TW201213102A - Method for manufacturing resin sheet - Google Patents

Method for manufacturing resin sheet Download PDF

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Publication number
TW201213102A
TW201213102A TW100123411A TW100123411A TW201213102A TW 201213102 A TW201213102 A TW 201213102A TW 100123411 A TW100123411 A TW 100123411A TW 100123411 A TW100123411 A TW 100123411A TW 201213102 A TW201213102 A TW 201213102A
Authority
TW
Taiwan
Prior art keywords
shape
resin sheet
resin
transfer
roll
Prior art date
Application number
TW100123411A
Other languages
Chinese (zh)
Inventor
Hidenori Kadoya
Seiji Shiromoto
Toyohiro Hamamatsu
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2011135261A external-priority patent/JP2012144033A/en
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Publication of TW201213102A publication Critical patent/TW201213102A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/24Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
    • B29C41/26Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length by depositing flowable material on a rotating drum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/24Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
    • B29C41/32Making multilayered or multicoloured articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24Calendering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/44Compression means for making articles of indefinite length
    • B29C43/46Rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/44Compression means for making articles of indefinite length
    • B29C43/46Rollers
    • B29C2043/461Rollers the rollers having specific surface features
    • B29C2043/463Rollers the rollers having specific surface features corrugated, patterned or embossed surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/914Cooling of flat articles, e.g. using specially adapted supporting means cooling drums
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/002Panels; Plates; Sheets

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

The present invention provides a manufacturing method of resin sheet for improving the transfer rate. The manufacturing method includes the steps of continuously extruding resin in a hot molten state from a die to produce a continuous resin sheet. The continuous resin sheet made by the sheet manufacturing step has a multilayered structure of plural layers in the thickness direction of the sheet, and has at least two layers, i.e. the shape transfer layer (A) is disposed on the sheet surface on the shape roller side, and the main layer (B) is adjacent to the back side of the shape transfer layer. The ratio of melt flow rate (MFR) of the shape transfer layer (A) (according to JISK7210 standard, the measured value at temperature of 200 DEG C and load of 49N) relative to the MFR of the main layer (B) is above 1.5.

Description

201213102 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種表面具有形狀之樹脂片材之製造方 法》 【先前技術】 作為製造表面具有形狀之樹脂片材(表面形狀轉印樹脂 片材)之方法,眾所周知有如下方法:使用擠出機,於加 熱熔融狀態下將樹脂自模具擠出而製造連續之樹脂片材 (連續樹脂片材),使用轉印模將轉印模之形狀轉印至連續 樹脂片材之表面(例如參照日本專利特開2〇〇9_22〇555號公 報)。5玄方法中,於片材之厚度方向上分開之第}擠壓報與 第2擠壓輥之間夾入連續樹脂片材而進行擠壓,將形成於 第2擠壓輥之表面之轉印模之形狀轉印至連續樹脂片材。 【發明内容】 發明所欲解決之問題 近年來,就表面施加有形狀之樹脂片材而言,要求高度 相對於單元形狀之間距(配置間隔)之比率即縱橫比較大之 形狀。然而,於先前之樹脂片材之製造方法中,相對於轉 印模之深度’樹脂並未充分地進入,轉印至樹脂片材之形 狀之高度亦不一定充分。因此,需要提高轉印至樹脂片材 之表面形狀之最大高度H,相對於轉印模之槽深η之比率印 轉印率(Η'/Η)。 解決問題之技術手段 本發明係為解決此種課題而完成者,其目的在於提供— 157219.doc 201213102 種食b夠實現轉印率之提高之樹脂片材之製造方法。 本發明提供樹脂片材之製造方法,其包括:片材製造步 驟,其係將加熱溶融狀態之樹脂自模具連續地擠出而製造 連續樹脂片材;及轉印步驟,其係使用於周面形成有轉印 模之形㈣,於連續樹脂片材之片材表面轉印轉印模;轉 p步驟包括.轉印開始步驟,其係利用擠壓輥與形狀棍爽 持並漏由片材製造步驟製造之連續樹脂片材,由此開始 將形狀輥之轉印模之形狀轉印至連續樹脂片材;搬送步 驟,其係使於轉印開始步驟中片材表面轉印有轉印模之形 狀之連續樹脂片材保持與形狀輥之周面密接而進行搬送; 及剝離步驟,其係將搬送步驟中搬送之連續樹脂片材自形 狀輥之周面剝離;且由片材製造步驟製造之連續樹脂片材 為於片材之厚度方向上具有複數層之多層構造,且具備於 轉印開始步驟中配置於形狀輥側之構成片材表面之形狀轉 印層(A)及鄰接於形狀轉印層之背面側之主層(b)之至少2 層;形狀轉印層(A)之MFR(MFR : Melt flow rate,熔體流 動速率)相對於主層(B)之MFR(以JISK7210為標準,於溫度 200°C、荷重49 N下測定之測定值)之比率為1.5以上。 根據此種本發明之樹脂片材之製造方法,能夠使樹脂片 材成為多層構造,能夠使構成形狀轉印層(A)之樹脂(a)之 流動性高於構成主層(B)之樹脂(b)之流動性。由此,可較 佳地使樹脂(a)進入至轉印模内,從而可實現轉印率之提 高。藉由於構成表面層(A)之樹脂(a)中使用高流動樹脂, 而能夠實現形狀轉印率之提高。 157219.doc 201213102 此處’較佳為轉印步驟包括:預壓步驟,其係利用預壓 輥與擠壓輥夾入由片材製造步驟製造之連續樹脂片材而進 行擠壓;及預備搬送步驟,其係使於預壓步驟中擠壓之連 續樹脂片材保持與擠壓輥之周面密接而進行搬送;且於轉 印開始步驟中,利用擠壓輥與形狀輥夾持並擠壓由預備搬 送步驟搬送之連續樹脂片材。由此,藉由利用預壓輥與擠 壓輥夾入之預壓步驟,能夠同時調節連續樹脂片材之厚度 及片材溫度,能夠實現形狀轉印率之提高。 又,較佳為於將構成形狀轉印層(A)之樹脂之玻璃轉 移溫度設為Tg(a)之情形時,即將與形狀輥之周面接觸之 形狀轉印層(A)之表面溫度為(Tg(a)+5〇)t: 〜(Tg(a)+i5〇)<>c 之範圍,剛剛自形狀輥之周面剝離之形狀轉印層(a)之表 面溫度為(Tg(a)_1 〇)°C〜(Tg(a)+40)t之範圍。 又,較佳為形狀轉印層(A)之厚度相對於主層(B)之厚度 之比率為1/2GG〜1/1Q之範圍。若於轉印形狀之前,樹脂片 材之厚度比率(形狀轉印層(A)/主層⑽為謂〜ι/ι〇之範 圍,則能夠進一步實現轉印率之提高。 又’較佳為包括加熱步驟’該加熱步驟係、於即將進行轉 P開始步驟之則’加熱密接於擠壓輥之周面而搬送之連續 樹脂片材之形狀轉印層(A)之表面。 又,較佳為轉印模中 複數個於形狀輥之周方 置間隔P為200 μιη〜500 ,於形狀輥之旋轉軸方向上並設有 向上連續之槽部,複數個槽部之配 μιη。 又’較佳為轉印模中 於形狀輥之旋轉軸方向上並設有 157219.doc 201213102 之槽部,複數個槽部等間 複數個於形狀輥之周方向上連續 隔地配置。 又’較佳為轉印模中,於形此 $狀輕之旋轉轴方向上並設有 複數個於形狀輥之周方向上連锖 硬續之槽部’複數個槽部之深 度 Η為 100 μχη〜500 μιη。 又’較佳為轉印模中,於开〉你扣^ $狀輥之旋轉軸方向上並設有 複數個於形狀輥之周方向上遠嬙 連續之槽部’複數個槽部之深 度Η相對於槽部之配置問隖ρ 間之比率即縱橫比Η/P為0.3以 上0 又’較佳為轉印模中,於形狀輥之旋轉軸方向上並設有 複數個於形狀報之周方向上連續之槽部,槽部之與形狀報 之周方向正交之方向之剖面形狀為大致半圓形狀大致半 橢圓形狀或者棱形狀。 又’較佳為轉印模中’於形狀輥之旋轉軸方向上並設有 複數個於形狀輥之周方向上㈣之槽部,㈣之與形狀報 之周方向正交之方向之剖面形狀為適應於形成光學透鏡之 形狀。 轉印模中,於形狀親之旋轉軸方向上並設有複數個於形 狀輥之周方向上連續之槽部,複數個槽部之配置間隔Μ 200 μηι〜500 μπι且為等間隔,槽部之深度Η*ι〇〇 μιη〜5〇〇[Technical Field] The present invention relates to a method for producing a resin sheet having a shape on the surface. [Prior Art] A resin sheet having a shape on the surface (surface shape transfer resin sheet) The method is known as follows: using an extruder, extruding a resin from a mold in a heated and molten state to produce a continuous resin sheet (continuous resin sheet), and transferring the shape of the transfer mold using a transfer mold It is printed on the surface of a continuous resin sheet (for example, refer to Japanese Laid-Open Patent Publication No. Hei. No. Hei. In the 5th method, the continuous resin sheet is sandwiched between the first squeeze roller and the second squeeze roller which are separated in the thickness direction of the sheet to be pressed, and the surface formed on the second squeeze roller is rotated. The shape of the stamp is transferred to a continuous resin sheet. DISCLOSURE OF THE INVENTION PROBLEMS TO BE SOLVED BY THE INVENTION In recent years, in the case of a resin sheet having a shape applied to the surface, a ratio of a height to a distance between the unit shapes (arrangement interval), that is, a shape having a large aspect ratio is required. However, in the conventional method for producing a resin sheet, the resin is not sufficiently entered with respect to the depth of the transfer mold, and the height of the shape transferred to the resin sheet is not necessarily sufficient. Therefore, it is necessary to increase the maximum height H of the surface shape transferred to the resin sheet, and to print the transfer rate (Η'/Η) with respect to the groove depth η of the transfer mold. Means for Solving the Problems The present invention has been made to solve such a problem, and an object of the present invention is to provide a method for producing a resin sheet in which the transfer rate is improved by the food preparation. The present invention provides a method for producing a resin sheet, comprising: a sheet manufacturing step of continuously extruding a resin in a heated and molten state from a mold to produce a continuous resin sheet; and a transfer step of using a peripheral surface Forming a shape of the transfer mold (4), transferring the transfer mold on the surface of the sheet of the continuous resin sheet; the step of transferring p includes a transfer start step, which uses a squeeze roll and a shape stick to hold and leak the sheet Manufacturing a continuous resin sheet produced by the step, thereby starting to transfer the shape of the transfer mold of the shape roll to the continuous resin sheet; and carrying the step of transferring the transfer mold to the surface of the sheet during the transfer start step The continuous resin sheet of the shape is held in close contact with the circumferential surface of the shape roll, and the peeling step is performed by peeling the continuous resin sheet conveyed in the transport step from the peripheral surface of the shape roll; and manufacturing by the sheet manufacturing step The continuous resin sheet has a multilayer structure having a plurality of layers in the thickness direction of the sheet, and has a shape transfer layer (A) disposed adjacent to the surface of the sheet formed on the shape roll side in the transfer start step, and adjacent to the shape At least 2 layers of the main layer (b) on the back side of the transfer layer; MFR (MFR: Melt flow rate) of the shape transfer layer (A) relative to the MFR of the main layer (B) (with JIS K7210) The ratio of the measured value measured at a temperature of 200 ° C and a load of 49 N is 1.5 or more. According to the method for producing a resin sheet of the present invention, the resin sheet can have a multilayer structure, and the resin (a) constituting the shape transfer layer (A) can have higher fluidity than the resin constituting the main layer (B). (b) Liquidity. Thereby, the resin (a) can be preferably introduced into the transfer mold, whereby the transfer rate can be improved. The shape transfer rate can be improved by using a high-flow resin in the resin (a) constituting the surface layer (A). 157219.doc 201213102 Here, the preferred transfer step includes: a pre-pressing step of squeezing by using a pre-pressing roll and a squeeze roll to sandwich a continuous resin sheet manufactured by a sheet manufacturing step; and preparing for transfer a step of holding the continuous resin sheet extruded in the pre-pressing step in close contact with the circumferential surface of the pressing roller for conveying; and in the transfer starting step, clamping and pressing by the pressing roller and the shape roller The continuous resin sheet conveyed by the preliminary transfer step. Thus, by using the pre-pressing step of the pre-pressing roller and the pressing roller, the thickness of the continuous resin sheet and the sheet temperature can be adjusted at the same time, and the shape transfer rate can be improved. Further, when the glass transition temperature of the resin constituting the shape transfer layer (A) is Tg (a), the surface temperature of the shape transfer layer (A) which is in contact with the peripheral surface of the shape roll is preferably used. For the range of (Tg(a)+5〇)t:~(Tg(a)+i5〇)<>c, the surface temperature of the shape transfer layer (a) which has just been peeled off from the peripheral surface of the shape roll is (Tg(a)_1 〇) °C~(Tg(a)+40)t range. Further, it is preferable that the ratio of the thickness of the shape transfer layer (A) to the thickness of the main layer (B) is in the range of 1/2 GG to 1/1 Q. If the thickness ratio of the resin sheet (the shape transfer layer (A) / the main layer (10) is in the range of 〜 ι / ι 之前 before the transfer shape, the transfer rate can be further improved. Including the heating step 'this heating step is to heat the surface of the shape transfer layer (A) of the continuous resin sheet which is conveyed to the peripheral surface of the squeeze roll immediately after the start of the P-transfer step. Further, preferably In the transfer mold, a plurality of spacers P are disposed at intervals of 200 μm to 500 in the circumferential direction of the shape roller, and are provided with upwardly continuous groove portions in the direction of the rotation axis of the shape roller, and a plurality of groove portions are provided with μηη. In the preferred transfer mold, a groove portion of 157219.doc 201213102 is provided in the direction of the rotation axis of the shape roller, and a plurality of groove portions are arranged in a continuous manner in the circumferential direction of the shape roller. In the stamp, in the direction of the rotation axis of the shape, a plurality of groove portions in the circumferential direction of the shape roller are formed, and the depth Η of the plurality of groove portions is 100 μχη to 500 μιη. 'Better in the transfer mold, in the open> you buckle the rotation axis of the $-roller The ratio of the depth Η of the plurality of groove portions in the circumferential direction of the shape roller in the circumferential direction of the shape roller to the arrangement of the groove portions is 0.3/P of 0.3 or more and 0. Preferably, in the transfer mold, a plurality of groove portions continuous in the circumferential direction of the shape report are provided in the direction of the rotation axis of the shape roller, and the groove portion has a cross-sectional shape in a direction orthogonal to the circumferential direction of the shape report. a substantially semi-elliptical shape or a prismatic shape in a substantially semicircular shape. Further preferably, in the transfer mold, a plurality of groove portions in the circumferential direction of the shape roller (four) are provided in the direction of the rotation axis of the shape roller, and (4) The cross-sectional shape of the shape in which the circumferential direction of the shape is orthogonal is adapted to form the shape of the optical lens. In the transfer mold, a plurality of grooves continuous in the circumferential direction of the shape roller are provided in the direction of the rotation axis of the shape. The arrangement interval of the plurality of groove portions is μ200 μηι to 500 μπι and is equally spaced, and the depth of the groove portion is Η*ι〇〇μιη~5〇〇

Km,縱橫比(Η/P)為0.3以上,槽部之與形狀輥之周方向正 交之方向之剖㈣狀為大致半@形狀、域半橢圓形狀或 者棱形狀;若為適應於形成光學透鏡之形狀,則難以利用 先前之製造方法製成轉印率較高之表面形狀轉印樹脂片 157219.doc 201213102 材。若使用基於本發明之樹脂片材之製造方法,則即使於 上述般轉印難度高之轉印模中亦能夠製成轉印率較高之表 面形狀轉印樹脂片材。 又’較佳為構成形狀轉印層(A)之樹脂(a)為笨乙烯系樹 脂或者丙烯酸系樹脂,構成主層(B)之樹脂(b)為笨乙烯系 樹脂或者丙烯酸系樹脂。 【實施方式】 下面參照附圖對本發明之實施形態進行說明。此外,對 相同或者相當之要素附上相同之符號,且省略重複之說 明。附圖之尺寸比率未必與說明之物體一致。 (Μ知片材之製造裝置)圖1係表示本發明之實施形態之 樹脂片材製造裝置之概略構成圖。樹脂片材製造裝置5〇為 能夠用於本發明之實施形態之樹脂片材之製造方法之裝 置。樹脂片材製造裝置50具備:將加熱熔融狀態之樹脂連 續地擠出而得到連續樹脂片材6〇之模具5 1,及自厚度方向 之兩側擠壓自模具51擠出之連續樹脂片材60之第1擠壓觀 (本發明中之擠壓輥)52Α及第2擠壓輥(本發明中之形狀 輥)52Β。 又’樹脂片材製造裝置50具備用於投入作為原料之樹脂 之樹脂投入口 57及用於擠出自樹脂投入口 57投入之樹脂之 擠出機58。本實施形態之樹脂片材製造裝置50成為能夠製 造於厚度方向上層疊之多層構造之樹脂片材60之構成,於 本實施形態中對製造圖10所示之2層構造之連續樹脂片材 6〇之情況進行說明。 1572l9.doc 201213102 第1擠壓輥52A及第2擠壓輥52B成為能夠圍繞相互平行 之旋轉軸旋轉之構成。第1擠壓輥52A及第2擠壓輥52B於 樹脂片材60之厚度方向上分開配置,相互之周面彼此之間 隔根據樹脂片材60之厚度進行設定。如圖8、圖21、圖22 及圖23所示,於第2擠壓輥52B之周面形成有與轉印至樹脂 片材60之凹凸形狀對應之轉印模53。詳細情況以後加以敍 述0 (樹脂片材之製造裝置之變形例)圖2為表示本發明之第2 實施形態之樹脂片材製造裝置之概略構成圖。圖2所示之 樹脂片材製造裝置5 0B與圖1所示之樹脂片材製造裝置5〇之 不同點為,於第2擠壓親(本發明中之形狀報)52B之後段具 備第3擠壓輥52C。第3擠壓輥52C為與第1擠壓輥(本發明中 之擠壓輥)52A相同之構成。於第3擠壓輥52C與第2擠壓輥 52B之間夾入連續樹脂片材6〇而進行擠壓。 圖3為表示本發明之第3實施形態之樹脂片材製造裝置之 概略構成圖。圖3所示之樹脂片材製造裝置5〇c與圖i所示 之樹脂片材製造裝置50之不同點為,於第!擠壓輥(本發明 中之擠壓輥)52A之前段具備預壓輥52D ^預壓報52D為與 第1擠壓輥52A相同之構成。於預壓輥52D與第i擠壓輥52a 之間夾入連續樹脂片材60而進行擠壓。 圖4為表示本發明之第4實施形態之樹脂片材製造裝置之 概略構成圖。圖4所示之樹脂片材製造裝置5〇D與圖2所示 之樹脂片材製造裝置50B之不同點為,於第3擠壓輥52(:之 後具借第4擠壓親(後擠壓報)52Εβ其他之構成為與圖2所 I572I9.doc 201213102 示之樹脂片材製造裝置50B相同之構成。於第4擠壓輥52E 與第3擠壓輥52C之間夾入連續樹脂片材60而進行擠壓。連 續樹脂片材60係以形狀轉印層61與第4擠壓輥52E密接之狀 態被搬送。 圖5為表示本發明之第5實施形態之樹脂片材製造裝置之 概略構成圖。圖5所示之樹脂片材製造裝置50E與圖3所示 之樹脂片材製造裝置50C之不同點為,於第2擠壓輥(本發 明中之形狀輥)52B之後具備第3擠壓輥(後擠壓輥)52C。其 他之構成為與圖3所示之樹脂片材製造裝置5〇c相同之構 成。於第3擠壓輥52C與第2擠壓輥52B間夾入連續樹脂片 材60而進行擠壓。連續樹脂片材6〇係以非形狀轉印層與第 3擠壓輥52C密接之狀態被搬送。 如圖1〜圖3所示,複數個輥可為於上下方向上鄰接地配 置之構成;亦可如圖4及圖5所示,複數個輥為水平方向上 鄰接地配置之構成。又,複數個輥可為於相對於水平方向 而傾斜之方向上鄰接地配置之構成。於圖5所示之樹脂片 材製造裝置50E中,因於配置於第三位之第2擠壓輥(本發 明中之形狀輥)之後段配置有第3擠壓輥52C,故可使樹脂 相對於第2擠壓輥52B之上侧半部(18〇度部分)密接。又, 藉由使連續樹脂片材與第3擠壓輥52C密接,而能夠調整連 續樹脂片材之溫度。 圖20為表示本發明之第6實施形態之樹脂片材製造裝置 之概略構成圖。圖20所示之樹脂片材製造裝置5〇F與圖3所 示之樹脂片材製造裝置50C之不同點為,具備於即將利用 157219.doc 201213102 第1擠壓輥52A與第2擠壓輥52B夾入連續樹脂片材60之 前’對連續樹脂片材60之形狀轉印層61側之片材表面進行 加熱之加熱器59。 樹脂片材製造裝置50F具備:將原料樹脂擠出並成形為 片狀之片材成形機54,用於藉由擠壓而將擠出之連續樹脂 片材60成形之一組擠壓輥組(52d、52A、52B),及用於抽 取連續樹脂片材60之一對抽取輥組(52G、52H)。 片材成形機54具備:用於將形狀轉印層(八)61之原料樹 脂(a)加熱熔融之第1擠出機(副擠出機)58A,用於將主層 (B)62之原料樹脂⑻加熱熔融之第2擠出機(主擠出 機)58B,被供給有於第i及第2擠出機58八、58B中熔融之 樹脂之進料器台55,及用於在片材狀態下擠出進料器台55 内之樹脂之模具5 1。 作為第1及第2擠出機58A、58B,例如可使用單軸擠出 機、雙軸擠出機等公知之擠出成形機。^及第2播出機 58A、58B中安裝有用於向擠出機之量筒内投入樹脂之 斗(樹脂投入口)57。 作為進料器。55,只要為能夠向模具51供給2種以上 樹脂’能夠以層疊之狀態共擠出之型式,則無特別 定,例如可使用2種3層分 ,絲〇成、 Λ 义 增刀配型、2種2層分配型等公知 ϋ ί» . 夂 3¾ 邗馮模具 制 等 ,、要為共擠出用之模具,則無特 可使用通φ之擠出成形法中所使用之金屬製』 模⑽之口(模具e叫之寬練據目標連續樹骑片木 157219.doc 201213102 60之寬度而進行選擇,例如為3〇〇mm〜3〇〇〇mme 預壓輥52D、第丨擠壓輥52A及第2擠壓輥52B分別包含圓 柱狀之金屬製(例如不鏽鋼製、鐵鋼製等)輥,為具有調節 其周面溫度(表面溫度)功能之冷卻報。第2擠壓觀52β之周 面設置有用於在連續樹脂片材6G上形成半橢圓凸狀部似 凹槽35b(參照圖18、圖19)之凹版轉印模53。 如圖2!所示’於該凹版轉印模53中,作為與半橢圓凸狀 4 35相反型之槽部之半橢圓凹槽7〇沿著第2擠壓輥UR之周 方向形成為多個條紋狀。即’於凹版轉印模对,半擴圓 凹槽7〇與相鄰之半橢圓凹槽70之間之凸條71沿著第2擠壓 輥52Β之轴方向交替地配置。 半橢圓凹槽70中,與其長度方向(周方向)正交之切剖面 ,、有大致半橢圓形狀之輪廓。半橢圓凹槽之深度Η比半 橢圓凸狀部35之高度η,略大,例如為1〇〇 μηι〜5〇〇㈣較 =為100 μηι〜300 μηι以下。若深度Η過大則高流動性聚 苯乙稀樹月日(構成形狀轉印層61之樹脂⑷)難以進入至半擴 圓凹槽70之前端為止。 又,相鄰 據半橢圓凸 之半橢圓凹槽70之中心彼此之距離(間距p)根 狀部35之形狀適當地確定,例如為2〇〇 μιη〜5〇〇 ’較佳為250 μηι〜450 μιη ’進而較佳為3〇〇 μιη〜400 μ於間距Ρ未滿200卿時,有樹脂與第2擠壓輥53接觸 t』固化之虞,其結果,有構成形狀轉印層(A)61之樹 ()未進入至半橢圓凹槽7〇之前端為止而無法得到目標之 轉「形狀之虞。另-方面,於間距P超過500 μιη時,有用 1572l9.doc 201213102 肉眼就可於液晶面板上觀察到間距之條紋之虞,或有出現 液晶面板10或光學膜41等之干涉條紋圖案之虞。 又’由半橢圓凹槽70之高度η相對於間距P之比率(H/P) 所表示之縱橫比例如為0.3以上,較佳為〇 5〜〇 7 ^此外, 半擴圓凸狀部35之高度Η,與半橢圓凹槽70之深度η之差係 起因於凹版轉印模53轉印至連續樹脂片材6〇而形成半橢圓 凸狀部35時之轉印率(η,/η)(%)。 又’馬達(未圖示)分別連接於各擠壓輥(52D、52Α、 52B)之旋轉軸。預壓輥52D及第2擠壓輥52B可逆時針地旋 轉’第1播壓輥52A可順時針地旋轉。即,擠壓報(52D、 52A、52B)以自上到下順序為「可逆時針地旋轉」、「可順 時針地旋轉」、「可逆時針地旋轉」。由此,能夠以全部輥 (52D、52A、52B)夾持連續樹脂片材6〇之狀態進行同步旋 轉。又’藉由適當地調節擠壓輥(52D、52A、52B)之旋轉 速度’可調整樹脂片材6〇之搬送速度。 各擠Μ報(52D、52A、52B)之直徑為例如1〇〇 mm〜500 mm。又,於使用金屬製輥作為擠壓輥(52D、52A、52B)之 情形時’亦可對其表面實施例如鍍鉻、鍍銅、鍍鎳、鍍 Ni-P等鍍敷處理。 又’於第1擠壓輥52A附近設置有用於將在第!擠壓輥 52A上搬送之樹脂片材60之形狀轉印層61之表面(被轉印之 側之表面)加熱之加熱器5 9。加熱器5 9以相對於第i擠壓輥 52A之周面離開之方式對向配置,自形狀轉印層“之片材 表面側對搬送之連續樹脂片材6〇進行加熱。作為加熱器 1572i9.doc •12· 201213102 59’例如可使用紅外加熱器等公知之加熱器。又,加熱器 59可為設置於搬送連續樹脂片材6〇之路線上之線上形加熱 器’亦可為使操作人員能以手持進行測定之手提式加熱 器。 一對抽取輥組(52G、52H)包含自厚度方向兩側夾入連續 樹脂片材60之一對抽取輥52G、52H。抽取報52G、52H分 別包含圓柱狀之金屬製(例如不鏽鋼製、鐵鋼製等)輥,以 使下側之抽取報52H之上端處於與第2擠壓報(形狀報)52b 之下端相同之高度位置之方式進行對向設置。由此,因能 夠於以剛剛送出之高度支持自第2擠壓輥52B送出之連續樹 脂片材60之狀態下進行水平搬送,故能夠減小搬送阻力。 (連續樹脂片材)其次,對利用本發明之實施形態之製造 方法製造之連續樹脂片材進行說明。圖1〇為表示本發明之 實施形態之連續樹脂片材之層構成之剖面圖。圖1〇為於與 連續樹脂片材之連續之方向(X方向)正交之方向(y方向、z 方向)上切出之剖面,表示表面形狀被轉印前之狀態。 連續樹脂片材60具有於片材之厚度方向(2方向)上層叠有 複數層之多層構造,且具備構成片材表面60a之形狀轉印 層(A)61及主層(b)62。例如將表面形狀轉印至具有片材表 面60a之形狀轉印層(A)61。主層(B)62於片材之厚度方向上 鄰接於轉印有形狀之形狀轉印層(A)61之背面側進行配 置_。 連續樹脂片材60可為如圖10所示之2種2層之構成(形狀 轉印層(A)/主層(B)),亦可為如圖6所示之2種3層(形狀轉 157219.doc -13· 201213102 印層(A)/主層(B)/背面層)。圖6所示之連續樹脂片材6〇具 備構成片材表面60a之形狀轉印層(A)61、構成片材表面 60b之背面層63、及夾於該等形狀轉印層(A)61及背面層63 之主層(B)62。於為2種3層之情形時’構成形狀轉印層61 與背面層63之樹脂為相同之樹脂。 圖7係模式性地表示本發明之實施形態之樹脂片材之構 成之立體圖。圖7表示將連續樹脂片材60切斷為特定之尺 寸而形成之樹脂片材30。樹脂片材30能夠用作搭載於後述 之透過型圖像裝置1、1B(參照圖11、圖16)之面光源裝置 (背光)20、20B之導光板30或者光擴散板30C。作為面光源 裝置(背光)20、2 0B,將 LED(light emitting diode,發光二 極體)荨光源配置於導光板3 0之側面3 3,可用作將自導光 板3 0之側面3 3入射之光向正面側出射之端面照光型。此 外’可相對於樹脂片材之側面33配置光源而用作導光板, 亦可相對於樹脂片材之背面32配置光源而用作光擴散板 (詳細情況以後進行敍述)。 於將樹脂片材用作導光板30時,通常對樹脂片材之背面 32實施使自側面入射之光漫反射之反射加工。作為進行反 射加工之印刷之方法,除了絲網印刷以外,可進行喷墨印 刷。或者作為反射加工之方法,可不進行印刷,而是藉由 雷射照射賦予圓點形狀之凹凸。 於樹脂片材30之表面31形成有於第i方向(χ軸方向)上延 伸並且於與該第丨方向正交之第2方向(y轴方向)上並列配置 之複數個凸狀部35°具有形成於表面31之凸狀部35之凹凸 157219.doc •14· 201213102 形狀由後述之轉印步驟而形成。 (導光板之使用例)其次’參照圖11對導光板之具體之使 用例進行說明。圖11係模式性地表示具備本發明之導光板 之透過型圖像顯示裝置之一實施形態之構成之剖面圖。圖 11分解地表示透過型圖像顯示裝置1。 (透過型圖像顯示裝置)透過型圖像顯示裝置1具備透過 型圖像顯示部10及於圖11中配置於透過型圖像顯示部1〇之 背面側之面光源裝置20。如圖11所示,面光源裝置2〇與透 過型圖像顯示部10之排列方向稱為Z方向(板厚方向),與2 方向正交之2個方向且相互正交之2個方向稱為χ方向及y方 向。 作為透過型圖像顯示部10,例如可列舉將直線偏光板 12、12配置於液晶單元丨丨之兩面之液晶顯示面板。此時, 透過型圖像顯示裝置!為液晶顯示裝置(或者液晶電視卜液 晶單元11、偏光板12、12可使用先前之液晶顯示裝置等透 過型圖像顯示裝置1中所使用之元件。作為液晶單元丨〖可 例示 TFT(Thin Film Transistors ’ 薄膜電晶體)型、STN (Super Twisted Nematic,超扭轉向列)型等公知之液晶單 元。 (面光源裝置)圖12係模式性地表示具備本發明之導光板 之面光源裝置之一實施形態之構成之後視圖,圖13係模式 性地表示具備本發明之導光板之面光源裝置之其他實施形 態之構成之後視圖’圖14係模式性地表示具備本發明之導 光板之面光源裝置之一實施形態之構成之前視圖。如圖 157219.doc • 15· 201213102 11〜圖14所示,面光源裝置2〇具備導光板(光學片)3〇、與導 光板30之側面33對向地配置之LED光源(點狀光源。此 外,於導光板30之正面側,可為於導光板3〇與透過型圖像 顯示部10之間,配置有各種膜41之構成。作為各種膜41, 可列舉擴散膜、稜鏡膜、亮度增強膜等。 (光源)LED光源22作為面光源裝置2〇之點狀光源而發揮 作用,如圖12所示,與於導光板30之丫軸方向上延伸之側 面33、33對向地配置。複數個LED光源22沿著侧面33之長 度方向(y軸方向)離散地配置。LED光源22之配置間隔通常 為5 mm〜20 mm〇點狀光源可為以與導光板3〇之4邊對向之 方式進行配置’可於與X軸方向對向之2邊(參照圖12)、與y 軸方向對向之2邊進行配置,還可僅於丨邊進行配置之構成 (參照圖13及圖14)。又’點狀光源不限於led光源,可為 其他點狀光源。進而’光源不限於點狀光源,亦可為配置 有線狀光源(冷陰極管)之構成。 LED光源22可為白色LED ’亦可於一處配置複數個led 而構成一個光源單元。例如作為一個光源單元,可將紅 色、綠色、藍色不同之三色之LED靠近並列地配置。而 且’具有複數個LED之光源單元沿著上述配置方向離散地 配置。於此情形時,較佳為不同LED彼此儘可能地靠近地 配置。 作為LED光源,能夠使用具有各種各樣之出光分佈之光 源,LED光源之法線方向(z軸方向)之發光強度為最大,較 佳為具有發光強度分佈之半值寬度為40度以上80度以下之 157219.doc •16· 201213102 出光分佈之光源。又’作為LED光源之類型,具體而言, 可列舉朗伯(Lambertian)型、炮彈型、側向發射型等。 (導光板)如圖12〜圖14所示,導光板3〇形成長方形,平 面視形狀之尺寸以適合於目標透過型时顯示裝置1〇之畫 面尺寸之方式進行選擇,正交之2邊之長度(LlxL2)通常為 25〇mmX44〇mm以上,較佳為500 mmx800 mm以上之大型 尺寸。導光板30之平面視形狀不限於長方形,可為正方 形,然而以下若無特別之限定,則以長方形進行說明。 導光板30由透光之透光性樹脂形成,且形成為板狀。此 外,導光板30可為片狀,亦可為膜狀。較佳為導光板刊之 厚度T為1 ·0 mm以上4.5 mm以下。 導光板30具備於z軸方向(厚度方向)上對向之一對主面 (31、32)、於X軸方向上對向之一對側面33、33及於γ軸方 向上對向之一對側面34、34。主面(3 1、32)於與側面(33、 34)交叉之方向上形成。 於z軸方向上對向之一對主面中之一主面(31)作為能夠出 射面狀之光之出射面31而發揮作用。出射面31配置於透過 型圖像顯示部1 0側’另一主面(背面32)配置於與透過型圖 像顯不部10相反一側。又,於與背面32對面之位置處,施 加有使導光板30内之光向出射面31側反射之反射片42。 (反射加工)又,如圖12及圖13所示,對導光板30之背面 32貫施使光漫反射之反射加工(例如絲網印刷)^作為進行 反射加工之印刷之方法,除絲網印刷以外,可進行喷墨印 刷。或者’作為反射加工之方法,可不進行印刷,而利用 157219.doc •17· 201213102 雷射照射賦予圓點形狀之凹凸。於本實施形態之導光板3〇 中,作為反射加工,印刷有圓點圖案。於圓點圖案之印刷 中’使用的是具有使光擴散之擴散粒子之油墨。又,構成 圓點圖案之各圓點38(印刷圓點)之直徑以隨著自光源側離 開而變大之方式協調變化。例如,使距光源近之區域之側 部附近之區域之圓點直徑為5 16 μηι左右,使距光源最遠之 區域之面板中央附近之區域之圓點直徑為9〇4 μηι左右,使 兩者中間區域之圓點直徑為729 μιη左右。 (凹凸形狀)圖7係模式性地表示本發明之導光板之一實 施形態之構成之立體圖,圖1 5係模式性地表示本發明之導 光板之其他實施形態之構成之立體圖。於出射面31形成有 向ζ轴方向之外側凸出之複數個凸狀部35。凸狀部35於X軸 方向(一方向)上延伸’且於y軸方向上並列配置複數個。 又,作為凸狀部35之形狀,可列舉稜鏡形狀、大致半圓 形狀、大致橢圓形狀等,較佳為於丨個凸狀部35(形狀單元) 中連續地變化之形狀,例如半圓形狀或者半橢圓形狀比稜 鏡形狀更佳。此外,較佳為凸狀部35之延伸方向與來自光 源之光之出射方向平行。又,可於凸狀部35鄰接之方向(y 轴方向)上,於鄰接之凸狀部35、35之間形成有平面部。 又,作為凸狀部之形狀,除此以外,可為光學透鏡形狀。 圖8係自X軸方向表示圖7中之凸狀部之放大圖。此處, 凸狀部35滿足ΗχΤ/Ρ2〇.23···(1)即可。其中,p為鄰接之凸 狀部35、35之間隔(μιη),η為凸狀部35之高度(μπι),τ為片 材厚度(mm)。如圖8所示,間隔ρ為鄰接之凸狀部35之頂點 157219.doc •18· 201213102 35a、35a之間之距離。凸狀部35之高度H為凸狀部35之下 端35b與頂點35a之間之距離。片材厚度T為凸狀部35之頂 點35a與背面32之距離。 (導光板之構成材料)導光板30由透光性樹脂形成。透光 性樹脂之折射率通常為1_49〜1.59。作為導光板30所使用之 透光性樹脂,主要使用甲基丙烯酸系樹脂。作為導光板3〇 所使用之透光性樹脂,可使用其他之樹脂,亦可使用苯乙 烯系樹脂。作為透光性樹脂,能夠使用丙烯酸系樹脂、苯 乙烯樹脂、碳酸酯樹脂、環狀烯烴樹脂、MS樹脂(丙烯酸 與本乙婦之共聚物)等。 將導光板應用於液晶顯示裝置(透過型圖像顯示裝置 1 ),可於導光板3 〇中添加光擴散劑、紫外線吸收劑、熱穩 定劑、光聚合穩定劑等添加劑。 (光擴散板之使用例)其次,參照圖16,對光擴散板之使 用例進行說明。圖16係模式性地表示具備本發明之光擴散 板之透過型圖像顯示裝之一實施形態之構成之側視圖。圖 17係圖16所示之透過型圖像顯示裝置之模式性立體圖。 (透過型圖像顯示裝置)透過型圖像顯示裝置⑺具備透過 型圖像顯示部H)、及於圖16中配置於透過型圖像顯示部ι〇 之彦面側之面光源裝置2〇b。如圖丨6所示,將面光源裝置 2〇B與透過型圖像顯示部1〇之排列方向稱為z方向(板厚方 向)將肖z方向正交之2個方向且相互正交之2個方向稱為 X方向及y方向。 作為透過型圖像顯不部1G,例如可列舉直線偏光板12、 157219.doc •19- 201213102 12配置於液晶單元11之兩面之液晶顯示面板。此時,透過 型圖像顯示裝置1為液晶顯示裝置(或者液晶電視)。液晶單 元11、偏光板12、12可使用先前液晶顯示裝置等透過型圖 像顯示裝置1中所使用之元件。作為液晶單元〖丨,可例示 出TFT型、STN型等公知之液晶單元。 面光源裝置(背光系統)20B具備:具有四角板狀之後壁 23及自後壁23之周邊向前方(正面側)一體地立設之四角框 狀之側壁24,且前面側開放之薄型箱狀之樹脂製燈箱25 ; 設置於燈箱25内之複數個線狀光源22B ;及將燈箱25之開 放面26(前面)遮擋之光擴散板30C。 即’就I目狀之燈箱25而言’其開放面26之輪廓由四角框 狀之側壁24劃分’於由側壁24及後壁23包圍之空間内設有 線狀光源2 2 B。於燈相2 5之後壁2 3内面,例如整體地安裝 有用於使自線狀光源22B向後壁23側入射之光向箱之開放 面26側反射之反射板42(參照圖11)。 (光源)線狀光源22B例如為直徑為2 mm〜4 mm之圓筒狀 燈。複數個線狀光源22B以對於光擴散板30C之背面32而 隔開一定間隔之狀態’相互平行地隔開相等之間隔進行配 置。 自省電之觀點出發,較佳為相鄰之線狀光源22B之中心 彼此之間隔Q為30 mm~60 mm。又,自薄型化之觀點出 發’較佳為光擴散板30C之背面32(例如背面32之中央部) 與線狀光源22B之中心之距離R為10 mm〜20 mm。又,較 佳為間隔Q相對於距離R之比率(Q/R)為2.5〜4.0 »特別較佳 157219.doc •20· 201213102 為間隔Q為40 mm〜55 mm,距離R為13 mm〜17 mm。又, 線狀光源22Β之數目必然由燈箱25之尺寸(透過型圖像顯示 裝置1Β之晝面尺寸)及間隔Q所決定,而例如於3 2型之液晶 顯示裝置1中’較佳為6〜10根。此外,於圖16及圖17中, 為了易於進行圖解而僅用5根來表示線狀光源22Β。 又’作為線狀光源22Β ’例如可使用螢光燈(冷陰極 管)、鹵素燈、鎢燈等公知之筒形燈。又,作為面光源裝 置20Β之光源,可代替線狀光源22Β而使用發光二極管 (LED)等點狀光源等。 (光擴散板)圖18係包含本發明之一實施形態之樹脂片材 之光擴散板之模式性立體圖。圖19係表示光擴散板之安裝 狀態之燈箱之主要部分放大剖面圖。如圖18所示,光擴散 板30C形成為與燈箱25之側壁24之框形狀大致相同之四角 之板狀。 光擴散板30C為於厚度方向z上至少層疊有2層樹脂層而 得之光透過性多層光擴散板,其具備包含高流動性樹脂之 形狀轉印層(A)(前面層)61、及包含低流動性樹脂之主層 (B)(背面層)62。 又,於光擴散板30C中根據需要可含有光擴散劑(光擴散 粒子)。作為光擴散劑,只要為折射率與構成光擴散板3〇c 之透光性樹脂不同且能夠擴散透射光之粒子,則無特別之 限制,例如作為無機系之光擴散劑.,可列舉碳酸妈、硫酸 鋇、氧化鈦、氫氧化鋁、二氧化矽、玻璃、滑石、雲母、 白碳、氧化鎂、氧化鋅等。該等可為用脂肪酸等實施了表 157219.doc -21· 201213102 面處理之產物。 又’例如作為有機系之光擴散劑,可列舉苯乙烯系聚合 物粒子、丙烯酸系聚合物粒子、矽氧烷系聚合物粒子等, 較佳為可列舉重量平均分子量為50萬〜500萬之高分子量聚 合物粒子、溶解於丙酮時之凝膠分率為1〇質量%以上之交 聯聚合物粒子。上述光擴散劑可單獨地使用或者將2種以 上併用。 於光擴散板30C含有光擴散劑時,光擴散劑之調配比例 相對於透光性樹脂1〇〇重量份為〇 OOiH重量份,較佳為 0.001〜0.01重量份。又,光擴散劑可用作與上述透光性樹 脂之母體膠料《又,自光擴散性之觀點出發,透光性樹脂 之折射率與光擴散劑之折射率之差之絕對值通常為 0·01~0.20,較佳為 〇.〇2〜0.15。 又,於光擴散板3〇C中,根據需要例如可添加紫外線吸 收劑、熱穩定劑、抗氧化劑、耐候劑、光穩定劑、螢光增 白劑、加工穩定剤等各種添加劑。 作為紫外線吸收劑,沒有特別之限定,例如可列舉水楊 酸苯醋系紫外線吸收劑、二苯甲㈣紫外線吸收劑、三喷 系紫外線吸收劑、苯并三唑系紫外線吸收劑等。於添加紫 外線吸收劑時,較佳為相對於透光性樹脂議重量份添加 紫外線吸收劑0·卜3重量份。只要於上述之範圍,就能夠 抑制向紫外線吸收劑之表面之滲出,能夠良好地維持光擴 散板之外觀。 作為熱穩定劑’沒有特別之眼也丨,也丨, 惑限制,例如可列舉錳化合 157219.doc •22· 201213102 物、酮化合物等。於添加熱敎劑時,較佳為於添加紫外 線吸收劑之同時,相對於透光性樹脂中之紫外線吸收劑^ 重量份,以2重量份以下之比例添加熱穩定劑更佳為相 對於透光性樹脂中之紫外線吸收劑i重量份,添加 重量份之熱穩定劑。 又,作為抗氧化劑,沒有特別地限制,例如可列舉受阻 酚化合物、受阻胺化合物等。於添加抗氧化劑時,較佳為 相對於透光性樹脂100重量份添加〇 1〜3重量份之抗氧化 劑。 而且,如圖19所示,光擴散板30C係於半橢圓凸狀部35 相對於燈箱25内之線狀光源22B平行之位置,使光擴散板 30C之背面32抵接於燈箱25之側壁24 ’而將其固定於燈箱 25 °由此’燈箱25之開放面26由光擴散板30C遮檔。 (樹脂片材之構成材料)包含樹脂片材之導光板或者光擴 散板由透光性樹脂形成。透光性樹脂之折射率通常為 1.49〜1.59。作為導光板或光擴散板所使用之透光性樹脂, 主要可使用曱基丙烯酸系樹脂。作為導光板或光擴散板所 使用之透光性樹脂’可使用其他之樹脂,亦可使用苯乙浠 系樹脂。作為透光性樹脂’可使用丙烯酸系樹脂、苯乙烯 樹脂、碳酸酯樹脂、環狀烯烴樹脂、]VIS樹脂(丙烯酸與苯 乙烯之共聚物)等。 又’圖10所示之樹脂片材60包含形狀轉印層(a)6 1與主 層(B)62,構成形狀轉印層(A)之樹脂(a)之MFR(a)相對於構 成主層(B)之樹脂(b)之MFR(b)之比率(MFR(a)/MFR(b))為 157219.doc •23· 201213102 1.5以上。MFR(a)及MFR(b)為以JISK7210為標準,於溫度 200°C、49 N荷重條件下測定之測定值(mfr : Melt flow rate,熔體流動速率)^該比率較佳為1〇以下,如果超過, 則表層之厚度變得不固定’或容易產生流痕(fl〇w mark) 作為構成形狀轉印層(A)之樹脂(a) ’通常可列舉利用加 熱而成為熔融狀態之熱塑性樹脂。較佳為樹脂(a)為苯乙烯 系樹脂或者丙烯酸系樹脂。樹脂(a)可為其他樹脂,可為碳 酸酯樹脂、環狀烯烴樹脂、MS樹脂(丙烯酸與苯乙烯之共 聚物)等。上述樹脂可添加光擴散劑、紫外線吸收劑、熱 穩定劑、抗靜電劑等添加劑。 作為構成主層(B)之樹脂(b),通常可列舉利用加熱而成 為熔融狀態之熱塑性樹脂。較佳為樹脂(b)為苯乙烯系樹脂 或者丙烯酸系樹脂。樹脂(b)可為其他樹脂,可為碳酸酯樹 月曰、環狀烯烴樹脂、MS樹脂(丙稀酸與苯乙歸之共聚物) 等。上述樹脂可添加光擴散劑、紫外線吸收劑、熱穩定 劑、抗靜電劑等添加劑。 (MFR值之例子)於構成形狀轉印層(A)之樹脂⑷及構成 主層(B)之樹脂(b)均為苯乙烯系樹脂時,可使mfr⑷為5 g/l〇 min〜15 g/10 min,使MFR(b)為 0.5 g/10 min〜2.0 g/10 min。 · 又’於構成形狀轉印層(A)之樹脂(a)及構成主層(B)之樹 脂(b)均為丙烯酸系樹脂時,可使MFR(a)為0.4 g/10 min〜3.0 g/l〇 min,使MFR(b)為 0.1 g/l〇 min〜2.0 g/min。 (樹脂片材之製造方法)對本發明之實施形態之樹脂片材 157219.doc •24· 201213102 之製造方法進行說明。圖9係表示本發明之實施形態之樹 脂片材之製造方法之順序之流程圖。本實施形態之樹脂片 材之製造方法例如能夠使用圖1〜圖5及圖20所示之樹脂片 材製造裝置50來實施。如圖9所示,本實施形態之樹脂片 材之製造方法具備將加熱熔融狀態之樹脂自模具連續地擠 出而成形出連續樹脂片材之片材製造步驟(S1),及使用周 面形成有轉印模(形狀輥)而將轉印模轉印至連續樹脂片材 之轉印步驟(S2)。 (片材製造步驟)於片材製造步驟中,以加熱熔融狀態將 樹脂自模具51連續地擠出而製造連續樹脂片材6〇。作為本 發明之製造方法較用之樹脂可列舉利用加熱而成為熔融 狀態之熱塑性樹脂。 常之擠出成形法相同, 軸擠出機,亦可為雙與 熱,以熔融之狀饈妯u 作為以加熱熔融狀態將上述樹脂連續地擠出之模具51, 可使用與通常之擠出成形法所使狀相同之金屬製之丁模 具等°對以加熱溶融狀態將樹脂自模具51擠出而言,與通 可使用擠出機58。擠出機58可為單Km, the aspect ratio (Η/P) is 0. 3 or more, the cross-section (four) shape of the groove portion in the direction orthogonal to the circumferential direction of the shape roll is substantially a half shape, a field semi-elliptical shape or a prism shape; if it is adapted to form a shape of an optical lens, it is difficult to use the previous manufacture. The method is to produce a surface shape transfer resin sheet with a high transfer rate of 157219. Doc 201213102 material. According to the method for producing a resin sheet of the present invention, a surface shape transfer resin sheet having a high transfer rate can be produced even in the transfer mold having high transfer difficulty. Further, it is preferable that the resin (a) constituting the shape transfer layer (A) is a stupid vinyl resin or an acrylic resin, and the resin (b) constituting the main layer (B) is a stupid vinyl resin or an acrylic resin. [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the drawings. In addition, the same or equivalent elements are denoted by the same reference numerals, and the repeated description is omitted. The dimensional ratios of the drawings are not necessarily identical to the illustrated objects. (Manufacturing Apparatus of the Known Sheet) Fig. 1 is a schematic configuration diagram of a resin sheet manufacturing apparatus according to an embodiment of the present invention. The resin sheet manufacturing apparatus 5 is an apparatus which can be used in the method for producing a resin sheet according to an embodiment of the present invention. The resin sheet manufacturing apparatus 50 includes a mold 51 in which a resin in a heated and molten state is continuously extruded to obtain a continuous resin sheet 6 , and a continuous resin sheet extruded from the mold 51 from both sides in the thickness direction. The first pressing view (the pressing roll in the present invention) 52 of the 60 and the second pressing roll (the shape roll in the present invention) 52 are. Further, the resin sheet manufacturing apparatus 50 includes a resin inlet 57 for introducing a resin as a raw material, and an extruder 58 for extruding a resin introduced from the resin inlet 57. The resin sheet manufacturing apparatus 50 of the present embodiment has a configuration in which the resin sheet 60 having a multilayer structure laminated in the thickness direction can be manufactured. In the present embodiment, the continuous resin sheet 6 having the two-layer structure shown in Fig. 10 is produced. Explain the situation. 1572l9. Doc 201213102 The first pressing roller 52A and the second pressing roller 52B are configured to be rotatable about mutually parallel rotation axes. The first pressing roller 52A and the second pressing roller 52B are disposed apart from each other in the thickness direction of the resin sheet 60, and the circumferential surfaces of the resin sheet 60 are set in accordance with the thickness of the resin sheet 60. As shown in Fig. 8, Fig. 21, Fig. 22, and Fig. 23, a transfer mold 53 corresponding to the uneven shape transferred to the resin sheet 60 is formed on the circumferential surface of the second pressing roll 52B. In the following, the structure of the resin sheet manufacturing apparatus according to the second embodiment of the present invention is shown in FIG. The resin sheet manufacturing apparatus 50B shown in FIG. 2 differs from the resin sheet manufacturing apparatus 5 shown in FIG. 1 in that it has the third stage in the second stage of the second pressing pair (shape report in the present invention) 52B. Squeeze roller 52C. The third pressing roller 52C has the same configuration as the first pressing roller (the pressing roller in the present invention) 52A. The continuous resin sheet 6 is sandwiched between the third pressing roll 52C and the second pressing roll 52B to be pressed. Fig. 3 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a third embodiment of the present invention. The resin sheet manufacturing apparatus 5〇c shown in Fig. 3 differs from the resin sheet manufacturing apparatus 50 shown in Fig. 1 in that! The nip roller (the squeezing roller in the present invention) 52A is provided with a pre-pressing roller 52D in the preceding stage. The pre-compression roller 52D has the same configuration as that of the first squeezing roller 52A. The continuous resin sheet 60 is sandwiched between the pre-pressing roll 52D and the i-th pressing roll 52a to be pressed. Fig. 4 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a fourth embodiment of the present invention. The resin sheet manufacturing apparatus 5A shown in FIG. 4 differs from the resin sheet manufacturing apparatus 50B shown in FIG. 2 in that the third pressing roll 52 (after the second pressing of the second pressing member) The 压β)β other composition is the same as I572I9 of Figure 2. The resin sheet manufacturing apparatus 50B shown in doc 201213102 has the same configuration. The continuous resin sheet 60 is sandwiched between the fourth pressing roll 52E and the third pressing roll 52C to be pressed. The continuous resin sheet 60 is conveyed in a state in which the shape transfer layer 61 and the fourth pressing roller 52E are in close contact with each other. Fig. 5 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a fifth embodiment of the present invention. The resin sheet manufacturing apparatus 50E shown in FIG. 5 differs from the resin sheet manufacturing apparatus 50C shown in FIG. 3 in that a third pressing roll is provided after the second pressing roll (the shape roll in the present invention) 52B. (post-squeezing roller) 52C. The other constitution is the same as that of the resin sheet manufacturing apparatus 5〇c shown in Fig. 3 . The continuous resin sheet 60 is sandwiched between the third pressing roll 52C and the second pressing roll 52B to be pressed. The continuous resin sheet 6 is conveyed in a state in which the non-shape transfer layer is in close contact with the third squeeze roll 52C. As shown in Fig. 1 to Fig. 3, a plurality of rollers may be arranged adjacent to each other in the vertical direction. Alternatively, as shown in Figs. 4 and 5, a plurality of rollers may be arranged adjacent to each other in the horizontal direction. Further, the plurality of rollers may be arranged adjacent to each other in a direction inclined with respect to the horizontal direction. In the resin sheet manufacturing apparatus 50E shown in FIG. 5, the third pressing roll 52C is disposed in the subsequent stage of the second pressing roll (the shape roll in the present invention) disposed in the third position, so that the resin can be used. The upper half (18-degree portion) of the second pressing roll 52B is in close contact with each other. Further, by bringing the continuous resin sheet into close contact with the third pressing roll 52C, the temperature of the continuous resin sheet can be adjusted. Fig. 20 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a sixth embodiment of the present invention. The resin sheet manufacturing apparatus 5A shown in Fig. 20 differs from the resin sheet manufacturing apparatus 50C shown in Fig. 3 in that it is used immediately. Doc 201213102 The heater 59 that heats the surface of the sheet on the side of the shape transfer layer 61 of the continuous resin sheet 60 before the first pressing roll 52A and the second pressing roll 52B sandwich the continuous resin sheet 60. The resin sheet manufacturing apparatus 50F includes a sheet forming machine 54 that extrudes and shapes a raw material resin into a sheet shape, and forms a group of extruded roll sheets by extruding the extruded continuous resin sheet 60 ( 52d, 52A, 52B), and a pair of extraction rolls (52G, 52H) for extracting a continuous resin sheet 60. The sheet forming machine 54 includes a first extruder (sub-extruder) 58A for heating and melting the raw material resin (a) of the shape transfer layer (VIII) 61, and is used for the main layer (B) 62. a second extruder (main extruder) 58B that is heated and melted by the raw material resin (8), and a feeder table 55 to which the resin melted in the i-th and second extruders 58 and 58B is supplied, and used in The resin mold 51 in the feeder table 55 is extruded in a sheet state. As the first and second extruders 58A and 58B, for example, a known extrusion molding machine such as a single-shaft extruder or a twin-screw extruder can be used. And the second dispensers 58A and 58B are provided with a hopper (resin input port) 57 for introducing a resin into the measuring cylinder of the extruder. As a feeder. 55 is not particularly limited as long as it can be coextruded in a state in which two or more kinds of resins can be supplied to the mold 51. For example, two types of three layers can be used, and that the two types of layers can be used. Two kinds of two-layer distribution type, etc. are known ϋ ί» .  夂33⁄4 邗 von mold system, etc., for the mold for co-extrusion, there is no special use of the metal 』 mold (10) used in the extrusion molding method of φ (the mold e called the broad training target) Continuous tree rides a piece of wood 157219. The width of the doc 201213102 60 is selected, for example, the 3〇〇mm~3〇〇〇mme pre-pressing roll 52D, the second pressing roll 52A, and the second pressing roll 52B are each made of a cylindrical metal (for example, made of stainless steel). Rolls made of iron steel, etc., have a cooling report that has the function of adjusting the temperature of the peripheral surface (surface temperature). A concave transfer mold 53 for forming a semi-elliptical convex portion like a groove 35b (see Figs. 18 and 19) on the continuous resin sheet 6G is provided on the circumferential surface of the second pressing view 52?. As shown in Fig. 2!, in the gravure transfer mold 53, a semi-elliptical groove 7〇 which is a groove portion opposite to the semi-elliptical convex shape 4 35 is formed along the circumferential direction of the second squeeze roll UR. Striped. That is, in the pair of intaglio transfer molds, the ridges 71 between the semi-circumferential grooves 7 〇 and the adjacent semi-elliptical grooves 70 are alternately arranged along the axial direction of the second squeezing roller 52 。. In the semi-elliptical groove 70, a cross section perpendicular to the longitudinal direction (circumferential direction) has a substantially semi-elliptical shape. The depth Η of the semi-elliptical groove is slightly larger than the height η of the semi-elliptical convex portion 35, and is, for example, 1 〇〇 μηι 5 to 5 〇〇 (4) = = 100 μηι to 300 μηι or less. If the depth is too large, the high-flowing polystyrene tree (the resin (4) constituting the shape transfer layer 61) hardly enters the front end of the semi-circular groove 70. Further, the distance between the centers of the semi-elliptical grooves 70 adjacent to each other according to the semi-elliptical convexity (pitch p) is appropriately determined, for example, 2〇〇μηη~5〇〇' is preferably 250 μηι~ 450 μιη', and further preferably 3 〇〇μιη~400 μ, when the pitch is less than 200 Å, the resin is in contact with the second squeezing roller 53 to cure, and as a result, the shape transfer layer is formed. ) The tree of 61 () does not enter the front end of the semi-elliptical groove 7〇 and cannot obtain the target rotation. The other side, when the pitch P exceeds 500 μη, it is useful for 1572l9. Doc 201213102 The eyeglasses of the pitch can be observed on the liquid crystal panel by the naked eye, or there is a pattern of interference fringe patterns such as the liquid crystal panel 10 or the optical film 41. Further, the aspect ratio represented by the ratio (H/P) of the height η of the semi-elliptical groove 70 to the pitch P is, for example, 0. 3 or more, preferably 〇5 to 〇7 ^ In addition, the difference between the height Η of the semi-expanded convex portion 35 and the depth η of the semi-elliptical groove 70 is caused by the transfer of the intaglio transfer mold 53 to the continuous resin sheet. The transfer rate (η, /η) (%) when the material is 6 〇 to form the semi-elliptical convex portion 35. Further, a motor (not shown) is connected to the rotation shafts of the respective pressing rolls (52D, 52A, 52B). The pre-pressing roller 52D and the second pressing roller 52B are rotatable counterclockwise. The first weaving roller 52A can be rotated clockwise. That is, the squeezing reports (52D, 52A, 52B) are "reversible clockwise rotation", "clockwise rotation", and "reversible clockwise rotation" from top to bottom. Thereby, it is possible to perform the synchronous rotation in a state where the continuous resin sheet 6 is sandwiched by all the rolls (52D, 52A, 52B). Further, the conveying speed of the resin sheet 6 can be adjusted by appropriately adjusting the rotational speed of the pressing rolls (52D, 52A, 52B). The diameter of each squeeze (52D, 52A, 52B) is, for example, 1 mm to 500 mm. Further, when a metal roll is used as the pressing roll (52D, 52A, 52B), the surface may be subjected to a plating treatment such as chrome plating, copper plating, nickel plating, or Ni-P plating. Further, it is provided in the vicinity of the first pressing roller 52A for the first! The surface of the shape transfer layer 61 (the surface on the side to be transferred) of the resin sheet 60 conveyed on the squeezing roller 52A is heated by a heater 59. The heaters 59 are disposed to face each other so as to be apart from the circumferential surface of the i-th squeezing roller 52A, and the continuous resin sheet 6 搬 conveyed from the sheet surface side of the shape transfer layer is heated as a heater 1572i9. . Doc • 12· 201213102 59' For example, a known heater such as an infrared heater can be used. Further, the heater 59 may be an in-line heater provided on a route for conveying the continuous resin sheet 6A. The portable heater may be a portable heater that allows an operator to perform measurement by hand. The pair of extraction roller groups (52G, 52H) include a pair of extraction rolls 52G, 52H sandwiching the continuous resin sheet 60 from both sides in the thickness direction. The extraction reports 52G and 52H each comprise a cylindrical metal (for example, stainless steel, iron steel, etc.) roller so that the upper end of the lower extraction 52H is at the same end as the second extrusion (shape report) 52b. The position is set in the height position. As a result, horizontal conveyance can be performed in a state where the continuous resin sheet 60 fed from the second squeeze roll 52B is supported at the height just sent out, so that the conveyance resistance can be reduced. (Continuous Resin Sheet) Next, a continuous resin sheet produced by the production method of the embodiment of the present invention will be described. Fig. 1 is a cross-sectional view showing the layer constitution of a continuous resin sheet according to an embodiment of the present invention. Fig. 1A is a cross-sectional view taken in a direction orthogonal to the continuous direction (X direction) of the continuous resin sheet (y direction, z direction), and shows a state before the surface shape is transferred. The continuous resin sheet 60 has a multilayer structure in which a plurality of layers are laminated in the thickness direction (two directions) of the sheet, and has a shape transfer layer (A) 61 and a main layer (b) 62 which constitute the sheet surface 60a. For example, the surface shape is transferred to the shape transfer layer (A) 61 having the sheet surface 60a. The main layer (B) 62 is disposed adjacent to the back side of the shape-transferred transfer layer (A) 61 in the thickness direction of the sheet. The continuous resin sheet 60 may be composed of two types of two layers as shown in FIG. 10 (shape transfer layer (A) / main layer (B)), or two kinds of three layers (shapes as shown in FIG. 6). Turn 157219. Doc -13· 201213102 Printing layer (A) / main layer (B) / back layer). The continuous resin sheet 6A shown in Fig. 6 is provided with a shape transfer layer (A) 61 constituting the sheet surface 60a, a back surface layer 63 constituting the sheet surface 60b, and a shape transfer layer (A) 61 interposed therebetween. And the main layer (B) 62 of the back layer 63. In the case of two types of three layers, the resin constituting the shape transfer layer 61 and the back layer 63 is the same resin. Fig. 7 is a perspective view schematically showing the constitution of a resin sheet according to an embodiment of the present invention. Fig. 7 shows a resin sheet 30 formed by cutting the continuous resin sheet 60 into a specific size. The resin sheet 30 can be used as the light guide plate 30 or the light diffusing plate 30C mounted on the surface light source devices (backlights) 20 and 20B of the transmissive image devices 1 and 1B (see Figs. 11 and 16) which will be described later. As a surface light source device (backlight) 20, 20B, an LED (light emitting diode) light source is disposed on the side surface 3 3 of the light guide plate 30, and can be used as the side 3 3 of the self-light guide plate 30. The end face that is incident on the front side is illuminated. Further, a light source may be disposed as a light guide plate with respect to the side surface 33 of the resin sheet, or a light source may be disposed on the back surface 32 of the resin sheet to serve as a light diffusing plate (details will be described later). When the resin sheet is used as the light guide plate 30, the back surface 32 of the resin sheet is usually subjected to reflection processing for diffusely reflecting light incident from the side surface. As a method of performing the printing of the reflective processing, in addition to screen printing, ink jet printing can be performed. Alternatively, as a method of reflection processing, the unevenness of the dot shape may be imparted by laser irradiation without performing printing. The surface 31 of the resin sheet 30 is formed with a plurality of convex portions 35 that extend in the i-th direction (the z-axis direction) and are arranged side by side in the second direction (y-axis direction) orthogonal to the second direction. The concave and convex portion 157219 having the convex portion 35 formed on the surface 31. Doc •14· 201213102 The shape is formed by a transfer step described later. (Example of use of light guide plate) Next, a specific use example of the light guide plate will be described with reference to Fig. 11 . Fig. 11 is a cross-sectional view schematically showing the configuration of an embodiment of a transmissive image display device including the light guide plate of the present invention. Fig. 11 is an exploded view of the transmissive image display device 1. (Transmissive Image Display Device) The transmissive image display device 1 includes a transmissive image display unit 10 and a surface light source device 20 disposed on the back side of the transmissive image display unit 1A in Fig. 11 . As shown in FIG. 11, the direction in which the surface light source device 2A and the transmissive image display unit 10 are arranged is referred to as the Z direction (plate thickness direction), and the two directions orthogonal to the two directions are orthogonal to each other. It is the χ direction and the y direction. The transmissive image display unit 10 is, for example, a liquid crystal display panel in which the linear polarizing plates 12 and 12 are disposed on both surfaces of the liquid crystal cell. At this time, the transmissive image display device! For the liquid crystal display device (or the liquid crystal television, the liquid crystal cell 11, the polarizing plates 12, 12, an element used in the transmissive image display device 1 such as the liquid crystal display device of the prior art can be used. As the liquid crystal cell 丨 exemplified TFT (Thin Film) A well-known liquid crystal cell such as a Transistors 'film transistor type' or a STN (Super Twisted Nematic type) (surface light source device) Fig. 12 is a view schematically showing one of the surface light source devices including the light guide plate of the present invention. FIG. 13 is a rear view showing a configuration of another embodiment of a surface light source device including a light guide plate according to the present invention. FIG. 14 is a view schematically showing a surface light source device including the light guide plate of the present invention. A front view of the composition of one embodiment. Figure 157219. Doc • 15· 201213102 11 to 14 , the surface light source device 2 〇 includes a light guide plate (optical sheet) 3 〇 and an LED light source (point light source) disposed opposite to the side surface 33 of the light guide plate 30 . The front side of the light guide plate 30 may be configured such that various films 41 are disposed between the light guide plate 3A and the transmissive image display unit 10. Examples of the various films 41 include a diffusion film, a ruthenium film, and a brightness enhancement film. The (light source) LED light source 22 functions as a point light source of the surface light source device 2A, and as shown in FIG. 12, is disposed opposite to the side faces 33 and 33 extending in the z-axis direction of the light guide plate 30. The LED light source 22 is discretely arranged along the longitudinal direction (y-axis direction) of the side surface 33. The arrangement distance of the LED light source 22 is usually 5 mm to 20 mm, and the point light source may be opposite to the four sides of the light guide plate 3 The arrangement of the method can be arranged on the two sides opposite to the X-axis direction (see FIG. 12) and the two sides facing the y-axis direction, and can be arranged only on the side (see FIGS. 13 and 14). And 'the point light source is not limited to the led light source, but can be other point light sources. Further 'light source It is limited to a point light source, and may be configured by a wired light source (cold cathode tube). The LED light source 22 may be a white LED 'may also be configured with a plurality of LEDs at one place to form a light source unit. For example, as a light source unit, LEDs of three colors of red, green, and blue are arranged in close proximity, and a light source unit having a plurality of LEDs is discretely arranged along the above-described arrangement direction. In this case, it is preferable that different LEDs are as close as possible to each other. As the LED light source, a light source having various light distributions can be used, and the light intensity of the normal direction (z-axis direction) of the LED light source is maximum, and preferably the half value width of the light-emitting intensity distribution is 40. Above the 80 degrees below the 157219. Doc •16· 201213102 Light source for light distribution. Further, as the type of the LED light source, specifically, a Lambertian type, a cannonball type, a lateral emission type, or the like can be cited. (Light guide plate) As shown in FIGS. 12 to 14, the light guide plate 3 is formed in a rectangular shape, and the size of the plan view shape is selected so as to be suitable for the screen size of the display device 1 目标 at the target transmission type, and the two sides of the orthogonal The length (LlxL2) is usually 25 〇 mm X 44 〇 mm or more, preferably 500 mm x 800 mm or more. The plan view shape of the light guide plate 30 is not limited to a rectangular shape and may be a square shape. However, unless otherwise specified, the shape of the light guide plate 30 will be described below. The light guide plate 30 is formed of a light transmissive light transmissive resin and formed into a plate shape. Further, the light guide plate 30 may be in the form of a sheet or a film. Preferably, the thickness T of the light guide plate is 1 · 0 mm or more. 5 mm or less. The light guide plate 30 is provided with one of the opposite main faces (31, 32) in the z-axis direction (thickness direction), one of the opposite side faces 33, 33 in the X-axis direction, and one of the opposite directions in the γ-axis direction. On the sides 34, 34. The main faces (3 1, 32) are formed in a direction crossing the side faces (33, 34). One of the main surfaces (31) facing the main surface in the z-axis direction functions as an exit surface 31 capable of emitting planar light. The exit surface 31 is disposed on the other side (back surface 32) of the transmissive image display unit 10 side, and is disposed on the opposite side of the transmissive image display unit 10. Further, a reflection sheet 42 for reflecting the light in the light guide plate 30 toward the emission surface 31 side is applied to a position opposite to the back surface 32. (Reflection processing) Further, as shown in FIGS. 12 and 13, a reflection processing (for example, screen printing) for diffusing light reflection is applied to the back surface 32 of the light guide plate 30 as a method of performing reflection processing, except for the screen. In addition to printing, inkjet printing is possible. Or 'as a method of reflection processing, without printing, use 157219. Doc •17· 201213102 Laser irradiation gives the unevenness of the dot shape. In the light guide plate 3 of the present embodiment, a dot pattern is printed as a reflection process. In the printing of dot patterns, an ink having diffusing particles for diffusing light is used. Further, the diameters of the dots 38 (printing dots) constituting the dot pattern are coordinated to change as they go away from the light source side. For example, the diameter of the dot near the side of the region near the light source is about 5 16 μηι, so that the diameter of the dot near the center of the panel farthest from the light source is about 9 〇 4 μηι, so that The diameter of the dot in the middle area is about 729 μηη. (Concave-convex shape) Fig. 7 is a perspective view schematically showing a configuration of an embodiment of a light guide plate of the present invention, and Fig. 15 is a perspective view schematically showing a configuration of another embodiment of the light guide plate of the present invention. A plurality of convex portions 35 projecting toward the outer side in the z-axis direction are formed on the exit surface 31. The convex portions 35 extend in the X-axis direction (one direction) and a plurality of them are arranged side by side in the y-axis direction. Further, the shape of the convex portion 35 may be a 稜鏡 shape, a substantially semicircular shape, a substantially elliptical shape, or the like, and is preferably a shape that continuously changes in one convex portion 35 (shape unit), for example, a semicircular shape or A semi-elliptical shape is better than a 稜鏡 shape. Further, it is preferable that the extending direction of the convex portion 35 is parallel to the outgoing direction of the light from the light source. Further, a flat portion may be formed between the adjacent convex portions 35 and 35 in a direction in which the convex portions 35 are adjacent to each other (y-axis direction). Further, the shape of the convex portion may be an optical lens shape. Fig. 8 is an enlarged view showing the convex portion in Fig. 7 from the X-axis direction. Here, the convex portion 35 satisfies ΗχΤ/Ρ2〇. 23···(1) can be. Here, p is the interval (μιη) of the adjacent convex portions 35 and 35, η is the height (μπι) of the convex portion 35, and τ is the sheet thickness (mm). As shown in Fig. 8, the interval ρ is the apex of the adjacent convex portion 35 157219. Doc •18· 201213102 The distance between 35a and 35a. The height H of the convex portion 35 is the distance between the lower end 35b of the convex portion 35 and the apex 35a. The sheet thickness T is the distance between the apex 35a of the convex portion 35 and the back surface 32. (Construction Material of Light Guide Plate) The light guide plate 30 is formed of a light transmissive resin. The refractive index of the transparent resin is usually 1_49~1. 59. As the light-transmitting resin used for the light guide plate 30, a methacrylic resin is mainly used. As the light-transmitting resin used for the light guide plate 3, other resins may be used, and a styrene-based resin may be used. As the light-transmitting resin, an acrylic resin, a styrene resin, a carbonate resin, a cyclic olefin resin, an MS resin (a copolymer of acrylic acid and the present invention), or the like can be used. The light guide plate is applied to a liquid crystal display device (transmissive image display device 1), and an additive such as a light diffusing agent, an ultraviolet absorber, a heat stabilizer, or a photopolymerization stabilizer may be added to the light guide plate 3. (Example of use of light diffusing plate) Next, an example of use of the light diffusing plate will be described with reference to Fig. 16 . Fig. 16 is a side view schematically showing a configuration of an embodiment of a transmissive image display device including the light diffusing plate of the present invention. Figure 17 is a schematic perspective view of the transmissive image display device shown in Figure 16. (Transmissive Image Display Device) The transmissive image display device (7) includes a transmissive image display unit H) and a surface light source device 2 disposed on the side of the transmissive image display unit ι of FIG. b. As shown in FIG. 6, the direction in which the surface light source device 2A and the transmissive image display unit 1 are arranged is referred to as the z direction (plate thickness direction), and the direction orthogonal to the z direction is orthogonal to each other. The two directions are called the X direction and the y direction. Examples of the transmissive image display portion 1G include linear polarizing plates 12 and 157219. Doc • 19- 201213102 12 A liquid crystal display panel disposed on both sides of the liquid crystal unit 11. At this time, the transmissive image display device 1 is a liquid crystal display device (or a liquid crystal television). As the liquid crystal cell 11, the polarizing plates 12, 12, an element used in the transmissive image display device 1 such as a liquid crystal display device can be used. As the liquid crystal cell, a known liquid crystal cell such as a TFT type or an STN type can be exemplified. The surface light source device (backlight system) 20B includes a square-shaped rear wall 23 and a rectangular frame-shaped side wall 24 that is integrally provided from the periphery of the rear wall 23 toward the front (front side), and has a thin box shape in which the front side is open. The resin light box 25; the plurality of linear light sources 22B disposed in the light box 25; and the light diffusing plate 30C that blocks the open surface 26 (front surface) of the light box 25. That is, in the case of the light box 25 of the I-shape, the outline of the open surface 26 is divided by the side wall 24 of the square frame. The linear light source 2 2 B is provided in the space surrounded by the side wall 24 and the rear wall 23. On the inner surface of the wall 2 3 after the lamp phase 25, for example, a reflector 42 for reflecting light incident from the linear light source 22B toward the rear wall 23 side toward the open surface 26 side of the casing is integrally attached (see Fig. 11). The (light source) linear light source 22B is, for example, a cylindrical lamp having a diameter of 2 mm to 4 mm. The plurality of linear light sources 22B are arranged at equal intervals in parallel with each other in a state of being spaced apart from each other with respect to the back surface 32 of the light diffusing plate 30C. From the viewpoint of power saving, it is preferable that the centers of the adjacent linear light sources 22B are spaced apart from each other by a distance Q of 30 mm to 60 mm. Further, from the viewpoint of thinning, it is preferable that the distance R between the back surface 32 of the light diffusing plate 30C (for example, the central portion of the back surface 32) and the center of the linear light source 22B is 10 mm to 20 mm. Further, it is preferable that the ratio of the interval Q to the distance R (Q/R) is 2. 5~4. 0 » Particularly preferred 157219. Doc •20· 201213102 The interval Q is 40 mm to 55 mm and the distance R is 13 mm to 17 mm. Further, the number of the linear light sources 22 is necessarily determined by the size of the light box 25 (the size of the transmission type image display device 1) and the interval Q, and is preferably 6 in the liquid crystal display device 1 of the type 32, for example. ~10 roots. Further, in FIGS. 16 and 17, the linear light source 22A is shown by only five in order to facilitate the illustration. Further, as the linear light source 22A', for example, a known tubular lamp such as a fluorescent lamp (cold cathode tube), a halogen lamp, or a tungsten lamp can be used. Further, as the light source of the surface light source device 20, a point light source such as a light-emitting diode (LED) can be used instead of the linear light source 22A. (Light diffusing plate) Fig. 18 is a schematic perspective view of a light diffusing plate comprising a resin sheet according to an embodiment of the present invention. Fig. 19 is an enlarged cross-sectional view showing the main part of the light box showing the state in which the light diffusing plate is mounted. As shown in Fig. 18, the light diffusing plate 30C is formed in a plate shape of four corners substantially the same as the frame shape of the side wall 24 of the light box 25. The light-diffusing sheet 30C is a light-transmitting multilayer light-diffusing sheet obtained by laminating at least two resin layers in the thickness direction z, and is provided with a shape transfer layer (A) (front layer) 61 containing a high fluidity resin, and The main layer (B) (back layer) 62 containing a low flow resin. Further, the light diffusing plate 30C may contain a light diffusing agent (light diffusing particles) as needed. The light diffusing agent is not particularly limited as long as it has a refractive index different from that of the light-transmitting resin constituting the light diffusing plate 3〇c and can diffuse the transmitted light, and is, for example, an inorganic light diffusing agent. Examples include carbonic acid mother, barium sulfate, titanium oxide, aluminum hydroxide, cerium oxide, glass, talc, mica, white carbon, magnesium oxide, and zinc oxide. These can be implemented with fatty acids, etc. Table 157219. Doc -21· 201213102 The product of surface treatment. In addition, examples of the organic light diffusing agent include styrene polymer particles, acrylic polymer particles, and decane polymer particles. Preferably, the weight average molecular weight is from 500,000 to 5,000,000. The high molecular weight polymer particles and the crosslinked polymer particles having a gel fraction of 1% by mass or more when dissolved in acetone. The above light diffusing agents may be used singly or in combination of two or more. When the light diffusing plate 30C contains a light diffusing agent, the blending ratio of the light diffusing agent is 〇 ii ii parts by weight, preferably 0% by weight based on 1 part by weight of the light transmitting resin. 001~0. 01 parts by weight. Further, the light diffusing agent can be used as a matrix compound of the above-mentioned light transmitting resin. Further, the absolute value of the difference between the refractive index of the light transmitting resin and the refractive index of the light diffusing agent is usually from the viewpoint of light diffusibility. 0·01~0. 20, preferably 〇. 〇2~0. 15. Further, in the light-diffusing sheet 3, C, various additives such as an ultraviolet absorber, a heat stabilizer, an antioxidant, a weathering agent, a light stabilizer, a fluorescent whitening agent, and a process-stabilizing crucible may be added as needed. The ultraviolet absorber is not particularly limited, and examples thereof include a salicylic acid benzene vinegar-based ultraviolet ray absorbing agent, a diphenylene (IV) ultraviolet absorbing agent, a three-spray ultraviolet absorbing agent, and a benzotriazole-based ultraviolet absorbing agent. When the ultraviolet absorber is added, it is preferred to add the ultraviolet absorber 0·b to 3 parts by weight based on the weight of the light-transmitting resin. When it is within the above range, bleed out to the surface of the ultraviolet absorbing agent can be suppressed, and the appearance of the astigmatism plate can be favorably maintained. As a heat stabilizer, there is no particular eye, nor is it a limitation. For example, manganese compound 157219 can be cited. Doc •22· 201213102 Materials, ketone compounds, etc. When a hot sputum agent is added, it is preferred to add a heat absorbing agent at a ratio of 2 parts by weight or less to the ultraviolet absorbing agent in the light-transmitting resin at the same time as the addition of the ultraviolet absorbing agent. A part by weight of the ultraviolet absorber i in the photo-resin is added with a part by weight of a heat stabilizer. Further, the antioxidant is not particularly limited, and examples thereof include a hindered phenol compound and a hindered amine compound. When an antioxidant is added, it is preferred to add 1 to 3 parts by weight of an antioxidant to 100 parts by weight of the light-transmitting resin. Further, as shown in FIG. 19, the light diffusing plate 30C is positioned such that the semi-elliptical convex portion 35 is parallel to the linear light source 22B in the light box 25, and the rear surface 32 of the light diffusing plate 30C abuts against the side wall 24 of the light box 25. 'It is fixed to the light box 25 ° and thus the open face 26 of the light box 25 is blocked by the light diffusing plate 30C. (Constituent Material of Resin Sheet) A light guide plate or a light diffusion plate including a resin sheet is formed of a light transmissive resin. The refractive index of the light transmissive resin is usually 1. 49~1. 59. As the light-transmitting resin used for the light guide plate or the light-diffusing sheet, a mercapto-based acrylic resin can be mainly used. As the light-transmitting resin used for the light guide plate or the light-diffusing sheet, other resins may be used, and a styrene-based resin may also be used. As the translucent resin, an acrylic resin, a styrene resin, a carbonate resin, a cyclic olefin resin, a VIS resin (copolymer of acrylic acid and styrene), or the like can be used. Further, the resin sheet 60 shown in Fig. 10 includes a shape transfer layer (a) 61 and a main layer (B) 62, and the MFR (a) of the resin (a) constituting the shape transfer layer (A) is opposite to the composition. The ratio of MFR(b) of the resin (b) of the main layer (B) (MFR(a)/MFR(b)) is 157219. Doc •23· 201213102 1. 5 or more. MFR (a) and MFR (b) are measured values (mfr: Melt flow rate) measured at a temperature of 200 ° C and a load of 49 N using JIS K7210 as a standard. In the following, when the thickness exceeds, the thickness of the surface layer is not fixed, or a flow mark is easily generated. The resin (a) constituting the shape transfer layer (A) is usually in a molten state by heating. Thermoplastic resin. Preferably, the resin (a) is a styrene resin or an acrylic resin. The resin (a) may be another resin, and may be a carbonate resin, a cyclic olefin resin, an MS resin (a copolymer of acrylic acid and styrene), or the like. Additives such as a light diffusing agent, an ultraviolet absorber, a heat stabilizer, and an antistatic agent may be added to the above resin. The resin (b) constituting the main layer (B) is usually a thermoplastic resin which is heated to be in a molten state. Preferably, the resin (b) is a styrene resin or an acrylic resin. The resin (b) may be another resin, and may be a carbonate tree ruthenium, a cyclic olefin resin, an MS resin (a copolymer of acrylic acid and styrene), or the like. Additives such as a light diffusing agent, an ultraviolet absorber, a heat stabilizer, and an antistatic agent may be added to the above resin. (Example of MFR value) When the resin (4) constituting the shape transfer layer (A) and the resin (b) constituting the main layer (B) are both styrene resins, mfr(4) can be made 5 g/l 〇 min 15 g/10 min, making MFR(b) 0. 5 g/10 min~2. 0 g/10 min. Further, when both the resin (a) constituting the shape transfer layer (A) and the resin (b) constituting the main layer (B) are acrylic resins, MFR (a) can be made 0. 4 g/10 min~3. 0 g/l〇 min, making MFR(b) 0. 1 g/l〇 min~2. 0 g/min. (Method for Producing Resin Sheet) A resin sheet according to an embodiment of the present invention 157219. Doc •24· 201213102 The manufacturing method will be explained. Fig. 9 is a flow chart showing the procedure of a method for producing a resin sheet according to an embodiment of the present invention. The method for producing a resin sheet of the present embodiment can be carried out, for example, by using the resin sheet manufacturing apparatus 50 shown in Figs. 1 to 5 and Fig. 20 . As shown in Fig. 9, the method for producing a resin sheet according to the present embodiment includes a sheet production step (S1) in which a resin in a heated and molten state is continuously extruded from a mold to form a continuous resin sheet, and a peripheral surface is formed. There is a transfer mold (shape roll) to transfer the transfer mold to the transfer step of the continuous resin sheet (S2). (Sheet Manufacturing Step) In the sheet manufacturing step, the resin is continuously extruded from the mold 51 in a heated and molten state to produce a continuous resin sheet 6?. The resin which is used in the production method of the present invention is a thermoplastic resin which is heated to be in a molten state. Usually, the extrusion molding method is the same, and the shaft extruder may be double and heat, and the molten resin is used as a mold 51 for continuously extruding the above resin in a heated and molten state, and can be used and extruded. The metal mold or the like which is formed by the molding method is used to extrude the resin from the mold 51 in a heated and molten state, and the extruder 58 can be used. Extruder 58 can be single

157219.doc 夕層構造’因而向模具51供給2 -狀態進行共擠出。對於將2種以 行共擠出而言,例如使用公知之 經由該器台向模具51供給樹脂。 •25- 201213102 此外,連續樹脂片材60之厚度根據所得之片材之用途進 行適當地調整即可。例如將連續樹脂片材6〇用作導光板3〇 或者光擴散板30C時’片材厚度較佳為之範圍為丨〇 mm以 上4.5 mm以下。 (轉印步驟)轉印步驟(S2)包括如下步驟:轉印開始步驟 (S3) ’藉由以第1擠壓軺^撩壓報)52A及第2擠壓輥(形狀 輥)52B將由片材製造步驟(S1)製造之連續樹脂片材6〇夾持 而進行擠壓;搬送步驟(S4),使轉印開始步驟(S3)中濟壓 而得之連續樹脂片材60與形狀輥52B之周面密接地進行搬 送;及剝離步驟(S5),將搬送步驟(S4)中搬送之連續樹脂 片材60自形狀親52B之周面(轉印模53)剝離。 (轉印開始步驟)如圖1所示’藉由轉印開始步驟(S3),以 第1擠壓輥52A及第2擠壓輥52B自片材之厚度方向之兩側 同時將上述片材製造步驟(S1)中所得之連續樹脂片材6〇炎 持而進行擠壓。 此時’於將構成形狀轉印層(A)之樹脂⑷之玻璃轉移溫 度设為Tg(a)時’即將接連於第2擠壓輥52B之連續樹脂片 材60之表面溫度較佳為(Tg(a)+50°C )〜(Tg(a)+150°C )之範 圍。表面溫度之調整可藉由擯·出機58之設定溫度之變更、 模具5 1之設定溫度之變更而進行調整。此外,連續樹脂片 材60之表面溫度可使用紅外線溫度計而進行計測。 又,可執行加熱步驟,其係於即將進行轉印開始步驟 時,對與第1擠壓輥52A之周面密接地進行搬送之連續樹脂 片材60之形狀轉印層61之片材表面進行加熱。 157219.doc -26- 201213102 於該轉印開始步驟(S3)中,將基於形成於第2擠壓輥(形 狀輥)52B之表面之轉印模53之形狀轉印至連續樹脂片材 6〇。此外,於本發明中’具備轉印模之第2擠壓輥52b亦稱 為轉印輥。上述轉印輥表面具備之轉印模抵壓至連續樹脂 片材60之表面,將其表面形狀作為反模轉印至連續樹脂片 材60。 作為第1及第2擠壓輥52A、52B,通常使用包含不鏽 鋼、鋼鐵等金屬之金屬製輥,其等之直徑通常為ι〇〇 mm〜500 mm。使用金屬製輥作為該等第1及第2擠壓輥 52A、52B時,其表面例如可被施以鍍鉻、鍍銅、鍍鎳、 鍍鎳-磷等鍍敷處理。又,第i擠壓輥52A之表面(周面)可 為鏡面,亦可為實施有壓花等凹凸之轉印面。 (搬送步驟)搬送步驟(84)為以使連續樹脂片材6〇與第2擠 壓輥52B之周面密接之狀態,跟隨第2擠壓輥52B之旋轉而 進行搬送之步驟。 (剝離步驟)剝離步驟(S5)為將連續樹脂片材6〇自第2擠壓 軺> 52B之周面剝離之步驟。 此時’較佳為相對於構成形狀轉印層(A)之樹脂(a)之玻 璃轉移溫度Tg(a),剛剛自第2擠壓輥52B剝離之連續樹脂 片材60之樹脂⑷之表面溫度為(Tg⑷_1〇)£>c〜(Tg(a)+4〇)〇c 之範圍。樹脂(a)之表面溫度比該範圍低時,生產效率不再 變咼。於樹脂(a)之表面溫度比上述之溫度範圍高時,轉印 至連續樹脂片材60之形狀由於熱而容易返回到原來之狀 癌’因此轉印率容易變差。剛剛自第2擠壓輥52b剝離之樹 157219.doc -27· 201213102 脂(a)之表面溫度更佳之範圍為(Tg(a)_5)°C〜(Tg(a)+1〇)〇c之 範圍。 又’將構成主層(B)之樹脂(b)之玻璃轉移溫度設為Tg(b) 時’構成表面層(A)之樹脂(a)之玻璃轉移溫度Tg(a)可為 (Tg(b)+2)°C <Tg(a)°C <(Tg(b)+20)°C 之範圍。 又,於自第2擠壓輥52B剝離後,形狀轉印層(A)之厚度 相對於主層(B)之厚度之比率為1/2〇〇〜1/1〇之範圍。於厚度 比率比1/200小及厚度比率比1/1〇大時,轉印率之提高不充 分。 (轉印模)圖8係模式性地表示形成於轉印模之凹部及形 成於樹脂片材之凸狀部之剖面圖。轉印模53包含設於形狀 輥52B之表面之複數個凹部。例如’凹部係於形狀輥52b 之周方向上連續地形成。凹部之間距通常為3〇 μηι以上, 較佳為50 μιη以上’但本發明之製造方法及製造裝置中, 較佳為凹。ρ之間距間隔為2〇〇 pm〜5〇〇 μπι,凹部之槽深η 為100 μπι〜500 μιη。凹部之間距間隔(ρ)係指鄰接之凹部之 槽部之間(底部彼此)之距離,凹部之槽深係指自形狀輥 52Β之表面圓周上開始到凹部之槽部(底部)為止之距離。 又,凹部之槽深(Η)相對於凹部之間距間隔(Ρ)之比率即 縱橫比(Η/P)例如為〇.3以上,較佳為〇 4〜〇 7。 又,作為轉印模53之凹部之剖面形狀,可列舉半圓形 狀、半橢圓形狀等。又,可為具有與稜鏡形狀對應之銳角 部之V字型形狀。 作為上述轉印模之製作方法,於對包含上述不鏽鋼、鋼 157219.doc •28· 201213102 鐵等之轉印輥之表面實施例如鍍鉻、鍍銅、鍍鎳、鍍鎳 鱗等之錢敷處理後,有時對該鍵敷面進行使用金剛石刀 片、金屬磨刀石等之除去加工、雷射加工或者化學蝕刻, 從而對形狀進行加工,但並不特別限於該等方法。 又,於形成上述轉印模後,例如以不損害表面形狀之精 度之水平,轉印輥之表面可被施以鍍鉻、鍍銅、鍍鎳、鍍 錄-罐等之鑛敷處理。 為了更精密地、重現性良好地形成上述轉印模之槽形 狀,較佳為車床與金剛石刀片之組合,.於銅上實施之鍍鉻 之厚度較佳為5 μιη以下,進而較佳為2 μηι以下。 (樹脂片材之製造方法之變形例)作為製造方法之變形 例,例如可於搬送步驟(S4)後,實施第2擠出步驟❶第2擠 出步驟能夠使用圖2所示之樹脂片材製造裝置5〇B來實施。 於第2擠出步驟中,藉由以第2擠壓輥(形狀輥)52β及第3擠 壓輥52C夾持由搬送步驟(84)搬送之連續樹脂片材6〇而進 行擠壓。將第2擠出步驟中擠出而得之連續樹脂片材6〇自 第2擠壓輥剝離(剝離步驟),與第3擠壓輥52C之周面密接 地進行搬送後,自第3擠壓輥52C之周面剝離。 又,作為製造方法之其他變形例,例如可於轉印開始步 驟(S3)之前,實施預先擠壓之預壓步驟。預壓步驟能夠使 用圖3所示之樹脂片材製造裝置5〇c而實施。於預壓步驟 中,藉由以預壓輥52D與第1擠壓輥52A將由片材製造步驟 (S1)製造之連續樹脂片材6〇夾持而預先進行擠壓。擠出而 得之連續樹脂片材60與第1擠壓輥52A之周面密接地進行搬 157219.doc -29· 201213102 送(預備搬送步驟),利用第1及第2擠壓輥52A、52B實行轉 印開始步驟(S3),對轉印率之提高有效果,較佳為使用該 製造方法》 又’於第1擠壓輥52A之附近,可設置用於對第1擠壓報 52 A上搬送之連續樹脂片材60之表面進行加熱之加熱器。 加熱器以相對於第1擠壓輥52A之周面離開之方式對向配 置’自表面側對搬送之連續樹脂片材進行加熱。作為加熱 器,例如可使用紅外線加熱器等公知加熱器。 (作用)於本發明之樹脂片材之製造方法中,藉由僅使形 狀轉印層為比較良好之流動性,而使主層為較低之流動 性,從而使基於樹脂(a)之表層部易於流入成轉印模之凹部 形狀,自轉印模53剝落後仍易於保持流入成轉印模53之凹 部形狀之樹脂之形狀。由此,能夠使形狀轉印率提高。因 此’能夠於樹脂片材上形成縱橫比高之表面形狀。 (實施例)以下列舉實施例1〜4對本發明進行更為詳細地 說明,但本發明並不限於該等實施例。 (實施例1、比較例1)使用圖3所示之樹脂片材製造裝置 50C製作實施例1及比較例1之片材。以下示出所使用之製 is·裝置50之條件。將擠出機58之螺桿直徑設為40 mm,將 擠出機58之擠出量設為20 kg/hr。將線(line)速度設為0.32 m/min,將片材寬度(γ方向之長度)設為25 cm。作為第2擠 壓報52B之轉印模之形狀’將間距p設為6〇〇 μΓη、深度η設 為300 μιη。將輥溫度(預壓輥52D/第1擠壓輥52Α/第2擠壓 輥 52Β)設為 80°C/80eC/80°C。 157219.doc •30· 201213102 於實施例1中,藉由擠出成形(片材製造步驟)製作片材 厚度4 mm 之 PMMA((P〇lymethylmethacrylate,聚甲基丙烯 酸甲酯)板。於實施例1中,使用2種樹脂製作3層構造之樹 脂片材(參照圖6)。 於構成表面層(A)之樹脂(a)中使用甲基丙烯酸甲酯與丙 烯酸甲酯之共聚物。樹脂(a)之規格如下所示。 重量比.甲基丙稀酸甲醋/丙烯酸曱醋=98/2 MFR(a) : 1.5 g/l〇 min(20(TC、49 N荷重條件) 玻璃轉移溫度Tg(a) : 107°C 厚度(單側):0.1 mm 此外,於23(TC、37 N(3.8 kgf)荷重條件下測定樹脂(a) 之MFR,為 9.4 g/10 min。 於構成主層(B)之樹脂(b)中,使用甲基丙烯酸甲酯與丙 烯酸曱酯之共聚物《樹脂(b)之規格如下所示。 重量比.甲基丙烯酸甲I旨/丙烯酸甲自旨=94/6 MFR(b) : 0.24 g/10 min(20(TC、49 N荷重條件) 玻璃轉移溫度Tg(b) : 102eC 厚度:3.8 mm 此外,於23(TC、37 N(3.8 kgf)荷重條件下測定樹脂(b) 之 MFR ’ 為 1.5 g/10 min。 表面層(A)相對於主層(B)之厚度之比率為1/38。 於比較例1中’使用上述樹脂製作單層構造之樹脂片 材。除使3層構造變為單層構造以外,與上述之實施例相 同0 157219.doc 201213102 於實施例1中,剛剛自第2擠壓輥52B剝離之樹脂片材之 表面溫度為l〇5°C,此時之形狀高度H'為183 μιη,形狀轉 印率(=H7H)為61 %。於比較例1中,剛剛自第2擠壓輥52Β 剝離之樹脂片材之表面溫度為l〇5°C,此時之形狀高度ΙΓ 為168 μιη,形狀轉印率(=H7H)為56%。 下表1表示實施例1及比較例1之試驗條件及試驗結果。 將形狀轉印率為60%以上之情況判定為合格。 [表1]The 157219.doc layer structure is thus supplied to the mold 51 in a 2-state for coextrusion. For the two types of co-extrusion, the resin is supplied to the mold 51 via the table, for example, using a known method. • 25- 201213102 Further, the thickness of the continuous resin sheet 60 may be appropriately adjusted depending on the use of the obtained sheet. For example, when the continuous resin sheet 6 is used as the light guide plate 3 or the light diffusion plate 30C, the thickness of the sheet is preferably in the range of 丨〇 mm or more and 4.5 mm or less. (Transfer Step) The transfer step (S2) includes the steps of: a transfer start step (S3) 'by pressing with a first press squeegee) 52A and a second squeezing roll (shape roll) 52B The continuous resin sheet 6 manufactured by the material manufacturing step (S1) is sandwiched and pressed; and the transfer step (S4) is performed to obtain the continuous resin sheet 60 and the shape roll 52B obtained by the press start step (S3). In the peeling step (S5), the continuous resin sheet 60 conveyed in the transporting step (S4) is peeled off from the peripheral surface of the shape pro 52B (transfer mold 53). (Transfer start step) As shown in Fig. 1, by the transfer start step (S3), the first press roll 52A and the second squeeze roll 52B simultaneously slide the sheets from both sides in the thickness direction of the sheet. The continuous resin sheet 6 obtained in the production step (S1) is pressed and pressed. At this time, when the glass transition temperature of the resin (4) constituting the shape transfer layer (A) is Tg (a), the surface temperature of the continuous resin sheet 60 to be successively connected to the second squeeze roll 52B is preferably ( Tg (a) + 50 ° C) ~ (Tg (a) + 150 ° C) range. The adjustment of the surface temperature can be adjusted by changing the set temperature of the crucible 58 and changing the set temperature of the mold 51. Further, the surface temperature of the continuous resin sheet 60 can be measured using an infrared thermometer. Further, a heating step may be performed which is performed on the surface of the sheet of the shape transfer layer 61 of the continuous resin sheet 60 which is conveyed in close contact with the circumferential surface of the first pressing roller 52A when the transfer start step is performed. heating. 157219.doc -26-201213102 In the transfer start step (S3), the shape of the transfer mold 53 based on the surface formed on the second squeeze roll (shape roll) 52B is transferred to the continuous resin sheet 6〇. . Further, in the present invention, the second pressing roller 52b having the transfer mold is also referred to as a transfer roller. The transfer mold provided on the surface of the transfer roller is pressed against the surface of the continuous resin sheet 60, and its surface shape is transferred as a reverse mold to the continuous resin sheet 60. As the first and second pressing rolls 52A and 52B, a metal roll including a metal such as stainless steel or steel is usually used, and the diameter thereof is usually ι mm to 500 mm. When a metal roll is used as the first and second pressing rolls 52A and 52B, the surface thereof may be subjected to plating treatment such as chrome plating, copper plating, nickel plating, or nickel-phosphorus plating. Further, the surface (peripheral surface) of the i-th squeezing roller 52A may be a mirror surface, or may be a transfer surface on which irregularities such as embossing are applied. (Transporting step) The transporting step (84) is a step of transporting the second pressing roller 52B in a state in which the continuous resin sheet 6A and the second pressing roller 52B are in close contact with each other. (Peeling Step) The peeling step (S5) is a step of peeling the continuous resin sheet 6 from the circumferential surface of the second extrusion 轺 > 52B. At this time, it is preferable that the surface of the resin (4) of the continuous resin sheet 60 which has just been peeled off from the second pressing roll 52B is the glass transition temperature Tg(a) of the resin (a) constituting the shape transfer layer (A). The temperature is in the range of (Tg(4)_1〇)£>c~(Tg(a)+4〇)〇c. When the surface temperature of the resin (a) is lower than this range, the production efficiency is no longer deteriorated. When the surface temperature of the resin (a) is higher than the above temperature range, the shape transferred to the continuous resin sheet 60 is easily returned to the original state due to heat. Therefore, the transfer rate is liable to be deteriorated. The tree which has just been peeled off from the second squeeze roll 52b 157219.doc -27· 201213102 The surface temperature of the grease (a) is more preferably in the range of (Tg(a)_5) °C~(Tg(a)+1〇)〇c The scope. Further, 'when the glass transition temperature of the resin (b) constituting the main layer (B) is Tg(b), the glass transition temperature Tg(a) of the resin (a) constituting the surface layer (A) may be (Tg ( b) +2) ° C < Tg (a) ° C < (Tg (b) + 20) ° C range. Further, after peeling from the second pressing roll 52B, the ratio of the thickness of the shape transfer layer (A) to the thickness of the main layer (B) is in the range of 1/2 Å to 1/1 Torr. When the thickness ratio is smaller than 1/200 and the thickness ratio is larger than 1/1, the improvement in the transfer rate is insufficient. (Transfer Mode) Fig. 8 is a cross-sectional view schematically showing a concave portion formed in a transfer mold and a convex portion formed in a resin sheet. The transfer mold 53 includes a plurality of recesses provided on the surface of the shape roller 52B. For example, the recessed portion is continuously formed in the circumferential direction of the shape roller 52b. The distance between the concave portions is usually 3 〇 μη or more, preferably 50 μm or more. However, in the production method and manufacturing apparatus of the present invention, it is preferably concave. The interval between ρ is 2〇〇 pm~5〇〇 μπι, and the groove depth η of the concave portion is 100 μπι to 500 μιη. The interval (ρ) between the recesses refers to the distance between the groove portions of the adjacent concave portions (bottom portions), and the groove depth of the concave portion refers to the distance from the circumferential surface of the shape roller 52Β to the groove portion (bottom portion) of the concave portion. . Further, the ratio of the groove depth (Η) of the concave portion to the interval (Ρ) between the concave portions, i.e., the aspect ratio (Η/P) is, for example, 〇.3 or more, preferably 〇 4 to 〇 7. Further, the cross-sectional shape of the concave portion of the transfer mold 53 may be a semicircular shape or a semi-elliptical shape. Further, it may be a V-shaped shape having an acute angle corresponding to the shape of the crucible. As a method of producing the transfer mold, the surface of the transfer roller including the stainless steel or the steel 157219.doc • 28·201213102 iron is subjected to, for example, chrome plating, copper plating, nickel plating, nickel plating, or the like. The key surface may be processed by a diamond blade, a metal whetstone, or the like by laser processing, laser processing, or chemical etching to process the shape, but is not particularly limited to these methods. Further, after the transfer mold is formed, for example, the surface of the transfer roller can be subjected to a mineralization treatment such as chrome plating, copper plating, nickel plating, plating-can, or the like, at a level that does not impair the accuracy of the surface shape. In order to form the groove shape of the transfer mold more precisely and reproducibly, it is preferably a combination of a lathe and a diamond blade. The thickness of the chrome plating on the copper is preferably 5 μm or less, and more preferably 2 Below μηι. (Modification of Manufacturing Method of Resin Sheet) As a modification of the production method, for example, after the transfer step (S4), the second extrusion step can be performed. The second extrusion step can use the resin sheet shown in FIG. The manufacturing apparatus 5〇B is implemented. In the second extrusion step, the continuous resin sheet 6〇 conveyed by the conveying step (84) is held by the second pressing roll (shape roll) 52β and the third pressing roll 52C, and is pressed. The continuous resin sheet 6 obtained by extruding in the second extrusion step is peeled off from the second pressing roll (peeling step), and is conveyed in close contact with the circumferential surface of the third pressing roll 52C. The peripheral surface of the pressure roller 52C is peeled off. Further, as another modification of the manufacturing method, for example, a pre-pressing pre-compression step may be performed before the transfer start step (S3). The pre-pressing step can be carried out using the resin sheet manufacturing apparatus 5〇c shown in Fig. 3 . In the pre-pressing step, the continuous resin sheet 6 manufactured by the sheet manufacturing step (S1) is sandwiched by the pre-pressing roller 52D and the first pressing roller 52A, and is pressed in advance. The continuous resin sheet 60 obtained by extrusion and the circumferential surface of the first squeeze roll 52A are placed in close contact with each other, and are transported 157219.doc -29·201213102 (prepared transfer step), and the first and second squeeze rolls 52A, 52B are used. The transfer start step (S3) is carried out, which has an effect on the improvement of the transfer rate, and is preferably used in the vicinity of the first squeeze roll 52A, and can be provided for the first squeeze report 52 A. A heater that heats the surface of the continuous resin sheet 60 that has been transferred. The heater is heated to the continuous resin sheet conveyed from the surface side so as to be spaced apart from the circumferential surface of the first pressing roller 52A. As the heater, for example, a known heater such as an infrared heater can be used. (Function) In the method for producing a resin sheet of the present invention, the surface layer of the resin (a) is made to have a lower fluidity by merely making the shape transfer layer have a relatively good fluidity. The portion easily flows into the shape of the concave portion of the transfer mold, and it is easy to maintain the shape of the resin flowing into the shape of the concave portion of the transfer mold 53 after being peeled off from the transfer mold 53. Thereby, the shape transfer rate can be improved. Therefore, it is possible to form a surface shape having a high aspect ratio on the resin sheet. (Embodiment) Hereinafter, the present invention will be described in more detail with reference to Examples 1 to 4, but the present invention is not limited to the examples. (Example 1 and Comparative Example 1) Sheets of Example 1 and Comparative Example 1 were produced using the resin sheet manufacturing apparatus 50C shown in Fig. 3 . The conditions of the is device 50 used are shown below. The screw diameter of the extruder 58 was set to 40 mm, and the extrusion amount of the extruder 58 was set to 20 kg/hr. The line speed was set to 0.32 m/min, and the sheet width (length in the γ direction) was set to 25 cm. The shape of the transfer mold as the second squeeze report 52B is set to a pitch p of 6 〇〇 μΓη and a depth η of 300 μm. The roll temperature (pre-press roll 52D / first press roll 52 Α / second press roll 52 Β) was set to 80 ° C / 80 eC / 80 ° C. 157219.doc •30·201213102 In Example 1, PMMA ((P〇lymethylmethacrylate) sheet having a sheet thickness of 4 mm was produced by extrusion molding (sheet manufacturing step). In the first embodiment, a resin sheet having a three-layer structure is produced using two kinds of resins (see Fig. 6). A copolymer of methyl methacrylate and methyl acrylate is used for the resin (a) constituting the surface layer (A). The specifications of a) are as follows: Weight ratio. Methyl methacrylate / Acrylic vinegar = 98 / 2 MFR (a) : 1.5 g / l 〇 min (20 (TC, 49 N load conditions) Glass transfer temperature Tg(a) : 107°C Thickness (one side): 0.1 mm Further, the MFR of the resin (a) was measured under a load of 23 (TC, 37 N (3.8 kgf), which was 9.4 g/10 min. In the resin (b) of the layer (B), a copolymer of methyl methacrylate and decyl acrylate is used. The specifications of the resin (b) are as follows. Weight ratio: methacrylic acid/I/acrylic acid= 94/6 MFR(b) : 0.24 g/10 min (20 (TC, 49 N load condition) Glass transition temperature Tg(b) : 102eC Thickness: 3.8 mm In addition, at 23 (TC, 37 N (3.8 kgf) load The MFR' of the resin (b) was measured to be 1.5 g/10 min. The ratio of the thickness of the surface layer (A) to the thickness of the main layer (B) was 1/38. In Comparative Example 1, 'a single layer was prepared using the above resin. The resin sheet of the structure is the same as the above-described embodiment except that the three-layer structure is changed to a single-layer structure. 0 157219.doc 201213102 In the first embodiment, the surface of the resin sheet which has just been peeled off from the second pressing roll 52B The temperature was l〇5 ° C, and the shape height H' at this time was 183 μm, and the shape transfer rate (=H7H) was 61%. In Comparative Example 1, the resin sheet which was just peeled off from the second squeeze roll 52Β The surface temperature was 10 ° C, and the shape height ΙΓ was 168 μm at this time, and the shape transfer rate (= H7H) was 56%. Table 1 below shows the test conditions and test results of Example 1 and Comparative Example 1. The case where the shape transfer rate was 60% or more was judged as acceptable. [Table 1]

層構成 樹脂、厚度 線速度 輥速度 片材溫度 形狀輥入口 /形狀輥後 形狀高度轉印率 實施例1 形狀轉印層:樹脂⑷ 0.32 80°C 203〇C 183 μτη 2種 (單側:0.1 mm) m/min 80°C /105°C 61% 3層 主層:樹脂(b) 80°C (3.8 mm) 比較例1 樹脂(b) 0.32 80°C 204〇C 168 μτη 單層 (0.4 mm) m/min 80°C /105°C 56% 80°C (實施例2、3,比較例2)使用圖3所示之樹脂片材製造裝 置50C製作實施例2、3及比較例2上述片材。以下示出所使 用之製造裝置50C之條件。將擠出機58之螺桿直徑設為120 mm,將擠出機58之擠出量設為700 kg/hr。於實施例2、3 中,將線速度設為2.85 m/min,於比較例2中,將線速度設 為2.83 m/min。實施例2、3及比較例2中均將片材寬度(Y方 向之長度)設為135 cm。作為第2擠壓輥52B之轉印模之形 狀,將間距P設為400 μπι,將深度Η設為222 μιη。於實施 157219.doc -32- 201213102 例2中,將輥溫度(預壓輥52D/第1擠壓輥52A/第2擠壓親 52B)設為80°C/85°C/97°C ’於實施例3中設為80。〇/85。〇:/ 87°C,於比較例2中設為80°C/85°C/95°C。 於實施例2、3中,藉由擠出成形(片材製造步驟)製作片 材厚度3 mm之PMMA板。於實施例2、3中,使用2種樹脂 製作3層構造之樹脂片材(參照圖6)。 於構成表面層(Α)之樹脂(a-2)中,使用曱基丙烯酸甲酯 與丙烯酸曱酯之共聚物。樹脂(a-2)之規格如下所示。 重量比:曱基丙烯酸甲醋/丙烯酸甲醋=9 5/5 MFR(a) : 1.4 g/10 min(20(TC、49 N荷重條件)Layer constituting resin, thickness linear velocity roller speed sheet temperature shape roll inlet/shape roll shape height transfer rate Example 1 Shape transfer layer: Resin (4) 0.32 80°C 203〇C 183 μτη 2 types (single side: 0.1 Mm) m/min 80°C /105°C 61% 3 layers Main layer: Resin (b) 80°C (3.8 mm) Comparative Example 1 Resin (b) 0.32 80°C 204〇C 168 μτη Single layer (0.4 Mm) m/min 80 ° C / 105 ° C 56% 80 ° C (Examples 2, 3, Comparative Example 2) Examples 2, 3 and Comparative Example 2 were produced using the resin sheet manufacturing apparatus 50C shown in Fig. 3 The above sheet. The conditions of the manufacturing apparatus 50C to be used are shown below. The screw diameter of the extruder 58 was set to 120 mm, and the extrusion amount of the extruder 58 was set to 700 kg/hr. In Examples 2 and 3, the linear velocity was set to 2.85 m/min, and in Comparative Example 2, the linear velocity was set to 2.83 m/min. In Examples 2, 3 and Comparative Example 2, the sheet width (length in the Y direction) was set to 135 cm. As the shape of the transfer mold of the second pressing roll 52B, the pitch P was set to 400 μm and the depth Η was set to 222 μm. In Example 2 of 157219.doc -32-201213102, the roll temperature (pre-press roll 52D / first press roll 52A / second press roll 52B) was set to 80 ° C / 85 ° C / 97 ° C ' In Example 3, it was set to 80. 〇/85. 〇: / 87 ° C, in Comparative Example 2, it was set to 80 ° C / 85 ° C / 95 ° C. In Examples 2 and 3, a PMMA sheet having a sheet thickness of 3 mm was produced by extrusion molding (sheet manufacturing step). In the examples 2 and 3, a resin sheet having a three-layer structure was produced using two kinds of resins (see Fig. 6). In the resin (a-2) constituting the surface layer (Α), a copolymer of methyl methacrylate and decyl acrylate was used. The specifications of the resin (a-2) are as follows. Weight ratio: methacrylic acid methyl vinegar / acrylic acid vinegar = 9 5/5 MFR (a): 1.4 g/10 min (20 (TC, 49 N load conditions)

玻璃轉移溫度Tg(a) : 102°C 厚度(單側):(實施例2)0.2 mm :(實施例3)0.2 mm 此外,於230。(:、37 Ν(3·8 kgf)荷重條件下測定樹脂 (a-2)之MFR,為 1〇.〇 g/l〇 min。 於構成主層(B)之樹脂(b)中,使用甲基丙烯酸曱酯與丙 浠酸甲酯之共聚物。樹脂(b)之規格如下所示。 重量比:曱基丙烯酸甲g旨/丙稀酸甲酉旨=94/6 MFR(b) : 0.24 g/10 min(200°C、49 N荷重條件) 玻璃轉移溫度Tg(b): 102°C 厚度··(實施例2)2.6 mm :(實施例3)2.6 mm 此外,於230°C、37 N(3.8 kgf)荷重條件下測定樹脂(b) 之MFR,為 1.5 g/l〇 min。 於比較例2中’使用上述樹脂(b)製作單層構造之樹脂片 材。 157219.doc •33· 201213102 於實施例2中,剛剛自第2擠壓輥52B剝離之樹脂片材之 表面溫度為124°C,此時之形狀高度Η為155 μπι,形狀轉印 率(=H7H)為61%。於實施例3中,剛剛自第2擠壓輥52Β剝 離之樹脂片材之表面溫度為119°C,此時之形狀高度Η為 167 μιη,形狀轉印率(=H7H)為75%。於比較例2中,剛剛 自第2擠壓輥52Β剝離之樹脂片材之表面溫度為123 °C,此 時之形狀高度Η為127 μιη,形狀轉印率(=H’/H)為57%。 下表2表示實施例2、3及比較例2之試驗條件及試驗結 果。將形狀轉印率為60%以上之情況判定為合格。 [表2]Glass transition temperature Tg (a): 102 ° C Thickness (one side): (Example 2) 0.2 mm: (Example 3) 0.2 mm Further, at 230. (:, 37 Ν (3·8 kgf) The MFR of the resin (a-2) was measured under a load condition of 1 〇.〇g/l〇min. In the resin (b) constituting the main layer (B), used Copolymer of methacrylate methacrylate and methyl propyl acrylate. The specifications of the resin (b) are as follows. Weight ratio: thiol methacrylate / acrylic acid methyl hydrazine = 94/6 MFR (b): 0.24 g/10 min (200 ° C, 49 N load condition) Glass transition temperature Tg (b): 102 ° C Thickness · (Example 2) 2.6 mm: (Example 3) 2.6 mm Further, at 230 ° C The MFR of the resin (b) was measured under a load of 37 N (3.8 kgf), and was 1.5 g/l 〇 min. In Comparative Example 2, a resin sheet having a single-layer structure was produced using the above resin (b). 157219.doc • 33·201213102 In the second embodiment, the surface temperature of the resin sheet which has just been peeled off from the second pressing roll 52B is 124° C., and the shape height Η is 155 μm, and the shape transfer rate (=H7H) is 61%. In Example 3, the surface temperature of the resin sheet which was just peeled off from the second pressing roll 52A was 119 ° C, and the shape height Η was 167 μm, and the shape transfer rate (=H7H) was 75. %. In Comparative Example 2, just after the second extrusion The surface temperature of the 52 Å peeled resin sheet was 123 ° C, and the shape height Η was 127 μm at this time, and the shape transfer rate (=H'/H) was 57%. Table 2 below shows Examples 2, 3 and comparison. The test conditions and test results of Example 2 were judged to be acceptable when the shape transfer rate was 60% or more. [Table 2]

層構成 樹脂、厚度 線速度 輥速度 片材溫度 形狀輥入口 /形狀輥後 形狀高度轉印率 實施例2 形狀轉印層:樹脂(a-2) 2.85 80°C 211。。 156 μιη 2種 (單側:〇·2 mm) m/min 85〇C /124〇C 70% 3層 主層:樹脂(b) 97〇C (2.6 mm) 實施例3 形狀轉印層:樹脂(a-2) 2.85 80°C 212〇C 167 μιη 2種 (單側:0.2 mm) m/min 85〇C /119°C 75% 3層 主層:樹脂(b) 87〇C (2.6 mm) 比較例2 樹脂(b) 2.83 80°C 21 l〇C 127 μιη 單層 (3.0 mm) m/min 85 °C /123〇C 57% 95〇C (實施例4、比較例3)使用圖3所示之樹脂片材製造裝置 50C製作實施例4及比較例3之上述片材。以下示出所使用 之製造裝置50C之條件。將擠出機58之螺桿直徑設為120 157219.doc -34- 201213102 mm,將擠出機58之擠出量設為1〇〇〇 kg/hr。於實施例# _,將線速度設為4.08 m/min,於比較例3中,將線速度設 為3.52 m/min。就片材寬度(γ方向之長度)而言,於實施例 4中設為i20 cm,於比較例3中設為135 cm。作為第罐壓 輥52B之轉印模之形狀,將間距p設為4〇〇 ,將深度η設 為222 μηι。於實施例4中,將輥溫度(預壓輥“以第i擠壓 輥52A/第2擠壓輥52B)設為8(rc/85t/87t,於比較例3 中,設為 80°C/85°C/98°C。 於實施例4中,藉由擠出成形(片材製造步驟)製作片材 厚度3 mm之PMMA板。於實施例4中,使用2種樹脂製作3 層構造之樹脂片材(參照圖6)。 於構成表面層(A)之樹脂(a_2)中,使用甲基丙烯酸甲酯 與丙烯酸甲酯之共聚物。樹脂(a_2)之規格如下所示。 重量比:曱基丙烯酸甲酯/丙烯酸甲酯=95/5 MFR(a-2): 1.4g/10min(20(TC、49N荷重條件)Layer Composition Resin, Thickness Linear Velocity Roller Velocity Sheet Temperature Shape Roller Entrance / Shape Roller Shape Height Transfer Rate Example 2 Shape Transfer Layer: Resin (a-2) 2.85 80 °C 211. . 156 μηη 2 species (single side: 〇·2 mm) m/min 85〇C /124〇C 70% 3 layers Main layer: Resin (b) 97〇C (2.6 mm) Example 3 Shape transfer layer: Resin (a-2) 2.85 80°C 212〇C 167 μηη 2 types (single side: 0.2 mm) m/min 85〇C /119°C 75% 3 layers Main layer: Resin (b) 87〇C (2.6 mm Comparative Example 2 Resin (b) 2.83 80 ° C 21 l〇C 127 μη Single layer (3.0 mm) m/min 85 °C /123〇C 57% 95〇C (Example 4, Comparative Example 3) The resin sheet manufacturing apparatus 50C shown in 3 produced the above-mentioned sheets of Example 4 and Comparative Example 3. The conditions of the manufacturing apparatus 50C used are shown below. The screw diameter of the extruder 58 was set to 120 157219.doc -34 - 201213102 mm, and the extrusion amount of the extruder 58 was set to 1 〇〇〇 kg / hr. In Example # _, the linear velocity was set to 4.08 m/min, and in Comparative Example 3, the linear velocity was set to 3.52 m/min. The sheet width (length in the γ direction) was set to i20 cm in Example 4 and 135 cm in Comparative Example 3. As the shape of the transfer mold of the first can roller 52B, the pitch p was set to 4 〇〇 and the depth η was set to 222 μη. In Example 4, the roll temperature (pre-press roll "by the ith press roll 52A / the second press roll 52B) was set to 8 (rc/85t/87t, and in Comparative Example 3, it was set to 80 °C). /85 ° C / 98 ° C. In Example 4, a PMMA plate having a sheet thickness of 3 mm was produced by extrusion molding (sheet manufacturing step). In Example 4, a three-layer structure was produced using two kinds of resins. A resin sheet (see Fig. 6). A copolymer of methyl methacrylate and methyl acrylate is used for the resin (a_2) constituting the surface layer (A). The specifications of the resin (a_2) are as follows. : mercapto methacrylate / methyl acrylate = 95/5 MFR (a-2): 1.4g/10min (20 (TC, 49N load conditions)

玻璃轉移溫度Tg(a) : 1 〇2°C 厚度(單侧):0.15 mm 此外’於230°C、37 N(3.8 kgf)荷重條件下測定樹脂 (a-2)之MFR ’ 為 ΐ〇·〇 g/i〇 min。 於構成主層(B)之樹脂(b)中,使用甲基丙烯酸曱酯與丙 烯酸甲酯之共聚物。樹脂(b)之規格如下所示。 重量比··曱基丙稀酸甲酯/丙稀酸甲酯=94/6 MFR(b) : 0.24 g/10 min(200°C、49 N荷重條件)Glass transition temperature Tg(a) : 1 〇 2 ° C Thickness (one side): 0.15 mm In addition, the MFR ' of the resin (a-2) was measured at 230 ° C, 37 N (3.8 kgf) load. ·〇g/i〇min. In the resin (b) constituting the main layer (B), a copolymer of decyl methacrylate and methyl acrylate is used. The specifications of the resin (b) are as follows. Weight ratio · Methyl methacrylate / methyl acrylate = 94 / 6 MFR (b) : 0.24 g / 10 min (200 ° C, 49 N load conditions)

玻璃轉移溫度Tg(b): 102°C 157219.doc ·35· 201213102 厚度:2.7 mm 此外,於230°C、37 N(3.8 kgf)荷重條件下測定樹脂(b) 之 MFR,為 1.5 g/10 min。 於比較例3中,使用上述之樹脂(b)製作單層構造之樹脂 片材。 於實施例4中,剛剛自第2擠壓輥52B剝離之樹脂片材之 表面溫度為135°C,此時之形狀高度Η為155 μπι,形狀轉印 率(=H7H)為70%。於比較例3中,剛岡J自第2擠壓輥52Β剝 離之樹脂片材之表面溫度為131°C,此時之形狀高度Η為 127 μιη,形狀轉印率(=H7H)為 57°/〇。 下表3表示實施例4及比較例3之試驗條件及試驗結果。 將形狀轉印率為60%以上之情況判定為合格。 [表3]Glass transition temperature Tg(b): 102°C 157219.doc ·35· 201213102 Thickness: 2.7 mm Further, the MFR of the resin (b) was measured at 230 ° C under a load of 37 N (3.8 kgf), which was 1.5 g / 10 min. In Comparative Example 3, a resin sheet having a single layer structure was produced using the above resin (b). In the fourth embodiment, the surface temperature of the resin sheet which was just peeled off from the second pressing roll 52B was 135 ° C, and the shape height Η was 155 μm and the shape transfer rate (= H7H) was 70%. In Comparative Example 3, the surface temperature of the resin sheet from which the Gangka J was peeled off from the second pressing roll 52 was 131 ° C, and the shape height Η was 127 μm, and the shape transfer rate (= H7H) was 57°. /〇. Table 3 below shows the test conditions and test results of Example 4 and Comparative Example 3. The case where the shape transfer rate was 60% or more was judged to be acceptable. [table 3]

層構成 樹脂、厚度 線速度 輥速度 片材溫度 形狀輥入口 /形狀輥後 形狀高度轉印率 實施例4 形狀轉印層:樹脂(a-2) 4.08 80°C 255 °C 155 μιη 2種 (單側:0.15 mm) m/min 85 °C /135。。 70% 3層 主層:樹脂(b) 87〇C (2.7 mm) 比較例3 樹脂(b) 3.52 80°C 222。。 127 μιη 單層 (3.0 mm) m/min 85〇C /131°C 57% 98〇C 線速度(4.08 m/min)快且輥溫度(87°C )低之實施例4達到 高於比較例3之形狀轉印率(70%)。 其次,基於實施例5、6及比較例4對本發明進行說明, 157219.doc -36- 201213102 但本發明並不限於下述之實施例。 (樹脂片材之原料)作為樹脂片材之原料,準備了以下 (1)〜(2)之材料。 (1) 非晶性樹脂(主層(B)):低流動性聚苯乙稀樹脂(東洋 苯乙烯株式會社製「HRM40」) MFR(b) : 1·3 g/l〇 min(2〇〇°C、49 N荷重條件) (2) 非晶性樹脂(形狀轉印層(A)):高流動性聚苯乙烯樹 脂(曰本聚笨乙烯株式會社製「G490N」) MFR(a) : 7·〇 g/l〇 min(20(TC、49 N荷重條件) (樹脂片材之製造裝置之構成)使用具有與圖2〇所示之樹 脂片材製造裝置相同之構成之裝置。 此外,作為擠壓輥’準備了表面實施了鍍鉻之鏡面冷卻 輥0 又,作為安裝於擠壓輥之轉印模,準備了表4所示之轉 印模A。於轉印模A中,半橢圓形狀之槽部以沿著擠壓輥 之周方向之方式平行地等間隔地形成。又,於表4中,「間 距P」及「深度H」分別為由上述實施形態定義之值。 [表4] 形狀 間距P 深度Η 縱橫比Layer constituting resin, thickness linear velocity roll speed sheet temperature shape roll inlet/shape roll shape height transfer rate Example 4 Shape transfer layer: Resin (a-2) 4.08 80°C 255 °C 155 μιη 2 types ( One side: 0.15 mm) m/min 85 °C / 135. . 70% 3 layers Main layer: Resin (b) 87〇C (2.7 mm) Comparative Example 3 Resin (b) 3.52 80 °C 222. . 127 μιη single layer (3.0 mm) m/min 85〇C /131°C 57% 98〇C line speed (4.08 m/min) fast and the roll temperature (87 °C) is low. Example 4 is higher than the comparative example. 3 shape transfer rate (70%). Next, the present invention will be described based on Examples 5 and 6 and Comparative Example 4, 157219.doc-36-201213102, but the present invention is not limited to the following examples. (Material of Resin Sheet) As the raw material of the resin sheet, the following materials (1) to (2) were prepared. (1) Amorphous resin (main layer (B)): low-flow polystyrene resin ("HRM40" manufactured by Toyo Styrene Co., Ltd.) MFR(b) : 1·3 g/l〇min (2〇 〇°C, 49 N load conditions) (2) Amorphous resin (shape transfer layer (A)): high-flow polystyrene resin ("G490N" manufactured by Sakamoto Polystyrene Co., Ltd.) MFR (a) (7) 〇g/l〇min (20 (TC, 49 N load condition) (The configuration of the apparatus for manufacturing a resin sheet) A device having the same configuration as that of the resin sheet manufacturing apparatus shown in Fig. 2A is used. A chrome-plated mirror cooling roll 0 was prepared as a squeezing roll ', and as a transfer die attached to a squeezing roll, a transfer mold A shown in Table 4 was prepared. In the transfer mold A, half The groove portions having an elliptical shape are formed at equal intervals in parallel along the circumferential direction of the squeeze rolls. Further, in Table 4, "pitch P" and "depth H" are values defined by the above embodiments. Table 4] Shape Spacing P Depth Η Aspect Ratio

项(實例5 6及比較例4)首先,向具有主擠出機(螺桿直 mV田彳擠出機(螺桿直徑20 mm)之多層擠出機之主擠 機田】擠出機之各者供給表2所示之非晶性樹脂,於量 157219.doc •37· 201213102 筒溫度210°C ~250°C下進行熔融混煉後,供給至2層分配型 進料器台。 其次,經由寬300 mm之T模具,於T模具溫度 24(TC〜250°C下將進料器台内之樹脂擠出為片狀,使得自 副擠出機向進料器台供給之樹脂成為形狀轉印層(高流動 性樹脂層)61,自主擠出機向進料器台供給之樹脂成為主 層(低流動性樹脂層)62。 然後,由預壓輥(鏡面冷卻輥)52D及第1擠壓輥(鏡面冷 卻輥)52A夾持經擠出而得之連續樹脂片材60,以纏繞於第 1擠壓輥52A之表面之狀態進行搬送,以第1擠壓輥52A及 第2擠壓輥(形狀輥)52B進行夾持,以纏繞於第2擠壓輥52B 之表面之狀態進行搬送,以抽取輥52G、52H抽取自第2擠 壓輥52B剝離之連續樹脂片材60。由此,得到高流動性樹 脂層轉印有凹形狀而得之表面形狀轉印樹脂片材。而且, 根據上式求出所得之樹脂片材之形狀轉印率T(=H7H)。結 果示於表5。 [表5] 層構成 樹脂、厚度 線速度 輥速度 片材溫度 形狀輥入口 /形狀輥後 /有無加熱器 形狀高度轉印率 實施例5 形狀轉印層:樹脂(a) 1.1 80°C 162〇C 2種 (0.1 mm) m/min 70°C /108°C 76% 2層 主層:樹脂(b) 95〇C /無加熱器 (1.9 mm) 157219.doc •38· 201213102 實施例6 2種 2層 形狀轉印層:樹脂(a) (〇1 mm) 主層:樹脂(b) (1.9 mm) 1.1 m/min 80°C 70°C 95〇C 187〇C /lilt /有加熱器 86% 比較例4 形狀轉印層:樹脂(b) 1.1 80°C 161 °C 2種 (0.1 mm) m/min 70°C /107°C 70% 2層 主層:樹脂(b) 95〇C /無加熱器 (1-9 mm) 這樣根據本發明之實施形態之樹脂片材之製造方法,能 夠提高樹脂片材之形狀轉印率。 以上’基於其實施形態對本發明進行了具體地說明,但 本發明並不限於上述實施形態。於上述實施形態中,作為 多層構造之連續樹脂片材’於厚度方向之兩側形成具有形 狀轉印層(A)及夾於該形狀轉印層(A)之間之主層(B)之構 成’但亦可由樹脂(a)構成轉印有轉印模之形狀之一片材表 面作為表面層(A),另一片材表面可由與樹脂(a)不同之其 他樹脂構成》例如由樹脂構成另一片材表面,可製造2 層構造之連續樹脂片材。 又,於上述實施形態中,作為樹脂片材,對導光板或者 光擴散板進行了說明,但亦可製作其他之樹脂片材。本發 明之樹脂片材製造方法對搭载於液晶7乂之背光之形狀導 光板及形狀擴散板之製造有效。本發明對縱橫比高之形狀 導光板及形狀擴散板之製造特別有效。 又,於上述實施形態中,使用圖丨〜圖5及圖2〇所示之樹 脂片材製造裝置50、50B、50C、50D、50E、5〇F進行連續 157219.doc •39· 201213102 樹脂片材之製造’亦可使用能夠實行其他製造步驟之樹脂 片材製造裝置。 又,較佳為相對於構成形狀轉印層(A)之樹脂⑷之玻璃 轉移溫度Tg(a),剛剛自形狀輥剝離之連續樹脂片材之表 面溫度為(Tg(a)-10)°C以上(Tg(a)+30)°C以下之範圍,但亦 可為其他溫度範圍。 又’相對於構成主層(B)之樹脂⑻之玻璃轉移溫度 Tg(b) ’剛剛自形狀輥剝離之連續樹脂片材之表面溫度可 為 Tg(b)°C~Tg(a)°C 之範圍。 根據本發明之上述實施形態之樹脂片材之製造方法,能 夠實現轉印至樹脂片材之形狀之轉印率之提高。 【圖式簡單說明】 圖1係表示本發明之實施形態之樹脂片材製造裝置之概 略構成圖。 圖2係表示本發明之第2實施形態之樹脂片材製造裝置之 概略構成圖。 圖3係表示本發明之第3實施形態之樹脂片材製造裝置之 概略構成圖。 圖4係表示本發明之第4實施形態之樹脂片材製造裝置之 概略構成圖。 圖5係表示本發明之第5實施形態之樹脂片材製造裝置之 概略構成圖。 圖6係模式性地表示本發明之實施形態之樹脂片材之層 構成之剖面圖。 157219.doc 201213102 圖7係模式性地表示本發明之實施形態之樹脂片材之構 成之立體圖。 圖8係模式性地表示形成於轉印模之凹部及形成於樹脂 片材之凸狀部之剖面圖。 圖9係表示本發明之實施形態之樹脂片材之製造方法之 順序之流程圖。 圖10係模式性地表示本發明之其他實施形態之樹脂片材 之層構成之剖面圖。 圖11係模式性地表示具備本發明之導光板之透過型圖像 顯示裝置之一實施形態之構成之剖面圖。 圖12係模式性地表示具備本發明之導光板之面光源裝置 之一實施形態之構成之後視圖。 圖13係模式性地表示具備本發明之導光板之面光源裝置 之其他實施形態之構成之後視圖。 圖14係模式性地表示具備本發明之導光板之面光源裝置 之一實施形態之構成之前視圖。 圖15係模式性地表示本發明之導光板之其他實施形態之 構成之立體圖。 圖16係模式性地表示具備本發明之光擴散板之透過型圖 像顯示裝置之一實施形態之構成之側視圖。 圖17係圖16所示之透過型圖像顯示裝置之模式性立體 圖。 圖18係包含本發明之一實施形態之樹脂片材之光擴散板 之模式性立體圖。 1572l9.doc •41 · 201213102 圖19係顯示光擴散板之安裝狀態之燈箱之主要部分放大 剖面圖。 圖20係表示本發明之第6實施形態之樹脂片材製造裝置 之概略構成圖。 圖21係安裝於第2擠壓輥(形狀輥)之凹版轉印模之主要 部分放大剖面圖。 圖22係表示凹版轉印模之第1變形例(大致半圓形狀)之 圖。 圖23係表示凹版轉印模之第2變形例(大致稜形)之圖。 【主要元件符號說明】 157219.doc 1、1B 透過型圖像裝置 10 透過型圖像顯示部 11 液晶单元 12 直線偏光板 20、20B 面光源裝置 22 LED光源(點狀光源) 22B 線狀光源 23 後壁 24 側壁 25 燈箱 26 開放面 30 導光板 30C 光擴散板 31 表面 ioc • 42- 50 > 50B ' 50C 'Item (Example 596 and Comparative Example 4) First, each of the extruders to the main extruder (the main extruder field of the multi-layer extruder of the screw straight mV 彳 extruder (screw diameter 20 mm)) The amorphous resin shown in Table 2 was supplied and melt-kneaded at a cylinder temperature of 210 ° C to 250 ° C in an amount of 157,219.doc •37·201213102, and then supplied to a two-layer distribution type feeder table. The T-die with a width of 300 mm is used to extrude the resin in the feeder table into a sheet shape at a T-die temperature of 24 (TC to 250 ° C, so that the resin supplied from the sub-extruder to the feeder table becomes a shape-turning The printing layer (high fluidity resin layer) 61, the resin supplied from the autonomous extruder to the feeder table becomes the main layer (low fluidity resin layer) 62. Then, the pre-pressing roller (mirror cooling roller) 52D and the first The squeeze roll (mirror cooling roll) 52A sandwiches the extruded continuous resin sheet 60, and is conveyed while being wound around the surface of the first press roll 52A, and the first press roll 52A and the second squeeze are carried out. The pressure roller (shape roller) 52B is nipped and wound around the surface of the second squeeze roller 52B, and the extraction rollers 52G and 52H are extracted from the second. The continuous resin sheet 60 from which the squeezing roller 52B is peeled off, thereby obtaining a surface shape transfer resin sheet obtained by transferring a highly fluid resin layer into a concave shape. Further, the obtained resin sheet is obtained from the above formula. The shape transfer rate T (= H7H). The results are shown in Table 5. [Table 5] Layer constitution resin, thickness linear velocity roll speed sheet temperature shape roll inlet/shape roll/with or without heater shape height transfer rate Example 5 Shape transfer layer: Resin (a) 1.1 80°C 162〇C 2 species (0.1 mm) m/min 70°C /108°C 76% 2 layers Main layer: Resin (b) 95〇C / no heating (1.9 mm) 157219.doc •38· 201213102 Example 6 Two 2-layer shape transfer layer: Resin (a) (〇1 mm) Main layer: Resin (b) (1.9 mm) 1.1 m/min 80° C 70 ° C 95 〇 C 187 〇 C / lilt / with heater 86% Comparative Example 4 Shape transfer layer: Resin (b) 1.1 80 ° C 161 ° C 2 species (0.1 mm) m / min 70 ° C / 107°C 70% Two-layer main layer: Resin (b) 95〇C / no heater (1-9 mm) Thus, according to the method for producing a resin sheet according to the embodiment of the present invention, the shape of the resin sheet can be improved. Imprint rate Although the present invention is specifically described, the present invention is not limited to the above embodiment. In the above embodiment, the continuous resin sheet as a multilayer structure is formed with a shape transfer layer on both sides in the thickness direction (A). And the composition of the main layer (B) sandwiched between the shape transfer layers (A), but the surface of one of the sheets on which the transfer mold is transferred may be formed of the resin (a) as the surface layer (A) The surface of the other sheet may be composed of another resin different from the resin (a). For example, the surface of the other sheet may be composed of a resin, and a continuous resin sheet having a two-layer structure can be produced. Further, in the above embodiment, the light guide plate or the light diffusing plate has been described as the resin sheet, but other resin sheets may be produced. The method for producing a resin sheet of the present invention is effective for the production of a shape light guide plate and a shape diffusion plate of a backlight mounted on a liquid crystal substrate. The present invention is particularly effective for the manufacture of a shape light guide plate and a shape diffusion plate having a high aspect ratio. Further, in the above embodiment, the resin sheet manufacturing apparatuses 50, 50B, 50C, 50D, 50E, and 5F shown in Figs. 5 to 2 and 2B are continuously subjected to 157219.doc •39·201213102 resin sheet. It is also possible to use a resin sheet manufacturing apparatus capable of performing other manufacturing steps. Further, it is preferable that the surface temperature of the continuous resin sheet which has just been peeled off from the shape roll is (Tg(a) - 10) ° with respect to the glass transition temperature Tg (a) of the resin (4) constituting the shape transfer layer (A). C or more (Tg(a) + 30) °C or less, but other temperature ranges. Further, the glass transition temperature Tg(b) with respect to the resin (8) constituting the main layer (B) 'the surface temperature of the continuous resin sheet which has just been peeled off from the shape roll may be Tg(b) ° C to Tg (a) ° C The scope. According to the method for producing a resin sheet of the above embodiment of the present invention, the transfer rate of the shape transferred to the resin sheet can be improved. [Brief Description of the Drawings] Fig. 1 is a schematic configuration view showing a resin sheet manufacturing apparatus according to an embodiment of the present invention. Fig. 2 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a second embodiment of the present invention. Fig. 3 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a third embodiment of the present invention. Fig. 4 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a fourth embodiment of the present invention. Fig. 5 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a fifth embodiment of the present invention. Fig. 6 is a cross-sectional view schematically showing the layer constitution of the resin sheet of the embodiment of the present invention. 157219.doc 201213102 Fig. 7 is a perspective view schematically showing the constitution of a resin sheet according to an embodiment of the present invention. Fig. 8 is a cross-sectional view schematically showing a concave portion formed in a transfer mold and a convex portion formed on a resin sheet. Fig. 9 is a flow chart showing the procedure of a method for producing a resin sheet according to an embodiment of the present invention. Fig. 10 is a cross-sectional view schematically showing a layer configuration of a resin sheet according to another embodiment of the present invention. Fig. 11 is a cross-sectional view schematically showing the configuration of an embodiment of a transmissive image display device including the light guide plate of the present invention. Fig. 12 is a rear view schematically showing a configuration of an embodiment of a surface light source device including a light guide plate of the present invention. Fig. 13 is a rear elevational view showing the configuration of another embodiment of the surface light source device including the light guide plate of the present invention. Fig. 14 is a front view schematically showing a configuration of an embodiment of a surface light source device including a light guide plate of the present invention. Fig. 15 is a perspective view schematically showing the configuration of another embodiment of the light guiding plate of the present invention. Fig. 16 is a side view schematically showing a configuration of an embodiment of a transmissive image display device including the light diffusing plate of the present invention. Figure 17 is a schematic perspective view of the transmissive image display device shown in Figure 16. Fig. 18 is a schematic perspective view of a light diffusing plate comprising a resin sheet according to an embodiment of the present invention. 1572l9.doc •41 · 201213102 Fig. 19 is an enlarged cross-sectional view showing the main part of the light box showing the state in which the light diffusing plate is mounted. Fig. 20 is a schematic block diagram showing a resin sheet manufacturing apparatus according to a sixth embodiment of the present invention. Fig. 21 is an enlarged cross-sectional view showing the main part of a gravure transfer mold attached to a second pressing roll (shape roll). Fig. 22 is a view showing a first modification (substantially semicircular shape) of the gravure transfer mold. Fig. 23 is a view showing a second modification (substantially prismatic shape) of the gravure transfer mold. [Description of main component symbols] 157219.doc 1, 1B Transmissive image device 10 Transmissive image display unit 11 Liquid crystal cell 12 Linear polarizing plate 20, 20B Surface light source device 22 LED light source (point light source) 22B Linear light source 23 Rear wall 24 Side wall 25 Light box 26 Open surface 30 Light guide plate 30C Light diffusing plate 31 Surface ioc • 42- 50 > 50B ' 50C '

50D、50E、50F 201213102 32 33、34 35 35a 35b 38 41 42 5150D, 50E, 50F 201213102 32 33, 34 35 35a 35b 38 41 42 51

52A52A

52B52B

52C52C

52D52D

52E52E

52G、52H 53 54 55 5752G, 52H 53 54 55 57

58 58A 58B 背面 側面 凸狀部 凸狀部35之頂點 凸狀部35之下端 圓點 光學膜 反射片 樹脂片材製造裝置 模具 第1擠壓輥52A 第2擠壓輥52B 第3擠壓輥 預壓輥 第4擠壓輥(後擠壓輥) 抽取棍組 凹版轉印模 片材成形機 進料器台 料斗(樹脂投入口) 擠出機 第1擠出機(副擠出機) 第2擠出機(主擠出機) -43- 157219.doc 201213102 59 60 60a、60b58 58A 58B Rear side convex portion convex portion 35 apex convex portion 35 lower end dot optical film reflection sheet resin sheet manufacturing apparatus mold first pressing roller 52A second pressing roller 52B third pressing roller pre Press roller 4th squeezing roller (rear squeezing roller) Extracting stick group gravure transfer die sheet forming machine feeder hopper (resin input port) Extruder 1st extruder (sub-extruder) 2nd Extruder (main extruder) -43- 157219.doc 201213102 59 60 60a, 60b

61 62 63 70 71 H H'61 62 63 70 71 H H'

PP

QQ

RR

T 加熱器 連續樹脂片材· 片材表面 形狀轉印層(A) 主層(B) 背面層 半橢圓凹槽 凸條 半橢圓凹槽70之深度 半橢圓凸狀部35之高度 鄰接之凸狀部35之頂點3 5a、35a 之間之距離 相鄰之線狀光源22B之中心彼此 之間隔 光擴散板30C之背面32與線狀光 源22B之中心之距離 片材厚度 157219.doc •44-T heater continuous resin sheet · sheet surface shape transfer layer (A) main layer (B) back layer semi-elliptical groove ridge semi-elliptical groove 70 depth semi-elliptical convex portion 35 height adjacent to the convex shape The distance between the apex 3 5a, 35a of the portion 35 is adjacent to the center of the linear light source 22B. The distance between the back surface 32 of the light diffusing plate 30C and the center of the linear light source 22B is 157219.doc • 44-

Claims (1)

201213102 七、申請專利範圍: 1. 一種樹脂片材之製造方法,其包括: 片材製造步驟,其係將加熱熔融狀態之樹脂自模具連 續地擠出而製造連續樹脂片材;及 轉印步驟,其係使用於周面形成有轉印模之形狀輥, 於上述連續樹脂片材之片材表面轉印上述轉印模; 上述轉印步驟包括: 轉印開始步驟,其係利用擠壓輥與上述形狀輥夾持並 擠壓由上述片材製造步驟製造之上述連續樹脂片材,由 此開始將上述形狀輥之上述轉印模之形狀轉印至上述連 續樹脂片材; 搬送步驟’其係使於上述轉印開始步驟中上述片材表 面轉印有上述轉印模之形狀之上述連續樹脂片材保持與 上述形狀輟i之周面密接而進行搬送;及 剝離步驟,其係將上述搬送步驟中搬送之上述連續樹 脂片材自上述形狀輥之周面剝離;且 由上述片材製造步驟製造之上述連續樹脂片材為於片 材之厚度方向上具有複數層之多層構造,且具備於上述 . 轉印開始步驟中配置於上述形狀輥側之構成上述片材表 面之形狀轉印層(A)及鄰接於上述形狀轉印層之背面側之 主層(B)之至少2層; 上述形狀轉印層A之MFR相對於上述主層b之上述MFR 之比率為1.5以上,其中上述MFR為以JISK7210為標準, 於溫度200°C、荷重49 N下測定之測定值。 1572l9.doc 201213102 2.如請求項1之樹脂片材之製造方法,其中上述轉印步驟 包括: 預壓步驟’其係藉由利用預壓輥與上述擠壓輥夾入由 上述片材製造步驟製造之上述連續樹脂片材而進行擠 壓;及 預備搬送步驟,其係使於上述預壓步驟中擠壓之上述 連續樹脂片材保持與上述擠壓輥之周面密接而進行搬 送;且 於上述轉印開始步驟中,利用上述擠壓輥與上述形狀 輥夹持並擠壓由上述預備搬送步驟搬送之上述連續樹脂 片材。 3. 如請求項1或2之樹脂片材之製造方法,其中於將構成上 述形狀轉印層(A)之樹脂(a)之玻璃轉移溫度設為Tg(a)之 情形時, 即將與上述形狀輥之上述周面接觸之上述形狀轉印層 (A)之表面溫度為 (Tg(a) + 50)°C 〜(Tg(a)+150)°C 之範圍, 剛剛自上述形狀輥之上述周面剝離之上述形狀轉印層 (A)之表面溫度為 (Tg(a)-10)°C 〜(Tg⑷+40)°C 之範圍。 4. 如請求項1至3中任一項之樹脂片材之製造方法,其中上 述形狀轉印層(A)之厚度相對於上述主層(B)之厚度之比 率為1/200〜1/10之範圍。 5. 如請求項1至4中任一項之樹脂片材之製造方法,其包括 157219.doc • 2· 201213102 加熱步驟,該加熱步驟係於即將進行上述轉印開始步驟 之前’加熱與上述擠壓輥之周面密接而搬送之上述連續 樹脂片材之上述形狀轉印層(A)之表面。 6. 如請求項1至5中任一項之樹脂片材之製造方法,其中上 述轉印模中,於上述形狀輥之旋轉軸方向上並設有複數 個於上述形狀輥之周方向上連續之槽部; 複數個上述槽部之配置間隔p為2〇〇 μπι~500 μηι。 7. 如請求項1至6中任一項之樹脂片材之製造方法,其中上 述轉印模中,於上述形狀輥之旋轉軸方向上並設有複數 個於上述形狀輥之周方向上連續之槽部; 複數個上述槽部等間隔地配置。 8. 如請求項1至7中任一項之樹脂片材之製造方法,其中上 述轉印模中,於上述形狀輥之旋轉軸方向上並設有複數 個於上述形狀輥之周方向上連續之槽部; 複數個上述槽部之深度只為1〇〇 μηι〜5〇〇 μιη。 9. 如凊求項1至8中任一項之樹脂片材之製造方法,其中上 述轉印模中,於上述形狀輥之旋轉軸方向上並設有複數 個於上述形狀輥之周方向上連續之槽部; 複數個上述槽部之深度Η相對於上述槽部之配置間隔Ρ 之比率即縱橫比Η/P為〇.3以上。 10·如請求項1至9中任一項之樹脂片材之製造方法,其中上 述轉印模中,於上述形狀輥之旋轉軸方向上並設有複數 個於上述形狀輥之周方向上連續之槽部; 上述槽°卩之與上述形狀輥之周方向正交之方向之剖面 157219.doc 201213102 形狀為大致半圓形狀、大致半橢圓形狀或者稜形狀。 11.如請求項1至10中任一項之樹脂片材之製造方法,其t 上述轉印模中,於上述形狀輥之旋轉軸方向上並設有複 數個於上述形狀輥之周方向上連續之槽部; 上述槽部之與上述形狀輥之周方向正交之方向之剖面 形狀為適應於形成光學透鏡之形狀。 12.如請求項1至11中任 例畑片材之製造方法,其中 構成上述形狀轉印層⑷之樹月旨(a)為苯乙稀系樹脂或 丙烯酸系樹脂; 有 乙婦系樹脂或者丙締 構成上述主層(B)之樹脂(b)為苯 酸系樹脂。 157219.doc201213102 VII. Patent Application Range: 1. A method for producing a resin sheet, comprising: a sheet manufacturing step of continuously extruding a resin in a heated molten state from a mold to produce a continuous resin sheet; and a transfer step a transfer roll formed on a surface of a sheet of the continuous resin sheet, wherein the transfer step comprises: a transfer start step using a squeeze roll The continuous resin sheet produced by the sheet manufacturing step is sandwiched and pressed with the shape roll, thereby starting to transfer the shape of the transfer mold of the shape roll to the continuous resin sheet; The continuous resin sheet in which the shape of the transfer mold is transferred onto the surface of the sheet in the transfer start step is kept in close contact with the peripheral surface of the shape 辍i, and the peeling step is performed. The continuous resin sheet conveyed in the transport step is peeled off from the circumferential surface of the shape roll; and the continuous resin sheet produced by the sheet manufacturing step is a sheet. a multilayer structure having a plurality of layers in the thickness direction of the material, and the shape transfer layer (A) constituting the surface of the sheet disposed on the shape roll side in the transfer start step and adjacent to the shape transfer layer At least two layers of the main layer (B) on the back side; the ratio of the MFR of the shape transfer layer A to the MFR of the main layer b is 1.5 or more, wherein the MFR is based on JIS K7210 and the temperature is 200°. C. The measured value measured at a load of 49 N. 2. The method of manufacturing a resin sheet according to claim 1, wherein the transferring step comprises: a pre-pressing step of: sandwiching the sheet by the pre-pressing roller and the pressing roller The continuous resin sheet produced by the extrusion is subjected to extrusion; and a preliminary transfer step of maintaining the continuous resin sheet extruded in the pre-pressing step in close contact with the circumferential surface of the squeeze roll for transport; In the transfer start step, the continuous resin sheet conveyed by the preliminary transfer step is sandwiched between the pressing rolls and the shape roll. 3. The method for producing a resin sheet according to claim 1 or 2, wherein, in the case where the glass transition temperature of the resin (a) constituting the shape transfer layer (A) is Tg (a), The surface temperature of the shape transfer layer (A) which is in contact with the circumferential surface of the shape roll is in the range of (Tg (a) + 50) ° C ~ (Tg (a) + 150) ° C, just from the above-mentioned shape roll The surface temperature of the shape transfer layer (A) which is peeled off by the circumferential surface is in the range of (Tg (a) - 10) ° C to (Tg (4) + 40) ° C. 4. The method for producing a resin sheet according to any one of claims 1 to 3, wherein a ratio of a thickness of the shape transfer layer (A) to a thickness of the main layer (B) is 1/200 to 1/1 The scope of 10. 5. The method of producing a resin sheet according to any one of claims 1 to 4, which comprises a heating step of 157219.doc • 2·201213102, which is preceded by the heating and the above extrusion immediately before the above-described transfer start step The surface of the shape transfer layer (A) of the continuous resin sheet which is conveyed by the circumferential surface of the pressure roller is closely adhered. 6. The method of producing a resin sheet according to any one of claims 1 to 5, wherein the transfer mold is provided in the direction of the rotation axis of the shape roller and is provided in a plurality of consecutive directions in the circumferential direction of the shape roller The groove portion; the arrangement interval p of the plurality of groove portions is 2〇〇μπι~500 μηι. 7. The method of producing a resin sheet according to any one of claims 1 to 6, wherein the transfer mold is provided in the direction of the rotation axis of the shape roller and is provided in a plurality of consecutive directions in the circumferential direction of the shape roller. The groove portion; a plurality of the groove portions are arranged at equal intervals. 8. The method of producing a resin sheet according to any one of claims 1 to 7, wherein the transfer mold is provided in the direction of the rotation axis of the shape roller and is provided in a plurality of consecutive directions in the circumferential direction of the shape roller. The groove portion; the depth of the plurality of groove portions is only 1〇〇μηι 5〇〇μιη. 9. The method of producing a resin sheet according to any one of claims 1 to 8, wherein the transfer mold is provided with a plurality of circumferential directions of the shape roller in a direction of a rotation axis of the shape roller. The continuous groove portion; the ratio of the depth Η of the plurality of groove portions to the arrangement interval Ρ of the groove portions, that is, the aspect ratio Η/P is 〇.3 or more. The method of producing a resin sheet according to any one of claims 1 to 9, wherein the transfer mold is provided in the direction of a rotation axis of the shape roller and is provided in a plurality of consecutive directions in the circumferential direction of the shape roller. The groove portion 157219.doc 201213102 having a shape in which the groove is perpendicular to the circumferential direction of the shape roll is substantially semicircular, substantially semi-elliptical or prismatic. The method of producing a resin sheet according to any one of claims 1 to 10, wherein, in the transfer mold, a plurality of the circumferential direction of the shape roller are provided in a direction of a rotation axis of the shape roller a continuous groove portion; a cross-sectional shape of the groove portion in a direction orthogonal to a circumferential direction of the shape roll is adapted to form an optical lens. 12. The method for producing a sheet according to any one of claims 1 to 11, wherein the shape of the shape transfer layer (4) is a styrene resin or an acrylic resin; The resin (b) constituting the main layer (B) of the propylene is a benzoic acid resin. 157219.doc
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