TW201212228A - Heterojunction Bipolar Transistor structure with GaPSbAs base - Google Patents

Heterojunction Bipolar Transistor structure with GaPSbAs base Download PDF

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TW201212228A
TW201212228A TW99130878A TW99130878A TW201212228A TW 201212228 A TW201212228 A TW 201212228A TW 99130878 A TW99130878 A TW 99130878A TW 99130878 A TW99130878 A TW 99130878A TW 201212228 A TW201212228 A TW 201212228A
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layer
base
gallium
emitter
substrate
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TW99130878A
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Chinese (zh)
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Yu-Chung Chin
Tsung-Hsin Su
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Visual Photonics Epitaxy Co Ltd
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Abstract

A heterojunction bipolar transistor (HBT) structure with a GaPSbAs base layer is disclosed. The HBT structure generally includes a substrate, a subcollector layer, a collector layer, a base layer, an emitter layer, an emitter cap layer, and a contact layer laminated from bottom to top sequentially, and optionally may further comprise a buffer between the substrate and the subcollector layer. The subcollector layer includes heavily doped GaAs; the collector layer includes one of GaAs, InGaP, and AlGaAs or their combinations; the base layer includes GaPSbAs compound; the emitter layer includes InGaP or AlGaAs; the emitter cap layer includes GaAs; the contact layer includes InGaAs; and the substrate includes semi-insulating GaAs. Since the base with GaPSbAs compound has lower band gap energy, the turn-on voltage of the transistors can be reduced. Furthermore, the GaPSbAs can form a type II band alignment with InGaP and AlGaAs emitters, the potential spike of the conduction band at the emitter-base interface is eliminated and thus further reduces the turn-on voltage of the transistors and reduces power consumption. As a result of the type II band alignment, the collector layer can be InGaP, or AlGaAs and other wide band gap materials, which increases the breakdown voltage and reduces the offset voltage and hence improves the power performance of the transistors.

Description

201212228 六、發明說明: 【發明所屬之技術領域】 本發明係有關一種異質接面雙極性電晶體(Heterojunction Bipolar Transistor’HBT)結構,尤其是具有鎵磷銻砷的基極層。 【先前技術】 比起一般以矽為基底的場效電晶體(Field-Effect Transistor),以具有較高電子遷移率(Mobility)的III-V族元素所 製造的異質接面雙極性電晶體(HBT),對於高頻信號,比如l_ 馨 頻帶(】-2GHz)、C-頻帶(4_8GHz)或是更高頻的頻帶,具有較低 的失真放大特性與較高的功率,尤其是無線通訊裝置中功率放 大器(Power Amplifier,PA),以普遍使用於手持式通訊裝置, 例如手機(Mobile Phone)。 異質接面雙極性電晶體主要利用不同半導體材料所構成 的射極及基極,在射極及基極的接面處形成異質接面,由於藉 由價帶位能的不連續(AEV),而減少了基極流向射極的電洞 流’而可以獲得更高的射極注入效率(Emitter Injecti〇n Efficiency)以及電流增益。HBT的導通電壓(Tum_〇n v〇ltage) • 由基極材料的能隙以及射極-基極接面之傳導帶不連續(aEc) 所決定,對元件功率消耗扮演了重要的角色。因此,當基極能 隙和傳導帶不連續(△£;〇越低,元件的功率消耗越低,而 電池的壽命較長。 桠及暴極敢吊用的半導體材料分別為磷化銦錢 (nGaP)及砷化鎵(GaAs),具有高功率以及高線性度的優點。 然而,使用基極能隙較大(室溫下為142電子伏特)的石由 =當作基極材料的缺點在於無法省f。另外,由於坤化錄血 寬能隙材料如磷化銦鎵與砷化鋁鎵形成第一型的能帶對準,因、 寬能隙材料以提高崩潰電1,因為會發生集極 U且擋效應(c〇llect〇r Current Blocking Effect),且具有較言 201212228 ΐϊϊί壓(〇ffset Vdtage) ’進而無法提升異質接面雙極性電 作性能。因此,需要—種基極能隙小且能用寬能 集極以提高崩潰電壓的異質接面雙極性電晶體結 構’以解決上述習用技術的問題。 【發明内容】 而雔2明之主要目的在提供—種具鎵俩神基極之異質接 声又ϊϊί晶體結構,包括由下而上依序堆疊的基板、次集極 二ΐ極層、層、射極層、射極覆蓋層以及接觸層,可進 :V選擇性地包括位於基板及次集極層之間的緩衝層,1 集極層包括重摻雜Ν型坤化鎵,集極層包括神化鎵、g 磷化銦鎵或社贿及此三種半導體敝合,基極層包 化合物,雜層包㈣化銦鎵辦她鎵,射極覆 ίϋ括石申化蘇、寬能隙材料_化銦鎵或神化铭鎵及此三種 ^體的組合喊板包括半職性較鎵,由於鎵磷録砂的基 坤化鎵更低的能隙,以及比磷化轉騎化銘鎵 更低的電子親和力,從而可降低電晶體的導通賴。此外 於月b將覓旎隙材料作為異質接面雙極性電 因此能提高崩潰電壓。進一步地,由於集4與身;= ^化銦鎵辦他_成,使得雜·基鋪面與基極-集極 接面的材料結構姻,所以麟低HBT的補償電壓。 【實施方式】 以下配合圖式及元件符麟本發明之實施方賴 的說Γ 使熟f該項技藝者在研讀本·書後能據以實施。 >閱第-圖’本發明具鎵;轉珅基極之異質接面雙極性 晶體(HBT)結構的示意圖。如第一圖所示,具鎵鱗録縣極之 縣板2G上由下而上依序堆疊的次集極層 、集極層40、基極層50、射極層6〇、射極 觸層⑽,其中基板2G包括半絕緣性(semi_insulating9, SI)= 201212228 鎵(GaAs),次集極層30包括重摻雜N型砷化鎵^+ d〇ped GaAs ),集極層40包括N型砷化鎵、N型磷化銦鎵(InGaP)或 N型砷化鋁鎵(AlGaAs)的其中之一或此三種半導體的組合,基 極層50包括P型鎵磷銻砷化合物(化學式為GaPxSb^yASy,且 〇<x$l ’0$ y $0.1),射極層的包括^^型磷化銦鎵及 石申化銘蘇的其中之一,射極覆蓋層7〇包括N型珅化鎵、n ,碌化銦鎵(InGaP)或N型石申化紹鎵(A1GaAs)的其中之一或此 三種半導體的組合,而接觸層80包括N型砷化銦鎵。 本發明的特點在於,比起一般用砷化鎵構成的基極層,在 本發明的册丁結構中,利用鎵磷銻砷化合物(GaPxSbixyA ) 所,^^基極層50具有較低的能隙(Band Gap Energy),亦即 導帶能量(Conduction Band Energy)與價帶能量(Valence Band201212228 VI. Description of the Invention: [Technical Field] The present invention relates to a Heterojunction Bipolar Transistor (HBT) structure, particularly a base layer having gallium, phosphorus, and antimony. [Prior Art] A heterojunction bipolar transistor made of a group III-V element having a higher electron mobility (Mobility) than a field-Effect Transistor which is generally based on germanium ( HBT), for high-frequency signals, such as l_xin band (]-2GHz), C-band (4_8GHz) or higher frequency band, with lower distortion amplification characteristics and higher power, especially wireless communication devices Medium Power Amplifier (PA) for general use in handheld communication devices, such as mobile phones. Heterojunction bipolar transistors mainly use the emitter and base of different semiconductor materials to form a heterojunction at the junction of the emitter and the base due to the discontinuity of the valence band energy (AEV). By reducing the flow of the base to the emitter, the emitter efficiency (Emitter Injecti〇n Efficiency) and current gain can be obtained. The turn-on voltage of the HBT (Tum_〇n v〇ltage) • It is determined by the energy gap of the base material and the conduction band discontinuity (aEc) of the emitter-base junction, which plays an important role in the power consumption of the component. Therefore, when the base energy gap and the conduction band are discontinuous (Δ£; the lower the 〇, the lower the power consumption of the component, and the longer the life of the battery. The semiconductor materials that are extremely daring to hang are the indium phosphide money respectively. (nGaP) and gallium arsenide (GaAs) have the advantages of high power and high linearity. However, the use of a large base energy gap (142 eV at room temperature) is a disadvantage of stone as a base material. It is impossible to save f. In addition, because the Kunhua recorded blood wide-gap material such as indium gallium phosphide and aluminum gallium arsenide form the first type of energy band alignment, because of the wide bandgap material to improve the collapse of electricity 1, because The current collector U and the current blocking effect (c〇llect〇r Current Blocking Effect) occur, and the 201212228 ΐϊϊί pressure (〇ffset Vdtage)' can not improve the bipolar electrical performance of the heterojunction. Therefore, a base is needed. A heterojunction bipolar transistor structure with a small energy gap and a wide energy collector to increase the breakdown voltage is used to solve the above-mentioned problems of the prior art. [Summary of the Invention] The main purpose of the invention is to provide a kind of gallium The heterogeneous connection of the base and the crystal structure, The substrate, the sub-collector dipole layer, the layer, the emitter layer, the emitter cap layer and the contact layer are sequentially stacked from bottom to top, and V: selectively includes between the substrate and the sub-collector layer Buffer layer, 1 collector layer includes heavily doped yttrium-type gallium arsenide, collector layer includes deuterated gallium, g indium gallium phosphide or bribe and the three semiconductors, base layer compound, hetero layer package (4) Indium gallium is used for her gallium, and the emitter is covered with 申 ϋ 申 申 申 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The lower energy gap of the kikon gamma, and the lower electron affinity than the phosphating ruthenium, which can reduce the conduction of the transistor. In addition, the gap material is used as the heterojunction bipolar in the month b. Electricity can therefore increase the breakdown voltage. Further, since the set 4 and the body; = ^ indium gallium do _ into, so that the hetero-base pavement and the base-collector junction material structure, so Lin low HBT compensation [Embodiment] The following is a description of the implementation of the invention and the components of the invention. After reading the book, you can implement it according to the text. > Read the figure - Figure 'The present invention has a gallium; a schematic diagram of the heterojunction bipolar crystal (HBT) structure of the transition base. As shown in the first figure, The sub-collector layer, the collector layer 40, the base layer 50, the emitter layer 6〇, and the emitter contact layer (10) are sequentially stacked from bottom to top on the 2G plate of the county plate of the county of Gallium, and the substrate 2G includes half. Insulation (semi_insulating9, SI) = 201212228 gallium (GaAs), sub-collector layer 30 includes heavily doped N-type gallium arsenide ^ + d〇ped GaAs), collector layer 40 includes N-type gallium arsenide, N-type phosphorus One of the indium gallium (InGaP) or N-type aluminum gallium arsenide (AlGaAs) or a combination of the three semiconductors, the base layer 50 includes a P-type gallium phosphide arsenic compound (the chemical formula is GaPxSb^yASy, and 〇< x$l '0$ y $0.1), one of the emitter layers including ^^-type indium gallium phosphide and Shi Shenhua Ming Su, the emitter cover layer 7〇 includes N-type gallium antimonide, n, Ion gallium One of (InGaP) or N-type bismuth gallium (A1GaAs) or a combination of the three semiconductors, and the contact layer 80 includes N-type indium gallium arsenide. The present invention is characterized in that the base layer 50 of the present invention has a lower energy than the base layer composed of gallium arsenide, in the structure of the present invention, using a gallium phosphonium arsenide compound (GaPxSbixyA). Band Gap Energy, which is the conduction band energy and the valence band energy (Valence Band)

Energy)之間的能量差’因此可降低HBT結構所需的導通電壓。 本發明的另一特點在於,依據本發明的HBT結構1〇,可 適S的組成及調配基極層5〇的鎵鱗錄砷化合物 (^aPxSbkyASy) ’使得基極層50能與構成集極層的材料,亦即 ==鎵、磷化銦鎵及砷化鋁鎵的其中之一,形成第二型π) 能帶對準(BandAlignment),亦即基極層%的導帶能量高於砷 ϊί家L磷化銦鎵或砷化鋁鎵的導帶能量,而且基極層50的價 • 帶能量亦高於砷化鎵、磷化銦鎵或砷化鋁鎵的價帶能量。因 此’集極層40可不再受限於只使用珅化鎵,而可使用寬能 材料_e Bandgap Material),比如磷化銦鎵或珅化鋁鎵,而 不會發生集極電流阻擋效應。同時,與相同厚度與摻雜濃 -般的石申化鎵集極層作比較’本發明寬能隙的集極層4〇具 有盈於高壓操作之較高的崩潰電壓。 〃 明的獅在於’由於可以增加寬·之集極層中 的4雜濃度’藉以改善克爾克效應(腿Ε_),進 件的強韌度(Ruggedness)。 另外’與具有相關潰電壓的—㈣化職極層作比較, 本發明的集極層可使用厚度較薄的寬能隙材料以增加異質接 6 201212228 ^ ί 3 ί晶體的截止頻率(Cutoff Frequency)。另外的優點在 = 極層會使集極層全部變成空乏區,而導祕極集 二㈣/μ 谷(BaSe_C〇丨丨ector Juncti〇n Capacitance)較不隨著偏壓 •支.’而進一步提升異質接面雙極性電晶體的線性度 (Linearity) 〇 具鎵磷錄縣極之異f接面雙極性電晶體結構10 30 性地包括一緩衝層(未顯示)於基板20及次集極層 姑·^^ 1者僅為肋觸本發明讀佳實關,並非企圖 ί神式上之限制’是以,凡有仙同之發明 = 發明之任何修飾或變更’皆仍應包括在本發 【圖式簡單說明】 體結才^^發明具雜弟珅基極之異質接面雙極性電晶 【主要元件符號說明】 10異質接面雙極性電晶體(ΗΒΤ)結構 20基板 30次集極層 40集極層 50基極層 60射極層 70射極覆蓋層 80接觸層The energy difference between Energy' can therefore reduce the turn-on voltage required for the HBT structure. Another feature of the present invention is that, according to the HBT structure of the present invention, the composition of the S and the gallium-labeled arsenic compound (^aPxSbkyASy) of the base layer 5〇 can be made such that the base layer 50 can form a collector. The material of the layer, that is, one of == gallium, indium gallium phosphide, and aluminum gallium arsenide, forms a second type of π) band alignment, that is, the conduction band energy of the base layer% is higher than The conduction band energy of arsenic ϊ 家 L phosphide or gallium arsenide, and the valence band energy of the base layer 50 is also higher than the valence band energy of gallium arsenide, indium gallium phosphide or aluminum gallium arsenide. Therefore, the collector layer 40 can no longer be limited to using only gallium antimonide, but a wide energy material such as indium gallium phosphide or aluminum gallium arsenide can be used without a collector current blocking effect. At the same time, compared with the same thickness and doping-rich sillimanite gallium collector layer, the wide-gap collector layer 4 of the present invention has a higher breakdown voltage which is higher than the high voltage operation. The lion of Ming Ming is based on the fact that it can increase the 4 impurity concentration in the wide layer of the collector layer to improve the Krk effect (leg Ε _) and the Ruggedness of the input. In addition, the collector layer of the present invention can use a thinner wide bandgap material to increase the cutoff frequency of the heterojunction (Cutoff Frequency) (Compared with the (4) chevron layer having the associated collapse voltage. ). Another advantage is that the = pole layer will cause the collector layer to become a depletion zone, and the guide set of the second (four) / μ valley (BaSe_C〇丨丨ector Juncti〇n Capacitance) will not further follow the bias voltage. Enhancing the linearity of a heterojunction bipolar transistor. The gallium-phosphorus bipolar junction bipolar transistor structure 10 30 includes a buffer layer (not shown) on the substrate 20 and the secondary collector. The layer of Gu·^^ 1 is only a ribbed touch of the invention to read Jiashiguan, not an attempt to restrict the lyrics of 'the invention, any invention or any modification or modification of the invention' should still be included in this [Simplified description of the figure] Body knot ^^ Invented heterogeneous junction bipolar electro-crystals with different bases [Major component symbol description] 10 Heterojunction bipolar transistor (ΗΒΤ) structure 20 substrate 30 sets Polar layer 40 collector layer 50 base layer 60 emitter layer 70 emitter cover layer 80 contact layer

Claims (1)

201212228 七、申請專利範圍: 1.-種具鎵獅神基極之異質接面雙極性電晶體結構,包括: 一基板; 一集極層,堆疊在該基板上; -_層’堆疊在該集極層上,包括p型綱斜化合物 以化學式GaPxSb—Asy表示’且〇<χ^及〇sy^〇丨;以及 一射極層,堆疊在該基極層上。 —· 2.依據申請專機圍第1項所述之異質接面雙極性電晶體結構, 進-步包括-次集極層,係堆疊在該基板及該集極層之間,並 包括重摻雜N型砷化鎵。 _ 1項所述之異質接面雙極性電晶體結 構、中該基板i括半絕緣性(semi_insulating)_化嫁(GaAs)。 i依ίϋ專利麵第1賴述之異倾面雙雛電晶體結 Γ “集極層包括Ν型砂化鎵、Ν型舰銦鎵㈣❿及ν ^申=1§鎵(AlGaAs)的其巾之-或該Ν糾化鎵、Ν型鱗化姻 銥及Ν型砷化鋁鎵之組合。 專利顧第1項所述之異雜面雙難電晶體結 構,其中4射極層包括N㈣化銦鎵及N㈣化銘鎵的其中之 構,進-步包括:堆疊i該基201212228 VII. Patent application scope: 1.- A bipolar transistor structure with a heterojunction of a gallium Lion's base, comprising: a substrate; a collector layer stacked on the substrate; a layer stacked on the layer On the collector layer, the p-type slant compound is represented by the chemical formula GaPxSb-Asy and 〇 χ 〇 〇 〇丨 〇丨 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 以及 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 —· 2. According to the heterojunction bipolar transistor structure described in the first application of the special machine, the step-by-step collector layer is stacked between the substrate and the collector layer, and includes the re-doping Hetero N-type gallium arsenide. The heterojunction bipolar transistor structure according to the item 1, wherein the substrate i includes semi-insulating (GaAs). i 依 ϋ ϋ ϋ ϋ ϋ 第 第 第 第 第 第 第 第 Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ - or a combination of the yttrium-corrected gallium, the scorpion-type squamous ingot, and the bismuth-type aluminum arsenide. The heterozygous double-difficult crystal structure described in the above-mentioned item, wherein the 4 emitter layer comprises N (tetra) indium The structure of gallium and N (four) yin gallium, the further steps include: stacking i the base
TW99130878A 2010-09-13 2010-09-13 Heterojunction Bipolar Transistor structure with GaPSbAs base TW201212228A (en)

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TWI580037B (en) * 2015-09-04 2017-04-21 穩懋半導體股份有限公司 Heterojunction bipolar transistor

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