201221146 六、發明說明： 本專利申請係主張在2010年1〇月19日申請之曰本 國專利申請第2010-234740號之優先權，在此援用。 【發明所屬之技術領域】 本發明為關於一種含粉末分散液之化妝料，特別是關 於一種含有粉末係均勻分散之分散液且使用感良好的化妝 料。 【先前技術】 以往’係藉由在化妝料中調配粉末，以賦予其從紫外 線保護肌膚、對暗斑及雀斑等之遮蔽、對皮脂之吸收等的 機能。 例如在：抗紫外線化妝料、彩妝用化妝料等領域，已 在使用以無機粉末分散在油中之分散液。此種分散液之調 製方法’係預先用分散機（dispersing machine)及塗料振 盪機（Paint shaker)使在表面經疏水化處理之金屬氧化物 作為主成分之無機粉末分散於含界面活性劑之油分中之方 法製作。 然而，該方法並無法使疏水性之無機粉本在油分中充 刀地均勻分散，因此在使用感方面仍有加以改善之餘地。 此外，在將疏水性之無機粉末均勻地分散在油相中的 分散物之調製方法，係在含界面活性劑之油分中加入疏水 性無機粉末後，以速續式研磨機（OBMiU、DynoMill等）、 批次式研磨機（環輥研磨機（Ring mi 11)等）進行高度分散 化之方法操作。 3 323407 201221146 然而，在此種方法係需要較多之手續，且於使用介質 之特性方面’會有處理量低而不適於大量生產之情形。 另外，由於以珠磨機粉碎時，在磨珠間會有大量料聚 (slurry)殘留，就環境負荷之觀點而言並不佳。 【發明内容】 ° 發明欲解決之課題 2明係有鑑於前述先前技術而成者，其須加以解決 供一種含有分散液之化妝料，該分散液係具有 業性，且使用感良好，而粉末均勻分散在油分中 之分散液。 解決課題之手段 社果對前賴加讀^課題騎精心研究， 現藉由包含經超音波粉碎機將含有特定量之揮發 刀的油分、粉末、分散助劑進行分散之分散液，可得 到作業性優異，且傕用忒俱这夕/以 您刀月文液了付 《用感優異之化妝料’遂完成本發明。 亦P ’本發明之化妝料，其特徵為 機分散T述（a)至⑷之分餘：超日波如碎 其中含相躲油分量為5至⑽質量％之揮發 (b)粉末，〇·1至40質量％ (C)分散助劑，0· 1至10質量％。 ionk:述二料中超音波粉碎機以具有頻率係10至 =，輸出係500至16000W之能力者為佳。 則述化妝料中’⑻以包含賦色材料者為佳。 323407 4 201221146 本發明之油中水型乳化化妝料之特徵，係在前述化妝 料中，（b)包含親水性粉末。 前述油令水型乳化化妝料中，（c)以包含陽離子性界 面活性劑0. 01至1質量％、軟脂酸〇. 〇2至2質量％為隹。 前述油中水型乳化化妝料中，以陽離子性界面活性劑 之調配量/軟脂酸之調配量=〇. 3至1為佳。 本發明之化妝料之製造方法，其特徵為：將（a)含相對 於油分量為5至1〇〇質量％之揮發性油分的油分、於分散液 中為0. 1至40質量％i(b)粉末、及於分散液中為〇. 1至 10質量％之（〇分散助劑以超音波粉碎機分散後，將所得之 分散液與化妝料基材進行混合。 發明之效果 本發明之化妝料，為包含將（a)油分，其中含相對於 油分量為5至100質量％之揮發性油分、（b)粉末〇. i至4〇 質量％、（c)分散助劑〇. 1至1〇質量％以超音波粉碎機進行 分散之分散液的化妝料，藉由含有均勻地分散之分散液， 因此可以提供使用感優異之化妝料。 【實施方式】 發明之實施形態 本發明之化妝料’係包含以超音波粉碎機分散（a)油分， 其中含相對於油分量5至100質量％之揮發性油分、（…粉 末0. 1至40質量％、（c)分散助劑〇· i至10質量％之分散液。 以下’對各成分進行詳細說明。 ((a)含揮發性油分的油分） 5 323407 201221146 (a)油分需含有揮發性八 下呈現揮發性之油分 ;7。揮發性油分為在室溫（25。〇 用。 早獨使用，亦可將2種以上併 揮發性油分之例，可列舉如 基二矽氧烷、十二 ·十甲基四矽氧烷、六甲 環四權、十；基二：：烷等鏈狀聚石夕氧燒;八子基 聚石夕氧油；輕質液❹；環狀聚錢料揮發性 等。 、蠟（Llght ll(iuid iS0paraffin) 織m 發性油分為十？基时氧燒。 揮發性油/刀之調配量，需為分散液中油分總量之5至 _質⑽M5C)至⑽質量％較佳。若在油分總量中之 揮發性油分舰量未達5質量％時，會有無 散力之情形。 刀 揮發(1/由刀以外之油分（非揮發性油分），具體可 =如·：、液體石徵、異石峨、角f、烧（s轉_)、聚丁稀 專.，羊毛知（lan〇Iin)等躐類；蓖麻油、撖欖油、棕櫊 /由椰子油夏咸夷豆油（Macadamianuts Oil)、荷荷巴油 專’由月曰’異硬月曰醇等向級醇；月桂酸、肉豆蔻酸、軟脂酸 等鬲級脂肪酸;甘油醇二異硬脂酸酯、三羥甲基丙烷三-2-乙基異硬丨a Igg、肉豆鐘酸異丙自旨、乙基己酸十六碳烧 酉曰甘/由一異硬脂酸酯、軟脂酸_2_庚基十一破炫酯、三異 更月曰1甘油酉曰截果酸二異硬脂酯（Dns〇stearyi 等i旨油類；二曱基聚珍纽、？基苯基聚魏烧、甲基氮 聚石夕氧烧等鏈狀聚發氧燒；三甲基魏基石夕酸醋 6 323407 201221146 (Trimethylsiloxy silicate);二苯甲酮（Benz〇phenone) 等紫外線吸收劑；純地蠟、卡拿巴蠟（Carnauba wax)、聚 乙烯蠟、石蠟（Paraffin wax)等蝶類等b ((b)粉末） (b)粉末只要為一般可使用在化妝料中之粉末即可， 並無特別之限定。粉末可以單獨使用，亦可以2種以上併 用。 粉末之例，可列舉如：滑石、高嶺土、絹雲母（Sericite)、 白雲母、金雲母、合成雲母、紅雲母、黑雲母、鍛燒滑石 (Burnt talc)、鍛燒絹雲母、鍛燒白雲母、鍛燒金雲母， 蛵石（Vermiculite)、碳酸鎂、碳酸鈣、矽酸鋁、矽酸鋇、 矽酸鈣、矽酸鎂、矽酸鳃、鎢酸金屬鹽、鎂、氧化矽（Silica)、 沸石（Zeolite)、硫酸鋇、鍛燒硫酸鈣（燒石膏（Calcined plaster))、磷酸鈣、氟化磷灰石、氫氧化磷灰石、陶瓷粉、 金屬皂（例如：肉豆蔻酸鋅、軟脂酸鈣、硬脂酸鋁等）、氮 化硼、光色性氧化鈦（氧化鐵經燒結之二氧化鈦）、還原辞 白；有機粉末（例如：聚矽氧彈性物（silic〇neeiastomer) 粉末、聚矽氧（Silicone)粉末、矽樹脂包覆聚矽氧彈性物 粉末、聚醯胺樹脂粉末（尼龍粉末）、聚乙烯粉末、聚甲基 丙烯酸曱酯粉末、聚苯乙烯粉末、苯乙烯與丙烯酸之共聚 物柄'脂粉末、苯並脈胺（Benz〇gUanamine)樹脂粉末、聚四 氟化乙烯粉末、纖維素粉末等）；無機白色顏料（例如：二 氧化鈥、氧化辞等）；無機紅色系顏料（例如：氧化鐵（鐵 丹）、鈦酸鐵等）；無機褐色系顏料（例如：氧化鐵等）； 7 323407 201221146 無機育色系顏料（例如：黃色氧化鐵、黃土等）；無機専色 系顏料（例如：黑色氧化鐵、低氧化鈦等）；無機i色系顏 料(例如.錳紫、鈷紫等）；無機綠色系顏料⑷如：氧化鉻、 氳氧化鉻、鈦酸料）；無機藍色系顏料（例如：群青、普 魯士藍等）；珠光賴（妙··氣氧化、欽雲母、 氧化鐵包覆鈦雲母、低氧化鈦包覆鈦雲母、具光色^欽雲 母；取代雲母而使用滑石、_、合成氟化金雲母、氧: 石夕、氯氧化银等以作為基板者；以低氧化欽、著色氧化欽、 氧化鐵、氧化!S、氧㈣、#、氧化鋅、氧化敍、銘等作 為包覆物而包覆在氧化鈦外者；作為機雜珠光顏料之： 以樹脂粒子包覆於珠光顏料表面者（曰本專利特開平 11-92688)、以氫氧化錄子包覆於珠絲料表面者（日本 專利特開臟-1侧8)、錢氧⑽粒子包覆於珠光顏料 表面者（日本專利特開2〇〇3_261421)、以硫酸鋇粒子包覆 於珠光顏料表面者（日本專利特開2〇〇3_61229)等）；金屬 粉末顏料（例如：鋁粉、銅粉等）；鍅、鋇或鋁色澱等有機 顏料（例如·紅色201號、紅色202號、紅色2〇4號、紅色 205號、紅色220號、紅色226號、紅色228號、紅色405 號、橙色203號、撥色204號、黃色205號、黃色401號、 及藍色404號等有機顏料；紅色3號、紅色1〇4號、紅色 106號、紅色227號、紅色230號、紅色4〇1號、紅色5〇5 號、撥& 205號、黃色4號、黃色.5號、黃& 202號、黃 色203號、綠色3號及藍色1號等）；天然色素（例如：葉 綠素、β _胡蘿蔔素等）等。 323407 201221146 有機系紫外線吸收劑之具體例，可列舉如：2,2’ -羥 基-5-曱基苯基苯并三°坐、2-(2’ 經基-5’ -第三辛基笨基） 苯并三唑、2-(2’ -羥基-5’ -甲基苯基）苯并三唑等之笨并 三0坐系紫外線吸收劑；二苯甲酸肼（Dibenzalazine)、二菌 香醯甲烷、4-第三丁基-4’ -甲氧基二苯曱醯曱烷、卜（4， -異丙基苯基）-3-苯基丙烷-1,3-二酮、5-(3,3’ -二曱基 -2-亞降茨基）-3-戊烷-2-酮等之笨曱醯曱烷系紫外線吸故 劑；對胺苯曱酸（p-aminobenzoic acid ; PABA)、PABA 單 甘油酯、N, N-二丙氧PABA乙酯、N, N-二乙氧PABA乙醋、201221146 VI. INSTRUCTIONS: This patent application claims priority from Japanese Patent Application No. 2010-234740, filed on Jan. 19, 2010. BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic containing a powder dispersion, and more particularly to a cosmetic containing a dispersion which is uniformly dispersed in a powder and having a good feeling in use. [Prior Art] In the past, the powder was formulated in a cosmetic material to impart protection from the ultraviolet rays to the skin, to dark spots and freckles, to absorption of sebum, and the like. For example, in the fields of anti-ultraviolet cosmetics and cosmetics for makeup, a dispersion in which an inorganic powder is dispersed in oil has been used. The method for preparing such a dispersion is to disperse an inorganic powder having a surface-hydrophobized metal oxide as a main component in a surfactant-containing oil in advance by a dispersing machine and a paint shaker. The method of making. However, this method does not allow the hydrophobic inorganic powder to be uniformly dispersed in the oil, so that there is still room for improvement in the feeling of use. Further, in the method of preparing a dispersion in which a hydrophobic inorganic powder is uniformly dispersed in an oil phase, a hydrophobic inorganic powder is added to an oil component containing a surfactant, followed by a quick-grinding mill (OBMiU, DynoMill, etc.) ), batch grinder (Ring mi 11, etc.) is operated in a highly decentralized manner. 3 323407 201221146 However, in this method, more procedures are required, and in terms of the characteristics of the use medium, there is a case where the processing amount is low and it is not suitable for mass production. Further, when pulverized by a bead mill, a large amount of slurry remains between the beads, which is not preferable from the viewpoint of environmental load. SUMMARY OF THE INVENTION The object to be solved by the invention is that, in view of the foregoing prior art, it is necessary to solve the problem of providing a cosmetic containing a dispersion which is practical and has a good feeling of use, and the powder A dispersion that is uniformly dispersed in the oil. Means for Solving the Problem The company has carefully studied the previous study of the subject, and now it is possible to obtain the operation by dispersing a dispersion containing an oil, a powder, and a dispersing aid containing a specific amount of a volatile knife through an ultrasonic pulverizer. The present invention is excellent in the use of the furniture and the use of the sensation of the cosmetics. Also, the cosmetic of the present invention is characterized in that the machine disperses the fractions of (a) to (4): a super-day wave such as a volatilized (b) powder containing 5 to 10% by mass of the oil-repellent component, 〇 1 to 40% by mass (C) dispersing aid, 0.1 to 10% by mass. Ionk: The ultrasonic pulverizer in the second material is preferably one having a frequency system of 10 to = and an output system of 500 to 16,000 watts. In the case of the cosmetic, '(8) is preferably included in the coloring material. 323407 4 201221146 The oil-based emulsified cosmetic of the present invention is characterized in that, in the cosmetic, (b) comprises a hydrophilic powder. In the above oil-in-water-type emulsified cosmetic composition, (c) contains a cationic surfactant of 0.01 to 1% by mass, and strontium palmitate. 〇 2 to 2% by mass is 隹. In the above-mentioned oil-type emulsified cosmetic, it is preferred that the amount of the cationic surfactant is adjusted to the amount of the palmitic acid = 3 to 1. 1至40质量%i。 The oil component of the present invention is 0. 1 to 40% by mass in the dispersion. (b) Powder and 分散. 1 to 10% by mass in the dispersion (The dispersion aid is dispersed in an ultrasonic pulverizer, and the resulting dispersion is mixed with a cosmetic base material. Effect of the Invention The cosmetic material comprises: (a) an oil component containing a volatile oil component of 5 to 100% by mass relative to the oil component, (b) a powder 〇. i to 4 〇 mass%, and (c) a dispersing aid 〇. The cosmetic of the dispersion which is dispersed by the ultrasonic pulverizer in an amount of 1 to 1% by mass contains a dispersion which is uniformly dispersed, and therefore, it is possible to provide a cosmetic having excellent feeling of use. The cosmetic material comprises: dispersing (a) an oil component in an ultrasonic pulverizer, wherein the volatile oil component is contained in an amount of from 5 to 100% by mass based on the oil component, (...a powder of 0.1 to 40% by mass, (c) a dispersing aid 〇· i to 10% by mass of the dispersion. The following 'details each component (a) Oils containing volatile oils 5 323407 201221146 (a) Oils should contain volatile oils that are volatile under eight; 7. Volatile oils are classified at room temperature (25. As an example, two or more kinds of volatile oils may be used, and examples thereof include a chain such as a bis-dioxane, a tetradecyltetraoxane, a hexamethylcyclotetradecene or a decyl group;聚石夕氧烧; 八子基聚石夕氧油; light liquid ❹; ring-shaped money volatility, etc., wax (Llght ll (iuid iS0paraffin) woven m hair oil is divided into ten-base oxygen burning. The blending amount of the volatile oil/knife is preferably 5 to _ mass (10) M5C) to (10) mass% of the total amount of the oil in the dispersion. If the amount of the volatile oil in the total amount of the oil is less than 5% by mass, There will be no situation of scatter. Knife volatilization (1/ oil other than knife (non-volatile oil), specifically = such as:, liquid stone sign, different stone 峨, angle f, burning (s turn _), poly Ding special., wool know (lan〇Iin) and other cockroaches; castor oil, eucalyptus oil, palm 櫊 / from coconut oil, glutinous soybean oil (Macadamianuts Oil), jojoba oil Specialized in 'classic alcohol', such as sulphuric acid, sulphuric acid, myristic acid, palmitic acid, etc.; glycerol diisostearate, trimethylolpropane, tris-2-ethyl Iso-hard 丨a Igg, meso-isobutyl citrate, ethylhexanoic acid hexacarbocyanine / from iso-stearate, palmitic acid _2_heptyl eleven Three different stagnation 酉曰1 glycerol guanidine diacetate diisostearyl ester (Dns〇stearyi et al. oils; diterpene polyphosphate, phenyl phenyl poly Wei, methyl nitrogen polysulfide, etc. Chain polyoxymethane; Trimethylsilyl vinegar 6 323407 201221146 (Trimethylsiloxy silicate); benzophenone (Benz phenone) and other UV absorbers; pure ceresin, Carnauba wax, b ((b) powder) such as a butterfly such as a polyethylene wax or a paraffin wax (b) The powder is not particularly limited as long as it is a powder which can be generally used in a cosmetic. The powder may be used singly or in combination of two or more. Examples of the powder include talc, kaolin, sericite, muscovite, phlogopite, synthetic mica, red mica, biotite, burnt talc, calcined sericite, and calcined muscovite. , calcined phlogopite, vermiculite, magnesium carbonate, calcium carbonate, aluminum citrate, barium strontium citrate, calcium citrate, magnesium citrate, barium strontium citrate, metal tungstate, magnesium, cerium oxide (Silica) , Zeolite, barium sulfate, calcined calcium sulfate (calccined plaster), calcium phosphate, fluorinated apatite, hydroxyapatite, ceramic powder, metal soap (eg zinc zinc myrate, Calcium palmitate, aluminum stearate, etc.), boron nitride, photochromic titanium oxide (iron oxide sintered titanium dioxide), reduction whitening; organic powder (for example: silic 〇neeiastomer powder) , Silicone powder, silicone resin coated polyoxyxide powder, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, styrene and Acrylic copolymer handle 'fat powder Benzoguanamine (Benz 〇gUanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (for example: cerium oxide, oxidation, etc.); inorganic red pigment (for example: iron oxide ( Iron oxide), iron titanate, etc.; inorganic brown pigments (eg iron oxide, etc.); 7 323407 201221146 Inorganic coloring pigments (eg yellow iron oxide, loess, etc.); inorganic ochre pigments (eg black Iron oxide, titanium oxide, etc.; inorganic i color pigments (eg, manganese violet, cobalt violet, etc.); inorganic green pigments (4) such as: chromium oxide, chromium oxide, titanate); inorganic blue pigments ( For example: ultramarine, Prussian blue, etc.; Pearl Light Lai (Miao··Gas Oxidation, Chin Mica, Iron Oxide Coated Titanium Mica, Titanium Oxide Coated Titanium Mica, Light Color^Qin Mica; Using Mica instead of Mica, _ Synthesis of fluorinated gold mica, oxygen: Shixi, silver oxychloride, etc. as a substrate; low oxidation, coloring oxidation, iron oxide, oxidation! S, oxygen (four), #, zinc oxide, oxidation, Ming, etc. Wrapped as a wrap In addition to titanium oxide; as a machine-like pearlescent pigment: a resin particle coated on the surface of a pearlescent pigment (Japanese Patent Laid-Open No. 11-92688), coated with a hydroxide precursor on the surface of the bead material (Japanese patent) Specially opened dirty side - 8), carbon oxide (10) particles coated on the surface of pearlescent pigments (Japanese Patent Laid-Open No. 2〇〇3_261421), coated with barium sulfate particles on the surface of pearlescent pigments (Japanese Patent Laid-Open 2) 3_61229), etc.; metal powder pigments (for example: aluminum powder, copper powder, etc.); organic pigments such as ruthenium, osmium or aluminum lake (for example, red 201, red 202, red 2 〇 4, red 205, Organic pigments such as red 220, red 226, red 228, red 405, orange 203, dial 204, yellow 205, yellow 401, and blue 404; red 3, red 1〇4 No., red 106, red 227, red 230, red 4〇1, red 5〇5, dial & 205, yellow 4, yellow. 5, yellow & 202, yellow 203 , green 3, blue 1 and so on); natural pigments (eg chlorophyll, β-carotene, etc.)323407 201221146 Specific examples of the organic ultraviolet absorber include, for example, 2,2'-hydroxy-5-nonylphenylbenzotriene, 2-(2'-based-5'-third octyl Base) benzotriazole, 2-(2'-hydroxy-5'-methylphenyl)benzotriazole, etc., stupid and triad UV absorber; dibenzalazine, diquat Methane, 4-tert-butyl-4'-methoxydiphenyl decane, Bu (4,-isopropylphenyl)-3-phenylpropane-1,3-dione, 5- (3,3'-dimercapto-2-arylene)-3-pentan-2-one and the like of the phenanthrene-based ultraviolet light absorber; p-aminobenzoic acid (p-aminobenzoic acid; PABA), PABA monoglyceride, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl vinegar,
N, N-二甲 PABA 乙酯、N, N-二甲 PABA 丁酯、N, N-二曱 PABA 曱酯等之苯曱酸系紫外線吸收劑；升蓋基乙醯鄰胺笨甲 酸（Homomenthy 卜 N-Acety lanthrani late)等胺鄰胺笨甲酸 系紫外線吸收劑；水楊酸戊酯、水揚酸蓋酯、水楊酸升著 酯、水揚酸辛酯、水楊酸苯酯、水楊酸笨甲酯、對異丙醇 水揚酸苯基酯等水楊酸系紫外線吸收劑；甲氧桂皮酸辛 (Octyl methoxycinnamate)、二對曱氧桂皮酸—單 乙夷 己酸甘油酯、桂皮酸辛酯、4~異丙基桂皮酸乙酯、2 5 _ 異丙基桂皮酸甲酯、2, 4-二異丙基桂皮酸乙g旨、2,4—二異 丙基桂皮酸曱酯、對曱氧桂皮酸丙酯、對甲氧桂皮酸異 酯、對甲氧桂皮酸異戊酯、對曱氧桂皮酸辛酯（對甲氧桂皮 酸-2-乙基己酯）、對甲氧桂皮酸-2-乙氧乙酯、對甲氧桂皮 酸環己酯、α -氰基-冷-苯基桂皮酸乙酯、^y | 基桂皮酸-2-乙基己酯、甘油醇單-2-乙己醯〜二對甲氧桂皮 酸酯等桂皮酸系紫外線吸收劑；3, 4, 5-三甲氧桂皮酸[3 323407 9 201221146 雙（三甲矽氧）甲矽4-曱丙基]酯、3, 4, 5-三曱氧桂皮酸-[3_雙（三甲矽氧）曱矽-3-甲丙基]酯、3, 4, 5-三曱氧桂皮酸 -[3-雙（三甲矽氧）曱矽丙基]酯、3, 4, 5-三曱氧桂皮酸-[3-雙（三甲矽氧）曱矽丁基]酯、3, 4, 5-三曱氧桂皮酸-[3-參 (三曱石夕氣）矽丁基]酯、3, 4-二曱氧桂皮酸-[3-參（三曱碎 氧）石夕-1〜甲丙基;|酯等之聚矽氧系桂皮酸紫外線吸收劑；其 他如3〜（4，-曱基苯亞甲基）-d，1-樟腦、3-苯亞甲基-d，1-樟腦、尿刊酸（Urocaninic acid)、尿刊酸乙酯、2-苯基-5-甲基笨并嚶唑、5-(3, 3’ -二曱-2-亞降茨啶）-3-戊烷-2-酮、聚矽氧改質紫外線吸收劑；含氟改質紫外線吸收劑等。 粉末可使用表面未經處理之物種，但亦可使用經聚石夕 氧或氟化合物、矽烧偶合劑、鐵弗龍（註冊商標）、脂肪酸、 脂肪酸皂、月桂醯離胺酸（Lauroyl lysine)等施予表面處 理者。 此外，分散液中之（b)粉末，因藉由調配著色料而可 顯著地呈現本發明之效果，故為有效。 在以往，將含著色料之化妝料進行調色時，在製造成 既定之顏色時之分散時間及分散次數係因機械而難以控 制。然而，使用本發明之超音波粉碎機所得之化妝料，其 效率比以往使用分散機進行製造而得到化妝料者佳，因此 自分散開始至平穩（PIateau)狀態為止所需之時間較短。故 本發明具有調色容易之優點。 此外，在以往之分散機方面，當調配粉末時，若不進 行原料之預攪拌/預粉碎，則會有無法改善凝集，而難以直 10 323407 201221146 接由原料得到分散液之情形。因此，在調配著色料之情形 •下會發生隨時間色調改變、明亮度降低之情形。然而，本 - 發明即使不進行預攪拌/預粉碎亦可得到均勻之分散液，且 即使調配著色料，亦可得到不發生隨時間色調改變的化妝 料。 又’（b)粉末之調配量，需為分散液總量之〇. 1至4〇 質量％。且以1至20質量％為更佳。粉末之調配量在未達 〇· 1質量％時，分散液之效果會不足。此外，在高於4〇質 星/時’會有分散液之黏度上升而無法得到充分的分散力之 情形 (&)分散助劑） (c)分散助劑只要為可溶於油分之者即可，並無特別 之限定。此外，分散助劑可以單獨使用，亦可將2種以上 併用。 ^分散助劑之例，可列舉如：聚氧伸乙基烷基醚、山梨 醇酐脂肪酸酯、聚氧伸乙基烷基磷酸酯、脂肪酸烷醇醯月安、 聚喊改質聚石夕氧油、聚石夕氧樹脂、兩末端石夕氧化聚甘、 專。 該等之中，較佳之分散助劑可列舉如山梨醇酐 西旨、兩末端矽氧化聚甘油醇。 文 (C)分散助劑之調配量，需為分散液總量中之〇 · ^至 、〇貝量/。。以1至8質量％較佳。分散助齊1之調配量 達〇. 1質量/〇時會無法發揮調配之效果。此外，即使高於 10質量亦不見得其效果能顯著地增加。 、 323407 11 201221146 本發月之77散液係藉由在（a)油分中加入（b)粉末與（c) 刀散助劑’且使帛超音波粉碎機進行分散處理而得到。 此外’在分散處理前，亦可使用分散機及均質混合 等進行預攪拌。 超音波粉碎機之功能雖無特別限定，惟以使用具有頻 率1〇至1〇〇kHz、輸出500至16000W的功能之超音波粉碎 機為佳。特別以使用具有輸出500至5000W的功能之超音 波粉碎機為更佳。若其功能過小，則會有隨時間發生色調 改變明免度降低之情形。此外，即使其功能為過大，亦 不見得效果能有顯著之提升，因此為不佳。 此外’本發明之化妝料中所含的分散液之黏度，以 2000cps以下為佳。若黏度高於2〇〇〇cps，則會有無法獲得 充分之分散力的情形。 本發明之化妝料中，除上述必需成分之分散液以外， 係依照須要而適當調配可用於一般化妝料之其他成分，例 如：粉末成分、液體油脂、固體油脂、蠟、烴、高級脂肪 酸、尚級醇、酯、聚矽氧、陰離子界面活性劑、陽離子界 面活性劑、兩性界面活性劑、非離子界面活性劑、保濕劑、 水溶性高分子、增黏劑、成膜劑、紫外線吸收劑、金屬離 子螯合劑、低級醇、多元醇、糖、胺基酸、有機胺、高分 子礼液、pH調整劑、皮膚營養劑、維生素、抗氧化劑、抗 氧化助劑、香料等’且依照财方法進行製造而得到。 本發明之化妝料可為任意之劑型，可以乳化系、水一 油一層系、凝膠、氣溶膠（Aer〇s〇l)、霧狀、及膠囊等任意 12 323407 201221146 形態提供。 例如分散液可以直接或以油性成分加以稀釋成為油 性化妝料。此外’亦可將該等與水相成分藉由〆般已知之 方法進行乳化處理而成為乳化化妝料。 本發明之化妝料，以分散液中含親水性粉末之油中水 型乳化化妝料為佳。 、以往之操作，要將親水性粉末能安定地調配在油相中 並不容易。亦即，以均質混合機等分散能力弱之分散機， 會有無法得到安定而均勻的油相（分散液）之情形。此外， 使用珠磨機等時，特別是在粉末濃度低之系及揮發性油分 多之系中，並不易進行分散，而會有無法得到均勻之油相 (分散液）的情形。 然而’依照本發明即可得到安定而均勻之油相（分散 液），因此可得到無色調改變，而易於塗抹等使用感方面優 異之油中水型乳化化妝料。 在調製調配有含親水性粉末之分散液的油中水梨乳 化级成物時’較佳係在分散液中，復包含分散液總量中之 0.01至1質量％的陽離子界面活性劑’以及分散液總量中 之〇· 02至2質量％的軟脂酸，以作為（c)分散助劑。藉由調 配陽離子界面活性劑及軟脂酸，可得到更為均勻之分散液。 相對於軟脂酸之調配量的陽離子界面活性劑之比例， 亦即陽離子界面活性劑之調配量/軟脂酸之調配量，係以 0· 3至1為特佳。 陽離子界面活性劑之例，可列舉如：硬脂基三曱基氯 13 323407 201221146 化銨、十六基三曱基氣化銨、十四基三曱基氣化銨、月桂 基二曱基氣化銨、C12單羥烷基醚陽離子、二羥烷基醚陽 離子、二羥烷基醚陽離子、椰子油二醯胺丙基陽離子、椰 子油二羧乙基陽離子、C16二羧乙基陽離子、C18二羧乙基 陽離子、P0P(15)二乙甲基陽離子、P0P(25)二乙甲基陽離 子、POP(40)二乙甲基陽離子、α2二醯胺丙曱胺、二 醯胺丙曱胺、C16二醯胺丙甲胺、C18二醯胺丙曱胺、異C18 二醯胺丙曱胺、二C18丙二曱基陽離子、羥丙基-雙-月桂 基陽離子、羥丙基-雙_硬脂基陽離子、羥丙基_雙_月桂基 酿胺陽離子、羥丙基-雙_硬脂基醯胺陽離子、C18單羥烷 基喊陽離子、雙-C18羥烷基醚陽離子、溴化C22三曱基銨、 C22丙一曱胺、季銨鹽-91(Quaternium-91)、C22三曱基硫 k 甲酿録（C22tri methyl ammonium methosulfate)、二可可 醯胺基乙基乙羥基陽離子、二C18醯胺基乙基乙羥基陽離 子、二C16醯胺基乙基乙羥基陽離子、二C18二甲基銨鹽、 C18二甲基苯曱銨鹽、全氟三甲基銨鹽、二醯基醯胺基乙 基乙羥基陽離子等。 該等之中，以硬脂基三曱基氣化銨較佳。 此外，本發明之化妝料可廣泛適用在以往適用於外皮 的之化妝料。例如：美容液、乳液、乳霜、貼敷劑、粉底、 口紅、眼影、眼線筆、睫毛膏、潔顏劑、防B麗乳霜、喷霧 劑、泡沫劑、潤絲精、洗髮精等。 實施例 以下列舉實施例以更詳細地說明本發明，惟本發明並 323407 14 201221146 * 不受此限定。其中之調配量除非特別載明，係表示相對於 所調配之系中該成分的質量％。 於說明實施例之前，首先加以說明用於本發明的試驗 之評估方法。 評估（1):分散性 以刮刀（doctor blade)將分散液（料漿）調整成膜厚 0. 137mm並乾燥15分鐘，之後確認分散液之狀態。 A*:目視下完全無粉體凝集物。 A:目視下近乎無粉體凝集物。 B:目視下稍有粉體凝集物。 C:目視下有相當程度的粉體凝集物。 評估（2):作業性 對分散機之作業性（使用時之手續）加以評估。 A:作業性良好。 B :無法評定。 C:作業性不佳。 評估（3):使用感 由專業品評人10名，對試樣之使用感（容易塗抹度及 滑順度）加以評估。又，評估係以均質混合機處理品為基準 試樣進行。 A* :有9名以上回答為使用感比基準試樣佳。 A :有5名以上未達9名回答為使用感比基準試樣佳。 B:未達5名回答為使用感比基準試樣佳。 評估（4):分散液（料漿）損失率 15 323407 201221146 測定所調配原料在分散機内發生了多少損失。又，測 定係操作5次。 評估（5):色差 對試樣在出料時之顏色、塗布狀態之顏色的色差，以 为光測色機CM-2600d型（Konica-Minolta公司製造）進行 測定。 出料時之顏色，係以3〇mm蓋玻片夾住測定。塗布顏 色，係對在人工皮膚（phantom skin)上塗布為2mg/cm2且 經自然乾燥15分鐘者進行測定。 首先，本發明人等對所使用之分散機種類加以變化， 而藉由下述製造方法，進行製造其調配組成係如下述表i 所示之試樣。又，在本化妝料中，相對於分散液中之油分’ 揮發性油分之比例為51質量％。 之後依照上述評分基準，以評估項目（丨）至（4)對各試 樣進行評估。又’分散機係使用均質混合機（pRIMn公司 製造’ 9000rpm’ 2分鐘）、珠磨機（vma__GETZMANn公司製造， 5000 rpmd>0.5,輸出15〇〇w，3〇分鐘）、超音波粉碎機 UIP1000(Dr. Hielscher 公司製造，輸出 i〇〇〇w，2 分鐘）。 其結果如表2所示。 化妝料（油中水型乳化粉底）製造方法 使用各種分散機，將（a)油分、（b)粉末、（c)分散助 劑調製成分散液。之後，以償常方法進行製造將所得之分 散液作為油相成分之油中水型乳化粉底。 16 323407 201221146 【表1】 二甲基聚矽氧烷 13 (丙烯酸酯類/甲基丙烯酸聚三甲矽 氧）共聚物 1.5 (a)油分 琥珀酸-二-2-乙基己酯 4 二甲矽氧烷-甲基（聚氧伸乙基)矽氧 烷共聚物 2 二甘油醇二異硬脂酸酯 t 甲氧桂皮酸辛酯 4 辛矽基化處理顏料級鈦 10 (b)粉末 聚矽氧處理鐵丹 1.4 聚矽氧處理黃色氧化鐵 0.45 S矽氧處理黑色氧化鐵 0.04 (c)分散助劑 月桂基PEG-9聚二甲矽氧乙二甲基聚 矽氧烷 2 二甲二硬脂基銨改質水輝石 0.5 硬脂酸處理金紅石型氧化鈦 5 球狀尼龍粉 5 球狀氡化矽 0.1 香料 0.04 離子交換水 39.248 乙醇 5 苯氧基乙醇 0.5 代納邁甘油（dynamiteglycerol) 5 乙二胺四乙酸三鈉 0.2 乙醯化玻尿酸 0.001 玫瑰萃取液 0.01 射干萃取液 0.01 硫代牛磺酸 0,001 17 323407 201221146 【表2】 均質混ϋ幾T ?失麼機 β_ r~ A C ~~ A 〇(批次式)10至40Benzoic acid-based ultraviolet absorbers such as N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-di-p-PABA decyl ester; literate acetophenone o-formic acid (Homomenthy) N-Acety lanthrani late) and other amine o-amine benzalic acid UV absorbers; amyl salicylate, salicylic acid capric acid, salicylic acid, octyl salicylate, phenyl salicylate, salicylate Salicylic acid-based ultraviolet absorbers such as acid methyl ester and isopropyl alcohol phenyl salicylate; Octyl methoxycinnamate, di-p-oxo-cinnamic acid-monoethylhexanoic acid, cinnamic acid octyl Ester, ethyl 4-isopropyl cinnamate, methyl 5% isopropyl cinnamate, ethylene glycol 2, 4-diisopropyl cinnamic acid, decyl 2,4-diisopropyl cinnamate Propyl propyl cinnamate, iso-methoxy cinnamic acid, isoamyl p-methoxycinnamate, octyl p-oxycitrate (2-ethylhexyl methoxycinnamate), p-methoxy cinnabar Acid-2-ethoxyethyl ester, cyclohexyl methoxycinnamate, α-cyano-cold-phenyl cinnamate ethyl ester, ^y | cinnamic acid 2-ethylhexyl ester, glycerol mono- 2-Ethyl hydrazine~Two pairs of methoxy Cinnamite-based ultraviolet absorber such as benzoate; 3, 4, 5-trimethoxy cinnamic acid [3 323407 9 201221146 bis(trimethyl oxime) formazan 4-mercaptopropyl] ester, 3, 4, 5-triazole Oxycitramic acid-[3_bis(trimethyloxonium)indole-3-methylpropyl]ester, 3,4,5-trisyloxycinnamic acid-[3-bis(trimethylsulfonium)pyranyl] Ester, 3, 4, 5-trioxonium cinnamic acid-[3-bis(trimethyloxonium) decyl butyl] ester, 3, 4, 5-trioxo cinnamic acid-[3-para (triterpene) Xiqi) butyl butyl ester, 3, 4-dioxa cinnamic acid-[3-para (triterpene oxyhydrochloride) shixi-1~methylpropyl; | esters and other polyoxy cinnamic acid ultraviolet absorption Others such as 3~(4,-mercaptobenzylidene)-d, 1-camphor, 3-benzylidene-d, 1-camphor, Urocaninic acid, ethyl urate , 2-phenyl-5-methyl benzoxazole, 5-(3, 3'-dioxa-2-yenzyl)-3-pentan-2-one, polyfluorene-modified UV absorption Agent; fluorine-modified UV absorber and the like. The powder may be used as a surface untreated species, but may also be used in the presence of a polysulfide or a fluorine compound, a terpene coupling agent, Teflon (registered trademark), a fatty acid, a fatty acid soap, and a lauroyl lysine. Wait for the surface treatment. Further, the (b) powder in the dispersion is effective because the effect of the present invention can be remarkably exhibited by blending a coloring material. In the past, when the cosmetic containing the coloring material was toned, the dispersion time and the number of dispersions in the production of a predetermined color were difficult to control due to the machine. However, the cosmetic obtained by using the ultrasonic pulverizer of the present invention is more efficient than the conventional one obtained by using a dispersing machine to obtain a cosmetic, and therefore the time required from the start of dispersion to the state of PIateau is short. Therefore, the present invention has the advantage of easy coloring. Further, in the case of the conventional dispersing machine, when the powder is blended, if the pre-stirring/pre-pulverizing of the raw material is not carried out, the agglomeration cannot be improved, and it is difficult to obtain a dispersion from the raw material. Therefore, in the case of blending the coloring material, the color tone changes with time and the brightness decreases. However, the present invention can obtain a uniform dispersion even without pre-stirring/pre-pulverization, and even if the coloring material is blended, a cosmetic which does not undergo a change in color tone over time can be obtained. Further, the amount of the powder (b) is required to be the total amount of the dispersion. 1 to 4% by mass. It is more preferably from 1 to 20% by mass. When the amount of the powder is less than 〇·1% by mass, the effect of the dispersion may be insufficient. In addition, when the viscosity is higher than 4 enamel stars, there is a case where the viscosity of the dispersion rises and sufficient dispersibility cannot be obtained (&) dispersing aid) (c) the dispersing aid is only those which are soluble in oil Yes, there is no particular limitation. Further, the dispersing aid may be used singly or in combination of two or more. Examples of the dispersing aid include, for example, polyoxyethylene ethyl ether, sorbitan fatty acid ester, polyoxyalkylene ethyl phosphate, fatty acid alkanol, and polystyrene. Xi Oxygen Oil, Ju Shi Xi Oxy Resin, and the two ends of the Shi Xi Oxidation Polyglycan, special. Among these, preferred dispersing aids include, for example, sorbitan and bismuth oxidized polyglycerol at both ends. (C) The amount of dispersing aid should be 〇 · ^ to , the amount of mussels / in the total amount of the dispersion. . It is preferably from 1 to 8 mass%. Distributing the amount of assisted Qi 1 Daxie. 1 mass / 〇 will not be able to play the effect of the deployment. In addition, even if it is higher than 10 masses, the effect is not significantly increased. 323407 11 201221146 The 77th liquid dispersion of this month is obtained by adding (b) powder and (c) knife dispersing aid to (a) oil component and dispersing the krypton ultrasonic pulverizer. Further, pre-stirring may be carried out using a dispersing machine and homomixing before the dispersion treatment. The function of the ultrasonic pulverizer is not particularly limited, but an ultrasonic pulverizer having a function of a frequency of 1 〇 to 1 〇〇 kHz and an output of 500 to 16,000 W is preferably used. It is particularly preferable to use an ultrasonic pulverizer having a function of outputting 500 to 5000 W. If the function is too small, there will be a case where the tone change is reduced over time. In addition, even if the function is too large, there is no significant improvement in the effect, so it is not good. Further, the viscosity of the dispersion contained in the cosmetic of the present invention is preferably 2,000 cps or less. If the viscosity is higher than 2 〇〇〇 cps, there is a case where sufficient dispersibility cannot be obtained. In the cosmetic of the present invention, in addition to the dispersion of the above-mentioned essential components, other components which can be used for general cosmetics, such as powder components, liquid fats, solid fats, waxes, hydrocarbons, higher fatty acids, and Alcohol, ester, polyfluorene oxide, anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, humectant, water soluble polymer, tackifier, film former, UV absorber, Metal ion chelating agent, lower alcohol, polyol, sugar, amino acid, organic amine, polymer liquid, pH adjuster, skin nutrient, vitamin, antioxidant, antioxidant, perfume, etc. It is obtained by manufacturing. The cosmetic of the present invention may be in any dosage form, and may be provided in the form of an emulsified system, a water-oil layer, a gel, an aerosol (Aer〇s〇l), a mist, and a capsule. For example, the dispersion may be diluted directly or as an oily component into an oily cosmetic. Further, the aqueous phase components may be emulsified by a method known in the art to form an emulsified cosmetic. The cosmetic of the present invention is preferably a water-based emulsified cosmetic in an oil containing a hydrophilic powder in the dispersion. In the past, it was not easy to stably hydrophilize the hydrophilic powder in the oil phase. In other words, in the case of a dispersing machine having a weak dispersing ability such as a homomixer, there is a case where a stable and uniform oil phase (dispersion liquid) cannot be obtained. Further, when a bead mill or the like is used, particularly in a system having a low powder concentration and a large amount of volatile oil, dispersion is difficult, and a uniform oil phase (dispersion liquid) may not be obtained. However, according to the present invention, a stable and uniform oil phase (dispersion liquid) can be obtained, so that a water-based emulsified cosmetic which is excellent in the feeling of use such as easy to apply and which is easy to apply can be obtained. When modulating the pear emulsified grade in the oil containing the dispersion containing the hydrophilic powder, it is preferably in the dispersion, and comprises 0.01 to 1% by mass of the cationic surfactant in the total amount of the dispersion' and dispersion In the total amount of the liquid, 02 to 2% by mass of palmitic acid is used as the (c) dispersing aid. By formulating a cationic surfactant and palmitic acid, a more uniform dispersion can be obtained. The ratio of the cationic surfactant to the amount of the palmitic acid, that is, the amount of the cationic surfactant/the amount of the palmitic acid, is particularly preferably from 0.3 to 1. Examples of the cationic surfactant include, for example, stearyl tridecyl chloride 13 323407 201221146 ammonium hydride, hexadecyl tridecyl ammonium hydride, tetradecyl tridecyl ammonium hydride, lauryl dihydrazide gas Ammonium, C12 monohydroxyalkyl ether cation, dihydroxyalkyl ether cation, dihydroxyalkyl ether cation, coconut oil diamidopropyl cation, coconut oil dicarboxyethyl cation, C16 dicarboxyethyl cation, C18 Dicarboxyethyl cation, POL (15) diethylethyl cation, POL (25) diethyl cation, POP (40) diethyl cation, α 2 dimethylamine propylene amide, dimethyl hydrazide , C16 diammonium propylamine, C18 decylamine propylamine, iso-C18 diamine propylamine, di-C18 propanediyl cation, hydroxypropyl-bis-lauryl cation, hydroxypropyl-double _ Stearyl cation, hydroxypropyl _ bis-lauryl amide cation, hydroxypropyl-bis-stearyl guanamine cation, C18 monohydroxyalkyl cation, bis-C18 hydroxyalkyl ether cation, brominated C22 Trimethylammonium, C22 propanamine, quaternium-91, C22 trimethyl ammonium methosulfate ), dicocoylaminoethyl hydroxy cation, di-C18 guanylaminoethyl hydroxy cation, di-C16 guanylaminoethyl hydroxy cation, di-C18 dimethylammonium salt, C18 dimethyl benzoate a salt, a perfluorotrimethylammonium salt, a dimercaptodecylaminoethylhydroxy cation or the like. Among these, it is preferred to use a stearyl tridecyl vaporized ammonium. Further, the cosmetic of the present invention can be widely applied to cosmetics which have been conventionally applied to the outer skin. For example: beauty lotion, lotion, cream, patch, foundation, lipstick, eye shadow, eyeliner, mascara, cleansing agent, anti-Breeze cream, spray, foaming agent, moisturizing essence, shampoo Wait. EXAMPLES Hereinafter, the present invention will be described in more detail by way of examples, but the present invention and 323407 14 201221146* are not limited thereto. The amount of the formulation, unless specifically stated, indicates the mass % of the component relative to the formulated system. Before explaining the examples, the evaluation method for the test of the present invention will be first described. Evaluation (1): Dispersibility The dispersion (slurry) was adjusted to a film thickness of 0.17 mm with a doctor blade and dried for 15 minutes, after which the state of the dispersion was confirmed. A*: Completely powder-free agglomerates under visual conditions. A: Nearly powder-free agglomerates are visually observed. B: There is slight powder agglutination under visual observation. C: There is a considerable degree of powder agglutination under visual observation. Evaluation (2): Workability The workability of the disperser (procedure at the time of use) is evaluated. A: Good workability. B: Unable to assess. C: Poor workability. Evaluation (3): Sense of use 10 professional evaluators were used to evaluate the feeling of use of the sample (easy smearing and smoothness). Further, the evaluation was carried out using a sample of a homomixer as a reference sample. A*: There are 9 or more people who answered that the feeling of use is better than the reference sample. A: There are 5 or more people who do not reach 9 and the answer is better than the reference sample. B: The answer to the five questions is better than the reference sample. Evaluation (4): Dispersion (slurry) loss rate 15 323407 201221146 Determine how much loss occurs in the disperser. Also, the measurement system was operated 5 times. Evaluation (5): Color difference The color difference of the color of the sample at the time of discharge and the color of the coating state was measured by a photochromic machine CM-2600d type (manufactured by Konica-Minolta Co., Ltd.). The color at the time of discharge was measured by sandwiching a 3 mm mm cover glass. The coating color was measured by coating on a phantom skin at 2 mg/cm2 and naturally drying for 15 minutes. First, the inventors of the present invention changed the type of the dispersing machine to be used, and manufactured a sample having the composition shown in the following Table i by the following production method. Further, in the present cosmetic composition, the ratio of the volatile oil component to the oil in the dispersion was 51% by mass. Each sample is then evaluated in accordance with the above-mentioned scoring criteria by evaluation items (丨) to (4). Further, the dispersing machine used a homomixer ("9000 rpm" manufactured by pRIMn Co., Ltd. for 2 minutes), a bead mill (manufactured by vma__GETZMANn, 5000 rpmd > 0.5, output 15 〇〇 w, 3 〇 minutes), and ultrasonic pulverizer UIP1000 ( Manufactured by Dr. Hielscher, output i〇〇〇w, 2 minutes). The results are shown in Table 2. Method for producing a cosmetic (water-based emulsified foundation for oil) Using a disperser, (a) an oil component, (b) a powder, and (c) a dispersion aid are prepared into a dispersion. Thereafter, the obtained dispersion liquid was used as an oil-based emulsified foundation in an oil phase component by a replenishing method. 16 323407 201221146 [Table 1] Dimethyl polyoxane 13 (Acrylate / polytrimethylene methacrylate) copolymer 1.5 (a) Oil succinic acid - di-2-ethylhexyl ester 4 dimethyl hydrazine Oxyalkyl-methyl (polyoxyethylidene) alkane copolymer 2 diglycerol diisostearate t octyl methoxycinnamate 4 octylation treatment pigment grade titanium 10 (b) powder polyoxyl Treatment of iron Dan 1.4 polyfluorene treatment yellow iron oxide 0.45 S 矽 oxygen treatment black iron oxide 0.04 (c) dispersion aid lauryl PEG-9 polydimethyl oxime dimethyl dimethyl phthalate 2 dimethyl distear Alkyl ammonium modified hectorite 0.5 Stearic acid treated rutile titanium oxide 5 spherical nylon powder 5 spherical bismuth oxide 0.1 perfume 0.04 ion exchange water 39.248 ethanol 5 phenoxyethanol 0.5 dynamiteglycerol 5 B Trisodium diamine tetraacetate 0.2 Ethyl hyaluronic acid 0.001 Rose extract 0.01 Dry extract 0.01 Thiosulfuric acid 0,001 17 323407 201221146 [Table 2] Homogeneous mixing several T? Loss machine β_ r~ AC ~~ A 〇 (batch type) 10 to 40
評估（1):分散性 評估（2):作業性 _評估（3):使用感 評估（4):損失率（％) 由表2可知，以往使用均質混合機時，雖然其作業性 良好，但可觀察到分散液中存在凝集，同時可觀察到顏色 集中之情形。而且含該種分散液之化妝料於使用感方面亦 無法令人滿意。 在使用球磨機時，並無分散液凝集，所得之化妝料使 用感亦良好。然而’由於係使用磨珠，故作業性為不佳。 另一方面，在使用超音波粉碎機時，不僅作業性良 讀性亦佳，所得之化妝料的㈣—«， 儿具有透明感。 其次 ，奉發明人等藉由上述製造方法，、〜， 配組成係如下絲3所*(分㈣及分散進仃製造其調 之試樣（油中水型乳化粉底）。又，本化妝料與表2相同） 散液中之油分，揮發性油分之比例為69.3 相對於分 之後，依照上述評分基準以評估項目。 對各試樣進行評估。其結果如表4所示。至（3)、（5)Evaluation (1): Dispersibility evaluation (2): Workability_Evaluation (3): Evaluation of use feeling (4): Loss rate (%) As can be seen from Table 2, although the workability was good in the past when using a homomixer, However, agglomeration was observed in the dispersion, and color concentration was observed. Moreover, the cosmetic containing such a dispersion is also unsatisfactory in terms of use. When the ball mill was used, there was no agglomeration of the dispersion, and the resulting cosmetic had a good feeling of use. However, since the bead is used, the workability is poor. On the other hand, when the ultrasonic pulverizer is used, not only the workability is good, but also the (four)-« of the obtained cosmetic material has a transparent feeling. Next, according to the above-mentioned manufacturing method, the composition of the inventor is as follows: the composition of the yarn is as follows: (4) and the dispersion of the sample (the water-based emulsified foundation in oil). Same as in Table 2) The oil content in the dispersion, the ratio of volatile oil is 69.3. After the score, the item is evaluated according to the above rating. Each sample was evaluated. The results are shown in Table 4. To (3), (5)
1S 323407 201221146 *【表3】 環甲基聚矽氧烷 21 二曱基聚矽氧烷 11 (a)油分 二苯石夕氧苯基三甲基聚矽氧烷 0.25 甲氧桂皮酸乙基己酯 3 PEG-10二甲基聚矽氧烷 2 (b)粉末(親水性） 氧化梦包覆氧化鋅 5 辛矽基化處理顏料級氧化鈦 8 (b)粉末 聚矽氧處理鐵丹 1.4 辛矽基化處理黃色氧化鐵 0.45 辛矽基化處理黑色氧化鐵 0.04 二甲基聚矽氧烷聚甘油-3-雙丁酯 1.65 (C)分散助劑 倍半異硬脂酸山梨醇酐酯 1.1 氯化二硬脂基銨 0.0465 軟脂酸 0.1 二甲基二硬脂基錄改質水輝石 1 硬脂酸處理金紅石型氧化鈦 3 遮蔽劑 0.002 離子交換水 餘量 乙醇 6 笨氧基乙醇 0.5 代納邁甘油 3 乙二胺四乙酸三鈉 0.2 焦亞硫酸鈉 0.003 19 323407 201221146 【表4】 均質混合機 珠磨機 超音波粉碎機 評估（1):分散性 B A A 評估（2):作業性 A C A 評估（3):使用感 一 A 1 A 評估（5):色差△E※ab 6. 08 一 4.48 由表4可知，使用以往之均質混合機時，雖然其作業 性良好，但可觀察到分散液中存在凝集，亦可觀察到顏色 集中的情形。 在使用珠磨機時’並無分散液凝集，所得之化妝料使 用感亦良好。然而，由於使用磨珠，故作業性為不佳。 另一方面’當使用超音波粉碎機時，不僅作業性良好， 分散液之分散性為佳，所得之化妝料的使用感亦優異，且 具有透明感。 此外’與岣質混合處理比較，進行超音波粉碎處理時， 可觀察到會有外觀顏色與塗布顏色接近之傾向，因此可知 可獲得>肖費者所喜好之化妝料。 其次’本發明人等係藉由下述之試樣製造方法，進行 製造其調配級成係如下述表 5所示之試樣（試樣A至C)。 之後’對各氧樣之粒徑以粒度分布測定儀MICROTRACK HRA (曰機裝公司製造）進行測定 。其結果如表6所示。 又’就分散機而言，係使用分散機（PRIMIX公司製造， 15〇〇rpm)、珠磨機（VMA-GETZMANN 公司製造，5000rpm，Φ 〇. 5 ’ 輸出 l5〇〇W)、超音波粉碎機 UIP1000(Dr. Hielscher 20 323407 201221146 公司製造，輸出1000W)。 表5中調配量之單位為g，表6中粒徑之單位為〆mc 試樣製造方法 先將（a)油分、（b)粉末、（〇分散助劑，使用分散機 進行預攪拌5分鐘（表6中以分散機表示）。 將經過預分散之試樣使用珠磨機或超音波粉碎機調 製成分散液。經珠磨機或超音波粉碎機處理而過預分散的 3式樣之量’係S周整為電力消耗量之等量。 【表5】 試樣 -- A B C (a)油分 非揮.爹性夕氧烷※1 360 一 - — 360 一 聚矽氧烷※2 — — 360 (b)粉末 _ 顏料級氧化鈦※3 120 120 120 (c)分散助 劑 一曱基聚石夕氧燒聚甘油-3-雙丁醋 40 40 40 ※玉：KF-96A-6T(信越化學工業社製造） ： Wacker-Belsil(R) DM1 PLUS(ffaker Asahikasei Sil icone 公司製造） ※3 : SACHTLEBEN RC402(SACHTLEBEN PIGMENTS 0Y 公司製造） 【表6】 試樣A 試樣B 試樣C 分散檨 分散液 (珠磨機） 液 (超音波粉碎機) 分散機 分散液 (珠磨機） 分散液 (超音波粉碎機) 分散機 分散液 (珠磨機） 分散液 (超音波粉碎機） 處理時間 — 8分 2.5分 — 7分 2分 — 7分 2分 dlO 0.19 0.17 0.15 (X24 0.17 0.15 0.22 0.17 0.17 d50 0.45 0.41 0.猫 0.48 0.40 0.35 0.50 0.39 0.36 d90 0.85 0.74 0.64 0.84 0.77 Ί 0.64 0.91 0.71 0*63 21 323407 201221146 由表6可知，當分散機消耗的電力相同時，超音波粉 碎機的粒子可較珠磨機的粒子小。亦即，超音波粉碎機用 以使分散液之粒徑變小所需消耗之電力，係較珠磨機比較 小。因此明瞭此係可期望達到節能化者。 此外，了解到含揮發性油分之分散液B及C，係可以 較分散液A短的時間内使粒子變小。因此，本發明化妝料 中所含之分散液，至少需含揮發性油分。 【圖式簡單說明】 無 【主要元件符號說明】 無 22 3234071S 323407 201221146 *[Table 3] Cyclomethyl polyoxane 21 Dimercapto polyoxyl olefin 11 (a) oil diphenyl sulfonate phenyl trimethyl poly oxane 0.25 methoxy cinnamic acid ethyl Ester 3 PEG-10 dimethyl polyoxane 2 (b) powder (hydrophilic) Oxidation dream coated zinc oxide 5 octylation treatment pigment grade titanium oxide 8 (b) powder polyfluorene treatment iron oxide 1.4 xin Thiolification treatment of yellow iron oxide 0.45 octylation treatment of black iron oxide 0.04 dimethyl polyoxazane polyglycerol-3-dibutyl ester 1.65 (C) dispersing aid sesquiisostearate sorbitan ester 1.1 Distearyl ammonium chloride 0.0465 palmitic acid 0.1 dimethyl distearyl recorded modified hectorite 1 stearic acid treated rutile titanium oxide 3 masking agent 0.002 ion exchange water balance ethanol 6 stupid ethanol 0.5 Denamai Glycerin 3 Ethylenediaminetetraacetic acid Trisodium 0.2 Sodium metabisulfite 0.003 19 323407 201221146 [Table 4] Homogenizer Mixer Bead Mill Ultrasonic Crusher Evaluation (1): Dispersibility BAA Evaluation (2): Operational ACA Assessment (3): use sense A 1 A evaluation (5): color difference △ E ※ Ab 6. 08 - 4.48 As is clear from Table 4, when the conventional homomixer was used, although the workability was good, aggregation was observed in the dispersion, and color concentration was observed. When the bead mill was used, there was no agglomeration of the dispersion, and the resulting cosmetic had a good feeling of use. However, workability is poor due to the use of beads. On the other hand, when an ultrasonic pulverizer is used, not only workability is good, but also dispersibility of the dispersion liquid is good, and the obtained cosmetic material is excellent in use feeling and has a transparent feeling. Further, when the ultrasonic pulverization treatment was carried out as compared with the enamel mixing treatment, it was observed that the appearance color and the coating color were close to each other. Therefore, it was found that the cosmetic material which was preferred by the viewer was obtained. Then, the inventors of the present invention produced the samples (samples A to C) shown in the following Table 5 by the following sample production methods. Thereafter, the particle size of each of the oxygen samples was measured by a particle size distribution analyzer MICROTRACK HRA (manufactured by Seiko Co., Ltd.). The results are shown in Table 6. In the case of the dispersing machine, a dispersing machine (15 rpm manufactured by PRIMIX Co., Ltd.), a bead mill (manufactured by VMA-GETZMANN, 5000 rpm, Φ 5. 5 'output l5 〇〇 W), ultrasonic pulverization Machine UIP1000 (Dr. Hielscher 20 323407 201221146 company, output 1000W). The unit of the formula in Table 5 is g, and the unit of the particle diameter in Table 6 is 〆mc. The sample preparation method firstly (a) oil, (b) powder, (〇 dispersing aid, pre-stirring using a dispersing machine for 5 minutes) (Refer to the disperser in Table 6.) The pre-dispersed sample is prepared into a dispersion using a bead mill or an ultrasonic pulverizer. The amount of the pre-dispersed 3 is treated by a bead mill or an ultrasonic pulverizer. 'System S is the same amount of power consumption. [Table 5] Samples - ABC (a) Oil is not a volatile. 1 夕 ※ ※ 1 1 1 1 1 1 1 1 360 360 360 360 360 360 ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ 360 (b) Powder _ Pigment grade titanium oxide*3 120 120 120 (c) Dispersing aid 曱 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 聚 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 Chemical Industry Co., Ltd.) : Wacker-Belsil(R) DM1 PLUS (manufactured by ffaker Asahikasei Sil icone) *3 : SACHTLEBEN RC402 (manufactured by SACHTLEBEN PIGMENTS 0Y) [Table 6] Sample A Sample B Sample C Dispersed and dispersed Liquid (bead mill) liquid (ultrasonic pulverizer) disperser dispersion (bead mill) dispersion (ultrasonic pulverizer) Dispersion dispersion (bead mill) Dispersion (ultrasonic pulverizer) Treatment time - 8 minutes and 2.5 minutes - 7 minutes and 2 minutes - 7 minutes and 2 points dlO 0.19 0.17 0.15 (X24 0.17 0.15 0.22 0.17 0.17 d50 0.45 0.41 0. Cat 0.48 0.40 0.35 0.50 0.39 0.36 d90 0.85 0.74 0.64 0.84 0.77 Ί 0.64 0.91 0.71 0*63 21 323407 201221146 It can be seen from Table 6 that when the power consumed by the disperser is the same, the particles of the ultrasonic pulverizer can be compared with the particles of the bead mill. That is, the power required to reduce the particle size of the dispersion by the ultrasonic pulverizer is smaller than that of the bead mill. Therefore, it is understood that the system can be expected to achieve energy saving. The dispersions of the oils B and C can reduce the particles in a shorter period of time than the dispersion A. Therefore, the dispersion contained in the cosmetic of the present invention needs at least a volatile oil component. No [Main component symbol description] No 22 323407