TW201140127A - Anti-dizzy polarized board and image display device using the polarized board - Google Patents

Abstract

Proposed is an anti-dizzy polarized board and an image display device using the anti-dizzy polarized board, the anti-dizzy polarized board including an anti-dizzy film having a transparent support body, and an anti-dizzy layer having a roughened surface and stacked on the transparent support body; and a polarized film constituted by intervening a first adhesion layer of a hardened object formed by a hardened compound having oxide resin and stacked on the transparent support body, the polarized film being opposite to the anti-dizzy layer, wherein the ratio of the target energy spectrum H1 in the space frequency 0.01um of the roughened surface and the ratio of the energy spectrum H2 of the space frequency 0.04um is 1 to 20, the ratio of the energy spectrum H3 in the space frequency 0.1um and the energy spectrum H2 is under 0.1, and the roughened surface of the anti-dizzy layer comprises an oblique angle of over 95% and a plane of under 5%.

Description

201140127 VI. Description of the Invention: [Technical Field] The present invention relates to an anti-glare property which exhibits better anti-glare property, prevents whitening and flash spots, and exhibits good contrast and imparts good visibility. A polarizing plate and an image display device using the polarizing plate. [Prior Art] Image display device such as liquid crystal display, plasma display panel, Braun tube (CRT, CRT, Cathode Ray Tube) display, organic electroluminescence (EL: E1 ectro 1 uminescence) display , when the external light is mapped to its display surface, the visibility is significantly impaired. In order to prevent such light, "the TV and the personal computer that pay attention to the enamel, the camera and the digital camera used outdoors outside the strong external light, and the mobile power that uses the reflected light to display the image are displayed on the image display device. The surface is provided with an anti-glare film for preventing the external light from being mapped. For example, in a liquid crystal display device, 'usually in the liquid crystal panel, the anti-glare polarizing plate is provided with: a polyethylene glycol resin. And using a polyethylene glycol-based adhesive to adhere to the fine anti-glare film, for example, in the Japanese Laid-Open Patent Publication No. 2006-053371, after the sandblasting of the ground mold substrate, 7° There is a ^ ^ ^ %J^ electroless chain record 'by making a mold with fine irregularities on the surface, and it is made of cellulose triacetate (TAC : Triacetyl Cellul: s^ - the side of the hardening resin layer is pressed) The surface of the photocurable resin layer is transferred onto the surface of the photocurable resin layer, and the surface of the photocurable resin layer is transferred to the surface of the photocurable resin layer, and the antiglare film is cured. The unevenness 322869 4 201140127 [Description of the Invention] For anti-glare film, except In addition to the anti-glare property, it is also desirable to exhibit a high contrast when disposed on the viewing side of the polarizing plate of the image display device, and when disposed on the viewing side of the polarizing plate of the image display device, the display surface is inhibited from being changed by the gas light. The occurrence of so-called "whitening" which causes turbidity in white, and when it is disposed on the viewing side of the polarizing plate of the image display device, the interference between the pixels of the image display device and the surface unevenness of the anti-glare film is suppressed. In the case of the anti-glare film described in Japanese Laid-Open Patent Publication No. 2006-053371, the anti-glare film described in Japanese Laid-Open Patent Publication No. 2006-053371 is a mold for forming a concave-convex shape. Since it is produced, the precision of the uneven shape formed in the anti-glare film is insufficient, and it is possible to produce a large uneven shape having a period of SG/^ or more, so that there is a problem that "flash spots" are likely to occur in the month. 'When using a polyvinyl alcohol-based adhesive which has been widely used in the past as an adhesive for bonding an anti-glare film to a partial domain composed of a polyvinyl alcohol resin, there is no money. There is a problem of (4) polarizing plates having high water resistance. Therefore, the object of the present invention is to provide a contrast which can exhibit better anti-glare and which exhibits good contrast while preventing "whitening" and "flash spot" polarizing plates. The present invention provides an anti-glare film having an anti-glare film and having a transparent support structure and having a concave long-lasting m resin film. a partial == layer; " and a polyethylene-based, "interlayered first adhesive layer" laminated on the opposite side of the 322869 5 201140127 transparent support from the anti-glare layer; The agent layer is composed of a cured product containing a curable composition of an epoxy resin; an energy spectrum Hl2 and a spatial frequency of the elevation of the uneven surface of the antiglare layer in the spatial frequency G.G1_-1. The ratio H'u of the energy spectrum H22 of the elevation of the concave-convex surface in 〇4 a ^ is in the range of i to 2 ;; the spatial frequency (the energy spectrum Μ and the spatial frequency of the elevation of the concave-convex surface in Μ#1)能'/ζπΓ1, the energy spectrum η of the elevation of the concave-convex surface, the ratio H32/H22 is 0·1 And; the uneven surface comprises 95% or more of an inclination angle of 5. The following faces. The anti-recording button of the present invention comprises an optical compensation layer such as a film or an optical compensation film which is laminated on a surface of the polarizing film opposite to the anti-glare film by a second adhesive layer. The optical compensation layer may be laminated on the protective film, and the second layer (4) may be laminated on the surface of the polarizing film opposite to the anti-glare film. The second adhesive layer is preferably composed of a cured product containing an epoxy. Further, it is preferable to use a polyvinyl alcohol-based resin film which is uniaxially stretched and adsorbed and has a dichroic dye (d1Chr_ pigment). The latter is also provided as an image display device having the above-mentioned anti-recording polarizing plate and image K. The anti-glare polarizing plate of the present invention has a viewing side on which the layer side is the middle member. The anti-glare polarizing plate of the present invention can display better anti-glare property and exhibit good contrast while effectively preventing the "whitening" and "flash spots" from being displayed on the side of the image display unit 322869 6 201140127. The resulting appearance is reduced in visibility and water resistance is also good. [Embodiment] <Anti-glare polarizing plate> Fig. 1 is a cross-sectional view schematically showing a preferred example of the anti-glare polarizing plate of the present invention. The anti-glare polarizing plate of the present invention has an anti-glare film 1 having a transparent support body 102 and an anti-glare laminated on the transparent support body 102 and having a fine uneven surface. a layer 1〇1; and a polarizing film 1〇4 made of a polyvinyl alcohol-based resin film, which is laminated on the transparent support 1〇2, opposite to the anti-glare layer 101, via the first adhesive layer 10a Side face. The first adhesive layer 103a is composed of a cured product containing a curable composition of an epoxy resin. The anti-glare polarizing plate of the present invention, as exemplified in Fig. 1, may further include a protective film or an optical compensation layer 105 which is laminated on the polarizing film 1〇4 via the second adhesive layer l〇3b. The surface on the opposite side of the anti-glare film 1. The optical compensation layer may be laminated on the protective film. The protective film is laminated on the surface of the polarizing film 1 () 4 opposite to the anti-glare film 1 via the second adhesive layer 10b. The anti-glare polarizing plate of the present invention will be described in more detail below. [1] Anti-glare film (anti-glare layer) The anti-glare film used in the anti-glare polarizing plate of the present invention is provided with an anti-glare layer laminated on a transparent support and having a fine uneven surface (fine uneven surface) Floor. The anti-glare layer is characterized in that the spatial frequency 〇.〇1 is the ratio of the energy spectrum Ηι2 of the surface of the fine concave-convex surface of the 322869 7 201140127 in the heart to the energy spectrum H22 of the height of the fine concave-convex surface in the spatial frequency Hi. In the range of i to 2 ,, the ratio of the spatial frequency (the energy spectrum W of the level of the fine uneven surface in the MW to the energy spectrum H2 of the height of the fine uneven surface in the (4) solution is 〇·1 or less. The period of the fine uneven surface of the anti-glare film is evaluated by the average length of the rough-slit curve elements described in jisb 0601, the average length PSm of the cross-sectional curve elements, and the average length wSm of the curved curve elements. However, in such a conventional evaluation method, it is not possible to correctly evaluate the plurality of periods contained in the surface of the fine uneven surface. Therefore, the correlation between the spot and the fine uneven surface and the correlation between the anti-recording and the fine uneven surface are also It cannot be correctly evaluated that it is difficult to produce an anti-glare film which can suppress both the speckle and the sufficient anti-glare property under the control of values such as RSm, pSm, and WSm. It has been found that in the antiglare film in which the antiglare layer having the fine uneven surface is formed on the transparent support, the fine uneven surface exhibits a specific spatial frequency distribution prescribed by the "energy spectrum of the elevation of the fine uneven surface". , that is, the anti-glare film with an energy spectrum of the elevation of Hi2/H22 in the range of i to 2 且 and HAH22 of less than 0.1, can show better anti-glare performance and prevent the occurrence of whitening. When the visibility is lowered, even when it is used in a fine image display device, no speckle is generated and two contrasts can be expressed. First, the energy spectrum of the level of the fine uneven surface of the antiglare layer will be described. The perspective view of the surface of the anti-glare film of the anti-glare polarizing plate of the present invention having 8 322 869 201140127 is schematically shown. As shown in Fig. 2, the anti-glare film 1 of the present invention is provided with a fine unevenness 2 In the present invention, the "elevation of the fine uneven surface" means that the lowest ς' height of the fine uneven surface in any point P on the surface of the anti-glare film 1 has The height The pseudo-plane (the elevation is based on the reference and is 0/ζπΟ, the linear distance from the main normal direction 5 of the anti-glare film (the above-mentioned virtual plane method, 'direction). As shown in Fig. 2, when x, y) to indicate the orthogonal coordinates in the plane of the anti-glare film 'the elevation of the fine concave surface can be represented by the two-dimensional function h(x, y) of the coordinate (x, y). In the second figure, the projection is 'projected' The surface of the entire anti-glare film is shown on the surface 3. The surface height of the fine uneven surface can be measured from a surface shape measured by a confocal microscope, an interference microscope, or an atomic force microscope (AFM: Atomic F〇rce Micr〇sc〇pe). The horizontal decomposition energy required by the measuring machine is at least 5 μm or less, preferably 2 β m or less, and the vertical decomposition energy is at least 〇. l#m or less, preferably 〇〇1/zm. the following. The non-contact three-dimensional surface shape and the coarse-slit measuring machine suitable for this measurement include the New View 5000 series (manufactured by Zygo Corporation, available from Zygo Co., Ltd. in Japan) and the 3D microscope pl 2300 (manufactured by Sensofar Co., Ltd.) )Wait. Regarding the measurement area, since the decomposition energy of the energy spectrum of the elevation must be 0.1 or less, the measurement area is preferably at least 200 ym x 200 /zm or more, and particularly preferably 500 / zmx 500 or more. Next, a method for obtaining the energy spectrum of the elevation from the two-dimensional function h(x, y) will be described. First, the two-dimensional function H(fx, fy) is obtained from the two-dimensional function h(x, y) by the two-dimensional Fourier transform defined by the following equation (1). 9 322869 201140127 (l)

"(Λ,Λ>S right == L and the sickle is the spatial frequency of the Χ direction and the Υ direction, with =Γ. In addition, the formula (1) (4) pi, i is the early position. The two-dimensional function H(fxfy) performs the square nose 'can find the height of the collision H2rf : y). This energy spectrum H (f x 丄) indicates the spatial frequency distribution of the fine uneven surface of the anti-glare layer. In order to more specifically describe the energy spectrum of the fine concavo-convex surface of the anti-glare layer. The three-dimensional information of the surface shape actually measured by the above-mentioned confocal microscope, interference microscopy, atomic force microscope, etc., is generally obtained as a discrete value, which is obtained at the elevation of a plurality of defects. Fig. 3 is a view showing a state in which the function h (x, w) indicating the elevation is discretely obtained. As shown in Fig. 3, when (x, y) is used to indicate the orthogonal coordinates in the plane of the anti-glare film and is indicated by a broken line When the line on the projection surface 3 of the anti-glare film is divided by the mother Δ X in the χ axis direction and the line divided by Δ y in the y pumping direction, the height of the surface of the fine uneven surface is actually measured. Obtained by the discrete elevation values of each intersection of each dotted line on the technical surface of the glare film. ' The number of elevation values obtained is determined by the measurement range and Δχ and Ay, as shown in Fig. 3. When the measurement range in the x-axis direction is χ=ΜΔχ and the measurement range in the y-axis direction is γ=ΝΔγ, the number of the obtained elevation values is (M+1)X(N+1). As shown in the figure, when the coordinate of the eye point A on the projection surface 3 of the anti-glare film is (jAx, kAy) (here, 'j is 〇 or more μ or less, and k is 〇322869 10 201140127 or more and N or less), Focus on

The elevation can be expressed as a heart). The point on the surface of the anti-glare film P r depends, / then the interval ΔΧ & Δ γ and the horizontal decomposition of the measuring machine L and the accuracy of the evaluation of the fine μ surface, * the above, to, set the range \ and the average 5 or less, and particularly preferably 2/zm or less. Further, ? = is preferably 20 or more as described above, and more preferably 500 y m or more. b In the actual measurement, the number of the elevation indicating the surface of the fine uneven surface is obtained as a discrete function h(x, y) having (值+1)χ(10)) values. Therefore, the discrete function H(fx, fy) is obtained by the discrete Fourier transform defined by the discrete function h (X, y) obtained by the measurement and the following equation (2), and by the discrete function H (fx) Fy) Perform a squaring operation to find the discrete function H (fx, fy) of the energy spectrum. In the formula (2)! An integer of _(New)/2 or more (m+1)/2 or less, and m is an integer of -(NH)/2 or more (N+1)/2 or less. Further, Δίχ and Afy are spatial frequency intervals in the x direction and the y direction, respectively, and are defined by equations (3) and (4), respectively. Δίχ and Afy are equivalent to the horizontal decomposition energy of the energy spectrum of the elevation. Formula (2) (3)

{Ν+Ι)Δ>» ^ (4) 11 322869 201140127 Fig. 4 shows the fine concave-convex surface of the anti-glare layer of the anti-glare polarizing plate of the present invention by a two-dimensional discrete function h(x, y) An example of the map of the elevation. In Fig. 4, the elevation is expressed in terms of white and black gradations (gradati〇n). The discrete function h(x, y) shown in Fig. 4 has 512 χ 512 values, and the horizontal decomposition energy Δ χ and Ay are 1.66 / / m. Further, Fig. 5 is a diagram showing the energy spectrum H2(fx, fy) of the elevation obtained by performing the discrete Fourier transform of the two-dimensional function h(x, y) shown in Fig. 4 in white and black gradations. The energy spectrum H2(fx,fy) of the elevation shown in Fig. 5 is also a discrete function with 512x512 values, and the horizontal decomposition energy Δίχ and Afy are 〇. 0012/ζπΓ丨. In the anti-glare layer of the anti-glare polarizing plate of the present invention, the fine uneven surface of the anti-glare layer of the present invention is composed of irregularly formed irregularities, so that the energy spectrum of the elevation is as follows. In the figure 5, it is symmetrical around the origin. Therefore, the spatial frequency (1) can be obtained from the profile of the 2 origins of the energy spectrum H2 (fx, fy) belonging to the two-dimensional function. The energy spectrum of the elevation in the heart 2, the elevation in the spatial frequency o.Mynf1 The energy spectrum 仏2 of the energy spectrum 仏2 and the spatial frequency/zm 汛2. Fig. 6 is a view showing a cross section at fx = 0 in the energy spectrum H2 (fx, fy) shown in Fig. 5. It can be seen from Fig. 6 that the energy spectrum Hi2 of the elevation of the fine concave-convex surface in the spatial frequency of 0.01/zm-1 is that the energy spectrum H22 of the elevation of the fine concave-convex surface in the spatial frequency is 0.35, and the spatial frequency is G. The energy spectrum H32 of the elevation of the fine uneven surface was 0.00076, and the ratio of Hi2/H2^14 was calculated to be 0.0022 for h32/H22. As described above, in the antiglare layer of the present invention, the ratio of the energy spectrum HlZ of the elevation of the surface of the fine uneven surface in the spatial frequency 〇.β 322869 12 201140127 to the energy spectrum W of the elevation of the spatial frequency 〇〇4# mM is mViL· 2 is set at! To the range of 2 〇. When the ratio of the energy spectrum of the elevation is less than one, it is shown that the long-period concave-convex shape of 1 〇 0 or more contained in the fine uneven surface of the anti-glare layer is small, and the short-period concave shape of less than 25 / / in is not obtained. More. At this time, the mapping of external light cannot be effectively prevented, and sufficient anti-glare performance cannot be obtained. On the other hand, in the case where the energy spectrum ratio of the elevation is higher than that of the HiVH22, the long-period shape of the long period of 100/zm or more contained in the surface of the fine uneven surface is large, and the short period of 25/m is not reached. Less bump shape. At this time, when the anti-glare polarizing plate is applied to a high-definition image display device, there is a tendency to generate a flare. In order to exhibit better anti-glare properties and more effectively suppress the speckle, the ratio of the energy spectrum of the elevation Ηι 2 / Η 22 is preferably in the range of 5 to 18, more preferably in the range of 8 to 15. Further, in the antiglare layer of the present invention, the spatial frequency 卩丨 is the ratio W/H22 of the energy spectrum Ha2 of the elevation of the fine uneven surface of the heart to the energy spectrum W of the elevation of the spatial frequency 0 04". In the following, it is preferably set to 〇. ^. The ratio h32/h22 is 〇·1 or less, and it is shown that the short-period component of less than 10/m in the surface of the fine uneven surface can be sufficiently reduced. Effectively suppresses the generation of whitening. The short-period component contained in the surface of the fine uneven surface is not effectively imparted anti-glare property, but also causes light incident on the surface of the fine uneven surface to become white. the reason. In the conventional anti-glare film described in Japanese Laid-Open Patent Publication No. 2006-053371, the energy spectrum 乩2 and the spatial frequency 〇.04/ of the surface of the fine uneven surface in the spatial frequency 〇〇1/znfl are obtained. The energy spectrum of the elevation in /^ 322869 13 201140127

The ratio of Hz H! /3⁄42 is larger than this case, so there is a problem that flash spots are likely to occur. Therefore, in order to set the ratio Ηι2/Η22 in the range of 1 to 20, the energy spectrum Ηι2 of the level of the fine uneven surface in the spatial frequency of 0.01 βπΓ1 must be lowered. Such an anti-glare film having a fine uneven surface whose energy spectrum Hi1 is reduced by the level of the fine uneven surface in mi, as described later, can be expressed by using a spatial frequency greater than 〇 Mi is 〇. It is ideally produced in a pattern (pat1: ern) which does not have a maximum energy spectrum in the range of mi or less. Here, the "pattern" generally means a second-order tone (for example, binarized white and black image data) or a computer made by a computer for forming a fine uneven surface of the anti-glare film. The image data composed of the gradation above the gradation 'but may also include data that can be converted into the image data in a single sense (the arranging data, etc. can be converted into image data in a single sense, for example, only The coordinates of the coordinates of the pixel and the tone, etc. Thus, the fine uneven surface of the anti-glare film is formed by using a pattern showing an energy spectrum having a maximum value in a range where the spatial frequency is larger than 〇 and is 0.04/ζπΓ1 or less. The energy spectrum Hl2 of the elevation of the fine uneven surface in the spatial frequency can be effectively reduced, and the ratio Hi2/H22 can be set in the range of 1 to 20. Furthermore, in order to obtain the spatial frequency 〇·1 in mi The energy spectrum of the elevation of the surface of the fine concave and convex surface and the energy spectrum 〇.04 of the space frequency 〇.04 from the gamma height ratio 札2/!^ is 防. 1 below the fine anti-glare surface of the anti-glare film, the energy spectrum of the aforementioned pattern , preferably in space The rate is greater than 〇〇4//nfl and has a maximum value in the range of not reaching Ol/zm1. By using a pattern having such an energy spectrum 322869 14 201140127 to form a fine uneven surface of the anti-glare film, the fine concave a in the frequency The surface (4) is high _2: large = will be set to be lower than H3VH22. The method of using such a pattern to form an anti-glare fine uneven surface is preferably used to form a mold having a concave-convex surface, and The method of transferring the uneven surface of the mold to the surface of the resin layer formed on the substrate film (embossing) is exemplified by the fact that the fine uneven surface of the antiglare layer is displayed. , the inclination angle distributor's will show better anti-glare performance, and more = also: whitening. That is, in the anti-glare polarizing plate of the present invention, the anti-glare layer, The surface system contains 95% or more of the inclination angle of 5. When the ratio of the surface with the bevel angle of 5 or less is less than 95%, the inclination angle of the concavity becomes steep, and the light from the circumference is concentrated, and it is easy to = The whole whitening of the surface is whitened. In order to suppress this concentrating effect and to order life :: (The inclination angle of the fine uneven surface is 5. The ratio of the lower surface is preferably better, preferably 97% or more, and more preferably (4) or more. This is the "inclination angle of the fine uneven surface" in the present invention. , = 曰, 展 2 2, at any point p on the surface of the anti-glare film 1, relative to the main normal direction 5, where the unevenness is weighted by the local product / i 6 angle The tilt angle of the surface must be. The tilt angle of the surface of the fine uneven surface can be measured by confocal microscopy, bismuth, bismuth microscopy, and atomic force microscopy (AFM). The three-dimensional information of the surface shape is obtained. Fig. 7 is a schematic diagram for explaining the measurement of the inclination angle of the fine uneven surface 15 322869 201140127. When the specific tilt angle determining method is described, as shown in FIG. 7, first, the eye point A' on the virtual plane FGHI indicated by the broken line is determined to be close to the point a on the X-axis passing through the point A. Almost symmetric points B and D, and points c and E which are almost symmetrical with respect to point A near the point of view A on the y-axis of point eight, and determine corresponding points B, C, D, The point q, R, s, τ of E on the anti-glare film surface. Further, in Fig. 7, the orthogonal coordinates in the plane of the anti-glare film are indicated by (x, y), and the coordinates in the thickness direction of the anti-glare film are indicated by z. The plane FGHI is a straight line passing through a point C on the y-axis and parallel to the X-axis and a line passing through the point E on the 7-axis and parallel to the X-axis, and passing through the point 8 on the <axis and parallel to the y-axis. The straight line and the surface formed by the intersections F, G, Η, I of the straight line passing through the point D on the X-axis and the parallel axis. Further, in the seventh drawing, the position of the actual anti-glare film surface is drawn upward with respect to the plane FGHI, but of course, the actual anti-glare surface can be made due to the difference in the position of the eye point A. The position is above or below the plane FGHI. The tilt angle can be obtained from the three-dimensional information of the measured surface shape, and the point B on the actual anti-glare film surface corresponding to the eye point A and the 4-point B corresponding to the vicinity of the eye point A can be obtained. The four planes of the polygon formed by the total of five points Q, R, S, and T on the actual anti-glare surface of C, D, and E, that is, the four triangles PQR, PRS, psT, and pTQ The average normal vector obtained by averaging the line vectors 6a, 6b, 6c, and 6d (the average normal vector is synonymous with the local normal 6 of the local portion weighted by the unevenness shown in FIG. 2) with respect to the anti-glare film Obtained from the polar angle of the main normal direction. After obtaining the tilt angle for each measurement point, a histogram is calculated. 16 322869 201140127 Fig. 8 is a graph showing an example of a histogram of the oblique angle distribution of the fine uneven surface of the antiglare layer provided in the antiglare film. In the graph shown in Fig. 8, the horizontal axis is the inclination angle ' and is 〇. Split for the scale. For example, the leftmost straight column indicates that the tilt angle is 〇 to 〇.5. The distribution of the set of ranges is then moved to the right, and the angle is increased by 〇. 5«. In Fig. 8, the lower limit of the value displayed on each of the two scales on the horizontal axis, for example, the portion of "1" on the horizontal axis indicates that the tilt angle is 1 to 1.5. In addition, the vertical axis represents the distribution of the inclination angle, and is a value of 1 (1% by weight) in total. In this case, the angle of inclination is 5. The ratio of the following is approximately 1%. The fine uneven surface for producing the antiglare layer contains 95% or more of an inclination angle of 5. The antiglare film of the following surface is preferably a method of producing a mold having a concave-convex surface using the pattern, and transferring the uneven surface of the mold to the surface of the resin layer formed on the base film (embossing) law). In such an embossing method, the inclination angle of the fine uneven surface of the antiglare layer is determined by the manufacturing conditions of the mold having the concave convex surface. Specifically, the control can be performed by changing the etching amount of the etching step in the method of manufacturing the mold described later. That is, by reducing the surname of the first surname step, the height difference of the formed first surface concavo-convex shape can be reduced, and the inclination angle can be increased by 5. The ratio of the following faces. In order to obtain an angle of inclination of 5, including 95% or more. The anti-glare film on the surface of the fine uneven surface of the following surface preferably has an etching amount of 2 to 8 μm in the second etching step. When the etching amount is less than 2/m, the metal surface hardly forms an uneven shape and becomes a nearly flat mold. Therefore, the anti-glare film produced by using the mold cannot exhibit sufficient anti-glare property. Further, when the etching amount exceeds 8/z in, the height difference of the uneven shape formed on the metal surface is increased, and the face having an inclination angle of less than or equal to 95% can be obtained by 322869 17 201140127. The anti-glare film produced by using this mold has a whitening effect. Further, the inclination angle of the fine uneven surface of the antiglare layer can be controlled by the etching amount of the second etching step. By increasing the etching amount in the second etching step, it is possible to effectively passivate the portion where the surface of the second surface irregular surface is steeply inclined, and to increase the inclination angle to 5. The ratio of the following faces. In order to obtain an angle of inclination of 5, including 95% or more. The following details

The anti-glare film on the surface of the micro-concave surface is preferably in the range of I to 20 " m in the etching amount in the second etching step. When the etching amount is small, the surface shape of the unevenness obtained by the i-th etching step is affected by the effect of the age, and the optical characteristics of the anti-glare film obtained by transferring the convex shape are not good. On the other hand, when the amount of etching is too large, the uneven shape almost disappears and becomes a nearly flat mold, so that the anti-glare property cannot be displayed. In the present invention, the antiglare layer may be composed of a hardening type tree hardened material such as a photocurable resin, and the towel is made of a photocurable resin (tetra). The anti-glare layer may also be dispersed with fine particles having a refractive index different from that of the hardened resin or the thermoplastic resin. The scattering of the particles can be more effectively suppressed by dispersing the particles. s When the fine particles are dispersed in the antiglare layer, the average particle diameter of the fine particles is preferably more than or equal to 6 (10) or more. Further, the average degree of the fine particles can be set to W or less, preferably the following. When the average particle diameter is lower than ^ _, the intensity of the scattered light on the wide-angle side caused by the particles rises, and the anti-glare polarizing plate is advantageous in the image display (4), which tends to be low. Further, the refractive index of the fine particles _ hardened material of the hardened resin or the refractory of 322 869 18 201140127 plastic resin is less than 0.98, and the refractive index ratio 仏 / 〜 is preferably 〇. 93 or more, or lh r 〇1 or more 1,04 or less, especially preferably 〇. 97 or more 0.98 or higher than 1. 〇4 hours ^ upper h 〇3 or less. When the refractive index ratio nb/ni• is lower than that of the 〇. 93 grain, the hardened or thermoplastic resin of the anti-hardening resin increases the tilt ratio of the decrease in the light transmittance, and as a result, the backscattering is increased, and the total bleed is increased. Increase, apply to ^. A decrease in the total light transmittance causes a haze of the anti-glare to occur when the refractive index is less than the n^ image. In addition, when the internal scattering % exceeds 〇.98 and does not reach 丨.01, the layer due to the microparticles is used to obtain the sensation of the smear, and the effect of imparting the predetermined scattering characteristics to the anti-glare particles. 'It may be necessary to increase the amount of particles added. In the case of parts by weight, A 2 is suspended in an amount of 50 parts by weight or less with respect to the curable resin or the thermoplastic resin 100. It is preferable that the content of the fine particles is 40 or less w. More than the amount. When the micro-synthesis is more than 1 part by weight, it is particularly preferable to be 15 heavy-spot suppression effect; if it is less than 1G weight, the particle-induced flash = particle material preferably satisfies the above preferred Refractive index ratio. In the present invention, the formation of the _ layer is preferably carried out by using UV embossing or palpitations. In this case, most of the cured products of the ultraviolet curable resin exhibit a refractive index of about 15 Å. Therefore, the design of the antiglare film can be selected as the fine particles from the range of the refractive index of U0 to 1.60. The particles are preferably those which are resin beads and which are almost spherical. Examples of preferred resin particles are as disclosed below. Melamine particles (refractive index 1.57), 322869 19 201140127 poly(meth)acrylate particles (refractive index 丨49), decyl methacrylate/styrene copolymer resin particles (refractive index 1.50 to 1.59), polycarbonate Particles (refractive index 1.55), polyethylene particles (refractive index 1.53), polystyrene particles (refractive index 丨.6), polyethylene particles (refractive index, siliC0ne resin particles) (Reflective Index 146), etc. (Transparent Support) The transparent support used in the antiglare film is preferably a resin film which is substantially optically transparent, and examples thereof include a cellulose triacetate film and a polyparaphenylene hydride. I. Ethyl ester film, polydecyl methacrylate film, polycarbonate film, non-crystalline cyclic poly-halogen with a norbornene compound as a monomer, and the like. The thermoplastic resin film 'may be a solvent-washed film (s〇lven1; cast fUm) or an extruded film, etc. These resin films may also be subjected to uniaxial stretching or biaxial stretching, etc. Stretching processor. The thickness of the transparent support, from the viewpoint of handling Preferably, it is 2 〇 ym or more, and it is preferably 100 # m or less from the viewpoints of reduction in thickness and cost of the image display device, etc. The thickness of the transparent support is preferably θ β m or more and 80 // m or less. (Method for Producing Anti-Glare Film) The anti-glare film used in the anti-glare polarizing plate of the present invention is preferably produced by the following steps (A) and steps (manufacturing method: 20 322869 201140127 (A) a step of producing a mold having a concave-convex surface according to a pattern showing an energy spectrum having a maximum value in a range where the spatial frequency is larger than Ο/znf1 and less than 0.04/ζπΓ1; and (Β) the uneven surface of the mold And a step of transferring to a surface of a resin layer such as a curable resin such as a photocurable resin or a thermoplastic resin, which is formed on a transparent support. The space frequency is greater than O/ζπΓ1 and is 0. (ΜμπΓ1 or less) A pattern having an energy spectrum of a maximum value is not included in the range, and a fine uneven surface having the above-described specific spatial frequency distribution can be formed with high precision. Further, a mold having a concave-convex surface is formed according to the pattern, and the mold is formed A method (embossing method) in which the uneven surface of the film is transferred to the surface of the resin layer formed on the transparent support, and an anti-glare layer having a fine uneven surface can be obtained with high precision and good reproducibility. "Pattern" generally means a computer-made 2nd-order tone (for example, binarized white and black image data) or a 3rd-order tone or more for use in forming a fine uneven surface of an anti-glare film. The image data composed of the gradation, but may also include data (array data, etc.) that can be converted into the image data in a single sense. The data can be converted into image data in a single sense, for example, only the coordinates of each pixel are saved. And the information of the tone, etc. The energy spectrum of the pattern used in the above step (Α), for example, in the case of image data, can be obtained by converting the image data into a 2nd-order binarized image data by a two-dimensional function g(x, y). The tone of the image data is represented, and the obtained two-dimensional function g(x, y) is subjected to discrete Fourier transform to calculate a two-dimensional function G(fx, fy), and then the obtained two-dimensional function G(fx, fy) Carrying a square transport 21 322869 201140127 and looking for it. Here, x and y represent orthogonal coordinates in the plane of the image data, and fx and fy respectively represent the spatial frequency in the X direction and the spatial frequency in the y direction. As in the case of obtaining the energy spectrum of the elevation of the fine concave-convex surface, the two-dimensional function g(x, y) of the tone is generally obtained as a discrete function when the energy spectrum of the pattern is obtained. At this time, the energy spectrum can be calculated by discrete Fourier transform as in the case of obtaining the energy spectrum of the elevation of the fine uneven surface. Specifically, the discrete function g (h, W ' is calculated by the discrete Fourier transform defined by the equation (5), and then the obtained discrete function G(ff ) is subjected to the flat energy spectrum _. (5) Medium (4) The number of rounds is early. In addition, Μ is the number of pixels in the X direction, the number of pixels in the direction, 1 is an integer of -M/2 or more and M/2 or less, and m is an integer of /2 or more and N/2 or less. Furthermore, W is the spatial frequency interval 'in the χ direction and the y direction, respectively, and is defined by the equations (6) and (7). The equations (8) and (7) are the horizontal decomposition energy in the X-axis direction and the y-axis direction, respectively. When the pattern is image data, ^ and ^ are respectively equal to the length of the U-axis direction of the 像素 pixel and the length of the y-axis direction, that is, when the pattern is made as 64 〇 _ (four) image data ' Δ χ = Δ γ = 4 / ζ η 'When the image data of the drawing is produced, the formula (5) (6) 322869 22 201140127 Fig. 9 is a view showing a part of the image data of the pattern which can be used for producing the anti-glare film of the present invention, which is a step The two-dimensional discrete function g(x, y) is used to represent the image. The image data of the pattern shown in Figure 9 is 2mm x 2inm and is 1280. 0dpi is produced. Figure 10 shows the energy spectrum G2 (fx, fy) obtained by discrete Fourier transform of the two-dimensional function g(x, y) of the tone shown in Fig. 9 in white and black gradation. Since the pattern shown in Fig. 9 is irregularly arranged dots, the energy spectrum G2(fx, fy) is symmetrical about the origin as shown in Fig. 10. The spatial frequency of the maximum value of the energy spectrum G2(fx,fy) of the display pattern can be obtained from the profile passing through the origin of the energy spectrum. The eleventh figure shows the energy spectrum G2 (fx, shown in Fig. 10). Fy) is a graph of the cross section at fx = 0. It follows that the pattern shown in Fig. 9 has a maximum value in the spatial frequency of 0. 045 //m_1, but is greater than 0/znf1 and is 0. In the range below 04/ζπΓ1, there is no maximum value. The energy spectrum G2(fx, fy) of the pattern for making the anti-glare film has a maximum value in a spatial frequency range greater than 0 to nf1 and 0.04# πΓ1 or less. At this time, the fine uneven surface of the obtained anti-glare film does not exhibit the above-described specific spatial frequency distribution, so that the elimination of the flare and the sufficient anti-glare property cannot be achieved at the same time. Energy spectrum G2 (fx, fy) a pattern having no maximum value in a spatial frequency range greater than O/ζπΓ1 and less than 0.04/znf1, for example, as in the pattern shown in Fig. 9, a plurality of points can be arranged irregularly and uniformly In addition, irregularly arranged dot diameters may be one or plural. In addition, in a pattern in which a plurality of dots are irregularly arranged, the spectrum can be displayed in the spatial frequency as the reciprocal of the average distance between the dots. A maximum value (maximum value in the smallest spatial frequency where the spatial frequency is greater than 23 322869 201140127). Since the spectrum G2(fx,fy) does not have a pattern of maximum values in a range larger than 〇"m-丨 盔 helmet ^ w -丨 and is below 0. 〇 4 (10), it is only necessary to make the average distance of the off 25 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作 制作The ratio of energy spectrum ...2 is set to 〇. ^ Below, the energy spectrum of the pattern is preferably a maximum value in the range where the spatial frequency is greater than 〇〇4 to ^ and not up to Ο.Ι#1. Such a pattern can be obtained by making the average distance between the dots larger than 1 〇 / im and not within the range of 25 / ^. Further, it can also be made by irregularly arranging such a plurality of dots. In the pattern, a pattern obtained by removing a high-pass filter having a low spatial frequency component below a specific spatial frequency is used. Further, it may be used in a pattern created by irregularly arranging a plurality of dots. By removing low spatial frequency components below a certain spatial frequency and above a specific spatial frequency A pattern obtained by a bandpass filter of a high spatial frequency component. As shown in Fig. 11, the energy spectrum of a pattern created by a plurality of dots is irregularly arranged, and indicates a dot diameter of a point to be arranged. And the average distance between the points depends on the maximum value 'by passing the patterns through the aforementioned high-pass filter or the aforementioned band-pass filter, unnecessary components can be removed. The energy of the pattern through the high-pass filter = or band-pass filter Since the spectrum 'has been removed by the filter, it has no maximum value in the range where the spatial frequency is greater than Oy m_1 and is less than 0.04#111_1. In addition, it can be more efficiently produced in the spatial frequency of 24 322869 201140127. a pattern having a maximum value in a range of more than 0.04/znf1 and not reaching 〇·1. Here, when the high-pass filter described above is used, in order to remove a spatial frequency greater than 0 # nf1 and a range of 〇·04" πΓ1 or less The maximum internal frequency, the upper spatial frequency of the removed low spatial frequency component is preferably 0.04 ζ π Γ 1 or less. In addition, when the aforementioned band pass filter is used, in order to remove the spatial frequency greater than 0/zm _1 is the maximum value in the range below Μ.ίΜμπΓ1, and the upper limit spatial frequency of the removed low spatial frequency component is better when the spatial frequency is greater than 0. 04βπΓ1 and does not reach the maximum value in the range of 0.1 enf1. 0/04/zm_1 or less, the lower-order spatial frequency of the removed high-space frequency component is preferably 0.08 ζ π Γ 1 or more. When a pattern is formed by a high-pass filter or a band-pass filter, filtering is performed. The pattern in front of the device may also be a pattern having an irregular brightness distribution by using a random number or a virtual random number generated by a computer to determine the shade. The details of the method of producing a mold according to the pattern obtained in the above manner will be described in detail later. The above step (Β) is a step of forming an antiglare layer having a fine uneven surface on a transparent support by an embossing method. The embossing method can be exemplified by a UV embossing method using a photocurable resin and a hot embossing method using a thermoplastic resin, and in terms of productivity, it is preferable that the embossing method β embossing method is A method in which a photocurable resin layer is formed on a surface of a transparent support, and the photocurable resin layer is pressed against the uneven surface of the mold to be cured, thereby transferring the uneven surface of the mold to the photocurable resin layer . More specifically, a coating liquid containing a photocurable resin is applied onto a transparent support of 322869 25 201140127, and the coated photocurable resin is adhered to the uneven surface of the mold, and is transparent. The support body side is irradiated with light such as ultraviolet rays to cure the photocurable resin, and then the transparent support body on which the cured photocurable resin layer is formed is peeled off from the mold, whereby the uneven shape of the mold is transferred. An anti-glare film to a light-curable resin layer (anti-glare layer) after curing. The photocurable resin in the case of using the uv embossing method is preferably an ultraviolet curable resin which is cured by ultraviolet rays, or an optically curable resin which is appropriately selected may be used in combination with an ultraviolet curable resin. A UV-resistant resin that is hardened by visible light. The type of the ultraviolet curable resin is not particularly limited, and a commercially available suitable product can be used. A preferred example of the ultraviolet curable resin is one or two or more kinds of polyfunctional acrylates such as trimethylolpropane triacrylate or pentaerythritol tetraacrylate, and Irgacure 907 (manufactured by Chiba Specialty Chemicals Co., Ltd.), Irgacure 184. (made by Chiba Specialty Chemicals),

A resin composition of a photopolymerization initiator such as Lucirin TP (manufactured by BASF Corporation). The coating liquid can be prepared by adding fine particles, a solvent, or the like to the ultraviolet curable resin as needed. (Method for Producing Mold for Manufacturing Anti-Glare Film) Hereinafter, a method for producing a mold used for producing an anti-glare film will be described. The method for producing a mold for use in the production of the anti-glare film for use in the anti-glare polarizing plate of the present invention is not particularly limited, but is excellent in precision and reproducible in order to obtain a specific surface shape obtained according to the above pattern. Preferably, the fine uneven surface is preferably produced, and preferably contains (1) a first plating step, (11) a polishing step, (iii) a photosensitive resin film forming step, (iv) 26 322869 201140127 exposure step, (v) a developing step, (vi) a first etching step, (vii) a photosensitive resin film peeling step, and (viii) a second plating step. Fig. 12 is a view schematically showing a preferred example of the first half of the method for manufacturing a mold. Fig. 13 is a view schematically showing a preferred example of the latter half of the method for manufacturing a mold. In Figs. 12 and 13, the cross section of the mold in each step is schematically shown. Hereinafter, each step of the method of manufacturing the mold will be described in detail with reference to Figs. 12 and 13. (i) First plating step In this step, copper or nickel is applied to the surface of the substrate used in the mold. As described above, by applying the key copper or the nickel to the surface of the substrate for a mold, the adhesion and gloss of the chrome plating in the subsequent second plating step can be improved. Since copper plating or nickel plating is highly coated and has a high smoothing effect, it is possible to embed a fine unevenness or a cavity of a substrate for a mold, and to form a flat and shiny surface. By the characteristics of such copper plating or nickel plating, even if chrome plating is applied in the second plating step to be described later, it is possible to eliminate the occurrence of minute irregularities or voids on the substrate. The surface of the ore is roughened, and since the coating of copper plating or nickel plating is high, the occurrence of fine cracks can be reduced. The copper or nickel used in the first plating step may be a copper-based alloy or a nickel-based alloy in addition to a pure metal. Therefore, the term "copper" in the present specification includes copper. And the meaning of copper alloy, in addition, "nickel" contains the meaning of nickel and nickel alloy. Copper plating and nickel plating can be carried out by electrolytic plating or electroless plating, respectively, and are generally electrolytically plated. 27 322869 201140127 When the bond copper or _ is applied, when the t-woven layer is too thin, the influence of the underlying surface cannot be completely excluded, so the thickness is preferably 50 (four) or more. The upper limit of the thickness of the bell coating is not limited. In terms of cost, etc., it is generally about 5 〇〇 (10). The metal material constituting the base material for the mold is exemplified by the name, the iron, and the like from the viewpoint of cost. In addition, in terms of handling convenience, it is especially good for lightweight. The IS or iron referred to herein may be an alloy mainly composed of iron or iron, in addition to pure metal. Further, the shape of the substrate for a mold may be any shape conventionally used in the field, and may be, for example, a cylindrical or cylindrical roller in addition to a flat plate shape. When a mold is produced using a roll-shaped base material, there is an advantage that an anti-glare film can be produced in a continuous roll shape. (ii) Grinding step In the subsequent polishing step, the surface of the substrate subjected to copper plating or nickel plating in the above-mentioned second plating step is ground. Preferably, the surface of the substrate is ground to a state close to the mirror surface by this step. Since this is a metal plate or a metal roll which becomes a base material, in order to achieve a desired precision, it is often subjected to machining such as cutting or grinding, and thus processing marks remain on the surface of the substrate even in the case where copper plating or nickel plating is applied. These processing marks may also remain, # and, in the plated state, the surface may not be completely smooth. In other words, even if the steps described later are applied to the surface on which the deep processing marks remain, the irregularities such as the processing marks may be deeper than the irregularities formed after the respective steps, and the possibility of residual processing marks may be affected. When using these molds to make an anti-glare film, it may cause unpredictable effects on optical characteristics 322869 28 201140127. In Fig. 12(a), a flat substrate 7 for a mold is schematically shown, and in the first shovel step, the surface is subjected to ore or nickel plating (copper or plating formed in this step) The layer of nickel is not shown)' and then has the state of the mirror-polished surface 8 by the grinding step. The method of polishing the surface of the substrate to which copper plating or nickel plating is applied is not particularly limited, and any of a mechanical polishing method, an electrolytic polishing method, and a chemical polishing method can be used. The mechanical polishing method may, for example, be a super processing method, a lapping method, a fluid polishing method, a buffing polishing method or the like. Further, the surface 7 of the substrate for the mold can be formed into a mirror surface by mirror cutting using a cutting tool. The material and shape of the cutting tool at this time are not particularly limited, and a superhard knife or cubic boron nitride can be used ((: 1113丨(:13〇1«〇11111圩1(16, CBN) knife, ceramic knife, A diamond blade or the like is preferably a diamond knife from the viewpoint of the processing accuracy. The surface roughness after polishing is preferably equal to or less than ra according to the predetermined line width roughness of JIS B 〇6〇1. More preferably, it is less than or equal to 5. When the average center roughness Ra of the center line after grinding is larger than 〇. ^ When the melon is used, the surface roughness of the surface of the finally formed mold may remain. The lower limit of the center line average accuracy Ra is not particularly limited, and can be appropriately determined in consideration of processing time, processing cost, etc. (iii) The photosensitive resin film forming step is carried out in the solvent of the subsequent photosensitive resin. The solution in which the photosensitive resin is dissolved is applied to the surface 8 of the surface of the mold recording material 7 which has been mirror-polished by the above-mentioned polishing step, and dried by adding 322869 29 201140127 to form a photosensitive resin film. Figure 12 (b) In the state in which the photosensitive resin film 9 is formed on the surface 8 to be polished of the substrate 7 for a mold, the photosensitive resin can be used as the photosensitive resin. For example, it can be cured as a photosensitive portion. The negative photosensitive resin of the nature can be used as a monomer or prepolymer, bisazide and diene for the acrylic acid having a propylene or methyl propyl group in the molecule. A mixture of rubber, a polyvinyl cinnamate compound, etc. Further, as a positive photosensitive resin having a property of eluting a photosensitive portion by development and leaving only an unsensitized portion, a resin or a varnish resin (novolac) can be used. In addition, as the photosensitive resin, various additives such as a sensitizer, a development accelerator, an adhesion modifier, and a coatability modifier may be blended as needed. When the surface 8 to be polished of the substrate 7 is used for the mold, in order to form a good coating film, it is preferably diluted with a suitable solvent to apply it, and a cellosolve solvent or a solvent: alcohol solvent can be used. Ester system Agents, alcohol-based solvents, _ solvents, highly polar solvents, etc. The method of coating the photosensitive resin solution can be applied using a meniscus (meniscus CGating), spray coating (f_tain ⑺ cuebid), dip

A commonly known method such as bubble coating, spin coating, roll coating, wire bar coating, air knife coating, knife coating, and curtain coating. The thick sound of the coating film is set to be in the range of 1 to 100 after drying. A (iv) exposing step is to expose the above-mentioned energy spectrum to the above-mentioned photosensitive resin film in the subsequent exposure step by using the above-mentioned energy spectrum in a frequency range greater than 〇 and below (4) without a maximum value, 322869 30 201140127 The photosensitive resin film 9 formed in the step. The light source used in the exposure step can be appropriately selected in accordance with the photosensitive wavelength or sensitivity of the applied photosensitive resin, for example, g-ray of a high-pressure mercury lamp (wavelength··436 nm), h-ray of a high-pressure mercury lamp (wavelength: 405nm), i-ray (wavelength: 365nm) of high-pressure mercury lamp, semiconductor

Laser (wavelength: 830nm, 532 nm, 488 nm, 405 nro, etc.), YAG

Laser (wavelength: 1064 nm), KrF excimer laser (wavelength: 248 nm), ArF excimer laser (wavelength: 193 nm), F2 excimer laser (wavelength: 157 nm), and the like. In order to accurately form the surface uneven shape of the mold and even the surface uneven shape of the anti-glare layer, in the exposure step, the pattern is preferably exposed to the photosensitive resin film in a state of precise control, specifically Preferably, the computer towel drawing (4) is image data, and according to the image data, the pattern is drawn on the photosensitive resin film by laser light emitted from a computer-controlled laser head. For laser rendering, a laser-printing device for printing can be used. Such a laser depiction device can be enumerated

Laser Stream FX (manufactured by Think Laboratory Co., Ltd.). In Fig. 12(c), the state in which the pattern is exposed to the photosensitive resin film 9 is schematically shown. When the photosensitive resin film is formed of a negative photosensitive resin, the exposed region 10 is subjected to a crosslinking reaction of the resin by exposure to lower the solubility of the developer to be described later. Therefore, the unexposed area 11 in the developing step is dissolved by the development, and only the exposed area 10 remains on the surface of the substrate to become a mask. On the other hand, when a photosensitive resin film is formed by a positive photosensitive resin, the exposed region 1 〇 is the solubility solution of the developing solution described later by 322869 31 201140127, and only the uncovered region U is used by the (four) liquid solution. The dissolution (7) development step is applied to the surface of the substrate to form a mask. In the subsequent development step, when the calendered resin film 9 is used, the unexposed negative-type photosensitive resin is exposed as a sensation in the exposed (four) domain 1G, and is developed as a mask in the last step. On the substrate, and in the continuation of the first nature, you also become, and, on the other hand, when using the positive photosensitive display "" resin film 9 only the exposed area 10 will be: = solution, the unexposed area U remains on the substrate for the mold, and functions as a mask in the subsequent step (10). The developer used in the step can be used as known. For example, inorganic water such as ammonia Test class; ethylamine, ::, read, sodium, n-propylamine, etc., second amines, dioxins, amines such as diethylamine, di-Z-ethanolamine, triethanolamine, etc. Money, nitrogen bottom; ί t et al! It is a four-stage salt of trimethyl ethyl ammonium; etc.; an aqueous solution of each solvent; and a steamer in an organic developing step such as diphenylbenzene and toluene^ The method of nozzle fog development, brush shadow, etc. The shadow method is not particularly limited, and a brush development can be used. In the ultrasonic display 12 (d), the photosensitive resin film 9 schematically shows a state in which development processing is performed using a negative photosensitive resin. Fig. 12 (c) 322869 32 201140127 10 (d) 11 Dissolving of the mash Only the exposed region 1 remains on the surface of the substrate to form the mask 12. In the 12th, the positive photosensitive resin is used as the photosensitive resin film 9 to dissolve the developer, only = two: 'The exposed area 10 will be, „ ^ , the unexposed area 11 remains on the surface of the substrate to become the mask 12. (vi) The first step of engraving is carried out in the subsequent step (4). After the above development step, the inductive resin film (4) remaining on the surface of the mold wire is used as a mask, mainly for the unmasked portion. The secret material 崎 _, and in the polished key surface opening / recessed ώ 13 (a) in the 'schematically shows the first button engraving step and mainly the untouched 13 of the mold 7 The substrate 7 for the mold in the lower portion of the J-shaped mask 12 is not left from the surface of the substrate for the mold, but is also carried out from the unshielded crucible 13 as the surface is polished (4). Because of A, in the vicinity of the boundary between the mask 12 and the unshielded portion 13, the substrate 7 for the lower portion of the mask 12 is also sideways. Hereinafter, in the vicinity of the boundary between the mask 12 and the unmasked portion 13, the substrate 7 for the mold at the lower portion of the mask 12 is also referred to as side etching by the remainder. The first side frequency silver etching process is generally performed by using a gasified iron (FeCh), copper chloride (CiiCh), an etching solution (Cu(10)(10)2), etc., by etching the metal surface, but hydrochloric acid or A strong acid such as sulfuric acid or a reverse electrolytic etching by applying a potential opposite to that of electrolytic plating. The concave shape formed on the substrate for a mold during the etching treatment is not the same as the type of the underlying metal, the type of the photosensitive resin film, and the etching method, etc., but it cannot be generalized, but when the etching amount is 1 When 〇#m or less, it is possible to carry out the engraving in a substantially isocratic manner from the metal surface which is in contact with the liquid. The amount referred to herein refers to the thickness of the substrate removed by etching. The amount of the first step of the engraving step is preferably i to 5 〇 _, and particularly preferably 2 to 10 / / m. When the amount of the touch is less than 1/m, the metal surface is hardly formed into a concave-convex shape and becomes a nearly flat mold, so that the anti-glare is not displayed. Further, when the etching amount exceeds 5 Å, the south-lower difference of the concave-convex shape formed on the metal surface is increased, and the image display apparatus using the anti-glare film produced by the obtained mold may cause whitening. In order to obtain an anti-glare film having a fine uneven surface including a surface having an inclination angle of 5 or less of 95% or more, the amount of the first step is preferably 2 to 8 mm. The etching process of the i-th etching step can be performed by one (four) etching process, or the etching process can be divided into two or more times. When the etching treatment is carried out in two or more steps, the total of the etching amounts of the etching treatment of two or more times is preferably within the above range. (vii) Photosensitive resin film peeling step In the subsequent photosensitive resin film peeling step, the photosensitive film which is used as a mask in the second etching step is completely dissolved and removed. Sensitive tree Lai Qing stepping money, _ liquid to dissolve the inductive resin film. The peeling liquid can be the same as the above (iv) liquid. By changing the pH, temperature, concentration, and immersion time of the stripping solution, etc., when the negative-sensitive resin is used, the photosensitive resin film of the exposed portion is completely dissolved, and when the f-type photosensitive tree is used, the non-exposed portion is used. The sense of the new tree is completely removed and removed. _ 感纽树赖_Steps of the _ method and 322869 34 201140127 _ shadow, spray development, brush development, super-tone special restrictions, can be used for dip wave development. In the case of 13 ® (5), the photosensitive resin film used in the first step (4) step *' green is also used to remove the < state. The first surface uneven shape 15 is formed on the surface of the substrate for a board by using the decoration of the mask 12 made of a photosensitive resin. (viii) The second plating step is followed by purifying the uneven shape of the surface by forming the uneven surface (the first surface uneven shape is made of chrome chrome). In Fig. 13 (C), The chrome-plated layer 16 is formed on the first surface uneven shape 15 formed by the closing process of the first step, and forms a surface in which the unevenness is more passivated than the i-th convex-amplitude 15 (the state of the secret surface (7) ί 肖 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳 佳Known as so-called lustrous chrome or ^ ^ • 良好 良好 良好 良好 良好 良好 chrome plating. Chrome plating is generally used by X':: ° Hai plating bath can use chromic anhydride (Cr 〇 3) with a small amount of sulfuric acid', by °The current density and the electrolysis time of the circumference can control the thickness of the shovel chrome. v In the second forging step, the plating other than the chrome is not good. This is due to the hardness in the (four) coating. Or low wear resistance, so that the durability of the mold is reduced, and it may cause 0 convex wear or damage during use. It is difficult to obtain sufficient anti-glare film to prevent glare function. In addition, the possibility of defects on the anti-glare film is also high. In addition, the surface grinding after plating is also not good. After the second plating step, the step of polishing the surface is not provided, and the uneven surface after the application of Zhong Ming' is directly used as the uneven surface of the mold transferred to the surface of the resin layer on the transparent support. Since the polishing produces a flat portion on the outermost surface, there is a possibility that the optical characteristics are deteriorated, and in addition, the control factor of the shape is increased, and the shape control such as reproducibility is difficult to be performed. For the surface on which the fine surface irregularities are formed, Qian Ming·' can passivate the four convex shape and obtain a mold whose surface hardness is improved. At this time, the degree of passivation of the unevenness is due to the type of the underlying metal, by the first The size and depth of the bumps obtained by the step-cutting green, as well as the type and thickness of the plating, cannot be generalized, but the biggest factor in controlling the degree of passivation is still thick and thick. When the thickness of the chrome plating is thin, the effect of passivating the surface shape of the unevenness obtained before the chrome plating is insufficient, and the optical characteristics of the anti-glare film obtained by transferring the uneven shape are not good. When the thickness of the coating is too thick, in addition to the deterioration of productivity, there is a problem that it is called odule &protrusion; the mineral deposit defect is not good. Therefore, the thickness of the chrome-plated thickness is especially good. The chrome plating layer formed in the second plating step is preferably formed so that the Vickers hardness is 800 or more, and more preferably formed to be 1 Å or more. This is because when the Vickers hardness of the chrome plating layer is less than 800, the durability of the mold is lowered and the hardness of the chrome plating layer is lowered, and the plating bath composition, the electrolysis condition, and the like may be abnormal during the plating treatment. Sexuality 322869 36 201140127 High 'and the possibility of a lesser impact on the occurrence of defects. Further, preferably, between the (vii) photosensitive resin film peeling step and the (VI11) second plating step, the second etching is performed by passivating the uneven surface formed by the second etching step by passivation. step. In the second etching step, the first surface uneven shape 15 formed by the first surname step by the use of the photosensitive resin film as a mask is made passivated by the surname process. By the second meal processing, the portion of the surface of the first surface uneven shape 15 formed by the first etching step can be eliminated, and the optical characteristics of the anti-glare film produced by using the obtained mold can be improved. Good direction changes. In the fourteenth aspect, the first surface uneven shape 15 of the mold base material 7 is passivated by the second etching treatment, and the portion having a steep surface inclination is purified to form a gentle surface inclination. The state of the second surface uneven shape 18 is obtained. In the etching process of the second etching step, similarly to the second etching step, generally, ferric chloride (FeCL) liquid, copper chloride (CuCl2) liquid, alkali money etching solution (Cu(NH3)4Ch), etc. are used. The surface is subjected to rot, but a strong acid such as hydrochloric acid or sulfuric acid may be used, or reverse electrolytic etching may be performed by applying a potential opposite to that at the time of electrolytic plating. The degree of passivation of the unevenness after the etching treatment differs depending on the type of the underlying metal, the etching method, and the size and depth of the unevenness obtained by the first etching step, and cannot be generalized, but the maximum factor for controlling the degree of passivation is The amount of etching. Here, the amount of the remaining amount is the same as the step of the first step, and refers to the thickness of the substrate removed by the engraving. When the amount of silver engraving is small, the effect of passivating the surface shape of the concavities and convexities obtained by the step 322869 37 201140127 is insufficient, and the optical characteristics of the anti-glare film obtained by transferring the concavo-convex shape are not good. . On the other hand, when the amount of etching is too large, the uneven shape almost disappears and becomes an almost flat mold, so that the anti-glare property cannot be displayed. Therefore, the etching amount is preferably in the range of 1 to 50 μm, and further, in order to obtain an anti-glare film having a fine uneven surface including 95% or more of the surface having an inclination angle of 5 or less, it is particularly preferably 4 to 20 / m range. The etching treatment in the second etching step may be performed by one etching process as in the first etching step, or may be performed by dividing the etching process into two or more times. Here, when the etch processing is performed twice or more, the total of the etching amounts of the etching treatment of 2 or more times is preferably within the above range. [2] Polarizing film Next, a polarizing film used in the anti-glare polarizing plate of the present invention will be described. In the present invention, a polarizing film in which a dichroic dye is adsorbed to a uniaxially stretched polyvinyl alcohol-based resin film is preferably used. The polyvinyl alcohol-based resin constituting the polarizing film is obtained by saponification of a polyvinyl acetate resin. In the case of the polyvinyl acetate resin, in addition to the polyvinyl acetate which is a homopolymer of vinyl acetate, a copolymer such as vinyl acetate and another monomer copolymerizable with the vinyl acetate can be exemplified. Examples of the other monomer copolymerizable with vinyl acetate include unsaturated carboxylic acids, olefins, vinyl esters, and unsaturated sulfonic acids. The degree of saponification of the polyvinyl alcohol-based resin is usually from 85 to 100 mol%, preferably from 98 to 100 mol%. The polyvinyl alcohol-based resin may be further modified, and for example, polyvinyl acetal modified with aldehydes (polyvinyl 38 322869 201140127 formal) or polyvinyl acetal may be used. The polymerization degree of the polyalcohol resin is usually from 1,000 to 10,000, preferably from 15 to 10,000. The polarizing film ' used in the present invention can be produced by the following steps: a step of uniaxially stretching the polyvinyl alcohol-based resin; dyeing the polyvinyl alcohol-based resin film with a dichroic dye and making the two A dream of chromatic dye adsorption; a step of treating a polyvinyl alcohol-based resin film having a dichroic dye adsorbed thereon with a boric acid aqueous solution; and a step of washing with a boric acid aqueous solution. The uniaxial stretching can be carried out by dyeing according to the dichroic dye, simultaneously with the dyeing by the dichroic dye, or after the dyeing by the dichroic dye. The single axis (four) can be followed by a single-shot recording after dyeing according to the dichroic color

Wet stretching by stretching in a swollen state. The draw ratio is generally 4 to 8 times.

For example, an aqueous solution of a coloring pigment can be used. Two-color residue dichroic dye. In the case of one element, a method of dyeing an aqueous solution of polyvinyl alcohol-based potassium is usually used. 322869 39 201140127. The iodine of the aqueous solution contains hydrazine, water is _ to U parts by weight, and the sling is relative to 100 parts by weight of water per 100 parts by weight of the water, usually relative to each of the $4n 〇rt|.AL, reset Share. The temperature of the aqueous solution is usually seconds. The dipping time in the water 'money is usually 30 to 300. On the other hand, when the dichroic enamel is used as the dichroic dye, the aqueous solution is used for dyeing. Bayes 3 has a water-soluble dichroic dye amount, which is usually a part of the dichroic dye relative to each of the aqueous solutions. The aqueous solution may contain sodium sulfate in water as 〇.001. The weight of the 01 is 20 to m: in addition, in the water, no: salt. The temperature of the aqueous solution is usually 3 (8) seconds. Also, the nighttime impregnation time is usually 30 to the acid-cutting treatment after dyeing according to the dichroic pigment, and the dyed poly-squamous tree is immersed in the Wei aqueous solution to enter the antimony ore aqueous solution. The content is usually 2 to 15 parts by weight per 1 part by weight of water, preferably "::" is a dichroic color cylinder, and the preparation is made of potassium. Iodide in the θ i ^ Μ Μ Μ 2 to Μ * _ I 'usually 2 to 2 parts by weight relative to the water per 100 Μ ' 'best 5 illus 5 immersion in Wei aqueous solution The time pass f is from 12 to (2 to (10) to _ second, more preferably 2 to the side of the second. Wei water is usually 5 〇 t: above, preferably 50 to 85 χ. / 皿理理. ==: :_ film, usually washed

Jc was first placed in the film by impregnating the polyethylene film 322869 201140127 resin film treated with Wei into water. After the treatment in the water washing treatment, the ridge is processed to obtain a polarizing light of 2 to 12 sec. The temperature of the German is usually 5 to the machine, the dipping time dryer or the far-infrared ray drying process can be used to dry the hot air, dry treatment; the drying temperature is usually 4 〇 to 吟 usually between 120 and 600 second. A polarizing film obtained by uniaxially stretching and having an adsorption alignment or a color chromaticity =:= is obtained. Polarizing film: Chemical composition 2 = containing the ring 1 described later: = 防 to 3 ^ month in the anti-glare polarizing plate 'From the viewpoint of mechanical strength, the polarizing film and the _ side of the anti- _ On the opposite side, the second adhesive layer described later is attached to the protective layer. The protective film is preferably a transparent resin film. When a specific example of the transparent resin film is used, for example, a cellulose resin such as a cellulose triacetate film; a chain-like polyolefin resin such as polyene; a non-crystalline polyolefin resin film; and a polyester resin; Film; (meth)acrylic resin film; polycarbonate-based resin film; poly-stone-type resin film; alicyclic poly-imide-based resin film. Among them, it is particularly preferable to use a cellulose triacetate film or a non-crystalline polyolefin resin film. The non-crystalline polyolefin resin is usually a copolymer having a cyclic hydrocarbon such as a reduced or polycyclic ring-eneken monomer, and may be a copolymer of a cyclic thin smoke and a chain olefin. Among them, the representative one is a thermoplastic saturated decene-based resin. In the amorphous polyolefin-based resin, a polar group can be introduced.

S 322869 201140127 Commercially available non-crystalline polyolefin resin, for example, "ARTON" (made by JSR Co., Ltd.), "ZE0N0R" (made by Japan Zeon Co., Ltd.), and "ΖΕ0ΝΕΧ" (made by Japan Zeon Co., Ltd.) , "ΑΡ〇" (manufactured by Mitsui Chemicals, Inc.), "APEL" (manufactured by Mitsui Chemicals, Inc.), etc. When the non-crystalline polyolefin-based resin of such a commercially available product is used, a film can be formed by a film-forming method such as a solvent washing method or a melt extrusion method to form a film. The thickness of the protective film is usually in the range of about 5 to 200 #m, preferably in the range of 10 to 120, more preferably in the range of 1 to 85. [4] Optical compensation layer The anti-glare polarizing plate of the present invention is also provided with an optical compensation layer as described below. The vine film is preferably an optical compensation layer which is laminated on the surface of the polarizing film opposite to the side on which the anti-glare film is bonded, in the second adhesive layer described later. Alternatively, the optical compensation layer may be laminated on the protective film, and the protective tape may be bonded to the opposite side of the polarizing film from the side to which the antiglare film is bonded. The optical compensation layer is a layer (including a film) for the purpose of compensating for phase difference or the like. The optical compensation layer for the purpose of compensating for the phase difference is also called "phase difference plate (or phase difference 臈)". The light-receiving layer may, for example, be a birefringent film formed of a stretched film of a transparent resin, or a diSC〇tic liquid crystal or a nematic liquid crystal. (The film of nematic ;; an optical compensation film formed of a disc-shaped liquid crystal or a liquid crystal layer formed on the base film. Among them, from the viewpoint of cost, it is preferable to use a stretching by a transparent resin. A birefringent film composed of a film such as 42 322869 201140127. This birefringent film can function as a protective film. Therefore, when it has high entanglement, an additional protective film can be omitted. When the optical compensation layer laminated on the polarizing film can be provided with a plurality of optical compensation layers, it is possible to accumulate (four) several layers of the same type of optical compensation layer. For example, it can be composed of a phase-compensated compensation layer or a non-resin stretch material. The birefringent film layer is a birefringent (10) 1 ^ other transparent resin film composed of a transparent stretched film or the like. The birefringence film is composed of a birefringence composed of a stretching medium of a transparent resin or the like. Transparent resin, Resin; polyvinyl alcohol 榭 ” 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了 了=Special. The stretched film can be used in an appropriate manner such as a hetero-uniaxial or biaxial. In addition, the following birefringent film can also be used as an optical compensation film, and the birefringent film is bonded to a heat-shrinkable film. Under (4) of the film composed of the above transparent resin, the refractive index in the thickness direction of the film is controlled by the contraction force and/or the stretching force. When the optical compensation layer is laminated on the protective film, From the viewpoints of the simplicity of the work and the prevention of the occurrence of optical distortion, the adhesion of the optical compensation layer to the protective film is preferably carried out using an adhesive (also referred to as a pressure-sensitive adhesive). The adhesive can be used with acrylic. A polymer composition, a polysiloxane polymer, a ruthenium, a polyurethane or a polyether, etc., as an adhesive composition of a base 322869 43 201140127 compound (base p〇iymer). It is preferred to use optical transparency, moderately wettability and Cohesive force, excellent adhesion to the substrate, and weather resistance, heat resistance, etc., acrylic adhesives that do not cause floating or stripping lion problems under heating or humidification conditions (acrylic polymers) As the base polymer adhesive), the base polymer of the acrylic acid adhesive is preferably made of a (meth)acrylic acid having a methyl group, an ethyl group, a butadiene 4 and an inverse number of 20 or less. The burned ester and (meth)acrylic acid or (mercapto)acrylic acid have a functional group-containing acrylonitrile-based acrylic copolymer with a functional group and the glass transition temperature is below hunger (more than 0C) The following is a polypropylene copolymer having a weight average molecular weight of more than 10,000. The optical compensation layer of the adhesive is bonded to the protective film by forming a protective film or an optical compensation layer, and interposing (4): Into the 5:: compound (optical compensation layer or protective film) to form a layer of the agent layer, for example, can be prepared by: ... weight dimethyl:, B - solution, film or optical compensation Forming the solution directly on the layer to form a layer of the coating agent layer formed on the protective film layer; or Yes (4) The layer is placed on the layer and the wire is moved to the protective film or the light is determined by the force, etc.; the thickness of the adhesive layer is #^ is 1 to 50 with a range of "1 . In the adhesive layer, resin granules, metal powder, other glass fibers, glazing antioxidants, and ultraviolet absorbing agents may be used as needed. The ultraviolet absorber may be a 322869 201140127 acid ester compound, a benzophenone compound, a benzodiazepine compound, a cyanoacrylic acid g-based compound, a nickel complex salt-based compound, or the like. When the optical compensation layer is directly laminated on the polarizing film without interposing the protective film, the bonding of the optical compensation layer and the polarizing film is performed using an adhesive. This adhesive is the one forming the second adhesive layer. Next, the optical compensation layer or the protective film which can be provided as the retardation plate of the anti-glare polarizing plate of the present invention, and the liquid crystal cell provided in the liquid crystal display device to which the anti-glare polarizing plate is applied (丨iquid crystal cel i) The relationship between the drive modes. The anti-glare polarizing plate of the present invention can be preferably provided with a phase difference plate or a protective film depending on the driving mode of the liquid crystal cell provided in the liquid crystal display device to which it is applied. The driving mode of the liquid crystal cell includes a Vertical Alignment (VA) mode, an In-Plane Switching (IPS) mode, and a Twisted Nematic (TN) mode. (Vertical alignment mode) Vertical alignment mode In the non-driving state, liquid crystal molecules are vertically aligned with respect to the unit substrate, so light is not passed along with changes in polarization. Therefore, the linear polarizing plates are disposed above and below the liquid crystal cell in such a manner that the polarization axes are orthogonal to each other, whereby an almost complete black display can be obtained when viewed from the front, and high contrast can be obtained. However, in the liquid crystal display device in which the linear polarizing plate is disposed only in the vertical alignment mode of the liquid crystal cell, when viewed from the oblique direction, the axial angle of the disposed linear polarizing plate is deviated from 9 〇 β, and the liquid crystal The rod-like liquid crystal molecules in the unit exhibit birefringence, so the 322869 45 201140127 produces light leakage, which reduces the contrast. In the / vertical alignment: mode liquid crystal display device, in order to eliminate such light leakage, a phase difference plate is disposed between the liquid helium unit and the linear polarizing plate. Vertical alignment, as described above, in the black display state, because the liquid crystal molecules are opposite; the unit substrate is vertically aligned, so the slow axis in the plane of the liquid crystal layer (d〇w ^ ^ (f ast axxs) When the refractive index in the thickness direction of the liquid crystal layer is nz, the liquid helium layer can be regarded as a positive type plate showing a relationship of nx = ny < nz. Therefore, it has been = between the polarizing film and the liquid crystal cell Refraction in the in-plane slow axis direction (1), the refractive index in the fast axis direction of the film is ny, the refractive index in the thickness direction of the film is 瞒, and the positive plate and the display (4) y when the display relationship is arranged. For both the negative c-plates of the relationship of nz, the light leakage can be appropriately removed. In addition, Japanese Laid-Open Patent Publication No. 2007-256766 discloses that the first phase difference plate having a relationship of nx >nygnz has a slow axis ', and the transmission axis of the adjacent polarizing film is nearly parallel or The square wire of almost orthogonal=relational relationship is disposed between the first retardation plate and the unit substrate, or between the other unit substrate and the opposite polarizing film, and has i^ny>gt;n2 The second phase difference plate of the relationship.使用 When the anti-glare polarizing plate of the present month is used in the liquid*, and the display device of the vertical alignment mode, it is preferable to appropriately arrange the polarizing film of the phase difference plate having the above configuration and the anti-glare film. One side is the side of the opposite side. In view of the durability of the production-oriented, anti-glare polarizing plate, etc., when the anti-glare polarizing plate of the present invention is applied to a liquid crystal display device of a vertical alignment mode, the anti-glare polarizing plate of the present invention is preferably In the second adhesive layer to be described later, a first phase difference plate having a relationship of nx > nygnz is laminated on the surface opposite to the side on which the anti-glare film is bonded to the polarizing film. And a second phase difference plate having a relationship of nx_ny > nz is laminated on the first phase difference plate with an adhesive layer or the like interposed therebetween. The first phase difference plate having a relationship can be obtained by subjecting a film made of a transparent resin having a positive refractive index anisotropy to uniaxial or biaxial stretching under appropriate conditions. As the transparent resin having a positive refractive index anisotropy, a cellulose resin represented by cellulose diacetate deuterated cellulose, a cyclic olefin resin, a polycarbonate resin or the like can be used. Here, the cyclic dilute-based resin is a resin having a cyclic olefin such as norbornene or dimethanooctahydronaphthalene as a monomer, and commercially available products include "ARTON" (manufactured by JSR Co., Ltd.) and "ZE0N0R". (made by Japan Zeon Co., Ltd.), "zeonEX" (made by Sakamoto Zeon Co., Ltd.), etc. Among these transparent resins, cellulose triacetate or a cyclic olefin resin can be preferably used because the photoelastic coefficient is small and the in-plane characteristics due to thermal strain under the use conditions are small. A second phase difference plate having a relationship between Πχ and Fly > , can be exemplified by coating a cholesteric liquid crystal on a substrate at a short pitch by coating a disk-shaped liquid crystal on a substrate film. In the film, a layer of an inorganic layered compound such as mica is formed on the substrate film, and the transparent resin film is subjected to biaxial stretching or the unstretched solvent washing mode. A commercially available phase difference plate having a relationship of ηχ and ny>Πζ, for example, "yM Film" (manufactured by Sumitomo Chemical Co., Ltd.) and "Fujitae 322869 47 201140127", due to a value of 0,

Film Co., Ltd.) and so on. The second phase difference plate is is^, the in-plane phase difference R. It is almost zero, so no matter what kind of η, it is not necessary to specify the axis angle of its slow axis. Further, the phase difference between the in-plane phase difference b and the thickness direction is such that the refractive index in the in-plane slow axis direction of the film (phase difference plate) is n, and the refractive index in the fast axis direction of Rth ' is ny. In the thickness direction, the folded surface nz, when the thickness of the film is d, is determined by the following formula (a) & (b), respectively, R 〇 = (nx - ny) xd (a)

Rth=[ (nx+ny)/2-nz]xd (b) The phase difference Re in the plane of the film (phase difference plate) and the phase difference Rth' in the thickness direction can be determined, for example, in the interlayer adhesive layer. When the target film is bonded to a glass plate, it is directly measured using a commercially available phase difference measuring device (K0BRA-21ADH (manufactured by Oji Scientific Instruments Co., Ltd.). In such a phase difference measuring device, for example, by using a wavelength Rotating analyzer method of 559 nm monochromatic light, measuring the phase difference Ro in the plane of the film, and measuring the inclination of the in-plane slow axis of the film as the tilt axis by 40 degrees The phase difference R4Q, and using the measured phase difference R4, the thickness d of the film, and the average refractive index n〇 of the film, to obtain nx, ny, nz' and calculate from the equivalent according to the above formula (b) The phase difference Rth in the thickness direction (IPS mode) The IPS mode is a method of changing the alignment state of liquid crystal molecules by applying a transverse electric field of a voltage parallel to the surface of the unit substrate, and the liquid crystal molecules are relatively in a state where no voltage is applied. The unit substrates are aligned in parallel. 48 322869 201140127 I PS mode liquid crystal display I罟.., in the device 'when the liquid crystal cell is clamped and only the configuration is biased from the oblique direction', the axial angle of the linear polarizer is 90 Deviation, and the rod-like liquid crystal molecules in the liquid crystal cell appear and refract*, so that light leakage occurs, and the contrast is remarkably lowered. In the liquid crystal display device of the ips mode, in order to eliminate such light leakage, the page is in the liquid crystal cell and the polarizing film. A phase difference plate is disposed between them. In order to compensate for the change in the viewing angle of the liquid crystal layer caused by the change of the viewing angle in the liquid crystal display device of the ips mode, it is known to be optically negative uniaxial and its optical axis is parallel with respect to the film surface. The phase difference plate or the phase difference plate which is oriented in the thickness direction is effective. For example, in the liquid crystal display device of the IPS mode, the liquid crystal cell and at least one of the polarized light are described in the Japanese Patent Publication No. Hei 10-54982. An optical compensation film having an optically negative uniaxiality and having an optical axis parallel to the film surface is disposed between the plates. In Japanese Laid-Open Patent Publication No. Hei 11-133408, the liquid in the IPS mode is described. Between the polarizing plates of one pair of crystal display devices, more specifically, between the liquid crystal cell and the polarizing plate, positive uniaxiality is arranged and optical compensation is performed in an optical axis perpendicular to the direction of the single 70 substrate In the liquid crystal display device of the IPS mode, the in-plane phase difference values are different between the liquid crystal cell and the pair of upper and lower polarizing plates. In the optical compensation film (phase difference plate), it is described that at least one phase difference plate is disposed between the back side polarizing film and the liquid crystal cell, and the phase difference plate 49 322869 201140127 includes The sum of the phase difference values Rth in the thickness direction of the birefringent layer of the phase difference plate existing between the liquid crystal cell side surface of the back side polarizing film and the back surface side substrate surface of the liquid crystal cell is _4〇ηιη to +4 The range of the phase difference Rq in the plane of the 〇mn is in the range of 1 〇〇 nm to 2 〇〇 nm. The front side polarizing plate is provided with a polarizing film, and at least The opposite side of the single 兀 is the opposite side The phase difference in the thickness direction between the liquid crystal cell side surface of the polarizing film and the front substrate side of the liquid crystal cell is seen in the range of _丨〇ηΠ1 to +40 nm. Polarizer. Further, a method of aligning a resin film in a thickness direction, for example, in Japanese Patent Laid-Open Publication No. Hei 7-23-7, discloses that it has a heat shrinkage property so that the heat shrinkable direction of the heat shrinkable film and the warp order The method of heat-shaping by axial stretching is applied to a method in which a heat-shrinkable film is peeled off after being subjected to heat shrinkage by at least one side of uniaxially stretched. The anti-glare polarizing plate of the present month is used in a liquid crystal display device of the IPS mode to achieve the above-described configuration, and the protective film or the phase difference plate is disposed in the polarizing film and attached thereto. The anti-glare polarizing plate of the present invention is applied to the ips mode when the liquid crystal is not used, and the anti-glare polarizing plate of the moon is better. The configuration of the first embodiment of the present invention is as follows: the second adhesive layer is described later, and the protective film of the thickness direction of the light film is placed in the range of 10 nm to +40 Å, and the protective film is laminated on the polarizing film. The side with the anti-glare film is the opposite side. The phase difference in such a direction is a protective film in the range of -10 〇 nm to +4 〇 nm, which can be easily obtained from the market, and has substantially no alignment and a phase difference Rth of thickness direction is l. In the case of 〇nra or less, a cyclic hydrocarbon resin film of 5 nm or less, a cellulose acetate vinegar resin film such as cellulose triacetate, or the like is further provided. Further, the solvent-washing film of the cellulose acetate-based resin film such as cellulose triacetate may be used because it has a small thickness and a phase difference of 40 nm or less in the thickness direction. When the anti-glare polarizing plate of the present invention has a phase difference in the thickness direction

When the Rth is a protective film in the range of -10 mn to +4 〇 nm, as described above, it is preferable to pass between the liquid crystal cell side surface of the polarizing film of the back side polarizing plate and the surface of the liquid crystal cell. The sum of the phase difference values Rth in the thickness direction of the existing birefringent layer is set to the range of _4〇11111 to +4 〇, and the sum of the phase difference 匕 in these planes is set to 1 至 to 2 〇〇 之 。. Such a birefringent layer may, for example, be a thermoplastic resin film which is uniaxially stretched and also oriented in the thickness direction; and has a negative refractive index anisotropy... a so-called negative-type slab (which may also be biaxial) obtained by uniaxial or biaxial stretching; a so-called negative uniaxiality and a so-called optical axis in a direction parallel to the film surface The negative type A plate is laminated on a so-called positive type plate having a positive uniaxiality and an optical axis located in the normal direction of the film. (TN mode) The TN mode is a method of changing the alignment state of liquid crystal molecules by applying a longitudinal electric field of a voltage perpendicularly to the surface of the unit substrate. In the TN mode, when the liquid crystal molecules are traced from the unit cell substrate to the other unit substrate, the liquid crystal alignment in a state where no voltage is applied is in a plane parallel to the 51 322 869 201140127 substrate in each portion. A state in which a state of twisting (twisted) of 9 turns is generated between the upper and lower substrates is aligned in parallel with respect to the unit substrate. In the conventional TN type liquid crystal display device, the viewing angle characteristics are insufficient due to the anisotropy of the refractive index due to the pretilt of the liquid crystal material in the liquid crystal cell. Japanese Patent Publication No. 6-214116 discloses an optical anisotropic layer which is disposed such that a negative uniaxial optical axis is obliquely oriented with respect to a film surface, and is disposed in a TN liquid crystal display device. The liquid crystal is between the single polarizer and the polarizing plate. Further, in Japanese Laid-Open Patent Publication No. Hei No. Hei. No. 186-356, the optical compensation film which exhibits a positive uniaxial liquid crystalline polymer in a liquid crystal state is prepared by a nematic hybrid alignment, and it is disclosed. The optical supplemental gamma is applied to the liquid crystal display device in order to expand the two angles. Thus, the optical anisotropic layer which is oblique with respect to the film surface using the optical axis is used as an optical compensation film (phase difference plate), and the viewing angle of the TN liquid crystal display device. also

The anti-glare polarizing plate of the present invention uses a liquid crystal display in a core mode. Preferably, the optical compensation film (phase difference plate) is appropriately formed on the side of the polarizing film and the side on which the anti-glare film is attached. Side of the side. When the anti-glare polarizing plate is applied to a liquid crystal display device of the TN mode, a preferred embodiment of the anti-glare polarizing plate is an example of a seaweed as described below. The second and subsequent (four) are described later. The protective layer is placed on the side opposite to the side on which the anti-glare film is bonded to the polarizing film, and is laminated on the silk film as a phase difference ratio optical anisotropic layer. The bonding and the phase j bonding are preferably carried out using an adhesive such as a C-based adhesive. The anisotropic layer is directly formed on the film. Silk anisotropy, M 322869 52 201140127 Jiaxie is optically negative uniaxial and its optical axis is inclined 5 to 5 from the normal direction of the film (an optically anisotropic layer of Γ and optically positive uniaxiality) And an optical anisotropic layer whose optical axis is inclined from the normal direction of the film by 5 to 5 Qe. Optically negative uniaxial and optically minus _ normal direction inclined by 5 to 50. Optical anisotropic layer, for example For the Japanese Patent Application No. 6_214116, it is said that the δ has been used in the A report. It is preferable to use an organic compound, in which a compound exhibiting liquid crystallinity and having a discotic molecular structure, or a liquid crystal having no liquidity is used. A compound which exhibits a negative refractive index anisotropy by an electric field or a magnetic field is coated on a transparent substrate film composed of cellulose triacetate or the like, and the optical axis is inclined from the normal direction of the film by 5 to 5 〇. The film is aligned, etc. The alignment is not only unidirectional, but also a so-called mixed alignment in which the slope gradually increases from one side of the film to the other. The liquid crystal is displayed and has a disc-shaped molecular structure. The compound can be exemplified by a disk of low molecular weight or high molecular weight. Liquid crystal, for example, a mother core having a planar structure such as triphenylene, trixene, or benzene, which is radially bonded with an alkyl group, an alkoxy group, and an alkyl substituted benzamidine oxygen. A linear substituent such as a benzyloxy group substituted with an alkoxy group. Among them, it is preferred that no absorption occurs in the visible light region. The organic compound having a discotic molecular structure is not limited to only In order to obtain a desired alignment, a plurality of species may be used as needed, or may be mixed with other organic compounds such as a polymer matrix. The organic compound to be used in combination with an organic compound having a disc-shaped molecular structure may be used. The solubility is not particularly limited as long as the organic compound having a discotic molecular structure is dispersed to a degree that does not scatter light. 53 322 869 201140127 Transparent base film composed of cellulose resin A film having a layer composed of the liquid crystalline compound and having an optical axis inclined with respect to a normal direction of the film is preferably used. For example, "WV Film" (Fuji Film Unit) can be used. The optically anisotropic layer which is optically positive uniaxial and whose optical axis is inclined from the normal direction of the film by 5 to 50. For example, it is described in Japanese Laid-Open Patent Publication No. Hei 10-186356. In general, an organic compound having an elongated rod-like structure, particularly a compound exhibiting nematic liquid crystallinity and having a molecular structure imparting positive optical anisotropy, or a liquid crystal having no electric field or A compound which exhibits a positive refractive index anisotropy by a magnetic field is formed on a transparent substrate made of cellulose diacetate or the like, and the optical axis is inclined from the normal direction of the film by 5 to 5 Å. The alignment or the like is such that the alignment is not only unidirectional, but also a so-called mixing alignment in which the slope gradually increases from one surface of the film toward the other surface. In the transparent substrate film, a layer made of a nematic liquid crystal compound and having an optical axis inclined with respect to the normal direction of the film is preferably used. For example, "NH Film" (manufactured by Nippon Oil & Steel Co., Ltd.) can be used. In addition, a dielectric "capable of forming a thin film by vacuum evaporation and exhibiting positive refractive index anisotropy when performing vapor deposition" is vapor-deposited on a transparent substrate in a direction oblique to the direction of the method. Optical on the film can also be made optical: positive uniaxial and its optical axis is inclined from 5 to 50 from the direction of the Langfa line. Optical two-layer: The dielectric used herein may be any of an electric substance composed of an inorganic compound or a dielectric composed of an organic compound, but with respect to heat stability during vacuum evaporation. In view of the above, it is preferable to use an inorganic dielectric for 322869 54 201140127. In terms of transparency, etc., it is preferable to use yttrium oxide (TaA5), tungsten oxide (W〇3), and sulphur dioxide (in terms of transparency). Si〇2), metal oxides such as cerium oxide (SiO), cerium oxide (BhOs), cerium oxide (this must). In metal oxides, it is preferable to use an oxidation button, tungsten oxide, cerium oxide, etc. When the rate is anisotropic and the film is hard. When an optically anisotropic layer is formed by laminating a dielectric layer of a dielectric material exhibiting refractive index anisotropy on the transparent substrate film, the optical anisotropic layer is The transparent substrate film side is bonded to the polarizing film or bonded to the polarizing film, and the film is laminated on the polarizing film or the protective film in a relative manner. In addition, in the TN mode, in order to further improve the viewing angle characteristics and height Hanging characteristics, better The anisotropic layer is disposed on the back side polarizing plate sandwiching the liquid crystal cell and disposed on the optical anisotropic layer of the back side polarizing plate. As described above, it is preferable to use an optically negative single axis. The optical axis of the foot is inclined from the normal direction of the film by 5 to 5 {an optical anisotropic layer. [5] Adhesive layer In the present invention, as shown in Fig. 1, the anti-glare film i is interposed. The buffer layer 103a is laminated on one surface of the polarizing film 1〇4. Further, when the film is laminated or the optical compensation layer 105, these are laminated on the polarizing film 104 via the second adhesive layer 1〇3b5. In the present invention, the adhesive for forming the first adhesive layer is a curable composition containing an epoxy resin (preferably containing an epoxy resin as a main component). The composition can improve the water resistance of the obtained anti-claw polarizing plate, and obtain high adhesion strength between the anti-glare film and the polarizing film, thereby improving the durability of the anti-glare polarizing plate. Forming the second layer 322869 55 201140127 The adhesive may be of the same kind or different from the adhesive forming the first adhesive layer From the viewpoint of adhesion and longevity, it is preferable that the preferred layer of the fish is the same as the hardenable composition containing an epoxy resin (preferably containing a ring gas system, the main component). It is better. Here, the compound of the molecular napkin having an average of two or more (tetra)oxy groups and hardened by the anti-molecule, in addition to the polymer, also contains an oligomer and a monomer. The anti-glare film and the polarizing film, the polarizing film and the protective film or the optical compensation layer, which are formed by using the adhesive composition composed of the above-mentioned curable composition, can be interposed by the bonding The coating layer of the adhesive is irradiated with an active energy ray or heated to cure the curable epoxy resin contained in the adhesive. According to the active energy ray or the curing of the epoxy resin by heating, it is preferable that the active energy ray by the cation aggregation is a concept including visible light, ultraviolet ray, xenon ray, and electron beam. The epoxy resin contained in the curable composition as an adhesive agent may, for example, be a chlorinated epoxy resin, an alicyclic epoxy resin, or an aliphatic group, from the viewpoints of weather resistance, refractive index, and cationic polymerizability. Epoxy resin, etc. Hydrogenated epoxy compound by pressurization in the presence of a catalyst

The aromatic polybasic compound of the raw material of the aromatic epoxy resin is selectively subjected to a nuclear hydrogenation reaction, and secondly, glycidol is gradually formed. The aromatic epoxy resin may, for example, be a bismuth sulphate (four) of a double scorpion, a diglycidyl sulphate of a double spleen F, and a second loser of a double age S. Oxygen resin; Phenol _lac epoxy resin, enamel epoxy 322869 56 201140127 resin, and base benzophenone cycline phenyl group _ glycidyl, _ oxygen _ day 4 secret Wei oxygen resin Oil ether, bismuth oxidized polyvinyl phenol, etc., such as a double lysine compound, which is a raw material of the scent, is subjected to the above-mentioned nuclear hydrogenation reaction, and the hydrogenated epoxy resin is obtained. When ‘:: people: make the pure alcohol react, and the double shrinking A is shrinking (10). '11-epoxy tree is purely hydrogenated so-called alicyclic epoxy resin, which is bonded to the epoxy group of the alicyclic ring, p-77 U 1 or more of the ring epoxy group" means ^^脂. In the following formula of "bonding to the moon ring", the structure is called ^ (CH2)r to remove the ^ ^ T in the (CH2) m of the above formula, but is not limited to such compounds. ^, (3) a ring of the formula (I): a long-alkane carboxylic acid epoxidized cyclohexyl group, the group of which is bonded to other chemical structures in the form of a enthalpy of a plurality of hydrogen atoms (in the middle or plural ^ ' can become The alicyclic type of soil is replaced by a linear alkyl group such as an ethyl group, and is suitably subjected to a methyl or bicyclohexyl ring (in the above formula, m = 3, ^ 乳乳树中中' has an epoxy m=4 The epoxy resin of the epoxy resin is used in the above formula. The following is a specific example of the adhesiveness of the present invention, and is suitable for the resin, but is not limited to the fat used in the chemical I. Cyclic esters 322869 (I) 201140127

(wherein R1 and R2 each independently represent a gas atom or a linear alkyl group having 1 to 5 carbon atoms). (b) Epoxy ring-burning vinegar of the diol of the following formula:

A C-0—(CH 2 ) n—〇—C R 3 cp 〇 R 4 (Π) (wherein R and R each independently represent a hydrogen atom or a linear alkyl group having a carbon number of 丄 to 5 ′ represents 2 An integer of up to 20.) (c) Epoxycyclohexyl decyl esters of dicarboxylic acids represented by the following formula (III): 0 R5 CH2-〇-&-(CH2) p

R

(m) (wherein R5 and R6 each independently represent an argon atom or a linear alkyl group having a carbon number of i to 5, and P represents an integer of 2 to 20). (4) Cyclohexane-methyl ether of polyethylene glycol represented by the following formula (IV) 322869 58 201140127 CH2—(0C2H4)q-0-CH2 R7 R8

(17) (wherein R7 and R8 each independently represent a hydrogen atom or a linear alkyl group having 1 to 5 carbon atoms, and q represents an integer of 2 to 10). (e) Epoxycyclohexyl methyl ethers of alkanediols represented by the following formula (V): , CH2-0-(CH2)r-〇-CH2, R9 (V) R1 (wherein R9 and R1 ( And independently represent a hydrogen atom or a linear alkyl group having 1 to 5 carbon atoms, and r represents an integer of 2 to 20. (f) a diepoxide trispirate compound represented by the following formula (VI): R11 (VI) (wherein R11 and R12 each independently represent a hydrogen atom or a linear alkyl group having 1 to 5 carbon atoms). (g) a diepoxymonosole compound represented by the following formula (VII): R13 (VII) (wherein R13 and R14 each independently represent a hydrogen atom or a linear thio group having 1 to 5 carbon atoms). (h) Vinylcyclohexene diepoxides of the following formula (VIII) · 59 322869 201140127

(In the formula, R15 represents a hydrogen atom or a linear alkyl group having a carbon number of i to 5) (i) an epoxycyclopentene ether of an alkanediol represented by the following formula (IX):

R16 r17 (K) (wherein R and R each independently represent a hydrogen atom or a linear alkyl group having 1 to 5 carbon atoms). (j) Diepoxy tricyclic terbene shown in the following formula (X)··

R18

• Q (X) (wherein R represents no hydrogen atom or a linear alkyl group having 1 to 5 carbon atoms). Among the alicyclic epoxy resins exemplified above, it is more preferable to use the ring-type cyclic fat transfer for the reason that it is easier to obtain. (A) an ester of 7-oxabicyclo[4.丨.〇]heptane-3-carboxylic acid with (7-oxabicyclo[4.1.0]heptan-3-yl)methanol [Formula (1) , Rl=R2=H compound], (B) 4-mercapto-7-oxabicyclo[4.l 〇]heptane_3 monocarboxylic acid and (4-fluorenyl-7-oxabicyclo[4.1〇 Glycol-3-()-esterification of methanol [in the formula (1), Rl=4_CH3, R2=4-CH3 compound], (C) 7-oxabicyclo[4·1·0]heptane-3- 60 322869 201140127 ester of carboxylic acid and 1,2-ethanediol [Compound in formula (II), R3=R4=H, n=2], (D) (7-oxabicyclo[4. 〇]heptan-3-yl)methanol and adipic acid as a compound [in the formula (III), R5=R6=H, p=4 compound], (E) (4-methyl-7-oxa Bicyclo[4. 1. 〇]heptan-3-yl) ester of methanol with adipic acid [in the formula (III), R5=4-CH3, R6=4-CH3, p=4 compound], (F (7-oxabicyclo[4. 1.〇]heptan-3-yl)methanol and ether of 1,2-ethanediol [in the formula (V), R9=f=H, r=2 compound ]. Further, the aliphatic epoxy resin may, for example, be a polyglycidyl ether of an aliphatic polyhydric alcohol or an alkylene oxide adduct thereof. In the case of gifts, for example, diglycidyl ether of 1,4-butanediol; 1, diglycidyl shreds of dimethoate; triglycidyl hydrazine of glycerol; Glycidyl ether; diglycidyl ether of polyethylene glycol; diglycidyl ether of propylene glycol; and one or more alkylene oxides (ethylene oxide, propylene pyrene (pr〇pyiene) Oxide, etc.) A polyglycidyl ether of a polyfluorene polyol obtained by forming an aliphatic polyol such as ethylene glycol, propylene glycol or glycerin. The epoxy resins exemplified above may be used alone or in combination of two or more. The epoxy equivalent of the epoxy resin is usually from 30 to 3,000 g/equivalent, and is preferably in the range of from 50 to 1,500 g/equivalent. When the epoxy equivalent is less than 3 〇g / equivalent, the flexibility of the hardened anti-glare polarizing plate may be lowered, or the strength of the connector may be lowered. On the other hand, when the epoxy equivalent exceeds 3 〇〇〇g/eq, the compatibility with other components contained in the adhesive may be lowered. 322869 61 201140127 From the viewpoint of reactivity, it is preferred to use cationic polymerization as a hardening reaction of an epoxy resin. Therefore, as the remaining curable composition, it is preferred to contain a cationic polymerization initiator, and the cationic polymerization initiator is produced by irradiation or heating of an active energy ray such as visible light, ultraviolet rays, X-rays, or electron beams. A cationic species or a Lewis acid, and the polymerization of the epoxy group begins. Regardless of the type of cationic polymerization initiator, it is preferred from the viewpoint of imparting a recess. Hereinafter, the cation polymerization initiator which generates a cationic species or a Lewis acid to cause the reaction to proceed, which is called "light will be generated by heat generation of a cationic species or a Lewis acid" = by the active energy ray It is more advantageous to irradiate less than the primary film because it can be hardened at room temperature and reduced, and the necessary light film caused by the strain or expansion of the film is followed. Light; photo-cationic polymerization for fat, preservation stability and workability is also excellent. Gwangyang 2; Yu = oxygen tree salt; and iron-propadiene complex, etc. h fragrant 锜 salt and other rust i incense The diazonium salt, for example, a gas diazonium salt such as A + gas, hexahydro sulphate, or the like, may be exemplified by tetrakis(pentafluorophenyl)diphenyl 322869. 62 201140127 =, hexafluoroweidiphenylene, hexafluoride riding diphenyl wire, squaric acid di(4-indolyl), etc.. = scented nickel salt, for example, hexafluorophosphate trisyl Bismuth, hexafluoro, acid three stupid base, tetrakis(pentafluorophenyl) triphenyl sulfonate, 4 4, _ double (two stupid base table 1_ Diphenyl sulfide di hexafluoroate, 4, 4, bis[bis(undo-hydroxyoxy)phenyl)diphenyl sulfide dihexafluoroate, 4, 4, ^ L-d silk ethoxy)phenyl sulfhydryl] diphenyl sulphide double hexafluoride acid = 7-[1 (p-tolyl) fluorenyl] 2_isopropyl sulphide hexazone Salt, one (p-tolyl) fluorenyl]-2-isopropyl thioxanthone four (five gas two 4 (on the second grade of Xianji County) _4, _ diphenyl secret group _ diphenyl thiophene six rats Citrate, 4-(p-tert-butylphenylcarbonyl)-4,-bis(p-tolyl)decyl-diphenyl sulfide tetrakis(pentafluorophenyl)borate, etc. In addition, iron-propion A fine complex compound, for example, may be exemplified by dioxan-cyclopentaenyl iron (II) hexafluoroantimonate, cumene-cyclopentadienyl iron (π) hexafluorophosphonium salt, xylene A cyclopentadienyl iron (yttrium)-tris(trifluoromethylsulfonyl) fluorenyl compound. These photocationic polymerization initiators may be used singly or in combination of two or more. Aromatic salt-salt, which imparts ultraviolet light absorption even in the above wavelength region, so it can be hardened. It is suitable for use as a cured product having good mechanical strength and strength. Therefore, these photocationic polymerization initiators can be easily obtained from commercially available products. For example, Knife is listed under the trade name "Kayarad PCI-220". And 63 322869 201140127 "Kayarad PCI-620" (above made by Nippon Kayaku Co., Ltd.), "UVI-6990" (made by Union Carbide), "Adeka Optomer SP-150" and "Adeka0ptomer SP-170" (above) "made by ADEKA Co., Ltd.", "CI-5102", "CIT-1370", "CIT-1682", "CIP-1866S", "CIP-2048S" and "CIP-2064S" (above is Japan Caoda Co., Ltd.) Company system), "DPI-101", "DPI-102", "DPI-103", "DPI-105", "MPI-103", "MPI-105", "BBI-101", "BBI-102" "BBI-103", "BBI-105", "TPS-101", "TPS-102", "TPS-103", "TPS-105", "MDS-103", "MDS-105", "DTS-102" and "DTS-103" (above is made by Midori Chemical Co., Ltd.), "P Bu 2〇74" (made by Rh〇dia), etc.The amount of the photocationic polymerization initiator to be added is usually 0.5 to 20 parts by weight, more preferably 1 part by weight or more, and more preferably 15 parts by weight or less based on 1 part by weight of the epoxy resin. When the amount of the photocationic polymerization initiator is less than 0.5 part by weight relative to 100 parts by weight of the epoxy resin, the hardening is insufficient, and the mechanical strength and the subsequent strength of the cured product tend to be lowered. Further, when the compounding amount of the photocationic polymerization initiator is more than 2 parts by weight relative to the reset portion of the epoxy resin 100, the hygroscopicity of the substance is increased due to an increase in the ionic substance in the hardened substance, which may result in Reduced durability. When a photo-ionic polymerization initiator is used, the curable composition may be required to contain a photo-sensitizer. By using a photosensitizer, the reactivity of the cationic polymerization can be enhanced, and the mechanical strength and the strength of the cured product can be improved. The photo-sensitizing stimuli include, for example, a few base compounds, an organic sulfur compound, a persulfide compound, a 64 322 869 201140127 redox system compound, an azo and a heavy gas compound, a halide, and a photoreductive dye. Specific examples of the photosensitizer include benzoin ether, benzoin isopropyl ether, and benzoin derivatives such as α,α-didecyloxy-α-phenylidene ethyl ketone; diphenyl ketone, 2, 4- Dichlorodiphenyl i, decyl phthalate, 4, 4'-bis(dimercapto)diphenyl fluorene and 4,4'-bis(diethylamino) diphenyl Diphenyl ketone derivatives such as ketones; thioxanthone derivatives such as 2-air thioxanthone and 2-isopropyl sinone; 2-chloroindole and 2-indenyl; g, hydrazine, etc. Anthracene derivatives; acridone derivatives such as N-methylacridone and N-butylacridone; others such as 〇:, α-diethoxyacetophenone, diphenylethylenedione (benzil), anthrone, xanthene, uranyl compound, halide, and the like. These photosensitizers may be used singly or in combination of two or more. The photosensitive sensitizer is preferably contained in the range of 0.1 to 20 parts by weight in the weight component of the curable composition. On the other hand, the thermal cationic polymerization initiator may, for example, be a benzyl chloride salt, a thiophenium salt, a thiolanium salt, a benzylammonium salt, a pyridinium salt or a hydrazine salt. (hydrazinium salt), carboxylate, sulfonate and amidoximine. These thermal cationic polymerization initiators can be easily obtained from commercially available products, and for example, "Adeka Opton CP77" and "Adeka Opton CP66" (above, ADEKA Co., Ltd.), rCI_2639" and " CI_2624" (above is made by Japan Soda Co., Ltd.), rSan_Aid SI_6〇L", "San-Aid SI-80L" and "San-Aid SI-100L" (above, Sanshin Chemical Industry Co., Ltd.). 65 322869 201140127 The epoxy resin contained in the binder can be hardened by any of the types of thermal cationic polymerization, and can be hardened by both "combination and thermal cationic polymerization." And a thermo-cationic polymerization initiator, and a curable composition as an adhesive, which may contain an oxetane or a polyhydric alcohol, which promotes cationic polymerization, etc. For the compound having a four-membered ring in the molecule, for example, 3-ethyl-3, a methyloxycarbonyl heterocyclic ring, a succinyl ethyl-3-oxetanyl methoxy group Methyl]benzene, 3-ethyl_3_(phenoxy-methyl) oxetane, bis[(3-ethyl-3-(oxacyclobutyl)methyl] shout -(2-ethylhexyloxymethyl)oxetane, phenol novolac oxetane, etc. These oxetane can be easily obtained from commercially available products, for example, by product name Listed as r Ar〇ne 〇xetane 〇χτ_丨〇丨", "Oxetane 〇n-121", "Arone 0xetane 0XT_2ii", "Ar〇ne

Oxetane OXT-221" and "Ar〇ne〇xetane〇XT_212" (both manufactured by Toyo Synthes Co., Ltd.). These oxetanes are usually contained in the curable composition at a ratio of 5 to 95% by weight, preferably 30 to 70% by weight. The polyol is preferably one in which no acidic group other than the phenolic hydroxyl group is present, and examples thereof include a polyol compound having no functional group other than a hydroxyl group, a polyester polyol compound, a polycaprolactone polyol compound, and a phenol. A polyol compound of a hydroxyl group, a polycarbonate polyol compound, or the like. The molecular weight of these polyhydric alcohols is usually 48 or more, preferably 62 or more, more preferably 100 or more, and further preferably 1,000 or less. These polyols are usually contained in a ratio of 5% by weight or less, preferably at most 5% by weight, in the composition of the hard 66 322869 201140127. Further, in the adhesive composed of the curable composition, other additives such as an ion trapping agent, an antioxidant, a chain transfer agent, and adhesion can be added without damaging the adhesion. Agents, thermoplastic resins, fillers, flow regulators, plasticizers, defoamers, and the like. Examples of the ion trapping agent include inorganic compounds such as powdery silver, lanthanide, lanthanide, lanthanide, calcium-based, titanium-based, and the like. The anti-gasifying agent may, for example, be a hindered phenol-based antioxidant. An adhesive agent composed of a curable composition containing the epoxy resin is applied to at least one of the bonding surfaces of the adherend (polarizing film, antiglare film, protective film, and optical compensation layer), and then separated. The anti-glare polarizing plate of the present invention is obtained by laminating the adhesive to be applied to each other and curing the uncured adhesive layer by irradiation with an active energy ray or heating. The thickness of the uncured adhesive layer is usually 50/zm or less, preferably 2 Å or less, more preferably 1 〇 or less. As a method of applying the coating layer, for example, various coating methods such as a doctor blade, a wire bar, a die coater, and a crepe coater (c〇mma coater) gravure coater can be used. At this time, since each of the coating methods has an optimum viscosity range, a solvent for viscosity adjustment can be contained in the curable composition. The solvent is not particularly limited as long as it does not degrade the optical properties of the polarizing film, and the curable composition can be dissolved. For example, a hydrocarbon represented by terpene and an organic solvent such as vinegar represented by ethyl acetate may be used. When the protective enamel or the optical compensation layer is attached to the side of the polarizing film opposite to the side to which the 322869 67 201140127 anti-glare film is attached, the anti-glare film and the protective film or the optical compensation layer may be pasted in stages. He Cui face, or fit both at once. When the adherend is bonded by an adhesive, saponification treatment, corona discharge treatment, primer treatment, or error coating may be applied to at least one of the bonding surfaces of the composition to be applied in advance (anchor coating) Processing is easy to proceed. When the adhesive is cured by irradiation of an active energy ray, the light source to be used is not particularly limited, and a light-emitting distribution having a wavelength of 400 nm or less, for example, a low-pressure mercury lamp, a medium-pressure mercury lamp, a high-pressure mercury lamp, a chemical lamp, or a black light can be used. Microwave-excited mercury lamps, metal toothed lamps, and the like. The light irradiation intensity of the docking agent varies depending on the composition, and is preferably in the range of 至. 1 to 100 mW/cm 2 in the wavelength region where the activation of the polymerization initiator is effective. When the intensity of light irradiation to the adhesive is less than 0·lmW/cm2, the reaction time is too long, and when it exceeds i〇〇mw/cm2, it may be due to radiant heat emitted from the lamp and heat generation of the curable composition during polymerization. The yellowing of the adhesive or the deterioration of the polarizing film is generated. The light irradiation time of the adhesive is controlled depending on the composition, and is not particularly limited, but it is preferably such that the integrated light amount represented by the product of the irradiation intensity and the irradiation time is in the range of 10 to 5000 mJ/cm 2 . set up. When the total amount of light to the adhesive is less than 10 mJ/cm2, the production of the active species from the polymerization initiator is insufficient, which may cause insufficient curing of the adhesive. Further, when the integrated light amount exceeds 5000 mJ/cm2, the irradiation time becomes extremely long. In terms of productivity improvement, it sometimes becomes unfavorable. When the curing of the adhesive is carried out by heat, it can be heated by a generally known method, and the conditions thereof are not particularly limited, and it is usually produced by a thermal cationic polymerization initiator which can be formulated in 322869 68 201140127. η is a blood-borne % ion species or a Lewis acid:: degree or more heating. The specific heating temperature is, for example, 5 〇 to _ whether it is by hardening the active energy ray or heating, preferably at The degree of polarization of the polarizing film, the transmittance, and the color of the anti-glare film or the transparency of the protective film and the phase difference characteristics of the optical compensation layer, such as the anti-glare polarizing plate, can be hardened. <Image Display Device> The present invention further provides (4) that the anti-glare polarizing plate of the present invention and the image of the =4 and 7G are not displayed. In the video display device of the present invention, the = polarizing plate is disposed on the image display element and the viewing side with the anti-glare layer side being outside. In other words, the anti-glare polarizing plate of the present invention is suitably used as a front polarizing plate, and the uneven surface of the anti-glare film, that is, the anti-glare layer 1 is disposed on the outer side (viewing side). The viewing of the component I° with respect to the image display device is representative of a liquid crystal cell in which the liquid crystal is sealed between the upper and lower sides and the alignment state of the liquid crystal is changed by applying a voltage to perform shadow=display. As described above, the driving mode of the liquid crystal cell has various modes such as a vertical alignment (VA) mode, a transverse electric field (In to Plane Switching: IPS) mode, and a twisted nematic (TN) mode. The anti-glare polarizing plate can be directly attached to the surface of the image display element, and the iyl 8 can be attached to the surface of the image display element by a protective film or an optical compensation layer as described above. The image display device having the anti-glare polarizing plate of the present invention can scatter the incident light and blur the map image by the irregularities on the surface of the anti-glare film of 69 322 869 201140127, thereby imparting better visibility. Further, even when the anti-glare polarizing plate of the present invention is used in a high-definition image display device, it does not generate a speckle as viewed by a conventional anti-glare film, and can exhibit sufficient prevention of mapping and panning. White, which suppresses the excellent performance of the reduction of the speckle and contrast. (Embodiment) The present invention will be described in more detail in the following examples, but the present invention is not limited thereto. The anti-glare film and the method for evaluating the pattern for producing an anti-glare film used in the anti-glare polarizing plate of the following examples are as follows. [1] Measurement of surface shape of anti-glare film used in anti-glare polarizing plate The surface shape of the anti-glare film was measured using a three-dimensional microscope PL v 2300 (manufactured by Sensofar Co., Ltd.). In order to prevent the warpage of the sample, an optically transparent adhesive is applied to the glass substrate so that the uneven surface becomes a surface, and then supplied to the measurement. When measuring, set the magnification of the objective lens to 10 times. The horizontal decomposition energy Δχ and Ay are both 1.66 μ m, and the measurement area is 850 /z mx850 e m. (The ratio of the energy spectrum of the elevation is HJ/iL·2 and H32/H22) From the measurement data obtained above, the elevation of the fine uneven surface of the anti-glare film is obtained as a two-dimensional function h(x, y), and the obtained The two-dimensional function h(x, y) performs discrete Fourier transform to obtain a two-dimensional function H(fx, fy). The two-dimensional function H(fx,fy) is squared to calculate the two-dimensional function H2(fx,fy) of the energy spectrum, and the spatial frequency is obtained from the H2(0, fy) of the profile curve of fx=0. The energy spectrum in 0. 01 μ m_1 and the energy spectrum in space 04.//m_1 are 70 322869 201140127 H22, and the ratio of energy spectrum HJ/IL·2 is calculated. In addition, the energy spectrum in the spatial frequency of 0.1 βπΓ1 is obtained, and the energy spectrum ratio H32/H22 is calculated. (inclination angle of fine uneven surface) Based on the measurement data obtained above, and calculated according to the above algorithm, a histogram of the inclination angle of the concave-convex surface is prepared, and the distribution of each inclination angle is obtained from the figure, and the calculation is calculated. The ratio of the angle at which the inclination angle is 5° or less. [2] Measurement of optical characteristics of anti-glare film used in anti-glare polarizing plate (Haze) The haze of the anti-glare film was measured by a method defined in JIS K 7136. Specifically, the haze is measured using a haze meter "HM-150 type" (manufactured by Murakami Color Research Laboratory Co., Ltd.) according to this specification. In order to prevent the warpage of the anti-glare film, an optically transparent adhesive is applied to the glass substrate so that the uneven surface is formed into a surface, and then supplied to the measurement. In general, when the haze is increased, the image used in the image display device is darkened, and as a result, the front contrast is easily lowered. Therefore, it is better to have a lower haze. [3] Anti-glare performance and contrast evaluation of the anti-glare polarizing plate The backlight of the thus-prepared liquid crystal display device was activated in a dark room, and the black display state was measured using a brightness meter "BM5A type" (manufactured by Topcon Co., Ltd.). The brightness of the liquid crystal display device in the white display state, and the comparison is calculated. Here, the comparison is expressed by the ratio of the brightness of the white display state to the brightness of the black display state. Next, the evaluation system is moved to a bright room, set to a black display state, and the mapping state and whitening are visually observed. Then, in the bright room, the white display state is set and the flare is also observed visually. About 71 322869 201140127 is as follows. Evaluation criteria for shot state, whitening, and flash spots Mapping 1: No mapping observed. 2: A few mappings were observed. 3: The mapping is clearly observed. Whitening 1: No whitening was observed. 2: A little whitewash was observed. 3: Whitening was clearly observed. Flash spot 1 · No spot is observed. 2: A few flash spots were observed. 3: Many flash spots were observed. [4] Evaluation of water resistance of anti-glare polarizing plate The water resistance was determined by the method shown below. First, take 靼#, 防 防 防 防 ) ) ) = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = Moth, so it covers all aspects of the ground: color. Next, in the state of holding a short side of the sample, about 80% of the length direction of the sample is immersed in 6 (Tc sink, and held for 4 hours. Then take the sample from the sink to wipe the moisture and Observe the polarizing plate. - The film is shrunk by 5 Hz warm water to shrink the polarizing film of the sample. In addition, the iodine is eluted from the peripheral portion of the polarizing film in contact with warm water by the temperature immersion, and this week The fading portion is fading. The degree of shrinkage and fading of the polarizing film can be determined by measuring the end of the sample from the center of the short side of the sample (one end of the anti-glare film) to the characteristic of the polarizing film remaining in the contracted polarizing film. The distance of the color area 72 322869 201140127 is evaluated and used as the erosion length. The smaller the erosion length, the smaller the shrinkage and fading of the polarizing film, and the higher the water resistance of the anti-glare polarizer. [5] Evaluation of anti-glare film manufacturing pattern The two-dimensional discrete function g(x, y) is used to represent the tonality of the pattern data produced. The horizontal decomposition energy Δχ and Ay of the discrete function g(X, y) 2 ym. The resulting two-dimensional function g(xy) The two-dimensional function G(fx,fy) is obtained by discrete Fourier transform. The two-dimensional function G(fx,fy) is squared to calculate the two-dimensional function G2(fx,fy) of the energy spectrum, and from fx=〇 In the G (0, fy) of the profile curve, it is evaluated whether it has a maximum value in a spatial frequency range greater than 〇#m-1 and below 〇. 〆m_1. <Example 1> (A) Production of polarizing film The polyvinyl alcohol film having an average polymerization degree of about 2400, a degree of saponification of 99.9 mol% or more and a thickness of 75/zra was immersed in 3 (TC pure water, and then immersed in iodine/potassium iodide/water at 3 (TC). The weight ratio is 〇· 02/2/100 aqueous solution, and then immersed in an aqueous solution of potassium iodide/boric acid/water in a weight ratio of 12/5/100 at 56.5 ° C. Secondly, it is pure at 8 ° C.倍倍。 (3 times. The total stretching ratio is 5.3 times. B) Preparation of mold for manufacturing anti-glare film First, a copper ball-plated plate was prepared on the surface of an aluminum roll (according to JIS A5056) with a diameter of 200 mm. The copper ballard plating was made of copper plating. / The thin silver plating layer / the surface copper plating layer is formed, the thickness of the entire plating layer is set to be large 73 322869 201140127 The force 200 is mirror-polished with m β of the copper surface, and the photosensitive resin is coated on the ground. The surface of the plated steel is dried to form a photosensitive resin film. Secondly, a pattern consisting of the image data shown in Fig. 15 is repeatedly arranged in a plurality of patterns to form a pattern, and the pattern is applied to the photosensitive tree. Exposure and development by laser light on the ruthenium film. Exposure and development by laser light were carried out using Laser Stream FX (manufactured by Think Laboratory Co., Ltd.). The photosensitive resin film is a positive photosensitive tree. The pattern shown in Fig. 15 is for the pattern of irregularly arranging a plurality of dots having a dot diameter of 12/m, which is used to remove the spatial frequency 〇. 04"^^ below the low spatial frequency component and 0. i Produced by a band-pass filter having a high spatial frequency component of mi or more. Then, the first etching treatment (etching amount: m) is performed with a copper chloride solution. After the first etching treatment, the photosensitive resin film is removed from the roller. The second etching treatment (etching amount: 10/zm) was carried out again with a copper chloride solution. Then, chrome plating was performed so that the thickness of the chrome plating was 4 μm to prepare a mold a. (C) Production of an anti-glare film The resin composition "GRANDIC 806T" (manufactured by Dainippon Ink Chemicals Co., Ltd.) was dissolved in ethyl acetate to prepare a solution having a concentration of 5 wt%, and then rLucirin τρο" of the photopolymerization initiator (BASF Corporation) Chemical name: 2, 4' 6-trimethylbenzimidyl diphenylphosphine oxide), and a coating liquid was prepared by adding 5 parts by weight per 1 part by weight of the curable resin component. Next, this coating liquid was applied to a cellulose triacetate (TAC) film having a thickness of 80 m so that the coating thickness after drying was 6 vm, and it was carried out for 3 minutes in a dryer set at 60 ° C. Dry 322869 74 201140127 Dry. The dried TAC film was pressed against the concave convex surface of the previously obtained mold A by a rubber roller so that the photocurable resin composition layer became the mold side, and was adhered. In this state, the light from the high-pressure mercury lamp having a strength of 2 〇 mW/cm 2 is irradiated from the TAC anti-glare film side so that the amount of light in the h-ray and the line-converted light becomes 200 mJ/cm 2 to form a photo-curable resin composition layer. hardening. Then, the TAC film was peeled off from the mold together with the cured resin, and a transparent antiglare film A composed of a laminate of a cured resin (antiglare layer) having irregularities on the surface and a TAC film was produced. (D) Preparation of an adhesive composed of a curable composition containing an epoxy resin as a main component, bis(3,4-epoxycyclohexylmethyl) adipate, 1 part by weight, hydrogenation double The diglycidyl group of A is called 25 parts by weight, and the photocationic polymerization initiator [4,4-bis(diphenylnonyl)diphenyl bis hexafluorowei salt 2 parts by weight is mixed and defoamed. Made of a hardenable composition; an adhesive. The silk ion polymerization initial limb is a 5 G f % propylene carbonate solution. ^ (E) Preparation of anti-glare polarizing plate The above-mentioned adhesive is applied to the surface of the anti-glare film A on the opposite side to the side on which the anti-glare layer is formed. The thickness of its electricity is i ^ 70. In addition, on the surface of the protective film, the electrosaumatic refraction (4) resin film ("ZE0N0R": manufactured by Co., Ltd.) (hereinafter also referred to as "Na Na") is electro=== After the above-mentioned adhesive agent is applied by a bar coater, the side of the cloth is placed on the opposite side of the surface of the polarizing film and the surface of the polarizing film 322869 75 201140127 having the anti-glare film. . Then, ultraviolet rays were irradiated by an ultraviolet irradiation device (irradiation lamp: Fusion D Lamp, integrated light amount: 1000 mJ/cm 2 ) with a conveyor belt, and left at room temperature for 1 hour to obtain an anti-glare polarizing plate A. (F) Production of a liquid crystal display device. A liquid crystal panel is taken out from a commercially available liquid crystal display ("LC-32GH3", manufactured by Sharp Co., Ltd.) of a liquid crystal display device (liquid crystal panel) in which a vertical alignment mode is mounted, and the liquid crystal cell is taken out from the liquid crystal cell. Lieutenant peeled off the polarizing plate. Then, the polarizing plate Sumikalan SRDB31E" (manufactured by Sumitomo Chemical Co., Ltd.) was placed in such a manner that the absorption axis of the polarizing plate was aligned with the direction of the retracting axis of the polarizing plate to be attached to each liquid crystal cell, and the adhesive layer was interposed. The liquid crystal panel was produced by laminating the back side of the liquid crystal cell (backlight side) and bonding the above-described anti-glare polarizing plate 8 to the front side (viewing side) of the liquid crystal cell. Next, the liquid crystal panel was assembled by a backlight/light diffusing plate/liquid crystal surface (four), and a liquid crystal display device A was produced. <Example 2> In the exposure step of mold making, the image shown in Fig. 16 will be

In the case of St, the plurality of sheets are repeatedly arranged in a row to form a pattern == on the photosensitive resin film by the laser light _ the amount of the first (fourth) processing is 5, and the amount of the button is the formula (10). : Outside 'others and examples! The same operation: x ' "1 B. In addition to the use of the sample operation _ In addition to the use of the anti-glare film B, the other 322869 76 201140127 made the anti-glare polarizing plate B and the liquid crystal display device 6. Figure i6 The pattern shown is a band-pass filter for removing a low-frequency component of a frequency of ~4 or less and a high-frequency component of 0.135 W or more for a pattern in which a plurality of dots of _12_ are not arranged finely. Producer. <Comparative Example 1> The surface of pure 300 (JIS &lt; A5〇56) having a diameter of 300 coffee was mirror-polished, and a sand blasting apparatus (manufactured by Fuji Manufacturing Co., Ltd.) was used to apply blasting pressure G. 1 MPa (measured pressure), particle amount 8 g / em 2 (roll surface area per 1 cm 2 ) cerium oxide particles TZm 7 (T〇s〇h Co., Ltd., average particle size: 20 / zm) sandblasting The surface of the polished aluminum surface was formed with irregularities on the surface. The obtained aluminum roll with irregularities was subjected to electroless nickel plating to prepare a mold c. At this time, the thickness of the electroless nickel plating was set to 15 #m. Other than the obtained mold C, the same operation as in the embodiment An anti-glare film C was produced, and an anti-glare polarizing plate C and a liquid crystal display device C were produced in the same manner as in Example 1 except that the anti-glare film C was used. <Comparative Example 2> Kuraray Co., Ltd. The carboxy-modified polyvinyl alcohol "Kuraray Poval KL318" (modified degree 2 mol%) ι. 8 parts by weight dissolved in 100 parts by weight of water 'then added as Sumika as a water-soluble polyamide resin "Sumirez Resin 65" (a 30% by weight aqueous solution of a solid content) sold by Chemtex Co., Ltd. was dissolved in 1.5 parts by weight to prepare a polyvinyl alcohol-based adhesive. Next, after the saponification treatment is performed on the side of the anti-glare film which is formed with the anti-glare layer on the side opposite to the side of 322869 77 201140127, the above-mentioned polyethylene-based adhesive is applied to the surface by a bar coater. The surface was coated, and the polarizing film was laminated thereon. Further, the corona discharge treated surface of the norbornene-based resin (the same as in Example 1) which was subjected to corona discharge treatment as the surface of the protective film was coated with a rod. After applying the polyvinyl alcohol-based adhesive 1()_ to the coating machine, the decylene film is laminated on the side opposite to the side where the anti-glare film is bonded to the polarizing film. The face. Then, it was dried at 8 {rc for 5 minutes, and then aged at normal temperature for 1 day to obtain an anti-glare polarizing plate D. The results of the above [1] to [4] measurement and evaluation are summarized as follows! Table and Table 2. Further, Fig. 17 is a cross-sectional view showing fx = 中 in the energy spectrum G2 (fx' fy) obtained from the pattern used in the production of the mold A of the embodiment and the mold B of the second embodiment. From Fig. 17, it can be seen that the energy spectrum of the patterns used in the first and second embodiments does not have a maximum value in a spatial frequency range larger than 〇Mnfl and 〇 〇4 or less. Table 1 Example 1 Example 2 Comparative Example 1 Anti-glare polarizing plate A B C Mold A B C energy spectrum ratio h, vh22 19 4 41 Surface shape H3VH22 0. 002 0. 001 0. 003 Tilt angle 5. The ratio of the following surface 100 100 100 Optical characteristic haze (%) 0.4 0. 6 0.4 Anti-glare performance map 1 1 1 Whitening 1 1 1 Flash spot 1 1 3 Comparison 1950 1950 1950 78 322869 201140127 Table 2 Example 1 Implementing your financial water intrusion length (mm) 0. 5 2Α~^^ ----s From the results shown in Table 1, it is known that the anti-glare polarizing plate A and the prevention of all the requirements of the present invention are obtained. The glare polarizing plate B showed no flare at all, showed sufficient anti-glare property, and did not cause whitening. In addition, when configured on an image display device, high contrast is also displayed. Further, as shown in the second table, the anti-glare polarizing plate A of the present invention has a high water resistance because a curable composition containing an epoxy resin as a main component is used as an adhesive. On the other hand, the energy spectrum ratio 2, 2/&quot; the anti-glare polarizing plate C of Comparative Example 1 which did not satisfy the requirements of the present invention, produced a flare. Further, the antiglare property D of Comparative Example 2 using a polyethylene glycol-based adhesive was inferior in water resistance. BRIEF DESCRIPTION OF THE DRAWINGS A preferred first embodiment of the anti-glare polarizing plate of the present invention is a cross-sectional view schematically showing an example. Fig. 2 is a perspective view schematically showing the surface of an anti-glare film provided in the anti-glare polarizing plate of the present invention. Figure 3 shows the non-discretely 寐 寐 西 西 西 西 西 西 西 西 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第 第An example of the elevation of the fine uneven surface of the layer provided in the anti-glare polarizing plate of the present invention. The two-dimensional picture 5 shown in Fig. 4 is not shown in white and black. Table 322869 79 201140127 Function h ( x, y ) The energy spectrum H2 (fx, fy) of the elevation obtained by discrete Fourier transform Figure. Fig. 6 is a view showing a cross section of fx = 中 in the energy spectrum H2 (fx, fy) shown in Fig. 5. Fig. 7 is a schematic view for explaining a method of measuring the inclination angle of the fine uneven surface. Fig. 8 is a graph showing an example of a histogram of the oblique angle distribution of the fine uneven surface of the antiglare layer provided in the antiglare film. Fig. 9 is a view showing a part of image data of a pattern usable for producing an anti-glare film provided in the anti-glare polarizing plate of the present invention. Fig. 10 is a diagram showing the energy spectrum G2(fx, fy) obtained by performing discrete Fourier transform on the two-dimensional function g(X, y) of the gradation shown in Fig. 9 in white and black gradations. Fig. 11 is a view showing a section of fx = 中 in the energy spectrum G\fx, fy) shown in Fig. 10. Fig. 12 (a) to (e) are diagrams schematically showing a preferred example of the half of the month of the mold manufacturing method. Fig. 13 (a) to (c) are diagrams schematically showing a preferred example of the latter half of the method for manufacturing a mold. Fig. 14 (a) and (b) are diagrams schematically showing a state in which the uneven surface formed in the first etching step is passivated by the second etching step. Fig. 15 is a view showing a pattern used in the production of the mold of Example 1. Fig. 16 is a view showing a pattern 322869 80 201140127 used in the mold making of Example 2. Fig. 17 is a view showing a cross section at fx = 0 in the energy spectrum of the pattern shown in Figs. 15 and 16. [Main component symbol description] 1 r\ Anti-glare film 2 Fine bump 3 Anti-glare film projection surface 5 Main normal direction 6 Local normal 6a, 6b, 6c, 6d Normal vector 7 Mold base 8 Grinded Surface 9 Photosensitive resin film 10 Expoched area 11 Unexposed area 12 Mask 13 No mask 15 First surface uneven shape 16 Chrome plating layer 17 Chrome plated surface 18 Second surface uneven shape 101 Antiglare layer 102 Transparent support Body 103a first adhesive layer 103b second adhesive layer 104 polarizing film 105 protective film or optical compensation layer 322869 81

Claims (1)

201140127 VII. Patent application scope: 1. An anti-glare polarizing plate, comprising: anti-glare, having a transparent support body, and an anti-glare layer having a concave-convex surface laminated on the transparent support body, and a polarizing film comprising a thin alcohol resin film, which is laminated on a surface of the transparent support opposite to the antiglare layer, via a first adhesive layer; wherein the first adhesive layer is a ring containing a ring The cured product of the curable composition of the oxygen-based resin; the energy spectrum of the elevation of the aforementioned concave-convex surface at a spatial frequency of 0.01/ΖΠΓ1 and the spatial frequency 〇. 标4 β mi of the aforementioned surface of the concave-convex surface The energy spectrum W ratio Hl2/H22 is in the range of 1 to 20; the spatial frequency is 0. lym-1 is the elevation of the aforementioned concave and convex surface energy δ#Η3 and the spatial frequency is 0. ηΓ1 is the elevation of the aforementioned concave and convex surface The energy spectrum Η22 ratio H3VH22 is 〇.1 or less; and the uneven surface includes 95% or more of the surface having an inclination angle of 5° or less. The anti-glare polarizing plate according to the above-mentioned item of the Shenjing patent scope, which has a protective coating film which is interposed between the second adhesive layer and laminated on the polarizing film opposite to the anti-glare film. Side face. The anti-glare polarizing plate according to claim 2, further comprising a photonic complement layer, wherein the optical compensation layer is laminated on the protective film. The anti-glare polarizing plate according to claim 3, wherein the optical compensation layer is an optical compensation film. The anti-glare polarizing plate according to the second aspect of the invention, wherein the first adhesive layer is composed of a cured product containing a curable composition of an epoxy resin. 6. The anti-glare polarizing plate according to claim 1, further comprising an optical compensation layer which is laminated on the polarizing film opposite to the anti-glare film by a second adhesive layer Side face. 7. The anti-glare polarizing plate according to claim 6, wherein the optical compensation layer is an optical compensation film. 8. The anti-glare polarizing plate according to claim 6, wherein the second adhesive layer is made of a cured product containing a curable composition of an epoxy resin. 9. The anti-glare polarizing plate according to claim 1, wherein the polarizing film comprises a polyvinyl alcohol-based resin film which is uniaxially stretched and adsorbed and has a dichroic dye. 10. An image display device comprising: an anti-glare polarizing plate according to claim 1; and an image display element; wherein the anti-glare polarizing plate is disposed such that an anti-glare layer side thereof is outside On the viewing side of the aforementioned image display element. 2 322869