TW201210488A - Fungicidal mixtures - Google Patents

Abstract

The present invention relates to binary and ternary fungicidal mixtures, comprising a component 1 and a component 2, wherein component 1 is the compound of the formula I.

Description

201210488 6. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to fungicidal compositions comprising a compound of formula I as component 1)

Each of the variables has the following meanings: A 2,4-difluorophenyl; B 2-phenylphenyl; and D SH (compound 1-1), S-CN (compound 1-2) or S-CH2-CH= CH2 (compound 1-3), wherein the compound I is present in whole or in part in its tautomeric form; and/or an agriculturally acceptable salt thereof; and as an active ingredient of component 2), which is selected from the group consisting of (pyraclostrobin), fluoropterin, "fluxapyroxad", fenpropimorph, prothioconazole, and chlorothalonil and/or agriculturally acceptable salts thereof; The weight ratio of the components is from 20:1 to 1:20. The invention further relates to the use of such fungicidal mixtures to control particular phytopathogenic fungi as detailed herein, as well as formulations or compositions comprising such mixtures. The invention is also additionally directed to seeds comprising such fungicidal mixtures. The invention further relates to a method of controlling a particular plant disease 157786.doc 201210488 protozoa as detailed herein, wherein the fungus or the material to be protected against fungal attack is treated with an effective amount of a fungicidal compound of the invention, Plant, soil or seed. The invention is also additionally directed to a process for preparing a mixture of the invention. SUMMARY OF THE INVENTION In order to reduce the rate of application and to broaden the spectrum of activity of known compounds, it is an object of the present invention to provide a mixture which exhibits improved improvement against important harmful fungi, especially certain indications, by reducing the total amount of active compound applied. Activity. Another object is to provide a mixture that can be used to control a particular pathogen in a particular important crop that is generally susceptible to pathogen attack. Therefore, we have found the mixtures and uses defined in the opening and following descriptions. [Embodiment] The triazolyl propylene oxide of the formula I, its preparation and its use in crop protection are described in WO 2009/077443 (PCT/EP2008/067394), which also discloses certain mixtures with other active compounds . Compound i may be in the form of the "thiol" of formula Ia or in the form of "thiocarbonyl" of formula lb:

Wherein A and B have the meanings defined above. Here, for the sake of brevity, only one of the two forms is shown in each case, usually in the form of "thiol". Similarly, 'Compounds 1-2 and 1-3 can exist in two tautomeric forms 157786.doc •4· 201210488. Due to the basic characteristics of its nitrogen atom, the compound ι (ie, compound 1, compound 1-2 or compound 丨-3) can form a salt or adduct with an inorganic or organic acid or with a metal ion, especially a salt with an inorganic acid. Examples of inorganic acids are hydrogen-acids (such as hydrofluoric acid, hydrochloric acid, hydrogen acid acid and hydroiodic acid), carbonic acid, sulfuric acid, wall acid and nitric acid. Suitable organic acids (for example) formic acid and alkanoic acids (such as acetic acid, tri-acetic acid, trichloroacetic acid and propionic acid, but also glycolic acid, thiocyanate, lactic acid, sulphuric acid, citric acid, benzoic acid and others) Aryl carboxylic acid, cinnamic acid, oxalic acid), alkyl sulfonic acid (linear or branched anhydride having 1 to 20 carbon atoms), aryl sulfonic acid or aryl disulfonic acid (containing One or two aromatic groups of a sulfonic acid group, such as a strepyl and naphthyl group, an alkylphosphonic acid (a linear or branched alkyl phosphonic acid having 1 to 2 carbon atoms), an aryl group a phosphonic acid or an aryl diphosphonic acid (an aromatic group carrying one or two phosphate groups, such as phenyl and zeo), wherein the alkyl or aryl group may carry other substituents, such as p-toluene Sulfonic acid, salicylic acid, p-aminosalicylic acid, 2-phenoxy acid, 2-ethyloxybenzoic acid, and the like. Suitable metal ions are especially ions of the second main group elements (especially calcium and magnesium), ions of the second and fourth main elements (especially those of the Ming, Xi and Wrong), and transitional elements from one to eight (especially It is an ion of chromium, fierce, iron, knot, recorded, copper, zinc, and other elements. The better one is the metal ion of the transition element of the fourth period. The metals may be present at a variety of valences that they may exhibit. Compound 1 (ie, compound 1-1, compound Ι·2 or compound Ι·3) contains the genus 157786.doc 201210488 and is a racemic form or a erythroformis diastereomer. Mixtures to obtain "The erythro and threo diastereomers of the compounds of the invention may be based on, for example, their different solubilities or by separation and separation by means of a tube. The homo-enantiomers can be obtained using such homogeneous non-isomer pairs using known methods. Suitable for use as an antimicrobial agent are both homo-diastereomers or enantiomers and mixtures thereof obtained in the synthesis. This applies correspondingly to fungicidal compositions. Compound 1 (i.e., compound 1-1, compound 1-2 or compound 13) is preferably present as a mixture of enantiomers of the "trans" isomer, i.e., in the compound I, the benzene rings are "" Trans." Therefore, the compound is preferably 2_[relative(2R,3S)-3-(2-phenylphenyl)_2-(2,4·difluorophenyl)epoxyethylidenemethyl]-2,4·dihexane -[1,2,4]triazol-3-thione, which may also exist in its tautomeric form or as a mixture of tautomers; and the compound χ·2 is preferably 1_[relative (2R'3S --3-(2-Phenylphenyl)_2_(2,4.:fluorophenyl)oxiranylmethyl]-5-thiocyanato-1Η-[1,2,4]triazole, It may also exist as a tautomeric form as a mixture of tautomers; and compound 13 is preferably [relative (211'38)-3-(2-phenylphenyl)-2-(2,4-di) Fluorophenyl) oxiranyl fluorenyl]-5-allyl-1 fluorene-[1,2,4]triazole. Specifically, in each case, a racemic mixture is present. In addition, any other ratio of trans enantiomers may be present, and any of the trans enantiomers may also be present in pure form. In other words, there may also be "cis" isomers, ie, 2 [relative (2R,3R)-3-(2-chlorophenyl)_2_(2,4-difluorophenyl)oxiranyl) Mercapto] 2,4-monohydro-[1,2,4]disindol-3-thio- and/or its tautomeric thiol form, or 1-[relative (2R,3R)-3-( 2-Phenylphenyl)-2-(2,4·difluorophenyl) ring 157786.doc 201210488 Oxygen bromide • fluorenyl]-5-cyanoindolyl-1H-[1,2,4]trisole , or 1-[relative (2R, 3R)-3-(2-phenylphenyl)-2-(2,4-difluorophenyl)oxiranyl sulfhydryl-5. thiocyano-1H- [1,2,4]triazole. This applies to each binary or ternary mixture as detailed herein. The active compounds of component 2 and component 3, their preparation and their effect on harmful fungi are known (cf. http://www.alanwood.net/pesticides/) and are mainly commercially available from the market. Active compounds can be found, for example, in The

Pesticide Manual, 14th edition, British Crop Protection

Council (2006) and other publications. fluorine. Compared with salivary amine (]^_(3',4,5,_three gas-linked-2-yl)-3 - one gas methyl-1-methyl-1Η-0 ratio. Amines and their preparation and use are described in WO 2006/087343. In the following, the preferred use of the inventive mixtures is further illustrated. In each case, the use of the mixture for controlling a particular phytopathogenic fungus according to the invention is also intended to encompass individual methods of controlling a particular phytopathogenic fungus, wherein the treatment is carried out with an effective amount of a fungicidal mixture as defined herein. A fungus or material, plant, soil or seed that is intended to protect against fungal attack. In the aspect of the invention, the mixture is a binary mixture, #includes a compound. 1 (ie, compound 1, 1, 1-2 or compound ^ from component 1} and another species. secret compound (component 2) The composition of the present invention as an active ingredient, wherein the group is selected from the group consisting of baikemin, flurazepam, fenflufen, thiophene sulphate and cytobacteria, and the weight ratio of the two components is 1: 2〇至2〇:1, Youjiashe 1〇 to 10: 曰1 range 'specifically in the range of 1:3 to 3:1. It is also preferred that the weight ratio is 1:2 to 2: In the context of the present invention, "binary mixture 157786.doc 201210488. The mixture may of course contain the following details to provide a suitable formulation for agriculture means that only two active compounds are present. Analogous. According to one embodiment, the present invention relates to a binary mixture of a compound hydrazine (ie, a compound 丨, a compound 1-2 or a compound │ 3) and a fluoropyrazole amine, both of which

Synergistic effects and the components are specifically used in synergistically effective amounts. According to an embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (ie, compound M, compound 1-2 or compound 1-3) and flupyrazolamide to control a sputum-like pathogen, wherein each component is The weight ratios mentioned are such that, in particular, the mixture is suitable for controlling wheat pathogens. When used in wheat, the preferred weight ratio of each active ingredient is from 20:1 to 1:2, specifically from 2.1 to 1:2', of which the compound ι (ie compound, compound 12 or compound 1) -3) is present in a ratio of 1:1 to 2:1 with flupyrazol. The mixture is particularly suitable for controlling wheat pathogens selected from the group consisting of Sept〇ria tritici, Stagonospora nodorum, Pyrenophora tritici repentis, and pUCcinia recondita. ), Puccinia striiformis and Blumeria graminis. In addition, the mixture can be used to control pathogens selected from the group consisting of Fusarium culmorum, Fusarium graminearum, and Pseudocercosporella herpotrichoides. 157786.doc 201210488 Furthermore, the mixture is suitable for controlling barley pathogens. When used in barley, the preferred weight ratio of each active ingredient is from 2〇η to u〇, specifically 2:1 to 1:2 ′. (i.e., compound, compound 12 or compound 1-3) and fluoropyrazolamide are present in from 2:1. The mixture is particularly suitable for controlling barley pathogens selected from the group consisting of: barley reticular bacteria, pyrenoPhera teres, RhyCh〇sporium secalis, Puccinia hordei, and powdery mildew. Further, the mixture can be used to control barley pathogens selected from the group consisting of Ramularia collo-cygni and Rhizoctonia solani. According to another embodiment, the invention relates to the use of a binary mixture of Compound 1 (i.e., Compound 1, Compound 1-2 or Compound 1-3) and flupyrazolamide to control soybean pathogens. When used in soybeans, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 3:1 to 1:3, and particularly preferably, compound 1 (ie, compound 1-1, compound) 1-2 or compound 1-3) and fluorine '« is present in a ratio of 3:1 to 2:1." In particular, the mixture is suitable for controlling a large denier pathogen selected from the group consisting of: large and clocky ( Phakopsora pachyrizi), P. meibomiae and Microsphaera diffusa. In soybeans, the mixture can also be effectively used to control so-called • FDC (leaf disease syndrome), such as against Septoria. glycines, Cercospora kikuchii, and C. sojina. ), Corynespora cassiicola and/or Alternaria spp. 〇 According to another embodiment, the invention relates to compound 1 (ie compound I-1, compound 1-2 or compound) 1-3) Binary mixture with flupyrazolamide controls the use of jade 157786.doc 201210488 rice pathogen. When used in corn, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and especially preferably compound 1 (ie compound 1-1, compound) 1-2 or compound 1-3) is present in the range of 2:1 to 1:1 with flupirtine. Specifically, the mixture is suitable for controlling a corn pathogen selected from the group consisting of Cercospora zeae·maydis, Puccinia sorghi, and Helminthosporium maydis. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound Ιβ1, compound 1-2 or compound 1-3) and flupyrazolamide to control a pathogen of a sweet potato. When used for sugar beet, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and especially preferably compound 1 (ie compound 1-1, compound) 1-2 or compound 1-3) is present in the range of 2:1 to 1:1 with flupirtine. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of Cercospora beticola, Erysiphe betae, RamuUria betae and Uromyces betae. ). According to a further embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (i.e., a compound, a compound 1-2 or a compound 1-3) and a fluoropyrazolamide to control, in particular, a peanut pathogen selected from the group consisting of: groundnuts Mycosphaerella arachidiS (=Cerc〇sp〇ra) and Puccinia arachidis » When used in groundnuts, the weight ratio of each active ingredient is 20:1 to 1 : 20, specifically 2:1 to 1:2, wherein it is preferred that compound 1 (ie, compound I-1, compound Ι·2 or compound I·3) and fluoropyrazolamide are 2:1 to 1:1 exists. 157786.doc •10· 201210488 According to yet another embodiment, the invention relates to the control of a binary mixture of compound I (ie compound I1, compound 1-2 or compound Ι·3) and fluoropyrazolamide, in particular selected from The following uses of rapeseed and fragrant pathogens include Sclerotinia sclerotiorum, Leptosphearia maculans, and Alternaria alternate. When used for rapeseed or canola, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound ι (ie compound) The compound 1-2 or the compound 1-3) is present in a ratio of 2:1 to 1:1 with the fluoronine than the salivium. According to a further embodiment, the invention relates to the use of a binary mixture of compound 1 (ie compound j, compound 1-2 or compound 1-3) and flupyrazolamide to control a rice pathogen selected from the group consisting of: Rhizobacteria (Rhiz〇ct〇nia solani) and Pyricularia oryzae. When used in rice, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie compound M, compound 12 or Compounds 1-3) and flupyrazolamide are present in a ratio of 2:1 to 1:1. Mixtures of Compound 1 (ie, Compound 1-1, Compound K2, or Compound 13) with inosine are also suitable for controlling pathogens such as turf, potato, tomato, gourd, grapes, apples, ornamental plants, and the like. Fragrance I. The turf pathogens which can be controlled by the present invention are selected from the group consisting of Sclerotinia home 〇carpa and Rhizoctonia solani. When used in turf, the preferred weight ratio of each active ingredient is from 20:1 to 1:2, in particular from 2:1 to 1:2', of which the compound may be compounded (ie, compound M, compound oxime or The compound is called 1:1 to 1:2 with fluridamide. The potato and the pathogen which can be controlled according to the present invention are specifically selected from the Phytophthora infestans 157786.doc 201210488 (Alternaria solani), an alternate chain The cucurbit pathogen controlled by the present invention is, in particular, the squash pathogen (Sphaerotheca fuliginea) which can be controlled according to the present invention. The grape pathogen which can be controlled according to the present invention has the genus Vibrio cholerae ( Uncinula necator) and Botrytis cinerea. Apple pathogens which can be controlled according to the invention are in particular Podosphaera leucotricha and Venturia inaequalis. Ornamental plant pathogens which can be controlled according to the invention Specifically, it is selected from the group consisting of melon to powdery mildew, Dipl〇carp〇n spp., Alternaria and Scler〇tinia spp. The banana pathogen controlled according to the present invention is specifically It is selected from Mycosphaerella fijiensis and Myc〇sphaere Ua musicola. According to another embodiment, the present invention relates to a compound (ie, compound ^, compound 1-2 or compound 1) -3) a binary mixture with baikemin, the weight ratio of the two being from 20:1 to 1:20, more specifically from 5:1 to 1:5, specifically from 3:1 to 1:3, more specific 2:1 to 1:2. Surprisingly, this mixture exhibits a synergistic effect and the components are used in particular in synergistically effective amounts. According to one embodiment, the invention relates to a compound 丨 (ie a compound) 1_1, compound hydrazine or compound!.3) and hexamin: the use of a mixture of steroids to control sputum pathogens, wherein each component is used in the weight ratios mentioned above. Specifically, the mixture is suitable for controlling wheat. Pathogens. When used in wheat, the ratio of the weight of each active ingredient is 20:1 to 1:2〇, specifically 2:1 to 1:2, of which the compound is better (ie, the compound 丨, compound ^ or compound 1.3) and 100 grams of fine fine 1:1 to 2:1 presence ^ mixture especially suitable for 157786.doc 1 2 201210488 Controlling wheat pathogens selected from the following: wheat sphaeroides, sphaeroides, wheat yellow leaf spot, wheat leaf rust, stripe rust fungus and powdery mildew. In addition, the mixture can be used for control selection Pathogens from the following: Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Furthermore, the mixture is suitable for controlling barley pathogens. When used in barley, 'the preferred weight ratio of each active ingredient is 20:1 to 1:20, specifically 2:1 to 1:2, and especially preferred is compound 1 (ie compound ^, compound 12) Or the compound 1-3) and the gram-sensitive system are present at 1:1 to 2:1. The mixture is particularly suitable for controlling barley pathogens selected from the group consisting of barley mutans, barley grisea, barley rust, and powdery mildew. In addition, the mixture can be used to control barley pathogens selected from the group consisting of colloidal goosegrass and wheat sheath blight. According to another embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and dextromethine to control a soybean pathogen. When used in soybeans, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 3:1 to 1:3, and particularly preferably, compound 1 (ie, compound 1-1, compound) 1-2 or compound ^) and 克克敏 are present at 2:ι to 2.1. In particular, the mixture is suitable for controlling soybeans selected from the following: pathogens: soybean rust, potato rust fungus and soybean powdery mildew. In soybean-tow, the mixture can also be effectively used in (4) so-called coffee (leaf disease syndrome), <Likes such as resistance to brown streak disease, soybean leaf spot, cowpea gray spot disease, multi-spore and/or genus. According to yet another embodiment, the invention relates to compounds! (ie compound Μ, compound or compound Μ) and a binary mixture of baikemin to control corn disease 157786. Doc •13- 201210488 It is used for the original body. A particularly good weight ratio for each active ingredient when used in corn. 1 to 1:20 ‘specifically 2:1 to 1:2 ’, of which the compound K is the compound 1-1, the compound 1-2 or the compound is called 2:1 to 1. 1 exists. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of corn gray spot g, corn common rust, and Helminthosporium. According to a further embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (i.e., a compound, a compound 1-2 or a compound 1-3) and a dextromethine to control a sugar beet path. When used for sugar beet, the preferred weight ratio of each active ingredient is 2〇:1 to 1:2G, specifically 2:1 to 1:2, and especially preferably compound 1 (ie compound 1-1, Compound _2 or Compound 1-3) and 克克敏 are present at 2:1 to 1.1. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of beetle sclerotium, sugar beet powder, sugar beet bacteria, and succulent bacteria. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., a compound hydrazine), a compound 1-2 or a compound 1-3) and a cyproterone to control, in particular, a peanut pathogen selected from the following: • a peanut cavity Bacteria (=C. cerevisiae) and rusting bacteria. When used for groundnut, the weight ratio of each active ingredient is 20:1 to 1:2〇, specifically 2:1 to 丨:2, among which the compound can be compounded (ie, compound Μ, compound 〖_2 Or compound 13) and hexagram are present at 2:1 to 1:1. According to a further embodiment, the invention relates to the use of a binary mixture of compounds (i.e., compound Li, compound 1-2 or compound 1-3) and cyproterone to control specific & Sclerotinia sclerotiorum, 157786. Doc •14· 201210488 Brassica oleracea and Alternaria alternata. When used in rapeseed or canola, the optimum weight ratio of each active ingredient is 2〇. · ι to ι: 2〇, specifically 2. In the case of 1:2, it is preferred that the compound [(ie, compound 丨, compound 或 or compound 1-3) and 克克敏) be present in a ratio of 2:1 to 1:1. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., a compound, 'compound 1-2 or compound 丨-3) and cyproterone to control a rice pathogen selected from the group consisting of Rhizoctonia solani and rice Heat bacteria. When used in rice, the preferred weight ratio of each active ingredient is 2〇: 丨 to 〗: 2〇, specifically to 1:2, and particularly preferably, it can be a compound 丨 (ie, compound 丨, compound 12) Or the compound 1-3) and the gram-sensitive system are present at 2:1 to ι:ι. Mixtures of Compound 1 (ie, Compound Μ, Compound 1-2 or Compound 13) and cyproterone are also suitable for controlling pathogens such as turf, potato, tomato, gourd, grapes, apples, ornamental plants, etc. And bananas. The turf pathogen which can be controlled according to the present invention is selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. When used in turf, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie, compound hydrazine, compound 1_2 or The compound ^) and the gram-sensitive system are present at 1:1 to 1:2. The potato and tomato pathogens which can be controlled according to the invention are in particular selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled according to the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled according to the invention are in particular C. grisea and Botrytis cinerea. The apple pathogens which can be controlled according to the invention are in particular apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled according to the invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, and genus Alternaria 157786. Doc •15· 201210488 Genus and Sclerotinia. The aromatized pathogens which can be controlled in accordance with the present invention are specifically selected from the group consisting of G. glabrata and P. sphaeroides. According to another embodiment, the invention relates to a weight ratio of the compound hydrazine (ie compound, compound 1-2 or compound 1-3) to a binary mixture of fenflufen of from 20:1 to 1:20, more specifically 5:1 to 1:5, specifically 3:1 to 1:3 'more specifically 2:1 to 1:2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to one embodiment, the present invention relates to the use of a binary mixture of a compound (i.e., compound j-oxime, compound 1-2 or compound 1-3) and fenflufen to control a sputum-like pathogen, wherein each component is as mentioned above And the weight ratio is used. In particular, the mixture is suitable for controlling wheat pathogens. When used in wheat, the preferred weight ratio of each active ingredient is 2〇: 丨 to 丨: 2〇, specifically 2: j to 1:2, of which the best ones can be combined (ie compound, compound 12 or Compounds 1-3) are present in a range of 1:1 to 2:1 with Fenford. The mixture is particularly suitable for controlling wheat pathogens selected from the group consisting of: A. glabrata, A. glabrata, A. fuliginea, Wheat leaf rust, A. sphaeroides, and B. burgdorferi. In addition, the mixture can be used to control pathogens selected from the group consisting of Fusarium oxysporum, Fusarium graminearum, and Rhizoctonia solani. Furthermore, the mixture is suitable for controlling barley pathogens. When used in barley, the preferred weight ratio of each active ingredient is 2〇:1 to 1:2〇, specifically 2:1 to 1:2′, among which the compound 1 (ie compound U, compound) 1-2 or compound 1-3) is present in a ratio of 1:1 to 2:1 with Fenford. The mixture is particularly suitable for controlling barley pathogens selected from the group consisting of barley mutans, barley grisea, barley rust, and powdery mildew. In addition, the mixture can be used to control 157786. Doc • 16 · 201210488 The following barley pathogens are selected: G. sphaeroides and R. solani. According to another embodiment, the invention relates to the use of a binary mixture of compound ι (i.e., Compound 1, Compound 1-2 or Compound) and Fenfen to control soybean pathogens. When used in soybeans, the preferred weight ratio of each active ingredient is 2〇:1 to 1:20, specifically 3:1 to 1:3, and particularly preferably, compound 1 (ie, compound 1-1, Compound _2 or Compound 1-3) is present in the range of 3:1 to 2:1 with Fenford. In particular, the mixture is suitable for controlling soybean pathogens selected from the group consisting of soybean rust, rust potato rust, and soybean powdery mildew. In Dali, the mixture can also be effectively used to control so-called "leaf disease syndromes", such as resistance to brown smut, soybean blight, soybean gray spot, Pseudomonas aeruginosa and/or Alternaria Genus. According to a further embodiment, the invention relates to the use of a binary mixture of Compound 1 (i.e., Compound, Compound 1-2 or Compound) and Fenfen to control corn pathogens. When used in corn, the preferred weight ratio of each active ingredient is 2:1 to 1:20', specifically 2:1 to 1:2, and particularly preferred is compound 1 (ie compound 1-1, Compound ^ or compound 1-3) and fenflufen 2" to 1. 1 Exist" specifically and §, the mixture is suitable for controlling a corn pathogen selected from the group consisting of: Helminthosporium oxysporum 0, common rust of corn, and Helminthosporium sinensis. According to yet another embodiment, the present invention relates to Compound 1 (ie Compounds ", compound ί-2 or compound!-3" and a mixture of fenflufen to control beet pathogens. When used in sugar beet, the ratio of the weight of each active ingredient is added to 1:20. Specifically, 2:1 to 1:2', among which the better one can be compound 157786. Doc •17- 201210488 I (ie, Compound I-1, Compound 1-2, or Compound 1-3) and Fenfford are present at 2:1 to 1:1. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of: S. cerevisiae, Saccharomyces cerevisiae, S. cerevisiae and S. cerevisiae. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (ie compound, compound 1-2 or compound 1-3) and fenflufen to control, in particular, a peanut pathogen selected from the group consisting of: (=C. cerevisiae) and rusting bacteria. When used for groundnuts, the preferred weight ratio of each active ingredient is from 20:1 to 1:2, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie, compound Μ, compound 1) -2 or compound 13) is present in 2:1 to 1:1 with Fenford. According to a further embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (ie compound, compound U or compound (iv)) and fenflufen to control, in particular, from the following rapeseed and canola pathogens: Sclerotinia sclerotiorum , Brassica albicans and Alternaria alternata. When used in rapeseed or canola, the preferred weight ratio of each active ingredient is from 20:1 to 12, specifically from 21 to U, with the preferred one being a compound! (i.e., compound W, compound oxime or compound 1-3) and fenflupro as 2:1 to ι:ι. According to still another embodiment, the present invention relates to the use of Compound 1 (ie, Compound Compound 1-2 or a binary mixture of a compound called Fenfu) to control a rice pathogen selected from the group consisting of Rhizoctonia solani and Rice fever pathogen When used in; 'the preferred weight ratio of each active ingredient is 2 (): 1 to 1: 2 (), specifically 2 to 1: 2, of which the better ones can be combined (ie, compound M, compound ^ or compound 1-3) and fenflupro as 2·· 1 to 1 · 1. • J8- 157786. Doc 201210488 Compound I (ie Compound I, Compound or Compound 13) and Fenfen's diterpene mixture are also suitable for controlling pathogens such as turf, potato, tomato, gourd, grape, apple, ornamental plant And bananas. The turf pathogens which can be controlled according to the invention are selected from the group consisting of silver leaf spot bacteria and Rhizoctonia solani. When used in turf, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, of which the compound is preferably compound 1-1, compound]: _2 or compound *^3) and Fenford are present in ι:ι to 1:2. The potato and tomato pathogens which can be controlled according to the present invention are specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The pathogens of G. serrata which can be controlled according to the present invention are, in particular, the grape pathogens which can be controlled by the melon to the powdery mildew according to the present invention, in particular, the genus Rhizoctonia solani and Botrytis cinerea. The apple pathogens which can be controlled according to the present invention are specifically apple powdery mildew and apple scab. The ornamental plant pathogens which can be controlled according to the invention are in particular selected from the group consisting of melon to powdery mildew, bivalve, genus genus and genus Sclerotinia. The banana pathogen which can be controlled according to the present invention is specifically selected from the group consisting of a genus Fibulae and a bacterium of the genus Banana. According to another embodiment, the invention relates to compounds! a binary mixture of (ie, compound ^, compound 1-2 or compound 1-3) and prothioconazole in a weight ratio of 20:1 to 1:20, more specifically 5:1 to 1:5 Specifically, 3. 1 to 1:3, more specifically 2:1 to 1:2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to an embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (ie, compound M, compound 1-2 or compound 1-3) and prothioconazole to control a sputum-like pathogen, wherein each component is in the above The weight ratio mentioned is to make 157786. Doc •19- 201210488. In particular, the mixture is suitable for controlling wheat pathogens. When used in wheat, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically 2:j to 1:2', of which the compound 1 (ie, compound Μ, compound 12 or Compound 1-3) is present in a range of 1:1 to 2:1 with prothioconazole. The mixture is particularly suitable for controlling wheat pathogens selected from the group consisting of: A. glabrata, A. glabrata, Wheat Leaf spot, Wheat leaf rust, Puccinia striiformis and B. burgdorferi. In addition, the mixture can be used to control pathogens selected from the group consisting of Fusarium oxysporum, Fusarium graminearum, and Rhizoctonia solani. Furthermore, the mixture is suitable for controlling barley pathogens. When used in barley, the preferred weight ratio of each active ingredient is 20:1 to 1:2, specifically 2: 丨 to 1:2', among which the compound 丨 (ie, compound κι, compound 12) Or the compound 1-3) and the prothioconazole system are present at 1:1 to 2:1. The mixture is particularly suitable for controlling barley pathogens selected from the group consisting of barley mutans, barley grisea, barley rust, and powdery mildew. In addition, the mixture can be used to control barley pathogens selected from the group consisting of G. sphaeroides and H. solani. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and prothioconazole to control a soybean pathogen. When used in soybeans, the preferred weight ratio of each active ingredient is from 20:1 to 1:20 'specifically 3:1 to 1:3', of which the compound 1 (ie compound 1-1, compound) Ϊ-2 or compound [_3) is present in the range of 3:1 to 2:1 with the prothiotoxin. Specifically, the mixture is suitable for controlling soybean pathogens selected from the group consisting of soybean rust, rust potato rust, and soybean powdery mildew. At the big 157786. Doc -20- 201210488 Beans, this mixture can also be effectively used to control the so-called FDC (leaf disease syndrome), such as resistance to brown smut, soybean smut, soybean gray spot, multi-capsule and/or chain Genus spp. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, 1-2 or compound 1-3) and prothioconazole to control a corn pathogen. When used in corn, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and especially preferably compound 1 (ie compound 1-1, compound) 1-2 or the compound 〖^) and the prothioconazole system are present from 2:1 to 1:1. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of: corn leaf spot, corn common rust, and worm. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e. compound, compound 1-2 or compound 1-3) with prothioconazole to control a beet pathogen. When used for sugar beet, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie compound 1-1, compound) Ι·2 or compound 1-3) is present in the range of 2:1 to 1:1 with prothioconazole. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of: S. cerevisiae, Saccharomyces cerevisiae, Saccharomyces cerevisiae and Beet rust. According to a further embodiment, the invention relates to the use of a binary mixture of a compound hydrazine (ie compound pi, compound Ι2 or compound 1-3) and prothioconazole to control, in particular, a peanut pathogen selected from the group consisting of: groundnuts Helicobacter pylori (= genus Cercospora) and rusting bacteria. When used for groundnuts, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, especially 157786. Doc •21- 201210488 The compound may be compound ι (ie compound w, compound 12 or compound is called 2:1 to 1:1 with prothioconazole). According to yet another embodiment, the present invention relates to compounding ( That is, the compound [the compound L2 or the compound and the thiophanate binary mixture control specifically uses the following rapeseed and fennel pathogens: Sclerotinia sclerotiorum, cabbage blackfoot disease i and xenobiotics. When used in rapeseed or fragrant flowers, the preferred weight ratio of each active ingredient is 2n1:2G, specifically Μ to 1:2 ', especially in the case of 彡 (ie compound M, compound 々 or compound 1) -3) is present in the range of 2:1 to 1:1 with prothioconazole. According to a further embodiment, the invention relates to a compound (i.e., compound, compound 1-2 or compound [3) and prothioconazole The meta-mixture controls the use of the following rice pathogens: Rhizoctonia solani and rice fever I, when used in rice, the preferred weight ratio of each active ingredient is 2〇:1 to 1:2〇, specifically 2 . 1 to 1. 2. Among them, a compound which is preferably a compound (i.e., compound ^, compound 1-2 or compound ι. 3) and a prothioconazole system are present in a ratio of 2:1 to 1:1. The binary mixture of Compound 1 (i.e., Compound Μ, Compound 1-2 or Compound 13) and prothioconazole is also suitable for controlling pathogens such as the following. Turf 'Potato, Fanyou, Yunchan, Grape, Frequency Fruit' ornamental plants and incense party. The turf pathogen controlled by the present invention is selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. When used in turf, the preferred weight ratio of each active ingredient is 20. To 1:20 "> specifically 2:1 to 1:2, wherein the compound which is a preferred compound, that is, the compound hydrazine, the compound j_2 or the compound i_3) and the prothioconazole system are present at 1:1 to 1:2. The potato and tomato pathogens which can be controlled according to the invention are specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Lithium nucleus 157786. Doc •22· 201210488 bacteria. The cucurbit pathogen which can be controlled according to the invention is specifically melon to powdery mildew. The grape pathogens which can be controlled according to the invention are in particular C. grisea and Botrytis cinerea. The apple pathogens which can be controlled according to the invention are in particular apple powdery mildew and apple scab. The ornamental plant pathogens which can be controlled according to the invention are in particular selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. The banana pathogens which can be controlled according to the invention are in particular selected from the group consisting of Fissionella Fibrosus and Rhizoctonia solani. According to another embodiment, the present invention relates to a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and chlorothalonil, in a weight ratio of 20:1 to 1:20, more specifically In terms of 5:1 to 1:5, specifically 3:1 to 13, more specifically 2:1 to 1:2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to an embodiment, the present invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and chlorothalonil to control a sputum-like pathogen, wherein each component is a weight ratio as mentioned above. To use. In particular, the mixture is suitable for controlling wheat pathogens. When used in wheat, the preferred weight ratio of each active ingredient is 2〇:1 to 1:2〇, specifically 21 to 1:2, and particularly preferably, it can be a compound 丨 (ie compound, compound 12 or compound) Worker-3) and π-bacteria are present at 1:1 to 2:1. The mixture is particularly suitable for controlling wheat pathogens selected from the group consisting of: A. oxysporum, A. glabrata, A. fuliginea, Wheat leaf rust, A. sphaeroides and B. burgdorferi. In addition, the mixture can be used to control pathogens selected from the group consisting of Fusarium oxysporum, Fusarium graminearum, and Rhizoctonia solani. Furthermore, the mixture is suitable for controlling barley pathogens. When used in barley, 157786. Doc •23- 201210488 The preferred weight ratio of each active ingredient is 2〇:1 to ^〇, specifically 2:1 to 1. 2 In particular, it is preferred that compound 1 (i.e., compound 1-1, compound or compound 1-3) and chlorothalonil are present at from 2 to 1:1. The mixture is particularly suitable for controlling barley pathogens selected from the group consisting of barley mutans, barley grisea, barley rust, and powdery mildew. In addition, the mixture can be used to control barley pathogens selected from the group consisting of: G. sphaeroides and R. solani. According to another embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and chlorothalonil to control a soybean pathogen. When used in soybeans, the preferred weight ratio of each active ingredient is 2〇:1 to 1:20, specifically 3:1 to 1:3, and particularly preferably, compound 1 (ie, compound 1-1, Compound 1-2 or compound ^) and chlorothalonil are present at 3:1 to 2:1. In particular, the mixture is suitable for controlling soybean pathogens selected from the group consisting of soybean rust, rust potato rust, and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as against brown smut, soybean smut, soybean gray spot, bacterium, and/or Alternaria. . According to a further embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and chlorothalonil to control a corn pathogen. When used in corn, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and that it can be compound 1 (ie compound 1-1, The compound Ι·2 or the compound 1-3) and the chlorothalonil system are present at 2:1 to 1:1. In particular, the mixture is suitable for controlling corn pathogens selected from the group consisting of: corn ash pathogen, corn common rust, and corn long woven 157786. Doc •24· 201210488 bacteria. According to still another embodiment, the invention relates to the use of a binary mixture of a compound (i.e., compound, compound 1-2 or compound 1-3) and chlorothalonil to control a sugar beet pathogen. When used for sugar beet, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and especially preferably compound 1 (ie compound I-1, compound) 1-2 or compound 1-3) and chlorothalonil are present at 2:1 to 1:1. Specifically, the mixture is suitable for controlling corn pathogens selected from the group consisting of: S. cerevisiae, Saccharomyces cerevisiae, Saccharomyces cerevisiae, and S. cerevisiae. According to a further embodiment, the invention relates to the use of a binary mixture of a compound (ie compound, compound 1-2 or compound 1-3) and chlorothalonil to control, in particular, s selected from the following groundnut pathogens: groundnut balls Cavity bacteria (= genus Cercospora) and rusting bacteria. When used for groundnuts, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie, compound Μ, compound _2) Or the compound 丨-3) and the chlorothalonil system are present at 2:1 to 1:1. According to a further embodiment, the invention relates to the use of a binary mixture of compound j (ie compound, compound 1-2 or compound 1-3) and chlorothalonil to control, in particular, from the following rapeseed and canola pathogens : Sclerotinia sclerotiorum, - Brassica albicans and Alternaria alternata. When used in rapeseed or canola, the preferred weight ratio of each active ingredient is from 20:1 to 1:2, specifically from 2:1 to 1:2, and particularly preferably, it can be compounded (ie, compound, compound)丨 or compound 1-3) and chlorothalonil are present from 2:1 to 1:1. According to a further embodiment, the invention relates to a compound (ie a compound Ι_ι, 157786. Doc •25· 201210488 Binary mixture of compound 1-2 or compound ι_3) with chlorothalonil controls the use of the following rice pathogens: Rhizoctonia solani and rice fever. When used in rice, the ratio of the weight of each active ingredient is 2〇:1 to 1:2〇, specifically 2:1 to 1:2′, especially the compound can be a compound][(ie compound ji, Compound 12 or compound 1-3) is present in the range of 2:1 to 1:1 with chlorothalonil. The binary mixture of Compound 1 (i.e., Compound 1_1, Compound _2 or Compound 13) and chlorothalonil is also suitable for controlling pathogens such as the following. Turf, potato, tomato, gourd, grapes, apples, ornamental plants and bananas. The turf pathogens which can be controlled according to the invention are selected from the group consisting of silver leaf spot bacteria and Rhizoctonia solani. When used in turf, the preferred weight ratio of each active ingredient is from 20:1 to 1:20, specifically from 2:1 to 1:2, and particularly preferred is compound 1 (ie, compound hydrazine, compound L2 or The compound ^) and the chlorothalonil are present as ι:ι to ^. The potato and tomato pathogens which can be controlled according to the present invention are specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled according to the present invention is specifically melon to white powder fungus. The grape pathogens which can be controlled according to the invention are in particular Helminthosporium and Botrytis cinerea. The apple pathogens which can be controlled according to the present invention are specifically apple powdery mildew and apple scab. The ornamental plant pathogens which can be controlled according to the invention are in particular selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. The banana pathogen which can be controlled according to the present invention is specifically selected from the group consisting of a genus Fibulae and a bacterium of the genus Banana. In another aspect of the invention, the mixture is a ternary mixture comprising Compound 1 (ie Compound 1-1 'Compound 丨-2 or Compound 1-3), second active ingredient (Component 2) and third activity Ingredients (Component 3) as the active ingredient of the invention 157786. Doc -26· 201210488 Composition. Component 2 is a) fluoro "biguanamine or b) prothiophene spit, and if the site is 2 fluoropyrazolamide, component 3 is selected from a) baikemin and fenfluz; Component 2 is prothioconazole, and component 3 is selected from b) flupyrazolamide, bixafen, dexamethasone, dimoxystrobin, picoxystrobin, fluoride Azoxystrobin (fluoxastrobin), fluorine. Fluopyram and penflufen. For the purposes of the present invention, "ternary mixture" means that only three active compounds are present. The mixture may of course contain any of the additives or analogs detailed below to provide a formulation suitable for agriculture. Here, the weight ratio of Compound 1 (i.e., Compound 1-1, Compound 〖-2 or Compound ι·3) to Component 2 is 1:20 to 20:1. Preferably, the weight is in the range of from 11 Torr to 10:1, preferably from 1:3 to 3:1, specifically from 1:2 to 2:1. The weight ratio of Compound 1 (i.e., Compound 1-1, Compound Ι·2 or Compound ι_3) to Component 3 is in the range of 1:20 to 20:1. Preferably, the weight is in the range of 1:1 〇 to 1 〇:1, preferably 1:3 to 3:1, specifically 1:2 to 2:1 » Compound ι (ie Compound 1-1, The weight ratio of the compound 1_2 or the compound 1-3) to the component 3 is in the range of 1:20 to 20:1, and specifically in the range of 1:1 〇 to 1 〇:1. The weight is preferably in the range of 1:3 to 3:1, specifically 1:2 to 2:1. According to an embodiment, the present invention relates to a ternary mixture of Compound 1 (ie, Compound Μ, Compound 1-2 or Compound )), fluoropyrazolamide and cyproteren, wherein the two of the components are as follows The weight ratio is present: 2 〇: 1 to 2 〇 'more specifically 5: 1 to 1: 5' specifically 2: 1 to 1: 2. Specifically, 5, the weight ratio of the two components is: component 1 is 1:1 to 2:1 than component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is Component 3 is 1:1 to 1:2. Compared with 157786. Doc -27· 201210488 The best of these components is present in a weight ratio of 1:1:1 to 2:1:2 or 2:1:2 to 2:1:1. Surprisingly, this mixture exhibits a synergistic effect and the components are used in particular in synergistically effective amounts. According to another embodiment, the present invention relates to the use of Compound 1 (ie, Compound 1-1, Compound 1-2 or Compound 1-3), a ternary mixture of flupirtine and Baikemin to control cereal pathogens, each of which The components are used in the weight ratios mentioned above. Specifically, the weight ratio of the three components is: component i is 1:1 to 2:1 than component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is 1:1 to 1:2 » According to a specific embodiment 'the ternary mixture is used to control wheat pathogens specifically selected from the group consisting of: A. oxysporum, Polygonum vaginalis, Wheat leaf spot, Wheat Leaf rust, strip-shaped bacterium, and powdery mildew. In addition, the mixture can be used to control wheat pathogens selected from the group consisting of Fusarium oxysporum, Fusarium graminearum, and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 ' and component 2 is more than component 3 Part 3 is 1:1 to 1:2 » According to another specific embodiment, the ternary mixture is used to control barley pathogens selected from the group consisting of barley reticular bacteria, barley mutans, barley rust fungus and Brinell white powder bacteria. Furthermore, the mixture is suitable for controlling barley pathogens selected from the group consisting of: G. sphaeroides and R. solani. Specifically, the ratio of the weight of the three components is: component i is 2 to 1 for component 2; component is 1:1 to 2:1 ' for component 3 and component 2 is for component 3 is 1:1 to 1:2. According to yet another embodiment, the ternary mixture is used to control a soybean pathogen selected from the group consisting of soybean rust, Phakopsora pachyrhizi, and soybean powdery mildew. At 157786. Doc •28· 201210488 Soybean, this mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as resistance to brown smut, soybean smut, soybean gray spot, multi-capsule and/or chain Genus spp. When used in soybeans, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 3:1 to 1:3. The better ones are the three components of 1:0. 5: 丄 to 1. 0. 5. 0. The weight ratio of 5 exists. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 ' and component 2 is less than component 3 Part 3 is 1:1 to 1:2. According to yet another embodiment, the ternary mixture is used to control corn pathogens specifically selected from the group consisting of: corn leaf spot, corn common rust, and snail. When used in corn, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2. The more preferred ones are those with a weight ratio of 1: 〇 5:1 to i: 〇 5: 〇 5. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is from 1:1 to 1:2. According to yet another embodiment, the ternary mixture is used to control a beet pathogen selected from the group consisting of: the genus Beetle, the sugar beet, and the bacterium And sugar beet rust. In the case of sugar beet, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2 ^specifically, three components The weight ratio is: the component 丨 ratio component is 1. 1 to 2. 1, group injury 1 is 1:1 to 2:1 than component 3, and component 2 is 1:1 to 1:2 than component 3. According to yet another embodiment, the ternary mixture is used to control specifically 157786. Doc •29· 201210488 The groundnut pathogen selected from the following: Glomus pyogenes (=S. cerevisiae) and rusting bacteria. When used for groundnuts, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the two components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is Component 3 is 1:1 to 1:2. According to yet another embodiment, the ternary mixture is used to control rapeseed and canola pathogens selected from the group consisting of Sclerotinia sclerotiorum, Brassica oleracea, and Alternaria alternata. When used for canola or fennel, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2, component 1 is 1:1 to 2:1 to component 3, and component 2 is grouped. Part 3 is 1:1 to 1:2. According to a further embodiment, the ternary mixture is used to control, in particular, the rice pathogens selected from the group consisting of Rhizoctonia solani and rice blast fungus. When used in rice, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 2 〇 1 to 1:20' specific and § 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1, and component 2 is compared to component 3. Part 3 is 1:1 to 1:2. According to yet another embodiment, the ternary mixture is used to control pathogens such as turf, horse yam, tomato, germination, grapes, apples, ornamental plants, and bananas. The turf pathogen which can be controlled using the ternary mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. When applied to turf, the active ingredients of the ternary mixture are especially 157786. Doc -30· 201210488 The best weight ratio is 2〇: 1 to 1:20, specifically 2:1 to 1:2. The potato and the genus pathogen which can be controlled according to the present invention are specifically selected from the group consisting of Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen controlled by the ternary mixture of the present invention can be specifically Melon against powdery mildew. The grape pathogen controlled by the diterpene mixture of the present invention may specifically be a bacterium of the genus Corynebacterium and Botrytis cinerea. The apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, powdery mildew and apple scab. The ornamental plant pathogen which can be controlled by using the ternary mixture of the present invention is specifically selected from the group consisting of melon to powdery mildew, bivalve 'Alternaria spp. and Sclerotinia genus. The banana pathogen controlled by the ternary mixture of the present invention can be used. Specifically, it is selected from the group consisting of Fibulae genus Fibrio bacterium Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is component 2 to 2:1, and component 2 is component 2 It is 1:1 to 1:2. According to another embodiment, the invention relates to compound 1 (ie compound i, compound 1-2 or compound 1-3), a ternary mixture of flupyrazolamide and fenflufen, wherein two of these components The present invention is present in the following weight ratios: 2〇: j to 1:20', more specifically 5:1 to 1:5, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:3 to 1:6' and component 2 is more than component 3 Part 3 is 1:3 to 1:6. Preferably, the components are present in a weight ratio of 1:1:3 to 1:1:6. It is surprising that this mixture exhibits synergistic effects and that the components are specifically used in synergistically effective amounts. According to a specific embodiment, the invention relates to compound 1 (i.e., compound μ, compound 1-2 or compound 1-3), flupyrazolamide and fenfluzol ternary 157786. Doc -31· 201210488 The mixture is used to control cereal pathogens. The components are used in the weight ratios mentioned above. Specifically, the weight ratio of the three components is: component! The composition 2 is 1:1 to 2:1; the component 丨 is 3:1 to 1:6, and the component 2 is 1:3 to 1:6. According to another specific embodiment, the mixture is used to control a wheat pathogen specifically selected from the group consisting of: A. oxysporum, Polygonum vaginalis, Wheat leaf spot, Wheat leaf rust, Puccinia gracilis and Brinell Powdery mildew (pink mildew). According to another embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum, and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1 to 1 to 2:1 for component 2; component 1 is 1 to 3 to 66 for component 3, and component 2 is Component 3 is from 1:3 to 1:6. According to yet another embodiment, the mixture is used to control barley pathogens selected from the group consisting of barley mutans, barley grisea, barley rust, and powdery mildew. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component i is 1:3 to 1:6' and component 2 is less than component 3 Part 3 is 1:3 to 1:6 » According to yet another embodiment, Compound 1 (ie, Compound ^, Compound 12 or Compound 1-3), a mixture of flupyrazolamide and fenflufen is used to control the selection The following soybean pathogens: soybean rust, potato rust fungus and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control so-called Fdc (leaf disease syndrome), such as against brown plaque, soybean leaf spot, soybean gray spot, bacterium, and/or Alternaria. . A particularly good weight ratio of the active ingredients of the 'ternary mixture' when used in soy is 2: i 157786. Doc •32· 201210488 to 1:20, specifically 3:1 to 1:3. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:3 to 1:6' and component 2 is more than component 3 Part 3 is 1:3 to 1:6. The preferred three-component system is present in a weight ratio of 1:1:3 to 1:1:6. According to yet another embodiment, 'Compound 1 (ie, Compound 1-1, Compound 1-2 or Compound 1-3), a mixture of flupyrazolamide and fenflufen is suitable for controlling specific corn stalks selected from the following : Gray leaf spot bacteria, common rust fungus of corn and Helminthosporium cerevisiae. When used in corn, the weight ratio of the two of the active ingredients of the ternary mixture is 20:1 to 1:20, specifically Word 2:1 to 1. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:3 to 丨:6, and component 2 is compared to component 3 Part 3 is 1:3 to 1:6. According to yet another embodiment 'Compound 1 (i.e., compound ι_1, compound ι_2 or compound 1-3), a mixture of flupyrazolamide and fenflufen is used to control a sugar beet pathogen specifically selected from the following: beet raw Cercospora, sugar beet powder, bacillus sphaeroides and sugar beet rust. In the case of sugar beet, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2 〇: 1 to 1:2 〇, specifically έ 2:1 to υ. Specifically, the weight ratio of the three components is: component i is 1:1 to 2:1 than component 2; component 1 is 1:3 to 1:6, and component 2 is compared to component 3 Part 3 is 1:3 to 1:6. According to yet another embodiment, a mixture of Compound 1 (ie, Compound Μ, Compound 2 or Compound 1-3), 峻 峻 贞 贞 用于 普 福 福 福 福 福 福 福Cavity bacteria (= genus Cercospora) and rusting bacteria. When used for groundnuts, the ternary mixture lives 157786. Doc •33· 201210488 The preferred weight ratio of the two components is 20:1 to 1:20, specifically 2:ι to 1:2. Specifically, the weight ratio of the three components is: component i is 1:1 to 2:1 than component 2; component 1 is 1:3 to 1:6, and component 2 is compared to component 3. Part 3 is 1:3 to 1:6. According to yet another embodiment, Compound 1 (ie, Compound Μ, Compound 1-2 or Compound 1-3), a mixture of flupyrazolamide and fenflufen is used to control specific and § selected from the following rapeseed and fennel Pathogens: Sclerotinia sclerotiorum, Brassica oleracea and Alternaria alternata. When used for canola or canola, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2 〇: 丨 to 丨 2〇, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is ι:3 to 1:6, and component 2 is compared to component 3 Part 3 is 1:3 to 1:6. According to yet another embodiment, 'Compound 1 (ie, compound _1, compound j 2 or compound 1-3), a mixture of flupyrazolamide and fenflufen is used to control a rice pathogen selected from the group consisting of: Rhizoctonia solani and rice fever bacteria. When used in rice, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 2:1 to 1:2, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition is 1:1 to 2:1 than the component 2; the component 丨 is 3: 1:3 to 1:6, and the component is 2 Part 3 is 1:3 to 1:6. According to yet another embodiment, a mixture of Compound 1 (i.e., Compound 化合物, Compound _ or Compound 1-3), fluoropyrazolamide and fenflufen is used to control pathogens such as: Turf, potato, tomato, produce, grapes, fruit, ornamental plants and bananas. The third of the present invention can be used; the turf pathogen controlled by the mixture is specifically selected from the group consisting of silver leaf spot bacteria and Li + 157786. Doc •34· 201210488 Rhizoctonia. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, in particular 2: 丨 to 丨] can be controlled according to the invention of the potato and tomato pathogens Specifically, it is selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata, and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled by the binary mixture of the present invention are specifically, C. grisea and Botrytis cinerea. Apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the binary mixture of the present invention are specifically selected from the group consisting of G. glabrata and C. sphaeroides. Therefore, the weight ratio of the three components is particularly: component 1 is 1:1 to 2:1 to component 2; component 丨 component 3 is 1:3 to 1:6, and component 2 is component 3 is 1:3 to 1:6. According to a further embodiment, the invention relates to a compound (ie compound, compound 1-2 or compound ^), a ternary mixture of prothioconazole and flupyrazolamide, wherein both of these components are It is present in the following weight ratios: Μ] to 1·2〇, more specifically 5:1 to 1:5, specifically 2:1 to. Preferably, the components are present in a weight ratio of 1:1:1 to 2:2:1. Specifically, the weight ratio of the three components is: 1:1 to 2: 1:1, the mixture exhibits a synergistic effect and the components are specifically coordinated according to a specific embodiment. The invention relates to compound 1 (ie compound 157786. Doc -35- 201210488 1. Compound 1-2 or compound 1-3) The use of a ternary mixture of prothioconazole and flupyrazolamide to control sputum pathogens, each of which is mentioned above Use by weight ratio. Specifically, the weight ratio of the three components is: Component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is 1:1 to 2:1. According to another specific embodiment, the ternary mixture is used to control a wheat pathogen specifically selected from the group consisting of: wheat husk, sclerotium, wheat yellow leaf spot, wheat leaf bacterium, strip rust fungus and Powdery mildew (Powder's disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Rhizoctonia solani, and Wheatgrass. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is 1:1 to 2:1. According to yet another embodiment, a compound 1 (ie, a compound, a compound or a compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control a barley pathogen selected from the group consisting of: barley reticular bacteria, Barley grisea, barley rust fungus and powdery mildew. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the components is: component 1 is 1:1 to 2:i for component 2; component 丨 is 3:1 to 2:1 for component 3, and component 2 is for group Part 3 is 1:1 to 2:1. According to yet another embodiment, a mixture of compound ι (ie compound, compound i 2 or compound 1-3), thiophene sulphate and fluconazole guanamine is used to control a soybean pathogen selected from the group consisting of: soybean bacterium, bean Potato leaf rust and large: powdery mildew. In soybeans, this mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as resistance to brown spot disease, large-line spot disease 157786. Doc -36- 201210488 Bacteria, Phytophthora sojae, Pseudomonas aeruginosa and/or Alternaria. When used in soybeans, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically, from 3:1 to L3, especially for the three components. : 1:1 to 2:2:1 weight ratio exists. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 is is 2:1 ' and component 2 is component 3 is 1:1 to 2:1. According to yet another embodiment 'Compound 1 (ie compound I_1, compound or compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control a corn pathogen specifically selected from the group consisting of corn ash Spot bacterium, common rust of corn and Helminthosporium helminium. When used in corn, the preferred weight ratio of the two of the ternary mixture / tongue component is 2 〇: i to 1:2 〇, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition 丨 is 2:1 to 2:1; the component 1 is 1:1 to 2:1, and the component is 2 Part 3 is 1:1 to 2:1. According to yet another embodiment, a compound (ie, a compound hydrazine, a compound or a compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control a sugar beet pathogen selected from the group consisting of: beet tails Spores, sugar beet powder, bacillus sphaeroides and sugar beet rust. When used for sugar beets, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 5:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3:1 to 2:1, and component 2 is compared to group Part 3 is 1:1 to 2:1. According to yet another embodiment, Compound 1 (ie, Compound 1-1, Compound 1_2 or Compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control 157786. Doc •37· 201210488 Specifically, it is selected from the following groundnut pathogens: G. glabrata (= Cercospora) and rusting bacteria. The preferred weight ratio of the active ingredients of the ternary mixture for use in groundnuts is 2 〇: 丨 to 丨: 2 〇, specifically 2·1 to 1. 2 » Specific and δ, the weight ratio of the two components: component 1 to component 2 is 1. 1 to 2:1; component 1 is 1:1 to 2:1 to component 3, and component 2 is 1:1 to 2:1 to component 3. According to yet another embodiment, a compound (ie, a compound diterpenoid, a compound or a compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control a rapeseed and canola pathogen specifically selected from the group consisting of : Sclerotinia sclerotiorum, Brassica oleracea and Alternaria alternata. When used for canola or fennel, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2 〇: 1 to 1:2 〇, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component i is 1:1 to 2:1 ' and component 2 is less than component 3 Part 3 is 1:1 to 2:1. According to a further embodiment, the compound (ie compound M, compound ^ or compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control a rice pathogen selected from the group consisting of: Rhizoctonia and rice fever. A particularly preferred weight ratio of the active ingredients of the 'ternary mixture' for use in rice is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is 1:1 to 2:1. According to yet another embodiment, a compound 丨 (i.e., Compound M, Compound 2 or Compound 1-3), a mixture of prothioconazole and flupyrazolamide is used to control pathogens such as the following: Turf, Ma Ling, Fan You, 157786. Doc • 38 - 201210488 Gourds, grapes, apples, ornamental plants and bananas. The turf pathogen which can be controlled using the ternary mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, in particular from 2:1 to 1:2 ^the potato and tomato which can be controlled according to the invention The pathogen is specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the triterpene mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled using the binary mixture of the present invention are, in particular, H. grisea and Botrytis cinerea. The apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of G. glabrata and P. sphaeroides. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 component 3 is ι:ι to 2:1 ' and component 2 is compared Part 3 is 1:1 to 2:1. According to a further embodiment, the invention relates to a ternary mixture of compound 1 (ie compound oxime, compound 1-2 or compound oxime), prothioconazole and bisexafine, wherein two of the components are It is present in the following weight ratios: 2 〇: 1 to 'more specifically 5:1 to 1:5, specifically 2:1 to 1:2. Preferably, the components are present in a weight ratio of 1:1:1 to 2:2:1. Specifically, the weight ratio of the three components is: Group #1 is 1:1 to 2:1 to Component 2; Component 3 is 1:1 to 2:1, and Component 2 is composed of components. 3 is 1:1 to μ. Surprisingly, this mixture shows a synergistic effect and the components are specifically synergistically effective 157786. Doc -39- 201210488 to use. According to a specific embodiment, the invention relates to the use of compound j (i.e., compound _1, compound 1-2 or compound 1-3), a ternary mixture of prothioconazole and bisexafine to control sputum pathogens, Each of the components is used in the weight ratio mentioned above. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 to component 3, and component 2 is compared to group Part 3 is 1:1 to 2:1 » According to another embodiment, the ternary mixture is used to control specific wheat pathogens selected from the following: · A. sinensis, A. sinensis, and Yellow Leaf Spot , wheat leaf rust, strip-shaped rust fungus and white powder bacteria (powder disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component i is 1:1 to 2:1 than component 3, and component 2 is compared to group Part 3 is 1:1 to 2:1. According to yet another embodiment, the compound ι (ie, the compound hydrazone, the compound or the compound 1-3), the mixture of prothioconazole and bisaphine are suitable for controlling barley pathogens selected from the group consisting of: barley reticular bacteria, barley cloud Plasmodium rust fungus and powdery mildew. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component! The ratio of component 3 is 1:1 to 2:1, and component 2 is 1:1 to 2:! According to yet another embodiment, the compound (i.e., compound, compound U or compound 1-3), a mixture of prothioconazole and texafine is suitable for controlling a large denier pathogen selected from the group consisting of: soybean rust, bean potato Layer rust and soybean white powder 157786. Doc -40- 201210488 bacteria. In soybeans, the mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as against brown smut, soybean smut, soybean gray spot, bacterium, and/or genus . When used in soybeans, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:20, specifically 3:1 to 1:3. The preferred three-component system is present in a weight ratio of 1:1:1 to 2:2:1. Specifically, the weight ratio of the three components is: Group injury 1 is 1:1 to 2:1 for group injury 2, component 1 is 1:1 to 2:1 for component 3, and component 2 is group Part 3 is 1:1 to 2:1. According to a further embodiment, the compound 1 (i.e., compound I-1, compound Ι2 or compound 1-3), the mixture of thiophanate and bisexafine are suitable for controlling a corn pathogen specifically selected from the group consisting of: Gray leaf spot, corn common rust and Helminthosporium. When used in corn, the weight ratio of one of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically 2. 1 to 1:2. Specifically, the weight ratio of the three components is: the composition 丨 is 2:1 to 2:1; the component 1 is 1:1 to 2:1, and the component is 2 Part 3 is 1:1 to 2:1. According to yet another embodiment, the compound (ie, compound, compound or compound 1-3), a mixture of prothioconazole and bisaphine is suitable for the control device.

The specific weight ratio of the two components is 1:1 to 2:1 and the composition 2 is 2〇:1 to 1:2〇, in terms of weight ratio of the three components: component 1 group Part 1 is 1:1 to 2:1 for component 3 and 1:1 to 2:1 for component 3. 157786.doc •41-201210488 According to yet another embodiment, the compound hydrazine (ie, Compound M, Compound 12 or Compound 1-3), a mixture of prothioconazole and bisexafine is used to control specifically selected from the following The groundnut pathogen: G. sphaeroides (= genus Cercospora) and rusting bacteria. When used for groundnuts, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:2, specifically from 2:1 to 1.2. Specifically, §, the weight ratio of the two components is: component 丨 is 2:1 to 2:1 for component 2; component 1 is 1:1 to 2:1 for component 3, and component 2 is Component 3 is 1:1 to 2:1. According to yet another embodiment, the compound hydrazine (ie, compound, compound 12 or 1-3), a mixture of prothioconazole and bisaphine is used to control rapeseed and canola pathogens selected, in particular, selected from the group consisting of : Sclerotinia sclerotiorum, Brassica oleracea, and alternate bond bacteria. When used in rapeseed or canola, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2〇:1 to 1:2〇, specifically s2:l to 1:2° specifically The weight ratio of the components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 丨: 丨 to 2:1, and component 2 is 1 to component 3: 1 to 2:1. According to a further embodiment, a compound 1 (ie compound] [_1, compound 12 or compound 1-3), a mixture of prothioconazole and texafine is used to control a rice pathogen selected from the group consisting of: Rhizoctonia solani and rice fever bacteria. A particularly preferred weight ratio of the active ingredients of the 'ternary mixture' for use in rice is from 20:1 to 1:20 ‘specifically 2:1 to 1:2. Specifically, the weight ratio of the three fine components is 1:1 to 2:1 for component 2; component i is 1:1 to 2:1 for component 3, and component 2 is Component 3 is 1:1 to 2:1. According to yet another embodiment, Compound 1 (ie, Compound, Compound 12 157786.doc • 42·201210488 or Compound (IV)), a mixture of prothioconazole and bisexafine is used to control pathogens such as: : turf, potato n-box, grapes, frequency fruit, ornamental plants and fragrances'. The turf pathogen which can be controlled using the ternary mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2. The potato and tomato pathogens which can be controlled according to the present invention are specifically selected from the group consisting of tomato early blight, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled by the ternary mixture of the present invention are specifically, Corynebacterium genus and Botrytis cinerea. Apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the binary mixture of the present invention are specifically selected from the group consisting of G. glabrata and C. sphaeroides. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2:1 ' and component 2 is more than component 3 Part 3 is 1:1 to 2:1. According to a further embodiment, the invention relates to a compound (ie compound, compound 1-2 or compound 1-3), a ternary mixture of prothioconazole and penflufen, wherein both of the components are It is present in the following weight ratios: 2 〇: i to 1:20, more specifically 5:1 to 1:5, specifically 2:1 to 1:2. Preferably, the components are present in a weight ratio of 1:1:1 to 2:2:1. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is compared to group 157786.doc •43·201210488 3 is 1:1 to 2:1 And component 2 is 1:1 to 2:1 than component 3. Surprisingly, this mixture shows synergistic effects and the components are used in particular in synergistic amounts. According to a specific embodiment, the present invention relates to a ternary mixture of compound 1 (i.e., compound ι_1, compound 1-2 or compound 1-3), thiophene sulphate and pentobenzene picumamine to control sputum pathogens. Use 'These components are used in the weight ratio mentioned above. Specifically, the weight ratio of the three components is: Component 1 is 1:1 to 2:1 to Component 2; Component 1 ratio Component 3 is 1:1 to 2:1, and component 2 is 1:1 to 2:1 to component 3. According to another specific embodiment, the ternary mixture is used to control specifically selected from the following Wheat pathogens: Trichosporon hirsutum, Polyporus fulvum, Wheat Leaf spot, Wheat leaf bacterium, Strip stalk and Brinell powder (Powder emblem)

2:1, and component 2 is 1:1 to 2:1 than component 3.

Barley rust fungus and powdery mildew.

1 is more than 1:1 to 2:1 for component 2; and component 2 is 1:1 to 2:1 » for component 3, and the barley pathogen is selected from the group consisting of colloidal gossypium and s, two groups Weight ratio of component: component component 1 is 1:1 to 2:1 to component 3, and 157786.doc -44 - 201210488. According to yet another embodiment, compound ι (ie, compound 丨, compound I- 2 or compound 1-3), prothiotoxin. The mixture of sitben and fenprofen is suitable for controlling soybean pathogens selected from the group consisting of soybean rust, rust potato rust, and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as resistance to brown smut, up to purple spot pathogen, soybean gray spot pathogen, multi-spore bacillus and/or grisea Genus. A particularly preferred weight ratio of two of the active ingredients used in the large and hourly mixture is from 20:1 to 1:20 Å, specifically from 3:1 to 1:3. The preferred three-component system is present in the following weight ratios: component 1 is 1:1 to 2:1 compared to component 2; components! The composition 3 is 1:1 to 2:1 ' and the composition 2 is 1:1 to 2:1 than the component 3. According to a further embodiment, the mixture of compound 1 (ie compound 1, compound 12 or compound 1-3), prothioconazole and penflufen is suitable for controlling a corn pathogen selected from the group consisting of: corn ash Spot bacteria, common maltools of corn and snails of corn. When used in corn, the preferred weight ratio of two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2 ^specifically, three components The weight ratio is 1:1 to 2:1 for component 2; component 1 is 1:1 to 2:1 for component 3, and component 2 is 1:1 for component 3 to 2:1. According to a further embodiment, the compound (ie compound M, compound or compound 1-3), the mixture of prothioconazole and penflufen is suitable for controlling beet pathogens selected in particular from the following: beet tails Spores, sugar beet powder, bacillus sphaeroides and sugar beet rust. When used for sugar beets, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: group 157786.doc •45- 201210488 injury 1 is greater than the group injury 2 is 1:1 to 2:1; component 1 is less than component 3 is i:丨 to 2:, And component 2 is ι:ι to 2:1 than component 3. According to yet another embodiment, a compound (ie compound, compound i 2 or compound 1-3), a mixture of prothioconazole and penflufen is used to control a peanut pathogen selected from the group consisting of: groundnuts Helicobacter pylori (= genus Cercospora) and rusting bacteria. When used for groundnuts, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 2:1 to 1:2, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition is 1:1 to 2:1 than the component 2; the component i is 1:1 to 2:1 than the component 3, and the component 2 is compared to the group Part 3 is 1:1 to 2:1. According to still another embodiment, a compound (ie, compound ^, compound 2 or compound 1-3), a mixture of prothioconazole and penflufen is used to control a specific rapeseed and canola pathogen selected from the group consisting of 5胄: Sclerotinia sclerotiorum, Brassica oleracea and Alternaria alternata. In the case of rapeseed or canola, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2 〇: 〖 to 1.2 〇, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition is 1:1 to 2:1 than the component 2; the component i is 1:1 to 2:1' and the component 2 is compared to the component 3 Part 3 is 1:1 to 2:i. According to a further embodiment, the mixture of the compound (i.e. compound 1_1, compound j_2 or compound 1-3), prothioconazole and pentopyramine is also suitable for controlling the rice pathogen selected from the group consisting of: Rhizoctonia solani and rice fever bacteria. When used in rice, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 157786.doc -46 - 201210488 3 is 1:1 to 2:1 And component 2 is 1:1 to 2:1 than component 3. According to yet another embodiment, a mixture of a compound (i.e., compound ^, compound i2 or compound 1-3), prothioconazole, and penflufen is used to control a pathogen in a special use such as: turf, Potatoes, banjo, gourds, grapes, apples, ornamental plants and bananas. The turf pathogen which can be controlled using the three-component mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20 Å, specifically from 2:1 to 1:2. The squash and tomato pathogens which can be controlled according to the present invention are specifically selected from the group consisting of P. faecalis, Alternaria alternata and Rhizoctonia solani β. The cucurbit pathogen controlled by the ternary mixture of the present invention can be specifically used. It is a melon against powdery mildew. The grape pathogen which can be controlled by the ternary mixture of the present invention is specifically the genus Clostridium and the gray mold pathogen. The apple pathogen which can be controlled by the ternary mixture of the present invention is specifically apple powdery mildew and apple black spot disease. . The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of G. glabrata and P. sphaeroides. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 2. 2:1, and component 2 is more than component 2 Component 3 is 1:1 to 2:1. According to yet another embodiment, the present invention relates to a compound (i.e., compound, compound 1-2 or compound 1-3), a ternary mixture of prothioconazole and baikemin. 'Where two of these components are present in the following weight ratios: 2〇: is 1:20' more specific and Lu 5:1 to 1:5' specifically 2:1 to 1:2. The preferred one is 157786.doc •47· 201210488 These components are present in a weight ratio of 10 U1:1:2. Specifically, the weight ratio of the three components is: the group is 1:1 to 2:1 than the component 2; the component i is 1:1 to I:2 than the component 3, and the component 2 is compared with the component 3 It is 1:1 to 1:2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to a specific embodiment, the present invention relates to the use of a compound (ie, compound 1 compound τ_2 or compound 1-3), a ternary mixture of prothioconazole and baikemin to control cereal pathogens, wherein each component is in the above The weight ratio mentioned is used. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3 to 1:1 to 1:2, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to another specific embodiment, the ternary mixture is used to control a wheat pathogen specifically selected from the group consisting of: A. oxysporum, Polyporus fulvum, Wheat leaf spot, Wheat leaf rust, Puccinia striiformis and Powdery mildew (Powder's disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specifically, the weight ratio of the three components is: 1:1 to 2:1 for component 丨 component 2; 1:1 to 1:2 for component 丨 component 3, and component 2 ratio group Part 3 is 1:1 to 1:2. According to yet another embodiment, a compound (ie, Compound M, Compound 12 or Compound 1-3), a mixture of prothioconazole and cyproterone is used to control barley pathogens selected from the group consisting of: Barley Reticulum, Barley Moiré The pathogen 'barley rust fungus and white powder bacteria. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component i is more than component 3 157786.doc •48· 201210488 is 1:1 to 1:2 'And component 2 is 1:1 to 1:2 than component 3. According to yet another embodiment, 'Compound 1 (ie, Compound I-1, Compound or Compound 1-3), a mixture of prothioconazole and cyproterone is used to control a soybean pathogen selected from the group consisting of: soybean rust, bean rust Bacteria and soybean powdery mildew. In soybean, the mixture can also be effectively used to control so-called FDC (leaf disease syndrome) such as against brown smut, soybean blight, Phytophthora sojae, Pseudomonas aeruginosa and/or Bacillus licheniformis. A particularly preferred weight ratio of the active ingredients of the 'ternary mixture' when used in soy is 2 〇: j to 1.2 0, specifically έ 3 : 1 to 1:3. The three components are preferably present in the following weight ratios: component 1 is 1:1 to 2:1 to component 2; component 1 is 1 to 1 to 1:2' and component 3 is component 2 is 1:1 to 1:2 for component 3. According to yet another embodiment, a mixture of Compound 1 (ie, Compound, Compound Ι·2 or Compound 1-3), Prothioconazole, and Baikemin is used to control specific corn pathogens selected from the group consisting of: Gray Leaf Spot Pathogen , corn common type rust and corn Helminthosporium. In the case of corn, the weight ratio of one of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: 1:1 to 2:1 for component 丨; component! The ratio of component 3 is 1: 丨 to 1:2, and component 2 is '1:1 to 1:2 for component 3. According to yet another embodiment, a mixture of Compound 1 (i.e., Compound I-1, Compound Ι·2 or Compound 1-3), prothioconazole, and cyproterone is used to control a sugar bee pathogen specifically selected from the group consisting of: Saccharomyces cerevisiae, sugar beet powder, bacillus sphaeroides and sugar beet rust. When used for sugar beet, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2〇:1 to 1:2〇, with 157786.doc -49· 201210488 body 2:1 to 1:2 . Specifically, the weight ratio of the three components is: the composition t is 1:1 to 2:1 than the component 2; the component 丨 is 3 to 1:1 to ι:2, and the component 2 is compared to the group. Part 3 is 1: ι to 1:2. According to yet another embodiment, the compound hydrazine (ie, compound, compound or compound Ι·3), a mixture of thiophene sulphate and cyproterone is used to control specific and 5 selected groundnut pathogens: Phytophthora sinensis (= tail) Phytophthora) and rusting bacteria. When used for groundnuts, a particularly good weight ratio of two of the active ingredients of the ternary mixture is added to (d), specifically 2:1 to specifically 'weight ratio of the three components: component 2 It is 1:1 to 2:1; component 丨 is 3 to 1:1 to 1:2, and component 2 is 1.1 to 1:2. According to yet another embodiment, a compound (ie, compound, compound 12 or compound 1-3), a mixture of prothioconazole and dexamethasone is used to control a rapeseed and canola pathogen selected from the group consisting of: , Brassica albicans and Alternaria alternata. When used in rapeseed or canola, ternary mixed. The weight ratio of the two of the tongue components is 2〇: 1 to 1, specifically “2·1 to 1:2”. Specifically, the weight ratio of the three components is: the group is 1:1 to 2:1 than the component 2; the component Ub component 3 is 1:1 to 1:2, and the component 2 is more than the component 3 For i:i to 1:2. According to yet another embodiment, the compound (ie, compound, compound II or compound 1-3), a mixture of prothioconazole and dexamethasone is used to control, in particular, the rice pathogen H selected from the group consisting of: Bacteria and rice fever bacteria. When used in rice, the preferred weight ratio of the two of the active ingredients of the ternary mixture is to 20, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is 157786.doc •50·201210488: component 1 is 1:1 to 2:1 to component 2; component is compared to component 1:2' and component 2 It is 1:1 to 1:2 than component 3. According to yet another embodiment, the compound hydrazine (ie, compound, compound </ RTI> or compound 1-3), a mixture of prothioconazole and cyproterone is used to control pathogens such as turf, horse mash , tomatoes, gourds, grapes, apples, ornamental plants and bananas. The turf pathogen which can be controlled using the ternary mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. When used in turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2" to 1:2. The potato and tomato pathogens which can be controlled according to the invention are specifically selected from the group consisting of tomato Phytophthora, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled by the ternary mixture of the present invention are specifically, Corynebacterium genus and Botrytis cinerea. Apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew 'Bisula, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of G. glabrata and G. glabrata. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 1:2, and component 2 is compared to component 3 Part 3 is 1:1 to 1:2. According to still another embodiment, the invention relates to a compound (i.e., compound, compound 1-2 or compound 1-3), a ternary mixture of prothioconazole and leptin, wherein both of the components are It is present in the following weight ratios: 2〇: 1 to 157786.doc -51 - 201210488 1:20 ' More specifically 5:1 to 1:5, specifically 2:1 to 1:2. Preferably, the components are present in a weight ratio of 1:1:1 to 1:1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component i is 1:1 to 1:2 compared to component 3, and component 2 is compared to group Part 3 is from 1:1 to 1:2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to a specific embodiment, the present invention relates to the use of a compound strontium (i.e., Compound 1, Compound 1-2 or Compound 1-3), a ternary quinone of Propionibacterium sp. and Triamectin to control sputum pathogens, wherein Each component is used in the weight ratios mentioned above. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is component i is i: 丨 to 丨: 2, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to another specific embodiment, the ternary mixture is used to control a wheat pathogen specifically selected from the group consisting of: A. oxysporum, Polyporus fulvum, Wheat leaf spot, Wheat leaf rust, Puccinia striiformis and Powdery mildew (Powder's disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3:1 to 1:2' and component 2 is compared to component 3 Part 3 is 1:1 to 1:2. According to still another embodiment, the compound} (ie, compound, compound 2 or compound 1-3), a mixture of prothioconazole and ether oxystrobin is suitable for controlling barley pathogens selected from the following: barley reticular bacteria, Barley grisea bacteria, Puccinia graminicola and B. baumannii. According to yet another embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the three groups of 157786.doc 201210488 is: the composition 1 is 1:1 to 2:1 to the component 2; the component i is 1:1 to 1:2 than the component 3, and the group Part 2 is 1:1 to 1:2 compared to component 3. According to yet another embodiment, a mixture of Compound 1 (ie Compound 1, Compound 12 or Compound 1-3), Prothioconazole and Epibutamicin is used to control a soybean pathogen selected from the group consisting of: Soybean Rust, Sweet Potato Layer rust and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control so-called FDC (leaf disease syndrome), such as against brown smut, soybean purpura, ugly smut, polygonum and/or bacillus Genus. A particularly good weight ratio of two of the active ingredients of the 'ternary mixture' when used in soybeans is 2:1 to 1:20 'specifically 3:1 to 1:3 » especially preferred are three component systems It is present in the following weight ratio: component 1 is 1:1 to 2:1 to component 2; component i is 1:1 to 1:2 compared to component 3, and component 2 is 1:1 to component 3 To 1:2. According to a further embodiment, the compound (ie compound, compound or compound 1-3), a mixture of prothioconazole and ether oxystrobin is used to control specific corn pathogens selected from the group consisting of: maize gray spot pathogen, corn Common rust fungus and Helminthosporium helminth. When used in corn, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:2, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition 丨 is 2:1 to 2:1 compared to the component 2; the component 1 is compared to the component 3: 〖to 丨: 2, and the component 2 is compared Part 3 is 1:1 to 1:2. According to yet another embodiment, the compound! (ie compound, compound 12 or compound 1-3), a mixture of prothioconazole and ether oxystrobin for controlling beet pathogens selected from the group consisting of: beetle sp., beet powder, beetle Bacteria and sugar beet rust. When used for sugar beet, the preferred weight ratio of two of the active ingredients of the ternary mixture 157786.doc •53·201210488 is 2〇:i to 丨:2〇, specifically 2:1 to 1: 2. Specifically, the weight ratio of the three components is: component j is 1:1 to 2:1 than component 2; component 1 is m to 1:2 to component 3, and component 2 is more than component 3 It is 1:1 to 1:2. According to yet another embodiment, a mixture of Compound 1 (ie Compound 1, Compound or Compound 1-3), prothioconazole and Ethracycline is used to control a peanut pathogen selected from the group consisting of: Glomus pyogenes: = Cercospora) and rusting bacteria. When used for groundnuts, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: the composition 丨 is 2:1 to 2:1; the component 1 is 1:1 to 1:2, and the component is 2 Part 3 is from 1:1 to 1:2 » According to yet another embodiment, a mixture of Compound 1 (ie, Compound ^, Compound 1-2 or Compound 1-3), Prothioconazole, and Ethionamide is used to control specific It is selected from the following rapeseed and canola pathogens: Sclerotinia sclerotiorum, Brassica oleracea, and Alternaria alternata. When used for canola or canola, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component j is 1:1 to 2:1 than component 2; component 1 is 1:1 to 丨:2, and component 2 is compared to component 3 Part 3 is 1:1 to 1:2. According to yet another embodiment, the compound hydrazine (ie, compound, compound 12 or compound 1-3), a mixture of prothioconazole and ether oxystrobin is used to control a rice pathogen selected from the group consisting of Rhizoctonia solani and rice Heat bacteria. When used in rice, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 157,786.doc •54·201210488 20:1 to 1:20, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component! The ratio of component 2 is 1:1 to 2:1; the component is more than 1:2' and the component 2 is 1:1 to 1:2. According to yet another embodiment, a mixture of Compound 1 (ie, Compound 1-1, Compound 1-2. or Compound 1-3), prothioconazole, and Ethracycline is used to control a specific use such as Pathogens · turf, potato, tomato, rhyme, grape, Lingguo, ornamental plants and incense. The turf pathogen, which is controlled by the ternary mixture of the present invention, is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. When used on turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. The potato and tomato pathogens which can be controlled according to the invention are specifically selected from the group consisting of tomato Phytophthora, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled by the binary composition of the present invention are specifically, C. grisea and Botrytis cinerea. Apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of G. glabrata and G. glabrata. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 1 is 1:1 to 1:2' and component 2 is more than component 3 Part 3 is 1:1 to 1:2. According to still another embodiment, the present invention relates to a ternary mixture of a compound (ie, a compound, a compound 1-2 or a compound 1-3), a thiophanate, and a oxyacil ester, 157786.doc • 55· 201210488, Wherein two of the components are present in the following weight ratios: 2 〇: 1 to 1:20, more specifically 5:1 to 1:5, specifically 2:1 to 1:2. Preferably, the components are present in the following weight ratios: component Ub component 2 is 1: 丨 to; component 1 is component 1:1 to 1:2, and component 2 is component 3 It is 1:1 to 丨: 2. Surprisingly, this mixture shows a synergistic effect and the components are used in particular in synergistically effective amounts. According to a specific embodiment, the present invention relates to the use of a ternary mixture of compound (i.e., Compound _1, Compound 1-2 or Compound 1-3), prothioconazole and oxystrobin to control sputum pathogens, wherein each group The parts are used in the weight ratio mentioned above. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component i is 1:1 to 1:2 compared to component 3, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to another embodiment, the ternary mixture is used to control wheat pathogens selected in particular from the group consisting of wheat husk, scorpion venom, oocying erythema, wheat leaf rust, and rust fungus And Brucella powdery mildew (powder disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specific shi _. 'The weight of the two components

Quantitative ratio: component 1 is 1:1 to 2:1 to component 2; έ is valence] α A , and substance 1 is 1:1 to 1:2 than component 3, and component 2 is compared Part 3 is 1:1 to 1:2. According to yet another embodiment, the compound hydrazine (i.e., the compound hydrazine, the compound oxime or the compound 1-3), the prothioconazole and the oxylacide ester are &quot;wool. The materials were used to control the barley pathogens selected from the following: barley nettle bacteria, cavewort pathworm, barley stalk, and powdery mildew. According to another extravagant case, the barley pathogen is selected from the group consisting of G. sphaeroides and H. solani. Specifically, the weight ratio of the three 157786.doc -56·201210488 components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 1:2 than component 3 And component 2 is 1:1 to } :2 than component 3. According to yet another embodiment, the compound, the substance (ie compound, compound 12 or compound 1-3), the mixture of prothioconazole and picoxystrobin is used to control a soybean pathogen selected from the group consisting of: soybean rust, beans Potato leaf rust and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control the so-called 1?1) (: (leaf disease syndrome)' such as against brown smut, soybean smut, soybean gray spot, multi-spore and/or Alternaria. When used in soybeans, a particularly good weight ratio of two of the active ingredients of the binary mixture is from i to 1:20, specifically from 3:1 to 1:3. The components are present in the following weight ratios: component 1 is 1:1 to 2Q to component 2; component i is 1:1 to 1:2 compared to component 3, and component 2 is 1 to component 3: 1 to 1: 2. According to still another embodiment, the compound j (ie, the compound hydrazine, the compound ^2 or the compound 1-3), the mixture of prothioconazole and picoxystrobin is used to control specifically selected from the following Corn pathogens: Gray leaf spot, corn common rust, and Helminthosporium. When used in corn, the preferred weight ratio of two of the ternary mixture I active ingredients is 20:1 to 1:2. 〇, specifically 2 i to 1:2. Specifically, the weight ratio of the three components is: component 丨 is 2 to 2:1 for component 2; component 1 is 1 for component 3: 1 to 1:2, and component 2 is 1:1 than component 3 To 1:2. According to a further embodiment, a mixture of compound 1 (ie compound hydrazine, compound 12 or compound 1-3), prothioconazole and picoxystrobin is used to control a beet selected in particular from the following Pathogens: Saccharomyces cerevisiae, sweet powdery mildew, Saccharomyces cerevisiae and sugar beet rust. When used in sugar beet, y = 157786.doc • 57· 201210488 The weight ratio is 20:1 to 1:2〇, specifically 2:1 to L2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2Π compared with component 2; 1 is 1:1 to 1:2 for component 2, and component 2 is 1:1 to 1:2 for component 3. According to yet another embodiment, the compound 丨 (ie, compound M, compound i 2 or compound) 1-3), a mixture of prothioconazole and picoxystrobin is used to control specific groundnut pathogens selected from the group consisting of: Glomus pyogenes (= Phytophthora) and rusting bacteria. When used in groundnuts The preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically ^ to 1: 2. Specifically, the weight ratio of the three components is: Component 丨 component 2 is Η to 2:1; component i is 1:1 to 1:2 compared to component 3, and component 2 is 1:1 to 1:2. Specific examples, a compound (ie, compound, compound 12 or compound), a mixture of prothioconazole and oxybacteria are used to prepare, for example, rapeseed and canola pathogens selected from the following: Sclerotinia sclerotiorum, : Alternaria alternata and Alternaria alternata. When used in rapeseed or fennel, the weight ratio of the two of the active ingredients of the mixture is 2〇:1 to 1:2〇, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 12 to component 3, and component 2 is composed of component 3 It is 1:1 to 1:2. According to yet another embodiment, the compound hydrazine (ie, the compound M, the compound ^ or the compound, the mixture of propyl sulfide and silk) is used to prepare a rice pathogen selected from the group consisting of Rhizoctonia solani and rice cultivar The preferred weight ratio of the active ingredients used for the ternary mixture in rice is 157786.doc -58· 201210488 is 20:1 to 1:20, specifically 2:1 to 1:2. Specifically The weight ratio of the three components is: component 1 is 2 to 2:1 for component 2; component i is 1:1 to 1:2 for component 3, and component 2 is 1:1 for component 3 To 1:2. According to still another embodiment, a compound (ie, compound 'compound ^) or compound 1-3), a mixture of prothioconazole and picoxystrobin is used to control a special use such as Pathogens: turf, potato, tomato, gourd, grape, apple, ornamental plant and banana. The turf pathogen controlled by the ternary mixture of the present invention is specifically selected from the group consisting of silver leaf spot bacteria and Rhizoctonia solani. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. The potato and tomato pathogen controlled by the invention is specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen controlled by the ternary mixture of the invention can be specifically melon to powdery mildew. The grape pathogen which can be controlled by the ternary mixture of the present invention is specifically the genus Clostridium and the gray mold. The apple pathogen controlled by the ternary mixture of the present invention can be specifically apple powdery mildew and apple black star. Pathogens. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. The ternary mixture of the present invention can be used to control The banana pathogen is specifically selected from the group consisting of Fissioning Fibrio and Fibrobacter sphaeroides. Specifically, the weight ratio of the three components is: Component 1 is 1:1 to 2:1 to Component 2; Component i ratio Component 3 is 1:1 to 1:2, and component 2 is 1:1 to 1:2 to component 3. According to still another embodiment, the present invention relates to a compound hydrazine (ie, a compound, a compound 1-2 or Compound 1-3), prothioconazole and fluorocime The ternary mixture 157786.doc •59-201210488, wherein the two components are present in the following weight ratios: 20: 丨 to 1:20, more specifically 5:1 to 1:5, specific 2:1 to 1:2. Preferably, the components are present in the following weight ratios: component 1 is 1:1 to 2:1 to component 2; component 1 is 1 to component 3: 1 to 1··2, and component 2 is from 1..1 to 1:2 to component 3. It is surprising that this mixture exhibits a synergistic effect and the components are specifically used in synergistically effective amounts. According to a specific embodiment, the invention relates to the use of a ternary mixture of a compound] [(ie compound 1, compound 1-2 or compound Ι 3), prothioconazole and fluoxastrobin to control cereal pathogens, wherein Each component is used in the weight ratios mentioned above. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1 to component 3: 丨 to 丨: 2, and component 2 is group Part 3 is 1:1 to 1:2. According to another specific embodiment, the ternary mixture is used to control specific wheat pathogens selected from the following: wheat sphaeroides, sphaeroides, sphaeroides, wheat leaf rust, wheat rust And Brinell powdery mildew (Powder's disease). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component! The ratio of component 3 to ι:ι to 1:2 ′ and component 2 to component 3 is 1:1 to 1:2. According to yet another embodiment, a compound (i.e., compound, compound 12 or compound 1-3), a mixture of prothioconazole and fluoxastrobin is used to control barley pathogens selected from the group consisting of: barley reticular mites, barley Moles, rust fungus and powdery mildew. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the 157786.doc-60-201210488 component is: component i ratio component 2 is 1:1 to 2:1; component 丨 is 3:1 to 1:2' for component 3 and component 2 is 1:1 to 1:2 for component 3. According to yet another embodiment, the compound (ie, compound, compound or compound 1-3), a mixture of prothioconazole and fluoxastrobin is used to control a soybean pathogen selected from the group consisting of: soybean rust, bean rust Bacteria and Soybean powdery mildew In soybeans, the / compound can also be effectively used to control so-called FDC (leaf disease syndrome), such as resistance to brown spot bacteria, soybean purple spot pathogen, soybean gray spot pathogen, multi-spore / or Alternaria. When used in soybeans, a particularly preferred weight ratio of two of the active ingredients of the binary mixture is from 2:1 to 1:20, specifically from 3:1 to 1:3. The three components are preferably present in the following weight ratios: component 1 is 1:1 to 2:1 to component 2; component i is 1:1 to 1:2' and component 2 is less than component 3 and component 2 It is 1:1 to 1:2 than component 3. According to a further embodiment, a mixture of compound 1 (ie compound 丨 丨, compound or compound 1-3), prothioconazole and fluoxastrobin is used to control a corn pathogen selected in particular from the following: corn ash Spot bacterium, common rust of corn and Helminthosporium helminium. When used in corn, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20 Å, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 丨:2 to component 3, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to a further embodiment, the compound (ie compound, compound 1-2 or compound 1-3), a mixture of prothioconazole and fluoxastrole is used to control a beet pathogen selected from the group consisting of: beet raw Cercospora, sugar beet powder, bacillus sphaeroides and sugar beet rust. When used for sugar beet, the preferred weight ratio of the two of the active ingredients of the ternary mixture 157786.doc -61 - 201210488 is 20:1 to 1:20, specifically 2:1 to 1:2 β Specifically, the weight ratio of the three components is: group ratio component 2 is 1:1 to 2:1; component! The ratio of component 3 is 1:1 to 1:2, and component 2 is 1:1 to 1:2 than component 3. According to yet another embodiment, a compound (i.e., compound, compound 12 or compound 1-3), a mixture of prothioconazole and fluoxastrobin is used to control a peanut pathogen selected from the group consisting of: arachnoid = Cercospora) and rusting bacteria. When used for groundnuts, a particularly preferred weight ratio of two of the active ingredients of the ternary mixture is from 20:1 to 1:2, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 1:2 compared to component 3, and component 2 is compared to group Part 3 is from 1:1 to 1:2. According to yet another embodiment, a mixture of Compound 1 (ie, Compound 丨_1, Compound or Compound 1-3), Propionithiocyanate and Fluoramicin is used to control specific It is selected from the following rapeseed and canola pathogens: Sclerotinia sclerotiorum, Brassica oleracea, and Alternaria alternata. When the vehicle is used for rapeseed or canola, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:2, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: 1:1 to 2:1 for component 2; component 1 is 1:1 to 1:2 for component 3, and component 2 is Component 3 is 1:1 to 1:2. According to yet another embodiment, 'Compound 1 (ie Compound 1_1, Compound 1_2 or Compound 1-3), a mixture of prothioconazole and fluoxastrobin is used to control a rice pathogen selected from the group consisting of: Nuclear bacteria and rice fever bacteria. When used in rice, the preferred weight ratio of the two components of the ternary mixture is 157786.doc • 62· 201210488 is 20:1 to 1:20, specifically 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3 to 1:1 to 1:2, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to yet another embodiment, the compound (i.e., Compound M, Compound or Compound 1-3), a mixture of prothioconazole and fluoxastrobin is used to control pathogens such as: turf Horse, potato, tomato, gourd, grape, apple 'ornamental plants and bananas. The turf pathogen which can be controlled using the ternary mixture of the present invention is specifically selected from the group consisting of a silver leaf spot pathogen and a Rhizoctonia solani. A particularly preferred weight ratio of the active ingredients of the 'ternary mixture' when used in turf is from 20:1 to 1:20, specifically from 2:1 to 1:2. The potato and tomato pathogens which can be controlled according to the present invention are specifically selected from the group consisting of P. faecalis, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogens which can be controlled by the ternary mixture of the present invention are specifically, Corynebacterium genus and Botrytis cinerea. Apple pathogens which can be controlled using the ternary mixture of the present invention are, in particular, apple powdery mildew and apple black spot. The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of G. glabrata and G. glabrata. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component i is 1:1 to 1:2 compared to component 3, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to a further embodiment, the invention relates to a ternary mixture of compound j (ie compound 'compound 1-2 or compound 1-3) 'propioconazole and acesulfame 157786.doc -63· 201210488 (orysastrobm) Wherein two of the components are present in the following weight ratios: 2〇: 1 to 1:2〇, more specifically 5:1 to 1:5, specifically 2:1 to 1:2. Preferably, the components are present in the following weight ratios: Component 1 is from 1:1 to 2:1 in component 2; and components! The specific component 3 is 2, and the component 2 is 1:1 to 1.2 than the component 3. Humans. Α ^ 7 people were surprised that this mixture showed a synergistic effect and the components were specifically used in synergistically effective amounts. According to a specific embodiment, the present invention relates to the use of a compound mixture of compound j (i.e., compound _1, compound 1-2 or compound (iv)), and a ternary mixture of prothioconazole and acesulfame to control cereal pathogens, each of which The components are used in the weight ratios mentioned above. Specifically, t, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3:1 to 1:2, and component 2 is compared Part 3 is 1:1 to 1:2. According to another specific embodiment, the ternary mixture is used to control a wheat pathogen specifically selected from the group consisting of: wheat sphaeroides, stalks and stalks? Package, wheat yellow leaf spot, wheat leaf iron fungus, bar-shaped fungus and powdery mildew (powder mildew). According to another specific embodiment, the wheat pathogen is selected from the group consisting of Fusarium oxysporum, Fusarium graminearum and Rhizoctonia solani. Specifically, the weight ratio of the three components is: the composition 丨 is 1 part 2 is 1:1 to 2:1 丨 the composition 1 is 1:1 to 1:2 than the component 3, and the composition 2 ratio Component 3 is 1:1 to 1:2. According to yet another embodiment, the compound hydrazine (ie, the hydrazine compound, the compound 12 or the compound 1-3), the mixture of prothioconazole and the anthraquinone are used to control a barley pathogen selected from the group consisting of: barley reticular bacteria, Barley grisea, barley rust fungus and powdery mildew. According to another specific embodiment, the barley pathogen is selected from the group consisting of G. sphaeroides and Rhizoctonia solani. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component K component 3 is 157786.doc -64·201210488 1:1 to 1:2, And component 2 is 1:1 to 1:2 than component 3. According to yet another embodiment, a mixture of Compound 1 (ie Compound 1, Compound or Compound 1-3), Prothioconazole and Oxystrobin is used to control a soybean pathogen selected from the group consisting of: Soybean Rust, Soybean Rust and soybean powdery mildew. In soybeans, the mixture can also be effectively used to control so-called Fj)c (leaf disease syndrome), for example against brown smut, soybean smut, soybean gray spot, bacterium, and/or Alternaria Genus. When used in soybeans, the preferred weight ratio of the two of the active ingredients of the ternary mixture is 2:1 to 1:20, specifically 3:1 to 1:3. The three components are preferably present in the following weight ratios: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 1:2' to component 3 and component 2 It is 1:1 to 1:2 than component 3. According to a further embodiment, a mixture of Compound 1 (ie Compound 1, Compound 12 or Compound 1-3), Prothioconazole and Oxystrobin is used to control specific &amp; corn pathogens selected from: corn Gray spot bacterium, common rust fungus of corn and Helminthosporium cerevisiae, when used in corn, a particularly good weight ratio of two of the active ingredients of the ternary mixture is 2:1 to 1:20, specifically 2: i to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 to component 2; component 1 is 1:1 to 1:2 to component 3, and component 2 is compared to group Part 3 is 1:1 to 1:2. According to a further embodiment, a mixture of compound 1 (i.e., compound hydrazine, compound 1; 2 or compound 1-3), prothioconazole and emodiamine is used to control a sugar beet pathogen selected from the group consisting of: beet Cerevisiae, sugar beet powder, sugar beet column and sugar beet rust. In the case of sugar beet, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:2 〇, and from 157786.doc -65 to 201210488, from 2:1 to 1:2. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 3 is 丨: 丨 to 丨: 2, and component 2 is compared to group Part 3 is from 1:1 to 1:2. According to yet another embodiment, a mixture of a compound (ie, Compound 1-1, Compound 1_2 or Compound 1-3), Prothioconazole, and Oxanthin is used for control. Specifically, it is selected from the following groundnut pathogens: Glomus pyogenes (=S. cerevisiae) and rusting bacteria. A particularly preferred weight ratio of the two active ingredients of the two 7G blends for use in groundnuts is 2:2 to 2, specifically 2" to 1:2. Specifically, the weight ratio of the three components is that component 1 is 1:1 to 2:1 to component 2; component 1 is component i is i: j to 1.2, and component 2 is component 3 It is 1 ·· 1 to 丨: 2. According to yet another embodiment, a mixture of Compound 1 (ie, Compound 1-1, Compound 1-2, or Compound 13), prothioconazole, and Oxystrobin is used to control rapeseed and canola, specifically selected from the group consisting of Pathogens: Sclerotinia sclerotiorum, Brassica oleracea and Alternaria alternata. When used for canola or canola, the preferred ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2. Specifically, the weight ratio of the three components is: group ratio component 2 is 1:1 to 2:1; component 1 is component 1:1 to 1:2, and component 2 is component 3 It is 1:1 to 1:2. According to still another embodiment, the compound (ie compound compound or compound 1-3), the mixture of prothiotoxin and (iv) alginate is used for control; the body is selected from the following rice pathogens: Rhizoctonia solani and Rice fever bacteria. ^ When used in rice, the preferred weight of two of the active ingredients of the ternary mixture is from 20:1 to 1:20, specifically from 2:1 to 1:2.罝丹 plating and §, the weight ratio of the three groups of funeral: component 1 is less than component 2 is 1:1 to 2. 〗 〖Know eight, 勹 master 1, component 1 is less than component 3 1:1 to 1 : 2, and component 2 is 1:1 to 丨: 2 than component 3. 157786.doc -66 - 201210488 According to yet another embodiment, a compound hydrazine (ie, compound, compound 12 or compound 1-3), a mixture of prothioconazole and acesulfame, is used to control a special use such as Pathogens: turf, potato, tomato, gourd, grape, apple, ornamental plant and banana. The turf pathogen controlled by the ternary mixture of the present invention is specifically selected from the group consisting of silver leaf spot bacteria and Rhizoctonia solani. In the case of turf, the preferred weight ratio of the two of the active ingredients of the ternary mixture is from 20:1 to 1:2, in particular from 2:1 to 1:2 ^, which can be controlled according to the invention The potato and tomato pathogens are specifically selected from the group consisting of tomato Phytophthora infestans, Alternaria alternata and Rhizoctonia solani. The cucurbit pathogen which can be controlled using the ternary mixture of the present invention is specifically melon to powdery mildew. The grape pathogen controlled by the ternary mixture of the present invention, in particular, the genus Rhizoctonia solani and Botrytis cinerea, can be controlled by the ternary mixture of the present invention, specifically apple powdery mildew and apple black spot disease . The ornamental plant pathogens which can be controlled using the ternary mixture of the present invention are specifically selected from the group consisting of melon to powdery mildew, bivalve, Alternaria and Sclerotinia. Banana pathogens which can be controlled using the binary mixture of the present invention are specifically selected from the group consisting of G. glabrata and C. sphaeroides. Specifically, the weight ratio of the three components is: component 1 is 1:1 to 2:1 than component 2; component 丨 is 3:1 to 1:2' and component 2 is compared to component 3 Part 3 is 1:1 to 1:2. It has been found according to the invention to simultaneously (i.e. jointly or separately) administer compound 1 (i.e. compound I·bu compound #2 or compound 1-3) (component 1} and component 2, or sequentially apply compound hydrazine (ie compound) M, Compound 12 or Compound _ = (Component 1), Component 2 and the other active compound specified herein (Component 3) allow for better control of harmful fungi than individual compounds (collaboration mixture ^ 157786.doc • 67- 201210488 As mentioned above, these mixtures are of interest in order to reduce the rate of application, as many of the mixtures show improved activity against harmful fungi, especially certain indications, by reducing the total amount of active compound applied. Simultaneously (ie, in combination or separately), Compound 1 (ie, Compound Μ, Compound 12 or Compound [_ 3] (Component 1) and Component 2, or Compound [(ie Compound Μ, Compound ΐ 2 or Compound (Component) D, component 2 and component 3 may enhance the fungicidal activity in a superadditive manner. For the purposes of the present invention, co-administration means a compound (i.e., compound ι_ι, compound 1-2 or compound 1-3) and components At least one of 2 or a combination At least one of the substance 1-1, the compound 1-2 or the compound ^", the component 2 and the component 3 is simultaneously present at the site of action in an amount sufficient to effectively control the growth of the fungus (ie, the plant-damaging fungus to be controlled and Its habitat, such as the recipient, plant propagation material (specifically seed, soil, material or space) and the plant 'plant propagation material (specifically seed, soil, material or space) to be protected against fungal attack). This can be achieved by the combined application of compound j (ie compound, compound 1-2 or compound ι.3) and component 2 or one of components 2 and 3 in a combined active compound formulation, or at least Simultaneous application of the two separate active compound formulations; or sequential application of the active compound to the site of action, the time interval between administration of the individual active compounds being selected such that the first active compound is administered in sufficient amount when the other active compound is administered Present at the site of action. The order in which the active compound is applied is not critical. The invention also relates in particular to fungicidal compositions comprising an active ingredient as defined herein And (if appropriate) one or more agriculturally suitable agents 157786.doc -68 · 201210488. The components of the compositions of the invention may be packaged separately and in the form of a ready-to-use mixture or a multi-part kit. Packaged and used. These kits may comprise one or two, or even all, of the components useful in the preparation of the agrochemical compositions of the present invention. For example, the kits may comprise one or more kills. A fungicide component and/or an adjuvant component and/or an insecticide component and/or a growth regulator component and/or a herbicide. One or more components may be present in a combined or pre-formulated form. In embodiments in which two or more components are provided in the group, the components may be combined with each other and packaged in a single container (e.g., a vessel, bottle, can, bag, bag, or metal can). In other embodiments, two or more of the kits may be packaged separately, i.e., without pre-conditioning or mixing. The kit may comprise one or more separate containers (e.g., vessels, bottles, cans, bags, bags or metal cans), each container comprising a separate component of the agrochemical composition. The components of the compositions of the present invention may be packaged and used separately, or packaged and used in the form of a ready-to-use mixture or a multi-part kit. In either form, the components may be used separately or in combination with other components or as part of a kit of parts of the invention&apos; used to prepare a mixture of the invention. The user typically uses the compositions of the present invention in a pre-dispensing device, a knapsack sprayer, a spray can or a spray plate. Here, the agrochemical composition is diluted with water and/or a buffer to a desired application concentration, and if other adjuvants are suitably added, thereby obtaining a ready-to-use spray liquid or an agrochemical composition of the present invention. Typically 5 to 5 liters, preferably 1 to 400 liters of ready-to-use spray liquid is applied per hectare of agricultural use. 157786.doc •69· 201210488 According to the “Examples”, the user may personally mix individual components (eg, parts of the kit or a mixture of two or three components of the composition of the invention) in a spray can' and if appropriate Other adjuvants (tank mix). In another embodiment, the user may mix the two individual components of the composition of the invention in a spray can and partially premix the components, and if appropriate, add other adjuvants (tank mix). In other embodiments, the user may combine (e.g., in tank mix) or sequentially use the two individual components of the compositions of the present invention and partially premix the components. Preferably, the mixtures and compositions of the present invention control fungal pathogens in such agricultural crops as well as in propagation material (e.g., seeds) and harvested products of such plants. The term plant propagation material comprises all reproductive parts of a plant (eg seeds) and vegetative plant parts (eg seedlings and tubers (eg potatoes)) which can be used to propagate plants, such plant propagation materials including seeds, roots, fruits, tubers, Bulbs, rhizomes, shoots and other plant parts, including seedlings and young plants transplanted after germination or emergence. Young plants can be protected from harmful fungi by partial or complete treatment, for example by dipping in water. The plant propagation material line is treated with the inventive mixture or composition for controlling a plurality of fungal pathogens in cereal crops such as wheat, barley, barley or swallow U, corn, cotton and soybean. According to the invention, crop plants which have been mouth-groomed by breeding, mutagenesis or genetic engineering methods, including biotech agricultural products which are commercially available or under development (1), see, for example, http://www.bi〇〇rg/speeches /pubs/er/ag, 157786.doc 201210488 products.asp). Genetically modified plant line genetic material has been modified in such a way that it will not be modified under natural conditions by hybridization, mutation or natural recombination (i.e., recombination of genetic information). In general, one or more genes are integrated into plant genetic material to improve plant characteristics. Such modifications achieved by genetic engineering include post-translational modifications of proteins, oligopeptides or polypeptides, for example by glycosylation or polymers (eg, prenylation, acetamylation or farnesylation groups or PEG) The attachment of the group) is achieved. By way of example, mention may be made of plants which have been rendered tolerant to certain herbicide species by breeding and genetic engineering. Such herbicides are, for example, auxin herbicides such as dicamba or 2 , 4-D; an albino herbicide, such as a hydroxyphenylpyruvate dioxygenase (HPPD) inhibitor or a phytoene dehydrogenase (PDS) inhibitor; an acetaminolate synthase (Als) inhibitor, For example, sulfonylurea; enol acetone oxalic acid-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate; glutamate synthase (GS) inhibitors, such as glufosinate; lipids Biosynthesis inhibitors, such as acetyl-C0A carboxylase (ACCase) inhibitors or benzonitrile herbicides (such as bromoxynil or iodobenzonitrile). In addition, crop plants that are resistant to a plurality of herbicide species due to a plurality of genetic manipulations, such as resistance to jiaphosphorus and chlorpyrifos, or to chlorhexidine and different types of herbicides (eg, ALS inhibition) are produced. Agents, HPPD inhibitors, auxin herbicides or ACCase inhibitors) are resistant. Such herbicide resistant techniques are described, for example, in Pest Managem. Sci. 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332 ; Weed Sci. 57, 2009, 108 ; Austral. J. Agricult. 157786.doc -71 201210488

Res. 5 8, 2007, 708; Science 316, 2007, 1185; and references cited therein. For example, by breeding and mutagenesis, Clearfield® canola (BASF SE, Germany) or sulfonylurea herbicide (such as bensulfuron-methyl) that is resistant to imidazolinones (such as imazamox) is produced. (tribenuron)) Tolerant ExpressSun® to DuPont USA. Genetically engineered methods to produce crop plants (eg, soybean, cotton, corn, sugar beet, and canola) that are resistant to galaxie or chlorpyrifos, and which are available under the trade name RoundupReady® (Monsanto, USA), Cultivance® (^°^ Lin Sun Resistance, BASF SE, Germany) and Liberty Link® (Bayer CropScience, Germany) were obtained. The invention also includes plants which produce one or more toxins (e.g., toxins of Bacillus bacterial strains) by genetic engineering intervention. Toxins produced by such genetically modified plants include, for example, insecticidal proteins of the genus Bacillus (B. thuringiensis), such as endotoxin CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl. , Cry9c, Cry34Abl or Cry35Abl; or vegetative insecticidal protein (VIP), such as VIP1, VIP2, VIP3, or VIP3A; nematode colonizing bacteria (such as Photorhabdus spp. or Xenorhabdus spp) ·)) insecticidal proteins; toxins of animal organisms, such as wasps, spiders or scorpion toxins; mycotoxins, such as from Streptomycete; plant lectins, such as from cowpea or barley; lectins; Inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, serum prion protein 157786.doc -72-201210488 (cystatin) or papain inhibitor; ribosome inactivating protein (RIP), eg T-toxin (dein), corn maid, acacia, bean awn (ow), loofah toxin (luffm), 4 grass toxic protein (sap () rin) or different strains White (bryodm); steroid-metabolizing enzymes, such as 3_base steroid oxidase, steroid steroid-IDP glycosyltransferase, cholesterol oxidase, quercetin inhibitor, or HMG-CoA reductase; ion channel block 胄Such as nanochannel or word channel inhibitor; juvenile hormone vinegar; diuretic hormone receptor (helicokinin receptor); stilbene synthase bibenzyl synthase, chitinase and glucosinolate Carbohydrase. In plants, the toxins can also be produced in the form of protoxins, hybrid proteins or truncated proteins or otherwise modified proteins. Hybrid proteins are characterized by novel combinations of different protein domains (see, for example, WO 2002/015701). Other examples of such toxins or genetically modified plants producing such toxins are disclosed in the following documents: ep a 374 753, WO 93/07278 WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/1 8810 and WO 03/52073. Methods of producing such genetically modified plants are known to those skilled in the art and are disclosed in For example, the publication A mentioned above. A plurality of the above-mentioned toxins confer tolerance to all arthropod pests of the plant producing the same, in particular to beetles (Coeleropta), double-winged insects (double The tolerance of the genus Diptera (Lepidoptera) and the nematode (Nematoda) ί&quot; genetically modified plants that produce '~ or a variety of genes encoding insecticidal toxins are described (eg The publications mentioned above, and some of them are commercially available, such as YieldGard® (a maize variety that produces the toxin CrylAb), YieldGard® Plus (a corn that produces the toxin CrylAb and Cry3Bbl 157786.doc • 73 - 2012104 88 variants), Starlink® (a maize variety producing the toxin Cry9c), Herculex® RW (a maize variety producing the toxin Cry34Abl, Cry35Abl and phosphinothricin-N-acetyltransferase [PAT]) ; NuCOTN® 33B (cotton variant producing toxin Cryl Ac), Bollgard® 1 (cotton variant producing toxin CrylAc), Bollgard® 11 (cotton variant producing toxin CrylAc and Cry2Ab2); VIPCOT® (cotton variant producing VIP toxin) NewLeaf® (potato variety producing toxin Cry3A); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Btll (eg Agrisure® CB) and Btl76 from Syngenta Seeds SAS, France (to produce toxin CrylAb and A corn variety of the PAT enzyme), MIR604 from Syngenta Seeds SAS, France (a modified maize form that produces a toxin Cry3 A, see WO 03/018810), MON 863 from Monsanto Europe SA 'Belgium (a corn producing toxin Cry3Bbl) Variant), IPC 531 from Monsanto Europe SA, Belgium (modified variant of cotton producing toxin CrylAc) and Pioneer Overseas Corporation, Belgium of 1507 (corn variety CrylF toxin and the enzyme PAT). The invention also encompasses plants which, by genetic engineering, produce one or more proteins having increased resistance to bacterial, viral or fungal pathogens, such as pathogenicity-related proteins (PR proteins, see EP-A 0 392). 225) a resistance protein (eg, a potato variety that produces two resistance genes against Phytophthora infestans, derived from wild type Mexican potato (Solanum bulbocastanum) or T4 lysozyme (For example, a potato variety that is resistant to bacteria such as Erwinia amylvora by the production of this protein.) &quot;, 7 The present invention also includes the use of genetic health methods to increase productivity. Plants, for example, by increasing potential yields (eg, biomass, grain yield, starch oil or protein content), tolerance to drought, salt or other limiting environmental factors, or pests and And the resistance of the viral pathogen to improve. The invention also includes that the ingredients have been modified by genetic engineering methods to improve, in particular, humans or animals. Edible plants, for example, oily plants that produce long-chain co3 fatty acids or monosaturated fatty acids that promote health (eg, Nexera8 canola, DOW Agro Sciences, Canada). The invention also includes modifications by genetic engineering methods to improve the production of raw materials. Plants, for example, by increasing the amylopectin content in potatoes (Amflora® horse yam, BASF SE, Germany). The compounds of formula I may exist in a variety of crystal modifications having different biological activities. Mixtures thereof are included in the scope of the invention By treating a harmful fungus, its habitat, or a plant or plant propagation material (eg, seed material), soil, area, material, or space protected by fungal attack with a fungicidal effective amount of the mixture of the invention. Or using the mixture of the invention in the form of a composition. The application can be carried out before and after the fungal infection of the plant, the plant propagation material (eg seed material), the soil, the area, the material or the space. It can be during sowing or even before sowing, Or with the invention during the transplant or even before the transplant Or a composition thereof for the prophylactic treatment of plants 157786.doc • 75- 201210488 propagation material. The invention additionally relates to agrochemical compositions comprising a solvent or solid carrier and a mixture of the invention, and also for controlling harmful fungi Use herein. The term "formulation" often has the same meaning as "composition," in particular, agrochemical composition and "mixture." The agrochemical composition comprises a fungicidally effective amount of a mixture of the invention. "Effective amount" means an amount of an agrochemical composition or mixture of the invention sufficient to control a harmful fungus on a crop plant or in the protection of the material and building and without causing any significant damage to the treated crop plant. This amount can vary over a wide range and can be affected by a variety of factors, such as harmful fungi to be controlled, individual crop plants or materials to be treated, climatic conditions, and compounds. Compound ι (ie compound, compound or compound 13) and component 2, or compound 1 (ie compound N1, compound 12 or compound ΐ3), group injury 2 and group injury 3 can be simultaneously (joined or separated) or sequentially Applied, and in the case of separate application, the order of application generally has no effect on the control results. Seeds, plants or soils are sprayed or applied separately or in combination to apply Compound 1 (ie, quinone 1-1, compound J_2 or compound 13) before or after plant planting, or before or after emergence of the plant. (Component i) and Component 2, or Compound 1 (ie Compound 1-1, Compound 1-2 or Compound 13), Component 2 and Group Injury 3 or a mixture of such components, thereby controlling harmful fungi The method. Chemical substance ι (ie compound κ, compound 12 or compound 13) (component 1) and group injury 2, or compound j (ie compound, compound ΐ 2 or compound _ 157786.doc • 76- 201210488 3) (group) Parts 1), 2 and 3 may be present in the combined composition or in separate compositions. Here, the type and preparation of the compositions correspond to the types and preparations set forth herein in the general manner for the compositions. Compound 1 (ie, Compound 1-1, Compound 1-2 or Compound 1-3) (Component 1) and Component 2, or Compound 1 (ie Compound 1-1, Compound 1-2 or Compound 1-3) (Component 1), Component 2 and Component 3, and their N-oxides and salts and mixtures thereof are converted into conventional types of agrochemical compositions, such as solutions, emulsions, suspensions, spreaders, powders , paste and granules. The type of composition will depend on the respective intended purpose; in each case, a fine uniform distribution of the individual compounds in the mixture of the invention will be ensured. Here, examples of the type of composition are suspensions (SC, OD, FS), emulsifiable concentrates (EC), emulsions (EW, EO, ES), pastes, pastilles, wettable powders or spreads. Agents (WP, SP, SS, WS, DP, DS) or water soluble or water dispersible (wettable) particles (GR, FG, GG, MG), as well as plant propagation materials such as seeds Gel (GF). In general, the type of composition (eg, EC, SC, OD, FS, WG, SG, WP, SP, SS, WS, GF) is used in diluted form. Composition types such as DP, DS, GR, FG, GG, and MG are generally used in undiluted form.

Agrochemical compositions are prepared in a known manner (see, for example, us 3,060,084; EP_A 707 445 (for liquid concentrates); Browning, "Agglomeration", Chemical Engineering, December 4, 1967, 147-48; Perry's Chemical Engineer's Handbook , 4th edition, McGraw-Hill, New York, 1963, 8-57 and following pages; WO 157786.doc-77-201210488 91/13546; US 4,172,714; US 4,144,050; US 3,920,442; US 5,180,587; US 5,232,701; US 5,208,030; GB 2,095,558; US 3,299,566; Klingman: Weed Control as a Science (John Wiley &amp; Sons, New York, 1961); Hance et al.: Weed Control Handbook (8th ed., Blackwell Scientific Publications, Oxford, 1989); Mollet, H. and Grubemann, A. : Formulation technology (Wiley VCH Verlag, Weinheim, 2001)). The agrochemical compositions may additionally comprise adjuvants customarily used in crop protection compositions, the choice of which depends on the particular form of use or active compound. Examples of suitable adjuvants are solvents, solid carriers, surfactants (eg other solubilizers, protective colloids, wetting agents and tackifiers), organic and inorganic thickeners, bactericides, antifreeze agents, defoaming agents A coloring agent and, if appropriate, a coloring agent (for example for seed treatment). Suitable solvents are water, organic solvents (such as mineral oil fractions with medium to high boiling points, such as kerosene and diesel, and coal tar; also plant or animal oils; aliphatic, cyclic and aromatic hydrocarbons, such as paraffin, tetrahydronaphthalene, Alkylated naphthalene and its derivatives, alkylated benzene and its derivatives; alcohols such as methanol, ethanol, propanol, butanol and cyclohexanol, diols; ketones such as cyclohexanone, γ-butyrolactone , dimethyl fatty decylamine, fatty acids and fatty acid esters; and strong polar solvents, such as amines, such as Ν-methyl η pirinone ρ In principle, solvent mixtures can also be used, as well as the solvents mentioned above Mixture with water. Solid carrier is mineral soil, such as alumina, tannin, niobate, talc 157786.doc •78· 201210488 powder, kaolin, limestone, lime, chalk, bolus, loess, clay , dolomite, Shiyuezao soil, sulfuric acid #5 and sulfuric acid town, oxidation town, polished plastic, fertilizer (such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea) and plant products (such as corn flour, bark powder, sawdust and Nutshell powder, Cellulose powder) or other solid carrier. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants and emulsifiers) are aromatic acid (eg lignin continuous acid (Borresperse® type, Borregaard) , Norway), Benzene acid, naphthoic acid (Morwet® type, Akzo Nobel, USA) and dibutylnaphthalene sulfonic acid (Nekal® type, BASF, Germany)) and alkali metal salts and alkaline earth metal salts of fatty acids And ammonium salts; alkyl- and alkaryl sulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates; also sulfated hexanol, heptanol and stearyl alcohol, and fatty alcohols a salt of an alcohol ether; a condensate of a sulfonated naphthalene and a derivative thereof with formaldehyde, a condensate of naphthalene or naphthalenesulfonic acid with phenol and furfural; a polyoxyethylene octylphenol ether, an ethoxylated isooctylphenol, a octyl Phenol or nonylphenol, alkyl phenyl polyglycol ether, tributyl phenyl polyglycol ether, alkyl aryl polyether alcohol, isotridecyl alcohol, fatty alcohol / ethylene oxide condensation , ethoxylated castor oil, polyoxyethylene alkyl ether or polyoxypropylene alkyl ether, lauryl polyethylene glycol ether acetate, sorbitol , lignin sulfite waste liquid; also protein, denatured protein, polysaccharide (such as methyl cellulose), hydrophobically modified temple powder, polyvinyl alcohol (Mowiol® type, Clariant, Switzerland), poly- oxalate ( Sokalan® type, BASF, Germany), polyoxyl compound, polyethylene amine (Lupamin® type, BASF, Germany), polyethyleneimine (Lupasol® type, BASF, Germany), polyethylene bismuth ratio Lozenketone and its total 157786.doc -79- 201210488 polymer. Thickeners (ie, compounds that impart improved flow characteristics (ie, high viscosity at rest and low viscosity in motion) to the composition) Polysaccharides and organic and inorganic layered extensions such as xanthan gum (Kelzan®, CP Kelco, USA), Rhodopol® 23 (Rhodia)

France) or Veegum® (R.T. Vanderbilt, USA) or Attaclay® (Enge Ihard, NJ, USA). A bactericide may be added to stabilize the composition. Examples of bactericides are based on the following bactericides: diclosan and benzyl alcohol hemi-restriction (from ICI)

Proxel® or Acticide® RS from Thor Chemie and from R〇hm &amp;

Haas's Kathon® MK), as well as heterodyne ketone derivatives (such as thioisothiazolinone and benzisothiazolinone (from Acticide® MBS from Thor Chemie). Examples of suitable antifreezes are ethylene glycol. , propylene glycol, urea and glycerin. Examples of defoamers are polyoxyn oximes (for example, 汕(10)8SRE 'Wacker' Germany or Rh〇d〇rsil16 'R〇dia, long-chain alcohols, fatty acids, fatty acid salts, organofluorine compounds And mixtures thereof. Examples of colorants are both water-soluble pigments and water-soluble dyes. Examples which may be mentioned are known dyes and pigments, which are named: Rhodamin B &gt; C τ ^ , II·颜枓红112 and C·〗·Solvent Red 1, Pigment Blue 15:4, Pigment Blue 15:3, Sister Sister Soft Blue 15:2, Pigment Blue 15j, Pigment Blue 80, Pigment Yellow 1, Pigment Sound n, 13 pigment red 48: 2, pigment red 48: 1, pigment red 57: 1, pigment red 53: 1, silk rough to orange, 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, color thick two masts white 6, pigment brown 25, alkaline purple 10, alkaline 157786.doc 201210488 purple 49, acid red 51, acid 52, acid red 14, acid blue 9, acid yellow 23, test red 10, test red 1 〇 8. Examples of adhesives are polyvinylpyrrolidone, polyethylene glycol ruthenium glycol and Cellulose (Tylose®, Shin-Etsu, Japan) Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions with medium to high boiling mineral oil fractions such as kerosene or diesel and coal tar ; and vegetable oil or animal oil; aliphatic, cyclic and aromatic hydrocarbons, such as toluene, xylene, stone butterfly, tetrahydronaphthalene, hospitalized naphthalene or its derivatives; methanol, ethanol, propanol, butanol, cyclohexane Alcohol; cyclohexanone, isophorone; strong polar solvent 'such as disulfoxide, N-decyl pyrrolidone and water. Powder, spreading material and applicable product can be mixed or simultaneously ground compound I and The other active compound II is prepared with at least one solid carrier. The particles (e.g., coated particles, impregnated particles, and homogeneous particles) can be prepared by combining the active compound with at least one solid carrier. (for example) mineral soils such as 矽Glue, silicate, talcum powder, kaolin, attaclay, limestone, lime, chalk, red basalt, loess, clay, dolomite, diatomaceous earth, calcium sulfate and magnesium sulfate, magnesium oxide, ground Synthetic substances, fertilizers (such as ammonium sulfate, ammonium phosphate, nitric acid, urea) and plant products (such as corn flour, bark powder, mineral chips and nut shell powder, cellulose powder) or other solid carrier. Examples of types: 1. Types of compositions diluted with water i) Water-soluble concentrates (SL, LS) 1 part by weight of active compound dissolved in 90 parts by weight of water or water 157786.doc -81 · 201210488 In the solvent. As an alternative, a wetting agent or other adjuvant is added. The active compound is dissolved after dilution with water. Thereby, the active compound content is obtained as 1 〇 weight ° /. Composition. Ii) Dispersible Concentrate (DC) 20 parts by weight of the active compound are dissolved in 7 parts by weight of cyclohexanone' and 10 parts by weight of a dispersing agent (for example, polyvinylpyrrolidone) is added. The dispersion was obtained after dilution with water. The active compound content is 2% by weight 〇 iii) Emulsifying concentrate (EC) 15 parts by weight of the active compound is dissolved in 75 parts by weight of xylene, and calcium dodecylbenzenesulfonate and ethoxylate are added. Baseted castor oil (each obtained by adding 5 parts by weight of p diluted with water to obtain an emulsion. The active compound content of the composition is 15% by weight. iv) Emulsion (EW, EO, ES) 25 parts by weight of active compound In 35 parts by weight of xylene, calcium dodecylbenzenesulfonate and ethoxylated castor oil (5 parts by weight each) were added. This mixture was added to 30 parts by weight of water by means of an emulsifier (e.g., u丨traturrax) to prepare a homogeneous emulsion. The emulsion was obtained after dilution with water. The active compound content of the composition was 25% by weight. v) Suspensions (SC, OD, FS) 'Crush 20 parts by weight of active compound in a ball mill, and add 10 parts by weight of dispersant and wetting agent and 7 parts by weight of water or organic The granules ' thereby forming a fine active compound suspension. After dilution with water, a stable suspension of the active compound is obtained. The active compound in the composition contains I57786.doc 82· 201210488 in an amount of 20% by weight. Vi) water-dispersible granules and water-soluble granules (WG, SG) finely mill 50 parts by weight of active compound' and add 5 parts by weight of dispersant and wetting agent, and by means of technical equipment (eg extruder, The spray tower, fluidized bed) is made into water dispersible granules or water soluble granules. A stable dispersion or solution of the active compound is obtained after dilution with water. The activity of the composition was 50% by weight of the compound. Vii) water-dispersible powders and water-soluble powders (WP, SP, SS, WS) grinding 75 parts by weight of active compound in a rotor-stator mill, and adding 25 parts by weight of dispersant, wetting agent and Silicone. A stable dispersion or solution of the active compound is obtained after dilution with water. The active compound content of the composition is 75% by weight. Viii) Gel (GF) Grinding 20 parts by weight of active compound, 1 part by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or organic solvent in a ball mill to obtain fine suspension. A stable suspension having an active compound content of 20% by weight is obtained after dilution with water. 2. Type of composition to be applied without dilution ix) Dispersing agent (DP, DS) 5 parts by weight of the active compound are finely ground and thoroughly mixed with 95 parts by weight of fine kaolin. Thus, the active compound content of 5% by weight of the applicable product can be obtained. X) Granules (GR, FG, GG, MG) 0.5 parts by weight of the active compound are finely ground and mixed with 99 parts by weight of 157786.doc • 83· 201210488 carrier. Current methods are extrusion, spray drying or fluidized beds. Thereby obtaining an undiluted and granules of the active compound in an amount of 〇·5% by weight. 0 xi) ULV solution (UL) 10 parts by weight of the active compound is dissolved in 9 parts by weight of the organic solvent (for example, two In toluene). Thus, a composition which can be applied without dilution at an active compound content of 10% by weight is obtained. In general, the composition of the mixture of the invention comprises from 9% by weight to 95% by weight, preferably from 〇% by weight to 9% by weight of the compound (ie, compound _1, compound 1-2 or compound) Io_3) (Component 1) and Component 2 or Compound (ie Compound 1-1, Compound 1_2 or Compound 1-3) (Component 丨), Component 2 and Component 3 or a mixture thereof. The purity of the active compound used is preferably from 9% to 10,000%, preferably from 95% to 10,000% (according to NMR spectroscopy). Water Soluble Concentrate (LS), Suspension (FS), Dispensing Reagent (DS), Water Dispersible and Water Soluble Powder (WS, SS), Emulsion (ES), Emulsifying Concentrate (EC) and Gel ( GF) is commonly used to treat plant propagation material, in particular seeds. The compositions may be applied to the propagation material, in particular the seed, in undiluted or preferably diluted form. In the case of &amp;, the corresponding composition may be diluted 2 to 1 fold so that from 1% by weight to 60% by weight, preferably from 3% by weight to 4% by weight, of the composition used for seed dressing Active compound. It can be applied before sowing or during sowing. Treatment of plant propagation material, in particular seed treatment, is known to those skilled in the art and is carried out by applying, coating, granulating, dip coating or soaking the plant propagation material. The best is carried out by granulation, coating and spreading or by treatment of the grooves 157786.doc -84 - 201210488 to, for example, prevent premature germination of the seeds. For seed treatments, 'preferably using suspensions', the compositions typically comprise from 1 to 800 g of active compound per liter, from 1 to 2 gram of surfactant A, to 200 g of antifreeze/bu 0 to 400 g. Adhesive / 丨, 〇 to 2 〇〇 g colorant / hydrazine and solvent (preferably water). Compound 1 (ie, compound 1-1, compound or compound, component 丨) and component 2 or compound 1 (ie, compound 丨, compound 1-2 or compound 13) (group injury 1), component 2 and Component 3 or a mixture thereof may be used in the original state or in the form of a composition by spraying, atomizing, spreading, spreading, raking in, impregnating or pouring, for example in the form of: Directly sprayed solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, spreadables, spreading materials or granules. The type of the composition depends entirely on the intended purpose; it is intended to ensure that the active compound or mixture of active compounds of the invention is distributed as finely as possible in each case. The aqueous use form can be prepared from an emulsion concentrate, a paste or a wettable powder (sprinkable powder, oily dispersion) by adding water. For the preparation of emulsions, pastes or oil dispersions, the materials may be homogenized in water in the original state or dissolved in an oil or solvent by means of a wetting agent, a tackifier, a dispersing agent or an emulsifier. Alternatively, concentrates composed of active substances, wetting agents, tackifiers, dispersing or emulsifying agents and, if appropriate, solvents or oils may be prepared, and such concentrates are suitable for dilution with water. A ready-to-use formulation allows the concentration of the active compound to vary over a relatively wide range. Typically, 5' such indifference systems are from 1% to 1%, preferably 〇. to. The active compound can also be used successfully in ultra low volume methods (ULV) whereby 157786.doc -85 - 201210488 can be applied containing more than 95 weights. /. The composition of the active compound, or even the active compound without additives. When used in crop protection, the application rate is 〇.〇〇丨 to 2 〇kg of active compound per hectare' preferably 0.005 to 2 kg/ha, especially preferably 〇5 to 0.9 kg/ha' especially 0.1 to 〇 .75 kg/ha depending on the nature of the desired effect. In the treatment of plant propagation materials such as seeds, the amount of active compound used (or the amount of active compound mixture) is generally from "〇" to 丨〇〇〇g/丨〇〇kg of propagation material or seed, preferably from 1 to 1000 g. /1〇〇kg, especially 1 to 100 g/100kg' especially 5 to 10〇g/l〇〇kg. The rate of application of the active compound or mixture of active compounds when applied to the protection of the material or stored product depends on the type of application area and the desired effect. The amount normally applied in the protection of the material is, for example, from 〇〇〇丨g to 2 kg of active compound per cubic meter of treated material, preferably from g5 g to 1 kge, as appropriate, until ready to be used (tank mixing) Various types of oils, moisturizers, adjuvants, herbicides, bactericides, other fungicides or insecticides are added to the active compound or mixture of active compounds or compositions comprising the same. These compositions may be combined with the compositions of the present invention in a weight ratio of from 1: 1 Torr to 1:1, preferably from 1:10 to 10:1. In this case, the following reagents are particularly suitable as adjuvants: organically modified polyoxyxenes such as Break Thru S 240®; alcohol alkoxylates such as Atplus® 245, Atplus® MBA 1303, Plurafac® LF 300 and

Lutensol® ON 30; EO-PO block polymers such as p]lur〇nic® rPE 2035 and Genapol® B; alcohol ethoxylates such as Lutens〇i® χρ 80; and dioctyl wall succinate Sodium, such as Le〇phen® ra. 157786.doc •86· 201210488 Synthesis Examples: The compounds of formula I are synthesized as described below (and as described in WO 2009/077443 (PCT/EP2008/067394)). Other compounds of formula I or precursors thereof are obtained using the procedures given in the following synthetic examples by means of suitable modifications to the starting materials. Melting points were obtained on a Mel-Temp II instrument and were uncorrected. The 1H-NMR spectrum was recorded at 300 MHz on a Bruker AC 300 spectrometer and referenced to tetramethyl zephyr (as obtained from Aldrich or Cambridge Isotope Laboratories) as an internal standard. ESI mass spectra were recorded on a Shimadzu LCMS-2010 EV mass spectrometer. APCI mass spectra were recorded on a Shimadzu LCMS-2010 EV mass spectrometer. HPLC analysis was performed on a Shimadzu Prominence HPLC system using an Alltech Alltima C18 Rocket column and PDA detection was performed at 254 nm unless otherwise stated. At a flow rate of 2.5 ml/min, the following time program was used: Volume percentage of time A B Volume percent [min] (H20 and 0·05. /. Trifluoroacetic acid TFA) (CH3CN and 0.05% trifluoroacetic acid) TFA) 1.00 90 10 4.50 0 100 10.00 0 100 11.50 90 10 Example I-1 1-[relative-(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl) Ethylene oxide methyl]-1H-[1,2,4]triazole-3-thiol (=1-[relative-(2S,3R)-3-(2-phenylphenyl)-2 -(2,4-difluorophenyl)oxirane 157786.doc * 87 - 201210488 methyl]-1Η-[1,2,4]triazole-5(4H)-thione) (compound Μ Synthesis of 60.6 ml of n-butyl 1.7 Μ solution in hexane was added dropwise to 3 1-£1-[relative _(211,38)-3-(2-gas) at -78 °C Phenyl)-2-(2,4-difluorophenyl)-oxiranyl fluorenyl]-111-[1,2,4]triazole was dissolved in 80 〇 1111 anhydrous THF. Then 5.5 g of sulphur was added and the mixture was stirred at _78 〇c for 90 minutes" at -78. (:, a saturated ammonium hydride solution was added to the solution, and after thawing to room temperature, the mixture was extracted three times with ethyl acetate. The combined organic phases were washed with a saturated sodium carbonate solution, dried and concentrated. The residue was repeatedly absorbed in a methyl tert-butyl ether/ethyl acetate mixture until excess sulfur was removed. The product was finally crystallized from ethyl acetate / diisopropyl ether / cyclohexane to give 25 g of white powder. Form 丨_[relative-(2R,3S)-3-(2-phenylphenyl)_2_(2,4-difluorophenyl)oxiranylmethyl]_ 1H-[1,2,4 Triazole-3-thiol (melting point 159_16 (TC). H-NMR (DMSO-d6): 13.3 (s, 1H), 8.2 (s, 1H), 7.6 (m, 2H), 7.5 (m, 2H) ), 7.4 (m, 1H), 7.3 (m, 1H), 7.0 (m, 1H), 4.5 (d, 1H), 4.4 (s, 1H), 4.1 (d, 1H). Example 1- [relative_ (2S3R)_3_(2chlorophenyl)2(24-difluorophenyl)epoxyethylamino]-5-thiocyanato-1H-1,2,4-triazole (compound Ϊ-2) Synthesis at room temperature 1-[relative _(2S,3R)_3_(2_gasphenyl)_2_(2,4-difluorobenzoate)oxiranylmethyl]]H_[124]triazole_ 5(4H)thione (i5〇mg, mm〇1), diethylamine (11 〇μΐ, 〇8 mm〇1) and bromide cyanide BrCN mg' 〇·59 mmol) in a mixture of tetrahydrofuran (THF, 5 mL) 157786.doc 88-201210488 Stir for 3 hours. Add ethyl acetate (2〇) The residue was purified by EtOAc EtOAc (EtOAc) The title compound (11 mg, 69%) was obtained as a white solid. HPLC-MS: 3.756 min (405) Example 1-3 1-[relative(2R,3S)_3_(2_chlorophenyl)_2_(2 Synthesis of 4 difluorophenyl)epoxyethylidenef-yl]-5-allyl-1H-[1,2,4]triazole (Compound I-3) at room temperature 1-[relative_ (2S,3R)_3_(2-chlorophenyl)_2_(2,4-difluorophenyl)-% oxyethenylmethyl]_1H-[1,2,4]III. Sit-5(4H) a mixture of thioketone (2.50 g, 6.6 mmol) and carbonic acid _ (1 36 g, 9.9 mmol) in anhydrous dimethylformamide (DMF, 50 mL), stirred for 5 min. Moth (1.66 g, 9.9 mmol) and the resulting mixture was stirred at room temperature for 12 hours. Ice-cold water (100 mL) was added and the mixture was extracted with methyl-t-butyl ether (200 mL). The organic phase was washed with water and then dried with a saturated sodium chloride solution (3×5 〇 mL). After evaporation, the residue was purified using EtOAc (EtOAc m. The title compound (2.07 g, 71%) was obtained as a pale yellow oil. HPLC-MS: 3.980 min (419). Application Examples The fungicidal action of the mixture of the present invention can be confirmed by the following tests: G) The greenhouse is prepared by the following several steps: preparing a stock solution: a solvent to emulsifier relationship (volume) of 99 to 1 acetone and / Or a mixture of disulfoxide and wetting agent/emulsifier Waittl (which is based on ethoxylated alkylphenol) is added to 157786.doc •89·201210488 to 25 mg of compound to obtain a total of 1 μm and then water is added丨〇〇w total volume. This stock solution was diluted to a given concentration with the solvent_emulsifier_water mixture. Example G1 Control of Tomato Late Blight Caused by Phytophthora infestans (Phytate Calcium Magnesium P1) Seedlings of tomato plants were grown in pots. The plants are sprayed to the effluent with an aqueous suspension containing the active ingredients of the concentrations mentioned in the table below or mixtures thereof. On the next day, the treated plants were inoculated with an aqueous suspension of the Phytophthora infestans sporangia. Immediately after inoculation, the test plants were transferred to a humidifier. After 6 days at 18 to 20 ° C and close to 100% relative humidity, the diseased leaf area was ❶/. The degree of fungal attack on the leaves was visually evaluated. The effect of converting disease into efficacy means that the degree of infection of the treated plant is comparable to that of the untreated control plant; a potency of 1 means that the treated plant is not infected. The Colby's formula [Rs Colby, "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] was used to determine the expected potency of the active compound mixture' and compared with the observed efficacy. Preventive Control of Wheat Leaf Rust Caused by Wheat Leaf Rust (Puccrt P1) Spraying the first two leaves of potted wheat seedlings with an aqueous suspension containing the active ingredients or mixtures thereof at the concentrations indicated below Flow out. On the second day, plants were inoculated with wheat leaf rust spores. To ensure successful vaccination, the plants were transferred to a matt chamber with a matte relative humidity of 95 to 99% and a temperature of 20 to 24 ° C for 24 h. The test plants will then be planted at 157786.doc • -90- 201210488 in the greenhouse at 20-24 ° C and between 65% and 70 ° /. The culture was carried out for 6 days under the relative humidity. The degree of fungal invasion on the leaves was visually evaluated by % of diseased leaf area. Results: G1) Calcium magnesium phytate P1 Active compound / active mixture concentration (ppm) Efficacy observed for the mixture Efficacy calculated according to Colby (%) Synergistic (%) Untreated control 80% of the diseased compound 1-1 4 - 1 gram of sensitive 4 - 0 prothiotoxin. Sit 4 0 Bixafine 1 - 0 Compound 1-1 4 1:1 19 1 18 Bai Kemin 4 Compound 1-1 4 1:1:1 19 1 18 Prothiotoxin. Sit 4 克克敏4 Compound 1-1 4 4:4:1 19 1 18 Propionibacterium D sit 4 Bixafine 1 G2) Puccrt P1 Active compound / active mixture concentration (ppm) The observed effect of the mixture is calculated according to Colby Efficacy (%) Synergism (%) Untreated control 80% of the diseased compound 1-1 1 - 25 0.25 - 1 Prothioconazole 1 0 0.25 - 0 Fluoropyrazolamide 0.063 0 Baikemin 0.25 - 13 Bixaphine 0.25 - 0 Compound 1-1 0.25 4:4:1 25 1 24 157786.doc -91 - 201210488 Propioni spit 0.25 Flurazazole Acrylamine 0.063 Compound 1-1 0.25 1:1:1 31 14 17 Propionibacter 嗤 0.25 克克敏 0.25 Compound 1-1 1 4:4:1 50 25 25 Propionate 嗤1 毕克萨芬 0.25 Μ) Preparation of microtest active compound Separate or co-mix the active compound A stock solution of 10 000 ppm in DMSO. The active compound, epothilone, is used as a commercial formulation and is diluted with water for the active compound. Comparing the measured value of the percentage of infection on the leaf (measured parameter) with the growth of the inactive compound control variant and the blank value of the fungic-free and inactive compound, thereby determining the relative growth % of the pathogen in the individual active compound, and thereby These measurements were converted to % efficacy of untreated controls. Efficacy means that the degree of infection is the same as the untreated control; a potency of 100 means that the infection is 0%. The Colby's formula (Colby, S. R. "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds, 15, pages 20-22, 1967) was used to determine the expected potency of the active compound combinations and to compare with the observed potency. The Abbot formula was used to calculate potency (E) as follows: Ε = (1 - a / β) · 1 〇〇 α corresponds to % of fungal infection of treated plants, and β corresponds to % of fungal infections of untreated (control) plants . At a potency of 0, the degree of infection of the treated plants was comparable to that of the untreated plants 157786.doc -92 - 201210488; at a potency of 100, the treated plants were not infected. The Colby's formula (Colby, S. R. "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds, 15, pp. 20-22, 1967) was used to determine the expected potency of the active compound combination and compare it to the observed efficacy.

Colby's formula: E=x+yxy/l 00 E The expected potency when using a mixture of active compounds A and B at concentrations a and b, expressed as % of untreated control X when using active compound A at concentration a Efficacy, expressed as % of untreated control y The efficacy when active compound B was used at concentration b, expressed as % of untreated control.

Ml) Resistance to Leptosphaeria nodorum in the microtiter plate test (Leptno) The stock solution was mixed according to the ratio, pipetted onto a microtiter plate (MTP) and diluted to the specified concentration with water. A spore suspension of the genus A. sinensis in an aqueous biomalt solution is then added. The plates were placed in a water vapor saturation chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. M2) Resistance to Phytophthora infestans in the microtiter plate test (Septgl) The stock solution was mixed according to the ratio, pipetted onto a microtiter plate (MTP) and diluted to the specified concentration with water. A spore suspension of the Phytophthora infestans in an aqueous biomalt solution is then added. The plates were placed in a water vapor 157786.doc -93 - 201210488 saturated chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. The measured parameters were compared to the growth of the control variant (100%) of the inactive compound and the blank value of the fungi-free and inactive compound to determine the relative growth % of the pathogen in the respective active compound. These parameters are converted to potency. A potency of 0 means that the degree of growth of the pathogen is comparable to that of the untreated control; an efficacy of 100 means that the pathogen has not grown. The Colby's formula [R.S. Colby, "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] was used to determine the expected potency of the active compound mixture and was compared to the observed potency.

Leptno Active Compound / Active Mixture Concentration (ppm) Efficacy observed for the mixture. Efficacy calculated according to Colby (%) Synergistic (%) Compound 1_1 0.063 • 2 Propionisulfone 11 Sit 0.063 3 Compound 1-1 0.063 1:1 22 5 17 Prothiotoxin. Sitting 0.063

Septgl Active Compound / Active Mixture Concentration (ppm) Mixture Observed Efficacy Calculated according to Colby (%) Synergistic (%) Compound 1-1 0.25 - 2 0.063 _ 2 Fluoropyrazole decylamine 0.016 - 0 Propionibacterium. Sit 0.063 • 64 chlorothalonil 0.25 - 18 Compound 1-1 0.063 4:1 59 3 56 Fluoropyrazole octaamine 0.016 Compound 1-1 0.063 1:1 100 65 35 157786.doc -94- 201210488 Propionithiocene 0.063 Compound 1-1 0.25 1:1 65 20 45 chlorothalonil 0.25 Compound 1-1 0.25 16: 1 :4 99 66 33 Fluoropyrazole decylamine 0.016 Propionylthiobacteria β sitting 0.063 M3 ) Resistance to wheat in microtiter plate test Leaf spot disease The activity of the genus A. sinensis was mixed according to the ratio, and the solution was pipetted onto a microtiter plate (MTP) and diluted with water to the specified concentration. A spore suspension of the genus A. sinensis in an aqueous biomalt solution is then added. The plates were placed in a water vapor saturation chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. Active Compound / Active Mixture Concentration (ppm) Efficacy observed for the mixture. Efficacy calculated according to Colby (%) Synergistic (%) 1 - 52 1 - 38 Fluoropyrazolamide 0.25 - 12 1 4:1 84 58 26 Fluorine Ratio 坐 坐 胺 0.25 \ Jl 1 4: 1 80 46 34 Fluoropyrazine 0.25 157786.doc • 95- 201210488 M4) Resistance to Barley Net Spot Barley Reticulum in the microtiter plate test The stock solution was pipetted onto a microtiter plate (MTP) and diluted to the specified concentration with water. A spore suspension of the barley mutans in the aqueous biomalt solution is then added. The plates were placed in a water vapor saturation chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. Active Compound / Active Mixture Concentration (ppm) Efficacy Observed for Mixture Efficacy Calculated According to Colby (%) Synergistic Effect (%) 1 - 5 0.063 3 0.063 - 3 100 gram sensitive 0.016 _ 46 Fenfen 0.25 13 chlorothalonil 0.25 46 Propionibacterium 0.25 55 Ίν A 0.063 4:1 72 48 24 baikemin 0.016 1 4:1 38 17 21 Fenpufu 0.25 157786.doc -96- 201210488 1 4:1 94 49 45 chlorothalonil 0.25 0.063 4 :1 72 48 24 克克敏0.016 Ία 1 4:1:1 100 55 45 Fenfen 0.25 chlorothalonil 0.25 Ά A 1 4:1:1 97 77 20 Prothioconazole 0.25 chlorothalonil 0.25 M5) in trace amounts The activity against the rice blast fungus in the titration plate test was mixed according to the ratio of the stock solution, pipetted to a microtiter plate (MTP) and diluted with water to the specified concentration. Then add the spore suspension of the rice fever pathogen in the aqueous biomalt solution. The plates were placed in water vapor at a temperature of 18 ° C to be saturated. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. 157786.doc •97- 201210488 Active Compound / Active Mixture Concentration (ppm) Efficacy observed for the mixture. Efficacy calculated according to Colby (%) Synergistic (%) 1 - 1 1 - 0 Fluopyrazolamide 0.25 • 3 Propane Sulfur Bacterium β sitting 0.25 - 16 1 4:1 99 4 Fluorine than sputum 0.25 1 4:1 81 17 Propionibacterium D sitting 0.25 \ Jl 1 4:1 100 3 Fluoropyrazolamide 0.25 1 4:1 89 16 prothiotoxin. Sit 0.25 Fi^ 1 4:1:1 94 17 77 Fenford 0.25 Probiotics. Sit 0.25 157786.doc -98- 201210488 M6) Resistance to leaf spot disease of M. grisea in microtiter plate test Mix the stock solution according to the ratio, pipette to microtiter plate (MTP) and dilute to the specified concentration with water. A spore suspension of the barley pathogen in an aqueous biomalt solution is then added. The plates were placed in a water vapor saturation chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. Active Compound / Active Mixture Concentration (ppm) Efficacy observed for the mixture. Efficacy calculated according to Colby (%) Synergistic (%) 0.063 - 16 〇0.063 - 5 克克敏 0.016 - 45 0.063 4:1 79 53 26 克克敏0.016 0.063 4:1 88 47 41 Baikemin 0.016 M7) Resist the activity of wheat leaf spot caused by the sclerotium of wheat stalks. Mix the stock solution according to the ratio, pipette to the microtiter plate (MTP) and dilute to the specified concentration with water. A spore suspension of S. cerevisiae in an aqueous biomah solution is then added. The plates were placed in a 157786.doc -99 - 201210488 water vapor saturation chamber at a temperature of 18 °C. On the 7th day after inoculation, MTP was measured at 405 nm using an absorption photometer. Active Compound / Active Mixture Concentration (ppm) Efficacy observed for the mixture. Efficacy calculated according to Colby (%) Synergistic (%) 1 - 43 0.063 _ 0 0.063 - 10 0.016 • 3 Fluopyrazolamide 0.016 - 36 Fenfen 0.25 - 3 chlorothalonil 0.25 • 29 prothiotoxin. Sit 0.016 - 32 fjC^ 0.063 4:1 87 36 51 Fluorine. Beefamide 0.016 Ά a 1 4:1 96 44 52 Fenfen 0.25 Fi^ 1 4:1 86 59 27 chlorothalonil 0.25 157786.doc •100· 201210488 0.016 1:1 63 34 29 Prothioconazole 0.016 0.063 4:1 91 43 48 Fluorine 0 to scented amine 0.016 1 4:1:1 98 60 38 Fenfen 0.25 chlorothalonil 0.25 157786.doc 101 -

Claims (1)

201210488 VII. Patent application scope: 1 · A fungicidal mixture comprising 1) a compound of formula I as component 1 Each of the variables has the following meanings: A 2,4-difluorophenyl; B 2-phenylphenyl; and D SH (compound 1-1), S-CN (compound 1-2) or S-CH2-CH= CH2 (compound 1-3), wherein the compound I is present in whole or in part in the form of its tautomer; and/or an agriculturally acceptable salt thereof; and 2) as the active ingredient of component 2, selected from Pyraclostrobin, fluoro-n-ratio (fiuxapyryr xad), fenpropimorph 'prosulfimazole' (pr〇thi〇c〇naz〇ie) and chlorothalonil and/ Or an agriculturally acceptable salt thereof; the weight ratio of the two components is from 2:1 to 1:2. 2. For example, requesting a fungicidal mixture 'wherein compound (2R'3S)-3-(2-phenylene)·2_(2 4_: phenyl) Ethylene ethene 2,4-monohydro-[I , 2, 4] triazole _3_thione, which may exist in the form of a complete or partial base], isomer. And 3. The fungicidal mixture of the claimed item, wherein the compound is 157 157786.doc 201210488 (2r'3s)-3-(2_ phenyl)_2_(2,4 di phenyl) epoxy Ethylmethyl]·Cucurbityl 1H-[1'2,4]diazole, which may exist wholly or partially in the form of a conformation. # 4. For the fungicidal mixture of your τ5 term in claims 1 to 3, wherein component 2 is selected from the group consisting of decylamine, prothioconazole, fenfluz and chlorothalonil, and/or its agriculturally acceptable salt. 5 · A fungicidal mixture of 1 to 3 φ JV, in which the component 2 is fluoropyrazolamide. 6. A fungicidal mixture according to any one of the claims, wherein the component 2 is a prothiotoxin. 7. The fungicidal mixture of claim 5, wherein the mixture additionally comprises a hundred grams of sensitizer. 8 The killing of claim 5: a fungal mixture wherein the mixture additionally comprises fenflufol. 9' The fungicidal mixture of claim 6, wherein the mixture additionally comprises fluorine. Ratio of amine, bixafen or penflufen. 10. The fungicidal mixture of claim 6, wherein the mixture additionally comprises 100 grams of dimoxystrobin, picoxystrobin or fluoxastr. 11. Use of a fungicidal mixture according to any one of claims 1 to 1 for controlling a wheat pathogen selected from the group consisting of Septoria tritici, Stagonospora nodorum , Pyren〇ph〇ra tritici repentis, Wheat leaf 157786.doc 201210488 (Puccima recondita), Puccinia striiformis Biumeria graminis, Fusarium Culmorum), Fusarium graminearum, and Pseudosporium solani (pseutj0cerc0Sp0reiia herpotrichoides) 〇12. The use of a fungicidal mixture according to any one of claims 1 to i, for controlling The following barley pathogens: Pyrenophera teres, Rhychosporium secalis, puccinia hordei, B. baumannii, Ramularia collo-cygni And wheat sheath blight. 13. Use of a fungicidal mixture according to any one of claims 1 to 1 for controlling a soybean pathogen selected from the group consisting of: phakopsora pachyrizi, pectinum rust (p. meibomiae) ), Microsphaera diffusa and FDC (leaf disease syndrome), the FDC comprising at least one pathogen selected from the group consisting of Septoria glycines, Cercospora kikuchii, and Soybean gray spot ( C. sojina), Corynespora cassiicola and Alternaria spp. An agrochemical composition comprising a solvent or a solid carrier and a fungicidal mixture according to any one of claims 1 to 10. 15. A seed comprising a fungicidal mixture according to any one of claims 1 to 10 in an amount of from 0.1 g to 1000 g per liter of seed. 157786.doc 201210488 r IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the characteristics that can best show the invention. Chemical formula: 157786.doc