TW201139653A - Surface multifunctional treatment agent composition - Google Patents

Abstract

A surface multifunctional treatment agent composition comprising octadecyldimethyl(3-trimethoxysilylpropyl)ammonium chloride and/or octadecyldimethyl(3-triethoxysilylpropyl)ammonium chloride, an amidoamine oxide, and an alcohol, and water, even when stored at low temperature, prevents the occurrence of cloudiness and precipitation and allows antimicrobial properties to be exhibited as well as improves deodorization, water repellency, and oil repellency and reduces frictional resistance.

Description

201139653 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to an octadecyldimethyltrimethoxydecylpropylammonium chloride and/or vaporized octadecyldimethylamine (a) A surface multifunctional treating agent composition of 3_triethoxydecylpropyl)ammonium. [Prior Art] In the field of anti-bacterial properties, there is a tendency to improve the awareness of hygiene in facilities such as facilities that people are exposed to. For medical instruments such as dental instruments, it is known that it is necessary to impart antibacterial properties to the surface of the device, and it is not only for medical use, but also known as sinks for toilets, toilets, food containers, fish, etc. , vases, cleaning utensils, clothing, and other uses for a variety of antibacterial properties. Therefore, as long as A, a metal such as silver, a compound such as silver, or a compound having various antibacterial properties such as an antibacterial agent such as an organic compound is used, or the antibacterial agent is blended to a material constituting the article to impart antibacterial properties. However, the surface treatments have the following conditions: in order to impart antibacterial properties, f, heat treatment steps rather than simply coating; or due to the surface: the car is weak, the antibacterial agent gradually peels off during use, Therefore, antibacterial!·Life does not last for a long period of time, or the antibacterial property is weakened by washing. In particular, if the antibacterial property is not sustained, there is antibacterial property even by antibacterial treatment, and it is not antibacterial in actual use, and as a result, not only the antibacterial treatment effect but also the unknown to the user is not obtained. In the case of use, the items that have been propagated by the bacterium have a health risk. Further, when an antibacterial agent such as a metal such as silver or a compound thereof or various antibacterial properties such as antibacterial property of 152976.doc 201139653 compound is blended into a material constituting the article, an antibacterial agent is also present in the interior of the article. Therefore, the antibacterial agent required is more than necessary. Under such circumstances, in recent years, it has been known to use a ruthenium-containing compound for the purpose of imparting antibacterial properties to coat the article (4). Among such a cerium-containing compound, octadecyldimethyl(3-trimethoxydecylpropyl) chloride is known. Patent Document 1 discloses a foaming of a cerium oxide gel coated with a dimethyl octadecyl dimethyl (3-trimethoxyxanthyl propyl)-based solution as a functional compound. The vitreous body was treated to fix octadecyl monomethyl (3-dimethoxypropenylpropyl) chlorohydrin. Patent Document 2 describes an antibacterial material characterized in that chlorine decamethyl-monomethyl (3-dimethoxyoxyalkylalkyl) ammonium is immobilized on a surface as a decane compound having an antibacterial substance. Patent Document 3 discloses that the secondary value of the aqueous solution is adjusted to 3.5 to 2.0 in an aqueous solution of an antibacterial agent containing octadecyl dimethylated trimethyloxy oxalate propyl group; It is excellent in the stability by setting the above-mentioned positive value range; and after the water material is brought into contact with the surface of the antibacterial material for a certain period of time, it is washed and dried. Patent Document 4 describes an antibacterial treatment of a resin obtained by impregnating a synthetic resin in an aqueous solution of octadecyldimethyl (3-dioxanyloxy) chlorohydrin chloride. The method; and the surface contact angle after the treatment is 80 to 90. . Patent Document 5 discloses a cleaning agent composition containing a compound such as chlorinated octadecyl dimethyl & octa 152976.doc 201139653 oxysulphate propyl) and by the cleaning Dentures, toilets, kitchen supplies, baths, bathroom accessories, tableware, glasses, sinks, kitchen week _ 4 supplies, washbasins, wash peripherals, fiber products and clothes; The composition of the composition is excellent in cleanability and excellent in anti-sense, and the treated materials are excellent in antibacterial durability. Patent Document 6 discloses an antibacterial separation membrane obtained by fixing a sulphuric acid compound having an antibacterial action such as octadecyl dimethyl sulfonate to a separation membrane. Patent Document 7b describes an anti-® film cassette in which a coating layer containing cellulose acetate as an antibacterial agent is formed on the inner surface of the film cartridge body. Patent Document 8 describes an antibacterial tempered glass article obtained by applying a solution containing f or a liquid in which silver fine particles are dispersed on the surface of a tempered glass article, and then heating and diffusing the silver to the inner surface of the surface layer portion. Patent Document 9 describes pre-killing bacteria for seawater used for slimming marine organisms. Patent Document 1G discloses a vase for accommodating flowers and the like, and is constituted by a substance containing an antimicrobial metal on the inner surface of the base plate. CITATION LIST Patent Literature Patent Literature 1: Patent Publication No. 2004-345243 Patent Document 2: Japanese Patent No. 3,834, 655 Patent Document 3: Japanese Patent Laid-Open Publication No. 2007-31290 Japanese Laid-Open Patent Publication No. 2007-146134, Patent Document 6: Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. Hei No. Hei. No. Hei. No. Hei. No. 2000-342074. Problems to be Solved As described above, a compound for surface treatment in which a gasified octadecyldimethyl(3_trimethoxydecylpropyl) saddle has an antibacterial action is known. However, since the stability of the aqueous solution of the compound is poor, there is a state in which a composition for surface treatment is prepared, especially if it is stored at a low temperature, which results in a white turbidity or a phlegm rather than a homogeneous solution, and thus cannot be used in subsequent use. A situation in which full effect is achieved. Further, after the preparation, it is applied to the object and added: during the drying period, there is a possibility that the composition is deteriorated, and in this state, the object to be treated may not exhibit a specific property. X is difficult to directly treat an object having poor acid resistance if the pH is adjusted to 3.5 to 2. G ' to form a solution. In addition, when it is only antibacterial, it is difficult to use it for the equipment, window glass, floor or wall used in the washing place of each manufacturing system. The Si must be actively deodorized in addition to the antibacterial property. X special object is treated after ', main green' or oil repellency to raise H π ..., must increase water repellent,) low friction (four). Read, and then must also have cleaning tools; 】 52976.doc 201139653 Qing 2 anti-pollution is also poor ', then the antibacterial treatment should be carried out frequently after the treatment of Ke, etc., the applicability is worse. Jw or rag (4) If the frictional resistance is particularly large in the contact area of the various cleaning tools for wiping and cleaning, the force required for further steps is required, so that more force is required for cleaning, so that cleaning is performed~'^ to strong Fatigue. In addition, when cleaning various cleaning tools after cleaning, the Ο:/month cleaning tool itself does not have antifouling properties, and the dirt adhering to the cleaning tool does not easily fall off, making it difficult to clean. In the field of preservation of other fields, food containers, biological breeding, and fresh (4), a cellulose acetate-containing layer, a diffusion layer of an antibacterial metal such as silver, or a seawater of a culture must be placed on other surfaces of the container. Used after sterilization. Means for Solving the Problem As a treating agent composition for solving the above problems, the present invention employs a chlorinated octadecyl dimethyl (3-trimethoxy succinylpropyl) group and/or chlorinated A versatile treatment composition of octadecyl bis-f-(3-triethoxy-propyl)ammonium, guanamine amine oxides, and an alcohol and water surface. Further, it may contain the above-mentioned vaporized octadecyldimethyl(3_trimethoxydecylpropyl) and octadecyl dimethyl chloride (3-triethoxy oxalate propyl) Only one of them, and its concentration is 〇〇1~1〇% by weight, or may also contain octadecyldidecyl(3-trimethoxydecylpropyl)ammonium chloride and octadecyl chloride Monomethyl(3-diethoxydecylpropyl)ammonium, and the total concentration of these is from 0. 01 to 10% by weight. Further, the above-mentioned amine amine oxides may be melamine dimethyl oxy 152976.doc 201139653 amines, and the concentration of guanamine amine oxides is also 1 to 10% by weight. Further, such a composition may further contain a polyhexamethylene biguanide compound in an amount of 〇 5 to 5 parts by weight. Moreover, the surface multifunctional treatment agent 袓. . . W, and σ can also be stable for more than one week in the range of 2 C to 50 C for its solution. EFFECTS OF THE INVENTION The effects of the present invention are as follows: · Even if octadecyl dimethyl (tetra)oxy ketopropyl chloride is stored and/or octadecyl dimethyl (3 _ ethoxy) is chlorinated矽Alkylpropyl)ammonium, also by the crude / * 4α system, 3 has amine amine oxides, and the storage stability is obviously improved #, and the decoration of the 丨 2 2, Μ文 π When the solution of the functional treatment composition is stable and turbid, it is also restored to the original stable six-hearted/exciting liquid by adding/dish, and the above effects are exerted, and the two treatments are processed. Things can play a specific effect. In addition, further effects can be obtained. You*., the surface multi-functional treatment composition has nothing to do with the preservation state, and it can be used for treatment after heating and heating. The present inventors have confirmed that by using 表面. At ^ 由 by using a surface containing a guanamine amine oxide, the composition of the treatment agent not only provides the following effects: ± ^ . At the same time, the surface of the treated material is water-repellent, low-lying rod*' surface, and also imparts a deodorizing effect. Further, the antibacterial property can be further improved by adding a ^ + substance to the surface treatment agent composition of the present invention. 'With the above effects, the material as a surface multi-functional treatment agent for the treatment of the treatment considers the hygienic treatment of the prosthesis, and in addition, the surface of the treatment of the 152976.doc 201139653 must be removed. Low friction to reduce the force required for cleaning, such as mopping (work), to prevent the occurrence of malodor, so that the burden of the alpha sweeper can be reduced or the work efficiency is improved, and the environment is Upgrade. Further, by cleaning the cleaning tool such as the mop, the cleaning tool is also low-frictional, so that the force required for the cleaning tool to be in close contact with the surface of the object and wiped can be further reduced. 1 obtained by a stabilized surface multifunctional treatment composition

^The surface of the antibacterial compound bonded to the surface of the object is different from the surface obtained by simply obtaining a layer containing the antibacterial substance by coating or the like, which can form a long-term antibacterial surface without spreading the silver. Heat treatment as usual. Moreover, it is not necessary to sterilize water in other devices for the cultivation or rearing of aquatic organisms such as marine organisms. [Embodiment] (Emulsified octadecyldidecyl (3_trimethoxy ketone)) and octadecyldimethyl(3-triethoxydecylpropyl)ammonium chloride, In the surface multifunctional treatment composition of the present invention, these components function as a main component for exerting an effect. The surface multifunctional treatment agent composition can be separately formulated with gasification octade sulphate dimethoxy fluorenyl alkyl propyl ammonium and octadecyl dimethyl chloride (3-ethoxy oxime; Propyl) recorded 'again, you can also mix them together. The snail is applied to the treatment by a methoxy or ethoxy group, and the ruthenium atom is bonded to the surface of the treatment via a ruthenium atom, whereby the decane compound is immobilized on the surface of the treatment. 152976.doc 201139653 The surface multifunctional treatment composition has a concentration of 〇〇ι~ι〇% by weight, preferably 0.5 to 7% by weight, more preferably 5% by weight. If the concentration is less than 0.01% 〇/〇, the sufficient treatment effect cannot be exerted, and even if it is higher than 1% by weight, the effect corresponding to the increase of the concentration is not observed, and the composition is stable. Sexual deterioration. (Indole amine oxide type) In the surface multifunctional treatment composition of the present invention, the guanamine amine oxide is a component added as a surfactant, and the concentration thereof is 〇〇1 to 1% by weight, preferably 2 to 8 wt%, more preferably 3 to 7 wt%. When the concentration of the amine oxide amine is less than 0.01% by weight, the storage stability at various temperatures from high temperature to low temperature is deteriorated, and even if it is more than 1% by weight, the effect as a surfactant is not exhibited. Further, even if a guanamine amine oxide as a surfactant is added to the surface multifunctional treatment composition, the water repellency and oil repellency of the surface of the object treated by the surface multifunctional treatment composition are not lowered. . As a brewing amine amine oxide type, you can use lauric acid propyl hydrazide amine oxide broth amine propyl dimethyl amine oxide, palmitic acid amine propyl dimethyl methacrylate, oil guanamine propyl dimethyl Base amine, stearamine dimethyl dimethyl amine oxide, coconut fatty acid guanamine propyl didecyl amine oxide, laurel amine ethyl dimethyl decyl amine oxide, lauryl propyl dimethyl amine oxide , laurel amphetamine propyl di-light ethyl amine oxide, lauryl propyl butyl dibutyl amine oxide, etc. (Alcohol) As the alcohol, it is preferred that methanol and/or ethanol 'is also dissolved in water. 152976.doc -10- 201139653 Other known solvents can be used, and the drying step after the treatment is considered. , the composition of '. Therefore, the concentration of the alcohol in the surface multifunctional treatment composition may be any concentration within the range of solubility, and is usually used as a chloro-triphenyl-methyl group (3-dimethoxy-stone) A solvent or a solvent of octadecyl chloro-(3-diethoxydecylpropyl)ammonium chloride which is directly formulated as a solvent for the surface multifunctional treating agent composition. (polyhexamethylene biguanide compound)

As the u-methyl biguanide compound, for example, polyhexamethylene biguanide hydrochloride, t ', methyl biguanide acetate can be used, and the surface polyfunctional treatment can be further improved by adding the polyhexamethylene diterpenoid compound The antibacterial property of the composition. The concentration in the surface multifunctional treatment composition is 0.001 to 5% by weight, and if the addition ratio is less than 0.01% by weight, the effect obtained by adding the polyhexamethylene bismuth-based compound cannot be sufficiently exhibited' and even if 5 weight is added More than %, we can't expect further antibacterial improvement. The surface multifunctional treatment composition may contain water. The term "water" as used herein refers to water contained in the composition and water used in the dilution, and the hardness of the water is preferably 300 mg/1 or less, more preferably 1 〇〇 mg/1 or less. . If the hardness is 300 mg/Ι or more, the minerals contained in the water are analyzed to have an adverse effect on the storage stability. This will affect the surface modification properties of the composition. Further, the use of water having a hardness of 100 mg/Ι or less has no effect on the storage stability or surface modification effect of the composition, so that there is no problem in using low-hardness water. The tap water quality standard is 3 〇〇 mg/i or less. In most areas, 152976.doc 11 201139653 is used when the tap water hardness is 100 mg/1 or less, so dilution is a problem. (Other components which can be added) As long as the function of the composition is not impaired, or in each of the known surface multifunctional treatment compositions which are excellent in dispersibility, a compatible substance can be added in addition to the above components. Examples of the substance to be added include other antibacterial agents, fungicides, other surfactants, viscosity adjusters, acrylic resins as a vehicle, resins such as alkyd resins, fillers such as calcium carbonate, and resin particles. Additives of various properties such as pigments such as cerium oxide, titanium dioxide, and carbon black, inorganic coloring pigments, organic pigments, pigments, fluorescent materials, ultraviolet absorbers, insecticides, and perfumes. In the case of using other antibacterial agents or bactericides, it is possible to select a bactericidal/antibacterial agent which has an effect on the fine g in order to eliminate the problematic bacteria depending on the site of use. If the viscosity modifier 'vehicle or filler is formulated, the viscosity of the surface multifunctional treatment composition can be controlled, or the thickness of the layer containing the surface multifunctional treatment composition when contacting the object can be adjusted, so that the thickness can be increased. The thickness of the film layer comprising the surface multifunctional treatment composition on the surface of the large object. Thus, the duration of the effect of the surface multifunctional treatment composition can be extended, or a higher effect can be exerted. When a pigment, a dye, or a camping substance is added, the layer containing the surface multifunctional treatment composition can be visually confirmed when it is peeled off or consumed as the object to be treated is used, and can be exhibited by presenting various colors. Creative effect. 152976.doc 12 201139653 The ultraviolet absorber prevents deterioration of the object and the surface multifunctional treatment composition layer by ultraviolet rays, and the effect of the surface multifunctional treatment composition can be sustained for a long period of time. (Preparation and Storage Method of Surface Multifunctional Treatment Agent Composition) The surface treatment agent composition is prepared by blending the above components, and the order of preparation is not limited, and the preparation method of the usual solution can be used for the temperature. Lower the allocation. Ο

The surface-multi-functional treatment composition obtained by the preparation is stored in a light-shielding container until it is applied to an object to which an antibacterial property or the like is applied, and the storage temperature thereof may be, for example, a temperature in a normal warehouse. As long as it is not a cold winter or a particularly heated environment, no special attention is required. If it is at a temperature of 0~50 °C, it can only be stored for more than eight months. That is, it is convenient for the surface multifunctional treatment composition to be turbid when stored, for example, by squatting at 5 Torr. The warming condition of the relatively gentle temperature for 2 hours is restored to the original state of no white turbidity. (The object to be treated by the surface multi-functional treatment composition) As an object which can be treated by the surface multi-functional group, the material is not limited, and the inorganic substance, the 豕w. the organic composition, the natural Any material can be used as the object material and/or the hard material, and any one which needs to impart antibacterial property, anti-good water, oil repellency, and low friction property can be used. - As an inorganic material, there are gold pottery such as iron or stainless steel, brick, concrete, stone pine ~ granules, polyethylene, polyester, and polyethylene. Into rubber, natural resin, wood, paper - 曰 Temple 50% resin or natural rubber, · bamboo and other natural products. 152976.doc 201139653 The shape of the object is not limited, and the following various forms can be included, cotton, natural fiber or rayon. Machine 4 fiber, repentance, metal weaving and other inorganic fibers: two = fiber, quasi-wire or cloth, clothing formed from the cloth, ^ resin sheet. film, metal sheet. film, paper, glass plate, : Various materials: A sheet or a film-like article such as a sheet. In addition, the surface of the foam or the inorganic foam or the inner surface is porous, and the article including the rods and the block shapes of the above various materials may be used. As a specific use of the object, it can be used for sputum, sponge or scorpion, Gu Gu, 4 ' ping /, know mop, brush,: 箕: genus:: etc.: wipe material 'rag , 斑斑 - t month 曰跛 its metal defeated, resin or metal, etc.: garbage phase, do not take off shoes with shoes, mats, porch, hoes, shoes, artificial leather, curtains, Umbrella stand, resin long shock, wooden long sense, linen 2 products (sheets, pillowcases, towels), clothing (underwear, shirts, uniforms?, children, hats L hygiene products (masks, diapers, diaper sets), air conditioning shoulders The inside of the waterway, the inside and outside of the water purifier, the kitchen equipment such as the sink, the faucet and other washing spare parts, the washbasin, the stainless steel bath, the resin bath, the gentleman and other cold equipment to clean the toilet seat parts ( Electric seat switch for toilet seat, matching official), toilet, baby products (feeding bottle, toy), food container, lighting appliance, etc., sliding door, door, wall, floor, etc. Residential equipment such as windows, indoor piping, washing of washing machines Home appliances such as automatic dishwashers, and the automatic sale of food and beverages 152976.doc 14 201139653 Machine components, sinks, vases, etc. Products of the field, hospitals, kindergartens, nursing homes, etc. The surface versatile treatment composition of the present invention is treated by the facility, the public transportation facility, the interior decoration of a building such as a public transportation facility, various spare parts or furniture, and the like in a facility requiring sanitary management. (Processing Method Using Surface Multi-Function Treater Composition) Ο Ο As a method of treating each of the above-mentioned objects to be treated by bringing the surface multi-functional treatment composition into contact, for example, by using a usual coating device By immersing a spray or the like to directly contact the surface multifunctional treatment composition with the surface of the object to be treated, χ 'may also cause the surface multifunctional treatment composition to adhere to the brush or cloth by means of the brush or cloth The surface of the object to be treated is spread, and no matter which method is used, it is necessary to process the entire surface of the object to be processed. X, when the contact is fixed After wiping with water, the excess surface multifunctional treatment composition is wiped or rinsed by water washing, etc., and the state becomes good. When the attack is performed by such a method, the object must be cleaned, and if it is dyed, However, it may not be possible to obtain sufficient treatment effect. χ, depending on the surface treatment such as corona discharge treatment or electropolymerization treatment as a pretreatment. Also, the surface multi-functional treatment at the time of treatment may be about normal temperature. It can be about 0 to 50 t. When the surface multi-functional treatment composition is white turbid, it is necessary to perform heating to eliminate white turbidity and to be used for treatment. In the case of treatment, it may be immersed in a bath of the surface treatment agent composition for about four minutes. In particular, the treatment material: 152976.doc -15- 201139653 In the case of a porous substance, in order to carry out sufficient treatment, The surface multifunctional treatment composition must be allowed to soak into the interior. After contact with the surface multifunctional treatment composition, the treatment is terminated by drying at normal temperature, or after a certain period of time, after wiping with water, the excess surface multifunctional treatment composition is wiped or washed by water washing or the like, thereby ending the treatment. . Example 1 Storage stability of the surface multifunctional treatment composition of the present invention For the surface multifunctional treatment composition based on the present invention of Nos. 1 to 10 shown in Table 1-1, the solution after the freshly adjusted solution was observed. The storage stability after storage for 1 month at 50 ° C, 40 ° C and 20 ° C, and storage at 5 ° C and 2 ° C for 7 days. The solution after the preservation was transparent was evaluated as 〇, and the white turbid was evaluated as Δ. Then, the solution of the white turbidity was further heated at 50 ° C for 2 hours, and the recovery property was observed by observing the presence or absence of white turbidity in the solution state. The white turbidity disappeared and the solution was transparent as the 〇. [Table 1-1] Surface multifunctional treatment composition No. 1 2 3 4 5 6 7 8 9 10 Ion exchange water 84.7 88.3 88 88 79.9 79.9 79.9 70.6 70.6 60.9 1 gasified octadecyldidecyl (3 -trimethoxydecylpropyl)ammonium 60%·sterol 40% solution 5 5 - 2.5 8.3 - 4.15 12.5 6.25 16.6 2 octadecyldidecyl chloride (3-triethoxydecylpropyl) Ammonium 60%. Ethanol 40% solution - 5 2.5 - 8.3 4.15 - 6.25 - 3 lauric acid propyl didecyl amine oxide (30%) 10 6.7 6.7 6.7 11.5 11.5 11.5 16.6 16.6 22.2 4®: hexamethylene Bismuth compound hydrochloride (100%) 0.3 - 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Total 100 100 100 100 100 100 100 100 100 100 I : Immediately adjusted solution state 〇〇〇〇〇〇〇〇〇〇 II : 50 ° C, 1 month storage stability 〇〇〇〇〇〇〇〇〇〇 111 : 40 ° C, 1 month storage stability 〇〇〇〇〇〇〇〇〇〇 IV : 20 ° C, 】 Monthly storage stability 〇〇〇〇〇〇〇〇〇〇V : 5 ° C, 7 days storage stability 〇〇〇〇〇〇〇〇〇 Δ VI : 2 ° C, 7 days Storage stability 〇〇〇〇 Δ Δ Δ 厶 Δ Δ VII : Restorative 〇〇〇〇〇〇-16- after 2 days of incubation, after 7 days of testing, after further heating at 50 ° C for 2 hours 152976.doc 201139653 As shown in Table 1-1, it is shown that the surface multifunctional treatment composition according to the present invention has no change in the state of the composition even after being stored at 20 to 50 ° C for one month. Good, when stored at 2 to 5 ° C for 7 days, octadecyldimethyl(3-trimethoxydecylpropyl)ammonium chloride and / or octadecyl chloride When the total concentration of methyl (3-triethoxydecylpropyl)ammonium is high, white turbidity occurs, but even in this case, white turbidity disappears by heating at 50 ° C for 2 hours, and is restored. The original transparent composition has good storage stability. Comparative Example 1 Storage stability of the treatment composition other than the present invention The treatment composition according to the present invention, which is not based on No. 1 to 8 shown in Table 1-2, was observed in the same manner as in Example 1. The state of the solution after the storage and storage stability at 50 ° C, 40 ° C and 20 ° C for 1 month, and storage at 5 ° C and 2 ° C for 7 days. The case where the solution was transparent after storage was evaluated as 〇, the white turbidity was evaluated as A, and the precipitated one was evaluated as X. Further, the solution which precipitated after 7 days of the test at 2 ° C was further heated at 50 ° C to observe the precipitation of the solution state or the presence or absence of white turbidity, and the recovery property was observed. The person whose precipitate did not disappear was evaluated as X. [Table 1-2] Surface multifunctional treatment composition No. 1 2 3 4 5 6 7 8 Ion exchange water 95 95 95 91 93 93 87 88.8 1 octadecyldidecyl chloride (3-trioxane) Base propyl propyl) ammonium 60% / methanol 40% solution 5 - - 5 - 5 2.5 - 2 gasified octadecyl dimethyl (3-triethoxy oxalyl propyl) ammonium 60% / ethanol 40% solution - 5 - - 5 - 2.5 5 3 gasification of 3-(trimethoxydecyl)propyl dimethyl hexadecyl ammonium - - 5 - - - - - 4 - alkyl alkyl Radix (50%), Kao (stock) SanisolC - - - 4 - - - - d waste oxygenated ethylene (20) sorbitan monooleate (100%), Kao (stock) Emasol0-120V - - - - 2 - - - 6 polyoxyalkyl branched mercapto ether, the first industrial pharmaceutical (share) Noigen XL-80 - - - - - 2 - - oxyethylene sodium lauryl sulfate, Kao (share) Emal20C (25%) 8 - 152976.doc -17- 201139653

8 lauric dimercapto amine oxide (320 /.), the first industrial pharmaceutical (share) Amogen AOL (32%) - - - - - - - 6.25 total 100 100 100 100 100 100 100 100 I · just reconciled Solution state 〇〇〇〇〇〇X 〇II : 50C, 1 month storage stability Δ Δ X Δ Δ 〇X 〇III · 40 C, 1 month storage stability 〇Δ X Δ Δ 〇X 〇IV : 20C 1 month storage stability XXX Δ Δ Δ X Δ V . 5C, 7 days storage stability XXXXXXXX VI · 2C ' 7 days storage stability XXXXXXXX VII . 2 L; ' After 7 days of testing, 5 (^c plus The solution state recovery property under temperature XXXXXXXX The comparative example of Table 1-2 is a composition different from the surface multifunctional treatment agent composition of the present invention in that no guanamine amine oxide is added. The treatment composition 3~ of the comparative example In the case of 8, a general-purpose surfactant or the like is used in place of the amine oxide, but all of the treatment composition is produced after 2 or 7 days of storage at a temperature below rc. Further, the treatment compositions 6 and 8 Other examples are just after reconciliation or after 50. (: After 1 month of storage, it will produce white turbidity or sinking. The solution was heated to 5 〇 ° C after 7 days of the test, but even if it was heated for several hours, the precipitation did not disappear and the storage stability was poor. Example 2 Attachment on the washbasin The number of bacteria was measured in advance using a commercially available bleach (Kitchen Haiter manufactured by Kao). After washing the washbasin, it was divided into two in the center of the washbasin, and the surface multifunctional treatment composition was applied as a tap water. No. 1 was diluted to 5 times, and the solution was applied to one side with a rag. After 5 minutes of contact, it was washed with water and processed. One day was used twice a day, and one and a half months later, a commercially available sterilized cotton swab ( Howamedic's DrSwab) was immersed in pure water, shake off excess water, wipe the surface with a cotton swab, and measure the number of bacteria. The other side is not processed. 152976.doc -18- 201139653 Further, in the following examples, the conditions of each of the bacteria for measuring the number of bacteria were as follows.

Trichophyton mentagrophytes, Saccharomyces cerevisiae, Rhizopus storonifer, Cladosporium cladosporioides, Fusarium graminearum, Aspergillus Ochraceus), Aspergillus ustus, Candida albicans, Aspergillus fumigatus, Epicoccum purpurascens, Pestalotiopsis neglecta, Saccharomyces Serpins·· PDA (Potato Dextrose Agar) medium for 4 days; Escherichia coli... MacConkey® agar medium for 1 day; culture temperature was 30. (:±5.(:下下实施. [Table 2] Surface Multi-Functional Treatment Agent Composition Treatment Species No Circles ✓ Trichophyton sinensis 100> It-infected bacteria (ankle, stubborn, in the bathroom) It is easy to produce in the floor mat) Saccharomyces cerevisiae 8.60E+07 Baker's yeast ✓ Trichophyton rubrum 0.00E+00 Body surface infection bacteria (ankle, stubborn, easy to produce in the floor mat of the bathroom) Saccharomyces cerevisiae 7.60E +06 Baker's yeast was treated on one side of the surface multi-functional treatment composition, the number of bacteria of Trichophyton rubrum was 0, and the number of Saccharomyces cerevisiae was 7.6x106 ' reduced to about one tenth. In the case of the number of bacteria, the sterilization was effectively completed. On the other hand, 'the other side of the treatment with the surface multifunctional treatment composition' was in a state of remaining the hairy fungus of the body surface infection bacteria. 152976. Doc •19- 201139653 Example 3 Determination of the number of attached bacteria on the urinal The commercially available bleach (Kitchen Haiter manufactured by Kao) was used to clean the urinal, and then split into two in the center of the toilet. Tap water will be used in the surface of the multi-function area The composition No. 3 was diluted to 5 times, and the solution was applied to one side with a rag, and after washing for 5 minutes, it was washed with water to carry out processing, and after one and a half months, a commercially available sterilized cotton swab (manufactured by Heiwamedic Co., Ltd.) was used. Dr. Swab) was immersed in pure water, shake off excess water, and wipe the surface with a cotton swab. The number of bacteria was measured after one and a half months. [Table 3] Surface multifunctional treatment composition treatment strain No trace of bacterial counts ✓ Rhizopus oryzae 2.70E+03 Phytopathogenic bacteria Saccharomyces cerevisiae 1.30E+04 Baker's yeast Trichophyton 100> Body surface infection bacteria (ankle, stubborn, easy to produce in the floor mat of the bathroom) ) Rhizopus oryzae 0 Phytopathogenic bacteria Saccharomyces cerevisiae 7.70E+04 Baker's yeast Trichophyton sinensis 0 Body surface infection bacteria (ankle, stubborn, easy to produce in the floor mat of the bathroom) Surface multi-functional treatment One side of the agent composition treatment, the number of bacteria of Rhizopus oryzae and Trichophyton rubrum is 0, and the number of Saccharomyces cerevisiae is 7.7x1 04, which is reduced to about one tenth. Since Rhizopus oryzae is a phytopathogenic bacteria, it must be Trichophyton rubrum is a surface infection, so it is understandable The surface treated with the surface multifunctional treatment composition becomes a cleaner surface. On the other hand, on the other side where the surface multifunctional treatment composition treatment is not performed, Rhizopus oryzae and Trichophyton mentagrophytes are abundantly present. Unclean surface. Example 4 152976.doc -20- 201139653 Determination of the number of bacteria in the preservation process of milk Prepare two sealed glass containers of the same shape with a total capacity of 120 ml, using commercially available bleach ( Kitchen Haiter manufactured by Kao) is thoroughly dried after washing, and the surface multifunctional treatment composition No. 4 of the example is diluted 5 times to 100 ml with tap water. The diluent is added to the glass container and left for 10 minutes to flow. After rinsing, it is dried, and a commercially available milk (delicious milk made by Meiji Dairy) is placed in the obtained glass container and the unprocessed glass container, and placed in an unsealed state for 5 hours to be in contact with airborne bacteria. After sealing, it was allowed to stand at room temperature for 1 week, after which the number of bacteria was measured. [Table 4] Surface multi-functional treatment agent composition treatment bacteria number Remarks None ✓ Rhizopus oryzae 5.50E+04 Plant pathogenic bacteria Cladosporium 1.60E+02 Plant pathogens, allergens (substrate Deterioration of pollution) ✓ Rhizopus oryzae 3.60E+03 Phytopathogenic fungus Cladosporium sp. 100> Plant pathogenic bacteria, allergen-causing bacteria (deterioration of substrate contamination) The treatment of surface multifunctional treatment agent composition was carried out without or without In comparison with the situation, the number of strains of Rhizopus oryzae and Cladosporium is reduced, and when it is treated, the growth of bacteria can be inhibited. Example 5 Measurement of the number of bacteria in the water tank of the red-salmon fish Two water tanks having the same shape and the same capacity were prepared, and the surface multifunctional treatment agent composition No. 5 of the example was diluted to 10 times with tap water, and the rag was used. It was applied to the inner surface of the water tank, left to stand for 10 minutes, washed with water and dried, and 25 red mullet were placed in the obtained water tank and the untreated water tank, and the number of bacteria in the water after one week of feeding at room temperature was measured. 152976.doc •21 · 201139653 [Table 5] Surface Multi-Functional Disposal No treatment of the composition of the agent has '--- bacteria number remarks ✓ T. rubrum 1.40E+02, infected bacteria (foot, Recalcitrant, easy to produce in the mantle) --- 点 艮 囷 J.lUb+U3 ^ ^ original bacteria 1 / 癣 癣 癣 S & & & & & & & & & & & & & & & & & & & & & & & & & & 〇 & 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 It is easy to produce in the mat) *.....(4) Sexual bacteria have been treated with the surface of the money for the treatment of the residue, and compared with the case where it is not carried out, the number of bacteria in the genus Trichophyton and Rhizopus oryzae is reduced. In the case of treatment, the growth of bacteria can be inhibited. Example 6 Test results of the number of bacteria in the preservation process of fresh cut flowers (Aster) and the test results of the storage state 2 kinds of glass vases with the same total capacity of 9 (9) ml were prepared, and only the surface multifunctional treatment agent was used for the tap water. The composition N〇3 was diluted 5 times to $ 〇mi, and the dilution was placed in the glass container II, and the dilution was placed on the inner surface and placed for 7 minutes to grasp the m and dry it, and the obtained vase was untreated. The same fresh cut flowers were placed in the bottles, and the number of bacteria was measured after i weeks of observation at room temperature. [Table 6]

Surface multi-function ϊ No i-agent composition imaginary ~--- Sclerotium number remarks ~ one ✓ ----J 癣 癣 1.4 1.40 Ε +02 body surface infection bacteria (ankle, stubborn, in the bathroom It is easy to produce in the floor mat.) The flower itself quickly withers. Rhizopus arrhizus -~·--- 3.10Ε+03 Plant pathogenic bacteria — The flower itself quickly withers. Trichophyton sinensis 100> Surface infection bacteria (black root mold 0 plant pathogenic bacteria in the floor mat of the bathroom " The flower itself quickly withered. ~^J 152976.doc •22- 201139653 Surface multifunctional treatment The treatment of the composition of the agent is compared with the case where it is not carried out, and the number of bacteria of the genus Trichophyton and Rhizopus oryzae is reduced, and when the treatment is carried out, the reproduction of the bacteria can be inhibited, especially since the flower is quickly withered. The number of bacteria of phytopathogenic bacteria is 〇, so this treatment is suitable for preservation of fresh-cutting. Example 7 The results of the measurement of the number of bacteria used in the wet towel and the test results related to the odor are prepared to perform the following operations on the same kind of towel. The operation proceeds, that is, A. The surface multifunctional treatment agent composition No. 3 of Example 1 was diluted to 30 times with tap water, immersed for 15 minutes, thoroughly rinsed with tap water and dried, B. Kamen Humming Flare (registered trademark) processing, use the above towel to wipe the body after the bath (right half, left half), after 10 days of placement, determine the number of bacteria. Two treatments: A. soak the towel to the surface of Example 1 The treatment composition No. 3 was washed for several minutes, and dried and used. B. The Humming Flare daily softener 0.3 g was diluted with tap water 1 1 , immersed for 15 minutes, taken out, wrung out, and dried. [Table 7] Treatment agent bacteria number Remarks Kao Humming Flare treatment of Fusarium graminearum 10 below mildew-producing bacteria Aspergillus oryzae 1.80E+02 Mold-producing bacteria Aspergillus sp. 100 or less Mold-producing bacteria Candida albicans 100 or more Conditional pathogens (fungi) Surface multi-functional treatment composition (30 times) treatment without bacteria 0 152976.doc •23· 201139653

The Humming Flare treatment is one of the washing methods usually carried out, and according to the method of the present invention, the bacteria remaining still treated by the Humming Flare are completely killed, so that the towel which is directly in contact with the human body is extremely sanitary. Moreover, the odor is also an almost imperceptible level. Example 8 Preparation of the surface multifunctional treatment composition of Example 1 with tap water by adding the polyhexamethylene diterpenoid compound to the surface multifunctional treatment composition of the present invention No. 1 and surface multifunctional treatment agent composition No. 2 were diluted to 30 times. Each of the new mops was dipped for 15 minutes in each diluted solution, thoroughly rinsed with running water, and dried to obtain a mop and surface-multifunctional treatment composition treated with the surface multifunctional treatment composition Νο. No. 2 handles one mop each. Using these mops, the number of bacteria in the mop after daily mopping of the water with water within one month was measured. [Table 8] Detection bacteria surface multifunctional treatment agent composition No. 1 Surface multifunctional treatment composition No. 2 Saccharomyces cerevisiae 20 or less 2.70E+02 Cladosporium sp. 10 or less 3.40E+02 Aspergillus niger ( Aspergillus niger) 1.40E+02 was not detected. According to the above test results, the surface multifunctional treatment composition No. 1 of the present invention containing a polyhexamethylene biguanide compound and the polyhexamethylene biguanide-based compound were not contained. Compared with the surface multifunctional treatment agent composition No. 2 of the present invention, the antibacterial effect is high. 152976.doc -24- 201139653 Example 9 Using the machine (Shimamura's men's socks HI 9 antibacterial and deodorant processing) The results of the number of bacteria and the test results related to the odor are prepared 2 pairs of the same kind of socks, A. in 1 pair In the preparation, the surface multifunctional treatment composition Νο·3 of the example was diluted to 30 times with tap water and immersed for 15 minutes, and then thoroughly rinsed with tap water and dried to obtain a gossip. The Kamen Humming Flare (registered trademark) was prepared to process the processor and the unprocessed person, and the number of bacteria in the socks after being worn by the same person for 24 hours was measured. Two treatment methods: A. The towel is impregnated with the surface multifunctional treatment composition for several minutes, washed and dried for use. B. Dilute Humming Flare's daily clothing softener 0.3 g with tap water, dip it for 15 minutes, remove it, wring it out and dry it. Q [Table 9] Treatment agent bacterial count Remarks control (not treated) Aspergillus fumigatus 10 or less phytopathogenic bacteria Trichophyton rubrum 1.60E+04 Surface infection bacteria (foot, 颂癣) Kao Humming Flare Treatment of 10 strains of Phytopathogenic bacterium, Rhizoctonia solani, 3.00E+03, surface-infected bacteria (ankle, stubborn), Phytophthora capsici, 1.40E+03 Phytopathogenic bacteria surface multi-functional treatment composition (30 times) treatment without bacteria 0 It is known that by using the surface multifunctional treatment composition of the present invention, the bacteria present in the control and the bacteria treated by Humming Flare remain 152976.doc -25-201139653 All killed, so the bacteria could not be detected, and the state of the scorpion was cleaned. Further, the socks for the test were subjected to antibacterial and deodorant processing, and since Humming Flare was used, the antibacterial and deodorizing functions were imparted, and the proliferation and odor suppression of the bacteria were not effective. Example 10 The results of the measurement of the number of bacteria on the mop used for the toilet cleaning and the test results relating to the odor were prepared for the same type of mop (Teramoto, FX mop head (J)), and for one of them, the tap water will be used as an example. The surface multifunctional treatment composition N 〇. 3 was diluted to 30 times and immersed for 15 minutes, then thoroughly rinsed with tap water and dried for processing, and the other was used as a control mop without treatment, using 2 The number of bacteria was measured after the month. The use of the mop is used in a normal cleaning twice a day, and is washed by washing with a scrubbing agent for cleaning the ground. [Table 10] Treatment agent bacterial count Remarks control (not treated) Escherichia coli 100 or less coliform Saccharomyces Serpins 3.90E+05 Baker's yeast Trichophyton rubid 2.40E+04 Surface infection bacteria (ankle, stubborn) Surface Multi-functional treatment composition (30 times) treatment without bacteria 0 A large amount of bacteria such as body surface infection bacteria are present on the mop which is not treated, and the mop which is treated by the surface multifunctional treatment composition is even After cleaning for 2 months in the toilet, bacteria were not detected and cleaned. Example 11 152976.doc -26- 201139653 Ceramic tile (Ceramica Cleopatra "Hi-Tec Stone OZ-4600") antibacterial property measurement result surface multifunctional treatment agent composition treatment method: washing the ceramic tile with detergent After drying, the surface multifunctional treatment composition of the examples was diluted to 5 times with tap water and applied, and after 5 minutes, it was washed with water and dried. [Table 11] Initial bacterial count Escherichia coli Surface multifunctional treatment composition No. 2 1.3χ10Ε+6 100 or less Surface multifunctional treatment composition Νο·3 10 or less surface multifunctional treatment composition Νο.4 10 or less Pseudomonas agerugiosa surface multifunctional treatment composition Νο.2 1.3χ10Ε+6 100 or less surface multifunctional treatment composition No.3 10 or less surface multifunctional treatment composition Νο.4 10 below yellow Staphylococcus Staphylococus aureus surface multifunctional treatment composition No. 2 1.5χ10Ε+6 100 or less surface multifunctional treatment agent composition No. 3 10 or less surface multifunctional treatment agent composition Νο·4 10 or less

[Table 12] Initial bacteria number Coliform Escherichia coli Treatment composition No. 1 1.3χ10Ε+6 100 or more treatment composition Νο.4 100 or more treatment composition No. 5 1.0x10 Pseudomonas agerugiosa treatment agent Composition No. 1 1.3χ10Ε+6 1.0x10 Treatment composition Νο.4 100 or more treatment composition Νο·5 1.5x10 Staphylococcus aureus treatment composition No. 1 1.5χ10Ε+6 100 or more treatment agent combination Νο.4 100 or more treatment agent composition Νο. 5 100 or more. In this test, the culture conditions for determining the number of bacteria are: Coconsin using MacConkey II agar medium, Pseudomonas aeruginosa and Staphylococcus aureus using OPA Staphylococcal medium was cultured for 1 day. After diluting with a diluent in a paper filter, it was dried at room temperature as a sample of 152976.doc -27-201139653. One ml of the test bacterial solution was transplanted onto the sample, and rinsed during the culture period of each strain to measure the number of bacteria. In the example using the composition of the present invention shown in Table ,, any of the ceramic tiles has a result that the number of bacteria after the treatment is 10 or less or 1 or less. This result means that if the ceramic monument is treated with the composition of the present invention, the antibacterial effect can be surely exhibited, and the description of other examples and the like clearly indicates that the processed material containing various materials other than the ceramic brick is also Can achieve the same effect. On the other hand, as shown in the above Table 12, a treatment agent as a comparative example using a composition equivalent to laurylamine propyl dimethylamine oxide as a guanamine amine oxide is used in the composition of the present invention. When the composition of *N〇1, 4, and 5 is combined, although some degree of antibacterial property is actually exhibited depending on the bacteria of the target, the antibacterial property is remarkably worse than that of the composition of the present invention shown in Table 丨丨. The effect obtained. From these results, it has been revealed that the reason why the composition of the present invention exerts antibacterial properties is not simply that it contains gasified ten people of dimethyl dimethyl (3 - trimethoxy oxalate) or gasified octadecyl group. Dimethyl (3-triethoxydecylpropyl) ammonium, but exhibits excellent antibacterial properties by also containing amidoxime amine oxide. Example 12 Ceramic tile (Ceramica cle〇patra "Hi Tec & View (9)") Water-repellent/oil-repellent-related test results Surface multifunctional treatment composition treatment method: Washing and washing ceramic tiles with detergent After drying, the surface multifunctional treatment composition Νο·3 of the example was diluted to 5 times with tap water and coated for 5 minutes, then washed with water and added 152976.doc -28-201139653, and the dried pair was subjected to the treatment. The contact angle of water was determined between the ceramic tile and the untreated ceramic tile under the following conditions. [Table 13]

According to the results, it is understood that the surface of the ceramic tile coated with the surface multifunctional treatment composition is improved in water repellency and oil repellency. * The contact angle was measured using a Dr〇pMaster 5 〇〇 image processing type. The solid-liquid interface analysis system (manufactured by Kyowa Interface) was carried out at 23 ° and 5 〇 % RH. Further, using the treatment composition Nos. 1, 4 and 5 of the above-mentioned surface 丨 2 which is a comparative example without a guanamine amine oxide, the ceramsite was treated in the same manner, and the distilled water was measured under the above conditions. Contact angle. [Table 14] Contact angle (°) Treatment composition No. 1 88 Treatment composition N〇.4 85 Treatment composition No. 5 Γ 90 The above Table 13 has been carried out by the present invention. The contact angle of the surface of the ceramic tile treated with distilled water was 96. On the other hand, the surface of the ceramics of the treatment composition No. 1, 4, and 5 containing no laurylamine dimethyl dimethylamine as a kind of guanamine amine oxide described in Table 14 was steamed. The contact angle of Heshui is only 90 when it is high. . The result indicates that the effect of water repellency obtained by the present invention is not simply by formulating octadecyldimethyl(3-trimethoxydecylpropyl)ammonium chloride 152976.doc -29-201139653 or gasification ten The effect obtained by octadecyldimethyl(3-triethoxydecylpropyl)ammonium is further enhanced by the effect of the amine oxide amine. Example 13 Test results relating to water repellency in a cleaning load test Three sheets of the same kind of glass plate were prepared, one piece was untreated, and the surface multifunctional treatment agent composition No. 3 of the example was diluted to 5 times with a tap water. The cloth was spread on the other two glass plates, and after 5 minutes, it was washed with distilled water and dried. Measuring the contact of the coated surface with water in one of the obtained two glass plates

For the other piece, the following additional cleaning test was carried out to measure the contact angle of water on the coated surface after the test. [Table 15] Untreated surface multi-functional treatment composition (5 times) treated contact angle (.) Salad oil 38 „ J 97 ------- _ / can / no additional post-test LZT 87 ^ This result can be understood as a 'glass plate and t, and the water repellency is improved by applying the surface multifunctional treatment composition of the present invention, and the durability of the effect is high. Further, if the contact after the cleaning load test is viewed, The value of the angle is as high as 87 after the harsh test of making the white pad reciprocating 7 times. The value of the surface multi-functional group of the present invention is evenly washed. It is still possible to maintain a high degree of water repellency. ※The cleaning load test is based on the durability (friction) of the mold (four) valence surface multi-functional treatment agent group. 'Use m K392 〇 floor soil test party 19, detergent resistance C) Test machine, installed Sumitomo 3M manufacturing 于 under the pressure of 1GGG g, at a speed of 37 round trips / minute, while no] 52976.doc -30- 201139653 dripping water while driving back and forth 7 000 times. Example 14 Tao Determination of the coefficient of friction of the brick (using the resistance value Test machine) Test results of friction coefficient measurement of ceramic brick (Ceramica Cleopatra "Hi-Tec Stone OZ-4600") Surface multi-functional treatment composition treatment method: After washing and drying the ceramic brick with detergent, The surface multifunctional treatment agent composition No. 3 of the example was diluted to 2.5 times with tap water and applied, and after 5 minutes, it was washed with water and dried. [Table 16] Surface resistance value (Ω) Ceramic tile: Surface multifunctional treatment agent composition (2.5 times dilution contact for 15 minutes) Friction coefficient contact angle static friction coefficient (μδ) Dynamic friction coefficient (μΚ) Distilled water salad oil untreated 2χ10Ε+10 0.316 0.293 61 25 Processed product 7χ10Ε+9 0.264 0.246 96 46 treated product and long-term negative 3.5何10Ε+9 0.216 0.187 - - 陶Ceramic brick processed by surface multifunctional treatment composition ( The treated product) has a static friction coefficient and a dynamic friction coefficient, and the smoothness of the surface is improved. This improvement in smoothness means, for example, that the smoothness of the cleaning tool such as the mop is improved when the surface of the ceramic tile is cleaned, and the effect of reducing the force of the cleaning operation is exhibited at the same time as the water repellent and the oil repellent effect. Further, in the case where the surface multifunctional treatment composition is treated, even if a cleaning durability load is applied, the friction coefficient does not become high, and it is understood that the durability is high. * The coefficient of friction was measured by mounting a cotton cloth on the surface measuring device HEIDON-14 ASTM flat head, and measuring it under the conditions of a moving speed of 75 mm/min and a load of 500 g of 152976.doc -31 · 201139653. For the purpose of simulating the durability (friction) of the surface multi-functional treatment composition, the JIS K3 920 floor wax test method, 19, detergent-resistant C) cleaning test machine, and the white pad manufactured by Sumitomo 3M were used for pressing. At a mass of 1000 g, at a rate of 37 round trips per minute, the vehicle is driven back and forth 7000 times while continuously dripping water. [Table 17] The coefficient of friction has no treatment and the durability is negative. The static friction coefficient (μδ) The dynamic friction coefficient (μΚ) The static friction coefficient (μδ) The dynamic friction coefficient (μΚ) The treatment composition No. l 0.275 0.269 0.295 0.305 Treatment composition No. 4 0.269 0.235 0.293 0.281 Treatment composition No. 5 0.275 0.263 0.305 0.290 Each of the examples shown in Table 17 of the comparative example is applied before the durability load of the treated product, The embodiment of the present invention shown in Table 1 6 shows the same degree of static friction coefficient and dynamic friction coefficient, but the static friction coefficient and the dynamic friction coefficient are higher than those before the application of the load after the durability load of the treated product is applied. It is shown that when the surface of the ceramic tile treated by the composition of the present invention is used, even if the ceramic tile is repeatedly washed, the force necessary for rubbing is less. On the contrary, from the results of Table 17, it can be understood that if a composition other than the composition of the present invention is used, the mop for wiping the surface of the ceramic tile is cleaned when the ceramic tile is cleaned with repeated cleaning. The force exerted by the cleaning device increases. The present invention is shown by octadecyldifluorenyl (3-trimethoxyfluorene 152976.doc -32-201139653 alkylpropyl)ammonium chloride and octadecyldimethyl chloride (3- In addition to triethoxy decyl propyl) ammonium, a guanamine amine oxide is added, and even if it is continuously used, the static friction coefficient and the dynamic friction coefficient of the treated surface are prevented from increasing, and the cleaning of the treated surface becomes easy. Example 15 Measurement Results of Friction Coefficient of Glass Plate (Using Resistance Value Measurement Tester) Surface Multi-Function Treatment Composition Treatment Method: After washing and drying the glass plate with a detergent, the surface multifunctional treatment agent of the example was treated with tap water. Composition No. 3 was diluted to 20 times and coated, and after 5 minutes, it was washed with water and dried. [Table 18] Surface resistance value (Ω) Glass plate · · Surface multi-function (2.5 times dilution of de-energizing agent composition Μ 15 minutes) Friction coefficient contact angle static friction coefficient (μδ) Dynamic friction coefficient (μΚ) Steaming water color Pull oil untreated 2χ10Ε+10 0.316 0.293 61 25 Treatment item 7χ10Ε+9 0.264 0.246 96 46 Treatment and long-term load 1 3.5χ10Ε+9 0.216 0.187 - - Treated by surface multifunctional treatment composition The surface resistance of the glass plate system decreases, and the static friction coefficient and the dynamic friction coefficient decrease, and the smoothness of the surface is improved. This improvement in smoothness means, for example, that the smoothness of the cleaning tool such as a rag is improved when the glass surface is cleaned, so that the effect of reducing the force of the cleaning operation is exerted at the same time as the water repellency and the oil repellency. * The coefficient of friction was measured by mounting a cotton cloth on the surface measuring device HEIDON-14 ASTM flat head, and measuring at a moving speed of 75 mm/min and a load of 500 g. 152976.doc -33- 201139653 Example 16 Determination of friction coefficient of floor tiles (using resistance value measuring test machine) Surface multifunctional treatment agent composition treatment method: Washing floor tiles with detergent (Tajima, Genius Plain, GE -1100) After washing, the example surface multifunctional treatment composition No. 3 of the example was diluted to 5 times with tap water and applied, and after 15 minutes, it was washed with water and dried. [Table 19]

Genius Plain (black) blue pad treatment monument · surface multifunctional treatment agent composition surface resistance value (Ω) (2.5 times dilution contact 15 minutes) friction coefficient static friction coefficient dynamic friction coefficient (μδ) (μΚ) untreated 2χ10Ε+ 10 0.373 0.323 treated product 7χ10Ε+9 0.33 0.295 For floor tiles, the surface resistance value of the treated body is also reduced by the surface multifunctional treatment composition, thereby reducing the accumulation of static electricity and contributing to the reduction of The problem caused by static electricity. Example 17 Test results relating to odor resistance (Part 1) [Results in the state where urine was applied to porcelain tile] Treatment method: A. After cleaning the porcelain brick with a neutral detergent, it was washed with water and dried. B. Wash and dry the 90 mm square porcelain tile with a detergent, and apply 1 g of kireinomisuto (registered trademark) made of Lion (gauze) to a ultrasonic cleaning machine (BRANSONIC B1200) with tap water. The mixture was washed at 30 ° C for 30 minutes, washed with water and dried. 152976.doc -34- 201139653 c. After cleaning the porcelain bricks, the surface multifunctional treatment agent composition No. 3 of the example was diluted to 5 times with tap water, coated with 1 g, washed with water and dried after 10 minutes. .

D. After cleaning the porcelain brick, the surface multifunctional treatment agent composition No. 3 of the example was diluted to 5 times with tap water, and 1 g was applied. After 10 minutes, it was washed with water and dried to obtain the obtained porcelain. The bricks were washed in a ultrasonic cleaning machine (BRANSONIC B1200) with tap water at 30 ° C for 30 minutes, washed with water and dried. [Table 20] Thermostat (35 ° C) Room temperature at room temperature 5 hours 10 hours 24 hours 10 days control (untreated) (A) 0 25 50 500 Lion, kireinomisuto (Ultrasonic cleaning) (B) 25 50 100 500 surface multifunctional treatment composition (5 times dilution) (C) 0 25 50 200 ppm surface multifunctional treatment composition (5 times dilution) + ultrasonic cleaning (D) 0 25 50 250 (Note: Value is When the concentration of ammonia is treated by kireinomisuto manufactured by Lion, there is no change compared with the control, and when the surface multifunctional treatment composition of the present invention is treated, although There was no significant change due to the presence or absence of ultrasonic cleaning, but the concentration of ammonia decreased as compared with the treatment with kireinomisuto. Further, in the treatment of the surface multifunctional treatment composition of the present invention, the concentration of ammonia was as high as that in the period up to 24 hours as compared with the control, but the concentration of ammonia was lowered after standing at room temperature for 10 days. ※ Apply 2 ml of urine to the entire surface of the porcelain bricks with gauze and place in room 152976.doc -35· 201139653 for 6 hours. Thereafter, it can be sealed with polyethylene with a total capacity of 1 800 ml. A porcelain No. 3D gas detection tube (Passive DosiTube) manufactured by Gastec was placed in the container, and the ammonia concentration of the detection tube was read. Example 18 [Results in a state in which a urine is placed in a glass bottle] Surface multifunctional treatment composition treatment method: 2 types of wide-mouthed melon bottles having a total volume of 450 ml were prepared, and the surface of the example was multifunctional with tap water. The treatment composition Νο·3 was diluted to 5 times, placed in 5 ml, contacted throughout the inner surface, placed for 10 minutes, rinsed with running water and dried, and the other bottle was rinsed with running water and dried, followed by 3 ml of urine was placed in each bottle, placed in the room for 6 hours, and then sealed, placed in a Gas No. 3D gas detection tube (Passive DosiTube) manufactured by Gastec, and the ammonia concentration of the detection tube was read. [Table 21] Thermostat (35 ° C) Room temperature for 5 hours ^ 10 hours 24 hours 10 days 14 days of control (untreated) ~ 0 25 50 200 500 Surface multifunctional treatment composition (5 times dilution) 0 25 50 150 300 In the case of treatment by the surface multifunctional treatment composition of the present invention, the effect of the short period of the high temperature period compared with the control is not particularly remarkable, but is left at room temperature for 10 days and 14 days. In the case of a long period of time, the concentration of ammonia is suppressed to be lower than that of the control, and the effect of suppressing the generation of malodor can be exhibited. Example 19 Determination of Friction Coefficient of Wall Mop Test Results Test Method: The test piece (90 x 70 mm) was set in HEIDON (surface 152976.doc -36-201139653 measuring machine) at a load of 0.5 kg, 1 50 mm/min. The measurement was carried out under the conditions. As a test piece, the mop is made of a flat mop (manufactured by Hanwa Co., Ltd.) and Teramoto (shared). Surface multifunctional treatment agent treatment method: The surface multi-functional treatment agent No. 3 of the example was diluted to 5 times with tap water, and the mop was impregnated for 10 minutes, washed, and dried. Dry refers to drying. The floor screw impregnated by the mop was used to measure the Luster·VX manufactured by Suisho Petrochemical Industry (I) in a moton equivalent to 15 ml/m2. [Table 22-1] Results of control (untreated) Flat drag ^ Ba (Sakae) Teramoto Static friction coefficient (μδ) Dynamic friction coefficient (μΚ) Static friction coefficient (μδ) Dynamic friction coefficient (μΚ) Dry 0.402 0.300 0.383 0.277 Luster VX (15 ml) 0.569 0.430 0.509 0.397 [Table 22-2] Results of surface multi-functional treatment (5-fold dilution) flat drag; 'Bar (Sakae) Teramoto static friction coefficient dynamic friction coefficient (μΚ) static friction coefficient dynamic friction coefficient (μΚ) Dry 0.290 0.236 0.287 0.242 Luster VX (15 ml) 0.466 0.373 0.439 0.348 As shown in Tables 22-1 and 22-2, it can be understood that both mops are impregnated with Luster and have no static friction coefficient and dynamic friction coefficient. If the mop is impregnated with wax, the friction coefficient will increase, so the force of 152976.doc -37-201139653 for pushing the mop is required. 5 It is understood that the two types of mops which have been subjected to the surface multifunctional treatment agent of the present invention are compared with those of the untreated ones, and the number of static friction and movement (four) of the dryer and the treated person become low. As a result, the mop treated by the surface multifunctional treating agent of the present invention can be used with less force, whether it is a dryer or a Lifter. In addition, in addition to the above-described friction coefficient measurement test, the actual use of the ground, the actual use of the mops by six people to personally experience the coating test 'can also confirm that the same as the above test results, the surface of the multi-functional treatment agent mop Underneath, you can feel it lighter, and if the amount of floor wax is fixed, it can be coated with a wider area. Example 20 Antifouling Test Results of Floor-Coated Surfaces 300 mm x 105 mm of floor tiles (manufactured by Tajima, Genius Plain, GE-1100) were washed with a washing agent, washed with water, dried, and coated with gauze. Luster.VX manufactured by Suisho Petrochemical Industry (stock) in an amount equivalent to 15 ml/m2 three times. The surface multifunctional treatment composition No. 3 of the example was diluted to 50 times with tap water. The surface of the tile was coated with gauze at a rate of 15 ml/m 2 for 10 minutes, washed with water and dried. Thereafter, according to the JISK 3920 2009 floor failure test method, the heel print test was compared with the untreated floor material. [Table 23] Resistance to heel print (number of heel prints) Untreated 8 Once processed 3 152976.doc -38- 201139653 Record 2:5 No J segment liver> 訾 訾 秘 secret + Lord z & The surface of the multi-functional treatment agent is added to the surface, and the heel impression (4) is less. This situation is beneficial for the ground maintenance and the removal of the γι color or the re-snoring of the ground. It’s a long life, so it’s very clean.

152976.doc •39·

Claims (1)

201139653 VII. Patent application scope: A surface multifunctional treatment composition containing 0 01 to 10 weight. / 〇 〇 十八 炫 炫 dimethyl dimethyl (3-trimethoxy decyl propyl) ammonium and / or octadecyl dimethyl (3-triethoxy decyl propyl) ammonium chloride 2 to 8 wt% of a guanamine amine oxide as a surfactant, a hexamethylene biguanide compound of 1 to 5 wt% of hydrazine, and an alcohol and water (excluding an algae production inhibitor for inhibiting algae production). 2. The surface multifunctional treatment composition of claim 1, wherein the above amine amine oxide is lauryl propyl dimethyl amine oxide. The surface multifunctional treatment composition according to claim 1 or 2, which is further stabilized in the range of 2 C to 50 ° C for 1 week or more. 〇 152976.doc 201139653 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the characteristics that can best show the invention. Chemical formula: (none) 152976.doc