load at the time of disposal, the above-mentioned polyethylene terephthalate brewing, (Α) breaking VS: cool or para-aromatic The film formed by polyamine has a tensile elongation of ~48 ° MPa, more ... 7 ° ~ 48 〇 MPa range, ~: 7 °%, more preferably 80 to 13. %. If it is easy to open the hole, it is better to have a Q-deformation': it is easy to break. Even if it is pinned, it is not all. , 17 makes the aluminum foil (C) thin, can also keep the battery container -10- 201222930 when: S: strong woven 250MPa 'because of the vibration from the outside of the battery - and the valley is easy to deform 'easy to crack, easy to break without ^ If the thickness of the ^(10) is lower than the m, it is not easy to maintain. If the breaking strength is higher than 48 〇Mpa, or sex (deep drawing property; the processing when forming the battery container is special... If the elongation at break is higher than the violent, the force of the battery inside the internal vibration of the genus, the exterior It is not suitable for elongation and rupture. The 呷仗 呷仗 夺 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易 易If the protective function is thinner than 3〇_, the processing characteristics (deep pull) are good, so the thickness of the crucible is preferably 4.5~3〇μηι. In order to produce a sub-battery that is superior to vibration and impact resistance. With the laminate material, the rupture strength of the ruthenium film (polyethylene terephthalate) of the foregoing polyethylene terephthalate is 100 to 250 MPa, more preferably 150 to 95: the elongation at break of the Paj is 17.5% or more, more preferably 190. % or more. If the right side is made of a large container having a deep-drawn type, it is not easily deformed for external force. It is not easy to be broken even if it is pinned. The power generation within it is not to "destroy the exterior materials, not to fly out to the outside, but also to thicken The film (8) is processed into a battery container. If the breaking strength is less than 10 MPa, the force from the vibration of the battery 1 for a long time is easily deformed, and cracks are likely to occur, which easily breaks I. In the collision of automobiles, etc., the internal power generation components are likely to break the outer material's flying out to the outside. If the breaking strength is higher than 250MPa -11 - 201222930, or the elongation at break is less than m%, (4) Deep pullability) is not suitable. It is better to add the shape of the 'A', the thicker the thickness of A, and the internal vibration of the car when it collides:: The shape is more stable', as if A is a brigade. It is preferable to go out to the outside. Even if the thickness of the crucible is less than 20Μηι, the internal power generating element is likely to fly out to the outside when the car is rushed & In the present invention, the 'nylon 6 film (Β) (hereinafter, only the well-known nylon 6 without alignment = the vibration of the film: β: : Γ: film) is weak, due to vibration from the outside of the battery. Force, the exterior is easy to break and not suitable. Nylon 6 film ( Thickness; 1Λ ρ , Λ .川,予度右1〇_厚, then Α easily rupture right than 30μιη溥', the processing characteristics are better 10~30_....sheng (ice pull) is good, so Β The thickness of the box (C) (hereinafter also referred to as (4) c) can be used in the well-known heart, and the ingredients can also be used in the well-known pure and well-known. In the above, the above-mentioned polyethylene terephthalate, poly The film (4) of naphthalene dicarboxylate = lactic acid has a breaking strength of 15 〇 25 and 25 〇 when the elongation is (10) 〜 15 G%, and if the thickness of C is 15 _ or more, the battery is easily inside the container. The vibration is generated, and the force at the time of vibration outside the container is preferably deformed or cracked. 'If the above-mentioned film (A) made of polyethylene terephthalate, polyethylene naphthalate or para-type aromatic polyamine has a breaking strength of 25 0 to 480 MPa, the elongation at break η* 〇λλ The length of the spring is 80~170%, even if the thickness of the aluminum (C) is reduced to 10μιη, it is not easy to be in the box. -12- Shao, (JIS) 3003, 3004, Preferably, the relationship between at least one of the constituent bismuth foils is 2. 0, iron or ruthenium; prevention of pinholes or cracks 0 and light materials> Further, a non-aligned film and a Young's polypropylene film which are washed in the present invention are applied as needed or in an organic solvent or the like. The vibration of the battery of 201222930, and the force or crack of the vibration outside the container, can maintain the shape of the battery container, so the thickness is better on the other 0, if the above-mentioned breaking strength of polyethylene terephthalate) When the thickness of the aluminum foil (c) is 10 μm or more, the vibration of the battery inside the aluminum foil and the deformation or cracking of the vibration outside the container can maintain the battery container. Form, so the thickness is above. The upper limit of the thickness is not specified, and the point from the cost is 8 〇 μηη or less. The purity of the system is particularly limited. It can be used in the range of 1.0% or more of 5052, 8021, 8079, etc., and the upper limit is not particularly limited by weight. Any one of the hardening materials which are effective for improving the laminated material may be used, and it may preferably be water, washed or the like in advance in terms of desired properties, adhesion, and the like. The propylene film (D) (hereinafter, only when the modulus is 500 MPa or less and the film is deformed to ΙΟμηι to change the film (Α) 17% or more is less likely to be caused by the container force, and preferably 1 〇μm is preferable. For the industrial use of pure alloys, such as iron, Shi Xizhong, but in the production of 1. 〇% by weight I (rigid), annealed material, rolling characteristics are preferably annealed * agent, acid, alkali called D The system can make the well-known 13-201222930 and the distribution of the collateral through heat sealing, D έ below. The vibration on the side of the system is easy to vibrate, and (C) ’ D and C are used to make the battery susceptible to leakage of the polypropylene film 10 Ο μπι. In the present modified polyolefin, the copolymerization of the functionalized ethylene 'polypropionic acid anhydride group, the binding of the official acrylic acid, the acetate, and the like, in particular, the official, in the composition of the unsaturated two: compared to The alignment film has a low heat sealing temperature and is easy to use, and the two-person battery is preferably a grain device. This is because the entanglement of polypropylene molecules is easy to progress in the absence of (iv) L sealing. The number of pulls should be less than 4 5 GGMPa, more preferably 45 〇., ', and if the Young's modulus is higher than 5 〇〇 MPa, the battery from the outside of the battery is easily conveyed to the inside of the container, the battery capacity, the inside of the burglary The force of the battery vibration is easily conveyed to the aluminum foil C and B is easily peeled off. If the thickness is 25 (four) or more, the sealing strength of the formed state is improved, and the seal is not easily peeled off. If the thickness is 10 〇μΓη or less, the thickness of the non-alignment system can be easily obtained in the market, so More preferably, the thickness is 25 to 5, and a layer is provided between the aluminum case (C) and the polypropylene film (D). A modified polyolefin (hereinafter also referred to as a modified P〇) is a polyolefin of a component, and as a modified polyolefin, an amine group, a carboxyl group, a hydroxyl group, and a horse base are introduced into a polyolefin such as a polyolefin. For the acryl-based, acrylate-based, and the like, the olefin of ethylene, propylene, etc. of the main monomer is polymerized with the acid ethylene, the glycidyl methacrylate, and the acrylic acid monomer. The olefin copolymer obtained is well known. Graft-modified polypropylene which is capable of graft-bonding is preferred. All or part of the polypropylene of the main skeleton is a graft copolymer obtained by grafting a copolymerized acid or an anhydride thereof. The homopolymer ' or propylene of the block dipyridamole formed by the polyacrylic monomer constituting the modified polypropylene-14-201222930 main skeleton may be, for example, a B/: or a random copolymer. As other monomers 'butene, 3-mercapto-fluorene-butene, butene, isobutylene, pentene, 2-methyl-1·1 Λ抡, 1 κκ, hexene, 3-mercapto 1-pentene, 2-methyl-1-pentene-heptene, etc., 1 # ^ , ^ έΒ λ This specialty can contain 1 or 2 other monomers in polypropylene. The content is usually 10% or less. From the viewpoint of cost, propylene homopolymer, ethylene propylene block, ν, 1, and ethylene propylene random copolymer are preferred. In order to form the modified polypropylene, the unsaturated acid or the liver (hereinafter referred to as "graft monomer") which is graft-polymerized with polypropylene may, for example, be propylene-based or propyl-based propylene. Unsaturated monosinetic acid, maleic acid, fukic acid Ikon S sulphonic acid, allyl succinic acid, mesaconic acid, glutaconic acid, nadic acid, methyl nadic acid , unsaturated dicarboxylic acid such as tetrahydrophthalic acid or mercaptotetrahydrophthalic acid, maleic anhydride, itaconic anhydride, citraconic anhydride, allyl succinic anhydride, glutaconic anhydride, Nadick An unsaturated dicarboxylic anhydride such as an acid anhydride, a quinone dicetic acid anhydride, a tetrahydro phthalic anhydride, or a methyltetrahydro benzene = a formal anhydride. The modified polypropylene may also contain such graft monomers in a single or a combination of two or more. Among these, maleic acid, maleic anhydride, nadic acid, and nadic anhydride are preferred from the viewpoint of cost and physical properties. The content of the graft monomer in the modified polypropylene is 〇1 to 1% by weight from the viewpoint of obtaining an adhesive composition excellent in adhesion to aluminum and adhesion to a polypropylene film. It is preferably 0.5 to 5% by weight. The modified polyolefin is easily combined with the aluminum foil (c) and the polypropylene film to reduce the ease of peeling of D and C due to vibration during running of an automobile or the like by modifying the polyolefin layer. -15- 201222930 If the thickness of the modified polyolefin layer is peeling 'if the thickness is less than 50μηι, the modified polyolefin layer can be set in C and polyolefin by coating and lamination method. The resulting film can be provided by a thermal lamination method with D. The secondary battery containers of the present invention are sequentially laminated. Since D is in the accumulation, it has a layer in which D and D are superposed. In order to prevent the impact of the aluminum foil C as much as possible, and in order to prevent the outer side from being the outermost layer, the external force is accumulated on the C, and the crucible must be placed on the outermost layer. Then, B wears out with external friction, and A/C/D/B or the like is not absorbed by the aluminum foil from the outermost layer to convey 'C-cracking. If C is laminated on the outermost layer, deformation, wear, and damage are not suitable. The production of the laminate of the present invention is carried out by the following method. When the naphthalene diacetate, polylactic acid or 1 〇μΐη or more is adhered by the dry laminate method, c and D are not easy, and the vibration is less likely to make the thickness of the modified polyolefin more preferably from 1 μm to 5 μμηη. Change the t-ene olefin resin by pressing between D. Further, it is also possible to use a function of sealing which is formed by laminating C and a modified polyolefin film laminate material in accordance with the A/B/C/D layer material as a battery container, and therefore it is necessary to be the innermost from the bag. Oxygen oxidation of the external vibrational force must be as much as possible on D. In order to protect C from being worn in order to prevent B from rubbing against the outside, it becomes B/A/C/D, B/C/A/D, and the battery container is easily broken. If it is two laminated layers C, the external vibration is easily cracked, and the battery container is easily broken. Due to the force from the outside, the C method is not particularly limited. It can be made of polyethylene terephthalate or poly-para-type. 16* 201222930 film (A), nylon 6 film (B) and aluminum foil (anthracene.) As a binder, a usual two-component type of a polyol-based main component and an isocyanate-based hardener can be used. The body type includes a two-liquid type of a trioxane-based main agent/Takenate (isocyanate-based curing agent) manufactured by Mitsui Chemicals Polyurethane Co., Ltd. And j can also be adhered by pressing and coating. As the extrusion and coating, a variety of polyethylenes, polyolefin resins, polyamines, polyesters, 1, polymethylpentene, acid-modified resins, and the like are used. As a specific example of the acid-modified resin, "--, etc., manufactured by Mitsubishi Chemical Corporation can be used. As the polyester resin, polyethylene terephthalate is preferred. (4) The film (9) and the polypropylene film (9) can be used. The above modified poly-dilution::: melted layer is used as the interlayer between D and D, and the film is laminated on the thin layer formed by ... η modified poly-baked hydrocarbon. Pressurization, by means of thermal layering, can bond A and B to become a/r. It becomes the A/B/C laminate: a wide-layer laminate, where B#l adheres to Na (10) laminate. Alternatively, (4) D can be layered to obtain a 4+ , ^ . , and adhere to 6 to form A/B laminate, and C: and D are laminated. AX laminate, 佶A/R laminate and C/D Laminated material with B and A/B product

Laminates. σ 而 黏 , 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造 制造D) The inner side is overlapped, and the eight sides are heat-sealed and melted to make, and see, the laminated material 'to make the polypropylene film d. In addition, it is also possible to cut out - "The two sides of the side are heat-sealed and melted to the inside so that one end is bent and melted to make a bag. -17- 201222930 The secondary battery container can be laminated by the present invention. Two pieces of laminated material are cut out from the material to form a mixture of polyethylene terephthalate, polynaphthalene, polylactic acid or para-aramid, & The film (A) is formed on the outer side, and one piece of the laminated material is deeply drawn into a belt by a mold, < a formed material for a deep-drawn portion for enclosing the power generating element is placed and the other piece = laminated material is ablated in polypropylene (D) On the side, the „ ... ... T is called 'sticky' to make a profit 0. [Embodiment] Hereinafter, the present invention will be described in detail by way of examples, but the invention is not subject to this purpose. The example is limited. "Furthermore, the value of the burial value of each characteristic value is measured by the following method. (1) Tensile strength, elongation at break, and Young's modulus are measured using a tensile tester (Tensilon) at a rate of 300 mm / / knife ring, width l 〇 mm, sample length 50 inrn a The length of the film = direction; the width direction, in the environment of ^, 65% RH, according to ^ 7 127 (1999), the breaking strength, "elongation, Young's 杈 value. The direction, the width of the column & the knife to each of the breaking strength, the cleavage elongation, the Young's modulus, each measured 5 4 D 夂, the average value was obtained, and the average of the length direction and the width direction were averaged again - (2) Film thickness # Using an electronic micrometer (ANRITSU shares right, "P 1 Herb Co., Ltd., trade name K-3 12A"), the barrier J was measured at a needle pressure of 3 〇g, and the thickness of the pancreas was found. , Aluminum foil) Dry I 0 (3) Thickness of modified polyolefin layer between C and D -18- 201222930 A small piece of A/B/C/D laminate (2mm x 2mm) is embedded in epoxy resin (1) FINETEC ( In the product name "Ep〇m_t" manufactured by the company, the embedded resin is cut into a thickness of 5 〇 nm by using a sliced branch. A microscope ("EcHpse" manufactured by NIKON Instruments Co., Ltd.) was observed at a magnification of 500 times. (4) Formability was deep drawn by a mold in such a manner that the polyester film (A) was outside. The laminated material of the present invention is molded. The size of the molding is 30 mm x 50 mm (the shape of the concave portion of the mold), and the deep drawing depth at the time of forming is from 3 mm per deep. The deep drawing depth of the laminated material is not broken. For evaluation, the maximum deep drawing depth is 5 mm or more, and the practical range is less than 5 mm. (5) Vibration resistance-1 Two pieces of 2〇Cmxl5cm laminated material are cut out from the laminated material of the present invention. The sheet was superimposed on the inside of the polypropylene film (D), and the three sides were sealed and melted to form a bag, and 1 〇〇g of the following test solution was placed in the ^中^, and placed as a battery constituting body.媪 丨 丨, Dan take the body of the aluminum plate (3_ thickness

After Xl5Cmxl〇Cm), the bag mouth is heat sealed and sealed. The 5 type test system is used in the case of carbonic acid # 7 _ 驮 驮 驮 s / 奴 奴 奴 奴 / / / / / / / / / / / / / ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Using this heat-sealed sample, it is fixed in a vibrating test machine ("BF-50UD" manufactured by IDEX Co., Ltd.), in the Xuan, σ ^chewei 'in / dish, amplitude 0.75mm ( In the longitudinal direction, as follows: ° = _, this was taken as one cycle, and after 8 hours, the damage of the heat-sealed sample was visually observed and evaluated by the following criteria. 状心措-19- 201222930 〇: No cracks or leaks were observed Change in liquid △: Although there is no visible crack or rupture in the bag, the tip slightly sees leakage. X is clearly visible in the scorpion, and leakage occurs from there. xx: The bag is broken, the liquid (6) Vibration resistance _ 2 From the 穑 screen u + τ1 mountain of the present invention, ^, and the coffin knives, 2 pieces of 20cm x 15cm laminated material 攸 1 piece of laminated material 'will be sealed 10cm x 5cm, depth 5mm 'deep-drawn part for electric elements' is a way to make the poly (tetra) film (A) outer: using a long side, a short side 5cm, an angle 2匪, a die shoulder ri 2_ a die shoulder 0.5mm 'Pressure pressure of pressurizing pressure 71^_2': a container shape having a soil forming depth of 5 mm, in which 20 g of the test liquid is placed in the container portion, and an aluminum plate (a) having a thickness of f jcm x Scm as a battery body simulation body is placed. One of the non-formed laminates was superposed such that the polypropylene film (D) was inside, and the crucible was heat-sealed and melted to form a container. The test solution was used in which lithium hexafluorophosphate (concentration: 15 N) was added to ethyl carbonate/ethyl carbonate-ethyl phthalate = 丨 / i (rear ratio). Use this heat seal sample and fix it on the vibration tester (IDEX Co., Ltd. BF_5〇UD), at room temperature, amplitude 〇 (longitudinal), and = 10Hz - 55Hz -> i〇Hz This was taken as a cycle, and after 8 b, the state of rupture and liquid leakage of the heat-sealed sample was visually observed, and the practical ranges of '〇, 〇~△ and △ were evaluated by the following criteria, and the practical range of X and XX systems was evaluated. 〇. No change in rupture or leakage. -20- 201222930 〇~△. Although there is no liquid leakage in the container, the crack is slightly seen. △: Although there is no visible crack or crack in the bag, However, the liquid leakage was slightly observed. X·The crack was clearly seen in the bag, and the liquid leakage occurred from the talk. XX. The bag broke and most of the liquid leaked. (7) Vibration resistance-3 Cut from the laminated material of the present invention Two sheets of laminated sheets of 2〇cmxl5cm are produced, and a deep-drawn part for a power-generating element of 15cm×l〇cm and depth is sealed from one laminated material, and the polyester film (A) is used as the outer side. Pressing 15cm, short side i〇cm, angle 2mm, die shoulder R1 2 rhyme, die shoulder 0.5mm, pressurizing A pressure of 8 kg/cm 2 was applied to form a container having a molding depth of 10 mm, and 12 μg of the following test liquid was placed in the container portion, and an aluminum plate (3 mm thickness x 12 cm×8 cm) as a battery body simulation body was placed, and the other side was placed. The non-formed laminated material is formed by heat-sealing and melt-bonding the polypropylene film (D) so as to be inside. The test liquid is used in ethyl carbonate/ethyl carbonate-ethyl ester = 1 Μ (Liu Libi) is added with lithium hexafluorophosphate (concentration ^"m〇1/L). Using this heat seal sample, fix the U疋 to the vibration tester ("BF-50UD" made by IDEX Co., Ltd.), and scan it at 10 Hz in 60 seconds for the officer, the field to the / dish, the amplitude 〇.75mm (longitudinal). 55Hz->irm c, 士 ☆ Hz 'This is taken as one cycle, and after 8 hours, the 埶^^ sample is visually observed. The state of rupture and liquid leakage of 0 is evaluated by the following criteria, 〇'n~ v v ^ ^ m 〇 Λ and △ are practical ranges, and X and X X are used outside the circle. 〇: No changes in rupture or leakage were observed. -21 - 201222930 〇~△: Although there is no liquid leakage in the container, 佴 slightly sees cracks. △. Although there was no visible crack or crack in the bag, a slight leak was observed. X: The crack is clearly seen in the bag, and leakage occurs from the place where X X · bag ruptures. (8) Time-impact property The test liquid prepared in the above (7) was sealed in a container, and the surface formed by the long side and the short side was set to the lower side, and the test piece on the marble was repeatedly dropped from the height of 5 meters. (equivalent to a collision of 35km per hour). After the repeated dropping, the state of the container was observed by rupture and liquid leakage was evaluated by the following criteria: 〇, Q △ △ and △ are practical ranges, and X and XX are outside the practical range. 〇: No changes in rupture or leakage were observed. 〇 △ Although there is no liquid leakage in the grain, the crack is slightly seen. △: The turtle was slightly seen in the container, and a slight leak was observed. X: Cracks are clearly seen in the container, and leakage occurs from there. XX: The container ruptured' most of the liquid did not leak. [Example 1] By the dry layer method, _ A was left. ^ ,, for a twist of 12μ1Ώ, a breaking strength of 240MPa, a fracture length of 118%, a biaxial alignment poly(p-phenylene film) (4) (Dongli Co., Ltd. 胄A-", thick and thick 15μιη, 断商') Ρ 60) An unaligned nylon ruthenium film with a strength of l〇3MPa and elongation at break ^ Λ degree of 3 98 /0 犋 (Β) (Dongli 溥 film processing shares

"Rayfan" (registered trademark) Ν〇 14〇 "Takel... well chemical polyamine iU (Urban alcohol base agent-22- 201222930) / Takenate A-3 (isocyanate) A hardening agent)" two-liquid type (1 〇〇 weight injury / 10 parts by weight) adhesive, made of A / B laminated material. Here, the adhesive application was carried out at a temperature of 5 g / m 2 on the A side, and after a / b bonding, the aging treatment was carried out at 40 ° C for 72 hours. Laminated A/B laminated material, aluminum with a thickness of 4〇μπ1 by dry laminate method

Ά (C) (“ e espa '' 8 〇 2 1), β and C 'Takelac A-910 (polyol) manufactured by Mitsui Chemicals Polyurethane Co., Ltd. Main agent),, / "Takenate A_3 (isocyanate hardening)

d ) - Liquid type (1 〇 0 parts by weight / 10 parts by weight) of adhesive to form a / B / C laminate. Here, the amount of the adhesive applied is 6 g/m on the B side as a solid content, and after bonding at B/c, the curing treatment at 45 ° C for 8 hours is carried out on the A/B/C laminate. A non-aligned polypropylene film (D) having a thickness of 7 〇 μιη with a breaking strength of 35 MPa, an elongation at break of 655%, and a Young's modulus of 415 MPa (made by Toyobo Co., Ltd. 邛丫 161^1„1-〇: ?1146,,) is extruded at a thickness of 14 (the melting temperature of rc is ι〇μηη, using modified polyolefin (manufactured by Mitsui Chemicals, Inc., Β-based graft modified polypropylene "Ad〇mer qE84〇" The interlayer between c and D was laminated to form an A/B/c/D laminate of the invention. The characteristics are shown in Table 1. [Example 2] In addition to the second embodiment, instead of the two axes Oriented polyethylene terephthalate film (A) 'Using a thickness of 15|im, a breaking strength of i6〇Mpa, and an elongation at break of 128%, a biaxial alignment polylactic acid film (Terramac, manufactured by UNmKA Co., Ltd.) In the same manner as in Example 1, except that TF), an A/B/C/D laminate was produced. The characteristics are shown in Table i. -23- 201222930 [Example 3] In Example 1, as a biaxially oriented polyethylene terephthalate film (A) 'Using a thickness of 25 μηι, a breaking strength of 225 MPa, and an elongation at break of 150%, the biaxially aligned polyparaphenylene An A/B/C/D laminate was produced in the same manner as in Example 1 except that the ethylene phthalate film ("Emb1" manufactured by U NITIK A Co., Ltd.) was used. The characteristics are shown in Table 1. Example 4] In addition to Example 2, as a biaxially oriented polyethylene terephthalate film (A), a biaxial alignment pairing having a thickness of 38 μm, a breaking strength of 216 MPa, and an elongation at break of 110% was used. An A/B/C/D laminate was produced in the same manner as in Example 1 except that the ethylene phthalate film ("Esterfilm E5 100" manufactured by Toyobo Co., Ltd.) was used. The characteristics are shown in Table 1. Example 5] In addition to the biaxially oriented polyethylene terephthalate film (A), a biaxially oriented polylactic acid having a thickness of 35 μm, a breaking strength of 150 MPa, and an elongation at break of 120% was used in addition to Example 1. Thin film ("Terramac TF" made by UNITIKA Co., Ltd.) In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 6] In addition to Example 1, a biaxially oriented polyethylene terephthalate film was used ( A) A biaxially-oriented polyethylene terephthalate film having a thickness of 6.5 μm, a breaking strength of 275 MPa, and an elongation at break of 181% ("Lumirr〇r" manufactured by Toray Film Processing Co., Ltd. (registered) In the same manner as in Example 1, except for the trademark P375), an A/B/C/D laminate was produced. The characteristics are shown in Table 1. -24-201222930 [Example 7] Except that in Example 1, as the biaxially-oriented poly(p-terphenylene phthalate), the film (A)' had a thickness of 4·5 μη1, a breaking strength of 27 μMpa, and an elongation at break. i 06% of the biaxially-oriented polyethylene terephthalate film (rLumirr〇r (registered trademark) 东) manufactured by Toray Industries, Inc., in the same manner as in Example i, A/B/c/D Under the laminated timber. The characteristics are shown in Table 1. [Example 8] In addition to Example 1, as the polypropylene film (D), a thick product of 40 μm, a breaking strength of 33 MPa, a tensile elongation and a length of 570%, and a Young's modulus of 380 were used.无 P a non-aligned polypropylene film (Table 迷 && 土 犋 犋 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( C/D laminate. The characteristics are shown in Table 1. [Example 9] Except for Example 1, as the polypropylene film (9), the thickness Η) was used, the breaking strength was 37 MPa, and the elongation at break was 73%. Yang: A non-aligned polypropylene (tetra) film having a modulus of 5 GG MPa ("Pylenfilm-CT P 1 1 47" manufactured by Toyobo Co., Ltd.), -; outside the same as in the first embodiment, A/B/C/ was prepared. D laminated material. The characteristics are shown in Table i. [Example 10] Except that in Example 1, 'as a polypropylene film (9), a non-orthogonal polyglybdenum 8 〇μΙη, a breaking strength A 37 MPa, an elongation at break of 73 ()%, and a yang = modulus of 50 Å were used. An A/B/C/D laminate was produced in the same manner as in Example i except that the propylene film ("Pyunfum-CTP1147" manufactured by Toyobo Co., Ltd.) was used. The characteristics are shown in Table i. -25-201222930 [Example 11] Except that in Example 1, as the polypropylene film (D), a thickness of 25 μm, a splitting strength of 40 MPa, an elongation at break of 480%, and a Young's modulus of 500 MPa were used. An A/B/C/D laminate was produced in the same manner as in Example i except for the alignment of a polypropylene film ("Pylenfilm_CT P1181" manufactured by Toyobo Co., Ltd.). The characteristics are shown in Table 1. [Example 12] An A/B/c/D laminate was produced in the same manner as in Example 1 except that the thickness of the interlayer of the modified polyolefin was 30 μm. The characteristics are shown in Table 1. [Example 13] In addition to the modified example 1, the modified polyene was replaced by an adhesive polyethylene (functional graft-modified polyethylene) "Adomer NE827" manufactured by Mitsui Chemicals Co., Ltd., and the interlayer thickness was A/B/C/D laminates were prepared in the same manner as in the case of 30 μτη. The characteristics are shown in Table 1. [Example 14] In the same manner as in Example 1, the modified polyolefin was replaced with an ethylene/vinyl acetate copolymer "Evaflex EV550" manufactured by Mitsui & Co., Ltd., and the thickness of the interlayer was 40 μm. A/B/C/D laminate. The characteristics are shown in Table 1. [Example 1 5] In addition to the modified polyolefin, it was replaced with a special vinyl copolymer (ethylene/mercaptoacrylate dimercapto acrylate/decyl acrylate) of Sumitomo Chemical Co., Ltd. in Example 1. /3/27 wt%) "Bondfast 7L", A/B/C/D laminate was produced in the same manner except that the melting temperature was 1 〇 5 °C. The characteristics are shown in Table 1. -26- 201222930 [Example lq soil removed in Example 1 as a modified polyolefin, replaced with Toyotec M10〇, a hot melt adhesive for polyolefins manufactured by Toyobo 1 Becker Co., Ltd., melting temperature is The characteristics of A/B/c/D laminates were similarly shown in Table 1 except for 160 〇c. [Example 17] In addition to the modified polyolefin in Example 1, it was changed to Mitsubishi Chemical Edition. Polypropylene adhesive resin (functionalized graft-modified polypropylene "Modic P553A") manufactured by Injury Co., Ltd., melting temperature: 168t: 'The thickness of the interlayer is 5〇μηΐ, and A/B/C/D layer is formed in the same manner. The properties are shown in Table 1. [Example 1 8 ; | In addition to the modified polyolefin in Example 1, a polypropylene-based adhesive resin manufactured by Mitsubishi Chemical Corporation was used (functional graft modification) Polypropylene "Modic Ρ 553 Α") 'The melting temperature was i68 ° C, and the interlayer thickness was 60 μηι, and the A/B/C/D laminate was similarly produced. The characteristics are shown in Table 1. [Example 1 9] In Example 1, as a modified poly-hydrocarbon, Mitsubishi Chemical Corporation was used. Polypropylene based adhesive resin (functional groups graft-modified polypropylene "ModicP553A '') 'refining melting temperature of i68 ° C, than the thickness of the interlayer 6μιη, creating the same manner as A / B / C / D laminate material. The characteristics are shown in Table 1. [Example 20] -27-201222930 In addition to Example 1, in the modified polyolefin, Mitsubishi Chemical Co., Ltd. was used to make a low-stretch linear polyethylene-adhesive adhesive resin (functional graft-modified polyethylene). "Modic M502"), except for the melting temperature, was similarly formed into an A/B/C/D laminate. The characteristics are shown in Table 1. [Example 2 1] In addition to the second embodiment, in place of the biaxially-aligned polyethylene terephthalate film (A), a thickness of 12 μm, a breaking strength of 31 MPa, and an elongation at break of 85 % were used. An A/B/C/D laminate was produced in the same manner as in Example 1 except that the polyethylene diethylene naphthalate film (Teonex, 'Q5l) manufactured by Teijin DuPont Film Co., Ltd. was used. [Table 2] [Example 2 2] In addition to Example 1, as a biaxially oriented polyethylene terephthalate film (A), a thickness of 12 μm, a breaking strength of 235 MPa, and an elongation at break of 95 were used. A/B/C/D laminate was produced in the same manner as in Example 1 except that a biaxially-oriented polyethylene terephthalate film (Esterfilm E5100, manufactured by Toyobo Co., Ltd.) was used. [Table 2] [Example 2 3] In addition to Example 1, as a biaxially oriented polyethylene terephthalate film (A), a thickness of 16 μm, a breaking strength of 285 MPa, and an elongation at break of 125 were used. % biaxially oriented polyethylene terephthalate film (made by Teijin Silicon Film Co., Ltd. In the same manner as in Example 1, except for Teigin Tetoron Film" G2), an A/B/C/D laminate was produced. The characteristics are shown in Table 1. 28-201222930 [Example 24] In Example 1, as A A two-axis alignment polyester film (A) having a breaking strength of 12 K111 and a breaking elongation of 95% (Esterfilm E7700, manufactured by Toyobo Co., Ltd.) was used. In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 25] In Example 1, a laminate was formed between the A/B/C laminate and d. A modified polypropylene film having a thickness of 30 μm ("Adomerfilm QE-060C" manufactured by TOHCELLO Co., Ltd.) is heated by a thermal lamination method at a stick temperature of 15 °C, a temperature of 30 kg/cm, and a transport speed of 20 m/min. The pressure-sensitive adhesive was used to form an A / B / C / D laminate. The characteristics are shown in Table 1. [Example 26] A was prepared in the same manner as in Example 1 except that the thickness of 'C was changed in Example 1 /B/C/D laminate. The characteristics are shown in Table 1. [Example 27] Except that in Example 1, the thickness of c was 8 〇μηι, In the same manner, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 28] In addition to Example 1, the biaxially oriented polyethylene terephthalate film (4) was used. Using a thickness of 5 〇μπι, a breaking strength of (9), and an elongation at break of 3 6 5 %, the biaxial alignment is _ ^ ^ ^ Gate 1 to find a film of ethylene diacetate (made by Teijin DuPont Film Co., Ltd. In the same manner as in the first embodiment of the actual -29-201222930, an A/B/C/D laminated material was produced in the same manner as in the case of the clothing i etlex FT7"). The characteristics are shown in Table 1. [Example 29] In addition to Example 2, as a biaxially oriented polyethylene terephthalate film (A), a biaxial alignment having a thickness of 14 μm, a breaking strength of 7 〇Mpa, and an elongation at break of 88% was used. A/B/C/D laminate was produced in the same manner as in Example 1 except that a polyethylene terephthalate film (Tearfine TF1 10 manufactured by Toyobo Co., Ltd.) was used. The characteristics are shown in Table 1. [Example 30] A biaxially oriented polyethylene terephthalate film (A) having a thickness of 6·5 μm, a breaking strength of 275 MPa, and an elongation at break of 181 % by dry-laid method (Dongli Co., Ltd.) Co., Ltd. "Lumirr〇r" (registered trademark) p375) and an unaligned nylon 6 film (B) having a thickness of 15 μm, a breaking strength of 1 〇 3 MPa, and an elongation at break ("Rayfan" manufactured by Toray Film Processing Co., Ltd.) (registered trademark) NO 1401), "Takelac A-910 (polyol-based main agent)"' / "Takenate Α·3 (isocyanate-based curing agent), "two liquids" manufactured by Mitsui Chemicals Polyurethane Co., Ltd. Type (9) parts by weight/10 parts by weight) of adhesive to form Α/Β 层 《 《 此处 此处 《 《 《 《 《 《 《 《 《 《 《 《 《 《 《 《 《 此处 《 此处 《 《 此处 《 此处 C C C C C C C C C C C C C C C C , 72 hours of ripening treatment. Mistaken by dry-lamination method 'A/B laminated material, aluminum foil (C) with a thickness of 25μηη (8〇2ι made by Fe Aluminum Foil Co., Ltd.), β and 匸, using Yijing Chemical Polyurethane Co., Ltd. "Takelac 9 〇 (polyol-based main agent), / ''Takenate A-3 (isocyanate-based hardening -30-201222930 agent)" two-liquid type (100 parts by weight / 10 parts by weight) adhesive, made a /b/c Laminate. Here, the amount of the adhesive applied was 6 g/m2' in terms of solid content on the B side, and after bonding at B/C, the aging treatment was carried out at 45 ° C for 80 hours. On the A/B/C laminated material, a non-aligned polypropylene film (D) having a breaking strength of 35 μηι of 35 MPa, a breaking elongation of 655%, and a Young's modulus of 4 i5 MPa (made by Toyobo Co., Ltd.)丫161^11!1-(:丁?1146'') is extruded at a melting temperature of 140 °〇 at a thickness of 1 (^111, using a modified polyolefin (manufactured by Mitsui Chemicals, Inc., functional base) The branched modified polypropylene "Adomer QE84(R)" was laminated on the interlayer 'between C and D' as the A/B/C/D laminate of the invention. The characteristics are shown in Table 1. [Example 3 1 In addition to Example 30, as a biaxially oriented polyethylene terephthalate film (A), a biaxial alignment having a thickness of 4.5 μm, a breaking strength of 271 MPa, and an elongation at break of 106% was used. In the same manner as in Example 30, a polyethylene terephthalate film ("Lumirror" (registered trademark) F53, manufactured by Toray Industries, Inc.) was used, and the thickness of the aluminum foil (C) was 30 μm, and A/B/C/ was produced in the same manner as in Example 30. D. Laminates. Characteristics are shown in Table 1. [Example 32] In addition to Example 30, instead of biaxial alignment of polyterephthalic acid Ethylene diester film (Α), using a biaxially oriented polyethylene naphthalate film having a thickness of 1 2 μηι, a breaking strength of 3 lOMPa, and an elongation at break of 85 % (Teonex, manufactured by Teijin DuPont Film Co., Ltd.) Q5 1) An A/B/C/D laminate was produced in the same manner as in Example 30 except that the thickness of the aluminum foil (C) was 1 μm. The characteristics are shown in Table 1. -31 - 201222930 [Example 3 3 In addition to Example 25, as a biaxially oriented polyethylene terephthalate film (A), a biaxially oriented polyparaphenylene having a thickness of 16 μm, a breaking strength of 285 MPa, and an elongation at break of 125% was used. Ethylene diacetate film (Teigi η T et 〇r ο n F i 1 m '' G 2) made by Teijin DuPont Film Co., Ltd. 'The thickness of the foil (c) is 1 > μηι, In the same manner as in Example 30, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 34] In addition to the biaxial alignment polyethylene terephthalate film in Example 30 (Α), using a para-type aromatic polyamide with a thickness of 4.5 μm, a breaking strength of 480 MPa, and an elongation at break of 80% A/B/C/D laminate was produced in the same manner as in Example 30 except that the film was made of "Mictron" (registered trademark) Gq manufactured by Toray Industries, Inc., and the thickness of the aluminum town was ΙΟμπι. The characteristics are shown in Table 1. [Example 35] Except for Example 30, as the polypropylene film (D), an unoriented polypropylene having a thickness of 40 μm, a breaking strength of 33 MPa, an elongation at break of 57%, and a Young's modulus of 3 80 MPa was used. In the same manner as in Example 3, except for the film (Pylenmm-CTPUM, manufactured by Toyobo Co., Ltd.), an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 36] In addition to Example 30, as the polypropylene film (D), an unoriented polypropylene film having a thickness of 37 MPa'" elongation of 73% by weight and a Young's modulus of 50 GMPa was used (Toyo Textile Co., Ltd. limited) In addition to the company's "Pyienfnm-CTP1147,", the A/B/C/D laminate was produced in the same manner as the implementation of "Life". The characteristics are shown in the table! in. -32-201222930 [Example 37] In addition to Example 30, as the polypropylene film (d), a thickness of 80 μηι, a breaking strength of 37 MPa, an elongation at break of 730%, and a Young's modulus of 500 MPa were used. An A/B/C/D laminate was produced in the same manner as in Example 30 except that the non-aligned polypropylene film (Pylenfilm-CT P1 147 manufactured by Toyobo Co., Ltd.) was used. The characteristics are shown in Table 1. [Example 38] Except for Example 30, as a polypropylene film, a non-alignment having a thickness of 25 μm, a breaking strength of 40 MPa, an elongation at break of 480%, and a Young's modulus of 500 Å P a was used. An A/B/C/D laminate was produced in the same manner as in Example 30 except that a polyacryl film ("P y丨enfi 1 m - CTP 1 1 8 1" manufactured by Toyobo Co., Ltd.) was used. The characteristics are shown in Table 1. [Example 39] An A/B/C/D laminate was produced in the same manner as in Example 30 except that the thickness of the interlayer of the modified polyolefin was changed to 30 μm. The characteristics are shown in Table 1. [Example 4 0] In addition to the modified polyolefin in Example 30, it was replaced with an adhesive polyethylene (functional graft-modified polyethylene) "Adomer ΝΕ 827" manufactured by Mitsui Chemicals, Inc., and the interlayer thickness was A/B/C/D laminates were prepared in the same manner as in the case of 30 μm. The characteristics are shown in Table 1. [Example 4 1] In addition to the modified polyolefin, the modified polyolefin was replaced by an ethylene-vinyl acetate copolymer "Evaflex EV550" manufactured by Mitsui & DuPont POLYCHEMICAL Co., Ltd., and the thickness of the interlayer was 4 〇 μιη. Similarly, A/B/C/D laminates were produced. The characteristics are shown in Table 1. -33- 201222930

[Example 4 2 J In addition to Example 30, a modified polyolefin was replaced with a special ethylene copolymer made by Sumitomo Chemical History " ί八右77 Ltd. (ethylene/methacrylate) I κ 内 妇 丙 丙 丙 旨 旨 旨 ============================================================================================== The system is shown in Table 1.

[Continuous Example 4 3 J In addition to the application of Example 3 〇, the modified polyene smoke was replaced by the Toyo Textiles Co., Ltd. 'The limited A system of hot-melt adhesive for polyfluorene hydrocarbons'' T 〇y 〇tac Μ 1 0 0,,, A/B/C/D laminate was produced in the same manner except that the temperature was 160 °C. The characteristics are shown in Table 1. [Example 44] In the same manner as in Example 30, the modified polyolefin was replaced with a polypropylene-based adhesive resin (functional graft-modified polyene) "Modic P553A" manufactured by Mitsubishi Chemical Corporation, melting temperature. A/b/C/D laminate was formed in the same manner as 168t and the interlayer thickness was 5〇μπι. The characteristics are shown in Table 1. [Example 4 5] In addition to the modified polyolefin in Example 30, a polypropylene-based adhesive resin (functionalized graft-modified polypropylene "Modie Ρ 5 5 3 Α") manufactured by Mitsubishi Chemical Corporation was used. A/b/c/d laminate was produced in the same manner except that the melting temperature was 1681 and the interlayer thickness was 60 μχη. The characteristics are shown in Table 1. [Example 46] -34-201222930 In addition to the modified polyolefin in Example 30, a polypropylene-based adhesive resin (functional graft-modified polypropylene "M〇dicp553A, manufactured by Mitsubishi Chemical Co., Ltd.) was used. '), the melting temperature was 168. The thickness of the interlayer was 6 μm, and the A/B/C/D laminate was formed in the same manner. The characteristics are shown in Table 1. [Example 47] Except in Example 30 'As a modified polyolefin, a low-density linear polyethylene-based adhesive resin (functional-based graft-modified polyethylene "Modic M502") manufactured by Mitsubishi Chemical Corporation was used, and the melting temperature was 124 t. /B/C/D laminate. The characteristics are shown in Table i [Example 48] except for the modification of the thickness of 30 μm between the A/B/C laminate and D in Example 30 A polypropylene film ("Adomerfilm QE-060C" manufactured by TOHCELLO Co., Ltd.) was heat-pressed by a heat lamination method at a roll temperature of 15 Torr, a roll pressure of 30 kg/cm, and a transfer speed of 20 m/min. B / C / D laminate. The characteristics are shown in Table 1. [Example 49] Except for implementation In the same manner as in Example 30, the A/B/C/D laminate was produced in the same manner as in Example 30, and the characteristics are shown in Table 1. [Example 50] Except for Example 30, except that the thickness of the "case" (C) was changed to 7 μπ. In the same manner as in Example 30 except that the thickness of the aluminum box (C) was 40 μm, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. -35 - 201222930 [Example 5 1] A biaxially oriented polyethylene terephthalate film (A) having a thickness of 25 μm, a breaking strength of i65 MPa, and an elongation at break of 215% by dry-lamination method (TefleX, FT3, manufactured by Teijin DuPont Film Co., Ltd.) Non-aligned nylon 6 film (B) having a thickness of 15 μm, a breaking strength of l〇3 MPa, and an elongation at break of 398% ("Ray fan" (s main book trademark) manufactured by Toray Film Processing Co., Ltd. N〇14〇1 ), "Takelac A-91 〇 (polyol-based main agent) / T ake na te A - 3 (isocyanate-based hardener)" by the Mitsui Chemical Polyamine Ethyl Copolymer Co., Ltd.'' two-liquid type (j (9) weight 10 parts by weight of the adhesive, as an A/B laminate. Here, the adhesive is coated on the A side as a solid component. 5g/m2, after A/B bonding, 40 C, 72 hours of aging treatment. By dry layering method, superimposed A/B laminated material, thickness 4 〇μηη of aluminum / # (C) 'ν spa spa spa 股份有限公司 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T T / "Takenate A_3 (isocyanate-based curing agent)" two-component type (100 parts by weight / 10 parts by weight) of an adhesive to form an A/B/c laminate. Here, the amount of the adhesive applied is 6 g/m in terms of solid content on the B side, and after bonding at B/C, the composition is aged at 45 ° C for 80 hours, and the thickness is applied to the A/B/C laminate. A 70 μm η unbonded polypropylene film (D) (Pylenfilm-CT P1 146 manufactured by Toyobo Co., Ltd.) having a breaking strength of 35 MPa, an elongation at break of 655%, and a Young's modulus of 415 MPa, at a melting temperature of 140 ° C It is extruded at a thickness of ι〇μπι, using a modified polyolefin (manufactured by Mitsui Chemicals, Inc., -36-201222930 functional graft-modified polypropylene "Adomer QE840") in a sandwich between c and D. The laminate was used as the Α/Β/C/D laminate of the invention. The characteristics are shown in Table 1. [Example 52] In addition to the biaxial alignment of polyethylene terephthalate in Example 51 Film (A), except for a biaxially oriented polyethylene terephthalate film (Teflex FT3 manufactured by Teijin DuPont Film Co., Ltd.) having a thickness of 5011111, a breaking strength of 195 MPa, and an elongation at break of 190%. In the same manner as in Example 51, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 5 3] In addition to Example 52, as the biaxially-oriented polyethylene terephthalate film (A), a two-axis having a thickness of 50 μm, a breaking strength of 195 MPa, and an elongation at break of 1 90% was used. A/B/C was prepared in the same manner as in Example 51 except that the polyethylene terephthalate film (Teflex FT3, manufactured by Teijin DuPont Film Co., Ltd.) and the thickness of the aluminum foil (C) were 1 Ομηι. /D Laminates. Characteristics are shown in Table 1. [Example 54] In Example 51, as the polypropylene film (D), a thickness of 40 μm, a breaking strength of 33 MPa, and an elongation at break of 570% were used. A non-aligned polypropylene film having a Young's modulus of 3 80 MPa (Pylenfilm-CT P1153 manufactured by Toyobo Co., Ltd.) was used to produce an A/B/C/D laminate in the same manner as in Example 51. The characteristics are shown in [Example 5 5 ] -37- 201222930 In addition to Example 51, as a polypropylene film (D), a thickness of 100 μm, a breaking strength of 37 MPa, an elongation at break of 73%, and a yang were used. Non-aligned polypropylene film with a modulus of 500 Μ P a (Toyo Textile Co., Ltd. has An A/B/C/D laminate was produced in the same manner as in Example 51 except for the "Pylenfilm-CTP1147" manufactured by Konica Minolta Co., Ltd. The characteristics are shown in Table i. [Example 56] Except in Example 51, As the polypropylene film (D), an unoriented polypropylene film (manufactured by Toyobo Co., Ltd.) having a thickness of 80 μm, a breaking strength of 37 MPa, a breaking elongation of 73% by weight, and a Young's modulus of 500 Å P a was used. In the same manner as in Example 51 except for Pylenfilm-CT P1147, a), an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Example 57] Except for Example 51, as the polypropylene film (D), a thickness of 25 μm, a breaking strength of 40 MPa, an elongation at break of 480%, and a modulus of Zu: 500 Μ P a were used. An A/B/C/D laminate was produced in the same manner as in Example η □ |aJ except for the oriented polypropylene film (Pylenfilm-CT P1181 manufactured by Toyobo Co., Ltd.). The characteristics are shown in Table 1. [Example 58] An A/B/C/D laminate was produced in the same manner as in Example 51 except that the thickness of the interlayer of the modified polyolefin was changed to 30 μm. The feature is shown in $&1. [Example 59] In the same manner as in Example 51, as a modified polyolefin, an adhesive polyethylene (functional graft-modified polyethylene) "Adomer ΝΕ 8 2 7" made of Erzhi Co., Ltd. was laminated. In the same manner as the thickness of 30 μm, the same L was used as the A/B/C/D laminate. The characteristics are shown in Table 1. -38-201222930 [Example 60] In the same manner as in Example 51, the modified polyolefin was replaced with an ethylene-vinyl acetate copolymer "Evaflex EV550" manufactured by Mitsui & DuPont POLYCHEMICAL Co., Ltd., and the interlayer thickness was 40 μm. In the same manner, A/B/C/D laminates were produced in the same manner. The characteristics are shown in Table 1. [Example 6 1] In addition to the modified polyolefin in Example 51, a special ethylene copolymer (ethylene/methacrylic acid bismuth methacrylate/methyl acrylate) manufactured by Sumitomo Chemical Co., Ltd. was replaced. = 7 〇 / 3 / 27 wt%) "Bondfast 7L", melting temperature is 105. A/B/C/D laminates were prepared in the same manner as 〇. The characteristics are shown in Table 1. [Example 6 2] In the same manner as in Example 51, the modified polyolefin was changed to "Toyotac M100" which is a hot-melt adhesive for polyolefins manufactured by Toyobo Co., Ltd., and the melting temperature was 160. A/B/C/D laminates were produced in the same manner except for ruthenium. The characteristics are shown in Table 1. '[Example 6 3 ] In addition to Example 51, the modified polyolefin was replaced with a polypropylene-based adhesive resin (functionalized graft-modified polypropylene "Modic P5 5 3 A" manufactured by Mitsubishi Chemical Corporation). The a/B/C/D laminate was formed in the same manner, except that the melting temperature was 168 ° C and the thickness of the interlayer was 5 μm. The characteristics are shown in Table 1. [Example 64] In addition to the modified polyolefin, a polypropylene-based adhesive resin manufactured by Mitsubishi Chemical Corporation was used as a modified polyolefin (functionalized graft-modified -39-201222930 polypropylene "M〇diCP5 5 3 A,,), the melting temperature was i68t:, and the interlayer thickness was 60 μm, and the A/B/c/D laminate was similarly produced. The characteristics are shown in Table 1. [Example 65] Except for Example 5 In the case of the modified polyolefin, a polypropylene-based adhesive resin (functional-based graft-modified polypropylene "Modic P5 53A") manufactured by Mitsubishi Chemical Corporation was used, and the melting temperature was 168 t: and the interlayer thickness was 6 μm. The A/B/C/D laminate was produced in the same manner. The characteristics are shown in Table 1. [Example 66] In addition to Example 51, as a modified polyolefin, a low density line manufactured by Mitsubishi Chemical Corporation was used. A polyethylene-based adhesive resin (functional-based graft-modified polyethylene "Modic Μ 502"), and an A/B/C/D laminated material was produced in the same manner except that the melting temperature was i24 ° C. The characteristics are shown in Table 1. [Example 67] Except in Example 51 'in A/B/C laminated material A functional group graft-modified polypropylene film ("Adomerfilm QE-060C" manufactured by TOHCELLO Co., Ltd.) having a thickness of 30 μm is laminated with D at a roll temperature of 150 Torr, a roll pressure of 30 kg/cm, and a conveying speed of 20 m/min. The A/B/C/D laminate was thermally pressed by a thermal lamination method. The characteristics are shown in Table 1. [Example 68] Except that in Example 51, the thickness of the mold (C) was In the same manner as in Example 51, except for 7 μm, the A/B/C/D laminate was produced. The characteristics are shown in Table 1. -40 - 201222930 [Example 69] In addition to Example 51, "Ming knot (C In the same manner as in Example 51, an A/B/C/D laminate was produced in the same manner as in Example 51. The characteristics are shown in Table 1. ...

[Example 70J as a biaxially oriented polyethylene terephthalate film (Α), using wt% of polyethylene terephthalate, and 6 wt% of polyester as isophthalic acid 10 The methane copolymerized polybutylene terephthalate was adjusted to have a spherical vermiculite particle having an average particle diameter of 12% by weight of 0.012% by weight. The polymer fragments are at 150. After drying for 3 hours in a vacuum, the uniaxial extruder was discharged from a normal nozzle, and then cooled and solidified on a mirror cooling drum while applying static electricity to obtain an unaligned film. By a non-adhesive polyfluorene roller (hardness 73.), 7 〇. . The elongation temperature of the unaligned film was extended by 2.0 times in the longitudinal direction, and then stretched by 2.0 Å in the width direction in the tenter. Then, at a film temperature of 1 § ,, while relaxing at 4% in the width direction while heat treatment for 5 seconds, a biaxially oriented polyparaphenylene having a thickness of 3 〇 μηη, a breaking strength of 10 MPa, and an elongation at break of 189% was obtained. A film of bismuth citrate. In the same manner as in Example 51, an a/b/C/D laminate was produced. The characteristics are shown in Table 1. [Example 7 1] In addition to the film of Example 5, 'as a biaxially oriented polyethylene terephthalate film (A)', the thickness was 50 μm, the breaking strength was 25 MPa, and the elongation at break was 178%. In the same manner as in Example 51, except for the film of the polyethylene terephthalate film ("Lumirror" (registered trademark) F99 manufactured by Toray Industries, Inc.), the A/B/C/D laminate was produced. . The characteristics are shown in Table 1. • 41 - 201222930 [Example 7 2 ] In addition to Example 51, as a biaxially oriented polyethylene terephthalate film (A), a thickness of 5 〇μΓη, a breaking strength of 232 MPa, and an elongation at break of 1 were used. An A/B/C/D was created in the same manner as in Example 51 except that 82% of the biaxially-oriented polyethylene terephthalate film ("Lumirror" (registered trademark) S56 manufactured by Toray Industries, Inc.) was used. Laminates. The characteristics are shown in Table 1. [Comparative Example 1] In the first embodiment, a nylon film (a biaxial alignment film "Hardenfilm N1 100" manufactured by Toyobo Co., Ltd.) was used as the nylon film (B). In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 2] Except that in Example 1, the modified polyolefin was not used, and UBE Polyethylene L7 1 9 made of Ube Industries, Ltd. was used instead, and the melting temperature was 1 〇 8 ° C. In the same manner, A/B/C/D laminates were produced in the same manner. The characteristics are shown in Table 1. [Comparative Example 3] In Example 1, a composite A/B/C laminate and an unoriented polypropylene film (D) ("pylenfilm-CT P 1 146" manufactured by Toyobo Co., Ltd.), C and D, "Takelac A-910 (Polyol based main agent) T akenate A - 3 (isocyanate sputum hardener)"' two liquid made by Mitsui Chemical Polyamine Ethylate Co., Ltd. by dry laminate method Type (1 〇〇 by weight/10 parts by weight) of adhesive to form a/b/c/d laminate. Here, the amount of adhesive applied is 6 g/m on the C side as solid content, at C/D. Post-42 - 201222930 After the combination, the aging treatment was carried out at 45 ° C for 80 hours. In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in Table i [Comparative Example] 4) In the first embodiment, an oriented polypropylene film having a thickness of 6 μm was used as the polypropylene film (D) (two-axis alignment polypropylene film "Torayfan" (registered trademark) 2500 Å manufactured by Toray Industries, Inc.) In the same manner as in Example 1, an A/B/C/D laminate was produced. It cannot be heat-sealed, it cannot be made into a bag, and it cannot be made into a container for secondary batteries. [Comparative Example 5] As the polypropylene film (D), an unaligned polypropylene film having a thickness of 40 μm, a breaking strength of 38 MPa, and a tensile elongation of Young's modulus of 630 MPa was used as the polypropylene film (D) (Toyobo Co., Ltd.) In the same manner as in Example i, except for "Pylenfilm-CT PlUl,", the A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 6] In Example 1, As D, an unaligned polypropylene film having a thickness of 6 〇μηι of 47 MPa, a breaking elongation of 635%, and a Young's modulus of 630 MPa was used. Torayfan (registered trademark) n manufactured by Toray Film Processing Co., Ltd. 〇33〇1). In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in the table! in. [Comparative Example 7] In Example 1, 'the polyester film (A) was not used. The A/B laminate was not formed. In the same manner as in Example 1, a B/c/D laminate was produced. The characteristics are shown in Table 1. -43-201222930 [Comparative Example 8] In Example 1, as D, an unaligned polypropylene film having a thickness of 40 μm of a breaking strength of 38 MPa, an elongation at break of 500%, and a Young's modulus of 585 MPa was used ( D) (Pylenfilm_CT Pll28, manufactured by Toyobo Co., Ltd.). In the same manner as in Example 1, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 9] In Example 1, the A/B laminate was laminated with C' A and C, and the adhesive, the amount of the adhesive applied, and the aging treatment of the example ' were carried out to form a B/A/C laminate. material. Then, in the same manner as in Example 1, a B/A/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 10] A biaxially-oriented polyethylene terephthalate film (A) having a thickness of 12 μm, a breaking strength of 240 MPa, and an elongation at break of 181 % by a dry build-up method (A) "Lumirr〇r" (registered trademark) p6〇 manufactured by Co., Ltd.) and aluminum foil (c) having a thickness of 40 μm ("Vespa" 8021 manufactured by Light Aluminum Foil Co., Ltd.) 'Using Mitsui Chemical Polyurethane Co., Ltd. "Takelac A-910 (polyol-based main agent butyl akenate A_3 (isocyanate-based hardener), two-component type (丨〇〇 parts by weight / 丨〇 part by weight) of adhesive, made of A / C laminated material. Here The amount of the adhesive applied was 6 g/m 2 in terms of solid content on the A side, and after 45 ° and 80 hours of aging treatment after bonding to A/C, the thickness was 15 μm and the breaking strength was 1 〇 3 MPa by the dry laminate method. The unaligned nylon ruthenium film (b) having a breaking elongation of 398% ("Rayfan" (registered trademark) No. 1401 manufactured by Toray Film Processing Co., Ltd.) and -44 - 201222930 has a breaking strength of 35 MPa at a thickness of 70 μm. The elongation at break is 655°/., and the Young's modulus is 4 1 5 Μ P a. Acrylic film (D) ("Pylenfilm_CT P1 146" manufactured by Toyobo Co., Ltd.), "Takelac A-9 1 0 (polyol-based main agent)" manufactured by Mitsui Chemicals Polyamine Oxime Co., Ltd. /" Takenate A-3 (isocyanate-based hardener), 'two-component type (100 parts by weight/10 parts by weight) of adhesive, made of B/D laminate. The amount of adhesive applied here is 5g/g on the B side in terms of solid content. M2, after bonding at B/D, was aged at 40 ° C for 72 hours. The A/C laminate and the b/d laminate were extruded at a melt temperature of 140 ° C at a thickness of 10 μm. A modified polyolefin (manufactured by Mitsui Chemicals Co., Ltd., functionally graft-modified polypropylene "Adomer QE840") was laminated on the interlayer ' between C and B to form an a/C/B/D laminate. The system is shown in Table 1. [Comparative Example 1 1] The uncomplexed polypropylene having a breaking strength of 35 MPa and an elongation at break of 655 ° /. and a Young's modulus of 415 MPa by a dry laminate method Film (D) ("pyienfilm_CT P1146" manufactured by Toyobo Co., Ltd.) and thickness 15μπι, breaking strength i〇3Mpa, Unaligned nylon 6 film (B) with a crack elongation of j98 / ("Rayfan" (registered trademark) NO 1401, manufactured by Toray Film Processing Co., Ltd.), "Take" manufactured by Mitsui Chemicals Polyurethane Co., Ltd.丨μ A-9i〇 (polyol based agent) / Takenate A-3 (isocyanate-based hardener), two-liquid type (1〇〇 heavy injury / ίο reset part) adhesive, made d/b laminated material . Here, the adhesion Jk Brill was 5 g/m 2 on the B side in terms of solid content, and after the bonding, the lamp was aged for 40 C for 72 hours. -45- 201222930 By D-B laminated method, laminated D/B laminated material, 40μm thickness of Ming Foil (C) (Vespa "8021) made by Light Aluminum Foil Co., Ltd., Β and C 'Use Mitsui Chemical Polyamine A ''Takelac A-910 (polyol-based main agent), '/''Takenate A-3 (isocyanate-based curing agent)" two-liquid type (100 parts by weight / 10 parts by weight) adhesive The D/B/C laminate was prepared. The amount of the adhesive applied was 6 g/m2 on the B side in terms of solid content, and after bonding at D/B/C, the curing treatment was carried out at 45 ° C for 80 hours. Biaxially oriented polyethylene terephthalate film (A) with a thickness of 12 μm, a breaking strength of 240 MPa, and an elongation at break of 18% on a D/B/C laminate (Dongli Co., Ltd.) "Lumirror" (registered trademark) P60) is extruded at a temperature of 140 ° C at a thickness of ΙΟμπι, using a modified polyolefin (manufactured by Mitsui Chemicals, Inc., functionally graft-modified polypropylene "Adomer QE84" 〇") The interlayer between C and Α is laminated to form A/C/B/D laminate. The characteristics are shown in Table 1. [Comparative Example 12] In Example 30, a nylon 6 film (β) was used as a nylon 6 film (β) (a biaxial alignment film "Hardenfilm N.1100") manufactured by Toyobo Co., Ltd.). 3〇 Similarly, an A/B/C/D laminate was produced. The characteristics are shown in Table j. [Comparative Example 1 3] Except that in Example 30, modified polyolefin was not used, and Ube Industries was used instead. A high-density polyethylene made by the company, "υβΕpolyethylene L719' is melted, and the 'cover degree is other than 108C'. The a/B/C/D laminate is produced in the same manner. The characteristics are shown in Table 1. 201222930 [Comparative Example 14] In Example 30, the a/b/c laminate and the unaligned polypropylene film (D) ("Pylenfilm CT PI i46" manufactured by Toyobo Co., Ltd.) were laminated by a dry laminate method. C and D, "Takelac A_9l (polyol-based main agent)" / "Takenate A-3 (isocyanate-based hardener)" manufactured by Mitsui Chemicals Polyamine Co., Ltd., two-liquid type (1〇〇) A part by weight / 10 parts by weight of the adhesive was prepared as an A/B/C/D laminate. Here, the amount of the adhesive applied was 6 g/m 2 on the C side in terms of solid content, and was carried out after C/D bonding. The aging treatment was carried out at ° C for 80 hours, and the A/B/C/D laminate was produced in the same manner as in Example 3, and the characteristics are shown in Table 1. [Comparative Example 15] In Example 30, In the polypropylene film (D), an oriented polypropylene film having a thickness of 6 〇 μηη (Torayfan (registered trademark) 2500 制, manufactured by Toray Co., Ltd.) was used in the same manner as in Example 30. , made of A / B / C / D laminated materials. It cannot be heat-sealed and cannot be made into a bag. ‘The container for secondary batteries cannot be made. [Comparative Example 16] As the polypropylene film (D), an unoriented polypropylene having a thickness of 40 μm, a breaking strength of 38 MPa, an elongation at break of 51%, and a Young's modulus of 630 MPa was used as the polypropylene film (D). In the same manner as in Example 3, except for the film (Pylenfilm-CT P1111 manufactured by Toyobo Co., Ltd.), an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 17] In Example 30, as D, an unaligned polypropylene having a thickness of 6 〇μηι of 47 MPa, an elongation at break of 635%, and a Young's modulus of 63 〇Mpa -47 to 201222930 was used. Film (D) (Torayfan (registered trademark) NO 3301, manufactured by Toray Film Processing Co., Ltd.). Otherwise, in the same manner as in Example 30, an A / B / C / D laminate was produced. The characteristics are shown in Table 1 [Comparative Example 18] In Example 30, a polyester film was not used. In the same manner as in Example 30, a b/C/D laminate was produced in the same manner as in the a/B laminate. The characteristics are shown in Table 1. [Comparative Example 19] In Example 30, as D, an unaligned polypropylene film (D) having a thickness of 4 〇 μηη of 38 MPa, an elongation at break of 5%, and a Young's modulus of 585 MPa was used ( "Pyunfilm-CT P1128" manufactured by Toyobo Co., Ltd.). Otherwise, in the same manner as in Example 3, an A/B/C/D laminate was produced. The characteristics are shown in Table 2. [Comparative Example 20] In the case of the Example 30, the laminated A/B laminated material and the c and A were similarly subjected to the adhesive, the amount of the adhesive applied, and the aging treatment to form a B/A/C laminated material. . Then, in the same manner as in Example 30, a B/A/C/D laminate was produced. The characteristics are shown in the table ι. [Comparative Example 2 1 ] By a dry-laid method, a thick sound, an elongation at break of 118% of two: g -, a breaking strength of 27, and a 3 f-axis alignment of a polyethylene terephthalate film (A) (Dongli >Tactical Processing Co., Ltd. trademark) P375) and thickness 25μηι, (4)(10)1*" (2) Secretary system "Vespa" 8021), use:: Yangshen light 1 Lu pig shares limited company - well chemical polyamine Formate Co., Ltd. -48- 201222930 Takelace A-91〇 (Polyol Master), //Takenate A-3 (Isocyanate Hardener)'' Two Liquid Type (1 part by weight) "ο parts by weight" Adhesive 'made as A/C laminate. Here, the amount of the adhesive applied was 6 g/m 2 on the a side as a solid component, and 45 after the A/C bonding. (:, 80 hours of aging treatment. By the dry layer method, the unaligned nylon 6 film (B) having a thickness of 15 μπ1, a breaking strength of 1〇3 MPa, and a breaking elongation of A 3 98% (Dongli film force = industrial shares) Co., Ltd. "Rayfan" (registered trademark) N〇14〇1) and a thickness of 7〇μηι with a breaking strength of 35MPa, an elongation at break of 655%, and a Young's modulus of 415MPa (D) ( "Pylenfilm_CT P1 M6" manufactured by Toyobo Co., Ltd.), "Takelac A_91" (Polyol Master 1) / Takenate A-3 (Isocyanate-based curing agent) manufactured by Mitsui Chemicals Polyamine Oxalate Co., Ltd. , 'Two-component type (1 〇〇 part by weight/10 parts by weight) of adhesive, made of B/D laminate. Here, the amount of adhesive applied is 5g/m2 on the B side in terms of solid content, and is bonded to B/D. After the 'curing treatment at 40 ° C for 72 hours. The A/C laminate and the B/D laminate were extruded at i4 (the melting temperature of TC, at a thickness of ΙΟμηη, using modified polyolefin (Mitsui Chemicals) Co., Ltd., functional group graft modified polypropylene "Ad〇mer qE84〇,,) between C and B The interlayer was laminated to form an A/c/B/D laminate. The characteristics are shown in the table. [Comparative Example 2 2] The fracture strength of the thickness of 70 μm by the dry laminate method was 35 MPa, and the elongation at break was 655%, non-aligned polypropylene/film (D) with Young's modulus of 415 MPa (made by Toyobo Co., Ltd., py 1 enf丨丨(7)c τ -49- 201222930 卩1146'') and thickness of 111 An unaligned nylon 6 film (B) having a breaking strength of 1〇3^1^ and a breaking elongation of 398% ("Rayfan" (registered trademark) Ν〇ι4〇1, manufactured by Toray Film Processing Co., Ltd.), used "Take 丨ac A_91 〇 (polyol-based main agent)"' / "Takenate A-3 (isocyanate-based curing agent)", manufactured by Mitsui Chemicals Polyurethane Co., Ltd., two-liquid type (100 weights: 3: parts / 10 parts by weight of the adhesive was prepared as a D/b laminate. Here, the amount of the adhesive applied was 5 g/m 2 on the B side in terms of solid content, and 4 0 C, 72 hours after the D/B bonding. Curing treatment. Aluminum foil (C) with a thickness of 25 μm is laminated by D/B laminate (Vespa, manufactured by Light Aluminum Foil Co., Ltd.) 8021), Β and C' use "TakeUc A-910 (polyol-based main agent)" / "Takenate A_3 (isocyanate-based curing agent)" two-liquid type (1〇) manufactured by Mitsui Chemicals Polyamine Oxalate Co., Ltd. 〇 Parts by weight / 1 part by weight) Adhesive, made of D/B/c laminate. Here, the amount of the adhesive applied was 6 g/m 2 on the B side in terms of solid content, and after bonding at D/B/C, it was aged at 45 ° C for 80 hours, and applied to the D/B/C laminate. A biaxially-oriented polyethylene terephthalate film (A) having a thickness of 6.5 μm, a breaking strength of 275 MPa, and an elongation at break of 118% ("Lumirror" (registered trademark) P60, manufactured by Toray Industries, Inc.) The melting temperature of 140C was extruded at a thickness of ΙΟμιη, and a modified polyolefin (manufactured by Sanken Chemical Co., Ltd., "functional graft-modified polypropylene "Adomer QE840") was sandwiched between C and Α. The layer was laminated to form an A/c/B/D laminate. The characteristics are shown in Table 1 -50 to 201222930 [Comparative Example 23] In addition to the embodiment, in place of the biaxial alignment of polyethylene terephthalate Ester film (A) 'Used a thick aromatic 纟 4.5 _, a breaking strength of 6 〇〇 Mpa, and an elongation at break of 50%. The para-type aromatic polyamide film (Mictron, manufactured by Toray Industries, Inc.) In the same manner as in Example 30 except for the trademark ML), an A/B/C/D laminate was produced. The characteristics are shown in Table i. [Comparative Example 24] In addition to the two-oriented polyethylene terephthalate film (A) in Example 30, a two-axis having a thickness of 12 μm, a breaking strength of 23 5 MPa, and an elongation at break of 95% was used. An A/B was produced in the same manner as in Example 3 except that the thickness of the aluminum foil (C) was ΐ〇μπι, which was made of a polyethylene terephthalate film (Toyobo Esterfilm E51 (manufactured by Toyobo Co., Ltd.). /C/D laminate. The characteristics are shown in Table 1. [Comparative Example 2 5] In addition to Example 30, 'as a biaxially oriented polyethylene terephthalate film (Α), thickness 50 μm , a rupture strength of 6 〇 MPa, and an elongation at break of 3 6 5 %, a sleeve-aligned poly(p-diphenyl phthalate) film (T ef 1 e X ρ τ 7, manufactured by Teijin DuPont Film Co., Ltd. In the same manner as in Example 30, 'A / B / C / D laminated material was produced. The characteristics are shown in Table 1. [Comparative Example 2 6] In Example 51, 'as a nylon 6 film (b) ), a aligning nylon 6 film (a two-axis alignment film "Hardenfilm N1 100" manufactured by Toyobo Co., Ltd.) was used. In the same manner as in Example 51, an A/B/C/D laminate was produced. The characteristics are shown in Table i. -51 - 201222930 [Comparative Example 27] In Example 51, no modified polyolefin was used instead. A high-density polyethylene "UBE Polyethylene L719" manufactured by Ube Industries, Ltd. was used, and an A/B/C/D laminate was produced in the same manner except that the melting temperature was 10 ° C. The characteristics are shown in Table 1. [Comparative Example 28] In Example 51, a/B/C laminate and unaligned polypropylene film (D) (Pylenfilm-CT P1 146 manufactured by Toyobo Co., Ltd.) were laminated by a dry laminate method. , C and D, using "Takelac A-910 (Polyol Master) / Takenate A-3 (Isocyanate-Based Hardener)" manufactured by Mitsui Chemicals Polyurethane® Co., Ltd. /10 parts by weight of the adhesive, made of A/B/C/D laminated material. Here, the adhesive coating is 6 g/m2 on the C side in terms of solid content, and after C/D bonding, d, 80 is carried out. The aging treatment was carried out in the same manner as in Example 5 j, and the A/B/C/D laminate was produced. The characteristics are shown in Table 。. [Comparative Example 29] In Example 51 As the polypropylene film (D), an oriented polypropylene film having a thickness of 6 μm was used (a two-axis alignment polypropylene film "Torayfan" (registered trademark) 25" manufactured by Toray Industries, Inc.). Similarly, an A/B/C/D laminate was produced. It could not be heat-sealed and could not be made into a bag. [Comparative Example 30] Except for the implementation of your "1 towel, as the polypropylene film (d), an unoriented polypropylene having a thickness of 40, a breaking strength of 38 MPa, an elongation at break of other %, and a Young's modulus of 630 MPa was used. A film of A/B/C/D was produced in the same manner as in Example 5 except that the film (Pylenfilm-CT PI 1 1 1) manufactured by Toyo Seiki Co., Ltd. was manufactured by Toyo Co., Ltd.. The characteristics are shown in Table 1. [Comparative Example 3 1] In Example 51, 'as D, an unaligned polypropylene film (D) having a thickness of 60 μηι having a breaking strength of 47 MPa, an elongation at break of 63 5%, and a Young's modulus of 630 MPa was used ( "Torayfan" (registered trademark) NO 3301 manufactured by Toray Film Processing Co., Ltd.). Otherwise, in the same manner as in Example 5-1, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. 〇 [t匕 Comparative Example 3 2 ] In Example 51, no polyester film was used. A/B laminate was not produced. In the same manner as in Example 51, a B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 3 3] In Example 51, as a crucible, an unaligned polypropylene crucible having a thickness of 40 μm and a breaking strength of 38 MPa, an elongation at break of 5 Å/q, and a Young's modulus of 585 MPa was used. (D) (Pylenfilm-CTP1128, manufactured by Toyobo Co., Ltd.). In the same manner as in Example ^, an A/B/C/D laminate was produced. The characteristics are shown in Table 1. [Comparative Example 3 4] In Example 51, the A/B laminate was laminated with C, A and C, and the adhesive, the amount of the adhesive applied, and the aging treatment of Example 51 were prepared in the same manner as in the case of B/A/ C laminated material. Then, in the same manner as in Example #1, a B/A/C/D laminate was produced. The characteristics are shown in the table. [Comparative Example 3 5 ] -53- 201222930 The two-axis alignment polyethylene terephthalate (Μ 由 由 由 又 又 又 厘 厘 厘 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又 又(Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te "Takelac A-910 (polyol-based main agent), /" Takenate A 3 (cyanic acid I-based curing agent), 'two-liquid type (100 parts by weight / 1 part by weight) adhered by Ester Co., Ltd. Agent, made A / C layer #. Here, the amount of the coating agent applied was 6 g/m2 in terms of solid content on the eight sides of the crucible, and after the A/C bonding, the curing treatment was carried out for 45 t and 8 hours. An unaligned nylon 6 film (B) having a thickness of 15 μm and a breaking strength of ι〇3Μρ& elongation at break of 398% by dry-laid method ("Rayfan" (registered trademark) N manufactured by Toray Film Processing Co., Ltd. "Non-aligned polypropylene film (D) (Pylenfilm_CT P1 146, manufactured by Toyobo Co., Ltd.) having a breaking strength of 35 MPa, a breaking elongation of 655%, and a Young's modulus of 415 MPa. "Takelac A_91" (Polyol based agent) / Takenate A-3 (isocyanate-based curing agent) manufactured by Mitsui Chemicals Polyurethane Co., Ltd., two-component type (1 part by weight / 10 parts by weight) The adhesive is used to form a B/D laminate. Here, the amount of the adhesive applied is 5 g/m 2 on the B side in terms of solid content, and after bonding at B/D, the curing treatment is carried out at 40 ° C for 72 hours. The A/C laminate and the β/D laminate were extruded at a melting temperature of 14 〇t at a thickness of 1 Ομηι, using a modified polyolefin (manufactured by Mitsui Chemicals, Inc., functional group graft modified poly Propylene "Adomer QE840") is laminated in the interlayer between C and B, A/C/B/D laminate. The characteristics are shown in Table 1. -54 - 201222930 [Comparative Example 36] The fracture strength of the 厘 ΐ 70 thickness 70 μπι is 35 Μρ & Unaligned aggregation of 655% and Young's modulus of 415

Acrylic film (9) ("pyienfUm_cT P1146" manufactured by Toyobo Masashi Co., Ltd.) and unaligned nylon 6 film (B) with a thickness of 15μηι, a breaking strength of mMpa, and an elongation at break of 398% (Dongli Film Processing Co., Ltd. "Rayfan" (registered trademark) N〇14〇1), using "Take丨ae A_9 1() (polyol-based agent) manufactured by Mitsui Chemicals Polyamine Tannin Co., Ltd., /"Takenate A_3 ( Isocyanic hardening agent), two-component type (1 part by weight by weight by weight) of adhesive, material (four) laminated material. Here, the amount of the coating agent applied was 5 Å on the B side in terms of solid content, and after aging, the aging treatment was carried out at 4 ° C for 72 hours. By dry layering method, laminated D/B laminated material, aluminum foil (C) with thickness of 25μηι (Vespa) 8021, Β and C made by Light Aluminum Foil Co., Ltd., using Mitsui Chemicals "Takelac A-9, a company made by the company, is called a polyol-based main agent... (Immediately, it is a hardened sheet J). One liquid | (1 〇〇 replacement part / 1 part by weight) of an adhesive is made into a laminate. 1 菩 丨 丨 θ θ 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Hours of aging treatment. On the D/B/C laminate, the thickness of 25 μm, the splitting strength is a gas-breaking elongation of 2 15 ° /. The biaxial alignment of the polyterpene terephthalate film (A (Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te Te The graft modified polypropylene "Adomer QE840") was laminated in the interlayer between C and A to form an A/C/B/D laminate. The characteristics are shown in Table 1. Example 37] In addition to the biaxially oriented polyethylene terephthalate film (A), a biaxial alignment having a thickness of 50 μm, a breaking strength of 60 MPa, and an elongation at break of 365 % was used instead of the biaxially oriented polyethylene terephthalate film (A). A/B/C/D laminate was produced in the same manner as in Example 51 except that a polyethylene terephthalate film ("Teflex" FT7 manufactured by Teijin DuPont Film Co., Ltd.) was used. The characteristics are shown in Table 1. [Comparative Example 3 8] In addition to Example 51, as a biaxially aligned poly(p-ethylene phthalate film (A), a thickness of Ι6 μm, a breaking strength of 177 MPa, and an elongation at break of 160% were used. A/B/C/D laminate was produced in the same manner as in Example 51 except that a biaxially-oriented polyethylene terephthalate film ("Lumirror" (registered trademark) F865) manufactured by Toray Film Processing Co., Ltd. was used. The properties are shown in Table 1. [Comparative Example 3 9] In addition to Example 51, as a biaxially-oriented polyethylene terephthalate film (A), a thickness of 38 μm and a breaking strength of 260 MPa were used. Biaxially oriented polyethylene terephthalate film with elongation at break of 168% (Toray film) A/B/C/D laminates were produced in the same manner as in Example 51 except for "Lumirror" (registered trademark) F99 manufactured by Seiko Co., Ltd. The characteristics are shown in Table 1. -56 - 201222930 [Comparative Example 4 0 ] In addition to Example 5 1, as a biaxially oriented polyethylene terephthalate film (Α), a biaxial alignment pair with a thickness of 38 μm, a breaking strength of 265 MPa, and an elongation at break of 1 70% was used. An A/B/C/D laminate was produced in the same manner as in Example 51 except that the ethylene phthalate film ("Lumirror" (registered trademark) ΤΙ 1 manufactured by Toray Industries, Inc.) was used. The characteristics are shown in Table 1. -57- 201222930 [1丨1<] Laminated layer stacking order ^VB/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D [VB/C/Change PO/D ^VB/C/modified PO/DA/B/C/modified PO/D ^VB/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D | A/B/C/modified PO/D 1 A/B/C/modified PO/D ^VB /C/modified PO/D 1 ^VB/C/modified PO/D | !A/B/C/modified PO/D 1 ^/B/C/modified PO/D > VB/C/ Modified PO/DA/B/C/modified PO/D 1 A/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/ C/modified PO/DA/B/C/modified PO/D impact resistance vibrancy-3 vibration resistance-2 vibrancy-1 〇〇〇〇〇〇~△ < 〇ο ι 〇〇 〇〇<<<<〇<1<1<1 Formability|mm oo o 00 KT) VO ON o Q\ ιη oo 00 oo oo 00 oo Bu Bu oo V) SO Bupoly Film (D) Young's modulus [MPa inch Λ ir 寸 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 - - - - - - - - - - - - - - - - - - - - - l l l l l l l l t;nv〇v〇iTj i〇Ό v〇u-) V〇655 570 730 730 480 |655 | in yr\ Ό ^55_1 Ό SO UI 655 in \r> 655 ID l〇VO ^Ti 'sn ^TJ \n vr> breaking strength|MPa in r^) m P〇mr〇tr» m A om «Ο UJ r^) m r<) ΙΛ>iT> Alignment of Ruirui Duan Rui nylon 6 film (B) elongation at break Degree 00 ON f<*| 398 398 398 398 398 j 398 00 o 〇〇O'· 398 398 ^98 | b98 398 OO ON m 398 | 398 398 398 | 398 oo 〇\ 00 On 398 398 Breaking strength | MPa S Ssssssss S sss S s S sssssssss ssssssssss ssssssssss s s s s o V-) CN ^Ti Fracture Strength|MPa 240 1 225 216 | § _1 o ο rS ο N_I oo rs o JN O 240 I o rs ο 240 | 〇o <n (N w*i oo S Alignment Two Axis Two-axis two-axis two-sleeve two-axis two-axis Ί Ί Two-axis two-axis Ί two-axis Ί two-axis Ί Ί two-axis 1 Ί Ί Ί Ί 素材 material PET PLA PET PET PLA PET PETi PET ΡΕΤ|PETl PFT PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET Example 10: 丨Example π 1 丨Example 丨21 |Example n| Example 14 丨Example 15 | |Example 丨6| |Example 17|1 Example 18| |Example 19|1 Implementation Example 2 | Example 21 | Example 22 I | Example 23 1 | Example 24 I Allied 0 knot fr--r Pool: z3d ISIro^BM^feie: HHd, οος — 3⁄43⁄4铋: od 铛佑铋:νΊο- 201222930 [<N-I <] Laminated material 1 laminated sequence A/B/C/modified PO/DA/B/C/modified PO/D ^V/B/C/modified PO/ DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D | A/B/C/modified PO/D 1 A/B/C/ Modified PO/D ^V/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D h/B/C/modified PO/DI lA/ B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/ B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D | A/B/C/modified PO/DA/B/C/modified PO /D Impact resistance 1 Vibration resistance-3 Vibration resistance-2 〇〇〇〇〇〇〇〇oo <1 <1 < o 〇〇~△ | <1 o For vibration -1 〇&lt ;〇0 <formability|mm OO o iT) ir> o polypropylene film (D) Young's modulus|MPa 415 415 1 |415_1 5 Ki5_! 415 o OO mo O os 415 415 415 415 415 415 415 | 415 415 Elongation at break in 655 655 655 655 655 丨655 ^55_I 655 | 〇730 730 k80 655 655 655 655 655 655 655 655 | 655 in <n breaking strength|MPa r·) i〇r·) yrt r^ ) IT» r<) l/·) ro A or^) i〇ITJ r<-| wi r<·) l〇r<*) Alignment difficult 磡 磡 瑞 瑞 Ruiji carbon 墉磲 carbon difficult 墀墀磲4i Nylon 6 film (B) Elongation at break OO 〇\ OO ON m OO Q\ r〇OO CN 398 OO Os OO ON ΓΛ OO 〇γ<Ί OO ON ΓΛ 398 OO 〇sr·) OO Os ΓΛ OO Os r*·) OO Os r^) OO On OO 〇s 398 OO as r*·) OO On r") OO Os OO ON Γη 398 | OO CN 398 Breaking strength|MPa SSS ss SSS ss S s SS sss SS sss S s Alignment film (A) Elongation at break OO OO OO 365 CO OO OO VO o OO U-) CN g OO OO OO OO OO OO OO OO OO OO OO OO OO OO breaking strength|MPa o 240 240 so 275 〇f*·) OO 480 | m_I JO m_ ¢75 JO rs JO 275 275 275 275 275 275 | i〇JO | Alignment two-axis two-axis two-axis dragon Ί two-axis Two-axis t Ί t M Ί Two-axis t two-axis two-axis t Ί Ί ί ί Two-pumper Ί M M 素材 material PET PET PET PET PET PET PET PEN! petI < cu PET PET PET PET PET PET PET PET PET PET PET PET PET PET Example 25 Example 26 Example 27 Example 28 Example 29 Example 30, | Example 31, Example 32 | Example 33 1 Example 34 S | Example 351 Example 36 1 "Example 37 1 Example 38 | Example 39 | Example 40 | | Example 411 | Example 42 | Example 43 Example 44 | Example 45 i | Example 46 I | Example 47 I | Example 48 | ISMO^fr-M Cover: z3d 遛-^0湓»-4}4 Lonely: 13d -6ς- 3⁄43⁄43⁄4 :〇dwsssi^^ikf^isiva. ^3⁄4 1⁄2 : v_ld 201222930 [eI ΐ laminate] stacking order ^V/B/C/modified PO/DA/B/C/modified P0/D ^VB/C/modified PO/DA/B/C/change PO/D |A/B/C/modified PO/DIA/B/C/modified PO/D ^VB/C/modified PO/DA/B/C/modified PO/D [A/B /C/modified PO/D 1 ^VB/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D ^/B/C/modified PO/DA /B/C/modified PO/D | a/B/C/modified PO/D ^i/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/D | A/B/C/modified PO/DA/B/C/modified PO/DA/B/C/modified PO/DA/B/C /modified PO / D | A / B / C / modified PO / D impact resistance 〇〇〇〇〇〇〇〇 <<<< o 〇 ~ △ 〇 ~ △ o 〇 ~ △ 〇 ooo Vibration resistance -3 〇〇〇〇〇〇〇〇<< o Ό~Λ 〇~△ o 〇~△ O ooo Vibration resistance-2 |〇~Δ 〇Vibration resistance-1 Formability|mm Propylene film (D) Young's modulus|MPa inch ir> inch WJ inch 380 500 500 ^00 ^15 415 ; Ul 415 ^15 415 U-) 415 415 | 415 415 415 | 415 Length |655 m \〇li-l in wo Ό in v〇o MX 730 730 |480 | •ο in ^55_I wi VJ? »·〇ir> \〇ΙΛ) Ό Ό »r> to V〇ITi IT5 \ 〇so m 655 iTi vn IT) ΙΛ Ό in in \n in \r> breaking strength [MPa ΙΛ Γ〇in r^) r<li〇r^l Pl o tr> r·) r^) in r·) Yn r^) r^ir〇 alignment nylon 6 film (B) elongation at break |398 398 OO Os r^) 398 398 OO Q\ 398 398 β98 i 00 〇\ ΡΛ 398 398 00 〇s 398 398 00 On OO ON 398 398 | 398 398 398 398 | oo Os breaking strength | MPa S s S ss S s 00 ossss S ss SS ssssss S alignment film (A) elongation at break 00 oo § oo ?] in 215 |2I5 cs 215 ?; V -) ID fq i〇n 215 | 215 215 〇s OO 00 <N OO breaking strength [MPa (275 uo V〇ON in Ό ό v〇Ό 〇SO Ό 2 ·〇Ό IT) VO in v〇ss 5 250 | 232 Alignment M Ί M Ί Ί Ί 轴 Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET丨PET PET PET PET | PET; PET PET PET PET PET PET PET PET PET PET | 1 Example 49 Example 50 Example 51 Example 52 Example 53 Example 54 Example 55 Example 56! Example 57丨Example 58 1 |Example 591 |Example 60 I |Example 6]1 Example 62 |Example 63 1 丨Example 64 1 丨Example 651 Example 66 |Example 67 | |Example 68 |Example 69 I Example 70 | Example 71 I 1 Example 72 1 -09- ls-r(o*«(s®-M concentrated: z3d ISMlo^B-Mi4i554: 13d 201222930 [inch'<;] Laminates|Lamination order| A/B/C/modified PO/D Ia/b/c/pe/d IA/B/C/DA/B/C/modified PO/DA/B/C/ Modified PO/DA/B/C/modified PO/DB/C/D [A/B/C/modified PO/DIB/A/C modified PO/DA/C/B/D ^ modified PO /C/B/D | ^VB/C/modified PO/DA/B/C/PE/DA/B/C/DA/B/C/modified PO/DA/B/C/modified PO/ DA/B/C/modified PO/DB/C/DA/B/C/modified PO/D | B/A/C modified PO/D | impact resistance: 1 vibration resistance-3 | vibration resistance Sex-2 XX XX XX 1 XX XX XX | XX Vibration resistance-1 XX X XX 1 X χ XX XX XX j XX XX @形性 | [mm 1 oo 00 1 卜卜ON 卜<?s 〇\ 〇s Polypropylene film (D) Modulus | MPa 415 W-ϊ 415 3012 |630 630 415 Vi oo »/*> 415 | 415 ^r, 415 415 415 β012 ο m \〇630 Wl <r> oo in 415 1 elongation at break 655 in 655 (N 〇\ |510 ν〇655 500 «·〇ΙΛ SO U*i <ς> J655 655 655 (N ON 510 w-) ui W-) vj-> 500 | in 1 breaking strength [MPa ρη in OO oo 00 卜 »r> 00 U-) r〇r^) »r> r ^) 00 00 oo 00 00 f^) r<) Alignment; Difficult 墀 Ί Difficulty m 瑞碟 m Difficult carbon 5 »1 Carbon 墉 male nylon 6 film (B) I elongation at break I oo ON οη 00 Os CO oo On r1) 00 ON n OO 〇\ oo On oo oo as r<) oo ON Γ*") oo 〇\ ΡΛ -1 oo oo Os oo 〇\ r*1) 398 oo ON oo ON OO 〇\ 398 | oo OS |Fracture Strength | |MPa 1 00 S s S sss SS ss Wear rs SS ss SS ss Alignment Mud 磡 磡 墀璀埦 墀璀埦 磔Ί 磔Ί 埦璀媸墉墀 媸 ( ( ( ( Elongation at break 00 oo 00 00 00 00 00 oo oo oo 00 00 00 00 00 OO OO 1 00 00 1 Degree|MPa 240 240 240 240 [240 o 1 _I o ^4〇_I o 卜 (N 275 JQ 275 jn CN JO rs I JO (N 275 Alignment Two-axis Ί Two-axis two-axis Ί Ί ! Ί Ί Ί \Ξ^\ Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί Ί PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 1 Comparative Example 5 1 | Comparative Example 6 I 丨 Comparative Example 7 1 ft 匕 Comparative Example 8 1 [t匕 Comparative Example 9 | f Comparative Example io| [fc匕 Comparative Example 11] Comparative Example 12 "Comparative Example 13 | Comparative Example 14 [Comparative Example 15 1 Comparative Example 16 | Comparative Example 17 | Comparative Example 18 | Comparative Example 19 | Comparative Example 20 sMo^B--r Spread: z3d IS-ro^BM ^^si: lUJd 敦$铋:〇d 绉 铋玑 铋玑 铋玑 ^ w^is: vcu 留^3⁄4 : vlcu 201222930 [S_I<] Laminate 1 stacking order A/C/modified PO/B/DA/Change PO/C/B/DA/B/C//modified PO/DA/B/C/modified P0/D ^VB/C/modified P0/DA/B/C/modified P0/DA/ B/C/PE/D |a/b/c/d I ^/B/C/modified P0/DA/B/C/modified P0/D ^VB/0/modified P0/D 1 !b /c/d A/B/C/modified P0/DB/A/C/modified P0/DA/C/modified PO/B/DA/modified, f± P0/C/B/DA/B/ C/ P0/DA/B/C/modified P0/DA/B/C/modified P0/D | A/B/C/modified P0/D impact resistance XX XX NX ! X χ XX kx XX XX XX XXXX Vibration resistance-3 XX XX ^<x 1 X χ XX Xx XX p<X Xx XXX y Vibration resistance-2 XX XX XX |xx Vibration resistance-1 Formability 1 Polypropylene film (D) Young Modulus tMPa 415 415 5 415 415 415 ^15_I 3012 沄|63〇_I 00 1/) ^15 ¢15_1 ^15 <n «n 415 Elongation at break · in Ό ITi Ό 655 «·〇in VO IT) So 655 ^55_I <N o IT) <^ί iT) Ό o 655 »·〇κη Ό Ό so Ό ir> »/*» breaking strength|MPa ΙΛ υΊ r<> U-) r*" ID oo 00 oo r*~i 00 in f^) «/>r<)ir>ir> f^| «Ο m | Alignment 璀m 璀5 M Carbon hard disk difficult nylon 6 film (B) Elongation at break 00 σ\ 〇〇On 〇〇〇s 398 |398 u-» 00 398 |398 | oo 〇\ OO σ\ Γη OO σν Γ<Ί 00 ON ^98 398 β98 398 oo ON r*) 398 OO <7\ r^) 398 breaking strength (MPa s S sss CO ss SSS sssssss S s P to carbon 碡 two-axis carbon hard carbon 墀磲 carbon 墀埤 disc carbon film (A > elongation at break 00 00 l〇ON [365 trj 215; IT) n IT) 刁Μ rs 1 215 ID Π «/ ) Ό s〇ms oo Ό o Breaking strength|MPa 275 275 o \〇235 g Ό so in Ό v〇1 »ri m vO tr> VO S r- 〇Ό Ό Alignment two-axis M ff two-axis Ί Axis | \Ξ^\ Ί Ί 轴 二 二 二 二 二 二 二 二 二 二 M M M M M M PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET PET pet|Comparative Example 21 Comparative Example 22 Comparative Example 23 Comparative Example 24 | Comparative Example 25 Comparative Example 26! 丨 Comparative Example 271 | Comparative Example 28] | Comparative Example 29 I Comparative Example 30 丨 Comparative Example 31 1 | Comparative Example 32 1 |Comparative Example 33 | Comparative Example 34 | Comparative Example 35 1 Comparative Example 36 Comparative Example 37 Comparative Example 38 | Comparative Example 39 | Comparative Example 40 SMO^BM 滹铋: z3d isMo?sB-Mi4si54: Idd

Iit-铋:〇d 3⁄43⁄4^3⁄4米米%'7xs: Vd 3⁄43⁄4 铋:Vld s-19_ 201222930 [Industrial Applicability] The laminated material of the present invention is excellent in workability and is formed of the laminated material of the present invention. The container is excellent in chemical resistance and vibration resistance. Therefore, the laminated material of the present invention can be suitably used as a laminate for a secondary battery container mounted on an electric vehicle, a hybrid vehicle, or an electric motorcycle. [Simple description of the diagram] Benefits 【 i [Description of main component symbols] None. -63-

Claims (1)

201222930 VII. Scope of application for patents: 1 · A laminate for secondary battery containers, a mixture of ethylene terephthalate and polyethylene naphthalate, with a film formed by poly-glycol aromatic polyamine , polylactic acid or counter-box (6), polypropylene film (9) laminated material nylon 6 film (8), Ming directional film, 8 and D-type unaligned film, which is: octagonal biaxially modified polyolefin layer, and D There is a space between Yang Mo C and D... Please patent range... 2 = ": _ below. The modified polyolefin layer is formed by grafting :: using a laminate material. 3. For example, if you apply for the patent scope 丨 or 2 _ ·Α # ^ ¥, the battery for the battery container, which consists of polyethylene terephthalate or polyethylene naphthalate. The resulting film (4) has a breaking strength of 150 to 25 MPa and an elongation at break of 100 to 150%. 4. For example, please use the laminated material for secondary battery containers of the first or second patent scope, which consists of polyethylene terephthalate, polyethylene naphthalate or para-aramid. The film (A) has a breaking strength of 250 to 48 MPa and an elongation at break of 80 to 170%. The film of the secondary battery container according to the first or second aspect of the patent scope of the invention has a breaking strength of 100 to 250 MPa and a breaking elongation of 170%. the above. A method for producing a laminate for a secondary battery container, characterized in that: a polyphenylene terephthalate having a breaking strength of 15 Å to 25 MPa and an elongation at break of 100 to 1 50% in this order Film (A) made of ethylene glycol, polyethylene naphthalate or polylactic acid, unaligned nylon 6 film (B), aluminum oil (C), modified polycondensation between C and D The olefin layer is an unaligned polypropylene film (D) having a laminated Young's modulus of 500 MPa or less. -64- 201222930 7. A method for producing a laminated material for a secondary battery container, characterized in that: a poly-p-benzoic acid B is formed by sequentially laminating a breaking strength of 250 to 480 MPa and an elongation at break of 80 to 170%. Film (A) made of diester, polyethylene naphthalate or para-aromatic polyamine, unaligned nylon 6 film (B), and foil (C), between C and D An unoriented polypropylene film (D) having a modified polyene fire two layer 'layered Young's modulus of 500 MPa or less is provided. 8 - a method for producing a laminated material for a human battery container, characterized in that: EA ^ male to ethylene glycol diester film is formed by sequentially laminating a breaking strength of 100 to 250 MPa and an elongation at break of 170% or more (A), unaligned Niyue ^ 6 film (8), 1 Lu (C) 'Set a modified poly-layer layer between C and D, the unaligned polypropylene film with a Young's modulus of 500 MPa or less (D). The secondary battery container according to any one of the items 8, wherein the modified polyolefin layer is formed by grafting, as in the method of the sixth aspect of the invention, to a method for producing a laminate. 10 Spearman battery Gu Yu, which is formed by a laminate for a secondary battery container as claimed in any of claims 1 to 3. -65- 201222930 IV. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: Yi 〇 « V. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: