201209088 六、發明說明： 【發明所屬之技術領域】 本發明係與發泡製程中所使用之填充劑有關，尤指一 種用於發泡製程中具多孔隙之植物性填充劑之製造方法。 【先前技術】 按，目前在一般生產發泡材（如EVA泡棉）之製造過 程中，化學添加劑是必需的主要配方之一，其除可有效降 φ 低原料成本之外，更可用以補強發泡材的物性，因此可說 是生產發泡材時相當重要的助劑。 而一般用於發泡製程中之化學添加劑乃為碳酸鈣 (CaCO〇 ’然而以碳酸鈣做盖填充劑所製出之發泡材既不 環保，且其係呈閉鎖式的氣室結構，因此並無法吸附濕氣 或臭味；再者，由於一般發泡製程中因使用DCP(Dicumyl Peroxide)作為架橋劑（corss linking agent)，更會導致發 #·泡材成品皆會有種令人感到嗆鼻、不適的氣味存在。 有鑑於此，故如何改進上述問題，即為本發明所欲解 決之首要課題’據此，本案發明人乃經過不斷苦思及試作 後，才終於有本發明之產生。 【發明内容】 本發明目的之一，係在於提供一種用於發泡製程中具 多孔隙之植物性填充劑之製造方法，其係具有成本低廉， 201209088 以及其係以天然植物產品的廢棄物再次回收利用，並可完 全取代用於發泡製程中之化學添加劑。 本發明目的之二，係在於提供一種用於發泡製程中具 多孔隙之植物性填充劑之製造方法，其係具有極佳的吸濕 及除臭之功效者。 為達前述之目的，本發明係提供一種用於發泡製程中 具多孔隙之植物性填充劑之製造方法，其包含有以下步驟： a .回收並集中廢棄之咖啡渣，再將其置於陽光下曝 曬至含水量5%〜15% ; b ·接著利用一烘乾設備以I20°c〜350°C對已曝曬過 後之咖啡渣進行烘烤1〜4小時； c .最後將烘烤後之咖啡渣研磨至1000mesh以下，即 得可用於發泡製程中具多孔隙之植物性填充劑。 再者’根據上述方法，於步驟a中更可先將回收集中 後之吻啡漁置入含有1· 5%的植物性分解酵素（hydro 1 ases) 之水中發酵7〜8小時後，在接著進行曝曬及其他後續步驟 〇 而本發明之上述目的與優點，不難從下述所選用實施 例之詳細說明與附圖中，獲得深入了解。 當然，本發明在某些另件上，或另件之安排上容許有 所不同，但所選用之實施例，則於本說明書中，予以詳細 說明。 【實施方式】 201209088 請搭配參閱第1圖，係本發明所提供之一種用於發泡 製程中具多孔隙之植物性填充劑之製造方法的一較佳實施 例。 本實施例中係以沖泡咖啡後所產生之咖啡渣來做為本 發明植物性填充劑之原料，而由於經炒熟的咖啡大致已碳 化形成具有一定的強度，再加上咖啡本身具有植物性的纖 維（fibers)，因此更可具有強化的支撐效果。 再者，咖啡豆本身含有數百種以上的化學物質 (Chemical substances)，其中比較重要的即為大家所熟知 是咖啡因（Caffein)，而這麼多的化學物質再經熱水沖泡 或在融熔（molten state)狀態中會完全釋出，因此即會導 致每個咖啡顆粒的表面形成多孔隙的結構（p〇r〇us structure)，並藉由這些孔隙即能達到吸溼又能除臭之功 效與市％上有將咖啡〉查包裝後吊在扇所防渥除臭的產品 原理相同。 ' 而欲將咖啡渣取代用於發泡製程中之化學添加劑係須 經過以下處理步驟： a .首先，回收並集中廢棄之咖啡渣，並將回收集中 之咖啡渣置於陽光下曝曬至含水量5%〜15%，以進 行初步的脫水動作’並於進行下段步驟前可先將 完成曝曬之咖啡渣裝入一預定容器中予以密封保 存，以避免回潮； b ·接著利用一烘乾設備以120¾〜350°C對已曝曬過 後之咖啡渣進行烘烤卜4小時，於本實施例中係 201209088 設定烘乾設備以12(TC對已曝曬過後之咖啡潰進 行烘烤2〜3小時’並藉此使咖啡渣可連到完全脫 水以及再次產生碳化作用之效果； c .最後對烘烤後之咖啡渣進行一研磨作業，並將咖 啡渣研磨至lOOOmesh以下，即得可用於發泡製程 中具多孔隙之植物性填充劑。 再者，如第2圖所示，係為本發明另一較佳實施例， 其主要係根據上述第一實施例之製法，並於進行步驟a 時，係先將回收集中後之咖啡渣置入含有L5%的植物性分 解酵素（hydrolases)之水中發酵7〜8小時後，再接著進 行曝曬及其他後續步驟，如第2圖所示，同樣可製得具多 孔隙之植物性填充劑’且洲此方式所製成之植物性填= 劑，因文植物性分解酵素（hydr〇lases)之發酵分解作用， 使咖啡渣質地得以變軟而有利於後續之加卫 即能更為適合商業用途及大量生產。 "糟此 ΤΠ3 Μ201209088 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a filler used in a foaming process, and more particularly to a method for producing a vegetable filler having a porosity in a foaming process. [Prior Art] According to the current production process of general production of foam materials (such as EVA foam), chemical additives are one of the main formulas required, in addition to effectively reducing φ low raw material costs, more can be used to reinforce The physical properties of the foamed material can be said to be an important additive when producing a foamed material. The chemical additive generally used in the foaming process is calcium carbonate (CaCO〇', however, the foamed material produced by using calcium carbonate as a capping filler is neither environmentally friendly nor has a closed cell structure. It is not able to absorb moisture or odor; in addition, due to the use of DCP (Dicumyl Peroxide) as a corss linking agent in the general foaming process, it will cause a lot of hair products. In view of this, how to improve the above problem is the primary problem to be solved by the present invention. According to this, the inventor of the present invention finally has the invention after continually thinking and trying. SUMMARY OF THE INVENTION One object of the present invention is to provide a method for producing a vegetable filler having a porosity in a foaming process, which is low in cost, 201209088 and discarded by natural plant products. The material is recycled again and can completely replace the chemical additive used in the foaming process. The second object of the present invention is to provide a plant having a porous structure in a foaming process. A method for producing a filler, which has an excellent effect of moisture absorption and deodorization. To achieve the foregoing object, the present invention provides a method for producing a vegetable filler having a porosity in a foaming process, The method comprises the following steps: a. Recycling and concentrating the discarded coffee grounds, and then exposing them to sunlight to a moisture content of 5% to 15%; b) then using a drying device at a ratio of I20°C to 350°C The coffee grounds after being exposed to the sun are baked for 1 to 4 hours; c. Finally, the coffee grounds after baking are ground to below 1000 mesh, which can be used for the porous vegetable filler in the foaming process. In the above method, in step a, the recovered corns and fats can be fermented in water containing 1.5% of hydrolyzed enzymes (hydro 1 ases) for 7 to 8 hours, followed by exposure and other The above-described objects and advantages of the present invention will be readily understood from the following detailed description of the embodiments of the invention and the accompanying drawings. Allowable differences, but selected The embodiment will be described in detail in the present specification. [Embodiment] 201209088 Please refer to FIG. 1 for a manufacturing method of a porous vegetable filler for use in a foaming process. A preferred embodiment. In this embodiment, the coffee grounds produced after brewing coffee are used as raw materials for the vegetable filler of the present invention, and since the roasted coffee is substantially carbonized to have a certain strength, In addition, coffee itself has plant fibers, so it can have enhanced support. In addition, coffee beans contain hundreds of chemical substances, among which the more important ones are well known. It is caffein, and so many chemicals are completely brewed by hot water or completely released in a molten state, thus causing a porous structure on the surface of each coffee particle ( P〇r〇us structure), and through these pores, it can achieve the effect of moisture absorption and deodorization, and the city has the coffee to check the packaging and then hang it in the fan to prevent deodorization. The same principle product. The replacement of coffee slag for the chemical additives used in the foaming process requires the following processing steps: a. First, the waste coffee slag is recovered and concentrated, and the concentrated coffee slag is exposed to sunlight to the moisture content. 5%~15% for preliminary dewatering action' and before the next step, the finished coffee slag can be sealed and stored in a predetermined container to avoid moisture regain; b. Then use a drying device to 1203⁄4~350 °C for baking the dried coffee grounds for 4 hours. In this example, the system is set to 201209088 to set the drying equipment to 12 (TC to bake 2~3 hours after the coffee has been exposed) Thereby, the coffee grounds can be connected to the effect of completely dehydrating and re-generating carbonization; c. Finally, a grinding operation is performed on the coffee grounds after baking, and the coffee grounds are ground to below 100 mesh, which can be used in the foaming process. Further, as shown in FIG. 2, it is a preferred embodiment of the present invention, which is mainly according to the method of the first embodiment described above, and when step a is performed, The coffee slag after the collection and concentration is first placed in water containing L5% of phytochemicals (hydrolases) for 7 to 8 hours, followed by exposure and other subsequent steps, as shown in Figure 2, the same can be made It is a plant-based filling agent made of porous material, and the plant-based filling agent made by this method is fermented and decomposed by phytochemical decomposition enzymes to make the coffee ground texture soft and beneficial. Subsequent enhancements are more suitable for commercial use and mass production. "不好ΤΠ3Μ
.· I作EVA鞋墊為例，係先將跳厚料、本發明 具多孔隙之植物性填充劑、發㈣卜架橋 溫度赋W混合㈣健 物料進行树贿私，並需_溫度在收Γ下 架橋劑及發泡劑過早產生交聯及發泡的現象； 分：ΓΓ物料倒入輪台，以11(3儀， 由觀輪台雜_，使其混< 二:二延壓機中以25°c-3«5-出片 灸把出片的片料置入發泡台中以壓力：150~ 201209088 kg/〇n2’溫度：155〜17〇ΐ，3(Μ〇分鐘進行發泡作業，並 在此步驛中產生架橋與發泡反應，生產eva泡綿； 將凡成發泡作業之EVA泡綿由發泡台中取出，並用剖 刀機將EVA泡錦裁剖成鞋塾所需厚度後，再進行Phylon成 型，其成型溫度為15〇ΐ，加熱時間6〜9分鐘，冷卻時間9 分30秒至12分鐘； 最後在將完成Phylon成型之EVA泡綿裁成具有預定尺 寸的鞋墊，即完成EVA鞋墊之製造。 並將依上述步驟所製成之EVA鞋墊與一般以化學填充 劑製成之EVA鞋墊進行物性比較： 一般EVA鞋墊 本鞋墊 硬度 45 43~46For example, as an EVA insole, the first is to jump the thick material, the porous filler of the invention, the hair (four), the temperature of the bridge, and the mixture of the materials to carry out the bribery, and the temperature needs to be collected. The under-bridge agent and foaming agent prematurely produce cross-linking and foaming phenomenon; points: ΓΓ material is poured into the wheel table, to 11 (3 instruments, by the observation wheel _ _, make it mixed < 2: two extension pressure In the machine, 25°c-3«5-extraction moxibustion is used to put the pieces into the foaming table with pressure: 150~ 201209088 kg/〇n2' temperature: 155~17〇ΐ, 3 (Μ〇 minutes Foaming operation, and in this step, the bridging and foaming reaction is produced to produce eva foam; the EVA foam of the foaming operation is taken out from the foaming table, and the EVA foam is cut into shoes by a slitting machine. After the required thickness, Phylon molding is carried out, the molding temperature is 15 〇ΐ, the heating time is 6 to 9 minutes, and the cooling time is 9 minutes 30 seconds to 12 minutes; finally, the EVlon foam which has completed Phylon molding is cut into a predetermined one. The size of the insole, that is, the manufacture of the EVA insole. The EVA insole made according to the above steps and the EVA insole generally made of chemical filler Comparison of Properties: Usually EVA insoles insole hardness 46 45 43 -
Asker C φ -比重 0.16 g/cm2 拉力 18.6 kg/cm2 延伸 220 0.Γ0.18 18.(Γ 18.9 200~ 220 201209088 撕裂 10 1〇~15 kg/cm 壓縮歪 65 60~ 70 % 収縮 〇·48 0.43^0.45 % 反彈 45 45~48 % 本發明之植物性填充劑所製成之EVA鞋墊經與化學性 填充劑（碳酸鈣）所製成EVA鞋墊的對照試驗的結果顯示， 在EVA鞋墊發泡過程中’以同量的咖啡渣取代配方中的化 學性填充劑（碳酸鈣）’不但在泡綿的物性沒有顯著差異， 且生產所用的機器设備及流程都一樣，並不需更改而可直 接取代。 另以-般EVA輕與本轉進行f際慢跑後之對照測 »式’試驗條件為每次慢跑i小時，溫度超過3〇t>c，測試期 間14天。 201209088 填充劑 碳酸鈣 使用量 30 PHR 步驟流程 一樣 機器設備 一樣 物理性質 一樣 慢跑流汗後 鞋塾味道 臭一很臭 鞋墊溼度 很溼 試驗對照結果： 一般鞋墊 本鞋墊 咖啡潰Asker C φ - specific gravity 0.16 g/cm2 tensile force 18.6 kg/cm2 extension 220 0. Γ 0.18 18. (Γ 18.9 200~ 220 201209088 tearing 10 1〇~15 kg/cm compression 歪 65 60~ 70 % shrinkage 〇 48 0.43^0.45 % rebound 45 45~48 % The result of the control test of the EVA insole made of the vegetable filler of the present invention and the EVA insole made of the chemical filler (calcium carbonate) is shown in the EVA insole. During the bubble process, 'the chemical filler (calcium carbonate) in the formula is replaced by the same amount of coffee grounds'. There is no significant difference in the physical properties of the foam, and the machines and processes used in the production are the same, without changing. It can be directly replaced. The comparison between the EVA light and the current rotation of the f-jogging is as follows: the test condition is i hour for each jog, the temperature exceeds 3〇t>c, and the test period is 14 days. 201209088 Filler carbonic acid Calcium usage 30 PHR Step process is the same as the machine equipment. Physically jogging, sweating, shoe last, smell, smell, very smelly, insole, humidity, wet test, comparison result: general insole, insole, coffee break
20-50PHR 一樣 一樣 一樣 不臭，稍有咖啡香味 乾燥不溼 並由上述試驗結果可清楚得知，本發明係藉由咖啡渣 本身具有多孔隙的結構（porous structure)，以及本身所 具有之咖啡香味，因此具有極佳的吸濕、除臭功效，且一 般EVA泡綿由於使用DCP做為架橋劑，因此泡綿具有濃烈 201209088 的嗆鼻味，然而，本發明因加入以咖啡渣所製成之植物性 填充劑，並藉其殘餘的咖。非香味能有效中和（neutralize) DCP的嗆鼻味，更是本發明之另一好處。 惟，以上所述實施例之揭示係用以說明本發明，並非 用以限制本發明，故舉凡數值之變更或等效元件之置換仍 應隸屬本創作之範疇。 綜上所述，係可使熟知本項技藝者明瞭本發明的確可 達成前述目的，實已符合專利法之規定，故本案發明人爰 依法提出申請。 201209088 【圖式簡單說明】 第1圖係本發明一較佳實施例之步驟流程圖 第2圖係本發明另一較佳實施例之步驟流程圖 【主要元件符號說明】 (無） 1120-50PHR is the same as not smelly, slightly coffee flavor is dry and not wet and it is clear from the above test results that the present invention has a porous structure by coffee slag itself, and coffee itself. Aroma, therefore, has excellent moisture absorption and deodorizing effects, and generally EVA foam is used as a bridging agent by using DCP, so the foam has a strong nose smell of 201209088, however, the present invention is made by adding coffee grounds. A vegetal filler and borrow its residual coffee. Non-fragrance can effectively neutralize the scent of DCP, which is another advantage of the present invention. However, the above description of the embodiments is intended to be illustrative of the invention and is not intended to limit the invention. In summary, it will be apparent to those skilled in the art that the present invention can achieve the foregoing objectives and is in accordance with the provisions of the Patent Law. Therefore, the inventor of the present invention filed an application according to law. 201209088 BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart of a preferred embodiment of the present invention. FIG. 2 is a flow chart of another preferred embodiment of the present invention. [Description of Main Components] (None) 11