201211708 六、發明說明： 【發明所屬之技術領域】 本發明係關於-種以太陽能電池作為電源之計時裝置，尤 指-種於鱗裝置讀面處設置__域能電似接收光源 轉換成電能供計時裝置使用之具有透明薄膜太陽能電池之計時裝 置。 【先前技術】201211708 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a timing device using a solar cell as a power source, and in particular, a __ domain capable of converting a power source into a power source A timing device with a transparent thin film solar cell for use in a timing device. [Prior Art]
傳統上，以太陽能電池作為電源的計時裝置，例如手錶、 時鐘’包含.-計時機組、-指示時間之刻度盤細示屏幕，一 玻璃面板、至少-太陽能電池模組以及—殼體。_·習知太陽能計 時裝置可參考美國第5761158號發明專利，其係由一刻度盤(4)及 指針(7)指示時間（參照第一圖），在刻度盤(4)下方，計時機組(2) 上方設置有一太陽能電池模組(3)，在刻度盤上方設置有一透明玻 璃板(5)以作為保護（參照第二圖）<5另一習知太陽能計時裝置可參 考美國第4234947號發明揭示的太陽能電池手錶，其係由一 LCD 顯示螢幕以數字方式指示時間，複數個太陽能電池模組(8)設置於 LCD顯示螢幕之兩側（參照第三圖、第四圖）。 以LCD顯示螢幕指示時間的計時裝置，如需太陽能電池做為 電源，受限於LCD顯示螢幕的面積，必須在計時器本體表面積上 另外設計容置太陽能電池的額外空間，使得設計受到限制，且無 法容置大面積的太陽能電池模組。而以刻度盤及指針指示時間的 計時裝置，太陽能電池係設置於刻度盤之下，而刻度盤是位於計 時器本體的下方，受到計時器殼體的陰影阻擔。 因此’有必要提供一種新穎的太陽能電池計時器，其能設置 具有大面積進光範圍的太陽能電池，以提高太陽能電池模組之供 電效能’進而取代有環境污染之虞的氧化銀(silver-oxide battery)或 銀鋅電池(si丨ver-zinc battery)。 201211708 【發明内容】 膜太ΐϊϊ之目的在於提供—種湘計時裝置之鏡面與-透明簿 合贿收光源並轉換成電能供計财 有透明薄臈太陽能電池之計時裝置。 ΐ使用之具 的太陽能電ί另以】能設置具有大面積進光範圍 臈太陽能電池之計H b電池模_供電效能之具有透明薄 本發明之再一目的係提供一種適 機組的薄臈太陽能電池模組。^用於叫曰針“不時間之計時 指示 包含達====;電=時裝置，其 :門係連結:_時機組，並'i由=電裝 =殼體’ _置前述薄膜太陽能』 池模組可作為計時裝置 “玉層且5亥透明薄臈太陽能電 置是在計時裝置之時間羁^不同於傳統太陽能電池計時裝 =或是將太陽能電池設置於太陽能 膜太陽能電池模組設置為時 不裝置之下，本發明將薄 並且增加光線照射面積，二裝置之上方，可有效利用空間 較佳地，本發明積提出電效率。 下列固定裝置之任何其中之専膜太陽旎電池計時器，更包含 掛裝置。 ·—錶帶、一外框、一支架或一懸 201211708 f實施方式】 太陽能發^'具體_彳之具有透明薄膜 具有凹槽；-_太陽能電池1G，’下方 以在光照射後產生電㈣，經⑽物γ Λ體開他之上’用 輸入計時機組20,計時機也㈣動/，未顯示）將所生源 太發明夕祕Γ 帶動時間顯示裝置3G以指示時間。 元作為計時裝盔上蓋種 = 透明度之薄膜太陽能電池單 ==太陽能電池埋設在殼體下方凹槽二也 ΐίίίί 同時容置太陽能電池單元和時間頻矛， 置，而使太陽能電池單元之面積受到_的缺點。U 丁裝 該計時機組20,含有：石英震盪器、Ic、 齒輪系統⑽未顯示）。計時機組2G在受戦以^ ^弦波或方波等重複電子訊號頻率，構成震蘆電路，再利用『板 ^員並控繼圈和磁鐵，—步進馬達（圖未顯示）接 欠時之二動後，驅動一齒輪系統，_ y 〇之時針32、》針34及秒針36，以在刻度盤38上指示時 之示本發明n施例之_太陽能電池10 ::構：圖，其包括:一透明基板1〇卜該透明基板ι〇之一面 102 Γϋ，由基板1〇1開始，往下依序疊層的是第一電極層 主吸收層103、第二電極層1〇4及保護層1〇5。在材質的使 電極層1〇2的材f為諸如選自氧化姻錫师）、氧化 及氧化鋅(Zn0)的透明導電氧化物，主吸收層1〇3之材質 ί ΡΓ= 型^之氮化非晶石夕，第二電極層104之材質為臟材 質’而保顧之材質為玻璃或其他透光性材料，例如塑膠。主吸 201211708 =jG3個域生電子電輯，以提供额 =⑽及第二電極層1〇4係用以取出電能與提昇=轉 上述薄膜太陽能電池10製作方法更包括：提供 利用物理氣相沉積(PVD)製程形成該第一電極層，且利^ :二 利用麵―製程形成:第： = 佳者，上述製作方法更包括:於該第一 ^ 、妾兮1錢明基板1G1之照光面受到太陽光照射，縣線藉由穿 ^子因導體層’使太陽光騎於p_n接面上，俾使部份 擁ί足_能量’離開原子而變成自由電子，失Γί子= f電洞，並透過Ρ型半導體及η型半導體= ΐ 再藉由第-電分開’在ρ~η接面兩端因而產生電位差， 使電子得以通^並盘層104連接一電路（圖未示）， 生電流，再藉由該第二端=^結合，便產 以轉換成可利用之功率層102及第一電極層1〇4取出電能， 池計係=本發明第-實施例之透明薄膜太陽能電 含賴太陽能電池ω作為計時器之面板，更包 之為計時^ .一外框、—支架或一懸掛裝置。 體實施例之透參照第八圖及第九圖，係另一具 係以液晶顯示裝置(LCD^=t計時器的别面視圖及俯視圖，其 iOXD) 80作姆間顯示裝置，細太陽能電池 201211708 源，用以在光照射後產生電壓 =於’薄膜太陽能電池"覆蓋於二:二裝方:二丄二發;: 纖， 埂]溥祺太％能電池最大之受光面積。 【圖式簡單說明】 能電池計時器第-示例之俯視圖。 ^二^1知太陽能電池計時器第二補之俯視圖。 ==!知太陽能電池計時器第二示例之剖面圖。 器的音 f面圖本發明一具體實施例之透明薄膜太陽能電池計時 之剖面第圖六圖係本發明—騎實_之㈣_太_電池結構 器的H私發明—騎倾獻咖軸鴻能電池計時 時器係本發㈣—具體實施例之透明_太陽能電池計 時器的m係本發日m體實關之翻_端能電池計 【主要元件符號說明】 1〇 溥膜太陽能電池模級 20 計時機組 30 時間顯示裝置 32 時針 34 « 分針 8 201211708 36 秒針 38 刻度盤 40 殼體 50 固定裝置 80 液晶顯示裝置 101 基板 102 第一電極層 103 主吸收層 104 第二電極層 • 105 保護層Conventionally, timing devices using solar cells as a power source, such as watches, clocks, include - timing units, - time indicating screens, a glass panel, at least - solar battery modules, and - housings. _·The known solar timing device can refer to US Patent No. 5761158, which is indicated by a dial (4) and a pointer (7) (refer to the first figure), under the dial (4), the timing unit ( 2) A solar cell module (3) is arranged above, and a transparent glass plate (5) is arranged above the dial for protection (refer to the second figure). [5] Another conventional solar timing device can refer to U.S. Patent No. 4,234,947. The solar cell watch disclosed in the invention is digitally indicated by an LCD display screen, and a plurality of solar cell modules (8) are disposed on both sides of the LCD display screen (refer to the third figure and the fourth figure). The timing device for displaying the time indicated by the LCD, if the solar battery is required as the power source, is limited by the area of the LCD display screen, and the additional space for accommodating the solar battery must be additionally designed on the surface area of the timer body, so that the design is limited, and Unable to accommodate large-area solar modules. With the dial and the hands indicating the time, the solar cell is placed under the dial, and the dial is located below the timer body and is blocked by the shadow of the timer housing. Therefore, it is necessary to provide a novel solar cell timer that can set a solar cell with a large area of light to improve the power supply performance of the solar cell module, thereby replacing the silver-oxide with environmental pollution. Battery) or silver-zinc battery (si丨ver-zinc battery). 201211708 [Summary of the Invention] The purpose of the membrane is to provide a mirror surface and a transparent book for the Xiang timing device. The light source is converted into electric energy for calculation. There is a timing device for the transparent thin solar battery.太阳能Using solar energy ί 能 能 能 能 能 能 能 能 能 能 能 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈 臈Battery module. ^ used for squeaking needles "not time timing indications include up to ====; electricity = time device, which: door connection: _ when the unit, and 'i by = electric equipment = housing' _ set the aforementioned thin film solar energy The pool module can be used as a timing device. “Yade layer and 5 Hai transparent thin solar power is set in the time of the timing device. ^It is different from the traditional solar battery timing device= or the solar battery is set in the solar film solar battery module. In the case of no device, the present invention will be thin and increase the area of light irradiation. Above the two devices, the space can be effectively utilized. Preferably, the present invention provides electrical efficiency. Any of the following fixtures, including the diaphragm solar battery timer, include a hanging device. ·—Band strap, a frame, a bracket or a suspension 201211708 f implementation method】 Solar energy ^ 'specific _ 彳 has a transparent film with grooves; - _ solar cell 1G, 'below to generate electricity after light irradiation (4) After the (10) object γ Λ body open on top of 'using the input timing unit 20, the chronograph is also (four) moving /, not shown) will be the source of the invention, the time display device 3G to indicate the time. Yuan as the chronograph helmet cover type = transparency of the thin film solar cell single == solar cell buried in the lower part of the housing groove 2 also ΐ ί ί ί ί 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能 太阳能Shortcomings. U Ding The timing unit 20 contains: quartz oscillator, Ic, gear system (10) not shown). The timing unit 2G is configured to repeat the electronic signal frequency by ^ sine wave or square wave to form the stun circuit, and then use the slab and control the relay ring and the magnet, and the stepping motor (not shown) is owed. After the second movement, a gear system, _ y 时 hour hand 32, "needle 34 and second hand 36" are displayed on the dial 38 to indicate the solar cell 10 of the present invention. The method includes: a transparent substrate 1 and a surface 102 of the transparent substrate Γϋ, starting from the substrate 〇1, sequentially laminating the first electrode layer main absorbing layer 103 and the second electrode layer 〇4 And the protective layer 1〇5. The material f of the electrode layer 1 2 of the material is a transparent conductive oxide such as selected from the group consisting of oxidized sulphur and zinc oxide (Zn0), and the material of the main absorbing layer 1 〇 3 is 氮 ΡΓ = type nitrogen The material of the second electrode layer 104 is a dirty material, and the material to be protected is glass or other light transmissive material, such as plastic. The main suction 201211708 = jG3 domain electronic series, to provide the amount = (10) and the second electrode layer 1 〇 4 system for taking out electric energy and lifting = turning the above-mentioned thin film solar cell 10 manufacturing method further includes: providing physical vapor deposition The (PVD) process forms the first electrode layer, and the second surface layer is formed by the process: the:: =, the above manufacturing method further includes: the illumination surface of the first ^, 妾兮1 Qianming substrate 1G1 Irradiated by the sun, the county line makes the sun ride on the p_n junction by wearing the conductor layer, so that part of the _ energy _ energy leaves the atom and becomes a free electron, and the Γ子 = f hole And through the Ρ-type semiconductor and the η-type semiconductor = ΐ and then by the first-electrical separation' at the ρ~η junction, thereby generating a potential difference, the electrons are passed through and the disk layer 104 is connected to a circuit (not shown). The current is generated by the second end=^, and is converted into the usable power layer 102 and the first electrode layer 1〇4 to extract electric energy. The cell system is the transparent thin film solar energy of the first embodiment of the present invention. The electric solar cell ω is used as the panel of the timer, and it is also included in the timing. Outer frame, bracket or a suspension device. Referring to the eighth embodiment and the ninth embodiment, the liquid crystal display device (the other surface view and the top view of the LCD^=t timer, iOXD) is used as the inter-mu display device, and the thin solar cell is used. 201211708 Source, used to generate voltage after light irradiation = in 'thin film solar cell' Covered in two: two-package: two-two-two;: fiber, 埂] 溥祺 too% can battery the maximum light-receiving area. [Simple diagram of the diagram] The top view of the battery timer section - example. ^ Two ^ 1 know the solar cell timer second supplement top view. ==! A cross-sectional view of the second example of the solar cell timer. Figure 6 is a cross-sectional view of a transparent thin film solar cell according to an embodiment of the present invention. Figure 6 is a schematic view of the present invention - riding a solid _ (four) _ too _ battery structure of the H private invention - riding a dedication The battery timing device is the same (4) - the transparency of the specific embodiment _ solar cell timer m system is the day of the m body real turn _ end energy battery meter [main component symbol description] 1 〇溥 film solar battery module Stage 20 timing unit 30 time display unit 32 hour hand 34 « minute hand 8 201211708 36 second hand 38 dial 40 housing 50 fixing device 80 liquid crystal display device 101 substrate 102 first electrode layer 103 main absorption layer 104 second electrode layer • 105 protective layer