TW201202806A - Retarder, display device including the retarder, and method for manufacturing retarder - Google Patents

Abstract

This invention provides a retarder having a plurality of regions with different slow axis directions, wherein the double refraction index Δ n(λ ) regarding a light with a wavelength λ (nm) satisfies formulae (1) and (2) in all regions. Δ n(450)/Δ n(550) ≤ 1.00 (1) 1.00 ≤ Δ n(650)/Δ n(550) (2)

Description

201202806 VI. Description of the Invention: The present invention relates to a phase difference plate, a display device having a phase difference plate, and a method of manufacturing a phase difference plate. [Prior Art] A phase difference plate having a plurality of regions having different phase retardation axes in different directions is described in Japanese Laid-Open Patent Publication No. 2005-49865. However, the optical characteristics of the phase difference plate are not described in the publication. SUMMARY OF THE INVENTION The present invention provides a phase difference plate, a display device having a phase difference plate, and a method of manufacturing a phase difference plate: &lt;1&gt; a phase difference plate having a plurality of regions having different phase delay axes And in any region, the birefringence Δη(λ) of the light having the wavelength χ(ηιη) satisfies the formulas (1) and (2): Δη(450)//Δη(550)^1.00 (1) And a phase difference plate according to <1>, which comprises a group represented by the formula (a) and at least one polymerizable property. A phase difference G1 - D1 - Ar - D2 - G2 - (A) obtained by polymerizing a compound of the group (wherein & represents a group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring) a divalent group of at least one aromatic ring, and a total number of agglomerated π electrons contained in the divalent group is 12 or more. Di and D2 are -〇)-0-, -〇-c〇_, _c(=s) — 〇—,~〇—= 'Build — CRR---CRV-CR3R4 ——〇_CRiR2___c ! 2_ -cr^-o-Cr3r4_ . -cr^-o-co- , -〇co :cr^ -ca—CR3R4—, —cr1r2—c〇—〇—cr3r4—, —NR-CRR---CR^-NR1 ——CO-咖-, or CO-; R, R2, r3, and r4 respectively represent a nitrogen atom, a said atom, or a carbon number 201202806, respectively, which independently represent a divalent alicyclic hydrocarbon group, the alicyclic hydrocarbon One or more methylene groups selected from the group consisting of the excimer group and the breaking group may be substituted with _〇&lt;3&gt; as described in <2>. a phase difference plate in which a compound containing i and at least one polymerizable group is represented by the following formula (9) = Ρ Ϊ 1 and -Al) rEl - Gi - D1 - Ar - D 2 - G 2 - in, for example, - Β 2 "2 —ρ2 (9) Meaning (where '^, ^^“, and “show the same Ε1 and Ε2 that are still defined independently of _cr5r6—CH2 —CH2___〇—, ~ co-o---o- Co——o-CO—〇___cr_s, ~co—, —〇—ch2_, —ch2-o- 0—, ———〇—c(=s)_0—, —c〇—S—CH〇: R5^ ^ aiV ^ B1 and B2 are independently represented - CR5R6---CH2-CH2___Q _, -s co-o O-CO---O-CO-0___cr=Sv II-C(=s)-,-〇 —c(=s)—Q—, „5:, „, °~CH2- '-CH2-0- ' -S-CH2- ' -CH —S—i, or single bond, R5 and R6 As above Above the same meaning. 2 (10) ¥ independently represents a divalent alicyclic hydrocarbon group or a divalent aromatic tobacco group, and the &quot;4 group and the divalent aromatic _ may have a octagonal atom, a carbon number of 1 Γ 碳, and a carbon number of 1 to 4. One of the group selected by the gas-substituted alkyl group, the alkoxy group having a carbon number of 1 to 4, the carbon number i~, the cyano group, the cyano group, and the aryl group is independently represented by k and 1 respectively. Integer. Θ and F2 each independently represent an alkylene group having a carbon number of 1212, and the alkylene group may have a group of 201202806 Ιίΐϋ6!, a carbon number of 1 to 5, and a group of germanium atoms, and a group of k More than one substituent, the -CH2_ contained in the alkylene group may be substituted with a 0- or a CO-. P and P each independently represent a hydrogen atom or a polymerizable group (however, at least one of pl &amp; P2 is a polymerizable group.) &lt;4&gt; A compound of the formula (3) that satisfies the formula (3) and the formula (4): crystallization of tinge (Νπ-4)/3&lt;k+l + 4 (3) 12^Νπ^22 (4) &lt; The phase difference plate according to any one of <2>, wherein the center is a base represented by the following formula (Ar-6);

(Ar-6), wherein Z1 independently represents a halogen atom, an alkyl group having a carbon number of i to 6, a cyano group, a nitro group, an alkylsulfinyl group having a carbon number of 1 to 6, and a carbon number of 丨6. An alkyl ore fluorenyl group, a fluoroalkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkylsulfanyl group having a carbon number of 丨6, and an N having a carbon number of 1 to 6 Alkylamino group, N,N-dialkylamino group having 2 to 12 carbon atoms, N-alkylamine sulfonyl group having 1 to 6 carbon atoms, N,N-dialkylamine having 2 to 12 carbon atoms A compound or a COOH. Q1 represents a CR9R10-, an S-, a Na-, a c--, or a ---, and R9 and R1G independently represent a hydrogen atom or an alkyl group having a carbon number of 丨4. Y2 represents a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted aromatic heterocyclic group. η represents an integer of 0 to 2.) &lt;6&gt; as in &lt;2&gt;~&lt;5&gt; And a phase difference plate according to any one of <3> to <6&gt;, wherein eight! and ¥ 201202806 is independently 1,4 - phenyl or cyclohexane - l, 4 - diyl; &lt; 8, such as &lt;3&gt;~&lt;6&gt; In the phase difference plate, only βΙ bonded to a1 and B2 bonded only to A2 are independently -Ch2—CH2—, :c〇〇, ~〇-CO-, —CO-NH-. ,—ΝΗ-CO-,—〇—ch2 CH2-〇-, or a single bond, B1 bonded to F1 and B2 bonded to F2 are independently—〇—, _c〇— '〇—CO—Ο - &gt;-CO-NH-'-NH-CO~&lt;8&gt;, wherein pi and p2, acryloxy, or mercaptopropenyloxy, and pi and P2 '-0-CO-_, or a single bond; &lt;9&gt; such as &lt;3&gt; are independently hydrogen atoms when they are different; &lt;10&gt; Semi-transmissive liquid crystal display device, including &gt The phase difference plate according to any one of the above-mentioned items, wherein the &lt;1&gt;&gt; A method of manufacturing a board, wherein the phase difference plate has a region in which a plurality of phase retardation axes are different in direction, and in all regions, a birefringence Δη(λ) of light having a wavelength of λ(ηιη) satisfies a formula (1) And formula (2), the manufacturing method The following steps (10) to (12) are included: Δη(450)/Δη(550)^1.00 (1) 1.00^Δη(650)//Δη(550) (2) (10) Forming an alignment film on a substrate Step; (11) a step of imparting an alignment film alignment energy to a plurality of regions having different alignment directions, and (12) a step of coating a polymerizable compound on the alignment film; &lt;13&gt; as described in <12> The manufacturing method, wherein the step (n) comprises the following steps (11a) to (11c): (11a) a first rubbing treatment step of applying a first rubbing treatment to the entire surface of the alignment film formed on the substrate; Covering the masking step, covering the alignment film with a mask having a predetermined pattern, applying the first rubbing treatment to the surface of the alignment film; and, on the surface, the surface to which the first rubbing treatment is applied to the alignment film is not The second rubbing treatment is applied to the portion of the mask covering layer; (13) · further includes the step of: (13) polymerizing the polymerizable compound applied to the alignment film; and the /it laminate comprising a plurality of alignments An alignment film of a region having a different direction, and a phase difference plate as described in the above-mentioned item on the alignment film; &lt;9&gt; And a phase difference plate according to any one of <'> to <9>. [Embodiment] The phase difference plate of the present invention has a region in which a plurality of phase delay axes have different directions. Further, in any region, that is, in all regions, the birefringence of light having a wavelength of λ (ηηι) such as (4) satisfies the formulas (1) and (7): Δη (450) / Δη (550) ^ 1. 〇〇(1) 1.00^Δη(650)/Δη(550) (2) In the present specification, the phase difference plate refers to an object that can transmit light and has optical properties. The so-called optical function refers to functions such as inflection and complex bending. The phase difference plate is used to convert linearly polarized light into circularly polarized light or sugar circularly polarized light, or to convert circularly polarized light or elliptically polarized light into linearly polarized light. It is known that the phase difference _(λ) given to the phase difference plate by the light having the wavelength ληιη is determined by the product of the birefringence Δη and the thickness d of the phase difference plate (10) (eight): In addition, the wavelength knife characteristic 4 is not the 値 (Re(x)/Re(55〇)) obtained by dividing the phase difference 値Re(X) at the wavelength λ by the phase difference 値Re (550) at 550 nm. In the wavelength band close to 1 in the collection / Re (550), or in [Re (45 〇) / Re (55 〇)] &lt; l and [Re (650) / Re (550)] &gt; A wavelength band showing reverse wavelength dispersion can perform uniform polarization conversion. The phase difference plate of the present invention has excellent transparency and is used in a wide variety of displays. The film thickness of the phase difference plate is different from 201202806 in accordance with the phase difference 値 of the obtained phase difference plate, but is preferably 0.1 to ΙΟμηη, more preferably 0.5 to 3 μηη. The phase difference 値 of the rabbit phase difference plate is 50 to 5 〇〇 1 or so, preferably 1 〇〇 to 300 qing. When the phase difference plate of the invention is a wide band λ/4 plate, the film thickness s of the phase difference plate is rounded so that the phase difference plate is reposed in any region in which the directions of the plurality of phase delay axes are different. 550) is 113 to 163 nm, preferably 135 to 140 nm, more preferably about 137.5 nm; and when the phase difference plate of the present invention is a broadband λ/2 plate, the film thickness of the phase difference plate is adjusted. The Re(550) of the phase difference plate is 250 to 300 nm, preferably 273 to 277 nm, and more preferably about 275 nm, in all regions in which the directions of the plurality of phase retardation axes are different. The s stomach "a region having a plurality of phases having different phase retardation axes" means that the phase difference plate has two or more regions "the direction of the phase retardation axis of the adjacent regions is not the same, and the adjacent regions have at least one boundary. line. The phase delay of non-adjacent areas may be the same. The direction of the phased delay axis is not the shape of __. Fig. 16 shows an example of the phase difference plate of the present invention. ^16(8) to (4) The phase difference plate 1GG has a phase delay (four) direction different regions 冈·^ domain 1〇〇B. Fig. 16 (8) shows a phase difference plate in which the area is set to a horizontal strip shape, and is set to a _ shape. Fig. 16 (6) is a case where a plurality of 仂" difference plates are provided. Fig. 16 (d) is a phase difference in which the area is set to an oblique strip shape, and '16 is an area in which the area is set to a checkerboard pattern. & Neutral is a phase difference obtained by polymerizing a polymerizable compound ^1'--D1-Ar--D2-Q2. Sometimes a compound of the formula ϋί (Α) and a polymerizable group (hereinafter referred to as % is "Compound (4)") Polymerization phase difference plate: (A) Selected? The face and the money are transferred to the group - the number of quotations is 2 or more. D and D respectively represent a single key, (10) two, two ^ ~ C (= S) _ 〇 "; - 〇 - C (Let a R ~ ~ CRR---〇 - CR1R2_, - CR1R2 - 〇 -, 201202806 1 RR—〇~C〇~CR3R4___CRi 2 ° CO-CR1^-NR^CRV---Nen 3 suspect i C〇-〇-CR3R4—, —CO— ;ri, R2, d3 LRR — service (7) ~ he 1~ , -, 】 The number 1 to 4 of the burnt beauty. rI B and 2 feet 4 respectively represent a hydrogen atom, a fluorogenic dihydrocarbyl group may be different, indicating a divalent waxy hydrocarbon group, a substituent, mt, money, and miscellaneous The group of tons of Γ Γ Γ 、 、 、 、 、 、 、 、 、 - - - - - - - 上 上 上 上 上 上 上 上 上 上 上 上 上 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 a group consisting of a divalent group of at least two aromatic rings and a pericyrene heterocyclic ring of the above 22 or less is selected as an aromatic hydrocarbon ring, and can be recycled as a ring of an aromatic ring; Preferably, the benzene ring plug, the *ring ring, the oxime ring, and Ar are preferably the following formula (&amp; oxazolidine, benzothiazole ring).

6) The base indicated. Any base of the base represented by the study, more Q1

^-2) (Ar-3) (Zl)m /(3⁄4 (Αγ-4) &lt;Αγ'5)

(Αι:Ί2) (Αγ-13) 201202806 Inverse i 〇 Pit base sub-stone 醯 base, carbon number 丨Si number ^ base, carbon number 1~6 silk base, carbon number ^; An antimony-alkylamino group having an inverse number of 1 to 6 and a ruthenium 1 having a carbon number of 2 to 12: r/-, a hydrazine of a hydrazine, or a hydrazine having a carbon number of 2 to 12, a mercaptoamine &amp; Q and Q3 are in contact with each other - cr9r1()___s

• NR—CO—, or a 〇—number 1~4 produced by γι V2 R and ^&quot; independently represent hydrogen atoms or carbon ί and Y singularly substituted or unsubstituted ▲ or replace or An unsubstituted aromatic heterocyclic group. W1 and W2 respectively represent a non-wind atom, a cyano group, a methyl group, or a halogen atom, and 1 represents 〇~ | η represents an integer of 〇~2. ) Number of turns? The fluorine atom, the chlorine atom, the desert atom, and the ruthenium atom are exemplified, and the parent car is a pro-J atom, a mouse atom, and a bromine atom. Examples of the carbon number of 1 to 6 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a decyl group/secondary butyl group, a parabutyl group, a pentyl group, and a hexyl group, preferably a carbon number of 1 to 6. 4 ship base, more preferably a carbon number 丨 ~ 2 of the base, particularly preferably a methyl group. /乍 is an alkylsulfinyl group having 1 to 6 carbon atoms, and examples thereof include a methylsulfinyl group, an ethyl sulfonium group, a propylheptylene group, an isopropylarylene group, and a butyl argon. a base, an iso-I yanoindolyl group, a secondary butyl sulfinylene group, a cis butyl sulfinylene group, a pentyl fluorenylene group, and a hexyl sulfinyl group, preferably having a carbon number of 1 to 4 The alkyl sulfhydryl group is more preferably an alkylsulfinyl group having 1 to 2 carbon atoms, particularly preferably a methylsulfinyl group. 'As the alkylsulfonyl group having 1 to 6 carbon atoms, a mercaptosulfonyl group, an ethyl sulfonyl group, a propylsulfonyl group, an isopropylsulfonyl group, a butylsulfonyl group, an isobutyl group a sulfonyl group, a secondary butyl fluorenyl group, a cis-butyl fluorenyl group, a pentyl sulfonyl group, and a hexyl fluorenyl group, preferably a decyl group having a carbon number of 1 to 4, more preferably The alkyl group having a carbon number of 丨~2 is a hydrazine group, and particularly preferably a methyl group. Examples of the fluoroalkyl group having 1 to 6 carbon atoms include a fluoromethyl group, a trifluoromethyl group, a fluoroethyl group, a pentafluoroethyl group, a heptafluoropropyl group, and a nonafluorobutyl group, and preferably a carbon number of 丨4. The fluoroalkyl group is more preferably a fluoroalkyl group having 1 to 2 carbon atoms, particularly preferably a trifluoromethyl group. Examples of the alkoxy group having 1 to 6 carbon atoms include a methoxy group, an ethoxy group, a propoxy group, 201202806 isopropoxy group, a butoxy group, an isobutoxy group, a secondary butoxy group, and a cis-oxygen group. The group, the pentyloxy group, and the hexyloxy group are preferably an alkoxy group having 1 to 4 carbon atoms, more preferably an alkoxy group having 1 to 2 carbon atoms, particularly preferably a methoxy group. Examples of the alkylsulfanyl group having 1 to 6 carbon atoms include a mercaptosulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, an isopropylsulfanyl group, a butylsulfanyl group, and an isobutyl sulfide. An alkyl group, a second butyl thiol group, a cis butyl sulphide group, a pentyl sulphur group, and a hexyl sulphide group, preferably an alkylthio group having 1 to 4 carbon atoms, more preferably carbon The thiol group of 1 to 2 is particularly preferably a mercapto group. Examples of the N-alkylamino group having 1 to 6 carbon atoms include an N-methylamino group, an N-ethylamino group, an N-propylamino group, an N-isopropylamino group, a butylamino group, and Sf-isobutylamino group, N-second butylamino group, N-parade butylamino group, N-pentylamino group, and N-hexylamino group, preferably having a carbon number of 1 to 4. The amine group is more preferably an N-alkylamino group having 1 to 2 carbon atoms, particularly preferably an N-fluorenylamino group. Examples of the N 'N-dialkylamino group having 2 to 12 carbon atoms include n,N-dimethylamino group, N-fluorenyl-N-ethylamino group, and N,N-diethylamino group. , n,N-monopropylamino, N'N-diisopropylamino, N,N-dibutylamino, n,N-isobutylamino, N'N-dipentyl An amine group, and an ST,N-dihexylamino group, preferably an N,N-dialkylamino group having 2 to 8 carbon atoms, more preferably an N,N-dialkylamine having 2 to 4 carbon atoms. The base is particularly preferably n,N-didecylamino. Examples of the N-alkylamine sulfonyl group having a carbon number of 1 to 6 include a fluorenyl sulfonyl group, an N-ethylamine sulfhydryl group, an N-propylamine fluorenyl group, and an N-isopropyl group. Ketoxanthyl, N-butylamine acid group, N-isobutylamine hydrazino, N-secondary butylamine hydrazino, N-parabutyl butylamine, N-pentyl And an n-alkylamine sulfonyl group having a carbon number of 1 to 4, more preferably an N-alkylamine sulfonyl group having a carbon number of 1 to 2, more preferably an N-alkylamine fluorenyl group having a carbon number of 1 to 4, Particularly preferred is N-decylamine sulfonyl. Examples of the N'N-dialkylamine sulfonyl group having 2 to 12 carbon atoms include N,N-monodecylamine fluorenyl group, N-fluorenyl-N-ethylamine sulphate, and n,N. —Diethyl month female acid group, N,N-dipropylamine continuous g basket, N 'N-diisopropylamine continuous g basket, N,N-dibutylamine sulfonyl, N , N-diisobutylamine sulfonyl, N:, N-dipentyl, and N'N-dihexylamine continuation of Si group' is preferably carbon number 2 to 8 11 201202806 N ' N - 2 The alkylamine sulfonyl group, more preferably a carbon number sulfhydryl group, and particularly preferably an N,N-dimethylamine sulfonyl group. Further, the N-dialkylamine sulfonate Z1 is preferably a halogen atom, a methyl fluorenyl 'methoxy group, a methyl sulfanyl group, a fluorenyl dimethyl sulfonyl group, a trifluoro Nf-amine, a waking group, and N. , N", dimethylamino group, ❼R, a carbon number J4 group, isopropyl group, butyl group, isobutyl group, exemplified methyl group, ethyl group, propyl group, more preferably methyl group. The base temple, preferably the alkane Q having a carbon number of 1 to 2, is preferably -s-, -co-, one---, one-s- or -co-., ~n(ch3)-, q3 is preferably m Examples of the aromatic nucleus aromatic hydrocarbon group, the monocyclic aromatic hybrid H, and the heterocyclic group of ^, 丫^ and ^ include a monopolycyclic aromatic heterocyclic group. The term "aromatic base group of the aromatic hydrocarbon group and the aromatic ring" has the meaning of having at least 2 2 condensed aromatic hydrocarbon groups and a 2 'diodor ring to be condensed to form a scented smoky group. "Hometown consumption_country; the aryl group formed by the row-bonding correction has at least one heteroaromatic ring and a heterocyclic group consisting of a ring and a heteroaromatic ring, and may include at least i rings of i or more selected The group of the scented scented squid is selected from the group consisting of the scented scented scented by the heterocyclic ring, and the scented heterocyclic ketone At least as ~2, and 丫3, „. f, phenanthryl, biphenyl and the like carbon number 6 ~ ^, phenyl, naphthyl, and hui f J are preferably phenyl. As a material: the fragrant silk 'preferably phenyl, naphthyl phenyl" ratio. The group, the oxime, the hetero group, the base, may be exemplified by the base, the base, containing at least one nitrogen atom, gas opening ^ An aromatic heterogeneous group of a soil, a benzophenanyl group, a benzophenone, preferably a hetero atom such as a sulfur atom, and a carbon number of 4 to 20, benzopyrazine, and a benzophenantyl group. Base, phenyl group, oxime group, benzoxyl group, alkyl group of ϋ, cyano group, nitro group, carbon 12 201202806 number 1~6 = alkyl sulfinyl group, carbon number 1 to 6 A sulfonyl group, a carboxyl group (a fluoroalkyl group having 1'-carbon number 1 to 6 or an alkoxy group having 1 to 6 carbon atoms, a thiol group having 1 to 6 carbon atoms, and an N-burning having 1 to 6 carbon atoms) Amino group, N,N-dialkylamino group having 2 to 12 carbon atoms, N-alkylamine sulfonyl group having 1 to 碳 carbon, N having 2 to 12 carbon atoms, fluorenyl sulfonate The fluorenyl group or the like is preferably a halogen atom, an alkyl group having 1 to 2 carbon atoms, a cyano group, a nitro group: an alkylsulfonyl group having 1 to 2 carbon atoms, a fluoroalkyl group having 1 to 2 carbon atoms, and a carbon number of 1. ～2, alkoxy group, alkylthioalkyl group having 1 to 2 carbon atoms, fluorenyl-alkylamino group having 1 to 2 carbon atoms, Ν'Ν-dialkyl group having 2 to 4 carbon atoms An amine group, an alkylamine sulfonyl group having a hindrance of 1 to 2. A green atom having a halogen atom, a carbon number of 1 to 6, a cyano group, a nitro group, a carbon number of 1 to 6 groups, and a carbon number of 1 to 6 *, silk, fluorine having a carbon number of 1 to 6 &lt; meta = alkoxy group having a number of 1 to 6; alkylsulfanyl group having a carbon number of 1 to fluorene; carbon number 1 to: ΐ ϋ-alkylamino group, Ν ' Ν-dialkylamine* having a carbon number of 2 to 12, a carbon number of 1 I amine stone base, and a ruthenium of 2 to 12 carbon atoms. Said: a single ring type family wire or a single ring type family -1) ~ formula (Υ-6) expressed in the base. """"" (Z2) a Μ (Z2) s

Sv (zV (γ-l) (Y-2)

(Y-3)

X (Z2) bl (Y-4) (Z%

.sjz2)^ '~~N (Y-5) (Y-6) 4 i-type Λ' = indicates the bonding site, z2 independently represents _ prime atom, carbon number, ΐ# carbon number 1~6 burning a mercapto group, a carbon number, a fluorenyl group, a fluorenyl group of a sulphur group, a sulphur-based group, a carbon number, a sulphur-based group, a carbon number of 1 to 6 N-silyl groups, and a carbon number 2^,, N--alkylamino group, N-alkylamine yellow carbon group having a carbon number of 1 to 6, or carbon] 13 201202806 2 to 12 N,N-dialkylamine sulfonyl group. a: an integer not represented by 0 to 5, a2 represents an integer of 〇4, and b represents an integer of 0 to 2, and a gas atom of 0 represents a total of z, preferably a dentine atom, a methyl group, and a nitrogen atom. US, ς) trifluoromethyl, methoxy, mercaptosulfanyl, anthracene, fluorene-dif, sulfo, carboxy, aryl. The basis of the soil, or Ν'-曱 From the viewpoint of the manufacturing steps or the cost, γι, γ2, and 3 are represented by the formula (Υ-1) or the formula (γ-3).夂Υ特佳 is a group represented by a polycyclic, aromatic hydrocarbon group or polycyclic aryl group (Υ1 -1)~ formula (Υ1-?).雅基基' can be cited

(YU) (Y!-5) σ!-6) Μ考^

(Υ]-7) (wherein, * indicates a bonding site, and Ζ3 independently represents a halogen atom, a carbon number J 1-6, a ketone group, a thiol group, a nitroso group, and a carbon number) of -6. a brain group, an alkylsulfinyl group having a 1:6 alkyl group, a carboxyl group, a fluoroalkyl group having a carbon number of 丨6, an alkoxy group having a carbon number of 1-6 or an alkylsulfanyl group having a carbon number of 1 to 6, An N,N-dihydroamino group having 2 to 8 carbon atoms or an N-alkylamino group having 1 to 4 carbon atoms. 11 Ο A V and V respectively represent -c〇—, — s—, —Se—, or a S〇2— 〇 W1 to W5 are independently represented by —cr3 = or one. 14 201202806 R, showing a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. However, at least one of 'V1, V2, and W1 to W5 represents a group including S, N, Ο, or Se. R11 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. a independently represents an integer of 0 to 3, respectively. b independently represents an integer of 〇~2. The mountain as Z3' may, for example, be a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cyano group, a nitro group, an anthracene group having an anisotropy of 1 fluorene, a decyl group having a carbon number of 1 to 6, and a carboxyl group. , a gas alkyl group having a carbon number of from 1 to 6, a carbon number alkoxy group, an alkylsulfanyl group having a carbon number of 丨6, an N-alkylamino group having a f number of 1 to 6, and a N having 2 to 12 carbon atoms. , N-dialkylamino group, N-alkylamine sulfonyl group of 1 to 6 carbon atoms, N,N-dialkylamine having 2 to 12 carbon atoms, aryl group, etc., preferably halogen atom, A Base, ethyl, isopropyl, secondary butyl, cyano, nitro, sulfo, nitroso, carboxyl, trifluoromethyl, decyloxy, decylthio, N,N-di An amino group or an n-methylamino group, more preferably a halogen atom, a methyl group, an ethyl group, an isopropyl group, a secondary butyl group, a cyano group, a nitro group or a trifluoromethyl group, particularly preferably a methyl group. Ethyl, isopropyl, secondary butyl, pentyl, hexyl. The mountain is a γ atom, an alkyl group having 1 to 6 carbon atoms, an alkylsulfinyl group having 1 to 6 carbon atoms, a fluorinated group having 1 to 6 carbon atoms, a fluoroalkyl group having 1 to 6 carbon atoms, An alkoxy group having a number of 丨~^, an alkylsulfanyl group having 1 to 6 carbon atoms, an N-alkylamino group having 1 to 6 carbon atoms, a N'N-dialkylamino group having 2 carbon atoms, and carbon The number of N-alkylamine sulfonyl groups of 1 to 6 and the N'N-dialkylamine of the stone having an anisotropy of 2 to 12 are each as described above. Preferably, V1 and V2 are independently -, s---NR11-, or -〇-. Preferably, W1 to W5 are independently -CR3= or one. R3 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, preferably a hydrogen atom. Preferably, at least i of V1, V2, and W1 to W5 are groups representing s, N, or Ο. a is preferably 0 or 1. b is preferably 〇. Among them, a group represented by the formula (Y3-1) to the formula (Y3-6) is preferred. 15 201202806

(wherein, *, Z3, a, b, V1, V2, and W1 have the same meanings as described above.) As a specific example of the base represented by the formula (Ar-Ι) to the formula (Ar-4), The base represented by the formula (ar-1) to the formula (ar-29) can be cited.

(ar-l) (ar-2) (ar-3) (ar_4)

(ar-9) 16 201202806

(ar-10)

SCH

3

(ar-12) (ar-13) (ar-14) (ar-11)

(ar-17) 〇 o

N〇2 (ar~18)

(ar-20) /CH3 〇2N-/&quot; V 02N-/^ Λ—(h3c)2n- &lt;&gt; =0=° 〇&lt;&gt; ^)=0 〇= -〇^-N〇 2 )-N(CH3)2 - VN(CH3)2 (ar-21) (ar-22) (ar-23) (ar-24)

(ar-25) (ar-26) (ar-27) (ar_28) (ar-29) Specific examples of the base represented by the formula (Ar-5) include the formula (ar-30)~ Ar—39) indicates the basis.

17 201202806

(ar-35) (ar-36) (ar-37)

F is a group represented by a specific example (3): - 40) of the formula (Ar-6) or the formula (Ar-7) represented by the formula (〇1 - 119). (ar-39) can be cited

(ar-40)

Br

(ar-44) (ar.41) (ar-42) (ar-43)

(ar-50) (ar-51) (ar-52)

(ar_49)

〇2N

(ar-56)

CH3 (ar-57) (ar-55) (ar-53)

N(CH3)2

(ar-59) 18 201202806

Sch3 (ar-60)

Ch3 (ar-62)

(ar'63) /CH3

Ch3 (ar.64) /OCH3

Br

NC CN (ar-65)

N02 (ar-66)

S

CN (ar-67)

, S

N02 (ar-68) /CH3, s

N〇2 (ar-69) -s

, S

(ar-73)

CH3 (ar-74) (ar-70) (ar-71) (ar-72)

(ar-75) (ar-77) (ar-78) (ar-79)

(ar-80) (ar_81) (ar-82) (ar-83) (ar-84) 19 201202806 , C1

(ar-85)Cl, ,Cl

(ar-90)

(ar-91) (ar-92)

(ar-88)

(ar-94) (ar-93)

(ar-95) (ar-97) (ar-97) (ar-98) (ar-99)

Sch3 (ar-100)

CN

(ar-106) (ar-107) (ar-108)

(ar-104)

20 201202806

(ar-110) (ar-111) (ar-112) (ar-113) (ar_114)

(ar-115)

(ar-118)

(ar-119) Specific examples of the group represented by the formula (Ar-8) or the formula (Ar-9) include a group represented by (ar-120) to (ar-129). Skillful

(ar-125)

(ar*126)

(ar-127)

(ar-128) (ar-129) 21 201202806 The _ of the formula shows „, „

(ar-130)

(ar-132)

(ax-133)

(ar-134)

(ar-135) (ar-131)

(ar-137)

(ar-138)

s

(ar.140) (ar-136) .CHg

W-143)

(ar-144)

(ar-141) -O

S

(ar-145)

(ar-146)

(ar-147)

(ar-148)

(ar-149) 22 201202806

(ar-150) (ar-151) (ar-152) (ar.153) (ar-154)

(ar-155) (ar. 156) (ar. 157) (ar. 158) (ar-159) Specific examples of the base represented by the formula (Ar-12) include the formula (ar-160) (ar - 179) indicates the basis.

(ar-160) (ar-16l) (ar_162) (ar-163) (ar-164)

Cl'

0

(ar-165) (ar-167) (ar-168) (ar-168) (ar-169) 23 201202806

(ar-170) (ar_171) (ar-172) (ar-173) (ar_174)

(ar-175) (ar-176) (ar-177) (ar-178) (ar-179) Specific examples of the base represented by the formula (Ar-13) include the formula (ar-180) The base represented by the formula (ar~ 189).

(ar-180) (ar-181) (ar-182) (ar_183) (ar-184)

(ar-185) (ar.186) (ar-187) (ar.188) (ar.189) 24 201202806 D and D2 are preferably 氺—〇—CO—,*—〇—c(=s)— , CR R2—, wood _ service 5 — crir2 one, or * — ship 5 — 键 bond joint. ). More preferably, D1 and D2 are *—〇~c〇~, *—, or *—NR5 —CO—(* indicates a bonding site with Ar.). R1, &amp; C(^S) and R4 are each independently a hydrogen atom or an alkyl group having a carbon number of i to 4, '#, a sub, a mercapto group, or an ethyl group. R5 is preferably a hydrogen atom, a fluorenyl group or an ethyl group. The alicyclic hydrocarbon group of the precursor, the alicyclic hydrocarbon group of the five-membered or six-membered ring = G1 and G2, which may be exemplified by the formula (g-1) to the formula (g-1). Can contain

(g_1) (g-2) (g-3) (g.4) (g-5)

I

, 〇s eight s; kv,... (g-6) (g-7) (9-8) (g-9) h) the number of hydrogen atoms; the number of the bases as exemplified above a sulphur group having a carbon number of 1 to 4 such as a methoxy group, a ethoxylate ϋ=, a butyl group such as a butyl group; and an alkoxy group having a carbon number of 1 to 4; trifluoromethyl «·« As G1 and G2, it is preferably a secondary atom. The hydrocarbon group is more preferably an alicyclic group composed of a six-membered ring represented by the formula (I-1). - base, particularly preferably anticyclohexane- 1,4-12 mDiAr-D2n-(8) (wherein, Ar, D1, D2, β 2 _ Ε 1 and Ε 2 are respectively represented independently = G represents the same as described above Meaning, ---C0-0---0~r ch2~ch2---ο---s -oc (=sb, -ο:, two: co-0 - C Bu s) - ο - , CO---〇-CH2___ci C〇~NR5——NR5 — CHr〇—, —s —CH2~—s—, 25 201202806 key; R1 and R2 respectively represent hydrogen atoms, gas atoms, or carbon numbers [ More preferably, the base 4 is represented by the formula (C) - Ar-D2-G2 - E24a2-B2- (C) - (-B1 - A ^ E1 - G1 - D1 - the door is in the 'f, D2 , Gl, G2, El, and E2 represent the same meaning as described above, B and B2 are respectively represented independently - cr5r6___CH CH___ 2: S -, - C0 - 〇 -, - 0 - co - 0 - co - 0 -, -C(= 〇~C(==S) 〇-C(=S)-〇---CO-NR1-, -NR-CO- . -〇-CH2- . -CH2-〇- , - S-CH2- &gt; -CH2 succinyl or single bond. R & R6 represents the same meaning as described above.) octane, compound (Α;) is particularly preferably a compound represented by formula (9): Ar, D1, D2, G1, G2, E1, E2, A1, A2, B1, B2, k The filament of the paste is described. F^F2 is divided into the carbon number of the vertical wire 1~ its, Shishan gold rf. The hydrogen atom contained in the alkylene group can be substituted with the carbon number of 1~1. An oxy group, or a dentate atom, the sub-generation is -0- or -〇)-. -1 and ?2 each independently represent at least one of the hydrogen groups 3, hP2, indicating that the polymerizable group is represented by the formula (9) It is a good compound (3) and a compound of the formula. (Νπ-4)/3 &lt;k+l + 4 (3) 12^Νπ^22 (4) Preferably, Ε1 and Ε2 are independently -0-, -5- , _*c〇—〇, Γϋ. More preferably, El is *—co—0—(* indicates a key with G;~.), Ε 1 —〇—c〇_ *(* indicates a key with The junction part.).] Jian, ^, is a two-valent alicyclic hydrocarbon group or aromatic smog group in ^2 and A2, and a five-membered ring or six-membered ring represented by 26 1% two-form (g-1〇) The composition of r

=: or in the formula (a-8), the carbon number 6~2〇2 is represented by J 201202806

(a-8) base; methoxy or ethoxy group, etc., number of discs W4, n, right, burn, r, in__, right, the same type of base i', it is easy to manufacture compound (4), because of her kind Further, as Al and A2, a monocyclic ring is preferred, and since it is easy to produce the compound (A), it is easy to produce a compound if it is a compound of the same kind. (Α), therefore, it is preferably the same type of base. Furthermore, since it is easier to manufacture the compound (Α), it is preferable that only the Β1 bond Β1 and the Α2 bond Β2 are independently a CH2 — CH2—, _CO-Ο—, one O—CO—, —CO—NH—, one-to-one-CO—, one—ch——one CH——Ο—, or a single bond, and because compound (a) shows High liquid crystal performance, so it is particularly good for a CO - Ο - or ~ 〇 a CO -. It is better that the B1 bonded to F1 and the B2 bonded to F2 are independently one -, - CO - 〇 - , a 〇—CO—, a 〇—C0 —0—, a CO—ΝΉ—, an NH—CO—, or a single bond. From the viewpoint of liquid crystal performance, preferably k and 1 respectively represent 0~ An integer of 3, more preferably k and 1 The sum of 〇~2.k and 1 is preferably 5 or less, more preferably 27 201202806 4 or less. l Bu and P are independently represented by a wind atom or a polymerizable group (however, pi and p2 represent aggregation) If both of the groups 1 and p2 are polymerizable groups, the hardness of the phase difference plate tends to be excellent. The "stomach-polymerizable group" means that the compound (4) can be polymerized. Substituent, specifically; 箕H vinyl, ethyleneoxy, ρ-(2-phenylvinyl)phenyl, propylene fluorenyl, decylene, propyloxy, methacryloxy group, secret , ethyl alcohol, base, carbon number! ~ 4 silk amine, amine, epoxy ethyl (tetra) (four)), j propyl (oxetanyl), brewing, isocyanate, and isothiocyanyl. Further, in the case where H is as described above, and the F] or F2 is followed, the money combination may include a base exemplified by B1 if. For example, 'preferably a radically polymerizable group derived from a silky bond, an ionic polymerizable group, particularly a propylene, a propylene, a propylene oxy group, and a methyl propyloxy group which are easy to manufacture in a county. Good, propylene, oxy. When both the right P and P are polymerizable groups, the hardness of the obtained phase difference plate is excellent. — 乍 is Π 1-G1-E1 — (A1—Bi-FLp1, *-D2-G2-E2 ~B) 具体-F specific examples, can be cited by the formula (R-丨) ~ formula (R-i34) 2 shows the basis. * indicates the bonding site with Ar. Further, the formula (R_"~-form (where η represents an integer of 2 to 12) 28 201202806 * 一〇

(

-(R-7) (R-8) (R-9)

(R-19)

t a Q

(R-20)

^-CnH2n-〇^ 广(R-21) CnH2nCH〇-κ> 俗略f15) (R-16) (R'22) (R-17) *-〇v^vn ^ ^ TT .n-/^ (R-23)

K&gt;^〇nH2n-&lt; (R'18)

(R-24) 29

汽〇^〇0 you-0{ A&lt;y\々私, ^_C^A&gt;-t^CnH2n

201202806

〇-CnH2n- (R-49)

CnH2n-〇^T

—〇S ;M^&gt;〇-CnH2n-0( (R-50)

〇vCnH2n-〇-C (R-51) *-0 d

(R-55) 〇-CnH2n-

(R-56) (R-57) (R-58) (R-59) (R_6〇) (R-61) (R-62) 31 201202806 *—Ο ό

Ο

〇~CnH2n- (R-63), ό

Ο

Ο O-CnH2n-〇- (R-64) Ο ~^}-〇-CnH2n-

〇-CnH2n- CnH2n- 〇ηΗ2η- (R-65) (R-66) (R-67) (R-68) 32 201202806

(R-69) (R-70)

(R-71)

ο

ο (R-72)

(R-73) (〇^&gt;〇-CnH2

(R-74)

33 201202806

Ο (R-75) (R-76) 9c.

o (R-77) ★ ·

Pb o

〇^Κκ2η (R-78)

o

〇-CnH2l (R-79)

* One Q

Pb

O

O

〇-CnH2n-

O (R-80) 34 201202806

(R-81) (R-82)

(R-83) (R-84)

(R-85) (R-86) 35 201202806

(R-87) (R-88)

(R-89) b-〇-o-cnH2n-o^~

(R-90)

(R-91) (R-92) 36 201202806

(R-93) (R-94) (R-95) (R-96)

2n (R-97) (R-98)

37 201202806

CnH2n- CnH2n-

(R-99) (R-100) 〇^〇r〇CnH2n- - ^ (R·101) o^Kh,- (R-102)

(R-103) (R-104) 38 201202806

(R-105) (R-106) (R-107) (R-108) (R-109) (R-110) 39 201202806

(R-lll) 〇-CnH2

(R-112) (R-113)

Cn(3~〇-CnH2n--〇^~

(R-114) (R-115)

(R-116) 40 201202806

(R-117) (R-118)

(R-119) 〇-CnH2n-

(R-120)

(R-121) (R-122) 41 201202806

Ο ο ^^CnH2n+i (R-123)

CnH2n+i (R-124) !v-〇-CnH2n+1 (R-125) Ο Ο

CnH2n+l (R-126) 3 HC^CnH2n+l (R-127) 3

CnH2n+l (R-128) 42 201202806

(R-129)

CnH2n+1

Ο (R-132)

(R-133) 氺―

〇-CnH2n+1 (R-134) As the compound (A), a compound (i) to a compound (xxxiv) can be exemplified. Ra in the table indicates a D1 - G^E1 - Ρ - Ρ1, and Rb represents a D2 - G2 - E2 - (A2 - B% - F2 - P2).

43 201202806 [Table i] Compound At ~-^——_ __R^_ (ϋ) (ar-40) (iii) (ar-41) (iv) (ar-42) (V) (ar-43) ( ()) (ar-44) (xii) (ar-80) (xiii) (ar-82) (xiv) (ar-83) (Rl)~(R-48), (R-57)~—(xv) (ar-84) ( R-1) Any of (R-48), (R-57)~ (R-131)-(xvi) (ar-81) (R-131) (ar-78)/(ar -79) -(xviii) (ar-77) (ar-72) -(xx) (ar-85) .(xxi) (ar-89) .(xxii) (ar-95) .(xxiii) (ar -97) (ar-45) -(xxv) (ar-76) (ar-110) one (xxvii, (ar-115), (xxviii) (ar-4) iSrvv, (ar-25) (xxxi) (Χχχΐι·, (ar-120)/(ar-121) (ar-122)/(ar-123) (R-57)~(R-12Q), (R-123)~ (R·128) Any one of (R-57)~(R-120), (11-123)~(1^128)._^〇〇ciii) . ~!- (ar-130) (ar-140) ( R-1)~(R-48), (R-57)~(R-1)~(R_48), (R-57)~(H-131), _ycxxiv) ith ^ (ar-150 Water, six children (R-131), one of them is called Shiyan In the XXX1 generation, any one of the bases represented by 圮 and the base indicated by 圮 is (R-57)~(R-12〇). In the above Table 1, the compound (xvii) represents any one of the following: Ar is a compound represented by the formula (ar), and Ar is a compound represented by the formula (ar-79). The substance or Ar is a mixture of a compound represented by the formula (ar-78) and a compound represented by the formula (ar-79). In the above Table 1, 'compound (XXX) means any one of the following: Ar is a compound represented by the formula (ar-120), Ar is a compound represented by the formula (ar-121), or Ar is a mixture of a compound represented by the formula (ar-120) and a compound represented by the formula (ar-121); the compound (xxxi) represents any one of the following: Ar is a formula (ar) —122) The compound represented by the group, Ar is a compound represented by the formula (ar — 123), or Ar is a compound represented by the formula (ar—122) and the formula (ar—123) A mixture of compounds represented by the group. Further, 'the compound (i), the compound (9), the compound (iv), the compound (v), the compound (vi), the compound (ix), the compound (X), the compound (xi), the compound (xvi), Representative of Compound (xviii), Compound (4), Compound (4), Compound (4), Compound (4), Compound (xxiv), Compound (xxv), Compound (xxvi), Compound (xxvii), Compound (xxvUi), and Compound (xxix) The sexual construction is exemplified as follows. In the phase difference plate of the present invention, a different plural kind of compound (A) can be used.

45 201202806 N〇2

(v-1) o-c6h12&lt; NO:) &lt;o-c8h16’

o o

p (v-2) oO^O-CA—C^y

,〇^0^〇_(:11|_122_1 N02 (v-3) -C8H16-0〇-0’ ¢)

o p cf&quot;l^V^-o-c8H16- (v4) 〇 46 201202806

(v-5) (v-6) (v'-l)

(ix-1)

C6h12-c o-^^-〇-c6h12- (x-1)

〇6Hi2~C 〇-^^-〇-C6H12·' 47 201202806

乂CeH12-〇H〇-C

ChCeHt Λ1 (xvi-1)

(xviii-1) 2y

(xix-1)

(xx_l) 0βΗΐ2〇~^^~,

,0&quot;KZ^_0_C6H 12_^y (xxi-1)

(xxiii-1)

\_^&gt;CeH12-〇^^

(xxiv-1) 48 201202806

49 201202806

〇·〇6Η·|2~〇ν (xxxii-1) (xxxiv-1) Further, as the compound (A), for example, the following examples are given. However, in the formula, nl and η2 each independently represent an integer of 2 to 12. 50 201202806 2

NO

N〆S TM-la N〇2 I]

H

N〆S TM-lb N〇2 I) h3c-(ch2)4 N^S-Ο.Ά__0^ 普 °·(εΗ2)4Τ TM-2a NO,

TM-3a 〇 TM-4a

〇-(CH2), Ό 51 201202806

CN H3C-(CH2)4

N^S''cold\)_^-〇_(CH2)6. TM-5a

CN H3C-(CH2)4-^3, N^S•《善ϊ..ο^Γ^°~(〇Η2)4,Η TM-6a CN )N,〆, H3C-(CH2)3 TM- 7a

CN 1ST _ H3c-(CH2)〇《善 J_w€&gt;·0 揭 TM-8a

, Y 52 201202806 N〇2 I)

NT S TM-9a

y(CH2)4 一《谷》一 P

TM-10a

乂(CH2)6 - ^o&quot;_"谷"&quot;of^°~(CH2)6 a K

TM-lla ^ΓεΗ2)6^Η^^〇^^·〇^〇^°&quot;(ΟΗ2)4^ TM-12a 53 201202806

Look up 2) 6 one.普^^ 《善》,〇^-(〇η2)4一:〆 TM-9b

TM-10b 乂 2) 6 one.普^^《善》_ 〇^-(ch2)6一

TM-llb

W0&quot;^KK%.CK _(CH2)6 A TM-12b 54 201202806

*-(〇η2)4-

CN

N,S TM-13b

(CH2)6--〇-^-C

CN N^SC^..CH&quot;(CH2)6 Ύ TM-14b

CN TM-15b

NT S

CN TM-16b

N, S W(ch2)6〆.普^^ 55 201202806 ΤΜ-17 H_(CH2)4〆. Office: H&gt; "Good" · &lt;χ·(〇Η2)1

ΤΜ-18 ΤΜ-19

ο ΤΜ-20 ~:-(ch2)6〆. 56 201202806

TM-21

TM-22

N,'S TM-23

H_(CH2)4-K&gt;T^KK(CH2)6T

TM-24 57 201202806

Br

TM-25

TM-26

TM-27

TM-28 58 201202806

ΤΜ-29

H&quot;(CH2)4 一Κ&gt;'{善 KX(CH2)4T

ΤΜ-30

WK&gt;'r^》._cH&quot;(CH2)6 a K

ΤΜ-31

ΤΜ-32 59 201202806

ΤΜ-35 As the compound (Α), a compound represented by the formula (Al-1) to the formula (Α64-8) can be cited. * indicates a bonding site, and a compound represented by the formula (A1 - 1) is a compound shown below.

(Α1-Ώ

-oQ-〇c6H,2-&lt;y ^1'1) (A1-5) Classification &quot;*°&quot;c price y (Al-2) *-〇〇-〇c6H12-^_y (Al- 6)

(Al-7) (Al-8) 60 201202806

3-〇〇c6H12-q^ (A2-1) c4h8-c -〇C4H8-〇y (A2-2) *~〇~{~~^-〇-c6h12 kC6H12-C&lt;° oc4h12-o (A2- 3) (A2-4)

:-〇-〇-〇C6H12-^_y (A3-1)

O-CeH!

(A3-2) (A3-3) (A3-4) -o~^^)-oc6h12-^^

-0-〇^OC6H12-^_y-〇-(y〇-c4^-(y (A4-1) (A4-2)

-〇~&lt;(^-〇C6H12-^y

(A5-1)

R_c&gt;^3_aC6Hi2'c^/ (A5-2) *-0-^)-0-C6Hu-cyj oc6h12-c (A5-3) —C4H8—c

0'C4H12~C (A5-4) -C6H12—(A2-5) (A2-6) (A2-7) (A2-8) (A3-5) (A3-6) (A3-7) (A3 -8) (A4-5) (A4-6) (A4-7) (A4-8) (A5-5) (A5-6) (A5-7) (A5-8) 61 201202806

〇^3~oCeHir^_/ (A6_1) 0-04Η8-^ f (A6-2) °OKi&gt;C6H12-^_y o-c4h1

C4He-’ Ύ -O-CeH!

-Q~〇〇C6H12-p (A7-1) OC4H0- -〇C4H8-

(A7-2) (A7-3) (A7-4) -〇〇6Η12&lt; p -OCeH! (A8-1)

Ύ o-c4Hq-c^^^ (A8-2) Bu C4H8— *-0-〇-^°'0αΗβ~}^izy -〇-CeH12 ice.

2-〇V (A8-3)

i〇4H12-C (A8-4) -CqHi:

-〇O~OCeH12-&lt;\_/ (A9-1) o-c4H8-q / (A9-2) O-CeH!

—Y (A9-3) (A9-4) -o-c4h8-o i 2&quot;^_/

Ch8- yy (A6-5) (A6-6) (A6-7) (A6-8) (A7-5) (A7-6) (A7-7) (A7-8) (A8-5) (A8 -6) (A8-7) (A8-8) (A9-5) (A9-6) (A9-7) (A9-8) 62 201202806

(A10-1) 'V -〇-〇-〇c4H8-q y (A10-2) -〇-^^-〇-C6H12-^y -c4h8- *-0- P &gt;〇6H12-cζ_ 〇- C4h12-c (A10-3) (A10-4) —c4h“c —CeH,

-〇-〇^〇c6Hi2-^_y (Aii-i) o^Q^o-c4h8--^_/ (All-2) *-cH3-o-c6Hir^y T (All-3 Bub c6h12 - C4h8-&lt; —...(All-4) -c6h12-

*—oO^CeHiz^y (A12_1) *_0^〇_0'c-'H8-^_y (A12-2) -o-(^)-oc6H12-q^ 6 c4h8~c -c6h1: (A12- 3) Bu c4h8· i&gt;-c4H12-q / (A12~4) *_(&gt;^)~〇6Ηι2

-CV〇OC6H,2-^y (A13-1) .o^Q^oc price p (A13-2) *-〇Ό~°^6Ηι2_&lt;^/ Λ (A13-3) ~ 〇-C6H12'Q / -o-c4h8-c

12V

Ch8-c 0~〇4Ηΐ2Η (A13-4) -〇6Hi (A10-5) (A10-6) (A10-7) (A10-8) (All-5) (All-6) (All-7) (All-8) (A12-5) (A12-6) (A12-7) (A12-8) (A13-5) (A13-6) (A13-7) (A13-8) 63 201202806

^〇^&gt;c6h12^_/ (A14-1) *_0_^3_0&quot;C4H8&quot;&quot;^_/ (A 14-2) *-o-^^-o-c6h!2~^_/ ,Λ (A14-3) -0-C4H8- &gt;c6h12 CKXtH! Ύ (A14-4) HT '-^3*-〇6Η12— \

^〇-〇~aC6H12-^y -〇^(^-〇C4H『^y (A15-2) (A15-1)

C4h8- -〇-c6Hi

卜 C&amp;hhfC (A15-3) -c4h8-c

〇-C4H12-C (A1S-4) *-〇-〇-C6H12-^_y

〇-C6HirC (A16-1) (A16-2) (A16-3)

-〇〇6Η12-' Ύ ~c4h8-c to-C4H,rQ / (A16-4&gt;*-〇&lt;^c6Hi2

*-〇-〇-〇c6H12-^_y *~〇&quot;(3_0'C4H8. q-c6h12-^ f (A17-1) A _ r\ &gt;〇-〇4»8-' (A 17- 2) *-〇-^)-〇^6Ηι (A17-3) *- ..."oc4H—(A17_4) -C4H3—c -C6Hr 2'^ (A14-5) (A14-6) (A14-7) (A14-8) (A15-5) (A15-6) (A15-7) (A15-8) (A16-5) (A16-6) (A16-7) (A16-8) (A17-5) (A17-6) (A17-7) (A17-8) 64 201202806

*-〇-〇^〇οβΗ12-^

(A18-3) —c4h8- 3-C6Hi 2'^ (A18-4) -C6Hr 2_r

(A19-1)

-O-CeHr t~°^^_oc6H1r^_/ / (A19-2) Λ (A19-3) ir^_/ u t&gt;C4H8-^_y 1,2-^y (A19-4) .-o ^yCeH^-^y 〇-C6Hi2 oc4h乜

^^ (A20-2) (A20-1)

〇C4H8h -〇〇βΗΐ2Η Bu c6h12- c (A20-3) *-c4h8-c 〇-〇4H12-q / (A20'4) *-〇-〇-c6H,2-^_/ (A21-1)

-a-〇^i&gt;C4H8-C^ (A21-2) *-0-〇-°&quot;°βΗΐ2-^_/ OCqH^ ry &lt;° 0~〇4Η·^2η (A21-3) ( A21-4) C8-, -C6Hi

Y2~Y (A18-5) (A18-6) (A18-7) (A18-8) (A19-5) (A19-6) (A19-7) (A19-8) (A20-5) (A20 -6) (A20-7) (A20-8) (A21-5) (A21-6) (A21-7) (A21-8) 65 201202806

(A22-2) *-〇-( ^°O-〇C6H12-Q ,(仏-1)~~y 卜〇6Ηΐ2. (A22-3) c4H8-q / (A22-5) (A22-6) (A22-7) 〇-C4H12-^ (A22*4) *^0-°^-^-/ (A22'8)

K~°~Oy~c&gt;C6Hi2'&lt;:Lj!' -0_〇~°^η£ (A23-2) n (A23-3)

(A23-5) (A23-6) (A23-7) (A23-8) 〇-C4H12-q / (^3'4) *-〇O&quot;c6Hi2-c ,, 2y

-〇-^-o-c4h, 〇~C6H12-g /

(A24-5) (A24-6) (A24-7) (A24-8) t&gt;c4H12-Q / (A24-4)*-〇~〇~c6h12

(A25-1) *_〇_〇&gt;_^~〇c4H8-(^/ (A25_5) (A25-2) -O-CeH,

V b-c6H12-o / (A25'3) 〇-c4h8-c C2-c (A25-4) ~C6H12-^ f (A25-6) (A25-7) (A25-8) 66 12'^ 201202806

-OC6H12fC (A26-1) (A26-2) 〇C4He-

(A26-5)

(A26-3) (A26-4) -OCgH-ia-

(A26-6) (A26-7) (A26-8)

-a-Q-oCeH^^y ^7'1) (A27-5) (A27-2) *-ch

-〇C6Hi2~C 〇-C6H12ri &lt;° o-c4h12-c

V (A27-3) (A27-4) P 〕-C4H8—I -c6h1: Y 2~r (A27-6) (A27-7) (A27-8)

-00βΗΐ2&lt; *-〇-{ Voc4h8-

&gt;c4h8- (A28-4) c6h12- (A28-1) (A28-2) (A28-3) -c4h8-

Y (A28-5) (A28-6) (A28-7) (A28-8)

-〇C6H12-C^y (A29-1) (A29-5)

(A29-2) -OCeHi

(A29-4) (A29-3)

_oXZ)~C6H 1 Factory (A29-6) (A29-7) (A29-8) 67 201202806

^30_1) °&quot;C4He~^ (A30-2) *-cy-Q-〇-CsHn-^_j (A30-3) -OCAHe d-c5h12-c oc4h1 2y C4H8—^_y (A30-4) ^ ο-{^-〇6Ηΐ2—

^〇-〇〇c6h12-^ (A31-D(A31_2) T (Following ''Y-C6H12

Cnirc (A31-4) -c6h12 &gt;〇6Hir( p (A32-D ~ C4H8- ~OC4H|

L8_r (A32-2) *-ο-{2^〇-〇6Ηι2&lt;(deleted)-〇&lt;HC4h (A32_4)

CeHi2—

&quot;(&gt;〇-c&gt;c6Hi2-^y (A33-1) ^_V _q^3_(&gt;CaH8_(^_/ (^33-2) *-〇-^)-o-ceH12-^_y OCaHu-Q/ &lt;° r^_y, w 〇-c4h8-^_j-(A33-4) *-o-^ y~CgH 12~^^ (A33-3)

Y (A30-5) (A30-6) (A30-7) (A30-8) (A31-5) (A31-6) (A31-7) (A31-8) (A32-5) (A32-6 ) (A32-7) (A32-8) (A33-5) (A33-6) (A33-7) (A33-8) 68 201202806 *-〇'-^^—0〇6Η12

-OC4H8h

ΥTV

(A34-3) -C4H"^y -C6H12—(A34-4) 〇αΗθ-^_/ (A34-5) (A34-6) (A34-7) (A34-8) .〇~Q^OC6H12 -C^ (A35_1)

-OCaH, rr (A3 5-2) -o-c6h12-c 〇C6Hi (A3 5-3) w o-c4h1 (A35-4) V ~C4H8- ~°ΚΖν〇6Η (A35-5) (A35- 6) (A35-7) (A35-8)

-〇C6Hi2~C (A36-1) *_〇_qJ〇-c_/ (A36-5) (A36-2)

-OC4H8-Q

-o-c6h12-^^

(A36-6) (A36-7) (A36-8)

Y (A37-1) (A37-5) -OCeH^-'

(A37-2) (A37-3) (A37-4)

V -OCeH!

(A37-6) (A37-7) (A37-8) 69 201202806

^-(3-σ〇6Ηΐ2&lt; (A38-1)

〇-c4i

Ό-〇-°·°4η8-^ (A38-2) *- P -O-CeHr *-〇- -CeHt (A38-3) Bu c4h8

OCA Ύ (A38-4) y -C6H12— §

(A39-1) *_〇_Q^OC4H8-^_y -oO^o^He-^y (A39-2) *-〇H〇&gt;-o-c6Hir^y 〇-c6h. Ύ (A39- 3) &quot;c4h8-c (A39-4) ~ί&gt;Η(Ξ)_〇6Η 12~^_/

&gt;〇βΗΐ2~

(A40-1)

(A40-2) (A40-3) (A40-4) ^〇h(3-C6H12 3-〇-〇C6Hi2-^_/

icv〇oc6Hl2-p (A41-1) *_〇_〇_bu price y -0_^^_&lt;&gt;c4H8-^_y (A41-2) ^-(^-o-CeH^-C oc6h12-c (A41-3) -C4H8-i

Y *-〇- -c4h12-c (A41-4) *一〇~&lt;^)-c6h12- (A38-5) (A38-6) (A38-7) (A38-8) (A39-5) (A39-6) (A39-7) (A39-8) (A40-5) (A40-6) (A40-7) (A40-8) (A41-5) (A41-6) (A41-7) (A41-8) 70 201202806

-o〇ac6H12y (A42-D (A42-5) -σ-〇-°-〇4Η0-^_/ (Α42-2) *-c^y〇c6Hi2-^ (Α42-6) hC6H12-' Υ ( Α42-3) -c4h8 (Α42-7) OC4Hi (Α42-4) 7 -c6h12—^_y (A42-8)

*-〇-f /—0-C4Ha· Bu c6h 丨-C4Hy

(A43-3) r (A43-6) (A43-7)

*-〇- 卜 c6h12-丨YΎ &gt;c4He-&lt; -OCgHi2~Q (Ας43-4)^〇-^^〇6Η12—(A43-8) (A44-1) *-〇-〇-^C4H8T / (A44-5) (A44-2) *-〇-^^(&gt;〇6Ηι2''^_/ (A44-6) (A44-3) -CKDH^-C4H3-^/ (A44-7) (A44-4) (A44-8)

a〇oc6H12y (A45-D (A45-5) (A45-2), 〇〇-叫(A45_6) 〇~〇6Η12*·( (A45-3) *-〇- -C4H8*~( (A45-7 )

Y (A45-4) *-〇-{ )-〇6Ηΐ2- (A45-8) 71 201202806

卞(A46-1) *-〇H8-p (^46-2) *-〇-(^-〇CeH 12_^_/ (A46-3) 卜 C4Hg 00^ 2y (A46-4) 7 -C6H12—

(A47-1) (A47-2) (A47-3) (A47-4) Bu C4H8·

He~r 12'^_/[Υ -C6H12

.(A49-1) *_〇 (A49-2)

C4h8-c -oc6h12—

Y

OCeHi

(A49-3) ^ Vc4H8-^_y (A49-4) l〇~&lt;^-c6h12- (A46-5) (A46-6) (A46-7) (A46-8) (A47-5) ( A47-6) (A47-7) (A47-8) (A48-5) (A48-6) (A48-7) (A48-8) (A49-5) (A49-6) (A49-7) ( A49-8) 72 201202806

C4h8- -〇O&quot;〇C6H12-(|_y (A50·1) (A50-2) *-〇~Q~i&gt;ceH12》y (A50-3) *- -o-c4h8 ί〇θΗ1: CKX^ Ύ (A50-4) 〇-C4He—“y

-CM C3H7

-ac6H12-q / (A51-1) -OC4H;

Irr a~^_y (A51-2) (A51-3) —c4H8 Call Ύ (A51-4) -CeH!

&gt;-〇^〇C6h12-^_/ (A52-1) ^0^0(^8-^/052-2)

Oc4h8-c

〕-&lt;^)-oc6hi2

(A53-!) 3_〇_c&gt;c4He-&lt;^_y 053-2)10^3-0^^ -oc6h12-c

Y o-c6h12-c OC4H12-i

(A50-5) (A50-6) (A50-7) (A50-8) (A51-5) (A51-6) (A51-7) (A51-8) (A52-5) (A52-6) (A52-7) (A52-8) (A53-5) (A53-6) (A53-7) (A53-8) 73 201202806

K^〇〇CeH12p (A54-D *-〇_〇·Ή4Η8^^ -0^3~0C4h8-^_^ (A54-2) *-〇-(3_(&gt;ceHi2'^_/ -°^ 〇Cc Ύ (A54-3) OC4Ht Ύ (A54-4) -C6Hr

-OCeHt -OC4H|

IBV

(A55-3) '-C4H8— -C6Hi; -C4H1; (A55-4) _c6h1:

\"Y

*-〇~{^〇C6Hn~(^_j (A56O *-〇~^~~^~〇~〇4^8~9 / (A56-2)

C4H8-C -O-CeH^'1

Y Bu c6h12-c (A56-3) Bu c4h8-c &gt;〇4Η! Ύ (A56-4) ~CeH12-

-OCeHi2HY '〇-c4h12-^_/ (A57-1) (A57-2) *-〇O_0'c6h (Λ57-3) *-〇{Χε^ (A57-4) y~c6H st~ (A54- 5) (A54-6) (A54-7) (A54-8) (A55-5) (A55-6) (A55-7) (A55-8) (A56-5) (A56-6) (A56- 7) (A56-8) (A57-5) (A57-6) (A57-7) (A57-8) 74 201202806 irr -oc6h12-〇// (A58-1)

C4h丨 l8p

〇-c4H8-q / (A58-2) *-〇-(3_〇-c6Hi2-c

Hsy (A58-3) Bu C4H8-c -〇4η12-^/ (a58_4)

O-c4h0- ~°~(^y~〇c^2~(^_/ (A59·1) _0_^^~°&quot;〇4Η8_9^_/ (A59-2) *-&lt;&gt;^( ^)-〇-c6h12-' (A59-3) 〇-C6Hi 卜C4H12~ u 〇-c4h8—(A59-4) *-ο-^~^—〇βΗΐ2~^ / ^02

Oc4h8-c

_&lt;&gt;θ^σε6Η12'^_7 ^60'1) * ^ -o-c4h8-q / (A60-2) *-〇-{3_c&gt;c6Hi2-^_/ (A60-3) *- Buc c6h12 -c OC4HQ-c oc4HirQ ^ (A60-4) *-a^}-c6H12-

12y 〇_0^C&gt;C6H12'^/ (A61-1) *_〇_^_^-〇c4H8-^_ 3^〇^(&gt;C'»h8-^_/ (A61-2) * -〇-&lt;Q^〇-CeH12-^

-CeHi2-C (A61-3) 卜C4H8- CK^ Ύ (A61-4) ^&lt;&gt;-ΑΛ-〇6η12- (A58-5) (A58-6) (A58-7) (A58-8 (A59-5) (A59-6) (A59-7) (A59-8) (A60-5) (A60-6) (A60-7) (A60-8) (A61-5) (A61-6 ) (A6I-7) (A61-8) 75 201202806

-OO-OCeH,^ (A62-l) t_〇_^y_}-〇-1 *-o-^^-〇c4h1 (A62-2) (A62-3) (A62-4) c4h8- -〇 C6Hi Buc4h8-c -o^^-c6h12—

~^~〇^CqH-|2

12.^ (A63-L) ^^yj-0-c.He-^ -o-^^-o-c4H8-c^y (A63-2) (A63-3) oc4 -c4h1: 2~^_j ^ 〇-c4H8-^y (A63-4) μ&gt;&lt;^)άη 0

L〇~Q&gt;~〇C6Hi2-^y (A64·1) (A64-2) *-o-(3_&lt;&gt;ceHi2-^_y o-CeH, 2y (A64-3) OC4H8- b-c4H12- q y (A64-4) *-〇-Q-c6h12 -O-CeH-j Ύ -o-c4h8-c o b-ceH12-q A o-c4h12-c^ (A66-2) *-〇-^ h〇c6H12-^_y (A66-3) (A66-4) o-c4h8- -c6h12- / (A62-5) (A62-6) (A62-7) (A62-8) (A63-5) ( A63-6) (A63-7) (A63-8) (A64-5) (A64-6) (A64-7) (A64-8) (A66-5) (A66-6) (A66-7) ( A66-8) 76 201202806

Ό-ζ^-〇-〇4Ηβ-^_/

(Α67-1) (Α67-2) (Α67-3) ^ W 〇Ό4Ηθ-^ (Α67-4) * (A67-5) (A67-6) (A67-7) (A67-8)

(A68-1) -〇-C4H8-^_y (A68_5) -oc4h

(A68-4) *-o-(^)--c6h12 (A68-2) (A68-3)

(A68-6) (A68-7) (A68-8) The method for producing the compound (A) will be described below. According to the structure of the compound (A), known organic synthesis reactions (for example, condensation reaction, esterification) described in Methoden der Organis Chen Chemie, Organic Reactions, Organic Syntheses, Comprehensive Organic Synthesis, New Experimental Chemistry Lecture, and the like Reaction, Williamson reaction, Ullmann reaction, Wittig reaction, Schiff base formation reaction, benzylation reaction, bacterial head reaction, Suzuki-Miyaura reaction , Root-bank reaction, Xiongtian reaction, Lushan reaction, Bukhwald-Hartwig reaction, Friedel_Craft reaction, Heck reaction, Aldol reaction, etc. Compound (A) is produced by appropriately combining. For example, in the case where D1 and D2 are compounds represented by the formula (D) of *—〇—c〇—, it can be produced by the following method: that is, by expressing by the formula (1-1) The compound is reacted with a compound represented by the formula (2) to obtain a compound represented by the formula (丨-3): HO-Ar-OH π-η 77 201202806 (f, where f1 represents the phase as described above _significance.)

Pi-Fi|.Bi_Aij__Ei_Gl__c〇2H In the meaning (formula), 'G1, El, A1, B1, F1, pl, and k represent the same + as described above—for example, Gl—”―' (4) (where Ar , G1, E1, A1, the same meaning.) B1, F1, P1 and k represent the phase α as described above, and the compound represented by the formula (1~~3) is obtained by the formula (1~~3) 1_4) Manufactured from the reaction of the compound: (1.4) H02c—^G2—E2-(-A2—B2)^—F2—P2 (G, E, A, B, F2, p2 and 1) The same meaning as described above is expressed. The reaction between the compound represented by the formula (1-1) and the compound represented by the formula (i-2), and the formula (1-3) The reaction of the compound with the compound represented by the formula (1-4) is preferably carried out in the presence of a condensing agent. j乍 is a condensing agent, and one cyclohexyl-3-(2-morpholinylethyl)carbon can be cited. Dimethyleneimine, l-CyClohexyl_3-(2-morpholinoethyl)Carbodii mide Metho-p-toluenesulfonate), dicyclohexylcarbodiimide, 1-ethyl-3-(3-bis Mercaptopropyl propyl) carbodiimide, 1-ethyl- 3 - (3 - two Aminopropyl)carbodiimide hydrochloride (partially water-soluble carbodiimide: WSc is commercially available), bis(2'6-diisopropylphenyl)carbodiimide Amine, bis(tridecylfluorenyl)carbodiimide, diisopropylcarbodiimide, carbodiimide, 2-mercapto-6-nitrobenzoic anhydride, 2,2, one Carbonyl bis- 1H-imidazole, 1, hydrazine-grascensyl 2 m sit, a basal acid-based nitride, 1 (4-nifeite yellow-branched)-1H-1,2,4-two坐 sitting, 1H-benzotriazine, 1- 1 -yl-oxy-trisole, lH-benzotriazol-l-yl-oxy-tripyrrolidinophosphonium hexafluoro ph osphate, 1H-benzene And triazolyl-1 -yloxy-sodium bis(diamino)-phosphonium-hes (dimethylamino)-phosphonium he 78 201202806 xafluoro phosphate), N, N,N' 'Ν'-four-mercapto-one-(N-amber succinimide)urea tetrafluoro succinate (]^凡&gt;1',1&lt;['46如11^%1_〇 -(]^11(:(:111^(171;)111'〇nium tetrafluoroborate), N—(1,2,2,2-four ethoxylated) Oxy) succinimide, N-benzyloxyindenyl succinimide, 〇-(6-chlorobenzotris-yl)-N'N, Ν', Ν'-tetramethylurea tetrafluoro Borate, bismuth-(6-gas benzotriazole- 1 -yl)-indole, hydrazine, Ν' 'Ν'-tetramethylurea hexafluoro-hydrochloride, 2-bromo-ethylidene tetrafluoroborate, 2-Gas-1,3-dimercaptoimidazolium chloride, 2-gas-; 1 '3-dimercaptoimidazolium hexafluorophosphate, 2-chloro-1-methylpyridinium iodide, 2-chloro 1 - mercapto acridine p-toluenesulfonate, 2-fluoro-1-methylpyridyl p-toluene hydrochloride, pentachlorophenyl trichloroacetate. From the viewpoints of reactivity, cost, solvent which can be used, etc., as a condensing agent, more preferably dicyclohexylcarbodiimide, 1-ethyl-3-(3-dimethylaminopropyl)carbon Diterpenoids,! —ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride, bis(2,6-diisopropylphenyl)carbodiimide, bis(trimethyl) Mercapto) carbodiimide, diisopropylcarbodiimide, 2,2, 鲈美美双一1H-imirene. Fire soil The phase difference plate of the present invention is preferably obtained by polymerizing a polymerizable component in the case where the composition of the compound (A) is referred to as "composition (A)". The composition (A) may contain a liquid crystal compound (however, it is different from the compound (A)", and the publication is published by Wei Jingwei Red Money Co., Ltd. ^: For the Maruzen Co., Ltd., issued on the 3rd of January, 1st, 2003) The third pair of rod-shaped liquid crystal molecules and 33 pairs of palmar rod-like liquid crystals have a polymerizable group-compound among the compounds. There is a poly = liquid composition. Among them, it is preferably a combination of pna~BU-Eum- (6) ??16) towel _,? 11 silk polymerizable base. A11 silk fat ribbean, aristocratic hydrocarbon group. The divalent alicyclic hydrocarbon group and the divalent aromatic tobacco containing 79 201202806 hydrogen atom T may be substituted with a halogen atom, an oxy group, a cyano group, or a hetero group. The Wei i jing atom, a carbon number of 1 to 6, a carbon number of 1 to 6, the calcined number of 1 to 6, and the carbon number of 1 to 6 alkoxy

CH=CH—, or a single bond. E, an alkylene group having a carbon number of not more than 12, and the hydrogen atom contained in the alkylene group may be an alkyl group having 1 to 5 carbon atoms or an alkoxy group having 1 to 5 carbon atoms. The hydrogen atom of the alkyl group and the alkoxy group may be substituted with a halogen atom, and the -CH2 '' contained in the alkylene group may be substituted with a fluorene- or -C0_. In the case of P11, in order to cure the phase difference plate, for example, photopolymerization is also used, and the car is preferably applied to a photopolymerizable radical polymerizable group or a cationic polymerizable group, and is particularly easy to handle and easy to manufacture. Therefore, it is preferably a group represented by the following formula: ~5).

In the formula, R17 to R21 each independently represent an alkyl group having 1 to 6 carbon atoms or a hydrogen atom. 氺 represents a bonding site with B11. P is preferably a formula (P-4) to a formula (P-10). ), based on the vinyl,

P —(2-phenylvinyl)phenyl, oxiranyl, epoxybutyl, isocyanate, and isothiocyanato. A 201202806 corpse

(P-9) (P-6) (P-7) (P-8) Wide o

(P-10)

A is an acryloxy group or a methacryloxy group - a phenyl group. ...·r—a cyclohexylene group or a 1,4 12 alkylene group. The methyl group contained as the E, preferably having an unbranched amount of 2 or more, may be substituted with fluorene. Specific examples thereof include methylene, ethylene, propylene, butylene, pentylene, hexyiene, heptylene, octylene, and arylene. Nonylene, deCaiene, undeCalene, dodeCalene, a CH2—CH 2 —O—CH 2 —CH 2 —, a CH 2 —CH 2 —0 —CH 2 —CH 2 —0—CH 2 —CH 2 —, and —CH 2 —CH 2 —0 —CH 2 —CH 2 —0 —CH 2 —CH 2 —0 —CH 2 —CH 2 — and so on. The compound (6) may, for example, be a compound represented by the formula (I), the formula (Π), the formula (ΙΠ), the formula (IV), the formula (V) or the formula (VI). pH - β11 - Ε11 - B12 - A11 - Β 13 - A12 - Β 14 - A13 - Β 15 - A14 - Β 16 - Ε 12 - Β 17 - Ρ 12 (I) ρ11 _βπ - Ε 11 - Β 12 - A11 - Β 13 - Α 12 - Β 14 - Α 13 - Β 15 —Α14 — F11 (II) —Ε11 —Β12-Α1] -Β13—Α12_Β14-Α13-Β15 —Ε12-Β17-Ρ12 (III) Ριι—Bnm—Βΐ3 —Αΐ2—βΜ—Α]3—Fn (ιν) ρ11_Β11_ΕΠ_Β12_ΑΠ_Β13 Α Β Β Β _ Β Β - - - - - - - - - - - - 201211 Synonyms. 81 201202806 F represents a hydrogen atom, an alkyl group having a carbon number of i~13, a carbon number of 135~13^yl 2 group, a trifluoromethyl group, a dimercaptoamine group, a trans group, a fluorenyl group of 1 to 1 The carboxy group of the alcoholic acid of the oxime or the octapeptide atom may be substituted with one oxime contained in the alkyl group and the alkyl fluorenyl group. ^ As a specific example of the compound (6), for example, the following formula The compound represented by the formula wherein k1 and k2 represent an integer of 2 to 12. These liquid crystal compounds are all due to the Or are commercially sold as easily start the like, it is preferred the liquid crystal compounds. ° ~ (CH2) kf〇

(CH2)k2-

°V (I-3) -(〇Η2)κ2-°^·( -〇-(CH2)kv

〇(CH2)k2-H (11-1) 〇-(CH2)ki·

0-(CH2)k2-H (II-2) (II-3) =3_〇-(CH2)k1,〇.

-(CH2)k2*H

M 82 201202806 -0—(CH2)k2·

〇 〇 ^0- ~C~^)-〇 0 -(CH2)k1—O 3-〇-(CH2)k1-cK:

O—(CH2)k2—O—^ -0-(CH2)k-0 =3^〇-(CH2)ki-O^

'~/ }~0~(CH2)k2~0~{ n \= 〇

^-〇-(C H2)k1-〇-&lt;〇^^Q =7 0 0 3-°- (in-1) (III-3) (NM) (III-5) h〇—(CH2) K2—〇乂(III-6), N=—(CH2)k2~〇~^ (IH-7) 〇(丨丨丨·8) y〇一(CH2)k2—〇' 83 201202806

〇 (CH2)k2-〇- &gt;o-(CH2)k.〇^-^V^^V〇 O 0 -(CH2)k2- _^~〇—(CH2)ki~Q~

(〇 〇' 〇 O

Br -O—(CH2)k2—〇 〇—~(CH2)k2— Br

N02 }〇—(CH2)k2

(III-9) (IIMO) (111-11) (IIM 2) (IIM 3) (111-14) (111-15) (111-16) (111-17) (111-18) (111-19 ) 84 201202806 Ο. -ο—(CH2)k—Ο- 1〇- (CH2)k1—〇- ί 〇〇一(CH2)k2—〇

(IN-20) /〇—(CH2)k2—〇~^= (111-21) 〇- -Ο—(CH2)k—0- -0—(CH2)k—〇-〇,〇Ο., 〇Q. ϋΟ° -〇—(CH2)k2~〇' -〇一(CH2)k2—〇- -〇Ό (MI-22) (MI-23) -(CH2)k“0-^ /J- OO' 〇~^^~〇~(CH2)k2—〇-^_ (HI-24) 〇-0—(CH2)k1—0-

Cl (CH2)k1-〇-

} 〇 -ο—(CH2)k2~〇- (III-25)

Cl

〇~(CH2)k2-~〇-^_ (IH-26) 85 201202806 O—(CH2)kf

I ov

O—(CH2)k2—'H

^-o-(CH2)k1—0 Or3-〇-(CH2)k1-〇H^^^〇^〇'(CH2)k2_H 〇-(〇h2^2—h -0^

〇-(CH2)k2-H _^〇~{CH2)m—〇(CH2)ki—〇 i 3~°~ “0- -〇—(CH2)ki—0 (CH2)k1—0

=&gt;〇-(CH2)k1-〇-{'^K〇-^^-CN

&gt; -(CH2)k1-〇^

-〇-(CH2)k〆. ·

(CH2\2^H -0—(CH2)ki—0-i- (丨V,1) (IV-2) (IV-3) (IV-4) (IV-5) (IV-6) ( IV-7) (IV-8) (IV-9) (IV-10) (IV-11) (IV-12) (IV-13) (IV-14)

-CN 86 201202806

〇

0-(CH2)k2-H

O (CH2)k—〇-^^-^^-^]^-〇-(CH2)k2-0^~^ (V-1) (V-2) (IV-1 5) (IV-16) (IV-17) (IV-18) (IV-1 9) /=\ .0 (VI-1) (VI-2) O-^-CN (VI-3) (VI-4) (.8 \_/&quot;COOH (VI-5) (VI-6) -'〇-(CH2)Ki-〇- -〇-(CH2)kr 〇- 0 -o-(CH2)kr〇-i =3^ 〇'(CH2)^__〇^q -〇-(CH2)ki-〇' -o-(CH2)ki-0- The content of the liquid crystal compound is 'for example, 100 parts by mass relative to the total amount of the liquid, 90 parts by mass or less. The substance/the chemical substance (A> The wavelength dispersion characteristic of the phase difference plate of the present invention can be determined by the following rain content: 87 201202806', that is, the compound (A) derived from the phase difference plate The content of the structural unit and the content of the structural unit derived from the liquid crystal compound. When the content of the structural unit derived from the compound (A) in the phase difference plate is increased, reverse wavelength dispersion characteristics can be added. Specifically, preparation 2 to 5 In the composition of the compound (A) having a different content of the structural unit, the phase difference 相位 of the phase difference plate obtained by calculating the phase difference plate of the film thickness of the production phase is as follows. and As a result, the correlation between the content of the structural unit derived from the different compound (A) and the phase difference 値 of the phase difference plate can be determined, and the phase difference required for the phase difference plate in the film thickness can be determined from the correlation obtained. The content of the structural unit derived from the compound is preferably a polymerization initiator. The polymerization initiator may, for example, be a thermal polymerization initiator, a photopolymerization initiator, or the like, and may be at a low temperature. The photopolymerization initiator is preferably polymerized in a stable manner. ^As a photopolymerization initiator, a benzoin compound, a diphenyl ketone compound, an acetophenone compound, a mercaptophosphine oxide compound, and a triazabenzene compound can be cited. And benzoin, benzoin methyl ether, benzoin, benzoin isopropyl, and benzoin isobutyl ether. As a diphenyl refining &amp; Phenyl ketone, decyl benzhydryl benzoate, 4-phenyldiphenyl ketone, 4-branched-4,-methyldiphenyl sulphur, 3,3,,4,4, — butyl butyl amide, diphenyl ketone, and 2, 4,6-tridecyldiphenyl ketone. As acetophenone 5, diethoxy phenethyl steel, stone H phenyl b 1 - acetone, 2~2-2-methylamino group + (4-morpholine basic) 1-butanone, ^-t-group:: dimethoxy-b-ethyl ketone, 2 - honest - 2 - fluorenyl-bu-reduced oxy) stupid] Bu-Bei steel, Bu Jingji An oligomer of cyclohexyl benzophenone and 2-indole-(4-isopropenylphenyl)-1-propanone. The f can be exemplified by 2' 4,6-trimethyl fine diphenyl oxidation: and; (2 4; 6: trisyl, phenylphosphine oxide. As a triazabenzene-one cow's di-milk base) a 6-(4-methoxyphenyl)-1,3,5-dioxin, 2'4-bis(trichloromethyl)-6-(4-methoxynaphthyl)_], 3 ,5 88 201202806 —Triazabenzene, 2,4-bis(tris)- 6-(4-methoxyphenylethyl)- 1,3,5-triazabenzene, 2,4 - bis(trichloroindenyl)-6-[2 - (5-fluorenyl succinyl-2-yl)vinyl]-1,3,5-triazabenzene, 2,4-bis(trim)曱基)一6 — [2 —(flfol-2-yl)vinyl]-1,3,5-triazabenzene, 2,4-bis(trichloroindenyl)-6-[2 — (4-diethylamino 2-nonylphenyl)vinyl]-1,3,5-triazabenzene, and 2,4-bis(trichloroindenyl)-6-[2— ( 3,4-dimethoxyphenyl)ethenyl]-1,3,5-tris-benzene. As a photopolymerization initiator, IrgaCure 907, IrgaCure 184, IrgaCure 651, IrgaCure 819, IrgaCure 250, IrgaCure 369 (all of which are manufactured by Ciba Japan Co., Ltd.), Seikuor BZ, Seikuor Z, and Seikuor BEE (all of which are Seiko) may be used. Chemical Co., Ltd.), 〖&amp;}^(^11 generation 6?100 (manufactured by Nippon Kasei Co., Ltd.), KayaCure UVI-6992 (manufactured by Dow), ADEKA OPTOMER SP-152, ADEKA OPTOMER SP-170 (above) It is a commercially available photopolymerization initiator such as ADEKA AG, TAZ-A, TAZ-PP (above, manufactured by Siberhegner, Japan), or TAZ-104 (manufactured by Sanwa Chemical Co., Ltd.). Preferably, it is an acetophenone compound, and more preferably 2-benzylated 2-dimethylamino-1-yl-(4-morpholinylphenyl-butanone). In the case of the start of the polymerization, the heat resistance and the heat and humidity resistance of the _difference plate are increased, so that the acetophenone compound is preferably used. The content of the polymerization starting group is, for example, 0% by mass based on the compound (4) (10). Shell, parts ~ 30 parts by mass Preferably, it is 5 parts by mass to 1 part by mass. _ Frequency, micro-paste, agent, and light-increasing <spiral attractant> The compound (VIII) or the liquid crystal compound in the form of Li, the compound is present. And a compound having the function of the above-mentioned strong helix torsion. As a spiral attracting agent, a compound having a different atomicity of an asymmetric carbon atom and an atomic compound, or a substance, or 89 201202806 Asymmetric carbon atom does not contain an asymmetric carbon atom, for example, or a compound having a binaphthyl skeleton. A compound having an isosorbide skeleton as a spiral attractant can be used in the device manual (3rd) Chapter 4-3, the compound described in the order: "Liquid Crystal Sakamoto Academic Promotion Association No. 142, ^ Spiral Inducing Agent, page 199 ' Brain 曰 曰 本 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : No. 2007-176870, No. 3, No. 39, No. 39, Japanese Patent Gazette, Japanese Patent, No. 7, No. 7, No. 7, 2007-169178, Eight Molybdenum, Shi * 15496遽, pp.蟫旋勉本公公表第平平平平平平平平平平平平平平平. Lure insects years from ⑺ agent is preferably represented by the following formula of the compound: hunt

—10—如3—e3_D3__CS^—e4 —ε4 + —(7) and D knife independent table-O-CO---C(=S)-〇-, -OC(-S)---cr22r23-- -CR22R23 - ΓΈ 2 V3 —. CR22R23- . ~CR22R23~n 〇22 r CR R —, —〇_ "Heart 23 ~ CR R — 〇CR22R2j - 〇- CR24R2^ _ , _ ^'l0''00-;^0-00'^23- ^ -CR2V3_〇_c〇-, -crC _C0—0—cr24r25—Serve 22-cr23r24 R23, R24 2 “(7)-NR22-, or -NR22-CO-. 圮2, R independently represent hydrogen atoms a fluorine atom or an alkane gas having a carbon number of 1 to 4, 0 ^ G&amp; and G4 each independently represent a divalent alicyclic hydrocarbon group or a divalent aromatic hydrocarbon group. The hydrogen atom to be contained may be substituted with 1 atom, an alkyl group having 1 to 4 carbon atoms, a carbon number of 1 to 4 alkoxy group, a cyano group or a nitro group. The alkyl group having 1 to 4 carbon atoms and the carbon number 丨The hydrogen atom contained in the ~4 alkoxy group may be substituted with an I atom. E3, E4, B3 and B4 each independently represent a CR22R23---CH2~CH2-^s-^co-〇1, -0-C0- , 0—C0~〇—, C(=S)—0---〇-C(=S)——0—C(=S) — 0—-CO—NR22 —,—take 22~ CO - 〇-CH2 - CH2-〇---S -CH -, -CH2-s, or single bond. 90 201202806 兮f 2 valence of a salt or a divalent aromatic hydrocarbon group. Valsin The inclusion of a orbital atom can be replaced by a subroutine, a filament with a number of 1 to 4, a carbon number of 4, an alkoxy group, a cyano group, or a smectite. The gorge radical and the Wei number 1 to 4 silk base contain a shunt atom. k and 1 are each independently represented by an integer of ^^. F3 and F4 each independently represent a single bond or an alkylene group having a carbon number of 丨~丨]. The hydrogen atom contained in the filament may be substituted with a carbon number i~5. Among the p-types, the compound represented by the following formula _ △ Ί k k's palioColor LC756 is sold on the market. LC756

^〇M〇^ P3 and P4 each independently represent a hydrogen atom or a polymerizable group. The content of the spiral attractant in the amount of the compound (A) 1 (X) f is, for example, 0 1 -50 f, ο^ο f1.0^30 f by controlling the content of the spiral attracting agent in the composition (4), The original position difference plate _ select the reflection wavelength band. In the case of selecting a coloring use such as a reflection wavelength, it is preferable to evaluate the inverse w wave (four) domain. Further, in the case of negative c, it is preferred to have a riding reflection wavelength band in the light-receiving zone.本Use the domain of the Can domain (4) (4) to obtain the date of the _ phase difference plate 1 ' | hair _ phase difference plate is preferably from the column phase ^ In addition, the center wavelength of the selective reflection wavelength band is preferably nm More 100 is 100~) 00 faces. The center wavelength (nm) of the selected reflection wavelength band can be expressed by λ == η · p. Here, n represents the average inflection rate of the composition, ^ 91 201202806 __ distance (four). I can be added to control the center of the selected reflection wavelength band. The cumbersome inducer selects the center wavelength λ(TM) of the reflection wavelength band. For example, if the amount of addition is to be reduced, if the amount of the selective wave-forming agent is to be low, the amount of the addition of the spiral attractant is increased, and the concentration of the inhibitor is increased as a polymerization inhibitor. The use of a t-base, a foot agent, a scorpion meaning, a base, etc., by using a t-blocking agent, can control the mass of the compound relative to the compound (4) (10) by a mass fraction of αι f~3 a = 〇·5 mass Parts ~ 10 parts by mass. Berry 乂 乂 Jia Feng <Light Sensitizer> • As a photosensitizer, 汕嗟 (xanth〇ne) and 9_oxysulfide 3 An onion such as an ether, phenothiazine, or rubrene. By using a photosensitizer, the sensitivity of the polymerization of the compound (A) or the like can be improved. Further, the amount of the photosensitizer to be used is 1 part by mass based on the compound (A), for example, y parts by mass to 30 parts by mass, preferably 5% by mass to 1 part by mass. <Leveling agent> 'As a leveling agent', for example, an additive for a radiation hardening coating (Βγκ)

Japan ΚΚ Manufactured: ΒΥΚ—352, ΒΥΚ—353, ΒΥΚ — 361Ν), coating additives (manufactured by Dow Coming Toray Co., Ltd.: SH28PA, DC11PA, ST 80PA), coating additives (manufactured by Shin-Etsu Chemical Co., Ltd.: KP321, KP323, X22) — 161A, KF6001), or a fluorine-based additive (manufactured by dic Corporation: F-445, F-470, F-479). By using a leveling agent, a smoother phase difference plate can be obtained. Further, in the manufacturing process of the phase difference plate, the fluidity of the composition (A) or the bridging density of the phase difference plate obtained by polymerizing the compound 92 201202806 can be controlled. The specific number in the usage is as follows, that is, for example, phase &amp; π. The magic spoon makes 0.1 parts by mass of ~% fold ~, ϋ Γ to the compound (4) 1G () parts by mass < < two> shell one enough parts ~〗 〖 parts by mass. The antibacterial agent may be any solvent which is capable of dissolving the organic solvent of the compound (A) and is inactive to the poly(1). Specifically, it may be exemplified by decyl alcohol, ethanol, and ethyl acetate. , butyl acetate, ethylene glycol A = U, γ-τ_, propylene glycol methyl methacrylate: L: pentanone, cyclohexanone 1 pentyl ketone, or = agent ==: 4 pits or series of non-gasline fats, tetrahydrogenated or dimethoxyethane; gas; 丨 2: This ίί, the agent can be called the use of 'can also be combined with a plurality of Π 剂, _ solvent, non Chlorine-based fat ===, lanthanum is dissolved, so even if you don't use 翕 笙 么 么 么 么 么 广 广 广 香 香 香 香 香 香 香 香 香 佳 佳 佳 佳 佳 佳 佳 佳 α α α α α α α α α α α α α α The concentration of the solid component in the occupant: ϋΪ (Α) is, for example, 5 to 50% by mass. (10) The concentration of the ingredients in the mail is 5% by mass. Berry / 〇. The optical compensation of the right solid to the liquid crystal panel must be double f, and there is a full amount of the method of manufacturing the differential plate of the present invention from the composition of the composition. <Alignment Film Forming Step> It is preferred to form the alignment film on the substrate. Examples of the support substrate include glass, a plastic sheet, a plastic film, and a light-transmitting film. 93 201202806 This ^, as the above-mentioned light-transmitting film, can be cited as polyethylene, poly

(朦b〇men polymer, such as polycarbon film, polyethylene film, polyparaphenylene Z d丄 poly: oxime oxime film 1, polypropylene _ film, weaving ester film, polydi-f-ester a film, a poly-rolled film, a polyether sulfone film, a polyether ketone film, a λ-extended base sulfide film, and a polyphenylene oxide film. The step of attaching the phase difference plate of the present invention, the carrying step, The step of storing the strength may be carried out by using the support substrate, and the phase difference plate of the present invention can be easily handled without causing a fractured temple. The alignment film is preferably: when the composition (A) is coated, When it is removed from the solvent or the liquid crystal alignment coffee, it has 5, raw, and is not bound by friction or the like during the miscellaneous treatment; and is preferably a substance or a composition containing the polymer. The λ amine may, for example, be a polystyrene having a kinky linkage in a molecule, ΐ··, polyvinyl alcohol, squamous polyglycol, polyacrylamide, polystyrene, Polymers such as polyvinyl hydroketone, polyacrylic acid, and fine acid vinegar. These polymers can be used alone or in combination of two or more. Or use in copolymerization. These polymers may be subjected to polycondensation, radical polymerization, agglomeration polymerization, coordination polymerization, lysine polymerization, etc., by the following reaction or deamination. It can be dissolved in a solvent and applied. d: Alcohol ΐ 苏 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Soil 3 acid vinegar, or lactic acid B solvent; propyl, methyl ethyl ketone, bismuth, 'pentyl ketone, or methyl isobutyl ketone, etc. _ solvent; pent, ., yuan or G A non-chlorinated aliphatic hydrocarbon solvent; a toluene or dimethyl hydrazine negative hydrocarbon solvent; a side solvent such as acetonitrile; a tetrahydrogen butterfly; a 2 糸r agent, a chlorine solvent such as chloroform or chlorobenzene, etc. The two can be used alone or in combination with a plurality of types. In the early days, 94 201202806 In addition, in order to form an alignment film, it is also possible to directly use the market as a commercially available postal material, and S._VER (^, feng feng; In the case of the use of the aligning film, the use of the aligning film, it is not Since the in-plane unevenness of the inflection is reduced by the extension, it is possible to provide a large-sized difference plate on the support substrate, and therefore it is also possible to increase the size of the flat panel display device (FPD). Forming a compounding method on the supporting substrate, for example, an alignment film material or a compound constituting the alignment film, and coating the compound on the upper layer, and then forming the upper substrate by the fire. The drying of the solvent can be carried out at the same time as the polymerization, but it is preferred to dry most of the solvent before the polymerization from the point of view. As the solvent-drying method, for example, natural drying and air drying can be cited. ~200C. In addition, as the drying time, it is preferably 1 second to 6 minutes. 30 seconds to 30 minutes. Only the WE dry temperature and the dry correction zone are in the above-mentioned fineness, and the support substrate may be used, and a support substrate having a low heat resistance may be used. The film thickness of the alignment film is, for example, 10 to 1 leg, preferably 0.5 to 1000. As long as it is in the above formula, the compound (A) can be made to have a degree. <Orientation can be given to the step> The alignment film formed is given an aligning energy to have a plurality of alignment directions. Hi: The enthalpy is a method of rubbing the alignment film or rubbing the alignment film, and can be used. For example, the alignment film wound around the friction roller and the carrier film placed on the stage is formed by forming a plurality of regions 95 201202806 in the alignment film by rubbing treatment. First, the mask is not directly transmitted through the mask. A first rubbing treatment is applied to the alignment film. Thereafter, a mask having a predetermined pattern is laminated on the alignment film, and a second rubbing treatment is applied in a direction different from the direction of the second rubbing treatment. Thereby, the portion covered with the mask is a region having the alignment direction formed by the first rubbing treatment, and the portion not covered by the mask is the region having the alignment direction formed by the second rubbing treatment. Further, after laminating the second mask having a predetermined pattern on the alignment film, the first rubbing treatment is applied, and then the portion having the surface of the first mask covering the alignment film is not covered with the opposite pattern. 2 The mask is layered on the alignment film, and by the second Mochi Festival, a plurality of regions having different alignment directions can be formed. Further, after the rubbing treatment, the third rubbing treatment is performed through the third mask, whereby an alignment film having three regions having different west-direction directions can be formed. In this way, the alignment film having the plurality of shirts in different directions is formed by repeating the rubbing process. Further, an alignment film having a complicated area pattern of a different alignment direction can also be formed. Further, as described in Japanese Laid-Open Patent Publication No. 2004-287406, (4) the coating may be patterned after being covered, or may be, for example, a schematic view showing the orientation of the alignment. =, take, the material of the mask can be listed as stainless steel, iron plate, 1^ plate, etc. Metallic 曱 曱 丙 夂曱 夂曱 夂曱 vinegar, polyethylene terephthalate vinegar, plastic and other plastic plates, etc. It is not necessary to break the material due to the rubbing treatment. : Polyfluorene is 2 〇, ～5 faces, more preferably 3 〇 - "Wu I mouth phase difference plate preparation step" and there is a composition which makes it less, so it is better to have a composition containing an organic solvent. It consists of the initiator Ϊ composition, and it is preferred to prepare a polymerized open plate. When the composition is applied and dried, an unpolymerized phase difference difference can be obtained. When the nematic liquid crystal phase is displayed, the obtained complex refractive index of the monodomain alignment is obtained. Phase difference 96 201202806 The board is below 0~25〇t:, preferably between 1〇~150. Alignment under 〇. The film thickness giving the desired = position difference can be prepared by appropriately adjusting the coating amount or concentration of the composition. When the amount of the polymerizable compound such as the compound (A) is a certain composition, the phase difference 値 (Retardati〇n値; ReW) of the obtained phase difference plate is determined by the formula (8). In order to obtain the desired Re (Q, it is only necessary to adjust the film thickness 4).

Re(X)=dxAn(X) (8) _ (wherein, Re〇) represents the phase difference 値 at the wavelength ληηι, d represents the film thickness, and (5) represents the birefringence at the wavelength ληπι. The method of coating on the support substrate or the alignment film may, for example, be an extrusion coating, a direct gravure coating method, a reverse gravure coating method, a CAp coating method, or a die coating method. Further, a method of applying a coating machine such as a marriage liquid dip coater, a rod coater, or a spin coater may be mentioned. The phase difference plate of the present invention satisfies the formulas (1) and (2): Δη(450)/Δη(550)^1.〇〇(1) 1 ·〇〇^Δη(650)//Δη(550) (7) . For example, by the content of the compound (Α) in the δ-circumferential composition (Α), the wavelength dispersion property of the whole-order-difference plate can be obtained, and the compound in the phase difference plate (2 is replaced by = ^ pain) The flat-wavelength splitting property and the reverse wavelength-wavelength property are obtained. The preparation can obtain a phase difference plate containing a compound (the content of the structural unit of the polymerizable compound wire) by the operation shown in the following (8) to (4). The composition is polymerized and the composition is polymerized. =) The composition of the group of the polymerizable compounds having different contents of about 2 to 5 types is prepared, and the composition of the side obtained by the needle is produced, and the same money is produced, and The polymerizable compound is composed of a phase difference plate having a different content of structural units, and + (6) Calculating the phase difference 値 of the phase difference plate obtained in (b), and calculating the phase difference ( obtained in (c) The correlation of the phase difference 値 of the polymer phase-containing compound from the early reading phase difference plate, '. 冓 (5) from the _ sex obtained in (4), the upper _ thick towel to the God's disparity plate 97 201202806 phase difference The content of the structural unit derived from the necessary polymerizable compound, that is, in the composition The content of the polymerizable compound. Generally, the phase difference 値Re(X) at the wavelength λ divided by the phase difference 値Re(550) at 550 nm (ReW/Re(550)) is close to the wavelength band of !, or [ Re(45〇)/

Re(550)] &lt;l and [Re(650)/Re(550)]&gt;1 in the wavelength band showing reverse wavelength dispersion can be uniformly polarized. <Unpolymerized phase difference plate polymerization step> In the unpolymerized phase plate difference plate polymerization step, the unpolymerized phase difference plate obtained in the above unpolymerized phase difference plate preparation step is polymerized and cured. Thereby, an alignment-fixed phase difference plate of the compound (A) or the like is formed, that is, a phase difference plate is polymerized. The method of polymerizing the unpolymerized phase difference plate may be selected according to the kind of the compound. When the polymerizable group contained in the compound (A) is a photopolymerizable group, it is photopolymerized; if the polymerizable group is a thermally polymerizable group, the above is not possible by thermal polymerization. Polymerization phase difference plate polymerization. The phase difference plate of the present invention preferably has an unpolymerized phase difference plate polymerized by photopolymerization. It is only necessary to polymerize the unpolymerized phase difference plate by photopolymerization, so that the heat resistance i of the support substrate is wider. In addition, it is also easy to manufacture in the industry. Further, it is preferable from the viewpoint of the film forming property that the discrimination is preferable. Photopolymerization is carried out by unpolymerizing her poor plate, illuminating, ultraviolet light, or laser light. From a processing point of view, it is especially good for external light. The heating can be carried out while heating at the temperature at which the compound (4) is a liquid crystal phase: at the same time, the polymerization retardation plate can be patterned by a mask or the like. 2 is a schematic view showing the phase difference plate u of the present invention. The phase difference plate does not have a domain and region 13. The region 12 and the region 13 intersect with each other in the direction of the phase retardation axis. In the method of manufacturing the phase difference plate of the invention, after the above steps, the step of scribing away from the support substrate is performed. By forming such a structure, the resulting layered product is 相位ίίϊί, a phase difference plate composed of a phase difference plate. Further, in addition to the above, the step of peeling off the alignment film may be further included. A phase difference plate can be obtained by forming a structure of the sample. / Zheng Hunt by the &amp; sample of the phase difference plate has excellent versatility, and is used in a variety of 98 201202806 display device with phase difference plate. The thickness of the layer formed is different as described above depending on the phase difference (four) phase difference 値. In the present invention, the thickness is preferably ^ ΙΟ ΙΟ μηη, and from the viewpoint of lowering the photoelasticity, such a film can be applied to a liquid crystal panel or a wider wavelength band. Organic EL and other fpd. In addition, since the present invention can be turned over, for example, it is applied to a film and polymerized by irradiation with ultraviolet rays, so that it can be more easily formed on the back side of the i|silk (ie, , the back side) or the opposite side of the front) forms a phase difference plate. V丨月九, 3,® 4 lie down The semi-transmissive Wei Jing display devices 3U and 31B of the present invention can be driven by a reflective and/or nuclear driven display. The semi-transmissive liquid crystal display device 31A is composed of a rabbit, and the north soil y 1/ , the back surface includes 32 sides in the order of the present invention (also referred to as a phase difference plate 34, a substrate 35, and a bright electrode 38). , the calender 39 (however, the irradiator reads: necessary), the present invention _ county board 4Q, the button 41, and the polarizing plate 42. The semi-transmissive liquid crystal display device 31B is produced... north, back) The first order includes a substrate 41 and a polarizing plate 42 on the side of the J light 32 side (also referred to as "the transparent electrode 38, the phase difference plate 40 of the present invention, which is not necessary"). The pixel 36 is divided into the first and the second deputy, and the second deputy is called the 5 丨丨蚩 | ― 2 7 tiandan is called the reflection 丨 J. ^ A Hungarian 笾 画. The first deputy book is also used as a sputum and a projection, and includes a back surface reflective electrode portion 36 manufactured by Megumi et al., for example, a transparent back surface made of ITO or the like: having a f 扛 扛 c c 6 丄 each * month concave Moon electrode portion 36B. Therefore, the back surface reflection is a reflection unit portion, and the back surface transparent electrode portion 3 is a permeation unit. In this (four) _ differential plate 4 与 and f % - transparent ^ ~ ϋΐ ϋΐ into the phase of the phase delay axis direction.平板The flat panel display device of the present invention_略®. The outline of the Li ^ __ set 51. The structure of the liquid crystal display is as follows: 'From the side of the backlight 52 (also referred to as the back side), it is included in order: partial 99 201202806 light plate 53, liquid crystal cell 54, and eccentric cylinder. The front and rear of the crystal unit 54 are provided with a polarizing plate 53 and a polarized light. , the difference plate 56. The - side ^ 55 of the opposite surface of the liquid crystal cell 54 of the liquid can be displayed 31) without the display device 51 of the polarizing plate 55. The phase difference plate 56 of the moon. The area of the liquid left eye image is: ^6, the area of the two image areas 56A, and the area where the left circularly polarized light is emitted, and the area 56A of the image for the eye is circularly polarized, and the area lake of the area is emitted. The right region 56A and the region 56B are formed in a strip shape; ^ is preferably == the area is substantially the same. Preferably, it is a pair of glasses (not shown), that is, a circular polarizer composed of a right-eye lens, a left-eye f-plate, and a non-domain 56Α phase retardation axis direction. ' As well as a polarizing plate and a circular polarizer composed of a phase difference plate having the same phase retardation direction as the region, 3D images can be observed. 6 is a schematic view showing a flat panel display device 61 other than the liquid crystal display device according to the present invention. Examples of the flat panel display device 6 other than the liquid crystal display device include an organic EL display device, a plasma display device, a field emission display (Fed), a surface conduction electron emission display (SED) type flat display, and electronic paper. Since the light emitted from these display devices is not polarized, the polarizing plate 63' is provided on the emission side of the front surface of the conventional flat panel display device 62, and the opposite side of the polarizing plate 63 on the side opposite to the conventional flat panel display device 62 is provided. The phase difference plate 64 of the invention can be displayed. 7 to 9 are schematic views showing liquid crystal display cracks 71 a to 71C in accordance with the present invention. The liquid crystal display devices 71A to 71C may have a structure in which a polarizing plate is disposed outside the liquid crystal cell. However, by arranging a polarizing plate and a phase difference plate of the present invention in the cell, crosstalk of the 3D display can be reduced. The so-called crosstalk refers to the current image of the 2012 20120806 image, which is caused by the color mixture of the right eye and the image for the left eye. Fig. 7 is a view showing the configuration of the liquid crystal display device display device 71A according to the present invention from the side of the backlight 72. The liquid crystal contains: a polarizing plate 73, a well-known phase difference plate 74, and a substrate; 5 is a double-sided, sequentially sequential crystal layer 77, a front transparent electrode 78, a filter 79 (but H electrode 76, liquid), and a polarizing plate. 82. The phase difference plate 8 of the present invention is 81° to the substrate. FIG. 8 is a schematic diagram showing a display device 71B for displaying a liquid crystal display device according to the present invention from the side of the backlight 72 (also referred to as a backlight, a polarizing plate 73, a known phase). The difference plate 74, the substrate 75, the back surface electrode 77, the front transparent electrode 78, the polarizing plate 82, the phase of the present invention: = 79 (however, the filter is not absolutely necessary), and the substrate 81. Figure 9 is a view showing the structure of the liquid crystal display device display device 1 according to the present invention (the money plate, the light plate 73, the well-known retardation plate 74, the substrate 75, the back surface electrode 77, the front transparent electrode 78, the polarizing plate 82. The filter 7 is absolutely necessary), the phase difference plate 80 of the present invention, and the substrate 81. Others. The following is a detailed description of the present invention by the actual compensation, the present invention. In addition, in the examples, "%" and "parts" refer to mass% and mass parts unless otherwise specified. <Reference Example 1>

DHPJ

K2CQ3. Df shape. 〇όΚ12-0.

乙乙昆气 cmT ρ-〇5Η12-〇—(

HCI THF ~ 〇 - 〇 η According to the method described in Japanese Patent Laid-Open Publication No. 2004-262884, p-benzoic acid and dihydrogen are used. Reaction with mer to give compound a. The obtained compound a50.1 g, potassium carbonate 97.1 g, 6-bromohexanol 46.7 g, and 101 201202806, 17Ρ were mixed. Under a nitrogen atmosphere, the resulting mixture = reaction at 90 C, and then reacted at iG (rc). The resulting counter-mixing chamber 2 was added with pure water and methyl isobutyl ketone in the reaction mixture, and was stirred. The ί liquid is an organic layer and an aqueous layer. The obtained organic layer is washed with sodium hydroxide water and pure water to dehydrate the washed organic layer, and then the alcohol is added to the miscellaneous impurities, and the precipitate is precipitated by filtration. The precipitate was taken out, and the precipitate was taken out by vacuum drying to obtain a compound % (6----hexane alcohol base). (4) g-bearing. dimethyl, 3, benzene-parametric butyl- 4~ L4〇g, soil amine 16.7g, and 1 '3-dimercapto-2-imidazolidinone 1〇〇g were dissolved in 600g of air. The resulting solution was cooled in ice water' and dropped in a nitrogen atmosphere. 58.1 g of helium gas was introduced and allowed to react at room temperature. Pure water was added to the obtained reaction mixture and stirred. The organic layer was separated from the aqueous layer, and the obtained organic layer was aqueous hydrochloric acid, saturated aqueous sodium carbonate, and Wash with pure water. Dry the washed organic layer?: 3 ' 5-di-parametric butyl- 4-based hydrazine benzene g, and concentrated moxibustion to give compound c. After mixing compound c with 200 mL of tetrahydrofuran, add tetrahydrofuran 20 μL. After adding hydrochloric acid to the obtained solution, it was reacted at 60 C under a nitrogen atmosphere. To the obtained reaction mixture, 5 mL of a saturated saline solution was added and stirred, and the mixture was separated into an organic layer and an aqueous layer. After the obtained organic layer was dried, hexane was added, and the mixture was cooled and stirred in ice water. The precipitated solid was taken out by filtration, and the solid which was taken out was vacuum-dried to give compound d90g. Yield: 79% (Compound c basis) HOOC-

COOH

Ph-CHs-Cl, ΚΙ K2C03

Yi'-(^y^〇〇〇H ^}··〇ε〇ΟΗ (0 cich2och2ch3 NEt3 〇- o 〇-

H2i Pd/C HOOO (h) 102 (0 201202806 will be a mixture of trans-1,4~cyclohexanedicarboxylic acid 2〇〇g and N,-lOOOOmL. Under nitrogen atmosphere, one side methyl monoethylammonium so^ c 139.7g of deuterated chlorine, the obtained solution is placed at 12 (rc followed by ^, then added T to set the reaction solution to cold (four) room temperature read reaction. Mix. Take the resulting crystal by i«. Wash and wash with water, then wash with water. Will, gentry straight *= ',,, with water sterol 3: 2 (v / v) powder 25lg. 1_真工(9)' and the steel containing compound _ The 251 g of the mixture was mixed with the age of 6 。. The bath was cooled in ice water, 93.5 g in nitrogen ring and 146.8 g in triethylamine. The reaction was allowed to react for a small time. Toluene was added to the reaction solution. =3, the three clever, salt. The filtrate obtained is washed with water = made by I steel. The crude scales obtained by the (four) age to the sodium after the sodium is vacuum dried, _=== a Liquid 242 § and tetrahydroanthracene containing compound (g). South 250 mL f port. Add 5 〇%^.〇g to the obtained solution under nitrogen atmosphere. After decompression, hydrogen substitution is carried out at room temperature. , often stir the resulting solution 6 small The reaction is carried out. Substituting nitrogen: The solution is over-treated, (10) the catalyst and solvent are removed, and the silk is dissolved in chloroform, and the gas-like solution of = is concentrated under reduced pressure, and helium is added to crystallize it. ^ f Τί Γΐ:: The compound was obtained (驿^ 化 反 反 反 1 1 1 1 1 1 39 39 39 39 39 39 39 39 39 39 39 39

p-CgH^-O—^ QH 0'

mCO〇CH2〇CH2CH3 HIOOCi

_cooch2och2ch3 p-CqH-(2-〇-^~~~c ο

...COOH e,

/〇—CeHu—Ο—<〉—丨Ο _ I 103 201202806 The chemical substance s ton, N,N-dimethylamine group ♦ 2, trans-i, the production will be - 150 g of Λ and 300 mL of chloroform were mixed. Stir in a nitrogen ring ice water, and drop a solution of dicyclohexyl / shout. After the completion of the drip, in the = liquid, add chloroform 2GG chaos and g-burning, and sputum recovery, washed with hydrazine, aqueous hydrochloric acid. After separating the insoluble components from /1································································ 0g, pure water 3.64g, a pair of stupid stone, wind and water, and 3 84g, =虱2侃, 1 Kunhe. The resulting mixture was allowed to overflow to the soil under nitrogen. After the mixture was allowed to stand to cool to room temperature, tetrahydropyran was removed and 62 〇〇 mL of heptane was added to the residue. The precipitated sedimentation hall was taken out, and washed with water, and then vacuum dried. The obtained powder was dissolved in chloroform and filtered for filtration. The time-tested and simplified in the age of the rainbow, the resulting solution was concentrated, and toluene was added. The solution was concentrated under reduced pressure to crystallize, and the obtained powder was taken out and dried in vacuo to give a compound e64.1 g. The yield is 76 〇/〇 based on compound d.

.V <Synthesis of Compound (All-1)> -^ OMe

-COOH

(All-1) 104 201202806 <Synthesis of 4,6-dimercaptobenzofuran> ΐ 3,5: 25 g of dimethyl group was dissolved in 150.0 g of N,N-dimercaptoacetic acid amine. After the solution was cooled by ice, 9 82 g of sodium hydroxide was added. The mixture was stirred at room temperature for 1 hour, and 25.49 g of chloroacetaldehyde didecyl acetal was added dropwise. At 1〇〇. The mixture was stirred for 2 hours, and the reaction solution was added to 1000 mL of water and hydrazine isobutyl ketone 4 Torr. The organic layer was recovered. The organic layer was washed twice with 500 mL of a 1 N-hydrogenated steel solution, and washed with 800 mL of pure water. After the organic layer was used, the water was sulfuric acid, and concentrated under reduced pressure in a steamed crane H to give a light, -,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ^Into the two solutions, a light red viscous liquid was added and dissolved in toluene 1 mLL, small, and then cooled to room temperature. Wash with 1N-sodium bicarbonate solution 2 times &amp; Wei = pure water 5 〇〇 mL. The organic phase was taken up and dehydrated with anhydrous sodium sulphate (4) and concentrated in vacuo to give a pale red liquid of 4, dimethyl benzoate 16.3⁄4. Yield. Phenol per base #55.%, ,: · T ^ &lt; 2 diir-4 '6-dimethylbenzene (tetra) extraction synthesis> '4^6-dimethylbenzoin 21 The kiss dissolves in n, n, - after the solution f is cooled, the human oxime - 2' is dropped in the WC after the chamber is titen. The reaction solution was placed in the crotch to the temperature to add 1 liter of pure water and neutralized with a small naphthalate. After the pH was adjusted to δ, I = recovered, and 2.6 g of activated carbon was added and used. The organic layer is finely dissolved in chloroform, and fine ^=(2) S is dry to produce 4,6~dimercaptobenzene on the second; this; the synthesis of the slow acid is one of the following > 2 - run a 4 '6 - 2 A: μ: #, '丄丄 mixed with i pure water. By methane 19 = sulfuric acid 13 qing, potassium hydroxide 25g, and = 5 two. Add 曱 肘 elbow TM to 12 in the liquid. Dispense it and collect 10.5 201202806 water layer, then wash the water layer with 200mL. The aqueous layer was recovered, and the pH was adjusted to 2 with 2n-hydrochloric acid, followed by the addition of 4 mL of toluene and liquid separation. The organic g recovered L is dehydrated with anhydrous sodium sulfate, concentrated under reduced pressure in a distiller, and subjected to air drying to obtain 4' 6-trimethylbenzene hydrazine - 2 - _ Μ % of yellow / color powder. The yield was 67% based on 2-aldehyde- 4,6-dimercaptobenzofuran. Synthesis of <4,6-Dimercaptobenzofuran-2-carboxylic acid

ΌΗ ΌΗΟ

COOEt

^ Xpc/-c〇〇H 八-二曱基15Qg, pair of 23G.lg, anhydrous magnesium chloride 175.4g knife guess 900mL towel. After mixing 3 ounces with chills, 474 g of tritonin was dropped into it over two hours. The mixture was allowed to react under a water bath for 8 hours and at room temperature for 14 hours. To the reaction liquid, 15 N of cold NN-hydrochloric acid was added, and i was subjected to liquid separation of 't acetic acid'. Then, the water layer was separated by sputum! The organic layer is recovered and is dehydrated with the previous organic layer, strontium sulphate, in a steamer. Adding 3g of activated carbon and 20g of Shixi gum to the residue & 〇Bade, and straightening the knife at room temperature. The filtrate was recovered and concentrated under reduced pressure in a steamer. Yield N,~&quot; Ester 5ΩΠ&amp;,,#λ甘士 C, the cost of 1 hour will be bromoacetate B

However, after the chamber was added, the compound was reacted at 8 〇t: for 4 hours. The reaction solution was allowed to cool so that the pot was I butyl hydrazine with 4 〇〇 mL ' to cool 1 N - 1000 mL of hydrochloric acid and there was ^ back. . The organic layer was washed 3 times with 1 G (K) mL of pure water, = finely added = 鹤 = 净 = net twice, and after the pH was 12 or more, the water layer was adjusted to 3 with toluene washing. The ^ 106 201202806 ίΐ is dried, and the 4,6-dimercaptobenzene is obtained and the carboxylic acid grade lg is yellow. The yield is based on 4,6-dimethyl salicaldehyde. , <Synthesis Example of Compound (11 ~ a)>, 2' 5-Methoxyaniline n.49g, 4,6-Dimethylbenzinc) η-Lianethylamine 7.59g, n 'N ,-Dimethylaminopyridine kiss: ^ ^ Methyl ethylamine 1嶋g mixed. The resulting solution was dissolved in an ice bath, 34.85 g of the B0P reagent, and allowed to react at room temperature for an hour. The read mixture was mixed with a mixed solution (water: methanol volume ratio 1). Crystallization was carried out. The lions that were riding were filtered out, and the mixture was washed with vacuum powder (=. sterol volume ratio of 3:2) and vacuum dried to obtain a light yellow powder of compound =2 = .3⁄4. The yield is based on 2,5-dimethoxyaniline (synthesis of <Compound (11-b)> 16.0 g of compound (11-a), 2,4-bis(4-methoxyl) Phenylbub 3 - 2 'hetero-2, '4 - di (ph〇sphetaBe)-2,4 - disulfide (lawson? toluene_mixed, the resulting mixture is warmed up, in cold touch it will Concentrated to obtain a red adhesive body, which is mainly composed of a compound (11-b) and a decomposition product of Lawson's reagent. Red <Compound Example of Compound (11-c)> First, the mixture of the compound (11-b) obtained by the project, hydrogen peroxide, .8g, and 250g of water are mixed', and the resulting mixture is cooled under ice water.

Iii, but add τ, containing potassium ferricyanide 44.i7g, under water-soluble J for 12 hours, and take out the deposited yellow sputum and take it out and wash it with water, then wash it with hexane, and Toluene gave a solid earth color solid of 4. lg. The yield is 2 = <Synthesis Example of Compound (11-d) based on the compound (n_a). (1^_§ and chlorinated _, mixed, and heated to (10) C, 3 hours. The resulting mixture Add in ice, take out the two places. After washing with water, wash with benzene, and vacuum machine to ^ 107 201202806 compound (11-d) as the main component of the loess color solid 3.4g. (η - c) is 93% of the standard. σ < Synthesis Example of Compound (All-1)> Compound (ll-d) 3.00 g, compound (e) 8.47 g, N,N-didecylamino group. 0.12 g of a mixture, and 40 mL of a gas-like mixture. Under the cooling of ice water, 2.92 g of N,N-isopropylcarbenol was added to the obtained mixture. The resulting reaction solution was allowed to stand at room temperature. After the reaction was filtered overnight, the mixture was filtered under reduced pressure, and then concentrated under reduced pressure. Methanol was added to the residue to crystallize the crystals. The crystals were filtered, taken out, dissolved in chloroform, and added with 3 g of activated carbon in the chamber. Stir at room temperature for one hour. Filter the solution, 'The filtrate was concentrated to 1/3 under reduced pressure in a steam evaporator, and then added with decyl alcohol while stirring. The precipitate was taken out by filtration, washed with heptane and dried under vacuum to give 7.60 g of a white powder of the compound (All-1). The yield was 71% of the compound of the compound. '1H of the compound (A11-1) NMR (CDCL3): 3〇PPmn, 45~U5(m, 24H), 2.36~2.87(m '18H), 3.93~3,97(.t,4H), 4.15~4 20(t, 4H), 5.79 ~5.84(dd ' 2H), 6.07~6.17(m,2H), 6.37~6'45(m,2H), 6.87~7.01(m '9H), 7_20(s '1H), 7.23(s, 2H), 7.53 (s, 1H) The phase transition temperature of the obtained compound was confirmed by the observation of the structure of the polarizing microscope. When the compound was heated, the intermediate phase having high viscosity was exhibited from the second. However, a clear nematic liquid crystal phase is present above 13rt. The nematic liquid phase has a crystal phase of 18 Å. At the time of cooling, the nematic liquid crystal phase is present until the machine is reached and the compound is still present. Production Example of X-a) The compound (xa) was synthesized by the following method, and was synthesized in the same manner as the method described in [· Chem SqC, p Tmns.l, 205-210 (2000). : that is, as described above In the process, except that the base chlorine is changed to the pheno- an anabase gas, the same method is used for the synthesis. Then, the compound (χ-a) and the compound (x-d) are 2〇〇g and gasified. L〇〇.Og (5 times mass) was mixed, and the resulting mixture was heated to 22 Torr. After the mixture was cooled, the water was added, and the obtained semen was filtered, and washed with water and heptane, and a solid of 17.4 g as a main component. The yield is the compound (x H|N H3CCt-^-〇〇Hi3

H3C

Xa <Synthesis Example of Compound (x-1)> The same method as the synthesis example of the compound (All-1), that is, the same method except that the compound (11-d) is changed to the compound (x-a) , the compound (X-1) is obtained. The yield was 84 Å/〇 based on the compound (X~a). 1H -> iMR (CDCl3) of the compound (X-1): δ (ΡΡιη) 1.43 to U3 (m, 24H), 2.29 to 2.82 (m ' 12H), 3.92 to 3.97 (t, 4H), 4.15 to 4 20( t, 4H), 5.80 to 5.84 (dd, 2H), 6.07 to 6.18 (m, _, 6.37 to 6.44 (m, '8H)' 7.12 (d 1,1H)-, 7.18 (s, 2H), 7.5_, 1H), 7.63 (dd, 1H) 3 The obtained compound transfer temperature was confirmed by a microstructure observation by a polarizing microscope. When the compound (x-1) was heated, it was in a frequency-series liquid crystal phase from 1 〇 1 M 1 〇 61: from 1%. (: to the following. (: When the temperature is lowered to the above, the nematic liquid crystal phase is crystallized until 81.] <Example of manufacturing of phase difference plate> Example 1 Coating of polyethylene on a glass substrate Lin (poly 6 瞒 2 ft 〇 / 〇 7Wt 5 degree 89mn film. Then, on the surface of the obtained film, the first step of the treatment is using a semi-automatic friction device (trade name is manufactured by Gongxue Co., Ltd.) ), by cloth (trade name: ΥΑ 〇 〇 1, 1, 1, 1, 1, 阮 阮 阮 司 司 ) ) ) ) 司 司 司 司 以 以 以 以 以 以 l l l l l l l l l l l l l l l l l l 。 。 。 〇0ipm, the width of the line of the micrometer (4) 遮 shown in the mask, from the relative ^Mo = 109 201202806

The conditions of the second county treatment were changed to the press-in amount 〇1. The rest of the conditions were the same as in the first embodiment, and a phase difference plate was formed on the glass substrate at 500 rpm and 8.35 mm/s. [Table 2]

Thousands and miles. , R from .Pu &gt; people... Therefore, the number of polymerization starters: irgaCure 819 (made by Ciba SpeCialty ChemiCals Co., Ltd.) Leveling agent: BYK361N (manufactured by BYK JapanKK) &lt;Measurement of optical characteristics&gt; The measurement of the phase difference 腿 (leg) and the aligning angle was performed by a measuring machine (K〇BRA — ^, manufactured by Prince Seiki Co., Ltd.) without peeling off the glass-based phase difference plate. Since the glass substrate is hardly folded, the measurement is performed without peeling off, and the phase difference 値 of the phase difference plate produced can be obtained. As a result of the measurement of the phase difference, it is found that the region 12 and the region 13 are regions in which the direction of the phase delay axis is different, and the phase retardation axis of the region and the delay axis of the region 13 are slightly smaller. . The phase difference 値 at wavelengths of 451 nm, 549 nm, and 628 nm is shown in Table 3. No 201202806 In addition, [Re(451)/Re(549] [Re(628)/Re(549)] (referred to as β) is calculated from the 値 of the phase difference '. ', ,, and the alignment angle Re (451) Re(549) Re(628) a β (nm) (nm) (nm) r Example 1 Region 13 0.08〇146.6 174.2 177.9 ~~ —~~-— 0.842 1 HOI Region 12 87.38° 143.3 168.7 172.2 0.849 - —---- Example 2 Area 13 -0.23° 135.8 156.2 159.5 1.021 0.869 1 n?i Area 12 88.37° 133.6 154.5 154.5 0.865 1 I— 1.038 Film thickness was measured by a laser microscope (LEXT3000) manufactured by 0LYMPUS Measurement of (nm) and line width (μπι). The line width was measured by a measuring machine under the condition that the phase difference plate fabricated on the glass substrate was not peeled off. The film thickness was measured [Table 4] ^ Under the condition of the -part_ of the phase difference plate, the measurement is performed by measuring the step difference. • Line width (nm) 268.1 Film thickness (μηι) ΰΕ. 13 - Area 12 279.2 - Area 13 279.9 __2 .3 ----- ? A area 12 272.2 ---- ? 7~ 歹1j 1~3 ~~-_ - Example 1 Example 2 &lt;Production Example of Phase Difference Plate&gt; On Glass Substrate (EAGLE2) 000, Pinggang Special Confirmation Co., Ltd., and the same method as in Example 1, apply the alignment film and perform the first rubbing treatment. The surface on which the first rubbing treatment is applied, except that the surface shown in Fig. 10 is used. I has ίί _ _ 纽 (plate thickness: 11 (four) instead of the iron steel dream ο Γ = line saw pattern shown in Figure 1 and the same as in the first embodiment, except C 2 2 m, After the removal of the upper board, the composition described in Table 5 was applied by the coating method, and heated to the / degree of the table 2 to obtain the single-area. Unpolymerized phase difference plate. ^The ultraviolet ray was irradiated at the temperature of the carrier, and the ultraviolet ray was _2 1]1 201202806 as shown in Table 6. Thus, a phase difference plate was fabricated on the glass substrate. A schematic diagram is shown in Fig. 11. [Table 5] Compound (A) (%) Liquid crystal compound (%) Polymerization initiator (%) Leveling agent (%) Solvent (%) Composition 1 All - 1 (28.01) — IrgaCure 369 (1.96) BYK361N (0.03) Cyclopentanone (70 fine composition 2 All-1 (22.43) x-1 (5.61) IrgaCure 369 (1·96) BYK361N (0.03) Cyclopentanone (69.9) 8) Composition 3 All-1 (11.68) b (1L68) IrgaCure 369 (1.96) BYK361N (0.02) Cyclopentanone (74.98) Composition 4 — b (29.12) IrgaCure 907 (0.87) BYK361N (0.03) Cyclopentane _ (69.97) Table 5 shows the content ratio (% by mass) of each component constituting the components 1 to 4 with respect to each component of the composition. Liquid crystal compound b: Polyocolor LC242 (manufactured by BASF Corporation) (compound represented by the following formula) Polymerization initiator: *1) : IrgaCure 369 (manufactured by Ciba Japan Co., Ltd.) (acetophenone compound) Film thickness (μιη) Drying temperature after coating Temperature accumulated light amount (mJ/cm2) at the time of ultraviolet irradiation Example 3 Composition 1 2.5 170 ° C uo ° c 2400 Example 4 Composition 2 2.4 145 〇 C 90 ° C 2400 Example 5 Composition 2 2.1 145 〇 C 90 ° C 2400 Comparative Example 1 Composition 3 1.8 110 ° c 90 ° C 2400 Comparative Example 2 Composition 4 1.0 I 45 ° c Room temperature 2400 Comparative Example 3 Composition 4 0.89 45 ° C Room temperature 2400 *2): IrgaCure9〇7 (manufactured by Ciba Japan Co., Ltd.) (acetophenone compound) Leveling agent: BYK361N (manufactured by BYK Japan KK) [Table 6] &lt;Measurement of optical characteristics&gt; The phase difference plate produced was the same as the example In the same way, the measurement of the phase 112 201202806 rnn (rnn) and the alignment angle was performed. The result of the measurement of the phase difference 显示 shows that the region 15 shown in Fig. η differs from the region 16 in the direction of the phase delay axis, and the phase delay axis of the region 15 forms an angle of 90 with the phase delay axis of the region 16. . Further, the phase difference 値 at wavelengths of 451 nm, 549 nm, and 628 nm is shown in Table 7. Further, from the 相位 of the phase difference α, α) and [Re(628)/Re(549)] (referred to as β) are calculated. , 乂, claws [Table 7]

&lt;Production of a circular polarizing plate&gt; Glass substrate (EAGLE2000's Hiraoka Special Nitrogen Manufacturing Co., Ltd. (the riding surface is completely 4, and the pharmaceutical industry shares are processed on the same side. The friction processing system uses semi-self-Ϊτ ^JA〇) ; 2Q-RW, manufactured by Yoshikawa Chemical Co., Ltd.) in the lower rotation (i) surface, the number of revolutions is 5 GG rpm, i6.7 mm / s. Then, the composition described in Table 5 of the upturn 1 is coated and rubbed. The heat treatment of the surface hardening of the treatment was carried out to obtain a coating film of a single region, and the thickness of the core i was the film thickness described in the table. Thereafter, the ultraviolet rays were cut in Table 6 (sp-7' USHI◦ Electric Co., Ltd. This is shown in Table 6. Thus, the phase difference plate 92 was obtained on the glass substrate. The ^113 201202806 difference plate 92 and the polarizing plate 93 (polyethylene glycol layer: jqjraj^ayrpovaL film, sheet TAC product, Sumitomo Chemical Co., Ltd. is laminated so that the phase retardation axis forms an angle of 45 degrees with the right or left direction of the absorption axis, and a circular polarizing plate 94 is produced. &lt;Device for evaluating color reproducibility&gt; No.: DRU-1515, manufactured by SIGMAKOKI) Set the LCD panel ( No.: N220W 'manufactured by HYUNDAI), the phase difference plate 14 of the present invention is bonded to a part of the surface of the liquid crystal panel such that the surface of the composition layer on the phase difference plate μ faces the one side of the liquid crystal panel. In addition to the portion where the phase difference plate 14 is bonded, the black paper is shielded from light. In addition, a spectroradiometer (model: SR-3A, manufactured by TOPCON Co., Ltd.) is placed, and the front end of the lens barrel of the spectroradiometer is located. A circularly polarizing plate 94 is attached to the front end portion from a position at a distance of 35 cm in the vertical direction from the surface of the phase difference plate 14. Further, the polarizing plate 91, the phase difference plate 14, and the circular polarizing plate 94 in the liquid crystal panel are provided. The circular polarizing plate 94 is a circularly polarizing plate obtained from the following composition, that is, used in the production of the phase difference plate 14 mounted on the liquid crystal pulling plate, as shown in Fig. 12 and Fig. 13. The same composition of the composition. The angle formed by the absorption axis 91A of the polarizing plate 91 in the liquid crystal panel and the phase retardation axis 15A of the region 15 of the phase difference plate 14 is slightly 45. The absorption axis 91A and the phase difference plate are formed. Phase delay of region 16 of 14 The angle formed by the shaft 16A is also slightly 45. The angle formed by the absorption axis 91A of the polarizing plate 91 in the liquid crystal panel and the absorption axis 93A of the polarizing plate 93 of the circularly polarizing plate 94 is slightly 90, and the phase difference plate 14 is formed. The phase delay axis 16A of the region 16 is slightly parallel to the phase delay axis of the phase difference plate 92 of the circularly polarizing plate 94. The spectroradiometer is connected to a personal computer through an RS-232C cable, and the color measurement software in the computer is used. (CS-900, manufactured by TOPCON TECHNOHOUSE Co., Ltd.) The measurement results of the spectroradiometer are output. &lt;Observation of Direction of Phase Delay Axis&gt; In the above device, white is displayed on the entire surface of the liquid crystal panel (γ = 71_93cd · m_2, x = 〇.3 (U, y = 0.283), from the spectroradiometer The liquid helium panel was observed on the side. The thermal theory was the phase difference plate of Example 3 or 4, and black was observed corresponding to the region 15 of the 201202806 phase difference plate, and white was observed corresponding to the region 16. When the phase retardation axis of the phase difference plate 14 of the liquid crystal panel and the phase retardation axis of the phase difference plate 92 of the circularly polarizing plate 94 are parallel, white is observed, and if it is mounted on the phase difference plate 14 of the liquid crystal panel. When the phase retardation axis is perpendicular to the phase retardation axis of the phase difference plate 92 of the circularly polarizing plate 94, the viewer is rushed to the inside. $ &lt; color reproducibility evaluation&gt; In the above arrangement, the measurement pass region 16 The spectral distribution of the light incident on the spectroradiometer. The radiation intensity at each wavelength when the spectroscopic blade in the state in which the phase difference plate and the circularly polarizing plate are not disposed is used as the reference radiation intensity (100%) Ratio is different. The higher the radiation intensity ratio, The less the loss of light emitted from the liquid crystal panel, the higher the color reproducibility of the image displayed on the liquid crystal panel. The results are shown in Table 8. ' [Table 8] Color έ total 4 green area, 450 nm 470 nm 49〇nm 525nm 545mn 565nm 590nm Onm Example 3 87.4% 89.6% 91.4% 96.8% 98.4% 100% 99.7% 100% QQ 实施 Example 4 76.6% 79.2% 85.3% 92.2% 94.5%&quot; 95.7% 99.9% 100% Yy. i /〇1 〇〇〇/n Comparative Example 1 61.3% 69.6% 80.8% 90.9% 95.0% 94.6% 100% 100% 1 00% Comparative Example 2 60.3% 72.1% 83.7% 91.8% 97.4%j _96.2 °/〇100% 100% 98.7% Example 5 and Comparative Example 3 &lt;Device for measuring luminance&gt; In the same manner as the device for evaluating color reproducibility, the phase difference plate 14 was bonded to the liquid crystal panel. Model: BM—5A, light source: f—1〇, T〇pc〇N (manufactured by the company), so that the front end of the lens barrel of the color dimension meter is located at the position of the phase difference plate M = in the vertical direction. A circular polarizing plate 94 is disposed at the bribe end portion such that the side of the polarizing plate 92 of the circular polarizing plate 94+ faces the side of the color luminance meter. The circular polarizing plate 94 is used to A circularly polarizing plate obtained from the following composition, i.e., the same composition as that of the surface of the liquid panel of the liquid crystal panel, was produced. 315 201202806 The color luminance meter and the internal memory are stored by the RS~232C cable (Harve s is connected to the measurement result of the sub-use. p,Ha朦Lab•manufacturing) Color luminance meter &lt;Measurement method of luminance> On the full surface of the above liquid crystal display device, 0.301 ^ y = 0.283) 〇 day color (Y-71.9, X- 卞 plate 94 is rotated by 1 degree to 1 degree, so that the color brightness is seen on the light plate 94. The direction of rotation, from the color luminance meter to the LCD panel, sees the past as 'counterclockwise direction. The outside of the luminance of the area 15 (unit: m) is not shown in the table ^. The lower the luminance Yb, the more vivid the display can be judged Black / L : the luminance % of the inner region 15 and the luminance Yw of the region 16 (unit: cd / m ), and the luminance Yw is divided by the luminance Yb (Yw / Yb). Yw / Yb is large, then It is judged that the image observed in the area is more distinct from the g image observed in the area 16, and the crosstalk can be reduced when used in the 3D display device. The luminance Yb and YW are based on the c... 1931 chromaticity seat. Rod.... [Table 9]

Rotation angle [degrees] In the apparatus for evaluating color reproducibility, the polarizing plate 91, the phase difference plate 14, and the circularly polarizing plate 96 are disposed in the same manner as described above with reference to Figs. 14 and 15 in the same manner as described above. The observation of the direction of the phase delay axis. The angle formed by the absorption axis 91A of the polarizing plate 91 in the liquid crystal panel and the phase retardation axis 15A of the region 15 of the phase difference plate 14 is slightly 45. The phase retardation axis 16A of the absorption axis 91A and the region 16 of the phase difference plate 14 and the angle formed are also slightly 116 201202806 45°. The angle formed by the absorption axis 9丨a of the polarizing plate 91 in the liquid crystal panel and the absorption axis 93A of the circular polarizing plate % plate 93 is slightly 9 〇. The angle formed by the phase retardation axis 16A of the phase difference plate i4 field 16 and the phase axis 95A of the phase difference plate % of the circular polarizing plate % is slightly 9 〇. . As a result, a white color is observed corresponding to the region 15 in the phase difference plate 14, and the luminance Yw is measured in the region 15 in accordance with the method of the same color as described above, and the luminance Yw in the region 15 is measured (unit: cd/ M2) and the region π ed / m2) ' and calculate the luminance Yw divided by the luminance milk, Yw, chromaticity coordinates. [Table 10] rotation angle: "degree 1 廑 廑 Yh^ 40 1.17 30 — _ ——__ 1.14 20 1.08 ~~~ 10 0.980 0 — 0.807 -10 1.03 -20 0.988 -30 0.898 -40 1.08 From the phase difference plate of Examples 1 and 2 Example 5

Yw, /Yb, 72.9 74.9 79.1 86.5 104 82.1 85.2 93.9 78.3 The thickness of the two is almost equal, indicating [Δη(450)/ F θ 'ΧΤ ° 5 ^»^^^[Re(628)/Re(549) ] ^ 1 △ n (55 〇 n ^ Af and 13 film thickness is almost equal, said (four) 650) i sub-I M ^ is on the field. That is, the phase difference plate of the present invention exhibits a reverse wavelength characteristic &amp; If the slave is used in a liquid crystal panel, it has an excellent optical compensation ratio. The phase difference plate of ^ and J shows a high radiation intensity at a wide range of wavelengths. The light emitted by the second light is not easily reduced by the phase difference plate mounted on the liquid crystal panel, and its color reproducibility is high. That is, since the phase difference plate 217 201202806 of the present invention has a different phase of the phase delay axis, and it can perform uniform polarization conversion in a wide range, it is particularly suitable for use in 31) display devices. Because 'WYb is big, it can be expected to reduce the crosstalk when used. Further, since the change in Yw/Yb is small even if the angle is changed, the angle dependency is also small. &amp;More Angles Industrial Applicability and a plurality of regions in which the direction of the phase delay axis is different, and uniform polarization conversion is performed. In addition, it is possible to display a semi-transmissive liquid crystal display that can display an excellent image by the present invention. [Simplified description of the drawing] A schematic view of the fresh 1 which is fine when _ is formed. Outlined. The original hair obtained by the esoteric _ her poor π map. Fig. 3 is a schematic view showing the liquid crystal display device 51 of the present invention, which is a schematic view of a transflective liquid crystal display device 3A according to the present invention. A schematic display device other than the liquid crystal display device of the present invention, FIG. 7 shows a liquid crystal display device according to the invention of the liquid crystal display device according to the present invention:: = system is not known, this The liquid crystal display device 7 of the present invention shows: the formation of the film into the film: the phase difference plate of the present invention obtained when the mask of Fig. 10 is used. Fig. 12 shows the portion of the evaluation device in the embodiment of the present invention. Figure. 118 201202806 FIG. 13 is a diagram showing evaluation conditions in an embodiment of the present invention. Figure 14 is a diagram showing a portion of an evaluation device in an embodiment of the present invention. Figure 15 is a diagram showing evaluation conditions in an embodiment of the present invention. 16(8) to (e) are schematic views of the phase difference plate 1A of the present invention. [Description of main component symbols] 1. 3 to 3, friction mask base material 2, 4 to friction mask gap portions 11, 14, 40, 56, 64, 80, 100 to phase difference plates 13, 15 to 1 of the present invention The phase retardation axes 16A and 31B of the phase retardation axes 16A to 16 of the rubbing processing regions 12 and 16 to the second rubbing processing regions 15A to 15 are transferred to the semi-transmissive liquid crystal display devices 32'52 and 72 to the backlight. 33, 42 53, 55, 63, 73, 82, 93 to polarizing plates 34 and 74 to a known retardation plate 35, 4, 75, 81 to a substrate 36 to 32A to a back surface reflective electrode portion 36B to a back transparent electrode portion 37 77 to liquid crystal layer 38, '78 to front transparent electrode 39, 79 to filter 43 to back electrode 51 to liquid crystal display device 54 to liquid crystal cell 61 to flat panel display device 62 other than liquid crystal display device to conventional flat panel display device 71A, 71B, 71C to liquid crystal display device 119 201202806 76 to back electrode 91 to the polarizing plate 91A in the liquid crystal panel to the phase of the absorption axis 92, 95 to the phase difference plate 92A to the phase difference plate 92 of the polarizing plate 91 in the liquid crystal panel The absorption axes 94, 96 of the retardation shaft 93A to the polarizing plate 93 are 95A~ phase retardation plate 95 polarizing plate retardation axis

100A~ Area A

100B~area B 120

Claims (1)

201202806 VII. Patent application scope: 1. A phase difference plate having a plurality of phases and satisfying the formula (1) and the formula (2) : , / I' in the direction of the neck A ^ axis regardless of the area-area towel Birefringence Δη(λ) Δη(450) ΧΔη(550) ΐ.οο (1) 1.00^Δη(650)χΔη(550) (2). For example, in the phase difference plate of the scope of the patent application, the = group and at least one polymerizable group are polymerized and (A) -G1 - D1 - Ar - D2 - G2 - Ϊ / Ϊ ring and aromatic The group consisting of a group of heterocyclic rings = 12 ^ ~ ° -c 〇 - ' - S) - ' ~ CR R2 - &gt; pp3D4 - CR3lR: -, -CRlR2-〇- CO—CRV—, —CRl 2 TO _ CR R—Cal—CR2R3—,—CIUnrL—shows a hydrogen atom, Rar4 independently represents the filament of f 4 ; Gl and G2 are independent of each other 垸Ϊ ΪΪ = '1_ It may have one or more substituents selected from the group consisting of a dentate atom and a carbon number of 4 2 groups f, and more than one fluorenylene group may be substituted with -〇-, -sH趟: and at least one polymerization. The compound of the group is the following formula (D; the D meaning G of the term 1) and the G system and the PF range PF such as -Al) rEl-Gl-Dl~Ar~D2-G2 —E24a2~B2^_F2__p2 121 201202806 E1 and E2 are independent of each other—cr5r6. -CH2-CH2---〇—, -S co-o- 一〇一c〇---O-CO-O---σ ==ς, —〇—,_〇_C(=s)---〇_C(=S)-〇——CO-NR5-. -NR5-CO---〇-CH2- -CH2 - 〇---S-CH2___: fluorine atom, 03⁄4-S-, or single bond; R5 and R6 independently represent a hydrogen atom, 2 or a carbon number of 1 to 4; B1 and B2 are independently represented —CR5R6---CH2-CH2___〇S) —s co-o---o-co---o-co-o---c(- -〇〇_C(=S)---0 -C(=S)-0 -CO-NR5-, -NR -CO---〇-CH2-, -CH2-〇---S-CH2___ CH2—f —, 2 or a single bond; R5 and R6 It means the same meaning as described above; A1 and A2 each independently represent a divalent alicyclic hydrocarbon group or a divalent aromatic group. The divalent alicyclic hydrocarbon group and the divalent aromatic hydrocarbon group may have _ Atom: an alkyl group having 1 to 4 carbon atoms, a fluorine-substituted alkyl group having a carbon number of i to 4, an alkoxy group having a carbon number of 丨4, a fluorine dog mirroroxy group having a carbon number of 1 to 4, a cyano group, and a nitrate Substituents of the base = 1 or more substituents; k and 1 each independently represent an integer of 〇 〜 3; F1 and F2 respectively represent an alkylene group having a carbon number of 丨 12, and the alkylene group may have carbon The alkyl group of 1 to 5, the alkoxy group of the carbon number 5, and the one or more substituents selected from the group of the atomic atoms, the CH2~ contained in the alkylene group may be substituted for A 0- or a CO-; P1 and P2 each independently represent a hydrogen atom or a polymerizable group (however, at least one of pi and P2 is a polymerizable group). 4. The phase difference plate according to item 3 of the patent application, wherein the compound represented by the formula (D) is a compound satisfying the formula (3) and the formula (4): (Νπ—4)/3 &lt;k+l + 4 (3) 12^Νπ^22 (4). 5. For the phase difference plate of claim 2 or 3, the shot is expressed by the following formula (Ar ~ 6): 122 201202806 (Αγ·6) (In the formula, Ζ1 independently represents a halogen atom, a carbon group having 1 to 6 carbon atoms, a k group, a nitro group, an alkylsulfinyl group having 1 to 6 carbon atoms, and a carbon number of 丨6. ^ base, slave number 1 to 6 of the gas-based group, carbon number of 1 to 6 of the hospitaloxy group, carbon number of 1 to 6 di-thiol group, carbon number of 1 to 6 N-alkylamine group, carbon number 2 to 12 N, n^ dialkylamino group, N-alkylamine sulfonyl group having 1 to 6 carbon atoms, carbon number 2 to "N-dialkylamine sulfonyl group, or a COOH; ' ' Q is not a CR ^ R1. _, a S -, a NR9 -, - ρρ» -; R and R1G independently represent a hydrogen atom or a carbon number of 1 to 4; 〆 aromatic ϋ ΐ 或 or unsubstituted 芳Recording, or replacing ^unsubstituted η, represents an integer from 0 to 2.) 6' = phase difference plate of claim 2 or 3, where Gl is -1, 4 - 2 US. u 1 3 Al^ 8 4 —Extension of a base or a cyclohexane to a 1,4-12 base. A phase difference plate of 'the first', wherein: B1 〇~CO---CO-NH-, NH, which is only bonded to Al ~CO c discusses 2—〇—, or a single bond; and B1 bonded to F1 and β2 bonded to F2 are independently —〇—, —O—CO—, —O— CO-O— ' —ΓΟ χπτ 10—, or a single bond. CO-ΝΗ—, —ΝΗ = 第 第 第 第 ' ' ' ' ' ' ' ' ' ' ' ' ' Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ Ρΐ The bonded Β2 is independently -ch2 - CH2___CO - ο -, 〇 ~ ch2 123 9. 201202806 10_ A semi-transmissive liquid crystal display device comprising the phase difference plate of claim 1 of the patent application. A 3D display device which comprises a phase difference plate as in the first aspect of the patent application. 12. A method of manufacturing a phase difference plate having a plurality of regions in which directions of a plurality of phase retardation axes are different, and in all regions, a birefringence Αη (λ) of light having a wavelength of λ (ηηι) (1) and (2): Δη(450)/Δη(550)^1.00 (1) 1·〇〇^Δη(650)/Δη(550) (2) wherein the phase difference plate is manufactured The following steps (]〇)~(12) are included: (10) an alignment film forming step of forming an alignment film on a substrate; (11) an alignment imparting step of imparting an alignment energy to the alignment film to have a plurality of alignments And a (12) coating step of coating the polymerizable compound on the alignment film. 13. The method of manufacturing a phase difference plate according to claim 12, wherein the step (n) comprises the following steps (11a) to 〇10: (11a) the second rubbing treatment step, which is formed on the substrate. a first rubbing treatment is applied to the entire surface of the alignment film; (Ub) a mask covering step, a mask having a predetermined pattern is applied to the surface of the alignment film to which the first rubbing treatment is applied; and (11c) a second rubbing treatment step The second rubbing treatment is applied to the surface of the alignment film to which the γ first rubbing treatment is applied and the portion where the mask is not covered. 14. The method for producing a phase difference plate according to the invention of claim 2 or 13, further comprising the following step (13): (13) a polymerization step of polymerizing the polymerizable compound applied to the alignment film. 15. A laminate comprising: a) an alignment film having a plurality of regions having different alignment directions; b) a phase difference plate according to any one of claims 1 to 9 formed on the alignment film . 16. A laminate comprising: a) a support substrate; 124 201202806 b) an alignment film formed on a support substrate; and C) a phase difference as claimed in any one of claims 1 to 9. A plate formed on the alignment film. Eight, schema: 125