CN104890327B - Camouflage color prints composite - Google Patents
Camouflage color prints composite Download PDFInfo
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- CN104890327B CN104890327B CN201510238482.9A CN201510238482A CN104890327B CN 104890327 B CN104890327 B CN 104890327B CN 201510238482 A CN201510238482 A CN 201510238482A CN 104890327 B CN104890327 B CN 104890327B
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- facial mask
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Abstract
Composite is printed the present invention relates to a kind of camouflage color, the composite from bottom to top sequentially includes base fabric, counterdie, middle film and facial mask, and the composite is prepared by following step：After base fabric impregnation starching, after drying heating, fitted successively with counterdie, middle film, facial mask, then good fortune is determined in cutting edge after cooling and shaping, is finally batched and is obtained.The present invention makes it possess good tensile strength, elongation at break, Tear strength, separation strength, indices meet national standard by optimization formula and technique.
Description
Technical field
The present invention relates to a kind of composite, composite is printed more particularly, to a kind of camouflage color.
Background technology
In recent years, the fast development of new material and production technology improves the kind and matter of CHINESE INDUSTRIES textile
Amount, tarpaulin material is that proportion is than a larger class in fabrics for industrial use, except harbour field work, car and boat transport, goods yard
Outside accumulation tarpaulin, at present Europe it is many country oneself through by flexible composite be used for soft container, automobile exterior fabric
Deng field.
With the continuous progress of science and technology, the development and application of China's tarpaulin material nearly ten years are in developing stage,
Fibrous raw material, the institutional framework of base fabric and the finishing process technology used is continuously updated, and traditional canopy material is just
To poly-talented transition of new generation, it is the concept based on covering to break through tarpaulin, is constantly extended to new market segment.Open
The flexible body advertising lamp box material of paulin lid new material of new generation, inflatable structure material, paulin face architectural fabrics, the soft top surface of automobile of hair
Exterior material etc..These materials are required for using for a long time out of doors, it is necessary to be amenable to strict anti-aging test.
And aging mainly has 3 big factors：One is thermal degradation.In the production and recombination process of basement membrane, polyvinyl chloride is by height
Temperature effect, occurs thermal degradation；Two be light aging.PVC spray painting cloths Prolonged exposure in the sunlight, 300~310 nm in sunshine
Ultraviolet light makes polyvinyl chloride molecular chain rupture and crosslinking.Three are accompanied with thermal degradation and light aging, the oxidation drop of polyvinyl chloride
Solution also occurs simultaneously.This 3 kinds chemical reactions have ultimately resulted in product colour intensification, and physical and mechanical property is greatly reduced.Therefore, such as
What sets up effective antiaging system, extends PVC composite service lifes, is always domestic and international PVC composite manufacturers
The research emphasis of family and direction.
The content of the invention
In order to lift the class and technology content of product, solution tradition PVC composite service lifes are short, easy aging, especially
The problems such as it solves such product pattern fugitive color, composite is printed the invention provides a kind of camouflage color.The present invention is in
Film is coloured, and the design of the PVC composite structures of surface coating and PVC film formula are preferred, solves the easy aging of conventional products, easily
Fade, the problems such as service life is short；Stabilizer is selected simultaneously, meets and the environmentally friendly index of PVC composites is wanted both at home and abroad
Ask, and the thus competitiveness of enhancing product commercially.
A kind of camouflage color prints composite, and the composite from bottom to top sequentially includes base fabric, counterdie, middle film and face
Film, the composite is prepared by following step：Base fabric impregnation starching after, drying heating after, successively with counterdie, in
Film, facial mask are fitted, then good fortune is determined in cutting edge after cooling and shaping, is finally batched and is obtained；
Wherein, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 60~80, the parts by weight of environment-friendly plasticizer 15~30, epoxy are big
The parts by weight of soya-bean oil 0.5~3, the parts by weight of non-toxic stabilizer 1~3, the parts by weight of mould inhibitor 0.1~0.5, the weight of colorant 0.2~0.5
Part；
The middle film or counterdie raw material are：The parts by weight of polyvinyl chloride resin 45~55, the parts by weight of environment-friendly plasticizer 35~45, epoxy
The parts by weight of soybean oil 1~3, the parts by weight of non-toxic stabilizer 1.5~3, the parts by weight of mould inhibitor 0.1~0.3, the weight of fire retardant 1~3
Part, the parts by weight of colorant 2~4；
Slurry is：Weight ratio is 1：1 polyethylene paste is with the mixture of epoxidized soybean oil and added with 5~9% mass percentages
The adhesive of ratio.
Preferably, the base fabric uses line density for 1000D × 1000D, Density is 28 × 28 pieces/inch of height
Strong terylene woven fabric.Use of the high-strength polyester through woven fabric greatly improves the strength and service life of PVC composites, effectively
It ensure that the fracture strength and tearing brute force during PVC composite uses.
Plastified afterwards preferably, the calendering technology of the counterdie, middle film or facial mask is that raw material is agitated, through ten thousand horsepowers
Machine stirring after filtering, calendering, cooling and shaping, batch to obtain accordingly PVC film.
Preferably, the typography of the facial mask is polychrome cylinder typography in batches.
Preferably, the control of laminating speed is in 2~5m/min, laminate pressure control exists in 4~8kg, binding temperature control
175~190 DEG C.In base fabric fits process with PVC film, because base fabric density is big and the influence of fabric structure, lead
Hot gas dissipation is difficult during causing laminating, so that the generation of bubble is caused, to solve the above problems, the present invention fits by adjusting
Speed, pressure and binding temperature in process effectively prevent the generation of bubble.
Preferably, the degree of polymerization of the polyvinyl chloride resin is 800~1000.
Preferably, the environment-friendly plasticizer is vegetable oil base class plasticizer or citric acid ester plasticizer.
Preferably, described adhesive is one kind in polyurethane, polyacrylate, epoxy resin.
Preferably, the slurry sizing amount is 5~10g/m3.Using base fabric and bottom, in, the attaching process of the film of face three,
To ensure its higher stripping fastness, the fastness of fitting between base fabric and PVC film on the one hand need to be considered, on the other hand also need to consider
Laminating fastness between PVC film, the starching amount that the present invention is used can effectively solve the problems, such as the laminating fastness between PVC film.
Preferably, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 70, acetyl citrate three that the degree of polymerization is 1000
The double phenoxazine arsenic mould inhibitors of the parts by weight of butyl ester 22, the parts by weight of epoxidized soybean oil 1.5, the parts by weight of calcium zinc stabilizer 2,10,10 '-oxo
0.2 parts by weight, the parts by weight of rutile type titanium white 0.3；The middle film or counterdie raw material are：The degree of polymerization is 1000 polyvinyl chloride resin
50 parts by weight, the parts by weight of ATBC 40, the parts by weight of epoxidized soybean oil 2, the parts by weight of calcium zinc stabilizer 2.2,10,10 '-oxygen
Generation double parts by weight of phenoxazine arsenic mould inhibitor 0.2, the parts by weight of inorganic combustion inhibitor 2, the parts by weight of rutile type titanium white 3；Slurry is：Weight
Than for 1：1 polyethylene paste and the mixture of epoxidized soybean oil and polyurethane binder added with 7% mass percent；Wherein,
Inorganic combustion inhibitor is that weight ratio is 1.5：1 aluminium hydroxide and magnesium hydroxide mixture；Speed of fitting control is in 3m/min, laminating
Stress control is controlled at 186 DEG C in 6kg, binding temperature；Slurry sizing amount is 8g/m3。
The present invention is from framework material（Base fabric）Selection, the determination of PVC film formula and PVC film calendering technology and PVC film
In-depth study analysis is all made in terms of the determination for production technology of being fitted with framework material, should consider that the fracture of product is strong
The indexs such as power, elongation at break, tearing brute force, separation strength, it is also contemplated that ageing-resistant, the preventing sheding tintability energy of product.
The beneficial effects of the present invention are：
1. advertising and printing composite due to long-term exposed to open air, its printed patterns often because ink volatilization or
Colorant conjugated structure destroys and produces discolouration phenomena, the service life of extreme influence advertising results and printed advertising material；For
Solve the above problems, the present invention proposes the new thought of facial mask bottom printing, and the mentality of designing is by facial mask surface layer to printing
The protective effect of pattern, be effectively reduced the volatilization of ink and the discolouration phenomena of pattern, it is to avoid overlay film protection is brought
Cost and working-procedure problem；
2. in advertising and printing composite, the use of terylene base fabric can effectively improve the strength and size of composite
Stability, still, the presence of middle level base fabric often influence the apparent display effect of printed patterns, greatly reduce visual sense of beauty；
The present invention creatively passes through middle film coloring grounding（Coffee color in camouflage color）Design, effectively covered in composite
Base fabric lines, dexterously solve influence of the base fabric lines to printed patterns；
3. camouflage color printing processing is the important manufacturing procedure that composite is printed in outdoor advertising, conventional plain net printer
Skill often has that lines is overlapping, printing quality is unstable and the low problem of processing efficiency；The present invention prints processing link in camouflage color
In innovatively introduce polychrome cylinder typography in batches, on the one hand greatly improve that printed patterns lines is overlapping and printing quality
Poor the problem of, the use of another aspect cylinder printing technology significantly improves printing efficiency.
Embodiment
With reference to specific embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1
A kind of camouflage color prints composite, and the composite from bottom to top sequentially includes base fabric, counterdie, middle film and face
Film, the composite is prepared by following step：Base fabric impregnation starching after, drying heating after, successively with counterdie, in
Film, facial mask are fitted, then good fortune is determined in cutting edge after cooling and shaping, is finally batched and is obtained；
Wherein, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 70, citroflex A-4 that the degree of polymerization is 1000
The double weights of phenoxazine arsenic mould inhibitor 0.2 of 22 parts by weight, the parts by weight of epoxidized soybean oil 1.5, the parts by weight of calcium zinc stabilizer 2,10,10 '-oxo
Measure part, the parts by weight of rutile type titanium white 0.3；The middle film or counterdie raw material are：The degree of polymerization is 1000 weight of polyvinyl chloride resin 50
Part, the double fens of the parts by weight of ATBC 40, the parts by weight of epoxidized soybean oil 2, the parts by weight of calcium zinc stabilizer 2.2,10,10 '-oxo
Dislike the parts by weight of arsenic mould inhibitor 0.2, the parts by weight of inorganic combustion inhibitor 2, the parts by weight of rutile type titanium white 3；Slurry is：Weight ratio is 1：
1 polyethylene paste and the mixture of epoxidized soybean oil and polyurethane binder added with 7% mass percent；Wherein, inorganic resistance
It is that weight ratio is 1.5 to fire agent：1 aluminium hydroxide and magnesium hydroxide mixture；Speed of fitting control is in 3m/min, laminate pressure control
System is controlled at 186 DEG C in 6kg, binding temperature；Slurry sizing amount is 8g/m3。
Each technical indicator of product of the present invention is as shown in table 1：
Table 1
The present invention by optimization formula and technique, make it possess good tensile strength, elongation at break, Tear strength with
And separation strength.
Embodiment 2
A kind of camouflage color prints composite, and the composite from bottom to top sequentially includes base fabric, counterdie, middle film and face
Film, the composite is prepared by following step：Base fabric impregnation starching after, drying heating after, successively with counterdie, in
Film, facial mask are fitted, then good fortune is determined in cutting edge after cooling and shaping, is finally batched and is obtained；
Wherein, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 60, citroflex A-4 15 that the degree of polymerization is 800
The double weight of phenoxazine arsenic mould inhibitor 0.1 of parts by weight, the parts by weight of epoxidized soybean oil 0.5, the parts by weight of calcium zinc stabilizer 4,10,10 '-oxo
Part, the parts by weight of rutile type titanium white 0.2；The middle film or counterdie raw material are：The degree of polymerization is 1000 weight of polyvinyl chloride resin 45
Part, the double fens of the parts by weight of ATBC 35, the parts by weight of epoxidized soybean oil 1, the parts by weight of calcium zinc stabilizer 1.5,10,10 '-oxo
Dislike the parts by weight of arsenic mould inhibitor 0.1, the parts by weight of inorganic combustion inhibitor 1, the parts by weight of rutile type titanium white 2；Slurry is：Weight ratio is 1：
1 polyethylene paste and the mixture of epoxidized soybean oil and polyurethane binder added with 5% mass percent；Wherein, inorganic resistance
It is that weight ratio is 1.5 to fire agent：1 aluminium hydroxide and magnesium hydroxide mixture；Speed of fitting control is in 3m/min, laminate pressure control
System is controlled at 190 DEG C in 6kg, binding temperature；Slurry sizing amount is 9g/m3。
Each technical indicator of product of the present invention is as shown in table 2：
Table 2
The present invention by optimization formula and technique, make it possess good tensile strength, elongation at break, Tear strength with
And separation strength.
Embodiment 3
A kind of camouflage color prints composite, and the composite from bottom to top sequentially includes base fabric, counterdie, middle film and face
Film, the composite is prepared by following step：Base fabric impregnation starching after, drying heating after, successively with counterdie, in
Film, facial mask are fitted, then good fortune is determined in cutting edge after cooling and shaping, is finally batched and is obtained；
Wherein, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 80, citroflex A-4 that the degree of polymerization is 1000
The double weight of phenoxazine arsenic mould inhibitor 0.3 of 30 parts by weight, the parts by weight of epoxidized soybean oil 3, the parts by weight of calcium zinc stabilizer 3,10,10 '-oxo
Part, the parts by weight of rutile type titanium white 0.5；The middle film or counterdie raw material are：The degree of polymerization is 1000 weight of polyvinyl chloride resin 55
Part, the double phenoxazines of the parts by weight of ATBC 45, the parts by weight of epoxidized soybean oil 3, the parts by weight of calcium zinc stabilizer 3,10,10 '-oxo
The parts by weight of arsenic mould inhibitor 0.3, the parts by weight of inorganic combustion inhibitor 3, the parts by weight of rutile type titanium white 4；Slurry is：Weight ratio is 1：1
Polyethylene paste with the mixture of epoxidized soybean oil and polyurethane binder added with 9% mass percent；Wherein, inorganic resistance
It is that weight ratio is 1.5 to fire agent：1 aluminium hydroxide and magnesium hydroxide mixture；Speed of fitting control is in 5m/min, laminate pressure control
System is controlled at 185 DEG C in 8kg, binding temperature；Slurry sizing amount is 7g/m3。
Each technical indicator of product of the present invention is as shown in table 3：
Table 3
The present invention by optimization formula and technique, make it possess good tensile strength, elongation at break, Tear strength with
And separation strength.
Claims (1)
1. a kind of camouflage color prints composite, it is characterised in that：The composite from bottom to top sequentially include base fabric, counterdie,
Middle film and facial mask, the composite are prepared by following step：After base fabric impregnation starching, after drying heating, successively
Fitted with counterdie, middle film, facial mask, then the cutting edge tentering after cooling and shaping, finally batch and obtain；
Wherein, the facial mask raw material is：The parts by weight of polyvinyl chloride resin 70, the weight of citroflex A-4 22 that the degree of polymerization is 1000
Measure part, the parts by weight of epoxidized soybean oil 1.5, the parts by weight of calcium zinc stabilizer 2, the double weight of phenoxazine arsenic mould inhibitor 0.2 of 10,10 '-oxo
Part, the parts by weight of rutile type titanium white 0.3；
The middle film or counterdie raw material are：The degree of polymerization for 1000 the parts by weight of polyvinyl chloride resin 50, the parts by weight of ATBC 40,
The double parts by weight of phenoxazine arsenic mould inhibitor 0.2 of the parts by weight of epoxidized soybean oil 2, the parts by weight of calcium zinc stabilizer 2.2,10,10 '-oxo, nothing
The parts by weight of machine fire retardant 2, the parts by weight of rutile type titanium white 3；
Slurry is：Weight ratio is 1：1 polyethylene paste and the mixture of epoxidized soybean oil and gathering added with 7% mass percent
Urethane adhesive；
Wherein, inorganic combustion inhibitor is that weight ratio is 1.5：1 aluminium hydroxide and magnesium hydroxide mixture；Speed of fitting control exists
3m/min, laminate pressure control is controlled at 186 DEG C in 6kg, binding temperature；Slurry sizing amount is 8g/m3。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510238482.9A CN104890327B (en) | 2015-05-12 | 2015-05-12 | Camouflage color prints composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510238482.9A CN104890327B (en) | 2015-05-12 | 2015-05-12 | Camouflage color prints composite |
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| CN104890327A CN104890327A (en) | 2015-09-09 |
| CN104890327B true CN104890327B (en) | 2017-08-04 |
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| CN201510238482.9A Active CN104890327B (en) | 2015-05-12 | 2015-05-12 | Camouflage color prints composite |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105751645A (en) * | 2016-03-15 | 2016-07-13 | 浙江宇立新材料有限公司 | Printing film for recreational vehicle decoration and production process thereof |
| CN107639911A (en) * | 2017-08-22 | 2018-01-30 | 盐城市昶桦户外用品股份有限公司 | A kind of preparation method of antibacterial ultraviolet-resistannanofiber line tent material |
| CN110588113B (en) * | 2019-08-29 | 2022-04-12 | 成都帝龙新材料有限公司 | PVC decorative film and water-based ink developing and printing method of PVC decorative film |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US8101257B2 (en) * | 2008-12-22 | 2012-01-24 | Sipix Chemical Inc. | Abrasion-resistant transfer printing structure |
| CN201800290U (en) * | 2010-08-06 | 2011-04-20 | 胡新佳 | Double-side folder black high-molecular spray painting cloth |
| CN102501672B (en) * | 2011-11-01 | 2013-08-14 | 浙江明士达新材料有限公司 | Inkjet printing material for bleeding and eduction resistance and high precision |
| CN202507697U (en) * | 2012-03-15 | 2012-10-31 | 杭州弘泽新材料有限公司 | Double-sided digital flex banner |
| CN104057684A (en) * | 2013-03-23 | 2014-09-24 | 上海纳尔数码喷印材料股份有限公司 | Spray-painting advertisement cloth and production process thereof |
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Address after: 314419, Hongqi Avenue, Haining warp knitting industrial park, Zhejiang, Jiaxing, 11 Patentee after: Zhejiang mingshida Co., Ltd Address before: 314419, Hongqi Avenue, Haining warp knitting industrial park, Zhejiang, Jiaxing, 11 Patentee before: ZHEJIANG MSD NEW MATERIAL Co.,Ltd. |