TW201221343A - Fibrous mask processing method - Google Patents

Fibrous mask processing method Download PDF

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TW201221343A
TW201221343A TW99139342A TW99139342A TW201221343A TW 201221343 A TW201221343 A TW 201221343A TW 99139342 A TW99139342 A TW 99139342A TW 99139342 A TW99139342 A TW 99139342A TW 201221343 A TW201221343 A TW 201221343A
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Taiwan
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mask
fibrous
epoxy resin
baking
product
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TW99139342A
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Chinese (zh)
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TWI394656B (en
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Wen-Hua Ji
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Jaan Chyi Chemical Industry Co Ltd
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Abstract

The invention provides a fibrous mask processing step. A modified epoxy resin layer, after partial reaction, is combined with a fiber fabric through baking and pressurizing manner to form a fibrous mask. The mask then is placed in a mold and delivered to a hot pressing furnace for heating. The baking temperature is between 140 degrees Celsius and 150 degrees Celsius. The baking time is between 25 minutes to 40 minutes. A preform shell is formed by membrane blowing and hot pressing. The preform shell formed by utilizing the fibrous mask has a flat surface with high toughness and high strength. The process method of the invention improves the flatness of the whole mask surface and massively reduces holes on the surface. In the subsequent process of grinding and flattening the surface of the preform, grinding and polishing are comparably easy to be performed to improve the overall production efficiency and reduce labor costs.

Description

201221343 六、發明說明: 【發明所屬之技術領域】 製程 本發明係涉及—種加工製程,尤指-種纖 維性面膜加工 【先前技術】 鑒於目前習用的環氧被+ &山Λ 乳Μ知與奴纖維布(C/F)或玻璃纖維201221343 VI. Description of the invention: [Technical field to which the invention pertains] Process The present invention relates to a process for processing, in particular to a kind of fibrous mask processing [Prior Art] In view of the current conventional epoxy being known as + & With slave fiber cloth (C/F) or fiberglass

布(G/F)的複合材料70於力σ 丁 士⑴a L 、加工成形後的表面有許多大小不 一的孔洞71及缺陷該複合# n Λ ± 及α材枓7〇的表面有許多大小不一 的孔洞71及缺陷,於後* 俊、戈加工需要經過研磨、填補及拋光 等後續製作過程,需耗費大詈 貫穴里的人力時間及多道反覆的製 作程序,目的將該產品表面伞 衣面千整化,製作過程中會耗費過 多的熱能去填補該孔洞71缺陷,如圖7及圖8。 為了改善上述的缺點是目前這行業所面臨最大的生產 困難及瓶頸,基於目前令批興&<# 卜 世界所呼龥的節能減碳以及增加 生產效能的訴求,目前改盖β欢nH b 、 j文σ及發明出一種碳纖維布或玻璃 纖維布表面的加工面膜就此因應而生。 【發明内容】 鑑於目前習用的環氧樹脂與碳纖維布(c/f)或破璃纖維 布(G/F)的複合材料於加工成型後的表面有許多大小不一的 ^同及缺陷,於產品表面平整化的製作過程中需要耗費大 量的人力時間及熱能去填補改善上述的缺點。 四本發明係提供一種纖維性面膜加工製程,其係由—改質 環氧樹脂層經過部份反應後疊合於一纖維布並以洪烤加壓 201221343 方式與該纖維布相結合,並形一且▲土 /、有向轫性且高強度的 纖維性面膜,提升整體_ @ ^ & 菔纖維a面膜表面的平整性及大量減 >面的孔洞,減少人力生產成本且提升整體生產效能。 :發明所提供的技術手段在於提供—種纖維性面膜加 工製私’其係包括以下步驟: ㈤準備-纖維布’其係由一環氧樹脂及一纖維材料混 合反應而成;The composite material 70 of the cloth (G/F) is in the force σ ding (1) a L, and the surface after processing and forming has many holes 71 of different sizes and defects. The surface of the composite # n Λ ± and the α material 枓 7 有 has many sizes. Different holes 71 and defects, after the * Jun, Ge processing needs to be grinded, filled and polished, and other subsequent production processes, it takes a lot of manpower time and multiple repetitive production procedures, the purpose of the product surface The umbrella surface is rectified, and excessive heat is consumed during the production process to fill the hole 71 defect, as shown in Figs. 7 and 8. In order to improve the above-mentioned shortcomings, the biggest production difficulties and bottlenecks faced by the industry at present are based on the current demand for energy saving and carbon reduction and increasing production efficiency that the Rising &<# 卜 world is screaming. b, j σ σ and invented a carbon fiber cloth or a fiberglass cloth surface of the processing mask in response to this. SUMMARY OF THE INVENTION In view of the conventional composite materials of epoxy resin and carbon fiber cloth (c/f) or glass fiber cloth (G/F), there are many different sizes and defects on the surface after processing. The production process of product surface flattening requires a lot of manpower and heat to fill in the above shortcomings. The invention provides a fibrous mask processing process, which is formed by laminating a modified epoxy resin layer after partial reaction to a fiber cloth and combining with the fiber cloth by means of a red baking pressure 201221343, and forming ▲ soil /, directional and high-strength fibrous mask, improve the overall _ @ ^ & 菔 fiber a mask surface flatness and a large number of reduced surface holes, reduce labor costs and improve overall production efficacy. The technical means provided by the invention is to provide a fibrous mask processing system, which comprises the following steps: (5) preparing - a fiber cloth, which is formed by mixing an epoxy resin and a fiber material;

⑻準備一改質環氧樹脂層,其係以—環氧樹脂及一含 /、氰酸鹽樹脂(-NCO樹脂)混合反應而成; ⑷添加-架橋劑於該改質環氧樹脂層中且充分混合 ,拌,以烘烤溫度介於常溫或室溫至12吖之間使該改質 環氧樹脂層經過部份反應; (d)泫改質壞氧樹脂層經過部份反應後係與該纖維布 且合,置入模具中並送入熱壓爐中,而烘烤溫度於至 1 5〇 C之間’進行25分鐘至40分鐘的烘烤,膜壓吹氣成型 並形成一產品初胚。 ▲較佳的,所述之纖維性面膜加工製程,其中步驟⑷的 車父佳烘烤溫度係約85。(:。 *較佳的,戶斤述之纖維性面膜加工製程,其中步驟(d), 4改質環氧樹脂層之的厚度係介於1 〇微米至3〇〇微米之 較佳的,所述之纖維性面膜加工製程,其中步驟(d)的 較佳烘烤溫度約135。(:。 較佳的,所述之纖維性面膜加工製程’其中步驟(d)的 較佳烘烤時間約30分鐘。 201221343 較佳的,所述之纖維性面膜加工製程,其中步驟(d), 該面膜硬度係介於A50至D90之間。 較佳的,所述之纖維性面膜加工製程,其中該產品初 胚係為一運動元件。 較佳的,所述之纖維性面膜加工製程,其中該產品初 胚係為一車體零件。 較佳的’所述之纖維性面膜加工製程,其中該產品初 胚係為一 3C電子產品。 本發明所提供之纖維性面膜加工製程,可以獲得的優 點和功效增進包括: 1.本發明纖維性面膜加工製程,製造出—具有高強度 高韌性的纖維性面膜表面,提升複材整體面膜表面的平整性 及大量減少表面的孔洞;改良習用的環氧樹脂層與碳纖維布 或玻璃纖維布的複合材料於加工成形後的表面有許多大小 不一的孔洞及缺陷。 2,該纖維性面膜為平整且高強度的表面結構,其硬度 可達A5G D9Q之間,可依照產品的需求做調整,該纖維 性面膜直接以膜壓吹氣成型一產品初胚外#,生產者於後續 的產品初胚表面平整化的製作過程中,可以較好加工及研 磨。 3.本發明製程中該改質環氧樹脂層與該纖維布中的環氧樹 脂成分相以烘烤加壓方式將兩者結合,形成一纖維性面 膜置入板具中並送入熱壓爐中以膜壓吹氣熱壓成型—產品 :胚’兩者層間的結合性非常好’沒有脫層、黏著不佳的:; 題,方便後續研磨、填補及拋光等f作過程,提升整體製程 201221343 的生產效能。 【實施方式】 為能詳細瞭解本發明的技術特徵及實用功效,並可依 照說明書的内容來實施,兹進一步以如圖式所;的較;圭實 施例’詳細說明如后: 本發明所提供之-種纖維性面膜加工製裎,較佳實施例 係如圖1及2所示,其係包括以下步驟: ⑷準備一纖維布10包括有一環氧樹脂及一纖維材料 混合反應而成’該纖維材料可為一碳纖維布或一玻璃纖維 布;該碳纖維布10係由一碳纖維紗束浸潤於環氧樹脂中, 於編織機的滾輪編織成布狀,並附著在離型紙上,靜=約2 至3天使製作過程中所添加入的丙明完全揮發後,再從離 型紙上取下即形成該纖維布1 〇 ; 。(b)準備-改質環氧樹脂層2〇 ’其係包括有一環氧樹 月曰A及一含異氰酸鹽樹脂B卜NC〇樹脂)混合反應而成; ⑷添加-架橋劑C與該改質環氧樹脂層2〇充分混合 授拌,塗佈在離型紙上,該架橋齊I c係為聚苯:: (PO丨ypheny丨ene _de, PPS),於供烤溫度常溫或室溫至 1 20 C之間製作出部份反應的改質環氧樹脂層20,較佳的烘 烤溫度係為85t,該改質環氧樹脂層20之的厚度係介於 ::微米至300微米之間’其厚度可依照產品需求作適度調 整製作, ⑷該改質環氧樹脂層2〇與該纖維布,〇相聂人,兩 者以烘烤加壓方式結合,該改f環氧樹脂層2Q經料份反 應後溶渗人該纖維布1Q的孔隙之間並填平,且該纖維布在广 [Ο ] 6 201221343 該改質環氧樹脂屉由 坦的表面。a ,於該纖維布1〇的外惻形成一平 該供烤加麗方 ' 及該纖維布10置且σ的δ亥改質環氧樹脂層20 I 才莫具 φ甘·,玄 14CTC至15〇t之間,進行、八、=熱壓爐中,烘烤溫度於 吹氣成型形成_產品初胚;並刀^至40分鐘的棋烤’膜麼 〇C及供烤時間約為 〃,較佳的烘烤溫度約135 應的部份與該纖维布,該改質環氧樹脂層2〇中未反 •程中該改質環氧二!二的環氧樹脂完全反應並結合,製 分相近,故兩與該纖维布10中的環氧樹脂成 玟兩者層間的結合性非常好, 佳的問題,該改質環氧 又 0 、黏著不 ,主 树月曰層20與該纖維布10形忐一承 坦表面的纖維性面膜3〇。 /成一平 如圖3、4及圖5所示,該纖維性面膜3〇表 孔^本發明可以廣泛應用於製作各種產品外殼表面^,二 开m工 置接置入杈具中’經熱漫吹氣熱塑 丨直: 表面的產品初胚外殼,如各種的運動元件、 車體零件或3C電子產品的外殼社槿 又、,,。構’利用該纖維性面膜30 斤形成的產品初胚外殼具有高物性、高強度的平坦表面,生 產者於後續產品表面平整化的製作過程中,可以較好加工及 研磨,提升整體生產效能;本發明製程改善習用的環氧樹脂 與碳纖維布或玻璃纖維布的複合材料於加工成形後的表面 有許多大小不一的孔洞及缺陷,且應用於產品表面時因附著 性不好而易產生脫落的現象。 如圖4、5及圖6所示,本發明加工製程以熱遷膜塑形 成各種產品初胚外殼表面,應用於各種運動元件、 + [ S] 201221343 件或3C電子周邊產品的外殼表面上,如羽球拍4〇、網球 拍、高爾夫球杆等運動產品的表面上,或是腳踏車車管5〇、 汽車等車體零配件之外殼表面上;另外,該纖維性面膜3〇 可以直接貼覆於產品外殼表面,如筆記型電腦6〇外殼表 7、照相機或手機外殼表面等電子3C產品上,本發明加工 製程所製作出的纖維性面膜3〇具有高韌性、高強度的表面 特性,可以直接應用於產品表面,得到一平整且美觀的產 表面方便生產者於後續產品初胚表面平整化的製作過 程中,可以較好加工及方便後續研磨、填補及拋光等製作 過程:提升整體生產效能;另外’在人造合成皮革的運用 ^也疋可以適用,本發明製程可以克服PU (p〇|yurethane, ^虱酯)系統中對空氣的溼度的敏感性反應而產生的氣泡問 題’提升了整體纖維面膜製程的生產效能。 【圖式簡單說明】 圖1係本發明纖維性面膜加工製程的流程圖。 圖2係本發明纖維性面膜結構的立體外觀圖。 圖3係本發明應用於產品表面上的外觀圖。 圖4係本發明第一較佳實施例的示意圖。 圖5係本發明第二較佳實施例的示意圖。 圖6係本發明第三較佳實施例的示意圖。 圖7係驾用的複合材料的立體外觀圖。 圖8係習用的複合材料應用於產品表面上的外觀圖。 【主要元件符號說明】 [S1 8 201221343 1 〇纖維布 30纖維性面膜 50腳踏車車管 70複合材料 Α環氧樹脂 C架橋劑 20改質環氧樹脂層 40網球拍 60筆記型電腦 71孔洞 B含異氰酸鹽樹脂(8) preparing a modified epoxy resin layer which is obtained by mixing and reacting epoxy resin and a cyanate resin (-NCO resin); (4) adding a bridging agent to the modified epoxy resin layer And thoroughly mixing and mixing, the baking epoxy resin layer is partially reacted at a baking temperature between room temperature or room temperature to 12 Torr; (d) the ruthenium modified oxy-resin layer is partially reacted And the fiber cloth is combined, placed in a mold and sent to a hot press furnace, and the baking temperature is between 15 and 40 °C for 25 minutes to 40 minutes, and the film is blown and formed into a film. Product embryo. ▲ In preferred, the fibrous mask processing process, wherein the stepping temperature of the step (4) is about 85. (:. * The preferred method of processing the fibrous mask, wherein step (d), 4, the thickness of the modified epoxy layer is preferably between 1 〇 micrometer and 3 〇〇 micrometer. The fibrous mask processing process, wherein the preferred baking temperature of the step (d) is about 135. (: Preferably, the fibrous mask processing process is the preferred baking time of the step (d) Preferably, the fibrous mask processing process, wherein the step (d), the mask hardness is between A50 and D90. Preferably, the fibrous mask processing process, wherein The primordial product is a moving component. Preferably, the fibrous mask processing process, wherein the product primordial is a body part. Preferably, the fibrous mask processing process, wherein The product embryo is a 3C electronic product. The advantages and enhancements that can be obtained by the fibrous mask processing process provided by the invention include: 1. The fiber mask processing process of the invention produces a fiber with high strength and high toughness. Sexual mask surface, mention The flatness of the surface of the composite mask and the large reduction of the pores on the surface; the composite of the modified epoxy resin layer and the carbon fiber cloth or the glass fiber cloth has many holes and defects of different sizes on the surface after the forming. The fibrous mask is a flat and high-strength surface structure, and the hardness thereof can reach between A5G and D9Q, and can be adjusted according to the requirements of the product. The fibrous mask is directly formed by film blowing to form a product of the initial embryo #, the producer In the preparation process of the subsequent initial surface flattening of the product, the processing and grinding can be better. 3. In the process of the invention, the modified epoxy resin layer and the epoxy resin component in the fiber cloth are baked and pressed. The method combines the two to form a fibrous mask into the board and feed it into the hot pressing furnace to form a hot press by the film pressure blowing. The product: the embryo 'the combination between the two layers is very good' without delamination and adhesion. Poor:; The problem is convenient for subsequent grinding, filling and polishing, etc., to improve the production efficiency of the overall process 201221343. [Embodiment] In order to understand the technical features and practical work of the present invention in detail And can be implemented according to the contents of the specification, which is further illustrated by the following figures; the detailed description of the embodiment of the present invention is as follows: The invention provides a fibrous mask processing system, and the preferred embodiment is 1 and 2, which comprises the following steps: (4) preparing a fiber cloth 10 comprising an epoxy resin and a fiber material mixed and reacting. The fiber material may be a carbon fiber cloth or a glass fiber cloth; the carbon fiber cloth The 10 series is impregnated into the epoxy resin by a bundle of carbon fiber yarns, and the rollers of the knitting machine are woven into a cloth shape and attached to the release paper. The static = about 2 to 3 angels are added during the production process. And removing the release cloth from the release paper to form the fiber cloth 1 〇; (b) preparing-modifying the epoxy resin layer 2〇' comprising an epoxy tree 曰A and an isocyanate-containing resin B (B) NC-resin) mixed reaction; (4) Add-bridge agent C and the modified epoxy resin layer 2 〇 thoroughly mixed and mixed, coated on a release paper, the bridge I c system is poly benzene:: ( PO丨ypheny丨ene _de, PPS), for baking temperature at room temperature or room temperature to 1 2 A partially reacted modified epoxy resin layer 20 is formed between 0 C. The preferred baking temperature is 85 t. The thickness of the modified epoxy resin layer 20 is between: micrometer and 300 micrometers. 'The thickness can be adjusted according to the product requirements. (4) The modified epoxy resin layer 2〇 and the fiber cloth, the 〇 phase Nie Ren, the two are combined by baking and pressing, the modified epoxy layer 2Q After the reaction of the fractions, the pores of the fiber cloth 1Q are infiltrated and filled in, and the fiber cloth is covered in a wide [Ο] 6 201221343. a, in the outer 恻 of the fiber cloth, a flat 供 供 供 供 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Between 〇t, in the eight, = hot press furnace, the baking temperature is formed in the air blow molding to form the product embryo; and the knife is pressed to 40 minutes, and the baking time is about 〃, The preferred baking temperature is about 135, and the epoxy resin is completely reacted and combined with the epoxy resin in the modified epoxy resin layer 2〇. The composition is similar, so the bonding between the two layers of the epoxy resin in the fiber cloth 10 is very good, and the problem is that the modified epoxy is 0, the adhesion is not, and the main tree layer 20 is The fiber cloth 10 is shaped like a fibrous mask of the surface of the tan. As shown in Figures 3, 4 and 5, the fibrous mask 3 〇 surface hole ^ the invention can be widely used in the production of various product shell surface ^, two open m placed into the cookware in the 'heat Blown air-heating and straightening: The surface of the product's initial embryonic shell, such as various moving parts, body parts or 3C electronic products, the shell and the other. The structure of the initial embryo shell formed by the fibrous mask of 30 kg has a high physical property and a high-strength flat surface. The producer can process and grind in the process of flattening the surface of the subsequent product, thereby improving the overall production efficiency; The composite material of the epoxy resin and the carbon fiber cloth or the glass fiber cloth which is used in the process of the invention has many holes and defects of different sizes on the surface after the processing, and is applied to the surface of the product, and is easy to fall off due to poor adhesion. The phenomenon. As shown in FIG. 4, FIG. 5 and FIG. 6, the processing process of the present invention forms a surface of the initial embryo shell of various products by using a heat transfer film, and is applied to the surface of the outer shell of various moving components, + [S] 201221343 pieces or 3C electronic peripheral products. Such as badminton racket 4 〇, tennis racket, golf clubs and other sports products on the surface, or bicycle body 5 〇, car and other body parts of the shell surface; in addition, the fibrous mask 3 〇 can be directly attached On the surface of the product casing, such as a notebook computer 6 〇 outer casing table 7, a camera or a mobile phone casing surface and other electronic 3C products, the fibrous mask 3 manufactured by the processing method of the invention has high toughness and high strength surface characteristics, and can It can be directly applied to the surface of the product to obtain a flat and beautiful surface. The manufacturer can process and facilitate the subsequent grinding, filling and polishing processes in the process of flattening the surface of the initial embryo surface: improving the overall production efficiency. In addition, the application of artificial synthetic leather can also be applied, and the process of the invention can overcome the air in the PU (p〇|yurethane) system. The bubble problem caused by the sensitive reaction of humidity has improved the production efficiency of the overall fiber mask process. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing a process for processing a fibrous mask of the present invention. Figure 2 is a perspective view of the fibrous mask structure of the present invention. Figure 3 is an appearance view of the present invention applied to the surface of a product. Figure 4 is a schematic illustration of a first preferred embodiment of the present invention. Figure 5 is a schematic illustration of a second preferred embodiment of the present invention. Figure 6 is a schematic illustration of a third preferred embodiment of the present invention. Figure 7 is a perspective view of a composite material for driving. Figure 8 is an appearance view of a conventional composite applied to the surface of a product. [Main component symbol description] [S1 8 201221343 1 〇 fiber cloth 30 fiber mask 50 bicycle car tube 70 composite material Α epoxy resin C bridging agent 20 modified epoxy layer 40 tennis racket 60 notebook computer 71 hole B containing Isocyanate resin

99

Claims (1)

201221343 七、申請專利範圍: =纖維性面膜加工製程’其係包括以下步驟: 準備一纖維布,其係由-環氧樹脂及'纖唯材料混 合反應而成; 取维材衬此 旦氰二1:一改質環氧樹脂層’其係以-環氧樹脂及-含 〆、亂-文孤树脂混合反應而成; r拌(,=:架橋劑於該改質環氧樹脂層中且充分混合201221343 VII. Patent application scope: = fibrous mask processing process 'The system includes the following steps: Prepare a fiber cloth, which is made up of a mixture of epoxy resin and fiber-like material; 1: a modified epoxy resin layer is formed by a mixture of epoxy resin and bismuth-containing chaotic resin; r-mixing (, =: bridging agent in the modified epoxy layer and Fully mixed ^ ^ 八烤皿度介於常溫或室溫至120。匚之間,使該改質 環氧樹脂層經過部份反應; 、 最八⑷心質環氧樹脂層經過部份反應後係與該纖維布 ^ 置。入杈具中並送入熱壓爐中,而烘烤溫度介於140 :至150C之間’進行25分鐘至4〇分鐘的烘烤膜壓吹 氣成型並形成一產品初胚。 、 „ 2·^請專利範圍第1項所述之纖維性面膜加工製 私其中步驟(C)的烘烤溫度為85艽。 〇盆 申咕專利範圍第2項所述之纖維性面膜加工製 乂驟(d) °亥改質環氧樹脂層之的厚度係介於1 〇微 米至300微米之間。 口 士申明專利範圍第3項所述之纖維性面膜加工製 程’其中步騾(d)的烘烤溫度為135。。。 5_如申明專利範圍第4項所述之纖維性面膜加工製 程’其中步驟⑷的供烤時間為3〇分鐘。 0 . . 龙 °明專利範圍第5項所述之纖維性面膜加工製 程其中步驟⑷,該面膜硬度係介於Α50至D90之間。 7.如申凊專利範圍第4、5 6項任一述之 t S] 10 201221343 維性面膜加工製程,其中該產品初胚係為一運動元件。 8.如申請專利範圍第4、5或6項任一項中所述之纖 維性面膜加工製程,其中該產品初胚係為一車體零件。 9 ·如申請專利範圍第4、5或6項任一項中所述之纖 維性面膜加工製程,其中該產品初胚係為一 3C電子產品。 八、圖式.(如次頁)^ ^ Eight baking degrees between room temperature or room temperature to 120. Between the crucibles, the modified epoxy resin layer is partially reacted; and the top (4) core epoxy resin layer is partially reacted with the fiber. It is placed in a cookware and fed into a hot press furnace, and the baking temperature is between 140: and 150 C. The baking film is blown and formed into a product embryo by 25 minutes to 4 minutes. „ 2·^Please request the processing of the fibrous mask as described in item 1 of the patent scope. The baking temperature of the step (C) is 85艽. The processing of the fibrous mask described in the second paragraph of the patent application scope Step (d) ° The thickness of the epoxy modified epoxy resin layer is between 1 〇 micrometer and 300 micrometers. The fiber mask processing process described in the third paragraph of the patent scope of the patent is 'step 骡 (d The baking temperature is 135. 5_ The processing method of the fibrous mask described in the fourth paragraph of the patent scope is as follows: wherein the baking time of the step (4) is 3 minutes. 0 . . The fibrous mask processing process of the present invention comprises the step (4), wherein the hardness of the mask is between Α50 and D90. 7. As described in any of claims 4 and 5 of the patent scope, t S] 10 201221343 dimensional mask The processing process, wherein the product is a moving element. 8. The fibrous mask processing process as described in any one of claims 4, 5 or 6, wherein the product is a car body Parts. 9. Fiber as described in any of claims 4, 5 or 6. The mask processing process, wherein the product is a 3C electronic product. Eight, schema. (such as the next page)
TW99139342A 2010-11-16 2010-11-16 Fibrous mask processing method TW201221343A (en)

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ATE548426T1 (en) * 2001-11-30 2012-03-15 Polyplastics Co FLAME-RESISTANT RESIN COMPOSITION
CN100402617C (en) * 2006-07-12 2008-07-16 山东省科学院新材料研究所 Heat resistant anticorrosive composite polyphenylene sulfide epoxy paint and its prepn
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