TW201211594A - Luminance- enhanced film - Google Patents

Luminance- enhanced film Download PDF

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Publication number
TW201211594A
TW201211594A TW100110821A TW100110821A TW201211594A TW 201211594 A TW201211594 A TW 201211594A TW 100110821 A TW100110821 A TW 100110821A TW 100110821 A TW100110821 A TW 100110821A TW 201211594 A TW201211594 A TW 201211594A
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TW
Taiwan
Prior art keywords
island
yarn
sea
birefringent
islands
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TW100110821A
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Chinese (zh)
Inventor
Seong-Dae Chi
Kyu-Chang Kim
Deog-Jae Jo
Jin-Soo Kim
Do-Hyun Kim
In-Young Yang
Hyoun-Soo Lee
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Woongjin Chemical Co Ltd
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Publication of TW201211594A publication Critical patent/TW201211594A/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements

Abstract

Disclosed is a luminance-enhanced film capable of preventing island aggregation and solving broken filament problem even when the number of island portions of the birefringent island-in-the-sea yarn is increased remarkably.

Description

201211594 六、發明說明· ' 【發明所屬之技術領域】 本發明係關於一種輝度增強膜,尤其是關於—種輝度 增強膜,即使雙折射海島紗之島部數目顯著地增加,其仍 可防止島部凝集並解決斷裂絲問題。 【先前技術】 液晶顯示器(Liquid Crystal Display,LCD)、投影顯示器 及電槳顯示面板(Plasma Display Panel,PDP)在平板顯示器 TV領域,已有牢固的市場。吾人亦期望場發射顯示器(Field Emission Display ,FED)、電致發光顯示器 (Electroluminescent Display,ELD)等’以該等各別有利的特 性隨同與此相關的技術改良,將會在市場上佔有一席之地 。LCD的應用範圍已延伸至筆記型電腦、個人電腦監視器 、液晶TV、車輛、飛機等。從1998年後半期開始,幸虧 需求的急遽增加,使得LCD佔有約80%平板市場,且全球 性銷售極為強勁。 於習知的LCD結構中’液晶與一電極基質係設置在一 對會吸光的光學膜之間。在LCD中,液晶藉由施加電壓到 兩個電極所產生的電場而移動,因此具有隨電場改變之光 學狀態。此程序係藉由在特定方向極化,來顯示「像素」 影像儲存資訊。據此,LCD包括一前光學膜及一後光學膜 來誘發此極化。 由於背光所放射之光線的50%以上係由後侧光學膜所 201211594 吸收’故LCD裝置未必對背光所放射之光線具有高使用效 率。因此,為了增加LCD裝置中該背光光線之使用效率, 可於光學凹穴與液晶組件之間插入輝度增強膜。 第la圖為一習知輝度增強膜之光學原理示意圖。具體 而言,由光學凹穴導向到液晶組件之光線的p極化光線可 經由輝度增強膜轉移到液晶組件,而其s極化的光線在該 輝度增強膜反射到該光學凹穴,再由光學凹穴的擴散反射 表面所反射,其中光線之極化方向成為隨機,然後再次轉 移到該輝度增強膜。結果,該S極化的光線被轉換成P極 化的光線,其可通過該液晶組件之偏光月,然後經由輝度 增強膜轉移到液晶組件。 S極化光線相對於在該輝度增強膜上的入射光線之選 擇性反射及P極化光線之穿透係藉由各別光學層之間折射 率的差異來進行,根據堆疊的光學層之延伸及該光學層之 折射率中的變化決定每一光學層的光學厚度,其狀態當中 具有異向性反射係數之平板光學層與具有同向性反射係數 之平板光學層以複數交替地堆疊。 也就是說’入射在該輝度增強膜上的光線受到該S極 化光線之反射及該p極化光線之穿透,而穿過該等接受的 光學層。因此,僅有該入射的極化光線之P極化光線被轉 移到該液晶組件。同時,該反射的S極化光線由該光學凹 穴的擴散反射表面所反射,其狀態當中其極化狀態如前述 成為隨機,然後再次轉移到該輝度增強膜。因此,可以降 低來自一光源所產生之光線損失及電力的浪費。 201211594 此ι知輝度增強膜係藉由交替土也堆疊平板形同向性光 干層與平板形異向性光學層來製造,其具有不同的折射 率’並在該堆#結構上執行—延伸程序,使該堆疊層 該等各別光學層之—折射率及—光學厚度,其可對於入射 的極化光線之選擇性反射及穿透來做最適化。因此,此製 造料複雜。特別是,因為該輝度增強膜之每—光學層具 有-平板形,p極化光線與s極化光線針㈣人射的極化 光線之入射角度的大範圍而必須彼此隔開。因此,此膜之 、、’口構田中堆疊有過度增加的光學層數目,因此造成製 本之指數性增加。此外,此結構之缺點在於造絲 因此劣化了光學效能。 貝失’ 吾人發現在基質中包含一雙折射海島紗的輝度增強膜 在解決上述問題極為有利。具體而言,在使用雙折^海島 紗時,相較於使用—般雙折射纖維時可顯著改良光學 效率及輝度。海島紗之島部為異向性H面海部為同 向性。在此情況,•在海島紗之島部及海部間之 雙折射界面’除了在海島紗及基f之間者之外,相較於二 纖維’其中雙折射界面僅形成於基質及雙折射纖 5之邊界,職學觀效應被_地改善,這使其能夠 代工業用途的堆疊型輝度增強膜。結果,雙折射海島紗 之使用,相較於-般雙折射纖維之使用,可提供更佳的^ :文良。也就是說,雙折射海島紗内部之雙折射界面之形 瓶其係由&部及海部之不同光學性質所造 顯著的輝度改良。 故供更 201211594 问呀,為了使光學調 -干取人化,权1主皮存在於錐 折射海島㈣雙折射界面之㈣增大。為此目的,存在ς 雙折射海島紗中之島部數目應為大量。然而,習知海島紗 至少包括圍繞-紡紗核心呈同心圓配置的島部。當島呷數 目為少時’則該剖面的結構並無問題。然而,#島部數目 為多時(約3〇0個或更多)’由於高密度,在紡紗期間愈形成 於海島紗中心的紡紗核心鄰接的島部可凝聚一起( 。更具體言之,第lb圖表示包含33Η固島部之習知海島^ 的剖面圖。在圖中,於海島紗中島部12圍繞-紡紗核心u 呈同〜圓地配置’且島部佔有海島紗全體剖 ,。當島部數目少時,此等剖面㈣構並㈣題。= ’备島部數目大時(約谓個或更多),由於高密度,在_ 2與形成於海島紗中心的纺紗核心11鄰接的島部可凝^ 心句話說’在海島紗之島部數目增加時,海島料 部之《及結塊的不良副仙(島凝集)报容易發生。 :此’由於島凝集現象,當島部數目增加 ==、具有顯著減少的雙折射界面區^ ”、、忒如所需改良光學調變效率。 【發明内容】 本發明揭示係指向提供—具 夠 ::島即使雙折射海島紗之島部數目顯著:增 防止島部凝集及解決斷裂絲的問題。 才- 本發明揭示亦指向提供可用於輝度增強膜之海島紗, 6 201211594 且能夠展現原樣的顏色。 ‘ 在一通常態樣,本發明揭示提供一種輝度增強膜,其 包含:一基質;及在基質中之一雙折射海島紗,其中雙折 射海島紗之一島部及一海部間之邊界形成雙折射界面,以 誘導光學調變,且雙折射海島紗包含:一核心,用以防止 島部凝集;一複數島部群,其環繞該核心形成為輻射狀。 在本發明揭示之一特定具體實施例,一邊界可形成於 島部群之間,以使在邊界每單位面積(μιη2)之島部數目小於 鄰近島部群中每單位面積(μηι2)島部數目,且鄰近島部群被 邊界所分隔。 在本發明揭示之另一特定具體實施例,該邊界係環繞 該核心形成為輕射狀。 在本發明揭示之另一特定具體實施例,在該核心之每 單位面積(μηι2)之島部數目,較島部群之每單位面積(μιη2) 之島部數目為小。具體而言,在該核心每單位面積(μιη2)之 島部數目係等於或小於在島部群中每單位面積(μιη2)之島 部數目之1/2或1/3。更具體而言,在邊界之每單位面積 (μιη2)之島部數目,係等於或小於在島部群中每單位面積 (μιη2)之島部數目之3/4或1/2。 在本發明揭示之另一特定具體實施例,該邊界環繞該 核心,以複數形成為環形狀。 在本潑明揭示之另一特定具體實施例,該島部群具有 剖面之形狀為扇形齒輪(sector)、等腰三角形或等腰梯形。 在本發明揭示之另一特定具體實施例,複數個島部群 201211594 之數目為10-50,且包含於一島部群之島部數目為800-2000 〇 在本發明揭示之另一特定具體實施例,包含於雙折射 海島紗之島部的總數為20000-30000。 在本發明揭示之另一特定具體實施例,雙折射海島紗 具有以方程式1所定義的A值為500或以上。 [方程式1] A= —單絲之島部數目/ 一複合絲之單絲數目 在本發明揭示之另一具體實施例,雙折射海島紗可梭 織成為織物,織物之緯紗及經紗之一種可為一雙折射海島 紗,且另一種可為一纖維, 在本發明揭示之另一特定具體實施例,雙折射海島紗 之島部的熔化起始溫度可高於纖維的熔化溫度。 在本發明揭示之另一特定具體實施例,其中雙折射海 島紗係梭織成為單絲。 在本發明揭示之另一具體實施例,一雙折射界面可形 成於雙折射海島紗之島部及海部間的邊界。更具體言之, 該島部係光學雙折射,且海部為光學同向性。 在本發明揭示之另一具體實施例中,纖維可為光學同 向性纖維。 在本發明揭示之另一具體實施例中,纖維可為選自由 聚合物纖維、自然纖維及無機纖維所組成群組中之一種或 多種纖維。 在本發明揭示之另一具體實施例,雙折射海島紗之島 8 201211594 部的熔化起始温度可高於海部的熔化溫度^ 在本發明揭示之另一具體實施例,雙折射海島紗之島 部的熔化起始溫度較纖維的熔化溫度高30°C或以上。雙折 射海島紗之島部的熔化起始溫度較海部之熔化溫度高3 0 ° C 或以上。 在本發明揭示之另一具體實施例,纖維及/或海部可部 分或全部溶化。 在本發明揭示之另一具體實施例中,纖維及雙折射海 島紗之海部可由相同材料製成。 在本發明揭示之另一具體實施例中,基質與雙折射海 島紗之間在二轴方向之折射率差異可為0.05或以下,且在 基質與雙折射海島紗間在剩餘之一軸方向的折射率之差異 為0.1或以上。 在本發明揭示之另一特定具體實施例中,假設該基質 在X-、y-及z-軸方向之折射率分別為nxl、nY1及nzl,且該 雙折射海島紗在X-、y-及Z-轴方向之折射率分別為Πχ2、Πγ2 及ηΖ2,則該基質在χ-、y-及ζ-軸方向之折射率之至少一者 可能與該雙折射海島紗折射率相同。 在本發明揭示之另一具體實施例中,該雙折射海島紗 之海部與該島部於二軸方向的折射率差異為0.05或以下, 且該雙折射海島紗之海部與該島部於其餘一軸方向的折射 率差異為0.1或以上。 在本發明揭示之另一特定具體實施例中,假設該雙折 射海島紗之島部於χ-(縱向)、y-及ζ-軸方向之折射率分別為 201211594 Ι1χ3、Πγ3及Πζ3 ’且該海部於X-、y_及Z-轴方向之折射率分 別為nX4、ny4及nZ4,則該基質於X-、y-及z-軸方向之折射 率之至少其一可與雙折射海島紗之折射率相同。 在本發明揭示之另一特定具體實施例中,折射率nX3 與nX4的差異之絕對值可能為0.1或以上。 在本發明揭示之另一具體實施例中,該雙折射海島紗 之直徑為1〇-1〇〇μπι。 在另一一般態樣,本發明揭示提供一用以增強輝度之 海島紗,其包含:一核心,用以防止海島紗中的島部凝集 :及複數個島部群,其環繞核心形成為輻射狀。 在本發明揭示之另一特定具體實施例中,邊界係形成 於島部群之間,以使在邊界每單位面積(μιη2)之島部數目小 於鄰近島部群中每單位面積(μιη2)之島部數目,且鄰近島部 群被邊界所分隔。 在本發明揭示之另一特定具體實施例,該邊界係環繞 該核心形成為輕射狀。 在本發明揭示之另一特定具體實施例,在該核心之每 單位面積(μιη2)之島部數目,較島部群中每單位面積(μιη2) 之島部數目為小。 在本發明揭示之另一特定具體實施例,該邊界環繞該 核心,以複數形成為環形狀。 在本發明揭示之另一特定具體實施例,該島部群具有 剖面之形狀為扇形齒輪、等腰三角形或等腰梯形。 在本發明揭示之另一特定具體實施例,複數個島部群 201211594 之數目為10-50,且包含於一島部群之島部數目為 800-2000 。 在本發明揭示之另一特定具體實施例,包含於雙折射 海島紗之島部的總數為20000-30000。 在此使用的術語將給予扼要的說明。 語句「纖維係雙折射的」意指當光照射在依不同方向 而具有不同折射率之纖維時,入射至該等纖維之光線係在 兩不同方向上折射。 術語「同向性」係指物品之一種光學性質,當光線通 過該物品時,該物品在所有方向之折射率均相同。 術語「異向性」係指一種物品依方向而定之光學性質 。異向性物品具有雙折雜,異向性之相反詞$同^性: 術語「光學調變」意指-種程序,其中所照射之光經 反射、折射或散射,或是其強度、波循環或特性被改變。 術語「核心」係指中心部分,從此中心部分,島部群 與邊界形成為輻射狀,其具有一預定區域,以便防止在海 島紗的剖面之島部凝集。 術#「炼化起始溫度」意指聚合物開始溶化之溫度, 以及術語「熔化温度」意指熔化發生最快速之溫度。因此 ,當聚合物之熔化溫度係由示差掃描量熱法(Differential Scanning Calorimetry,DSC)觀察時,熔化吸熱尖峰起點之溫 度為熔化起始溫度,且對應於吸熱尖峰之頂端的溫度為熔 化溫度。 術語「光變色纖維」係指藉由根據干擾光之纖維的結 11 201211594 構上/光學設計,使纖維顯出顏色,而不會物理/化學結合於 例如染料或色素的色誘導劑。 根據本發明揭示,包含雙折射海島紗的輝度增強膜, 即使島部之數目為20_或以上,亦不在海島紗的中央部 分發生島部凝集。由於20000或以上的島部可在海島紗中 形成,光學調變用介面之區域被最大化,且光學調變效應 明顯的被改良。因此,相較於當使用已知的雙折射纖維或 具有約500個島部之海島紗,由於包含本發明揭示之雙 射海島办的輝度增強膜具有非常優越的光學調變效應 得光學調變用介面之面積顯著的增加,因而輝度可顯著的 改良。 當雙折射海島紗被梭織成為纖維之形式,且包含於輝 =膜由於其具有大量的島部,即使為(雙折射海 ^之)早絲,亦可獲致所需的輝度,因此,由於並益需 ^織用以改良輝度之數以十計的雙折射海島紗之股 複°絲,故可避免紗斷裂與斷裂絲。 ’、' 再者由於多數島部配置於用以輝度 故紗的精密度可予減低。因為可製造在一海島= 输維炻超纖維,此不僅對製造超微細 纖、准極為有利,且製造成本可顯著地降低。 -直!;Γ之其他特徵及態樣由下述詳細說明、附圖及申 請專利範圍為明顯可知。 ㈣及甲 【實施方式】 12 201211594 t::述提及的附圖之下列具體實施例所描述,本 不、點、特徵及態樣將明顯可知。本發明揭示, ;、、;、而可以不同形式具體化且*應被 的具體實施例所限制。當然,該等具體實施_== 此= 容徹底且完整,且將完全傳達予熟悉該= 士本發明揭示之範轉。在此使用的術語係僅用以描述; !==意圖限制例示具體實施例。在此所使用的, 早"」及「該」也意圖包含複數形式,除非在 下文有另外清楚地說明。吾人進—步瞭解當使用於本 書時,術語「至少、包括」指明存在所述特徵、整數° 驟、操作、元件及/或組件,但並不排除存在或附加 多種其他特徵、整數、步驟、操作、元件、組件及/或群:且 〇 '201211594 VI. OBJECTS OF THE INVENTION · TECHNICAL FIELD OF THE INVENTION The present invention relates to a brightness enhancement film, particularly to a brightness enhancement film, which can prevent an island even if the number of islands of the birefringent island yarn is significantly increased. The part agglutinates and solves the problem of broken wire. [Prior Art] A liquid crystal display (LCD), a projection display, and a Plasma Display Panel (PDP) have a strong market in the field of flat panel display TVs. We also hope that Field Emission Display (FED), Electroluminescent Display (ELD), etc. will have a place in the market with these various advantageous features along with the related technical improvements. LCD applications have extended to notebook computers, personal computer monitors, LCD TVs, vehicles, airplanes, and more. Since the second half of 1998, thanks to the rapid increase in demand, LCDs account for about 80% of the tablet market, and global sales are extremely strong. In a conventional LCD structure, a liquid crystal and an electrode substrate are disposed between a pair of optical films that absorb light. In an LCD, a liquid crystal moves by applying a voltage to an electric field generated by two electrodes, and thus has an optical state that changes with an electric field. This program displays "pixel" image storage information by polarizing in a specific direction. Accordingly, the LCD includes a front optical film and a rear optical film to induce this polarization. Since more than 50% of the light emitted by the backlight is absorbed by the rear side optical film 201211594, the LCD device does not necessarily have high use efficiency for the light emitted from the backlight. Therefore, in order to increase the efficiency of use of the backlight light in the LCD device, a brightness enhancement film may be interposed between the optical recess and the liquid crystal module. Figure la is a schematic diagram of the optical principle of a conventional luminance enhancement film. Specifically, the p-polarized light of the light guided by the optical recess to the liquid crystal component can be transferred to the liquid crystal module via the luminance enhancement film, and the s-polarized light is reflected to the optical cavity by the luminance enhancement film, and then The diffuse reflective surface of the optical cavity is reflected, wherein the direction of polarization of the light becomes random and then transferred to the luminance enhancement film again. As a result, the S-polarized light is converted into P-polarized light which can pass through the polarizing month of the liquid crystal module and then transferred to the liquid crystal module via the luminance enhancement film. The selective reflection of the S-polarized light with respect to the incident light on the luminance enhancement film and the penetration of the P-polarized light are performed by the difference in refractive index between the respective optical layers, according to the extension of the stacked optical layers And the change in the refractive index of the optical layer determines the optical thickness of each optical layer, and the flat optical layer having the anisotropic reflection coefficient and the flat optical layer having the isotropic reflection coefficient are alternately stacked in plural in the state. That is, the light incident on the luminance enhancement film is reflected by the S-polarized light and penetrated by the p-polarized light to pass through the received optical layers. Therefore, only the P-polarized light of the incident polarized light is transferred to the liquid crystal element. At the same time, the reflected S-polarized light is reflected by the diffuse reflection surface of the optical cavity, and its polarization state is randomized as described above, and then transferred to the luminance enhancement film again. Therefore, it is possible to reduce the light loss and power waste generated from a light source. 201211594 The illuminance enhancement film is manufactured by stacking a flat-shaped isotropic dry layer and a flat anisotropic optical layer, which have different refractive indices and are executed on the stack # structure. The program is such that the stacking layers of the respective optical layers have a refractive index and an optical thickness that are optimized for selective reflection and penetration of incident polarized light. Therefore, this manufacturing material is complicated. In particular, since each of the optical enhancement films has a flat shape, the p-polarized light and the s-polarized light (four) human incident polarized light have a wide range of incident angles and must be spaced apart from each other. Therefore, the number of optical layers which are excessively increased is stacked in the film, and thus the exponential increase of the cost. Moreover, this structure has the disadvantage that the wire is thus degraded in optical performance. Beibei' We have found that a brightness enhancement film containing a birefringent island-in-the-sea yarn in the matrix is extremely advantageous in solving the above problems. Specifically, when a double-folded island yarn is used, optical efficiency and luminance can be remarkably improved as compared with the use of a general birefringent fiber. The island island of Yarn Island is an anisotropic H-faced sea. In this case, • the birefringent interface between the island of the island yarn and the sea is 'in addition to the island yarn and the base f, compared to the two fibers', wherein the birefringent interface is formed only on the matrix and the birefringent fiber. At the boundary of 5, the effect of vocational education has been improved, which makes it possible to use a stacked type of brightness enhancement film for industrial use. As a result, the use of birefringent island yarns provides a better quality than the use of birefringent fibers. That is to say, the shape of the birefringent interface inside the birefringent island-in-the-sea yarn is improved by the brightness of the different optical properties of the & Therefore, for more 201211594, in order to make the optical adjustment - dry, the main skin of the weight 1 exists in the cone refraction island (four) birefringence interface (four) increase. For this purpose, the number of islands in the bismuth birefringent island yarn should be large. However, conventional island yarns include at least island portions that are concentrically arranged around the spinning core. When the number of islands is small, the structure of the section is not problematic. However, when the number of islands is long (about 3 〇 0 or more) ' due to the high density, the islands adjacent to the spinning core which are formed at the center of the island yarn during spinning can be agglomerated together. In the figure, the lb diagram shows a cross-sectional view of a conventional island 2 including a tamping island portion. In the figure, the island portion 12 is disposed in the same manner as the spinning core u in the island yarn, and the island portion occupies the entire island yarn. Section: When the number of islands is small, these sections (4) are combined (4). = 'When the number of islands is large (about one or more), due to the high density, at _ 2 and formed at the center of the island yarn The island part adjacent to the spinning core 11 can be condensed and said, 'When the number of islands in the island yarn is increased, the island's material section and the bad afforestation of the agglomeration (island agglutination) are easy to occur. Aggregation phenomenon, when the number of islands is increased ==, there is a significantly reduced birefringence interface area, such as the desired improved optical modulation efficiency. [Invention] The present invention discloses that the pointing is provided - with enough:: island even The number of islands of the birefringent island yarn is remarkable: increase the prevention of island agglutination and solve the broken wire Problem - The present disclosure also points to providing a sea-island yarn that can be used for a brightness enhancement film, 6 201211594 and capable of exhibiting the same color. In a general aspect, the present invention provides a brightness enhancement film comprising: a substrate; And a birefringent island-in-the-sea yarn in the matrix, wherein a boundary between an island portion and a sea portion of the birefringent island-in-the-sea yarn forms a birefringent interface to induce optical modulation, and the birefringent island-in-the-sea yarn comprises: a core for preventing An island agglomeration; a plurality of island groups formed radially around the core. In a particular embodiment of the invention, a boundary may be formed between the island groups such that the boundary per unit area (μιη2) The number of islands is less than the number of islands per unit area (μηι2) in the adjacent island group, and the adjacent island groups are separated by boundaries. In another specific embodiment of the present disclosure, the boundary is formed around the core In a particular embodiment of the invention, the number of islands per unit area (μηι2) of the core is greater than the unit area of the island group The number of islands (μιη2) is small. Specifically, the number of islands per unit area (μιη2) of the core is equal to or less than 1/2 of the number of islands per unit area (μιη2) in the island group. Or 1/3. More specifically, the number of islands per unit area (μιη2) at the boundary is equal to or less than 3/4 or 1/ of the number of islands per unit area (μιη2) in the island group. 2. In another particular embodiment of the present disclosure, the boundary surrounds the core and is formed in a ring shape in a plurality. In another specific embodiment disclosed in the present disclosure, the island group has a cross-sectional shape of a sector A sector, an isosceles triangle or an isosceles trapezoid. In another specific embodiment of the present disclosure, the number of island groups 201211594 is 10-50, and the number of islands included in an island group is 800-2000 In another particular embodiment of the present disclosure, the total number of islands included in the birefringent island-in-the-sea yarn is 20,000-30,000. In another particular embodiment of the present disclosure, the birefringent island-in-the-sea yarn has an A value of 500 or greater as defined by Equation 1. [Equation 1] A = - Number of islands of monofilament / Number of filaments of a composite yarn In another embodiment disclosed in the present invention, a birefringent island-in-the-sea yarn can be woven into a fabric, a weft of a fabric and a warp yarn In the case of a birefringent island-in-the-sea yarn, and the other may be a fiber, in another specific embodiment of the invention, the melting initiation temperature of the island portion of the birefringent island-in-the-sea yarn may be higher than the melting temperature of the fiber. In another particular embodiment of the present invention, the birefringent island yarn is woven into a monofilament. In another embodiment of the present disclosure, a birefringent interface can be formed at the boundary between the island portion of the birefringent island-in-the-sea yarn and the sea portion. More specifically, the island is optically birefringent and the sea is optically isotropic. In another embodiment of the present disclosure, the fibers can be optically oriented fibers. In another embodiment of the present disclosure, the fibers may be one or more fibers selected from the group consisting of polymeric fibers, natural fibers, and inorganic fibers. In another embodiment of the present disclosure, the melting initiation temperature of the island 8 201211594 of the birefringent island-in-the-sea yarn may be higher than the melting temperature of the sea portion. In another embodiment of the present disclosure, the island of birefringent island yarn The melting initiation temperature of the portion is 30 ° C or more higher than the melting temperature of the fiber. The melting initiation temperature of the island of the double-split island yarn is 30 ° C or more higher than the melting temperature of the sea. In another embodiment of the present disclosure, the fibers and/or sea portions may be partially or fully melted. In another embodiment of the present disclosure, the sea portion of the fiber and the birefringent sea island yarn may be made of the same material. In another embodiment of the present disclosure, the difference in refractive index between the substrate and the birefringent island-in-the-sea yarn in the biaxial direction may be 0.05 or less, and the refraction in the remaining axis direction between the substrate and the birefringent island-in-the-sea yarn The difference in rates is 0.1 or more. In another specific embodiment of the present disclosure, it is assumed that the refractive indices of the matrix in the X-, y-, and z-axis directions are nxl, nY1, and nzl, respectively, and the birefringent island-in-the-sea yarn is in X-, y- And the refractive indices in the Z-axis direction are Πχ2, Πγ2, and ηΖ2, respectively, and at least one of the refractive indices of the matrix in the χ-, y-, and ζ-axis directions may be the same as the refractive index of the birefringent island-in-the-sea yarn. In another embodiment of the present disclosure, the difference in refractive index between the sea portion of the birefringent island-in-the-sea yarn and the island portion in the biaxial direction is 0.05 or less, and the sea portion of the birefringent island yarn and the island portion are The difference in refractive index in one axial direction is 0.1 or more. In another specific embodiment of the present disclosure, it is assumed that the islands of the birefringent island-in-the-sea yarn have refractive indices in the χ-(longitudinal), y-, and ζ-axis directions of 201211594 Ι1χ3, Πγ3, and Πζ3′, respectively. The refractive indices of the sea in the X-, y_ and Z-axis directions are nX4, ny4 and nZ4, respectively, and at least one of the refractive indices of the matrix in the X-, y- and z-axis directions can be combined with the birefringent island yarn The refractive index is the same. In another particular embodiment of the present disclosure, the absolute value of the difference between the refractive indices nX3 and nX4 may be 0.1 or more. In another embodiment of the present disclosure, the birefringent island-in-the-sea yarn has a diameter of from 1 〇 to 1 μm. In another general aspect, the present invention provides a sea-island yarn for enhancing brightness, comprising: a core for preventing island agglutination in the island-in-the-sea yarn: and a plurality of island groups, the surrounding core being formed into radiation shape. In another specific embodiment of the present disclosure, a boundary system is formed between the group of islands such that the number of islands per unit area (μιη2) at the boundary is smaller than the unit area per unit area (μιη2) of the adjacent island group. The number of islands, and the adjacent island group is separated by boundaries. In another particular embodiment of the present disclosure, the boundary is formed as a light shot around the core. In another specific embodiment of the present invention, the number of islands per unit area (μιη2) of the core is smaller than the number of islands per unit area (μιη2) in the island group. In another particular embodiment of the present disclosure, the boundary surrounds the core and is formed in a ring shape in a plurality. In another particular embodiment of the present disclosure, the island group has a cross-sectional shape of a sector gear, an isosceles triangle or an isosceles trapezoid. In another specific embodiment of the present disclosure, the number of island groups 201211594 is 10-50, and the number of islands included in an island group is 800-2000. In another particular embodiment of the present disclosure, the total number of islands included in the birefringent island yarn is from 20,000 to 30,000. The terms used herein will be given a brief description. The phrase "fibrous birefringent" means that when light is irradiated to fibers having different refractive indices in different directions, the light rays incident on the fibers are refracted in two different directions. The term "isotropic" refers to an optical property of an article that has the same refractive index in all directions as it passes through the article. The term "anisotropy" refers to the optical properties of an article depending on the direction. An anisotropic article has a double-fold, the opposite of the anisotropy. The term "optical modulation" means a procedure in which the irradiated light is reflected, refracted or scattered, or its intensity, wave. The loop or feature is changed. The term "core" refers to a central portion from which the group of islands and the boundary are formed into a radial shape having a predetermined area to prevent agglomeration in the island portion of the profile of the sea island yarn. The "refining start temperature" means the temperature at which the polymer begins to melt, and the term "melting temperature" means the temperature at which the melting occurs the fastest. Therefore, when the melting temperature of the polymer is observed by Differential Scanning Calorimetry (DSC), the temperature at which the melting endothermic peak starts is the melting onset temperature, and the temperature corresponding to the tip end of the endothermic peak is the melting temperature. The term "photochromic fiber" refers to a color-inducing agent which, by virtue of the conformation/optical design of the knot of the fiber of the interference light, makes the fiber appear color without physical/chemical bonding to, for example, a dye or a pigment. According to the present invention, the luminance enhancement film containing the birefringent island-in-the-sea yarn does not cause island aggregation in the central portion of the island-in-the-sea yarn even if the number of island portions is 20_ or more. Since the island portion of 20,000 or more can be formed in the island yarn, the area of the optical modulation interface is maximized, and the optical modulation effect is remarkably improved. Therefore, compared to the use of known birefringent fibers or island-in-the-sea yarns having about 500 islands, the brightness enhancement film comprising the two-shot island of the present invention has a very superior optical modulation effect. The area of the interface is significantly increased, so that the brightness can be significantly improved. When the birefringent island-in-the-sea yarn is woven into a fiber form, and is contained in the hui=film, since it has a large number of island portions, even if it is a (birefringent sea) early yarn, the desired luminance can be obtained, and therefore, And it is necessary to improve the number of birefringence island yarns used to improve the brightness of the yarn, so that yarn breakage and broken yarn can be avoided. ‘,' In addition, the precision of the majority of the islands used for the brightness of the yarn can be reduced. Since it is possible to manufacture ultra-fibrous fibers in an island=transmission, it is not only advantageous for manufacturing ultrafine fibers, but also can be significantly reduced in manufacturing cost. - The other features and aspects of the invention are apparent from the following detailed description, drawings and claims. (4) and A. [Embodiment] 12 201211594 t:: The following specific embodiments of the drawings are referred to, and the features, points, features and aspects will be apparent. The invention is disclosed, and can be embodied in various forms and should be limited by the specific embodiments. Of course, these specific implementations _== this = complete and complete, and will be fully communicated to the familiarity of the invention. The terminology used herein is for the purpose of description only. As used herein, "the" and "the" are also intended to include the plural unless otherwise clearly indicated below. The term "at least, includes" when used in this document indicates the presence of such features, integers, operations, components and/or components, but does not exclude the presence or addition of various other features, integers, steps, Operations, components, components and/or groups: and 〇 '

兹參照附圖’詳細說明例示性具體實施例如下。 如前述,由已知用以製造海島紗之纺嘴所製備 紗至少包含環繞一紡絲核心配置成為同心圓狀的島邱: 以無紡絲核心方式隨機配置島部。在島部數目少時邵,或 剖面結構並無問題。然而,當島部數目大時(約邓0 =種 多)’則在紡絲期間,由於高密度,鄰接於形成在海島=更 心的紡絲核心的島部,則凝集一起(島部凝集)。就是s I 海島紗島部之數目增加時,在海島紗中心邱八—說田 集(第lb圖)。 77部會凝 在韓國專利申請第2009-7642號,如其第㉛圖戶_ 本發明人等已使用紡嘴之上分配板製備一輝度增強^不, 、 其 13 201211594 包含在一單絲中具有1016個島部的雙折射海島紗。第2a 圖表示具有1016個島部之雙折射海島紗,吾人可知,雖然 島部數目超過500,但島部凝集並不發生於雙折射海島紗之 中心部分。然而,由於第5圖所示之具有1〇16個島部的雙 折射海島紗(單絲)僅為單絲(直徑=丨9 μ m)而具有低光學調 變效率,其被製備成40丹尼(denier)/12單絲(股)、80/24(丹 尼/單絲)之複合絲,且複合絲被編織成作為緯紗或經紗之織 物,並被使用於輝度增強膜。具體而言,第九圖及第2d 圖表示包含第2a圖之雙折射海島紗(單絲)的織物6〇。藉由 =合-股(單絲)雙折射海島紗61成為嶋(丹尼/單二 同向性纖維62作為緯紗來製備織物. 2 。結果’雖然改良了光學調變效率,但是由 ;複5的是彳、單絲直徑及Α量絲因而發生 =人、3、〇,在輝度增_造成_單絲/(第。 在島部數目超過10000時,在韓國專、ρ曰。再者, 號所揭示之雙折射海島紗仍舊存在島部凝月集之第2009-7642 為解決此問題,本發明提供1輝斤可能性。 —基質;及位於基質内部之—雙折射海^其包含: ,島紗包含—核心,用以防止島部凝集;其中雙折射 環繞該核心形成為輻射狀。结果,即'、 鼓個島部群, 部數目超過2_0,島部凝集亦不致^雙島紗中島 卓絲製備而無使雙折射海島紗複合 •此,當織物以 雙折射介面增加,能夠維持高輝度。;軒射海島紗中 強膜中的單絲之糾纏,及紗斷裂可予包含於輝度增 ’固而不致發生 201211594 斷裂單絲。結果’輝度增強膜之缺陷可予避免,且在無反 極化下,可維持均勻的輝度。 參照第3圖,就包含於本發明揭示之輝度增強膜中的雙 折射海島紗予以詳細說明,第3圖為根據本發明揭示之一特 定具體實施例的包含於輝度增強膜中的海島紗剖面之電子 顯微鏡影像(X1000)。該雙折射海島紗至少包含:一核心 510 ’用以防止島部凝集;及複數個島部群52〇、,其環 繞該核心510而形成為輻射狀。 〆首先說明形成於雙折射海島紗中的核心HO。核心51〇 係形成於雙折射海島紗中以防止島凝集。具體言之,其係 形成於雙折射海島紗之中心部分’且被島部群52〇、別之 末端部環繞。-般而言,如果雙折射海島紗之島部數目增 加,由於島部集中在海島紗之中心部分,則在該中心部分 易於產生島凝集。因此,在本發明之揭示,能夠避免島凝 集之核心510係形成於雙折射海島紗中,以防止島凝集,即 使島部之數目顯著的增加亦然:。具體言之,當在核心51〇中 每^位面積(μιη2)之島部數目小於島部群中每單位面積 (μηι2)之島部數目’防止島凝集極為有利。具體言之,在第 3圖中,當比較C顯示核心之部分’且Α顯示島部群之内部, 吾人可觀察到每單位面積之島部數目,在c遠比八更 小。當雙折射海島紗自-紡嘴被紡絲,由於鎮口腫服⑼e 繼IHng) ’則島部酿並擴張。島部甚至祕並擴張至只 有海部存在的區域。因此,在纺紗之早期階段,當空隙(或 僅海部)形成於海島紗之中心部分,則在纺絲的末階段,該 15 201211594 =脹:擴張至海島紗之中心部分。然而,由於在海島 二 島部,故在海島紗之中心部分的鎮口腫 島权島凝集可予避免。亦即,在纺絲之早期階段,雖 然在核心中並無空隙,例如海島紗之中心部分,由於鎮口 腫脹,該島部腫脹並擴張至核心。但是,由於島部在海島 紗的核心中最初幾乎碎在,故在鎮口腫脹發生時,在核 心t母早位面積«)之島部數目小於在島部群中每單位 面積(〆)之島部數目。具體言之,在核心中每單位面積 (μη〇之島部數目較島部群中每單位面積(〆)之島部數目 等於或小於1/2 ’較佳為1/3。該單位_之蚊,係使核心 510與島部群520、530中之島部數目可予比較。具體言之, 該單位面積可定為Ιμηι2,但不限於此。 /一在本發明揭示之一特定具體實施例,該核心510具有-直裎,此夠防止島部凝集且與此相對應之區域。根據雙折 射海島紗之直徑與島部數目,該直徑與面積可予變化。具 體言之’當核心51〇具有圓形狀,其直徑可為〇2_5μιη,當 核心510具有卵形狀,主軸可為0.5-ΙΟμιη,當核心510具有 多角形狀’從一頂點至最遠頂點之距離可為0.5-10μιη。然 而,並無限定於此,該核心510之形成,以使其較島部群之 島部更少,得以防止島部凝集。 接著’詳細說明島部群520、530,與分隔島部群520、 530之邊界54〇 ’如在此所使用,島部意指包含於雙折射海 島紗之微細纖維。來自一島部群之一些島部,及島部群係 以複數存在。具體言之,島部群520、530係以複數個環繞 201211594 核心510而形成為輻射狀’且複數個島部群520、530係由形 成在鄰近島部群520、530之間的邊界540而被分隔。具體言 之,該邊界540係環繞核心510而形成為輻射狀,且邊界540 之數目較島部群之數目小至少1。具體言之,在形成於鄰近 島部群520、530之間的邊界之每單位面積(μ^2)之島部數目 小於在島部群中每單位面積(μπι2)之島部數目,以防止島部 凝集。具體έ之,在第3圖,當比較Β顯示邊界54〇的部分, 而Α顯示島部群520内部,吾人可觀察到每單位面積(μηι2) 之島部數目,相較於A,Β則更小。當雙折射海島紗係自紡 嘴紡紗時,由於鎂口膨脹’則島部腫脹。島部甚至腫脹至 只有海部存在之區域。因此在紡絲之早期階合 可形成作為海部你成於絲紗之中心料,在 島部腫脹至邊界。由於在海島紗之邊界並無島部,故在海 島紗之邊界賴π賴島敎島部凝射Μ避免。亦 即’由於島部在海島紗的邊界最域乎不存在,即使在鎮 口腫脹發生時’在邊界每單位面積(μπι2)之島部數目遠小於 在^部群中每單位面積(μπι2)之島部數目。具體言之,在邊 界每單位面積(〆)之島部數目相較於在島部群中每單 面積㈣2)之島部數目可等於或小於3/4,較佳為1/2。該軍 位面積之決定係使在邊界54〇與在島部群52〇、5 。具體言之’該單位面積可定為1μιη2,但不 在本發明揭示之另i定具體實施例,該邊 核心而形成為輻射狀〇另一 衣 狀另方面,一個或多個環形邊界 17 201211594 _=形成為同心圓。該環形邊界可為連續或不連續。 心5^形=之剖面形狀並無特別限^,只要能夠環繞核 為扇形齒& ^ ^ 可具有剖面之形狀 茵輪、專腰三角形或等腰梯形。 目為fotf明揭示之另一具體實施例’複數個島部群之數 -’且包含於一島部群之島部數目為__2_。 吵中二示之另—具體實施例,包含於雙折射海島 、、/中島邻的總數為2〇〇〇〇·3〇〇〇〇。具體言之, 發明揭示之一特定具體實施例,海島紗的電 =象雙折射海島紗具有2。個島部群,每一島部 /、有1250島部,且包含於雙折射海 25000。因.,钿站丄八η…•馬口Ν悤數為 1〇_ $、 據本發揭不,該雙折射海Α紗較佳為 s以上,更佳為20000或以上,在用於輝度婵睥 ,島部可使輝度改良最大化,並防止絲斷裂。 時 在此揭示之雙折射海島紗之直徑較佳為1〇 佳為40·1〇〇μπι,但並不限於此。 μιη,更 =述’如第2&圖所示,即使島部數目超過挪 生:具有1016個島部之雙折射海島紗,在相 况下’右島部數目10_或以上,則島部凝 生。再者,如第2〇圖、第2d圖所示,當雙折射=發 備成為80/24(丹尼/單絲),且複合絲被梭織成島紗被製 緯紗之織物,卿斷裂產生,且絲是,會為經紗或 反極化。因此’在本發明揭示之另—具體實施例_裂絲及 海島紗之以方程式1所定義的Α值為500或以上。^雙折射 在此情況, 18 201211594 ^於m輝度增強财之單㈣及紗斷裂不會發 故可避免斷裂絲。結果,輝度妗強膜之缺^ 且輝度可維持均勻。s 、、日可予避免, [方程式1] Α 一I單絲之島部數目/ —複合絲之單絲數目 通吊’係將具有300個島部之習知的5〇股雙 複合、’或將具有1G16個島部之習知的12股雙折射 、、办予以複合。在此情形,A值僅各為6與 、 於500。對比之下,米姑θ丄 退小 個良勒 有25000個島部〇股)或15_ i W之雙折射海島紗,則Α值各成為25000及 ,运大於500。相較於當數根股被複合時之情形,由於 使用單絲顯著地降低起因於紗斷裂之纖維糾纏與斷裂單 絲之風險,吾人更想要使用雙折射海島紗,其A值為1000 或以上、5〇0〇或以上、10000或以上,或20000或以上。 最佳是具有10000-20000或更多島部的雙折射海島紗的一 單絲,或約2股的複合絲,可用以有效地避免纖維糾纏及 斷裂單絲。第5圖表示根據本發明揭斧之一特定具體實施 例,使用一海島紗(具有25〇〇〇島部)的單絲作為經紗之織 物。如第5圖所示,在雙折射海島纱中炎不發生紗斷裂。 設若將具有不同島部數目之單絲予以複合(例如,設若 將具有300個島部的10單絲,及具有5〇〇個島部的10單 絲予以複合),平均數可界定為一單絲之島部數目。 在本發明揭示之另一具體實施例,雙折射海島紗之之 島部之熔化起始溫度為 高於纖維及/戒海部之熔化溫度。當 19 201211594 雙折射海島紗照原樣合併成為—輝度增強膜,在例如疊層 期間雙折射海島办可容易地移動(例如被糾纏)。因此,在 至少包括雙折射海島紗之織物被編織後,織物在基質間可 被疊層以便修復雙折射海島紗。㈣,如果雙折射海島紗 合併於輝度增強膜成為織物形式,而不是照原樣用於液晶 顯示器_,即使構成織物之纖維係用透明材料製造,务 從外部發光,則織物(纖維)為可見。因此,要商業化有極: 因此,為了解決該等問題,本發明提供一種輝度增強 膜’其中雙折射海島紗島部祕化㈣溫度高於纖維^溶 化溫度。 I先―第5圖’詳細說明包含於該輝度增強膜的織 。第5圖以圖不顯不可用於本發明揭示之織物。該織物包 含經紗及轉。經料料之—駿折料A紗,衫他 為-纖維。換句話說,當—雙折射海島紗被用作緯紗,則 纖維被用作經紗。且當雙折射海島紗被用作經紗,則 維被用作轉。構成織物之轉及經紗可 材料製造,以使光線通過。 次牛透月 在本發明揭示之-具體實施例,雙折射海島紗之島部 的溶化起始溫度高於纖維之熔化溫度。因此,當施加敎及/ ==與基質疊層,而溫度係在纖維的炫化溫度與 島㈣熔化起始溫㈣,由於尚未相胁㈣始严产, 故島部仍舊不溶化,但纖維已部分或全部熔化。因此^作 為緯紗或經紗之纖維在疊層期㈣化且成為基質之一部 201211594 分’僅剩下所獲得輝度增強膜内部之雙折射海島紗。 纖維I見度問題可顯著的改善。再者,由於溶化纖維。可你 為黏著劑’織物可黏著於基質而不需使用額外的 因此,雙折射海島㈣A部可具雜化起始溫度高於^ 的溶化狐度。具體而言,雙折射海島紗之島部的匕起如 溫度可較纖維溶化溫度高到或以上,更佳為,或以起上始 且,雙折射海島紗島部的熔化起始溫度可高於海 溶化溫度’更佳為雙折射海島紗之島部祕化起始溫; 較海部之耗溫度高寶或以上。結果,雙折射海 海部可部分或全雜化。在本發明揭示之具體實施例^ 折射海島紗之島部的溶化起始溫度可為13(M3〇()c,同 纖維之炼化溫度可為i⑼-嫣。。,雙折射海島紗之海部 化溫度可為100-400°C,且疊層溫度可為·42〇。 無受到限制。 b 結論是,由於用作織物之緯紗或經紗之同向性纖維的 熔化溫度低於用作卿或緯紗之雙折射海島紗醜化起始 溫度,當疊層係在同向性纖維祕化起始溫度 ^ 島紗的熔化溫度之間之溫度進行,則包含該織物之輝度增 強膜能夠解決纖維可見度問題,這是因為同向性纖 ^ 或全部脉。再者由於雙折射海島紗之海部祕化溫度低 於島部之熔化起始溫度,若疊層之進行係在介於該等之間 之溫度,則海部料或全雜化,&而提供層^黏著而 不需使用額外黏著劑。 茲說明基質,基質可用熱塑性或熱固性聚合物來製造 21 201211594 ’其可轉移光波長所需範圍,可為允許光線容易穿透的透 明或半透明材料。具體而言,該基質可為非晶形或半結晶 性,並可為均聚物、共聚物或其混合物。特定例子包括聚 碳酸酯(pc);對排型及同排型聚苯乙烯(PS);烷基笨乙烯; 烷基、芳香族或脂環族(曱基)丙烯酸酯,例如聚曱基丙烯酸 曱醋(PMMA)及PMMA共聚物;(曱基)丙烯酸乙醇鹽及丙 醇鹽;多官能性(曱基)丙烯酸酯;丙烯酸化環氧樹脂;環氧 樹脂;其他乙烯不飽和化合物;環烯烴及環烯烴共聚物; 丙烯腈-丁二烯-苯乙烯(ABS);苯乙烯丙烯腈(SAN)共聚物 ;聚乙烯基環己烷;PMMA/聚氟乙烯摻合物;聚苯醚合金 ;苯乙烯嵌段共聚物;聚醯亞胺;聚颯;聚氯乙烯;聚二 甲基矽氧烷(PDMS);聚胺基曱酸酯;不飽和聚酯;聚乙烯 ;聚丙烯(PP);聚對酞酸烷酯,例如聚對酞酸乙二酯(PET) ;聚萘二甲酸烷基酯’例如聚萘二曱酸乙二酯(PEN);聚醯 胺;離子聚合物;乙酸乙稀酯/聚乙稀共聚物;乙酸纖維素 ;乙酸丁酸纖維素;含氟聚合物;聚苯乙烯聚乙烯共聚物 ;PET及PEN共聚物,例如聚烯烴PET及PEN ;及聚碳酸 酯/脂肪族PET摻合物。更具體而言,聚萘二曱酸乙二酯 (PEN)、萘二甲酸乙二酯共聚物(C0_peN)、聚對酞酸乙二酯 (PET)、聚碳酸酯(PC)、聚碳酸酯(PC)合金、聚苯乙烯(PS) 、耐熱性聚苯乙烯(PS)、聚曱基丙烯酸曱酯(PMMA)、聚對 酞酸丁二酯(PBT)、聚丙烯(PP)、聚乙烯(PE)、丙烯腈-丁二 烯-苯乙烯(ABS)、聚胺基曱酸酯(PU)、聚醯亞胺(PI)、聚氣 乙烯(PVC)、苯乙烯丙烯腈(SAN)掺合物、乙烯-乙酸乙烯酯 22 201211594 (EVA)、聚醯胺(PA)、聚縮駿(P0M)、聚驗、環氧樹脂㈣ 、尿素(UF)、三聚氰胺(_)、不飽和聚酉旨(up)、石夕⑼、彈 性體及環烯煙聚合物(C〇P,日本z職股份有限公司及日 本皿股份有限公司)’此等可單獨使用或以其組合使用。 更具體而言,該基質可用與雙折射海島紗之海部相同㈣ 料構成。再者,該基質亦可包含添加劑,只要該添加劑不 會造成物理性質變差即可;此等添加劑例如有抗氧化劑、 光安定齊卜熱安定劑、潤滑劑、分散劑、uv吸收劑、白色 色素,及螢光增白劑。該基質可為光學同向性。 在考量不同物理性質下,對於基質之構成成分或其光 學性質可選擇與海部及/或纖維者相同。在該情況,於疊層 製程中,該基質可部分或完全熔化’因此能約在不使用額 外的黏著劑下,增進雙折射海島紗與基質之間之附著性。 該基質可包含二層。具體而言,經由聚合物之共擠出,可 將該三層形成為具有堆4結構者,該堆疊結構包含表_ 層)、核心層(A層)及表層(B層)。對應於織物之表層可具有 與海部及/或纖維相同的溶化溫度,以増進與雙折射海島紗 之黏著。核心層可由具有比海部及/或纖維更高熔化溫度之 材料製成,以防止因燈具所產生熱造成之基質變形。 因此,當上述的織物在三層薄片間被疊層,可獲得表 層(A 1)/核心層(B1)/表層(A2)/織物/表層(A3)/核心層(B2)/表 層(A4)的結構。當表層與海部及/或纖維具有相同熔化溫度 ,則該表層與海部可一起熔化,以使表層(A2,Λ3)及織物 層成為一層。 23 201211594 接下來’說明可用作織物 纖維,只要可與 、或!紗之纖維。任何 有關溫度之規定,均可予、y、為織以形成織物且符合上述 。具體而言’當考雄吏,而對於、纖维類型沒有限定 編織時,纖維可為光學同向射海島紗垂直之方式 =生,則藉由雙折射海島紗調變過之::若纖維亦為雙折 纖維。纖維可為聚合物、天先線可能無法通過該 維)或其組合。更且 …機纖維(例如玻璃纖 部相同的材料。再、f :,纖維可為與雙折射海島紗之海 丹者’在本發明揭示之η 二以,可與基質折:率 紗。在雙折射海島紗中、、乂或轉的雙折射海島 質以使光學調變效圭县;島錢海部可具有不同的光學性 平敢大化。更且躺τ 、 性且海部可為同向性。 尺/、體而&,島部可為異向 之海島紗中,沿=至1包括光學同向性海部及異向性島部 度或不相“會二:t:::折射:之本質上相等程 成比例地隨著折射率的差異之平方估厂散射效能 異增加ί沿著該轴偏極化之光線將更 ^ . ®在特疋轴之折射率的差異小時,沿 ㈣散射。當於特定抽海部之折射 等於島部之折射率時,不論海島紗之尺寸、形狀 ’被電場偏極化而與該轴平行之入射光可能會 過海島、、少、而不被散射。再具體而言,第4圖例示光通過 24 201211594 雙折射海島紗之剖面圖,在此情況,P-波(以實線代表)通過 海島紗而不會受到外部與雙折射海島紗間之界面以及雙折 射海島紗之島部與海部間的界面影響,而8_波(以虛線代表) 交到基質與雙折射海島紗間之界面及/或雙折射海島紗之 島部與海部間之界面影響,因此被光學調變。 上述光學調變現象主要發生在基質與雙折射海島紗間 之界面及/或雙折射海島紗之島部與海部間的界面。具體而 言’當基質為光學同向性時,如同一般的雙折射纖維,光 學調變發生在基質與雙折射海島紗間之界面。更具體而 言’在基質與海島紗間之二軸方向中折射率的差異可為 0·05或以下,且在其餘一軸方向折射率的差異可為〇」或 以上。更具體而S,假設基質在x_、M ζ_軸方向之折射 率分別為nxl、nY1及ηζι且雙折射海島紗在x_、y-及ζ_軸方 向之折射率分別為ηΧ2、恥2及巧2,基質在χ_、^及ζ_軸方 向之折射率之至少-者可與雙折射海島紗者 而言,可具有下列關係JnX2>nY2=nz2。 更,、體 同時,在雙折射海島紗中,島部及海部可具有不同的 光學性質以形成雙折射界面。具體而言,當島部為異向性 且海部為同向性時,可於島部與海部間之邊界形成雙折射 界面。更具體而言,在二軸方向折射率之差異可為〇 〇5或 以下,以及在其餘-軸方向之折射率的差異可為〇1或以 上。在該情況,P-波通過海島紗之雙折射界面,而s_波被 光學調變。為了更詳細說明,假設雙折射海島紗之島部在 Χ-(縱向)、y-及Z_軸方向之折射率分別為n幻、Μ及, 25 201211594 且其海部在χ·、y-及Z-軸方向之折射率分別為ηχ4、ηγ4及 ηΖ4 ’則基質在X-、y-及Ζ-轴方向之折射率之至少一者可與 雙折射海島紗者相同。折射率nx3與nx4之差異之絕對值可 為〇. 1或以上。更具體而言,當海島紗之海部與島部在縱 向之折射率的差異為0.1或以上且海部與島部在其餘二軸 之折射率實質相等時可使光學調變效率最大化。同時,當 基質與雙折射海島紗之海部具有相同折射率時,可容易地 增進光學調變效率。 所以,為了增進光學調變效率,可選擇島部及海部在 縱向之折射率差異大,同時在其他二軸具有實質相同之折 射率之雙折射海島紗。 雙折射海島紗之海部及/或島部可由聚萘二曱酸乙二 酯(PEN)、共聚萘二曱酸乙二酯(co-PEN)、聚對酞酸乙二酯 (ΙΈΤ)、聚碳酸酯(pc)、聚碳酸酯(PC)合金、聚苯乙烯(PS) 、耐熱性聚笨乙烯(PS)、聚曱基丙烯酸曱酯(PMMA)、聚對 酞酸丁二酯(PBT)、聚丙烯(PP)、.聚乙烯(PE)、丙烯腈-丁二 烯-苯乙烯(ABS)、聚胺基甲酸酯(PU)、聚醯亞胺(PI)、聚氯 乙烯(PVC)、苯乙烯丙烯腈(SAN)摻合物、乙烯-乙酸乙烯酯 (EVA)、聚醯胺(PA)、聚縮醛(POM)、聚酚、環氧樹脂(EP) 、尿素(UF)、三聚氰胺(MF)、不飽和聚酯(UP)、矽(SI)、彈 性體及環烯烴聚合物及其組合製成。具體而言,鑑於有效 率地增進光學調變,可選擇島部及海部在二轴具有實質相 同之折射率但在一軸具有之折射率差異大之材料。但是, 更具體而言,當使用聚萘二曱酸乙二酯(PEN)做為雙折射海 26 201211594 島紗之島部的材料,且使用共聚萘二甲酸乙二酯、聚碳酸 酉曰合金或其組合做為海部之材料時’相較於由常用材料製 成的雙折射海島紗,可大幅增進輝度。尤其當使用聚礙酸 酉曰合金做為海部時,可製備具有最優良光學調變性質的雙 折射海島紗。在此情況’聚碳酸酯合金較佳地可至少包括 聚奴&L酯及改質的聚對酞酸伸環己基二亞甲基酯二醇 (PCTG)。更具體言之,使用至少包括聚碳酸酯及改質的聚 對酞酉夂伸環己基二亞甲基g旨二醇(pcTG)且該二者之重量比 為15 . 85至85 : 15之聚碳酸酯合金,其可有效地增進輝 ,田象碳酸酯之存在量小於15%時,將過度增加紡紗效 =所:求的聚合物黏度,而有無法使用纺紗機之缺點。且 田^碳㈣之存在量超過85%時,自喷嘴喷出後,玻璃轉 移/凰度夂加且紡紗張力增加,因此變得難以確保紡紗效能 〇 敢佳疋使用至少包括聚碳酸酯及改質的聚對酞酸伸環 己基一亞甲基酯二醇(PCTG)且該二者之重量比為4 : ό至ό .4之聚碳酸酯合金,其可有效地增進輝度。再者,鑑於光 學調變效率之有效率增進,較佳地島料海部係選擇在縱 向折射率差異大而在其他二轴具有實質上相同折射率者。 、將同向性材料改質成為雙折射材料之方法在本技術中 為眾所熟知。例如,聚合物分子可被定向,因此當將其在 適當溫度條件拉伸時,將成為雙折射性。本發明揭示之雙 折射海島紗可以例如共擠壓來製備,但並無限定於此。 因此,當已知海島紗僅使用在熔化海部後遺留下來的 27 201211594 島部作為微細纖維,而 海島紗,其至少包含 心彳射,但本發明揭示使用 替代炫化海島紗之海部有生質的海部與島部,以 向性,而海部為同向性之情匕月揭示,係採用島部為異 擇使用。 况,然而,相反的情況亦可選 ,島部及了使雙折射海島紗的光學調變效率最大^ 面==有不同光學性質,且光學調變用之介-島。為此,島部之數目應予增加。具體言之, 光1二二大於500。然而,在已知的海島紗,即使島部為 子、0且海部為光學同向性’當島部數目超過50C ’、則島部傾向於凝集。結果,光學調變狀介面面積被減 夕、且光子調變效率降低。相較之下,本發明揭示之雙折 射海島紗能夠防止島部之凝集。結果,海島紗之光學調變 效率被最大化,且根據本發明揭示,當雙折射海島紗被用 作輝度增強麟,則光學調變效率與輝度增賴的輝度如 下所述,可做極大的改良。 在本發明揭示之一具體實施例中,本發明揭示之輝度 增強膜上可具有結構化之表面層。更具體而言,該結構化 表面層可形成在射出光線侧。該結構化表面層可為稜鏡、 雙凸型透鏡或凸透鏡之形式。更具體而言,在該輝度增強 膜之射出光線側可具有凸透鏡形式的曲面。該曲面可聚售 或散焦通過該表面的光線。又,該射出光線表面可具有稜 鏡式圖樣。 接下來說明根據本發明揭示之雙折射海島紗之製造方 28 201211594 法。此等雙折射海島紗可藉由任何通常用於包含複合之製 造海島紗之方法來製造而沒有特殊限定。只要能夠製備雙 折射海島紗,可使用任何紡嘴或紡紗喷嘴而不限制其形狀 。一般而言,所使用之紡嘴或紡紗喷嘴可具有自雙折射海 島紗剖面所見之島部配置圖案實質相同之形狀。具體而言 任何纺嘴,只要可製備海島紗,均可加以使用,該海島 紗係藉由將從中空栓(―pin)或紡紗喷嘴擠出之島部與 從通道供應之海部加以組合,其中該中空栓或紡紗喷嘴被 適田"又什成可使島部分隔,而該通道被設計成可填滿其間 之空間;經由一使該組合流逐漸變窄之排出口,擠出該組 口机,而形成具有2個或以上紡紗核心之海島紗。適用的 紡嘴的特定例子示於第6圖巾,但可用於本發明的紡嘴非 限於此。第6圖表示根據本發明揭示之一特定具體實施例 用以製備-海島紗之紡嘴的上分配板的剖面。 、’上分配板至少包含:一核心121,其形成^7 心並防止 凝集,複數個島部供給單元123、124,其圍繞核心121 成為幸田射狀,且具有複數個島部供給通道122在其間形 複數個海。(5供給單元125沿著島部供給單元in、124 外周^形成,且在其巾具有複數個海部供給通道。韓國 利申明案第1〇-2〇1〇_0〇27670號在此併入以供參考。用以 絲本發明揭7F之雙折射海島紗之紡嘴包含上述上分配板 在凊況根據所需形狀與海島紗之特徵可有不同的組. 在使上分配板配列於上部之後,具有漏斗形狀1 下紡嘴板可配列於下部作為海島紗之排出口。同時,如第 29 201211594 圖所示,下纺嘴板130包含流道52、53 ’以使自島部供應 單元及海邛供應單元供應的聚合物材料可流至一排出口 131根據纺嘴的結構,流道132、133的數目與形狀可有 不同的设计。該排出口 131可配列於符合流道之處。 再者,額外的分配板可以適當數目配置於上分配板之 上方及/或下方,以促進島部與海部之分配與混合。 接下來說明本發明揭示之輝度增強膜之製備方法。首 先如上述,在使用雙折射海島紗使織物被編織後,織物可 配置於基質間且其後予以疊層。具體言之,基質具有表層/ 核心層/表層之二層結構。在疊層時,可形成表層(A丨)/核心 層(B)/表層(A2)/織物層(〇/表層(A3)/核心層(B2)/表層(A4) 共七層。如上述,若鄰接於織物層之表層A2、A3具有與 雙折射海島紗之海部與纖維相同之熔化溫度,則該等可部 分或全部熔化。疊層可藉由例如捲繞式或熱壓程序實施。 在此情況,為了防止起泡可在真空狀態下進行熱壓,因而 可改善接著力與輝度。具體而言,在熱壓期間之真空度可 為5-500托,施加壓力可為i.〇_i〇〇kgf/cm2,且處理時間可 為1-30分鐘。如詳述於上,疊層溫度可適度的在雙折射海 島紗之島部的溶化起始溫度及纖維及/或海部的溶化溫度 間選擇。當真空度小於5牦,製程效率不令人滿意。當大 於500托時,則消泡並不充分。當施加壓力低於lokgfycm2 ,則薄膜黏附性並不充分,且當壓力超過l〇〇kgf/cm2時, 由於過度壓力’使得纖維排列中斷。當處理時間小於i分 鐘時,則消泡及接著不充分。且當處理時間超過30分鐘時 201211594 ’則製程效率並不令人滿意。 · 本發明揭示之輝度增強膜可廣泛使用於平板顯示器, 其包含LCD、LED TV、投影顯示器、電漿顯示器、場發射 顯示器等。 實施例 茲說明本發明之實施例及實驗方法。下述之實施例及 實驗方法僅作為例示目的,且非意圖限制本發明所揭示之 範轉。 <實施例1> 作為海部(11^1.57、1¥=1.57、112=1.57,熔化溫度=145〇〇:) 係使用同向性聚碳酸酯(PC)合金,其包括pc及改質的 PCTG,比例為5 : 5,且島部係使用異向性ρΕΝ(ηχ=188、 %=1.57、ηζ=1.57,熔化起始溫度=262〇c)。 為了獲得具有如第3圖所示之剖面的雙折射海島紗, 將該等材料供應至-紡嘴’其具有如第6圖所示具備12個 島部供給單元之上分配板,及具有如第7圖所示具備一排 出口的下㈣板。藉以製備如第3圖所示具有剖面的雙折 射海島紗(單絲,島部數目=25040個,直徑=66 5μιη)。在以 紡紗速率2500ΜΡΜ製備部分定向紗(ρ〇γ,85丹尼/1單絲 之後’ ΡΟΥ在140〇C被拉伸次藉以製備fy(4〇丹尼八 使用如此製備的雙折射海島紗(單絲,4〇丹尼八單絲 作為經紗,且使用相同於海部之同向性叱合金纖_ 溫度=,驅G丹尼/24單絲)作為特來編織織物。 201211594 禮;5圖所示為在實施例1所製備的織物表面之s腿影 ^口人可觀察到用作經紗的雙折射海島紗並無紗斷裂發 生0 比較例1> 包括PC及pCTG比率為5 : 5的同向性π合金被用 作海部(ηχ吃57、ny=1.57、nz=l 57,炼化溫度=145。〇,且 異向性 PEN(nx=l 88、η=]57 _ ny 1·57、ηζ=157,熔化起始溫度 =262°C)被用作島部。 為了獲得如第2a圖具有剖面的雙折射海島紗,將該等 材料被供應至㈣,其具有如第2b圖所示之上分配板。兹 製備如第5 ®所轉有剖蚊雙折射料紗(單絲,島部數 目1016個’直技’㈣。在以紡紗速_ 2·娜%及紡紗 μ度290 C製備ρ〇γ(85丹尼/12單絲)之後,ρ〇γ在14〇〇c 被拉伸2·1次以製備FY(40丹尼/12單絲)。 使用複合成為80丹尼/24單絲的雙折射海島紗 FY40/12之2股作為經紗,且使用與海部相同的同向性pc 合金纖維(熔化溫度=145。(:,ρ〇γ 6〇/24)作為緯紗來編織織 物。。Exemplary embodiments are described in detail below with reference to the accompanying drawings. As described above, the yarn prepared by the spinning nozzle known to manufacture sea-island yarns includes at least a island which is concentrically arranged around a spinning core: the island portion is randomly arranged in a non-woven core manner. When the number of islands is small, Shao, or the structure of the section is no problem. However, when the number of islands is large (about Deng 0 = more species), then during spinning, due to the high density, adjacent to the island formed in the island = the center of the spinning core, agglutination together (island agglutination) ). When the number of islands in the island of s I increased, at the island yarn center, Qiu Ba, said Tian Tianji (fig. lb). The 77th will be condensed in Korean Patent Application No. 2009-7642, as in its 31st household _ the present inventors have used the distribution plate above the spinning nozzle to prepare a brightness enhancement ^ No, and its 13 201211594 is contained in a monofilament 1016 islands of birefringent island yarn. Fig. 2a shows a birefringent island-in-the-sea yarn having 1016 islands. It is known that although the number of islands exceeds 500, the agglomeration of the island does not occur in the central portion of the birefringent island-in-the-sea yarn. However, since the birefringent island-in-the-sea yarn (monofilament) having 1 〇 16 islands shown in Fig. 5 is only a monofilament (diameter = 丨 9 μm) and has low optical modulation efficiency, it is prepared as 40. A composite yarn of denier/12 monofilament (strand), 80/24 (danny/monofilament), and the composite yarn is woven into a weft or warp fabric, and is used for a brightness enhancement film. Specifically, the ninth and second graphs show the fabric 6 of the birefringent island-in-the-sea yarn (monofilament) of Fig. 2a. The fabric is prepared by using a conjugated-strand (monofilament) birefringent island-in-the-sea yarn 61 as a weft (Danny/single-dimerity fiber 62 as a weft yarn. 2. Results 'Although the optical modulation efficiency is improved, 5 is the diameter of the 彳, the diameter of the monofilament and the Α 因而 因而 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = , the birefringent island yarn disclosed by the number still exists in the island of the condensed moon collection 2009-7642. To solve this problem, the present invention provides a possibility of stimulating. - a matrix; and a birefringent sea located inside the matrix : The island yarn contains a core to prevent the island from agglutinating; wherein the birefringence is formed around the core to form a radial shape. As a result, 'the drum island group, the number of parts exceeds 2_0, and the island agglutination does not cause the double island. The yarn is made in the yarn without the birefringence island yarn composite. Therefore, when the fabric is increased by the birefringence interface, the high brightness can be maintained. The entanglement of the monofilament in the strong film in the island yarn and the yarn breakage can be included. In the case of the increase in brightness, it does not occur in 201211594 broken monofilament. The defect of the luminance enhancement film can be avoided, and the uniform luminance can be maintained without reverse polarization. Referring to Fig. 3, the birefringent island-in-the-sea yarn included in the luminance enhancement film disclosed in the present invention will be described in detail, and the third The present invention is an electron microscope image (X1000) of a sea-island yarn profile included in a brightness enhancement film according to a specific embodiment of the present invention. The birefringent island-of-the-sea yarn comprises at least a core 510' for preventing island agglutination; And a plurality of island groups 52〇, which are formed in a radial shape around the core 510. First, the core HO formed in the birefringent island-in-the-sea yarn is described. The core 51 is formed in the birefringent island yarn to prevent island agglutination. Specifically, it is formed in the central portion of the birefringent island yarn and is surrounded by the island group 52〇 and other end portions. In general, if the number of islands of the birefringent island yarn increases, due to the island Focusing on the central portion of the island yarn, island agglomeration is apt to occur in the center portion. Therefore, in the disclosure of the present invention, the core 510 system capable of avoiding island agglutination is formed in the birefringent island yarn. In order to prevent island agglutination, even if the number of islands increases significantly: In particular, when the number of islands per area (μιη2) in the core 51〇 is smaller than the area per unit area (μηι2) in the island group The number of islands 'prevents island agglutination is extremely beneficial. Specifically, in Figure 3, when comparing C shows the core part' and shows the inside of the island group, we can observe the number of islands per unit area, in c is much smaller than eight. When the birefringent island yarn is spun from the spinning nozzle, the island is brewed and expanded due to the swelling of the town (9)e (IHng). The island even secretly expands to the area where only the sea is present. Therefore, in the early stage of spinning, when the void (or only the sea portion) is formed in the central portion of the island yarn, at the end of the spinning, the 15 201211594 = expansion: expansion to the central portion of the island yarn. However, since it is in the island of the island, the agglomeration of the island of the island in the central part of the island yarn can be avoided. That is, in the early stage of spinning, although there is no void in the core, such as the central portion of the island yarn, the island is swollen and expanded to the core due to swelling of the town. However, since the island is initially almost broken in the core of the island yarn, when the swelling occurs in the town, the number of islands in the core area of the core t is smaller than that in the island group (〆). Number of islands. Specifically, the number of islands per unit area in the core (the number of islands per μη〇 is smaller than or equal to 1/2' per unit area (〆) in the island group is preferably 1/3. The mosquitoes may be compared with the number of islands in the core group 510 and the island group 520, 530. Specifically, the unit area may be Ιμηι2, but is not limited thereto. One of the specific embodiments disclosed in the present invention, The core 510 has a straight cymbal which is sufficient to prevent the island from agglutinating and corresponding to the area. The diameter and the area may vary depending on the diameter of the birefringent island-in-the-sea yarn and the number of islands. Specifically, when the core 51〇 It has a circular shape and may have a diameter of 〇2_5μιη. When the core 510 has an egg shape, the major axis may be 0.5-ΙΟμιη, and when the core 510 has a polygonal shape, the distance from a vertex to the farthest vertex may be 0.5-10 μm. The core 510 is formed so as to be smaller than the island portion of the island group, thereby preventing the island from being aggregated. Next, the island group 520, 530 and the island group 520, 530 are described in detail. Boundary 54〇' as used here, island It refers to the microfibrils contained in the birefringent island yarn. Some islands from the island group and the island group exist in plural. In particular, the island group 520, 530 is surrounded by a plurality of cores 510 of 201211594. Formed as a radial ' and a plurality of island groups 520, 530 are separated by a boundary 540 formed between adjacent island groups 520, 530. In particular, the boundary 540 is formed radially around the core 510. And the number of boundaries 540 is at least less than the number of island groups. Specifically, the number of islands per unit area (μ^2) formed at the boundary between adjacent island groups 520, 530 is smaller than that in the island. The number of islands per unit area (μπι2) in the group to prevent agglutination of the island. Specifically, in Fig. 3, when comparing the area showing the boundary 54〇, and showing the inside of the island group 520, we can The number of islands per unit area (μηι2) was observed, which is smaller than that of A. When the birefringent island yarn is spun from the spinning nozzle, the island is swollen due to the expansion of the magnesium mouth. The island is even swollen. To the area where only the sea is present, so in the early days of spinning The combination can be formed as the center material of the sea yarn, and it is swollen to the boundary in the island. Since there is no island at the boundary of the island yarn, it is avoided at the border of the island yarn. That is, because the island is the most non-existent at the boundary of the island yarn, even when the swelling of the town mouth occurs, the number of islands per unit area (μπι2) at the boundary is much smaller than that per unit area (μπι2) in the group. The number of islands. Specifically, the number of islands per unit area (〆) at the boundary may be equal to or less than 3/4, preferably 1 per island area (4) in the island group. /2. The decision on the area of the military is based on the border 54 and the island group 52〇, 5. Specifically, the unit area may be set to 1 μm 2 , but not in the specific embodiment disclosed in the present invention, the side core is formed into a radial shape, another garment shape, and one or more annular boundaries 17 201211594 _ = formed into concentric circles. The annular boundary can be continuous or discontinuous. The shape of the heart 5^ shape= is not particularly limited, as long as it can surround the core as a sector tooth & ^ ^ can have the shape of a cross section, a wheel, a waist triangle or an isosceles trapezoid. Another specific embodiment disclosed by fotf is 'the number of the plurality of island groups -' and the number of islands included in an island group is __2_. In the other case, the total number of the examples included in the birefringent island, / / Nakajima neighborhood is 2〇〇〇〇·3〇〇〇〇. In particular, one of the specific embodiments of the invention discloses that the electric island-like birefringent island-in-the-sea yarn of the island-in-the-sea yarn has two. The island group, each island / has 1,250 islands, and is included in the birefringence sea 25000. Because., 钿站丄八η...•The number of horse mouth 为 is 1〇_ $, according to the present disclosure, the birefringent sea bream yarn is preferably s or more, more preferably 20,000 or more, used for brightness Oh, the island can maximize the brightness improvement and prevent the wire from breaking. The diameter of the birefringent island-in-the-sea yarn disclosed herein is preferably 1 40 40. 1 〇〇 μπι, but is not limited thereto. Ιιη,更=说' As shown in the 2& figure, even if the number of islands exceeds that of Nassen: a birefringent island yarn with 1016 islands, in the case of 'the right island number 10_ or more, the island Condensed. Furthermore, as shown in Fig. 2 and Fig. 2d, when birefringence = hair is made into 80/24 (Danny/monofilament), and the composite yarn is woven into an island yarn, the weft yarn is produced, and the crack is generated. And the silk is, it will be warp or reversed. Thus, the enthalpy value defined by Equation 1 in the other embodiments of the present invention - the split wire and the island yarn is 500 or more. ^Birefringence In this case, 18 201211594 ^In the m-luminance enhancement of the single (four) and the yarn breakage will not be detected to avoid breaking the wire. As a result, the brightness of the film is weak and the brightness can be maintained evenly. s , , day can be avoided, [Equation 1] 数目 The number of islands of I monofilament / the number of monofilaments of composite filaments will be the same as the conventional 5 〇 double compound of 300 islands, ' Or a conventional 12-strand birefringence with 1G16 islands, or a composite. In this case, the A values are only 6 and 500 respectively. In contrast, the Mi Gu θ 丄 retreats a small Liang Le has 25,000 island 〇 strands) or 15 _ i W birefringent island yarn, the depreciation each become 25000 and the transport is greater than 500. Compared to the case when several strands are compounded, since the use of monofilaments significantly reduces the risk of fiber entanglement and rupture of monofilaments due to yarn breakage, we prefer to use birefringent island-in-the-sea yarns with an A value of 1000 or Above, 5〇0〇 or more, 10000 or more, or 20,000 or more. Preferably, a monofilament of birefringent island-in-the-sea yarn having 10,000 to 20,000 or more islands, or a composite yarn of about 2 strands, can be used to effectively avoid fiber entanglement and breakage of the monofilament. Fig. 5 is a view showing a specific embodiment of the axe according to the present invention, using a monofilament yarn having a sea-island yarn (having a 25-inch island portion) as a warp yarn. As shown in Fig. 5, yarn breakage does not occur in the birefringent island yarn. If the monofilaments with different numbers of islands are combined (for example, if 10 monofilaments with 300 islands and 10 monofilaments with 5 islands are compounded), the average number can be defined as a single Number of Silk Island Departments. In another embodiment of the present invention, the melting initiation temperature of the island portion of the birefringent island-in-the-sea yarn is higher than the melting temperature of the fiber and/or the sea portion. When 19 201211594 birefringent island yarns are merged as they are - a luminance enhancement film, the birefringence island can be easily moved (e.g., entangled) during, for example, lamination. Therefore, after the fabric including at least the birefringent island-in-the-sea yarn is woven, the fabric can be laminated between the substrates to repair the birefringent island-in-the-sea yarn. (4) If the birefringent island-in-the-sea yarn is incorporated into the brightness enhancement film into a fabric form, instead of being used as it is for the liquid crystal display, even if the fibers constituting the fabric are made of a transparent material, the fabric (fiber) is visible from the outside. Therefore, there is a limit to commercialization: Therefore, in order to solve such problems, the present invention provides a luminance enhancement film wherein the temperature of the birefringence island island is higher than the fiber melting temperature. I first - Fig. 5' details the weave included in the luminance enhancement film. Figure 5 is not shown to be useful in the fabrics disclosed herein. The fabric contains warp yarns and turns. Through the material, the spring is a yarn, and the shirt is a fiber. In other words, when a birefringent island-in-the-sea yarn is used as the weft yarn, the fiber is used as a warp yarn. And when the birefringent island-in-the-sea yarn is used as a warp yarn, the dimension is used as a turn. The fabric constituting the warp and warp yarns can be made of material to allow light to pass through. In the disclosed embodiment - the specific embodiment, the melting initiation temperature of the island portion of the birefringent island-in-the-sea yarn is higher than the melting temperature of the fiber. Therefore, when 敎 and / == are applied to the matrix stack, and the temperature is at the tempering temperature of the fiber and the island (4) melting initiation temperature (four), the island is still insoluble due to the lack of threat (4), but the fiber has been Part or all melted. Therefore, the fiber as the weft or warp yarn is formed in the lamination period (4) and becomes a part of the substrate. 201211594 minutes, only the birefringent island-in-the-sea yarn inside the obtained brightness enhancement film remains. The fiber I visibility problem can be significantly improved. Furthermore, due to melting of the fibers. But you can be an adhesive. The fabric can be adhered to the substrate without using an extra. Therefore, the Birefringence Island (4) Part A can have a melting fox having a hybrid starting temperature higher than ^. Specifically, the island portion of the birefringent island-in-the-sea yarn may have a temperature higher than or equal to or higher than the fiber melting temperature, more preferably, or from the beginning, and the melting initiation temperature of the island of the birefringent island may be high. The sea melting temperature is better for the island temperature of the island of birefringence island yarn; the temperature of the sea is higher than that of the sea. As a result, the birefringence sea can be partially or fully hybridized. In the specific embodiment disclosed in the present invention, the melting initiation temperature of the island portion of the refraction island yarn may be 13 (M3 〇 () c, and the refining temperature of the same fiber may be i (9) - 嫣., the sea portion of the birefringent island yarn The temperature can be 100-400 ° C, and the lamination temperature can be 42 〇. Unrestricted b The conclusion is that the melting temperature of the isotropic fiber used as the weft or warp of the fabric is lower than that used for Qing or The birefringence island yarn singulation starting temperature of the weft yarn is performed at a temperature between the melting temperature of the isotropic fiber initializing temperature and the island yarn, and the brightness enhancement film containing the fabric can solve the fiber visibility problem. This is because of the isotropic fiber or all the veins. Moreover, since the sea surface secret temperature of the birefringent island yarn is lower than the melting initiation temperature of the island, if the lamination is carried out at a temperature between the two , the sea part is either fully hybridized, and the layer is provided without the use of an additional adhesive. The matrix is described, and the matrix can be made of a thermoplastic or thermosetting polymer 21 201211594 'The required range of wavelength of the transferable light can be To allow light to be easily worn Transparent or translucent material. Specifically, the substrate may be amorphous or semi-crystalline, and may be a homopolymer, a copolymer or a mixture thereof. Specific examples include polycarbonate (pc); Polystyrene (PS); alkyl stupid ethylene; alkyl, aromatic or alicyclic (fluorenyl) acrylates, such as polyacrylic acid vinegar (PMMA) and PMMA copolymer; (fluorenyl) acrylic acid Ethyl ethoxide and propoxide; polyfunctional (fluorenyl) acrylate; acrylated epoxy resin; epoxy resin; other ethylenically unsaturated compound; cyclic olefin and cyclic olefin copolymer; acrylonitrile-butadiene-styrene (ABS); styrene acrylonitrile (SAN) copolymer; polyvinyl cyclohexane; PMMA/polyvinyl fluoride blend; polyphenylene ether alloy; styrene block copolymer; polyimine; Polyvinyl chloride; polydimethyl methoxy oxane (PDMS); polyamino phthalate; unsaturated polyester; polyethylene; polypropylene (PP); polyalkyl phthalate, such as polyethylene terephthalate Ester (PET); polyalkyl naphthalate's such as polyethylene naphthalate (PEN); polyamine; ionic polymer; Ester/polyethylene copolymer; cellulose acetate; cellulose acetate butyrate; fluoropolymer; polystyrene polyethylene copolymer; PET and PEN copolymers, such as polyolefin PET and PEN; and polycarbonate/fat Group PET blends. More specifically, polyethylene naphthalate (PEN), ethylene naphthalate copolymer (C0_peN), polyethylene terephthalate (PET), polycarbonate ( PC), polycarbonate (PC) alloy, polystyrene (PS), heat resistant polystyrene (PS), polydecyl methacrylate (PMMA), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), acrylonitrile-butadiene-styrene (ABS), polyamino phthalate (PU), polyimine (PI), polyethylene (PVC), styrene Acrylonitrile (SAN) Blend, Ethylene Vinyl Acetate 22 201211594 (EVA), Polydecylamine (PA), Polycondensation (P0M), Polymerization, Epoxy Resin (IV), Urea (UF), Melamine (_ ), unsaturated poly(up), shixi (9), elastomer and cyclomethine polymer (C〇P, Japan Z Co., Ltd. and Nippon Dish Co., Ltd.)' These can be used alone or in their Used in combination. More specifically, the substrate may be constructed of the same (four) material as the sea portion of the birefringent island-in-the-sea yarn. Furthermore, the substrate may also contain an additive as long as the additive does not cause deterioration of physical properties; such additives include, for example, an antioxidant, a light stabilizer, a lubricant, a dispersant, a uv absorber, and a white color. Pigments, and fluorescent brighteners. The matrix can be optically isotropic. In consideration of different physical properties, the constituents of the matrix or its optical properties may be selected to be the same as those of the sea and/or fiber. In this case, the matrix may be partially or completely melted during the lamination process, so that the adhesion between the birefringent island-in-the-sea yarn and the substrate can be improved about without using an additional adhesive. The matrix can comprise two layers. Specifically, the three layers may be formed to have a structure of a stack 4 including a surface layer, a core layer (layer A), and a surface layer (layer B) via coextrusion of a polymer. The skin layer corresponding to the fabric may have the same melting temperature as the sea portion and/or the fiber to adhere to the birefringent island yarn. The core layer may be made of a material having a higher melting temperature than the sea and/or fibers to prevent deformation of the substrate due to heat generated by the luminaire. Therefore, when the above-mentioned fabric is laminated between the three-layer sheets, the surface layer (A 1) / core layer (B1) / surface layer (A2) / fabric / surface layer (A3) / core layer (B2) / surface layer (A4) can be obtained. )Structure. When the surface layer has the same melting temperature as the sea and/or the fiber, the surface layer and the sea portion can be melted together so that the surface layer (A2, Λ 3) and the fabric layer become a layer. 23 201211594 Next 'Description can be used as fabric fiber, as long as it can be with, or! Yarn of yarn. Any temperature-related regulations may be given, y, woven to form a fabric and conform to the above. Specifically, when Kao Xiong, and for the fiber type, there is no limited weaving, the fiber can be optically perpendicular to the island of the island yarn. The way it is raw is modulated by the birefringent island yarn: Also a double-fold fiber. The fibers may be polymers, the antenna may not pass through the dimension, or a combination thereof. Moreover, the machine fiber (for example, the same material of the glass fiber portion. Further, f:, the fiber may be the sea bream with the birefringent island yarn), in the present invention, the η ii can be folded with the matrix: the rate yarn. The birefringence islands in the double-refraction island yarn, so that the optical modulation can change the effect of the county; the island money sea can have different optical flatness. More lies, the sex and the sea can be the same direction The ruler / body and & the island can be in the island yarn of the opposite direction, along the = to 1 including the optically isotropic sea and the anisotropic island degree or not "Meet 2: t::: refraction : In essence, the equal process proportionally increases the scattering efficiency of the factory with the square of the difference in refractive index. ί The polarization of the light along the axis will be smaller. (4) Scattering. When the refraction of a particular pumping part is equal to the refractive index of the island, regardless of the size and shape of the island's yarn, the incident light parallel to the axis may be crossed by the electric field, and may not pass the island. Scattering. More specifically, Figure 4 illustrates a cross-sectional view of the light passing through 24 201211594 birefringent island yarn. In this case, the P-wave (represented by the solid line) passes through the island-in-the-sea yarn without being affected by the interface between the outer and birefringent island-in-the-sea yarns and the interface between the island and the sea of the birefringent island yarn, and the 8 wave (with a dotted line) Representation) The interface between the substrate and the birefringent island yarn and/or the interface between the island and the sea of the birefringent island yarn is optically modulated. The above optical modulation phenomenon mainly occurs in the matrix and birefringent island yarn. The interface between the island and the sea between the birefringent island yarn and the sea. Specifically, when the matrix is optically isotropic, like ordinary birefringent fibers, optical modulation occurs in the matrix and birefringent island yarn. The interface between the two, more specifically, the difference in refractive index between the matrix and the island yarn may be 0.05 or less, and the difference in refractive index in the remaining one axis may be 〇 or more. S, assuming that the refractive indices of the matrix in the x_ and M ζ-axis directions are nxl, nY1, and ηζ, respectively, and the refractive indices of the birefringent island-in-the-sea yarns in the x_, y-, and ζ-axis directions are respectively ηΧ2, shame 2, and 2 , the matrix is in the direction of χ_, ^ and ζ_axis At least the rate of incidence may be the same as that of the birefringent island-in-the-sea yarn yarn, JnX2>nY2=nz2. Further, at the same time, in the birefringent island-in-the-sea yarn, the island portion and the sea portion may have different optical properties. Forming a birefringent interface. Specifically, when the island portion is anisotropic and the sea portion is isotropic, a birefringent interface can be formed at the boundary between the island portion and the sea portion. More specifically, the refractive index in the biaxial direction The difference may be 〇〇5 or less, and the difference in refractive index in the remaining -axis directions may be 〇1 or more. In this case, the P-wave passes through the birefringent interface of the island-in-the-sea yarn, and the s_wave is optically modulated. For a more detailed explanation, it is assumed that the refractive indices of the islands of the birefringent island yarn in the Χ-(longitudinal), y-, and Z_ axes are respectively n illusion, Μ, 25 201211594 and the sea is at χ·, y- And the refractive indices in the Z-axis direction are ηχ4, ηγ4, and ηΖ4', respectively, and at least one of the refractive indices of the matrix in the X-, y-, and Ζ-axis directions may be the same as those of the birefringent island-in-the-sea yarn. The absolute value of the difference between the refractive index nx3 and nx4 may be 〇. 1 or more. More specifically, the optical modulation efficiency can be maximized when the difference in refractive index between the sea portion and the island portion in the longitudinal direction of the island yarn is 0.1 or more and the refractive indices of the sea portion and the island portion are substantially equal in the remaining two axes. At the same time, when the matrix has the same refractive index as the sea portion of the birefringent island-in-the-sea yarn, the optical modulation efficiency can be easily improved. Therefore, in order to improve the optical modulation efficiency, a birefringent island-in-the-sea yarn having a large difference in refractive index between the island portion and the sea portion in the longitudinal direction and having substantially the same refractive index in the other two axes can be selected. The sea and/or island of the birefringent island yarn may be composed of polyethylene naphthalate (PEN), copolyethylene naphthalate (co-PEN), polyethylene terephthalate (ΙΈΤ), poly Carbonate (pc), polycarbonate (PC) alloy, polystyrene (PS), heat resistant polystyrene (PS), polydecyl methacrylate (PMMA), polybutylene terephthalate (PBT) , Polypropylene (PP), Polyethylene (PE), Acrylonitrile Butadiene Styrene (ABS), Polyurethane (PU), Polyimine (PI), Polyvinyl Chloride (PVC) ), styrene acrylonitrile (SAN) blend, ethylene vinyl acetate (EVA), polydecylamine (PA), polyacetal (POM), polyphenol, epoxy resin (EP), urea (UF) Made of melamine (MF), unsaturated polyester (UP), bismuth (SI), elastomer and cyclic olefin polymers, and combinations thereof. Specifically, in view of an effective increase in optical modulation, a material having an island portion and a sea portion having substantially the same refractive index on both axes but having a large difference in refractive index on one axis can be selected. However, more specifically, when polyethylene naphthalate (PEN) is used as the material of the island of the island of the birefringent sea 26 201211594, and the copolymer of ethylene naphthalate or polycarbonate is used. When it is used as a material for the sea, it can greatly enhance the brightness compared to the birefringent island yarn made of common materials. Particularly when a bismuth alloy is used as the sea portion, a birefringent island-in-the-sea yarn having the most excellent optical modulation properties can be prepared. In this case, the polycarbonate alloy preferably includes at least a polynuclear&L ester and a modified polyparaxylcyclohexyl dimethylene glycol (PCTG). More specifically, at least a polycarbonate and a modified poly-p-cyclohexylene dimethyl dimethyl diol (pcTG) are used and the weight ratio of the two is 15.85 to 85:15. A polycarbonate alloy which can effectively enhance the glow, and when the amount of the field carbonate is less than 15%, the spinning effect is excessively increased: the viscosity of the polymer is determined, and the disadvantage of the spinning machine cannot be used. When the amount of the field of the carbon (4) exceeds 85%, the glass transfer/magnification increases and the spinning tension increases after the nozzle is ejected, so it becomes difficult to ensure the spinning performance. And a modified poly(p-citric acid) cyclohexylmonomethylene glycol diol (PCTG) and a weight ratio of 4: ό to 聚碳酸酯. 4 of the polycarbonate alloy, which can effectively enhance the brightness. Further, in view of the efficiency improvement of the optical modulation efficiency, it is preferable that the sea portion of the island material has a large difference in the longitudinal refractive index and a substantially the same refractive index in the other two axes. Methods for upgrading isotropic materials to birefringent materials are well known in the art. For example, polymer molecules can be oriented so that when stretched at the appropriate temperature conditions, they will become birefringent. The birefringent island-in-the-sea yarn disclosed in the present invention can be produced, for example, by co-extrusion, but is not limited thereto. Therefore, it is known that the island yarn only uses the 27 201211594 island portion left after melting the sea portion as the fine fiber, and the island-in-the-sea yarn contains at least the heart-shaped shot, but the present invention discloses that the sea portion having the substitute dazzling island yarn has the raw material. The sea and the islands are directional, while the seas are the same as the sympathy. However, the opposite case is also optional. The island and the optical modulation efficiency of the birefringent island-in-the-sea yarn are maximized. The surface has a different optical property and is used for optical modulation. To this end, the number of islands should be increased. Specifically, light 1 22 is greater than 500. However, in the known island-in-the-sea yarn, even if the island portion is a child, 0 and the sea portion is optically isotropic, when the number of island portions exceeds 50 C', the island portion tends to aggregate. As a result, the optical modulation interface area is reduced and the photon modulation efficiency is lowered. In contrast, the birefringent island-in-the-sea yarn disclosed in the present invention is capable of preventing agglomeration of islands. As a result, the optical modulation efficiency of the island yarn is maximized, and according to the present invention, when the birefringent island-in-the-sea yarn is used as the luminance enhancement lining, the luminance of the optical modulation efficiency and the luminance increase is as follows, and can be made extremely large. Improvement. In one embodiment of the present disclosure, the brightness enhancement film disclosed herein may have a structured surface layer. More specifically, the structured surface layer can be formed on the side of the emitted light. The structured surface layer can be in the form of a 稜鏡, lenticular lens or a convex lens. More specifically, a curved surface in the form of a convex lens may be provided on the side of the light emitted from the luminance enhancement film. The surface can be spotted or defocused through the light from the surface. Further, the surface of the emitted light may have a prismatic pattern. Next, the method of manufacturing the birefringent island-in-the-sea yarn disclosed in the present invention 28 201211594 will be explained. These birefringent island-in-the-sea yarns can be produced by any method generally used for the production of island-in-the-sea yarns, and are not particularly limited. Any spinner or spinning nozzle can be used without limiting its shape as long as it can produce a birefringent island-in-the-sea yarn. In general, the spun or spinning nozzle used may have substantially the same shape as the island configuration pattern seen from the birefringent sea island yarn profile. Specifically, any spinning nozzle can be used as long as it can prepare an island-in-the-sea yarn by combining an island portion extruded from a hollow pin or a spinning nozzle with a sea portion supplied from a passage. Wherein the hollow plug or the spinning nozzle is partitioned by the "field", and the channel is partially partitioned, and the channel is designed to fill the space therebetween; and extruded through a discharge port which gradually narrows the combined flow The set of mouth machines forms an island yarn having two or more spinning cores. A specific example of a suitable spinning nozzle is shown in Fig. 6, but the spinning nozzle which can be used in the present invention is not limited thereto. Figure 6 is a cross-sectional view showing an upper distribution plate for preparing a spun yarn of a island-in-the-sea yarn in accordance with a specific embodiment of the present invention. The upper distribution plate comprises at least: a core 121 which forms a heart and prevents agglutination, and a plurality of island supply units 123, 124 which are around the core 121 and are provided with a plurality of island supply channels 122. In the meantime, several seas are formed. (5 The supply unit 125 is formed along the outer circumference of the island supply units in, 124, and has a plurality of sea supply passages in its towel. Korean Patent Application No. 1〇-2〇1〇_0〇27670 is incorporated herein. For reference, the spinning nozzle for the birefringent island-in-the-sea yarn of the present invention includes the above-mentioned upper distribution plate which may be different from the characteristics of the island-in-the-sea yarn according to the desired shape. The upper distribution plate is arranged in the upper part. Thereafter, the spinneret having the funnel shape 1 can be arranged in the lower portion as the discharge port of the island yarn. Meanwhile, as shown in the figure 29 201211594, the lower spinner plate 130 includes the flow passages 52, 53' to supply the unit from the island. The polymer material supplied by the jellyfish supply unit can flow to a row of outlets 131. Depending on the structure of the nozzle, the number and shape of the flow passages 132, 133 can be differently designed. The discharge port 131 can be arranged in accordance with the flow path. Furthermore, an additional distribution plate may be disposed above and/or below the upper distribution plate to promote the distribution and mixing of the island portion and the sea portion. Next, a method for preparing the brightness enhancement film disclosed in the present invention will be described. Above, in use After the island yarn is refracted so that the fabric is woven, the fabric can be disposed between the substrates and thereafter laminated. Specifically, the substrate has a two-layer structure of a surface layer/core layer/surface layer. When laminated, a surface layer can be formed (A丨) / core layer (B) / surface layer (A2) / fabric layer (〇 / surface layer (A3) / core layer (B2) / surface layer (A4) a total of seven layers. As mentioned above, if adjacent to the fabric layer A2, A3 Having the same melting temperature as the sea portion of the birefringent island-in-the-sea yarn and the fiber, these may be partially or completely melted. The lamination may be carried out by, for example, a winding or hot pressing procedure. In this case, in order to prevent foaming, vacuum may be applied. The hot pressing is performed in the state, so that the adhesion force and the luminance can be improved. Specifically, the degree of vacuum during hot pressing can be 5 to 500 Torr, and the applied pressure can be i.〇_i〇〇kgf/cm2, and the processing time It can be 1-30 minutes. As detailed above, the lamination temperature can be selected between the melting initiation temperature of the island of the birefringent island yarn and the melting temperature of the fiber and/or sea portion. When the degree of vacuum is less than 5牦The process efficiency is not satisfactory. When it is more than 500 Torr, the defoaming is not sufficient. When the applied pressure is lower than lokgfycm2, the adhesion of the film is not sufficient, and when the pressure exceeds l〇〇kgf/cm2, the fiber arrangement is interrupted due to excessive pressure. When the treatment time is less than i minutes, defoaming and then insufficient And when the processing time exceeds 30 minutes, 201211594 'the process efficiency is not satisfactory. · The brightness enhancement film disclosed in the invention can be widely used in flat panel displays, including LCD, LED TV, projection display, plasma display, field The present invention is described by way of example only, and is not intended to limit the scope of the invention. <Example 1> As a sea portion (11^1.57, 1¥=1.57, 112=1.57, melting temperature=145〇〇:), an isotropic polycarbonate (PC) alloy including pc and modified PCTG, the ratio is 5:5, and the island system uses an anisotropy ρΕΝ (ηχ=188, %=1.57, ηζ=1.57, melting initiation temperature=262〇c). In order to obtain a birefringent island-in-the-sea yarn having a cross-section as shown in Fig. 3, the materials are supplied to a --spinning nozzle which has a distribution plate on top of 12 island supply units as shown in Fig. 6, and has Figure 7 shows the lower (four) plate with a row of outlets. A birefringent island-in-the-sea yarn having a cross section as shown in Fig. 3 (monofilament, number of islands = 25040, diameter = 66 5 μmη) was prepared. After preparing a partially oriented yarn (ρ〇γ, 85 denier/1 monofilament at a spinning rate of 2500 '), the crucible was stretched at 140 ° C to prepare fy (4 〇 Danny eight using the birefringent island yarn thus prepared) (monofilament, 4 inch Danny eight monofilament as warp yarn, and the same isotropic sea 之 alloy fiber _ temperature =, drive G Danny / 24 monofilament) as a special woven fabric. 201211594 ceremony; 5 map It is shown that the surface of the fabric prepared in Example 1 can be observed as a birefringent island-in-the-sea yarn used as a warp yarn without yarn breakage. 0 Comparative Example 1> including PC and pCTG ratio of 5:5 The isotropic π alloy is used as the sea portion (ηχ eat 57, ny=1.57, nz=l 57, refining temperature = 145. 〇, and anisotropic PEN (nx=l 88, η=]57 _ ny 1· 57, η ζ = 157, melting initiation temperature = 262 ° C) is used as an island portion. In order to obtain a birefringent island-in-the-sea yarn having a cross section as shown in Fig. 2a, the materials are supplied to (d), which has a pattern as shown in Fig. 2b. The distribution plate is shown above. It is prepared to have a birefringent birefringent yarn (the monofilament, the number of islands is 1016 'straight skills' (four) as in the 5th. In the spinning speed _ 2·na% and spinning After preparing ρ〇γ (85 denier/12 monofilament) at a yarn degree of 290 C, ρ〇γ was stretched 2·1 times at 14〇〇c to prepare FY (40 denier/12 monofilament). Two strands of birefringent island-in-the-sea yarn FY40/12 of 80 Danny/24 monofilaments were used as warp yarns, and the same isotropic pc alloy fiber as the sea portion was used (melting temperature = 145. (:, ρ〇γ 6〇/24 ) weave the fabric as a weft yarn.

第2c圖所示係在比較例丨中所製備之織物表面的SEM 影像。吾人可觀察到在作為經紗的雙折射海島紗發生紗斷 裂。 由於本發明揭示之輝度增強膜顯示優異的先學調變效 應,其可廣泛使用於光學裝置,例如照相機及需要高亮度 之LCD裝置,例如行動電話、LCD、LEDTv等。 32 201211594 本發明揭示内容就具體實施例而言已做描述,在不偏 離下述申料·_界定树精神及 發明可做不同之變更與修改,對熟悉該項技藝人士明顯可 【圖式簡單說明】 本發明揭示之上述及其他標的、特徵及優點,由 =同附圖所提供之-些飾性具财關的描述為明顯可 第la圖係習知輝度增強膜原理示意圖; 第lb圖係習知雙折射海島紗之刮面圖; 第2a圖係雙折射海島紗的剖面圖;第㉛目係 備第2a圖雙折射海島紗之紡嘴的上分配板;第〜圖 ^圖係包含第2a圖之雙折射海島紗織物之電子顯微鏡影 海島紗 海島紗剖 第3圖係根據本發明揭示之特定具體實施例 剖面之電子顯微鏡影像; 第4圖係根據本發明揭示特定具體實施例, 面之電子顯微鏡影像; 第5圖係根據本發明揭示特定具體實施例, 島紗之織物,用於根據本發明揭示之—輝度增_广―海 、第6圖係根據本發明揭示之特定具體例,用以 海島、、y、之紡嘴的上分配板的剖面圖;以及 備 第 7圖係根據本發明揭示特定具體例, 用以製備一海 33 201211594 島紗之紡嘴的下板剖面圖。 吾人應瞭解附圖並不需要按照比例,提出稍簡略化的 不同較佳特徵的代表例已足以說明本發明揭示之基本原理 。如在此所揭示之本發明揭示内容的特定設計特徵,其包 含例如特定尺度、方向性、位置及形狀,將藉由特定意欲 的應用及使用環境來做某種程度的決定。 在圖中,參考數字係表示揭示内容遍及附圖之數種圖 形中之相同或等值部分。 【主要元件符號說明】 11 紡紗核心 12 島部 20 聚合物射出單元 60 織物 61 雙折射海島紗 62 同向性纖維 120 上分配板 121 核心 122 島部供給通道 123 島部供給單元 124 島部供給單元 125 海部供給單元 130 下紡嘴板 131 排出口 34 201211594 132 、 133 流道 510 核心 520 、 530 島部群 540 邊界 A、B、C 紗斷裂Figure 2c shows the SEM image of the surface of the fabric prepared in the comparative example. It has been observed that yarn breakage occurs in the birefringent island yarn as warp yarn. Since the luminance enhancement film disclosed in the present invention exhibits an excellent prior tone modulation effect, it can be widely used in optical devices such as a camera and an LCD device requiring high brightness such as a mobile phone, an LCD, an LEDTv, and the like. 32 201211594 The disclosure of the present invention has been described in terms of specific embodiments, and various changes and modifications may be made without departing from the following claims. The spirit of the tree and the invention may be changed to those skilled in the art. The above and other objects, features and advantages of the present invention are disclosed in the accompanying drawings. The scraped surface of the conventional birefringent island yarn; the second drawing is a sectional view of the birefringent island-in-the-sea yarn; the 31st is the upper distribution plate of the spinning nozzle of the birefringent island yarn of the second drawing; An electron microscope image of a birefringent island-in-the-sea yarn fabric comprising a second embodiment of Fig. 2a is an electron microscope image of a cross section of a specific embodiment according to the present invention; and Fig. 4 is a specific embodiment according to the present invention. , an electron microscope image of a face; FIG. 5 is a fabric of island yarn according to a specific embodiment of the present invention, for use in the light of the present invention - the brightness increase _ wide sea, the sixth figure is according to the present invention A specific cross-sectional view of the upper distribution plate for the island, y, and the spinning nozzle; and a seventh embodiment for producing a sea 33, the opening of the island yarn of the 201211594 island yarn according to the present invention The lower plate section view. It should be understood that the appended drawings are not necessarily to Specific design features of the present disclosure as disclosed herein, including, for example, particular dimensions, directionality, location, and shape, are to be determined to some extent by the particular intended application and use. In the figures, reference numerals indicate the same or equivalent parts of the various figures in the drawings. [Description of main components] 11 Spinning core 12 Island 20 Polymer injection unit 60 Fabric 61 Birefringent island yarn 62 Isotactic fiber 120 Upper distribution plate 121 Core 122 Island supply passage 123 Island supply unit 124 Island supply Unit 125 Sea Supply Unit 130 Lower Spinner Plate 131 Discharge Port 34 201211594 132 , 133 Flow Path 510 Core 520 , 530 Island Group 540 Boundary A, B, C Yarn Break

Claims (1)

201211594 七、申請專利範圍: 1. 一種輝度增強膜,其至少包含: 一基質;及 一雙折射海島紗,其位於基質中,其中在雙折射海島 紗之島部與海部間之邊界形成雙折射介面,以誘導光學調 變,且雙折射海島紗包含:一核心,用以防止島凝集;及 一複數島部群,其環繞該核心形成為輻射狀。 2. 如申請專利範圍第1項所述之輝度增強膜,其中在島部群 之間形成邊界,以使在邊界之每單位面積(μπι2)之島部數 目小於鄰近島部群中每單位面積(μιη2)之島部數目,且鄰 近島部群被邊界所分隔。 3. 如申請專利範圍第2項所述之輝度增強膜,其中該邊界係 壞繞該核心成為輕射狀。 4. 如申請專利範圍第1項所述之輝度增強膜,其中在該核心 之每單位面積(μιη2)之島部數目,較島部群之每單位面積 (μπι2)之島部數目為小。 5. 如申請專利範圍第4項所述之輝度增強膜,其中在該核心 每單位面積(μιη2)之島部數目較島部群中每單位面積(μιη2) 之島部數目為等於或小於1/2或1/3。 6. 如申請專利範圍第3項所述之輝度增強膜,其中該邊界環 繞該核心,以複數形成為環形狀。 7. 如申請專利範圍第1項所述之輝度增強膜,其中該島部群 具有剖面之形狀為扇形齒輪、等腰三角形或等腰梯形。 8. 如申請專利範圍第1項所述之輝度增強膜,其中複數個島 36 201211594 部群之數目為10·5〇, 800-2000。 且匕&於一島部群之島部數目為 9.如申請專利範圍第1 折射海島紗之島部的、述之輝度增強膜,其中包含於雙 -如申請專利^第=嶋議^ 每單位面積(_2)之;!=之輝度增強膜,其中在邊界 一之島部數目係等島 Η·如申請專利範J或小於3/4或1/2。 海島紗具有度增強膜,其中雙析射 [方程幻] 斤疋義的八值為500或以上: 如申複合絲之單絲數目。 海島紗被編織成織物,:::度增強膜’其中雙折射 海島紗,另-為::。緯紗與經紗之-為雙折射 13.如申請專利範圍第丨 14 =部之―度高於雙折射 .海述之輝度增,其”折射 .如申料·圍第12項麟之 :島紗之島部為光學異向性,且海部二為= 16.ΓΠ::範圍第12項之輝度增強膜,其中纖維係選自 ::口物纖維,自然纖維及無機纖維所組成群組中之一 種或多種纖維。 37 201211594 17·如申請專利範圍第12項所述之輝度增強膜,其中雙折射 海島紗之島部的熔化起始溫度係高於海部的熔化溫度。 18.如申請專利範圍第12項所述之輝度增強膜,其中雙折射 海島紗之島部的熔化起始溫度較纖維的熔化溫度高3〇〇c 或以上。 19. 如申π專利&圍第12項所述之輝度增強膜,其中雙折射 海島々、之島部之炫化起始溫度較海部之熔化溫度高 或以上。 20. 如申請專利範圍第12項所述之輝度增強膜,其中纖維為 部分或完全熔化。 儿如申請專利範圍第、項所述之輝度增賴,其中基質與 雙折射海島》間在二軸方向之折射率差為_或以 下’且基質與雙折射海島紗間在剩餘—軸方向之折射率 差為0.1或以上。 22. 如申請專利範圍第1項所述之輝度增強膜,其中雙折射 海島紗之海部與島部在二軸方向之折射率差0 05或以 下,且雙折射海島紗之海部與島邹在剩餘—軸方向之折 射率差0.1或以上。 23. 如申請專利範圍第1項所述之輝度增強臈,其中雙折射 海島紗直徑為1〇_1〇〇μηι。 38201211594 VII. Patent application scope: 1. A brightness enhancement film comprising: at least: a substrate; and a birefringent island-in-the-sea yarn, which is located in a matrix, wherein birefringence is formed at a boundary between the island portion of the birefringent island yarn and the sea portion The interface is to induce optical modulation, and the birefringent island-in-the-sea yarn comprises: a core for preventing island agglutination; and a plurality of island groups surrounding the core to form a radial shape. 2. The brightness enhancement film of claim 1, wherein a boundary is formed between the group of islands such that the number of islands per unit area (μπι2) at the boundary is smaller than the area per unit area of the adjacent island group. The number of islands (μιη2), and the adjacent island group is separated by boundaries. 3. The brightness enhancement film of claim 2, wherein the boundary is broken around the core to become a light shot. 4. The brightness enhancement film according to claim 1, wherein the number of islands per unit area (μιη2) of the core is smaller than the number of islands per unit area (μπι2) of the island group. 5. The luminance enhancement film according to item 4 of the patent application, wherein the number of islands per unit area (μιη2) of the core is equal to or smaller than the number of islands per unit area (μιη2) in the island group. /2 or 1/3. 6. The brightness enhancement film of claim 3, wherein the boundary surrounds the core and is formed in a ring shape in plural. 7. The brightness enhancement film of claim 1, wherein the island group has a cross-sectional shape of a sector gear, an isosceles triangle or an isosceles trapezoid. 8. For the brightness enhancement film described in item 1 of the patent application, the number of the plurality of islands 36 201211594 is 10.5〇, 800-2000. And the number of islands in the island of the island is 9. The patented range is the first to refract the island of the island, and the brightness enhancement film is included in the double-application patent ^ Brightness enhancement film per unit area (_2); !=, where the number of islands at the boundary is the same as that of the island, such as the patent application J or less than 3/4 or 1/2. The island yarn has a degree-enhancing film, in which the double-ejection [Equation Magic] has an eight value of 500 or more: such as the number of monofilaments of the composite yarn. The island yarn is woven into a fabric, a :: degree reinforced film 'where birefringent island yarn, another - is::. The weft and warp yarns are birefringent. 13. If the scope of application is 丨14 = the degree of the part is higher than the birefringence. The brightness of the sea is increased, and its "refraction. For example, the 12th item of the material, the lining: the island yarn The island is optically anisotropic, and the sea part is = 16.ΓΠ:: the brightness enhancement film of the 12th item, wherein the fiber is selected from the group consisting of: mouth fiber, natural fiber and inorganic fiber. 37. The brightness enhancement film according to claim 12, wherein the melting initiation temperature of the island portion of the birefringent island-in-the-sea yarn is higher than the melting temperature of the sea portion. The brightness enhancement film according to Item 12, wherein the melting initiation temperature of the island portion of the birefringent island-in-the-sea yarn is higher than the melting temperature of the fiber by 3 〇〇 c or more. 19. As described in claim π Patent & The brightness enhancement film, wherein the luminescence initiation temperature of the island of the birefringent island is higher or higher than the melting temperature of the sea portion. 20. The brightness enhancement film according to claim 12, wherein the fiber is partially or Completely melted. The brightness increase according to the item, wherein the difference in refractive index between the matrix and the birefringent island in the biaxial direction is _ or less' and the refractive index difference between the matrix and the birefringent island-in-the-sea yarn in the residual-axis direction is 0.1 or more 22. The brightness enhancement film according to claim 1, wherein the sea portion and the island portion of the birefringent island-in-the-sea yarn have a refractive index difference of 0 05 or less in the biaxial direction, and the sea portion and the island of the birefringent island yarn are used. The difference in refractive index in the residual-axis direction is 0.1 or more. 23. The brightness enhancement enthalpy of claim 1, wherein the birefringent island-in-the-sea yarn has a diameter of 1 〇_1 〇〇 μηι.
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