TW201142106A - Method for manufacturing high visibility fluorescent rubber tarpaulins - Google Patents

Method for manufacturing high visibility fluorescent rubber tarpaulins Download PDF

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Publication number
TW201142106A
TW201142106A TW099117222A TW99117222A TW201142106A TW 201142106 A TW201142106 A TW 201142106A TW 099117222 A TW099117222 A TW 099117222A TW 99117222 A TW99117222 A TW 99117222A TW 201142106 A TW201142106 A TW 201142106A
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Taiwan
Prior art keywords
rubber
weight
parts
fluorescent
paste
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TW099117222A
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Chinese (zh)
Inventor
Hui-Zhi You
zheng-ji Xu
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Formosan Rubber Group Inc
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Application filed by Formosan Rubber Group Inc filed Critical Formosan Rubber Group Inc
Priority to TW099117222A priority Critical patent/TW201142106A/en
Publication of TW201142106A publication Critical patent/TW201142106A/en

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Abstract

The invention provides a method for manufacturing high visibility fluorescent rubber tarpaulins, which comprises the steps of blending a rubber material into a fluorescent gum, coating the rubber gum on a surface of a basic fabric, then calendering the surface with the fluorescent gum to form a composite fabrics, adding sulfur into the composite fabrics, and finally coating a layer of rubber paste or fluorescent gum over another surface of the composite fabrics that is not coated with the rubber paste or the fluorescent gum. With a feature for the fluorescent gum capable of reflecting light beam, the invention mainly applies the rubber tarpaulins on a canopy to increase its visibility so as to enhance the rescue chance.

Description

201142106 六、發明說明: 【發明所屬之技術領域】 本發明係有關一種防水膜料之製造技術,特別是指一種高能見度 螢光橡膠篷布之製造方法。 【先前技術】 按,具有螢光高能見度、防水之橡膠布可應用於帳棚、救生筏及 救生筏之頂篷,藉由螢光之發光效果,即使於黑夜中待救援之救生筏 亦清晰可見,提高救援機率,增加遇難者之生存機會。 Φ 螢光色粉如何附著於橡膠布上而仍能維持其發光效果為一重要課 題,現行市場上之螢光色粉雖顏色種類繁多,但色粉之間無法相互調 配顏色,否則螢光度大幅下降,因此無法藉由調配色粉而微調外觀色 澤,更會因螢光度降低而連帶降低夜間能見度,若做為救生筏之塗料 應用,將使救生筏夜間可辨識度不足,救援成功機率大減,危及遇難 者之生命安全〇 因此’本發明即提出一種高能見度螢光橡膠篷布之製造方法,以 有效克服上述之該等問題’具體架構及其實施方式將詳述於下。 【發明内容】 • 本發明之主要目的在提供一種高能見度螢光橡膠篷布之製造方 法’其使用之螢光膠料具有較高透明度,當光線通過橡膠篷布表面之 勞光膠料時’經過橡膠糊之反射後可使螢光膠料與橡膠糊之顏色產生 視覺變化,提高可見度。 本發明之另一目的在提供一種高能見度螢光橡膠篷布之製造方 法’其係在基布上以二次裱糊方式塗佈橡膠糊及螢光膠料,提高塗料 與基布之接著面與橡膠糊含量,以增加橡膠糊色澤之呈現並降低最終 橡膠蓬布之透光性。 為達上述之目的’本發明提供一種高能見度螢光橡膠篷布之製造 方法,包括下列步驟:將複數橡膠原料混煉成一螢光膠料,冷卻後將 201142106 螢光膠料進行第二次混煉;將一橡膠糊以裱糊或含浸方式設置於一基 布上,再利用一壓延機將螢光膠料貼合於基布之一面,形成一複合式 織物,之後將複合式織物進行連續加硫處理;以及於複合式織物之未 貼合螢光膠料之一面上再塗佈橡膠糊或螢光膠料,即形成螢光之橡膠 篷布。 底下藉由具體實施例詳加說明,當更容易暸解本發明之目的、技 術内容、特點及其所達成之功效。 【實施方式】 本發明提供一種高能見度螢光橡膠篷布之製造方法,其將透明度 較高之螢光膠料及透光度較低之橡膠糊塗佈於基布上,使光線經過榮 光膠料後被橡膠糊反射,進而提高橡膠篷布產品之能見度。 第一圖為本發明中螢光橡膠篷布之一實施例示意圖,本發明之登 光橡膠篷布包含一基布10、正反兩面皆有橡膠糊12、12’及正面設有 螢光膠料14,基布10之材質可為尼龍纖維布、玻璃纖維、聚酯纖維 布、棉布、聚酯尼龍混紡紗布、或其他纖維混紡梭織布。 第一圖所不為本發明之方塊圖’第三圖為本發明之流程圖,請同 時參考第二圖及第三圖,本發明係在步驟S10中利用萬馬力機20將 複數橡膠原料混煉成一螢光膠料,此橡膠原料包含1〇〇重量份之主 膠;50〜70重量份之填充劑及補強劑;5〜20重量份之軟化劑;3~8重 量份之功能性配合劑;以及2_5〜6_8重量份之硫化劑,其中,主膠包 括50重量份之天然橡膠、30重量份之乙烯丙烯橡膠及2〇重量份之聚 丁二烯橡膠’填充劑及補強劑包括1〇〜20重量份之碳酸約及4〇~50重 量份之白煙,功能性配合劑包括1〜3重量份之抗氧化劑及2〜5重量份 之硬脂酸,硫化劑包括2〜6重量份之加硫劑及〇·5〜〇 8重量份之加硫 助劑,軟化劑為可塑劑中之過氧化脂質(LPO)。 於步驟S10中係將上述橡膠原料中之主膠、功能性配合劑、填充 劑、補強劑、軟化劑依序投入萬馬力機20中,以140〜150°C之溫度 201142106 混煉五分鐘,混煉後冷卻至室溫存放24小時,之後將上述混煉完成之 螢光膠料以二滾輪22與硫化劑進行第二次混煉,混煉時間為兩分半 鐘,溫度為65〜75°C。 接著如步驟S12所述,將橡膠糊以裱糊機24裱糊(Coating)或 是以含浸(Dipping)方式設置於基布上,再將步驟S10中所混煉出之 螢光膠料送入一連續式橡膠壓延機26中貼合於基布之一面,操作溫度 為75〜85°C,螢光膠料設定之壓延厚度可為〇.〇6〜0.10釐米(mm), 經壓延後形成一複合式織物,可連續式生產,或收捲以備下一流程。 步驟S14中’將步驟S12所製成之複合式織物進行連續加硫處 理’在本實施例中係以直立式熱空氣烘箱28、溫度設定140〜160°C進 行加硫,產速為每分鐘15〜20碼;加硫後可連續式生產,或收捲以備 下一流程。 加硫完成後’最後於步驟S16中在複合式織物之未貼合螢光膠料 之布面上再塗佈一層橡膠糊或螢光膠料,即在步驟S18中形成如第一 圖所示之具高可見度之螢光橡膠篷布。 故’本發明之製造方法係採用二次裱糊方式塗佈橡膠糊及螢光朦 料,可提高塗料與基布之接著面與橡膠糊含量,增加橡膠糊色澤之呈 現並降低橡膠篷布之透光性《本發明亦可以含浸方式塗上橡膠糊或榮 光膠料,雖可減少生產製成,但塗佈量會下降,而降低塗料的色澤呈 現且增加橡膠篷布之透光性,因此仍以裱糊塗佈方式為較佳之實施例。 綜上所述,本發明之製造方法使用透明度較高之橡膠膠料貼合於 織物上’當光線通過表面膠料經由糊料反射,視覺上會因糊料顏色的 不同導致膠料顏色之變化,如此能對外觀色澤進行微調,並維持原榮 光色粉之螢光度,使所製造出之橡膠篷布不僅有一般橡膠布耐候性強 及防水性佳之性質’更擁有高能見度及主成分不含鹵素之特性,使其 作為救生筏頂蓬能增加被救援之機會外,頂蓬還可接雨水飲用,增加 遇難者等待救援的時間及生存機會。 唯以上所述者,僅為本發明之較佳實施例而已,並非用來限定本 201142106 =實施之麵。故即凡依本發明中請範騎述之特徵及精 =專變化或修飾,均應包括於本發明之申請專利範圍内。 【圖式簡單說明】 第一圖為本發明高能見度螢光橡膠篷布之結構示意圖。 第二圖為本發明高能見度螢光橡膠篷布之製造方法之方塊圖β 第三圖為本發明高能見度螢光橡膠篷布之製造方法之流程圖。 【主要元件符號說明】 10基布 12、12,橡膠糊 14螢光膠料 2〇萬馬力機 22二滾輪 24裱糊機 26連續式橡膠壓延機 28直立式熱空氣烘箱201142106 VI. Description of the Invention: [Technical Field] The present invention relates to a manufacturing technique of a waterproof film material, and more particularly to a method for manufacturing a high-visibility fluorescent rubber tarpaulin. [Prior Art] Pressed, high-visibility, waterproof rubber sheet can be applied to tents, life rafts and life rafts. With the glow effect of fluorescent light, even the life rafts to be rescued in the dark are clear. It can be seen that the rescue rate is increased and the survival opportunities of the victims are increased. Φ How the fluorescent toner adheres to the rubber cloth and still maintains its luminous effect is an important issue. The current market of fluorescent toners has a wide variety of colors, but the toners cannot be matched with each other, otherwise the fluorescence is greatly increased. Decrease, so it is impossible to fine-tune the appearance color by blending the toner, and it will reduce the nighttime visibility due to the decrease of the fluorescing. If it is used as a life raft paint application, the life raft will be less recognizable at night and the chance of rescue success will be greatly reduced. Therefore, the life safety of the victims is endangered. Therefore, the present invention proposes a method for manufacturing a high-visibility fluorescent rubber tarpaulin to effectively overcome the above-mentioned problems. The specific structure and its implementation will be described in detail below. SUMMARY OF THE INVENTION The main object of the present invention is to provide a method for manufacturing a high-visibility fluorescent rubber tarpaulin which has a high transparency when the light passes through the varnish of the rubber tarpaulin surface. After the rubber paste is reflected, the color of the fluorescent rubber compound and the rubber paste can be visually changed to improve the visibility. Another object of the present invention is to provide a method for manufacturing a high-visibility fluorescent rubber tarpaulin which is coated with a rubber paste and a fluorescent rubber on a base cloth in a secondary paste manner to improve the adhesion between the coating and the base fabric. The rubber paste content increases the color of the rubber paste and reduces the light transmission of the final rubber tarpaulin. For the above purposes, the present invention provides a method for manufacturing a high-visibility fluorescent rubber tarpaulin, comprising the steps of: kneading a plurality of rubber raw materials into a fluorescent rubber compound, and cooling the 201142106 fluorescent rubber compound for a second mixing. Refining; placing a rubber paste on a base fabric in a paste or impregnation manner, and then attaching the fluorescent rubber to one side of the base fabric by using a calender to form a composite fabric, and then continuously adding the composite fabric Sulfur treatment; and coating a rubber paste or a fluorescent rubber on one side of the unbonded fluorescent compound of the composite fabric to form a fluorescent rubber tarpaulin. The purpose, technical contents, features and effects achieved by the present invention will become more apparent from the detailed description of the embodiments. [Embodiment] The present invention provides a method for manufacturing a high-visibility fluorescent rubber tarpaulin, which applies a high-viscosity fluorescent rubber compound and a low-transmitting rubber paste to a base cloth to allow light to pass through the glory compound. Reflected by the rubber paste, which improves the visibility of the rubber tarpaulin product. The first figure is a schematic view of an embodiment of a fluorescent rubber tarpaulin according to the present invention. The Dengguang rubber tarpaulin of the present invention comprises a base fabric 10, rubber paste 12, 12' on both sides, and a fluorescent glue on the front side. Material 14, the material of the base fabric 10 may be nylon fiber cloth, glass fiber, polyester fiber cloth, cotton cloth, polyester nylon blended gauze, or other fiber blended woven fabric. The first figure is not a block diagram of the present invention. The third figure is a flow chart of the present invention. Please refer to the second figure and the third figure at the same time. The present invention uses the 10,000 horsepower machine 20 to mix a plurality of rubber materials in step S10. Refining into a fluorescent compound, the rubber raw material comprises 1 part by weight of the main glue; 50 to 70 parts by weight of the filler and the reinforcing agent; 5 to 20 parts by weight of the softening agent; and 3 to 8 parts by weight of the functional compound And 2_5~6_8 parts by weight of the vulcanizing agent, wherein the main glue comprises 50 parts by weight of natural rubber, 30 parts by weight of ethylene propylene rubber and 2 parts by weight of polybutadiene rubber 'filler and reinforcing agent including 1 〇20 parts by weight of carbonic acid and 4 〇 to 50 parts by weight of white smoke, the functional complexing agent comprises 1 to 3 parts by weight of antioxidant and 2 to 5 parts by weight of stearic acid, and the vulcanizing agent comprises 2 to 6 parts by weight. A sulphurizing agent and a sulphuric acid auxiliary agent in a plasticizer. The softening agent is a peroxidized lipid (LPO) in a plasticizer. In step S10, the main rubber, the functional compounding agent, the filler, the reinforcing agent and the softening agent in the rubber raw material are sequentially introduced into the 10,000 horsepower machine 20, and kneaded at a temperature of 140 to 150 ° C for 2011 minutes. After mixing, it is cooled to room temperature and stored for 24 hours. Then, the above-mentioned kneaded fluorescent rubber compound is kneaded by the second roller 22 and the vulcanizing agent for a second time. The mixing time is two and a half minutes, and the temperature is 65 to 75°. C. Then, as described in step S12, the rubber paste is pasteed by a paste machine 24 or placed on the base cloth by dipping, and then the fluorescent rubber compounded in step S10 is fed into a continuous process. The rubber calender 26 is attached to one side of the base fabric at an operating temperature of 75 to 85 ° C, and the calendering thickness set by the fluorescent rubber compound may be 〇.〇6 to 0.10 cm (mm), and a composite is formed after calendering. Fabrics can be produced continuously or wound up for the next process. In step S14, 'the continuous sulphurization treatment of the composite fabric made in step S12' is performed in the present embodiment by using a vertical hot air oven 28 and a temperature setting of 140 to 160 ° C for sulfurization at a production rate of one minute per minute. 15~20 yards; after sulfur addition, it can be continuously produced, or wound up for the next process. After the vulcanization is completed, finally, in step S16, a rubber paste or a fluorescent rubber compound is further coated on the surface of the unbonded fluorescent rubber compound of the composite fabric, that is, as shown in the first figure in step S18. High visibility fluorescent rubber tarpaulin. Therefore, the manufacturing method of the present invention applies a rubber paste and a fluorescent coating by a secondary paste method, which can improve the adhesion surface of the coating and the base fabric and the rubber paste content, increase the color of the rubber paste and reduce the penetration of the rubber tarpaulin. Lightness "The present invention can also be coated with a rubber paste or a glory compound in an impregnation manner, although the production can be reduced, but the coating amount is lowered, and the color of the paint is lowered and the light transmittance of the rubber tarpaulin is increased, so A preferred embodiment is a paste coating method. In summary, the manufacturing method of the present invention uses a rubber compound with a high transparency to be attached to the fabric. When the light is reflected by the surface rubber through the paste, the color of the rubber is visually changed due to the difference in the color of the paste. In this way, the appearance color can be fine-tuned, and the luminosity of the original glory toner can be maintained, so that the rubber tarpaulin produced not only has the general weather resistance and waterproof property of the rubber cloth, but also has high visibility and main components. The characteristics of halogen make it a life-saving rafter that can increase the chance of being rescued. The canopy can also be used for rainwater drinking, increasing the time and survival opportunities for the victims to wait for rescue. The above is only the preferred embodiment of the present invention and is not intended to limit the scope of this application. Therefore, the characteristics and precision changes or modifications of the invention should be included in the scope of the patent application of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a schematic view of the structure of a high-visibility fluorescent rubber tarpaulin according to the present invention. The second figure is a block diagram of a method for manufacturing a high-visibility fluorescent rubber tarpaulin according to the present invention. The third figure is a flow chart of a method for manufacturing a high-visibility fluorescent rubber tarpaulin according to the present invention. [Main component symbol description] 10 base cloth 12, 12, rubber paste 14 fluorescent compound 2 million horsepower machine 22 two rollers 24 paste machine 26 continuous rubber calender 28 vertical hot air oven

Claims (1)

201142106 七、申請專利範圍: 1. 一種高能見度螢光橡膠篷布之製造方法,包括: (a) 將複數橡膠原料混煉成一螢光膠料,冷卻後將該螢光膠料進行 第二次混煉; (b) 將一橡膠糊設於於一基布上,再利用一壓延機將該螢光膠料貼 合於該基布之一面,形成一複合式織物; (c) 將該複合式織物進行連續加硫處理;以及 (d) 於該複合式織物之未貼合該螢光膠料之一面上塗佈該橡膠糊 或該螢光膠料,即形成一橡膠篷布。 • 2.如申請專利範圍第1項所述之高能見度螢光橡膠篷布之製造方 法’其中該基布為尼龍纖維布、玻璃纖維、聚酯纖維布、棉布、聚 酯尼龍混紡紗布、或其他纖維混紡梭織布。 3. 如申請專利範圍第1項所述之高能見度螢光橡膠篷布之製造方 法’其中該橡膠原料包括: 100重量份之主膠; 50~70重量份之填充劑及補強劑; 5〜20重量份之軟化劑; 3~8重量份之功能性配合劑;以及 籲 2.5〜6.8重量份之硫化劑。 4. 如申請專利範圍第3項所述之高能見度螢光橡膠篷布之製造方 法’其中該主膠包括50重量份之天然橡膠、30重量份之乙烯丙烯 橡膠及20重量份之聚丁二烯橡膠,該填充劑及該補強劑包括 10〜20重量份之碳酸鈣及40〜50重量份之白煙,該功能性配合劑 包括1〜3重量份之抗氧化劑及2~5重量份之硬脂酸,該硫化劑包 括2〜6重量份之加硫劑及〇.5〜〇·8重量份之加硫助劑。 5·如申請專利範圍第3項所述之高能見度螢光橡膠篷布之製造方 法’其中該軟化劑為可塑劑中之過氧化脂質(LPO)。 6.如申請專利範圍第3項所述之高能見度螢光橡膠篷布之製造方 201142106 法’其中該步驟(a)係將該橡膠原料中之主膠、功能性配合劑、填 充劑、補強劑及軟化劑依序投入一萬馬力機中混煉五分鐘,混煉完 成後冷卻24小時’再以一二滾輪(〇pen R0||er)及硫化劑混煉兩 分半鐘。 7. 如申請專利範圍第6項所述之高能見度螢光橡膠篷布之製造方 法’其中該萬馬力機之溫度為140〜15CTC,該二滾輪之溫度為 65~75°C 〇 8. 如申請專利範圍第1項所述之高能見度螢光橡膠篷布之製造方 法’其中該步驟(b)係利用一裱糊機將該橡膠糊塗佈於該基布上, 或是以含浸處理將該橡膠糊附著於該基布上。 9. 如申請專利範圍第1項所述之高能見度螢光橡膠篷布之製造方 法’其中該步驟(b)中該壓延機為連續式橡膠壓延機,其操作溫度 為 75〜850C。 10. 如申請專利範圍第彳項所述之高能見度螢光橡膠篷布之製造方 法,其中該步驟(c)係以一直立式熱空氣烘箱進行加硫,溫度為 140~160°C,該複合式織物之產速為每分鐘15~2〇碼。201142106 VII. Patent application scope: 1. A method for manufacturing high-visibility fluorescent rubber tarpaulin, comprising: (a) mixing a plurality of rubber raw materials into a fluorescent rubber material, and cooling the fluorescent rubber material for a second time (b) placing a rubber paste on a base fabric, and then bonding the phosphor paste to one side of the base fabric by using a calender to form a composite fabric; (c) compounding the composite The fabric is subjected to continuous sulfurization; and (d) the rubber paste or the phosphor is coated on one side of the composite fabric which is not attached to the phosphor, thereby forming a rubber tarpaulin. 2. The method for manufacturing a high-visibility fluorescent rubber tarpaulin as described in claim 1, wherein the base fabric is nylon fiber cloth, glass fiber, polyester fiber cloth, cotton cloth, polyester nylon blended gauze, or Other fiber blended woven fabrics. 3. The method for manufacturing a high-visibility fluorescent rubber tarpaulin according to claim 1, wherein the rubber material comprises: 100 parts by weight of a main glue; 50 to 70 parts by weight of a filler and a reinforcing agent; 20 parts by weight of a softening agent; 3 to 8 parts by weight of a functional compounding agent; and 2.5 to 6.8 parts by weight of a vulcanizing agent. 4. The method for producing a high-visibility fluorescent rubber tarpaulin according to claim 3, wherein the main rubber comprises 50 parts by weight of natural rubber, 30 parts by weight of ethylene propylene rubber and 20 parts by weight of polybutylene. The olefin rubber, the filler and the reinforcing agent comprise 10 to 20 parts by weight of calcium carbonate and 40 to 50 parts by weight of white smoke, and the functional complexing agent comprises 1 to 3 parts by weight of an antioxidant and 2 to 5 parts by weight of the Stearic acid, the vulcanizing agent comprises 2 to 6 parts by weight of a sulfurizing agent and 5% to 5 parts by weight of a sulfur addition aid. 5. The method of producing a high-visibility fluorescent rubber tarpaulin according to claim 3, wherein the softening agent is a peroxide peroxide (LPO) in a plasticizer. 6. The manufacturer of high-visibility fluorescent rubber tarpaulin according to item 3 of the patent application scope 201142106, wherein the step (a) is the main glue, functional compounding agent, filler, reinforcing in the rubber raw material. The agent and the softener are sequentially mixed into a 10,000-horsepower machine for five minutes, and after the mixing is completed, the mixture is cooled for 24 hours. Then, the two-roller (〇pen R0||er) and the vulcanizing agent are mixed for two and a half minutes. 7. The method for manufacturing a high-visibility fluorescent rubber tarpaulin according to claim 6 wherein the temperature of the 10,000 horsepower machine is 140 to 15 CTC, and the temperature of the two rollers is 65 to 75 ° C. The method for manufacturing a high-visibility fluorescent rubber tarpaulin according to claim 1, wherein the step (b) applies the rubber paste to the base fabric by using a paste machine, or the rubber is impregnated. The paste is attached to the base fabric. 9. The method of manufacturing a high-visibility fluorescent rubber tarpaulin according to claim 1, wherein the calender in the step (b) is a continuous rubber calender having an operating temperature of 75 to 850C. 10. The method for manufacturing a high-visibility fluorescent rubber tarpaulin according to the above-mentioned patent application, wherein the step (c) is sulphurizing in a vertical hot air oven at a temperature of 140 to 160 ° C. The speed of the composite fabric is 15~2 yards per minute.
TW099117222A 2010-05-28 2010-05-28 Method for manufacturing high visibility fluorescent rubber tarpaulins TW201142106A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013121322A2 (en) * 2012-02-13 2013-08-22 Sebo Gyula Structural arrangement for a textile strap with fluorescent coating
CN103302943A (en) * 2012-03-14 2013-09-18 厚生股份有限公司 Method for producing rubber tarpaulin
TWI666113B (en) * 2018-04-09 2019-07-21 厚生股份有限公司 Rubber composite structure and method for manufacturing the same
WO2021052582A1 (en) * 2019-09-18 2021-03-25 Biwi S.A. Luminescent manufactured object and method for producing same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013121322A2 (en) * 2012-02-13 2013-08-22 Sebo Gyula Structural arrangement for a textile strap with fluorescent coating
WO2013121322A3 (en) * 2012-02-13 2013-12-27 Sebo Gyula Structural arrangement for a textile strap with fluorescent coating
CN103302943A (en) * 2012-03-14 2013-09-18 厚生股份有限公司 Method for producing rubber tarpaulin
TWI666113B (en) * 2018-04-09 2019-07-21 厚生股份有限公司 Rubber composite structure and method for manufacturing the same
WO2021052582A1 (en) * 2019-09-18 2021-03-25 Biwi S.A. Luminescent manufactured object and method for producing same

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