201215673 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種用於衛浴領域’特別是施用於一衛 浴用品上的附著劑，例如施用於一便器。 【先前技術】 此類附著劑具有黏性，通常為糊狀，其自一適當之容 器直接覆於衛浴用品表面，附著於此，須經相對多次沖洗 方能脫離表面。 WO 99/66017揭示一種用於清潔及芳香之衛浴附著 劑，其含有表面活性劑、水、芳香劑及助黏劑。將該衛浴 附著劑直接施用於衛浴用品上後，須經相對多次沖洗方能 被沖刷掉。 EP 1 325 1 03 B 1揭示此種衛浴附著劑的一改良方案， 其因添加有多元醇而表面更為光滑。 EP 1 3 1 8 19 1 B 1揭示其他衛浴附著劑，此等附著劑基 於含寡聚伸烷基氧化物或聚伸烷基氧化物之嵌段共聚物或 基於芳基乙氧化物或烧基芳基乙氧化物，DE 10 2004 056 5 5 4 A 1則揭示含漂白劑之衛浴附著劑。 该等習知之衛浴附著劑可藉由恰當之設備以簡單且衛 生之方式進行施加’其附著於衛浴用品表面’保持其形狀 不變，水無法將其完全沖刷，須經多次沖洗方會逐漸完全 溶解。 此等衛浴附著劑之優點主要在於，可避免使用例如所 4 201215673 謂之“廊所小筐”（Wc_K0rbchen)的附加容器，人們認為，該 等附加容器之使用是不衛生的，特別是指在替換衛浴附著 劑或清潔便器時。 近年來湧現了多種使用在便器之廁所小筐中之傳統塊 狀廁所清潔劑及芳香劑的多相產品： 例如WO 00/23558所揭示之含附加漂白劑的衛浴附著 劑’ EP 1 41 8 225 A1所揭示之含清潔劑型體相及凝膠相的 衛浴附著劑，以及W0 00/58434所揭示之清潔劑型體，其 包括一含水溶性鹽類及非水溶性鹽類的相。 該等多相附著劑可藉由將一廁所清潔劑及芳香劑劃分 為需完成各種功能之多個相，舉例而言，一專門相用於強 效芳香，一專門相用於清潔，從而可更佳地滿足用戶要求。 '【發明内容】 本發明之目的在於提供一種可以簡單且衛生之方式施 用的衛浴附著劑’其可多方面應用，且在強效芳香及有效 清潔方面可滿足用戶需求。 此目的藉由如請求項1之特徵而達成。 本發明出人意料地發現，一黏度至少為3〇 pa s(在剪切 梯度為2.62 s-i及20t下，使用黏度計、板/板系統 測量，板徑為10 _)且含填充劑及一助黏劑之衛浴附著劑 不僅可直接施加於衛浴用品上，附著於此，須經相對多次 沖洗方會被沖掉、然而’亦可藉由其黏性將塊狀衛浴附著 劑附著在便器上，纟中’該助黏劑選自氫化之聚笨乙烯衍 201215673 烯烴均聚物及兩個或兩個以 組，且其_ , M & % & 上埽烴之共聚物之群 "經均聚物及共聚物 專用助黏劑用於使衛浴附著劑附著皮:：風化。 上，以及將其他材料(如含有具清潔或芳香:：冷用品表面 的塊狀衛浴附著劑)黏著於附著劑表面之有效成分 特點在於，含有此助_之衛_ 匕4助1占劑之另一 刷掉，含有此附者劑可不留痕跡地被沖 有此助黏劑之衛浴附著劍中狀打* 合比的變化對彳κ — 力點劑與填充劑之混 夂化對術冷附著劑無明顯影響。 藉由添加適當之填充劑可對 沖刷性進行調節，以刀#〜、,、 香則之黏度及/或可 色效果。 以及使料附著劑達到預期之芳香及染 本發明之衛浴附著劑具有廣泛用途·· 字u·心附著劑用在“純專占著劑 了被用戶認為是不衛生之廟所小望广口:者㈣成為 表面之附著劑上可附著含有…施用於便器 著劑，如且有卞” Λ刀且具自有功能的塊狀附 ㈣I、有-或多個相的傳統清潔塊 潔塊、芳香片劑、含有漂、：：香相的々 衛生地取代腐所小Μ，反霜塊其令，附著劑 反覆沖洗後與黏著於其上的塊狀附 劑或含有效成分之水、容性Λ 或 製而成的片 上。 /生或非水溶性塑膠附著於附著劑 在此種應用方式φ 万式中，该術浴附著劑含有至少一本 =助黏劑及—增稍劑。由於本發明之助黏劑通常為黏性液 體，故必須添加-增稠劑作為填充劑，方能使該衛浴附著 6 201215673 ‘劑之=制〇hGPas之預期值。 • s然亦可在邊由助黏劑及描 加其他成分，例如染料、^周劑組成之基礎配方中添 泡劑等。 蜊、（視情況）表面活性劑及起 根據第一具體實例的— 助黏劑及增稠劑外還含'^方案杨☆附著劑除 到黏著及芳香兩種ί用香料’故該衛浴附著劑可同時起 在第二應用方式中’該附著劑 作為填充劑的表面活性 $月之助黏剤及 夕甘从； ^ 因而藉由對表面活性劑及可能 自身即具有清潔功…，仃適田遥擇，可使該附著劑 、此利用勘附作用可在便芎中祐Λ 1 -Wr 期望之有效附著劑，存“此〇 』隹便盗中施加其他 及廣告載體等 例如將❹劑、漂白片劑、除垢片劑 藉由具清潔作用之附著劑， 選擇相應之香味以月虚 "伋據自身思願201215673 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to an adhesive agent for use in the sanitary field, particularly for application to a sanitary ware, such as a toilet. [Prior Art] Such an adhesive is viscous, usually in the form of a paste, which is applied directly to the surface of a sanitary article from a suitable container, and is attached thereto to be detached from the surface after a relatively large number of flushes. WO 99/66017 discloses a sanitary and fragrant sanitary adhesive comprising a surfactant, water, a fragrance and an adhesion promoter. After the sanitary adhesive is applied directly to the bathroom, it must be washed out after relatively many flushes. EP 1 325 1 03 B 1 discloses a modification of such a bathroom adhesive which has a smoother surface due to the addition of a polyol. EP 1 3 1 8 19 1 B 1 discloses other bathroom adhesives based on block copolymers containing oligomeric alkylene oxide or polyalkylene oxide or based on aryl ethoxylates or alkylates Aryl ethoxylates, DE 10 2004 056 5 5 4 A 1 , disclose bathing agents containing bleaching agents. These conventional sanitary adhesives can be applied in a simple and hygienic manner by means of appropriate equipment to 'attach them to the surface of the bathroom' to keep their shape unchanged, water cannot be completely washed out, and it is necessary to wash it multiple times. completely dissolved. The advantage of these sanitary adhesives is that they avoid the use of additional containers such as the "Small Baskets" (Wc_K0rbchen), which are considered to be unsanitary, especially in the use of such additional containers. When replacing bathroom adhesives or cleaning the toilet. In recent years, a variety of multi-phase products of conventional block toilet cleaners and fragrances used in toilet baskets have been emerging: for example, bathroom adhesives containing additional bleach disclosed in WO 00/23558 'EP 1 41 8 225 A sanitary ware comprising a detergent-type body phase and a gel phase disclosed in A1, and a detergent formulation disclosed in WO 00/58434, comprising a phase comprising a water-soluble salt and a water-insoluble salt. The multi-phase adhesive can be divided into a plurality of phases for performing various functions by dividing a toilet detergent and a fragrance. For example, a special phase is used for a strong fragrance, and a special phase is used for cleaning. Better meet user requirements. [Explanation] It is an object of the present invention to provide a sanitary ware agent that can be applied in a simple and hygienic manner, which can be applied in various aspects, and can meet user needs in terms of strong aroma and effective cleaning. This object is achieved by the features of claim 1. The present invention surprisingly finds that a viscosity of at least 3 〇pa s (measured using a viscometer, a plate/plate system, a plate diameter of 10 _ at a shear gradient of 2.62 si and 20 t) and containing a filler and an adhesion promoter The bathroom adhesive agent can be directly applied to the sanitary ware, and it is attached to the bathroom. It must be washed out after a relatively large number of rinsings. However, it can also be attached to the toilet by its adhesiveness. 'The adhesion promoter is selected from the group consisting of hydrogenated polystyrene ethylene derivative 201215673 olefin homopolymer and two or two groups of copolymers of _, M & % & upper terpene hydrocarbons" Adhesives for polymers and copolymers are used to attach sanitary adhesives to the skin: weathering. And the active ingredient of other materials (such as a block-shaped bathroom adhesive containing a clean or aromatic:: cold surface) adhered to the surface of the adhesive agent is characterized by the inclusion of the aid _ _ _ 4 help 1 agent Another brushed off, containing this additive can be washed without any traces of the adhesive attached to the bathroom attached to the sword in the shape of the match * the change of the ratio 彳 κ - the combination of the force agent and the filler The adhesive has no significant effect. The scouring property can be adjusted by adding a suitable filler to achieve the viscosity and/or color effect of the knife #~, ,, and the fragrance. And the adhesive agent to achieve the desired aroma and dyeing the bathroom adhesive of the invention has a wide range of uses. · The word u · heart adhesive is used in the "pure special occupation of the temple that is considered by the user to be unsanitary." (4) It can be attached to the surface of the adhesive agent, which can be applied to the toilet agent, such as a squeegee and has its own function, and has a traditional cleaning block, aroma, and a plurality of phases. Tablets, containing bleaching::: fragrant sputum to replace the sputum sputum hygienic, anti-frost block, the adhesive agent is repeatedly washed and adhered to the block attached agent or water containing active ingredients, capacitive Λ or made on the film. / Raw or water-insoluble plastic attached to the adhesive agent In this application mode φ million, the bath adhesive contains at least one = adhesion promoter and - enhancer. Since the adhesion promoter of the present invention is usually a viscous liquid, it is necessary to add a thickener as a filler to enable the bathroom to adhere to the expected value of the GPhGPas. • It is also possible to add a foaming agent to the base formulation consisting of adhesion promoters and other ingredients such as dyes and elixirs.蜊, (as appropriate) surfactants and according to the first specific example - adhesion promoters and thickeners also contain '^ program Yang ☆ adhesive agent in addition to adhesive and aromatic two 用 with spices', so the bathroom attached The agent can simultaneously function in the second application mode, the surface active agent of the adhesive agent as a filler, and the benefit of the coating; Tian Yaoxuan can make the adhesive agent, the use of the splicing effect, can be used in the toilet, 1 -Wr, the desired effective adhesive agent, and the application of other and advertising carriers, such as sputum, , bleaching tablets, descaling tablets by means of a cleaning agent, choose the corresponding fragrance to the moon, "according to their own wishes
如 將相應的芳香片劑壓至已施覆之H 潔作用的附著劑上，婪龙μ w G她復之具，月 方香片劑從而可黏附於附著劑上，此 做法可使廊所持續芳香一或兩週。 膠、二::r著劑甚至可與一系列之芳香峨芳香凝 用戶從而可：、除垢片劑及強效清潔片劑等整套配合使用， 可為其附著劑進行個人化配備。 右用戶期望進行額外漂白，則可 附著劑表面。 V曰月劑黏者於 用之期望對廊所進行強效清潔’則可在已具清潔作 Α’上另黏附-清潔片劑。亦可構建由黏著劑-功能 7 201215673 附著劑-黏著劑-功垆m I才，μ 附者劑等若干層構成的多 開篇所述之習知1念丨拉 …/劑雖可良好而持久地附著於衛、、谷 口口 ，但此等衛浴附著劑上盔法“黏W4，，甘> 、 …次黏附其他附著劑。 *用於相衛生外，該附著劑亦可用作冷 由於添加有表面活性劑而可被水沖掉。該附著劑可在卜: 範圍内作為冷黏著劑用於將物體附著於小便池中，二： 用在沖淋裝置中的盟洗水槽或宽磚上，或使 了使 廳、屠宰場或其他可用水沖刷的地方。 ⑧ 餐 若將該冷黏著劑使用在可用水沖刷的地方，則 ㈣附著㈣同時亦藉由附著劑所含之表面活性劑進行清 潔0 ’月 亦可將本發明之附著劑使用於機動車之清洗震 施用於排水管或水溝上/内，從而實現暫時芳香。 一 本發明之附著劑亦可作為呈可洗刷掉的糊劑供應於斜 枓以防治害蟲使用，或將其連續使用而用於附著於淋 向戶或房屋表面。 本發明之附著劑之各成分如下： 選自聚苯乙烯衍生物群組之助黏劑尤佳為溶於礦物油 之交聯聚苯乙烯衍生物，特定言之為伸烷基苯乙烯共聚 物，例如氫化丁烯/乙烯/苯乙烯共聚物及氫化乙烯/丙烯 乙稀共聚物，此等共聚物例如由penrec〇公司以商業名 “Versagel M750”或“Versagel M1600”進行銷售。 此外可將非水溶性稀烴均聚物以及兩個及兩個以上稀 烴之共聚物用作助黏劑。舉例而言，聚丁二烯橡膠苯乙 201215673 '—締-肷段聚合物及共聚物及聚異丙烯屬於此類化合 物。亦可使用“任意（嵌段）聚合物，，（藉由在苯乙烯或（X曱基 本乙烯上1,3-加成丁二烯或異戍二烯而製成）、乙烯及丙烯 之均戎物或共聚物（如乙烯-丙烯二烯-三元共聚物、天然橡 L及降冰片烯聚合物（如聚雙環戍二烯）。選自烯烴均聚物及 八I物群組之化合物亦可部分氫化。 田然亦可將上述助黏劑之組合應用於本發明之附著 劑0 及助黏劑使該附著劑附著於衛浴用品表面。本發明之 著h丨既可附著於乾燥表面，亦可附著於潮濕表面。 此外，忒專用助黏劑亦可使所施覆之附著劑的表面具 有黏性，藉此可在該附著劑之表面黏著其他有效附著劑:、 γ泰助黏劑通常亦會產生網路狀結構，此結構使該附著 ㈣即便在受到沖洗用水之極大作用力的情況下亦能呈有必 要之形狀穩定性。 «黏劑之所用漠度取決於該助黏劑之材料類別及網 2形成能力，通常介於2爾一之間，較佳介於 人50wt%之間，尤佳介於8,4〇咖之間。 έ此外，本發明之附著劑包含填充‘，其可選自下列群 定且:表面活性劑、增稠劑、芳香劑、染料、鹽類、泡沫穩 疋Μ、柘泡劑、起泡劑及聚合天然物質。 子表：：^ I!使用所有習知的陰離子表面活性劑及/或陽離 性；以""及’或非離子性表面活性劑及/或兩性表面活 丨生劑，其中’粉末狀至硬糊狀表面活性劑為較佳之選。該 201215673 附著劑内之表面活性劑部分應介於 車乂佳為10 wt%至60 wt%，尤佳為 0 wt°/〇與 80 wt%之 25 wt%至 45 wt% 〇 間， 陰離子表面活性劑在本發明令具有多種作用；其—， 當聚合物基質為非水溶性時，陰離子表面活性劑在^破壞 黏性之情況下將該聚合物基質乳化。其次，陰離子表面: 性劑作為增黏劑（增稠劑）亦具有將該初始聚合物（助黏劑）塑 化之作用。陰離子表面活性劑較佳亦應具有強效起泡作 用’以便在便器t產生視覺上之清潔效果。最後，此類表 面活性劑亦應具有由良好之满濕特性支持的良好之 用。 、 較佳將選自羧酸鹽、硫酸半酯及磺酸之群組，較佳選 自脂肪酸、脂族烧基硫酸及烧基芳基績酸之群組的—❹ 種物質用作陰離子表面活性劑。此等陰離子表面活性劑之 碳鏈分布範圍為6至40個碳原子，較佳為8至3()個碳原 子’特定言之為12至22個碳原子。 金屬鹽類（較佳為鹼金屬鹽）及天然或合成混合物形式 之羧酸（C6-C22)以及硫酸半酯及相對長鏈醇類之鹼金屬鹽 亦可用作陰離子表面活性劑。 可用於本發明之：另一類別的陰離子表面活性劑是烷基 醚硫酸之鹼金屬鹽。烷基醚硫酸與烷基硫酸一樣係用脂肪 醇合成，脂肪醇與環氧乙烷反應生成相應之乙氧基脂肪 醇。亦可用環氧丙烷代替環氧乙烷。隨後磺化產生烷基醚 硫酸。 在本發明範圍内，亦可將烷磺酸及烯烴磺酸之鹼金屬 10 201215673 鹽用作陰離子表面活㈣卜燒韻可以末賴結（―級烧續 酸）或沿碳鏈（二級烷磺酸）之方式含有磺酸基。具代表性之 典型者係為烷基苯磺酸鹽，尤佳為直鏈烷基苯磺酸鹽 (LAS)。 上述之陰離子表面活性劑可以其中性形式單獨使用， 或彼此混合使用。 在本《明$&圍内’若以重量為基準，該表面活性劑相 車乂佳3有10糾％至9〇 wt%之月桂基硫酸鹽尤佳含有 wt%至85 wt%之月桂基硫酸鹽。 可將烧氧基化醇，較佳乙氧基化醇，特定言之含有較 佳8至㈣碳原子、每莫耳醇平均i至12莫耳環氧乙院㈣) 的一級醇用作非離子性表面活性劑，在此等醇中，醇基可 為直鏈或較佳》2位甲基支鏈，抑或含有如含氧醇基中之 混合狀態的直鏈基及甲基支鏈基。但含有碳原子數為12至 18之天然醇類(例如椰油醇、棕搁油醇、動物脂醇或油醇） ^鏈基、每莫耳醇平均2至8莫耳E〇的醇乙氧基化物為較 佳之選。除此等非離子性表面活性劑外，亦可使用12 e〇 以上的脂肪醇。例如14 E0、25 EO、30 EO或40 EO之動 物脂醇。 可將通式為烷基-0(G)的烷基醣苷用作非離子性表面活 ^ ，、中’烷基”代表含有8至22個、較佳12至18個 碳原子的—級直鏈脂族基或甲基支鏈（特定言之為2位甲基 支鏈）¾奴基，G代表含有5或6個碳原子的醣苷單元， 佳代表葡萄糖。 201215673 可用於本發明之另一較佳類別的非離子性表面活性劑 是烷基鏈中較佳含丨至4個碳原子的烷氧基化脂肪酸烷基 酯，較佳乙氧基化脂肪酸烷基酯或乙氧基化及丙氧基化脂 肪酸烷基酯，特定言之脂肪酸甲酯，此等非離子性表面活 性劑既可單獨使用，亦可與其他非離子性表面活性劑結合 使用。亦可將氧化胺用作非離子性表面活性劑，例如N_椰 油烷基-N，N-二甲胺基氧化物及N_動物脂烷基_N，N_二羥乙 基氧化胺或烧醇醯胺。 该或該等非離子性表面活性劑在整個表面活性劑相上 的含量可達50%，較佳可達3〇%，尤佳可達25%。 若需要，亦可為該表面活性劑相配備陽離子表面活性 劑或兩性表面活性劑或兩性離子表面活性劑。舉例而言， 可為兩性表面活性劑配備具有C5_C12脂肪酸含量的脂肪酸 醯胺丙基甜菜鹼，當然亦可配備兩性二乙酸酯。 陽離子表面活性劑較佳在酸性配方中與殺菌物質結合 使用。兩性離子表面活性劑可示範性地描述成四級錢成 分、鏞成分或錶成分，其藉由脂族橋鍵與一其他陰離子基 團（例如羧基、磺酸鹽、硫酸鹽、磷酸鹽或膦酸鹽）相連。 該附著劑内可繼續添加用作起泡劑的烯基磺酸鹽、醚 硫酸自旨或酸甲基牛磺酸（Sauremethyltaurid )。若需使用強 效起泡劑，則可將该表面活性劑之較佳i %至5〇%，特定言 之l-25%f換成-或乡種選自（例如）甜㈣、烧氧基化烧基 謎硫酸醋或乳糖酸衍生物之群組之起泡劑。此類起泡劑可 在具有C5-C21脂肪酸含量之脂肪酸醯胺丙基甜菜鹼（例如 12 201215673 椰油醯胺丙基甜菜鹼）、具有丨至5 E〇之月桂基醚硫酸酯的 驗丨生鹽或叙鹽、乳糖椰油醯胺（Lact〇bi〇n〇C〇C〇ylamid)、乳 糖油醯胺、乳糖動物脂醯胺等等及其混合物中選擇。此等 起泡劑可良好地進入該對壓力敏感之附著劑内。較佳使用 X Ο L車又佳粉末狀或高黏之形式存在的助表面活性劑。 除本發明之成分外，該附著劑可含有其他常用成分， 例如鹽類、殺菌劑（例如氧或氯氣釋放劑）、防腐劑（例如異 噻唑啉酮衍生物l泡沫穩定劑€例如烷醇醯胺卜疏水劑（例 如礦物油或（部分）甲基化之矽氧烷及矽烷卜鈣分散劑（如多 羧酸之鈉鹽）或染料。If the corresponding aromatic tablet is pressed onto the applied H-cleaning adhesive, the 婪龙μ w G she reconstitutes, and the Yuefangxiang tablet can adhere to the adhesive, which can make the corridor Continue to scent for one or two weeks. Glue, two::r agent can even be combined with a series of aromatic scented aroma users, such as: descaling tablets and powerful cleaning tablets, can be used for personalization of the adhesive. The right user expects additional bleaching to adhere to the surface of the agent. V 曰 剂 剂 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望 期望It is also possible to construct a conventionally known 1 丨 丨 / / / 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 2012 The ground is attached to the mouth of Wei, and Gu, but these sanitary adhesives are applied to the helmet method "stick W4, gan >, ... adhesion to other adhesives. * For phase hygiene, the adhesive can also be used as cold due to It is added with a surfactant and can be washed away by water. The adhesive can be used as a cold adhesive for attaching objects to the urinal, and 2: for washing the sink or wide brick in the shower. On or in the place where the hall, slaughterhouse or other available water is washed. 8 If the cold adhesive is used in a place where water can be washed, then (4) adhesion (4) also by the surfactant contained in the adhesive Cleaning can be carried out for 0 'month. The cleaning agent of the present invention can also be applied to the drain pipe or the gutter on the inside of the drain pipe to achieve temporary aroma. The adhesive of the present invention can also be used as a washable paste. The agent is supplied to the scorpion to control the use of pests, or It is used continuously for attachment to the surface of the house or the house. The components of the adhesive of the present invention are as follows: The adhesion promoter selected from the group of polystyrene derivatives is preferably a crosslinked polystyrene dissolved in mineral oil. Derivatives, in particular alkylene styrene copolymers, such as hydrogenated butene/ethylene/styrene copolymers and hydrogenated ethylene/propylene ethylene copolymers, such as those sold by Penrec Corporation under the trade name "Versagel" M750" or "Versagel M1600" is sold. In addition, a water-insoluble dilute hydrocarbon homopolymer and a copolymer of two or more dilute hydrocarbons can be used as an adhesion promoter. For example, polybutadiene rubber styrene 201215673 '-------polymers and copolymers and poly-isopropenes belong to such compounds. "Arbitrary (block) polymers can also be used, (by styrene or (X 曱 basic ethylene 1,3 - addition of butadiene or isoprene), homogen or copolymer of ethylene and propylene (such as ethylene-propylene diene-terpolymer, natural rubber L and norbornene polymer (such as Polybicyclononadiene) selected from olefin homopolymers and eight I The compound of the group may also be partially hydrogenated. The combination of the above adhesion promoter may be applied to the adhesive agent 0 and the adhesion promoter of the present invention to adhere the adhesive agent to the surface of the sanitary article. Attached to the dry surface, it can also adhere to the wet surface. In addition, the special adhesion promoter can also make the surface of the applied adhesive agent sticky, so that other effective adhesives can be adhered to the surface of the adhesive: γ-Tax adhesion promoters usually also have a network-like structure, which allows the adhesion (4) to have the necessary shape stability even under the extreme force of the rinsing water. «The viscosity of the adhesive depends on the moisture used. The material type of the adhesion promoter and the formation capacity of the net 2 are usually between 2 and 1, preferably between 50% and 50%, especially preferably between 8,4. Further, the adhesive of the present invention comprises a filler, which may be selected from the group consisting of: surfactants, thickeners, fragrances, dyes, salts, foam stabilizers, foaming agents, foaming agents, and Polymerize natural substances. Sub-table::^ I! Uses all conventional anionic surfactants and/or cations; with "" and 'or nonionic surfactants and/or amphoteric surface active agents, where 'powder A toluene-like surfactant is preferred. The surfactant portion of the 201215673 adhesive should be between 10 wt% and 60 wt%, especially preferably 0 wt ° / 〇 and 80 wt% 25 wt% to 45 wt% ,, anionic surface The active agent has a plurality of effects in the present invention; it is - when the polymer matrix is not water-soluble, the anionic surfactant emulsifies the polymer matrix in the event of destructive viscosity. Secondly, the anionic surface: the agent acts as a tackifier (thickener) and also has the effect of plasticizing the initial polymer (adhesion). Preferably, the anionic surfactant should also have a strong sudsing action to produce a visually cleansing effect on the toilet bowl t. Finally, such surfactants should also have good endurance supported by good full wetness characteristics. Preferably, it is selected from the group consisting of a carboxylate, a sulfuric acid half ester, and a sulfonic acid, preferably selected from the group consisting of a fatty acid, an aliphatic alkylsulfuric acid, and an alkyl aryl acid, as an anionic surface. Active agent. These anionic surfactants have a carbon chain distribution ranging from 6 to 40 carbon atoms, preferably 8 to 3 () carbon atoms', specifically 12 to 22 carbon atoms. A metal salt (preferably an alkali metal salt) and a carboxylic acid (C6-C22) in the form of a natural or synthetic mixture, and an alkali metal salt of a sulfuric acid half ester and a relatively long chain alcohol can also be used as the anionic surfactant. It can be used in the present invention: another class of anionic surfactants are the alkali metal salts of alkyl ether sulfates. The alkyl ether sulfuric acid is synthesized in the same manner as the alkyl sulfuric acid by a fatty alcohol, and the fatty alcohol is reacted with ethylene oxide to form the corresponding ethoxylated fatty alcohol. Instead of ethylene oxide, propylene oxide can also be used. Subsequent sulfonation produces alkyl ether sulfuric acid. In the scope of the present invention, an alkali metal 10 201215673 salt of an alkanesulfonic acid and an olefin sulfonic acid may also be used as an anionic surface active (four), and a rhenium may be used as a final layer (a graded acid) or along a carbon chain (a secondary alkane). The sulfonic acid) means a sulfonic acid group. A typical representative is an alkylbenzene sulfonate, more preferably a linear alkylbenzene sulfonate (LAS). The above anionic surfactants may be used singly in their neutral form or in combination with each other. In this "Bian$&inside", based on the weight, the surfactant phase car 乂佳3 has 10% to 9% by weight of lauryl sulfate, especially preferably 5% by weight to 85 wt% of laurel Base sulfate. A primary alcohol having an alkoxylated alcohol, preferably an ethoxylated alcohol, specifically containing from 8 to (4) carbon atoms, and an average of from i to 12 moles per mole of oxime (4) can be used as the nonionic A surfactant, in which the alcohol group may be a linear or preferred "2-branched methyl group" or a linear group or a methyl-branched group in a mixed state such as an oxyhydroxide group. However, it contains a natural alcohol having a carbon number of 12 to 18 (for example, cocool, palmitolol, tallow alcohol or oleyl alcohol). The chain group has an average of 2 to 8 moles per mole of alcohol. Oxylates are preferred. In addition to these nonionic surfactants, fatty alcohols of 12 e 〇 or more can also be used. For example, 14 E0, 25 EO, 30 EO or 40 EO animal alcohols. An alkyl glycoside having the formula alkyl-0(G) can be used as a nonionic surface active, and a 'alkyl group' can be a straight line containing 8 to 22, preferably 12 to 18 carbon atoms. a chain aliphatic group or a methyl branch (specifically, a 2-methyl group) 3⁄4 slave group, G represents a glycoside unit having 5 or 6 carbon atoms, preferably represents glucose. 201215673 Another useful in the present invention Preferred classes of nonionic surfactants are alkoxylated fatty acid alkyl esters preferably having from 丨 to 4 carbon atoms in the alkyl chain, preferably ethoxylated fatty acid alkyl esters or ethoxylated and Propoxylated fatty acid alkyl esters, in particular fatty acid methyl esters, these nonionic surfactants may be used alone or in combination with other nonionic surfactants. An ionic surfactant such as N_cocoalkyl-N,N-dimethylamino oxide and N_tallow alkyl_N,N-dihydroxyethylamine oxide or decylamine. The nonionic surfactant may be present in the total surfactant phase in an amount of up to 50%, preferably up to 3% by weight, particularly preferably up to 25%. The surfactant phase may also be provided with a cationic surfactant or an amphoteric surfactant or a zwitterionic surfactant. For example, the amphoteric surfactant may be provided with a fatty acid guanamine propyl betaine having a C5_C12 fatty acid content. It is of course also possible to equip the amphoteric diacetate. The cationic surfactant is preferably used in combination with a bactericidal substance in an acidic formulation. The zwitterionic surfactant can be exemplarily described as a quaternary component, a bismuth component or a table component. An aliphatic bridge is attached to a further anionic group such as a carboxyl group, a sulfonate, a sulfate, a phosphate or a phosphonate. The alkenyl sulfonate used as a foaming agent can be continuously added to the adhesive. Ether sulphuric acid or acid methyl taurine (Sauremethyltaurid). If a strong foaming agent is required, the surfactant may be preferably i% to 5%, in particular, 1-25% f A foaming agent selected from the group consisting of, for example, sweet (tetra), alkoxylated sulphuric acid sulphuric acid vinegar or a lactobionic acid derivative. Such a foaming agent can be used in fatty acids having a C5-C21 fatty acid content. Amidinopropyl beet Alkali (eg 12 201215673 cocoamidopropyl betaine), test salt or salt of lauryl ether sulfate with 丨5 E〇, lactose cocoamine (Lact〇bi〇n〇C〇 C〇ylamid), lactose amide, lactose tallowamine, and the like, and mixtures thereof. These foaming agents can well enter the pressure sensitive adhesive. It is better to use X Ο L car. A co-surfactant in the form of a powder or a high viscosity. In addition to the ingredients of the present invention, the adhesive may contain other common ingredients such as salts, bactericides (such as oxygen or chlorine gas release agents), preservatives (such as Thiazolone derivatives l foam stabilizers such as alkanolamine hydrophobizing agents (such as mineral oil or (partially) methylated decane and decane calcium dispersing agent (such as sodium salt of polycarboxylic acid) or dye .
藉由香料油或芳香劑之添加，該黏著劑亦可用於芳香 室内空氣。 A 可將各種芳香物質化合物（例如醛、醇、酯、醚、酮及 之口成產物）用作香料油或芳香劑。酯類芳香物質化合物 例如有乙酸节酿或甲酸节酯。驗類有节基乙基喊，酸類有 香茅醛，_類冑α_異曱基紫羅蘭酮，醇類有香茅醇、丁香 油酉分、香葉醇及沈香醇。烴類主要有祐類，如檸檬油精及 蒎烯。但較佳使用不同芳香劑之混合物，以便產生所期望 香未其中包括含有草本天然芳香物質混合物的香料 油，例如松油、树橘油、熏、衣草;由、薄荷油或橘皮油/ 芳香劑以介於0.25 Wt%與20 wt%之間，較佳介於3 wt% 與15 wt%之間’尤佳介於5赠。與1() «間的濃 加入該配方。 又且按 若需要，亦可在此配方内添加鹽類填充劑，例如硫酸 13 201215673 鈉’以便提高溶解速度。高至90 wt%的鹽類含量可極大地 降低產物成本。鹽類含量通常高至10 wt%，較佳高至5 wt/°強I之鹼金屬鹽（如硫酸鈉、氯化鈉或聚磷酸鈉）為適 用之瓜類亦可使用單羧酸、二羧酸及多羧酸之鹼金屬鹽 及強酸之鹼土金屬鹽（如硫酸鈣）或碳酸之鹽類。 為提高可沖刷性，可在該附著劑内添加鈣皂分散劑， 例士兩f生一丙敲g曰（Lonza KL型）或順丁烯二酸/丙烯酸-丘 聚物-納鹽（BASF公司s〇kalan系列，如s〇kaian CP5 :戈 CP45)。 該附著劑内可添加任何一種對需用染料加以處理之表 面無明顯直接性的染料填充劑。若在該配方t使用水溶性 木料·^使4 方作為成品與水接觸（例如用水沖洗便器）， 則可獲得有利色彩標高，其亦與㈠肖爭議 (Marketing-Argumenten )相關。舉例而言，-緩慢的染藍 過程（淡藍向深藍之變化過程）可指出有效成分缓缓發生作 用直至達其最佳活性。 同樣地，亦可將該附著劑調節為酸性，使其含有例如 可溶解石灰石垢或尿垢(酸)之物質作為填充劑。 此外，本發明之附著劑内亦可添加（共）增稍劑’以便提 高該附著劑之塑性。舉例而t，可㈣土、粉末狀表面活 I·生β —仙膠、聚τ二烯橡膠、聚異丙稀、敌段共聚物（含 有由寡-或聚環氧乙院及/或寡.或環氧丙烧及/或寡_或聚氧 化丁稀構成之交聯寡聚物)及芳基乙氧化物或烧基芳基乙氧 基化物用作(共)增铜劑。聚合天然物質，例如木質素或其驗 14 201215673 . 金屬鹽❹土金屬鹽，亦可料⑻增稠劑。 • '親水性三仙膠為（共）增稠劑之較佳類別。使用親水性三 仙膠可在該附著劑内產生親水性極強之化合物，將該附： 劑黏者於潮濕表面時，該化合物會“吸收”周圍水分。 此外亦可在該附著劑内添加疏水劑形式之填充劑 ^煙霧狀二氧切（Aei>()sU)，特別是完全甲基化之煙霧狀二 氧化石夕（Carbot Carbon)。 ，右心加I·夬附著速度，則可在該附著劑内添加增黏劑带 式之填充劑，特別是烴樹脂類、天然樹脂(如塔羅油松香或 香樹脂）類或聚萜烯樹脂類的增黏劑。 為了除去異味，該附著劑可含有除臭劑，此等除臭剌 較佳添加在芳香劑中。（例如）us 7,288,507 B2揭示過 除臭劑。 施用及更換本發明之附著劑時不會接觸到與廟所水槽 相連的不潔淨設備，故施用方式十分衛生。 g 4本發日月之附著劑的一大優點在於，該附著劑可按用戶 需求加以分配使用及/或用各種不同的份額包裝進行提供。 例如’該附著劑之施用可藉由注射器完成，抑或藉由恰當 之設備以經預分配之用量進行施用。此等施用設備可= 為“夾具系統，’、夾鉗或臈撕型薄片、帶有先拉元件的施用系 統，此等設備可將相應份額之附著劑安置於陶瓷表面。 本發明之附著劑亦可以簡單之方式同時施加在衛浴用 品的不同位置上’以便使多種有效附著劑(例如芳香片劑與 漂白片劑）可就近發揮其效甩。 、 15 201215673 可達到極佳之附 ’該附著劑亦不 該附著劑在衛浴用品之垂直表面上亦 著效果，即便受到沖洗用水之附加作用力 會脫落。 本發明n賴經相對乡^ ^會被沖掉 :人數取決於所用附著劑之組成、施用量及所用附著劑之幾 何形狀，在施用厚度為2m 土 j mm ·<信況下，可將贫m 著劑沖掉之沖洗次數通常介於5〇次與15〇次之間，特定言 之在12 0次以上。 若將該附著劑作為黏著劑使用在便器中，則該附著劑 之耐久性主要取決於所施用之其他附著劑（塊狀附著劑）的 耐冲洗時間。若以傳統廁所清潔塊為例，則可實現之财久 陡為100次至200次沖洗，部分情況下可達25〇次以上， 在此過程中，該附著劑逐漸隨附著材料一起被沖掉。施用 量占被黏著附著劑之質量的3 wt%至丨5 wt%，特定言之為5 wt%至 10 wt%。 本發明之附著劑較佳為白色，呈膏狀、糊狀及/或乳狀， 升;^狀穩疋，故該附著劑不會“下落，，或“下滴，’。 該附著劑即便在受到沖水過程所引起之較大力（摩擦、 變形、剪切效應）的作用時亦會保持其附著狀態及形狀。 該附著劑基本上展現假塑性，亦即，黏度隨剪力增大 而變小。但若剪切速率較低，則可觀察到極強之限流效應； 此外，黏度曲線在介於2.5 s-1與30 s·1之間的剪切速率減速 階段會出現局部最大值。顯然，該附著劑具有不同黏度範 圍’抑或该附著劑會在較短之測量時間（1 0 0秒之減速時間） 16 201215673 内改變其結構。 此附著劑在剪切梯度為2.62 s·1及20。(：下，使用Haake 黏度计、板/板系統，板徑為10 mm上所測定之黏度應為至 3〇PaS較佳應為至少45Pas，尤佳應為至少l〇〇pas。 δ亥等黏度奴佳應介於15〇 s或300 Pa s與6000 Pa s之 間’尤佳應介於20〇 Pa s與1000 Pa s之間或i_ Pa 8與 4000 Pas 之間。 本啦明之含有表面活性劑的附著劑較佳會產生細泡狀 $沬藉由恰當之添加劑（增泡劑）可對此泡沫之容積進行調 即本發明之附著劑的泡數應超過40 m卜尤佳之泡數應>6〇 更佳之泡數應為14〇 ml或超過2〇〇 。 遠附者劑之表面張力可介於5G mN/m與65 mN/m之 :二較佳之附著劑的表面張力係6〇 _岫。尤佳之附著劑 的表面張力應小於等 4於40 —表面張力係為一種用於 里度表面之可潤濕性 容易潤濕。良好…：準表面張力愈小，則該表面愈 的前提條件。㈣、效果係該附著劑具備好的清潔能力 攪拌Γ::,附著劑的製備方式係在室溫下將該各個成分 【實施方式】 說 下文將藉由不同之具體實例及試驗對本發明進行 發明說明部分文 刀末尾所附之表1集中仏 呆甲、··口出了本發明之附 17 201215673 者劑的各種配方。 表1中的沖洗次數係在2_5 g之施用量上測定的。 ’發明說明部分末尾所附之表2給出了製備本發明如们 所列之附著劑所用的原料。 ::發明配方V18至V24之黏著劑具有極佳之附著效 杲，其外表面所具之黏性可視具體之黏著劑用量黏住質量 南至50 g的傳統型廁所清潔劑。其中，塊肤附牮 質量與點著劑質量之比…塊狀附者劑之黏附 比最大為100:1，較佳最大為50:卜尤 佳竑大為1 〇:丨。洛鈇， 、，'右《大黏附面積，則可改良該附著 之m—^接果。常用之黏附面積介於1000 lW與800酿2 二：觸若成環帶狀塗覆黏著劑則黏附面積亦可 小於 400 rnm2。 在所有將該等附著劑成功沖掉的試驗中所用之 活性劑均為陰離子表面活性 、 ,,.;^ 此寺附者劑所能經受之沖 洗次數表明此等附著劑具有較高至高耐久性。 V24僅含有（陰離子）表面活 成分構成之附著劑亦且有符入_ 助^。該僅由兩種 刀，、有符合預期之附著能力、必要之溆 性及1 00次以上之沖洗次數。 “與之相反，純助黏齊！ VersageI Μι_(^τ 苯乙烯共聚物）施用在便器上後 外户A▲ 佼索牛固地黏附在便器上，細 :: 後亦不會被沖掉。此等助黏劑上亦可黏附廟： 清潔塊，但廁所清潔塊會隨黏著 、 表3表明，本發明之附著 响―起逐漸下滑。 所揭示之習知附著劑。1明顯不同於EP 1325】〇⑽ 18 201215673 測定泡數時，將1〇〇ml被調溫之母液導入一 25〇 ml令里瓶内’用PTFE塞子封閉該容量瓶。隨後將容量瓶 來Γ翻轉二十次（顛倒2G次）。分別於Immin 後碩取並記錄所產生之泡沫容積（爪丨）。 本發明經試驗之全部附著劑均既可極佳地 乾燥表面，亦可極佳地附著/黏附在濕潤表^ #讀在 ㈣==外？所具之黏性可視具體之黏著劑用 罝黏住質里…0以以上的傳統型廟所清潔劑 將該等附著劑成功沖掉的試驗中，利之表心性 陰離子表面活性劑。此等附著劑所能經受之 ‘： 此等附著劑具有較高至高耐久性。 數表月 表1 V18 V24 g g Tensopol USP 94 49.6 70.0 表面 Versagel Μ1600 36.7 30.0 Kelzan ASX 0.99 增稠劑 Orange Fun 12.71 香料 總量【g】 100.00 100 一 ... 一· ——.«« 沖洗次數 > 150 130 19 201215673 表2 製造商 型號 化學成分 功能 Tensopol USP 94 Manro Tensopol USP 94 C12-C16月桂基硫酸 鹽 表面活性劑 Orange Fun Qu est #F561415 香料 Kelzan ASX Kelco Kelzan ASX 三仙膠 增稠劑/共增稠劑 Versagel Ml600 sblack/Penreco Ml 600 礦物油（及）氫化丁烯/ 乙烯/苯乙烯共聚物 (及）氫化乙烯/丙烯/苯 乙烯共聚物 助黏劑 表 試驗编號 泡數[mm】 【Pas】，PP，10 mm， 20°(：，γ’= 2.62 s· [Pas],感測器 PK 5, 20°C, V=〇.3 s'1 表面張力 18 n.b. 328 不可測 n.b. EP 1325103 B1 所揭 示之比較凝膠 70/25/10 524 n.b. 56.6/48.7/45.5 【圖式簡單說明】 無 【主要元件符號說明】 無 20The adhesive can also be used in aromatic indoor air by the addition of perfume oils or fragrances. A Various aromatic compounds (e.g., aldehydes, alcohols, esters, ethers, ketones, and the like) can be used as a fragrance oil or a fragrance. The ester aromatic compound is, for example, an acetic acid throttling or a formic acid ester. The test class has a stilbene group, the acid has citronellal, _ class 胄α_isoindolyl ionone, the alcohol has citronellol, clove oil, geraniol and linalol. Hydrocarbons are mainly useful, such as limonene and terpenes. However, it is preferred to use a mixture of different fragrances in order to produce a desired fragrance which does not include a perfume oil containing a mixture of herbal natural fragrances, such as pine oil, tangerine oil, smoked or sorrel; from, peppermint oil or orange peel oil / The fragrance is between 0.25 Wt% and 20 wt%, preferably between 3 wt% and 15 wt%. Add the formula with 1() «. Further, if necessary, a salt filler such as sulfuric acid 13 201215673 sodium may be added to the formulation to increase the dissolution rate. Salt levels up to 90 wt% can greatly reduce product costs. The salt content is usually as high as 10 wt%, preferably as high as 5 wt/°, and the alkali metal salt (such as sodium sulfate, sodium chloride or sodium polyphosphate) is suitable for the melon, and the monocarboxylic acid can also be used. An alkali metal salt of a carboxylic acid and a polycarboxylic acid and an alkaline earth metal salt of a strong acid (such as calcium sulfate) or a salt of a carbonic acid. In order to improve the scouring property, a calcium soap dispersing agent may be added to the adhesive, such as singapore, singapore, gamma (g), or maleic acid/acrylic acid-mercapto-salt (BASF). The company s〇kalan series, such as s〇kaian CP5: Ge CP45). Any dye filler which has no direct directness to the surface to be treated with the dye may be added to the adhesive. If the water-soluble wood is used in the formulation t to make the 4 parties contact the water as a finished product (for example, flushing the toilet with water), a favorable color elevation can be obtained, which is also related to (1) Marketing-Argumenten. For example, the slow blue dyeing process (the process of light blue to dark blue) indicates that the active ingredient is slowly acting until it reaches its optimum activity. Similarly, the adhesive may be adjusted to be acidic to contain, for example, a substance which dissolves limestone scale or urinary scale (acid) as a filler. Further, a (co)additive agent may be added to the adhesive of the present invention in order to improve the plasticity of the adhesive. For example, t, (4) soil, powdery surface active I · raw β — celery, poly-t-diene rubber, polyisopropyl, enemy copolymer (containing oligo- or polyepoxy and/or oligo Or a propylene oxide and/or a crosslinked oligomer composed of oligo- or polyoxy-butyl sulphate) and an aryl ethoxylate or a calcinyl aryl ethoxylate are used as the (co) copper-donating agent. Polymerization of natural substances, such as lignin or its test 14 201215673 . Metal salt bauxite metal salt, may also be (8) thickener. • 'Hydrophilic Sanxian Gum is a preferred class of (co) thickeners. The use of hydrophilic tri-sandwich produces a highly hydrophilic compound in the adhesive which will "absorb" the surrounding moisture when adhered to a wet surface. Further, a filler in the form of a hydrophobic agent, a smog-type dioxo (Aei > (sU), in particular a completely methylated smog-like carbohydrate, may be added to the adhesive. , the right heart plus I·夬 adhesion speed, the adhesive agent can be added to the adhesive agent, especially hydrocarbon resin, natural resin (such as Tarot oil rosin or fragrant resin) or polydecene Resin tackifier. In order to remove odor, the adhesive may contain a deodorant, and such deodorant hydrazine is preferably added to the fragrance. (for example) us 7,288,507 B2 discloses a deodorant. When the adhesive of the present invention is applied and replaced, it does not come into contact with the unclean equipment connected to the sink of the temple, so the application method is very sanitary. A major advantage of g 4 of the present day is that the adhesive can be dispensed as needed by the user and/or provided in a variety of different packages. For example, the application of the adhesive can be accomplished by a syringe or by a suitable amount of equipment in a pre-dispensed amount. Such applicators can be = "clamp systems,", clamps or tear-off sheets, application systems with first pull elements, which can place a corresponding portion of the adhesive on the ceramic surface. Adhesives of the invention It can also be applied to different positions of the toiletries at the same time in a simple way so that a variety of effective adhesives (such as aromatic tablets and bleached tablets) can be used in the vicinity. 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 The agent should also not be effective on the vertical surface of the toiletries, even if it is subjected to the additional force of the rinse water. The invention will be washed away from the hometown: the number depends on the composition of the adhesive used. The application rate and the geometry of the adhesive used, in the application thickness of 2m soil j mm · < the letter, the rinse can be washed out of the m-thickness agent usually between 5 and 15 times, Specifically, it is more than 120 times. If the adhesive is used as an adhesive in a toilet, the durability of the adhesive mainly depends on the washing resistance of other adhesives (block adhesive) applied. If the traditional toilet cleaning block is taken as an example, the achievable wealth can be as long as 100 to 200 flushes, and in some cases up to 25 times, during which the adhesive is gradually washed with the attached material. The application amount is from 3 wt% to 5 wt% of the mass of the adhesive adhering agent, specifically 5 wt% to 10 wt%. The adhesive agent of the present invention is preferably white, in the form of a paste, a paste and / or milky, liter; ^ shape is stable, so the adhesive will not "fall," or "drip,". The adhesive is even subjected to the large force caused by the flushing process (friction, deformation, shear The effect of the effect) will also maintain its attachment state and shape. The adhesive agent exhibits pseudoplasticity, that is, the viscosity becomes smaller as the shear force increases. However, if the shear rate is low, it can be observed to be extremely strong. The current limiting effect; in addition, the viscosity curve will have a local maximum during the shear rate deceleration phase between 2.5 s-1 and 30 s·1. Obviously, the adhesive has different viscosity ranges or the adhesive will Change it within a shorter measurement time (deceleration time of 100 seconds) 16 201215673 The adhesion agent has a shear gradient of 2.62 s·1 and 20. (:, using a Haake viscometer, a plate/plate system, the viscosity measured on a plate diameter of 10 mm should be 3 〇 PaS. For at least 45Pas, it should be at least l〇〇pas. δ海 and other viscosity slaves should be between 15〇s or 300 Pa s and 6000 Pa s, especially between 20〇Pa s and 1000 Pa s. Between or between i_ Pa 8 and 4000 Pas. The surfactant-containing adhesive of Benjamin preferably produces a fine foam. The volume of the foam can be adjusted by a suitable additive (foaming agent). The number of bubbles of the adhesive of the present invention should exceed 40 m. The number of bubbles should be >6. The preferred number of bubbles should be 14 〇ml or more. The surface tension of the remote agent may be between 5 G mN/m and 65 mN/m: the surface tension of the preferred adhesive is 6 〇 岫. The surface tension of the preferred adhesive should be less than or equal to 4 to 40. The surface tension is a wettability for the surface of the inner surface. Good...: The smaller the quasi-surface tension, the more preconditions the surface will be. (4) The effect is that the adhesive has good cleaning ability. Stirring:: The preparation method of the adhesive is based on the components at room temperature. [Embodiment] Hereinafter, the present invention will be invented by different specific examples and tests. It is indicated that the table 1 attached to the end of the section of the knife is concentrated in the group A, and the various formulations of the invention of the invention 17 201215673 are presented. The number of rinses in Table 1 was determined on an application rate of 2 - 5 g. Table 2 attached at the end of the description of the invention gives the materials used in the preparation of the adhesives as set forth in the present invention. ::Inventive Formulations V18 to V24 adhesives have excellent adhesion. The adhesiveness of the outer surface can be adhered to the traditional toilet cleaner of quality up to 50 g depending on the specific amount of adhesive. Among them, the ratio of the mass of the skin to the mass of the pointing agent... The adhesion ratio of the block attached agent is at most 100:1, preferably the maximum is 50: Bu Youjia is 1 〇: 丨. Luo Wei, ,, 'Right' large adhesion area, can improve the attached m-^ fruit. Commonly used adhesive areas are between 1000 lW and 800. 2: The contact area of the adhesive tape can be less than 400 rnm2. The active agents used in all tests in which the adhesives were successfully washed away were anionic surfactants, and the number of rinses that the applicator was able to withstand showed that these adhesives had higher to high durability. . V24 contains only the (anionic) surface active component of the adhesive agent and also has a _ aid. There are only two types of knives, which have the expected adhesion, the necessary ambiguity and the number of rinsing times of more than 100 times. "In contrast, purely self-adhesive! VersageI Μι_(^τ styrene copolymer) is applied to the toilet and the external household A ▲ 佼 牛 固 固 fixed to the toilet, fine:: will not be washed away. These adhesion promoters may also adhere to the temple: the cleaning block, but the toilet cleaning block will stick with the adhesion, Table 3 shows that the adhesion of the present invention gradually declines. The disclosed conventional adhesive agent. 1 is significantly different from EP 1325 〇(10) 18 201215673 When measuring the number of bubbles, introduce 1 〇〇ml of the temperature-regulated mother liquor into a 25 〇ml jar. Close the volumetric flask with a PTFE stopper. Then turn the volumetric flask up and down twenty times (reversely 2G times). After the Immin, the foam volume (claw) produced is recorded and recorded. All the adhesives tested in the present invention can both dry the surface excellently and adhere or adhere to the wet table. ^ #读在(四)==外? The viscosity of the adhesive can be seen as a specific adhesive used to stick to the quality... 0 in the above-mentioned traditional type of temple cleaner to successfully wash away the adhesive agent, the advantage of the heart Anionic surfactants. These adhesives can withstand ': Adhesive agent has high to high durability. Number of watches 1 V18 V24 gg Tensopol USP 94 49.6 70.0 Surface Versagel Μ1600 36.7 30.0 Kelzan ASX 0.99 Thickener Orange Fun 12.71 Total amount of spices [g] 100.00 100 a... —.«« Number of Flushings> 150 130 19 201215673 Table 2 Manufacturer Type Chemical Composition Function Tensopol USP 94 Manro Tensopol USP 94 C12-C16 Lauryl Sulfate Surfactant Orange Fun Qu est #F561415 Spice Kelzan ASX Kelco Kelzan ASX Sanxian gum thickener / co-thickener Versagel Ml600 sblack/Penreco Ml 600 mineral oil (and) hydrogenated butene / ethylene / styrene copolymer (and) hydrogenated ethylene / propylene / styrene copolymer adhesion test table test Number of bubbles [mm] [Pas], PP, 10 mm, 20° (:, γ' = 2.62 s· [Pas], sensor PK 5, 20 ° C, V = 〇.3 s'1 surface Tension 18 nb 328 Not measurable nb EP 1325103 B1 Revealed gel 70/25/10 524 nb 56.6/48.7/45.5 [Simple diagram description] No [Main component symbol description] No 20