TW201206897A - Compound and colored composition - Google Patents

Abstract

This invention provides a colored composition comprising at least one selected from resin, photopolymerizable compound, photopolymerization initiator and solvent, and a coloring agent containing xanthene-based dye. This invention provides a compound represented by formula (I): wherein L is a bivalent saturated alkyl with 1-20 carbon atoms; the hydrogen atoms of the saturated alkyl can also be substituted by halogen atoms; the -CH2- of the saturated alkyl can be substituted by -CO- or -O-; R1 and R2 individually represent the hydrogen atom, substituted monovalent aliphatic alkyl with 1-16 carbon atoms or substituted acyl group with 2-18 carbon atoms; R3-R10 individually represent the hydrogen atom, substituted monovalent aliphatic alkyl with 1-8 carbon atoms, or substituted monovalent aromatic alkyl with 6-10 carbon atoms, wherein the–CH2- of the aliphatic alkyl can be substituted by –O-; R11-R14 individually represent the hydrogen atom or the methyl; X1 and X2 represent the inorganic anion or the organic anion.

Description

201206897 VI. Description of the Invention: [Technical Field] The present invention relates to a compound effective as a dye and a colored composition comprising the same. [Prior Art] In a liquid crystal display panel, an electroluminescence panel, and a plasma display In a color filter for a display device used in a panel or the like, a dye is always used as a colorant. As such a dye, for example, a dibenzopyran compound such as c.j. redness 1 is known (Patent Document 1). Patent Document 1: Japanese Laid-Open Patent Publication No. 2001-106712. SUMMARY OF THE INVENTION As a coloring agent for a color filter for a display device, if a dye having a high transferability is used, the dye is applied to a color filter of another color. Or a protective film or the like, the resin film of the 3 coloring agent is moved, thereby causing display characteristics of the display device. Here, the term "transporting property" means adhering to the dye x digas or water vapor contained in the target material as a medium. Other materials are either absorbed, but the above dibenzophenone. The base compound has a case where the transfer property is not necessarily sufficiently satisfied. That is, the present invention provides the following [丨]~[6]. [1] - a compound represented by formula (I), P4

156701.doc 201206897 [In the formula (1), L represents a carbon number as a valence saturated hydrocarbon group. The hydrogen atom contained in the saturated hydrocarbon group may also be substituted by a functional atom, and the -CH2· contained in the saturated hydrocarbon group may also pass through -CO- Or -〇-substituted; R and R each independently represent a hydrogen atom, a monovalent aliphatic hydrocarbon group having a carbon number of 1 to 16 which may have a substituent, or a fluorenyl group having a carbon number of 2 to 18 which may have a substituent And R to R each independently represent a hydrogen atom, a monovalent aliphatic hydrocarbon group having a carbon number of 1 to 8 or a monovalent aromatic hydrocarbon group having a carbon number of 6 to 1 Å which may have a substituent, The _CH2 contained in the aliphatic hydrocarbon group may also be substituted with _〇_; and R to R14 each independently represent a hydrogen atom or a methyl group. X1- and X2· represent an inorganic anion or an organic anion]. [2] The compound of [1], wherein L is an alkanediyl group having a carbon number of 5 to 15, and -CH2· contained in the alkanediyl group may also be substituted. [3] A dye which is mainly composed of a compound such as [1] or [2]. [4] A coloring composition comprising: at least one selected from the group consisting of a resin, a photopolymerizable compound, a photopolymerization initiator, and a solvent, and a coloring agent containing the dye of [3]. [5] A color filter formed using the coloring composition as in [4]. [6] A display device 'which contains a colored tear film as in [5]. [Embodiment] The compound of the present invention is a compound represented by the formula (I) (hereinafter sometimes referred to as "compound (I)"). 156701.doc Δ * 8 201206897

(i> [In the formula (1), L represents a saturated hydrocarbon group having a carbon number of s", and the hydrogen atom of s in the saturated hydrocarbon group may be substituted by a fang atom, and -CH2- contained in the saturated smoky group It may be substituted by _C〇- or -0. R1 and R2 each independently represent a hydrogen atom, a monovalent aliphatic hydrocarbon group having a carbon number of 1 to 16 which may have a substituent, or a carbon number which may have a substituent a fluorenyl group of 2 to 18. The RR group independently represents a hydrogen atom, a monovalent aliphatic lung hydrocarbon group having a carbon number of 1 to 8 or a substituent having a carbon number of 6 to 10 The valent aromatic hydrocarbon group 'which is contained in the aliphatic smoky group may be substituted by _〇_. R 〜 R each independently represents a hydrogen atom or a contending group. X and X represent an inorganic anion or an organic anion]. The number is a linear divalent linear hydrocarbon group of 1 2G, and the halogen atom contained in the saturated tobacco group may be substituted by a south atom, and the -Cfi2- contained in the saturated hydrocarbon group may also be -CO- or -0 _Substitute = and the nicotine group may be any group of carbons having a carbon number of 〇2〇, a carbon number of Η, and a carbon number of 4 to 2g. ^ #j幻举Methylene, Ethyl, propylenediyl, propylenediyl, butyldiyl, pentylpentyl, hexyldiyl, heptyldiyl, octyldiyl, oxime 156701.doc 201206897 Diji, 14th Institute II and 20 Hyun•diyl, etc. As the -CH2·trans-oxime-substituted alkanediyl group, -(CH2)3-〇-(ch2)3-, -(CH2)3-〇-(CH2)4- 〇-(CH2)3- and -(CH2)3-〇-(CH2)2-〇-(CH2)2-〇-(ch2)3-, etc. As the cycloalkanediyl group, cyclopentane is exemplified The base, the cyclohexanediyl group, the cyclooctyldiyl group, etc. The base group which is combined with a ring base group, and the base shown below are mentioned.

As L, it is preferred that -CHr may be substituted with an alkyl 2 group having 5 to 15 carbon atoms, and preferably -CH 2 may be substituted with a linear alkyl group of 5 to 15 which is substituted by _〇. More preferably, the CH2· may be substituted with a linear alkyl group having a carbon number of 6 to 1 Å. Preferred examples include, for example, _(CH2)6_, _(CH2)i〇_, -(CH2)3-o-(CH2)3-'-(CH2)3-〇-(CH2)4- 〇-(CH2)3-^-(CH2)3-0-(CH2)2-0-(CH2)2-0-(CH2)3-. R and R each independently represent a hydrogen atom, and may have a substituent of a monovalent aliphatic hydrocarbon group having 1 to 16 carbon atoms or may have a substituent having a carbon number of 2 to 18 156701.doc * 6 -

Base of 201206897. The monovalent aliphatic hydrocarbon group having 1 to 16 carbon atoms may be any of a linear chain, a branched chain or a ring. The carbon number of the aliphatic hydrocarbon group does not include the carbon number of the substituent, and the number is preferably 6 to 1 Torr, more preferably 1 to 4. Examples of the above monovalent aliphatic hydrocarbon group include a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, an isobutyl group, a second butyl group, a third butyl group, and a methyl butyl group (for example). 1,1,3,3-tetramethylbutyl or the like), methylhexylfluorene 5-dimethylhexyl, etc.) 6-hexyl group (2-ethylhexyl group, etc.), cyclopentyl group, cyclohexyl group, methyl group Hexyl (2-methylcyclohexyl, etc.) and cyclohexylalkyl group. The hydrogen atom contained in the above monovalent aliphatic hydrocarbon group may be substituted by an alkoxy group or a slow group having a carbon number of 丨8. Examples of the valent aliphatic hydrocarbon group substituted by the alkoxy group having a carbon number of 8 include a propoxypropyl group (3-(isopropoxy)propyl group, etc.) and an alkoxypropyl group (3-(2).乍 等 such as -ethylhexyloxy)propyl group is substituted by a carboxyl group. The 丨.丨6 aliphatic hydrocarbon group 'is exemplified by 2-carboxyethyl, 3-carboxyethylpropyl and 4-carboxybutyl. The hydrogen atom contained in the fluorenyl group having a carbon number of 2 18 may be substituted by an alkoxy group having a carbon number of 1 to $. The carbon number of the fluorenyl group having a carbon number of 2 to 18 which may have a substituent includes a substitution. The number of carbons is preferably calculated as the fluorenyl group which may have a substituent, and examples thereof include an acetamyl group, a benzoquinone group, and a methoxybenzylidene group (p-methoxybenzyl group). And R2 is preferably a hydrogen atom, a carbon number of a valence group, or a carbon number of 2 to 5. As a preferred group, a hydrogen atom, a (10) group and a C. The sulfhydryl group is more preferably a hydrogen atom. R to R each independently represent a hydrogen atom, and the carbon number which may be substituted is VIII 8 156701, the monovalent aliphatic hydrocarbon group of doc 201206897 or the carbon number which may be substituted is 6 ~10 of the H Jia Aroma The carbon number of the monovalent aliphatic hydrocarbon group having a carbon number of 1 to 8 does not include the carbon number of the substituent, and the number is 1 to 8'. Preferably, the carbon number of the valent aromatic hydrocarbon group is 1 to Ο. Including the carbon number of the substituent, the number is 6 to 1 Torr, preferably 6 to 8 〇. The valence of the aliphatic hydrocarbon group having a carbon number of 1 to 8 may be a linear chain, a branched chain or a ring 2 In the above-mentioned aliphatic hydrocarbon group, the number of carbons in the group which is exemplified as the monovalent aliphatic hydrocarbon group of the Chinese and R2 is J 8 to 8. The valence aliphatic group having a carbon number of 1 to 8 The CHr contained in the hydrocarbon group may also be substituted by _〇-. The carbon number is VIII; the valent aliphatic hydrocarbon group _ contained hydrogen atom may be substituted by a halogen atom such as a gas atom. R~R is preferably a hydrogen atom. Further, -CHr may be substituted by _〇_ with a carbon number of 1 to 6. The preferred group may be a gas atom, a methyl group, an ethyl group, or a (CH2)2CH(CH3)2. -(CH2) 2-〇-CH3 ^^-(CH2)3-0-CH3, ^ is a hydrogen atom or an ethyl group. R to R14 each independently represent a hydrogen atom or a methyl group, preferably a methyl group. Inorganic anion or organic anion. As an anion machine anion Can be listed as sugarcane. Preparation ^ fluoride ion, chloride ion, bromide from octapeptide ion 'perchlorate ion, hypochlorous acid ion, p-toluene, thousands of, CH3-CO〇-, Ph ^ is listed: gasification Rr perchloric acid; ro"cF3·803·, etc., preferred ion, C perchloric acid 夂 ion, CH3-C00-, p-toluene recorded in the case of the organic compound in the resin hardening compound It is useful as a non-metal salt, and is also useful in the field of emphasizing the insulating injection. > 156701.doc 201206897 As the compound (I), a compound represented by the formula (1-1) to the formula (1-18) can be cited. . L in the table indicates that the bond bond on the right side is a bond with the nitrogen atom of -NR1-.

[Table 1] 1-1 L R1 R2 —H —H R3 R3, R4 R4′ —C2H5 —C2H5 —c2h5 —C2H5 R5 R5, R6 R6′ —Η ——H —H —H R7 R7′ R8 R8 ' —ch3 —ch3 —ch3 —ch3 X • X Cl Cl [Table 2] 1-2 L R1 R2 —(CH2)12 — —H —H R3 R3′ R4 R4′ —C2H5 —C2H5 —C2H5 —c2h5 R5 R5 ' R6 R6' ——H —H —H —H R7 R7′ R8 R8, _ch3 —CH3 —CH3 —ch3 XX' Cl Cl 156701.doc 201206897 [Table 3] 1-3 L Ri R2 —H —H R3 R3 ' R4 R4' —C2H5 _C2H5 —C2H5 _C2H5 R5 R5′ R6 R6′ ——Η —H —H —H R7 R7, R8 R8′ —ch3 —ch3 _ch3 —ch3 XX, Cl Cl [Table 4] 1-4 L R1 R2 h3c &H3 —H —H R3 R3, R4 R4′ —C2H5 —C2H5 —C2H5 —C2H5 R5 R5′ R6 r6_ —H —H —H —H R7 R7 R8 R8′ —ch3 —ch3 _ch3 _CH3 XX' Cl Cl 156701.doc •10- 8 201206897 [Table 5] 1-5 L R1 R2 H3Cxrc r ——H —H R3 R3, R4 R4, —C2H5 —C2H5 —C2H5 —C2H5 R5 R5′ R6 R6′ —Η — H — H — H R7 R7' R8 R8' — ch3 — ch3 — ch3 — ch3 XX, Cl Cl [Table 6] 1-6 L R1 R2 ——H —H R3 R3′ R4 R4′ _C2H5 —C2H5 —C2H5 —c2h5 R5 R5′ R6 R6′ —H —H ——H ——H R7 R7 ' R8 R8. —ch3 —ch3 —ch3 —CH3 XX' Cl Cl 156701.doc -11 - 201206897 [Table 7] 1-7 L R1 R2 —H —H R3 R3′ R4 R4′ One c2h5 —c2h5 _C2H5 One C2H5 R5 R5' R6 R6' - c2h5 - C2H5 - C2H5 - C2H5 R7 R7' R8 R8. - Η - H - H - HXX, Cl Cl [Table 8] 1-8 L R1 R2 — (CH2)i2 — — H —H R3 R3' R4 R4' —C2H5 —C2H5 —C2H5 —C2H5 R5 R5′ R6 R6′ _c2h5 _C2Hs —C2H5 —C2H5 R7 R7′ R8 R8′ —H —H —H —HXX' Cl Cl 156701.doc •12 - 8 201206897 [Table 9] 1-9 L R1 R2 —H —H R3 R3′ R4 R4′ —C2H5 —c2h5 A C2H5 —〇2H5 R5 R5′ R6 R6′ _C2H5 —C2H5 _C2H5 —C2H5 R7 R7' R8 R8' —H —H —H —HXX, Cl Cl [Table 10] 1-10 L R1 R2 h3c XT &H3 —H —H R3 R3′ R4 R4′ _C2H5 —C2H5 —C2Hs —C2H5 R5 R5′ R6 R6′ — C2h5 -·c2h5 —C2H5 —C2H5 R7 R7' R8 R8' —H —H —H —HXX, Cl Cl r- * 156701.doc •13- 201206897 [Table 11] 1-11 L R1 R2 H3C^nc xCH3 —H —H R3 R3, R4 R4′ —C2H5 —C2H5 — C2H5 — C2H5 R5 R5' R6 R6' _c2h5 _c2h5 —c2h5 _c2h5 R7 R7' R8 R8' —Η ——H —H —HXX, Cl Cl [Table 12] 1-12 L R1 R2 —H —H R3 R3, R4 R4' —c2h5 _c2h5 —C2H5 —c2h5 R5 R5′ R6 R6′ _C2^5 _c2h5 —c2h5 —c2h5 R7 R7. R8 R8′ —H —H —H —HXX, Cl Cl 156701.doc • 14· 8 201206897 [Table 13] 1-13 L R1 R2 —H —H R3 R3, R4 R4′ ch3 ch3 —H ——H R5 R5′ R6 R6′ —c2h5 _C2H5 a c2h5 —C2Hs R7 R7′ R8 R8′ —H ——H — H —HXX, Cl Cl [Table 14] 1-14 L R1 R2 —(CH2)12~ ——H ——H R3 R3′ R4 R4′ ch3 丄ch3 —H ——H R5 R5, R6 R6′ —C2H5 _C2H5 _C2H5 —C2H5 R7 R7, R8 R8' —H —H —H ——HXX, Cl Cl •15· 156701.doc 201206897 [Table 15] 1-15 L R1 R2 —H —H R3 R3′ R4 R4′ ch3 Eight people ch3 —H —H R5 R5. R6 R6' _C2H5 —C2H5 a c2h5 —C2H5 R7 R7. R8 R8' —Η —H —H —HXX' Cl Cl [Table 16] 1-16 L R1 R2 h3c ——H —HJ/CH3 ch3 R3 R3. R4 R4' ch3 ch3 Eight JL Eight Diagrams - H - H R5 R5, R6 R6' One C2H5 - C2H5 - C2H5 _C2H5 R7 R7' R8 R8' - H - H - H - HXX, Cl Cl 156701.doc •16· 8 201206897 [Table 17] 1-17 L R1 R2 HXn〇^〇h3 —H —H R3 R3, R4 R4′ ch3 ch3 —H —H R5 R5′ R6 R6′ —C2H5 _C2H5 a c2h5 —C2H5 R7 R7. R8 R8' —H —H —H —HXX' Cl Cl [Table 18] 1-18 L R1 R2 —H —H R3 R3′ R4 R4′ ch3 ch3 —H —H R5 R5′ R6 R6′ _C2H5 — C2h5 —c2h5 _C2H5 R7 R7' R8 R8' —H —H —H —HXX, Cl Cl 156701.doc •17- 201206897 /The composition (1) is preferably...with, ruler 4 and ruler 8, meaning 5 The compound which is the same as the ruler 9, the & 6 and the ruler 10, R, R and rm, x! and X2, respectively, that is, the compound represented by the formula (4) is more preferably the same base as R1 and R2. It Compound. If it is such a compound, a compound can be manufactured easily.

In the formula (4), L, heart, Rn, R, and xl represent the same meanings as described above. The compound (1) can be produced by a compound represented by the formula (I-A) and a compound represented by the formula (Ι·Α,) in a solvent.

[Formula (Ι-Α) and (式-Α,)] 'R3~Rl4, χ1 and χ2 Table* have the same meanings as above. Υ1 and Υ2 represent a transradical, 〇r2〇 or dentate atom. R2〇 represents an aliphatic hydrocarbon group having a carbon number of 1 to 8. And the compound represented by formula (I-B) 156701.doc 8 -18- 201206897

[In the formula (Ι_Β), 'L, R1 and R2 have the same meanings as described above. ] The reaction was carried out at ~〇25〇t. Examples of the compound represented by the formula (IB) include ethylenediamine, butanediamine, hexamethylenediamine, cyclohexanediamine, 1,12-diaminododecane, and 4,4-arylenediamine ( 2_mercaptohexylamine), isophoronediamine, 1,4-butanediol bis(3-aminopropyl)ether, diethylene glycol bis(3-aminopropyl)ether, and the like. The compound represented by the formula (I-B) may be used singly or in combination of two or more. With respect to the total amount of the compound represented by the formula (Ι-A) and the compound represented by the formula (IA,), the amount of the compound represented by the formula (I_B) is preferably 0.5 to 3 mol. ear. In the case where γ and γ2 are hydroxyl groups, it is preferred to use the hydrochloride salt of the compound represented by the formula. Further, in the case where Y1 and Y2 are hydroxyl groups, it is preferred to use a known condensation agent. Examples of the condensing agent include (Ph〇)3p, (ph〇)pCl2, php〇(^, (^3H7)3P(0)0, POCl3, s〇cl2_Et3N, ph3p_c2ci6, etc. The combination of the compound of the formula and the compound represented by the formula (Ι_Α,), the amount of the condensing agent is preferably 2~. (1) The total amount of the compound represented by the formula (10) and the compound represented by the formula (Ι·Α·)! In the case of Mohr, the amount of pyridine used is preferably 2 Å to 8 Å. In the case of , for example, it is preferred to add a known base catalyst. Examples of the base catalyst include sodium ethoxide and sodium hydride. With respect to the total amount of the compound represented by the formula (I Α) J5670l.doc -19·201206897 and the compound represented by the formula (I_A'), the amount of the base catalyst used is preferably 〇〇. 1 to 2 moles. The above reaction is carried out in a solvent. As the solvent, for example, preferred are: water; ethers such as 1,4-dioxane (especially cyclic ethers); gas imitation, dichloromethane, carbon tetrachloride, i,2-dichloroethane , ethylene glycol, trichloroethylene, perchloroethylene, -chloropropanol, gas-fired, 1,2_: Molybdenum and other toothed hydrocarbons; acetone, methyl isobutyl ketone, cyclohexanone Ketones; [carbonaceous aromatics such as toluene and xylene] N,N-monomethylamine, N,N-dibutylamylamine, hydrazine, dimethylacetamide, Nf-based pyrrolidine Alkyl hydrazines such as ketones may be used, and two or more kinds may be used in combination. The amount of solvent used is preferably 1 part by mass of the compound represented by the formula (I_A) and the compound represented by the formula (Ι·Α·). It is 1 to 2G parts by mass, more preferably 2 to Η) by mass. The above reaction is preferably carried out under a nitrogen atmosphere or an argon atmosphere. It can also be carried out under air which is dried by gasification or the like. 2 should be the temperature f is preferably G ~ 25 generation 'better than 1G ~ fine. c. When the reaction is carried out, 4 is preferably 1 to 25 hours, more preferably ^ hours. The compound represented by the formula (Ι_Α), the compound represented by the formula (Ι-Β), and the order of addition of the compound are not particularly limited, and it is preferred to include the formula (IV). The compound represented by the compound, the formula, the compound of the formula and the solvent is added (added) to the compound represented by the formula _. In the case of the (iv) mixture, it is preferred to show the compound, formula (" , in the case of the compound shown in Fig. 2, when adding (dropping) the formula (4)) to the coldness of the cold form, it is preferred to use the octahydrate of the formula. (Ι-Α) is a compound represented by the formula 156701.doc -20. 201206897 (Ι-A'), a solution of a base catalyst and a solvent, and a (drop) formula (Ι-Β) is added. The method of obtaining the compound (I) as the target compound in the reaction mixture obtained in the above manner is not particularly limited, and various known methods (such as acid precipitation or salting out) can be employed. The crystal is usually washed with water or the like, and then dried. Further, it is also known to use recrystallization or the like as needed. Further, the compound of the present invention exhibits high solubility, low transferability, and high spectroscopic concentration, and thus can be used as a dye in a fiber material, a liquid crystal display device or the like which performs color display by reflected light or transmitted light. Further, the compound of the present invention has a maximum absorption in a wavelength band of 500 to 600 nm when measuring an absorption spectrum, and thus can be used as a red or violet dye. The dye of the present invention is a dye containing a compound of the present invention as a main component, and A dye containing the compound of the present invention in an amount of 50% by mass or more. The dye of the present invention may be the compound (1) alone, preferably a dye of two or more kinds of the compound (I). More preferably, it is a mixture. Two or more kinds of dyes which are different from the compound (I), and are excellent in solubility in a solvent by combining the compounds. As a preferred combination of the compounds (1), for example, the formula (1-1) And a compound represented by the formula (1-2): A dye obtained by mixing two or more kinds of the compound (I) can be produced by separately preparing each compound (1) and then mixing them. It can be obtained by making a mixture at the time of manufacture. The latter can be used, for example, in the reaction of the compound represented by the formula (Ι-A) and the compound represented by the formula (I_A,) and the formula (IB), using two or more types ( The compound represented by I_B) is obtained by making a mixture. 156701.doc • 21 · 201206897 The coloring composition of the present invention comprises: a resin selected from a resin (hereinafter sometimes referred to as "resin (B)"), photopolymerizability a compound (hereinafter sometimes referred to as "photopolymerizable compound (C)"), a photopolymerization initiator (hereinafter sometimes referred to as "photopolymerization initiator (D)"), and a solvent (hereinafter sometimes referred to as "solvent" (E)") at least one of the group consisting of the coloring agent containing the dye of the present invention (hereinafter sometimes referred to as "coloring agent (A)"). The colorant (A) may further contain a dye different from the dye of the present invention, and the pigment (A-2) is a dye different from the dye of the present invention, and may be exemplified by the Colour Index (The Society of Dyers and Colourists). In the publication, it is classified into a Solvent, Acid, Basic, Reactive, Direct, Disperse, or Vat compound. More specifically, a dye such as the following dye index (C.I.) may be mentioned, but is not limited thereto. CI Solvent Yellow 25, 79, 81, 82, 83, 89; CI·Acid Yellow 7, 23, 25, 42, 65, 76; C_I. Reaction Yellow 2, 76, 116; CI Direct Yellow 4, 28, 44, 86,132; CI disperse yellow 54,76; CI solvent dial 41,54,56 '99; CI acid orange 56,74,95,1〇8,149,162; CI reaction orange 16; CI direct dial 26 ; CI Solvent Red 24, 49, 90, 9 Bu 118, 119, 122, 124, 125, 156701.doc 8 -22· 201206897 127, 130, 132, 160, 218; C·I. Acid Red 73, 9l, Q9, 〇7 y2 97, 138, 15 Bu 2U, 274, 289; CI Acid Violet i〇2; C ccccccccc Γ·Solvent Blue 35, 37, 38 I· Acid Blue 40, 45, 78 I. Test Blue 65, 14 〇; I. Reaction Blue 15, 38; Work. Disperse Blue 143; L Direct Blue 86, 87; I·Solvent Green 1, 5; I. Acid Green 3, 5, 9 I. Green 1; I. Green 1 ; 44 , 59 , 64 , 67 , 70 ; 8〇 ' 83 , 90 , 100 , 171 185 ; 25 ' 28 ; CI acid black 5 8 , 6 〇 , 1 〇 7 ; CI solvent black 27 , etc . The pigment (A-2) may, for example, be an organic pigment or an inorganic pigment which is usually used in a pigment dispersion anti-money agent. Examples of the inorganic pigment include a metal compound such as a metal oxide or a metal salt, and specific examples thereof include metal oxides such as iron, cobalt, aluminum, ore, lead, copper, titanium, magnesium, chromium, and rhodium. Composite metal oxide. Further, specific examples of the organic pigment and the inorganic pigment are listed in the Colour Index (published by The Society of Dyers and Colourists) and classified as a pigment (Pigment) compound. More specifically, the following dye index (Cl) number of pigments may be mentioned, but it is not limited thereto. 156701.doc 23· 201206897 CI Pigment Yellow 2〇, 24, 3 Bu 53, 83, 86, 93, 94, 109, 110, 117' 125, 137, 138, 139, 147, 148, 150, 153, 154, 166, 173 and 180; cl pigment orange 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65 and 71; CI pigment red 9, 97, 105, 122, 123, 144, 149, 166, 168, 176, 177, 180, 192, 215, 216, 224, 242, 254, 255 and 264; CI Pigment Violet 14, 19, 23, 29, 32, 33, 36, 37 and 38 CI Pigment Blue 15 (15:3, 15:4, 15:6, etc.), 21, 28, 60, 64 and 76; CI Pigment Green 7, 10, 15, 25, 36 and 47; C. I · Pigment 2, CI Pigment Black 1 and 7, etc. The content of the colorant (A) is preferably 5 to 60% by mass, more preferably 8 to 5 5 %, based on the solid content of the coloring composition. The mass%, and more preferably 10 to 50% by mass. Here, the term "solid content component" means the total of components other than the solvent in the coloring composition. In the case where the colorant (A) further contains a dye or pigment (A-2) different from the dye of the present invention, the content of the dye of the present invention in the toner (A) is preferably from 3 to 80% by mass. 'Better is 3 to 70 mass. /. More preferably, it is 3 to 5 〇 mass%. The content of the pigment (A-2) in the colorant (A) is from 2 to 97% by mass, preferably from 30 to 97% by mass, more preferably from 50 to 97% by mass. 156701.doc -24- 201206897 The resin (B) is not particularly limited, and any resin can be used. For example, the resin (B) contains a structural unit derived from (meth)acrylic acid. Here, (meth)acrylic acid means acrylic acid and/or methacrylic acid. As the resin (B), specifically, preferred is: methacrylic acid/methacrylic acid vinegar copolymer, methacrylic acid/benzyl methacrylate/styrene copolymer, methacrylic acid/methacrylic acid Benzyl ester / isobornyl methacrylate copolymer, methacrylic acid / styrene / benzyl methacrylate / N_phenyl maleimide copolymer, methacrylic acid and selected from the formula (Bqq) A copolymer of at least one of the compound and the compound represented by the formula (B-1-2).

The acid value of the resin (B) is preferably from 5 to 15 Torr, more preferably from 6 to 135, and particularly preferably from 7,000 to 28,000. More preferably 60~135, especially good is 70~135. Relative to the solid content of the coloring composition

quality%.

The active white sputum produced by the initiator (D), the secret μ " ~ self-photopolymerization with irradiation light - the keyization

Compounds, etc. 156701.doc •25·201206897 The photopolymerizable compound (c) is preferably a photopolymerizable compound having three or more polymerizable groups. Examples of the photopolymerizable compound having three or more polymerizable groups include pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol pentaacrylate, dipentaerythritol pentamethyl acrylate, and dipentaerythritol hexaacrylate. Ester, dipentaerythritol / methacrylate, and the like. The photopolymerizable compound (c) may be used singly or in combination of two or more. The content of the photopolymerizable compound (C) is preferably from 5 to 65% by mass, more preferably from 1 to 6 % by mass, based on the solid content of the coloring composition. Examples of the photopolymerization initiator (D) include a living radical generator, a ruthenium generator, and the like. The living radical generating agent is a compound which generates an active radical by irradiating light. The living radical generating agent may, for example, be an acetophenone compound, a benzoin compound, a dioxin, a thioxanthone compound, a tris-toxin compound or an anthraquinone compound. Examples of the acetophenone compound include diethoxyacetophenone, 2-N-morpholinyl-1-(4-methylsulfanylphenyl)-2-mercaptopropanone, and 2-hydroxyl group. -2-mercapto-1-phenylpropane-fluorenone, benzoin dimethyl ketal, 2-hydroxyl-factor methyl-W4-(2-hydroxyethoxy)phenyl]propanone, hydrazine An oligomer of 2-hydroxycyclohexylphenylphosphonium, 2-carbyl-2-methyl-[4-(1-methylethenyl)phenyl]propylamine, etc., preferably 2-morpholine Methylsulfanylphenyl)-2-mercaptopropyl-i-ketone and the like. The benzoin compound may, for example, be benzoin, amyl ether, benzoin ethyl ether, benzoin isopropyl (tetra), benzoin isobutyl ether or the like as the above benzophenone compound, and for example, 156701.doc -26·201206897 benzene Ethyl mercaptobenzoate, 4-phenylbenzophenone, 4-benzylidene- 4,•methyldiphenyl sulfide, 3,3,,4,4,-tetra (t-butyl Peroxycarboxyl)dibenzophenone, 2,4,6-tridecyldibenzophenone, and the like. Examples of the above thioxanthone compound include 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, and 2,4-dithioxanthone. Buqi-4-propoxythioxanthone and the like. Examples of the above-mentioned di-cultivated compound '2,4 bis(trimethylsulfonyl)-6-(4-methoxyphenyl)-1,3,5_3 1> well, 2,4_double ( Triseocarbyl)_6_(4_methoxynaphthyl)-1,3,5 tris, 2,4-bis(trichloroindenyl)_6_(4_decyloxystyryl)-1,3, 5-Mitjing, 2,4-bis(trimethylmethyl)_6_[2_(5_mercaptofuran-2-yl)vinyl]-1,3,5-three tillage, 2,4-double (three gas Base)_6_[2_(furan_2_yl)vinyl]-1,3,5-three tillage, 2,4-bis(trismethyl)_6·[2_(4_diethylamino-2 -mercaptophenyl)vinyl]_丨, 3,5_three tillage, 2,4_bis(trimethylsulfonyl)-6_[2-(3,4·didecyloxyphenyl)vinyl] -1,3,5-three tillage, etc. As the above-mentioned compound, for example, a ruthenium-based fluorene-based compound can be mentioned, and specific examples thereof include: Ν_benzhydryloxy_丨_(4-phenylsulfanylphenyl)butane-1 -keto-2-imine, N-phenylhydrinyloxy 4-(4-phenylsulfanylphenyl)octane-1-one-2-imine, N-ethyloxyl_ι_[ 9-Ethyl-6-(2-methylbenzylidene)-9H-indazol-3-yl]ethane-1-imine, N•ethyloxy-indenyl-ethyl-6- {2-Mercapto-4-(3,3-dimercapto-2,4-dioxolanyloxy)phenylhydrazinyl 9H-indazol-3-yl]ethane-1- Imine and the like. 'As a living radical generator, for example, 2,4,6-trimethyl adenyl diphenylphosphine oxide, 2,2,-bis(o-chlorophenyl)-4,4, ,5,5'-tetraphenyl-1,2'-biimidazole, 10-butyl-2-acacridone, 2-ethyl hydrazine, diphenyl 156701.doc -27· 201206897 Diketone, 9,1 quinone-phenanthrenequinone, camphorquinone, methyl phenylglyoxylate compound, and the like. An acid generator is a compound which generates an acid by irradiating light. Examples of the acid generator include, for example, 4-hydroxyphenyldi, phenyl-p-toluene citrate, 4-hydroxyphenyldimethylsulfonium hexafluoroantimonate, and ethoxylated phenyl dimethyl carbonate.锜p-toluenesulfonate, 4_acetoxyphenyl-methyl-benzyl hexafluoroantimonate, triphenyl(tetra)pyridinium salt, triphenyl sulfamate, diphenyl It is a rust salt such as a phthalic acid salt or a diphenyl sulfonium salt or a nitrobenzyl toluene sulfonate or a benzoin tosylate. Further, in the above compound as the above-mentioned living radical generating agent, there is also a compound (9) which generates an acid at the same time as the active radical is generated. For example, a sakizaki photopolymerization initiator can also be used as the acid generator. The content of the photopolymerization initiator (D) is preferably 〇30% by mass, more preferably 1 to 20% by mass based on the total amount of the resin (Β) and the photopolymerizable compound (c). /. . When the content of the photopolymerization initiator is within the above range, the sensitivity is increased and the exposure time is shortened, thereby improving productivity. Examples of the solvent (8) J include a ketone, a trans group, a ketone other than the above, an alcohol, a self-acting type, and a guanamine. As the above-mentioned slits, for example, it can be exemplified by the following: exemplified by tetrahydrofuran, tetrahydropyran, decyl dioxane, ethylene glycol monoterpene ether, ethylene glycol monoethyl ether, & ethylene glycol monobutyl Ether, diethylene glycol monomethyl ether glycol monobutyl ether, diethylene glycol dioxime ether, alcohol methyl ethyl ether, diethyl propylene glycol monoterpene ether, propylene glycol monoterpene ether ethylene glycol monopropyl Ether, monoethyl, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, malonate, propylene glycol monoethyl ether acetate 156701.doc 8 -28· 201206897 propylene glycol monopropyl ether acetate, Yue Acetate, diethylene glycol monoacetic acid vinegar: ethylene glycol single ethyl, such as A, _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Shouting 酉夂 酉夂 As the above aromatic furnace _ ^, for example, stupid, toluene, -A laughing, and all three f benzene are mentioned. The present ketones, for example, 3 lions, "ketone, 2-butanone, 2 · heptanone, 3 heptanone, 4-heptanone, 4-methyl 7# an m fluorenone, 4_ residue -4-Methyl-2-fluorenone, levopentone, cyclohexanone, etc. As the above alcohols, for example, it can be listed in the field, and exemplified by methanol, ethanol, propanol, butanol, ':cyclohexanol Ethylene glycol, glycerin, etc. Examples of the above-mentioned brewings include acetic acid 6 vinegar, n-butyl vinegar acetate, isobutyl ketone acetate, valeric acid formic acid, isovaleric acid acetate, isobutyl vinegar acetate, and butyl vinegar. Butyric acid isopropyl vinegar, butyric acid, butyl vinegar, butyl vinegar, lactic acid methyl vinegar, lactic acid ethyl vinegar, lactic acid butyl vinegar, methyl acetate methyl vinegar, methoxy acetic acid vinegar, methoxy Butyl acetate, ethoxyacetic acid methyl acetate, ethyl ethoxyacetate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, decyl ethoxy propionate, 3- Ethyl ethoxypropionate, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, decyl 2-ethoxypropionate, ethoxylate Ethyl propyl propionate, decyl 2-methoxy-2-methylpropionate, 2-ethoxy-2 曱Ethyl propionate, methyl pyruvate, ethyl pyruvate, propyl pyruvate, decyl acetate, ethyl acetate, 3-methoxybutyl acetate, 3-methyl-3- Examples of the above guanamines include hydrazine, hydrazine dimethyl carbamide, hydrazine, hydrazine-dimercaptoacetamide, hydrazine- Methylpyrrolidone, etc. 156701.doc • 29- 201206897 As the solvent (E), propylene glycol monoterpene ether and propylene glycol monoterpene ether acetate are preferred. These solvents may be used singly or in combination of two. The content of the solvent (E) in the coloring composition is preferably 70 to 95% by mass, more preferably 75 to 90% by mass based on the coloring composition. The coloring composition of the present invention may further The surfactant (G) is contained. Examples of the surfactant (G) include a polyfluorene-based surfactant, a fluorine-based surfactant, and a polyfluorene-based surfactant having a fluorine atom. Examples of the surfactant include a surfactant having a decane bond, etc. Specifically, Toray Silicone DC3PA, To Ray Silicone SH7PA, Toray Silicone DC11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone SH30PA, Polyether Modified Emu Oil SH8400 (trade name: Dow Corning Toray Co., Ltd.), KP321, KP322, KP323, KP324 'KP326, KP340, KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF-4446, TSF4452, TSF4460 (manufactured by Momentive Performance Materials Japan Co., Ltd.). The fluorine-based surfactant may, for example, be an interface active agent having a fluorocarbon chain. Specific examples include: Fluorad (trade name) FC430, Fluorad FC431 (manufactured by Sumitomo 3M Co., Ltd.), Megafac (trade name) F142D, Megafac F171, Megafac F172, Megafac F173, Megafac F177, Megafac F183, Megafac R30 (DIC shares limited) 156701.doc -30- 8 201206897 company made), Eftop (trade name) EF301, Eftop EF303, Eftop EF351, Eftop EF352 (manufactured by Mitsubishi Materials Electronic Chemicals Co., Ltd.), Surflon (trade name) S38 Bu Surflon S382, Surflon SC101 , Surflon SC105 (manufactured by Asahi Glass Co., Ltd.), E5844 (manufactured by Daikin Precision Chemical Research Co., Ltd.), etc. Examples of the polyoxo-based surfactant having the above-mentioned atoms include a surfactant having a cerium oxide bond and a fluorocarbon chain. Specific examples include: Megafac (registered trademark) R〇8, Megafac BL2〇, pm,

Megafac F477, Megafac F443 (manufactured by DIC Corporation), and the like. The content of the surfactant (9) is preferably 0.00001 to 0.2 mass based on the coloring composition. /〇 ‘Better is the quality 〇/〇. When the content of the surfactant (9) is within the above range, the flatness becomes good and the tendency is good. The sputum-inducing agent can be used as a single color film or a pattern thereof as the use of the composition of the present invention. Method: The colored composition of the present invention is applied to a pure or other resin layer (for example, pre-formed on a substrate: and the like: a substance: etc.), and a volatile component such as a solvent is removed/dried to form a colored layer' and passes through the light. In the case where there is no case, the film thickness of the coating film is not particularly limited, and may be appropriately adjusted depending on the materials to be used, the use, and the like. , 0Λ 疋 0.1~30 μηι, more preferably 1~20μ1η, and more preferably, the coating method of the enamel coloring composition is illusory. The rubbing coating method, directly 156701.doc -31· 201206897 concave Plate printing method, reverse gravure drawing Φ2V + P brush coating method, CAP coating method ' = using a dip coater, a bar coater, a spin coater, a slit & spin coating Cloth machine, m heart # 贱 to knife coating machine (sometimes also known as extrusion coating machine, curtain coating machine, non-cloth Non-rotating machine coater), etc. As for coating coater of removing the solvent or drying, such as drying, drying under reduced pressure and the like. Specifically, from (four) dry 'ventilation, dry / dish is better than 1 〇 ~ 12 〇 Τ ', more preferably 25 ~ 10CTC.干燥 The drying time is preferably from 10 seconds to 6 minutes, more preferably from % seconds to % minutes. In the case of drying under reduced pressure, it is preferably carried out under a pressure of 5 Torr to 5 Torr, and a temperature of 20 to 25 ° C. The coating film of the dry region is not particularly limited by the mask for forming the target pattern. The shape of the pattern on the mask is not particularly limited, and the pattern shape corresponding to the target of the disc can be used. As the light source for exposure, a light source for generating light having a wavelength of 250 to 450 nm is preferable. Specific examples thereof include a mercury lamp, a light-emitting diode, a metal element lamp, a tooth lamp, and the like, and can also be worn by using a light-emitting sheet of a specific band or by selectively extracting a band pass m of a specific band. And exposure. In order to illuminate the parallel light of the entire exposure surface, or to perform the precise alignment of the mask "earth material", it is preferable to use a mask aligner, a stepper, etc. After the exposure, The pattern can be obtained by developing the material, for example, by dissolving the unexposed portion, and obtaining a pattern. As the developer, 156701.doc 8 -32·201206897 can also include a basic compound which can also contain a surfactant ( An aqueous solution such as a water-sparking-removing solution, a sodium carbonate or a tetramethylammonium hydroxide, etc. The plating method may be any one of a liquid coating method, a dipping method, a spray method, etc. Further, the substrate may be tilted at any time during development. The angle is preferably water-washed after development. ▲ Further 'post-baking treatment may be performed as needed. The post-baking treatment is preferably in the range of, for example, 150 to 230 ° C for 10 to 240 minutes. The coloring composition can be suitably used for forming a color filter or a colored pattern. By the coloring composition of the present invention, coloring patterns and colors excellent in color density, brightness, contrast, sensitivity, resolution, heat resistance, and the like can be obtained. The color filter or the colored pattern may be used as part of a component such as an optical film, an array substrate, a color filter substrate, etc. Further, selected from the optical film, the array substrate, and the color filter. At least one type of the group of the sheet substrates can be used in a display device such as a liquid crystal display device or an organic EL (Electroluminescence) device, and a solid-state image sensor or the like in a device related to a color image. Since the compound of the present invention has low transferability, a color filter for a display device having excellent display characteristics can be produced from a coloring composition containing a dye containing a compound of the present invention as a main component. Examples Hereinafter, the present invention will be described by way of examples. Further, the "%" and "parts" in the examples and comparative examples are % by mass and parts by mass unless otherwise specified. Example 1 156701.doc 33·201206897 The following reaction was carried out under a nitrogen atmosphere. After adding N-mercaptopyridone 2 份 2 parts to 15.0 parts of C.I. redness in a four-necked flask equipped with a reflux tube, the mixture was stirred for 30 minutes to prepare a reaction solution. 1.05 parts of 1,1 2-diaminododecane was added dropwise while removing the reaction solution at room temperature. After the completion of the dropwise addition, the reaction vessel was kept at 140 degrees while mixing for 3 hours. Further, 0.53 parts of J j 2_monoamine 10·1 Hyun> was added to the reaction solution, and then the anti-deer was held at 140 degrees for 3 hours. Further, 0.53 parts of 1,12-diamine was added to the reaction solution, and then the reaction vessel was kept at 140 degrees while mixing for 3 hours. The reaction solution cooled to room temperature was poured into 0 2 liter of 10% hydrochloric acid water to obtain a red suspension. The red solid obtained by filtration was dried under reduced pressure at 60 ° C to obtain 1.3 parts of the compound of the formula (I-1) (yield 23%).

The structure of the compound (1-2) is determined by mass spectrometry. The mass spectrometer was JMS-7〇0 (manufactured by JEOL Ltd.). Mass spectrometry. Ionization mode = FD + : m / z = 1065 0.35 g of compound (1-2) was dissolved in ethyl lactate to make a volume of 250 cm 3 , and 2 cm 3 of it was diluted with ion-exchanged water. The volume was 100 cm3 (concentration: 0.028 g/L), and the absorption spectrum was measured using an ultraviolet-visible near-infrared spectrophotometer (V-650; manufactured by JASCO Corporation) (quartz cell, optical path length: 1 cm). The compound was shown to be 156701.doc •34· 8 201206897 absorbance of 1·6 (arbitrary unit) at Xinax=529 nm. Example 2 The following reaction was carried out under a nitrogen atmosphere. After adding 20.0 parts of Ν-methylpyrrolidone to 15.0 parts of C.I. basic red in a four-necked flask equipped with a reflux tube, the mixture was stirred for 30 minutes to prepare a reaction solution. The reaction solution was stirred at room temperature while 1.07 parts of 1,4-butanediol bis(3-aminopropyl)ether was added dropwise. After the completion of the dropwise addition, the reaction vessel was kept at 140 ° while stirring for 3 hours. Further, 0.54 parts of 1,4-butanediol bis(3-aminopropyl)ether was added to the reaction solution, and the mixture was stirred while maintaining the reaction vessel at 140 degrees for 3 hours. Further, 0.54 parts of 1,4-butanediol bis(3-aminopropyl)ether was added to the reaction solution, and then the reaction vessel was kept at 140 ° while stirring for 3 hours. The reaction solution cooled to room temperature was poured into 0.2 liter of 1% hydrochloric acid water to obtain a red suspension. The red solid obtained was filtered under reduced pressure, 6 Torr. (: drying was carried out) to obtain 1,6 parts of the compound represented by the formula (1-3) (yield 29%).

The structure of the compound (1-3) is determined by mass spectrometry. The mass spectrometer was JMS-700 (manufactured by JEOL Ltd.). Mass spectrometry: ionization mode = FD + : m / z = 10 〇 68 The compound (1-2) 0.35 g was dissolved in ethyl lactate to make a volume of 25 〇 cm ' and the 2 em 3 of the towel was ion exchanged. The water was diluted to a volume of 156701.doc •35·201206897 of 1〇〇cm (concentration: 0.028 g/L). The absorption spectrum was measured using an ultraviolet-visible near-infrared spectrophotometer (quartz trough 'light path length: 1 cm). The compound showed an absorbance of 2 〇 (arbitrary unit) at Xmax = 53 0 nm. Resin Synthesis Example 1 In a flask equipped with a reflux condenser, a dropping funnel, and a stirrer, nitrogen was introduced into a nitrogen atmosphere, and 3-methoxybutanol was added in an amount of 2 parts by mass and 3- 1 part by mass of methoxybutyl acetate was heated to 70 C while stirring. Then, 98 parts by mass of mercaptoacrylic acid, _3,4 epoxybicycloquinone·2.1·02 decyl acrylate (the compound represented by the mixed formula (B-1-1) at a molar ratio of 50:50 and 394 parts by mass of the compound represented by the formula (B-1 - 2) was dissolved in 140 parts by mass of 3-methoxy-1-butanol to prepare a solution, and the solution was added dropwise to the mixture for 4 hours using a drip pump. The temperature was kept at 7 Torr < t to the inside of the flask. On the other hand, using a different drip pump, a polymerization initiator 2,2'-azobis(2,4-dimethylvaleronitrile) was dissolved in 24 parts by mass of 3-methoxybutyl acetate. 27 parts by mass of the solution was added dropwise to the flask over 4 hours. After completion of the dropwise addition of the polymerization initiator solution, it was kept at 70 C for 4 hours, and then cooled to room temperature to obtain a solution of a copolymer (resin b 1) having a solid content of 44.3 % by mass. The obtained resin B i had a weight average molecular weight Mw of 7500 'molecular weight distribution of I? and an acid value of 111 mgKOH/g. H2C-CH-C-0

(B-l-1) ο H2C=CH-C-0

The components used in the following examples may be omitted as described below. 156701.doc • 36 - 201206897 (1-2) Colorant: azo compound synthesized in Example 1 σ·3) Colorant: azo compound (II-1) coloring agent synthesized in Example 2: Authentic Red 1 (Β-1) Resin: Resin Β1 solution (Β-2) Resin: methacrylic acid/benzyl methacrylate (Morby: Copolymer (manufactured by Tajika Chemical Industry Co., Ltd., average molecular weight 1〇) 7〇〇, acid value 70mgKOH/g) 33.8% propylene glycol monomethyl ether acetate solution (C-1) polymerizable compound · dipentaerythritol hexaacrylate (KAYARAD DPHA; manufactured by Nippon Kayaku Co., Ltd.) (D- 1) Photopolymerization initiator: N_benzoyloxyphenylsulfanyl group) octyl-1-oxan-2-amine (lrgacure OXE01; manufactured by BASF Japan) (G-1) interface Active agent: polyether modified shisha oil (T〇ray Silicone SH8400; manufactured by D〇W Corning Toray Co., Ltd.) (E-1) Solvent: propylene glycol monomethyl ether (E-2) solvent: propylene glycol monomethyl ether Acid ester (E-3) solvent: N,N-dimethyl decylamine Example 3 [Preparation of coloring composition] (1-2) 0.30 parts by mass (B-1) 1.67 parts by mass (C-1) 0.74 parts by mass (D-1) 0.22 parts by mass (G-1) 0.001 parts by mass doc -37·201206897 (Ε-1) 6.23 parts by mass (Ε-2) 〇·84 parts by mass to obtain a colored composition 0 [Preparation of Resin Composition] (Β-2) 40.2 parts by mass (C-1) 5.8 parts by mass (D-1) 0.58 parts by mass (G-1) 0·01 parts by mass (Ε-1) 46.6 parts by mass (Ε-2) 6.8 parts by mass of the mixture was mixed to obtain a resin composition. [Formation of Colored Coating Film] The above-obtained coloring composition was applied onto glass (#1737; Coming) by a spin coating method, and the volatile component was volatilized at 10 Torr for 3 minutes. After cooling, 'Using an exposure machine (TME-150RSK; manufactured by T〇pc〇n Co., Ltd.)', the light is irradiated at a dose of 150 mj/cm 2 (365 nm basis) in the atmosphere to form a coating of the colored composition. Film film (film thickness 2 2 μπι). [Formation of Resin Coating Film] The coloring composition obtained above was applied onto glass (#1737; Corning) by a spin coating method, and the volatile component was volatilized at i〇〇°C for 3 minutes. After cooling, light irradiation was performed using an exposure machine (TME-150RSK; manufactured by Topcon Co., Ltd.) at an exposure amount of 150 mJ/cm 2 (365 nm) in an atmospheric environment. The film was heated at 220 ° C for 2 hours in an oven to form a coating film (film thickness 2.2 μηι) of the resin composition. 156701.doc 8 •38-201206897 [Evaluation of the transfer property] The coating film of the coloring composition and the coating film of the resin composition were opposed to each other at a space of 70 μm, and heated at 230 ° C. In the minute, the color difference (AEab*) before and after heating of the coating film of the resin composition was measured using a colorimeter (〇SP-SP-2〇0; manufactured by OLYMPUS Co., Ltd.) 实施 The above-mentioned transfer film was subjected to the above-mentioned transferability. As a result, the color difference (?Eab*) of the resin composition was 2 2 as a result. Example 4 [Evaluation of Transfection Property] Except that (1-2) coloring agent: the octagonal compound synthesized in Example 1 + was changed to (1-3) coloring agent: other than the azo compound synthesized in Example 2. In the same manner as in Example 3, the coating film of the colored composition and the coating method of the resin "object" were subjected to evaluation of the transferability, and as a result, the resin combination (?Eab*) was 1.8. Comparative Example 2 [ Preparation of coloring composition] (IM) 0·30 parts by mass (B-1) h 67 parts by mass (C-1) 〇·74 parts by mass (D-1) G·22 parts by mass (G-1) 〇· 1 part by mass of (E-2) 0.84 parts by mass (E-3) and 6·23 parts by mass were mixed to obtain a colored composition. [Formation and Evaluation of Coating Film] 156701.doc -39·201206897 In the same manner, the coating film of the coloring composition and the coating film of the resin composition were prepared, and the dyeing property was evaluated. As a result, the color difference (ΔΕ & 13*) of the resin composition was 57.2. From the above results, it was found that In comparison with the compounds of the comparative examples, the compounds of the examples have very low transferability. [Industrial Applicability] The compounds of the present invention have low transferability, and therefore By combination of the colored dye compound of the main component of the next 7 to the display device of the present invention is excellent. Glance without significant characteristics of the color filter 156701.doc

Claims (1)

201206897 VII. Scope of Application: 1. A compound represented by formula (1): [In the formula (1), L represents a valence saturated hydrocarbon group having a carbon number of (d), and a hydrogen atom contained in the saturated hydrocarbon group may be substituted with a γ atom, and -CH 2 · contained in the saturated hydrocarbon group may also be -CO- or substituted And R and R are independently a hydrogen atom, an aliphatic hydrocarbon group having a carbon number of 1 to 16 or a fluorenyl group having a carbon number of 2 to 18 which may have a substituent; R3 to R1Q Each of the hydrogen atoms, a monovalent aliphatic hydrocarbon group having a carbon number of 1 to 8 or a substituent having a carbon number of 6 to i 彳, which is a substituent, each independently represents a hydrogen atom. The _ch2_ contained in the aliphatic hydrocarbon group may also be substituted with -0-; R11 to R14 each independently represent a hydrogen atom or a fluorenyl group; and X1- and X2· represent an inorganic anion or an organic anion]. 2. The compound of claim 1, wherein L is an alkanediyl group having a carbon number of 5 to 15, and -CH2- contained in the alkanediyl group may be substituted by -0. 3. A dye which is based on the compound of claim 1 or 2 as a main component. 4. A coloring composition comprising: a coloring agent selected from the group consisting of a resin, a photopolymerizable compound 156701.doc 201206897, a photopolymerization initiator, and a solvent, and a dye having the dye of claim 3. 5. A color filter. It is a coloring composition as claimed in claim 4 and a display device comprising the color filter of the fifth aspect. 156701.doc 8 201206897 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the characteristics that can best show the invention. Chemical formula: 156701.doc