201217039 六、發明說明： 【發明所屬之技術領域】 本發明係將分散於液中之固體狀聚合物從該液體予以 分離之手段》 【先前技術】 在化學工業、食品工業、礦工業等的領域，將分散於 液中之固體（例如粒子狀的固體等）從該液予以分離，再 取出固體之製程存在有多數。 例如，在化學工業領域，於橡膠製品的製造過程，使 蒸氣作用於溶解在溶媒中之聚合物（一般爲高分子材料） ，從聚合物去除溶媒後，以破碎機將此聚合物予以破碎， 作成爲固體的小塊物（固體狀聚合物，將其稱爲屑粒）。 在此，屑粒（固體狀聚合物）係呈分散於藉由蒸氣所加溫 之熱水中（液中）的狀態。然後，從熱水分離屑粒，對所 取出之屑粒進一步進行必要的脫水、乾燥後，對屑粒予以 沖壓成形，獲得塊狀橡膠材料（中間製品）。 又，在前述橡膠製品的製造過·程，爲了從熱水分離並 取出屑粒，以往以來，使用固定式篩或循環驅動型篩。 固定式篩係爲例如，對水平面傾斜並加以固定之金網 製的平面篩。當在該平面篩上，送入包含已分散的屑粒之 熱水時，熱水會通過平面篩的網眼，而殘留於平面篩上之 屑粒會自傾斜的該平面篩落下。藉此，能將屑粒從熱水加 以分離。201217039 VI. Description of the Invention: [Technical Field of the Invention] The present invention is a method for separating a solid polymer dispersed in a liquid from the liquid. [Prior Art] In the fields of the chemical industry, the food industry, the mining industry, and the like The solids (for example, particulate solids, etc.) dispersed in the liquid are separated from the liquid, and a large number of processes for removing the solids are present. For example, in the chemical industry, in the manufacturing process of rubber products, steam is applied to a polymer (generally a polymer material) dissolved in a solvent, and after removing the solvent from the polymer, the polymer is broken by a crusher. It is made into a solid piece (solid polymer, which is called crumb). Here, the crumb (solid polymer) is in a state of being dispersed in hot water (liquid) heated by steam. Then, the crumb is separated from the hot water, and the removed crumb is further subjected to necessary dehydration and drying, and then the crumb is press-formed to obtain a block rubber material (intermediate product). Further, in the production of the rubber product, in order to separate and extract the crumb from the hot water, a fixed sieve or a circulation-driven sieve has been conventionally used. The stationary screen is, for example, a gold mesh flat screen that is inclined to the horizontal plane and fixed. When the hot water containing the dispersed crumb is fed onto the flat screen, the hot water passes through the mesh of the flat screen, and the crumb remaining on the flat screen falls from the inclined flat screen. Thereby, the crumb can be separated from the hot water.
S -5- 201217039 循環驅動型篩係爲將多數個金屬製板予以組合所形成 之無端軌道狀篩（參照專利文獻1)。當在該無端軌道狀 篩上，送入包含已分散的屑粒之熱水時，熱水會通過金屬 製板所形成之縫細的間隙，而殘留於循環驅動型篩上之屑 粒朝預定方向被搬送，而從循環驅動型篩分離。藉此，能 將屑粒從熱水加以分離。 [先行技術文獻] [專利文獻1]日本特開平6-304417號公報 【發明內容】 但，當使用這些固定式篩或循環驅動型篩，將屑粒從 熱水加以分離時，會產生以下的問題。 首先’在固定式篩’當小直徑的屑粒進入到平面篩的 網眼並殘存時，會有堵塞網眼之情況。如此，會造成熱水 的分離效果降低’在之後的脫水、乾燥製程，會與屑粒一 同供給多量的遊離水，即使藉由該脫水、乾燥，也無法從 屑粒去除水分，會有在中間製品之塊狀橡膠材料含有過多 的水分之虞產生。 又’會有新的屑粒附著於殘存在網眼之屑粒而成長成 大之塊體，該大塊之屑粒會有突然從網眼剝離，而被送至 之後的脫水、乾燥製程之情況。在此情況，在該脫水、乾 燥製程，會產生搬送不良，造成讓製程（生產過程）之虞 。又’會有容易產生脫水、乾燥不良，最終在中間製品之 -6- 201217039 塊狀橡膠材料含有過多的水分之虞。 前述這種問題，在依據橡膠製品的規格 之聚合物的附著性、凝集性高之情況，屑粒 情況容易產生。爲了解決這些問題，例如， 〜1 5天更換篩等的對策。但，此定期性作 ’並且由於在作業前間需停止製程（生產過 使中間製品的生產效率降低。又，爲了減少 度’亦可考量每15〜30分分鐘實施高壓洗 ，此定期作業也非常費工。 在循環驅動型篩，亦存在有以下這種其 ，形成有縫細之金屬製板，由於在驅動時會 故’金屬碰觸（金屬彼此接觸）多，產生浮 意地混入到屑粒進而混入到中間製品之塊狀 〇 又，循環驅動型篩，因進行使用，會有 狀篩之多數個金屬製板伸展，各金屬製板成 以需要定期進行張力、位置等的調整。且， 軌道狀篩之構件的鏈條，因長期間的連續使 等的構成零件劣化之虞。又，依據劣化的狀 鏈條全體或襯套等的構成零件的更換。爲了 、更換作業’不僅需要作業者熟練度，且費 需要進行長時間之試運轉。並且，在進行這 轉期間，由於需要停止製程（生產過程）， 製品的生產效率降低。又，即使爲鏈條，也 ，於製造過程 作成更小徑之 可考量每1 0 業非常費工時 程），故，會 此篩的更換頻 淨之對策。但 他問題。首先 相互地滑動， 遊的金屬不注 橡膠材料之虞 構成無端軌道 爲不平行，所 用來驅動無端 用，會有襯套 態，需要進行 進行這些調整 時費工，並且 些作業、試運 故，會讓中間 會引起金屬碰S -5-201217039 The cycle-driven sieve system is an endless rail-shaped sieve formed by combining a plurality of metal plates (see Patent Document 1). When the hot water containing the dispersed crumb is fed onto the endless rail-shaped sieve, the hot water passes through the fine gap formed by the metal plate, and the crumb remaining on the circulation-driven sieve is intended to be predetermined. The direction is conveyed and separated from the circulation-driven sieve. Thereby, the crumb can be separated from the hot water. [Patent Document 1] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei 6-304417. SUMMARY OF THE INVENTION However, when these fixed sieves or circulation-driven sieves are used to separate crumbs from hot water, the following problem. First, in the case of a fixed sieve, when small-sized crumbs enter the mesh of the flat screen and remain, there is a case where the mesh is clogged. In this way, the separation effect of the hot water is lowered. In the subsequent dehydration and drying processes, a large amount of free water is supplied together with the crumb particles, and even if the dehydration or drying is performed, the water cannot be removed from the crumbs, and there is a middle in the middle. The block rubber material of the product contains excessive moisture and is produced. In addition, there will be new crumbs attached to the crumbs remaining in the mesh and grow into large blocks. The large pieces of crumb will be suddenly peeled off from the mesh and sent to the subsequent dehydration and drying process. Happening. In this case, in the dehydration and drying process, poor transfer occurs, which causes the process (production process) to be paralyzed. In addition, there is a tendency to cause dehydration and poor drying, and finally the -6-201217039 block rubber material in the intermediate product contains excessive moisture. As described above, in the case where the adhesion and aggregation of the polymer according to the specifications of the rubber product are high, the crumb is likely to occur. In order to solve these problems, for example, measures such as changing the screen for ~15 days. However, this regular work 'and because of the need to stop the process before the operation (production has reduced the production efficiency of intermediate products. Also, in order to reduce the degree) can also be considered to carry out high pressure washing every 15 to 30 minutes, this regular operation also It is very labor-intensive. In the circulation-driven type of screen, there is also the following, which forms a metal plate with a fine seam. Since the metal touches (the metal touches each other) during the driving, the floating metal is mixed into the chip. The pellets are further mixed into the block-shaped crucible of the intermediate product, and the circulation-driven sieve is used. As a result, a plurality of metal plates of the sieve are stretched, and each of the metal plates is required to be periodically adjusted in tension, position, and the like. The chain of the member of the rail-shaped screen is deteriorated due to the continuous construction of the components in the long period of time. In addition, the replacement of the components such as the deteriorated chain or the bushing is required. Proficiency, and it takes a long time to run the test. Moreover, during the transfer, the production efficiency of the product is lowered due to the need to stop the process (production process). . Moreover, even for the chain, also, made the manufacturing process more trails the industry can be considered a very cost per 10 hours away), so, countermeasures will replace the sieve net of frequency. But he is a problem. First of all, sliding on each other, the metal of the swim does not contain rubber material, and the endless track is non-parallel. It is used to drive the endless use, there is a bushing state, it is necessary to carry out these adjustments, and some work, trial operation, Will cause the metal to touch the middle
S 201217039 觸，產生浮遊的金屬不注意地混入到屑粒進而混入到中間 製品之塊狀橡膠材料之虞。 本發明係有鑑於這樣的情事而開發完成之發明，其目 的係在於提供下述手段，即，能夠屑粒與熱水良好地分離 ，進而可自該液將分散於液中之固體狀聚合物予以分離， 不會有金屬混入到屑粒（固體狀聚合.物）之虞，且，不會 有多餘的水分（熱水、液）殘存於屑粒（固體狀聚合物） ，因此，在中間製品之塊狀橡膠材料也不會含有金屬、過 多的水分等，並且不需要洗淨、調整、更換等的作業或頻 度少即可完成，不需要長期間連續地停止製造過程。經過 精心硏究的結果，發現依據以下的手段可解決此課題而完 成了本發明。 即’首先’若依據本發明，提供固體狀聚合物用分離 裝置’其係將分散於液中之固體狀聚合物自該液予以分離 之裝置’具備有：形成有多數個縫細之筒狀的篩；使該篩 朝（周方向）旋轉之驅動機構；設置於篩的內周面之導引 板；在篩的外周面側，朝向該篩的外周面的方式設置之第 1液體噴射機構；及至少包圍篩，並且在下方具有排出口 之外殻。 在筒狀的篩’例如，將鋼索平行地排列，構成與周面 接觸的部分，即可形成多數個縫細。縫細（鋼索的間隙） 可依據處理對象之固體狀聚合物的大小，任意地設定。當 考量篩的洗淨性，理想爲1〜3mm，更理想爲1.5〜2.5mm 。舗的形狀呈圓筒狀爲更佳。在此情況，驅動機構使篩朝 -8 - 201217039 圓周方向旋轉。 驅動機構係藉由例如，驅動源與驅動力傳達機構所構 成。具體而言，能以電動機（驅動源）、連接於該電動機 之鏈輪、設置成連接於筒狀的篩的入口側之驅動管、纏繞 於該驅動管的圓周上之鏈條、及與該驅動管密接設置之滾 子（驅動力傳達機構）來構成。藉由使連接於電動機之鏈 輪旋轉，並使嚙合的鏈條，使得驅動管及篩旋轉。藉由使 驅動管及篩搭載於滾子上的方式，使得驅動管及篩圓滑地 旋轉。 導引板係在篩的內周面，設置於自筒狀的篩的入口側 到出口側爲止的範圍。此導引板呈螺旋狀爲佳。此螺旋狀 的導引板爲處理對象之固體狀聚合物的區隔板，形成溝槽 。在設有後述之延長管的情況時’在該延長管設置導引板 爲佳。導引板可連續或斷續地形成，但連續形成爲佳。在 導引板呈螺旋狀之情況時，其條數可依據處理對象之固體 狀聚合物的處理量（每平均時間之質量）、向之後的脫水 、乾燥製程供給屑粒之狀況’加以任意地設定。當考量篩 的洗淨性時，螺旋狀的導引板之條數，4〜8條爲佳’ 5〜 7條爲更佳。螺旋狀的導引板的高度，可依據處理對象之 固體狀聚合物的處理量（每平均時間之質量）’加以任意 地設定。當考量篩的洗淨性時’螺旋狀的導引板之高度’ 5〜15cm爲佳，8〜12cm爲更佳。 在本說明書中’入口側係指處理對象之液及分散於'該 液中之固體狀聚合物進入之（投入）側。出口側係指已被S 201217039 Touch, the floating metal is inadvertently mixed into the crumb and then mixed into the block of rubber material in the middle product. The present invention has been made in view of such circumstances, and an object thereof is to provide a means for separating a crumb and a hot water well, and further capable of dispersing a solid polymer dispersed in a liquid from the liquid. Separation, no metal is mixed into the crumb (solid polymer), and no excess water (hot water, liquid) remains in the crumb (solid polymer), so in the middle The block rubber material of the product does not contain metal, excessive moisture, etc., and does not require work such as washing, adjustment, replacement, etc., or the frequency is small, and it is not necessary to continuously stop the manufacturing process for a long period of time. As a result of careful investigation, it has been found that the present invention can be solved by the following means. That is, according to the present invention, there is provided a separation device for a solid polymer, which is a device for separating a solid polymer dispersed in a liquid from the liquid, and has a cylindrical shape in which a plurality of slits are formed. a screen for rotating the screen toward the (circumferential direction); a guide plate provided on the inner peripheral surface of the screen; and a first liquid ejecting mechanism disposed on the outer peripheral surface side of the screen toward the outer peripheral surface of the screen And an outer casing that surrounds the sieve at least and has a discharge port at the bottom. In the cylindrical sieve, for example, a plurality of slits are formed by arranging the steel cables in parallel to form a portion in contact with the circumferential surface. The slit (the gap of the cable) can be arbitrarily set depending on the size of the solid polymer to be treated. When considering the cleanability of the sieve, it is preferably 1 to 3 mm, more preferably 1.5 to 2.5 mm. The shape of the paving is preferably cylindrical. In this case, the drive mechanism rotates the screen in the circumferential direction of -8 - 201217039. The drive mechanism is constituted by, for example, a drive source and a drive force transmitting mechanism. Specifically, an electric motor (drive source), a sprocket connected to the motor, a drive tube that is connected to the inlet side of the cylindrical screen, a chain wound around the circumference of the drive tube, and the drive can be used. The tube is closely connected to the roller (driving force transmission mechanism). The drive tube and screen are rotated by rotating the sprocket coupled to the motor and engaging the chain. The drive tube and the screen are smoothly rotated by mounting the drive tube and the screen on the roller. The guide sheets are attached to the inner peripheral surface of the screen and are provided in a range from the inlet side to the outlet side of the cylindrical screen. This guide plate is preferably spiral. The spiral guide sheet is a partition of the solid polymer to be treated to form a groove. In the case where an extension pipe to be described later is provided, it is preferable to provide a guide plate in the extension pipe. The guide sheets may be formed continuously or intermittently, but are preferably formed continuously. When the guide sheets are spiral, the number of the sheets may be arbitrarily determined depending on the amount of processing of the solid polymer to be treated (the mass per average time), the condition of supplying the crumbs to the subsequent dehydration and drying processes. set up. When considering the detergency of the sieve, the number of the spiral guide sheets, 4 to 8 strips are preferably '5 to 7 strips as better. The height of the spiral guide sheet can be arbitrarily set depending on the amount of processing (the mass per average time) of the solid polymer to be treated. When considering the detergency of the sieve, the height of the spiral guide plate is preferably 5 to 15 cm, and more preferably 8 to 12 cm. In the present specification, the "inlet side" refers to the liquid to be treated and the (input) side in which the solid polymer dispersed in the liquid enters. The exit side means that it has been
S -9- 201217039 處理（自液分離）後之固體狀聚合物出來（排出）之側。 入口側、出口側之用語，並非僅對筒狀的篩使用，對固體 狀聚合物用分離裝置全體、篩以外之要件也使用。 在這樣的本發明之固體狀聚合物用分離裝置，於導引 板呈螺旋狀之情況時，使篩朝周方向即與導引板之螺旋狀 的方向配合之方向旋轉，自筒狀的篩的一方的開口（入口 )連續地投入分散於液中之固體狀聚合物，則液（體）會 通過縫細，從外殻下方之排出口被排出到系統外。另外， 固體狀聚合物會與液分離，而殘留在筒狀的篩的內周面， 依據螺旋狀的導引板之導引，以每定量且一定間隔自筒狀 的篩的另一方之開口（出口）排出。 第1液體噴射機構係在篩的外周面側，朝該篩的外周 面設置。此第1液體噴射機構係例如，噴射對象成爲篩的 外周面之上側的方式安裝於外殼的上方。自第1液體噴射 機構，將液體朝篩的外周面噴射，可防止固體狀聚合物的 附著、凝集，或可將已附著的固體狀聚合物自篩去除。第 1液體噴射機構的數量，可對筒狀的篩的（軸方向的）長 度加以任意地設定。當考量篩的洗淨性時，篩的長度每 lm，設置3〜15個爲佳，篩的長度每lm，設置5〜10個 爲更佳。 在本發明之固體狀聚合物用分離裝置，在筒狀的篩的 出口側，具備有朝該篩的內周面上側設置之第2液體噴射 機構爲佳。 第2液體噴射機構係在筒狀的篩的出口側，朝該篩的 -10- 201217039 內周面上側設置著。此第2液體噴射機構，例如，以噴射 對象處成爲篩的內周面上側，且，噴射口位於筒狀的篩的 出口附近之與軸方向垂直的面（圓形）的中心的方式，藉 由支承具或配管安裝著。噴射，可防止固體狀聚合物的附 著 '凝集，或可將已附著的固體狀聚合物自篩去除。第2 液體噴射機構的數量，可對筒狀的篩的（軸方向的）長度 。筒狀的篩的（軸方向的）長度及內周面的大小（面積） ，加以任意地設定。當考量篩的洗淨性時，設置1〜5個 爲佳，設置2〜4個爲更佳。 在本發明之固體狀聚合物用分離裝置，在外殻內的上 方，具備朝該外殼的內面設置之第3液體噴射機構爲佳。 此第3液體噴射機構，例如，以噴射對象處成爲外殼 的內面的方式，設置於外殻的內面之頂面，或頂面與側面 相交的角部分（角落部分）。自第3液體噴射機構，將液 體朝外殼的內面（特別是頂面及側面的上側）噴射，可防 止固體狀聚合物的附著、凝集，或可將已附著的固體狀聚 合物自外殼去除。第3液體噴射機構的數量，對外殼的大 小（內面的面積），可加以任意地設定。當考量外殼內面 的洗淨性時，設置4〜1 6個爲佳，設置8〜1 4個爲更佳。 在本發明之固體狀聚合物用分離裝置，在外殼內的下 方，具備朝該外殼的內面設置之第4液體噴射機構爲佳。 此第4液體噴射機構，例如，能以噴射對象處成爲外 殼的內面的方式，設置於外殻的底面與側面相交的角部分 (角落部分）。自第4液體噴射機構，將液體朝外殼的內S -9- 201217039 The side of the solid polymer coming out (discharged) after treatment (from liquid separation). The terms of the inlet side and the outlet side are not used only for the cylindrical sieve, and are also used for the entire solid polymer separation device and the sieve. In the separation device for a solid polymer according to the present invention, when the guide plate is spirally formed, the sieve is rotated in the circumferential direction, that is, in a direction in which the spiral direction of the guide plate is fitted, and the sieve is formed from a cylindrical shape. When one of the openings (inlet) is continuously introduced into the solid polymer dispersed in the liquid, the liquid (body) is sewn through the slit and discharged from the discharge port below the outer casing to the outside of the system. In addition, the solid polymer is separated from the liquid and remains on the inner peripheral surface of the cylindrical sieve, and is guided by the spiral guide plate at the interval of the other side of the cylindrical sieve at every certain interval. (export) discharge. The first liquid ejecting mechanism is provided on the outer peripheral surface side of the screen and is provided on the outer peripheral surface of the screen. The first liquid ejecting mechanism is attached to the upper side of the casing so that the object to be ejected is on the upper side of the outer peripheral surface of the screen. From the first liquid ejecting mechanism, the liquid is ejected toward the outer peripheral surface of the sieve to prevent adhesion or aggregation of the solid polymer, or to remove the adhered solid polymer from the sieve. The number of the first liquid ejecting mechanisms can be arbitrarily set to the length of the cylindrical sieve (in the axial direction). When considering the cleanability of the sieve, the length of the sieve is preferably 3 to 15 per lm, and the length of the sieve is preferably 5 to 10 per lm. In the separation device for a solid polymer of the present invention, it is preferable that the second liquid ejecting mechanism provided on the inner peripheral surface side of the sieve is provided on the outlet side of the cylindrical sieve. The second liquid ejecting mechanism is provided on the outlet side of the cylindrical sieve, and is provided on the inner peripheral surface side of the -10-201217039 of the sieve. In the second liquid ejecting mechanism, for example, the injection target is located on the inner circumferential surface side of the sieve, and the injection port is located at the center of the surface (circular shape) perpendicular to the axial direction near the outlet of the cylindrical sieve. It is mounted by a support or a pipe. The spraying prevents the attachment of the solid polymer from 'aggregation, or the attached solid polymer can be removed from the sieve. The number of the second liquid ejecting mechanism can be the length of the cylindrical sieve (in the axial direction). The length of the cylindrical sieve (in the axial direction) and the size (area) of the inner peripheral surface are arbitrarily set. When considering the cleanability of the sieve, it is preferable to set 1 to 5, and it is more preferable to set 2 to 4. In the separating apparatus for a solid polymer of the present invention, it is preferable that a third liquid ejecting mechanism provided on the inner surface of the outer casing is provided above the outer casing. The third liquid ejecting mechanism is provided, for example, at a top surface of the inner surface of the outer casing or a corner portion (corner portion) where the top surface intersects the side surface so that the object to be ejected becomes the inner surface of the outer casing. Since the third liquid ejecting mechanism ejects the liquid toward the inner surface of the outer casing (especially the upper side and the upper side of the side surface), adhesion or aggregation of the solid polymer can be prevented, or the attached solid polymer can be removed from the outer casing. . The number of the third liquid ejecting mechanisms can be arbitrarily set to the size of the outer casing (the area of the inner surface). When considering the cleanability of the inner surface of the outer casing, it is preferable to set 4 to 16 pieces, and it is preferable to set 8 to 1 4 pieces. In the separating apparatus for a solid polymer of the present invention, a fourth liquid ejecting mechanism provided on the inner surface of the outer casing is preferably provided below the outer casing. The fourth liquid ejecting mechanism can be provided, for example, at a corner portion (corner portion) where the bottom surface and the side surface of the outer casing intersect each other so that the object to be ejected becomes the inner surface of the outer casing. From the fourth liquid ejecting mechanism, the liquid is directed into the outer casing
S -11 - 201217039 面（特別是頂面及側面的上側）噴射，可防止固體狀聚合 物的附著、凝集，或可將已附著的固體狀聚合物自外殻去 除。第4液體噴射機構的數量，對外殼的大小（內面的面 積），可加以任意地設定。當考量外殼底面的洗淨性時， 設置4〜10個爲佳，設置6〜8個爲更佳。 在本發明之固體狀聚合物用分離裝置，具備以連接於 筒狀的篩的出口側的方式設置之延長管，及在筒狀的篩的 出口側，具備朝該延長管的內周面下側設置之第5液體噴 射機構爲佳。 第5液體噴射機構，例如，以噴射對象處成爲延長管 的內周面下側的方式，且，噴射口位於筒狀的篩的出口附 近（即，延長管的附近）之與軸方向垂直的面（圓形）的 中心的方式，藉由支承具或配管安裝著。自第5液體噴射 機構，將液體朝延長管的內周面下側噴射，防止固體狀聚 合物的附著，並且藉由使用冷水作爲液體，可將朝下一製 程（脫水、乾燥等）之固體狀聚合物予以冷卻。第5液體 噴射機構的數量，可對延長管的內周面的大小（面積）， 加以任意地設定。當考量延長管的洗淨性時，設置1〜5 個爲佳，設置2〜4個爲更佳。 在第1液體噴射機構、第3液體噴射機構、及第4液 體噴射機構，所使用（噴射）之液體的壓力，當考量各自 的洗淨性時，越高越佳。當考量噴射對象處（篩等）的強 度’及針對篩，考量對其旋轉之抵抗時，液體的壓力係1 〜7MPa爲佳。 -12- 201217039 另外，在第2液體噴射機構，所使用（噴射）的液體 的壓力，當考量在篩內部之屑粒的飛散等時，與第1液體 噴射機構、第3液體噴射機構、及第4液體噴射機構相等 左右即可，不需要高的壓力，理想爲0.2〜0.6MPa左右。 在第1液體噴射機構、第2液體噴射機構、第3液體 噴射機構、及第4液體噴射機構，所使用（噴射）的液體 的溫度，可依據處理對象之固體狀聚合物的硬度、黏度、 附著性 '凝集性所代表之物性的溫度依存性，加以任意地 設定。當考量附著性（或剝離容易度）時，液體的溫度係 50〜95°C爲佳，70〜90°C爲更佳。 另外，在第5液體噴射機構，所使用（噴射）的液體 的壓力，爲0·1〜0.6MPa即可。又，在第5液體噴射機構 ，所使用（噴射）的液體的溫度係5〜40°C爲佳，1 5〜3 0 t爲更佳。 第1液體噴射機構、第2液體噴射機構、第3液體噴 射機構、第4液體噴射機構、及第5液體噴射機構，分別 以例如，經由配管連接於具有壓力的液體源之噴射噴嘴所 構成。具有壓力之液體源係指例如，儲存液體之槽與送出 液體之泵浦，這些亦可不含於本發明之固體狀聚合物用分 離裝置的結構。 在本發明之固體狀聚合物用分離裝置，驅動機構可調 節篩的旋轉速度爲佳。 例如’藉由任意地調節驅動機構的驅動源的旋轉數， 可任意地控制篩的旋轉數。具體而言，在驅動機構的驅動 -13- 201217039 源爲電動機之情況時，藉由設置變換器進行頻率控制等， 可調節篩的旋轉速度。篩的旋轉數，可依據筒狀的篩的大 小（爲圓筒狀的篩則指其徑），處理對象之固體狀聚合物 的處理量（每平均時間之質量）及固體狀聚合物分離裝置 的出口之屑粒中的水分量，加以任意地設定。篩的旋轉數 ，理想爲5〜35rpm，更理想爲12〜28rpm。 在本發明之固體狀聚合物用分離裝置，於篩與外殼之 間，具備有防止異物從篩的系統外（外側）侵入到系統內 (內側）之減渦板爲佳。更具體而言，在外殻的驅動部（ 有入口側的滾子之空間）與被分離的熱水流動的部分之間 、及被分離的熱水流動之部分與有出口側的滾子之空間之 間，分別具有防止異物（例如，滾子之切削片）從外側（ 有滾子的空間）侵入到內側（被分離的熱水流動之空間） 之減渦板爲佳。此滾子爲構成驅動力傳達機構之零件。 本發明之固體狀聚合物用分離裝置，在固體狀聚合物 爲自由丁二烯橡膠、異戊二烯橡膠、苯乙烯-丁二烯橡膠 、苯乙烯-異戊二烯橡膠、乙烯-α-烯烴共聚合橡膠、乙 烯-α-烯烴-非共軛二烯共聚合橡膠、丁基橡膠、苯乙烯· 丁二烯-苯乙烯嵌段共聚合物、氫化苯乙烯-丁二烯-苯乙 烯嵌段共聚合物、丁二烯樹脂、及丙烯酸樹脂所構成的聚 合物群選擇之聚合物的情況時，可理想地使用》 其次，若依據本發明，提供使用前述任一者之固體狀 聚合物用分離裝置，將分散於液中之固體狀聚合物自該液 予以分離之固體狀聚合物的分離方法。 -14- 201217039 其次，若依據本發明，提供一種橡膠材料的製造方法 ，該製造方法具有：將與溶媒混合後的單體予以聚合，獲 得聚合物之聚合製程；使蒸氣作用，來從聚合物去除溶媒 之溶媒去除製程；使用前述任一者之固體狀聚合物用分離 裝置，將去除了溶媒之聚合物自蒸氣液化之熱水予以分離 的分離製程；將自熱水分離後的聚合物的水分進一步去除 之脫水製程及乾燥製程：以及將去除了水分之聚合物成形 爲預定的形狀之成形製程。 本發明之固體狀聚合物用分離裝置，因具有形成有多 數個縫細之筒狀的篩、使該篩旋轉之驅動機構、及設置於 篩的內周面之導引板，所以，若從筒狀的篩的一方的開口 (入口），將分散於液中之固體狀聚合物連續地投入，則 液（例如熱水）會通過縫細，從外殼下方的排出口排出至 系統外，而固體狀聚合物（例如屑粒）會與該液分離，殘 留於筒狀的篩的內周面，依據導引板之導引，以每定量的 方式，從筒狀的篩的另一方之開口（出口）排出。又，因 第1液體噴射機構及第2液體噴射機構，在篩的外周面及 內周面，防止固體狀聚合物的附著、凝集，或從篩去除附 著的固體狀聚合物，所以不會造成篩的縫細堵塞。因此， 不會有所謂的有效濾過面積減少，且液（例如熱水）的分 離效果不會降低。因此，可將分散於液中之固體狀聚合物 自該液予以良好地分離，且在處理後的固體狀聚合物（例 如屑粒）不會殘存有大量的水分（液（例如熱水）），在 最終的製品（例如中間製品之塊狀橡膠材料）也不會含有S -11 - 201217039 The surface (especially the top side and the upper side of the side) is sprayed to prevent adhesion or agglomeration of the solid polymer or to remove the attached solid polymer from the outer casing. The number of the fourth liquid ejecting mechanisms can be arbitrarily set to the size of the outer casing (the area of the inner surface). When considering the detergency of the bottom surface of the casing, it is preferable to set 4 to 10, and it is better to set 6 to 8. The separation device for a solid polymer according to the present invention includes an extension pipe that is connected to the outlet side of the cylindrical sieve, and an outlet surface of the cylindrical sieve that is provided below the inner circumferential surface of the extension pipe. The fifth liquid ejecting mechanism provided on the side is preferred. The fifth liquid ejecting mechanism is, for example, such that the injection target portion is on the lower side of the inner peripheral surface of the extension pipe, and the injection port is located in the vicinity of the outlet of the cylindrical sieve (that is, in the vicinity of the extension pipe) perpendicular to the axial direction. The manner of the center of the face (circular) is mounted by a support or a pipe. From the fifth liquid ejecting mechanism, the liquid is sprayed toward the lower side of the inner peripheral surface of the extension pipe to prevent the adhesion of the solid polymer, and by using cold water as the liquid, the solid toward the next process (dehydration, drying, etc.) can be used. The polymer is cooled. The number of the fifth liquid ejecting mechanisms can be arbitrarily set for the size (area) of the inner peripheral surface of the extension pipe. When considering the detergency of the extension tube, it is preferable to set 1 to 5, and set 2 to 4 as better. In the first liquid ejecting mechanism, the third liquid ejecting mechanism, and the fourth liquid ejecting mechanism, the pressure of the liquid used (sprayed) is preferably as high as possible in consideration of the respective detergency. When considering the strength of the object to be sprayed (screen, etc.) and the resistance against the rotation of the sieve, the pressure of the liquid is preferably 1 to 7 MPa. -12-201217039, the pressure of the liquid used (injected) in the second liquid ejecting mechanism, and the first liquid ejecting mechanism, the third liquid ejecting mechanism, and the like when considering the scattering of the crumb inside the sieve or the like The fourth liquid ejecting mechanism may be equal to the right and left, and does not require a high pressure, and is preferably about 0.2 to 0.6 MPa. The temperature of the liquid used (sprayed) by the first liquid ejecting mechanism, the second liquid ejecting mechanism, the third liquid ejecting mechanism, and the fourth liquid ejecting mechanism may depend on the hardness and viscosity of the solid polymer to be treated. The temperature dependence of the physical properties represented by the adhesion 'aggregability' is arbitrarily set. When the adhesion (or ease of peeling) is considered, the temperature of the liquid is preferably from 50 to 95 ° C, more preferably from 70 to 90 ° C. Further, in the fifth liquid ejecting mechanism, the pressure of the liquid to be used (sprayed) may be from 0.1 to 0.6 MPa. Further, in the fifth liquid ejecting mechanism, the temperature of the liquid to be used (sprayed) is preferably 5 to 40 ° C, more preferably 15 to 30 t. Each of the first liquid ejecting mechanism, the second liquid ejecting mechanism, the third liquid ejecting mechanism, the fourth liquid ejecting mechanism, and the fifth liquid ejecting mechanism is configured by, for example, an injection nozzle that is connected to a liquid source having a pressure via a pipe. The source of the pressurized liquid means, for example, a tank for storing the liquid and a pump for discharging the liquid, and these may not be contained in the structure of the separating apparatus for a solid polymer of the present invention. In the separating apparatus for a solid polymer of the present invention, the driving mechanism can preferably adjust the rotation speed of the screen. For example, the number of rotations of the screen can be arbitrarily controlled by arbitrarily adjusting the number of rotations of the drive source of the drive mechanism. Specifically, when the drive of the drive mechanism is -13-201217039, the rotation speed of the sieve can be adjusted by setting the inverter for frequency control or the like. The number of rotations of the sieve can be determined according to the size of the cylindrical sieve (the diameter of the cylindrical sieve), the treatment amount of the solid polymer to be treated (the mass per average time), and the solid polymer separation device The amount of water in the crumb of the outlet is arbitrarily set. The number of rotations of the sieve is desirably 5 to 35 rpm, more preferably 12 to 28 rpm. In the separating apparatus for a solid polymer of the present invention, it is preferable to provide a vortex plate between the screen and the outer casing to prevent foreign matter from entering the inside (inside) of the system from the outside (outer side) of the screen. More specifically, between the driving portion of the outer casing (the space of the roller on the inlet side) and the portion where the separated hot water flows, and the portion where the separated hot water flows and the space with the roller on the outlet side It is preferable to have a vortex plate for preventing foreign matter (for example, a cutting piece of a roller) from invading to the inside (the space in which the separated hot water flows) from the outside (for example, the cutting piece of the roller). This roller is a component that constitutes a driving force transmission mechanism. The separation device for a solid polymer of the present invention, wherein the solid polymer is free butadiene rubber, isoprene rubber, styrene-butadiene rubber, styrene-isoprene rubber, ethylene-α- Olefin copolymerized rubber, ethylene-α-olefin-non-conjugated diene copolymerized rubber, butyl rubber, styrene-butadiene-styrene block copolymer, hydrogenated styrene-butadiene-styrene embedded In the case of a polymer selected from a polymer group composed of a segment copolymer, a butadiene resin, and an acrylic resin, it is preferably used. Secondly, according to the present invention, a solid polymer using any of the foregoing is provided. A method for separating a solid polymer obtained by separating a solid polymer dispersed in a liquid from the liquid by a separating device. -14- 201217039 Next, according to the present invention, there is provided a method for producing a rubber material, which comprises: polymerizing a monomer mixed with a solvent to obtain a polymerization process of a polymer; and allowing a vapor to act from a polymer a solvent removal process for removing a solvent; a separation process for separating a solvent-removed polymer from steam liquefied hot water using a separation device for any of the foregoing solid polymers; and a polymer separated from the hot water The dehydration process and the drying process for further removing moisture: and a molding process for forming the moisture-removed polymer into a predetermined shape. The separation device for a solid polymer of the present invention has a guide plate in which a plurality of slits are formed in a cylindrical shape, a drive mechanism for rotating the sieve, and a guide plate provided on the inner peripheral surface of the sieve. When one of the openings (inlet) of the cylindrical sieve is continuously supplied with the solid polymer dispersed in the liquid, the liquid (for example, hot water) is sewn through the slit and discharged from the discharge port below the outer casing to the outside of the system. The solid polymer (for example, crumb) is separated from the liquid and remains on the inner peripheral surface of the cylindrical sieve, and is guided from the other side of the cylindrical sieve in a quantitative manner according to the guide plate. (export) discharge. In addition, the first liquid ejecting mechanism and the second liquid ejecting mechanism prevent adhesion or aggregation of the solid polymer on the outer peripheral surface and the inner peripheral surface of the sieve, or remove the adhered solid polymer from the sieve, so that the first liquid ejecting mechanism does not cause The seam of the sieve is finely clogged. Therefore, there is no so-called effective filtration area reduction, and the separation effect of liquid (e.g., hot water) is not lowered. Therefore, the solid polymer dispersed in the liquid can be well separated from the liquid, and a large amount of moisture (liquid (for example, hot water)) does not remain in the treated solid polymer (for example, crumb). , the final product (such as the block rubber material of the intermediate product) will not contain
S -15- 201217039 過多的水分。 本發明之固體狀聚合物用分離裝置，供固體狀聚合物 投入之篩僅旋轉’在其旋轉期間，固體狀聚合物僅依據導 引板之導引從入口朝出口移動而已。在進行分離之處理期 間，固體狀聚合物用分離裝置（篩）之中，在屑粒、液體 直接接觸的部分，不會產生金屬碰觸。例如，在將篩的驅 動機構作成爲連接於電動機之鏈輪與纏繞於驅動管的圓周 上之鏈條嚙合之構造的情況時，有可能引起金屬碰觸。但 ’該驅動機構所存在的空間與已被分離之屑粒及液體所存 在的空間分別被減渦板等所遮開。因此，即使在此情況， 也不會有金屬（例如屑粒）混入至處理後的固體狀聚合物 ’在最終的製品（例如中間製品之塊狀橡膠材料）也不會 含有金屬。 在本發明之固體狀聚合物用分離裝置，因不存在有鏈 條等要進行調整、更換之零件，所以，不需要進行這些調 整、更換等的作業，不需要長期間連續地停止製造過程， 有助於製品（例如中間製品之塊狀橡膠材料）的生產效率 提升。 本發明之固體狀聚合物用分離裝置如前述，第1液體 噴射機構及第2液體噴射機構在篩的外周面及內周面，防 止固體狀聚合物的附著、凝集。並且，本發明之固體狀聚 合物用分離裝置理想爲具備第3液體噴射機構及第4液體 噴射機構，這些機構個別在外殼的內面（頂面 '側面、及 底面），防止固體狀聚合物的附著。又這些所有的液體噴 -16 - 201217039 射機’在進行分離處理期間，能夠連續地噴射液體。又， 如前述’若可防止固體狀聚合物對篩的附著、凝集，可不 需要進行洗淨、調整等的作業或進行頻度少即可，不需要 長期間連續地停止製造過程，有助於製品（例如中間製品 之塊狀橡膠材料）的生產效率提升。 本發明之固體狀聚合物用分離裝置理想，爲在筒狀的 篩的出口側，具備有朝其延長管的內周面下側設置之第5 液體噴射機構，所以，藉由對固體狀聚合物直接進行液體 (例如冷水）噴霧，能夠調節對下一個所要進行之脫水、 乾燥製程供給的屑粒之溫度。 在本發明之固體狀聚合物用分離裝置，自液分離並依 據導引板之導引而被搬送之固體狀聚合物，會在該狀態下 朝向下一個製程行進。並且，暫時附著於篩、外殼等的內 面（頂面、側面、及底面）而被第1液體噴射機構〜第4 液體噴射機構所去除之固體狀聚合物會落下，而與液體一 同自外殼下方的排出口排出。此被排出之液體及固體狀聚 合物’在實施靜置分離後被回收，藉由預先投入至本發明 之固體狀聚合物用分離裝置，能夠將固體狀聚合物自液體 加以分離。於是，不會有被排出至系統外之固體狀聚合物 ’可回收大約100%，可有助於製品（例如中間製品之塊 狀橡膠材料）的生產效率提升。又，即使原本就分散有固 體狀聚合物之液’亦可作爲自第1液體噴射機構〜第4液 體噴射機構所噴射的液體進行再利用。如此，本發明之固 體狀聚合物用分離裝置，可成爲不會產生多餘的廢棄物並S -15- 201217039 Excessive moisture. The solid polymer of the present invention is used in a separating apparatus for the solid polymer to be fed into the screen to rotate only. During the rotation thereof, the solid polymer moves only from the inlet toward the outlet in accordance with the guide of the guide plate. During the separation process, in the separation device (screen) of the solid polymer, no metal contact is generated in the portion where the crumb and the liquid are in direct contact. For example, in the case where the driving mechanism of the screen is configured such that the sprocket connected to the motor meshes with the chain wound around the circumference of the driving tube, there is a possibility that the metal is touched. However, the space existing in the driving mechanism and the space in which the separated crumbs and liquids are present are respectively blocked by the vortex plate or the like. Therefore, even in this case, no metal (e.g., crumb) is mixed into the treated solid polymer. The final product (e.g., the block rubber material of the intermediate product) does not contain metal. In the separation device for a solid polymer of the present invention, since there is no component to be adjusted or replaced, such as a chain, it is not necessary to perform such operations such as adjustment and replacement, and it is not necessary to continuously stop the manufacturing process for a long period of time. It contributes to the production efficiency of products such as block rubber materials of intermediate products. In the separation device for a solid polymer of the present invention, the first liquid ejecting mechanism and the second liquid ejecting mechanism prevent the adhesion and aggregation of the solid polymer on the outer circumferential surface and the inner circumferential surface of the sieve. Further, the separation device for a solid polymer of the present invention preferably includes a third liquid ejecting mechanism and a fourth liquid ejecting mechanism, and these mechanisms are individually formed on the inner surface (top surface 'side surface and bottom surface) of the outer casing to prevent solid polymer Attachment. Further, all of the liquid sprays -16 - 201217039 can be continuously ejected during the separation process. Further, as described above, if it is possible to prevent adhesion or aggregation of the solid polymer to the sieve, it is not necessary to perform work such as washing or adjustment, or the frequency of the operation is small, and it is not necessary to continuously stop the manufacturing process for a long period of time, contributing to the product. The production efficiency of (for example, a block rubber material of an intermediate product) is improved. It is preferable that the separation device for a solid polymer of the present invention has a fifth liquid ejecting mechanism provided on the lower side of the inner peripheral surface of the extension tube on the outlet side of the cylindrical sieve, and therefore, the solid polymerization is performed. The liquid is directly sprayed with a liquid (for example, cold water) to adjust the temperature of the crumbs supplied to the next dehydration and drying process to be performed. In the separating apparatus for a solid polymer of the present invention, the solid polymer which is separated from the liquid and transported according to the guide of the guide sheet travels in this state toward the next process. Further, the solid polymer which is temporarily attached to the inner surface (top surface, side surface, and bottom surface) of the screen, the outer casing, or the like and removed by the first liquid ejecting mechanism to the fourth liquid ejecting mechanism is dropped, and is separated from the liquid by the outer casing. The discharge port below is discharged. The discharged liquid and solid polymer 'is recovered after standing separation, and the solid polymer can be separated from the liquid by being previously supplied to the separation device for a solid polymer of the present invention. Thus, no solid polymer discharged to the outside of the system can be recovered by about 100%, which contributes to an increase in the production efficiency of the article (e.g., the block rubber material of the intermediate product). Further, even if the liquid which originally disperses the solid polymer is used, it can be reused as the liquid ejected from the first liquid ejecting mechanism to the fourth liquid ejecting mechanism. Thus, the separation device for a solid polymer of the present invention can be made without generating excess waste.
S -17- 201217039 對環境負荷小且優良之裝置。 【實施方式】 以下，參照圖面，說明關於本發明的實施形態’但’ 本發明不限於這些實施形態，在不超出本發明的技術思想 範圍內，可依據該業者之知識，進行各種變更、修正、改 良。例如，圖面係顯示本發明的實施形態者，但，本發明 不限於圖面所示的形態、圖面所示的資訊等。在用來實施 或驗證本發明，適用本說明書中相同的手段或均等的手段 ，但，理想的手段爲以下所敘述之手段。再者，在圖1A 〜圖ID，內部亦以實線所描繪。 首先，說明、關於本發明之固體狀聚合物用分離裝置的 構成。圖1A〜圖4、圖5A、及圖6A所示的固體狀聚合 物用分離裝置1，爲可將分散於熱水（液）中之屑粒（固 體狀聚合物）從該熱水加以分離之裝置。 固體狀聚合物用分離裝置1，具備有：篩11、驅動機 構12、延長管13、導引板15、液體噴射機構16(第1液 體噴射機構）、液體噴射機構17(第2液體噴射機構） 、液體噴射機構21(第3液體噴射機構）、液體噴射機 構22 (第4液體噴射機構）、液體噴射機構23 (第5液 體噴射機構）、及外殻1 8。 篩11係呈圓筒狀，其周面（理想爲）以將斷面呈三 角形狀的鋼索1 1 1具規則性且平行地排列固定於圓筒狀的 篩11的軸方向的方式形成（參照圖2A〜圖2C)。又， -18- 201217039 藉由鋼索111，形成用來供熱水通過之多數個縫細112。 此縫細1 12之寬度（網眼開度）（理想）爲1.5〜2.5mm 〇 驅動機構12爲使篩11朝圓周方向S(參照圖2B及 圖2C)旋轉之手段。驅動機構12，以電動機121、連接 於電動機之鏈輪141、設置成連接於篩11的入口側（參 照圖1 A及圖2A中之左側）的驅動管123、捲繞於驅動管 圓周上之鏈條142及與該驅動管123密接設置的4個滾子 122所構成（參照圖4)。連接於電動機121之鏈輪141 與鏈條142相嚙合，使電動機121轉動，而而讓固定於其 之鏈輪141旋轉，則嚙合於鏈輪141之鏈條142及驅動管 12旋轉，使得與其連接之篩11旋轉。4個滾子122支承 驅動管123、篩1 1、及延長管13，而可圓滑地旋轉。在 電動機121的電路（例如）設有變換器，可調節、變更電 動機121的旋轉數。這是意味著可將篩11的旋轉數（理 想）調節成12〜28rpm。 延長管13連接於圓筒狀的篩11的出口側。此延長管 1 3係呈與篩1 1同徑的圓筒狀，但非以鋼索所形成的篩， 而是圓筒狀的金屬板。 螺旋狀的導引板15係在篩11及與篩連接的延長管 1 3的內周面，自篩1 1的入口側到出口側進一步到延長管 13 (例如）連續地設置著（參照圖2A〜圖2C )。藉由此 螺旋狀的導引板15’在篩Π及延長管13的內周面形成 溝槽151。此螺旋狀的導引板15的條數（理想）爲4〜8 -19- 201217039 ，高度Η (理想）爲5〜15cm，並對篩呈垂直地設置爲佳 (參照圖2B及圖2C)。 外殻18係將篩11、驅動機構12、延長管13、導引 板15、液體噴射機構16、液體噴射機構17、液體噴射機 構21、液體噴射機構22、及液體噴射機構23這些予以包 圍，並且在上方具有檢查口 181，而在下方具有排出口 182(參照圖1A〜圖1D)。又，液體噴射機構21及液體 噴射機構22安裝於外殼18的內面。外殼18的頂面係形 成爲斷面呈梯形，在其斜面設有檢查口 181 (參照圖1C 及圖1 D )。又，外殼1 8的底面傾斜而窄成錐狀，在其終 端設有排出口 1 8 2 (參照圖1 A )。 在外殻1 8，檢查口 1 81係形成爲外殼1 8的內面（以 斷面成爲梯形的方式所形成之頂面）呈平坦（參照圖6A )。因此，藉由自後述的噴射噴嘴213所噴射的液體的噴 射流6 1，可良好地防止屑粒之附著、凝集。在如圖6B所 示的以往的形態，僅檢查口 62以凹陷的方式設置，其結 果，造成在外殻的內面形成凸凹。如此，在液體的噴射流 61，無法對外殼內面均等地（遍及）噴射液體，會有無法 去除附著的屑粒63之虞，但，若藉由外殼18的檢查口 1 8 1，則不會有這樣之虞產生。 又，在外殻18的入口側（配置驅動管12之位置）的 滾子122存在之空間和被分離的熱水流動之部分之間、及 外殼18的出口側（配置延長管13之位置）的被分離的熱 水流動之部分與出口側的滾子1 22所存在的空間之間，分 -20- 201217039 別設有減渦板1 3 1，用以自外側（滾子1 22存在之空間） 遮斷內側（被分離的'熱水流動之空間）（參照圖3及圖4 )。藉由此減渦板1 3 1，可防止異物自外側侵入到系統內 (外殼1 8中之水流動的部分）。 液體噴射機構16係藉由連接於液體源（未圖示）之 配管162、和設置於其之噴射噴嘴161所構成。配管162 ，以呈2列的方式設置於篩1 1的（外周面的）斜上方（ 參照圖1B〜圖1D)，在每1列，（理想）設有8〜14個 噴射噴嘴161。噴射噴嘴161的噴射對象處’主要爲篩11 的外周面。 液體噴射機構17係藉由連接於液體源（未圖示）之 配管172、和設置於其前端之噴射噴嘴所構成（參照 圖1A及圖1D)。配管172係在延長管13(篩11的出口 附近），配設成自上方朝與圓筒狀的篩11 (延長管13) 的軸方向呈垂直之面（圓形）的中心延伸。又，在中心（ 配管172之前端），設有（例如）2個噴射噴嘴171。2 個噴射噴嘴171的噴射對象處，皆爲篩11的內周面上側 〇 液體噴射機構21係藉由連接於液體源（未圖示）之 配管212、和設置於其前端之噴射噴嘴211、及噴射噴嘴 213所構成（參照圖1A〜圖1D)。噴射噴嘴211係以（ 例如）朝向四方的方式’呈4個設置於外殻18的頂面的 略中央。噴射噴嘴211的噴射對象處爲外殼18的4個側 面。噴射噴嘴2 1 3係呈（例如）2列的方式設置於外殼1 8 -21 - 201217039 的頂面。此噴射噴嘴2 1 3的噴射對象處係朝向重點地洗淨 容易產生屑粒之附著且與篩平行之側面（2面）。 液體噴射機構22係藉由連接於液體源（未圖示）之 配管22 2、和設置於其前端之噴射噴嘴22 1所構成（參照 圖1A、圖1B、及圖5A)。噴射噴嘴221係在外殼18的 底面中之出口側（延長管13的側）的角部分（角落部分 )，呈（例如）4個的方式設置著。噴射噴嘴221的噴射 對象處爲外殼1 8的側面的下側、及底面。液體噴射機構 22之4個噴射噴嘴221，以噴射位置偏移的方式安裝著， 藉此，可防止液體的噴射流51的衝撞、相互干涉，可有 效率地使液體朝外殼的底面與側面的下側衝撞，可防止屑 粒之附著、凝集。在如圖5 B所示的形態，4個噴射噴嘴 5 2之噴射位置係形成相同，造成液體的噴射流51衝撞且 相互干涉。又，藉由篩11進行與屑粒分離之熱水，由於 會在篩1 1的單一側（篩1 1旋轉，而屑粒存在之側）會被 多數分離，故，熱水的流向容易偏向單一側。因此，在外 殼的底面中，容易產生流動不均，流動弱（流量少）之部 位，會容易堆積自篩的網眼脫離之屑粒、自壁面剝落之屑 粒53。相對於此，如液體噴射機構22這樣地，採取調整 液體的噴射位置且所噴射之液體彼此不會相互干涉之構造 ，則不會產生這種問題。 液體噴射機構23係配置於大致與液體噴射機構1 7相 同的位置。此液體噴射機構23係藉由連接於液體源（未 圖示）之配管232、和設置於其前端之噴射噴嘴231所構 -22- 201217039 成（參照圖1A及圖ID )。配管23 2係在延長管13 (篩 11的出口附近）配設成自上方朝與圓筒狀的篩11 (延長 管13)的軸方向呈垂直之面（圓形）的中心延伸。又， 在中心（配管2 3 2之前端），設有（例如）1個噴射噴嘴 231。噴射噴嘴23 1的噴射對象處爲延長管13的內周面下 側。 其次，針對製造本發明之固體狀聚合物用分離裝置的 方法，以固體狀聚合物用分離裝置1爲例進行說明。 固體狀聚合物用分離裝置1係可藉由購買市面販賣之 構件、板金或進行加工來組裝所獲得。用來形成篩1 1 ( 鋼索111及其固定構件）、.驅動機構12的驅動管123、 延長管13、導引板15、液體噴射機構16，17，21，22， 23的配管及噴射噴嘴、及外殼18(包含減渦板）之材料 ，理想爲不銹鋼。具體而言，SUS304、SUS316(日本工 業規格）等。特別是使用低碳之不銹鋼爲佳。驅動機構 12的滾子，使用由高強度之樹脂材料（工程塑料）所構 成者爲佳。具體而言，可舉出MC尼龍（登錄商標，聚醯 胺系樹脂）。 其次’針對本發明之橡膠材料的製造方法，以丁二烯 橡膠之情況爲例進行說明。又，透過該情況，亦以使用前 述固體狀聚合物用分離裝置1之情況爲例，針對本發明之 固體狀聚合物的分離方法進行說明。 首先，準備丁二烯單體（1,3-丁二烯）。其一般係除 了藉由將從原油所取出之石腦油之熱分解（作爲副產物）S -17- 201217039 A device that is small and excellent in environmental load. [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the drawings. However, the present invention is not limited to the embodiments, and various modifications can be made based on the knowledge of the manufacturer without departing from the scope of the technical spirit of the present invention. Correction and improvement. For example, the drawings show the embodiments of the present invention, but the present invention is not limited to the embodiments shown in the drawings, the information shown in the drawings, and the like. The same means or equivalent means as used in the present specification are applied to the practice or verification of the present invention, but the preferred means are as described below. Furthermore, in FIG. 1A to FIG. ID, the inside is also depicted by a solid line. First, the configuration of the separation device for a solid polymer of the present invention will be described. The separation device 1 for a solid polymer shown in Figs. 1A to 4, 5A, and 6A is capable of separating crumbs (solid polymer) dispersed in hot water (liquid) from the hot water. Device. The separation device 1 for a solid polymer includes a sieve 11, a drive mechanism 12, an extension pipe 13, a guide plate 15, a liquid ejecting mechanism 16 (first liquid ejecting mechanism), and a liquid ejecting mechanism 17 (second liquid ejecting mechanism) The liquid ejecting mechanism 21 (third liquid ejecting mechanism), the liquid ejecting mechanism 22 (fourth liquid ejecting mechanism), the liquid ejecting mechanism 23 (the fifth liquid ejecting mechanism), and the outer casing 18. The sieve 11 has a cylindrical shape, and its circumferential surface (ideally) is formed so that the steel wires 1 1 1 having a triangular cross section are regularly and parallelly arranged and fixed in the axial direction of the cylindrical sieve 11 (refer to 2A to 2C). Further, -18-201217039, by the cable 111, a plurality of slits 112 for supplying hot water are formed. The width (mesh opening) of the slit 1 12 (ideally) is 1.5 to 2.5 mm. The driving mechanism 12 is a means for rotating the screen 11 in the circumferential direction S (see Figs. 2B and 2C). The drive mechanism 12 is wound around the circumference of the drive tube by a motor 121, a sprocket 141 connected to the motor, and a drive tube 123 connected to the inlet side of the screen 11 (see the left side in FIGS. 1A and 2A). The chain 142 and the four rollers 122 that are in close contact with the drive tube 123 are formed (see FIG. 4). The sprocket 141 connected to the motor 121 is engaged with the chain 142 to rotate the motor 121, and the sprocket 141 fixed thereto is rotated, and the chain 142 and the drive tube 12 meshed with the sprocket 141 are rotated to be connected thereto. The screen 11 is rotated. The four rollers 122 support the drive tube 123, the screen 1 1 and the extension tube 13 to be smoothly rotated. An inverter is provided in the circuit of the motor 121, for example, to adjust and change the number of revolutions of the motor 121. This means that the number of rotations of the sieve 11 (ideally) can be adjusted to 12 to 28 rpm. The extension pipe 13 is connected to the outlet side of the cylindrical sieve 11. The extension pipe 13 has a cylindrical shape having the same diameter as the sieve 1, but is not a sieve formed of a steel wire but a cylindrical metal plate. The spiral guide plate 15 is attached to the inner peripheral surface of the sieve 11 and the extension pipe 13 connected to the sieve, and is continuously provided from the inlet side to the outlet side of the sieve 11 to the extension pipe 13 (for example) (refer to the figure). 2A~Fig. 2C). A groove 151 is formed in the inner circumferential surface of the sieve and the extension pipe 13 by the spiral guide plate 15'. The number of the spiral guide sheets 15 (ideally) is 4 to 8 -19 to 201217039, and the height Η (ideally) is 5 to 15 cm, and it is preferable to set the screen vertically (refer to FIG. 2B and FIG. 2C). . The outer casing 18 surrounds the sieve 11, the drive mechanism 12, the extension pipe 13, the guide plate 15, the liquid ejecting mechanism 16, the liquid ejecting mechanism 17, the liquid ejecting mechanism 21, the liquid ejecting mechanism 22, and the liquid ejecting mechanism 23. Further, the inspection port 181 is provided on the upper side and the discharge port 182 is provided on the lower side (see FIGS. 1A to 1D). Further, the liquid ejecting mechanism 21 and the liquid ejecting mechanism 22 are attached to the inner surface of the outer casing 18. The top surface of the outer casing 18 has a trapezoidal cross section, and an inspection port 181 is provided on the inclined surface thereof (see Figs. 1C and 1D). Further, the bottom surface of the outer casing 18 is inclined and narrowly tapered, and a discharge port 1 8 2 is provided at the terminal end thereof (see Fig. 1A). In the outer casing 18, the inspection port 1 81 is formed such that the inner surface of the outer casing 18 (the top surface formed in a trapezoidal cross section) is flat (see Fig. 6A). Therefore, the adhesion and aggregation of the crumbs can be favorably prevented by the jet flow 61 of the liquid ejected from the injection nozzle 213 to be described later. In the conventional embodiment shown in Fig. 6B, only the inspection port 62 is provided in a recessed manner, and as a result, a convexo-concave is formed on the inner surface of the outer casing. As described above, in the liquid jet 61, the liquid cannot be ejected evenly over the inner surface of the outer casing, and there is a possibility that the adhered scraps 63 cannot be removed. However, if the inspection port 18 1 of the outer casing 18 is not used, There will be such a flaw. Further, between the space where the roller 122 on the inlet side of the outer casing 18 (the position where the drive pipe 12 is disposed) and the portion where the separated hot water flows, and the outlet side of the outer casing 18 (the position where the extension pipe 13 is disposed) Between the part where the separated hot water flows and the space where the roller 1 22 on the outlet side exists, the -20-201217039 is provided with a vortex plate 1 3 1 for the space from the outside (the roller 1 22 exists) ) Interrupted inside (space where the separated hot water flows) (see Figures 3 and 4). By the vortex plate 133, foreign matter can be prevented from intruding into the system from the outside (the portion where the water flows in the outer casing 18). The liquid ejecting mechanism 16 is constituted by a pipe 162 connected to a liquid source (not shown) and an injection nozzle 161 provided therein. The piping 162 is provided in two rows so as to be obliquely upward (see Fig. 1B to Fig. 1D) of the screen 1 1 (see Fig. 1B to Fig. 1D), and 8 to 14 injection nozzles 161 are provided (ideally) in each row. The injection target portion ' of the injection nozzle 161 is mainly the outer peripheral surface of the screen 11. The liquid ejecting mechanism 17 is constituted by a pipe 172 connected to a liquid source (not shown) and an injection nozzle provided at the tip end thereof (see Figs. 1A and 1D). The pipe 172 is disposed in the extension pipe 13 (near the outlet of the sieve 11), and is disposed so as to extend from the upper side toward the center perpendicular to the axial direction of the cylindrical sieve 11 (extension pipe 13). Further, at the center (the front end of the pipe 172), for example, two injection nozzles 171 are provided. The injection targets of the two injection nozzles 171 are both on the inner peripheral surface of the screen 11 and the liquid ejecting mechanism 21 is connected by The pipe 212 of the liquid source (not shown), the injection nozzle 211 provided at the tip end thereof, and the injection nozzle 213 are formed (see FIGS. 1A to 1D). The spray nozzles 211 are disposed in the center of the top surface of the outer casing 18 in a manner of, for example, four sides. The ejection target of the ejection nozzle 211 is the four sides of the outer casing 18. The injection nozzles 2 1 3 are provided on the top surface of the outer casing 18 - 21 - 201217039 in a row of, for example, two rows. The injection target portion of the injection nozzle 2 1 3 is washed toward the center, which is easy to generate adhesion of the crumb and is parallel to the screen (two sides). The liquid ejecting mechanism 22 is constituted by a pipe 22 connected to a liquid source (not shown), and an injection nozzle 22 1 provided at the tip end thereof (see Figs. 1A, 1B, and 5A). The injection nozzle 221 is provided at an angular portion (corner portion) on the outlet side (the side of the extension pipe 13) in the bottom surface of the outer casing 18, for example, in four. The ejection target of the ejection nozzle 221 is the lower side of the side surface of the outer casing 18, and the bottom surface. The four injection nozzles 221 of the liquid ejecting mechanism 22 are attached so that the ejection position is shifted, whereby the collision and mutual interference of the liquid ejection flow 51 can be prevented, and the liquid can be efficiently directed toward the bottom surface and the side surface of the outer casing. The lower side collides to prevent adhesion and agglomeration of the crumb. In the form shown in Fig. 5B, the ejection positions of the four ejection nozzles 52 are formed identically, causing the jets 51 of the liquid to collide and interfere with each other. Further, since the hot water separated from the crumb by the sieve 11 is mostly separated on the single side of the sieve 1 (the sieve 11 is rotated and the crumb is present), the flow of the hot water is easily biased. One side. Therefore, in the bottom surface of the outer casing, unevenness in flow and weak flow (less flow rate) are likely to occur, and it is easy to accumulate crumbs which are detached from the mesh of the sieve and scraps 53 which are peeled off from the wall surface. On the other hand, as in the liquid ejecting mechanism 22, such a configuration is adopted in which the ejection position of the liquid is adjusted and the ejected liquids do not interfere with each other, such a problem does not occur. The liquid ejecting mechanism 23 is disposed at substantially the same position as the liquid ejecting mechanism 17. The liquid ejecting mechanism 23 is formed by a pipe 232 connected to a liquid source (not shown) and an injection nozzle 231 provided at the tip end thereof (see Fig. 1A and Fig. ID). The pipe 23 2 is disposed so as to extend from the upper side toward the center of the surface (circular shape) perpendicular to the axial direction of the cylindrical sieve 11 (extension pipe 13) in the extension pipe 13 (near the outlet of the sieve 11). Further, at the center (the front end of the pipe 2 3 2), for example, one injection nozzle 231 is provided. The injection target of the injection nozzle 23 1 is the lower side of the inner peripheral surface of the extension pipe 13. Next, a method for producing a solid polymer separation device of the present invention will be described by taking a solid polymer separation device 1 as an example. The separation device 1 for a solid polymer can be obtained by assembling a commercially available member, sheet metal or processing. Pipe and spray nozzle for forming the screen 1 1 (the cable 111 and its fixing member), the drive tube 123 of the drive mechanism 12, the extension tube 13, the guide plate 15, and the liquid ejecting mechanisms 16, 17, 21, 22, 23 And the material of the outer casing 18 (including the vortex plate), ideally stainless steel. Specifically, SUS304, SUS316 (Japanese Industrial Standards) and the like. In particular, it is preferable to use a low carbon stainless steel. It is preferable that the roller of the drive mechanism 12 is made of a high-strength resin material (engineering plastic). Specifically, MC nylon (registered trademark, polyamine-based resin) can be mentioned. Next, the case of the method for producing a rubber material according to the present invention will be described by taking a case of butadiene rubber as an example. In this case, the method of separating the solid polymer of the present invention will be described by taking the case of using the above-described solid polymer separation device 1 as an example. First, a butadiene monomer (1,3-butadiene) is prepared. It is generally decomposed by thermal decomposition of naphtha extracted from crude oil (as a by-product).
S -23- 201217039 來生產外，亦可自乙烯加以製造。將此丁二烯單體與進行 脫水精製後的甲苯、苯、或二甲苯等的溶媒混合，進一步 添加鎳系的觸媒、或其他的鈦系、鈷系、鈸系、鋰系等的 觸媒並進行聚合，獲得丁二烯聚合物。然後再添加甲醇等 的聚合停止劑、必要的老化防止劑後，使105〜200 °c之 蒸氣作用，而去除溶媒。 在此’ 丁二烯聚合係在屑粒（小塊）的狀態下，分散 於因蒸氣所生成之熱水中的狀態。因此，使用固體狀聚合 物用分離裝置1，將丁二烯聚合物自熱水加以分離。此分 離係在固體狀聚合物用分離裝置1，預先使篩1 1朝篩i i 的圓周方向之與導引板15的螺旋狀的方向相對之方向旋 轉’從篩11的入口（驅動管123的側），將分散於熱水 中之丁二烯聚合物連續地投入即可。於是，熱水通過縫細 112，自外殻18的排出口 182排出，另外，丁二烯聚合物 從熱水被分離，而殘留於篩11的內周面，隨著螺旋狀的 導引板15的導引，以每定量的方式，從篩n的出口（延 長管13的側）移送至下一個製程。 然後’將丁 一稀聚合物以脫水裝置進一步進行脫水後 ’再以乾燥裝置予以乾燥’再以（例如）沖壓成形裝置成 形爲預定的塊形狀’再實施必要之包覆，獲得橡膠材料（ 中間製品）。 [產業上的利用可能性] 本發明之固體狀聚合物用分離裝置係可在各種橡膠製 •24- 201217039 品的製造過程，理想地利用來作爲將分散於液體中之固s 狀聚合物從該液體予以分離之手段。 【圖式簡單說明】 圖1A係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，透視內部之正面圖。 圖1B係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，透視內部之平面圖（上面圖）。 圖1C係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，透視內部之左側面圖。 圖1D係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，透視內部之右側面圖。 圖2A係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，顯示圓筒狀的篩及與其連接的延長 管及驅動管之正面圖。 圖2B係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，僅顯示圓筒狀的篩之右側面圖。 圖2C係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，顯示圓筒狀的篩及延長管之斜視圖 〇 圖3係示意地顯示本發明之固體狀聚合物用分離裝置 的一實施形態之圖，將其一部分（左端部周邊）透視並加 以顯示之部分正面圖。 圖4係示意地顯示本發明之固體狀聚合物用分離裝置S -23- 201217039 To be produced, it can also be made from ethylene. The butadiene monomer is mixed with a solvent such as toluene, benzene, or xylene which is subjected to dehydration purification, and a nickel-based catalyst or other titanium-based, cobalt-based, lanthanide-based, or lithium-based catalyst is further added. The polymerization was carried out to obtain a butadiene polymer. Then, a polymerization stopper such as methanol or a necessary anti-aging agent is added, and then a vapor of 105 to 200 ° C is applied to remove the solvent. Here, the butadiene polymerization is in a state of being scraped (small pieces) in a state of being dispersed in hot water generated by steam. Therefore, the butadiene polymer is separated from the hot water by using the separation device 1 for the solid polymer. This separation is performed in the separation device 1 for a solid polymer, and the sieve 1 1 is previously rotated in the direction opposite to the spiral direction of the guide plate 15 in the circumferential direction of the sieve ii 'from the inlet of the sieve 11 (the drive tube 123 On the side, the butadiene polymer dispersed in hot water may be continuously supplied. Then, the hot water is discharged from the discharge port 182 of the outer casing 18 through the slit 112, and the butadiene polymer is separated from the hot water and remains on the inner peripheral surface of the sieve 11, with the spiral guide plate The guidance of 15 is transferred from the outlet of the screen n (the side of the extension tube 13) to the next process in a quantitative manner. Then, 'the D-thin polymer is further dehydrated by a dehydration device, and then dried by a drying device', and then formed into a predetermined block shape by, for example, a press forming device, and then necessary coating is carried out to obtain a rubber material (middle) product). [Industrial Applicability] The separation device for a solid polymer of the present invention can be suitably used as a solid s-like polymer dispersed in a liquid in the production process of various rubber products from 24 to 201217039. The means by which the liquid is separated. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1A is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, and a front view of the inside of a see-through. Fig. 1B is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, and a plan view of the inner portion (top view). Fig. 1C is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, and a left side view of the inside of the see-through. Fig. 1D is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, and a right side view of the inside of the see-through. Fig. 2A is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, showing a front view of a cylindrical sieve and an extension pipe and a drive pipe connected thereto. Fig. 2B is a view schematically showing an embodiment of the separating apparatus for a solid polymer of the present invention, showing only the right side view of the cylindrical sieve. 2C is a view schematically showing an embodiment of the separation device for a solid polymer of the present invention, showing a cylindrical sieve and an elongated tube. FIG. 3 is a view schematically showing the solid polymer of the present invention. A diagram of an embodiment of the separating apparatus, a part of which (the periphery of the left end) is seen through and partially displayed. Figure 4 is a view schematically showing a separation device for a solid polymer of the present invention
S -25- 201217039 的一實施形態之圖’顯示僅取出驅動機構後，自左側觀看 的樣子之圖。 圖5A係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，顯示外殼的底面之圖。 圖5B係顯示以往的固體狀聚合物用分離裝置的一例 之圖，爲與圖5A對應之圖。 圖6A係示意地顯示本發明之固體狀聚合物用分離裝 置的一實施形態之圖，顯示外殻的頂面中設置於斜面之檢 查口的圖。 圖6B係顯不以往的固體狀聚合物用分離裝置的一·例 之圖，爲與圖6A對應之圖。 【主要元件符號說明】 1:固體狀聚合物用分離裝置 11 :篩 1 2 ·驅動機構 13 :延長管 15:(螺旋狀的）導引板 1 6 :液體噴射機構 1 7 :液體噴射機構 18 :外殻 2 1 :液體噴射機構 22 :液體噴射機構 23 :液體噴射機構 -26-A diagram of an embodiment of S-25-201217039' shows a view of a state seen from the left side only after the drive mechanism is taken out. Fig. 5A is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, showing a bottom surface of the outer casing. Fig. 5B is a view showing an example of a conventional separation device for a solid polymer, and corresponds to Fig. 5A. Fig. 6A is a view schematically showing an embodiment of a separating apparatus for a solid polymer of the present invention, showing a view of an inspection port provided on a slope of a top surface of the outer casing. Fig. 6B is a view showing an example of a separation apparatus for a solid polymer which is not conventional, and corresponds to Fig. 6A. [Description of main components] 1: Separation device for solid polymer 11 : Screen 1 2 · Drive mechanism 13 : Extension tube 15 : (spiral) guide plate 1 6 : Liquid ejecting mechanism 1 7 : Liquid ejecting mechanism 18 : Housing 2 1 : Liquid ejecting mechanism 22 : Liquid ejecting mechanism 23 : Liquid ejecting mechanism -26 -