201210979 六、發明說明： 【發明所屬之技術領域】 本發明是有關於一種混凝土用漿料，特別是指一種混 凝土用的鹼活化漿料。 【先前技術】 近年來由於工業及都市發展快速，因此排放出大量的 一氧化碳’大量排放的二氧化碳因為無法被海洋與森林吸 收而會積存在大氣層中’而大氣層中二氧化碳積留越多， 氣溫增加就越多；氣溫增加越多，留在大氣層中的二氧化 碳就越多’這就形成了惡性循環，導致了地球環境的汙染 及溫室效應日趨嚴重；其中，二氧化碳排放的最大產生工 業，除了煉鋼、燃煤發電之外，最重要的就是水泥業。 水泥是台灣建設和經濟發展的重要產業，但是傳統水 泥漿料需要以碳酸鈣經過高溫燒製後再配置而得，在生產 過程中不僅會消耗大量的能源，同時也會產生大量的二氧 化碳；一般估計生產1公嘲水泥會排放880公斤的二氧化 碳’右以台灣母年的水泥生產量約為2，0 0 0萬公嘲計算，則 台灣每年因生產水泥所產生的二氧化碳量高達1600萬公嘲 以上’而自2 0 0 5年初『京都協議書』生效後，溫室氣體減 量的議題正式進.入具國際法律約束力的新階段，我國雖非 議定書簽署國，但是我國溫室氣體排放總量世界排名第22 名’占全世界近1%，所以，如何積極的減少各項產業的溫 室氣體排放量，則為目前重要的環保課題之一。 因此，如何開發可以取代傳統水泥漿料，且在生產過 201210979 程中不會消耗大量的能源，同時也不會產生二氧化碳的新 材料，在工業科技發展的同時，也盡力降低因科技發展對 地球環境所造成的污染和傷害，實為此技術領域者持續努 力開發的重要課題。 【發明内容】 因此，本發明之目的，即在提供一種含有鹼活化液及 無機粉體的鹼活化漿料。 於是，本發明一種鹼活化漿料，包含：無機粉體及鹼 活化液，其中，該無機粉體包括矽酸鹽類化合物，該鹼活 化液的二氧化矽與金屬氧化物的莫耳比值介於0.25〜0.5，且 二氧化矽與三氧化二鋁的莫耳比值介於2〇〜1〇〇之間。 本發明之功效在於：利用經由驗活化後之無機粉體製 得的漿料作為黏結材料，不僅可單獨供補強材料或防火材 料使用，也可在添加㉟量的粗、細骨材後形成砂聚或混凝 土，取代傳統水泥漿料，供營建材料使用。 【實施方式】 <發明詳細說明> 有關本發明之前述及其他技術内容、特點與功效，在 以下配合一個較佳實施例的詳細說明中，將可清楚的呈 現。 本發明驗活化漿料的該較佳實施例包含：無機粉體， 及鹼活化液。 該無機粉體是選自石夕酸鹽化合物，較佳&，該無機粉 體是可選自非晶質石夕酸鹽化合物，適用於本發明該佳實施 201210979 例的無機粉體包括玻璃，例如.^ 1夕J如.破璃粉、廢玻璃、玻璃纖 維、飛灰’例如：燃煤飛灰、.嫉、度& — _ A燃煤底灰、焚化飛灰、焚化 底灰、火山灰、黏土、各類爐渣、熔渣、各類廢土及於泥 等石夕酸鹽化合物，且可以單-或複合方式混合使用。 該鹼活化液是由鹼活化劑與水混合後而得，其中，該 驗活化劑是選自驗金屬盏盏#札 „ a,風虱化物、鹼金屬矽酸鹽、矽酸 膠，或其中一組合，及鹼金屬鋁酸鹽、鋁粉，或其中一組 合配製而得，且該驗活化液之三氧化石夕與驗金屬氧化物的 莫耳比值（SiCMMA，Μ為鹼金屬元素）介於〇 25〜〇 5，二氧 化矽與二氧化二鋁的莫耳比值（SiOVALOj介於2〇〜1〇〇之 間，較佳地，適用於本發明該較佳實施例的鹼金屬鋁酸鹽 是選自鋁酸鈉或鋁酸鉀，該鹼金屬氫氧化物及鹼金屬矽酸 鹽是選自矽酸鈉、矽酸鉀、及氫氧化鈉、氫氧化鉀。 由於在常溫下，水、酸、鹼和鹽類等物質，只有鹼對 石夕酸鹽物質的網狀結構具有直接的破壞作用；驗性越強、 溫度越高，越易造成矽酸鹽網狀結構的斷鏈。一般來說， 結晶物質的活性較低，而非晶物質因結構不完整，所以活 性較高，為了有效地使晶質或非晶質矽酸鹽產生化學活 性’必須以高鹼性溶液破壞Si-0-Si及/或Si-〇-Al網狀結 構，使顆粒表面網狀聚集體解聚、瓦解，形成矽氧四面 體、鋁氧四面體之單體或雙聚體等活性物，造成其化學活 性提升’而此等Si04、Al〇4四面體則會再度經過脫水、縮 合、硬化等過程，重新聚合鍵結而形成膠結材料。 然而，當高鹼性溶液自矽酸鹽表面溶解出之Si04、 201210979201210979 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a slurry for concrete, and more particularly to an alkali-activated slurry for concrete. [Prior Art] In recent years, due to the rapid development of industry and urban areas, a large amount of carbon monoxide is emitted. 'The large amount of carbon dioxide emitted is accumulated in the atmosphere because it cannot be absorbed by the ocean and forests', and the more carbon dioxide is accumulated in the atmosphere, the temperature increases. The more the temperature increases, the more carbon dioxide remains in the atmosphere. This creates a vicious circle, which causes the pollution of the global environment and the greenhouse effect to become more serious. Among them, the largest producer of carbon dioxide emissions, in addition to steelmaking, In addition to coal-fired power generation, the most important thing is the cement industry. Cement is an important industry in Taiwan's construction and economic development. However, traditional cement slurry needs to be prepared after high-temperature firing of calcium carbonate. In the production process, not only a large amount of energy is consumed, but also a large amount of carbon dioxide is generated; It is estimated that the production of 1 public cement will emit 880 kilograms of carbon dioxide. 'The right amount of cement produced in Taiwan’s mother year is about 2 million. The annual amount of carbon dioxide produced by Taiwan’s cement production is as high as 16 million. After the 'Kyoto Agreement' came into effect in early 2005, the issue of greenhouse gas reduction was officially entered. It entered a new stage of international legal binding. Although China is not a signatory to the protocol, China’s total greenhouse gas emissions are in the world. Ranked 22nd, 'accounting for nearly 1% of the world, so how to actively reduce greenhouse gas emissions in various industries is one of the most important environmental issues. Therefore, how to develop new materials that can replace traditional cement slurry and not consume a lot of energy in the process of production 201210979, and will not produce carbon dioxide, while developing industrial technology, also try to reduce the development of technology due to the earth. The pollution and damage caused by the environment is an important issue that continues to be developed by the technical field. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide an alkali-activated slurry containing an alkali-activated liquid and an inorganic powder. Thus, an alkali-activated slurry of the present invention comprises: an inorganic powder and an alkali-activated liquid, wherein the inorganic powder comprises a phthalate compound, and the molar ratio of the cerium oxide to the metal oxide of the alkali-activated liquid is It is between 0.25 and 0.5, and the molar ratio of cerium oxide to aluminum oxide is between 2 〇 and 1 〇〇. The utility model has the advantages that the slurry obtained by the inorganic powder system after the activation is used as the bonding material, and the reinforcing material or the fireproof material can be used alone, or the sand can be formed after adding 35 kinds of coarse and fine aggregates. Poly or concrete, replacing traditional cement slurry for construction materials. [Embodiment] The above and other technical contents, features and effects of the present invention will be apparent from the following detailed description of the preferred embodiments. The preferred embodiment of the activated slurry of the present invention comprises: an inorganic powder, and an alkali activating solution. The inorganic powder is selected from the group consisting of a silicate compound, preferably &, and the inorganic powder is selected from the group consisting of amorphous oxalate compounds, and is suitable for use in the present invention. The inorganic powder of the preferred embodiment 201210979 includes glass. For example, ^1 夕J, such as broken glass, waste glass, fiberglass, fly ash, for example: coal-fired fly ash, 嫉, degree & - _ A coal-burning bottom ash, incinerated fly ash, incinerated bottom ash , volcanic ash, clay, all kinds of slag, slag, all kinds of waste soil and mud and other compound compounds, and can be used in a single- or composite way. The alkali activating liquid is obtained by mixing an alkali activator with water, wherein the activator is selected from the group consisting of metal 盏盏#, a cockroach, an alkali metal silicate, a phthalic acid glue, or a combination, and an alkali metal aluminate, aluminum powder, or a combination of one of them, and the molar ratio of the metal oxide of the test solution to the metal oxide (SiCMMA, Μ is an alkali metal element) 〇25~〇5, the molar ratio of cerium oxide to aluminum oxide (SiOVALOj is between 2 〇 and 1 〇〇, preferably, suitable for the alkali metal aluminate of the preferred embodiment of the present invention The salt is selected from sodium aluminate or potassium aluminate, and the alkali metal hydroxide and alkali metal silicate are selected from the group consisting of sodium citrate, potassium citrate, and sodium hydroxide and potassium hydroxide. Acid, alkali and salt, etc., only the base has a direct destructive effect on the network structure of the cerium salt material; the stronger the testability and the higher the temperature, the more likely the chain cleavage of the citrate network structure is caused. In general, the activity of crystalline materials is low, while amorphous materials are highly active due to incomplete structure. In order to effectively chemically activate crystalline or amorphous citrates, the Si-0-Si and/or Si-〇-Al network structure must be destroyed by a highly alkaline solution to deagglomerate the network surface aggregates. Disintegrating, forming an active substance such as a helium tetrahedron or an aluminoxy tetrahedron monomer or a dimer, causing an increase in its chemical activity, and such Si04, Al〇4 tetrahedrons are again subjected to dehydration, condensation, hardening, etc. Process, re-aggregation bonding to form a cementitious material. However, when the highly alkaline solution is dissolved from the surface of the niobate, Si04, 201210979
Al〇4單體若數量太少，則膠結材料會因結構不完整而造成 強度不足，因此，本發明除了以鹼金屬氫氧化物、鹼金屬 矽酸鹽’及/或矽酸膠控制鹼活化液的鹼性之外，並進一步 藉由鹼金屬鋁酸鹽或鋁粉調控鹼活化液的鋁含量，依照實 際情形補足所需的Al〇4單體，如此不僅可彌補高鹼性溶液 自無機粉體表面溶解出之Aio4單體數量不足的缺點’且者 田 無機粉體是使用一般不含鋁之矽酸鹽類化合物或鋁含量極 低之石夕酸鹽類化合物時，例如玻璃，也可正常使用，不僅 可藉由鋁的添加使膠結材料結構更完整進而增強其強度， 且不受限於使用之材料種類，而可有更廣泛的材料選擇。 要說明的是’當驗性（M2〇)過高時，會在由該漿料製得 的成品的表面形成由鹼金屬與空氣中的水氣和二氧化碳反 應而形成的重碳酸鈉結晶物質（俗稱白華），且會因驗性過高 反而會破壞形成之鍵結而造成強度降低；而當鹼性不足 時’則反應性過低，由該漿料製得的成品強度不足因 此，較佳地，該鹼活化液之二氧化矽與鹼金屬氧化物的莫 耳比值（Si02/M20)介於0.375〜0.5，二氧化矽與三氧化二紹 的莫耳比值（SiCMAhO3)介於20〜80之間；更佳地，該驗活 化液之二氧化矽與鹼金屬氧化物的莫耳比值（Si〇2/M2〇)介於 0.375〜0.5 ’且一氧化石夕與三氧化二紹的莫耳比值 (Si02/Al203)介於 40-60 之間。 此外’要再說明的是’當該鹼活化漿料的黏度過低 時’則流動性過高，而容易於使用過程中因自重而引起垂 流現象，黏度過高時則容易造成驗活化裂體授拌不易，而 201210979 使鹼活化反應不完全’因此’較佳地，該鹼活化液與無機 粉體的重量比值（以下簡稱液/固比）是介於1〜0.5之間，更佳 地，該驗活化液與無機粉體的液/固比是介於i〜〇 67之間， 且該鹼活化漿料的黏度為10,000〜60,000 mpas。 當利用該鹼活化漿料進一步與粗、細骨材混合形成砂 漿或混凝土時’即可供營建材料使用，不僅可部份或完全 取代傳統水泥’且由於使用的無機材料可為晶質、非晶質 的原料或廢棄物，因此，不需像傳統水泥，須先經由將碳 φ 酸鈣高溫燒製後再製得水泥，更具有節能減碳之功能，由 於該粗、細骨材的材料種類選擇為本技術領域者所週知， 且非為本技術重點因此不再多加贅述。 本發明該較佳實施例再配合以下16個具體例及4個比 較例的說明後當可更清楚明白。 無機粉體原料 1.水淬爐石粉：一貫作業煉鋼廠在高爐煉鐵時所產生 的水淬爐渣經過研磨而成。 籲 2.燃煤飛灰：發電廠燒煤發電，經煙道搜集極細粒的 未燃物質。 3·廢玻璃粉：將回收之廢玻璃研磨成粉而得。 <具體例1 > 本發明該鹼活化漿料的具體例1是先秤取水淬爐石粉 為無機粉體原料，並將氫氧化鈉、矽酸鈉與鋁酸鈉加入水 中授掉混合均勻後得到一鹼活化液，並控制鹼活化液的 Sl〇2/Na2〇的莫耳比值為〇·5，Si02/Al203的莫耳比值為 201210979 20，且無機粉體與鹼活化液的液/固比為10，接著將該鹼活 化液加入前述之無機粉體進行攪拌，讓鹼活化液和無機粉 體形成均勻之漿體，即得到本發明之鹼活化漿料。 接著，再將該鹼活化漿料鑄模成型，製成尺寸為5cm χ 10cm的圓柱狀試體，即可製得丨號試樣。 〈具體例2〜5 > 本發明該鹼活化漿料的具體例2〜5，及由該鹼活化漿料 製知的2〜5號試樣，其使用的無機粉體種類及製作方法與 該具體例1大致相同，不同處在於Si02/Na20與Si02/Al203 之間的莫耳比值不同。 〈具體例6〜16> 本發明該鹼活化漿料的具體例6〜16，及由該鹼活化漿 料製得的6號〜16賴樣，其製作方法與該具_,M大致相 同，不同處在於該些具體例6〜16使用的無機粉體為由水淬 爐石粉與燃煤飛灰及/或玻璃粉以不同比例混合而得且 SiCVNkO與SiCVAhO3之間的莫耳比值也不同。 <比較例1〜4> 本發明驗活化聚料的比較例卜4，及由該比較例卜4的 鹼活化_得的17號〜2〇號試樣，其製作方法與該具體 例1大致相同，不同處在於該些比較例卜4的鹼活化液中 無添加铭酸納Al20；3。 201210979 茲將本發明該具體例1〜16及比較例1〜4的鹼活化漿料 的組成種類、配比，及由其所製得試樣的28天抗壓強度結 果分別整理於表1及表2。 表1If the amount of Al〇4 monomer is too small, the cemented material may be insufficient in strength due to structural incompleteness. Therefore, the present invention controls alkali activation by using an alkali metal hydroxide, an alkali metal niobate and/or a tannic acid gel. In addition to the basicity of the liquid, and further adjusting the aluminum content of the alkali activation liquid by alkali metal aluminate or aluminum powder, the required Al〇4 monomer is supplemented according to the actual situation, so that not only the high alkaline solution can be compensated for A disadvantage of insufficient amount of Aio4 monomer dissolved on the surface of the powder, and the inorganic powder of the field is a compound containing no aluminum, or a compound having a very low aluminum content, such as glass, It can be used normally, not only can the cement material structure be more complete and enhanced by the addition of aluminum, and it is not limited to the kind of materials used, but has a wider choice of materials. It should be noted that when the test property (M2〇) is too high, a sodium bicarbonate crystal substance formed by reacting an alkali metal with water vapor and carbon dioxide in the air is formed on the surface of the finished product prepared from the slurry ( Commonly known as Baihua), and because of the high testability, it will destroy the bond formed and cause the strength to decrease; and when the alkali is insufficient, the reactivity is too low, and the strength of the finished product made from the slurry is insufficient. Preferably, the molar ratio of the cerium oxide to the alkali metal oxide (Si02/M20) of the alkali activating solution is between 0.375 and 0.5, and the molar ratio (SiCMAhO3) of cerium oxide to lanthanum trioxide is between 20 and Between 80; more preferably, the molar ratio of the cerium oxide to the alkali metal oxide (Si〇2/M2〇) of the activation liquid is between 0.375 and 0.5' and the oxidization of the oxidized stone and the oxidized The molar ratio (Si02/Al203) is between 40-60. In addition, it is to be explained that when the viscosity of the alkali-activated slurry is too low, the fluidity is too high, and it is easy to cause a vertical flow phenomenon due to its own weight during use. When the viscosity is too high, it is easy to cause activation cracking. The body mixing is not easy, and 201210979 makes the alkali activation reaction incomplete. Therefore, preferably, the weight ratio of the alkali activation liquid to the inorganic powder (hereinafter referred to as the liquid/solid ratio) is between 1 and 0.5, more preferably The liquid/solid ratio of the test activation liquid to the inorganic powder is between i and 〇67, and the viscosity of the alkali-activated slurry is 10,000 to 60,000 mpas. When the alkali-activated slurry is further mixed with coarse and fine aggregates to form mortar or concrete, it can be used as a construction material, which can not only partially or completely replace the traditional cement, but also can be crystalline or non-organic due to the inorganic materials used. Crystalline raw materials or waste, therefore, it is not necessary to use traditional cement, it must first be fired by high-temperature carbon citrate to produce cement, which has the function of energy saving and carbon reduction, due to the material type of the coarse and fine aggregates. The selection is well known to those skilled in the art, and is not the focus of this technology and therefore will not be further described. The preferred embodiment of the present invention will be more clearly understood in conjunction with the following 16 specific examples and the description of the four comparative examples. Inorganic powder raw material 1. Water quenching furnace stone powder: The water quenching slag produced by the steelmaking plant in the blast furnace is uniformly ground. 2. Coal-fired fly ash: The power plant burns coal to generate electricity, and collects very fine particles of unburnt substances through the flue. 3. Waste glass powder: The recovered waste glass is ground into powder. <Specific Example 1> The specific example 1 of the alkali-activated slurry of the present invention is that the water quenching furnace powder is first weighed as an inorganic powder raw material, and sodium hydroxide, sodium citrate and sodium aluminate are added to water to be uniformly mixed. After obtaining an alkali activation solution, and controlling the molar ratio of S1〇2/Na2〇 of the alkali activation solution to 〇·5, the molar ratio of SiO 2 /Al 203 is 201210979 20 , and the liquid of the inorganic powder and the alkali activation liquid/ The solid ratio is 10, and then the alkali activation liquid is added to the above-mentioned inorganic powder and stirred to form a uniform slurry of the alkali activation liquid and the inorganic powder, thereby obtaining the alkali-activated slurry of the present invention. Next, the alkali-activated slurry was molded into a cylindrical sample having a size of 5 cm χ 10 cm to prepare a sample of nickname. <Specific Examples 2 to 5 > Specific examples 2 to 5 of the alkali-activated slurry of the present invention, and samples of samples 2 to 5 which are known from the alkali-activated slurry, and inorganic powder types and preparation methods thereof This specific example 1 is substantially the same except that the molar ratio between SiO 2 /Na 20 and SiO 2 /Al 203 is different. <Specific Examples 6 to 16> Specific examples 6 to 16 of the alkali-activated slurry of the present invention, and No. 6 to 16 which are obtained from the alkali-activated slurry, are produced in substantially the same manner as the _, M, The difference is that the inorganic powders used in the specific examples 6 to 16 are obtained by mixing water quenching furnace powder with coal-fired fly ash and/or glass powder in different ratios, and the molar ratio between SiCVNkO and SiCVAhO3 is also different. <Comparative Examples 1 to 4> Comparative Example 4 of the activated polymer of the present invention, and Sample No. 17 to No. 2, which was obtained by the alkali activation of Comparative Example 4, a production method thereof and the specific example 1 Roughly the same, the difference is that the alkali-activated liquid of the comparative example 4 is not added with the succinic acid Al20; 201210979 The composition and ratio of the alkali-activated slurry of the specific examples 1 to 16 and the comparative examples 1 to 4 of the present invention and the 28-day compressive strength of the sample prepared therefrom are respectively summarized in Table 1 and Table 2. Table 1
試 鹼活化漿料 28天抗 壓強度 (MPa) 樣 鹼活化劑（莫耳比） 編 號 無機粉體種類/比例 Si〇2/Na2〇 Si02/Al203 液/固比 1 水淬爐石粉 0.5 20 1 23 2 水淬爐石粉 0.5 40 1 31 3 水淬爐石粉 0.5 60 1 28 4 水淬爐石粉 0.5 80 1 24 5 水淬爐石粉 0.5 100 1 20 6 水淬爐石粉+燃煤飛灰/1:1 0.25 40 0.67 15 7 水淬爐石粉+燃煤飛灰/1:1 0.25 60 0.67 17 8 水淬爐石粉+燃煤飛灰/1:1 0.375 40 0.67 31 9 水淬爐石粉+燃煤飛灰/1:1 0.375 60 0.57 31 10 水淬爐石粉+燃煤飛灰/1:1 0.25 100 0.67 13 11 水淬爐石粉+玻璃粉A: 1 0.25 40 0.67 18 12 水淬爐石粉+玻璃粉^:1 0.25 60 0.67 17 13 水淬爐石粉+玻璃粉/1:1 0.375 60 0.67 25 14 水淬爐石粉+玻璃粉/1:1 0.25 100 0.67 11 15 水淬爐石粉+燃煤飛灰+玻 璃粉/1:1:1 0.25 40 0.67 15 16 水淬爐石粉+燃煤飛灰+玻 璃粉/1:1:1 0.375 40 0.67 26 201210979 表2 試 ------鹼活化漿料 28天 樣 無機粉體種類/比例 鹼活化劑 (莫耳比） 抗壓 號 Si〇2/Na2〇 Si02/Al2〇3 液/固比 強度 (MPa) i / 水淬爐石# -- 0.25 0 0.67 10 18 水淨爐石粉 0.25 0 1 12 19 水序爐石粉+玻璃粉/1.1 0.25 0 0.67 12 20 水淬爐石粉+燃煤飛灰+玻 璃粉/1:1:1 0.25 0 0.67 9 由表1及2結果可知，當鹼活化液中無添加鋁酸鈉 時’其製得試樣的28天抗壓強度均差’而當控制鹼活化液籲 的Si02/Na20及Si〇2/Al203的莫耳比值分別在介於0.25-0.5 及20〜1〇〇之間時，由不同無機粉體配製而得的鹼活化漿料 所製得的試樣，其28天抗壓強度均可達到i〇MPa ;而當控 制驗活化液SiCVAbO3的莫耳比值在20〜80之間時，由鹼 活化漿料製得之試樣的28天抗壓強度則可達到i5MPa以 上’當再進一步控制鹼活化液的Si〇2/Na2〇的莫耳比值在 0.375〜0.5且Si02/Al203的莫耳比值在40〜60之間時，則由 鹼活化漿料製得之試樣其28天抗壓強度更可大於25MPa。 _ 本發明利用鹼活化漿體形成的膠結材料，除了以鹼金 屬氫氧化物及鹼金屬矽酸鹽控制鹼活化液的鹼性之外，並 進一步藉由鹼金屬鋁酸鹽調控鹼活化液的鋁含量，依照實 際情形補足所需的A104單體，藉由鋁的添加使膠結材料結 構更完整進而增強其強度，且不受限於使用之材料種類， 而可有更廣泛的材料選擇，因此，不需像傳統水泥漿料， 須先經由將碳酸鈣高溫燒製後再製得水泥漿料，更具有節 10 201210979 月b減♦之功能，且本發明的鹼活化漿體不僅可單獨供補強 材料或防火材料使用’也可在添加適量的粗、細骨材後形 成砂浆或混凝土，取代傳統水泥漿料，供營建材料使用， 故確實能達成本發明之目的。 惟以上所述者，僅為本發明之較佳實施例與具體例而 已 ^不此以此限定本發明實施之範圍 申請專利範圍及發明說明内容所作之簡 飾’皆仍屬本發明專利涵蓋之範圍内。 ’即大凡依本發明 單的等效變化與修 【圖式簡單說明】 無 【主要元件符號說明】Test alkali activated slurry 28 days compressive strength (MPa) Alkali activator (Morby) No. Inorganic powder type / ratio Si〇2/Na2〇SiO2/Al203 Liquid/solid ratio 1 Water quenching furnace powder 0.5 20 1 23 2 Water quenching furnace powder 0.5 40 1 31 3 Water quenching furnace powder 0.5 60 1 28 4 Water quenching furnace powder 0.5 80 1 24 5 Water quenching furnace powder 0.5 100 1 20 6 Water quenching furnace powder + coal-fired fly ash / 1: 1 0.25 40 0.67 15 7 Water quenching furnace powder + coal-fired fly ash / 1:1 0.25 60 0.67 17 8 Water quenching furnace powder + coal-fired fly ash / 1:1 0.375 40 0.67 31 9 Water quenching furnace powder + coal burning Ash / 1:1 0.375 60 0.57 31 10 Water quenching furnace powder + coal fly ash / 1:1 0.25 100 0.67 13 11 Water quenching furnace powder + glass powder A: 1 0.25 40 0.67 18 12 Water quenching furnace powder + glass powder ^:1 0.25 60 0.67 17 13 Water quenching furnace powder + glass powder / 1:1 0.375 60 0.67 25 14 Water quenching furnace powder + glass powder / 1:1 0.25 100 0.67 11 15 Water quenching furnace powder + coal-fired fly ash + Glass powder /1:1:1 0.25 40 0.67 15 16 Water quenching furnace powder + coal-fired fly ash + glass powder / 1:1:1 0.375 40 0.67 26 201210979 Table 2 Test ------ alkali activated slurry 28 Day-like inorganic powder type / ratio alkali activator (Mo Ear ratio) Compressor No. Si〇2/Na2〇Si02/Al2〇3 Liquid/solid ratio strength (MPa) i / Water quenching furnace stone # -- 0.25 0 0.67 10 18 Water furnace stone powder 0.25 0 1 12 19 Water sequence Hearthstone powder + glass powder / 1.1 0.25 0 0.67 12 20 Water quenching furnace stone powder + coal-fired fly ash + glass powder / 1:1:1 0.25 0 0.67 9 From the results of Tables 1 and 2, there is no aluminum added in the alkali activation liquid. When sodium is used, 'the 28-day compressive strength of the sample is poor', and when the alkali-activated liquid is controlled, the molar ratios of SiO 2 /Na 20 and Si 〇 2 /Al 203 are between 0.25-0.5 and 20 〜1, respectively. When the crucible is mixed, the 28-day compressive strength of the sample prepared from the alkali-activated slurry prepared from different inorganic powders can reach i〇MPa; and when the control test solution SiCVAbO3 has a molar ratio When the temperature is between 20 and 80, the 28-day compressive strength of the sample prepared from the alkali-activated slurry can reach i5 MPa or more. 'When the alkali-activated liquid is further controlled, the molar ratio of Si〇2/Na2〇 is 0.375. When the molar ratio of ～SiO 2 /Al 203 is between 40 and 60, the 28-day compressive strength of the sample prepared from the alkali-activated slurry may be more than 25 MPa. _ The present invention utilizes a base-activated slurry to form a cementitious material, in addition to controlling the alkalinity of the alkali-activated solution with an alkali metal hydroxide and an alkali metal citrate, and further adjusting the alkali-activated liquid by an alkali metal aluminate. The aluminum content, according to the actual situation, complements the required A104 monomer, and the addition of aluminum makes the structure of the cement material more complete and enhances its strength, and is not limited to the type of materials used, but has a wider selection of materials. It does not need to be like traditional cement slurry. It must be fired at a high temperature to prepare cement slurry. It has the function of saving 10 201210979 b, and the alkali-activated slurry of the present invention can not only be separately reinforced. The use of materials or fireproof materials can also be used to form a mortar or concrete after adding an appropriate amount of coarse and fine aggregates, instead of the conventional cement slurry, for use in construction materials, so that the object of the present invention can be achieved. However, the above description is only for the preferred embodiments and specific examples of the present invention, and thus the scope of the invention and the description of the invention are not limited thereto. Within the scope. ‘that is, the equivalent change and repair of the single invention according to the invention. [Simple description of the diagram] None [Main component symbol description]